tiempo de

Ptotal vida media Pr P,atm

200 265 200 0.26315789
240 186 180 0.23684211
280 115 160 0.21052632
320 104 140 0.18421053
360 67 120 0.15789474
t Ca ΔT Δca (-(Δca/ΔT)) Cam Ln(Cam)
0 1000
100 500 100 -500 -5 750 6.62007321
200 333 100 -167 -1.67 416.5 6.03188646
300 250 100 -83 -0.83 291.5 5.67504001
400 200 100 -50 -0.5 225 5.4161004

Chart Title
2

1.5 f(x) = 1.91211476438133 x − 11.0391868569112

R² = 0.999819994085637
1

0.5

0
5.2 5.4 5.6 5.8 6 6.2 6.4 6.6

-0.5

-1

donde:
Y = 1.9121X - 11.039
n = 1.9121
Lnk = -11.039
K 1.6063E-05
K 1.61E-05 m3/(mol*min)
 Ln(-ΔC/ΔT)

1.60943791
0.51282363
-0.18632958
-0.69314718

Title

11.0391868569112

6 6.2 6.4 6.6 6.8

Datos
Cao 1 mmol/L
Ceo 0.01 mmol/L

transformanda por ecuacion de michaelis-menten

Ca(mmol/L) t(h)
0.84 1
0.68 2
0.53 3
0.38 4
0.27 5
0.16 6
0.09 7
0.04 8
0.018 9
0.006 10
0.0025 11

(Ln(Cao/Ca))/(Cao-Ca) v
7.00000000

6.00000000
f(x) = 1.01022850495015 x − 5.0
(Ln(Cao/Ca))/(Cao-Ca)

5.00000000 R² = 0.998044060445988

4.00000000

3.00000000

2.00000000

1.00000000

0.00000000
6 7 8
(K4*t)/(C

interseccion
pendiente(m) 1.0102
entonces
K5 = -5.08 K3
M -0.197 K4 = 1.0102
M = 0.197
Ceo =0.01
por tanto
ra = (19.9*Ca*Ceo)/(0.197+Ca)
 (Ln(Cao/Ca))/(Cao-Ca) (K4*t)/(Cao-Ca)
1.08970867 6.25
1.20519525 6.25
1.35080483 6.382978723404
1.56061940 6.451612903226
1.79360729 6.849315068493
2.18164460 7.142857142857
2.64609408 7.692307692308
3.35299565 8.333333333333
4.09102192 9.164969450102
5.14687707 10.06036217304
6.00648075 11.02756892231

Ln(Cao/Ca))/(Cao-Ca) vs (K4*t)/(Cao-Ca)
0

0
f(x) = 1.01022850495015 x − 5.09598819949225
0 R² = 0.998044060445988

0
6 7 8 9 10 11 12
(K4*t)/(Cao-Ca)

19.90094 h^-1
 Cao 0.001 mol/L

t(h) Ca(mmol/L) Ca(mol/L) (-(dCa/dt)) Ln(dCa/dt) = y Ln(Ca) = x

1 0.84 0.00084 0.0009 -3.0457574906 -3.07572071
2 0.68 0.00068 0.00077 -3.1135092748 -3.16749109

Ln(dCa/dt)
-4.4 -4.2
3 0.53 0.00053 0.000605 -3.2182446253 -3.27572413
4 0.38 0.00038 0.00045 -3.3467874862 -3.4202164
5 0.27 0.00027 0.00032 -3.4948500217 -3.56863624
6 0.16 0.00016 0.00021 -3.6777807053 -3.79588002
7 0.09 9E-05 0.00013 -3.8860566477 -4.04575749
8 0.04 4E-05 6E-05 -4.2218487496 -4.39794001
f(x)
9 0.018 1.8E-05 R² =
10 0.006 6E-06
11 0.0025 2.5E-06

Ca vs t
0.0009 0.0009
0.0008 0.0008
0.0007 0.0007
0.0006 0.0006
0.0005 0.0005
0.0004 0.0004
0.0003 0.0003
0.0002 0.0002
0.0001 0.0001
0 0
1 2 3 4 5 6 7 8 9 10 11

t(h) Column D
 Ln(dCa/dt) vs Ln(Ca)
0
Ln(dCa/dt)

-4.4 -4.2 -4 -3.8 -3.6 -3.4 -3.2 -3 -2.8

-0.5
-1
-1.5
-2
-2.5
-3
f(x) = 1.12670136860427 x + 0.35071497949684 -3.5
R² = 0.999412312408995
-4
-4.5
-5
Ln(Ca)

Del grafica tenemos el orden de reaacion y la constante

Donde:
m=α 1.1267
Log(k) = 0.3507
k= 0.4459642

metodo cinetico
(-(dCa/dt)) = 0.446*Ca^1.1267