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Topic 4.2
4.2 Moles -- Question 3
3

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11 The
The formula
formula for the arsenate(
for the V) ion
arsenate(V) ion is AsO43–. Complete
is As043-. Complete the
the ionic
ionic equation for the
equation for the
formation of
formation of copper( II) arsenate(
copper(ll) V).
arsenate(V).

3 [2]
......Cu
Cu2+ +
2+ 2.....As043-
+ ......AsO 4
3–
→ Cu 3(AsO4)2
.................................. [2]

2
2 Natural
Natural gas
gas may
may contain
contain small
small amounts
amounts of
of hydrogen
hydrogen sulphide,
sulphide, H2S.
H2S.

(i)
(i) Complete the symbol
Complete the symbol equation for the
equation for the combustion
combustion of
of hydrogen
hydrogen sulphide.
sulphide.

2 H
..... 3 02 →
2S +
H2S + .....
..... O 2 -9 2H2O +
2H20 2SO2
+ 2S02 [2]
[2]

3
3 Complete the
the equation to show the
equation to the formation
formation of
of nickel
nickel ions
ions from
from nickel.
nickel.

2 e-
Ni → Ni2+ + ... [1]

4
4 Using
Using 25.0
25.0 cm
cm3 of
3
of aqueous
aqueous lithium
lithium hydroxide,
hydroxide, concentration
concentration 2.48
2.48 mol / dm3, 2.20
mol/dm3, 2.20gg of
of hydrated
hydrated
lithium
lithium sulfate was obtained.
sulfate was obtained.
Calculate
Calculate the
the percentage yield, giving
percentage yield, your answer
giving your answer to
to one
one decimal
decimal place.
place.

2LiOH
2LiOH +
+ H2SO4 → Li
H2S04 2SO4 +
Li2S04 + 2H 2O
21-420

Li 2SO4 +
Li2S04 + H2O → Li
H20 2SO4.H2O
Li2S04.H20

Number
Number of
of moles
moles of
of LiOH
LiOH used
used = 0.062
= .......................

0.031
Number
Number of
of moles
moles of
of Li 2SO4.H2O which
Li2S04.H20 which could
could be
be formed
formed =
= .......................

Mass
Mass of
of one
one mole
mole of
of Li 2SO4.H2O =
Li2S04.H20 = 128
128gg
3.97g
Maximum yield of
Maximum yield of Li 2SO4.H2O =
Li2S04.H20 = ....................... g

Percentage yield =
Percentage yield = .......................%
55.4 [4]
[4]
 5 Benzene contains
contains 92.3% of
of carbon
carbon and its
its relative
relative molecular
molecular mass is
is 78.
78.

(i)
(i) What is the percentage
is the percentage of
of hydrogen
hydrogen in
in benzene?
benzene?

7.7% [1]

(ii) Calculate
Calculate the
the ratio
ratio of
of moles of
of C atoms:
atoms: moles of
of H atoms in
in benzene.
benzene.

1:1

[2]
[2]

(iii)
(iii) Calculate
Calculate its
its empirical
empirical formula
formula and
and then
then its
its molecular formula.
molecular formula.

The empirical CH
empirical formula
formula of
of benzene is
is

The molecular formula of

molecular formula of benzene is
is
C6H6 [2]
[2]

6
6 Quantities
Quantities of
of chemicals,
chemicals, expressed
expressed in
in moles,
moles, can
can be
be used
used to find the
to find formula of
the formula of a
a
compound,
compound, to
to establish
establish an
an equation
equation and
and to
to determine
determine reacting
reacting masses.
masses.

(a)
(a) A compound
compound contains
contains 72% magnesium
magnesium and
and 28% nitrogen. What is
nitrogen. What is its
its empirical
empirical
formula?
formula?

Mg3N2

[2]
[2]