(Landolt-Börnstein - Group IV Physical Chemistry 15A - Physical Chemistry) J. Winkelmann (Auth.), M.D. Lechner (Eds.) - Gases in Gases, Liquids and Their Mixtures-Springer-Verlag Berlin Heidelberg (20

Landolt-Börnstein / New Series
Numerical Data and Functional Relationships

in Science and Technology
New Series
Editor in Chief: W. Martienssen
Units and Fundamental Constants in Physics and Chemistry
Elementary Particles, Nuclei and Atoms (Group I)

(Formerly: Nuclear and Particle Physics)
Molecules and Radicals (Group II)

(Formerly: Atomic and Molecular Physics)
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(Formerly: Solid State Physics)
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Landolt-Börnstein
Numerical Data and Functional Relationships in Science and Technology
New Series / Editor in Chief: W. Martienssen
Group IV: Physical Chemistry

Volume 15
Subvolume A: Gases in Gases, Liquids and their Mixtures

ISSN 1615-2018 (Physical Chemistry)
ISBN 978-3-540-62429-5 Springer Berlin Heidelberg New York
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Zahlenwerte und Funktionen aus Naturwissenschaften und Technik, Neue Serie
Editor in Chief: W. Martienssen
Vol. IV/15A: Editor: M.D. Lechner
At head of title: Landolt-Börnstein. Added t.p.: Numerical data and functional relationships in science and technology.
Tables chiefly in English.
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I. Börnstein, R. (Richard), 1852-1913. II. Landolt, H. (Hans), 1831-1910.
III. Physikalisch-chemische Tabellen. IV. Title: Numerical data and functional relationships in science and technology.
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Preface
Diffusion – defined as mass, amount, or particle transport process – is the most essential transport
property besides viscosity and thermal conductivity. Diffusion is widely used in nature, technical and
scientific applications, ranging from diffusion in all kinds of gases, liquids, solids, electrolytes and their
mixtures. Due to the large amount of data, the volume LB IV/15 "Diffusion in Gases, Liquids, and
Electrolytes" is divided into three subvolumes:
Part A: Gases in Gases, Liquids and their Mixtures.
Part B: Liquids in Liquids and Liquid Mixtures.
Part C: Ions and Electrolytes in Liquids, Electrolytes and Molten Salts.
The presented subvolume A includes the main chapters Measurement methods, Diffusion in Pure
Gases, Diffusion in Gaseous Mixtures, Diffusion of Gas/Vapor in Gases or Liquids and Diffusion of
Gases in Solution. Due to the very different and widespread measurement methods, a precise description
of these methods is given.
As the amount of data exceeds the available place for printing, additional material exists as an online
extension to supplement the book version. The entire volume in PDF format is available on our website
www.landolt-boernstein.com. You can access and download all data files and electronically search for
substances, data, and references by the fulltext search engine and our substance indices. Additionally it is
possible to obtain the computerized data from the electronic version for numerical calculations and
graphical presentations.
The editor wishes to express his thanks to the author J. Winkelmann for this excellent volume which
appears 38 years after the corresponding volume of Landolt-Börnstein’s 6th edition, "Transport-
phänomene I (Viskosität und Diffusion)".
The encouraging support of the chief-editor W. Martienssen and R. Poerschke and T. Schwaibold from
Springer Verlag is kindly acknowledged. The publisher and the editor are confident that this volume will
increase the use of the Landolt-Börnstein.
Osnabrück, February 2007 The Editor

Editor
Prof. Dr. M.D.Lechner
Institut für Chemie Universität Osnabrück
Barbarastr. 7
49069 Osnabrück, Germany
lechner@uni-osnabrueck.de
Author
Prof. Dr. J. Winkelmann
Institut für Physikalische Chemie, Universität Halle-Wittenberg
Mühlpforte 1
06108 Halle, Germany
winkelmann@chemie.uni-halle.de
Landolt-Börnstein: Editorial Office

Gagernstr. 8
D-64283 Darmstadt, Germany
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e-mail: Redaktion.Landolt-Boernstein@springer.com
Internet: http://www.landolt-boernstein.com
Table of Contents
LB IV/15: Diffusion in Gases, Liquids and Electrolytes

Part A: Gases in Gases, Liquids and their Mixtures
1 Introduction
1.1 Selection of data .......................................................................................................................... 1
1.2 Definitions and units ................................................................................................................... 2
1.2.1 Diffusion coefficients ....................................................................................................... 2
1.2.2 Temperature, pressure and density, concentration ........................................................... 5
1.3 Arrangement of data .................................................................................................................... 6
1.4 Substances and nomenclature...................................................................................................... 6
1.5 Data reduction and correlations................................................................................................... 6
1.6 References for 1........................................................................................................................... 8
2 Measurement methods
2.1 NMR spin echo techniques........................................................................................................ 10
2.2 Optical methods......................................................................................................................... 11
2.2.1 Interferometry.................................................................................................................. 11
2.2.2 Holographic interferometry ............................................................................................. 11
2.2.3 Light scattering................................................................................................................ 12
2.3 Capillary diffusion methods ...................................................................................................... 12
2.3.1 Closed tube (Loschmidt cell) ........................................................................................... 12
2.3.2 Two-bulb method ............................................................................................................ 13
2.3.3 Evaporation tube (Stefan cell) ......................................................................................... 13
2.3.4 Open ended capillary....................................................................................................... 14
2.4 Chromatographic methods......................................................................................................... 14
2.4.1 Gas chromatography........................................................................................................ 15
2.4.2 Taylor dispersion method ................................................................................................ 15
2.4.3 Arrested and reversed flow methods ............................................................................... 15
2.5 Diffusion in diaphragm cells and through a porous barrier....................................................... 16
2.6 Steady-state methods ................................................................................................................. 16
2.7 Gas absorption methods ............................................................................................................ 17
2.7.1 Wetted wall and wetted sphere absorber ......................................................................... 17
2.7.2 Laminar liquid jet ............................................................................................................ 17
2.7.3 Bubble collapse and bubble solution .............................................................................. 17
2.7.4 N2O-analogy ................................................................................................................... 18
2.8 Recommended data sets for calibration..................................................................................... 18
2.9 References for 2......................................................................................................................... 19
3 Diffusion in pure gases

3.1 Data ........................................................................................................................................... 20
3.2 References for 3......................................................................................................................... 37
4 Diffusion in gaseous mixtures

4.1 Data ........................................................................................................................................... 39
4.1.1 Diffusion in binary mixtures ........................................................................................... 39
4.1.1.1 Diffusion in binary gaseous mixtures ............................................................... 39
4.1.1.2 Diffusion of gas/vapor in supercritical fluid systems....................................... 104
4.1.1.3 Diffusion of gas/vapor in liquid ....................................................................... 106
4.1.2 Diffusion in binary mixtures at infinite dilution............................................................ 111
4.1.3 Diffusion in ternary and quaternary mixtures................................................................ 139
4.2 References for 4....................................................................................................................... 142
5 Diffusion of gas/vapor in gas or liquid

5.1 Data ......................................................................................................................................... 145
5.1.1 Diffusion of gas/vapor in gas ........................................................................................ 145
5.1.2 Diffusion in supercritical fluid systems......................................................................... 276
5.1.3 Diffusion of gas/vapor in liquid .................................................................................... 314
5.2 References for 5....................................................................................................................... 365
6 Diffusion of gas in solution

6.1 Data ......................................................................................................................................... 374
6.1.1 Diffusion of gas in solution ........................................................................................... 374
6.1.2 Diffusion of gas in electrolyte solution ......................................................................... 396
6.2 References for 6....................................................................................................................... 408
1 Introduction 1
1 Introduction
Data extract from Landolt-Börnstein IV/15A: Diffusion of Gases in Gases, Liquids
and their Mixtures
1.1 Selection of data

Thirty-six years after the publication of a data collection on diffusion in gases and in liquid systems in the
6th edition of Landolt-Börnstein [1969A1], the first volume of a new series on diffusion coefficients of
gases and liquids in fluid and electrolyte mixtures is presented here, providing an up-to-date information
on this property. The first volume contains data on diffusion of gases in fluids and fluid mixtures, starting
from about 1965, where the collection of the previous edition ends, and ending in December 2004.
Contrary to other thermophysical transport properties diffusion phenomena are very widespread in nat-
ure. Besides diffusion of single atoms, excited states or spins, which are not considered here, the most
important is mass diffusion, ranging from diffusion in solids and porous media, from macromolecules in
biological systems to diffusion in gases and supercritical fluids. The corresponding diffusion coefficients
vary from 10–3 m2/s in gases to 10–9 m2/s in liquids and 10–15 m2/s in solid systems, depending on concen-
tration, temperature, pressure or density. Contrary to the measurement of momentum (viscosity) or heat
transfer, where a few well developed experimental methods exist, we find a wide spectrum of different
methods for measuring mass diffusion coefficients ranging from NMR spectroscopy, scattering and inter-
ferometry, chromatography, diffusion through barrier and diaphragm and in capillary systems, and electro-
analytical methods, with quite different degree of accuracy [1991W1].
Diffusional mass transport can be described either on a molecular or on a macroscopic level within the
framework of thermodynamics of irreversible processes (TIP). In molecular diffusion particles move due to
their thermal energy, hindered by friction and by intermolecular repulsion and attraction. In low density
media their transport behavior can be described by the kinetic theory of gases which provides helpful rela-
tions between mass diffusion, viscosity and thermal conductivity. In dense media, however, the transport
mechanism is completely different; here one assumes a series of jumps of particles or defects in a lattice
structure. Within the TIP the linear transport equations describe a mass flux resulting from a corresponding
driving force [1990H1]. There are two different classes of diffusion coefficients: (i) Stefan-Maxwell
(SM-DC) coefficients, describing mass transport as the result of a gradient in the chemical potential, and
(ii) the classical Fick’s (F-DC) diffusion coefficients, relating the mass flux to a gradient in concentration.
The difference between the two classes of coefficients is described by the so-called thermodynamic factor
Γ = 1 + (d ln γi / d ln xi) where γi denotes the activity coefficient and xi the corresponding mole fraction. It con-
tains the influence of thermodynamic non-ideality, i.e. intermolecular forces, on the mass transport [1993T1].
Although the SM-DC are more consistent with TIP theory, the F-DC are those coefficients primarily
accessible in experiments. Therefore in the present collection we exclusively report Fick’s diffusion data.
Many handbooks, e.g. the Properties of gases and liquids [1987R1, 2000P1], the CRC Handbook of
chemistry and physics [1994L1], the collection of Berezhnoi and Semenov [1997B1] and that of Lobo on
electrolyte solution data [1989L1], and also a number of electronic data bases like DETHERM [2004D1]
or ELDAR [1998B1] (for details consult the file NUMERIGUIDE provided by STN International), contain
data on different diffusion coefficients. However, there is no database that provides the complete material.
The most comprehensive data collection on gaseous diffusion coefficients of binary mixtures is that of
Marrero and Mason [1972M1], which covers all data prior to 1971. It provides a critical evaluation and cor-
relation by theoretically based fitting functions. Based on a classification of experimental methods the sys-
tems are divided into three different groups according to their reliability. There are seventy-four systems for
which the data are sufficiently extensive, consistent and accurate to allow diffusion coefficients to be recom-
mended with confidence. Similar collections on self-diffusion coefficients by Boushehri et al. [1987B1] and
on diffusion coefficients of noble gases and their mixtures at low density by Kestin et al. [1984K1] use cri-
tically evaluated data for their correlation. Based on these sources and, of course, on the data from the 6th
edition of Landolt-Börnstein, we searched in Chemical Abstracts and in the relevant journals beginning with
1965 up to the end of 2004 for numerical diffusion coefficient data; results presented only in the form of
Landolt-Börnstein DOI: 10.1007/978-3-540-49718-9_1

New Series IV/15A # Springer 2007
2 1 Introduction
graphs are not considered here. To avoid the propagation of typing errors through different levels of data
bases and to provide information on the method and quality of measurements we decided to refer exclu-
sively to the primary literature, not taking into account data from handbooks or electronic data bases.
The present collection of data does not include those data prior to 1965 which are assumed to be covered
by the 6th edition of Landolt-Börnstein series [1969A1].
Because of the vast amount of data on diffusion coefficients available today, in comparison to the former
collection in the 6th edition of Landolt-Börnstein series, a specialization for the new volumes was necessary.
In the new series on Diffusion in Gases, Liquids and Electrolytes we will exclude the following classes of
systems which are outside the scope of this survey:
(i) solid systems, i.e. metals and alloys, salts, ceramics and glasses and their melts (only molten salt sys-
tems will be included in this collection);
(ii) polymers and liquid crystals;
(iii) surfactants, colloids and micellar systems;
(iv) biomolecules and diffusion in biological systems;
(v) surface and porous media.
The new series consists of a Part A: Diffusion of Gases in Gases, Liquids and their Mixtures including elec-
trolyte solutions and the technologically relevant supercritical fluid systems. Part B will deal with Diffusion
of Liquids in Liquids and Liquid Mixtures and the final Part C with Diffusion of Ions and Electrolytes in
Liquids, Electrolytes and Molten Salts. Nevertheless, the amount of data exceeds the available place for
printing by far. Thus, the volume has an electronic version containing additional data which is available
on www.landolt-boernstein.com. For all systems where more data sets were collected than selected and
printed in this volume, the substance is marked by an asterisk (*).
An evaluation was made for all data to be printed and published in electronic form. In contrast to most of
the above mentioned sources, we decided to select one or two recommended original data sets only. In addi-
tion we included all different types of correlation equations given by the authors in order to provide the user
with more systematic information. However, the literature search reveals that for a large number of systems
only single data points exist. Due to the widespread spectrum of experimental methods (see Section 2) with
quite different degrees of accuracy the quality of an experimental data point strongly depends on the method
of its determination. Therefore the knowledge of the experimental method and conditions is essential for the
evaluation of a data set, that is why the measuring method is given for all data sets in this collection. Since
diffusion coefficients in fluid systems strongly depend on temperature and pressure, information on both
quantities have to be provided. Data sets without information on temperature or pressure are dismissed; data
without information on the accuracy of their temperature measurement are ranked lower. Because the relia-
bility and accuracy of experimental techniques considerably improved over the years, measurements made
in recent years were preferred to older ones. The experience of those authors who conducted extensive ser-
ies of measurements over a period of several years was taken into account. Nevertheless, selected data from
different authors may show differences being larger than the usual accuracy of the data itself. The repeat-
ability achieved in precise measurements is ±(0.05–0.2)%, scattering of good data is ±(0.2–1.0)%, a mod-
erate accuracy ranges about ±(2.0–3.0)% and fair measurements have ±5% [1991W1], but deviations/errors
may even reach 10% and more, especially in the case of older data. Providing the original data in this col-
lection ensures that the user receives the information of their inherent inaccuracy without smoothing. For
many fluid systems, however, the user will not have a choice between several data sets for a special type
of diffusion coefficient, because it was measured only once.
1.2 Definitions and units

1.2.1 Diffusion coefficients
Mass diffusion is defined as a transport process where an initially non-uniform distribution of particles pro-
ceeds towards a uniform distribution; it is the result of the random motion of individual molecules distrib-
uted throughout space. In our definitions we follow the recommendations given in [1991W1].
DOI: 10.1007/978-3-540-49718-9_1 Landolt-Börnstein

# Springer 2007 New Series IV/15A
1 Introduction 3
The SI unit for all types of diffusion coefficients is (m2/s). An older unit (cm2/s), based on the cgs system,
is still widely in use, especially in gaseous diffusion. But we decided to convert all diffusion coefficients to
the SI unit system.
Self-diffusion coefficient D1s

In a pure fluid system with only one component the diffusional motion can be studied by NMR spectro-
scopy or by labelling a particle and following its motion. The diffusion coefficient thus obtained is consid-
ered to be independent of the method of identifying the moving particle and is called self-diffusion
coefficient. It can be obtained theoretically in Molecular Dynamics Simulation studies via mean-square dis-
placement or via time correlation functions, and from the kinetic theory using collision integrals [1972M1].
Interdiffusion coefficients Dij
Binary mixtures:
If c1 and c2 are the molar concentrations of component 1 and 2 in a binary mixture with their transfer velo-
cities u1 and u2 and ct is the total molar concentration, then the diffusion flux Ji is related to the correspond-
ing mole fraction gradient by Fick’s First Law [1993T1, 1990H1]
X
2
Ji ¼ ct ðui uÞ ¼ ct Dmi rxi i ¼ 1; 2; with Ji ¼ 0: ð1Þ
i¼1
For a binary mixture there exists only one independent driving force rxi and only one independent dif-
fusion flux. Instead of the molar diffusion flux with respect to the molar average velocity Ji we may use
the diffusion flux JVi in the volume average reference velocity frame uV, which describes the diffusion flow
relative to the volume fixed reference frame at some time t as a result of its concentration gradient. Then,
under isothermal conditions, Fick’s First Law has the alternative form [1993T1, 1990H1, 1991W1]
JV
i ¼ Dmi rci : ð2Þ
If we choose the concentration difference for an experimental measurement so that there is no volume
change on mixing, either JVi can be measured with respect to a fixed plane in the diffusion cell
[1991W1] and Dm1 ¼Dm2 ¼D12 is the single interdiffusion coefficient of a binary mixture. Sometimes it is
called mutual diffusion coefficient.
When the concentration gradient changes with time, the local mass balance continuity equation yields
@ci
¼ divJ i ¼ divðD12 r ci Þ: ð3Þ
@t
Assuming that, during the experiment, D12 does not depend on the concentration, equation (3) reduces to
2
@ci @ ci
¼ D12 i ¼ 1; 2; ð4Þ
@t @ z2
which is the historic form of Fick’s Second Law [1990H1, 1991W1].
Multicomponent mixtures:
For a n-component mixture we have (n–1) independent fluxes Ji and independent driving forces rxi . Thus
assuming a linear transport equation we find
X
n1
J i ¼ ct Dik rxk i ¼ 1; :::; n 1; ð5Þ
k¼1
which can be written in matrix form as

ðJ Þ ¼ ct ½DðrxÞ; ð6Þ
or
ðJ Þ ¼ ½DV ðrcÞ;

4 1 Introduction
where (J) and ðrxÞ represent column matrices and the matrix [D ] of Fick’s diffusion coefficients is a square
matrix of (n–1)×(n–1) elements:
8 9
> D11 D12 :::: D1;n1 >
>
> >
>
: D21
> D22 :::: D2;n1 > >
;:
> ð7Þ
Dn1;1 Dn1;2 :::: Dn1;n1
Due to the character of diffusion the off-diagonal elements or cross-diffusion coefficients Dij , i ≠ j, of Fick's
diffusion matrix are, in general, non-zero. It is very important to note that in ternary and higher mixtures,
where (n–1) independent driving forces and fluxes exist, one has to define the n-th reference component
before beginning any experimental measurements. Then all (n–1)×(n–1) diffusion coefficients are related
to that chosen reference. The numerical values of Fick's diffusion coefficients are only valid for a given
order of components; simply changing the order of components or changing the reference component will
change all numerical values Dij of that system [1986M1].
Intradiffusion coefficients DiT and diffusion coefficients at infinite dilution D0i(j)

The IUPAC monograph [1991W1] defines the intradiffusion coefficient, or tracer diffusion coefficient
[1986C1], DiT so that in a binary or multicomponent mixture it characterizes the diffusion of each of the
components i', i in an otherwise uniform mixture of i, i', j,… where the component under study i' is chemi-
cally identical with the component i but can be distinguished by some label such as isotopic form. When
diffusion is initiated by adding a vanishingly small amount of species i' to a mixture of i and one or more
other components, the diffusional flow is described by a tracer diffusion coefficient. In the simplest case,
where a small amount of isotopically labelled material is used to initiate diffusion in a pure substance,
the tracer diffusion coefficient will be identical to the self-diffusion coefficient, provided that the trace is
not significantly altered by the isotopic mass.
In concentrated solutions, intradiffusion is a much more complex process and the corresponding diffu-
sion coefficients are different from the other coefficients even in a binary mixture. The situation is illustrated
in Figure 1, where the different diffusion coefficients in a binary system cyclohexane(1)-benzene(2) at
298.15 K are shown. We see that the intradiffusion coefficients DiT, obtained by using different radioactive
isotopes, can differ from each other and from the interdiffusion coefficient D12.
The graph of an intradiffusion coefficient DiT ends at the self-diffusion coefficient of the respective pure
fluid. At the other end of the concentration range it becomes the diffusion coefficient at infinite dilution D0i(j)
of a few particles of i in almost pure component j. The graph of the interdiffusion coefficient D12 ends on
both sides of the concentration scale in these infinite dilution coefficients D0i(j). Since these coefficients are
corner-stone parameters in a series of theoretical and semi-empirical correlation models they are treated as a
separate category of diffusion coefficients and they are collected in separate subchapters called mixtures
Fig. 1. Diffusion coefficients in the

binary system cyclohexane(1) – benzene
(2) at 298.15 K [1969A1].

1 Introduction 5
at infinite dilution. As a summary, the definition binary interdiffusion occurs with two chemically distinct
species. In contrast, intradiffusion occurs with three distinguishable species, one of the species is chemically
different from the other two [1986C1].
Integral diffusion coefficients

As shown in Figure 1, the interdiffusion coefficients in dense mixtures depend on concentration; therefore
they are called differential coefficients. Some experimental methods, like experiments in a diaphragm-cell,
require larger concentration differences so that a concentration-averaged integral diffusion coefficient is
obtained
cðA
1
D ðcÞ ¼ ðcA cB Þ D12 dc: ð8Þ
cB
In gaseous mixtures, however, one observes only a small variation of diffusion coefficients with concentra-
tion. Therefore we find a huge amount of experimental data that were obtained under the following
experimental conditions: a gas is allowed to diffuse into another gas or into a gaseous or liquid mixture.
The respective diffusion coefficient D*12 of gas(1) in gas(2), D*1(2) of gas(1) in liquid(2), and D*1(23) of
gas(1) in liquid mixture is reported at a given temperature and pressure; it has to be considered as an integral
diffusion coefficient.
1.2.2 Temperature, pressure and density, concentration
For better comparison of different data sets temperatures are given exclusively in K, values given in °C or
°F are converted. No conversion of units was done for the pressure. Here, besides the normal pressure of
101.325 kPa all other SI and non-SI units were accepted.
Mass densities ρ in (g/ml) or (g/cm3) are used, and in some cases we find the so-called number density n
in 1/(10–25 m3), which is commonly used in statistical thermodynamics. In rare cases, especially when dif-
fusion coefficients in supercritical fluid systems were reported, the diffusion coefficients are given at a tem-
perature and a molar density. Besides standard density units we find the amagat ρA= ρ/ρSTP as a
dimensionless measure of relative density in terms of the density at standard conditions, where ρSTP=
44.614774 mol/m3. None of these units has been converted.
Mole fraction xi, volume fraction φi and mass fraction wi

Three different concentration fractions were used in the literature. In most cases the mole fraction xi is given
(xi = ni / Σnk, ni = amount of substance of component i), but for a number of mixtures the volume fraction φi
(φi = υi / Συk, υi = volume of component i) or the mass fraction wi (wi = mi / Σ mk, mi = mass of component i)
are used. The subscript i = 1 or 2 denotes the concentration of first or second component in the mixture,
respectively.
Molarity ci and molality mi

For the molar concentration ci we find the dimensions (mol/dm3) or (mol/l) , whereas in some cases of dif-
fusion of gases in liquid or electrolyte solutions the molality mi as (mol/kg solvent) is used. Some of the
mixtures were characterized by their mass ratio w2/w3 or volume ratio v2/v3.
1.3 Arrangement of data

The data tables for the pure fluids are organized by the gross formulae according to the Hill system, i.e. with
increasing number of C and H atoms followed by the other atoms according to their alphabetical order with
an Arabic numeral indicating the number of atoms of each element (if different from 1) in the right subscript
position. If substance formulae have the same first element, then the substance having a larger number of
that element follows the one with a lower number. If these numbers are the same, then the next elements

6 1 Introduction
are considered, using similar criteria. The absence of a next element in one of the substances confers a lower
position in the order to it. Isomeric substances are further sorted in the alphabetical order of their names.
No special substance indices are prepared for this volume, as the order of the substances corresponds to a
substance index based on their gross formula (in difficult cases it is recommended to apply the data of the
electronic form and to search there).
The data tables for the mixtures are organized by the gross formula of the first substance and for mixtures
with a common gross formula of the first substance by the gross formulae of the second one. Since diffusion
data are sensitive to the order of the components (see above) we have to keep the substances in the order
they were put by the experimentalists.
Different from the ordering in the previous 6th edition of Landolt-Börnstein [1969A1] we classify the
systems according to the type of their diffusion coefficient data. Section 3 contains self-diffusion co-
efficients of pure gases. In Section 4 we present intradiffusion and interdiffusion coefficients of gaseous
mixtures including diffusion in supercritical fluid systems and diffusion coefficients at infinite dilution.
Section 5 contains all systems with diffusion of gases or vapors in gas or liquid systems, and Section 6 con-
tains systems with diffusion of gases in liquid mixtures, electrolyte solutions and molten salt systems. In all
sections we present both experimental data and primary correlation equations.
Numbering of all references according to the Landolt-Börnstein system was made once for all systems,
and the printed references are a part of this overall reference list.
1.4 Substances and nomenclature

In general, for each substance, an unambiguous and unique name was chosen as the preferred name. For
organic substances, it is usually one of the various systematic names recommended by IUPAC
[1979IU1]. A few other systematic names and widely used trivial names were adopted as synonyms. The
symbols used to denote the natural elements are those recommended by IUPAC [1991IU1]. Each substance
is characterized by its chemical name and by its Chemical Abstracts Service (CAS) Registry Number to
allow a well-defined search where chemical names are difficult or different chemical names are in common
use. The CAS registry number can easily be searched for in all electronic files.
An index of substance names did not seem to be necessary. There are too many different names in use
and the CAS registry names as systematic names are rather complicated and not common enough to be
applied for such a purpose in this volume (LIDE [1994L1] applied these systematic names for alphabetical
ordering of the table of organic substances, together with a synonym index, a molecular formula and a struc-
tural formula index, which is all too extensive for our volume). Nevertheless, the user will find the informa-
tion he is looking for by first searching the gross formula of a given substance following the order of the
volume as described above.
1.5 Data reduction and correlations

As already mentioned above, we decided to present primary data sets only as we found them in the original
literature. In addition we included all different types of correlation equations given by the authors because
they provide more systematic information to the user. Again we present primary correlation results only, that
is, those correlations where the authors published both their own experimental data and gave an immediate
correlation of their measurements. In these cases we believe that the authors knowing the quality of their
data are able to present a reliable correlation. There are many papers where only "secondary" correlations
were reported and where the authors took literature data for their fits without discussing the quality of the
raw material. These correlation results were omitted.
In a few rare cases huge data pools (of all existing data) were collected from literature. These data were
critically evaluated and then all data which satisfy a certain quality standard were used for a data reduction.
The resulting correlation equations represent a kind of recommended smoothed data set with a very high
degree of reliability. These correlation results are included in the present volumes and marked with the
method CORR. Examples for such type of collections are the well-known collection of Marrero and Mason
[1972M1] on binary gaseous mixtures and those of Boushehri et al. [1987B1] and of Kestin et al. [1984K1].

1 Introduction 7
There is a large group of semi-empirical correlations of D(T), based on different Arrhenius type equa-
tions, and some are series expansions of D or ln D with respect to temperature and concentration. Marrero
and Mason derived semi-theoretical correlation equations for the product pD12, based on the Chapman-
Enskog theory:
h ’ i2 S 0
S
lnðp D12 Þ ¼ ln A þ s ln T ln ln 0
; ð9Þ
kT T T2
whereas experimental data D12(x1) were adjusted to refer to an equimolar composition according to equation
(10), where the D12 are theoretical expressions given in [1972M1]

1 þ D 12 ðx1 ¼ 0:5Þ
D12 ðx1 ¼ 0:5Þ ¼ D12 ðx1 Þ : ð10Þ
1 þ D 12 ðx1 Þ
An equimolar basis is a reasonable compromise between composition extremes and requires a minimum
number of adjustments of the data.
A similar type of equation is used to correlate binary diffusion coefficients of gaseous mixtures,
8 9
a1 x 2 >
D12 ¼ D012 > :1 þ ;; ð11Þ
1 þ a2 x 2
and to calculate recommended values for reference mixtures by Dunlop and co-workers [1977A1].

8 1 Introduction
References
1969A1 Andrussow, L: Landolt-Börnstein, Zahlenwerte und Funktionen aus Physik, Chemie,
Astronomie, Geophysik und Technik, 6th Ed., Vol.2, Part 5a, pp. 513–697, Springer-Verlag,
Berlin, Goettingen, Heidelberg 1969.
1972M1 Marrero, T.R., Mason, E.A.: Gaseous Diffusion Coefficients: J. Phys. Chem. Ref. Data 1 (1972)
1–118.
1977A1 Arora, P.S., Shankland, I.R., Bell, T.N., Yabsley, M.A., Dunlop, P.J: Rev. Sci. Instrum. 48 (1977)
673.
1979IU1 IUPAC Organic Chemistry Division: Nomenclature of organic chemistry, Rigaudy, J., Klesney,
S.P. (eds.), Pergamon Press, Oxford 1979.
1984K1 Kestin, J., Knierim, K., Mason, E.A., Najafi, B., Ro, S.T., Waldman, M.: J. Phys. Chem. Ref.
Data 13 (1984) 299–303.
1984T1 Tyrrell, H.J.V., Harris, K.R.: Diffusion in Liquids, Butterworths, London 1984.
1986C1 Cussler, E.L.: Diffusion, Mass transfer in fluid systems, Cambridge University Press 1986.
1986M1 Miller, G.G., Sartorio, R., Vitagliano, V.: J. Phys. Chem. 90 (1986) 1509–1519.
1987B1 Boushehri, A., Bzowski, J., Kestin, J., Mason, E.A.: J. Phys. Chem. Ref. Data 16 (1987)
445–466.
1987R1 Reid, R.C., Prausnitz, J.M., Polling, P.E.: The properties of gases and liquids, McGrawHill,
New York 1987.
1989L1 Lobo, V.M.M.: Handbook of Electrolyte Solutions, Elsevier, Amsterdam 1989.
1990H1 Haase, R.: Thermodynamics of irreversible processes, Dover Publications, New York 1990.
1991IU1 IUPAC Commission on Atomic Weights and Isotopic Abundances: Atomic weights of the
elements 1989, Pure Appl. Chem. 63 (1991) 991.
1991W1 IUPAC Commission on Thermodynamics: Measurement of the Transport Properties of Fluids,
Wakeham, W.A., Nagashima, A., Sengers, J.V. (eds.), Blackwell Sci. Publ., Oxford 1991.
1993T1 Taylor, R., Krishna, R.: Multicomponent Mass Transfer, John Wiley, New York, Chichester,
Brisbane, Toronto, Singapure 1993.
1994L1 Lide, R.D. (ed.): CRC Handbook of chemistry and physics, 75th Ed., CRC Press, Boca Raton,
Ann Arbor, London, Tokyo 1994.
1997B1 Berezhnoi, A.N., Semenov, A.V.: Binary diffusion Coefficients of Liquid Vapors in Gases,
Begell House, New York 1997.
1997M1 McNaught, A.D., Wilkinson, A.: Compendium of Chemical Technology, Blackwell Science
Oxford 1997.
1998B1 Barthel, J., Neueder, R.: ELDAR electrolyte solution data base, DECHEMA Frankfurt/M., FIZ
CHEMIE Berlin 1998.
2000P1 Polling, B.E., Prausnitz, J.M., O’Connell, J.P.: The properties of gases and liquids, McGrawHill,
New York 2000.
2004D1 DETHERM data base v.2.0, DECHEMA Frankfurt/M., FIZ CHEMIE Berlin 2004.

2 Measurement Methods 1
2 Measurement Methods
Data extract from Landolt-Bornstein IV/15A: Diffusion of Gases in Gases, Liquids
and their Mixtures
Methods for the measurement of diffusion coefficients of fluids were carefully reviewed by the IUPAC
Commission on Thermodynamics in its Experimental Thermodynamics Series [1991W1] and by Dunlop
et al. [1992D1]. Those monographs describe methods currently in use by active research workers, whereas
a detailed discussion of some of the older methods can be found in [1972M1, 1984T1]. Some review
papers, dealing with special topics, are on self-diffusion by Woolf and Mills [1973W1], on tracer diffusion
at high pressures by Barton and Speedy [1971B1], by Tyrrell and Watkiss [1976T1], on NMR studies of
self-diffusion by Weingärtner [1994W1], on chromatography by Maynard and Grushka [1975M1], on
liquid vapors in gases by Berezhnoi and Semenov [1997B1], and on supercritical fluid systems by Liong
et al. [1991L1] and by Funazukuri et al. [2004F1]. According to Table 1 the knowledge of the measurement
method is essential when evaluating accuracy and reliability of an experimental data set.
Table 1. Classification of different experimental methods with respect to accuracy and range of application,
according to the IUPAC review [1991W1].
Method Self- Intra- Inter- Accuracy Temperature Pressure
diffusion diffusion diffusion range range
diaphragm yes yes (yes) good (0.5–1%) moderate wide
open capillary yes moderate (1–2%) wide narrow
closed capillary yes yes high (0.2%) ambient moderate
two bulb yes yes good (0.2–1%) wide moderate
conductance yes high (0.2%) ambient narrow
Taylor dispersion yes yes moderate (≈1%) wide moderate
NMR yes yes moderate (1–2%) wide wide
light scattering yes moderate wide wide
Gouy interferometry yes high (< 0.1%) ambient narrow
Rayleigh yes high (< 0.1%) ambient narrow
interferometry
Cataphoresis yes moderate (2%) wide narrow
Back-diffusion yes moderate (2%) moderate moderate
Table 2. Symbols and abbreviations used within the present new Landolt-Börnstein series on Diffusion of
Gases and Liquids in Gases, Liquids and Electrolyte Mixtures to identify the experimental methods used for
the determination of an individual data set.
Symbol Description Symbol Description
ABSORB Wet column gas absorption DLS Dynamic light scattering
ARF Arrested flow EA Ch Electroanalytical methods:
BACK Back diffusion Chronopotentiometry
B-INT Bryngdahl interferometry EA ChA Electroanalytical methods:
BUBBLE Bubble collapse rate Chronoanperometry
CATA Cataphoresis EA DME Electroanalytical methods:
CC Closed capillary Polarography
CON Conductimetric methods EA RDE Electroanalytical methods:
CORR Correlation of experimental data Rotating disk electrode
(continued)

2 2 Measurement Methods
Table 2. (Continued)
Symbol Description Symbol Description
CT Loschmidt cell (Closed tube) EA V Electroanalytical methods:
DB Diffusion bridge Voltammetry
DIA Diaphragm cell GC Gas chromatography
GEL Gel techniques No Stand No standard method used
G-INT Gouy interferometry OEC Open ended capillary
HOLO Holographic interferometry OTE Open Tube Elution Method
INS Inelastic neutron scattering PF Porous frits, plug or barrier
INT Interferometry POINT Point source in steady flow
KMD KMD bubble solution RFGC Reversed flow gas
LAM Laminar liquid jet chromatography
M-INT Michelson interferometry R-INT Rayleigh interferometry
MZ-INT Mach-Zehnder interferometry SAV-INT Savart plate interferometry
NMR FG NMR spin echo field gradient STEFAN Stefan tube (Evaporation tube)
NMR PG MNR spin echo pulse gradient TAYLOR Taylor dispersion technique
No Info No Information on method used TB Two-bulb apparatus
2.1 NMR spin echo techniques

The NMR spin-echo technique is a rapid and reasonably accurate method for the measurement of self-
diffusion and intra-diffusion coefficients. It can be used to obtain data for gases, liquids or solutions over a
rather wide range (10–4 - 10–14 m2/s) and has several advantages over conventional tracer techniques, namely
the small sample size, the short time of measurement for rather high precision and its usability over a wide
temperature and pressure range. Its accuracy is moderate, namely ±(1–2)%, but the uncertainties can increase
up to ±10% in high-pressure experiments (up to 200 MPa). The limitations which applied to earlier versions
using static magnetic-field gradients and low frequencies yielding self-and intra-diffusion coefficients for
one component only are overcome by pulsed gradient methods and by Fourier transform techniques. This
enables the simultaneous determination of as many intradiffusion coefficients as there are resolvable resonant
frequencies [1991W1, 1992D1, 1994W1].
The NMR FG method (also abbreviated as FGSE) is based on the generation of spin echoes in two-pulse
experiments (Hahn's method for the measurement of relaxation times T2), in which a 90° radio frequency
(rf) pulse is applied to the sample at t = 0, followed by a 180° pulse at time τ. Due to thermal motion of
the particles, diffusion gives rise to more relaxation in addition to the normal spin-spin T2 mechanisms,
which is observed in an inhomogeneous magnetic field. The measurement of the echo height as a function
of pulse separation and gradient strength G allows to determine the self-diffusion coefficient. The echo
amplitude is given by [1994W1, 1991W1]

Að2tÞ ¼ Aðt ¼ 0Þ exp 2 2 G 2 t 3 D=3 exp½2t=T2 ; ð12Þ
where γ is the gyromagnetic ratio of the resonant nucleus and D is the self-diffusion coefficient. There are
practical limitations on the gradient that make measurements increasingly difficult if T2 is short, γ is low or
D is small. The standard method for overcoming problems associated with signal broadening by a field gra-
dient is the pulsed field gradient spin-echo technique (NMR PG method, also abbreviated as PFGSE), intro-
duced 1968 by Stejskal and Tanner (see [1994W1, 1992D1, 1991W1]). Here, the 90°–180° experiment is
performed in the presence of a pulsed field gradient, when pulsed gradients of duration δ and distance Δ are
applied between both rf-pulses. In a perfect homogeneous field the echo amplitude is given by [1994W1]
h i
Að2tÞ ¼ Aðt ¼ 0Þ exp ðGÞ2 ðD =3ÞD exp½2t=T2 : ð13Þ

Over the years many different rf-pulse sequences have been developed. The pulsed gradient method is
superior to the static gradient method which makes it the method of choice. The Fourier transform technique
of spin-echo experiments, as in other FT-NMR, transforms the second half of the spin-echo in the time
domain in order to separate individual contributions to the echo in the frequency domain. This results
in a significant improvement of the signal-to-noise ratio and, most important, it allows the simultaneous
determination of self- and intra-diffusion coefficients of the various components of a mixture. This requires
high-resolution PFGSE measurements. Experimental aspects and new methodological developments are
discussed in a series of monographs [1994W1, 1992D1, 1991W1].
2.2 Optical methods

2.2.1 Interferometry
The most precise experimental methods for the determination of interdiffusion coefficients in binary and ternary
liquid mixtures are Gouy and Rayleigh optical interferometric methods. With both methods in binary mixtures
one can achieve diffusion coefficients with an accuracy of about ±0.2% and a precision of ±(0.1–0.2)%. With
the best instruments an accuracy of better than ±0.1% and a precision of ±0.03% has been obtained
[1991W1]. In both interferometric methods monochromatic light passes through a diffusion boundary within
a diffusion cell and produces fringe patterns which are used for analysis. Other interferometric methods like that
of Jasmin, Mach-Zehnder or the shearing interferometry of Bryndahl have been developed. The first two yield
patterns similar to those of the Rayleigh method: all of them use two cells and give a refractive index profile.
Currently, only the shearing interferometry is used, primarily for molten salt systems [1991W1]. However, none
of the three methods has achieved the same precision as Gouy or Rayleigh (for details see [1984T1]).
In all interferometric methods, free diffusion in a vertical column starts from an infinitely sharp boundary
between two solutions of different concentration. As for the experimental conditions, the concentrations are
chosen to differ only slightly, the diffusion coefficients refer to the volume-fixed reference frame and are
effectively constant. Then, Fick's Second Law from equation (4) can be used. Its solution yields a concen-
tration profile in the shape of an error-function:
c pffiffiffiffiffiffiffiffi pffi
cðzÞ ¼ c þ erf y= D12 ; with y ¼ z 2 t ; ð14Þ
2
where Δc = cB – cT is the concentration difference between top and bottom of the cell. This profile is con-
verted into a profile of the refractive index from which the diffusion coefficient can be extracted. Fringe
positions in Rayleigh patterns yield the refractive index at corresponding levels of the cell, whereas Gouy
fringe patterns are a Fourier transform of the refractive-index gradient. For precise measurements the instru-
ment must be free of any mechanical vibrations which disturb the interface, and the diffusion cell and solu-
tion has to be kept at constant temperature to ±0.001 K. The relative advantages of the Gouy method are its
simpler optics and plate reading or fringe data acquisition, whereas the Rayleigh method has simpler theory
and running procedure. Additionally, it can go to smaller Δc and is more insensible to optical imperfections
and a poorly formed boundary. For details of instrumentation, experimental procedure and data analysis the
user is referred to monographs [1991W1].
2.2.2 Holographic interferometry
Holographic interferometry has been applied to diffusion measurements only recently. It combines
the advantages of the classic Mach-Zehnder interferometry (where no calibration is needed for a diffusion
measurement) with those of a holographic arrangement. Using a holographic plate instead of a reference cell
for the second channel allows to simplify the experimental arrangement. The instrument does not need a
reference cell with a time-constant medium nor does it need high-quality optical cells, yet it allows measure-
ments of a similarly high precision as other interferometric methods. One of the reviews on the experimental
setup and its development, on data evaluation and error analysis is given by Ruiz-Bevia et al. [1985R1].
The beam of a laser light source is split into a measuring and a reference beam.The measuring beam

passes the diffusion cell and on a holographic plate it is superimposed with the reference beam, resulting in
a interference fringe pattern. The cell is filled with a homogeneous liquid without refractive-index gradient
and the resulting pattern is stored on the holographic plate. The plate is used as basic hologram. During the
measurement the reference light beam, striking the holographic plate, reproduces the reference pattern
which is now used to produce the interferometric fringe pattern due to a concentration gradient in the diffu-
sion cell. A constant temperature of < ±0.02 K is required for real-time experiments, and a sharp initial inter-
face between the two liquids in the diffusion cell can be achieved by the flowing-junction technique
[1972D1]. Data analysis procedures developed for the Rayleigh or Mach-Zehnder interferometry can be
directly applied [1991W1].
2.2.3 Light scattering
A monochromatic beam of light passes through a dielectric medium and will be scattered by the molecules.
The Brownian motion of the molecules gives rise to local fluctuations in the dielectric susceptibility, asso-
ciated with local changes in temperature (entropy fluctuations) and concentration (mass diffusion fluctua-
tions). Diffusion coefficients and thermal diffusivities can be obtained from the results of Dynamic Light
Scattering (Photon Correlation Spectroscopy) [1991W1, 1976T1]. This popular way of studying transport
processes in liquid mixtures consists of monitoring the real-time fluctuations in terms of the intensity-time-
autocorrelation function G(2)(τ) of the scattered light, detected at different scattering angles θ or wave vec-
tors q with

4nD
q ¼ j qj ¼ sin ; ð15Þ
l 2
where nD is the refractive index and λ the wave length of the incoming light beam. Measurements of G(2)(τ)
provide information about hydrodynamic transport properties of the solute, such as diffusion coefficients
and viscosity. Since in actual DLS experiments the scattering intensity is monitored by certain arrangements
of photomultiplier tubes and is processed in a digital correlator, the autocorrelation function G(2)(τ) is the
primary experimental information. It becomes
Gð2Þ ðtÞ ¼ 1 þ ðIS exp½t=tS þ IC exp½t=tC Þ2 ð16Þ
and includes two exponential terms with their own characteristic decay time and transport coefficient. In
general we have to take into account both contributions from thermal diffusion DT and from mass diffusion
D12:

DT ¼ lim 1 q2 tS ; D12 ¼ lim 1 q2 tC : ð17Þ
q!0 q!0
The experimental setup for DLS measurements is described in [1991W1, 2004I1]. During the past three
decades DLS experiments have been used to study transport behavior in critical fluid mixtures. Krahn et al.
[1983K1] measured interdiffusion coefficients of a number of binary liquid mixtures in good agreement
with interferometric data. They claimed that an accuracy of 0.5% can be achieved for equimolar mixtures.
In ternary liquid mixtures, however, dynamic light scattering does not yield the mass diffusion coefficients
itself but it agrees with one of the eigenvalues of Fick’s diffusion matrix [2005I1].
2.3 Capillary diffusion methods

2.3.1 Closed tube (Loschmidt cell)
The closed-tube method was employed by Loschmidt in 1870, who determined the D12 for 10 gas pairs
between 252 and 293 K. The essential characteristic of this method is a variation of the mixture composition
with time and position along a tube which is closed at both ends. The gases of the mixture interdiffuse at
constant temperature and pressure. The arrangement can be applied both to liquid and gaseous systems

(closed capillary) [1972M1, 1991W1, 1992D1]. It is an absolute method, that is, no calibration is needed.
The diffusion cell usually consists of two identical symmetrical sections, joined together around a common
pivot. Initially both halves are isolated and filled with a gas or a mixture at identical pressure. Then the two
halves are carefully aligned and the diffusion is allowed to proceed. In an ideal model the diffusion can be
described by the solution of the one-dimensional Fick’s Second Law from equation (4). Taking into account
the boundary conditions, the concentration distribution in z-direction (0 ≤ z ≤ L) is given by
X1 nz
n 2 2 D12 t
c1 ðz; t Þ ¼ An cos exp ; ð18Þ
n¼0
L L2
where the An depend on the initial conditions.

The concentration changes are measured either continuously or after a definite period of time. There
are two different methods of measurement: (i) the concentration is measured at two planes, equidistant from
the initial boundary and normal to the longitudinal axis of the cell, or (ii) the alternate method is to stop
the diffusion process after a time tm before mixing is complete and measure the concentration. This second
method is applicable for gases only because their diffusion coefficients are much less dependent on compo-
sition [1991W1]. Uncertainties of the method are discussed in [1972M1]. A Loschmidt-cell experiment
can be combined with interferometric detection. Other modifications, such as the use of thermistor sensors
by Harned or by Dunlop, of scintillator sensors by Codastefano or mass spectrometer sensors by
Hogervorst, are discussed in [1992D1]. At moderate pressures Shakeland and Dunlop measure D12 at
300 K and 323 K with an accuracy of ±0.7% [1991W1, 1992D1], whereas Marrero and Mason assume
an accuracy of ±(1–3%) [1972M1].
2.3.2 Two-bulb method
The two-bulb method is the most widely used technique for diffusion coefficient measurements of gases.
The two bulbs or chambers are connected by a vertical tube of constant cross section and filled with gas
of known pressure. A small amount of a second, heavier gas is carefully added to the bottom bulb so that
diffusion takes place through the connecting capillary. Similar to the closed tube Fick’s Second Law from
equation (4) is solved under the respective initial and boundary conditions. The method was developed by
Ney and Armistead in 1947, and Barnes was first to derive a correct equation for evaluation. Corrections to
the method and precautions are discussed in [1991W1] and in [1992D1]. Dunlop and co-workers reported
diffusion coefficients for many systems with an accuracy of 0.1–0.2%. The method covers a wide range of
temperature: Cain and Taylor studied noble gas systems in the range 350–1300 K with an estimated accu-
racy of ±2%. An extension of the method, the dual two-bulb method, was introduced by Vugts and co-work-
ers, who measured ratios of diffusion coefficients D12(T1)/D12(T0) that are accurate to 0.1% [1992D1].
2.3.3 Evaporation tube (Stefan cell)
In 1873 Stefan developed the evaporation-tube method which is useful for the determination of diffusion
coefficients of liquid vapor-gas systems. The method has been extensively used, and almost all values on
vapor-gas mixtures have been produced this way [1972M1, 1997B1]. The experimental setup consists of
a vertical evaporation tube of uniform cross-section, sealed at one end and partially filled with the liquid.
The rest of the tube with length L is filled with the respective gas. From the gas-liquid interface vapor dif-
fuses through the gas to the mouth of the tube. Gas, flowing across the tube outlet, carries the vapor away.
The evaporation rate of the liquid is controlled by diffusion through the stagnant gas which fills the rest of
the tube. At constant temperature and pressure the diffusion coefficient can be determined from the slow
loss of liquid inside the tube. Under the assumption of quasi-steady-state conditions and gas insolubility,
an equation can be derived from Fick’s First Law which leads to
2 8 98 9 8 9
L2 L21 > > RT >
> : liq ; >> p pS >
>
D12 ¼ : ; ln: ;; ð19Þ
2ð t 2 t 1 Þ p M p

where pS is the vapor pressure. The subscripts 1, 2 on L, t denote the initial and final observation time of the
evaporation loss during an interval of diffusion [1972M1]. The diffusion coefficients obtained this way
belong to the integral type D*12 of vapor(1) in gas(2), and the error is (1–2)% (for details see [1997B1]).
The same procedure is applicable to the volatilization of a solid in the tube.
2.3.4 Open ended capillary
If the top of a gas container is opened, the gas will diffuse through the mouth into the surrounding volume.
An analysis of the composition of the remaining gas after a known period of time permits the determination
of the diffusion coefficient. First measurements were performed in 1882 by Obermayer; the theory was
described by Stefan [1972M1]. It is mainly used in isotope tracer experiments to determine self-diffusion
coefficients. Woolf and Mills give an accuracy of ±(1–2)% [1973W1].
A modification of the method for application to dilute electrolyte solutions was described by Lobo and
co-workers [1992D1]: A capillary, closed at one end, is filled with a solution of a given composition and
immersed in a stirred bath of a different composition, and diffusion is then allowed to proceed. After a sui-
table time interval the capillary is removed and its content is analyzed. The solution of the diffusion equa-
tion is similar to equation (18), although convergence of the Fourier series can be slow. The method is
particularly suited to tracer diffusion, but it has been commonly used with electrolytes and molten salts.
The precision of this method is typically ±0.5% [1992D1].
2.4 Chromatographic methods

All chromatographic methods are based on the dispersion of a small fluid sample volume of a given com-
position in the slow laminar flow of a carrier fluid with a slightly different composition within a linear tube
of uniform circular cross-section. As this narrow pulse is carried through the tube it spreads due to the influ-
ence of axial convection and molecular diffusion in radial direction. Eventually the peak elutes and a suita-
ble detector measures the radially averaged concentration profile as a function of time. Under well-defined
experimental conditions the rectangular sample plug is broadened to a peak with Gaussian distribution.
These rapid measurements of diffusion coefficients can, with careful design of the equipment, have an accu-
racy of ±1% [1991W1, 1992D1]. They can be performed in a rather wide range of temperature and pressure,
including supercritical fluid systems [1991L1, 2004F1]. This technique is used to measure interdiffusion
coefficients in binary liquid and gaseous mixtures, tracer diffusion in dense gases at high pressure and even
self-diffusion coefficients using deuteriated or radiotracer species [1992D1].
The general mathematical theory was developed by Taylor (1953) and by Aris (1956) and later modified
according to the needs of different methods. A fluid flows through a tube of length L and radius R with velo-
city u(r). At time t = 0 a sample plug is injected, and under suitable experimental conditions of laminar flow
the detector records a peak with Gaussian profile and a retention time tR. Fick’s Second Law simplifies to an
expression similar to equation (4), where we find the dispersion coefficient K instead of D12:
R2 u2 L
K ¼ D12 þ with u ¼ : ð20Þ
48D12 tR
A general solution has the form [1992D1]

" #
n ðt t R Þ2
cð t Þ ¼ pffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi exp ; ð21Þ
R 2 u 4Kt=u 2 2 2Kt=u2
where the variance is σ2 = 2Kt=u 2 . We can assume that σ2 =2KtR =u 2 , and the plate height H of the diffusion
column is then given by
H ¼ 2 u 2 =L ¼ ð2D12 = uÞ þ R 2 u=ð24D12 Þ: ð22Þ

2.4.1 Gas chromatography
The method of gas chromatographic peak broadening (CPB) was first introduced by Giddings and Seager
and has been used by many other workers for the measurement of gas-gas and gas-liquid vapor diffusion
coefficients. For gaseous systems, where D12 ≈ 10–4 m2/s, only the first term in (22) is significant, but many
workers prefer to solve (22) graphically [1975M1, 1991L1] or numerically. The instrumentation is based on
gas chromatography techniques. Different modifications, especially with respect to supercritical fluid sys-
tems, are discussed in [2004F1].
2.4.2 Taylor dispersion method
The Taylor dispersion method, based on commercially available HPLC instrumentation, is the most versa-
tile method for quick and reliable diffusion coefficient measurements in liquid and electrolyte binary to qua-
ternary mixtures. Here D12 ≈ 10–9 m2/s, so only the second term of (22) is significant. From (21) the
diffusion coefficients can be obtained either by the method of temporal moments [1991W1] or by a direct
non-linear least-square fit of a working equation (24) to the concentration profile of the peak. This is a more
accurate and recommended way of parameter estimation which can be easily extended to ternary liquid mix-
tures. The detector output signal S(t),
SðtÞ ¼ B1 þ B2 t þ B3 S ðt Þ; ð23Þ
is normalized to remove baseline and amplitude effects. For a ternary mixture the signal consists of two
overlapping Gaussian profiles that depend on the eigenvalues Di of the Fick’s diffusion matrix:
rffiffiffiffi 2 ( " #)
tR X Wi 12Di ðt tR Þ2
S ðt Þ ¼ exp : ð24Þ
t i¼1 W1 þ W2 R2 t
The normalized weighing factors Wi are functions of the concentration difference, the eigenvalues and the 4
diffusion coefficients Dij [2005I1]. Design criteria and details of the data analysis can be found in [1991W1,
1992D1] and, with special focus on supercritical systems, in [2004F1].
2.4.3 Arrested and reversed flow methods
Knox and McLaren [1964K1] have developed a modification of the peak-broadening technique, the
Arrested Flow Gas Chromatography (ARF) for the determination of gaseous diffusion coefficients. The
method is based on the idea that a small plug of a gas A is allowed to diffuse into a gas B, resulting in a
Gaussian concentration profile. The gas A is injected as a sharp band into a moving stream of gas B in
an empty column. The band is eluted about halfway through the tube, than the carrier stream is stopped
and A is allowed to diffuse into B for a given time t. The band is then eluted and the concentration profile
monitored. The experiment is repeated and the variance of the peaks versus the delay time yields an integral
diffusion coefficient of gas in gas. The method is independent on flow irregularities and requires short col-
umns only. It has a moderate accuracy of ±1.5% [1975M1].
Reversed-Flow Gas Chromatography (RFGC) consists of reversing the direction of flow of the carrier
gas from time to time. The experimental setup consists of another column, the diffusion column, which is
placed perpendicularly in the center of the chromatographic column (sampling column). The carrier gas
flows continuously through the sampling column, while it is stagnant inside the diffusion column. If other
gases are contained in the carrier and their concentration depends on a rate process within the column, each
flow reversal creates a series of extra peaks (sample peaks). Then by repeated flow reversal a repeated sam-
pling of this rate process is performed. The injection of the solute is done at the upper end of the diffusion
column, and any displacement of the sample is only caused by diffusion into the stagnant carrier gas. Thus,
plots of the height or area of sample peaks versus time from the solute’s injection on leads to the diffusion
coefficients [2004G1]. The precision of the RFGC is ±1%, which is claimed to be better than ARF and

continuous elution techniques. A review of the determination of diffusion coefficients by gas chromatogra-
phy is given in [2004K1].
2.5 Diffusion in diaphragm cells and through a porous barrier

Fick’s First Law describes the decay of a concentration gradient by diffusional mass transport. In an experi-
ment other mixing due to thermal or mechanical noise must be eliminated. One way to do this is a flow in
narrow channels such as Millipore filters, glass or metal sintered frits or porous barriers. The diaphragm cell
by Stokes is based on a sintered frit and is the standard cell type [1992D1, 1991W1]. The method is widely
used for binary, ternary and tracer or intra-diffusion [1968M1] with many modifications for special pur-
poses. For interdiffusion measurements there may be a loss of accuracy when extracting the required diffu-
sion coefficients. There are also problems with adsorption in some electrolyte solutions.
In a standard diaphragm cell experiment one starts with solutions of different composition in the two cell
compartments, and after a suitable time the contents of both cells are analyzed. The result of the experiment
is an integral diffusion coefficient in the sense of equation (8), additionally averaged over time. The value of
the diffusion coefficient is obtained from

1 cðt Þ
D ¼ ln ; ð25Þ
bt cð0Þ
where β is the cell constant, determined by a calibration measurement using aqueous KCl solutions. Experi-
mental criteria, features of cell design and high pressure measurements are discussed in [1991W1].
The diffusion of liquid vapors in gases through a porous barrier can be considered as a modification of
the Stefan diffusion cell where a porous barrier exists between the surface of the liquid and the gas phase. A
detailed description is given in [1997B1].
2.6 Steady-state methods

The diffusion bridge is a steady-state flow method in which two gas streams flow across opposite ends of a
hollow capillary tube or across opposite ends of a porous plug. The resulting gas streams are analyzed. The
flow rates have to be controlled and adjusted in order to produce the desired pressure difference across the
capillary. The ends of the capillary are generally kept at constant total pressure. The advantage of the diffu-
sion bridge is its usability over a wide temperature range [1972M1].
Another method for the determination of gaseous diffusion coefficients is back diffusion. The idea of this
method is to allow one component to diffuse upstream against the laminar flow of a second component. The
main gas flows through a tube XY at a certain mean velocity. At a point z = 0 the admixture gas enters the main
stream through a tube Z. An upstream transport of the admixture gas against the main flow takes place and
results in a steady state. Details of an instrument by Reuss et al. are discussed in [1991W1]. Back diffusion
can be used at extreme high or low temperatures. The range of measurement has been extended to diffusion coef-
ficients of noble gases at temperatures between 300 K and 1300 K with a precision of ±1% [1991W1, 1992D1].
The point source method was developed especially for measurements at high temperatures. It is very
similar to the gas chromatography method, except that the tracer is continuously streaming through a fine
hypodermic tube into the flowing carrier. By diffusion the tracer spreads through the carrier gas that has
characteristics of a steady-state laminar flow. The mixture composition is measured by means of a sample
probe located at various distances downstream of the tracer inlet. Point source measurements are available
from room temperature up to 1900 K. Details of the method are discussed in [1972M1]. The general relia-
bility is considered to be better than ±5%.
2.7 Gas absorption methods

The physical absorption of gases into liquids or liquid mixtures can be used to determine an integral diffu-
sion coefficient which is related to the mass transfer.

