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Chemical kinetics
The rate of a reaction is expressed in different ways as follows :

+1 d [C] -1 d [D] d [A] - d [B]

= = +1 =
2 dt 3 dt 4 dt dt

The reaction is :

A 4A + B → 2C + 3D

B B + 3D → 4 A + 2 C

C A+B→ C+D

D B+D → A+C
The rate of a reaction is expressed in different ways as follows :

+1 d [C] -1 d [D] d [A] - d [B]

= = +1 =
2 dt 3 dt 4 dt dt

The reaction is :

A 4A + B → 2C + 3D

B B + 3D → 4 A + 2 C

C A+B→ C+D

D B+D → A+C
 For a reaction pA + qB → products, the rate law expression is
r = k [A]m [B]n then

A (p + q) ≠ (m + n)

B (p + q) = (m + n}

C (p + q) may or not be equal to (m + n)

D (p + q) > (m + n)
 For a reaction pA + qB → products, the rate law expression is
r = k [A]m [B]n then

A (p + q) ≠ (m + n)

B (p + q) = (m + n}

C (p + q) may or not be equal to (m + n)

D (p + q) > (m + n)
 The rate of reaction increases with increase of temperature
because

A fraction of reactant molecules having sufficient energy increases.

B the average energy of the products increases

C threshold energy changes

D activation energy is lowered

 The rate of reaction increases with increase of temperature
because

A fraction of reactant molecules having sufficient energy increases.

B the average energy of the products increases

C threshold energy changes

D activation energy is lowered

 The rate of reaction is doubled for every 10oC rise in
temperature. The increase in rate as result of increase in
temperature from 10oC to 100oC is :

A 112

B 512

C 400

D 256
 The rate of reaction is doubled for every 10oC rise in
temperature. The increase in rate as result of increase in
temperature from 10oC to 100oC is :

A 112

B 512

C 400

D 256
Electrochemistry
 The standard free energy change for the following reaction
is – 210 kJ. What is the standard cell potential ?
2H2O2(aq) → 2H2O(l) + O2(g)

A + 0.752

B + 1.09

C + 0.420

D + 0.640
 The standard free energy change for the following reaction
is – 210 kJ. What is the standard cell potential ?
2H2O2(aq) → 2H2O(l) + O2(g)

A + 0.752

B + 1.09

C + 0.420

D + 0.640
 Co | Co2+ (C2) || Co2+ (C1) | Co for this cell, ΔG is negative if :

A C2 > C1

B C1 > C2

C C1 = C,

D unpredictable
 Co | Co2+ (C2) || Co2+ (C1) | Co for this cell, ΔG is negative if :

A C2 > C1

B C1 > C2

C C1 = C,

D unpredictable
 How many electrons are delivered at the cathode during
electrolysis by a current of 1A in 60 seconds ?

A 3.74 × 1020

B 6.0 × 1023

C 7.48 × 1021

D 6.0 × 1020
 How many electrons are delivered at the cathode during
electrolysis by a current of 1A in 60 seconds ?

A 3.74 × 1020

B 6.0 × 1023

C 7.48 × 1021

D 6.0 × 1020
 If x specific resistance (in S–1 cm) of the electrolyte solution
and y is the molarity of the solution, then ∧m(in S cm2 mol–1) is
given by :

A 1000x / y

B 1000 (x/y)

C 1000/xy

D xy/1000
 If x specific resistance (in S–1 cm) of the electrolyte solution
and y is the molarity of the solution, then ∧m(in S cm2 mol–1) is
given by :

A 1000x / y

B 1000 (x/y)

C 1000/xy

D xy/1000
Solid state
 In fcc lattice, the neighbouring number of atoms for any
lattice point is

A 6

B 8

C 12

D 14
 In fcc lattice, the neighbouring number of atoms for any
lattice point is

A 6

B 8

C 12

D 14
 An alloy of Cu, Ag and Au is found to have copper constituting
the ccp lattice. If silver atoms occupy the edge centre and gold
is present at body centre, the alloy has a formula

