THERMODYNAMICS

Q1 Express the change internal energy of a system when

i) No heat is absorbed by the system from the surrounding but work
is run on the system .What type of wall does the system have ?
ii) no work is done on the system but q amount of heat is taken out
from the system and given to the surroundings . What wall does
the system have ?
iii) w amount of work is done by the system and q amount of heat is
supplied to the system . What type of system would it be ?
Q2 A system loses 627 J of energy and performs work equal to 210 J.
Calculate the internal energy change of the system .
Q3 A system has internal energy equal to 100 J stored in it . 100 J of heat
energy is supplied and 50 J of work is done on the system Calculate change
in internal energy and finals and energy of system in the final state .
Q4 Calculate the work done when one mole of water at 373 K vaporises
against atmospheric pressure of 1atm. Assume ideal gas behaviour .
[-3.1 kJ]
Q5 2 litres of an ideal gas at a pressure of 10 atm expands isothermally into a
vacuum until its total volume is 10 litre .How much heat is absorbed and how
much work is done in the expansion ?
i)Calculate the work done if the expansion is carried out against a constant
external pressure of 1 atm. [ 8 L atm]
ii) Calculate the work done if the expansion is carried out reversibly do a final
volume of 10 litre. [ 32.2 L atm]
Q6 A gas occupies 2 litre at STP. If 300 J heat is given to the gas its volume becomes
2.5 litre at 1atm . Calculate the change in internal energy .
[249.35 J]
Q7 A gas absorbs 2000 J of heat and expands against an internal pressure of 2atm
from a volume of 0.5 L to 10.5 L. Calculate the change in internal energy .
[ -26 J]
Q8 calculate the number of moles of carbon monoxide if it is allowed to expand
isothermally and reversibly from 20 m3 to 40 m3 and the work of obtained is 47 kJ.
[2.75 moles]
Q9 5 moles of an ideal gas at the initial pressure of one atmosphere at 0 ℃ were
expanded reversibly under isothermal conditions to final pressure of 0.18
atmosphere. Calculate the work done by the gas, change in internal energy and
heat absorbed by the system.
[ w = -26 kJ, ∆U = 0 , q= +26KJ]
Q10 Identify open closed and isolated system :
i) human being
ii) can of tomato soup
iii) satellite in orbit
iv) coffee in a thermos flask
v) helium filled balloon
Q11 Identify the state function :
i) height of a Hill
ii) energy consumed in climbing the Hill
Q12 Neither q nor w is a state function but q + w is a state function
Explain .
Q13 The enthalpy of combustion of benzoic acid (C 6H5COOH) at 298 K
and one atmosphere is -2546 kJ/mol. Calculate the internal energy
change . [-2544.8 kJ/mol]
Q14 The heat produced during combustion of one mole of CH4(g) at
constant volume is measured in a bomb calorimeter at 298 K and is
found to be -885 kJ/mol. Find the value of enthalpy change(∆𝐻).
[-880 kJ]
Q15 When NH4NO2(s) decomposes at 373 K it forms N2(g) and H2O(g).
The ∆𝐻 for the reaction at one atmosphere pressure and 373 K is -
223.6 kJ/mol of NH4NO2(s) decomposed. Calculate the value of internal
energy change for the reaction. [ -232.9 kJ/mol]