CONCORDIA COLLEGES BWP

1st YEAR CHEMISTRY

CHAPTER#11
MCQ, s a) Decrease in the activation energy of
1. In zero order reaction, the rate is reaction
independent of. b) Decrease in number of collision between
a) Temperature of reaction the molecules
b) Concentration of reactants c) Increase in activation energy of reactant
c) Concentration of products d) Increase in number of effective collision
d) None of these 10. The unit of rate constant is the same as
2. If the rate equation of reaction 2A + B → that of the rate of reaction in.
Products is, rate = k [A]2 [B], and A is a) Zero order reaction
present in large excess then order of b) First order reaction
reaction is. c) Second order reaction
a) 1 b) 2 d) Third order reaction
c)3 d) None of these 11. The minimum amount of energy required
3. The rate of reaction. for an effective collision is called.
a) Increases as the reaction proceeds a) Activation energy b) Internal energy
b) Decreases as the reaction proceeds c) Translational energy d) None of these
c) Remains the same as the reaction proceeds 12. When a reaction proceeds in sequence of
d) May decrease or increase as the reaction steps, the overall rate is determined by.
proceeds a) Fastest step b) Slowest step
4. With increases of 100C temperature the c) Molecularity of all steps
rate of reaction doubles. This increase in d) Order of different steps
rate of reaction is due to. 13. A substance which makes the catalyst
a) Decrease in activation energy of reaction more effective is called.
b) Decrease in the number of collisions a) Inhibitor b) Retarder
between reactant molecules c) Promoter d) Auto catalyst
c) Increase in activation energy of reactions 14. The unit of rate constant for zero order
d) Increase in number of effective collisions reaction is.
5. The unit of the rate constant is the same a) dm3s-1 b) mole dm-3s-1
as that of the rate of reaction in. c) mole dm3s-1 d) mole s-1
a) First order reaction b) Second order reaction 15. Indicate the enzyme which catalyses the
c) Zero order reaction d) Third order reaction following C6H12O6 → 2C2H5OH + 2CO2.
6. In zero order reaction, the rate is a) Disease b) Urease
independent of. c) Zymase d) Invertase
a) Temperature of reaction 16. Photo chemical reactions are.
b) Concentration of reactant a) First order b) Third order
c) Concentration of product c) Second order d) Zero order
d) None of these 17. The rate of a chemical reaction is
7. If the rate equation of reaction 2A + B → independent of.
Product Rate = K [A]2 [B] and A is present a) Molecularity b) Temperature
in large excess, then order of reaction is. c) Nature of reactant
a) 2 b) 1 d) Concentration of reactant
c) 3 d) None of these 18. Which of following is an example of
8. The rate of reaction. homogenous catalyst?
a) Increases as the reaction proceeds a) Formation of ghee from oil
b) Decreases as reaction proceeds b) Formation of SO3 in contact process
c) Remains the same as reaction proceeds c) Hydrolysis of ester
d) May decrease or increase as the reaction d) Formation of NH3 in Haber process
proceeds 19. The equation K = Ae-Ea/RT+ is called.
9. With increase of 100C temperature, the a) Rate law b) Arrheniuss equation
rate, of reaction becomes double. This c) Rate equation d) General gas equation
increase in rate of reaction is due to. 20. hydrolysis of Tertiary butyl bromide has
order of a catalyst is called.
a) First order b) Pseudo first order
c) Second order d) Third order 8) Name the types of methods used
21. For the reaction 2N2O5 → 2N2O4 + O2 the
order of reaction is.
for determining order of
a) 2 b) 1
c) 3 d) 0
22. Velocity constant is the rate of reaction reaction?
when the concentration of reactants is.
a) Zero b) Unity LONG QUESTIONS
c) Two d) three

SHORT QUESTIONS 1) How Arrhenius equation explains

1) Define rate of reaction. Give
the effect of temperature on the
example.
rate constant of a reaction?
2) Rate of reaction decreases with
2) How will you find the order of
the passage of time, explain.
reaction by half-life method?
3) Differentiate between rate of

reaction and specific rate

constant of a reaction.

4) The sum of coefficients of a

balanced chemical equation is not

necessarily important to give

order of reaction. Justify?

RESPECT IS THE FIRST
5) 50% of hypothetical first order STEP TOWARDS
reaction completes in one hour. SUCCESS,
RESPECT YOUR
The remaining 50% needs more
TEACHERS
than one hour to convert itself
Prepared By:
into products. Why?
Prof. MUHAMMAD
6) The radioactive decay is always a ABDUL SAMAD
first order reaction. Explain. HOD CHEMISTRY,
CONCORDIA
7) Define activation energy and
COLLEGE
activated complex. BAHAWALPUR.