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If the activation energy for the forward reaction is 60 kilocalories, then the activation energy
for the reverse reaction is
A. 30 kcal C. 40 kcal
B. 60 kcal D. 20 kcal
13. What is the reducing agent in the reaction?
A. Pb C. Ag+
B. NO3- D. Ag
14. Given the reaction:
Which concentration relationship is an indication that this reaction has reached equilibrium?
A. [A] equals [B] C. [A] [B] [C] and [D] is constant
B. [C] equals [D] D. [A] [B] [C] and [D is equal
15. Given the equilibrium system at 298 Kelvin:
The equilibrium constant for the reaction Ka will change if there is an increase in
A. concentration of HCO3--(aq) C. concentration of CO2(g)
B. temperature D. pressure
16. Given the reaction:
150 cm3 of water at 303 Kelvin was placed in an insulated flask, and the temperature
measured at 20 second intervals for 3 minutes. The results are shown on the graph below.
After 60 seconds, 0.1 mol of the compound NaX was added to the water.
Room temperature was 293 Kelvin throughout the experiment.
19. The enthalpy change when 1 mol of H2SO4 is formed according to the equation is given by
A. C C. B
B. A D. D
20. The equilibrium constant for the reaction is equal to
A. B C. D
B. C D. A
21. A mixture of SO2 and O2 at a fixed temperature reacts according to the equation
D.
B.
22. 1X1020 molecules of HI were introduced into a vessel of fixed volume at a particular
temperature. After some time there were 6.0 X 1019 molecules of HI, 2.0 X 1019 molecules
of I3 in the vessel. The temperature was unchanged and, at this temperature, the value of
the equilibrium constant for the reaction 2HI↔H2 + I2 is K = 2.0.
Which one of the following statements about the system is correct?
A. The system is not at equilibrium C. The system is at equilibrium
B. It is impossible to decide whether D. It is impossible to decide whether
the system is at equilibrium or not, the system is at equilibrium or not,
as K refers to concentrations as the temperature was not stated
expressed in mol dm -3 and the
volume of the vessel was not stated.
23. The addition of a catalyst to a system at equilibrium will increase the rate of
A. both forward and reverse reactions C. the reverse reaction only
B. neither the forward nor reverse D. the forward reaction only
reaction
24. Which type of reaction involves the transfer of electrons?
A. neutralization C. oxidation-reduction
B. alpha decay D. double replacement
25. The addition of a catalyst to a chemical reaction provides an alternate pathway that
A. decreases the activation energy C. decreases the potential energy of
B. increases the potential energy of reactants
reactants D. increases the activation energy
26. The reaction of an Arrhenius acid with an Arrhenius base produces water and
A. a halocarbon C. an aldehyde
B. an ester D. a salt
The graph shows that the reaction is at equilibrium after 60. seconds because the
concentrations of both NO2(g) and N2O4(g) are
A. increasing C. constant
B. decreasing D. zero
28. During photosynthesis, plants use carbon dioxide, water, and light energy to produce
glucose, C6H12O6, and oxygen. The reaction for photosynthesis is represented by the
balanced equation below.
All of the following state evidence that indicates photosynthesis is an endothermic reaction.
hich of the following is not true
A. The energy term is on the right side C. The reaction requires light.
of equation. D. Photosynthesis is an endothermic
B. ΔH is positive. reaction because light energy is
absorbed.
Early scientists defined oxidation as a chemical reaction in which oxygen combined with
another element to produce an oxide of the element. An example of oxidation based on this
definition is the combustion of methane. This reaction is represented by the balanced
equation below.
The definition of oxidation has since been expanded to include many reactions that do not
involve oxygen. An example of oxidation based on this expanded definition is the reaction
between magnesium ribbon and powdered sulfur when heated in a crucible. This reaction is
represented by the balanced equation below.
A. 4 C. 2
B. 1 D. 3
36. Given the balanced equation representing a reaction:
Choose the letter of the correct balance equation in your answer booklet, using the
smallest whole-number
coefficients.
ΔH for
A. A C. C
B. D D. B
For the next three items, refer to he following information.
Oxygen gas and iron may react in three different ways as shown in the equation below,
42. Three equal amounts of iron are reacted with oxygen gas, as shown in the following
equation:
Which of the following is the most exothermic?
A. I C. III
B. II D. none
43. The ΔH for the following reaction, represented by the equation.
A. C.
B. D.
Carbon monoxide was used in the blast furnace for the production of iron from Fe2O3(s).
The energy change for the reaction of 1 mol of Fe2O3(s) with CO is
A. C.
B. D.
A. C C. D
B. B D. A
50. Given the lead-acid battery reaction::
Which electronic equation represents the half reaction for the oxidation that occurs?
A. 3 C. 2
B. 1 D. 4
51. Given the reaction at equilibrium:
N2(g) + 3H2(g) 2NH3(g) + 91.8 kJ
A. The rate of the forward reaction and C. The rate of the forward reaction and
the the
concentration of N2(g) both concentration of N2(g) ) both
decrease. increase.
B. The rate of the forward reaction D. What occurs when the
decreases concentration of H2(g) is
and the concentration of N2(g) increased?
increases.
52. An investigation was conducted to study the effect of the concentration of a reactant on the
total time needed to complete a chemical reaction. Four trials of the same reaction were
performed. In each trial the initial concentration of the reactant was different. The time
needed for the chemical reaction to be completed was measured. The data for each of the
four trials are shown in the table below.
A. 1 C. 4
B. 2 D. 3
57. Which statement correctly describes a solution with a pH of 9?
A. It has a higher concentration of OH- C. It has a higher concentration of
than H3O+ and causes methyl H3O+ than OH- and causes methyl
orange to turn yellow orange to turn yellow
B. It has a higher concentration of D. It has a higher concentration of OH-
H3O+ than OH- and causes litmus than H3O+ and causes litmus to
to turn blue. turn blue.
58. Describe, in terms of LeChatelier’s principle, why an increase in temperature increases the
solubility of KNO3.
Given the equilibrium equation at 298 K:
In the smelting of iron ore, Fe2O3 is reduced in a blast furnace at high temperature by a
reaction with carbon monoxide. Crushed limestone, CaCO3, is also added to the mixture to
remove impurities in the ore. The carbon monoxide is formed by the oxidation of carbon
(coke), as shown in the reaction below: