SECOND QUARTER SUMMATIVE TEST ON GENERAL CHEMISTRY 2

NAME:________________________________________________STRD & SC:_ __________

DIRECTIONS: Read and analyze the questions carefully and write the letter that
corresponds to the best answer.

1. It is the study of the interrelation of heat and work with chemical reactions or with physical changes of
state within the confines of the laws of thermodynamics.
A. Chemical Thermodynamics C. Heat and Thermodynamics
B. Physical Thermodynamics D. Thermodynamics
2. When the entropy change in the universe is greater than zero, the process is spontaneous.
A. Fact B. Bluff
3. The second law of thermodynamics tells us that heat always flows from a body at a
higher temperature to a body at the lower temperature
A. Fact B. Bluff
For Number 4 to 8: Directions: Compute for the ∆𝐺0 of the given reactions at 250C using
the quantities ∆𝐻0 and ∆𝑆0. Show your complete solution. Determine whether the reaction is
spontaneous or non-spontaneous.

C2H2(g) + O2(g) → CO2(g) + H2O(l)

4. Which of the following is the balance equation of the given formula above?
A. 3C2H2(g) + 4O2(g) → 3CO2(g) + 3H2O(l)
B. 2C2H2(g) +3 O2(g) → 4CO2(g) + H2O(l)
C. 2C2H2(g) + 5O2(g) → 4CO2(g) + 2H2O(l)
D. 3C2H2(g) + 3O2(g) → 3CO2(g) + H2O(l)
5. Which of the following is the value of ∆𝐻0?
A. 2568.9 kj/mol B. -2786.98 kj/mol C. 2878.98 kj/mol D. -2598.80 kj/mol
6. Which of the following is the correct value of ∆𝑆0?
A. -0.4324 kj/(k.mol) B. 0.1929 kj/(k.mol) C. -0.0235 kj/(k.mol) D. 0.2738 kj/(k.mol)
7. Compute for the ∆𝐺0:
A. -2345 kj/mol B. 2375 kj/mol C. -2469.94 kj/mol D. 2734.87 kj/mol
8. What type of reaction took place in the situation?
A. Spontaneous Reaction B. Non-Spontaneous Reaction
For Numbers 9-14: Equilibrium Constant
9. Which of following are equal for a chemical system at equilibrium? If all are equal.
A. The concentration of reactants and products are equal
B. The rate constant for the forward and reverse reactions are equal
C. The time that a particular atom or molecule spends as a reactant and product are equal
D. The rate of the forward and reverse reaction
E. All of the above.
10. A Chemical Equilibrium may be established by starting a reaction with ____________.
A. Reactant only C. Equal Quantities of reactant and Product
B. Product Only D. Any Quantities of reactant and Product
11. An Equilibrium that strongly favors products has __________________.
A. a value of K << 1
B. a value of K >> 1
C. a value of Q >> 1
D. a value of Q << 1
E. K = Q
12. The equilibrium constant for the acid ionization of mercaptoethanol is 1.91 * 10-10.
The reaction is given by HSCH2CH2OH (aq) -H+(aq) + SCH2CH2OH-(aq)
Which of the following statements is true regarding this equilibrium?
I. The reaction is product favored.
II. The reaction is reactant favored
III. Equilibrium lies far to the right
IV. Equilibrium lies far to the left
A. I and II D. II and IV
B. I and IV E. None are True
C. II and III
 13. The equilibrium constant for the formation of hydrogen iodide from iodine is 45 at a certain
temperature. H2 (g) + I2 (g) 2HI
Which of the following statements is true regarding this equilibrium?
I. The reaction is product favored.
II. The reaction is reactant favored
III. Equilibrium lies far to the right
IV. Equilibrium lies far to the left
A. I and II D. II and IV
B. I and IV E. None are True
C. II and III
14. For the following hypothetical equilibrium, what is the value of the equilibrium constant if
the concentrations at equilibrium are shown as : A(g) + 2B(g) 2C(g)
when A = 4.5 * 10-5M; B = 2.2 * 10-2M; and C = 2.2 * 10-3M
A. 0.22 D. 2.3 * 108
B. 9.9 E. 9.5 * 103
C. 4.3*105
15. Which of the following is TRUE for a chemical reaction at equilibrium?
A. only the forward reaction stops
B. only the reverse reaction stops
C. both the forward and reverse reactions stops
D. the rate constant for the forward and backward reactions is equal
E. the rates of the forward and backward reactions are equal
16. Which of the following is TRUE regarding the concentration of products, for a chemical
reaction that is already at equilibrium assuming no disruptions to the equilibrium?
A. The concentrations of products will not change because there are no more reactants.
B. The concentrations of products will not change because the limiting reagent is gone.
C. The concentrations of products will not change because the forward and reverse rates
are equal
D. The concentrations of products will change continually because of reversibility
17. If the reaction quotient Qc has a smaller value than the related equilibrium constant Kc.
_________?
A. the reaction is at equilibrium
B. the reaction is not at equilibrium, and will make more products at the expense of the
reactants
C. the reaction is not at equilibrium, and will make more reactants at the expense of the
products
D. the value of Kc will decrease until it is equal to Q
E. the reaction favors the products
For Number 18,19 and 20: Directions: Predict the direction of the following chemical
equations given in each items.
18. For the reaction below, what change would cause the equilibrium to shift to the right?
CH4(g) + 2H2S(g) ↔ CS2(g) + 4H2(g)
A. Decrease the concentration of dihydrogen sulfide.
B. Increase the pressure on the system.
C. Increase the temperature of the system.
D. Increase the concentration of carbon disulfide.
E. Decrease the concentration of methane.
19. What would happen to the position of the equilibrium when the following changes are
made to the equilibrium system below? 2SO3(g) ↔ 2SO2(g) + O2(g)
A. Sulfur dioxide is added to the system.
B. Sulfur trioxide is removed from the system.
C. Oxygen is added to the system.
20. What would happen to the position of the equilibrium when the following changes are
made to the reaction below? 2HgO(s) ↔ Hg(l) + O2(g)
A. HgO is added to the system.
B. The pressure on the system increases.

Prepared by:

SID ELEAZAR R. GAFFUD

Teacher II