A Cu4 Ag2 Au

B Cu4 Ag2 Au

C Cu4 Ag3 Au

D CuAgAu
 An alloy of Cu, Ag and Au is found to have copper constituting
the ccp lattice. If silver atoms occupy the edge centre and gold
is present at body centre, the alloy has a formula

A Cu4 Ag2 Au

B Cu4 Ag2 Au

C Cu4 Ag3 Au

D CuAgAu
 Potassium has a bcc structure with nearest neighbour
distance 4.52 Å. Its atomic weight is 39. Its density will be

A 454 kg m–3

B 804 kg m–3

C 852 kg m–3

D 908 kg m–3
 Potassium has a bcc structure with nearest neighbour
distance 4.52 Å. Its atomic weight is 39. Its density will be

A 454 kg m–3

B 804 kg m–3

C 852 kg m–3

D 908 kg m–3
 Which of the following statements is not true about NaCl
Structure :

A Cl– ions are in fcc arrangement

B Na+ ions have coordination number 4

C Cl– ions has coordination number 6

D Each unit cell contains 4NaCl molecules

 Which of the following statements is not true about NaCl
Structure :

A Cl– ions are in fcc arrangement

B Na+ ions have coordination number 4

C Cl– ions has coordination number 6

D Each unit cell contains 4NaCl molecules

Redox
 The oxidation state of chromium in Cr(CO)6 is :

A 0

B +2

C -2

D +6
 The oxidation state of chromium in Cr(CO)6 is :

A 0

B +2

C -2

D +6
 In which of the following pairs, there is greatest difference in the
oxidation number of the underlined elements?

A NO2 and N2O4

B P2O5 and P4O10

C N2O and NO

D SO2 and SO3

 In which of the following pairs, there is greatest difference in the
oxidation number of the underlined elements?

A NO2 and N2O4

B P2O5 and P4O10

C N2O and NO

D SO2 and SO3

 In the following reaction :
NO3- + As2S3 + H2O → AsO43- + NO + SO42-
the equivalent weight of As2S3(with molecular weight M)is :

A 3M/28

B M/4

C M/24

D M/28
 In the following reaction :
NO3- + As2S3 + H2O → AsO43- + NO + SO42-
the equivalent weight of As2S3(with molecular weight M)is :

A 3M/28

B M/4

C M/24

D M/28
 The volume strength of 1.5 N H2O2 solution is :

A 4.8

B 8.4

C 3.0

D 8.0
 The volume strength of 1.5 N H2O2 solution is :

A 4.8

B 8.4

C 3.0

D 8.0
Thermodynamics
 An ideal gas receives 10 J of heat in a reversible isothermal
expansion. Then the work done by the gas :

A would be more than 10 J

B 10 J

C would be less than 10 J

D Cannot be determined
 An ideal gas receives 10 J of heat in a reversible isothermal
expansion. Then the work done by the gas :

A would be more than 10 J

B 10 J

C would be less than 10 J

D Cannot be determined
 For a reversible process at equilibrium, the change in
entropy may be expressed as :

A ΔS = Tqrev

B ΔS = qrev / T

C ΔS = -ΔH / T

D ΔS = ΔG
 For a reversible process at equilibrium, the change in
entropy may be expressed as :

A ΔS = Tqrev

B ΔS = qrev / T

C ΔS = -ΔH / T

D ΔS = ΔG
 Which of the following conditions is not favourable for
the feasibility of a process ?

A ΔH = –ve, TΔS = –ve and TΔS <

ΔH

B ΔH = +ve, TΔS = +ve and TΔS > ΔH

C ΔH = –ve, TΔS = +ve and TΔS < ΔH

D ΔH = +ve, TΔS = +ve and TΔS < ΔH

 Which of the following conditions is not favourable for
the feasibility of a process ?

