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JONAYAT - Transient Model of Meniscus and Slag Consumption - Published Version
JONAYAT - Transient Model of Meniscus and Slag Consumption - Published Version
The behavior of the slag layer between the oscillating mold wall, the slag rim, the slag/liquid
steel interface, and the solidifying steel shell, is of immense importance for the surface quality of
continuous-cast steel. A computational model of the meniscus region has been developed, that
includes transient heat transfer, multi-phase fluid flow, solidification of the slag, and movement
of the mold during an oscillation cycle. First, the model is applied to a lab experiment done with
a ‘‘mold simulator’’ to verify the transient temperature-field predictions. Next, the model is
verified by matching with available literature and plant measurements of slag consumption. A
reasonable agreement has been observed for both temperature and flow-field. The predictions
show that transient temperature behavior depends on the location of the thermocouple during
the oscillation relative to the meniscus. During an oscillation cycle, heat transfer variations in a
laboratory frame of reference are more severe than experienced by the moving mold thermo-
couples, and the local heat transfer rate is increased greatly when steel overflows the meniscus.
Finally, the model is applied to conduct a parametric study on the effect of casting speed, stroke,
frequency, and modification ratio on slag consumption. Slag consumption per unit area
increases with increase of stroke and modification ratio, and decreases with increase of casting
speed while the relation with frequency is not straightforward. The match between model
predictions and literature trends suggests that this methodology can be used for further inves-
tigations.
DOI: 10.1007/s11663-014-0097-9
The Minerals, Metals & Materials Society and ASM International 2014
Here, rsl-Fe is the constant surface tension of the The other terms are given by
interface between the slag and steel (N/m), and j is the 0" ( pffiffiffi ! )#4 1
local curvature of this interface, found from k 500m 4q r x2 k
F1 ¼ tanh@ min max ; ; mix A;
j¼r^
n; ½7 0:09xy y2 x CDkx y2
Slag Top Surface speed (vx = 0, vy = vc). It is given the fixed temperature
profile (T = Tsc) predicted by the CON1D simulation.
Interface (coupled wall) Melting
Solidifying zone
zone Slag layer 5. Shell hot face
The shell contacting the liquid steel is modeled as a
xsol
Zero-gradient wall Gravity
Shell cold Liquid Steel style equation by Won and Thomas[71] in CON1D.
face Constant at
liquidus temp.
6. Steel bottom surface
Shell hot face This surface is modeled as a stationary wall
(vx = 0; vy = 0) with zero heat flux (qs = 0).
B ¼ 31; 140 23; 896 XCaO þ XMnO þ XMgO alumina pick-up, which agrees with the observations of
many previous experimental studies.[79,80] Considering a
þXFeO þ XB2 O3 Þ 46; 356XCaF2
typical fraction of alumina inclusions absorbed from the
39; 519ðXNa2 O þ XK2 O þ XLi2 O Þ þ 68; 833XAl2 O3 : steel into this slag, a ~7 pct pick-up is assumed for the
½27 current model simulations of the commercial process.
A limitation of the Riboud model is that it does not
Here, Xi is the molar fraction of the ith compound. predict the abrupt increase in viscosity observed at some
Alumina content in the molten slag can increase as temperature during cooling,[79] termed as the break
much as 30 pct[54] during casting. The temperature- temperature (TBr). The following power-law relation[35]
dependent viscosity of the Shin-P2 molten slag, based on captures this phenomenon
2.31, 5.15, and 6.94 pct Al2O3 pickup are calculated
using the Riboud model and compared in Figure 3
along with the measured viscosity by Shin et al.[19] The To Tfsol n
l ¼ lo ; ½28
results show that the viscosity increases with increasing T Tfsol
Fig. 3—Temperature dependent slag viscosity predicted by Riboud U ¼ 0:003731 ðpct Al2 O3 Þ þ 0:005973 ðpct SiO2 Þ
model for different pctAl2O3 pickup vs measured values.
þ 0:005806 ðpct CaOÞ:
½30
22.23 mm
10.63 mm
-11 TC 1 Far-field steel-
-5 TC 2 slag interface ing slag consumption curve (Figure 11) closely follows
2 TC 3 7.9 mm the oscillating mold velocity, which agrees with Anzai
Water slot
Meniscus (Badri)
8 TC 4
et al.[23] Slag consumption is positive only from 0.0846
14 TC 5
Hot face
21 TC 6
to 0.2621 seconds, which overlaps NST. Slag is drawn
Mold Photo
15.8 mm
upwards during the rest of the cycle. The result is an
Mold Molten Steel
Cold Hot 51.6 mm average consumption of 0.0051 kg/m s or 0.220 kg/m2.
