Reactivo 2

Calvin Jacob Orozco García

 a) Carbonatacion del sulfato de plomo
PbSO4 + Na2CO3 = PbCO3 + NasSO4

Eh (Volts) Pb - C - Na - S - H2O - System at 25.00 C

2.0 PbO2 Eh (Volts) C - Na - Pb - S - H2O - System at 25.00 C
PbSO4
2.0
CO2(g)
NaHCO3
1.5 CO3(-2a)
1.5
PbO2

1.0 1.0

0.5 0.5 Na2CO3*10H2O

PbCO3 Pb12O17
Pb(+2a)
0.0 PbO*PbCO3 0.0
PbO
CO2(-g)

Pb -0.5
-0.5 PbS

-1.0
-1.0 Pb
-1.5 CH4(a)
-1.5
H2O Limits
Pb(-g)
H2O Limits -2.0
0 2 4 6 8 10 12 14
-2.0
0 2 4 6 8 10 12 14 C:\Users\Usuario\Desktop\PbCNaS25.iep pH

C:\Users\Usuario\Desktop\PbCNaS25.iep pH
ELEMENTS Molality Pressure
Pb 1.000E+00 1.000E+00
ELEMENTS Molality Pressure C 1.000E+00 1.000E+00
Pb 1.000E+00 1.000E+00 Na 1.000E+00 1.000E+00
C 1.000E+00 1.000E+00 S 1.000E+00 1.000E+00
Na 1.000E+00 1.000E+00
S 1.000E+00 1.000E+00

https://tesis.ipn.mx/jspui/bitstream/123456789/24457/1/Arellano%20Solorio%202015%20MC%20en%20IM.pdf
Eh (Volts) Na - C - Pb - S - H2O - System at 25.00 C Eh (Volts) S - C - Na - Pb - H2O - System at 25.00 C
2.0 NaO3 2.0 PbSO4 SO3

1.5 NaSO4(-a) 1.5

NaSO4(-a)
1.0
1.0

0.5
Na2SO4*10H2O 0.5

0.0 Na2CO3*10H2O Na2SO4*10H2O

0.0
-0.5 NaOH(a)
-0.5 PbS
Na2S
-1.0
Na2S
-1.0
-1.5 S(-2a)
NaH Na(-g)
H2O Limits -1.5
-2.0
0 2 4 6 8 10 12 14 S(H3)(g) H2O Limits
-2.0
C:\Users\Usuario\Desktop\PbCNaS25.iep pH 0 2 4 6 8 10 12 14

ELEMENTS Molality Pressure C:\Users\Usuario\Desktop\PbCNaS25.iep pH

Pb 1.000E+00 1.000E+00
C 1.000E+00 1.000E+00 ELEMENTS Molality Pressure
Na 1.000E+00 1.000E+00
Pb 1.000E+00 1.000E+00
S 1.000E+00 1.000E+00
C 1.000E+00 1.000E+00
Na 1.000E+00 1.000E+00
S 1.000E+00 1.000E+00
 b) Disolución del carbonato con
HCl PbCO3 + HCl = PbCl2 + H2CO3
Eh (Volts) Pb - C - Cl - H2O - System at 25.00 C Eh (Volts) C - Cl - Pb - H2O - System at 25.00 C
2.0 2.0
PbO2
1.5 1.5
HCO3(-a)
CO2(a) CO3(-2a)

1.0 1.0
PbCl4(g)
PbCl3(a) 0.5
0.5
Pb12O17
C PbCO3
0.0 PbCO3 0.0 2PbO*PbCO3
2PbO*PbCO3
PbO
PbCl2

-0.5 -0.5
Pb
-1.0
-1.0

Pb(-g) CH4(a)
-1.5
-1.5
Pb(H3)(g) H2O Limits
H2O Limits
-2.0
-2.0 0 2 4 6 8 10 12 14
0 2 4 6 8 10 12 14
C:\Users\Usuario\Desktop\PbCCl25.iep pH
C:\Users\Usuario\Desktop\PbCCl25.iep pH
ELEMENTS Molality Pressure
ELEMENTS Molality Pressure Pb 1.000E+00 1.000E+00
Pb 1.000E+00 1.000E+00 C 1.000E+00 1.000E+00
C 1.000E+00 1.000E+00 Cl 1.000E+00 1.000E+00
Cl 1.000E+00 1.000E+00

https://reader.elsevier.com/reader/sd/pii/S0309170818303713?token=7668B30BC20CE76D32401C7AC9
35F5620EBC77D0C6F3CA0E839EB86C08C80B70D0B73357C6C17C5606FF1F409BDE56B6
https://www.sciencedirect.com/science/article/pii/S0309170818303713
Eh (Volts) Cl - C - Pb - H2O - System at 25.00 C
2.0
ClO4(-a)

1.5
PbCl4(g)
1.0

PbCl3(a)
0.5

0.0
PbCl2

-0.5

-1.0
Cl(-a)

-1.5

H2O Limits
-2.0
0 2 4 6 8 10 12 14

C:\Users\Usuario\Desktop\PbCCl25.iep pH

ELEMENTS Molality Pressure

Pb 1.000E+00 1.000E+00
C 1.000E+00 1.000E+00
Cl 1.000E+00 1.000E+00