A ΔH = –ve, TΔS = –ve and TΔS <

ΔH

B ΔH = +ve, TΔS = +ve and TΔS > ΔH

C ΔH = –ve, TΔS = +ve and TΔS < ΔH

D ΔH = +ve, TΔS = +ve and TΔS < ΔH

 An imaginary reaction X → Y takes place in three steps :
X → A, ΔH = –q1 ; B → A, ΔH = –q2 ; B → Y , ΔH = –q3
If Hess’ law is applicable, then the heat of the reaction
(X → Y) is:

A q1 – q2 + q3

B q2 - q3- q1

C q1 - q2 - q3

D q3- q2- q1
 An imaginary reaction X → Y takes place in three steps :
X → A, ΔH = –q1 ; B → A, ΔH = –q2 ; B → Y , ΔH = –q3
If Hess’ law is applicable, then the heat of the reaction
(X → Y) is:

A q1 – q2 + q3

B q2 - q3- q1

C q1 - q2 - q3

D q3- q2- q1
Chemical equilibrium
 The suitable expression for the equilibrium constant of the reaction
2NO (g) + Cl2(g) ⇌ 2NOCl (g) is :

[2NOCl] B [NOCl]2
A KC = KC =
[2NO] [Cl2] [NO]2 [Cl2]

[NOCl]2 [NOCl]2
C KC = D KC =
[NO] [Cl2]2 [NO]2 [Cl2]2
 The suitable expression for the equilibrium constant of the reaction
2NO (g) + Cl2(g) ⇌ 2NOCl (g) is :

[2NOCl] B [NOCl]2
A KC = KC =
[2NO] [Cl2] [NO]2 [Cl2]

[NOCl]2 [NOCl]2
C KC = D KC =
[NO] [Cl2]2 [NO]2 [Cl2]2
 In which of the following, the reaction proceeds towards
completion :

A K = 103

B K = 10-2

C K = 10

D K=1
 In which of the following, the reaction proceeds towards
completion :

A K = 103

B K = 10-2

C K = 10

D K=1
 In which of the following equilibria, the value of Kp is less than Kc :

A H2+ I2 ⇌ 2HI

B N2 + 3H2 ⇌ 2 NH3

C N2 + O2 ⇌ 2NO

D CO + H2O ⇌ CO2 + H2
 In which of the following equilibria, the value of Kp is less than Kc :

A H2+ I2 ⇌ 2HI

B N2 + 3H2 ⇌ 2 NH3

C N2 + O2 ⇌ 2NO

D CO + H2O ⇌ CO2 + H2
 What is the effect of halving the pressure by doubling the
volume on the following system at 500°C
H2+ I2 ⇌ 2HI

A Shift to product side

B Shift to product formation

C Liquification of HI

D No effect
 What is the effect of halving the pressure by doubling the
volume on the following system at 500°C
H2+ I2 ⇌ 2HI

A Shift to product side

B Shift to product formation

C Liquification of HI

D No effect
Ionic equilibrium
 For a weak acid HA, Ostwald’s dilution law is represented by the
equation :

B α2c
A Ka =
αc Ka =
1 - α2 1-α

Kac α2c
C Ka = D Ka =
1-c 1 - α2
 For a weak acid HA, Ostwald’s dilution law is represented by the
equation :

B α2c
A Ka =
αc Ka =
1 - α2 1-α

Kac α2c
C Ka = D Ka =
1-c 1 - α2
 The principal buffer present in human blood is :

A (a) NaH2PO4 + Na2HPO4

B H3PO4+ NaH2PO4

C CH3COOH + CH3COONa

D H2CO3+ HCO3-
 The principal buffer present in human blood is :

A (a) NaH2PO4 + Na2HPO4

B H3PO4+ NaH2PO4

C CH3COOH + CH3COONa

D H2CO3+ HCO3-
 Let the solubility of an aqueous solution of Mg(OH)2 be x then its
ksp is :

A 4x3

B 108x5

C 27x4

D 9x
 Let the solubility of an aqueous solution of Mg(OH)2 be x then its
ksp is :

A 4x3

B 108x5

C 27x4

D 9x
Structure of atom
 According to Bohr’s atomic theory , which of the following is
correct ?

A Potential energy of electron ∝ Z2 / n2

B The product of velocity of electron and principle quantum number ∝ Z2

C Frequency of revolution of electron in an orbit ∝ Z2 / n3

D Coulombic forces of attraction on the electron ∝ Z2 / n2

 According to Bohr’s atomic theory , which of the following is
correct ?