2.7.1 Wetted wall and wetted sphere absorber
In a wetted wall column absorber, the liquid flows uniformly as a thin film on the outside of a cylinder
inside the absorption cell. The gas passes the cell and both flow rates are measured. The gas absorption rate
is determined as the difference between inlet and outlet gas flow rates. The wetted sphere absorber is a mod-
ification of the wetted wall; the use of a spherical surface can eliminate ribbles in the liquid film and thus
provide a more homogeneous film. In both cases the specific absorption rate NA is related to the diffusion
coefficient [1995L1]. For absorption of a slightly soluble gas at short contact time the penetration theory
(Danckwerts [1970D1]) yields
rffiffiffiffiffiffiffi
DA pA
NA ¼ 2 ; ð26Þ
tc HA
where tc is the contact time, pA the partial pressure and HA the Henry constant of the gas A. The method can
be calibrated with measurements of N2O or CO2 in water and has an average error of ±2%.
2.7.2 Laminar liquid jet
Dynamic absorption measurements in a laminar liquid jet with very short contact time have several advan-
tages: (i) short contact time minimizes the influence of chemical reactions; (ii) no Marangoni instabilities
and interfacial resistance and (iii) an accurately known interfacial area from the dimensions of the jet.
The range of contact time can vary between 0.001 s and 0.5 s. In the absorption cell a jet of liquid traveling
from the nozzle to the receiver passes the second (gaseous or liquid) phase. For an ideal liquid jet the solu-
tion of the diffusion equation yields [1964W1]
rffiffiffiffiffiffiffiffi
ci c0 x

¼ 4 D ; ð27Þ
c c0
where denotes the flow rate and x the axial coordinate. The experimental error of this method is
within ±2%.
2.7.3 Bubble collapse and bubble solution
The rate of growth and collapse of bubbles in a liquid phase has been subject to numerous investigations.
Methods have been developed according to which the diffusion coefficient of a slightly soluble gas in a
liquid is calculated from the volume of gas that is absorbed per unit of time from a gas bubble of constant
size [1981D1]. The change of bubble radius with time is related to the diffusion coefficient by

dr DAB ½cðrÞ cðr ¼ 1ÞRT r
¼ 1þ p ffiffiffiffiffiffiffiffiffiffiffiffiffi
ffi : ð28Þ
dt pðrÞ r DAB t
Neglecting the transient term leads to a simplified version which had been frequently used but which is in
some discrepancy with experimental results. In [1981D1] a modification of a constant bubble size is pro-
posed and details of the theory and instrumentation are discussed. Another modification based on equation
(28) was developed by Krieger, Mulholland and Dickey [1967K1]. They propose a bubble solution method
by applying the penetration theory to the collapse of bubbles in a liquid phase. Various modifications
have been studied to simplify the measurements without loss of accuracy which is assumed to be between
2% and 5%.
2.7.4 N2O-analogy
Due to the chemical reactions of CO2 with all kind of amines, neither solubility nor diffusivity of CO2 in
these systems can be measured directly. On the other hand, acid gases like CO2 or H2S have to be removed

from natural gas, synthetic natural gas or other process gas streams by means of absorption, which requires
the knowledge of their solubility and diffusivity. The similarity in mass, molecular structure and molecular
interaction forces of CO2 and N2O led to the assumption that the ratio of their diffusivities is similar in dif-
ferent liquid systems. The so-called N2O-analogy assumes that the diffusion coefficient of CO2 can be
obtained from experimental data of N2O in the same liquid or mixture:

DCO2
DCO2 ¼ DN2 O : ð29Þ
DN2 O in water
Versteeg and van Swaaij [1988V1] proposed, based on available data for the diffusivity of N2O and CO2 in
water, convenient equations
DN2 O ¼ 5:07 106 exp½2371=ðT ½KÞ m2 s1 ;
DN2 O ¼ 2:35 106 exp½2119=ðT ½KÞ m2 s1 ; ð30Þ

which can be used as reference equations in the N2O-analogy and for calibration of gas absorption measure-
ments.
2.8 Recommended data sets for calibration

Many experimental techniques for the determination of diffusion coefficients are operated in an absolute
mode. In the case of instruments for gas phase measurements, however, calibration can sometimes be neces-
sary in order to evaluate corrections. For liquid-phase measurements it can be advantageous to perform rela-
tive measurements by the commonly used diaphragm cell technique. In either case high-precision reference
values of the diffusion coefficients are particularly useful for checking the operation of any new instrument
[1991W1].
For gas mixtures recommended reference data of the diffusion coefficients of five mixtures at 300 K and
101.325 kPa can be calculated from equation (11),

a 1 x2
D12 ¼ D012 1 þ ; ð31Þ
1 þ a2 x 2
which represents experimental data by Dunlop et al. [1977A1]. The estimated uncertainty of these data is
about ±0.1%. In this equation x2 denotes the mole fraction of the heavier component, and the values of
D012, a1 and a2 are listed in Table 3.
Temperature dependencies of diffusion coefficients over a very wide range of temperatures from 50 to
1000 K are given as correlation equations developed by Kestin et al. [1984K1]. The authors collected all
experimental data, critically evaluated them and present correlation equations which areincluded in the data
collection.
Table 3. Values for the parameters D012, a1 and a2 for equation (31).
System D012 [105 m2s–1] a1 a2
He - Ar 7.344 0.0846 1.4825
He - N2 7.067 0.0676 1.4883
He - O2 7.469 0.0564 1.1270
He - CO2 6.029 0.0905 2.3952
N2 - Ar 2.034 0.0041 0.0

References
1964K1 Knox, J.H., McLaren, L.: Anal. Chem. 36 (1964) 1477.
1964W1 Ward, W.J., Quinn, J.A.: A.I.Ch.E. Journal 10 (1964) 155.
1967K1 Krieger, I.M., Mulholland, G.W., Dickey, C.S.: J. Phys. Chem. 71 (1967) 1123.
1968M1 Mills, R., Woolf, L.A.: The Diaphragm Cell, ANU press Canberra 1968.
1970D1 Danckwerts, P.V.: Gas-Liquid Reaction, McGraw-Hill, New York 1970.
1971B1 Barton, A.F.M., Speedy, R.J.: High Temp. – High Press. 2 (1971) 587–595.
1972D1 Dunlop, P.J., Steel, B.J., Lane, J.E.: Experimental methods for studying diffusion in gases,
liquids, and solids, Weissberger, A. Rossiter, B.W.(eds.), Physical Methods of Chemistry, Vol. 1,
Part IV, Wiley-Interscience, New York, 1972, 205.
1972M1 Marrero, T.R., Mason, E.A.: Gaseous Diffusion Coefficients J. Phys. Chem. Ref. Data 1 (1972)
1–118.
1973W1 Woolf, L.A., Mills, R.: Proc. Symp. Thermophys. Prop. 6 (1973) 124–129.
1975M1 Maynard, V.R., Grushka, E.: Adv. Chromatography 12 (1975) 99–140.
1976T1 Tyrrell, H.J.V., Watkiss, P.J.: Ann. Rep. Prog. Chem., Sect. A 73 (1976) 35–52.
1977A1 Arora, P.S., Shankland, I.R., Bell, T.N., Yabsley, M.A., Dunlop, P.J: Rev. Sci. Instrum. 48 (1977)
673.
1981D1 De Blok, W.J., Fortuin, J.M.H.: Chem. Eng. Sci. 36 (1981) 1687–1694.
1983K1 Krahn, W., Schwieger, G., Lucas, K.: J. Phys. Chem. 87 (1983) 4515.
Data 13 (1984) 299–303.
1984T1 Tyrrell, H.J.V., Harris, K.R.: Diffusion in Liquids, Butterworths, London 1984.
1985R1 Ruiz-Beviá, F., Celdran-Mallol, A., Santos-Garcia, C., Fernández-Sempere, J.: Applied Optics
24 (1985) 1481–1484; Canad. J. Chem. Eng. 63 (1985) 765-771.
1988V1 Versteeg, G.F., van Swaaij, W.P.M.: J. Chem. Eng. Data 33 (1988) 29–34.
1991L1 Liong, K.K., Wells, P.A., Foster, N.R.: J. Supercritical Fluids 4 (1991) 91–108.
1991W1 IUPAC Commission on Thermodynamics: Measurement of the Transport Properties of Fluids,
Wakeham, W.A., Nagashima, A., Sengers, J.V. (eds.), Blackwell Sci. Publ., Oxford 1991.
1992D1 Dunlop, P.J., Harris, K.R., Young, D.J.: Experimental methods for studying diffusion in gases,
liquids, and solids, Rossiter, B.W. Beatzold, R.C.(eds.), Physical Methods of Chemistry, 2n ed.,
Vol. 6, Wiley-Interscience, New York, 1992, 175–288.
1994W1 Weingärtner, H.: Ann. Rep. Prog. Chem., Sect. C 91 (1994) 36–69.
1995L1 Li, M.-H., Lai, M.-D.: J. Chem. Eng. Data 40 (1995) 486–492.
1997B1 Berezhnoi, A.N., Semenov, A.V.: Binary diffusion Coefficients of Liquid Vapors in Gases,
Begell House, New York 1997.
2004F1 Funazukuri, T., Kong, C.Y., Kagei, S.: J. Chromatography A 1037 (2004) 411–429.
2004G1 Gavril, D., Rashid Atta, K., Karaiskakis, G.: Fluid Phase Equil. 218 (2004) 177–188.
2004I1 Ivanov, D.A., Winkelmann, J.: Phys. Chem. Chem. Phys. 6 (2004) 3490–3499.
2004K1 Karaiskakis, G., Gavril, D.: J. Chromatography A 1037 (2004) 147–189.
2005I1 Ivanov, D.A., Grossmann, T., Winkelmann, J.: Fluid Phase Equil. 228-229 (2005) 283–291.

Index of substances
Index of substances
Data extract from Landolt-Börnstein IV/15A: Diffusion of Gases in Gases, Liquids and their Mixtu
Diffusion in Pure Gases
Diffusion in Gaseous Mixtures

Binary Mixtures
Diffusion in Binary Gaseous Mixtures
Diffusion of Gas/Vapor in Supercritical Fluid Systems
Diffusion of Gas/Vapor in Liquid
Binary Mixtures at Infinite Dilution
Ternary and Quaternary Mixtures
Diffusion of Gas/Vapor in Gas or Liquid

Diffusion of Gas/Vapor in Gas
Diffusion in Supercritical Fluid Systems
Diffusion of Gas in Solution

Diffusion of Gas in Electrolyte Solution
Landolt-Börnstein DOI: 10
New Series IV/15A # Sprin
2
Diffusion in Pure Gases

Ar, argon He, helium
# Springer 2007
C2H4, ethene D3N, ammonia-d3
CClF3, trifluoro-chloro-methane C2H4Br2, 1,2-dibromo-ethane D4C, methane-d4 Kr, krypton
CF4, tetrafluoro-methane C2H6, ethane F6Mo, molybdenum hexafluoride NO, nitrogen oxide
CH2Br2, dibromo-methane C3H6, propene F6S, sulfur hexafluoride N2, nitrogen
DOI: 10.1007/978-3-540-49718-9_3
CH4, methane C3H8, propane F6U, uranium hexafluoride N2, nitrogen-(15-N)
CO, carbon monoxide C3D8, propane-d8 F6W, tungsten hexafluoride N2O, nitrous oxide
CO2, carbon dioxide C4H10, butane H2, hydrogen Ne, neon
C2H2, ethyne C5H12, pentane H2O, water O2, oxygen
C2D2, ethyne-d2 D2, deuterium H3N, ammonia Xe, xenon
Diffusion in Gaseous Mixtures

Binary Mixtures
Diffusion in Binary Gaseous Mixtures

Component (1): Air
Component (2): CO2, carbon dioxide F6S, sulfur hexafluoride H2O, water
Component (1): Ar, argon
Component (2): Air C3H6O, propan-2-one H3N, ammonia O2, oxygen
CH4, methane C4H10O, diethyl ether He, helium Xe, xenon
CO, carbon monoxide C6H6, benzene Kr, krypton
Index of substances
CO2, carbon dioxide F6S, sulfur hexafluoride N2, nitrogen

C2H6O, ethanol H2, hydrogen Ne, neon
Component (1): CHCl3, trichloro-methane
Component (2): Air
Component (1): CH3Cl, chloro-methane
Component (2): C2H5Cl, chloro-ethane
Component (1): CH4, methane
Component (2): Air CF4, tetrafluoro-methane C2H6, ethane
Ar, argon CH3Cl, chloro-methane
Component (2): C3D8, propane-d8
Component (2): C3H8, propane
Component (1): CO, carbon monoxide
Component (2): Air CO2, carbon dioxide F6S, sulfur hexafluoride O2, oxygen
Component (1): CO2, carbon dioxide
Landolt-Börnstein
New Series IV/15A
Component (2): Ar, argon CH4, methane C2H4, ethene
Component (2): C16H34, hexadecane
Component (2): F6S, sulfur hexafluoride
Component (2): N2, nitrogen
Component (2): N2O, nitrous oxide
Component (1): C2H4, ethene
Component (1): C2H6, ethane
Component (2): Ar, argon C3H7ClO2S, propane-1-sulfonyl chloride C4H10, butane He, helium
CF4, tetrafluoro-methane C3H8, propane C5H12, 2,2-dimethyl-propane N2, nitrogen
CO2, carbon dioxide C4H10, 2-methyl-propane F6S, sulfur hexafluoride
Component (1): C3H6, propene
Component (2): Kr, krypton
Component (2): Ar, argon C4H10, butane C5H12, 2,2-dimethyl-propane N2, nitrogen
Index of substances
C4H10, 2-methyl-propane C4H6O2, butane-2,3-dione He, helium

Component (1): C4H10, butane
Component (2): Ar, argon CO2, carbon dioxide
Component (1): C4H10, 2-methyl-propane
Component (2): C5H12, 2,2-dimethyl-propane
Component (2): C5H12, 2,2-dimethyl-propane He, helium N2, nitrogen
Component (1): C5H12, pentane
Component (2): He, helium N2, nitrogen
DOI: 10
# Sprin
4
Component (1): C8H16, oct-1-ene

Component (2): C2H6, ethane C3H8, propane C6H14, hexane
Component (1): C10H8, naphthalene
# Springer 2007
Component (1): C14H10, phenanthrene
DOI: 10.1007/978-3-540-49718-9_3
Component (1): DH, hydrogen-deuterium
Component (2): Ar, argon N2, nitrogen
Component (1): D2, deuterium
Component (2): Ar, argon Kr, krypton Ne, neon Xe, xenon
CO2, carbon dioxide N2, nitrogen O2, oxygen
Component (2): Ar, argon Kr, krypton Ne, neon
He, helium N2, nitrogen Xe, xenon
Component (1): H, hydrogen atom
Component (2): Ar, argon H2, hydrogen He, helium
Component (1): H2, hydrogen
Component (2): Air C2H6, ethane D2, deuterium Ne, neon
Ar, argon C3H8, propane He, helium O2, oxygen
CH4, methane C4H10, butane F6S, sulfur hexafluoride Xe, xenon
CO, carbon monoxide C4H10, 2-methyl-propane Kr, krypton
CO2, carbon dioxide C5H12, 2,2-dimethyl-propane N2, nitrogen
Component (1): H2O, water
Index of substances
Component (1): He, helium

Component (2): Air C2F3H3, 1,1,1-trifluoro-ethane C2H6, ethane H3N, ammonia
Ar, argon C2F3H3, 1,1,2-trifluoro-ethane C3F8, octafluoro-propane He-3, helium-3
CClF3, trifluoro-chloro-methane C2F4H2, 1,1,1,2-tetrafluoro-ethane C3H6, cyclopropane Kr, krypton
CF4, tetrafluoro-methane C2F6, hexafluoro-ethane C3H8, propane NO, nitrogen oxide
CHF3, trifluoro-methane C2HF5, 1,1,1,2,2-pentafluoro-ethane C4F8, octafluoro-cyclobutane N2, nitrogen
CH3F, fluoro-methane C2H2, ethyne C4H6, buta-1,3-diene N2O, nitrous oxide
CH4, methane C2H2F4, 1,1,2,2-tetrafluoro-ethane C4H10, butane Ne, neon
CO, carbon monoxide C2H4, ethene F6S, sulfur hexafluoride O2, oxygen
COS, carbon oxide sulfide C2H4F2, 1,1-difluoro-ethane H2, hydrogen T2, tritium
CO2, carbon dioxide C2H5F, fluoro-ethane D2, deuterium Xe, xenon
Component (1): He-3, helium-3
Component (2): H2, hydrogen D2, deuterium He, helium T2, tritium
Component (2): Ar, argon CO2, carbon dioxide F6S, sulfur hexafluoride NO, nitrogen oxide
CF4, tetrafluoro-methane C2H4, ethene H2, hydrogen N2O, nitrous oxide
Landolt-Börnstein
New Series IV/15A
CH4, methane C2H6, ethane H2O, water O2, oxygen
CO, carbon monoxide C4H10, butane He, helium Xe, xenon
Component (1): Ne, neon
Component (2): Ar, argon CO, carbon monoxide H2, hydrogen N2, nitrogen
CF4, tetrafluoro-methane CO2, carbon dioxide He, helium O2, oxygen
CH4, methane F6S, sulfur hexafluoride Kr, krypton Xe, xenon
Component (1): O, oxygen atom
Component (2): Ar, argon He, helium N2, nitrogen O2, oxygen
Component (1): O2, oxygen
Component (2): Ar, argon F6S, sulfur hexafluoride H2O, water Kr, krypton
CO2, carbon dioxide H2, hydrogen He, helium N2, nitrogen
Component (1): O2S, sulfur dioxide
Component (1): Xe, xenon
Component (2): Ar, argon CO2, carbon dioxide He, helium Ne, neon
CH4, methane H2, hydrogen Kr, krypton O2, oxygen
CO, carbon monoxide H3N, ammonia N2, nitrogen
Diffusion of Gas/Vapor in Supercritical Fluid Systems

Component (1): C3H6O, propan-2-one
Index of substances
Component (1): C6H6, benzene

Component (1): C6H6O, phenol
Component (1): C19H36O2, cis-octadec-9-enoic acid methyl ester
Component (1): C20H30Fe, decamethyl-ferrocene
Component (2): CHF3, trifluoro-methane
Component (1): C20H30Fe * F6P, decamethyl-ferrocenium hexafluorophosphate
Component (2): CHF3, trifluoro-methane
H2 O, water
DOI: 10
# Sprin
6

# Springer 2007
Component (2): C12F27N, tris-nonafluorobutyl-amine
Component (1): CF4, tetrafluoro-methane
DOI: 10.1007/978-3-540-49718-9_3
Component (2): C12F27N, tris-nonafluorobutyl-amine C14H27N, tetradecanenitrile C14H30, tetradecane
Component (1): CO2, carbondioxide
Component (2): C7H16, heptane
Component (1): H3N, ammonia
Component (2): C3H9N, trimethylamine
Component (1): He-3, helium-3
Component (1): N2O4, dinitrogen tetraoxide
Index of substances
Component (2): HNO3, nitricacid


Component (2): C9H7N, quinoline C10H9N, 2-methyl-quinoline C10H9N, 4-methyl-quinoline C10H9N, 7-methyl-quinoline
C9H7N, isoquinoline C10H9N, 3-methyl-quinoline C10H9N, 6-methyl-quinoline C10H9N, 8-methyl-quinoline
Binary Mixtures at Infinite Dilution
Landolt-Börnstein
New Series IV/15A
Component (2): CH4, methane H2, hydrogen N2, nitrogen Xe, xenon
CO2, carbon dioxide H3N, ammonia O2, oxygen
Component (2): He, helium C8H18, octane
Component (2): C20H42, eicosane
Component (2): C20H42, eicosane
Component (1): C2H3Cl, chloro-ethene
Component (2): C6H12, cyclohexane
Component (2): C6H12, cyclohexane C8H18, octane
Component (2): C16H34, hexadecane C6H14, hexane C7H16, heptane
C4H10O, butan-1-ol C6H5Cl, chlorobenzene C8H18, octane
Component (2): O2, carbon dioxide
Component (2): Ar, argon Kr, krypton Xe, xenon
Index of substances
He, helium Ne, neon

Component (2): Ar, argon C20H42, eicosane Ne, neon
CO2, carbon dioxide Kr, krypton Xe, xenon
Component (2): Ar, argon C2F3H3, 1,1,1-trifluoro-ethane C3F8, octafluoro-propane Kr, krypton
CF4, tetrafluoro-methane C2F4H2, 1,1,1,2-tetrafluoro-ethane C3H6, cyclopropane NO, nitrogen oxide
CHF3, trifluoro-methane C2F6, hexafluoro-ethane C3H8, propane N2, nitrogen
CH2F2, difluoro-methane C2HF5, 1,1,1,2,2-pentafluoro-ethane C4F8, octafluoro-cyclobutane N2O, nitrous oxide
CH3F, fluoro-methane C2H2, ethyne C4H6, buta-1,3-diene Ne, neon
CH4, methane C2H2F4, 1,1,2,2-tetrafluoro-ethane C4H10, butane O2, oxygen
CO, carbon monoxide C2H4, ethene F6S, sulfur hexafluoride Xe, xenon
COS, carbon oxide sulfide C2H4F2, 1,1-difluoro-ethane H2, hydrogen
CO2, carbon dioxide C2H5F, fluoro-ethane D2, deuterium
DOI: 10
# Sprin
8

Component (2): Ar, argon CO2, carbon dioxide O2, oxygen
# Springer 2007
Component (2): Ar, argon CO2, carbon dioxide N2, nitrogen
CF4, tetrafluoro-methane H2, hydrogen O2, oxygen
CH4, methane Kr, krypton Xe, xenon
DOI: 10.1007/978-3-540-49718-9_3
Component (2): Air, air
Component (2): CH4, methane H2, hydrogen N2, nitrogen
Index of substances
Landolt-Börnstein
New Series IV/15A
Component (3): H2, hydrogen He, helium N2, nitrogen
Component (1): C7H6O2, benzoic acid
Component (3): CH4O, methanol
Component (1): C13H9N, acridine
Component (3): Ar, argon Ne, neon Xe, xenon
Index of substances

DOI: 10
# Sprin
10
Diffusion of Gas/Vapor in Gas or Liquid

Diffusion of Gas/Vapor in Gas
# Springer 2007
Component (1): Air
Component (2): Ar, argon C2H2, ethyne C6H5Cl, chlorobenzene Cl2CO, phosgene
DOI: 10.1007/978-3-540-49718-9_3
Br2, bromine C2H6O, ethanol C6H5NO2, nitrobenzene F6S, sulfur hexafluoride
CClN, cyanogen chloride C3H8O, propan-2-ol C6H6, benzene H2O, water
CCl3NO2, trichloro-nitro-methane C4H10O, butan-1-ol C6H7N, aniline H3N, ammonia
CHN, hydrogen cyanide C4H10O, butan-2-ol C7H8, toluene He, helium
CH4, methane C4H8O2, acetic acid ethyl ester C12H10, biphenyl O2, oxygen
CO2, carbon dioxide C5H12O, pentan-2-ol Cl2, chlorine O2S, sulfur dioxide
Component (1): Ar, argon-37
Component (2): CCl4, tetrachloro-methane C6H12, cyclohexane C7H8, toluene He, helium
CH4, methane C6H14, 2,3-dimethyl-butane C8H18, 2,2,4-trimethyl-pentane Kr, krypton
CO, carbon monoxide C6H14, hexane C8H18, octane NO, nitrogen oxide
CO2, carbon dioxide C6H5NO2, nitrobenzene DH, hydrogen-deuterium N2, nitrogen
C2H2, ethyne C6H6, benzene D2, deuterium Ne, neon
C3H6O, propan-2-one C6H7N, aniline F6S, sulfur hexafluoride O2, oxygen
C3H8, propane C7H16, heptane H2, hydrogen O2S, sulfur dioxide
C6H12, methyl-cyclopentane C7H16, 2,4-dimethyl-pentane H3N, ammonia Xe, xenon
Component (1): Br2, bromine
Index of substances
Component (2): Air H2, hydrogen

Component (1): CCl2F2, dichloro-difluoro-methane
Component (2): Air C2H6O, ethanol H2O, water O2, oxygen
Ar, argon C3H8, propane N2, nitrogen
CO2, carbon dioxide C6H6, benzene Ne, neon
Component (1): CCl3F, trichloro-fluoro-methane
Component (2): Air
Component (1): CCl3NO2, trichloro-nitro-methane
Component (2): Air
Component (1): CCl4, tetrachloro-methane
Component (2): Air CH4, methane N2, nitrogen
CF4, tetrafluoro-methane CO2, carbon dioxide
Component (1): CF4, tetrafluoro-methane
Component (2): Ar, argon He, helium
Component (2): Air CO2, carbon dioxide He, helium N2, nitrogen
Component (1): CH2BrCl, bromo-chloro-methane
Landolt-Börnstein
New Series IV/15A
Component (2): Air
Component (1): CH2Br2, dibromo-methane
Component (1): CH2Cl2, dichloro-methane
Component (2): Air He, helium
Component (1): CH2F2, difluoro-methane
Component (2): Air C3H8, propane He, helium Ne, neon
Component (1): CH2I2, diiodo-methane
Component (2): Air
Component (1): CH2O2, formic acid
Component (2): Air
Component (2): Air
Component (1): CH3I, iodo-methane
Component (1): CH3NO2, nitromethane
Component (2): Air
Component (1): CH3T, methane-t
Component (2): Ar, argon CF4, tetrafluoro-methane CH4, methane
Component (2): Air CO, carbon monoxide H2, hydrogen N2, nitrogen
Index of substances
Ar, argon C2H6, ethane H2O, water O2, oxygen

CF4, tetrafluoro-methane C3H8, propane He, helium
Component (2): Air H2, hydrogen N2, nitrogen
CO2, carbon dioxide He, helium
Component (2): Ar, argon F6S, sulfur hexafluoride He, helium
CO, carbon monoxide H2, hydrogen N2, nitrogen
Component (2): Air CO2, carbon dioxide C14 F6S, sulfur hexafluoride N2, nitrogen
Ar, argon C2H4O, oxirane H2, hydrogen N2O, nitrous oxide
CH4, methane C3H8, propane H2O, water O2, oxygen
DOI: 10
# Sprin
12
Component (1): C2Cl2F4, 1,2-dichloro-1,1,2,2-tetrafluoro-ethane

Component (2): Air
Component (1): C2Cl3F3, 1,1,2-trichloro-1,2,2-trifluoro-ethane
# Springer 2007
Component (2): Air
Component (1): C2Cl4, 1,1,2,2-tetrachloro-ethene
Component (2): Air CF4, tetrafluoro-methane CH4, methane
DOI: 10.1007/978-3-540-49718-9_3
Component (1): C2F3H3, 1,1,1-trifluoro-ethane
Component (2): Air
Component (1): C2F4H2, 1,1,1,2-tetrafluoro-ethane
Component (2): Air
Component (1): C2HClF4, 2-chloro-1,1,1,2-tetrafluoro-ethane
Component (2): Air
Component (1): C2HCl2F3, 2,2-dichloro-1,1,1-trifluoro-ethane
Component (2): Air
Component (1): C2HCl3, 1,1,2-trichloro-ethene
Component (2): Air
Component (1): C2HCl5, pentachloro-ethane
Component (2): Air
Component (1): C2HF5, 1,1,1,2,2-pentafluoro-ethane
Component (2): Air
Component (1): C2H2, ethyne
Component (2): Air C2H4, ethene
Component (1): C2H2Br2, 1,2-dibromo-ethene
Component (2): Air
Index of substances
Component (1): C2H2Cl4, 1,1,2,2-tetrachloro-ethane

Component (2): Air
Component (1): C2H3Cl, chloro-ethene
Component (1): C2H3Cl3, 1,1,1-trichloro-ethane
Component (2): Air CF4, tetrafluoro-methane
Component (1): C2H3Cl3, 1,1,2-trichloro-ethane
Component (2): Air
Component (2): Air H2, hydrogen He, helium
C3H6, propene H2O, water N2, nitrogen
Component (1): C2H4Cl2, 1,1-dichloro-ethane
Component (2): Air
Component (1): C2H4O2, acetic acid
Component (2): Air
Component (1): C2H4O2, formic acid methyl ester
Landolt-Börnstein
New Series IV/15A
Component (2): Air
Component (1): C2H5Br, bromo-ethane
Component (1): C2H5ClO, 2-chloro-ethanol
Component (2): Air
Component (1): C2H5I, iodo-ethane
Component (2): Air C2H2, ethyne H2, hydrogen
Ar, argon C2H4, ethene He, helium
CO2, carbon dioxide C3H8, propane N2, nitrogen
Component (1): C2H6O, ethanol
Component (2): Air CO2, carbon dioxide He, helium
Ar, argon H2, hydrogen N2, nitrogen
Component (1): C2H6O2, ethane-1,2-diol
Component (2): Air CO2, carbon dioxide N2, nitrogen
Component (1): C2H8N2, ethane-1,2-diamine
Component (2): Air
Component (1): C3H3N, acrylonitrile
Component (2): Air
Component (1): C3H4, propyne
Index of substances
Component (2): Air

Component (1): C3H4, propadiene
Component (2): Air
Component (1): C3H5Br2Cl, 1,2-dibromo-3-chloro-propane
Component (2): Air
Component (1): C3H5Cl, 3-chloro-prop-1-ene
Component (2): Air
Component (2): Air
Component (1): C3H6, cyclopropane
Component (2): Air
Component (2): H2, hydrogen He, helium N2, nitrogen
DOI: 10
# Sprin
14

Component (2): Air
Component (1): C3H6O, prop-2-en-1-ol
# Springer 2007
Component (2): Air
Component (2): Ar, argon CO2, carbon dioxide He, helium N2, nitrogen
DOI: 10.1007/978-3-540-49718-9_3
Component (1): C3H6O2, acetic acid methyl ester
Component (2): Air
Component (1): C3H6O2, formic acid ethyl ester
Component (2): Air
Component (1): C3H6O2, propionic acid
Component (2): Air
Component (1): C3H7Br, 1-bromo-propane
Component (2): Air
Component (2): Air
Index of substances

Component (1): C3H7Cl, 1-chloro-propane
Component (1): C3H7I, 1-iodo-propane
Component (2): Air
Component (2): Air
Component (1): C3H8O, propan-1-ol
Component (2): Air
Landolt-Börnstein
New Series IV/15A
Component (2): Air
Component (1): C3H8O2, propane-1,2-diol
Component (2): Air
Component (1): C3H8O2, 2-methoxy-ethanol
Component (2): Air
Component (1): C4H6, buta-1,3-diene
Component (2): Air
Component (1): C4H6, but-1-yne
Component (2): Air
Index of substances
Component (1): C4H8, trans-but-2-ene

Component (2): Air
Component (1): C4H8, cis-but-2-ene
Component (2): Air
Component (1): C4H8, 2-methyl-propene
Component (2): Air
Component (1): C4H8, but-1-ene
Component (2): Air
Component (1): C4H8, cis-but-2-ene
DOI: 10
# Sprin
16
Component (1): C4H8, trans-but-2-ene

Component (1): C4H8Cl2O, bis-(2-chloro-ethyl) ether
# Springer 2007
Component (2): Air
Component (1): C4H8O, butan-2-one
Component (2): Air
DOI: 10.1007/978-3-540-49718-9_3
Component (1): C4H8O2, isobutyric acid
Component (2): Air
Component (1): C4H8O2, butyric acid
Component (2): Air
Component (1): C4H8O2, propionic acid methyl ester
Component (2): Air
Component (1): C4H8O2, 1,4-dioxane
Component (2): Air
Component (1): C4H8O2, formic acid propyl ester
Component (2): Air
Component (1): C4H8O2, acetic acid ethyl ester
Component (2): Air N2, nitrogen
Component (1): C4H9Br, 1-bromo-butane
Component (1): C4H9Br, 2-bromo-butane
Component (1): C4H9Cl, 1-chloro-butane
Index of substances
Component (1): C4H9Cl, 2-chloro-butane

Component (1): C4H9I, 1-iodo-butane
Component (1): C4H9I, 2-iodo-butane
Component (2): Air
Component (2): Ar, argon C3H8O, propan-2-ol H2, hydrogen He, helium
Component (1): C4H10O, butan-2-ol
Component (2): Air
Component (1): C4H10O, 2-methyl-propan-1-ol
Landolt-Börnstein
New Series IV/15A
Component (2): Air
Component (2): Air
Component (1): C4H10O, diethyl ether
Component (2): Air Ar, argon CO2, carbon dioxide
Component (2): CO2, carbon dioxide H2, hydrogen
Component (2): H2 (hydrogen)
Component (2): H2 (hydrogen)
Index of substances

Component (1): C4H10O2, 2-ethoxy-ethanol
Component (2): Air
Component (1): C4H10O3, 2-(2-hydroxy-ethoxy)-ethanol
Component (1): C4H11N, isobutylamine
Component (2): Air
Component (1): C4H11N, diethylamine
Component (2): Air
Component (1): C4H11N, butylamine
DOI: 10
# Sprin
18
Component (1): C5H8, 2-methyl-buta-1,3-diene

Component (2): Air
Component (1): C5H10, pent-1-ene
# Springer 2007
Component (2): Air
Component (1): C5H10, cyclopentane
Component (2): Air
DOI: 10.1007/978-3-540-49718-9_3
Component (1): C5H10O, pentan-2-one
Component (2): Air
Component (1): C5H10O2, formic acid isobutyl ester
Component (2): Air
Component (1): C5H10O2, propionic acid ethyl ester
Component (2): Air
Component (1): C5H10O2, butyric acid methyl ester
Component (2): Air
Component (1): C5H10O2, acetic acid propyl ester
Component (2): Air
Component (1): C5H10O2, acetic acid isopropyl ester
Component (2): Air
Component (1): C5H10O2, 3-methyl-butyric acid
Component (2): Air
Component (1): C5H10O2, isobutyric acid methyl ester
Component (2): Air
Component (1): C5H11Cl, 1-chloro-pentane
Index of substances
Component (1): C5H12, 2-methyl-butane

Component (2): Air
Component (2): Air
Component (2): Air
Component (2): Ar, argon C3H8O, propan-2-ol He, helium
CO2, carbon dioxide H2, hydrogen N2, nitrogen
Component (1): C5H12O, pentan-1-ol
Component (2): Air
Component (1): C5H12O, pentan-2-ol
Component (2): Air
Component (1): C6F6, hexafluoro-benzene
Component (1): C6H4Cl2, 1,2-dichloro-benzene
Landolt-Börnstein
New Series IV/15A
Component (2): Air
Component (1): C6H4Cl2, 1,3-dichloro-benzene
Component (2): Air
Component (1): C6H5Br, bromobenzene
Component (1): C6H5Cl, chlorobenzene
Component (1): C6H5F, fluorobenzene
Component (1): C6H5NO2, nitrobenzene
Component (2): Air CO2, carbon dioxide H2, hydrogen N2, nitrogen
Ar, argon F6S, sulfur hexafluoride He, helium
Component (1): C6H7N, aniline
Component (1): C6H10O, 4-methyl-pent-3-en-2-one
Component (2): Air
Component (2): Air
Component (1): C6H12, hex-1-ene
Index of substances
Component (2): Air

Component (2): CO2, carbon dioxide F6S, sulfur hexafluoride H2, hydrogen N2, nitrogen
Component (1): C6H12O, 4-methyl-pentan-2-one
Component (2): Air
Component (1): C6H12O2, acetic acid butyl ester
Component (2): Air
Component (1): C6H12O2, formic acid pentyl ester
Component (2): Air
Component (1): C6H12O2, formic acid isopentyl ester
Component (2): Air
Component (1): C6H12O2, 4-hydroxy-4-methyl-pentan-2-one
Component (2): Air
DOI: 10
# Sprin
20
Component (1): C6H12O2, 4-methyl-pentanoic acid

Component (2): Air
Component (1): C6H12O2, isobutyric acid ethyl ester
# Springer 2007
Component (2): Air
Component (1): C6H12O2, hexanoic acid
Component (2): Air
DOI: 10.1007/978-3-540-49718-9_3
Component (1): C6H12O3, acetic acid 2-ethoxy-ethyl ester
Component (2): Air
Component (1): C6H13Br, 1-bromo-hexane
Component (1): C6H13F, 1-fluoro-hexane
Component (1): C6H14, hexane
Component (2): Air
Component (1): C6H14, 3-methyl-pentane
Component (1): C6H14, 2,3-dimethyl-butane
Index of substances
Component (1): C6H14, 2,2-dimethyl-butane

Component (2): Ar, argon CH4, methane
Component (2): CO2, carbon dioxide H2, hydrogen He, helium N2, nitrogen
Component (1): C6H14O, diisopropyl ether
Component (2): Air
Component (1): C6H14O, hexan-1-ol
Component (2): Air
Component (1): C6H14O, 2-methyl-pentan-2-ol
Component (1): C6H14O3, 2-(2-ethoxy-ethoxy)-ethanol
Component (2): Air
Component (1): C6H14O4, triethylene glycol
Landolt-Börnstein
New Series IV/15A
Component (1): C6H15N, triethyl-amine
Component (2): Air
Component (1): C6H15O4P, phosphoric acid triethyl ester
Component (2): Air
Component (1): C7H5N, benzonitrile
Component (2): Air
Component (1): C7H7Cl, chloromethyl-benzene
Component (2): Air
Component (1): C7H7Cl, 4-chloro-toluene
Component (2): Air
Component (2): Air
Component (2): Air
Component (1): C7H7F, 4-fluoro-toluene
Component (1): C7H8, toluene
Component (2): Air CO2, carbon dioxide H2, hydrogen
Ar, argon F6S, sulfur hexafluoride He, helium
Component (1): C7H8O, benzyl alcohol
Index of substances
Component (2): Air

Component (1): C7H14, methyl-cyclohexane
Component (2): Air F6S, sulfur hexafluoride
Component (1): C7H14O2, butyric acid propyl ester
Component (2): Air
Component (1): C7H14O2, isobutyric acid isopropyl ester
Component (2): Air
Component (1): C7H14O2, isobutyric acid propyl ester
Component (2): Air
Component (1): C7H14O2, propionic acid butyl ester
Component (2): Air
Component (1): C7H14O2, propionic acid isobutyl ester
Component (2): Air
DOI: 10
# Sprin
22
Component (1): C7H14O2, acetic acid pentyl ester

Component (2): Air
# Springer 2007
Component (2): Air Ar, argon CO2, carbon dioxide He, helium
Component (1): C7H16, 3-methyl-hexane
DOI: 10.1007/978-3-540-49718-9_3
Component (1): C7H16, 2-methyl-hexane
Component (1): C7H16, 2,4-dimethyl-pentane
Component (1): C7H16, 2,2,3-trimethyl-butane
Component (1): C7H16O, heptan-1-ol
Component (2): Air
Component (1): C8H8, styrene
Component (2): Air
Index of substances
Component (1): C8H10, 1,3-dimethyl-benzene

Component (2): Air
Component (2): Air
Component (1): C8H10, ethylbenzene
Component (2): Air
Component (2): Air
Component (1): C8H10, ethylbenzene
Component (1): C8H16, cyclooctane
Component (2): Ar, argon CH4, methane
Component (1): C8H16, trans-1,2-dimethyl-cyclohexane
Landolt-Börnstein
New Series IV/15A
Component (2): CH4, methane F6S, sulfur hexafluoride
Component (1): C8H16, cyclooctane
Component (2): F6S, sulfur hexafluoride He, helium
Component (1): C8H16, trans-1,2-dimethyl-cyclohexane
Component (1): C8H16O2, isobutyric acid isobutyl ester
Component (2): Air
Component (1): C8H16O2, pentanoic acid propyl ester
Component (2): Air
Component (1): C8H16O2, butyric acid isobutyl ester
Component (2): Air
Component (1): C8H16O2, propionic acid pentyl ester
Component (2): Air
Component (1): C8H18, 2,2,4-trimethyl-pentane
Component (2): Air
Component (1): C8H18, octane
Component (2): Air Ar, argon
Index of substances

Component (1): C8H18, 3-methyl-heptane
Component (1): C8H18, 2,4-dimethyl-hexane
Component (1): C8H18, 3-ethyl-hexane
Component (1): C8H18, 3-ethyl-2-methyl-pentane
Component (1): C8H18, 2,3-dimethyl-hexane
DOI: 10
# Sprin
24
Component (1): C8H20O7P2, diphosphoric acid tetraethyl ester

Component (2): Air
Component (1): C8H24O4Si4, octamethyl-cyclotetrasiloxane
# Springer 2007
Component (2): Air
Component (1): C9H6N2O2, 2,4-diisocyanato-1-methyl-benzene
Component (2): Air
DOI: 10.1007/978-3-540-49718-9_3
Component (1): C9H10O2, acetic acid benzyl ester
Component (2): Air
Component (1): C9H12, propylbenzene
Component (2): Air
Component (1): C9H12, 1,2,4-trimethyl-benzene
Component (2): Air
Component (1): C9H12, 1,3,5-trimethyl-benzene
Component (2): Air
Component (1): C9H12, 1-methylethyl-benzene
Component (2): Air
Component (1): C9H14O, 3,5,5-trimethyl-cyclohex-2-enone
Component (2): Air
Component (1): C9H18O2, butyric acid pentyl ester
Component (2): Air
Component (1): C9H18O2, pentanoic acid isobutyl ester
Component (2): Air
Component (1): C9H18O2, isobutyric acid pentyl ester
Component (2): Air
Index of substances
Component (1): C9H20, nonane

Component (2): Air Ar, argon CO2, carbon dioxide He, helium
Component (1): C10H8, naphthalene
Component (2): Air C2H4, ethene N2, nitrogen
CO2, carbon dioxide H2, hydrogen
Component (1): C10H14, 1-isopropyl-4-methyl-benzene
Component (2): Air
Component (1): C10H22, decane
Component (1): C11H16, 1-(1,1-dimethyl-ethyl)-4-methyl-benzene
Component (2): Air
Component (1): C11H24, undecane
Component (2): Air
Component (1): C12H27O3P, phosphorous acid tributyl ester
Component (2): Air
Component (1): C14H10, anthracene
Landolt-Börnstein
New Series IV/15A
Component (2): Air
Component (2): Air
Component (1): C16H10, pyrene
Component (2): Air
Component (1): C16H22O4, phthalic acid dibutyl ester
Component (2): Air N2, nitrogen
Component (1): C16O4P, bis-(2-ethylhexyl) phosphate
Component (2): Air
Component (1): C18H12, 1,2-benzanthracene
Component (2): Air
Component (1): C18H34O4, decanedioic acid dibutyl ester
Component (2): CO2, carbon dioxide He, helium N2, nitrogen
Component (1): C20H12, 4,5-benzopyrene
Component (2): Air
Component (1): C21H21O4P, tricresyl phosphate
Component (2): Air
Component (1): C24H38O4, phthalic acid diisooctyl ester
Component (2): Air
Component (1): C24H38O4, phthalic acid bis-(2-ethyl-hexyl) ester
Component (2): CO2, carbon dioxide He, helium N2, nitrogen
Index of substances
Component (1): Cl2, chlorine

Component (1): DH, hydrogen-deuterium
Component (2): Air C7H16, 2,4-dimethyl-pentane F6S, sulfur hexafluoride Kr, krypton
Ar, argon C8H18, 2,2,4-trimethyl-pentane HT, hydrogen-tritium N2, nitrogen
CO, carbon monoxide C8H18, octane H2, hydrogen Ne, neon
CO2, carbon dioxide DH, hydrogen-deuterium H3N, ammonia T2, tritium
C7H16, heptane DT, deuterium-tritium He, helium
Component (1): D3CH, methane-d3
Component (2): Ar, argon Ne, neon
Component (1): D4C, methane-d4
DOI: 10
# Sprin
26
Component (1): H, hydrogen atom

Component (2): Ar, argon H2, hydrogen N2, nitrogen
Component (1): HNO3, nitric acid
# Springer 2007
Component (2): Air
Component (1): HT, hydrogen-tritium
DOI: 10.1007/978-3-540-49718-9_3
Component (2): Air C4H10, butane C6H14, hexane DT, deuterium-tritium
Ar, argon C4H4S, thiophene C7H8, toluene F6S, sulfur hexafluoride
CCl2F2, dichloro-difluoro-methane C4H8S, tetrahydro-thiophene C7H16, 2,4-dimethyl-pentane HT, hydrogen-tritium
CH4, methane C5H5N, pyridine C7H16, heptane H2O, water
CO, carbon monoxide C5H11N, piperidine C8H18, 2,2,4-trimethyl-pentane H3N, ammonia
CO2, carbon dioxide C6H5NO2, nitrobenzene C8H18, octane He, helium
C2Cl2F4, 1,2-dichloro-1,1,2,2-tetrafluoro-ethane C6H6, benzene C10H22, 2,3,3-trimethyl-heptane Kr, krypton
C2H6, ethane C6H7N, aniline C10H22, decane N2, nitrogen
C2H6O, ethanol C6H12, cyclohexane C12H26, dodecane Ne, neon
C3H6O, propan-2-one C6H12, methyl-cyclopentane DH, hydrogen-deuterium O2, oxygen
C3H8, propane C6H14, 2,3-dimethyl-butane D2, deuterium T2, tritium
Component (2): Air CH4, methane H2, hydrogen N2, nitrogen
Ar, argon CO2, carbon dioxide He, helium O2, oxygen
Component (1): H2O4S, sulfuric acid
Component (1): H3N, ammonia
Index of substances
Component (2): Air C4H10O, diethyl ether He, helium

Ar, argon F6S, sulfur hexafluoride Kr, krypton
CO, carbon monoxide H2, hydrogen N2, nitrogen
Component (2): Air C2H6, ethane C7H16, heptane H3N, ammonia
Ar, argon C2H6O, ethanol C7H16, 2,4-dimethyl-pentane He-3, helium-3
CCl2F2, dichloro-difluoro-methane C3H8O, propan-1-ol C8H18, octane Kr, krypton
CH4, methane C3H8O, propan-2-ol C8H18, 2,2,4-trimethyl-pentane NO, nitrogen oxide
CH4O, methanol C4H10O, butan-1-ol DH, hydrogen-deuterium N2, nitrogen
CO, carbon monoxide C5H12O, pentan-1-ol D2, deuterium Ne, neon
CO2, carbon dioxide C6H5NO2, nitrobenzene F6S, sulfur hexafluoride O2, oxygen
C2Cl2F4, 1,2-dichloro-1,1,2,2-tetrafluoro-ethane C6H6, benzene HT, hydrogen-tritium T2, tritium
C2H2, ethyne C6H14, hexane H2, hydrogen Xe, xenon
C2H4, ethene C6H14O, hexan-1-ol H2O, water
Component (1): INa, sodium iodide
Component (2): Ar, argon Kr, krypton Xe, xenon
Landolt-Börnstein
New Series IV/15A
Component (2): Ar, argon CO2, carbon dioxide D2, deuterium Ne, neon
CF4, tetrafluoro-methane C2H4, ethene H2, hydrogen O2, oxygen
CHCl3, trichloro-methane C3H6O, propan-2-one He, helium O2S, sulfur dioxide
CH4, methane C4H10O, diethyl ether NO, nitrogen oxide Xe, xenon
CO, carbon monoxide DH, hydrogen-deuterium N2, nitrogen
Component (1): N, nitrogen atom
Component (2): Ar, argon C3H6O, propan-2-one C6H12, methyl-cyclopentane C12H26, dodecane
CCl2F2, dichloro-difluoro-methane C4H10, butane C6H12, cyclohexane F6S, sulfur hexafluoride
CCl3F, trichloro-fluoro-methane C4H10, 2-methyl-propane C6H14, hexane H2, hydrogen
CH3Cl, chloro-methane C4H10O, diethyl ether C6H14, 2,3-dimethyl-butane H2O, water
CH4, methane C4H4S, thiophene C7H8, toluene H2S, hydrogen sulfide
CO, carbon monoxide C4H8S, tetrahydro-thiophene C7H16, heptane H3N, ammonia
CO2, carbon dioxide C5H5N, pyridine C7H16, 2,4-dimethyl-pentane He, helium
C2Cl2F4, 1,2-dichloro-1,1,2,2-tetrafluoro-ethane C5H11N, piperidine C8H18, 2,2,4-trimethyl-pentane O2, oxygen
C2H4, ethene C6H5NO2, nitrobenzene C8H18, octane O2S, sulfur dioxide
C2H6, ethane C6H6, benzene C10H22, 2,3,3-trimethyl-heptane
C2H6O, ethanol C6H7N, aniline C10H22, decane
Component (2): Air C3H8, propane O2, oxygen
Index of substances
C2H4O, oxirane N2, nitrogen

