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Chemistry (/chemistry/) > Metals and Nonmetals (/chemistry/metals-and-nonmetals/) > Corrosion Inhibitor
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Corrosion Inhibitor is a chemical solvent which is applied in a given environment to reduce the rate of corrosion
of the metal which is subjected to that specific environment, such as air or water. The corrosion inhibitor can be
abbreviated to CI.
One method for the inhibition of corrosion would be the addition of a coating on the surface of the metal which
acts as a passivation layer and disallows access to the surface of the(https://byjus.com/byjus-classes-book-a-free-
metal.
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Types of Corrosion Inhibitor
Corrosion inhibitors can be classified into four general types based on the method in which they work on the
metal to prevent corrosion. These types are:
Examples for Cathodic Inhibitors include sulfite and bisulfite ions which Aufbau
can react with oxygen to form sulphates.
Principle
Another example of a cathodic inhibitor is a catalyzed redox reaction (https://byjus.com/chemistry/oxidation-and-
(Https://Byjus.Com/Chemistry/Aufbau-
reduction/) by nickel. Principle/)
Electron Configuration
Anodic Inhibitor
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These types of corrosion inhibitors form a thin preventive oxide layer on the surface of the metal. This reaction
Configuration/)
leads to a big anodic shift, turning the metallic surface into a passivation area. This passivation area helps in
Isomerism
reducing the corrosion of the metal.
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Examples for anodic inhibitors include chromates, nitrites, orthophosphates, and molybdates.
Planck's Quantum Theory
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Volatile Corrosion Inhibitor
Theory/)
Volatile corrosion inhibitors can be used to halt the corrosion of condenser tubes in boilers. They are also
Valence Bond Theory
referred to as vapour phase inhibitors or VPIs.
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VPIs work by changing the pH of the exterior atmosphere to less acidicTheory/)
conditions in order to control corrosion.
Examples include morpholine and hydrazine which are used to control the corrosion of the condenser pipes in
Reactivity Series
boilers.
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Series/)
Mixed Inhibitors
Named Reactions
These types of corrosion inhibitors also form a film on the surface of the metal. They work to reduce cationic
(Https://Byjus.Com/Chemistry/Named-
reactions as well as anionic reactions. This is done via the formation of a precipitate on the surface of the metal.
Reactions/)
Examples for Mixed inhibitors include silicates and phosphates (https://byjus.com/chemistry/phosphate/) which
Dipole Moment
are used as water softeners to stop the rusting of water.
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