A Potential energy of electron ∝ Z2 / n2

B The product of velocity of electron and principle quantum number ∝ Z2

C Frequency of revolution of electron in an orbit ∝ Z2 / n3

D Coulombic forces of attraction on the electron ∝ Z2 / n2

 No. of waves produced by an electron in one complete
revolution in nth orbit is :

A n

B n2

C (n+1)

D ( 2n + 1 )
 No. of waves produced by an electron in one complete
revolution in nth orbit is :

A n

B n2

C (n+1)

D ( 2n + 1 )
 The mass of an electron is m , charge is e and it is accelerated
from rest through a potential difference of V volts . The velocity
acquired by electron will be :

A (V / m)1/2

B (eV / m)1/2

C (2eV / m)1/2

D zero
 The mass of an electron is m , charge is e and it is accelerated
from rest through a potential difference of V volts . The velocity
acquired by electron will be :

A (V / m)1/2

B (eV / m)1/2

C (2eV / m)1/2

D zero
 If λo and λ be the threshold wavelength and the wavelength of
incident light , the velocity of photo-electrons ejected from the
metal surface is :

A [(2h / m) (λo-λ)] 1/2

B [(2hc / m) (λo-λ)] 1/2

C [ (2hc / m) ( (λo-λ) / (λoλ) ) ] 1/2

D [ (2h / m) ( (1 / λo) - (1 / λ) ) ] 1/2

 If λo and λ be the threshold wavelength and the wavelength of
incident light , the velocity of photo-electrons ejected from the
metal surface is :

A [(2h / m) (λo-λ)] 1/2

B [(2hc / m) (λo-λ)] 1/2

C [ (2hc / m) ( (λo-λ) / (λoλ) ) ] 1/2

D [ (2h / m) ( (1 / λo) - (1 / λ) ) ] 1/2

States of matter
 Which of the following curve does not represent Boyle’s law ?

Θ = 45O

A P↑ B logP ↑

V→ log(V-1) →

Θ = 135O D
C
logP ↑ PV ↑

log(V-1) → V→
 Which of the following curve does not represent Boyle’s law ?

Θ = 45O

A P↑ B logP ↑

V→ log(V-1) →

Θ = 135O D
C
logP ↑ PV ↑

log(V-1) → V→
 Densities of two gases are in the ratio 1 : 2 and their temperatures
are in the ratio 2 : 1, then the ratio of their respective molar mass
at certain pressure is :

A 1:1

B 1:2

C 2:1

D 4:1
 Densities of two gases are in the ratio 1 : 2 and their temperatures
are in the ratio 2 : 1, then the ratio of their respective molar mass
at certain pressure is :

A 1:1

B 1:2

C 2:1

D 4:1
 At a definite temperature(T) , the distribution of velocities is given by the
curve . The curve that indicates that the velocities corresponding to
points A, B and C are :

A Most probable , average and root mean square

B Average , root mean square and most probable

C root mean square , average and most probable

D Most probable , root mean square and average

 At a definite temperature(T) , the distribution of velocities is given by the
curve . The curve that indicates that the velocities corresponding to
points A, B and C are :

A Most probable , average and root mean square

B Average , root mean square and most probable

C root mean square , average and most probable

D Most probable , root mean square and average

 At low pressure , the van der Waals equation become :

A PVm = RT

B P(Vm-b) = RT

C ( P + (a/Vm2)) Vm = RT

D P = (RT / Vm) + (a/ Vm2)

 At low pressure , the van der Waals equation become :

A PVm = RT

B P(Vm-b) = RT

C ( P + (a/Vm2)) Vm = RT

D P = (RT / Vm) + (a/ Vm2)

 At a definite temperature (T), the distribution of velocities is given by
the curve> The curve that indicates that the velocities corresponding to
point A , B and are :

Fraction of molecules
A
B

C
A Most probable, average and root mean square

B Average, root mean square, and most probable

C root mean square, average and most probable

D Most probable, root mean square and average Velocity

 At a definite temperature (T), the distribution of velocities is given by
the curve> The curve that indicates that the velocities corresponding to
point A , B and are :

Fraction of molecules
A
B

C
A Most probable, average and root mean square

B Average, root mean square, and most probable

C root mean square, average and most probable

D Most probable, root mean square and average Velocity

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