Component (1): Na, sodium
Component (2): NO, nitrogen oxide DH, hydrogen-deuterium He, helium
Ar, argon D2, deuterium Kr, krypton
Component (1): Ne, neon-22
Component (2): Ne, neon-20
Component (1): O, oxygen atom
Component (2): Ar, argon Kr, krypton O2, oxygen
He, helium N2, nitrogen
DOI: 10
# Sprin
28

Component (2): CO2, carbon dioxide H2, hydrogen
Component (1): P, phosphorus
# Springer 2007
Component (1): Rb, rubidium
DOI: 10.1007/978-3-540-49718-9_3
Component (1): T2, tritium
Component (2): Ar, argon D2, deuterium Kr, krypton
Component (2): Ar, argon D2, deuterium He, helium N2, nitrogen
DH, hydrogen-deuterium H2, hydrogen Kr, krypton Ne, neon
Component (1): Zn, zinc
Component (2): Ar, argon H2, hydrogen He, helium N2, nitrogen
Index of substances
Index of substances
Diffusion of Supercritical Fluid Systems
Component (1): CCl4, tetrachloro-methane Component (1): C6H5Cl, chlorobenzene

Component (2): CO2, carbon dioxide Component (2): CO2, carbon dioxide
F6S, sulfur hexafluoride Component (1): C6H5I, iodobenzene
Component (1): CHCl3, trichloro-methane Component (2): CO2, carbon dioxide
Component (2): CO2, carbon dioxide Component (1): C6H5NO2, nitrobenzene
Component (1): CH2Cl2, dichloro-methane Component (2): CO2, carbon dioxide
Component (2): CO2, carbon dioxide Component (1): C6H6, benzene
Component (1): CH4O, methanol Component (2): CO2, carbon dioxide
Component (2): CO2, carbon dioxide C6H14, 2,3-dimethyl-butane
Component (1): C2H6O, ethanol F6S, sulfur hexafluoride
Component (2): CO2, carbon dioxide Component (1): C6H6O, phenol
Component (1): C3H6O, propan-2-one Component (2): CO2, carbon dioxide
Component (2): CClF3, trifluoro-chloro-methane Component (1): C6H14, hexane
CO2, carbon dioxide Component (2): CO2, carbon dioxide
Component (1): C3H8O, propan-1-ol F6S, sulfur hexafluoride
Component (2): CO2, carbon dioxide Component (1): C6H14O, diisopropyl ether
Component (1): C4H8O, butan-2-one Component (2): CO2, carbon dioxide
Component (2): CO2, carbon dioxide Component (1): C7H6O, benzaldehyde
Component (1): C4H8O, tetrahydrofuran Component (2): CO2, carbon dioxide
Component (2): CO2, carbon dioxide Component (1): C7H6O2, benzoic acid
Component (1): C4H8O2, acetic acid ethyl ester Component (2): CO2, carbon dioxide
Component (2): CO2, carbon dioxide F6S, sulfur hexafluoride
Component (1): C4H8O2, 1,4-dioxane Component (1): C7H7NO3, 2-nitro-anisole
Component (1): C4H10O, diethyl ether Component (1): C7H8, toluene
Component (1): C4H10O, butan-1-ol C6H14, 2,3-dimethyl-butane
Component (1): C5H2F6O2, 1,1,1,5,5,5-hexafluoro-pentan-2,4-dione Component (1): C7H8O, anisole
Component (1): C5H5F3O2, 1,1,1-trifluoro-pentan-2,4-dione Component (1): C7H12O, cycloheptanone
Component (1): C5H8O, cyclopentanone Component (1): C7H14O, heptan-2-one
Component (1): C5H10O, pentan-3-one Component (1): C7H14O, heptan-3-one
Component (1): C5H10O, pentan-2-one Component (1): C7H14O, heptan-4-one
Component (1): C5H12, pentane Component (1): C7H14O, 2,4-dimethyl-pentan-3-on
Component (1): C5H12O, pentan-1-ol Component (1): C7H16, heptane
Component (1): C6H4Br2, 1,3-dibromo-benzene Component (1): C8H5F3O2S, 1,1,1-trifluoro-4-(2-thieny
Component (2): CClF3, trifluoro-chloro-methane Component (2): CO2, carbon dioxide
Component (1): C6H4Cl2, 1,2-dichloro-benzene Component (1): C8H7N, indole
Component (1): C6H4Cl2, 1,4-dichloro-benzene Component (1): C8H8, styrene
Component (1): C6H5Br, bromobenzene Component (1): C8H10, 1,4-dimethyl-benzene
Component (2): CO2, carbon dioxide Component (2): CClF3, trifluoro-chloro-methane
30 Index of substances
Component (1): C8H10, 1,2-dimethyl-benzene Component (1): C10H14, 1,1-dimethylethyl-benzene

Component (1): C8H10, 1,3-dimethyl-benzene Component (1): C10H14O, tricyclo[3.3.1.1(3.7)]-dec
Component (1): C8H10, 1,4-dimethyl-benzene Component (1): C10H16, 4-isopropenyl-1-methyl-cy
Component (1): C8H10, ethylbenzene Component (1): C10H16, (R)-(+)-limonene
Component (1): C8H10, 1,4-dimethyl-benzene Component (1): C10H16, 2,6,6-trimethylbicyclo[3.1.
Component (2): F6S, sulfur hexafluoride Component (2): CO2, carbon dioxide
Component (1): C8H10N4O2, 1,3,7-trimethyl-2,6 Component (1): C10H16, 6,6-dimethyl-2-methylene-
-dioxopurine heptane
Component (1): C8H10O, 2,4-dimethyl-phenol Component (1): C10H16O, 3,7-dimethyl-octa-2,6-die
Component (1): C8H16, oct-1-ene Component (1): C10H18O, (+-)-3,7-dimethyl-octa-1,
C2H6, ethane Component (1): C10H22, decane
Component (1): C8H18, octane Component (2): CO2, carbon dioxide
F6S, sulfur hexafluoride Component (1): C11H8O2, 2-methyl-1,4-naphthoqui
Component (1): C8H18O, octan-1-ol Component (2): CO2, carbon dioxide
Component (2): CO2, carbon dioxide Component (1): C11H16O, cis-3-methyl-2-pent-2-en
Component (1): C9H12, 1-methylethyl-benzene enone
Component (1): C9H12, propylbenzene Component (1): C11H22O, undecan-6-one
Component (1): C9H12, 1,3,5-trimethyl-benzene Component (1): C11H24, undecane
F6S, sulfur hexafluoride Component (1): C12H10, biphenyl
Component (1): C9H16O, cyclononanone Component (2): CO2, carbon dioxide
Component (2): CO2, carbon dioxide Component (1): C12H12, 2,3-dimethyl-naphthalene
Component (1): C9H18O, nonan-2-one Component (2): CO2, carbon dioxide
Component (1): C9H18O, nonan-5-one Component (2): CO2, carbon dioxide
Component (1): C9H18O, 2,2,4,4-tetramethyl-pentan-3-one Component (2): CO2, carbon dioxide
Component (2): CO2, carbon dioxide Component (1): C12H26, dodecane
Component (1): C9H20, nonane Component (2): CO2, carbon dioxide
Component (1): C9H20O, nonan-1-ol Component (1): C13H9N, acridine
Component (1): C10H8, naphthalene Component (1): C14H10, phenanthrene
C6H14, 2,3-dimethyl-butane C6H14, 2,3-dimethyl-butane
F6S, sulfur hexafluoride Component (1): C14H14N3NaO3S, sodium 4-(4'-dim
Component (1): C10H8CuF6O4, bis(1,1,1-trifluoro-pentan-2,4- phenylazo)-benzene-1-sulfonate
dionato-O,O') copper Component (2): CO2, carbon dioxide
Component (2): CO2, carbon dioxide Component (1): C14H14O, dibenzyl ether
Component (1): C10H8O, naphthalen-2-ol Component (2): CO2, carbon dioxide
Component (2): CO2, carbon dioxide Component (1): C14H30, tetradecane
Component (1): C10D8, naphthalene-d8 Component (2): CO2, carbon dioxide
Component (2): C2H4, ethene F6S, sulfur hexafluoride
DOI: 10.1007/978-3-540-49718-9_3
# Springer 2007
Index of substances
Component (1): C15H28O2, cis-9-tetradecenoic acid methyl ester Component (1): C21H40O2, cis-11-icosenoic acid m
Component (1): C15H30O2, tetradecanoic acid methyl ester Component (1): C21H40O4, cis-octadec-9-enoic acid
Component (2): CO2, carbon dioxide 3-triol monoester
Component (1): C16H10, pyrene Component (2): CO2, carbon dioxide
Component (2): CO2, carbon dioxide Component (1): C22H32O2, cis-4,7,10,13,16,19-doco
Component (1): C17H32O2, cis-hexadec-9-enoic acid methyl ester Component (2): CO2, carbon dioxide
Component (2): CO2, carbon dioxide Component (1): C22H32O2, retinol acetate
Component (1): C17H34O2, hexadecanoic acid methyl ester Component (2): CO2, carbon dioxide
Component (2): CO2, carbon dioxide Component (1): C23H34O2, cis-docosa-4,7,10,13,16
Component (1): C18H12, 1,2-benzophenantrene acid methyl ester
Component (1): C18H19NO, 4'-(pentyloxy)-[1,1'-biphenyl]-4- Component (1): C23H44O2, cis-docos-13-enoic acid
carbonitrile Component (2): CO2, carbon dioxide
Component (2): CO2, carbon dioxide Component (1): C25H48O2, cis-tetracos-15-enoic ac
Component (1): C18H21NO, N-(4-methoxybenzylidene)-4-n- Component (2): CO2, carbon dioxide
butylaniline Component (1): C29H50O2, D-alpha-tocopherol
Component (1): C18H30O2, cis,cis,cis-octadeca-6,9,12-trienoic acid Component (1): C29H50O2, DL-alpha-tocopherol
Component (1): C18H30O2, cis,cis,cis-octadeca-9,12,15-trienoic acid Component (1): C30H50, 2,6,10,15,19,23-hexamethy
Component (2): CO2, carbon dioxide 2,6,10,14,18,22-tetracosahexaen
Component (1): C18H32O2, cis,cis-octadeca-9,12-dienoic acid Component (2): CO2, carbon dioxide
Component (2): CO2, carbon dioxide Component (1): C31H46O2, 2-methyl-3-phytyl-1,4-n
Component (1): C18H34O2, cis-octadec-9-enoic acid Component (2): CO2, carbon dioxide
Component (2): CO2, carbon dioxide Component (1): C39H72O5, cis-octadec-9-enoic acid
Component (1): C18H36O2, octadecanoic acid 3-triol diester
Component (1): C19H32O2, cis-octadeca-6,9,12-trienoic acid methyl ester Component (1): C40H56, beta-carotene
Component (1): C19H34O2, cis,cis-octadeca-9,12-dienoic acid methyl Component (1): C57H92O6, trilinolenin
ester Component (2): CO2, carbon dioxide
Component (2): CO2, carbon dioxide Component (1): C57H104O6, cis-octadec-9-enoic aci
Component (1): C19H36O2, cis-octadec-9-enoic acid methyl ester 3-triyl ester
Component (1): C19H36O2, trans-octadec-9-enoic acid methyl ester Component (1): C59H90O4, 2,3-dimethoxy-5-methy
Component (2): CO2, carbon dioxide 1,4-benzoquinone
Component (1): C20H30O2, cis-5,8,11,14,17-eicosapentaenoic acid
Component (2): CO2, carbon dioxide Component (1): C63H98O6, 1,2,3-tri-[(cis,cis,cis,cis)
14-eicosatetraenoyl]-glycerol
Component (1): C20H32O2, all-cis-eicosa-5,8,11,14-tetraenoic acid
Component (1): C69H128O6, 1,2,3-tri-[(cis)-13-doco
Component (1): C20H38O2, cis-octadec-9-enoic acid ethyl ester
Component (1): C75H140O6, 1,2,3-tri-[(cis)-15-tetrac
Component (1): C21H32O2, cis-eicosa-5,8,11,14,17-pentaenoic acid
glycerol
methyl ester
Component (1): Air C3H8O, propan-1-ol

Component (2): C2H4O2, formic acid methyl ester C3H8O, propan-2-ol
C4H4O, furan C4H10O, butan-1-ol
C4H8O, tetrahydrofuran C6H6, benzene
C5H4O2, furfural C6H12, cyclohexane
C5H6O, 2-methyl-furan C6H14, hexane
C5H6OS, furan-2-yl-methanethiol C7H8, toluene
C5H10O, 2-methyl-tetrahydro-furan C7H14, methyl-cyclohexane
C5H10O2, tetrahydrofuran-2-yl-methanol C7H16, heptane
C6H8O, 2,5-dimethyl-furan C8H18, 2,2,4-trimethyl-pentane
C6H12O, 2,5-dimethyl-tetrahydro-furan C8H18, octane
H2O, water C8H18O, octan-1-ol
C10H22, decane
C12F27N, tris-nonafluorobutyl-amin
C12H26, dodecane
CH4O, methanol
C14H30, tetradecane
C4H4N2, succinonitrile
C16H34, hexadecane
C4H10O, butan-1-ol
C16H36Sn, tetrabutyl-stannane
C6H6, benzene
H2O, water
C6H12, cyclohexane
C6H12O, cyclohexanol Component (1): CH4O, methanol
C6H14, hexane Component (2): Air, air
C8H18, octane Component (1): CO, carbon monoxide
C8H18O, octan-1-ol Component (2): CH4O, methanol
C10H22, decane C7H8, toluene
C12F27N, tris-nonafluorobutyl-amine C7H16, heptane
C14H30, tetradecane C12H26, dodecane
C16H36Sn, tetrabutyl-stannane C16H34, hexadecane
H2O, water C28H58, octacosane
N2, nitrogen H2O, water
Component (1): CCl2F2, dichloro-difluoro-methane N2, nitrogen
Component (2): H2O, water Component (1): COS, carbon oxide sulfide
Component (1): CF4, tetrafluoro-methane Component (2): H2O, water
Component (2): CCl4, tetrachloro-methane Component (1): CO2, carbon dioxide
C6H6, benzene Component (2): kerosene
C6H12, cyclohexane CCl4, tetrachloro-methane
C6H14, hexane CH4O, methanol
C7H8, toluene C2H6O, ethanol
C7H14, methyl-cyclohexane C2H6OS, dimethyl sulfoxide
C7H16, heptane C3H6O, propan-2-one
C8H18, octane C3H8O, propan-1-ol
C8H18, 2,2,4-trimethyl-pentane C4H8O, butan-2-one
C12F27N, tris-nonafluorobutyl-amine C4H10O, butan-1-ol
Component (1): CHCl2F, dichloro-fluoro-methane C4H10O, 2-methyl-propan-1-ol
Component (2): H2O, water C5H10O, pentan-3-one
C5H12O, pentan-1-ol
Component (1): CH3Br, bromo-methane
C6H5Cl, chlorobenzene
C6H6, benzene
C6H12O, 4-methyl-pentan-2-one
C6H14, hexane
Component (1): CH4, methane C7H8, toluene
Component (2): CCl4, tetrachloro-methane C7H16, heptane
CH4O, methanol C7H16O, heptan-1-ol
C3H6O, propan-2-one
DOI: 10.1007/978-3-540-49718-9_3
# Springer 2007
Index of substances
C8H10, 1,4-dimethyl-benzene Component (1): C3H8, propane

C8H18, 2,2,4-trimethyl-pentane Component (2): C3H8O, propan-2-ol
C8H18O, octan-1-ol C4H8O, tetrahydrofuran
C10H12O2, 4-allyl-2-methoxy-phenol C7H16O, heptan-1-ol
C10H18, decahydro-naphthalene C8H18O, octan-1-ol
C12H26, dodecane H2O, water
C14H30, tetradecane Component (1): C4H8, 2-methyl-propene
C16H34, hexadecane Component (2): C26H42O4, 1,2-benzenedicarboxyli
C28H58, octacosane ester
H2O, water Component (1): C4H8, but-1-ene
Component (1): C2H2, ethyne Component (2): H2O, water
Component (2): H2O, water Component (1): C4H10, butane
Component (1): C2H3Cl, chloro-ethene Component (2): C4H8O, tetrahydrofuran
Component (2): H2O, water H2O, water
Component (1): C2H4, ethene Component (1): C4H11NO2, bis-(2-hydroxy-ethyl)-a
Component (2): CH4O, methanol Component (2): H2O, water
C2H2Cl2, trans-1,2-dichloro-ethene Component (1): C5H12, 2,2-dimethyl-propane
C2H3N, acetonitrile Component (2): C10H22, decane
C3H8O, propan-2-ol C14H30, tetradecane
C4H8O, tetrahydrofuran H2O, water
C6H5NO2, nitrobenzene Component (1): C5H12, pentane
C6H12, cyclohexane Component (2): H2O, water
C6H14, hexane
Component (1): C6H15NO2, bis-(2-hydroxy-propyl)
C7H16, heptane Component (2): H2O, water
C8H18, 2,2,4-trimethyl-pentane
H2O, water
Component (1): C57H104O6, cis-octadec-9-enoic aci
triyl ester
CH4O, methanol
Component (2): C13H28, tridecane
C2H3N, acetonitrile
Component (1): ClH, hydrogen chloride
C6H12, cyclohexane
Component (2): C2H2Cl2, trans-1,2-dichloro-ethene
C7H16, heptane
C2H6O2, ethane-1,2-diol
C8H18, 2,2,4-trimethyl-pentane
C6H5NO2, nitrobenzene
C12F27N, tris-nonafluorobutyl-amine
H2O, water Component (1): Cl2, chlorine
Component (1): C2H7NO, 2-amino-ethanol
H2O, water
Component (1): Cl2CO, phosgene
Component (2): C2H4O2, acetic acid
C2H6O2, ethane-1,2-diol Component (1): D2, deuterium
C3H6O, propan-2-one Component (2): CCl4, tetrachloro-methane
C3H7NO, N,N-dimethyl-formamide C12F27N, tris-nonafluorobutyl-amin
C4H8O2, acetic acid ethyl ester Component (1): F6S, sulfur hexafluoride
C4H10O, butan-1-ol Component (2): CCl4, tetrachloro-methane
C6H5Cl, chlorobenzene Component (1): H2, hydrogen
C7H8, toluene Component (2): CCl4, tetrachloro-methane
C8H18, octane CH4O, methanol
C16H34, hexadecane C2H6O, ethanol
H2O, water C3H6O, propan-2-one
Component (1): C3H6O, propan-2-one C3H8O, propan-1-ol
Component (2): C4H4N2, succinonitrile C4H10O, 2-methyl-propan-1-ol
C5H12O, pentan-1-ol
C6H4Cl2, 1,2-dichloro-benzene C6H5Cl, chlorobenzene

C6H6, benzene C6H5NO2, nitrobenzene
C6H10, cyclohexene C6H6, benzene
C6H12, cyclohexane C6H10O, cyclohexanone
C6H12O, cyclohexanol C6H12O, 4-methyl-pentan-2-one
C6H14, hexane C6H12O, cyclohexanol
C7H16, heptane C6H14O, hexan-1-ol
C8H18, octane C7H7NO2, 2-nitro-toluene
C12F27N, tris-nonafluorobutyl-amine C7H8, toluene
C12H26, dodecane C7H16O, heptan-1-ol
C16H34, hexadecane C8H18, octane
C28H58, octacosane C8H18O, octan-1-ol
H2O, water C12F27N, tris-nonafluorobutyl-amin
Component (1): H2S, hydrogen sulfide H2O, water
Component (2): H2O, water Component (1): N2O, nitrous oxide
Component (1): H3N, ammonia Component (2): C2H6O, ethanol
Component (2): H2O, water C7H8, toluene
Component (1): He, helium H2O, water
Component (2): CCl4, tetrachloro-methane Component (1): Ne, neon
C2H6O, ethanol Component (2): CCl4, tetrachloro-methane
C12F27N, tris-nonafluorobutyl-amine C12F27N, tris-nonafluorobutyl-amin
H2O, water H2O, water
Component (1): I2, iodine Component (1): O2, oxygen
Component (2): CCl4, tetrachloro-methane Component (2): CCl4, tetrachloro-methane
Component (1): Kr, krypton C2H4Cl2, 1,2-dichloro-ethane
Component (2): CCl4, tetrachloro-methane C2H6O, ethanol
CH4O, methanol C3H6O, propan-2-one
C3H6O, propan-2-one C4H8O2, 1,4-dioxane
C3H8O, propan-2-ol C6H6, benzene
C4H10O, butan-1-ol C6H11N2*C2F6NO4S2, 1-ethyl-3-
C6H6, benzene methylimidazolium bis-((trifluor
sulfonyl)-imide
C6H12, cyclohexane
C6H12, cyclohexane
C6H14, hexane
C6H12, hex-1-ene
C8H18, octane
C6H12O2, acetic acid butyl ester
C8H18O, octan-1-ol
C6H14, hexane
C10H22, decane
C7H8, toluene
C14H30, tetradecane
C7H14, methyl-cyclohexane
C16H36Sn, tetrabutyl-stannane
C7H16, heptane
H2O, water
C8H10, 1,3-dimethyl-benzene
Component (1): NO2, nitrogen dioxide
C8H10, ethylbenzene
C8H16, oct-1-ene
C8H18, octane
Component (2): CCl4, tetrachloro-methane C8H18, 2,2,4-trimethyl-pentane
CHCl3, trichloro-methane
C9H20, nonane
C2H2Cl4, 1,1,2,2-tetrachloro-ethane
C10H18, cis-decahydro-naphthalene
C2H6O2, ethane-1,2-diol
C10H18, trans-decahydro-naphthale
C3H6O, propan-2-one
C10H18, decahydro-naphthalene
C3H8O, propan-1-ol
C10H20, dec-1-ene
C4H10O, butan-1-ol
C10H20, butyl-cyclohexane
C5H12O, pentan-1-ol
C10H22, decane
C6H4Cl2, 1,2-dichloro-benzene
C11H24, undecane
C6H5Br, bromobenzene C12H22, bicyclohexyl
DOI: 10.1007/978-3-540-49718-9_3
# Springer 2007
Index of substances
C12H24, dodec-1-ene C3H6O, propan-2-one

C12H26, dodecane C3H7NO, N,N-dimethyl-formamid
C12H28N*C2F6NO4S2, triethyl-hexyl-ammonium C3H8O, propan-2-ol
bis-((trifluoromethyl)- sulfonyl)-imide C4H10O, butan-1-ol
C13H28, tridecane C5H12, pentane
C14H28, tetradec-1-ene C6H6, benzene
C14H30, tetradecane C6H12, cyclohexane
C15H32, pentadecane C6H14, hexane
C16H32, hexadec-1-ene C7H16, heptane
C16H34, hexadecane C8BrF17, 1-bromo-heptadecafluoro
C30H62, 2,6,10,15,19,23-hexamethyl-tetracosane C8H10, 1,4-dimethyl-benzene
H2O, water C8H18, octane
Sb, antimony C8H18O, octan-1-ol
Component (1): O2S, sulfur dioxide C9H20, nonane
Component (2): C7H16, heptane C10H22, decane
H2O, water C11H24, undecane
Component (1): O3, ozone C12H26, dodecane
Component (2): H2O, water C13H28, tridecane
Component (1): T2, tritium C14H30, tetradecane
Component (2): N2, nitrogen C15H32, pentadecane
C16H34, hexadecane
Component (2): CCl4, tetrachloro-methane C16H36Sn, tetrabutyl-stannane
H2O, water
CH4O, methanol
36
# Springer 2007

DOI: 10.1007/978-3-540-49718-9_3
Component (3): C2H6O, ethanol C4H8O2, 1,4-dioxane
Component (1): CCl2F2, dichloro-difluoro-methane
Component (3): C12H22O11, saccharose
Component (1): COS, carbon oxide sulfide
Component (3): C2H6O2, ethane-1,2-diol C5H13NO2, bis-(2-hydroxy-ethyl)-methyl-amine
Component (2):
Index of substances
CH4O, methanol
Component (3): C2H6O, ethanol C6H6, benzene H2O, water
Component (3): CH3NO, formamide
Component (3): C2H6O2, ethane-1,2-diol C4H11NO2, bis-(2-hydroxy-ethyl)-amine C6H15NO3, tris-(2-hydroxy-ethyl)-amine
Landolt-Börnstein
New Series IV/15A
C3H8O3, propane-1,2,3-triol C5H12O2, pentane-1,5-diol
C4H11NO, 2-amino-2-methyl-propan-1-ol C5H13NO2, bis-(2-hydroxy-ethyl)-methyl-amine
Component (4): C4H11NO, 2-amino-2-methyl-propan-1-ol C5H13NO2, bis-(2-hydroxy-ethyl)-methyl-amine C6H15NO3, tris-(2-hydroxy-ethyl)-amine
Component (3): C4H11NO, 2-amino-2-methyl-propan-1-ol
Component (4): C4H11NO2, bis-(2-hydroxy-ethyl)-amine
Component (4): C4H11NO, 2-amino-2-methyl-propan-1-ol C5H13NO2, bis-(2-hydroxy-ethyl)-methyl-amine
Component (3): C5H13NO2, bis-(2-hydroxy-ethyl)-methyl-amine
Component (4): C2H7NO, 2-amino-ethanol C4H11NO2, bis-(2-hydroxy-ethyl)-amine
Index of substances

Component (3): C12H26, dodecane
DOI: 10
# Sprin
38
Component (1):
C8H7N, indole
Component (2):
CO2, carbon dioxide
Component (3):
C6H14, hexane
# Springer 2007
Component (1):
C11H8O2, 2-methyl-1,4-naphthoquinone
Component (2):
CO2, carbon dioxide
Component (3):
C6H14, hexane
DOI: 10.1007/978-3-540-49718-9_3
Component (1):
C14H10, anthracene
Component (2):
H2O, water
Component (3):
CH4O, methanol
Component (1):
C14H10, anthracene
Component (2):
H2O, water
Component (3):
CH4O, methanol
Component (4):
CO2, carbon dioxide
Component (1):
C19H34O2, cis,cis-octadeca-9,12-dienoic acid methyl ester
Component (2):
CO2, carbon dioxide
Component (3):
C6H14, hexane
Component (1):
Cl2, chlorine
Component (2):
H2O, water
Component (3):
H2O2, hydrogen peroxide
Component (1):
H2, hydrogen
Component (2):
H2O, water
Component (3):
C2H6O, ethanol
Component (1):
N2, nitrogen
Component (2):
H2O, water
Index of substances
Component (3):
CH4O, methanol C2H6O, ethanol
Component (1):
N2O, nitrous oxide
Component (2):
C2H6O, ethanol
Component (3):
C4H11NO2, bis-(2-hydroxy-ethyl)-amine
Component (1):
N2O, nitrous oxide
Component (2):
H2O, water
Component (3):
C2H6KNO3S, 2-amino-ethanesulfonic acid potassium salt C3H9NO, 1-amino-propan-2-ol C5H13NO2, bis-(2-hydroxy-ethyl)-methyl-amine
C2H6O2, ethane-1,2-diol C4H11NO, 2-amino-2-methyl-propan-1-ol C6H15NO2, bis-(2-hydroxy-propyl)-amine
C2H7NO, 2-amino-ethanol C4H11NO, 2-dimethylamino-ethanol C6H15NO3, tris-(2-hydroxy-ethyl)-amine
C2H8N2, ethane-1,2-diamine C4H11NO2, bis-(2-hydroxy-ethyl)-amine
C3H8O3, propane-1,2,3-triol C5H12O2, pentane-1,5-diol
Landolt-Börnstein
New Series IV/15A
Component (4): C4H11NO, 2-amino-2-methyl-propan-1-ol C5H13NO2, bis-(2-hydroxy-ethyl)-methyl-amine
Component (3): C5H13NO2, bis-(2-hydroxy-ethyl)-methyl-amine
Component (4): C2H7NO, 2-amino-ethanol C4H11NO2, bis-(2-hydroxy-ethyl)-amine
Component (2): C7H8, toluene
Component (3): CH4O, methanol C3H8O, propan-1-ol C12H22O11, saccharose
C2H6O, ethanol C3H8O, propan-2-ol H2O2, hydrogen peroxide
Index of substances
DOI: 10
# Sprin
40
Diffusion of Gas in Electrolyte Solution
Component (1): Air
# Springer 2007
Component (3): ClNa, sodium chloride
DOI: 10.1007/978-3-540-49718-9_3
Component (3): BrNa, sodium bromide ClNa, sodium chloride INa, sodium iodide
CaCl2, calcium chloride Cl2Mg, magnesium chloride MgO4S, magnesium sulphate
ClK, potassium chloride Cl3La, lanthanum chloride
Component (1): CNa2O3, sodium carbonate
Component (3): BrK, potassium bromide HKO, potassium hydroxide KNO3, potassium nitrate
ClH, hydrogen chloride HNaO, sodium hydroxide MgN2O6, magnesium nitrate
ClH4N, ammonium chloride H2O4S, sulfuric acid MgO4S, magnesium sulphate
ClK, potassium chloride H4IN, ammonium iodide NNaO3, sodium nitrate
ClNa, sodium chloride H4N2O3, ammonium nitrate Na2O4S, sodium sulphate
Cl2Mg, magnesium chloride IK, potassium iodide
Component (3): ClNa, sodium chloride
Index of substances
Component (4): Cl2Mg, magnesium chloride Na2O4S, sodium sulphate

Component (3): Cl2Mg, magnesium chloride
Component (4): Na2O4S, sodium sulphate
Component (3): NNaO3, sodium nitrate
Component (4): Na2O4S, sodium sulphate
Component (1): Cl2, chlorine
Component (1): Cl2CO, phosgene
Component (3): ClK, potassium chloride HKO, potassium hydroxide MgO4S, magnesium sulphate
Landolt-Börnstein
New Series IV/15A
Cl2Mg, magnesium chloride KNO3, potassium nitrate
Component (1): H2S, hydrogen sulfide
Component (3): ClK, potassium chloride Cl2Mg, magnesium chloride Na2O4S, sodium sulphate
ClNa, sodium chloride IK, potassium iodide
Component (3): ClK, potassium chloride
Component (3): CK2O3, potassium carbonate
Component (4): CHKO3, potassium hydrogen carbonate
Component (2): C2H6OS, dimethyl sulfoxide
Component (3): ClC8H20NO4, tetraethyl ammonium perchlorate
Component (3): C8H9NaO3S, 2,5-dimethylbenzenesulfonic acid sodium salt ClNa, sodium chloride KNO3, potassium nitrate
C10H21NaO3S, 1-decanesulfonic acid sodium salt ClNaO4, sodium perchlorate K3PO4, potassium phosphate
C18H29NaO3S, dodecylbenzenesulfonic acid sodium salt Cl2Mg, magnesium chloride MgO4S, magnesium sulphate
ClK, potassium chloride HKO, potassium hydroxide Na2O4S, sodium sulphate
Index of substances
ClLi, lithium chloride HNaO, sodium hydroxide Na3O4P, tri-sodium orthophosphate

Component (3): ClCu, copper(I) chloride
Component (3): CoN2O6, cobalt(II) nitrate
Component (4): N2O6Sr, strontium nitrate
Component (3): ClNaO4, sodium perchlorate H5NO3S, ammonium hydrogen sulphite
DOI: 10
# Sprin
Diffusion of argon 1
Diffusion of argon
Data extract from of Landolt-Börnstein IV/15A, Chapter 3: Diffusion in Pure Gases
Ar argon 7440-37-1
Self Diffusion Coefficient D1s(T ); Method: INS Ref.: 1984K4
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0058
100.0 101.325 0.0221
150.0 101.325 0.0489
200.0 101.325 0.0856
250.0 101.325 0.1308
300.0 101.325 0.1839
273.15 101.325 0.1545
293.15 101.325 0.1762
313.15 101.325 0.1991
333.15 101.325 0.2231
353.15 101.325 0.2483
373.15 101.325 0.2745
423.15 101.325 0.3444
473.15 101.325 0.4204
523.15 101.325 0.5022
573.15 101.325 0.5895
623.15 101.325 0.6820
673.15 101.325 0.7796
723.15 101.325 0.8821
773.15 101.325 0.9892
873.15 101.325 1.2172
973.15 101.325 1.4626
1073.15 101.325 1.7250
1173.15 101.325 2.0037
1273.15 101.325 2.2985
1773.15 101.325 4.0042
2273.15 101.325 6.0781
2773.15 101.325 8.4984
3273.15 101.325 11.2483
Comment: extended data set from a correlation, accuracy: ±0.7%
Ar argon 7440-37-1
Self Diffusion Coefficient D1s(T ); Method: DB Ref.: 2003A2
T [K] p [kPa] D · 104 [m2/s]
290.0 ± 0.5 101.325 0.18
340.2 ± 0.5 101.325 0.24
390.4 ± 0.5 101.325 0.28
450.6 ± 0.5 101.325 0.36
502.1 ± 0.5 101.325 0.42
560.0 ± 0.5 101.325 0.48
600.2 ± 0.5 101.325 0.54
(continued)

2 Diffusion of argon
650.4 ± 0.5 101.325 0.60

700.2 ± 0.5 101.325 0.66
750.3 ± 0.5 101.325 0.72
802.4 ± 0.5 101.325 0.80
860.4 ± 0.5 101.325 0.92
903.0 ± 0.5 101.325 0.96
954.0 ± 0.5 101.325 1.06
1002.6 ± 0.5 101.325 1.12
Ar argon 7440-37-1
Self Diffusion Coefficient D1s(T ); Method: DB Ref.: 1970Z2
T [K] p [kPa] D · 109 [m2/s]
85.7 ± 0.6 101.325 1.6 ± 0.2
103.5 ± 0.8 101.325 2.8 ± 0.2
115.9 ± 0.6 101.325 5.0 ± 0.1
Ar argon 7440-37-1
Self Diffusion Coefficient D1s(T ); Method: OEC Ref.: 1962N1
T [K] p [atm] D · 109 [m2/s]
90 ± 0.03 1.32 2.43 ± 5%
100 ± 0.03 3.21 3.54 ± 5%
110 ± 0.03 6.59 4.80 ± 5%
120 ± 0.03 11.98 6.06 ± 5%
130 ± 0.03 19.99 7.45 ± 5%
140 ± 0.03 31.3 8.72 ± 5%
150 ± 0.03 46.8 9.98 ± 5%
Ar argon 7440-37-1
Self Diffusion Coefficient D1s(T ); Method: TB Ref.: 1967D3
T [K] p [kPa] D · 106 [m2/s]
77.5 ± 0.01 101.325 1.31 ± 1%
77.6 ± 0.01 101.325 1.31 ± 1%
77.9 ± 0.01 101.325 1.29 ± 1%
78.0 ± 0.01 101.325 1.30 ± 1%
82.1 ± 0.01 101.325 1.54 ± 1%
85.1 ± 0.01 101.325 1.71 ± 1%
85.1 ± 0.01 101.325 1.65 ± 1%
86.6 ± 0.01 101.325 1.74 ± 1%
90.0 ± 0.01 101.325 1.81 ± 1%
91.5 ± 0.01 101.325 1.83 ± 1%
91.8 ± 0.01 101.325 1.83 ± 1%
94.6 ± 0.01 101.325 1.96 ± 1%
94.7 ± 0.01 101.325 1.97 ± 1%
100.7 ± 0.01 101.325 2.31 ± 1%
101.0 ± 0.01 101.325 2.17 ± 1%
111.0 ± 0.01 101.325 2.57 ± 1%
(continued)
112.0 ± 0.01 101.325 2.85 ± 1%

120.7 ± 0.01 101.325 3.13 ± 1%
294.0 ± 0.01 101.325 17.9 ± 1%
294.0 ± 0.01 101.325 17.9 ± 1%
294.0 ± 0.01 101.325 17.7 ± 1%
294.0 ± 0.01 101.325 17.6 ± 1%
294.0 ± 0.01 101.325 17.6 ± 1%
Ar argon 7440-37-1
Self Diffusion Coefficient D1s(T ); Method: TB Ref.: 1967D3
T [K] p [Torr] D · 106 [m2/s]
77.5 ± 0.01 126.0 7.90 ± 1%
77.6 ± 0.01 123.0 8.08 ± 1%
77.9 ± 0.01 167.0 5.87 ± 1%
78.0 ± 0.01 160.0 6.19 ± 1%
82.1 ± 0.01 86.5 13.5 ± 1%
85.1 ± 0.01 116.0 11.2 ± 1%
85.1 ± 0.01 88.5 14.2 ± 1%
86.6 ± 0.01 94.0 14.1 ± 1%
90.0 ± 0.01 431.0 3.20 ± 1%
91.5 ± 0.01 391.0 3.56 ± 1%
91.8 ± 0.01 287.0 4.84 ± 1%
94.6 ± 0.01 442.0 3.37 ± 1%
94.7 ± 0.01 491.0 3.05 ± 1%
100.7 ± 0.01 490.0 3.58 ± 1%
101.0 ± 0.01 536.0 3.08 ± 1%
111.0 ± 0.01 288.0 6.78 ± 1%
112.0 ± 0.01 125.0 17.3 ± 1%
120.7 ± 0.01 522.0 4.56 ± 1%
294.0 ± 0.01 404.0 33.7 ± 1%
294.0 ± 0.01 560.0 24.2 ± 1%
294.0 ± 0.01 497.0 27.1 ± 1%
294.0 ± 0.01 287.0 46.6 ± 1%
294.0 ± 0.01 467.0 26.6 ± 1%
Ar argon 7440-37-1
Self Diffusion Coefficient D1s(T ); Method: TB Ref.: 1969V2
T [K] p [kPa] D
234.68 ± 0.02 101.325 1.5564 ± 0.1%
246.08 ± 0.02 101.325 1.4252 ± 0.1%
333.30 ± 0.02 101.325 0.8166 ± 0.1%
346.15 ± 0.02 101.325 0.7611 ± 0.1%
358.10 ± 0.02 101.325 0.7175 ± 0.1%
372.29 ± 0.02 101.325 0.6697 ± 0.1%
382.80 ± 0.02 101.325 0.6362 ± 0.1%
393.40 ± 0.02 101.325 0.6060 ± 0.1%
(continued)

4 Diffusion of argon
404.19 ± 0.02 101.325 0.5764 ± 0.1%

417.59 ± 0.02 101.325 0.5443 ± 0.1%
Comment: relative diffusion coefficients D = [D1s (298.15 K)/D1s (T )]
Ar argon 7440-37-1
Self Diffusion Coefficient D1s(T ); Method: OEC Ref.: 1960C3
T [K] p [kPa] D · 109 [m2/s]
84.56 101.325 1.53 ± 0.03
Ar argon 7440-37-1
Self Diffusion Coefficient D1s(T ); Method: INT Ref.: 1995K8
T [K] p [kPa] D · 104 [m2/s]
295.0 101.325 0.40 ± 0.03
Ar argon 7440-37-1
Self Diffusion Coefficient D1s(T ); Method: No Info Ref.: 1967R1
T [K] p [kPa] D · 104 [m2/s]
280.0 101.325 0.1640
Ar argon 7440-37-1
Self Diffusion Coefficient D1s(T ); Method: CT Ref.: 1972H7
Equation: D = A exp[ –B / (RT)] Range: 19 < T/K < 23
Parameter: A [cm2/s] B [cal/mol]
0.20 ± 0.15 3600.0 ± 150.0
Comment: D1s [m2/s] = D 10–4; solid phase
Ar argon 7440-37-1
Equation: D = A exp[ B/T ] Range: 90 < T/K < 150
Parameter: p [atm] A · 107 B
57.5 1.12 362
103.0 0.94 367
135.0 0.89 373
12.9 1.16 352
Ar argon 7440-37-1
Self Diffusion Coefficient D1s(T ); Method: Non-stand Ref.: 1968P2
Equation: D = A · exp[ –B / (RT)] Range: 66 < T/K < 83
0.2 ± 0.14 3600 ± 150
Comment: measurements of solid argon; D1s [m2/s] = D · 10–4

References
1984K4 Kestin, J., Knierim, K., Mason, E. A., Najafi, B., Ro, S.T., Waldman, M.: J. Phys. Chem. Ref.
Data 13 (1984) 229–303.
2003A2 Al'zhanov, K.Z., Musenov, K.K.: Bayandamalary Kazak. Resp. Ulttyk Gylym Akadem. (2003)
32–38.
1970Z2 Zandveld, P., Andriesse, C.D., Bregman, J.D., Hasman, A., Van Loef, J.J.: Physica 50 (1970)
511–523.
1962N1 Naghizadeh, J., Rice, S.A.: J. Chem. Phys. 36 (1962) 2710–2720.
1967D3 De Paz, M., Turi, B., Klein, M.L.: Physica 36 (1967) 127–135.
1969V2 Vugts, H.F., Boerboom, A.J.H., Los, J.: Physica 44 (1969) 219–226.
1960C3 Cini‐Castagnoli, G., Ricci, F.P.: J. Chem. Phys. 32 (1960) 19–20.
1995K8 Kosov, N.D., Poyarkov, I.V.: Meas. Tech. (English Transl.) 38 (1995) 1394–1396.
1967R1 Raman, S., Paul, R., Watson, W.W.: J. Chem. Phys. 46 (1967) 3916–3920.
1972H7 Henry, R., Norberg, R.E.: Phys. Rev. B 6 (1972) 1645–1653.
1968P2 Parker, E.H.C., Glyde, H.R., Smith, B.L.: Phys. Rev. 176 (1968) 1107–1110.

Diffusion of trifluoro-chloro-methane 1
Diffusion of trifluoro-chloro-methane
CClF3 trifluoro-chloro-methane 75-72-9

Self Diffusion Coefficient D1s(T ); Method: NMR FG Ref.: 1978H3
T [K] p [MPa] D · 109 [m2/s]
303.15 ± 0.02 3.68 60.2
303.15 ± 0.02 3.69 59.6
303.15 ± 0.02 3.95 40.2
303.15 ± 0.02 3.99 33.6
303.15 ± 0.02 3.97 34.3
302.65 ± 0.02 3.97 33.9
303.15 ± 0.02 3.98 31.7
303.15 ± 0.02 3.98 30.0
303.15 ± 0.02 4.00 27.7
303.15 ± 0.02 3.99 25.5
302.65 ± 0.02 3.95 24.6
303.15 ± 0.02 4.01 22.7
303.15 ± 0.02 4.02 22.3
303.15 ± 0.02 4.35 17.5
303.15 ± 0.02 5.48 14.5
303.15 ± 0.02 5.49 14.7
303.15 ± 0.02 5.51 14.9
303.15 ± 0.02 5.58 14.4
303.15 ± 0.02 5.61 14.4
303.15 ± 0.02 8.45 12.3
303.15 ± 0.02 8.60 12.0
303.15 ± 0.02 15.47 9.98
303.15 ± 0.02 19.76 9.27
303.15 ± 0.02 31.10 7.58
303.15 ± 0.02 31.43 7.44
303.15 ± 0.02 39.44 7.06
303.15 ± 0.02 69.73 5.30
303.15 ± 0.02 76.60 5.08
303.15 ± 0.02 125.61 3.90
303.15 ± 0.02 140.41 3.60
303.15 ± 0.02 173.50 3.20
323.15 ± 0.02 5.11 45.3
323.15 ± 0.02 5.13 43.8
323.15 ± 0.02 5.56 34.8
323.15 ± 0.02 5.96 28.4
323.15 ± 0.02 6.20 25.8
323.15 ± 0.02 6.58 23.4
323.15 ± 0.02 6.61 23.1
323.15 ± 0.02 7.74 18.8
323.15 ± 0.02 7.76 18.9
323.15 ± 0.02 10.09 15.9
323.15 ± 0.02 14.85 12.8
(continued)
2 Diffusion of trifluoro-chloro-methane
323.15 ± 0.02 14.85 13.1

323.15 ± 0.02 22.31 10.7
323.15 ± 0.02 24.06 10.5
323.15 ± 0.02 40.93 8.14
323.15 ± 0.02 70.35 5.98
323.15 ± 0.02 119.00 4.74
323.15 ± 0.02 119.60 4.58
323.15 ± 0.02 150.52 4.00
323.15 ± 0.02 151.46 4.01
323.15 ± 0.02 188.38 3.55
348.15 ± 0.02 6.50 48.7
348.15 ± 0.02 7.53 36.9
348.15 ± 0.02 8.04 33.3
348.15 ± 0.02 8.56 30.6
348.15 ± 0.02 10.00 24.6
348.15 ± 0.02 12.24 20.3
348.15 ± 0.02 16.02 16.6
348.15 ± 0.02 22.60 13.7
348.15 ± 0.02 30.85 11.5
348.15 ± 0.02 34.05 11.2
348.15 ± 0.02 53.61 8.87
348.15 ± 0.02 83.74 7.07
Comment: accuracy: ±(1–2)%; ΔP = ±0.01 MPa
Reference
1978H3 Harris, K.R.: Physica A 93 (1978) 593–610.

Diffusion of tetrafluoro-methane 1
Diffusion of tetrafluoro-methane
CF4 tetrafluoro-methane 75-73-0

Self Diffusion Coefficient D1s(T ); Method: CORR Ref.: 1987B2
T [K] p [kPa] D · 104 [m2/s]
200.0 101.325 0.0316
250.0 101.325 0.0481
300.0 101.325 0.0675
273.15 101.325 0.0568
293.15 101.325 0.0647
313.15 101.325 0.0729
333.15 101.325 0.0815
353.15 101.325 0.0905
373.15 101.325 0.0998
423.15 101.325 0.1248
473.15 101.325 0.1517
523.15 101.325 0.1806
573.15 101.325 0.2114
623.15 101.325 0.2439
673.15 101.325 0.2782
723.15 101.325 0.3143
773.15 101.325 0.3521
873.15 101.325 0.4324
973.15 101.325 0.5190
1073.15 101.325 0.6117
1173.15 101.325 0.7104
1273.15 101.325 0.8147
1773.15 101.325 1.4190
2273.15 101.325 2.1557
2773.15 101.325 3.0091
3273.15 101.325 3.9626
Comment: data review; present data are corrected for errors reported in erratum
CF4 tetrafluoro-methane 75-73-0

Self Diffusion Coefficient D1s(T ); Method: NMR FG Ref.: 1963R2
T [K] p [kPa] D · 1010 [m2/s]
88 ± 0.25 101.325 3.02
90.5 ± 0.25 101.325 3.39
93 ± 0.25 101.325 3.33
95.5 ± 0.25 101.325 4.50
98 ± 0.25 101.325 4.84
103 ± 0.25 101.325 6.23
108 ± 0.25 101.325 7.59
113 ± 0.25 101.325 9.20
118 ± 0.25 101.325 11.2
123 ± 0.25 101.325 12.8
(continued)

2 Diffusion of tetrafluoro-methane
128 ± 0.25 101.325 15.9

133 ± 0.25 101.325 17.9
138 ± 0.25 101.325 21.1
143 ± 0.25 101.325 24.0
Comment: overall uncertainty: ±8.1%
References
445–466.
1963R2 Rugheimer, J.R., Hubbard, P.S.: J. Chem. Phys. 39 (1963) 552–564.

Diffusion of dibromo-methane 1
Diffusion of dibromo-methane
CH2Br2 dibromo-methane 74-95-3

Self Diffusion Coefficient D1s(T ); Method: NMR PG Ref.: 1988K1
Parameter: A · 107 B · 10–3 Std-Dev
1.399 11.33 10.0%
Comment: low accuracy
Reference
1988K1 Kempka, M., Peplinska, B., Pajak, Z.: Ber. Bunsenges. Phys. Chem. 92 (1988) 686–689.