From Shin et al.,[19] the measured consumption calcu-
Fig. 7—Badri experiment thermocouple locations (left) and mold
dimensions (right).
Fig. 8—Displacement, velocity, and NST time over one oscillation Fig. 10—Predicted slag pressure at 0.4 mm from hot face and
cycle (0.77 to 1.12 s) for Shin case. 0.5 mm above shell tip (Shin case: 0.77 to 1.12 s).
Fig. 9—Meniscus region events over one oscillation cycle (0.77 to 1.12 s) for Shin case.
V. PARAMETRIC STUDIES
The validated computational model developed in this
work was simplified to increase computational effi-
ciency, and applied in a parametric study to predict slag
consumption as a function of different casting variables.
D. Results
1. Casting Speed (vc)
The predicted mean slag consumption (kg/m2)
decreases slightly with increasing casting speed, as
shown in Table V, Case C1-3 and in Figure 29(a).
Specifically, an 8.6 pct increase in casting speed (from
23.3 to 25.3 mm/s) causes the slag consumption rate (g/
m s or g/m cycle) to increase by only 7.5 pct, which
corresponds to a decrease in slag consumption of 1 pct.
This relationship is well documented in previous mea-
surements,[19,20,47,48] including casters with both sinu-
soidal and non-sinusoidal oscillation.[46]
Fig. 29—Predicted effect of changing casting speed, stroke and mod-
ification ratio on slag consumption.
2. Stroke (s)
Based on Case S1-3 in Table V, Figure 29(a) shows consumption by only 2 pct, however, this agrees with
that consumption (kg/m2) increases slightly with previous measurements, such as quantified with the
increase of stroke. Increasing stroke by 40 pct increases empirical equation of Tsutsumi et al.,[46]
kb s0:4 1000 vc
Q¼ pffiffiffi cos1 ; ½34
Tcs l vc 2pfs Fig. 32—Predicted and measured[74] slag consumption vs negative
strip time.
where Q is slag consumption (kg/m2), vc is casting speed
(m/min), f is frequency (cpm), s is stroke (mm), l is researchers[46,52,101,102] as reviewed by Saraswat et al.[103]
viscosity at 1573 K (1300 C) (P), Tcs is crystallization that show both increasing and decreasing slag con-
temperature (C) and kb is constant. In Eq. [34], stroke sumption per unit area. The inverse relationship with
appears in two places with opposite effects. The net consumption per cycle (g/m cycle) agrees with Shin’s[19]
effect of increasing stroke is a slight increase of all three equation.
measures of consumption: (g/m s, g/m cycle, and
kg/m2). 4. Modification Ratio (am)
The effect of non-sinusoidal oscillation was investi-
3. Frequency (f) gated with two casting conditions (M2-3) using 12 and
Two sets of simulations with two different strokes 24 pct modification ratio (am) which is defined after Eq.
(F1-4, F2-1-3) were done to study the effect of changing [20]. Increasing am to 24 pct is predicted to increase slag
frequency. Frequency has small inconsistent effect on consumption by ~2.4 pct, as shown in Figure 29(b).
slag consumption (kg/m2) as shown in Figure 30(a). This trend agrees quantitatively with many previous
Increasing frequency by ~62 pct causes only 1 to 2 pct measurements.[4,19] Tsutsumi et al.,[46] measured over
variation (both decrease and increase) although it 50 pct higher consumption and explained this trend is
decreases slag consumption per cycle (g/m cycle) by due to the increase in PST that accompanies the increase
~35 pct, as shown in Figure 30(b) for both F1-4 and of am. Suzuki et al.[4] reported that this trend is due to
F2-1-3. This agrees with empirical equations by many decreasing frictional force. Finally, the relative speed of
Case\Components C Mn S P Si Cr Ni Cu Ti Al N Mo V Nb
Shin case (pct) 0.003 0.08 0.01 0.015 0.005 0.01 0.01 0.01 0.05 0.04 — — — —
Badri case (pct) 0.0046 0.46 0.0089 0.011 0.1 0.035 0.015 0.027 0.015 0.051 0.0057 0.004 0.003 0.0002