STARS ACADEMY LAHORE

Head office: 30 Kashmir Block Allama Iqbal Town Lahore 042-37800293, 0333-1409100, www.starscollege.edu.pk
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Roll No. of Candidate Name of Candidate

STARS ENTRY TEST SYSTEM – 2019

Assignment Code: C5 Session MDCAT Time Allowed: 40 mints
0C
1 The rate constant activation energy and Arrhenius parameter of a reaction at 25 are 3.0 x 10-4s-1,
104.4kJ/mol and 6.0 x
1014s-1respectively. The value of the rate constant at T →∞ is
A) 2.0 x 1018 xs-1 B) 6.0 x 1014s-1 C) 3.6 x 1030s-1 D) ∞
2 The rate constant for the reaction 2N2O5 → 4NO2 +O2 is 3.0 x 10 s-1 . If the rate is 2.4 x 10-5 molL-1,s-1 , the concentration in
-5

mol L-1 is
A) 0.8 B) 0.04 C) 1.2 D) 1.4
3 When A and B are mixed to give C and D , the reaction quotient Q at the initial stages of the reaction
A) Increase with time B) Decrease with time C) Is independent of time D) Is Zero
4 The rate law for the reaction RCl + NaOH → ROH + NaCl is given by rate = k[RCl]. The rate of reaction will be
A) Doubled on doubling the B) Halved on reducing the C) Increased on D) In affected on increasing
concentration of NaOH concentration of alkyl increasing the the temperature of
halide to one half temperature of reaction.
reaction
5 The rate constant of a first order reaction is dependent on
A) Time B) Temperature C) Concentration of D) Concentration of
reaction products
6 The half life period of a first order reaction is 10min . If the initial amount is 0.08mol L -1 and the concentration at some
instant is 0.01mol L-1 , then t =
A) 10min B) 30min C) 20min D) 40min
7 If the t1/2for a reaction is 4min , the time after the reaction is 99.9% completed is
A) 16min B) 8min C) 32mins D) 40min
8 For exothermic reaction, the product are at a lower energy level than the reactants and the decrease in potential energy
appear as _________________ of the product
A) Decrease in kinetic energy B) Increase in kinetic energy C) Decrease in thermal D) Increase in thermal
energy energy
9 If two initial concentration and times for reaction are given then which method is used to find out order of reaction
A) Method of hit and trial B) Method of large excess C) Differential method D) Half life method
basis
10 The half life period of a zero order reaction is
A) Proportional to initial B) Independent of C) Proportional to square D) Inversely proportional to
concentration concentration of of concentration initial concentration
reactants
11 Identify the correct statement
A) The rate of chemical B) The hydrolysis of ethyl C) For a first order D) For a second order
change is directly acetate in acidic medium reaction the rate of reaction the rate of
proportional to is a Secord order reaction reaction doubles as doubles as the
concentration the concentration of concentration of the
the reactant (s) reaction(s) doubles
doubles
12 A plot of log k Vs 1/T of a reaction give a straight line with
A) A non zero intercept and B) A zero intercept and C) A non zero intercept D) A zero intercept and
negative slope negative slope and positive slope positive slope
13 The diazonium salt decomposes as C6H5N2+Cl-→ C6H5Cl + N2. At O0C , the evolution of N2 becomes two times faster when the
initial concentrating of the salt is doubled , Therefore it is
A) A first order reaction B) A second order reaction C) A zero order reaction D) Independent of the initial
concentration of the salt
14 The formation of nitrogen oxide is endothermic then enthalpy change of reaction is ……………….. KJ/mol
A) 41.6 B) 278.85 C) 285.58 d) 290.87
15 In the thermodynamics, a process is called reversible when
A) The surrounding and B) There is no boundary C) The surroundings are D) The system changes into
system change into each between system and always in equilibrium the surroundings
other surroundings with the system spontaneous

16 Which of the following statement is false

A) Work is a state function B) Temperature is a state C) Change in the state is D) Work appears at the
function completely defined boundary of the system
when the initial and
final states are
specified
17 Which of the following is an exothermic reaction
A) Conversion of graphite to B) Dehydrogenation of C) Decomposition of D) Combustion of methane
diamond ethane to ethylene water
18 The standard molar enthalpy of formation of CO2 is equal to
A) Zero B) The standard molar C) The standard molar D) The sum of the standard
enthalpy of combustion entropy of combustion molar enthalpies of CO
of carbon(graphite) of C(gaseous) and CO2
19 Which of the following equations correctly represents the standard heat of formation (∆ H0f) of methane?
A) C(diamond) + 2H2(g) = B) C(graphite) + 2H2(g) = C) C(graphite) + 2H2(g) = D) C(graphite) + 4H =
CH4(g) CH4(l) CH4(g) CH4(g)
20 The surface which separate system and surroundings is called …………………
A) Boundary B) Area C) Linc D) All of these
21 For an endothermic reaction where∆𝑯 represents the enthalpy of the reaction in kJ/mol, the maximum value for the energy
of activation will be
A) Less than ∆𝑯 B) More than ∆𝑯 C) Equal to ∆𝑯 D) Zero
22 The sum all kinds of energy of system is called internal energy. These energies are
A) Bouncing energy B) Elastic potential energy C) All kinds of K.E D) All of these

23 Which of the following reaction is an endothermic reaction?

A) 2H2 + O2 → 2H2O B) 2NaOH +H2SO4 → C) C2H5OH + 3O2→ D) N2 +O2→ 2NO
Na2SO4+2H2O 2CO2 + 3H2O
24 The enthalpy of combustion of cyclohexone, cyclohexanol and H2 is -3920, -3800 and -241 kJ/mol respectively. The heat of
hydrogenation (in kJ/mol) of cyclohexone is
A) -121 B) +121 C) -242 D) +242
25 The products of combustion of an aliphatic thiol (RHS) at 298k are
A) CO2 B) CO2 ,H2Og and SO2g C) CO2g , H2Og and D) CO2(g) and SO2(l)
SO2(g)
26 If pressure on the one mole gas is 2Nm-2 produced 3dm3 volume change and enthalpy of system is 9 J/mole the internal
energy of system is ……………………
A) 12 J/mole B) 6 J/mole C) 3 J/mole d) 9 J/mole
27 In what proportion 1M NaOH and 0.5M H2SO4 are mixed so as to release maximum amount of energy and to form 100ml
solution
A) 33 and 67 B) 67 and 33 C) 40 and 60 D) 50 and 50
28 The enthalpy of combustion of glucose is -2840kJ/mol. The enthalpy of formation of 60 g of glucose is
A) 2840kJ B) 946.6kJ C) -946.6KJ D) 1420kJ
29 The heat of reaction at constant pressure is given by
A) HR - HP B) EP-ER C) ER-EP D) HP-HR
30 The enthalpy change which occurs when the certain number of moles of reactants as indicated by balanced chemical
equation, reacts to form product of standard temperature and pressure is called ………………
A) Enthalpy of reaction B) Enthalpy of atomization C) Enthalpy of formation D) Enthalpy of combustion

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