Diffusion of methane 1
Diffusion of methane
CH4 methane 74-82-8

T [K] p [kPa] D · 104 [m2/s]
200.0 101.325 0.1104 ± 2.0%
250.0 101.325 0.1689 ± 2.0%
300.0 101.325 0.2368 ± 2.0%
273.15 101.325 0.1992 ± 2.0%
293.15 101.325 0.2270 ± 2.0%
313.15 101.325 0.2560 ± 2.0%
333.15 101.325 0.2865 ± 2.0%
353.15 101.325 0.3182 ± 2.0%
373.15 101.325 0.3512 ± 2.0%
423.15 101.325 0.4389 ± 2.0%
473.15 101.325 0.5339 ± 2.0%
523.15 101.325 0.6359 ± 2.0%
573.15 101.325 0.7445 ± 2.0%
623.15 101.325 0.8595 ± 2.0%
673.15 101.325 0.9807 ± 2.0%
723.15 101.325 1.1080 ± 2.0%
773.15 101.325 1.2412 ± 2.0%
873.15 101.325 1.5248 ± 2.0%
973.15 101.325 1.8306 ± 2.0%
1073.15 101.325 2.1578 ± 2.0%
1173.15 101.325 2.5058 ± 2.0%
1273.15 101.325 2.8741 ± 2.0%
1773.15 101.325 5.0057 ± 2.0%
2273.15 101.325 7.6126 ± 2.0%
2773.15 101.325 10.677 ± 2.0%
3273.15 101.325 14.163 ± 2.0%
CH4 methane 74-82-8

Self Diffusion Coefficient D1s(T ); Method: CORR Ref.: 1976T1
T [K] p [kPa] D · 104 [m2/s]
198.15 101.325 0.103
223.15 101.325 0.133
248.15 101.325 0.164
273.15 101.325 0.197
298.15 101.325 0.232
323.15 101.325 0.268
348.15 101.325 0.307

2 Diffusion of methane
CH4 methane 74-82-8

Self Diffusion Coefficient D1s(T ); Method: CORR Ref.: 1976T1
T [K] p [bar] D · 107 [m2/s]
198.15 5.0 20.7
223.15 5.0 26.2
248.15 5.0 32.6
273.15 5.0 39.6
298.15 5.0 46.6
323.15 5.0 54.3
348.15 5.0 61.9
198.15 10 9.97
223.15 10 12.8
248.15 10 16.0
273.15 10 19.6
298.15 10 23.1
323.15 10 27.0
348.15 10 30.9
198.15 20 4.74
223.15 20 6.07
248.15 20 7.75
273.15 20 9.51
298.15 20 11.4
323.15 20 13.3
348.15 20 15.3
198.15 30 2.77
223.15 30 3.82
248.15 30 4.98
273.15 30 6.18
298.15 30 7.43
323.15 30 8.77
348.15 30 10.2
198.15 40 1.821
223.15 40 2.71
248.15 40 3.59
273.15 40 4.52
298.15 40 5.48
323.15 40 6.50
348.15 40 7.58
223.15 50 2.03
248.15 50 2.75
273.15 50 3.53
298.15 50 4.31
323.15 50 5.14
348.15 50 6.01
223.15 60 1.55
248.15 60 2.21
273.15 60 2.86
298.15 60 3.53
(continued)

323.15 60 4.23
348.15 60 5.00
223.15 70 1.20
248.15 70 1.81
273.15 70 2.40
298.15 70 2.98
323.15 70 3.59
348.15 70 4.26
223.15 80 0.966
248.15 80 1.53
273.15 80 2.05
298.15 80 2.57
323.15 80 3.11
348.15 80 3.70
223.15 90 0.791
248.15 90 1.30
273.15 90 1.78
298.15 90 2.25
323.15 90 2.74
348.15 90 3.27
248.15 100 1.13
273.15 100 1.57
298.15 100 2.00
323.15 100 2.45
348.15 100 2.93
248.15 110 0.991
273.15 110 1.40
298.15 110 1.80
323.15 110 2.21
348.15 110 2.65
248.15 120 0.890
273.15 120 1.26
298.15 120 1.63
323.15 120 2.01
348.15 120 2.42
248.15 130 0.810
273.15 130 1.15
298.15 130 1.49
323.15 130 1.85
348.15 130 2.23
273.15 140 1.06
298.15 140 1.38
323.15 140 1.71
348.15 140 2.07
273.15 150 0.983
298.15 150 1.28
323.15 150 1.59
348.15 150 1.93
(continued)

273.15 160 0.920

298.15 160 1.20
323.15 160 1.49
348.15 160 1.81
298.15 170 1.13
323.15 170 1.41
348.15 170 1.70
298.15 180 1.07
323.15 180 1.33
348.15 180 1.61
298.15 190 1.02
323.15 190 1.27
348.15 190 1.53
298.15 200 0.969
323.15 200 1.21
348.15 200 1.45
323.15 220 1.11
348.15 220 1.33
323.15 240 1.03
348.15 240 1.23
348.15 260 1.15
CH4 methane 74-82-8

Self Diffusion Coefficient D1s(T ); Method: NMR FG Ref.: 1970D2
T [K] p [lb/sq.in.] D · 108 [m2/s]
353.8 ± 0.2 993 42.56 ± 6%
353.8 ± 0.2 1256 33.15 ± 6%
353.8 ± 0.2 1680 23.86 ± 6%
353.8 ± 0.2 2138 18.91 ± 6%
353.8 ± 0.2 2640 15.37 ± 6%
353.8 ± 0.2 3498 11.67 ± 6%
353.8 ± 0.2 4699 8.76 ± 6%
353.8 ± 0.2 6025 7.215 ± 6%
322.5 ± 0.2 709 50.06 ± 6%
322.5 ± 0.2 945 36.65 ± 6%
322.5 ± 0.2 1185 28.78 ± 6%
322.5 ± 0.2 1489 22.83 ± 6%
322.5 ± 0.2 1851 18.05 ± 6%
322.5 ± 0.2 2264 14.49 ± 6%
322.5 ± 0.2 2975 10.96 ± 6%
297.0 ± 0.2 771 38.39 ± 6%
297.0 ± 0.2 982 29.53 ± 6%
297.0 ± 0.2 1386 20.53 ± 6%
297.0 ± 0.2 1846 14.75 ± 6%
297.0 ± 0.2 2370 11.24 ± 6%
297.0 ± 0.2 3020 8.81 ± 6%
297.0 ± 0.2 4161 6.58 ± 6%
(continued)
297.0 ± 0.2 5996 5.02 ± 6%

256.7 ± 0.2 322 69.41 ± 6%
256.7 ± 0.2 451 50.37 ± 6%
256.7 ± 0.2 598 36.35 ± 6%
256.7 ± 0.2 731 29.41 ± 6%
256.7 ± 0.2 928 22.28 ± 6%
256.7 ± 0.2 1115 17.83 ± 6%
256.7 ± 0.2 1447 12.64 ± 6%
256.7 ± 0.2 1816 9.51 ± 6%
256.7 ± 0.2 2270 7.32 ± 6%
256.7 ± 0.2 3100 5.45 ± 6%
256.7 ± 0.2 4350 4.19 ± 6%
256.7 ± 0.2 5935 3.61 ± 6%
221.9 ± 0.2 279 62.72 ± 6%
221.9 ± 0.2 384 42.96 ± 6%
221.9 ± 0.2 511 31.32 ± 6%
221.9 ± 0.2 646 23.38 ± 6%
221.9 ± 0.2 803 17.16 ± 6%
221.9 ± 0.2 941 13.62 ± 6%
221.9 ± 0.2 1108 10.34 ± 6%
221.9 ± 0.2 1304 7.44 ± 6%
221.9 ± 0.2 1720 5.24 ± 6%
221.9 ± 0.2 2407 4.02 ± 6%
221.9 ± 0.2 3398 3.36 ± 6%
221.9 ± 0.2 4557 2.89 ± 6%
197.7 ± 0.2 112 131.58 ± 6%
197.7 ± 0.2 198 71.01 ± 6%
197.7 ± 0.2 303 42.68 ± 6%
197.7 ± 0.2 419 28.72 ± 6%
197.7 ± 0.2 555 19.22 ± 6%
197.7 ± 0.2 644 14.76 ± 6%
197.7 ± 0.2 1101 3.99 ± 6%
197.7 ± 0.2 1991 2.98 ± 6%
190.9 ± 0.2 230 55.97 ± 6%
190.9 ± 0.2 280 42.54 ± 6%
190.9 ± 0.2 335 34.02 ± 6%
190.9 ± 0.2 390 27.95 ± 6%
190.9 ± 0.2 455 23.02 ± 6%
190.9 ± 0.2 532 18.23 ± 6%
190.9 ± 0.2 595 14.17 ± 6%
190.9 ± 0.2 625 12.54 ± 6%
190.9 ± 0.2 857 3.49 ± 6%
190.9 ± 0.2 3950 2.05 ± 6%
187.1 ± 0.2 251 46.88 ± 6%
187.1 ± 0.2 349 30.86 ± 6%
187.1 ± 0.2 448 22.47 ± 6%
187.1 ± 0.2 536 15.82 ± 6%
187.1 ± 0.2 1380 2.73 ± 6%
(continued)

187.1 ± 0.2 4530 1.83 ± 6%

173.4 ± 0.2 199 48.75 ± 6%
173.4 ± 0.2 241 38.19 ± 6%
173.4 ± 0.2 299 29.13 ± 6%
173.4 ± 0.2 341 24.08 ± 6%
173.4 ± 0.2 368 21.23 ± 6%
173.4 ± 0.2 407 2.51 ± 6%
173.4 ± 0.2 1464 1.96 ± 6%
173.4 ± 0.2 3958 1.56 ± 6%
154.5 ± 0.2 141 57.61 ± 6%
154.5 ± 0.2 175 42.72 ± 6%
154.5 ± 0.2 216 1.65 ± 6%
154.5 ± 0.2 3460 1.19 ± 6%
CH4 methane 74-82-8

Self Diffusion Coefficient D1s(T ); Method: NMR FG Ref.: 1969W3
T [K] p [bar] D · 107 [m2/s]
298.15 ± 0.17 67.71 2.77 ± 1%
298.15 ± 0.17 95.56 1.91 ± 1%
298.15 ± 0.17 121.69 1.44 ± 1%
298.15 ± 0.17 127.28 1.43 ± 1%
298.15 ± 0.17 138.93 1.24 ± 1%
298.15 ± 0.17 156.17 1.09 ± 1%
298.15 ± 0.17 163.40 1.01 ± 1%
298.15 ± 0.17 173.40 0.977 ± 1%
330.93 ± 0.17 121.69 1.91 ± 1%
330.93 ± 0.17 138.93 1.65 ± 1%
330.93 ± 0.17 156.17 1.44 ± 1%
330.93 ± 0.17 173.40 1.32 ± 1%
353.71 ± 0.17 68.46 4.04 ± 1%
353.71 ± 0.17 115.83 2.295 ± 1%
353.71 ± 0.17 147.41 1.84 ± 1%
364.26 ± 0.17 121.69 2.43 ± 1%
364.26 ± 0.17 138.93 2.09 ± 1%
364.26 ± 0.17 156.17 1.85 ± 1%
364.26 ± 0.17 173.40 1.64 ± 1%
CH4 methane 74-82-8

Self Diffusion Coefficient D1s(T ); Method: NMR FG Ref.: 1971O2
T [K] ρA [amagat] D · 107 [m2/s]
170.21 ± 0.01 49 2.45
173.91 ± 0.01 49 2.46
181.82 ± 0.01 49 2.60
190.48 ± 0.01 49 2.80
200.00 ± 0.01 49 2.88
210.53 ± 0.01 49 3.06
222.22 ± 0.01 49 3.28
(continued)
235.29 ± 0.01 49 3.45

250.00 ± 0.01 49 3.67
266.67 ± 0.01 49 3.77
285.71 ± 0.01 49 4.11
299.20 ± 0.01 49 4.34
307.69 ± 0.01 49 4.39
181.82 ± 0.01 75 1.72
190.48 ± 0.01 75 1.84
200.00 ± 0.01 75 1.91
210.53 ± 0.01 75 2.03
222.22 ± 0.01 75 2.11
235.29 ± 0.01 75 2.29
250.00 ± 0.01 75 2.39
266.67 ± 0.01 75 2.58
285.71 ± 0.01 75 2.62
299.20 ± 0.01 75 2.75
307.69 ± 0.01 75 2.90
186.05 ± 0.01 108 1.25
190.48 ± 0.01 108 1.29
200.00 ± 0.01 108 1.36
210.53 ± 0.01 108 1.40
222.22 ± 0.01 108 1.47
235.29 ± 0.01 108 1.52
250.00 ± 0.01 108 1.65
266.67 ± 0.01 108 1.73
285.71 ± 0.01 108 1.87
299.20 ± 0.01 108 1.96
307.69 ± 0.01 108 1.96
190.48 ± 0.01 126 1.12
200.00 ± 0.01 126 1.18
210.53 ± 0.01 126 1.23
222.22 ± 0.01 126 1.29
235.29 ± 0.01 126 1.35
250.00 ± 0.01 126 1.44
266.67 ± 0.01 126 1.51
285.71 ± 0.01 126 1.62
299.20 ± 0.01 126 1.69
307.69 ± 0.01 126 1.72
195.12 ± 0.01 235 0.61
200.00 ± 0.01 235 0.62
210.53 ± 0.01 235 0.63
222.22 ± 0.01 235 0.67
235.29 ± 0.01 235 0.70
250.00 ± 0.01 235 0.73
266.67 ± 0.01 235 0.76
285.71 ± 0.01 235 0.79
299.20 ± 0.01 235 0.84
307.69 ± 0.01 235 0.87

CH4 methane 74-82-8

194.75 ± 0.05 110 0.146
194.75 ± 0.05 124 0.144
194.75 ± 0.05 242 0.136
194.75 ± 0.05 282 0.135
194.75 ± 0.05 322 0.127
194.75 ± 0.05 338 0.127
194.75 ± 0.05 356 0.121
194.75 ± 0.05 387 0.115
194.75 ± 0.05 424 0.108
194.75 ± 0.05 447 0.103
194.75 ± 0.05 480 0.103
194.75 ± 0.05 501 0.090
273.15 ± 0.05 50 0.202
273.15 ± 0.05 75 0.198
273.15 ± 0.05 100 0.200
273.15 ± 0.05 125 0.200
273.15 ± 0.05 150 0.196
273.15 ± 0.05 175 0.192
273.15 ± 0.05 200 0.193
273.15 ± 0.05 225 0.191
273.15 ± 0.05 250 0.186
273.15 ± 0.05 275 0.179
273.15 ± 0.05 300 0.175
273.15 ± 0.05 325 0.171
273.15 ± 0.05 350 0.163
273.15 ± 0.05 375 0.155
273.15 ± 0.05 400 0.152
273.15 ± 0.05 425 0.145
273.15 ± 0.05 450 0.140
273.15 ± 0.05 475 0.135
273.15 ± 0.05 500 0.122
273.15 ± 0.05 525 0.114
273.15 ± 0.05 550 0.103
273.15 ± 0.05 575 0.095
298.15 ± 0.02 137 0.207
298.15 ± 0.02 167 0.201
298.15 ± 0.02 194 0.199
298.15 ± 0.02 220 0.201
298.15 ± 0.02 263 0.196
298.15 ± 0.02 300 0.191
298.15 ± 0.02 324 0.183
298.15 ± 0.02 347 0.181
298.15 ± 0.02 382 0.171
298.15 ± 0.02 431 0.155
298.15 ± 0.02 465 0.147
(continued)

298.15 ± 0.02 501 0.133

298.15 ± 0.02 520 0.124
298.15 ± 0.02 549 0.116
CH4 methane 74-82-8

90.92 ± 0.01 631 2.52
95.94 ± 0.01 623 3.01
100.00 ± 0.01 614 3.61
105.26 ± 0.01 604 4.35
111.11 ± 0.01 593 5.23
117.65 ± 0.01 579 6.34
125.00 ± 0.01 562 7.76
133.33 ± 0.01 545 9.56
142.86 ± 0.01 522 11.8
153.85 ± 0.01 492 15.3
166.67 ± 0.01 450 21.2
173.91 ± 0.01 420 24.9
181.82 ± 0.01 379 30.3
186.05 ± 0.01 350 35.8
190.48 ± 0.01 350 58.5
Comment: liquid phase of methane
CH4 methane 74-82-8

137.93 ± 0.01 13.2 7.76
142.86 ± 0.01 16.8 6.15
148.15 ± 0.01 21.3 4.99
153.85 ± 0.01 27.6 3.95
160.00 ± 0.01 35.8 3.06
166.67 ± 0.01 47.0 2.46
170.21 ± 0.01 55 2.18
173.91 ± 0.01 65 1.87
177.78 ± 0.01 77 1.71
181.82 ± 0.01 95 1.45
186.05 ± 0.01 120 1.15
190.48 ± 0.01 120 0.67
Comment: vapor phase of methane
CH4 methane 74-82-8

T [K] p [MPa] D · 109 [m2/s]
223.15 ± 0.02 3.15 340
223.15 ± 0.02 4.34 227
(continued)
223.15 ± 0.02 5.35 171

223.15 ± 0.02 6.20 140
223.15 ± 0.02 7.89 92.0
223.15 ± 0.02 9.36 69.4
223.15 ± 0.02 10.03 62.3
223.15 ± 0.02 11.30 53.7
223.15 ± 0.02 13.08 46.3
223.15 ± 0.02 14.72 41.8
223.15 ± 0.02 16.92 37.8
223.15 ± 0.02 21.68 32.8
223.15 ± 0.02 35.85 26.0
223.15 ± 0.02 63.29 19.8
223.15 ± 0.02 89.96 16.5
223.15 ± 0.02 143.85 12.9
223.15 ± 0.02 143.90 12.8
223.15 ± 0.02 144.04 12.7
223.15 ± 0.02 173.00 11.4
273.15 ± 0.02 16.81 79.1
273.15 ± 0.02 16.81 78.3
298.15 ± 0.02 4.53 438
298.15 ± 0.02 8.57 217
298.15 ± 0.02 10.49 169
298.15 ± 0.02 12.38 141
298.15 ± 0.02 16.22 105
298.15 ± 0.02 19.69 85.6
298.15 ± 0.02 20.48 82.5
298.15 ± 0.02 20.49 83.0
298.15 ± 0.02 20.54 84.8
298.15 ± 0.02 20.55 84.2
298.15 ± 0.02 20.57 82.6
298.15 ± 0.02 20.60 83.6
298.15 ± 0.02 20.63 81.6
298.15 ± 0.02 25.80 66.9
298.15 ± 0.02 25.81 68.1
298.15 ± 0.02 27.29 66.2
298.15 ± 0.02 32.89 55.5
298.15 ± 0.02 32.92 54.7
298.15 ± 0.02 42.14 46.4
298.15 ± 0.02 56.71 38.9
298.15 ± 0.02 76.73 31.4
298.15 ± 0.02 77.27 31.7
298.15 ± 0.02 77.29 31.3
298.15 ± 0.02 77.32 32.4
298.15 ± 0.02 107.63 26.9
298.15 ± 0.02 140.75 22.9
298.15 ± 0.02 163.68 20.8
323.15 ± 0.02 9.64 227
323.15 ± 0.02 11.84 186
(continued)

323.15 ± 0.02 14.11 154

323.15 ± 0.02 18.79 111
323.15 ± 0.02 24.13 88.3
323.15 ± 0.02 24.14 89.3
323.15 ± 0.02 30.70 71.7
323.15 ± 0.02 39.30 59.6
323.15 ± 0.02 44.76 53.6
323.15 ± 0.02 50.93 49.2
323.15 ± 0.02 66.94 41.2
323.15 ± 0.02 89.79 34.4
323.15 ± 0.02 89.82 34.8
323.15 ± 0.02 89.82 34.4
323.15 ± 0.02 89.83 34.4
323.15 ± 0.02 122.82 28.8
323.15 ± 0.02 159.79 24.6
Comment: accuracy: ±2%; ΔP = ±0.01 MPa
CH4 methane 74-82-8

T [K] p [kPa] D · 109 [m2/s]
91 ± 0.25 101.325 2.23
93 ± 0.25 101.325 2.41
95 ± 0.25 101.325 2.63
97 ± 0.25 101.325 2.77
99 ± 0.25 101.325 3.03
101 ± 0.25 101.325 3.18
103 ± 0.25 101.325 3.48
105 ± 0.25 101.325 3.73
107 ± 0.25 101.325 3.94
109 ± 0.25 101.325 4.04
Comment: overall uncertainty ±8.1%
CH4 methane 74-82-8

T [K] p [MPa] D · 109 [m2/s]
110.00 2.076 5.12
110.00 2.077 5.19
110.00 9.898 4.78
110.00 9.900 4.63
110.00 20.883 4.18
110.00 33.200 3.82
110.00 46.781 3.48
110.00 61.493 2.95
110.00 65.597 2.91
110.00 80.060 2.62
140.00 1.525 11.1
140.00 5.464 10.4
(continued)
140.00 18.047 8.86

140.00 34.838 7.68
140.00 56.313 6.48
140.00 84.840 5.46
140.00 84.843 5.40
140.00 119.968 4.41
140.00 164.410 3.52
140.00 221.58 2.85
160.00 1.649 17.5
160.00 7.188 15.8
160.00 15.387 13.9
160.00 26.820 12.5
160.00 42.089 10.7
160.00 61.851 9.03
160.00 86.857 7.91
160.00 118.061 6.59
160.00 156.763 5.62
160.00 204.770 4.58
223.15 11.30 55.2
223.15 35.85 26.8
223.15 143.90 13.0
298.15 32.89 57.9
298.15 77.30 33.6
298.15 140.85 23.8
Comment: precision: ±2%; ΔP = ±0.001 MPa
CH4 methane 74-82-8

Self Diffusion Coefficient D1s(T ); Method: NMR PG Ref.: 1996H5
T [K] p [MPa] D · 109 [m2/s]
303.3 30 62 ± 5%
303.3 40 49 ± 5%
303.3 50 43 ± 5%
333.1 30 75 ± 5%
333.1 40 60 ± 5%
333.1 50 51 ± 5%
CH4 methane 74-82-8

Self Diffusion Coefficient D1s(T ); Method: TB Ref.: 1964M5
T [K] p [kPa] D · 104 [m2/s]
298.2 ± 0.1 101.325 0.235 ± 0.001
353.6 ± 0.1 101.325 0.315 ± 0.001
382.6 ± 0.1 101.325 0.360 ± 0.001

CH4 methane 74-82-8

T [K] p [kPa] D · 104 [m2/s]
293.15 101.325 0.274 ± 0.004
CH4 methane 74-82-8

Self Diffusion Coefficient D1s(T ); Method: TB Ref.: 1971W5
T [K] p [kPa] D · 104 [m2/s]
293.2 101.325 0.233
298.2 101.325 0.240
303.2 101.325 0.248
CH4 methane 74-82-8

T [K] p [kPa] D · 104 [m2/s]
273.2 101.325 0.197
298.2 101.325 0.232
353.6 101.325 0.319
382.6 101.325 0.366
CH4 methane 74-82-8

Coefficient D1s(T ); Method: CORR
Self Diffusion Ref.: 1976T1
Equation: D = A + B ∙ T + C ∙ T2 + E ∙ T 3 Range: 90.2 < T/K < 382.6
Parameter: A B ∙ 103 C ∙ 105 E ∙ 108 Std-Dev
0.0540 –0.9159 0.7456 –0.7794 1.0%
Comment: D1s [m2/s] = D ∙ 10–4; extended data set from a correlation; accuracy: 1.0%
CH4 methane 74-82-8

Equation: D = A ∙ exp[ B/T ] Range: 91 < T/K < 109
Parameter: A ∙ 109 B
86.2 –332
CH4 methane 74-82-8

Equation: D = A ∙ exp[ B/T ]
Parameter: A ∙ 105 [cm2/s] B
1.5 –1580
–4
Comment: D1s [m /s] = D ∙ 10 ; data near critical point; temperature range 8 K around Tc
2

CH4 methane 74-82-8

Self Diffusion Coefficient D1s(T ); Method: NMR FG Ref.: 1963G1
Parameter: A ∙ 109 B
80.5 –332
CH4 methane 74-82-8

Parameter: p [atm] A ∙ 107 B
8.50 1.95 419
60.9 2.00 431
114.2 2.08 443
References
445–466.
1976T1 Takahashi, S., Iwasaki, H.: Rev. Phys. Chem. Jpn. 46 (1976) 88–94.
1970D2 Dawson, R., Khoury, F., Kobayashi, R.: AIChE J. 16 (1970) 725–729.
1969W3 Woessner, D.E., Snowden, B.S., George, R.A., Melrose, J.C.: Ind. Eng. Chem. Fundam. 8
(1969) 779–787.
1971O2 Oosting, P.H., Trappeniers, N.J.: Physica 51 (1971) 418–431.
1978H2 Harris, K.R.: Physica A 94 (1978) 448–464.
1980H1 Harris, K.R., Trappeniers, N.J.: Physica A 104 (1980) 262–280.
1996H5 Helbæk, M., Hafskjold, B., Dysthe, D.K., Sørland, G.H.: J. Chem. Eng. Data 41 (1996)
598–603.
1964M5 Mueller, C.R., Cahill, R.W.: J. Chem. Phys. 40 (1964) 651–654.
1970M6 Mistler, T.E., Correll, G.R., Mingle, J.O.: AIChE J. 16 (1970) 32–37.
1971W5 Weissman, S., Dubro, G.A.: J. Chem. Phys. 54 (1971) 1881–1883.
1970C4 Cini Castagnoli, G., Longhetto, A., Anfossi, D.: Physica 49 (1970) 153–156.
1963G1 Gaven, J.V., Waugh, J.S., Stockmayer, W.H.: J. Chem. Phys. 38 (1963) 287–290.

Diffusion of carbon monoxide 1
Diffusion of carbon monoxide

CO carbon monoxide 630-08-0

T [K] p [kPa] D · 104 [m2/s]
100.0 101.325 0.0279 ± 2.0%
150.0 101.325 0.0613 ± 2.0%
200.0 101.325 0.1041 ± 2.0%
250.0 101.325 0.1553 ± 2.0%
300.0 101.325 0.2138 ± 2.0%
273.15 101.325 0.1815 ± 2.0%
293.15 101.325 0.2054 ± 2.0%
313.15 101.325 0.2304 ± 2.0%
333.15 101.325 0.2564 ± 2.0%
353.15 101.325 0.2835 ± 2.0%
373.15 101.325 0.3117 ± 2.0%
423.15 101.325 0.3864 ± 2.0%
473.15 101.325 0.4672 ± 2.0%
523.15 101.325 0.55375 ± 2.0%
573.15 101.325 0.6459 ± 2.0%
623.15 101.325 0.7435 ± 2.0%
673.15 101.325 0.8464 ± 2.0%
723.15 101.325 0.9545 ± 2.0%
773.15 101.325 1.0677 ± 2.0%
873.15 101.325 1.3091 ± 2.0%
973.15 101.325 1.5698 ± 2.0%
1073.15 101.325 1.8493 ± 2.0%
1173.15 101.325 2.1472 ± 2.0%
1273.15 101.325 2.4635 ± 2.0%
1773.15 101.325 4.3184 ± 2.0%
2273.15 101.325 6.6183 ± 2.0%
2773.15 101.325 9.3474 ± 2.0%
3273.15 101.325 12.492 ± 2.0%

Self Diffusion Coefficient D1s(T ); Method: CT Ref.: 1963A2
T [K] p [kPa] D · 104 [m2/s]
194.7 ± 0.01 101.325 0.1095 ± 1%
273.2 ± 0.01 101.325 0.1904 ± 1%
319.6 ± 0.01 101.325 0.2473 ± 1%
373.0 ± 0.01 101.325 0.323 ± 1%

2 Diffusion of carbon monoxide

Self Diffusion Coefficient D1s(T ); Method: OEC Ref.: 1963A2
Equation: log D = A + B log (T ) Range: 195 < T/K < 373
Parameter: A B
–4.7628 1.6601
Comment: D1s [m2/s] = D · 10–4
References
445–466.
1963A2 Amdur, I., Shuler, L.M.: J. Chem. Phys. 38 (1963) 188–192.

Diffusion of carbon dioxide 1
Diffusion of carbon dioxide

CO2 carbon dioxide 124-38-9

T [K] p [kPa] D · 104 [m2/s]
250.0 101.325 0.0828 ± 2.0%
300.0 101.325 0.1187 ± 2.0%
273.15 101.325 0.0987 ± 2.0%
293.15 101.325 0.1135 ± 2.0%
313.15 101.325 0.1289 ± 2.0%
333.15 101.325 0.1453 ± 2.0%
353.15 101.325 0.1623 ± 2.0%
373.15 101.325 0.1801 ± 2.0%
423.15 101.325 0.2276 ± 2.0%
473.15 101.325 0.2793 ± 2.0%
523.15 101.325 0.3350 ± 2.0%
573.15 101.325 0.3945 ± 2.0%
623.15 101.325 0.4577 ± 2.0%
673.15 101.325 0.5243 ± 2.0%
723.15 101.325 0.5944 ± 2.0%
773.15 101.325 0.6678 ± 2.0%
873.15 101.325 0.8242 ± 2.0%
973.15 101.325 0.9927 ± 2.0%
1073.15 101.325 1.1731 ± 2.0%
1173.15 101.325 1.3647 ± 2.0%
1273.15 101.325 1.5675 ± 2.0%
1773.15 101.325 2.7372 ± 2.0%
2273.15 101.325 4.1502 ± 2.0%
2773.15 101.325 5.7904 ± 2.0%
3273.15 101.325 7.6385 ± 2.0%

Self Diffusion Coefficient D1s(T ); Method: CC Ref.: 1976D3
T [K] ρ [kg/m3] D · 107 [m2/s]
306.40 ± 0.01 19 10.26
306.40 ± 0.01 28 7.27
299.35 ± 0.01 28 6.89
298.75 ± 0.01 40 4.98
298.55 ± 0.01 54 3.71
298.15 ± 0.01 66 2.90
297.95 ± 0.01 81 2.39
297.95 ± 0.01 98 1.79
304.15 ± 0.01 98 1.85
304.15 ± 0.01 109 1.62
304.15 ± 0.01 139 1.31
(continued)

2 Diffusion of carbon dioxide
304.15 ± 0.01 151 1.15

299.45 ± 0.01 151 1.24
298.96 ± 0.01 206 0.74
301.22 ± 0.01 206 0.74
304.31 ± 0.01 215 0.73
304.33 ± 0.01 316 0.43
307.87 ± 0.01 342 0.40
307.93 ± 0.01 400 0.30
307.87 ± 0.01 604 0.19
Comment: results from outside the critical region

Self Diffusion Coefficient D1s(T ); Method: CC Ref.: 1976D3
T [K] ρ [kg/m3] D · 107 [m2/s]
304.64 ± 0.01 362 2.01
307.33 ± 0.01 362 0.61
304.65 ± 0.01 362 1.74
304.61 ± 0.01 400 5.91
304.64 ± 0.01 420 13.46
304.68 ± 0.01 450 14.12
304.65 ± 0.01 486 13.45
304.65 ± 0.01 527 2.12
307.87 ± 0.01 478 0.97
307.87 ± 0.01 512 0.74
304.65 ± 0.01 512 4.87
304.65 ± 0.01 604 0.42
307.87 ± 0.01 468 1.23
306.96 ± 0.01 468 2.67
306.16 ± 0.01 468 5.02
305.25 ± 0.01 468 9.41
304.90 ± 0.01 468 12.18
304.65 ± 0.01 468 15.7
Comment: critical region results; [1981K4] claim that these data are much too large and may be in error

Self Diffusion Coefficient D1s(T ); Method: CT Ref.: 1952T1
T [K] p [atm] D · 109 [m2/s]
298.0 113.2 9.05
302.1 103.1 1.37
300.6 178.9 7.02
298.1 103.1 9.34
297.9 130.3 7.64
298.1 562.0 5.12
323.2 232.3 9.16
323.2 250.0 8.84
323.1 470.5 7.04
298.0 402.5 4.09
(continued)
298.2 402.5 4.34

298.0 562.0 3.54
298.2 752.0 3.18
298.2 1023.0 2.53
272.9 137.1 4.04
273.2 307.1 3.20
273.2 512.0 2.46
273.1 802.5 1.98
323.0 470.5 4.98
322.9 596.5 4.53
322.9 837.0 3.92
322.9 1029.0 3.48
298.2 561.0 3.51
298.1 1030.5 2.45

Self Diffusion Coefficient D1s(T ); Method: CT Ref.: 1968R6
T [K] p [atm] D · 108 [m2/s]
295.67 ± 0.01 69.1 1.97 ± 0.23
295.67 ± 0.01 109.2 1.86 ± 0.46
295.67 ± 0.01 145.8 1.59 ± 0.40
295.67 ± 0.01 182.3 1.56
273.77 ± 0.01 72.8 1.18 ± 0.09
273.77 ± 0.01 72.8 1.17 ± 0.05
273.77 ± 0.01 145.6 1.00 ± 0.08

T [K] p [kPa] D · 104 [m2/s]
300.1 ± 0.5 101.325 0.15
350.2 ± 0.5 101.325 0.19
400.6 ± 0.5 101.325 0.24
460.2 ± 0.5 101.325 0.26
504.8 ± 0.5 101.325 0.34
556.9 ± 0.5 101.325 0.42
601.2 ± 0.5 101.325 0.46
660.8 ± 0.5 101.325 0.52
710.9 ± 0.5 101.325 0.57
760.3 ± 0.5 101.325 0.64
820.2 ± 0.5 101.325 0.69
830.3 ± 0.5 101.325 0.76
930.9 ± 0.5 101.325 0.80
1002.3 ± 0.5 101.325 0.88
1070.9 ± 0.5 101.325 0.95


T [K] p [MPa] D · 109 [m2/s]
223.0 ± 1.0 10 4.86 ± 2%
243.0 ± 1.0 10 7.34 ± 2%
273.0 ± 1.0 10 12.4 ± 2%
298.0 ± 1.0 10 18.8 ± 2%
298.0 ± 1.0 20 15.1 ± 2%
333.0 ± 1.0 20 26.9 ± 2%
333.0 ± 1.0 30 20.8 ± 2%
373.0 ± 1.0 30 33.7 ± 2%
424.0 ± 1.0 30 56.4 ± 2%
223.0 ± 1.0 50 3.48 ± 2%
243.0 ± 1.0 50 5.19 ± 2%
273.0 ± 1.0 50 8.42 ± 2%
298.0 ± 1.0 50 11.0 ± 2%
333.0 ± 1.0 50 16.0 ± 2%
373.0 ± 1.0 50 24.3 ± 2%
424.0 ± 1.0 50 36.6 ± 2%
450.0 ± 1.0 50 52.2 ± 2%
373.0 ± 1.0 75 18.9 ± 2%
424.0 ± 1.0 75 27.3 ± 2%
450.0 ± 1.0 75 33.9 ± 2%
450.0 ± 1.0 88 30.2 ± 2%
223.0 ± 1.0 100 2.92 ± 2%
243.0 ± 1.0 100 3.85 ± 2%
273.0 ± 1.0 100 6.05 ± 2%
298.0 ± 1.0 100 8.23 ± 2%
333.0 ± 1.0 100 11.1 ± 2%
373.0 ± 1.0 100 15.4 ± 2%
424.0 ± 1.0 100 24.1 ± 2%
450.0 ± 1.0 100 26.7 ± 2%
424.0 ± 1.0 125 18.6 ± 2%
450.0 ± 1.0 125 22.2 ± 2%
223.0 ± 1.0 150 2.52 ± 2%
243.0 ± 1.0 150 3.18 ± 2%
273.0 ± 1.0 150 4.85 ± 2%
298.0 ± 1.0 150 6.63 ± 2%
333.0 ± 1.0 150 8.98 ± 2%
373.0 ± 1.0 150 12.4 ± 2%
424.0 ± 1.0 150 17.0 ± 2%
450.0 ± 1.0 150 19.5 ± 2%
223.0 ± 1.0 200 2.12 ± 2%
243.0 ± 1.0 200 2.83 ± 2%
273.0 ± 1.0 200 4.29 ± 2%
298.0 ± 1.0 200 5.89 ± 2%
333.0 ± 1.0 200 7.71 ± 2%
373.0 ± 1.0 200 10.3 ± 2%
(continued)

424.0 ± 1.0 200 13.3 ± 2%

450.0 ± 1.0 200 17.0 ± 2%

Self Diffusion Coefficient D1s(T ); Method: NMR FG Ref.: 1981K4
T [K] ρ [g/cm3] D · 109 [m2/s]
304.65 ± 0.03 0.468 63.0 ± 10%
304.90 ± 0.03 0.468 64.0 ± 10%
305.25 ± 0.03 0.468 65.0 ± 10%
306.16 ± 0.03 0.468 67.0 ± 10%
306.96 ± 0.03 0.468 68.0 ± 10%
307.87 ± 0.03 0.468 70.0 ± 10%
304.65 ± 0.01 0.468 1572.0 *
304.90 ± 0.01 0.468 1218.0 *
305.25 ± 0.01 0.468 941.0 *
306.16 ± 0.01 0.468 502.0 *
306.96 ± 0.01 0.468 267.0 *
307.87 ± 0.01 0.468 123.0 *
Comment: values at critical density;
*: data of Duffield and Harris [1976D3] are much larger and may be in error

Self Diffusion Coefficient D1s(T ); Method: NMR PG Ref.: 1992E1
T [K] p [bar] D · 107 [m2/s]
323.15 ± 0.01 274.41 0.189 ± 0.7%
323.15 ± 0.01 343.36 0.171 ± 0.7%
323.15 ± 0.01 411.62 0.156 ± 0.7%
323.15 ± 0.01 482.63 0.148 ± 0.7%
348.15 ± 0.01 10.69 12.99 ± 0.7%
348.15 ± 0.01 20.68 6.303 ± 0.7%
348.15 ± 0.01 38.44 3.250 ± 0.7%
348.15 ± 0.01 49.85 2.329 ± 0.7%
273.15 ± 0.01 10.34 8.000 ± 0.7%
273.15 ± 0.01 20.86 3.512 ± 0.7%
273.15 ± 0.01 32.10 1.998 ± 0.7%
273.15 ± 0.01 55.36 0.135 ± 0.7%
273.15 ± 0.01 68.95 0.130 ± 0.7%
273.15 ± 0.01 137.21 0.117 ± 0.7%
273.15 ± 0.01 208.91 0.107 ± 0.7%
273.15 ± 0.01 270.27 0.100 ± 0.7%
273.15 ± 0.01 346.12 0.095 ± 0.7%
273.15 ± 0.01 415.06 0.091 ± 0.7%
298.15 ± 0.01 10.34 9.510 ± 0.7%
298.15 ± 0.01 20.68 4.400 ± 0.7%
298.15 ± 0.01 24.48 3.729 ± 0.7%
298.15 ± 0.01 35.03 2.540 ± 0.7%
298.15 ± 0.01 42.54 1.832 ± 0.7%
(continued)
298.15 ± 0.01 46.68 1.585 ± 0.7%

298.15 ± 0.01 48.26 1.515 ± 0.7%
298.15 ± 0.01 56.67 1.104 ± 0.7%
298.15 ± 0.01 62.05 0.896 ± 0.7%
298.15 ± 0.01 62.40 0.913 ± 0.7%
298.15 ± 0.01 64.19 0.808 ± 0.7%
298.15 ± 0.01 68.12 0.218 ± 0.7%
298.15 ± 0.01 137.89 0.165 ± 0.7%
298.15 ± 0.01 206.84 0.147 ± 0.7%
298.15 ± 0.01 275.79 0.134 ± 0.7%
298.15 ± 0.01 344.74 0.125 ± 0.7%
298.15 ± 0.01 413.68 0.116 ± 0.7%
298.15 ± 0.01 482.00 0.110 ± 0.7%
323.15 ± 0.01 10.34 11.01 ± 0.7%
323.15 ± 0.01 20.68 5.410 ± 0.7%
323.15 ± 0.01 33.99 3.099 ± 0.7%
323.15 ± 0.01 48.26 1.960 ± 0.7%
323.15 ± 0.01 63.91 1.396 ± 0.7%
323.15 ± 0.01 72.39 1.198 ± 0.7%
323.15 ± 0.01 84.81 0.875 ± 0.7%
323.15 ± 0.01 101.35 0.523 ± 0.7%
323.15 ± 0.01 109.90 0.408 ± 0.7%
323.15 ± 0.01 136.52 0.287 ± 0.7%
323.15 ± 0.01 206.15 0.216 ± 0.7%
348.15 ± 0.01 63.91 1.732 ± 0.7%
348.15 ± 0.01 70.67 1.527 ± 0.7%
348.15 ± 0.01 91.15 1.134 ± 0.7%
348.15 ± 0.01 115.14 0.781 ± 0.7%
348.15 ± 0.01 137.89 0.551 ± 0.7%
348.15 ± 0.01 158.58 0.450 ± 0.7%
348.15 ± 0.01 204.08 0.322 ± 0.7%
348.15 ± 0.01 272.34 0.265 ± 0.7%
348.15 ± 0.01 342.67 0.227 ± 0.7%
348.15 ± 0.01 413.68 0.202 ± 0.7%
348.15 ± 0.01 498.48 0.184 ± 0.7%

Self Diffusion Coefficient D1s(T ); Method: NMR PG Ref.: 1993E2
T [K] ρ [mol/dm3] D · 107 [m2/s]
304.15 ± 0.005 1.765 2.490 ± 0.7%
304.15 ± 0.005 4.100 1.108 ± 0.7%
304.15 ± 0.005 5.419 0.896 ± 0.7%
304.35 ± 0.005 9.25 0.504 ± 0.7%
304.35 ± 0.005 10.55 0.477 ± 0.7%
304.25 ± 0.005 1.746 2.55 ± 0.7%
304.15 ± 0.005 0.964 4.704 ± 0.7%
304.15 ± 0.005 0.570 7.800 ± 0.7%
(continued)

304.35 ± 0.005 2.052 2.191 ± 0.7%

304.35 ± 0.005 3.400 1.314 ± 0.7%
304.25 ± 0.005 4.606 1.06 ± 0.7%
304.25 ± 0.005 6.82 0.662 ± 0.7%
304.16 ± 0.005 12.80 0.390 ± 0.7%
304.21 ± 0.005 10.59 0.433 ± 0.7%
304.21 ± 0.005 10.76 0.418 ± 0.7%
304.22 ± 0.005 10.00 0.446 ± 0.7%
304.23 ± 0.005 9.30 0.493 ± 0.7%
304.25 ± 0.005 10.20 0.432 ± 0.7%
304.21 ± 0.005 13.22 0.317 ± 0.7%
304.60 ± 0.005 13.16 0.316 ± 0.7%
304.65 ± 0.005 11.81 0.361 ± 0.7%
304.63 ± 0.005 10.47 0.442 ± 0.7%
304.64 ± 0.005 8.80 0.509 ± 0.7%
304.65 ± 0.005 5.58 0.793 ± 0.7%
Comment: measurements in the vicinity of the critical point

Self Diffusion Coefficient D1s(T ); Method: No Info Ref.: 2001A7
T [K] p [bar] D · 109 [m2/s]
323.15 40.3 2.60
323.15 60.3 1.56
323.15 101.1 0.56
323.15 123.5 0.35
323.15 143.7 0.28
323.15 163.2 0.26
323.15 184.4 0.25
323.15 197.0 0.24

Self Diffusion Coefficient D1s(T ); Method: PF Ref.: 1968T1
T [K] p [atm] D · 107 [m2/s]
298.15 ± 0.02 10.0 11.2
298.15 ± 0.02 20.0 5.30
298.15 ± 0.02 30.0 3.26
298.15 ± 0.02 40.0 2.25
298.15 ± 0.02 50.0 1.62
323.15 ± 0.02 10.0 13.2
323.15 ± 0.02 20.0 6.35
323.15 ± 0.02 30.0 4.06
323.15 ± 0.02 40.0 2.90
323.15 ± 0.02 50.0 2.18
348.15 ± 0.02 10.0 15.2
348.15 ± 0.02 20.0 7.48
348.15 ± 0.02 30.0 4.81
(continued)

348.15 ± 0.02 40.0 3.51

348.15 ± 0.02 50.0 2.71

T [K] p [atm] D · 107 [m2/s]
298.15 ± 0.1 2.91 39.1
298.15 ± 0.1 2.91 39.2
298.15 ± 0.1 3.91 29.0
298.15 ± 0.1 3.91 28.7
298.15 ± 0.1 4.91 23.5
298.15 ± 0.1 4.91 23.2
298.15 ± 0.1 6.81 16.7
298.15 ± 0.1 8.74 12.8
298.15 ± 0.1 10.30 11.0
298.15 ± 0.1 10.68 10.4
298.15 ± 0.1 12.61 8.78
298.15 ± 0.1 14.55 7.43
298.15 ± 0.1 15.3 7.15
298.15 ± 0.1 20.5 5.12
298.15 ± 0.1 30.4 3.20
298.15 ± 0.1 40.4 2.23
298.15 ± 0.1 50.4 1.61
323.15 ± 0.1 2.91 45.8
323.15 ± 0.1 3.91 34.2
323.15 ± 0.1 4.91 26.9
323.15 ± 0.1 5.89 22.7
323.15 ± 0.1 6.81 19.4
323.15 ± 0.1 6.87 19.1
323.15 ± 0.1 8.74 15.0
323.15 ± 0.1 10.3 12.8
323.15 ± 0.1 10.68 12.5
323.15 ± 0.1 12.61 10.3
323.15 ± 0.1 14.55 8.98
323.15 ± 0.1 15.3 8.50
323.15 ± 0.1 20.5 6.21
323.15 ± 0.1 30.4 3.98
323.15 ± 0.1 40.4 2.88
323.15 ± 0.1 50.4 2.13
348.15 ± 0.1 2.91 52.1
348.15 ± 0.1 3.91 38.7
348.15 ± 0.1 4.91 30.7
348.15 ± 0.1 5.89 26.1
348.15 ± 0.1 6.87 22.4
348.15 ± 0.1 8.74 17.4
348.15 ± 0.1 10.68 14.4
348.15 ± 0.1 11.4 13.5
(continued)

348.15 ± 0.1 12.61 12.1

348.15 ± 0.1 14.55 10.6
348.15 ± 0.1 15.3 9.81
348.15 ± 0.1 20.5 7.09
348.15 ± 0.1 30.4 4.71
348.15 ± 0.1 40.4 3.45
348.15 ± 0.1 50.5 2.59
Comment: ΔP = ±0.2 atm up to 20 atm, ±0.1 atm at 10..50 atm and ±0.5 atm at 50..250 atm;
plug of sintered bronze (larger grain size)

T [K] p [atm] D · 107 [m2/s]
323.15 ± 0.1 19.2 6.62
323.15 ± 0.1 22.4 5.69
323.15 ± 0.1 29.9 4.11
323.15 ± 0.1 30.3 4.00
323.15 ± 0.1 40.0 2.95
323.15 ± 0.1 40.8 2.83
323.15 ± 0.1 49.8 2.21
323.15 ± 0.1 53.1 1.99
323.15 ± 0.1 58.8 1.70
323.15 ± 0.1 67.1 1.47
323.15 ± 0.1 70.9 1.31
323.15 ± 0.1 80.7 1.03
323.15 ± 0.1 86.7 0.907
323.15 ± 0.1 92.5 0.792
323.15 ± 0.1 98.0 0.678
323.15 ± 0.1 101.7 0.600
323.15 ± 0.1 102.2 0.595
323.15 ± 0.1 109.5 0.453
323.15 ± 0.1 113.2 0.436
323.15 ± 0.1 123.3 0.379
323.15 ± 0.1 150.3 0.297
323.15 ± 0.1 182.5 0.266
323.15 ± 0.1 189.4 0.260
323.15 ± 0.1 199.4 0.250
323.15 ± 0.1 240.0 0.228
348.15 ± 0.1 20.2 7.20
348.15 ± 0.1 20.3 7.22
348.15 ± 0.1 21.1 7.24
348.15 ± 0.1 30.3 4.84
348.15 ± 0.1 32.3 4.52
348.15 ± 0.1 40.1 3.40
348.15 ± 0.1 40.1 3.54
348.15 ± 0.1 40.4 3.33
348.15 ± 0.1 41.2 3.54
348.15 ± 0.1 50.1 2.77
(continued)
348.15 ± 0.1 50.2 2.67

348.15 ± 0.1 50.2 2.54
348.15 ± 0.1 50.5 2.49
348.15 ± 0.1 58.1 2.33
348.15 ± 0.1 61.0 2.06
348.15 ± 0.1 67.4 1.85
348.15 ± 0.1 81.5 1.42
348.15 ± 0.1 91.5 1.23
348.15 ± 0.1 92.5 1.20
348.15 ± 0.1 99.4 1.12
348.15 ± 0.1 103.5 0.956
348.15 ± 0.1 117.5 0.770
348.15 ± 0.1 123.1 0.759
348.15 ± 0.1 158.5 0.503
348.15 ± 0.1 208.3 0.386
348.15 ± 0.1 245.6 0.303
Comment: ΔP = ±0.2 atm up to 20 atm, ±0.1 atm at 10..50 atm and ±0.5 atm at 50..250 atm;
plug of sintered bronze (small grain size)

T [K] p [atm] D · 107 [m2/s]
298.15 ± 0.1 10.0 11.2
298.15 ± 0.1 20.0 5.30
298.15 ± 0.1 30.0 3.26
298.15 ± 0.1 40.0 2.25
298.15 ± 0.1 50.0 1.62
323.15 ± 0.1 10.0 13.2
323.15 ± 0.1 20.0 6.35
323.15 ± 0.1 30.0 4.05
323.15 ± 0.1 40.0 2.90
323.15 ± 0.1 50.0 2.18
348.15 ± 0.1 10.0 15.2
348.15 ± 0.1 20.0 7.48
348.15 ± 0.1 30.0 4.81
348.15 ± 0.1 40.0 3.51
348.15 ± 0.1 50.0 2.71
Comment: smoothed values of previous data

Self Diffusion Coefficient D1s(T ); Method: POINT Ref.: 1965P2
T [K] p [kPa] D · 105 [m2/s]
1103 101.325 1.62 ± 5%
1204 101.325 1.78 ± 5%
1213 101.325 1.94 ± 5%
1250 101.325 2.12 ± 5%
1278 101.325 2.19 ± 5%
(continued)
1302 101.325 2.26 ± 5%

1321 101.325 2.19 ± 5%
1338 101.325 1.99 ± 5%
1372 101.325 2.30 ± 5%
1416 101.325 2.34 ± 5%
1434 101.325 2.56 ± 5%
1451 101.325 2.47 ± 5%
1471 101.325 2.62 ± 5%
1478 101.325 2.69 ± 5%
1498 101.325 2.49 ± 5%
1607 101.325 3.12 ± 5%
1610 101.325 2.95 ± 5%
1654 101.325 3.21 ± 5%
1671 101.325 3.13 ± 5%
1703 101.325 3.33 ± 5%
1719 101.325 3.45 ± 5%
1745 101.325 3.31 ± 5%
1782 101.325 3.67 ± 5%
1796 101.325 3.59 ± 5%
1944 101.325 4.30 ± 5%

Self Diffusion Coefficient D1s(T ); Method: POINT Ref.: 1962E1
T [K] p [kPa] D · 104 [m2/s]
296 101.325 0.109
298 101.325 0.109
1180 101.325 1.73
1180 101.325 1.84
1218 101.325 2.04
1330 101.325 2.38
1445 101.325 2.80
1445 101.325 2.86
1450 101.325 2.56
1487 101.325 2.88
1490 101.325 2.98
1520 101.325 2.78
1576 101.325 3.12
1580 101.325 3.33
1665 101.325 3.29
1680 101.325 3.50

T [K] p [kPa] D · 104 [m2/s]
248 101.325 0.083
289 101.325 0.110
296 101.325 0.114
(continued)
295 101.325 0.116

308 101.325 0.124
331 101.325 0.146
342 101.325 0.155
353 101.325 0.167
362 101.325 0.168

Self Diffusion Coefficient D1s(T ); Method: TAYLOR Ref.: 2002C3
T [K] p [bar] D · 109 [m2/s]
323.15 ± 0.05 63.91 13.9
323.15 ± 0.05 72.39 12.0
323.15 ± 0.05 84.81 8.8
323.15 ± 0.05 101.35 5.2
323.15 ± 0.05 109.90 4.1
323.15 ± 0.05 136.52 2.9
323.15 ± 0.05 206.15 2.2
323.15 ± 0.05 274.41 1.9
323.15 ± 0.05 343.36 1.7
323.15 ± 0.05 411.62 1.6
323.15 ± 0.05 482.63 1.5

T [K] p [kPa] D · 104 [m2/s]
293.15 101.325 0.151 ± 0.006

T [K] p [kPa] D · 104 [m2/s]
293.2 101.325 0.112
298.2 101.325 0.116
303.2 101.325 0.120

Equation: D = A ((T ) / B)C Range: 245 < T/K < 360
Parameter: A ∙ 106 B C Std-Dev
1.66 1.000 1.96 1.3%
Comment: D1s [m2/s] = D ∙ 10–4
References
445–466.
1976D3 Duffield, J.S., Harris, M.J.: Ber. Bunsenges. Phys. Chem. 80 (1976) 157–163.

1952T1 Timmerhaus, K.D., Drickramer, H.G.: J. Chem. Phys. 20 (1952) 981–984.

1968R6 Robinson, R.C., Stewart, W.E.: Ind. Eng. Chem. Fundam. 7 (1968) 90–95.
32–38.
1998G2 Groß, T., Buchhauser, J., Lüdemann, H.‐D.: J. Chem. Phys. 109 (1998) 4518–4522.
1981K4 Krynicki, K., Meragi, A.L., Powles, J.G.: Ber. Bunsenges. Phys. Chem. 85 (1981) 1153–1154.
1992E1 Etesse, P., Zega, J.A., Kobayashi, R.: J. Chem. Phys. 97 (1992) 2022–2029.
1993E2 Etesse, P., Ward, A.M., House, W.V., Kobayashi, R.: Physica B 183 (1993) 45–52.
2001A7 Adam, W., Diedering, M., Trifonov, A.V.: Chem. Phys. Lett. 350 (2001) 453–458.
1968T1 Takahashi, S., Iwasaki, H.: Rev. Phys. Chem. Jpn. 38 (1968) 28–40.
1966T1 Takahashi, S., Iwasaki, H.: Bull. Chem. Soc. Jpn. 39 (1966) 2105–2109.
1965P2 Pakurar, T.A., Ferron, J.R.: J. Chem. Phys. 43 (1965) 2917–2918.
1962E1 Ember, G., Ferron, J.R., Wohl, K.: J. Chem. Phys. 37 (1962) 891–897.
1963W2 Wendt, R.P., Mundy, J.N., Weissman, S., Mason, E.A.: Phys. Fluids 6 (1963) 572–578.
2002C3 Coelho, L.A.F., de Oliveira, J.V., Tavares, F.W., Matthews, M.A.: Fluid Phase Equilib. 194‐197
(2002) 1131–1140.
1970M6 Mistler, T.E., Correll, G.R., Mingle, J.O.: AIChE J. 16 (1970) 32–37.

Diffusion of ethyne 1
Diffusion of ethyne
C2H2 ethyne 74-86-2

T [K] p [kPa] D · 104 [m2/s]
298.2 ± 0.1 101.325 0.133 ± 0.001
352.6 ± 0.1 101.325 0.191 ± 0.001
382.5 ± 0.1 101.325 0.241 ± 0.001
Reference

Diffusion of ethyne-d2 1
Diffusion of ethyne-d2
C2D2 ethyne-d2 1070-74-2

Self Diffusion Coefficient D1s(T ); Method: NMR FG Ref.: 1973S5
Parameter: A · 103 [cm2/s] B
6.37 ± 1.65 1.96 ± 0.11
Comment: liquid ethyne-d2; D1s [m2/s] = D · 10–4 ; ΔD = ± 5%
Reference
1973S5 Scheie, C.E., Peterson, E.M., O´Reilly, D.E.: J. Chem. Phys. 59 (1973) 2303–2304.

Diffusion of ethene 1
Diffusion of ethene
C2H4 ethene 74-85-1

T [K] p [kPa] D · 104 [m2/s]
250.0 101.325 0.0892 ± 2%
300.0 101.325 0.12765 ± 2%
273.15 101.325 0.1063 ± 2%
293.15 101.325 0.1221 ± 2%
313.15 101.325 0.1387 ± 2%
333.15 101.325 0.1563 ± 2%
353.15 101.325 0.1745 ± 2%
373.15 101.325 0.1936 ± 2%
423.15 101.325 0.2446 ± 2%
473.15 101.325 0.3002 ± 2%
523.15 101.325 0.3601 ± 2%
573.15 101.325 0.4241 ± 2%
623.15 101.325 0.4920 ± 2%
673.15 101.325 0.5636 ± 2%
723.15 101.325 0.6389 ± 2%
773.15 101.325 0.7177 ± 2%
873.15 101.325 0.8857 ± 2%
973.15 101.325 1.0667 ± 2%
1073.15 101.325 1.2605 ± 2%
1173.15 101.325 1.4664 ± 2%
1273.15 101.325 1.6842 ± 2%
1773.15 101.325 2.9409 ± 2%
2273.15 101.325 4.4590 ± 2%
C2H4 ethene 74-85-1

Self Diffusion Coefficient D1s(T ); Method: GC Ref.: 1978K3
T [K] p [MPa] D · 106 [m2/s]
254 0.80 1.20 ± 0.06
314 0.80 1.77 ± 0.09
573 0.80 4.9 ± 0.3
760 0.80 8.5 ± 0.8
C2H4 ethene 74-85-1

Self Diffusion Coefficient D1s(T ); Method: NMR FG Ref.: 1981A5
T [K] p [bar] D · 108 [m2/s]
123.15 20.44 0.1719 ± 1.0%
123.15 101.33 0.1608 ± 1.0%
123.15 202.65 0.1488 ± 1.0%
123.15 350.00 0.1350 ± 1.0%
(continued)

2 Diffusion of ethene
123.15 542.92 0.1186 ± 1.0%

123.15 786.68 0.1028 ± 1.0%
123.15 1013.25 0.08879 ± 1.0%
123.15 1139.91 0.08216 ± 1.0%
123.15 1197.60 0.07939 ± 1.0%
123.15 1200.70 0.07965 ± 1.0%
173.15 20.44 0.5764 ± 1.0%
173.15 101.33 0.5411 ± 1.0%
173.15 150.00 0.5168 ± 1.0%
173.15 300.00 0.4663 ± 1.0%
173.15 500.00 0.4133 ± 1.0%
173.15 785.68 0.3532 ± 1.0%
173.15 1013.25 0.3131 ± 1.0%
173.15 1519.88 0.2562 ± 1.0%
173.15 2055.28 0.2100 ± 1.0%
173.15 2721.68 0.1675 ± 1.0%
223.15 25.00 1.313 ± 1.0%
223.15 50.00 1.290 ± 1.0%
223.15 150.00 1.143 ± 1.0%
223.15 250.00 1.062 ± 1.0%
223.15 300.00 1.017 ± 1.0%
223.15 400.00 0.9510 ± 1.0%
223.15 500.00 0.8678 ± 1.0%
223.15 607.95 0.8172 ± 1.0%
223.15 810.60 0.7196 ± 1.0%
223.15 1013.25 0.6585 ± 1.0%
223.15 1519.88 0.5399 ± 1.0%
223.15 2026.50 0.4490 ± 1.0%
223.15 2721.68 0.3646 ± 1.0%
C2H4 ethene 74-85-1

Self Diffusion Coefficient D1s(T ); Method: NMR FG Ref.: 1981A5
T [K] p [bar] D · 107 [m2/s]
273.15 45.564 0.3206 ± 1.0%
273.15 63.446 0.2805 ± 1.0%
273.15 96.824 0.2499 ± 1.0%
273.15 152.485 0.2196 ± 1.0%
273.15 238.592 0.1940 ± 1.0%
273.15 364.940 0.1710 ± 1.0%
273.15 542.924 0.1435 ± 1.0%
273.15 785.682 0.1252 ± 1.0%
273.15 1109.118 0.1059 ± 1.0%
273.15 1526.983 0.08714 ± 1.0%
273.15 2056.270 0.07491 ± 1.0%
273.15 2721.681 0.06280 ± 1.0%
298.15 58.37 1.1360 ± 1.0%
298.15 62.18 0.9365 ± 1.0%
(continued)

Diffusion of ethene 3
298.15 65.047 0.7991 ± 1.0%

298.15 67.505 0.6866 ± 1.0%
298.15 70.041 0.6210 ± 1.0%
298.15 73.244 0.5481 ± 1.0%
298.15 77.989 0.4945 ± 1.0%
298.15 85.662 0.4425 ± 1.0%
298.15 98.420 0.3958 ± 1.0%
298.15 119.368 0.3466 ± 1.0%
298.15 152.687 0.3121 ± 1.0%
298.15 203.863 0.2743 ± 1.0%
298.15 279.693 0.2408 ± 1.0%
298.15 388.528 0.2092 ± 1.0%
298.15 540.104 0.1820 ± 1.0%
298.15 745.570 0.1557 ± 1.0%
298.15 1018.811 0.1344 ± 1.0%
298.15 1374.869 0.1166 ± 1.0%
298.15 1828.468 0.09927 ± 1.0%
C2H4 ethene 74-85-1

T [K] p [atm] D · 107 [m2/s]
298.15 ± 0.05 20.52 5.12
298.15 ± 0.05 20.61 5.17
298.15 ± 0.05 49.00 1.59
298.15 ± 0.05 49.5 1.56
298.15 ± 0.05 59.8 0.971
298.15 ± 0.05 67.6 0.626
298.15 ± 0.05 77.1 0.480
298.15 ± 0.05 86.2 0.394
323.15 ± 0.05 20.36 6.48
323.15 ± 0.05 20.65 6.33
323.15 ± 0.05 50.0 2.06
323.15 ± 0.05 51.3 2.07
323.15 ± 0.05 72.6 1.23
323.15 ± 0.05 84.5 0.891
323.15 ± 0.05 98.5 0.644
323.15 ± 0.05 117.1 0.539
323.15 ± 0.05 138.4 0.467
348.15 ± 0.05 20.45 7.47
348.15 ± 0.05 20.45 7.54
348.15 ± 0.05 51.1 2.55
348.15 ± 0.05 51.2 2.63
348.15 ± 0.05 87.1 1.28
348.15 ± 0.05 121.0 0.752
348.15 ± 0.05 158.8 0.579
348.15 ± 0.05 196.5 0.504
Comment: 14-C labelled ethene diffusing in normal ethene; accuracy: ±3%

4 Diffusion of ethene
C2H4 ethene 74-85-1

Self Diffusion Coefficient D1s(T ); Method: PF Ref.: 1978R2
T [K] p [kPa] D · 106 [m2/s]
304 101.325 0.24 ± 0.006
C2H4 ethene 74-85-1

T [K] p [kPa] D · 104 [m2/s]
298.2 ± 0.1 101.325 0.125 ± 0.001
352.6 ± 0.1 101.325 0.173 ± 0.001
382.5 ± 0.1 101.325 0.205 ± 0.001
References
445–466.
1978K3 Kolk, J.F.M., Matulewicz, E.R.A., Moulijn, J.A.: J. Chromatogr. A 160 (1978) 11–28.
1981A5 Arends, B., Prins, K.O., Trappeniers, N.J.: Physica A 107 (1981) 307–318.
1977T1 Takahashi, S.: J. Chem. Eng. Jpn. 10 (1977) 339–342.
1978R2 Rastogi, R.P., Mishra, B.: J. Phys. Chem. 82 (1978) 2341–2346.

Diffusion of 1,2-dibromo-ethane 1
Diffusion of 1,2-dibromo-ethane
C2H4Br2 1,2-dibromo-ethane 106-93-4

Self Diffusion Coefficient D1s(T ); Method: NMR PG Ref.: 1988K1
Parameter: A · 107 B · 10–3 Std-Dev
1.930 13.56 10.0%
Comment: low accuracy
Reference
1988K1 Kempka, M., Peplinska, B., Pajak, Z.: Ber. Bunsenges. Phys. Chem. 92 (1988) 686–689.

Diffusion of ethane 1
Diffusion of ethane
C2H6 ethane 0 74-84-0

T [K] p [kPa] D · 104 [m2/s]
250.0 101.325 0.0750 ± 2%
300.0 101.325 0.1074 ± 2%
273.15 101.325 0.0895 ± 2%
293.15 101.325 0.1027 ± 2%
313.15 101.325 0.1167 ± 2%
333.15 101.325 0.1314 ± 2%
353.15 101.325 0.1468 ± 2%
373.15 101.325 0.1628 ± 2%
423.15 101.325 0.2057 ± 2%
473.15 101.325 0.2523 ± 2%
523.15 101.325 0.3026 ± 2%
573.15 101.325 0.3562 ± 2%
623.15 101.325 0.4132 ± 2%
673.15 101.325 0.4733 ± 2%
723.15 101.325 0.5365 ± 2%
773.15 101.325 0.6027 ± 2%
873.15 101.325 0.7436 ± 2%
973.15 101.325 0.8955 ± 2%
1073.15 101.325 1.0581 ± 2%
1173.15 101.325 1.2310 ± 2%
1273.15 101.325 1.4136 ± 2%
1773.15 101.325 2.4682 ± 2%
2273.15 101.325 3.7423 ± 2%
C2H6 ethane 0 74-84-0

Self Diffusion Coefficient D1s(T ); Method: NMR PG Ref.: 1996H5
T [K] p [MPa] D · 109 [m2/s]
303.2 30 18.6 ± 5%
303.2 40 16.7 ± 5%
303.2 50 15.2 ± 5%
333.1 30 25 ± 5%
333.1 40 21 ± 5%
333.1 50 19.2 ± 5%
C2H6 ethane 0 74-84-0

Self Diffusion Coefficient D1s(T ); Method: No Info Ref.: 2001A7
T [K] p [bar] D · 109 [m2/s]
323.15 40.0 0.67
323.15 50.0 0.62
(continued)

2 Diffusion of ethane
323.15 60.0 0.57

323.15 80.0 0.48
323.15 100.0 0.40
323.15 120.0 0.38
323.15 140.0 0.35
323.15 160.0 0.32
323.15 180.0 0.30
323.15 200.0 0.28
C2H6 ethane 0 74-84-0

T [K] p [kPa] D · 104 [m2/s]
298.2 ± 0.1 101.325 0.105 ± 0.001
352.6 ± 0.1 101.325 0.147 ± 0.001
382.5 ± 0.1 101.325 0.170 ± 0.001
C2H6 ethane 0 74-84-0

Self Diffusion Coefficient D1s(T ); Method: NMR FG Ref.: 1969P7
Equation: ln D = A + B · T + C · ρ + E · ρ · T Range: 155 < T/K < 298
Parameter: A B · 103 C E · 102
3.97 –4.78 –10.6 2.30
Comment: ρ in [g/cm3] , D1s [m2/s] = D · 10–4
References
445–466.
598–603.
2001A7 Adam, W., Diedering, M., Trifonov, A.V.: Chem. Phys. Lett. 350 (2001) 453–458.
1969P7 Powles, J.G., Gough, M.C.: Mol. Phys. 16 (1969) 349–367.

Diffusion of propene 1
Diffusion of propene
C3H6 propene 115-07-1

T [K] p [MPa] D · 106 [m2/s]
327 0.80 11.5 ± 0.5
Reference

Diffusion of propane 1
Diffusion of propane
C3H8 propane 74-98-6

Self Diffusion Coefficient D1s(T ); Method: CT Ref.: 1968R6
T [K] p [atm] D · 108 [m2/s]
295.95 ± 0.01 14.5 1.22 ± 0.21
295.95 ± 0.01 83.9 1.20 ± 0.05
295.95 ± 0.01 168.2 0.99
332.96 ± 0.01 29.5 1.97 ± 0.13
332.96 ± 0.01 83.9 1.80 ± 0.19
358.85 ± 0.01 42.1 3.08 ± 0.22
358.85 ± 0.01 83.9 2.34
358.85 ± 0.01 168.0 1.82 ± 0.18
Reference
1968R6 Robinson, R.C., Stewart, W.E.: Ind. Eng. Chem. Fundam. 7 (1968) 90–95.

Diffusion of propane-d8 1
Diffusion of propane-d8
C3D8 propane-d8 2875-94-7

Self Diffusion Coefficient D1s(T ); Method: NMR FG Ref.: 1969W3
T [K] p [bar] D · 108 [m2/s]
298.15 ± 0.17 121.69 1.08 ± 5%
298.15 ± 0.17 138.93 1.02 ± 5%
298.15 ± 0.17 156.17 0.97 ± 5%
298.15 ± 0.17 173.40 0.98 ± 5%
330.93 ± 0.17 121.69 1.46 ± 5%
330.93 ± 0.17 138.93 1.38 ± 5%
330.93 ± 0.17 156.17 1.36 ± 5%
330.93 ± 0.17 173.40 1.30 ± 5%
358.71 ± 0.17 42.68 2.82 ± 5%
358.71 ± 0.17 85.01 2.36 ± 5%
358.71 ± 0.17 170.30 1.82 ± 5%
364.26 ± 0.17 121.69 2.09 ± 5%
364.26 ± 0.17 138.93 1.94 ± 5%
364.26 ± 0.17 156.17 1.87 ± 5%
364.26 ± 0.17 173.40 1.85 ± 5%
Reference
(1969) 779–787.

Diffusion of butane 1
Diffusion of butane
C4H10 butane 106-97-8

Self Diffusion Coefficient D1s(T ); Method: NMR FG Ref.: 1986B2
T [K] p [MPa] D · 108 [m2/s]
397.83 4.2 2.5
406.04 15.42 1.52
314.86 8.97 0.76
416.42 39.61 1.26
407.27 101.96 0.78
Comment: graphs for T = 150 - 451 K are given
Reference
1986B2 Bachl, F., Lüdemann, H.‐D.: Z. Naturforsch. A 41 (1986) 963–970.

Diffusion of pentane 1
Diffusion of pentane
C5H12 pentane 109-66-0

Self Diffusion Coefficient D1s(T ); Method: CT Ref.: 1969B2
T [K] p [atm] D · 104 [m2/s]
273.1 0.1890 0.0109
273.1 0.1921 0.0114
273.1 0.2191 0.0119
273.1 0.2144 0.0116
Comment: 14C- pentane in normal pentane
Reference
1969B2 Beatty, J.W.: J. Chem. Phys. 51 (1969) 4673–4674.

Diffusion of deuterium 1
Diffusion of deuterium
D2 deuterium 7782-39-0
Self Diffusion Coefficient D1s(T ); Method: NMR FG Ref.: 2001C2
T [K] p [MPa] D · 107 [m2/s]
372 ± 0.5 50 3.97 ± 2%
334 ± 0.5 50 3.22 ± 2%
296 ± 0.5 50 2.80 ± 2%
274 ± 0.5 50 2.53 ± 2%
243 ± 0.5 50 2.03 ± 2%
213 ± 0.5 50 1.67 ± 2%
172 ± 0.5 50 1.15 ± 2%
372 ± 0.5 75 2.79 ± 2%
334 ± 0.5 75 2.27 ± 2%
296 ± 0.5 75 1.95 ± 2%
274 ± 0.5 75 1.76 ± 2%
243 ± 0.5 75 1.43 ± 2%
213 ± 0.5 75 1.18 ± 2%
172 ± 0.5 75 0.83 ± 2%
372 ± 0.5 100 2.16 ± 2%
334 ± 0.5 100 1.79 ± 2%
296 ± 0.5 100 1.55 ± 2%
274 ± 0.5 100 1.39 ± 2%
243 ± 0.5 100 1.18 ± 2%
213 ± 0.5 100 0.96 ± 2%
172 ± 0.5 100 0.70 ± 2%
372 ± 0.5 125 1.79 ± 2%
334 ± 0.5 125 1.57 ± 2%
296 ± 0.5 125 1.33 ± 2%
274 ± 0.5 125 1.19 ± 2%
243 ± 0.5 125 0.99 ± 2%
213 ± 0.5 125 0.81 ± 2%
172 ± 0.5 125 0.59 ± 2%
372 ± 0.5 150 1.59 ± 2%
334 ± 0.5 150 1.35 ± 2%
296 ± 0.5 150 1.17 ± 2%
274 ± 0.5 150 1.02 ± 2%
243 ± 0.5 150 0.89 ± 2%
213 ± 0.5 150 0.72 ± 2%
172 ± 0.5 150 0.51 ± 2%
372 ± 0.5 175 1.41 ± 2%
334 ± 0.5 175 1.23 ± 2%
296 ± 0.5 175 1.02 ± 2%
274 ± 0.5 175 0.91 ± 2%
243 ± 0.5 175 0.80 ± 2%
213 ± 0.5 175 0.66 ± 2%
172 ± 0.5 175 0.47 ± 2%
(continued)
2 Diffusion of deuterium
372 ± 0.5 200 1.30 ± 2%

334 ± 0.5 200 1.11 ± 2%
296 ± 0.5 200 0.94 ± 2%
274 ± 0.5 200 0.84 ± 2%
243 ± 0.5 200 0.71 ± 2%
213 ± 0.5 200 0.60 ± 2%
172 ± 0.5 200 0.43 ± 2%
D2 deuterium 7782-39-0
Equation: D = A · exp[ –B / (RT)] Range: 18.2 < T/K < 24.1
Parameter: A · 108 B
5.70 ± 1.45 107.3 ± 9.3
References
2001C2 Chen, L., Gross, T., Krienke, H., Ludemann, H.D.: Phys. Chem. Chem. Phys. 3 (2001)
2025–2030.
1977O1 O´Reilly, D.E., Peterson, E.M.: J. Chem. Phys. 66 (1977) 934–937.

Diffusion of ammonia-d3 1
Diffusion of ammonia-d3
D 3N ammonia-d3 13550-49-7
T [K] p [MPa] D · 109 [m2/s]
203.5 ± 1.0 10 1.92 ± 5%
212.9 ± 1.0 10 2.51 ± 5%
222.9 ± 1.0 10 3.12 ± 5%
233.7 ± 1.0 10 3.87 ± 5%
242.7 ± 1.0 10 4.44 ± 5%
273.7 ± 1.0 10 7.33 ± 5%
298.4 ± 1.0 10 10.95 ± 5%
332.9 ± 1.0 10 16.7 ± 5%
373.6 ± 1.0 10 27.3 ± 5%
203.5 ± 1.0 50 1.72 ± 5%
212.9 ± 1.0 50 2.15 ± 5%
222.9 ± 1.0 50 2.71 ± 5%
233.7 ± 1.0 50 3.39 ± 5%
242.7 ± 1.0 50 4.00 ± 5%
273.7 ± 1.0 50 6.63 ± 5%
298.4 ± 1.0 50 9.21 ± 5%
332.9 ± 1.0 50 13.6 ± 5%
373.6 ± 1.0 50 20.5 ± 5%
423.6 ± 1.0 50 32.5 ± 5%
473.5 ± 1.0 50 51.2 ± 5%
203.5 ± 1.0 100 1.53 ± 5%
212.9 ± 1.0 100 1.81 ± 5%
222.9 ± 1.0 100 2.34 ± 5%
233.7 ± 1.0 100 2.95 ± 5%
242.7 ± 1.0 100 3.50 ± 5%
273.7 ± 1.0 100 5.59 ± 5%
298.4 ± 1.0 100 7.99 ± 5%
332.9 ± 1.0 100 11.5 ± 5%
373.6 ± 1.0 100 16.5 ± 5%
423.6 ± 1.0 100 24.4 ± 5%
473.5 ± 1.0 100 34.0 ± 5%
203.5 ± 1.0 150 1.26 ± 5%
212.9 ± 1.0 150 1.57 ± 5%
222.9 ± 1.0 150 2.09 ± 5%
233.7 ± 1.0 150 2.58 ± 5%
242.7 ± 1.0 150 3.05 ± 5%
273.7 ± 1.0 150 4.95 ± 5%
298.4 ± 1.0 150 6.92 ± 5%
332.9 ± 1.0 150 9.89 ± 5%
373.6 ± 1.0 150 14.2 ± 5%
423.6 ± 1.0 150 20.2 ± 5%
473.5 ± 1.0 150 27.4 ± 5%
(continued)
2 Diffusion of ammonia-d3
212.9 ± 1.0 200 1.37 ± 5%

222.9 ± 1.0 200 1.85 ± 5%
233.7 ± 1.0 200 2.27 ± 5%
242.7 ± 1.0 200 2.78 ± 5%
273.7 ± 1.0 200 4.30 ± 5%
298.4 ± 1.0 200 6.22 ± 5%
332.9 ± 1.0 200 8.88 ± 5%
373.6 ± 1.0 200 12.6 ± 5%
423.6 ± 1.0 200 17.4 ± 5%
473.5 ± 1.0 200 23.7 ± 5%
Reference
1999B1 Buchhauser, J., Groß, T., Karger, N., Lüdemann, H.‐D.: J. Chem. Phys. 110 (1999) 3037–3042.

Diffusion of methane-d4 1
Diffusion of methane-d4
D 4C methane-d4 558-20-3
T [K] p [MPa] D · 109 [m2/s]
143.0 ±1.0 21 0.716 ± 5%
160.0 ±1.0 21 1.08 ± 5%
193.0 ±1.0 21 1.87 ± 5%
223.0 ±1.0 21 3.02 ± 5%
253.5 ±1.0 21 4.97 ± 5%
295.0 ±1.0 21 8.04 ± 5%
327.0 ±1.0 21 10.7 ± 5%
364.0 ±1.0 21 13.2 ± 5%
427.0 ±1.0 21 19.2 ± 5%
454.0 ±1.0 21 32.0 ± 5%
143.0 ±1.0 27 0.665 ± 5%
160.0 ±1.0 27 1.05 ± 5%
193.0 ±1.0 27 1.68 ± 5%
223.0 ±1.0 27 2.77 ± 5%
253.5 ±1.0 27 4.01 ± 5%
295.0 ±1.0 27 6.06 ± 5%
327.0 ±1.0 27 8.56 ± 5%
364.0 ±1.0 27 10.9 ± 5%
427.0 ±1.0 27 15.6 ± 5%
454.0 ±1.0 27 16.8 ± 5%
143.0 ±1.0 31 0.635 ± 5%
160.0 ±1.0 31 0.983 ± 5%
193.0 ±1.0 31 1.52 ± 5%
223.0 ±1.0 31 2.61 ± 5%
253.5 ±1.0 31 3.75 ± 5%
295.0 ±1.0 31 5.62 ± 5%
327.0 ±1.0 31 7.43 ± 5%
364.0 ±1.0 31 9.22 ± 5%
427.0 ±1.0 31 13.3 ± 5%
454.0 ±1.0 31 14.6 ± 5%
143.0 ±1.0 57 0.517 ± 5%
160.0 ±1.0 57 0.808 ± 5%
193.0 ±1.0 57 1.26 ± 5%
223.0 ±1.0 57 1.88 ± 5%
253.5 ±1.0 57 2.55 ± 5%
295.0 ±1.0 57 3.78 ± 5%
327.0 ±1.0 57 4.65 ± 5%
364.0 ±1.0 57 5.72 ± 5%
427.0 ±1.0 57 7.89 ± 5%
454.0 ±1.0 57 8.69 ± 5%
143.0 ±1.0 107 0.375 ± 5%
160.0 ±1.0 107 0.547 ± 5%
(continued)
2 Diffusion of methane-d4
193.0 ±1.0 107 0.899 ± 5%

223.0 ±1.0 107 1.38 ± 5%
253.5 ±1.0 107 1.84 ± 5%
295.0 ±1.0 107 2.55 ± 5%
327.0 ±1.0 107 3.06 ± 5%
364.0 ±1.0 107 3.83 ± 5%
427.0 ±1.0 107 5.07 ± 5%
454.0 ±1.0 107 5.56 ± 5%
143.0 ±1.0 157 0.289 ± 5%
160.0 ±1.0 157 0.442 ± 5%
193.0 ±1.0 157 0.719 ± 5%
223.0 ±1.0 157 1.08 ± 5%
253.5 ±1.0 157 1.38 ± 5%
295.0 ±1.0 157 2.02 ± 5%
327.0 ±1.0 157 2.40 ± 5%
364.0 ±1.0 157 2.91 ± 5%
427.0 ±1.0 157 3.73 ± 5%
454.0 ±1.0 157 4.17 ± 5%
143.0 ±1.0 207 0.227 ± 5%
160.0 ±1.0 207 0.352 ± 5%
193.0 ±1.0 207 0.591 ± 5%
223.0 ±1.0 207 0.887 ± 5%
253.5 ±1.0 207 1.14 ± 5%
295.0 ±1.0 207 1.64 ± 5%
327.0 ±1.0 207 1.96 ± 5%
364.0 ±1.0 207 2.40 ± 5%
427.0 ±1.0 207 3.24 ± 5%
454.0 ±1.0 207 3.60 ± 5%
Reference
1999B1 Buchhauser, J., Groß, T., Karger, N., Lüdemann, H.‐D.: J. Chem. Phys. 110 (1999) 3037–3042.

Diffusion of molybdenum hexafluoride 1
Diffusion of molybdenum hexafluoride

F6Mo molybdenum hexafluoride 7783-77-9

T [K] p [kPa] D · 109 [m2/s]
293.15 ± 1.0 101.325 2.8
301.15 ± 1.0 101.325 3.3
316.15 ± 1.0 101.325 4.7
319.15 ± 1.0 101.325 4.2
328.15 ± 1.0 101.325 5.45
341.15 ± 1.0 101.325 6.3
351.15 ± 1.0 101.325 7.7
Reference
1967R4 Rigny, P., Virlet, J.: J. Chem. Phys. 47 (1967) 4645–4652.

Diffusion of sulfur hexafluoride 1
Diffusion of sulfur hexafluoride

F6S sulfur hexafluoride 2551-62-4

T [K] p [kPa] D · 104 [m2/s]
250.0 101.325 0.0253
300.0 101.325 0.0360
273.15 101.325 0.0301
293.15 101.325 0.0344
313.15 101.325 0.0390
333.15 101.325 0.0437
353.15 101.325 0.0488
373.15 101.325 0.0540
423.15 101.325 0.0680
473.15 101.325 0.0830
523.15 101.325 0.0994
573.15 101.325 0.1166
623.15 101.325 0.1350
673.15 101.325 0.1544
723.15 101.325 0.1748
773.15 101.325 0.1960
873.15 101.325 0.2415
973.15 101.325 0.2903
1073.15 101.325 0.3426
1173.15 101.325 0.3982
1273.15 101.325 0.4571
1773.15 101.325 0.7968
2273.15 101.325 1.2079
2773.15 101.325 1.6855
3273.15 101.325 2.2238

T [K] p [kPa] D · 109 [m2/s]
223 ± 0.5 101.325 2.11 ± 5%
228 ± 0.5 101.325 2.41 ± 5%
233 ± 0.5 101.325 2.64 ± 5%
238 ± 0.5 101.325 2.82 ± 5%
243 ± 0.5 101.325 3.28 ± 5%
248 ± 0.5 101.325 3.44 ± 5%
253 ± 0.5 101.325 3.90 ± 5%
258 ± 0.5 101.325 4.21 ± 5%
263 ± 0.5 101.325 4.71 ± 5%
268 ± 0.5 101.325 4.84 ± 5%
273 ± 0.5 101.325 5.48 ± 5%
(continued)

2 Diffusion of sulfur hexafluoride
278 ± 0.5 101.325 5.83 ± 5%

283 ± 0.5 101.325 6.42 ± 5%
288 ± 0.5 101.325 6.92 ± 5%
293 ± 0.5 101.325 8.61 ± 5%
297 ± 0.5 101.325 8.95 ± 5%
303 ± 0.5 101.325 11.1 ± 5%
306 ± 0.5 101.325 11.2 ± 5%
309 ± 0.5 101.325 11.6 ± 5%
312 ± 0.5 101.325 12.6 ± 5%
315 ± 0.5 101.325 14.9 ± 5%
Comment: sample liquefied under pressure

Self Diffusion Coefficient D1s(T ); Method: NMR FG Ref.: 1980Z3
T [K] ρ [mol/cm3] D · 107 [m2/s]
323.15 0.4999 2.987 ± 0.013
323.15 1.0175 1.493 ± 0.004
323.15 1.5956 0.9669 ± 0.0020
323.15 2.1288 0.7288 ± 0.0028
323.15 2.8393 0.5466 ± 0.0013
323.15 2.973 0.5213 ± 0.0018
323.15 3.173 0.4896 ± 0.0011
323.15 3.402 0.4567 ± 0.0012
323.15 3.828 0.4055 ± 0.0011
323.15 3.916 0.3935 ± 0.0017
323.15 4.163 0.3692 ± 0.0007
323.15 4.579 0.3339 ± 0.0008
323.15 4.840 0.3135 ± 0.0007
323.15 5.239 0.2872 ± 0.0003
323.15 5.439 0.2743 ± 0.0007
323.15 5.572 0.2656 ± 0.0006
323.15 5.708 0.2581 ± 0.0003
323.15 5.772 0.2541 ± 0.0018
323.15 5.985 0.2414 ± 0.0005
323.15 6.164 0.2322 ± 0.0004
323.15 6.532 0.2120 ± 0.0004
323.15 7.095 0.1855 ± 0.0002
323.15 7.509 0.1681 ± 0.0001
323.15 8.111 0.1452 ± 0.0002
323.15 8.392 0.1360 ± 0.0002
323.15 8.597 0.1309 ± 0.0002
323.15 8.776 0.1238 ± 0.0001
323.15 9.131 0.1163 ± 0.0003

Diffusion of sulfur hexafluoride 3

Self Diffusion Coefficient D1s(T ); Method: NMR FG Ref.: 1975D3
T [K] ρ [g/cm3] D · 109 [m2/s]
296.0 ± 2.0 1.335 9.40 ± 6%
296.0 ± 2.0 1.50 7.70 ± 6%
296.0 ± 2.0 1.60 6.60 ± 6%
296.0 ± 2.0 1.70 5.23 ± 6%
296.0 ± 2.0 1.80 3.83 ± 6%
296.0 ± 2.0 1.90 2.32 ± 6%
398.0 ± 2.0 1.00 25.0 ± 6%
398.0 ± 2.0 1.10 21.0 ± 6%
398.0 ± 2.0 1.20 18.2 ± 6%
398.0 ± 2.0 1.30 15.4 ± 6%
398.0 ± 2.0 1.40 13.1 ± 6%
398.0 ± 2.0 1.50 11.1 ± 6%
398.0 ± 2.0 1.60 9.22 ± 6%
398.0 ± 2.0 1.70 7.58 ± 6%
398.0 ± 2.0 1.80 5.90 ± 6%
398.0 ± 2.0 1.85 4.94 ± 6%

Self Diffusion Coefficient D1s(T ); Method: NMR FG Ref.: 1971T6
T [K] p D · 109 [m2/s]
270.0 ± 0.01 p.sat 228.0 ± 6%
280.0 ± 0.01 p.sat 169.0 ± 6%
290.0 ± 0.01 p.sat 126.0 ± 6%
300.0 ± 0.01 p.sat 93.6 ± 6%
310.0 ± 0.01 p.sat 65.8 ± 6%
314.0 ± 0.01 p.sat 53.9 ± 6%
316.0 ± 0.01 p.sat 46.9 ± 6%
317.0 ± 0.01 p.sat 42.5 ± 6%
318.0 ± 0.01 p.sat 37.0 ± 6%
318.70 ± 0.01 p.sat 29.2 ± 6%
Comment: data at saturation pressure p.sat along coexistence curve

Self Diffusion Coefficient D1s(T ); Method: NMR FG Ref.: 1971T6
T [K] p [kPa] D · 109 [m2/s]
320.0 101.325 29.6 ± 6%
330.0 101.325 30.5 ± 6%
340.0 101.325 31.4 ± 6%
350.0 101.325 32.0 ± 6%
360.0 101.325 33.0 ± 6%
370.0 101.325 33.9 ± 6%
Comment: homogeneous fluid above critical temperature

4 Diffusion of sulfur hexafluoride
References
445–466.
1963H1 Hackleman, W.R., Hubbard, P.S.: J. Chem. Phys. 39 (1963) 2688–2693.
1980Z3 Zykov, P.G., Bogdanov, P.I., Raspopin, A.S.: Zh. Tekh. Fiz. 50 (1980) 606–609.
1975D3 DeZwaan, J., Jonas, J.: J. Chem. Phys. 63 (1975) 4606–4612.
1971T6 Tison, J.K., Hunt, E.R.: J. Chem. Phys. 54 (1971) 1526–1531.

Diffusion of uranium hexafluoride 1
Diffusion of uranium hexafluoride

F6U uranium hexafluoride 7783-81-5

T [K] p [kPa] D · 109 [m2/s]
340.15 ± 1.0 101.325 7.1
346.15 ± 1.0 101.325 9.1
355.15 ± 1.0 101.325 9.5
361.15 ± 1.0 101.325 10.1
366.15 ± 1.0 101.325 11.3
370.15 ± 1.0 101.325 13.2
371.15 ± 1.0 101.325 12.5
Reference

Diffusion of tungsten hexafluoride 1
Diffusion of tungsten hexafluoride

F6W tungsten hexafluoride 7783-82-6

T [K] p [kPa] D · 109 [m2/s]
281.15 ± 1.0 101.325 3.15
288.15 ± 1.0 101.325 3.2
301.15 ± 1.0 101.325 4.5
310.15 ± 1.0 101.325 4.65
328.15 ± 1.0 101.325 5.35
324.15 ± 1.0 101.325 5.55
336.15 ± 1.0 101.325 6.5
Reference

Diffusion of hydrogen 1
Diffusion of hydrogen
H2 hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
300.1 ± 0.5 101.325 1.24
350.2 ± 0.5 101.325 1.70
400.6 ± 0.5 101.325 2.01
460.2 ± 0.5 101.325 2.32
504.8 ± 0.5 101.325 2.76
556.9 ± 0.5 101.325 3.15
601.2 ± 0.5 101.325 3.60
660.8 ± 0.5 101.325 4.20
710.9 ± 0.5 101.325 4.52
760.3 ± 0.5 101.325 5.26
820.2 ± 0.5 101.325 5.70
830.3 ± 0.5 101.325 6.42
930.9 ± 0.5 101.325 7.24
1002.3 ± 0.5 101.325 7.90
1070.9 ± 0.5 101.325 8.60
Self Diffusion Coefficient D1s(T ); Method: INS Ref.: 1977C2
T [K] p [atm] D · 107 [m2/s]
293.0 1000 1.97 ± 0.19
293.0 1504 1.46 ± 0.13
293.0 1946 1.20 ± 0.10
78.0 130 0.88 ± 0.05
78.0 279 0.52 ± 0.03
78.0 500 0.36 ± 0.01
78.0 800 0.27 ± 0.01
78.0 1000 0.23 ± 0.01
T [K] p [MPa] D · 107 [m2/s]
274 ± 0.5 50 2.63 ± 2%
243 ± 0.5 50 2.33 ± 2%
213 ± 0.5 50 1.96 ± 2%
171 ± 0.5 50 1.39 ± 2%
334 ± 0.5 75 2.61 ± 2%
296 ± 0.5 75 2.14 ± 2%
274 ± 0.5 75 1.97 ± 2%
243 ± 0.5 75 1.74 ± 2%
213 ± 0.5 75 1.37 ± 2%
(continued)

2 Diffusion of hydrogen
171 ± 0.5 75 1.02 ± 2%

372 ± 0.5 100 2.57 ± 2%
334 ± 0.5 100 2.07 ± 2%
296 ± 0.5 100 1.77 ± 2%
274 ± 0.5 100 1.59 ± 2%
243 ± 0.5 100 1.44 ± 2%
213 ± 0.5 100 1.18 ± 2%
171 ± 0.5 100 0.85 ± 2%
372 ± 0.5 125 2.20 ± 2%
334 ± 0.5 125 1.84 ± 2%
296 ± 0.5 125 1.50 ± 2%
274 ± 0.5 125 1.37 ± 2%
243 ± 0.5 125 1.23 ± 2%
213 ± 0.5 125 1.02 ± 2%
171 ± 0.5 125 0.75 ± 2%
372 ± 0.5 150 1.95 ± 2%
334 ± 0.5 150 1.60 ± 2%
296 ± 0.5 150 1.35 ± 2%
274 ± 0.5 150 1.23 ± 2%
243 ± 0.5 150 1.09 ± 2%
213 ± 0.5 150 0.91 ± 2%
171 ± 0.5 150 0.66 ± 2%
372 ± 0.5 175 1.71 ± 2%
334 ± 0.5 175 1.45 ± 2%
296 ± 0.5 175 1.23 ± 2%
274 ± 0.5 175 1.14 ± 2%
243 ± 0.5 175 1.00 ± 2%
213 ± 0.5 175 0.83 ± 2%
171 ± 0.5 175 0.60 ± 2%
372 ± 0.5 200 1.57 ± 2%
334 ± 0.5 200 1.35 ± 2%
296 ± 0.5 200 1.14 ± 2%
274 ± 0.5 200 1.06 ± 2%
243 ± 0.5 200 0.92 ± 2%
213 ± 0.5 200 0.76 ± 2%
171 ± 0.5 200 0.56 ± 2%
Self Diffusion Coefficient D1s(T ); Method: NMR FG Ref.: 1962L1
T [K] p [kPa] D · 104 [m2/s]
55.5 ± 0.4 101.325 0.0736 ± 8%
77.5 ± 0.2 101.325 0.133 ± 8%
90.3 ± 0.2 101.325 0.192 ± 8%

Diffusion of hydrogen 3
Equation: D = A · exp[ B/T ] Range: 14 < T/K < 20
10.0 –46
8.58 ± 0.98 89.0 ± 3.4
References
32–38.
1977C2 Chen, S.H., Postol, T.A., Skold, K.: Phys. Rev. A 16 (1977) 2112–2119.
2001C2 Chen, L., Gross, T., Krienke, H., Ludemann, H.D.: Phys. Chem. Chem. Phys. 3 (2001)
2025–2030.
1962L1 Lipsicas, M.: J. Chem. Phys. 36 (1962) 1235–1237.
1960H1 Hass, W.P.A., Seidel, G., Poulis, N.J.: Physica 26 (1960) 834–852.
1977O1 O´Reilly, D.E., Peterson, E.M.: J. Chem. Phys. 66 (1977) 934–937.

Diffusion of water 1
Diffusion of water
H 2O water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
318.15 101.325 3.58 ± 0.05
H 2O water 7732-18-5
Self Diffusion Coefficient D1s(T ); Method: NMR FG Ref.: 1981L2
T [K] p [bar] D · 109 [m2/s]
673.15 199 286.0 ± 10%
673.15 221 243.0 ± 10%
673.15 241 213.0 ± 10%
673.15 265 161.0 ± 10%
673.15 280 120.0 ± 10%
673.15 291 112.0 ± 10%
673.15 314 89.7 ± 10%
673.15 378 70.0 ± 10%
673.15 565 57.1 ± 10%
673.15 1056 47.4 ± 10%
773.15 256 326.0 ± 10%
773.15 314 251.0 ± 10%
773.15 359 213.0 ± 10%
773.15 403 189.0 ± 10%
773.15 491 141.0 ± 10%
773.15 551 125.0 ± 10%
773.15 691 95.6 ± 10%
773.15 910 74.5 ± 10%
773.15 1313 61.7 ± 10%
873.15 336 361.0 ± 10%
873.15 403 282.0 ± 10%
873.15 467 242.0 ± 10%
873.15 584 194.0 ± 10%
873.15 696 156.0 ± 10%
873.15 809 125.0 ± 10%
873.15 1074 97.0 ± 10%
873.15 1459 76.4 ± 10%
973.15 397 471.0 ± 10%
973.15 480 346.0 ± 10%
973.15 568 285.0 ± 10%
973.15 731 226.0 ± 10%
973.15 893 172.0 ± 10%
973.15 1060 155.0 ± 10%
973.15 1455 108.0 ± 10%
Comment: compressed supercritical water

2 Diffusion of water
References
1980H1 Harris, K.R., Trappeniers, N.J.: Physica A 104 (1980) 262–280.
1981L2 Lamb, W.J., Hoffman, G.A., Jonas, J.: J. Chem. Phys. 74 (1981) 6875–6880.

Diffusion of ammonia 1
Diffusion of ammonia
H 3N ammonia 7664-41-7
T [K] p [kPa] D · 104 [m2/s]
301.3 ± 0.02 101.325 0.200 ± 0.001
326.4 ± 0.02 101.325 0.233 ± 0.002
348.7 ± 0.02 101.325 0.268 ± 0.001
373.8 ± 0.02 101.325 0.308 ± 0.003
397.3 ± 0.02 101.325 0.343 ± 0.002
422.9 ± 0.02 101.325 0.399 ± 0.003
445.6 ± 0.02 101.325 0.441 ± 0.001
T [K] p [MPa] D · 109 [m2/s]
203.0 ± 0.5 10 2.61 ± 2%
213.0 ± 0.5 10 3.40 ± 2%
223.0 ± 0.5 10 4.13 ± 2%
243.0 ± 0.5 10 6.02 ± 2%
273.0 ± 0.5 10 9.30 ± 2%
298.5 ± 0.5 10 12.8 ± 2%
332.0 ± 0.5 10 19.8 ± 2%
373.0 ± 0.5 10 49.2 ± 2%
203.0 ± 0.5 50 2.37 ± 2%
213.0 ± 0.5 50 2.93 ± 2%
223.0 ± 0.5 50 3.69 ± 2%
243.0 ± 0.5 50 5.29 ± 2%
273.0 ± 0.5 50 8.10 ± 2%
298.5 ± 0.5 50 11.1 ± 2%
332.0 ± 0.5 50 16.7 ± 2%
373.0 ± 0.5 50 25.6 ± 2%
423.0 ± 0.5 50 39.5 ± 2%
473.0 ± 0.5 50 53.0 ± 2%
373.0 ± 0.5 75 22.1 ± 2%
423.0 ± 0.5 75 31.4 ± 2%
473.0 ± 0.5 75 43.4 ± 2%
203.0 ± 0.5 100 1.90 ± 2%
213.0 ± 0.5 100 2.54 ± 2%
223.0 ± 0.5 100 3.03 ± 2%
243.0 ± 0.5 100 4.61 ± 2%
273.0 ± 0.5 100 7.01 ± 2%
298.5 ± 0.5 100 9.50 ± 2%
332.0 ± 0.5 100 14.2 ± 2%
373.0 ± 0.5 100 20.1 ± 2%
423.0 ± 0.5 100 28.9 ± 2%
(continued)
2 Diffusion of ammonia
473.0 ± 0.5 100 38.5 ± 2%

203.0 ± 0.5 150 1.67 ± 2%
213.0 ± 0.5 150 2.23 ± 2%
223.0 ± 0.5 150 2.77 ± 2%
243.0 ± 0.5 150 4.10 ± 2%
273.0 ± 0.5 150 6.20 ± 2%
298.5 ± 0.5 150 8.31 ± 2%
332.0 ± 0.5 150 12.3 ± 2%
373.0 ± 0.5 150 17.2 ± 2%
423.0 ± 0.5 150 24.5 ± 2%
473.0 ± 0.5 150 32.1 ± 2%
213.0 ± 0.5 200 1.88 ± 2%
223.0 ± 0.5 200 2.39 ± 2%
243.0 ± 0.5 200 3.56 ± 2%
273.0 ± 0.5 200 5.57 ± 2%
298.5 ± 0.5 200 7.65 ± 2%
332.0 ± 0.5 200 10.9 ± 2%
373.0 ± 0.5 200 15.2 ± 2%
423.0 ± 0.5 200 21.8 ± 2%
473.0 ± 0.5 200 30.1 ± 2%
Self Diffusion Coefficient D1s(T ); Method: NMR FG Ref.: 1961M3
T [K] p [kPa] D · 109 [m2/s]
240.15 101.325 5.71
239.15 101.325 5.75
238.15 101.325 5.37
231.15 101.325 5.00
223.15 101.325 4.14
216.15 101.325 3.56
215.15 101.325 3.57
207.15 101.325 2.90
199.15 101.325 2.33
199.15 101.325 2.41
Self Diffusion Coefficient D1s(T ); Method: TB Ref.: 1966P4
T [K] p [kPa] D · 104 [m2/s]
233 101.325 0.108 ± 0.004
273 101.325 0.115 ± 0.003
313 101.325 0.209 ± 0.003
353 101.325 0.269 ± 0.003
References
1970B1 Baker, C.E.: J. Chem. Phys. 52 (1970) 2159–2161.
1997G2 Groß, T., Buchhauser, J., Price, W.E., Tarassov, I.N., Lüdemann, H.‐D.: J. Mol. Liq. 73‐74
(1997) 433–444.

Diffusion of ammonia 3
1961M3 Mccall, D.W., Douglass, D.C., Anderson, E.W.: Phys. Fluids 4 (1961) 1317–1318.
1966P4 Paul, R., Watson, W.W.: J. Chem. Phys. 45 (1966) 2675–2677.

Diffusion of helium 1
Diffusion of helium
He helium 7440-59-7
Self Diffusion Coefficient D1s(T ); Method: CORR Ref.: 1984K4
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0888
100.0 101.325 0.2874
150.0 101.325 0.5669
200.0 101.325 0.9188
250.0 101.325 1.3378
300.0 101.325 1.8200
273.15 101.325 1.5534
293.15 101.325 1.7503
313.15 101.325 1.9569
333.15 101.325 2.1731
353.15 101.325 2.3986
373.15 101.325 2.6333
423.15 101.325 3.2597
473.15 101.325 3.9411
523.15 101.325 4.6761
573.15 101.325 5.4632
623.15 101.325 6.3014
673.15 101.325 7.1895
723.15 101.325 8.1266
773.15 101.325 9.1119
873.15 101.325 11.2242
973.15 101.325 13.5207
1073.15 101.325 15.9970
1173.15 101.325 18.6491
1273.15 101.325 21.4733
1773.15 101.325 38.0791
2273.15 101.325 58.6286
2773.15 101.325 82.9239
3273.15 101.325 110.8216
He helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
290.0 ± 0.5 101.325 1.04
340.2 ± 0.5 101.325 1.36
390.4 ± 0.5 101.325 1.62
450.6 ± 0.5 101.325 2.08
502.1 ± 0.5 101.325 2.40
560.0 ± 0.5 101.325 2.82
600.2 ± 0.5 101.325 3.10
(continued)

2 Diffusion of helium
650.4 ± 0.5 101.325 3.50

700.2 ± 0.5 101.325 3.90
750.3 ± 0.5 101.325 4.40
802.4 ± 0.5 101.325 4.80
860.4 ± 0.5 101.325 5.32
903.0 ± 0.5 101.325 5.76
954.0 ± 0.5 101.325 6.40
1002.6 ± 0.5 101.325 6.84
He helium 7440-59-7
Self Diffusion Coefficient D1s(T ); Method: INT Ref.: 1995K8
T [K] p [kPa] D · 104 [m2/s]
295.0 101.325 1.26 ± 0.06
References
Data 13 (1984) 229–303.
32–38.
1995K8 Kosov, N.D., Poyarkov, I.V.: Meas. Tech. (English Transl.) 38 (1995) 1394–1396.

Diffusion of krypton 1
Diffusion of krypton
Kr krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0032
100.0 101.325 0.0116
150.0 101.325 0.0255
200.0 101.325 0.0448
250.0 101.325 0.0693
300.0 101.325 0.0984
273.15 101.325 0.0822
293.15 101.325 0.0941
313.15 101.325 0.1067
333.15 101.325 0.1200
353.15 101.325 0.1340
373.15 101.325 0.1486
423.15 101.325 0.1878
473.15 101.325 0.2307
523.15 101.325 0.2771
573.15 101.325 0.3268
623.15 101.325 0.3797
673.15 101.325 0.4356
723.15 101.325 0.4945
773.15 101.325 0.5562
873.15 101.325 0.6878
973.15 101.325 0.8297
1073.15 101.325 0.9814
1173.15 101.325 1.1427
1273.15 101.325 1.3131
1773.15 101.325 2.2940
2273.15 101.325 3.4784
2773.15 101.325 4.8714
3273.15 101.325 6.4705
T [K] p [kPa] D · 106 [m2/s]
297.15 ± 0.5 101.325 9.6 ± 0.7
297.15 ± 0.5 101.325 9.8 ± 0.2
Comment: graduate experiment using neutron generator

2 Diffusion of krypton
T [K] p [MPa] D · 106 [m2/s]
336 0.80 1.7 ± 0.15
Self Diffusion Coefficient D1s(T ); Method: Non Stand Ref.: 1970C6
T [K] p [kPa] D · 109 [m2/s]
109.29 101.325 1.9
111 101.325 2.2
Comment: isotope exchange between solid Kr and vapor
T [K] p [bar] D · 106 [m2/s]
293.15 ± 0.05 30.083 0.2984 ± 0.0011
T [K] p [atm] D · 108 [m2/s]
220.5 ± 0.02 5.46 95.0 ± 3.8
220.55 ± 0.02 5.65 77.5 ± 3.1
222.53 ± 0.02 9.37 55.2 ± 2.9
220.4 ± 0.02 9.76 53.9 ± 2.0
220.12 ± 0.02 11.987 40.6 ± 5.4
220.00 ± 0.02 11.913 41.4 ± 5.3
221.40 ± 0.02 17.242 29.6 ± 2.0
220.55 ± 0.02 17.98 29.1 ± 0.9
220.30 ± 0.02 18.499 26.2 ± 2.3
220.42 ± 0.02 18.485 25.2 ± 2.1
220.50 ± 0.02 19.18 26.7 ± 0.9
221.40 ± 0.02 23.566 20.4 ± 1.3
219.35 ± 0.02 23.555 18.7 ± 1.0
219.40 ± 0.02 23.834 17.1 ± 0.9
219.30 ± 0.02 31.553 13.4 ± 0.6
219.50 ± 0.02 31.732 14.4 ± 0.6
221.51 ± 0.02 34.65 12.5 ± 0.7
221.50 ± 0.02 34.908 12.7 ± 0.8
218.8 ± 0.02 38.403 11.1 ± 0.6
219.95 ± 0.02 39.746 11.3 ± 0.5
219.80 ± 0.02 39.618 11.0 ± 0.6
220.4 ± 0.02 43.858 9.45 ± 0.40
220.32 ± 0.02 43.933 8.75 ± 0.41
219.9 ± 0.02 52.486 6.87 ± 0.27

T [K] p [atm] D · 108 [m2/s]
274.15 ± 0.02 15.128 48.1 ± 4.9
273.10 ± 0.02 15.181 52.6 ± 7.1
273.10 ± 0.02 15.397 52.2 ± 6.1
273.35 ± 0.02 21.495 39.9 ± 8.7
273.45 ± 0.02 36.570 21.0 ± 1.3
273.25 ± 0.02 39.45 17.5 ± 1.3
273.35 ± 0.02 47.79 14.3 ± 0.8
273.55 ± 0.02 51.047 14.4 ± 0.7
273.15 ± 0.02 51.065 14.5 ± 0.8
273.20 ± 0.02 56.221 12.4 ± 0.51
273.35 ± 0.02 65.114 10.1 ± 0.40
273.3 ± 0.02 74.76 8.79 ± 0.42
273.5 ± 0.02 77.33 7.86 ± 0.32
272.80 ± 0.02 87.745 8.31 ± 0.33
273.15 ± 0.02 92.26 7.03 ± 0.29
T [K] p [atm] D · 108 [m2/s]
232.99 ± 0.02 65.83 5.69 ± 0.34
232.97 ± 0.02 64.80 6.08 ± 0.35
233.04 ± 0.02 87.45 3.22 ± 0.17
222.80 ± 0.02 52.36 6.66 ± 0.65
223.3 ± 0.02 71.0 3.69 ± 0.20
222.80 ± 0.02 70.37 3.61 ± 0.24
218.31 ± 0.02 83.04 1.82 ± 0.09
218.34 ± 0.02 82.60 1.93 ± 0.08
218.38 ± 0.02 98.88 1.66 ± 0.06
218.34 ± 0.02 76.07 2.36 ± 0.12
218.36 ± 0.02 72.86 2.47 ± 0.16
218.35 ± 0.02 68.88 3.03 ± 0.21
210.01 ± 0.02 84.4 1.37 ± 0.07
210.08 ± 0.02 85.4 1.29 ± 0.06
210.20 ± 0.02 111.28 1.12 ± 0.06
199.55 ± 0.02 97.45 0.92 ± 0.04
183.6 ± 0.02 94.3 0.615 ± 0.026
183.57 ± 0.02 97.35 0.646 ± 0.020
222.29 ± 0.02 101.5 1.51 ± 0.07
220.25 ± 0.02 82.22 2.04 ± 0.11
220.24 ± 0.02 72.89 2.79 ± 0.15
220.22 ± 0.02 62.39 4.62 ± 0.39
220.18 ± 0.02 70.68 3.37 ± 0.16
220.21 ± 0.02 71.20 3.12 ± 0.18
220.21 ± 0.02 68.27 3.62 ± 0.40

T [K] p [atm] D · 106 [m2/s]
293.0 ± 0.1 8.438 1.127 ± 0.0051
293.0 ± 0.1 9.877 0.9717 ± 0.0040
293.0 ± 0.1 11.188 0.8469 ± 0.0039
293.0 ± 0.1 12.504 0.7537 ± 0.0038
293.0 ± 0.1 14.932 0.6295 ± 0.0019
293.0 ± 0.1 16.273 0.5753 ± 0.0007
293.0 ± 0.1 17.50 0.5325 ± 0.0009
293.0 ± 0.1 18.79 0.4896 ± 0.0008
293.0 ± 0.1 20.90 0.4401 ± 0.0008
293.0 ± 0.1 21.70 0.4137 ± 0.0005
293.0 ± 0.1 22.20 0.4116 ± 0.0015
293.0 ± 0.1 22.87 0.3981 ± 0.0008
293.0 ± 0.1 24.53 0.3688 ± 0.0006
293.0 ± 0.1 27.50 0.3269 ± 0.0006
293.0 ± 0.1 30.35 0.2929 ± 0.0006
Self Diffusion Coefficient D1s(T ); Method: PF Ref.: 1962D3
T [K] p [atm] D · 107 [m2/s]
308.15 7.458 13.71
308.15 15.48 6.718
308.15 29.53 3.413
308.15 67.41 1.393
308.15 96.27 0.9376
308.15 110.08 0.8147
308.15 134.85 0.6358
308.15 187.86 0.4178
308.15 227.9 0.3446
Comment: diffusion of 85Kr in Kr; ionization cell – porous ceramic plug
Self Diffusion Coefficient D1s(T ); Method: PF Ref.: 1962D3
T [K] p [atm] D · 107 [m2/s]
308.15 3.649 2.765
308.15 3.807 2.622
308.15 7.463 1.317
308.15 15.50 0.6487
Comment: diffusion of 85Kr in Kr; ionization cell – glass capillary porous plug
T [K] p [kPa] D · 104 [m2/s]
232 101.325 0.0570
(continued)

243 101.325 0.0619

273 101.325 0.0759
288 101.325 0.0861
295 101.325 0.090
295 101.325 0.097
343 101.325 0.130
414 101.325 0.188
470 101.325 0.249
Comment: data of unknown accuracy
T [K] p [kPa] D · 104 [m2/s]
195.7 101.325 0.0427 ± 2%
305.2 101.325 0.104 ± 2%
366.5 101.325 0.144 ± 2%
479.7 101.325 0.233 ± 2%
717.5 101.325 0.484 ± 2%
1036.1 101.325 0.934 ± 2%
T [K] p [kPa] D · 104 [m2/s]
232 101.325 0.065
243 101.325 0.072
273 101.325 0.084
288 101.325 0.095
296 101.325 0.099
295 101.325 0.101
343 101.325 0.135
414 101.325 0.194
470 101.325 0.254
T [K] p [kPa] D · 104 [m2/s]
302.6 101.325 0.0971 ± 0.016
Self Diffusion Coefficient D1s(T ); Method: CT Ref.: 1972H7
Equation: D = A · exp[ –B / (RT)]
3.0 ± 2.0 4800.0 ± 200
2 –4
Comment: D1s [m /s] = D · 10 ; solid phase

3.1 ± 2.1 5010.0 ± 220.0
Comment: D1s [m2/s] = D · 10–4; solid phase
Parameter: A · 105 [cm2/s] B [cal/mol]
103.0 ± 17 930.0 ± 40.0
Comment: D1s [m2/s] = D · 10–4; liquid phase
Self Diffusion Coefficient D1s(T ); Method: Non-Standard Ref.: 1968C6
3.0 4800
8.48 0.48 405
39.1 0.37 414
Equation: D = A ((T ) / B)C Range: 230 < T/K < 470
Parameter: A · 106 B C Std-Dev
1.74 1.000 1.93 2.0%
References
Data 13 (1984) 229–303.
1976B4 Benenson, R.E., Rimawi, K., Chaitin, M., Goldenberg, S., Kaplan, D.: Am. J. Phys. 44 (1976)
1089–1093.
1970C6 Chadwick, A.V., Morrison, J.A.: Phys. Rev. B 1 (1970) 2748–2753.
1977C5 Codastefano, P., DiRusso, A., Zanza, V.: Rev. Sci. Instrum. 48 (1977) 1650–1653.
1976C3 Carelli, P., De Santis, A., Modena, I., Ricci, F.P.: Phys. Rev. A 13 (1976) 1131–1139.
1973C5 Carelli, P., Modena, I., Ricci, F.P.: Phys. Rev. A 7 (1973) 298–303.
1978C4 Codastefano, P., Ricci, M.A., Zanza, V.: Physica A 92 (1978) 315–322.

1962D3 Durbin, L., Kobayashi, R.: J. Chem. Phys. 37 (1962) 1643–1654.

1970W1 Weissman, Stanley, DuBro, G.A.: Phys. Fluids 13 (1970) 2689–2692.
1963W2 Wendt, R.P., Mundy, J.N., Weissman, S., Mason, E.A.: Phys. Fluids 6 (1963) 572–578.
1964W2 Watts, H.: Trans. Faraday Soc. 60 (1964) 1745–1751.
1976C8 Cowgill, D.F., Norberg, R.E.: Phys. Rev. B 13 (1976) 2773–2781.
1968C6 Chadwick, A.V., Morrison, J.A.: Phys. Rev. Lett. 21 (1968) 1803–1805.

Diffusion of nitrogen oxide 1
Diffusion of nitrogen oxide

NO nitrogen oxide 10102-43-9

T [K] p [kPa] D · 104 [m2/s]
150.0 101.325 0.0593
200.0 101.325 0.1026
250.0 101.325 0.15465
300.0 101.325 0.2145
273.15 101.325 0.1815
293.15 101.325 0.2059
313.15 101.325 0.2315
333.15 101.325 0.2583
353.15 101.325 0.2861
373.15 101.325 0.3151
423.15 101.325 0.3919
473.15 101.325 0.4749
523.15 101.325 0.5640
573.15 101.325 0.6588
623.15 101.325 0.7591
673.15 101.325 0.8650
723.15 101.325 0.9761
773.15 101.325 1.0924
873.15 101.325 1.3400
973.15 101.325 1.6073
1073.15 101.325 1.8934
1173.15 101.325 2.1982
1273.15 101.325 2.5208
1773.15 101.325 4.4252
2273.15 101.325 6.8311
2773.15 101.325 9.6931
3273.15 101.325 12.9766
Comment: data review; erratum: present data are corrected
Reference
445–466.

Diffusion of nitrogen 1
Diffusion of nitrogen
N2 nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
100.0 101.325 0.0279 ± 1%
150.0 101.325 0.0313 ± 1%
200.0 101.325 0.1041 ± 1%
250.0 101.325 0.15525 ± 1%
300.0 101.325 0.2138 ± 1%
273.15 101.325 0.1815 ± 1%
293.15 101.325 0.2054 ± 1%
313.15 101.325 0.2304 ± 1%
333.15 101.325 0.2564 ± 1%
353.15 101.325 0.2835 ± 1%
373.15 101.325 0.3117 ± 1%
423.15 101.325 0.3864 ± 1%
473.15 101.325 0.4672 ± 1%
523.15 101.325 0.5538 ± 1%
573.15 101.325 0.6459 ± 1%
623.15 101.325 0.7435 ± 1%
673.15 101.325 0.8464 ± 1%
723.15 101.325 0.9545 ± 1%
773.15 101.325 1.0677 ± 1%
873.15 101.325 1.3091 ± 1%
973.15 101.325 1.5698 ± 1%
1073.15 101.325 1.8493 ± 1%
1173.15 101.325 2.1472 ± 1%
1273.15 101.325 2.4635 ± 1%
1773.15 101.325 4.3184 ± 1%
2273.15 101.325 6.61825 ± 1%
2773.15 101.325 9.3474 ± 1%
3273.15 101.325 12.4924 ± 1%
T [K] p [kPa] D · 104 [m2/s]
273.15 101.325 0.1811
298.15 101.325 0.2112
358.15 101.325 0.2845

2 Diffusion of nitrogen
T [K] p [kPa] D · 104 [m2/s]
300.4 ± 0.5 101.325 0.20
350.6 ± 0.5 101.325 0.26
400.7 ± 0.5 101.325 0.32
451.2 ± 0.5 101.325 0.36
500.8 ± 0.5 101.325 0.44
559.0 ± 0.5 101.325 0.50
600.4 ± 0.5 101.325 0.58
652.0 ± 0.5 101.325 0.62
700.6 ± 0.5 101.325 0.80
800.9 ± 0.5 101.325 0.86
854.0 ± 0.5 101.325 0.94
900.2 ± 0.5 101.325 1.02
970.2 ± 0.5 101.325 1.12
1000.8 ± 0.5 101.325 1.20
References
445–466.
32–38.

Diffusion of nitrogen-(15-N) 1
Diffusion of nitrogen-(15-N)
N2 nitrogen-(15-N) 29817-79-6
T [K] p [kPa] D · 109 [m2/s]
77.3 101.325 2.60 ± 0.23
Comment: liquid phase
N2 nitrogen-(15-N) 29817-79-6
Equation: D = A · exp[ B/T ] Range: 77.3 < T/K < 93
238.0 –350.0
Comment: liquid phase
Reference
1974K10 Krynicki, K., Rahkamaa, E.J., Powles, J.G.: Mol. Phys. 28 (1974) 853–855.

Diffusion of nitrous oxide 1
Diffusion of nitrous oxide

N 2O nitrous oxide 10024-97-2

T [K] p [kPa] D · 104 [m2/s]
300.0 101.325 0.1184
273.15 101.325 0.0983
293.15 101.325 0.1131
313.15 101.325 0.1287
333.15 101.325 0.1452
353.15 101.325 0.1625
373.15 101.325 0.1805
423.15 101.325 0.2288
473.15 101.325 0.2814
523.15 101.325 0.3382
573.15 101.325 0.3989
623.15 101.325 0.4633
673.15 101.325 0.5313
723.15 101.325 0.6030
773.15 101.325 0.6779
873.15 101.325 0.8376
973.15 101.325 1.0101
1073.15 101.325 1.1944
1173.15 101.325 1.3904
1273.15 101.325 1.5977
1773.15 101.325 2.7935
2273.15 101.325 4.2368
2773.15 101.325 5.9110
3273.15 101.325 7.7993
Reference
445–466.

Diffusion of neon 1
Diffusion of neon
Ne neon 7440-01-9
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0206
100.0 101.325 0.0766
150.0 101.325 0.1589
200.0 101.325 0.2627
250.0 101.325 0.3851
300.0 101.325 0.5245
273.15 101.325 0.4476
293.15 101.325 0.5045
313.15 101.325 0.5639
333.15 101.325 0.6258
353.15 101.325 0.6901
373.15 101.325 0.7570
423.15 101.325 0.9345
473.15 101.325 1.1268
523.15 101.325 1.3328
573.15 101.325 1.5518
623.15 101.325 1.7835
673.15 101.325 2.0277
723.15 101.325 2.2842
773.15 101.325 2.5527
873.15 101.325 3.1256
973.15 101.325 3.7451
1073.15 101.325 4.4100
1173.15 101.325 5.1194
1273.15 101.325 5.8722
1773.15 101.325 10.2579
2273.15 101.325 15.6205
2773.15 101.325 21.8983
3273.15 101.325 29.0462
Ne neon 7440-01-9
T [K] p [kPa] D · 104 [m2/s]
77.4 ± 0.2% 101.325 0.0499 ± 2%
300.2 ± 0.2% 101.325 0.516 ± 2%
446.3 ± 0.2% 101.325 1.01 ± 2%
573.0 ± 0.2% 101.325 1.54 ± 2%
(continued)

2 Diffusion of neon
597.3 ± 0.2% 101.325 1.61 ± 2%

738.0 ± 0.2% 101.325 2.31 ± 2%
1200.5 ± 0.2% 101.325 5.17 ± 2%
1400.0 ± 0.2% 101.325 6.72 ± 2%
Ne neon 7440-01-9
Parameter: A · 104 [cm2/s] B [cal/mol]
6.6 ± 2.0 211.0 ± 15.0
Ne neon 7440-01-9
0.12 ± 0.10 947.0 ± 38.0
Ne neon 7440-01-9
Self Diffusion Coefficient D1s(T ); Method: OEC Ref.: 1971B6
Parameter: A · 105 [cm2/s] B [K] Std-Dev
84.2 ± 2.8 –113.0 ± 7.0 5%
Ne neon 7440-01-9
Self Diffusion
Coefficient D1s(T ); Method: OEC Ref.: 1971B6
Equation: D = A · exp[B · p] Range: 10 < p/atm < 100
Parameter: T [K] A · 105 [cm2/s] B · 103 [atm–1] Std-Dev
37.0 4.2 ± 0.3 –3.6 ± 0.8 5%
27.0 1.30 ± 0.05 –2.5 ± 0.8 5%
References
Data 13 (1984) 229–303.
1973W2 Weissman, S.: Phys. Fluids 16 (1973) 1425–1428.
1971B6 Bewilogua, L., Gladun, C., Kubsch, B.: J. Low Temp. Phys. 4 (1971) 299–303.

Diffusion of oxygen 1
Diffusion of oxygen
O2 oxygen 7782-44-7
T [K] p [kPa] D · 104 [m2/s]
150.0 101.325 0.0606
200.0 101.325 0.1045
250.0 101.325 0.1572
300.0 101.325 0.2179
273.15 101.325 0.1845
293.15 101.325 0.2092
313.15 101.325 0.2352
333.15 101.325 0.2623
353.15 101.325 0.2904
373.15 101.325 0.3197
423.15 101.325 0.3975
473.15 101.325 0.4815
523.15 101.325 0.5717
573.15 101.325 0.6676
623.15 101.325 0.7692
673.15 101.325 0.8762
723.15 101.325 0.9887
773.15 101.325 1.1064
873.15 101.325 1.3570
973.15 101.325 1.6276
1073.15 101.325 1.9174
1173.15 101.325 2.2259
1273.15 101.325 2.5525
1773.15 101.325 4.4740
2273.15 101.325 6.8604
2773.15 101.325 9.6640
3273.15 101.325 12.8518
O2 oxygen 7782-44-7
Self Diffusion Coefficient D1s(T ); Method: PF Ref.: 1978R2
T [K] p [kPa] D · 106 [m2/s]
303 101.325 0.38 ± 0.002
References
445–466.
1978R2 Rastogi, R.P., Mishra, B.: J. Phys. Chem. 82 (1978) 2341–2346.

Diffusion of xenon 1
Diffusion of xenon
Xe xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0019
100.0 101.325 0.0069
150.0 101.325 0.0149
200.0 101.325 0.0260
250.0 101.325 0.0403
300.0 101.325 0.0576
273.15 101.325 0.0479
293.15 101.325 0.0551
313.15 101.325 0.0627
333.15 101.325 0.0707
353.15 101.325 0.0792
373.15 101.325 0.0880
423.15 101.325 0.1120
473.15 101.325 0.1385
523.15 101.325 0.1673
573.15 101.325 0.1983
623.15 101.325 0.2314
673.15 101.325 0.2666
723.15 101.325 0.3037
773.15 101.325 0.3428
873.15 101.325 0.4265
973.15 101.325 0.5171
1073.15 101.325 0.6142
1173.15 101.325 0.7177
1273.15 101.325 0.8272
1773.15 101.325 1.4582
2273.15 101.325 2.2168
2773.15 101.325 3.0935
3273.15 101.325 4.0846
Xe xenon 7440-63-3
T [K] p [kPa] D · 106 [m2/s]
297.15 ± 0.5 101.325 5.66 ± 0.17
297.15 ± 0.5 101.325 5.5 ± 0.2
297.15 ± 0.5 101.325 6.33 ± 0.15
Comment: graduate experiment using neutron generator

2 Diffusion of xenon
Xe xenon 7440-63-3
Self Diffusion Coefficient D1s(T ); Method: NMR FG Ref.: 1963Y1
T [K] p [kPa] D · 1010 [m2/s]
160 101.325 6.62
154 101.325 2.62
148 101.325 1.02
143 101.325 0.411
138 101.325 0.158
133 101.325 0.0636
129 101.325 0.0248
125 101.325 0.0130
Comment: measurements in solid Xe
Xe xenon 7440-63-3
248.00 ± 0.005 425.0 0.06145
248.00 ± 0.005 390.0 0.07683
273.00 ± 0.005 330.86 0.1218
273.00 ± 0.005 350.33 0.1093
273.00 ± 0.005 400.18 0.08024
273.00 ± 0.005 450.11 0.05695
298.00 ± 0.005 25.020 2.054
298.00 ± 0.005 50.062 1.038
298.00 ± 0.005 75.160 0.7007
298.00 ± 0.005 100.38 0.5340
298.00 ± 0.005 120.75 0.4479
298.00 ± 0.005 141.59 0.3841
298.00 ± 0.005 162.35 0.3341
298.00 ± 0.005 183.10 0.2940
298.00 ± 0.005 203.09 0.2611
298.00 ± 0.005 222.32 0.2340
298.00 ± 0.005 241.64 0.2111
298.00 ± 0.005 261.19 0.1910
298.00 ± 0.005 280.67 0.1729
298.00 ± 0.005 300.48 0.1552
298.00 ± 0.005 320.36 0.1403
298.00 ± 0.005 340.29 0.1252
298.00 ± 0.005 360.21 0.1114
298.00 ± 0.005 380.17 0.09930
298.00 ± 0.005 400.15 0.08775
298.00 ± 0.005 425.13 0.07398
298.00 ± 0.005 450.10 0.06224
298.00 ± 0.005 475.09 0.05141
343.00 ± 0.005 100.15 0.6080
343.00 ± 0.005 150.95 0.4030
343.00 ± 0.005 200.40 0.2973
343.00 ± 0.005 250.34 0.2264
(continued)
Diffusion of xenon 3
343.00 ± 0.005 300.23 0.1746

343.00 ± 0.005 375.13 0.1149
343.00 ± 0.005 400.11 0.09941
343.00 ± 0.005 425.10 0.08568
343.00 ± 0.005 450.08 0.07253
343.00 ± 0.005 460.08 0.06738
Comment: Xenon-129 isotope; accuracy: ±1%
Xe xenon 7440-63-3
273.15 ± 0.005 20.015 2.383
273.15 ± 0.005 30.036 1.583
273.15 ± 0.005 40.059 1.213
273.15 ± 0.005 50.088 0.9722
273.15 ± 0.005 60.154 0.8166
298.00 ± 0.005 10.009 5.228
298.00 ± 0.005 20.013 2.593
298.00 ± 0.005 40.044 1.306
298.00 ± 0.005 50.062 1.042
298.00 ± 0.005 60.096 0.8647
298.00 ± 0.005 70.136 0.7517
298.00 ± 0.005 80.188 0.6667
298.00 ± 0.005 100.38 0.5385
343.00 ± 0.005 20.011 2.963
343.00 ± 0.005 30.020 1.985
343.00 ± 0.005 40.030 1.494
343.00 ± 0.005 50.042 1.199
343.00 ± 0.005 60.057 1.005
343.00 ± 0.005 70.076 0.8723
343.00 ± 0.005 80.098 0.7645
343.00 ± 0.005 90.123 0.6859
343.00 ± 0.005 100.15 0.6230
343.00 ± 0.005 115.20 0.5363
343.00 ± 0.005 130.25 0.4736
343.00 ± 0.005 150.32 0.4097
Xe xenon 7440-63-3
203.00 ± 0.005 5460.1 0.3718
223.00 ± 0.005 5460.1 0.4125
243.00 ± 0.005 5460.1 0.4534
263.00 ± 0.005 5460.1 0.4958
283.00 ± 0.005 5460.1 0.5400
303.00 ± 0.005 5460.1 0.5815
(continued)
4 Diffusion of xenon
323.00 ± 0.005 5460.1 0.6263

343.00 ± 0.005 5460.1 0.6739
Xe xenon 7440-63-3
Self Diffusion Coefficient D1s(T ); Method: TB Ref.: 1972H8
T [K] p [kPa] D · 104 [m2/s]
300.45 101.325 0.0576
Xe xenon 7440-63-3
Equation: D = A · exp[ –B / (RT)]
7.3 ± 0.20 7400.0 ± 50.0
Xe xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
302.6 101.325 0.0600
Xe xenon 7440-63-3
8.20 0.70 607
41.8 0.57 614
References
Data 13 (1984) 229–303.
1976B4 Benenson, R.E., Rimawi, K., Chaitin, M., Goldenberg, S., Kaplan, D.: Am. J. Phys. 44 (1976)
1089–1093.
1963Y1 Yen, W.M., Norberg, R.E.: Phys. Rev. 131 (1963) 269–275.
1989P3 Peereboom, P.W.E., Luigjes, H., Prins, K.O.: Physica A 156 (1989) 260–276.
1972H8 Hesse, D.: Z. Phys. Chem. Neue Folge 81 (1972) 113–134.
1965W5 Watts, H.: Can. J. Chem. 43 (1965) 431–435.

Diffusion of air (1); carbon dioxide (2) 1
Diffusion of air (1); carbon dioxide (2)

Data extract from of Landolt-Börnstein IV/15A, Chapter 4.1.1: Diffusion in Binary
Gaseous Mixtures
Air (1) air 132259-10-0

CO2 (2) carbon dioxide 124-38-9
Mutual Diffusion Coefficient: D12(T ); Method: CORR Ref.: 1972M1
Equation: ln (D · p) = ln A + B · ln T – C/T Range: 280 < T/K < 1800
5
Parameter: A · 10 B C
2.70 1.590 102.1
Comment: x1 = 0.50; D12(T ) · p [atm · cm2/s] = (D · p); Marrero‐Mason group III
Reference
1972M1 Marrero, T.R., Mason, E.A.: J. Phys. Chem. Ref. Data 1 (1972) 3–118.

Diffusion of air (1); sulfur hexafluoride (2) 1
Diffusion of air (1); sulfur hexafluoride (2)

Gaseous Mixtures
Air (1) air 132259-10-0

F6S (2) sulfur hexafluoride 2551-62-4
5
1.83 1.576 121.1
Reference

Diffusion of air (1); water (2) 1
Diffusion of air (1); water (2)

Gaseous Mixtures
Air (1) air 132259-10-0

H 2O (2) water 7732-18-5
Equation: ln (D · p) = ln A + B · ln T Range: 282 < T/K < 450
0.187 2.072
2.75 1.632*
Comment: x1 = 0.50; D12(T ) · p [atm · cm2/s] = (D · p); Marrero‐Mason group III;
*: temperature range 450 to 1070 K
Reference

Diffusion of argon (1); air (2) 1
Diffusion of argon (1); air (2)

Gaseous Mixtures
Ar (1) argon 7440-37-1

Air (2) air 132259-10-0
5
0.917 1.749
Reference

Diffusion of argon (1); methane (2) 1
Diffusion of argon (1); methane (2)

Gaseous Mixtures
Ar (1) argon 7440-37-1

CH4 (2) methane 74-82-8
Equation: (D · p) = A · T C
Parameter: A · 106 C
5.27 11/6
low temperature asymptote with C = 11/6
Ar (1) argon 7440-37-1

CH4 (2) methane 74-82-8
0.784 1.785
Ar (1) argon 7440-37-1

CH4 (2) methane 74-82-8
Mutual Diffusion
Coefficient: D12(x1); Method: TB Ref.: 1982T7
Equation: D = A (1 + B x /(1 + C x)) Range: 0.0 < x1 < 1.0
Parameter: A B C Std-Dev
0.2196 0.0190 1.3787 0.02%
Comment: T = 300 K; D12 [m2/s] = D · 10–4;
A = –3.2510 · 10–2 + 3.7440 · 10–4 · T + 1.5525 · 10–6 · T 2 [277 - 320 K]
References
1982T7 Trengove, R.D., Robjohns, H.L., Dunlop, P.J.: Ber. Bunsenges. Phys. Chem. 86 (1982)
951–955.

Diffusion of argon (1); carbon monoxide (2) 1
Diffusion of argon (1); carbon monoxide (2)

Gaseous Mixtures
Ar (1) argon 7440-37-1

CO (2) carbon monoxide 630-08-0
5
0.904 1.752
Ar (1) argon 7440-37-1

Mutual DiffusionCoefficient: D12(T ); Method: CT Ref.: 1978A10
Equation: D = A + B T + C T2 Range: 275 < T/K < 323
Parameter: A · 102 B · 104 C · 106 Std-Dev
–2.8714 3.3599 1.5034 0.06%
Comment: x2 = 0.35; D12 [m2/s] = D · 10–4
Ar (1) argon 7440-37-1

Mutual Diffusion Coefficient: D12(x1); Method: CT Ref.: 1978A10
0.2067 0.0065 0 0.02%
Comment: T = 300 K; D12 [m2/s] = D · 10–4;
A = –3.2510 · 10–2 + 3.7440 · 10–4 · T + 1.5525 · 10–6 · T 2 [277 K- 320 K]
Ar (1) argon 7440-37-1

Mutual Diffusion Coefficient: D12(x1); Method: TB Ref.: 1984T9
0.2067 0.0065 0 0.02%
Comment: T = 300 K; D12 [m2/s] = D · 10–4;
A = – 0.04274 + 0.4348 · 10–3 · T + 1.3246 · 10–6 · T 2 [277 K- 320 K]
References
1978A10 Arora, P.S., Robjohns, H.L., Shankland, I.R., Dunlop, P.J.: Chem. Phys. Lett. 59 (1978)
478–480.
450–453.

Diffusion of argon (1); carbon dioxide (2) 1
Diffusion of argon (1); carbon dioxide (2)

Gaseous Mixtures
Ar (1) argon 7440-37-1

Intradiffusion Coefficient: D2T(T ); Method: TB Ref.: 1974L11
T [K] p [kPa] D · 104 [m2/s]
175.3 101.325 0.0554 ± 0.9%
203.4 101.325 0.0739 ± 0.9%
233.1 101.325 0.0968 ± 0.9%
263.2 101.325 0.123 ± 0.9%
296.0 101.325 0.156 ± 0.9%
418.2 101.325 0.292 ± 0.9%
484.2 101.325 0.380 ± 0.9%
587.2 101.325 0.534 ± 0.9%
670.8 101.325 0.669 ± 0.9%
775.8 101.325 0.865 ± 0.9%
Comment: concentration of trace component = 2.5%
Ar (1) argon 7440-37-1

Intradiffusion Coefficient: D12(T ); Method: TB Ref.: 1999G2
T [K] p [kPa] D · 104 [m2/s]
318.15 ± 0.05 101.325 0.1690
320.55 ± 0.05 101.325 0.1700
330.61 ± 0.05 101.325 0.1820
332.38 ± 0.05 101.325 0.1864
341.58 ± 0.05 101.325 0.1950
353.36 ± 0.05 101.325 0.2075
358.44 ± 0.05 101.325 0.2130
360.34 ± 0.05 101.325 0.2145
Ar (1) argon 7440-37-1

Intradiffusion Coefficient: D1T(T ); Method: DB Ref.: 2004A3
T [K] p [kPa] D · 104 [m2/s]
300.4 101.325 0.16
406.3 101.325 0.25
450.6 101.325 0.29
500.1 101.325 0.35
550.8 101.325 0.42
600.9 101.325 0.49
680.2 101.325 0.59
700.8 101.325 0.63
750.2 101.325 0.69
(continued)

2 Diffusion of argon (1); carbon dioxide (2)
800.6 101.325 0.82

840.2 101.325 0.85
900.3 101.325 0.99
960.2 101.325 1.07
1000.7 101.325 1.12
1060.8 101.325 1.22
Ar (1) argon 7440-37-1

T [K] p [kPa] D · 104 [m2/s]
300.4 101.325 0.17
406.3 101.325 0.26
450.6 101.325 0.31
500.1 101.325 0.37
550.8 101.325 0.44
600.9 101.325 0.51
680.2 101.325 0.62
700.8 101.325 0.66
750.2 101.325 0.73
800.6 101.325 0.85
840.2 101.325 0.90
900.3 101.325 1.03
960.2 101.325 1.12
1000.7 101.325 1.18
1060.8 101.325 1.28
Ar (1) argon 7440-37-1

Mutual Diffusion Coefficient: D12(T ); Method: DB Ref.: 2004A3
T [K] p [kPa] D · 104 [m2/s]
300.4 101.325 0.15
406.3 101.325 0.27
450.6 101.325 0.31
500.1 101.325 0.37
550.8 101.325 0.44
600.9 101.325 0.52
680.2 101.325 0.63
700.8 101.325 0.68
750.2 101.325 0.75
800.6 101.325 0.85
840.2 101.325 0.92
900.3 101.325 1.06
960.2 101.325 1.18
1000.7 101.325 1.24
1060.9 101.325 1.36

Ar (1) argon 7440-37-1

2.70 1.590 102.1
2
Comment: x1 = 0.50; D12(T ) · p [atm · cm /s] = (D · p); Marrero‐Mason group III
Ar (1) argon 7440-37-1

Mutual Diffusion Coefficient: D12(x1); Method: CT Ref.: 1984R3
Parameter: A Std-Dev
0.1538 ± 0.08% 0.14%
Comment: T = 300 K; D12 [m2/s] = D · 10–4;
A = –2.4447 · 10–1 + 1.7934 · 10–3 · T – 1.5545 · 10–6 · T 2 [277 - 323 K]
References
1974L11 Loiko, A.E., Ivakin, B.A., Suetin, P.E.: Zh. Tekh. Fiz. 44 (1974) 682–684.
1999G2 Gianturco, F.A., Paesani, F., Laranjeira, M.F., Vassilenko, V., Cunha, M.A., Shashkov, A.G.,
Zolotoukhina, A. F.: Mol. Phys. 97 (1999) 869–880.
83–88.
1984R3 Robjohns, H.L., Dunlop, P.J.: Ber. Bunsenges. Phys. Chem. 88 (1984) 1239–1241.

Diffusion of argon (1); ethanol (2) 1
Diffusion of argon (1); ethanol (2)

Gaseous Mixtures
Ar (1) argon 7440-37-1

C2H6O (2) ethanol 64-17-5
Mutual Diffusion Coefficient: D12(φ1); Method: STEFAN Ref.: 1978K7
Equation: D = A + B x + C x2 Range: 0.0 < φ1 < 1.0
Parameter: A B C
–2.349 5.306 –2.859
Comment: T = 300 K; D12 [m2/s] = D · 10–4; x = volume fraction φ1
Reference
1978K7 Kurlapov, L.I., Chernyak, S.N.: Inzh. Fiz. Zh. 35 (1978) 287–291.

Diffusion of argon (1); propan-2-one (2) 1
Diffusion of argon (1); propan-2-one (2)

Gaseous Mixtures
Ar (1) argon 7440-37-1

C3H6O (2) propan-2-one 67-64-1
Parameter: A B C
0.08184 0.07496 –0.06610
Reference

Diffusion of argon (1); diethyl ether (2) 1
Diffusion of argon (1); diethyl ether (2)

Gaseous Mixtures
Ar (1) argon 7440-37-1

C4H10O (2) diethyl ether 60-29-7
Parameter: A B C
0.1449 –0.1244 0.05762
Reference

Diffusion of argon (1); benzene (2) 1
Diffusion of argon (1); benzene (2)

Gaseous Mixtures
Ar (1) argon 7440-37-1

C6H6 (2) benzene 71-43-2
Parameter: A B C
–0.1532 0.6033 –0.3740
Reference

Diffusion of argon (1); sulfur hexafluoride (2) 1
Diffusion of argon (1); sulfur hexafluoride (2)

Gaseous Mixtures
Ar (1) argon 7440-37-1

5
1.48 1.596 145.4
Reference

Diffusion of argon (1); hydrogen (2) 1
Diffusion of argon (1); hydrogen (2)

Gaseous Mixtures
Ar (1) argon 7440-37-1

H2 (2) hydrogen 1333-74-0
Integral Diffusion Coefficient: D (xi); T = 298.15 K; Method: CT Ref.: 1968K2
x1 p [Torr] D · 104 [m2/s]
0.9771 804.1 0.745 ± 0.555%
0.8334 801.4 0.749 ± 0.137%
0.3137 803.0 0.721 ± 0.251%
0.2131 802.6 0.695 ± 0.352%
0.1038 803.3 0.693 ± 0.599%
Ar (1) argon 7440-37-1

H2 (2) hydrogen 1333-74-0
x1 p [Torr] D · 104 [m2/s]
0.7934 59.1 8.45 ± 1.04%
0.7648 107.4 5.02 ± 0.73%
0.8005 203.1 2.98 ± 0.66%
0.8334 801.4 0.749 ± 0.14%
0.8193 804.2 0.766 ± 0.24%
0.8795 1202.6 0.508 ± 0.17%
Comment: x1: arithmetic mean of mole fractions
Ar (1) argon 7440-37-1

H2 (2) hydrogen 1333-74-0
19.5 11/6
Ar (1) argon 7440-37-1

H2 (2) hydrogen 1333-74-0
Equation: ln (D · p) = ln A + B · ln T – ln [ ln(C/T ) ]2 – E/T Range: 242 < T/K < 10000
Parameter: A · 103 B C · 10–8 E
23.5 1.519 0.488 39.8
Comment: x1 = 0.50; D12(T ) · p [atm · cm2/s] = (D · p); Marrero‐Mason group II

2 Diffusion of argon (1); hydrogen (2)
References
1968K2 Kerl, K.: Ph. D. Thesis, TU Braunschweig, 1968.

Diffusion of argon (1); ammonia (2) 1
Diffusion of argon (1); ammonia (2)

Gaseous Mixtures
Ar (1) argon 7440-37-1

H 3N (2) ammonia 7664-41-7
Mutual Diffusion Coefficient: D12(x1); Method: TB Ref.: 1987D5
0.2281 0.0017 0 0.2%
Comment: T = 300 K; D12 [m2/s] = D · 10–4;
A = –0.8384 · 10–1 + 0.6491 · 10–3 · T + 1.3200 · 10–6 · T 2 [280 - 400 K]; ΔA = ±0.13%
Reference
1987D5 Dunlop, P.J., Bignell, C.M.: Ber. Bunsenges. Phys. Chem. 91 (1987) 817–819.

Diffusion of argon (1); helium (2) 1
Diffusion of argon (1); helium (2)

Gaseous Mixtures
Ar (1) argon 7440-37-1

He (2) helium 7440-59-7
Mutual Diffusion Coefficient: D12(T ); x1 = 0.50; Method: TB Ref.: 1968M5
T [K] p [kPa] D · 104 [m2/s]
270.0 ± 0.1 101.325 0.610
290.0 ± 0.1 101.325 0.690
310.0 ± 0.1 101.325 0.780
330.0 ± 0.1 101.325 0.875
350.0 ± 0.1 101.325 0.975
Ar (1) argon 7440-37-1

He (2) helium 7440-59-7
Intradiffusion Coefficient: D12 · p (T ); Method: TB Ref.: 1968V1
T [K] p [kPa] D · 106 [atm ·m2/s]
90.2 101.325 9.48 ± 0.08
169.3 101.325 28.53 ± 0.15
295.0 101.325 73.4 ± 0.4
400.0 101.325 123.3 ± 0.6
Comment: D at x2 = 0.50 given as (D12 · p) in [m2· atm/s]
Ar (1) argon 7440-37-1

He (2) helium 7440-59-7
x1 p [Torr] D · 104[m2/s]
0.8459 807.7 0.669 ± 0.169%
0.3167 805.4 0.653 ± 0.255%
0.1074 806.7 0.634 ± 0.668%
Ar (1) argon 7440-37-1

He (2) helium 7440-59-7
x1 p [Torr] D · 104[m2/s]
0.7949 29.4 12.4 ± 0.89%
0.7764 60.9 7.24 ± 0.65%
0.7996 111.0 4.51 ± 0.35%
0.7891 408.6 1.33 ± 0.23%
0.8459 807.7 0.669 ± 0.17%
0.8820 1205.9 0.453 ± 0.16%
Comment: x1: arithmetic mean of molefractions

2 Diffusion of argon (1); helium (2)
Ar (1) argon 7440-37-1

He (2) helium 7440-59-7
Integral Diffusion Coefficient: D (T ); Method: CT Ref.: 1968K2
T [K] p [Torr] D · 104[m2/s]
277.87 ± 0.01 800.1 0.608 ± 0.27%
287.85 ± 0.01 804.3 0.623 ± 0.13%
298.16 ± 0.01 807.7 0.669 ± 0.17%
308.17 ± 0.01 805.3 0.720 ± 0.18%
328.55 ± 0.01 808.3 0.759 ± 0.19%
References
1968M5 Mathur, B.P., Saxena, S.C.: Appl. Sci. Res. 18 (1968) 325–335.
1968V1 van Heijningen, R.J.J., Harpe, J.P., Beenakker, J.J.M.: Physica 38 (1968) 1–34.

Diffusion of argon (1); Krypton (2) 1
Diffusion of argon (1); Krypton (2)

Gaseous Mixtures
Ar (1) argon 7440-37-1

kr (2) krypton 7439-90-9
Mutual Diffusion Coefficient: D12 · p (n); T = (300.00 ± 0.005) K; Method: CT Ref.: 1980S6
n [1/10–25 m3] p [atm] D · 104 [atm · m2/s]
2.451 1.001 0.1404 ± 0.2%
2.450 1.000 0.1406 ± 0.2%
2.450 1.000 0.1406 ± 0.2%
4.911 2.002 0.1404 ± 0.2%
4.910 2.002 0.1406 ± 0.2%
9.848 4.003 0.1394 ± 0.2%
14.808 6.004 0.1390 ± 0.2%
19.794 8.003 0.1384 ± 0.2%
24.815 10.006 0.1379 ± 0.2%
Comment: n: number density
Ar (1) argon 7440-37-1

kr (2) krypton 7439-90-9
Intradiffusion Coefficient: D12 · p (n); T = (323.16 ± 0.005) K; Method: CT Ref.: 1980S6
n [1/10–25 m3] p [atm] D · 104 [atm ·m2/s]
2.273 1.000 0.1614 ± 0.2%
2.272 0.999 0.1611 ± 0.2%
4.554 2.001 0.1608 ± 0.2%
4.552 2.000 0.1606 ± 0.2%
9.122 4.000 0.1599 ± 0.2%
13.719 6.004 0.1595 ± 0.2%
18.319 8.001 0.1586 ± 0.2%
22.953 10.004 0.1583 ± 0.2%
Ar (1) argon 7440-37-1

kr (2) krypton 7439-90-9
Intradiffusion Coefficient: D1T (T ); Method: TB Ref.: 1973L6
T [K] p [kPa] D · 104 [m2/s]
127.3 ± 0.1 101.325 0.0274 ± 0.9%
297.4 ± 0.1 101.325 0.1357 ± 0.9%
297.4 ± 0.1 101.325 0.1367 ± 0.9%
776.4 ± 0.1 101.325 0.773 ± 0.9%

2 Diffusion of argon (1); Krypton (2)
Ar (1) argon 7440-37-1

kr (2) krypton 7439-90-9
Intradiffusion Coefficient: D12(T ); Method: CATA Ref.: 1971H6
T [K] p [kPa] D · 104 [m2/s]
300 101.325 0.140
350 101.325 0.186
400 101.325 0.235
450 101.325 0.289
500 101.325 0.347
550 101.325 0.410
600 101.325 0.478
650 101.325 0.549
700 101.325 0.624
750 101.325 0.698
800 101.325 0.784
850 101.325 0.865
900 101.325 0.960
950 101.325 1.050
1000 101.325 1.145
1050 101.325 1.248
1100 101.325 1.345
1150 101.325 1.445
1200 101.325 1.545
1250 101.325 1.665
1300 101.325 1.77
1350 101.325 1.89
1400 101.325 2.02
Comment: accuracy: ±(0.5–1)%; Krypton concentration: 1.0%
Ar (1) argon 7440-37-1

kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
127.3 ± 0.1 101.325 0.0274 ± 0.9%
163.6 ± 0.1 101.325 0.0450 ± 0.9%
203.5 ± 0.1 101.325 0.0675 ± 0.9%
242.8 ± 0.1 101.325 0.0938 ± 0.9%
297.4 ± 0.1 101.325 0.1356 ± 0.9%
297.4 ± 0.1 101.325 0.1370 ± 0.9%
398.5 ± 0.1 101.325 0.238 ± 0.9%
501.0 ± 0.1 101.325 0.360 ± 0.9%
592.3 ± 0.1 101.325 0.486 ± 0.9%
697.7 ± 0.1 101.325 0.641 ± 0.9%
776.4 ± 0.1 101.325 0.765 ± 0.9%

Ar (1) argon 7440-37-1

kr (2) krypton 7439-90-9
Mutual Diffusion Coefficient: D12(T ); Method: CORR Ref.: 1984K4
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0044
100.0 101.325 0.0165
150.0 101.325 0.0365
200.0 101.325 0.0642
250.0 101.325 0.0987
300.0 101.325 0.1395
273.15 101.325 0.1168
293.15 101.325 0.1335
313.15 101.325 0.1511
333.15 101.325 0.1697
353.15 101.325 0.1890
373.15 101.325 0.2093
423.15 101.325 0.2635
473.15 101.325 0.3226
523.15 101.325 0.3862
573.15 101.325 0.4543
623.15 101.325 0.5266
673.15 101.325 0.6029
723.15 101.325 0.6831
773.15 101.325 0.7670
873.15 101.325 0.9457
973.15 101.325 1.1382
1073.15 101.325 1.3439
1173.15 101.325 1.5624
1273.15 101.325 1.7933
1773.15 101.325 3.1253
2273.15 101.325 4.7472
2773.15 101.325 6.6511
3273.15 101.325 8.8208
Comment: x1 = 0.75, extended data set from a correlation, accuracy: ±2.0%
Ar (1) argon 7440-37-1

kr (2) krypton 7439-90-9
Intradiffusion Coefficient: D12(T ); Method: CORR Ref.: 1984K4
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0044
100.0 101.325 0.0165
150.0 101.325 0.0365
200.0 101.325 0.0642
250.0 101.325 0.0988
300.0 101.325 0.1396
273.15 101.325 0.1169
293.15 101.325 0.1336
313.15 101.325 0.1513
(continued)
333.15 101.325 0.1698

353.15 101.325 0.1893
373.15 101.325 0.2096
423.15 101.325 0.2639
473.15 101.325 0.3233
523.15 101.325 0.3872
573.15 101.325 0.4556
623.15 101.325 0.5283
673.15 101.325 0.6050
723.15 101.325 0.6856
773.15 101.325 0.7701
873.15 101.325 0.9499
973.15 101.325 1.1436
1073.15 101.325 1.3506
1173.15 101.325 1.5705
1273.15 101.325 1.8029
1773.15 101.325 3.1424
2273.15 101.325 4.7707
2773.15 101.325 6.6822
3273.15 101.325 8.8607
Ar (1) argon 7440-37-1

kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0044
100.0 101.325 0.0165
150.0 101.325 0.0365
200.0 101.325 0.0642
250.0 101.325 0.0988
300.0 101.325 0.1397
273.15 101.325 0.1170
293.15 101.325 0.1337
313.15 101.325 0.1514
333.15 101.325 0.1700
353.15 101.325 0.1895
373.15 101.325 0.2098
423.15 101.325 0.2644
473.15 101.325 0.3239
523.15 101.325 0.3881
573.15 101.325 0.4568
623.15 101.325 0.5298
673.15 101.325 0.6069
723.15 101.325 0.6880
773.15 101.325 0.7729
873.15 101.325 0.9537
973.15 101.325 1.1486
(continued)
1073.15 101.325 1.3569

1173.15 101.325 1.5781
1273.15 101.325 1.8118
1773.15 101.325 3.1583
2273.15 101.325 4.7926
2773.15 101.325 6.7112
3273.15 101.325 8.8982
Ar (1) argon 7440-37-1

kr (2) krypton 7439-90-9
3.51 11/6
Ar (1) argon 7440-37-1

kr (2) krypton 7439-90-9
5.346 1.556 13.0 47.3
Comment: x1 = 0.50; D12(T ) · p [atm · cm2/s] = (D · p); Marrero‐Mason group I
Ar (1) argon 7440-37-1

kr (2) krypton 7439-90-9
Equation: D = A + B · T + C · T2 Range: 275 < T/K < 323
0.0630 0.06087 1.3502 0.05%
2 –4
Comment: x2 = 0.15; D12 [m /s] = D · 10
Ar (1) argon 7440-37-1

kr (2) krypton 7439-90-9
Mutual DiffusionCoefficient: D12(T ); Method: TB Ref.: 1978A9
6.298 6.0874 1.3502 0.05%
Comment: x2 = 0.15; D12 [m2/s] = D · 10–4

Ar (1) argon 7440-37-1

kr (2) krypton 7439-90-9
0.14036 0.00256 0 0.05%
2 –4
Comment: T = 300 K; D12 [m /s] = D · 10
Ar (1) argon 7440-37-1

kr (2) krypton 7439-90-9
Mutual Diffusion Coefficient: D12(x2); Method: TB Ref.: 1978A9
0.1404 0.0026 0 0.05%
Comment: T = 300 K; D12 [m2/s] = D · 10–4
References
1980S6 Shankland, I.R., Dunlop, P.J.: Physica A 100 (1980) 64–84.
1971H6 Hogervorst, W.: Physica 51 (1971) 59–76.
Data 13 (1984) 229–303.
1979A6 Arora, P.S., Robjohns, H.L., Dunlop, P.J.: Physica A 95 (1979) 561–571.
1978A9 Arora, P.S., Carson, P.J., Dunlop, P.J.: Chem. Phys. Lett. 54 (1978) 117–119.

Diffusion of argon (1); nitrogen (2) 1
Diffusion of argon (1); nitrogen (2)

Gaseous Mixtures
Ar (1) argon 7440-37-1

N2 (2) nitrogen 7727-37-9
Integral Diffusion Coefficient: D (T ); T = 298.18 K; Method: CT Ref.: 1968K2
T [K] p [kPa] D · 104[m2/s]
298.18 ± 0.01 801.2 0.204 ± 0.65%
308.18 ± 0.01 801.5 0.212 ± 0.34%
Ar (1) argon 7440-37-1

N2 (2) nitrogen 7727-37-9
x1 p [Torr] D · 104[m2/s]
0.7557 207.4 0.493 ± 1.07%
0.7829 406.3 0.324 ± 0.59%
0.8401 604.7 0.273 ± 0.67%
0.8530 801.2 0.204 ± 0.65%
0.9246 1208.9 0.136 ± 0.57%
Ar (1) argon 7440-37-1

N2 (2) nitrogen 7727-37-9
Mutual Diffusion Coefficient: D12(xi); T = 300 K; Method: CT Ref.: 1976S7
x1 p [kPa] D · 104 [m2/s]
0.5000 101.325 0.2036
0.5000 101.325 0.2036
0.4999 101.325 0.2039
0.5001 101.325 0.2036
0.5004 101.325 0.2040
0.5001 101.325 0.2037
0.5001 101.325 0.2035
0.5000 101.325 0.2036
0.5000 101.325 0.2036
0.5000 101.325 0.2039
0.5000 101.325 0.2038
0.5000 101.325 0.2037
0.5000 101.325 0.2036
0.5000 101.325 0.2037
Comment: errors: ±0.1%

2 Diffusion of argon (1); nitrogen (2)
Ar (1) argon 7440-37-1

N2 (2) nitrogen 7727-37-9
Equation: (D · p) = A · T c
4.93 11/6
Ar (1) argon 7440-37-1

N2 (2) nitrogen 7727-37-9
5
0.904 1.752
Ar (1) argon 7440-37-1

N2 (2) nitrogen 7727-37-9
–7.4946 6.3930 0.9653 0.05%
Comment: x2 = 0.50; D12 [m2/s] = D · 10–4
Ar (1) argon 7440-37-1

N2 (2) nitrogen 7727-37-9
0.2034 0.0041 0 0.04%
Comment: T = 300 K; D12 [m2/s] = D · 10–4
Ar (1) argon 7440-37-1

N2 (2) nitrogen 7727-37-9
0.2034 0.0041 0 0.04%
Comment: T = 300 K; D12 [m2/s] = D · 10–4;
A = –0.086126 + 0.71359 · 10–3 · T + 0.8375 · 10–6 · T 2 [277 K- 323 K]; ΔA = ±0.06%
References
1976S7 Shankland, I.R., Dunlop, P.J.: Chem. Phys. Lett. 39 (1976) 557–559.

478–480.
1982T5 Trengove, R.D., Dunlop, P.J.: Physica A 115 (1982) 339–352.

Diffusion of argon (1); neon (2) 1
Diffusion of argon (1); neon (2)

Gaseous Mixtures
Ar (1) argon 7440-37-1

Ne (2) neon 7440-01-9
Mutual Diffusion Coefficient: D12 · p (T ); Method: TB Ref.: 1968V1
T [K] p [kPa] D · 106 [atm · m2/s]
90.2 101.325 3.71 ± 0.02
169.3 101.325 12.02 ± 0.07
295.0 101.325 31.6 ± 0.2
400.0 101.325 53.0 ± 0.3
Comment: D at x2 = 0.50 given as (D12 · p) in [m2 · atm/s]
Reference

Diffusion of argon (1); oxygen (2) 1
Diffusion of argon (1); oxygen (2)

Gaseous Mixtures
Ar (1) argon 7440-37-1

O2 (2) oxygen 7782-44-7
Integral Diffusion Coefficient: D(T ); T = 298.18 K; Method: CT Ref.: 1968K2
x1 p [Torr] D · 104 [m2/s]
0.8396 803.2 0.219 ± 1.40%
Ar (1) argon 7440-37-1

O2 (2) oxygen 7782-44-7
Integral Diffusion Coefficient: D(xi); T = 298.19 K; Method: CT Ref.: 1968K2
x1 p [Torr] D · 104 [m2/s]
0.8986 403.6 0.310 ± 0.54%
0.8739 803.2 0.217 ± 1.09%
Ar (1) argon 7440-37-1

O2 (2) oxygen 7782-44-7
Integral Diffusion Coefficient: D(T ); T = 298.18 K; Method: CT Ref.: 1968K2
T [K] p [Torr] D · 104 [m2/s]
298.19 ± 0.01 803.2 0.219 ± 1.09%
308.18 ± 0.01 801.3 0.264 ± 1.35%
Ar (1) argon 7440-37-1

O2 (2) oxygen 7782-44-7
5
0.977 1.736
Ar (1) argon 7440-37-1

O2 (2) oxygen 7782-44-7
–0.5062 0.4619 1.2870 0.04%
Comment: x1 = 0.50; ΔT = ±2 mK

2 Diffusion of argon (1); oxygen (2)
Ar (1) argon 7440-37-1

O2 (2) oxygen 7782-44-7
0.2037 0.0024 0 0.02%
Comment: T = 300 K; D12 [m2/s] = D · 10–4
Ar (1) argon 7440-37-1

O2 (2) oxygen 7782-44-7
0.2037 0.0024 0 0.02%
Comment: T = 300 K; D12 [m2/s] = D · 10–4;
A = –0.5029 · 10–1 + 0.4609 · 10–3 · T + 0.1284 · 10–5 · T 2 [280 - 320 K]; ΔA = ±0.04%
References
1980A9 Arora, P.S., Robjohns, H.L., Bell, T.N., Dunlop, P.J.: Aust. J. Chem. 33 (1980) 1993–1996.

Diffusion of argon (1); xenon (2) 1
Diffusion of argon (1); xenon (2)

Gaseous Mixtures
Ar (1) argon 7440-37-1

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0037
100.0 101.325 0.0134
150.0 101.325 0.0295
200.0 101.325 0.0517
250.0 101.325 0.0799
300.0 101.325 0.1132
273.15 101.325 0.0947
293.15 101.325 0.1083
313.15 101.325 0.1228
333.15 101.325 0.1380
353.15 101.325 0.1540
373.15 101.325 0.1707
423.15 101.325 0.2155
473.15 101.325 0.2644
523.15 101.325 0.3174
573.15 101.325 0.3740
623.15 101.325 0.4343
673.15 101.325 0.4981
723.15 101.325 0.5652
773.15 101.325 0.6355
873.15 101.325 0.7853
973.15 101.325 0.9469
1073.15 101.325 1.1197
1173.15 101.325 1.3033
1273.15 101.325 1.4972
1773.15 101.325 2.6137
2273.15 101.325 3.9622
2773.15 101.325 5.5383
3273.15 101.325 7.3323
Ar (1) argon 7440-37-1

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0037
100.0 101.325 0.0134
150.0 101.325 0.0295
200.0 101.325 0.0518
(continued)
2 Diffusion of argon (1); xenon (2)
250.0 101.325 0.0799

300.0 101.325 0.1133
273.15 101.325 0.0947
293.15 101.325 0.1084
313.15 101.325 0.1229
333.15 101.325 0.1382
353.15 101.325 0.1542
373.15 101.325 0.1709
423.15 101.325 0.2159
473.15 101.325 0.2650
523.15 101.325 0.3182
573.15 101.325 0.3752
623.15 101.325 0.4359
673.15 101.325 0.5000
723.15 101.325 0.5676
773.15 101.325 0.6384
873.15 101.325 0.7893
973.15 101.325 0.9522
1073.15 101.325 1.1264
1173.15 101.325 1.3115
1273.15 101.325 1.5070
1773.15 101.325 2.6321
2273.15 101.325 3.9885
2773.15 101.325 5.5731
3273.15 101.325 7.3769
Ar (1) argon 7440-37-1

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0037
100.0 101.325 0.0134
150.0 101.325 0.0295
200.0 101.325 0.0518
250.0 101.325 0.0799
300.0 101.325 0.1133
273.15 101.325 0.0947
293.15 101.325 0.1084
313.15 101.325 0.1229
333.15 101.325 0.1382
353.15 101.325 0.1542
373.15 101.325 0.1709
423.15 101.325 0.2159
473.15 101.325 0.2650
523.15 101.325 0.3182
573.15 101.325 0.3752
623.15 101.325 0.4359
(continued)
673.15 101.325 0.5000

723.15 101.325 0.5676
773.15 101.325 0.6384
873.15 101.325 0.7893
973.15 101.325 0.9522
1073.15 101.325 1.1264
1173.15 101.325 1.3115
1273.15 101.325 1.5070
1773.15 101.325 2.6321
2273.15 101.325 3.9885
2773.15 101.325 5.5731
3273.15 101.325 7.3769
Ar (1) argon 7440-37-1

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
163.4 101.325 0.0359 ± 0.9%
290.3 101.325 0.107 ± 0.9%
764.9 101.325 0.640 ± 0.9%
Ar (1) argon 7440-37-1

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
128.0 101.325 0.0219 ± 0.9%
163.4 101.325 0.0361 ± 0.9%
203.1 101.325 0.0541 ± 0.9%
243.4 101.325 0.0773 ± 0.9%
290.3 101.325 0.107 ± 0.9%
384.4 101.325 0.182 ± 0.9%
483.5 101.325 0.277 ± 0.9%
578.7 101.325 0.384 ± 0.9%
673.7 101.325 0.502 ± 0.9%
764.9 101.325 0.631 ± 0.9%
Comment: concentration of trace component: 2.5%
Ar (1) argon 7440-37-1

Xe (2) xenon 7440-63-3
Mutual Diffusion Coefficient: D12(T ); Method: CATA Ref.: 1971H6
T [K] p [kPa] D · 104 [m2/s]
300 101.325 0.114
350 101.325 0.153
400 101.325 0.195
(continued)

4 Diffusion of argon (1); xenon (2)
450 101.325 0.238

500 101.325 0.290
550 101.325 0.341
600 101.325 0.400
650 101.325 0.458
700 101.325 0.523
750 101.325 0.590
800 101.325 0.662
850 101.325 0.732
900 101.325 0.804
950 101.325 0.880
1000 101.325 0.965
1050 101.325 1.048
1100 101.325 1.135
1150 101.325 1.225
1200 101.325 1.320
1250 101.325 1.407
1300 101.325 1.505
1350 101.325 1.605
1400 101.325 1.705
Comment: accuracy: ±(0.5–1)%; xenon concentration: 1.0%
Ar (1) argon 7440-37-1

Xe (2) xenon 7440-63-3
2.93 11/6
Comment: x1 = 0.50; D12(T ) · p [atm · cm2/s] = (D · p); low temperature asymptote with C = 11/6
Ar (1) argon 7440-37-1

Xe (2) xenon 7440-63-3
5.000 1.563 36.8 59.9
Ar (1) argon 7440-37-1

Xe (2) xenon 7440-63-3
–2.0482 0.18420 0.8822 0.10%
2 –4
Comment: x1 = 0.15; D12 [m /s] = D · 10

Ar (1) argon 7440-37-1

Xe (2) xenon 7440-63-3
0.11403 0.00167 0 0.06%
Comment: T = 300 K; D12 [m2/s] = D · 10–4
References
Data 13 (1984) 229–303.

Diffusion of trichloro-methane (1); Air (2) 1
Diffusion of trichloro-methane (1); Air (2)

Gaseous Mixtures
CHCl3 (1) trichloro-methane 67-66-3

Air (2) air 132259-10-0
Integral Diffusion Coefficient: D(xi); T = 323.15 ± 0.005 K; Method: OTE Ref.: 1968M10
x1 p [kPa] D · 104 [m2/s]
0.000 101.325 0.106
0.174 101.325 0.107
0.257 101.325 0.108
0.364 101.325 0.11
0.435 101.325 0.111
0.566 101.325 0.115
Reference
1968M10 Mrazek, R.V., Wicks, C.E., Prabhu, K.N.S.: J. Chem. Eng. Data 13 (1968) 508–510.

Diffusion of chloro-methane (1); chloro-ethane (2) 1
Diffusion of chloro-methane (1); chloro-ethane (2)

Gaseous Mixtures
CH3Cl (1) chloro-methane 74-87-3

C2H5Cl (2) chloro-ethane 75-00-3
Mutual Diffusion Coefficient: D12(T ); x1 = 0.50; Method: CT Ref.: 1974G4
T [K] p [Torr] D · 104 [m2/s]
298.2 730.5 0.05851
298.3 735.8 0.05767
357.9 741.9 0.08656
378.2 740.9 0.1003
418.5 741.0 0.1216
438.4 731.1 0.1336
Reference
1974G4 Gotoh, S., Manner, M., Sørensen, J.P., Stewart, W.E.: J. Chem. Eng. Data 19 (1974) 169–171.

Diffusion of methane (1); Air (2) 1
Diffusion of methane (1); Air (2)

Gaseous Mixtures
CH4 (1) methane 74-82-8

Air (2) air 132259-10-0
5
1.03 1.747
Reference

Diffusion of methane (1); argon (2) 1
Diffusion of methane (1); argon (2)

Gaseous Mixtures
CH4 (1) methane 74-82-8

Ar (2) argon 7440-37-1
Intradiffusion Coefficient: D1T (x2); T = 150 K; Method: NMR FG Ref.: 1978M4
x2 p [kPa] D · 109 [m2/s]
0.00 101.325 4.5 ± 6%
0.20 101.325 9.9 ± 6%
0.40 101.325 9.9 ± 6%
0.60 101.325 1.4 ± 6%
0.80 101.325 3.0 ± 6%
CH4 (1) methane 74-82-8

Ar (2) argon 7440-37-1
x2 p [kPa] D · 109 [m2/s]
0.00 101.325 11.0 ± 6%
0.20 101.325 13.8 ± 6%
0.40 101.325 14.8 ± 6%
0.60 101.325 15.6 ± 6%
0.80 101.325 17.5 ± 6%
CH4 (1) methane 74-82-8

Ar (2) argon 7440-37-1
x2 p [kPa] D · 109 [m2/s]
0.00 101.325 8.6 ± 6%
0.20 101.325 9.7 ± 6%
0.40 101.325 10.3 ± 6%
0.60 101.325 10.5 ± 6%
0.80 101.325 11.5 ± 6%
0.90 101.325 12.0 ± 6%
CH4 (1) methane 74-82-8

Ar (2) argon 7440-37-1
x2 p [kPa] D · 109 [m2/s]
0.00 101.325 6.7 ± 6%
0.20 101.325 7.6 ± 6%
0.40 101.325 7.5 ± 6%
0.60 101.325 7.9 ± 6%
0.80 101.325 8.2 ± 6%
0.90 101.325 9.0 ± 6%

2 Diffusion of methane (1); argon (2)
CH4 (1) methane 74-82-8

Ar (2) argon 7440-37-1
x2 p [kPa] D · 109 [m2/s]
0.00 101.325 5.5 ± 6%
0.20 101.325 5.3 ± 6%
0.40 101.325 5.2 ± 6%
0.60 101.325 5.2 ± 6%
0.80 101.325 5.1 ± 6%
0.90 101.325 5.8 ± 6%
CH4 (1) methane 74-82-8

Ar (2) argon 7440-37-1
x2 p [kPa] D · 109 [m2/s]
0.00 101.325 3.6 ± 6%
0.20 101.325 4.2 ± 6%
0.40 101.325 4.0 ± 6%
0.60 101.325 4.1 ± 6%
0.80 101.325 4.5 ± 6%
0.90 101.325 4.0 ± 6%
CH4 (1) methane 74-82-8

Ar (2) argon 7440-37-1
Intradiffusion Coefficient: D12(T ); Method: ARF Ref.: 1976C6
T [K] p [kPa] D · 104 [m2/s]
298.5 101.325 0.219*
298.5 101.325 0.218
Comment: D12 at concentration x1 = 0.5;
*: at trace concentration of (1); exp. deviation: ±1%
References
1978M4 Mikhailenko, S.A., Yakuba, V.V., Butko, A.E.: Fiz. Nizk. Temp. (Kiev) 4 (1978) 562–573.
1976C6 Cloete, C.E., Smuts, T.W., De Clerk, K.: J. Chromatogr. 120 (1976) 17–27.

Diffusion of methane (1); tetrafluoro-methane (2) 1
Diffusion of methane (1); tetrafluoro-methane (2)

Gaseous Mixtures
CH4 (1) methane 74-82-8

CF4 (2) tetrafluoro-methane 75-73-0
Intradiffusion Coefficient: D1T(x1); T = 348.15 ± 0.02 K; Method: NMR FG Ref.: 1975K7
x1 p [atm] D · 106 [m2/s]
0.75 50 0.4976 ± 4%
0.75 75 0.3228 ± 4%
0.75 100 0.2377 ± 4%
0.75 150 0.1548 ± 4%
0.75 300 0.07865 ± 4%
0.50 50 0.4406 ± 4%
0.50 75 0.2848 ± 4%
0.50 100 0.2077 ± 4%
0.50 150 0.1350 ± 4%
0.50 300 0.07026 ± 4%
0.25 50 0.3791 ± 4%
0.25 75 0.2435 ± 4%
0.25 100 0.1778 ± 4%
0.25 150 0.1151 ± 4%
0.25 300 0.06077 ± 4%
Comment: results smoothed with respect to pressure
CH4 (1) methane 74-82-8

x1 p [atm] D · 106 [m2/s]
0.75 50 0.2905 ± 4%
0.75 75 0.1893 ± 4%
0.75 100 0.1387 ± 4%
0.75 150 0.09006 ± 4%
0.75 300 0.04581 ± 4%
0.50 50 0.2438 ± 4%
0.50 75 0.1548 ± 4%
0.50 100 0.1157 ± 4%
0.50 150 0.07471 ± 4%
0.50 300 0.03869 ± 4%
0.25 50 0.1953 ± 4%
0.25 75 0.1249 ± 4%
0.25 100 0.09111 ± 4%
0.25 150 0.05911 ± 4%
0.25 300 0.03125 ± 4%

2 Diffusion of methane (1); tetrafluoro-methane (2)
CH4 (1) methane 74-82-8

Intradiffusion Coefficient: D12(x1); T = 348.15 ± 0.02 K; Method: NMR FG Ref.: 1975K7
x1 p [atm] D · 106 [m2/s]
0.75 50 0.3395 ± 4%
0.75 75 0.2196 ± 4%
0.75 100 0.1600 ± 4%
0.75 150 0.1027 ± 4%
0.75 300 0.05154 ± 4%
0.50 50 0.3381 ± 4%
0.50 75 0.2169 ± 4%
0.50 100 0.1565 ± 4%
0.50 150 0.09909 ± 4%
0.50 300 0.04805 ± 4%
0.25 50 0.3285 ± 4%
0.25 75 0.2081 ± 4%
0.25 100 0.1491 ± 4%
0.25 150 0.09281 ± 4%
0.25 300 0.04752 ± 4%
CH4 (1) methane 74-82-8

Intradiffusion Coefficient: D1T (x1); T = 348.15 ± 0.02 K; Method: NMR FG Ref.: 1975K7
x1 p [atm] D · 106 [m2/s]
0.75 35.23 0.7258 ± 4%
0.75 68.67 0.3607 ± 4%
0.75 133.72 0.1757 ± 4%
0.75 201.71 0.1167 ± 4%
0.75 275.85 0.08370 ± 4%
0.75 335.73 0.07077 ± 4%
0.75 471.50 0.05323 ± 4%
0.50 35.33 0.6334 ± 4%
0.50 49.04 0.4522 ± 4%
0.50 67.36 0.3181 ± 4%
0.50 138.43 0.1451 ± 4%
0.50 206.40 0.09687 ± 4%
0.50 274.57 0.07662 ± 4%
0.50 338.43 0.06331 ± 4%
0.50 483.20 0.04792 ± 4%
0.25 24.80 0.7966 ± 4%
0.25 35.43 0.5475 ± 4%
0.25 49.04 0.3859 ± 4%
0.25 137.73 0.1261 ± 4%
0.25 207.80 0.08276 ± 4%
(continued)

0.25 276.57 0.06563 ± 4%

0.25 335.03 0.05676 ± 4%
0.25 470.00 0.03935 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 106 [m2/s]
0.75 38.72 0.3822 ± 4%
0.75 78.20 0.1785 ± 4%
0.75 135.03 0.1021 ± 4%
0.75 205.10 0.06460 ± 4%
0.75 277.27 0.04959 ± 4%
0.75 336.43 0.04260 ± 4%
0.75 483.12 0.02792 ± 4%
0.50 34.93 0.3537 ± 4%
0.50 48.84 0.2478 ± 4%
0.50 137.73 0.08140 ± 4%
0.50 207.10 0.05488 ± 4%
0.50 277.97 0.04205 ± 4%
0.50 335.03 0.03641 ± 4%
0.50 496.15 0.02564 ± 4%
0.25 21.71 0.4650 ± 4%
0.25 35.33 0.2845 ± 4%
0.25 49.04 0.1967 ± 4%
0.25 67.96 0.1384 ± 4%
0.25 140.54 0.06344 ± 4%
0.25 206.40 0.04367 ± 4%
0.25 275.87 0.03350 ± 4%
0.25 339.83 0.02886 ± 4%
0.25 433.50 0.02081 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 106 [m2/s]
0.75 50 0.4263 ± 4%
0.75 75 0.2749 ± 4%
0.75 100 0.1999 ± 4%
0.75 150 0.1281 ± 4%
0.75 300 0.06470 ± 4%
0.50 50 0.3725 ± 4%
0.50 75 0.2388 ± 4%
0.50 100 0.1725 ± 4%
0.50 150 0.1098 ± 4%
0.50 300 0.05715 ± 4%
0.25 50 0.3196 ± 4%
(continued)
0.25 75 0.2023 ± 4%
0.25 100 0.1450 ± 4%
0.25 150 0.09204 ± 4%
0.25 300 0.04972 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 106 [m2/s]
0.75 50 0.2496 ± 4%
0.75 75 0.1602 ± 4%
0.75 100 0.1163 ± 4%
0.75 150 0.07414 ± 4%
0.75 300 0.03679 ± 4%
0.50 50 0.2070 ± 4%
0.50 75 0.1324 ± 4%
0.50 100 0.09585 ± 4%
0.50 150 0.06092 ± 4%
0.50 300 0.03198 ± 4%
0.25 50 0.1643 ± 4%
0.25 75 0.1040 ± 4%
0.25 100 0.07489 ± 4%
0.25 150 0.04740 ± 4%
0.25 300 0.02565 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 104 [m2/s]
0.75 50 0.2900 ± 4%
0.75 75 0.1849 ± 4%
0.75 100 0.1328 ± 4%
0.75 150 0.08299 ± 4%
0.75 300 0.04040 ± 4%
0.50 50 0.2848 ± 4%
0.50 75 0.1802 ± 4%
0.50 100 0.1285 ± 4%
0.50 150 0.07921 ± 4%
0.50 300 0.03752 ± 4%
0.25 50 0.2746 ± 4%
0.25 75 0.1697 ± 4%
0.25 100 0.1178 ± 4%
0.25 150 0.07061 ± 4%
0.25 300 0.03680 ± 4%

CH4 (1) methane 74-82-8

x1 p [atm] D · 106 [m2/s]
0.50 135.40 0.1230 ± 4%
0.50 280.40 0.06183 ± 4%
0.50 387.81 0.04679 ± 4%
0.50 496.35 0.03692 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 106 [m2/s]
0.50 184.10 0.04904 ± 4%
0.50 348.92 0.02778 ± 4%
0.50 402.21 0.02537 ± 4%
0.50 516.13 0.02040 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 106 [m2/s]
0.75 50 0.3556 ± 4%
0.75 75 0.2252 ± 4%
0.75 100 0.1616 ± 4%
0.75 150 0.1009 ± 4%
0.75 300 0.05224 ± 4%
0.50 50 0.3079 ± 4%
0.50 75 0.1926 ± 4%
0.50 100 0.1367 ± 4%
0.50 150 0.08549 ± 4%
0.50 300 0.04994 ± 4%
0.25 50 0.2617 ± 4%
0.25 75 0.1607 ± 4%
0.25 100 0.1124 ± 4%
0.25 150 0.07032 ± 4%
0.25 300 0.04274 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 106 [m2/s]
0.75 50 0.2092 ± 4%
0.75 75 0.1318 ± 4%
0.75 100 0.09443 ± 4%
(continued)

0.75 150 0.05873 ± 4%

0.75 300 0.03045 ± 4%
0.50 50 0.1724 ± 4%
0.50 75 0.1074 ± 4%
0.50 100 0.07545 ± 4%
0.50 150 0.04752 ± 4%
0.50 300 0.02568 ± 4%
0.25 50 0.1348 ± 4%
0.25 75 0.08262 ± 4%
0.25 100 0.05755 ± 4%
0.25 150 0.03605 ± 4%
0.25 300 0.02036 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 104 [m2/s]
0.75 50 0.2414 ± 4%
0.75 75 0.1503 ± 4%
0.75 100 0.1061 ± 4%
0.75 150 0.06401 ± 4%
0.75 300 0.03202 ± 4%
0.50 50 0.2344 ± 4%
0.50 75 0.1443 ± 4%
0.50 100 0.1002 ± 4%
0.50 150 0.06019 ± 4%
0.50 300 0.03017 ± 4%
0.25 50 0.2231 ± 4%
0.25 75 0.1327
0.25 100 0.08783 ± 4%
0.25 150 0.05070 ± 4%
0.25 300 0.02934 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 106 [m2/s]
0.75 26.99 0.7005 ± 4%
0.75 49.65 0.3591 ± 4%
0.75 92.18 0.1756 ± 4%
0.75 197.50 0.07569 ± 4%
0.75 357.26 0.04320 ± 4%
0.50 25.30 0.6515 ± 4%
0.50 56.24 0.2721 ± 4%
0.50 102.25 0.1320 ± 4%
0.50 173.09 0.07492 ± 4%
(continued)
0.50 210.60 0.05998 ± 4%

0.50 392.00 0.03817 ± 4%
0.50 502.20 0.02745 ± 4%
0.25 20.60 0.7058 ± 4%
0.25 41.08 0.3312 ± 4%
0.25 80.92 0.1456 ± 4%
0.25 113.40 0.09559 ± 4%
0.25 216.00 0.05153 ± 4%
0.25 313.52 0.03786 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 106 [m2/s]
0.75 29.80 0.3662 ± 4%
0.75 68.83 0.1478 ± 4%
0.75 121.44 0.07408 ± 4%
0.75 316.79 0.02968 ± 4%
0.75 411.74 0.02399 ± 4%
0.50 25.85 0.3559 ± 4%
0.50 45.92 0.1880 ± 4%
0.50 78.70 0.1027 ± 4%
0.50 122.51 0.05863 ± 4%
0.50 201.40 0.03500 ± 4%
0.50 400.65 0.02021 ± 4%
0.50 524.00 0.01487 ± 4%
0.25 24.05 0.3062 ± 4%
0.25 46.99 0.1472 ± 4%
0.25 75.80 0.08028 ± 4%
0.25 170.78 0.03220 ± 4%
0.25 393.50 0.01694 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 106 [m2/s]
0.75 50 0.2883 ± 4%
0.75 75 0.1765 ± 4%
0.75 100 0.1227 ± 4%
0.75 150 0.07509 ± 4%
0.75 300 0.03996 ± 4%
0.50 50 0.2473 ± 4%
0.50 75 0.1485 ± 4%
0.50 100 0.1015 ± 4%
0.50 150 0.06271 ± 4%
0.50 300 0.03586 ± 4%
0.25 50 0.2050 ± 4%
(continued)
0.25 75 0.1186 ± 4%
0.25 100 0.07885 ± 4%
0.25 150 0.05029 ± 4%
0.25 300 0.03247 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 106 [m2/s]
0.75 50 0.1682 ± 4%
0.75 75 0.1039 ± 4%
0.75 100 0.07219 ± 4%
0.75 150 0.04407 ± 4%
0.75 300 0.02360 ± 4%
0.50 50 0.1367 ± 4%
0.50 75 0.08263 ± 4%
0.50 100 0.05697 ± 4%
0.50 150 0.03498 ± 4%
0.50 300 0.01990 ± 4%
0.25 50 0.1053 ± 4%
0.25 75 0.06066 ± 4%
0.25 100 0.04037 ± 4%
0.25 150 0.02558 ± 4%
0.25 300 0.01629 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 104 [m2/s]
0.75 50 0.1943 ± 4%
0.75 75 0.1174 ± 4%
0.75 100 0.07956 ± 4%
0.75 150 0.04628 ± 4%
0.75 300 0.02376 ± 4%
0.50 50 0.1859 ± 4%
0.50 75 0.1097 ± 4%
0.50 100 0.07337 ± 4%
0.50 150 0.04259 ± 4%
0.50 300 0.02108 ± 4%
0.25 50 0.1736 ± 4%
0.25 75 0.09641 ± 4%
0.25 100 0.05926 ± 4%
0.25 150 0.03432 ± 4%
0.25 300 0.02103 ± 4%

CH4 (1) methane 74-82-8

x1 p [atm] D · 106 [m2/s]
0.50 70.73 0.1579 ± 4%
0.50 111.80 0.08896 ± 4%
0.50 174.55 0.05278 ± 4%
0.50 301.15 0.03550 ± 4%
0.50 460.45 0.02299 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 106 [m2/s]
0.50 124.80 0.04148 ± 4%
0.50 188.23 0.02880 ± 4%
0.50 292.61 0.01999 ± 4%
0.50 460.18 0.01309 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 107 [m2/s]
0.75 50 4.976 ± 4%
0.75 75 3.228 ± 4%
0.75 100 2.377 ± 4%
0.75 150 1.548 ± 4%
0.75 300 0.7865 ± 4%
0.50 50 4.406 ± 4%
0.50 75 2.848 ± 4%
0.50 100 2.077 ± 4%
0.50 150 1.350 ± 4%
0.50 300 0.7026 ± 4%
0.25 50 3.791 ± 4%
0.25 75 2.435 ± 4%
0.25 100 1.778 ± 4%
0.25 150 1.151 ± 4%
0.25 300 0.6077 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 107 [m2/s]
0.75 50 2.905 ± 4%
0.75 75 1.893 ± 4%
0.75 100 1.387 ± 4%
(continued)
0.75 150 0.9006 ± 4%

0.75 300 0.4581 ± 4%
0.50 50 2.438 ± 4%
0.50 75 1.584 ± 4%
0.50 100 1.157 ± 4%
0.50 150 0.7471 ± 4%
0.50 300 0.3869 ± 4%
0.25 50 1.953 ± 4%
0.25 75 1.249 ± 4%
0.25 100 0.9111 ± 4%
0.25 150 0.5911 ± 4%
0.25 300 0.3125 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 107 [m2/s]
0.75 35.23 7.258 ± 4%
0.75 68.67 3.607 ± 4%
0.75 133.72 1.757 ± 4%
0.75 201.71 1.167 ± 4%
0.75 275.85 0.8370 ± 4%
0.75 335.73 0.7077 ± 4%
0.75 471.50 0.5323 ± 4%
0.50 35.33 6.334 ± 4%
0.50 49.04 4.522 ± 4%
0.50 67.36 3.181 ± 4%
0.50 138.43 1.451 ± 4%
0.50 206.40 0.9687 ± 4%
0.50 274.57 0.7662 ± 4%
0.50 338.43 0.6331 ± 4%
0.50 483.20 0.4792 ± 4%
0.25 24.80 7.966 ± 4%
0.25 35.43 5.475 ± 4%
0.25 49.04 3.859 ± 4%
0.25 137.73 1.261 ± 4%
0.25 207.80 0.8276 ± 4%
0.25 276.57 0.6563 ± 4%
0.25 335.03 0.5676 ± 4%
0.25 470.00 0.3935 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 107 [m2/s]
0.75 38.72 3.822 ± 4%
0.75 78.20 1.785 ± 4%
(continued)
0.75 135.03 1.021 ± 4%

0.75 205.10 0.6460 ± 4%
0.75 277.27 0.4959 ± 4%
0.75 336.43 0.4260 ± 4%
0.75 483.12 0.2792 ± 4%
0.50 34.93 3.537 ± 4%
0.50 48.84 2.478 ± 4%
0.50 137.73 0.8140 ± 4%
0.50 207.10 0.5488 ± 4%
0.50 277.97 0.4205 ± 4%
0.50 335.03 0.3641 ± 4%
0.50 496.15 0.2564 ± 4%
0.25 21.71 4.650 ± 4%
0.25 35.33 2.845 ± 4%
0.25 49.04 1.967 ± 4%
0.25 67.96 1.384 ± 4%
0.25 140.54 0.6344 ± 4%
0.25 206.40 0.4367 ± 4%
0.25 275.87 0.3350 ± 4%
0.25 339.83 0.2886 ± 4%
0.25 433.50 0.2081 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 107 [m2/s]
0.75 50 4.263 ± 4%
0.75 75 2.749 ± 4%
0.75 100 1.999 ± 4%
0.75 150 1.281 ± 4%
0.75 300 0.6470 ± 4%
0.50 50 3.725 ± 4%
0.50 75 2.388 ± 4%
0.50 100 1.725 ± 4%
0.50 150 1.098 ± 4%
0.50 300 0.5715 ± 4%
0.25 50 3.196 ± 4%
0.25 75 2.023 ± 4%
0.25 100 1.450 ± 4%
0.25 150 0.9204 ± 4%
0.25 300 0.4972 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 107 [m2/s]
0.75 50 2.496 ± 4%
(continued)
0.75 75 1.602 ± 4%
0.75 100 1.163 ± 4%
0.75 150 0.7414 ± 4%
0.75 300 0.3679 ± 4%
0.50 50 2.070 ± 4%
0.50 75 1.324 ± 4%
0.50 100 0.9585 ± 4%
0.50 150 0.6092 ± 4%
0.50 300 0.3198 ± 4%
0.25 50 1.643 ± 4%
0.25 75 1.040 ± 4%
0.25 100 0.7489 ± 4%
0.25 150 0.4740 ± 4%
0.25 300 0.2565 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 107 [m2/s]
0.50 135.40 1.230 ± 4%
0.50 280.40 0.6183 ± 4%
0.50 387.81 0.4679 ± 4%
0.50 496.35 0.3692 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 107 [m2/s]
0.50 184.10 0.4904 ± 4%
0.50 348.92 0.2778 ± 4%
0.50 402.21 0.2537 ± 4%
0.50 516.13 0.2040 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 107 [m2/s]
0.75 50 3.556 ± 4%
0.75 75 2.252 ± 4%
0.75 100 1.616 ± 4%
0.75 150 1.009 ± 4%
0.75 300 0.5224 ± 4%
0.50 50 3.079 ± 4%
0.50 75 1.926 ± 4%
0.50 100 1.367 ± 4%
0.50 150 0.8549 ± 4%
(continued)
0.50 300 0.4994 ± 4%

0.25 50 2.617 ± 4%
0.25 75 1.607 ± 4%
0.25 100 1.124 ± 4%
0.25 150 0.7032 ± 4%
0.25 300 0.4274 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 107 [m2/s]
0.75 50 2.092 ± 4%
0.75 75 1.318 ± 4%
0.75 100 0.9443 ± 4%
0.75 150 0.5873 ± 4%
0.75 300 0.3045 ± 4%
0.50 50 1.724 ± 4%
0.50 75 1.074 ± 4%
0.50 100 0.7545 ± 4%
0.50 150 0.4752 ± 4%
0.50 300 0.2568 ± 4%
0.25 50 1.348 ± 4%
0.25 75 0.8262 ± 4%
0.25 100 0.5755 ± 4%
0.25 150 0.3605 ± 4%
0.25 300 0.2036 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 107 [m2/s]
0.75 26.99 7.005 ± 4%
0.75 49.65 3.591 ± 4%
0.75 92.18 1.756 ± 4%
0.75 197.50 0.7569 ± 4%
0.75 357.26 0.4320 ± 4%
0.50 25.30 6.515 ± 4%
0.50 56.24 2.721 ± 4%
0.50 102.25 1.320 ± 4%
0.50 173.09 0.7492 ± 4%
0.50 210.60 0.5998 ± 4%
0.50 392.00 0.3817 ± 4%
0.50 502.20 0.2745 ± 4%
0.25 20.60 7.058 ± 4%
0.25 41.08 3.312 ± 4%
0.25 80.92 1.456 ± 4%
0.25 113.40 0.9559 ± 4%
(continued)
0.25 216.00 0.5153 ± 4%

0.25 313.52 0.3786 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 107 [m2/s]
0.75 29.80 3.662 ± 4%
0.75 68.83 1.478 ± 4%
0.75 121.44 0.7408 ± 4%
0.75 316.79 0.2968 ± 4%
0.75 411.74 0.2399 ± 4%
0.50 25.85 3.559 ± 4%
0.50 45.92 1.880 ± 4%
0.50 78.70 1.027 ± 4%
0.50 122.51 0.5863 ± 4%
0.50 201.40 0.3500 ± 4%
0.50 400.65 0.2021 ± 4%
0.50 524.00 0.1487 ± 4%
0.25 24.05 3.062 ± 4%
0.25 46.99 1.472 ± 4%
0.25 75.80 0.8028 ± 4%
0.25 170.78 0.3220 ± 4%
0.25 393.50 0.1694 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 107 [m2/s]
0.75 50 2.883 ± 4%
0.75 75 1.765 ± 4%
0.75 100 1.227 ± 4%
0.75 150 0.7509 ± 4%
0.75 300 0.3996 ± 4%
0.50 50 2.473 ± 4%
0.50 75 1.485 ± 4%
0.50 100 1.015 ± 4%
0.50 150 0.6271 ± 4%
0.50 300 0.3586 ± 4%
0.25 50 2.050 ± 4%
0.25 75 1.186 ± 4%
0.25 100 0.7885 ± 4%
0.25 150 0.5029 ± 4%
0.25 300 0.3247 ± 4%

CH4 (1) methane 74-82-8

x1 p [atm] D · 107 [m2/s]
0.75 50 1.682 ± 4%
0.75 75 1.039 ± 4%
0.75 100 0.7219 ± 4%
0.75 150 0.4407 ± 4%
0.75 300 0.2360 ± 4%
0.50 50 1.367 ± 4%
0.50 75 0.8263 ± 4%
0.50 100 0.5697 ± 4%
0.50 150 0.3498 ± 4%
0.50 300 0.1990 ± 4%
0.25 50 1.053 ± 4%
0.25 75 0.6066 ± 4%
0.25 100 0.4037 ± 4%
0.25 150 0.2558 ± 4%
0.25 300 0.1629 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 107 [m2/s]
0.50 70.73 1.579 ± 4%
0.50 111.80 0.8896 ± 4%
0.50 174.55 0.5278 ± 4%
0.50 301.15 0.3550 ± 4%
0.50 460.45 0.2299 ± 4%
CH4 (1) methane 74-82-8

x1 p [atm] D · 107 [m2/s]
0.50 124.80 0.4148 ± 4%
0.50 188.23 0.2880 ± 4%
0.50 292.61 0.1999 ± 4%
0.50 460.18 0.1309 ± 4%
CH4 (1) methane 74-82-8

0.1455 0.0079 0 0.04%
Comment: T = 300 K; D12 [m2/s] = D · 10–4

CH4 (1) methane 74-82-8

–3.2028 2.9646 0.9876 0.03%
2 –4
Comment: x2 = 0.15; D12 [m /s] = D · 10
References
1975K7 Khoury, F.M., Kobayashi, R.: Physica A 80 (1975) 1–24.
1975K6 Khoury, F.M., Kobayashi, R.: Int. Congr. Chem. Eng., Chem. Equip. Des. Autom., Proc., 5th
(1975), Volume F, F2.8, 17 pp.; Publisher: 5th Congr. CHISA, Prague, Czech. F (1975).
478–480.

Diffusion of methane (1); chloro-methane (2) 1
Diffusion of methane (1); chloro-methane (2)

Gaseous Mixtures
CH4 (1) methane 74-82-8

T [K] p [Torr] D · 104 [m2/s]
297.6 740.0 0.1458
298.2 738.5 0.1453
358.0 738.5 0.2090
378.2 743.1 0.2297
418.2 744.7 0.2795
438.4 733.3 0.3112
477.8 735.2 0.3632
Reference

Diffusion of methane (1); ethane (2) 1
Diffusion of methane (1); ethane (2)

Gaseous Mixtures
CH4 (1) methane 74-82-8

C2H6 (2) ethane 74-84-0
Integral Diffusion Coefficient: D(T ); Method: CORR Ref.: 1978A1
T [K] p [kPa] D · 105 [m2/s]
298.15 101.325 1.50
333.15 101.325 1.87
373.15 101.325 2.29
418.15 101.325 2.86
468.15 101.325 3.49
Comment: calculated from viscosity
CH4 (1) methane 74-82-8

C2H6 (2) ethane 74-84-0
Intradiffusion Coefficient: D12(T ); x1 = 0.50; Method: CT Ref.: 1974G4
T [K] p [Torr] D · 104 [m2/s]
298.0 733.6 0.1615
378.2 739.8 0.2520
437.8 743.9 0.3274
CH4 (1) methane 74-82-8

C2H6 (2) ethane 74-84-0
0.1588 0 0 0.05%
Comment: T = 300 K
CH4 (1) methane 74-82-8

C2H6 (2) ethane 74-84-0
–0.2404 0.1973 1.3740 0.04%
References
1978A1 Abe, Y., Kestin, J., Khalifa, H.E., Wakeham, W.A.: Physica A 93 (1978) 155–170.

Diffusion of methane (1); propane-d8 (2) 1
Diffusion of methane (1); propane-d8 (2)

Gaseous Mixtures
CH4 (1) methane 74-82-8

C3D8 (2) propane-d8 2875-94-7
Intradiffusion Coefficient: D1T(x1); T = 364.26 ± 0.17 K; Method: NMR FG Ref.: 1969W3
x1 p [bar] D · 108 [m2/s]
0.306 121.69 5.88 ± 1%
0.306 138.93 5.22 ± 1%
0.306 156.17 4.73 ± 1%
0.306 173.40 4.47 ± 1%
0.500 121.69 10.16 ± 1%
0.500 138.93 8.58 ± 1%
0.500 156.17 7.51 ± 1%
0.500 173.40 6.79 ± 1%
0.704 121.69 15.07 ± 1%
0.704 138.93 13.15 ± 1%
0.704 156.17 11.79 ± 1%
0.704 173.40 10.29 ± 1%
CH4 (1) methane 74-82-8

C3D8 (2) propane-d8 2875-94-7
Intradiffusion Coefficient: DD2T(x1); T = = 364.26 ± 0.17 K; Method: NMR FG Ref.: 1969W3
x1 p [bar] D · 108 [m2/s]
0.306 121.69 4.17 ± 5%
0.306 138.93 3.51 ± 5%
0.306 156.17 3.26 ± 5%
0.306 173.40 3.15 ± 5%
0.514 121.69 6.06 ± 5%
0.514 138.93 5.05 ± 5%
0.514 156.17 4.54 ± 5%
0.514 173.40 4.13 ± 5%
0.704 121.69 8.79 ± 5%
0.704 138.93 8.28 ± 5%
0.704 156.17 7.53 ± 5%
0.704 173.40 6.61 ± 5%
CH4 (1) methane 74-82-8

C3D8 (2) propane-d8 2875-94-7
x1 p [bar] D · 108 [m2/s]
0.306 121.69 3.60 ± 1%
0.306 138.93 3.38 ± 1%
0.306 156.17 3.25 ± 1%
0.306 173.40 3.03 ± 1%
(continued)

2 Diffusion of methane (1); propane-d8 (2)
0.500 121.69 6.17 ± 1%

0.500 138.93 5.30 ± 1%
0.500 156.17 4.86 ± 1%
0.500 173.40 4.50 ± 1%
0.704 121.69 10.86 ± 1%
0.704 138.93 9.19 ± 1%
0.704 156.17 7.85 ± 1%
0.704 173.40 7.03 ± 1%
CH4 (1) methane 74-82-8

C3D8 (2) propane-d8 2875-94-7
x1 p [bar] D · 108 [m2/s]
0.306 121.69 2.52 ± 5%
0.306 138.93 2.41 ± 5%
0.306 156.17 2.29 ± 5%
0.306 173.40 2.13 ± 5%
0.514 121.69 3.88 ± 5%
0.514 138.93 3.82 ± 5%
0.514 156.17 3.94 ± 5%
0.514 173.40 3.51 ± 5%
0.704 121.69 6.46 ± 5%
0.704 138.93 5.60 ± 5%
0.704 156.17 5.07 ± 5%
0.704 173.40 4.34 ± 5%
CH4 (1) methane 74-82-8

C3D8 (2) propane-d8 2875-94-7
x1 p [bar] D · 108 [m2/s]
0.306 121.69 2.31 ± 1%
0.306 138.93 2.29 ± 1%
0.306 156.17 2.20 ± 1%
0.306 173.40 2.14 ± 1%
0.500 121.69 3.48 ± 1%
0.500 138.93 3.275 ± 1%
0.500 156.17 3.07 ± 1%
0.500 173.40 2.97 ± 1%
0.704 121.69 6.55 ± 1%
0.704 138.93 5.69 ± 1%
0.704 156.17 5.02 ± 1%
0.704 173.40 4.69 ± 1%

Diffusion of methane (1); propane-d8 (2) 3
CH4 (1) methane 74-82-8

C3D8 (2) propane-d8 2875-94-7
x1 p [bar] D · 108 [m2/s]
0.306 121.69 1.63 ± 5%
0.306 138.93 1.55 ± 5%
0.306 156.17 1.57 ± 5%
0.306 173.40 1.49 ± 5%
0.514 121.69 2.47 ± 5%
0.514 138.93 2.25 ± 5%
0.514 156.17 2.19 ± 5%
0.514 173.40 2.04 ± 5%
0.704 121.69 4.37 ± 5%
0.704 138.93 3.61 ± 5%
0.704 156.17 3.82 ± 5%
0.704 173.40 3.53 ± 5%
Reference
(1969) 779–787.

Diffusion of methane (1); propane (2) 1
Diffusion of methane (1); propane (2)

Gaseous Mixtures
CH4 (1) methane 74-82-8

C3H8 (2) propane 74-98-6
); Method: CORR
Integral Diffusion Coefficient: D(T Ref.: 1978A1
T [K] p [kPa] D · 105 [m2/s]
298.15 101.325 1.20
333.15 101.325 1.49
373.15 101.325 1.84
418.15 101.325 2.29
468.15 101.325 2.80
CH4 (1) methane 74-82-8

C3H8 (2) propane 74-98-6
Intradiffusion Coefficient: D12(T ); Method: CT Ref.: 1974G4
T [K] p [Torr] D · 104 [m2/s]
298.0 735.6 0.1262
378.2 737.8 0.2013
437.6 738.5 0.2639
438.4 733.2 0.2669
Comment: equimolar composition
CH4 (1) methane 74-82-8

C3H8 (2) propane 74-98-6
0.1265 0 0 0.06%
Comment: T = 300 K
CH4 (1) methane 74-82-8

C3H8 (2) propane 74-98-6
–0.0240 –0.0003 1.3797 0.06%
References

Diffusion of methane (1); 2-methyl-propane (2) 1
Diffusion of methane (1); 2-methyl-propane (2)

Gaseous Mixtures
CH4 (1) methane 74-82-8

C4H10 (2) 2-methyl-propane 75-28-5
T [K] p [Torr] D · 104 [m2/s]
298.0 735.2 0.1067
378.3 729.2 0.1722
436.3 733.5 0.2236
Reference

Diffusion of methane (1); butane (2) 1
Diffusion of methane (1); butane (2)

Gaseous Mixtures
CH4 (1) methane 74-82-8

C4H10 (2) butane 106-97-8
Integral Diffusion Coefficient: D (T); Method: CORR Ref.: 1978A1
T [K] p [kPa] D · 105 [m2/s]
298.15 101.325 1.02
333.15 101.325 1.28
373.15 101.325 1.57
418.15 101.325 1.98
468.15 101.325 2.41
CH4 (1) methane 74-82-8

C4H10 (2) butane 106-97-8
T [K] p [Torr] D · 104 [m2/s]
298.3 731.4 0.1079
378.2 737.6 0.1704
436.3 733.3 0.2243
CH4 (1) methane 74-82-8

C4H10 (2) butane 106-97-8
0.1078 0 0 0.04%
Comment: T = 300 K
CH4 (1) methane 74-82-8

C4H10 (2) butane 106-97-8
–0.0193 0.0284 1.1242 0.07%
References

Diffusion of methane (1); 2,2-dimethyl-propane (2) 1
Diffusion of methane (1); 2,2-dimethyl-propane (2)

Gaseous Mixtures
CH4 (1) methane 74-82-8

C5H12 (2) 2,2-dimethyl-propane 463-82-1
T [K] p [Torr] D · 104 [m2/s]
298.0 734.5 0.09219
378.2 741.9 0.1452
436.2 733.5 0.1923
Reference

Diffusion of methane (1); sulfur hexafluoride (2) 1
Diffusion of methane (1); sulfur hexafluoride (2)

Gaseous Mixtures
CH4 (1) methane 74-82-8

T [K] p [Torr] D · 104 [m2/s]
297.6 747.6 0.1145
298.2 739.0 0.1136
357.9 733.5 0.1617
378.1 745.3 0.1757
418.2 742.8 0.2121
438.3 737.8 0.2323
477.9 729.4 0.2768
CH4 (1) methane 74-82-8

1.10 1.657 69.2
2
Comment: x1 = 0.50; D12(T ) · p [atm · cm /s] = (D · p); Marrero‐Mason group III
References

Diffusion of methane (1); helium (2) 1
Diffusion of methane (1); helium (2)

Gaseous Mixtures
CH4 (1) methane 74-82-8

He (2) helium 7440-59-7
Mutual Diffusion Coefficient: D12(T ); Method: ARF Ref.: 1976C6
T [K] p [kPa] D · 104 [m2/s]
294.7 101.325 0.662*
294.7 101.325 0.680
296.6 101.325 0.670*
296.6 101.325 0.687
372.0 101.325 0.999*
372.0 101.325 1.027
Reference

Diffusion of methane (1); krypton (2) 1
Diffusion of methane (1); krypton (2)

Gaseous Mixtures
CH4 (1) methane 74-82-8

Kr (2) krypton 7439-90-9
x2 p [kPa] D · 109 [m2/s]
0.0 101.325 6.7 ± 11%
0.2 101.325 5.7 ± 11%
0.4 101.325 4.8 ± 11%
0.6 101.325 4.2 ± 11%
0.8 101.325 3.3 ± 11%
CH4 (1) methane 74-82-8

Kr (2) krypton 7439-90-9
Intradiffusion Coefficient: D1T(x2); T = 130 K; Method: NMR FG Ref.: 1979M3
x2 p [kPa] D · 109 [m2/s]
0.0 101.325 8.8 ± 11%
0.2 101.325 8.3 ± 11%
0.4 101.325 7.3 ± 11%
0.6 101.325 6.5 ± 11%
0.8 101.325 6.1 ± 11%
CH4 (1) methane 74-82-8

Kr (2) krypton 7439-90-9
x2 p [kPa] D · 109 [m2/s]
0.0 101.325 11.0 ± 11%
0.2 101.325 10.7 ± 11%
0.4 101.325 10.2 ± 11%
0.6 101.325 9.3 ± 11%
0.8 101.325 8.4 ± 11%
CH4 (1) methane 74-82-8

Kr (2) krypton 7439-90-9
x2 p [kPa] D · 109 [m2/s]
0.0 101.325 14.5 ± 11%
0.2 101.325 13.8 ± 11%
0.4 101.325 13.6 ± 11%
0.6 101.325 13.2 ± 11%
0.8 101.325 13.0 ± 11%

2 Diffusion of methane (1); krypton (2)
CH4 (1) methane 74-82-8

Kr (2) krypton 7439-90-9
x2 p [kPa] D · 109 [m2/s]
0.0 101.325 18.2 ± 11%
0.2 101.325 18.0 ± 11%
0.4 101.325 17.7 ± 11%
0.6 101.325 17.4 ± 11%
0.8 101.325 17.2 ± 11%
CH4 (1) methane 74-82-8

Kr (2) krypton 7439-90-9
x2 p [kPa] D · 109 [m2/s]
0.0 101.325 23.5 ± 11%
0.2 101.325 22.7 ± 11%
0.4 101.325 22.0 ± 11%
0.6 101.325 21.5 ± 11%
0.8 101.325 21.0 ± 11%
CH4 (1) methane 74-82-8

Kr (2) krypton 7439-90-9
x2 p [kPa] D · 109 [m2/s]
0.0 101.325 28.7 ± 11%
0.2 101.325 28.5 ± 11%
0.4 101.325 28.4 ± 11%
0.6 101.325 28.2 ± 11%
0.8 101.325 27.8 ± 11%
CH4 (1) methane 74-82-8

Kr (2) krypton 7439-90-9
Intradiffusion Coefficient: D1T(T ); Method: CC Ref.: 1977C4
T [K] p [atm] D · 107 [m2/s]
219.33 18.98 3.50 ± 0.00
219.69 43.59 1.27 ± 0.06
219.47 53.73 0.97 ± 0.05
219.55 59.87 0.70 ± 0.02
219.37 63.69 0.61 ± 0.02
219.36 68.24 0.51 ± 0.01
219.62 70.74 0.42 ± 0.02
219.44 72.16 0.47 ± 0.01
219.80 73.04 0.47 ± 0.01
219.31 73.43 0.37 ± 0.01
219.49 76.74 0.33 ± 0.01
219.74 81.77 0.30 ± 0.01
(continued)
Diffusion of methane (1); krypton (2) 3
219.62 97.82 0.197 ± 0.007

219.09 100.03 0.190 ± 0.007
215.05 97.62 0.18 ± 0.02
201.86 96.92 0.107 ± 0.009
180.39 94.75 0.062 ± 0.003
174.66 95.19 0.056 ± 0.005
CH4 (1) methane 74-82-8

Kr (2) krypton 7439-90-9
Mutual Diffusion Coefficient: D12(T ); Method: CT Ref.: 1978A10
–4.3961 3.6896 1.2438 0.03%
2 –4
Comment: x2 = 0.15; D12 [m /s] = D · 10
CH4 (1) methane 74-82-8

Kr (2) krypton 7439-90-9
Mutual Diffusion
Coefficient: D12(x2); Method: CT Ref.: 1978A10
0.1786 0.0008 0 0.02%
Comment: T = 300 K; D12 [m2/s] = D · 10–4
References
1979M3 Mikhailenko, S.A., Yakuba, V.V.: Ukr. Fiz. Zh. 24 (1979) 612–619.
1977C4 Codastefano, P., Ricci, M.A., Rocca, D.: Phys. Rev. A 15 (1977) 2103–2107.
478–480.

Diffusion of methane (1); nitrogen (2) 1
Diffusion of methane (1); nitrogen (2)

Gaseous Mixtures
CH4 (1) methane 74-82-8

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
294.4 101.325 0.226*
294.4 101.325 0.226
CH4 (1) methane 74-82-8

N2 (2) nitrogen 7727-37-9
5.54 11/6
CH4 (1) methane 74-82-8

N2 (2) nitrogen 7727-37-9
1.00 1.750
References

Diffusion of methane (1); oxygen (2) 1
Diffusion of methane (1); oxygen (2)

Gaseous Mixtures
CH4 (1) methane 74-82-8

O2 (2) (2) oxygen 7782-44-7
5
1.68 1.695 44.2
Reference

Diffusion of methanol (1); Air (2) 1
Diffusion of methanol (1); Air (2)

Gaseous Mixtures
CH4O (1) methanol 67-56-1

Air (2) air 132259-10-0
Integral Diffusion Coefficient: D (xi); T = 328.15 ± 0.005 K; Method: OTE Ref.: 1968M10
x1 p [kPa] D · 104 [m2/s]
0.000 101.325 0.195
0.148 101.325 0.196
0.242 101.325 0.196
0.473 101.325 0.197
Reference
1968M10 Mrazek, R.V., Wicks, C.E., Prabhu, K.N.S.: J. Chem. Eng. Data 13 (1968) 508–510.

Diffusion of carbon monoxide (1); Air (2) 1
Diffusion of carbon monoxide (1); Air (2)

Gaseous Mixtures

Air (2) air 132259-10-0
5
1.12 1.730
Reference

Diffusion of carbon monoxide (1); carbon dioxide (2) 1
Diffusion of carbon monoxide (1); carbon dioxide (2)

Gaseous Mixtures

0.577 1.803
Reference

Diffusion of carbon monoxide (1); sulfur hexafluoride (2) 1
Diffusion of carbon monoxide (1); sulfur hexafluoride (2)

Gaseous Mixtures

5
1.76 1.584 139.4
Reference

Diffusion of carbon monoxide (1); oxygen (2) 1
Diffusion of carbon monoxide (1); oxygen (2)

Gaseous Mixtures

O2 (2) oxygen 7782-44-7
5
1.13 1.724
Reference

Diffusion of carbon dioxide (1); argon (2) 1
Diffusion of carbon dioxide (1); argon (2)

Gaseous Mixtures

Ar (2) argon 7440-37-1
Mutual Diffusion Coefficient: D12(T ); Method: TB Ref.: 1977G1
T [K] p [kPa] D · 108 [m2/s]
313.15 101.325 4.85
310.15 101.325 4.74
308.15 101.325 4.33
306.15 101.325 3.25
304.65 101.325 1.83
302.65 101.325 0.953
301.45 101.325 0.688
300.95 101.325 0.213
Comment: x2 = 0.0485; measurements close to the critical point of carbon dioxide

Ar (2) argon 7440-37-1
Intradiffusion Coefficient: D12(T ); Method: OEC Ref.: 1966P3
T [K] p [kPa] D · 104 [m2/s]
1132 101.325 1.71 ± 5%
1146 101.325 1.77 ± 5%
1280 101.325 2.10 ± 5%
1366 101.325 2.27 ± 5%
1378 101.325 2.31 ± 5%
1501 101.325 2.75 ± 5%
1545 101.325 2.96 ± 5%
1662 101.325 3.32 ± 5%
1717 101.325 3.47 ± 5%
1722 101.325 3.35 ± 5%
1761 101.325 3.50 ± 5%
1798 101.325 3.71 ± 5%
Comment: mole fraction of component 2: x2 = 0.10

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
1185 101.325 1.83 ± 5%
1388 101.325 2.13 ± 5%
1403 101.325 2.43 ± 5%
1427 101.325 2.53 ± 5%
1439 101.325 2.47 ± 5%
(continued)

2 Diffusion of carbon dioxide (1); argon (2)
1495 101.325 2.65 ± 5%

1633 101.325 3.14 ± 5%

Ar (2) argon 7440-37-1
Mutual Diffusion Coefficient: D12(T ); Method: OEC Ref.: 1966P3
T [K] p [kPa] D · 104 [m2/s]
1181 101.325 1.88 ± 5%
1207 101.325 1.88 ± 5%
1225 101.325 2.01 ± 5%
1315 101.325 2.38 ± 5%
1364 101.325 2.39 ± 5%
1368 101.325 2.59 ± 5%
1371 101.325 2.48 ± 5%
1380 101.325 2.43 ± 5%
1445 101.325 2.66 ± 5%
1482 101.325 2.71 ± 5%
1503 101.325 2.84 ± 5%
1538 101.325 3.08 ± 5%
1600 101.325 3.17 ± 5%
1676 101.325 3.21 ± 5%

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
1182 101.325 1.96 ± 5%

Ar (2) argon 7440-37-1
Intradiffusion Coefficient: D1T(x2); T = 348.15 K; Method: PF Ref.: 1968T3
x2 p [atm] D · 107 [m2/s]
1.000 13.99 13.9
1.000 50.6 3.90
1.000 50.9 3.94
1.000 98.5 2.04
1.000 104.5 1.92
1.000 157.6 1.28
1.000 202.5 1.03
1.000 239.4 0.872
0.719 13.83 13.0
0.719 45.4 3.88
0.719 52.9 3.40
(continued)

0.719 112.5 1.53

0.719 151.1 1.16
0.719 196.5 0.878
0.719 247.1 0.701
0.497 14.44 11.7
0.497 52.1 3.14
0.497 52.1 3.16
0.497 101.0 1.57
0.497 153.3 0.980
0.497 200.4 0.738
0.245 14.42 11.0
0.245 14.43 11.0
0.245 51.3 2.90
0.245 51.6 2.92
0.245 101.5 1.31
0.245 156.2 0.771
Comment: CO2 diffusing in a mixture of 12CO2 + Ar

Ar (2) argon 7440-37-1
x2 p [atm] D · 107 [m2/s]
1.000 14.50 11.7
1.000 14.96 11.6
1.000 15.35 11.2
1.000 64.2 2.69
1.000 69.0 2.47
1.000 102.2 1.68
1.000 114.1 1.50
1.000 147.6 1.21
1.000 151.9 1.15
1.000 171.4 1.03
1.000 209.5 0.869
1.000 220.7 0.834
1.000 249.8 0.741
0.719 14.51 10.7
0.719 15.02 10.5
0.719 15.31 10.1
0.719 51.3 3.00
0.719 52.2 2.95
0.719 52.7 2.91
0.719 75.6 2.00
0.719 86.6 1.75
0.719 96.2 1.56
0.719 101.2 1.47
0.719 103.2 1.45
0.719 110.2 1.34
0.719 135.7 1.10
(continued)
4 Diffusion of carbon dioxide (1); argon (2)
0.719 150.4 0.963

0.719 200.4 0.710
0.719 205.5 0.685
0.719 248.5 0.583
0.719 252.9 0.566
0.497 14.44 9.88
0.497 14.44 9.80
0.497 14.45 9.81
0.497 54.4 2.51
0.497 103.8 1.24
0.497 104.2 1.22
0.497 151.3 0.789
0.497 200.5 0.584
0.497 245.5 0.475
0.245 14.36 9.09
0.245 14.39 9.03
0.245 14.49 9.17
0.245 51.4 2.37
0.245 54.6 2.20
0.245 105.9 0.933
0.245 150.3 0.567
0.245 191.4 0.424

Ar (2) argon 7440-37-1
x2 p [atm] D · 107 [m2/s]
1.000 10.57 14.1
1.000 20.6 7.46
1.000 20.8 7.35
1.000 20.9 7.24
1.000 30.9 4.95
1.000 40.7 3.76
1.000 51.6 2.97
1.000 60.8 2.48
1.000 97.6 1.56
1.000 151.6 1.01
1.000 204.8 0.793
1.000 249.8 0.666
0.719 14.61 9.40
0.719 20.4 6.54
0.719 60.3 2.17
0.719 102.6 1.26
0.719 151.6 0.804
0.719 200.4 0.621
0.719 201.5 0.601
0.719 247.5 0.495
(continued)
0.497 14.48 8.77

0.497 20.3 6.09
0.497 61.9 1.84
0.497 90.9 1.14
0.497 102.7 1.00
0.497 146.3 0.650
0.497 150.1 0.626
0.497 199.7 0.447
0.245 20.7 5.48
0.245 30.9 3.54
0.245 31.3 3.43
0.245 51.1 1.91
0.245 51.2 1.97
0.245 70.2 1.24
0.245 101.0 0.652
0.245 120.1 0.447
0.245 148.4 0.334
References
1977G1 Gurvich, V.S., Lukin, L.P., Matizen, E.V.: Zh. Eksp. Teor. Fiz. 73 (1977) 671–680.
1966P3 Pakurar, T.A., Ferron, J.R.: Ind. Eng. Chem. Fundam. 5 (1966) 553–557.
1968T3 Takahashi, S.: Bull. Chem. Soc. Jpn. 41 (1968) 1573–1577.

Diffusion of carbon dioxide (1); methane (2) 1
Diffusion of carbon dioxide (1); methane (2)

Gaseous Mixtures

CH4 (2) methane 74-82-8
x2 p [atm] D · 107 [m2/s]
0.731 14.38 14.6
0.731 14.41 14.8
0.731 50.4 4.00
0.731 50.9 4.04
0.731 105.2 1.85
0.731 156.1 1.22
0.731 199.6 0.959
0.731 251.0 0.771
0.522 14.41 13.3
0.522 14.45 13.0
0.522 50.6 3.55
0.522 50.8 3.50
0.522 102.0 1.67
0.522 102.8 1.67
0.522 151.6 1.07
0.522 199.5 0.817
0.522 252.7 0.664
0.243 14.41 11.2
0.243 14.41 11.4
0.243 50.6 2.89
0.243 50.6 2.96
0.243 103.0 1.28
0.243 147.3 0.798
0.243 149.7 0.773
0.243 203.1 0.525
0.243 249.4 0.419
Comment: CO2 diffusing in a mixture of 12CO2 + methane

CH4 (2) methane 74-82-8
x2 p [atm] D · 107 [m2/s]
0.731 14.14 12.2
0.731 14.41 12.2
0.731 14.41 12.3
0.731 50.2 3.46
0.731 50.2 3.44
0.731 103.0 1.55
0.731 150.6 0.979
(continued)
2 Diffusion of carbon dioxide (1); methane (2)
0.731 201.0 0.723

0.731 252.3 0.586
0.522 14.41 10.8
0.522 14.43 11.2
0.522 50.0 3.01
0.522 102.8 1.26
0.522 146.1 0.816
0.522 200.7 0.575
0.522 250.2 0.455
0.243 14.41 10.00
0.243 14.41 9.64
0.243 50.2 2.54
0.243 50.3 2.40
0.243 102.8 0.912
0.243 128.2 0.581
0.243 168.4 kPa 0.456

CH4 (2) methane 74-82-8
x2 p [atm] D · 107 [m2/s]
0.731 14.43 10.5
0.731 14.47 10.6
0.731 50.4 2.87
0.731 50.5 2.80
0.731 102.0 1.22
0.731 151.3 0.770
0.731 201.3 0.569
0.731 245.7 0.497
0.731 251.5 0.467
0.522 14.41 9.44
0.522 14.44 9.33
0.522 50.2 2.40
0.522 50.5 2.42
0.522 102.3 1.01
0.522 149.0 0.530
0.522 183.3 0.473
0.522 247.6 0.355
0.243 14.41 8.12
0.243 14.51 7.94
0.243 50.5 1.87
0.243 50.6 1.89
0.243 50.7 1.83
0.243 72.9 1.07
0.243 99.2 0.580
0.243 100.2 0.572
0.243 117.4 0.409
(continued)
0.243 130.0 0.357

0.243 144.9 0.313
0.243 197.3 0.234
0.243 250.8 0.224

CH4 (2) methane 74-82-8
x2 p [atm] D · 107 [m2/s]
1.000 14.41 21.3
1.000 50.1 5.97
1.000 103.0 2.85
1.000 105.0 2.73
1.000 153.1 1.93
1.000 202.3 1.44
1.000 243.5 1.21
1.000 250.0 1.17
0.522 15.30 17.0
0.522 15.38 17.1
0.522 50.4 5.09
0.522 50.5 5.04
0.522 69.2 3.53
0.522 100.9 2.23
0.522 133.8 1.65
0.522 173.9 1.24
0.522 233.8 0.892
0.000 14.41 14.9
0.000 14.41 14.6
0.000 50.0 3.65
0.000 51.0 3.63
0.000 72.3 2.22
0.000 72.5 2.19
0.000 104.8 1.28
0.000 123.3 0.910
0.000 129.2 0.837
0.000 155.3 0.633
Comment: CH3T as trace in the binary mixtures

CH4 (2) methane 74-82-8
x2 p [atm] D · 107 [m2/s]
1.000 14.38 18.2
1.000 14.44 18.8
1.000 51.1 4.95
1.000 51.3 5.05
(continued)
1.000 103.3 2.40

1.000 151.2 1.66
1.000 201.5 1.26
1.000 252.3 1.01
0.522 14.41 16.5
0.522 49.0 4.45
0.522 81.2 2.44
0.522 104.1 1.85
0.522 124.2 1.42
0.522 161.2 1.03
0.522 199.4 0.813
0.000 14.33 12.5
0.000 14.41 12.4
0.000 50.0 3.06
0.000 50.3 2.99
0.000 60.0 2.25
0.000 76.2 1.50
0.000 82.5 1.26
0.000 92.9 0.935
0.000 102.2 0.620

CH4 (2) methane 74-82-8
x2 p [atm] D · 107 [m2/s]
1.000 14.41 16.5
1.000 24.7 9.41
1.000 50.2 4.58
1.000 66.0 3.46
1.000 103.2 2.03
1.000 151.5 1.39
1.000 175.9 1.12
1.000 211.7 0.970
0.522 14.41 14.7
0.522 14.41 14.2
0.522 14.41 14.4
0.522 45.5 4.32
0.522 49.9 3.77
0.522 99.0 1.56
0.522 101.1 1.58
0.522 149.3 0.833
0.522 149.3 0.843
0.522 149.3 0.878
0.522 153.1 0.814
0.000 14.41 11.3
0.000 36.5 3.69
0.000 36.6 3.61
(continued)
0.000 46.7 2.41

0.000 49.3 2.26
References
1970T1 Takahashi, S., Iwasaki, H.: Bull. Chem. Res. (Tohoku Univ.) 20 (1970) 27–36.

Diffusion of carbon dioxide (1); ethene (2) 1
Diffusion of carbon dioxide (1); ethene (2)

Gaseous Mixtures

C2H4 (2) ethene 74-85-1
Intradiffusion Coefficient: D1T(T ); Method: PF Ref.: 1982T2
T [K] p [MPa] D · 107 [m2/s]
298.2 0.101325 128.0*
298.2 1.097 11.1
298.2 1.099 10.7
298.2 2.066 5.58
298.2 2.068 5.66
298.2 2.931 3.70
298.2 2.941 3.69
298.2 5.05 1.57
298.2 5.13 1.44
298.2 6.80 0.684
298.2 6.81 0.721
298.2 8.87 0.422
298.2 9.91 0.444
298.2 10.94 0.353
298.2 10.95 0.348
323.2 0.101325 149.0*
323.2 1.095 12.6
323.2 1.099 12.9
323.2 2.067 6.12
323.2 2.074 6.35
323.2 2.946 4.33
323.2 2.949 4.20
323.2 4.02 2.94
323.2 4.02 2.93
323.2 5.18 2.13
323.2 5.18 2.19
323.2 7.50 1.11
323.2 7.53 1.14
323.2 9.97 0.643
323.2 10.17 0.655
323.2 12.50 0.518
323.2 12.50 0.513
323.2 15.05 0.455
323.2 17.08 0.406
323.2 17.61 0.400
348.2 0.101325 172.0*
348.2 1.097 14.9
348.2 1.099 15.2
348.2 2.069 7.67
348.2 2.072 7.75
(continued)
2 Diffusion of carbon dioxide (1); ethene (2)
348.2 3.022 5.13

348.2 3.032 4.97
348.2 4.00 3.64
348.2 4.09 3.43
348.2 5.15 2.71
348.2 6.94 1.86
348.2 8.81 1.28
348.2 11.30 0.868
348.2 13.21 0.721
348.2 15.18 0.618
348.2 15.85 0.600
348.2 18.77 0.514
Comment: *: extrapolated
Reference
1982T2 Takahashi, S., Hongo, M.: J. Chem. Eng. Jpn. 15 (1982) 57–59.

Diffusion of carbon dioxide (1); propane (2) 1
Diffusion of carbon dioxide (1); propane (2)

Gaseous Mixtures

C3H8 (2) propane 74-98-6
0.177 1.896
Comment: x1 = 0.50; D12(T ) · p [atm · cm2/s] = (D · p)
Reference

Diffusion of carbon dioxide (1); hexadecane (2) 1
Diffusion of carbon dioxide (1); hexadecane (2)

Gaseous Mixtures

C16H34 (2) hexadecane 544-76-3
Intradiffusion Coefficient: D1T(T ); Method: NMR PG Ref.: 1993E1
T [K] p [bar] D · 109 [m2/s]
308.15 ± 0.005 15.51 662.5 ± 0.7%
308.15 ± 0.005 42.20 207.3 ± 0.7%
308.15 ± 0.005 69.08 93.48 ± 0.7%
308.15 ± 0.005 79.80 31.02 ± 0.7%
308.15 ± 0.005 96.87 21.26 ± 0.7%
308.15 ± 0.005 124.10 17.24 ± 0.7%
308.15 ± 0.005 138.24 15.88 ± 0.7%
308.15 ± 0.005 143.55 15.49 ± 0.7%
313.15 ± 0.005 8.96 1156 ± 0.7%
313.15 ± 0.005 42.06 206.5 ± 0.7%
313.15 ± 0.005 69.64 97.33 ± 0.7%
313.15 ± 0.005 82.74 64.00 ± 0.7%
313.15 ± 0.005 116.52 20.30 ± 0.7%
323.15 ± 0.005 27.92 400.0 ± 0.7%
323.15 ± 0.005 55.72 168.37 ± 0.7%
323.15 ± 0.005 83.43 88.63 ± 0.7%
323.15 ± 0.005 110.32 36.72 ± 0.7%
323.15 ± 0.005 137.89 23.04 ± 0.7%
323.15 ± 0.005 155.13 19.39 ± 0.7%
323.15 ± 0.005 165.13 16.95 ± 0.7%
333.15 ± 0.005 7.58 441.5 ± 0.7%
333.15 ± 0.005 34.82 86.03 ± 0.7%
333.15 ± 0.005 68.95 35.96 ± 0.7%
333.15 ± 0.005 103.42 17.80 ± 0.7%
333.15 ± 0.005 137.89 10.05 ± 0.7%
333.15 ± 0.005 175.13 6.122 ± 0.7%

Intradiffusion Coefficient: D2T(T ); Method: NMR PG Ref.: 1993E1
T [K] p [bar] D · 109 [m2/s]
308.15 ± 0.005 7.93 357.4 ± 0.7%
308.15 ± 0.005 13.93 197.4 ± 0.7%
308.15 ± 0.005 42.20 54.37 ± 0.7%
308.15 ± 0.005 55.16 36.77 ± 0.7%
308.15 ± 0.005 68.95 23.88 ± 0.7%
308.15 ± 0.005 79.29 13.05 ± 0.7%
308.15 ± 0.005 83.08 8.844 ± 0.7%
308.15 ± 0.005 96.53 6.571 ± 0.7%
(continued)
2 Diffusion of carbon dioxide (1); hexadecane (2)
308.15 ± 0.005 110.32 6.088 ± 0.7%

308.15 ± 0.005 124.11 5.378 ± 0.7%
308.15 ± 0.005 137.89 3.500 ± 0.7%
313.15 ± 0.005 27.58 96.19 ± 0.7%
313.15 ± 0.005 41.37 58.70 ± 0.7%
313.15 ± 0.005 55.16 39.33 ± 0.7%
313.15 ± 0.005 68.95 25.70 ± 0.7%
313.15 ± 0.005 83.36 15.10 ± 0.7%
313.15 ± 0.005 93.08 9.561 ± 0.7%
313.15 ± 0.005 103.77 7.687 ± 0.7%
313.15 ± 0.005 117.35 6.670 ± 0.7%
323.15 ± 0.005 38.20 71.07 ± 0.7%
323.15 ± 0.005 68.95 31.64 ± 0.7%
323.15 ± 0.005 82.74 22.60 ± 0.7%
323.15 ± 0.005 96.53 15.31 ± 0.7%
323.15 ± 0.005 109.63 10.60 ± 0.7%
323.15 ± 0.005 124.11 9.064 ± 0.7%
323.15 ± 0.005 137.89 7.014 ± 0.7%
323.15 ± 0.005 151.68 6.249 ± 0.7%
323.15 ± 0.005 165.47 4.957 ± 0.7%
333.15 ± 0.005 18.96 596.9 ± 0.7%
333.15 ± 0.005 68.95 130.7 ± 0.7%
333.15 ± 0.005 102.80 70.06 ± 0.7%
333.15 ± 0.005 137.89 32.94 ± 0.7%
333.15 ± 0.005 174.09 20.29 ± 0.7%
333.15 ± 0.005 203.74 16.56 ± 0.7%
Reference
1993E1 Etesse, P., Chapman, W.G., Kobayashi, R.: Mol. Phys. 80 (1993) 1145–1164.

Diffusion of carbon dioxide (1); sulfur hexafluoride (2) 1
Diffusion of carbon dioxide (1); sulfur hexafluoride (2)

Gaseous Mixtures

0.140 1.886
Reference

Diffusion of carbon dioxide (1); nitrogen (2) 1
Diffusion of carbon dioxide (1); nitrogen (2)

Gaseous Mixtures

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
1141 101.325 1.79 ± 5%
1227 101.325 1.98 ± 5%
1383 101.325 2.45 ± 5%
1414 101.325 2.46 ± 5%
1421 101.325 2.67 ± 5%
1530 101.325 2.83 ± 5%
1542 101.325 2.96 ± 5%
1657 101.325 3.33 ± 5%
1680 101.325 3.33 ± 5%
1760 101.325 3.73 ± 5%
1810 101.325 3.82 ± 5%

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
1098 101.325 1.68 ± 5%
1262 101.325 2.08 ± 5%
1426 101.325 2.55 ± 5%
1490 101.325 2.92 ± 5%
1500 101.325 2.77 ± 5%
1708 101.325 3.51 ± 5%
1728 101.325 3.40 ± 5%

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
1081 101.325 1.64 ± 5%
1156 101.325 1.78 ± 5%
1158 101.325 1.92 ± 5%
1214 101.325 2.07 ± 5%
1275 101.325 2.21 ± 5%
1286 101.325 2.34 ± 5%
1333 101.325 2.26 ± 5%
1430 101.325 2.72 ± 5%
(continued)

2 Diffusion of carbon dioxide (1); nitrogen (2)
1469 101.325 2.85 ± 5%

1569 101.325 2.99 ± 5%
1588 101.325 3.15 ± 5%
1653 101.325 3.32 ± 5%
1670 101.325 3.43 ± 5%

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
1164 101.325 1.95 ± 5%
1191 101.325 2.08 ± 5%

N2 (2) nitrogen 7727-37-9
Intradiffusion Coefficient: D1T(x2); T = 298.15 ± 0.1 K; Method: PF Ref.: 1977T4
x2 p [atm] D · 107 [m2/s]
1.000 14.41 12.1 ± 3%
1.000 50.7 3.36 ± 3%
1.000 88.2 1.98 ± 3%
1.000 152.1 1.12 ± 3%
1.000 200.4 0.887 ± 3%
1.000 249.2 0.720 ± 3%
0.741 14.32 10.6 ± 3%
0.741 14.36 10.3 ± 3%
0.741 50.5 2.79 ± 3%
0.741 50.7 2.80 ± 3%
0.741 103.0 1.32 ± 3%
0.741 153.3 0.918 ± 3%
0.741 202.5 0.691 ± 3%
0.741 244.5 0.581 ± 3%
0.515 14.37 8.91 ± 3%
0.515 14.38 9.14 ± 3%
0.515 50.5 2.41 ± 3%
0.515 51.0 2.29 ± 3%
0.515 103.2 1.02 ± 3%
0.515 150.7 0.665 ± 3%
0.515 175.9 0.557 ± 3%
0.238 14.41 8.27 ± 3%
0.238 14.41 7.92 ± 3%
0.238 49.9 1.91 ± 3%
0.238 78.9 0.925 ± 3%
0.238 100.7 0.685 ± 3%
0.238 122.6 0.498 ± 3%
(continued)

0.238 124.5 0.421 ± 3%

0.238 147.5 0.373 ± 3%
Comment: CO2 diffusing in a mixture of 12CO2 + nitrogen

N2 (2) nitrogen 7727-37-9
x2 p [atm] D · 107 [m2/s]
1.000 14.37 13.6 ± 3%
1.000 50.5 3.73 ± 3%
1.000 100.8 1.93 ± 3%
1.000 154.3 1.26 ± 3%
1.000 201.8 0.975 ± 3%
1.000 253.3 0.831 ± 3%
0.741 14.41 11.5 ± 3%
0.741 50.6 3.21 ± 3%
0.741 103.8 1.48 ± 3%
0.741 151.5 1.04 ± 3%
0.741 199.5 0.803 ± 3%
0.741 250.1 0.643 ± 3%
0.515 14.35 10.6 ± 3%
0.515 14.36 11.1 ± 3%
0.515 51.6 2.64 ± 3%
0.515 102.4 1.22 ± 3%
0.515 151.3 0.785 ± 3%
0.515 209.7 0.567 ± 3%
0.238 14.41 9.02 ± 3%
0.238 50.6 2.20 ± 3%
0.238 74.3 1.35 ± 3%
0.238 101.8 0.853 ± 3%
0.238 124.0 0.695 ± 3%
0.238 150.7 0.536 ± 3%

N2 (2) nitrogen 7727-37-9
x2 p [atm] D · 107 [m2/s]
1.000 14.36 14.8 ± 3%
1.000 14.36 14.5 ± 3%
1.000 50.5 4.13 ± 3%
1.000 50.5 4.14 ± 3%
1.000 102.9 2.12 ± 3%
1.000 152.0 1.44 ± 3%
1.000 202.5 1.09 ± 3%
1.000 245.7 0.933 ± 3%
1.000 250.3 0.951 ± 3%
(continued)
0.741 14.41 13.2 ± 3%

0.741 14.41 13.1 ± 3%
0.741 50.2 3.70 ± 3%
0.741 102.9 1.82 ± 3%
0.741 103.0 1.70 ± 3%
0.741 153.1 1.17 ± 3%
0.741 200.5 0.933 ± 3%
0.741 247.0 0.776 ± 3%
0.515 14.24 11.8 ± 3%
0.515 14.28 11.8 ± 3%
0.515 50.4 3.23 ± 3%
0.515 50.6 3.17 ± 3%
0.515 103.4 1.49 ± 3%
0.515 148.7 1.01 ± 3%
0.515 197.4 0.747 ± 3%
0.515 249.1 0.575 ± 3%
0.238 13.27 11.8 ± 3%
0.238 50.1 2.88 ± 3%
0.238 50.4 2.74 ± 3%
0.238 100.5 1.24 ± 3%
0.238 141.4 0.793 ± 3%
0.238 197.3 0.542 ± 3%
References
1966P3 Pakurar, T.A., Ferron, J.R.: Ind. Eng. Chem. Fundam. 5 (1966) 553–557.
1977T4 Takahashi, S.: J. Chem. Eng. Jpn. 10 (1977) 258–261.

Diffusion of carbon dioxide (1); nitrous oxide (2) 1
Diffusion of carbon dioxide (1); nitrous oxide (2)

Gaseous Mixtures

N 2O (2) nitrous oxide 10024-97-2
0.281 1.866
Reference

Diffusion of ethene (1); carbon dioxide (2) 1
Diffusion of ethene (1); carbon dioxide (2)

Gaseous Mixtures
C2H4 (1) ethene 74-85-1

Intradiffusion Coefficient: D1T(T ); Method: PF Ref.: 1982T2
T [K] p [MPa] D · 107 [m2/s]
298.2 0.101325 0.122 · 10–4*
298.2 1.078 10.3
298.2 1.092 10.7
298.2 1.095 10.1
298.2 2.041 5.53
298.2 2.065 5.18
298.2 2.081 5.35
298.2 2.916 3.52
298.2 2.925 3.42
298.2 3.024 3.30
298.2 3.96 2.38
298.2 4.04 2.28
298.2 5.01 1.65
298.2 5.01 1.68
323.2 0.101325 0.143 · 10–4 *
323.2 1.093 12.4
323.2 1.099 11.8
323.2 2.068 6.25
323.2 2.078 6.21
323.2 2.946 4.14
323.2 2.949 4.28
323.2 4.10 2.31
323.2 4.12 2.69
323.2 5.11 2.15
323.2 5.13 2.11
323.2 6.47 1.52
323.2 8.68 0.890
323.2 9.85 0.641
323.2 11.32 0.427
323.2 13.42 0.326
323.2 15.67 0.297
323.2 20.31 0.233
348.2 0.101325 0.165 · 10–4 *
348.2 1.088 14.2
348.2 1.097 14.6
348.2 2.051 7.56
348.2 2.055 7.71
348.2 3.010 4.98
348.2 3.011 4.88
348.2 4.02 3.52
(continued)
2 Diffusion of ethene (1); carbon dioxide (2)
348.2 4.02 3.63

348.2 5.02 2.74
348.2 5.04 2.70
348.2 6.98 1.82
348.2 6.99 1.92
348.2 9.22 1.30
348.2 11.52 0.869
348.2 13.73 0.643
348.2 15.91 0.496
348.2 18.12 0.417
348.2 20.22 0.365
Reference
1982T2 Takahashi, S., Hongo, M.: J. Chem. Eng. Jpn. 15 (1982) 57–59.

Diffusion of ethane (1); argon (2) 1
Diffusion of ethane (1); argon (2)

Gaseous Mixtures
C2H6 (1) ethane 74-84-0

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
302.5 101.325 0.149*
302.5 101.325 0.149
483.2 101.325 0.357*
Reference

Diffusion of ethane (1); tetrafluoro-methane (2) 1
Diffusion of ethane (1); tetrafluoro-methane (2)

Gaseous Mixtures
C2H6 (1) ethane 74-84-0

Integral Diffusion Coefficient: D (T ); Method: CORR Ref.: 1979A1
T [K] p [kPa] D · 105 [m2/s]
298.15 101.325 0.872
333.15 101.325 1.09
373.15 101.325 1.34
423.15 101.325 1.68
468.15 101.325 1.98
Reference
1979A1 Abe, Y., Kestin, J., Khalifa, H.E., Wakeham, W.A.: Ber. Bunsenges. Phys. Chem. 83 (1979)
271–276.

Diffusion of ethane (1); carbon dioxide (2) 1
Diffusion of ethane (1); carbon dioxide (2)

Gaseous Mixtures
C2H6 (1) ethane 74840

CO2 (2) carbon dioxide 124389
T [K] p [kPa] D · 105 [m2/s]
298.15 101.325 1.11
333.15 101.325 1.38
373.15 101.325 1.70
418.15 101.325 2.10
468.15 101.325 2.58
Reference
271–276.

Diffusion of ethane (1); propane-1-sulfonyl chloride (2) 1
Diffusion of ethane (1); propane-1-sulfonyl chloride (2)

Gaseous Mixtures
C2H6 (1) ethane 74-84-0

C3H7ClO2S (2) propane-1-sulfonyl chloride 10147-36-1
T [K] p [kPa] D · 105 [m2/s]
298.15 101.325 0.78
333.15 101.325 0.98
373.15 101.325 1.20
418.15 101.325 1.49
468.15 101.325 1.85
Reference

Diffusion of ethane (1); propane (2) 1
Diffusion of ethane (1); propane (2)

Gaseous Mixtures
C2H6 (1) ethane 74-84-0

C3H8 (2) propane 74-98-6
T [K] p [Torr] D · 104 [m2/s]
298.0 740.8 0.08041
378.2 741.3 0.1316
437.6 737.7 0.1760
Reference

Diffusion of ethane (1); 2-methyl-propane (2) 1
Diffusion of ethane (1); 2-methyl-propane (2)

Gaseous Mixtures
C2H6 (1) ethane 74-84-0

T [K] p [Torr] D · 104 [m2/s]
298.0 731.8 0.06814
378.2 734.1 0.1106
436.9 735.6 0.1476
Reference

Diffusion of ethane (1); butane (2) 1
Diffusion of ethane (1); butane (2)

Gaseous Mixtures
C2H6 (1) ethane 74-84-0

C4H10 (2) butane 106-97-8
T [K] p [kPa] D · 105 [m2/s]
298.15 101.325 0.66
333.15 101.325 0.82
373.15 101.325 1.01
418.15 101.325 1.26
468.15 101.325 1.55
C2H6 (1) ethane 74-84-0

C4H10 (2) butane 106-97-8
T [K] p [Torr] D · 104 [m2/s]
298.0 733.4 0.06597
378.2 736.3 0.1085
437.2 737.4 0.1460
References

Diffusion of ethane (1); 2,2-dimethyl-propane (2) 1
Diffusion of ethane (1); 2,2-dimethyl-propane (2)

Gaseous Mixtures
C2H6 (1) ethane 74-84-0

T [K] p [Torr] D · 104 [m2/s]
298.0 735.3 0.05827
378.1 744.5 0.09290
436.1 734.4 0.1247
Reference

Diffusion of ethane (1); sulfur hexafluoride (2) 1
Diffusion of ethane (1); sulfur hexafluoride (2)

Gaseous Mixtures
C2H6 (1) ethane 74-84-0

Integral Diffusion Coefficient: D(T ); Method: CORR Ref.: 1979A1
T [K] p [kPa] D · 105 [m2/s]
298.15 101.325 0.681
333.15 101.325 0.840
373.15 101.325 1.04
423.15 101.325 1.32
468.15 101.325 1.56
Reference
271–276.

Diffusion of ethane (1); helium (2) 1
Diffusion of ethane (1); helium (2)

Gaseous Mixtures
C2H6 (1) ethane 74-84-0

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
294.5 101.325 0.482
298.1 101.325 0.516
Comment: at trace concentration of (1); exp. deviation: ±1%
Reference

Diffusion of ethane (1); nitrogen (2) 1
Diffusion of ethane (1); nitrogen (2)

Gaseous Mixtures
C2H6 (1) ethane 74-84-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
301.0 101.325 0.167*
301.0 101.325 0.167
483.2 101.325 0.381*
483.2 101.325 0.381
C2H6 (1) ethane 74-84-0

N2 (2) nitrogen 7727-37-9
Integral Diffusion Coefficient: D̄(T ); Method: CORR Ref.: 1979A1
T [K] p [kPa] D · 105 [m2/s]
298.15 101.325 1.45
333.15 101.325 1.78
373.15 101.325 2.20
418.15 101.325 2.69
468.15 101.325 3.27
References
271–276.

Diffusion of propene (1); krypton (2) 1
Diffusion of propene (1); krypton (2)

Gaseous Mixtures
C3H6 (1) propene 115-07-1

Kr (2) krypton 7439-90-9
x2 p [kPa] D · 109 [m2/s]
0.0 101.325 7.02 ± 10%
0.195 101.325 7.31 ± 10%
0.400 101.325 7.54 ± 10%
0.600 101.325 7.78 ± 10%
0.760 101.325 7.90 ± 10%
C3H6 (1) propene 115-07-1

Kr (2) krypton 7439-90-9
x2 p [kPa] D · 109 [m2/s]
0.0 101.325 4.65 ± 10%
0.195 101.325 4.98 ± 10%
0.400 101.325 5.25 ± 10%
0.600 101.325 5.46 ± 10%
0.760 101.325 5.62 ± 10%
C3H6 (1) propene 115-07-1

Kr (2) krypton 7439-90-9
x2 p [kPa] D · 109 [m2/s]
0.0 101.325 2.82 ± 10%
0.195 101.325 3.34 ± 10%
0.400 101.325 3.60 ± 10%
0.600 101.325 3.82 ± 10%
0.760 101.325 3.97 ± 10%
C3H6 (1) propene 115-07-1

Kr (2) krypton 7439-90-9
x2 p [kPa] D · 109 [m2/s]
0.0 101.325 2.03 ± 10%
0.195 101.325 2.31 ± 10%
0.400 101.325 2.52 ± 10%
0.600 101.325 2.80 ± 10%
0.760 101.325 2.94 ± 10%

2 Diffusion of propene (1); krypton (2)
C3H6 (1) propene 115-07-1

Kr (2) krypton 7439-90-9
x2 p [kPa] D · 109 [m2/s]
0.0 101.325 1.13 ± 10%
0.195 101.325 1.44 ± 10%
0.400 101.325 1.69 ± 10%
0.600 101.325 1.84 ± 10%
0.760 101.325 2.09 ± 10%
Reference
1982M2 Mikhailenko, S.A., Yakuba, V.V.: Ukr. Fiz. Zh. 27 (1982) 712–717.

Diffusion of propane (1); argon (2) 1
Diffusion of propane (1); argon (2)

Gaseous Mixtures
C3H8 (1) propane 74-98-6

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
301.8 101.325 0.106
483.2 101.325 0.247
C3H8 (1) propane 74-98-6

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 105 [m2/s]
298.15 101.325 0.846
333.15 101.325 1.06
373.15 101.325 1.31
418.15 101.325 1.61
468.15 101.325 1.99
References
271–276.

Diffusion of propane (1); 2-methyl-propane (2) 1
Diffusion of propane (1); 2-methyl-propane (2)

Gaseous Mixtures
C3H8 (1) propane 74-98-6

T [K] p [Torr] D · 104 [m2/s]
298.0 739.7 0.05066
378.2 738.8 0.08463
437.8 745.7 0.1136
Reference

Diffusion of propane (1); butane (2) 1
Diffusion of propane (1); butane (2)

Gaseous Mixtures
C3H8 (1) propane 74-98-6

C4H10 (2) butane 106-97-8
T [K] p [Torr] D · 104 [m2/s]
378.2 737.3 0.07921
437.7 745.7 0.1086
Reference

Diffusion of propane (1); butane-2,3-dione (2) 1
Diffusion of propane (1); butane-2,3-dione (2)

Gaseous Mixtures
C3H8 (1) propane 74-98-6

C4H6O2 (2) butane-2,3-dione 431-03-8
T [K] p [kPa] D · 105 [m2/s]
298.15 101.325 0.51
333.15 101.325 0.64
373.15 101.325 0.78
418.15 101.325 0.98
468.15 101.325 1.20
Reference

Diffusion of propane (1); 2,2-dimethyl-propane (2) 1
Diffusion of propane (1); 2,2-dimethyl-propane (2)

Gaseous Mixtures
C3H8 (1) propane 74-98-6

T [K] p [Torr] D · 104 [m2/s]
298.1 736.7 0.04450
378.2 741.9 0.07199
437.7 737.4 0.09736
Reference

Diffusion of propane (1); helium (2) 1
Diffusion of propane (1); helium (2)

Gaseous Mixtures
C3H8 (1) propane 74-98-6

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
294.4 101.325 0.392
296.6 101.325 0.411
C3H8 (1) propane 74-98-6

He (2) helium 7440-59-7
Mutual Diffusion Coefficient: D12(T ); Method: GC Ref.: 1984T2
Equation: log (D ) = A + B log (T ) Range: 294 < T/K < 333
Parameter: A B r
–8.1277 3.0805 0.9976
Comment: r = correlation coefficient
References
1984T2 Tang, F.-T., Hawkes, S.: J. Chem. Eng. Data 29 (1984) 124–125.

Diffusion of propane (1); nitrogen (2) 1
Diffusion of propane (1); nitrogen (2)

Gaseous Mixtures
C3H8 (1) propane 74-98-6

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 105 [m2/s]
298.15 101.325 1.13
333.15 101.325 1.39
373.15 101.325 1.72
418.15 101.325 2.10
468.15 101.325 2.57
C3H8 (1) propane 74-98-6

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
292.8 101.325 0.113*
292.8 101.325 0.113
297.5 101.325 0.122*
297.5 101.325 0.123
References
271–276.

Diffusion of butane (1); argon (2) 1
Diffusion of butane (1); argon (2)

Gaseous Mixtures
C4H10 (1) butane 106-97-8

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
297.1 101.325 0.096*
297.1 101.325 0.096
298.5 101.325 0.096*
298.5 101.325 0.096
476.7 101.325 0.276*
Reference

Diffusion of butane (1); carbon dioxide (2) 1
Diffusion of butane (1); carbon dioxide (2)

Gaseous Mixtures
C4H10 (1) butane 106-97-8

T [K] p [kPa] D · 105 [m2/s]
298.15 101.325 0.705
333.15 101.325 0.877
373.15 101.325 1.08
418.15 101.325 1.33
468.15 101.325 1.66
Reference
271–276.

Diffusion of 2-methyl-propane (1); 2,2-dimethyl-propane (2) 1
Diffusion of 2-methyl-propane (1); 2,2-dimethyl-propane

(2)
Gaseous Mixtures

Mutual Diffusion Coefficient: D12(T); x1 = 0.50; Method: CT Ref.: 1974G4
T [K] p [Torr] D · 104 [m2/s]
298.1 746.6 0.03682
378.2 741.6 0.05940
437.7 746.7 0.07999
Reference

Diffusion of butane (1); 2,2-dimethyl-propane (2) 1
Diffusion of butane (1); 2,2-dimethyl-propane (2)

Gaseous Mixtures
C4H10 (1) butane 106-97-8

T [K] p [Torr] D · 104 [m2/s]
298.0 733.5 0.04283
378.3 741.9 0.06598
437.8 741.0 0.08607
Reference

Diffusion of butane (1); helium (2) 1
Diffusion of butane (1); helium (2)

Gaseous Mixtures
C4H10 (1) butane 106-97-8

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
292.9 101.325 0.330*
292.9 101.325 0.337
296.6 101.325 0.347*
296.6 101.325 0.354
Reference

Diffusion of butane (1); nitrogen (2) 1
Diffusion of butane (1); nitrogen (2)

Gaseous Mixtures
C4H10 (1) butane 106-97-8

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 105 [m2/s]
298.15 101.325 0.940
333.15 101.325 1.16
373.15 101.325 1.44
418.15 101.325 1.76
468.15 101.325 2.16
C4H10 (1) butane 106-97-8

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
293.8 101.325 0.097*
293.8 101.325 0.097
371.9 101.325 0.141*
479.1 101.325 0.238*
481.2 101.325 0.237*
References
271–276.

Diffusion of 2,2-dimethyl-propane (1); argon (2) 1
Diffusion of 2,2-dimethyl-propane (1); argon (2)

Gaseous Mixtures

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
297.9 101.325 0.077
Reference

Diffusion of pentane (1); 2,2-dimethyl-propane (2) 1
Diffusion of pentane (1); 2,2-dimethyl-propane (2)

Gaseous Mixtures
C5H12 (1) pentane 109-66-0

Mutual Diffusion Coefficient: D12(T ); Method: CT Ref.: 1969B2
T [K] p [atm] D · 104 [m2/s]
273.1 0.2105 0.0185
273.1 0.2075 0.0196
273.1 0.2096 0.0198
Reference
1969B2 Beatty, J.W.: J. Chem. Phys. 51 (1969) 4673–4674.

Diffusion of 2,2-dimethyl-propane (1); helium (2) 1
Diffusion of 2,2-dimethyl-propane (1); helium (2)

Gaseous Mixtures

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
292.8 101.325 0.297
296.8 101.325 0.317
Reference

Diffusion of 2,2-dimethyl-propane (1); nitrogen (2) 1
Diffusion of 2,2-dimethyl-propane (1); nitrogen (2)

Gaseous Mixtures

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
293.6 101.325 0.078
297.4 101.325 0.089
Reference

Diffusion of hexachloro-benzene (1); carbon dioxide (2) 1
Diffusion of hexachloro-benzene (1); carbon dioxide (2)

Gaseous Mixtures
C6Cl6 (1) hexachloro-benzene 118-74-1

Mutual Diffusion Coefficient: D12(ρ1); T = 328 K; Method: TAYLOR Ref.: 1996A2
ρ1 [g/ml] p [bar] D · 109 [m2/s]
0.40 108.9 17.2 ± 5%
0.50 119.2 15.3 ± 5%
0.60 135.2 13.6 ± 5%
0.70 167.6 12.0 ± 5%
0.80 238.2 10.5 ± 5%

Intradiffusion Coefficient: D12(ρ1); T = 318 K; Method: TAYLOR Ref.: 1996A2
ρ1 [g/ml] p [bar] D · 109 [m2/s]
0.55 104.2 14.0 ± 5%
0.65 118.0 12.2 ± 5%
0.75 153.7 10.8 ± 5%
0.85 240.1 9.1 ± 5%

ρ1 [g/ml] p [bar] D · 109 [m2/s]
0.70 96.7 11.2 ± 5%
0.75 111.2 10.6 ± 5%
0.80 138.4 9.6 ± 5%
0.85 181.3 8.9 ± 5%
0.90 247.4 7.9 ± 5%
Reference
1996A2 Akgerman, A., Erkey, C., Orejuela, M.: Ind. Eng. Chem. Res. 35 (1996) 911–917.

Diffusion of benzene (1); carbon dioxide (2) 1
Diffusion of benzene (1); carbon dioxide (2)

Gaseous Mixtures
C6H6 (1) benzene 71-43-2

Mutual Diffusion Coefficient: D12(xi); T = 313.2 ± 0.1 K; Method: TAYLOR Ref.: 1996F4
x1 p [MPa] D · 108 [m2/s]
0.0 8.43 2.58 ± 2%
0.0 8.53 2.45 ± 2%
0.0 8.63 2.36 ± 2%
0.0 8.73 2.54 ± 2%
0.0 9.02 2.16 ± 2%
0.0 9.32 2.07 ± 2%
0.0 9.41 2.16 ± 2%
0.0 9.51 1.94 ± 2%
0.0 10.0 1.77 ± 2%
0.0 10.9 1.62 ± 2%
0.0 11.0 1.56 ± 2%
0.0 11.1 1.66 ± 2%
0.0 11.2 1.58 ± 2%
0.0 12.0 1.54 ± 2%
0.0 12.1 1.56 ± 2%
0.0 12.7 1.49 ± 2%
0.0 12.8 1.53 ± 2%
0.0 12.9 1.47 ± 2%
0.0 14.6 1.41 ± 2%
0.0 14.7 1.33 ± 2%
0.0 16.1 1.38 ± 2%
0.0 16.2 1.41 ± 2%
0.0 19.5 1.28 ± 2%
0.0 19.7 1.30 ± 2%
0.0 19.8 1.32 ± 2%
0.0 19.9 1.17 ± 2%
0.0 24.5 1.15 ± 2%
0.0 24.6 1.16 ± 2%
0.0 24.7 1.16 ± 2%
0.0 30.0 1.13 ± 2%
0.0 30.2 1.06 ± 2%
Comment: component (1) at infinite dilution in (2)
Reference
1996F4 Funazukuri, T., Nishimoto, N.: Fluid Phase Equilib. 125 (1996) 235–243.

Diffusion of heptane (1); methane (2) 1
Diffusion of heptane (1); methane (2)

Gaseous Mixtures
C7H16 (1) heptane 142-82-5

CH4 (2) methane 74-82-8
Mutual Diffusion Coefficient: D12(xi); T = 310.9 K; Method: PF Ref.: 1963R3
x2 p [MPa] D · 107 [m2/s]
0.80 0.1013 54.0
0.90 0.1013 60.2
1.00 0.1013 65.5
0.80 0.138 36.8
0.90 0.138 41.0
1.00 0.138 45.2
0.80 0.276 15.2
0.90 0.276 17.3
1.00 0.276 18.9
0.80 0.414 9.15
0.90 0.414 10.3
1.00 0.414 11.1
0.80 0.689 5.11
0.90 0.689 5.94
1.00 0.689 6.14
0.80 1.38 2.59
0.90 1.38 3.36
1.00 1.38 3.26
0.80 3.45 1.49
0.90 3.45 1.91
1.00 3.45 1.89
0.80 6.89 1.17
0.90 6.89 1.33
1.00 6.89 1.47
0.80 10.34 1.02
0.90 10.34 1.19
0.80 13.79 0.907
0.80 17.24 0.803
0.80 20.68 0.726
C7H16 (1) heptane 142-82-5

CH4 (2) methane 74-82-8
Intradiffusion Coefficient: D12(xi); T = 377.6 K; Method: PF Ref.: 1963R3
x2 p [MPa] D · 107 [m2/s]
0.80 0.138 67.8
0.90 0.138 75.1
1.00 0.138 81.7
0.80 0.276 31.3
0.90 0.276 35.1
(continued)
2 Diffusion of heptane (1); methane (2)
1.00 0.276 38.6

0.80 0.414 20.40
0.90 0.414 22.9
1.00 0.414 25.0
0.80 0.689 11.9
0.90 0.689 13.7
1.00 0.689 14.4
0.80 1.38 5.88
0.90 1.38 6.86
1.00 1.38 6.98
0.80 3.45 2.33
0.90 3.45 2.81
1.00 3.45 2.90
0.80 6.89 1.16
0.90 6.89 1.44
1.00 6.89 1.57
0.80 10.34 0.775
0.90 10.34 0.977
1.00 10.34 1.11
0.80 13.79 0.582
0.90 13.79 0.746
1.00 13.79 0.864
0.80 17.24 0.467
0.90 17.24 0.602
1.00 17.24 0.713
0.80 20.68 0.389
0.90 20.68 0.506
1.00 20.68 0.608
C7H16 (1) heptane 142-82-5

CH4 (2) methane 74-82-8
Intradiffusion Coefficient: D12(xi); T = 344.3 K; Method: PF Ref.: 1963R3
x2 p [MPa] D · 107 [m2/s]
0.80 0.1013 75.6
0.90 0.1013 83.5
1.00 0.1013 91.0
0.80 0.138 52.6
0.90 0.138 58.8
1.00 0.138 64.0
0.80 0.276 23.4
0.90 0.276 26.3
1.00 0.276 29.2
0.80 0.414 14.0
0.90 0.414 16.4
1.00 0.414 18.5
0.80 0.689 8.14
0.90 0.689 9.30
(continued)

Diffusion of heptane (1); methane (2) 3
1.00 0.689 10.5

0.80 1.38 4.00
0.90 1.38 4.72
1.00 1.38 5.20
0.80 3.45 1.83
0.90 3.45 2.17
1.00 3.45 2.36
0.80 6.89 1.11
0.90 6.89 1.28
1.00 6.89 1.40
0.80 10.34 0.719
0.90 10.34 0.986
1.00 10.34 1.08
0.80 13.79 0.685
0.90 13.79 0.840
1.00 13.79 0.921
0.80 17.24 0.563
0.90 17.24 0.778
1.00 17.24 0.845
0.80 20.68 0.534
0.90 20.68 0.743
1.00 20.68 0.822
Reference
1963R3 Reamer, H.H., Sage, B.H.: J. Chem. Eng. Data 8 (1963) 34–40.

Diffusion of oct-1-ene (1); ethane (2) 1
Diffusion of oct-1-ene (1); ethane (2)

Gaseous Mixtures
C8H16 (1) oct-1-ene 111-66-0

C2H6 (2) ethane 74-84-0
Mutual Diffusion Coefficient: D12(T ); Method: TAYLOR Ref.: 1997E1
T [K] p [bar] D · 109 [m2/s]
322.0 ± 1.0 124.1054 16.26 ± 0.625
340.0 ± 1.0 124.1054 18.52 ± 0.940
357.0 ± 1.0 124.1054 22.67 ± 0.612
378.0 ± 1.0 124.1054 31.12 ± 0.346
414.0 ± 1.0 124.1054 37.61 ± 2.515
503.0 ± 1.0 124.1054 55.49 ± 4.476
Reference
1997E1 Eaton, A.P., Akgerman, A.: Ind. Eng. Chem. Res. 36 (1997) 923–931.

Diffusion of oct-1-ene (1); propane (2) 1
Diffusion of oct-1-ene (1); propane (2)

Gaseous Mixtures
C8H16 (1) oct-1-ene 111-66-0

C3H8 (2) propane 74-98-6
T [K] p [bar] D · 109 [m2/s]
314.0 ± 1.0 124.1054 11.81 ± 0.288
354.0 ± 1.0 124.1054 14.31 ± 0.393
384.0 ± 1.0 124.1054 16.29 ± 0.746
408.0 ± 1.0 124.1054 22.70 ± 0.547
429.0 ± 1.0 124.1054 26.88 ± 0.843
453.0 ± 1.0 124.1054 24.59 ± 0.664
485.0 ± 1.0 124.1054 44.88 ± 0.640
544.0 ± 1.0 124.1054 54.65 ± 0.395
523.0 ± 1.0 62.0527 86.89 ± 1.610
533.0 ± 1.0 62.0527 88.77 ± 3.551
543.0 ± 1.0 62.0527 90.61 ± 0.451
Reference

Diffusion of oct-1-ene (1); hexane (2) 1
Diffusion of oct-1-ene (1); hexane (2)

Gaseous Mixtures
C8H16 (1) oct-1-ene 111-66-0

C6H14 (2) hexane 110-54-3
T [K] p [bar] D · 109 [m2/s]
483.0 ± 1.0 124.1054 18.50 ± 0.325
523.0 ± 1.0 103.4212 22.50 ± 0.110
523.0 ± 1.0 82.7369 26.22 ± 0.715
523.0 ± 1.0 62.0527 29.70 ± 1.521
523.0 ± 1.0 44.8158 38.97 ± 2.336
563.0 ± 1.0 62.0527 53.00 ± 2.755
563.0 ± 1.0 44.8158 82.10 ± 3.145
Reference

Diffusion of naphthalene (1); carbon dioxide (2) 1
Diffusion of naphthalene (1); carbon dioxide (2)

Gaseous Mixtures
C10H8 (1) naphthalene 91-20-3

ρ1 [g/ml] p [bar] D · 109 [m2/s]
0.40 108.2 22.5 ± 5%
0.50 119.4 19.3 ± 5%
0.60 134.9 16.9 ± 5%
0.70 167.9 14.7 ± 5%
0.75 196.0 13.7 ± 5%
0.80 237.9 12.8 ± 5%

ρ1 [g/ml] p [bar] D · 109 [m2/s]
0.60 109.6 16.1 ± 5%
0.65 117.7 14.9 ± 5%
0.70 131.3 14.0 ± 5%
0.75 147.0 13.2 ± 5%
0.80 188.4 12.5 ± 5%
0.85 240.3 11.6 ± 5%

ρ1 [g/ml] p [bar] D · 109 [m2/s]
0.70 96.4 13.7 ± 5%
0.75 111.9 12.8 ± 5%
0.80 138.7 12.2 ± 5%
0.85 181.4 11.0 ± 5%
0.90 247.2 9.9 ± 5%
Reference

Diffusion of phenanthrene (1); carbon dioxide (2) 1
Diffusion of phenanthrene (1); carbon dioxide (2)

Gaseous Mixtures
C14H10 (1) phenanthrene 85-01-8

ρ1 [g/ml] p [bar] D · 109 [m2/s]
0.40 108.1 19.2 ± 5%
0.50 119.0 16.5 ± 5%
0.60 135.3 14.7 ± 5%
0.70 167.9 13.1 ± 5%
0.80 238.1 11.2 ± 5%

ρ1 [g/ml] p [bar] D · 109 [m2/s]
0.60 109.4 13.7 ± 5%
0.65 118.0 12.8 ± 5%
0.75 153.6 11.7 ± 5%
0.85 240.2 10.0 ± 5%

ρ1 [g/ml] p [bar] D · 109 [m2/s]
0.70 96.5 11.4 ± 5%
0.75 111.8 10.9 ± 5%
0.80 138.4 10.4 ± 5%
0.85 181.1 9.7 ± 5%
0.90 248.8 9.0 ± 5%
Reference

Diffusion of hydrogen-deuterium (1); argon (2) 1
Diffusion of hydrogen-deuterium (1); argon (2)

Gaseous Mixtures
DH (1) hydrogen-deuterium 13983-20-5

Ar (2) argon 7440-37-1
Mutual Diffusion Coefficient: D12(xi); T = 300.00 ± 0.001 K; Method: CT Ref.: 1973H3
x2 p [kPa] D · 104 [m2/s]
0.0639 101.325 0.6923 ± 0.1%
0.1290 101.325 0.6917 ± 0.1%
0.1965 101.325 0.6932 ± 0.1%
0.2751 101.325 0.6936 ± 0.1%
0.4069 101.325 0.6964 ± 0.1%
0.4577 101.325 0.6977 ± 0.1%
0.5198 101.325 0.6975 ± 0.1%
0.6688 101.325 0.6984 ± 0.1%
0.7305 101.325 0.6996 ± 0.1%
0.7971 101.325 0.6978 ± 0.1%
0.8454 101.325 0.6987 ± 0.1%
0.8977 101.325 0.6994 ± 0.1%
0.9500 101.325 0.7012 ± 0.1%

Ar (2) argon 7440-37-1
Mutual Diffusion Coefficient: D12(x2); Method: CT Ref.: 1973H3
Equation: D=A+Bx Range: 0.0 < x2 < 1.0
Parameter: A B Std-Dev
0.69169 0.00945 0.0010
Comment: T = 300 K; D12 [m2/s] = D · 10–4
Reference
1973H3 Harris, K.R., Bell, T.N.: Can. J. Phys. 51 (1973) 2101–2107.

Diffusion of hydrogen-deuterium (1); nitrogen (2) 1
Diffusion of hydrogen-deuterium (1); nitrogen (2)

Gaseous Mixtures

N2 (2) nitrogen 7727-37-9
x2 p [kPa] D · 104 [m2/s]
0.0638 101.325 0.6636 ± 0.1%
0.1361 101.325 0.6648 ± 0.1%
0.2605 101.325 0.6666 ± 0.1%
0.4054 101.325 0.6685 ± 0.1%
0.5230 101.325 0.6690 ± 0.1%
0.6159 101.325 0.6694 ± 0.1%
0.7467 101.325 0.6713 ± 0.1%
0.8090 101.325 0.6716 ± 0.1%
0.8731 101.325 0.6721 ± 0.1%
0.9380 101.325 0.6729 ± 0.1%

N2 (2) nitrogen 7727-37-9
0.66359 0.01003 0.0004
Comment: T = 300 K; D12 [m2/s] = D · 10–4
Reference

Diffusion of deuterium (1); argon (2) 1
Diffusion of deuterium (1); argon (2)

Gaseous Mixtures
D2 (1) deuterium 7782-39-0

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
127.0 ± 0.1 101.325 0.128 ± 0.9%
294.6 ± 0.1 101.325 0.595 ± 0.9%
294.6 ± 0.1 101.325 0.592 ± 0.9%
494.0 ± 0.1 101.325 1.485 ± 0.9%
D2 (1) deuterium 7782-39-0

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
127.0 ± 0.1 101.325 0.1267 ± 0.9%
163.9 ± 0.1 101.325 0.204 ± 0.9%
203.3 ± 0.1 101.325 0.297 ± 0.9%
237.0 ± 0.1 101.325 0.391 ± 0.9%
294.6 ± 0.1 101.325 0.581 ± 0.9%
294.6 ± 0.1 101.325 0.578 ± 0.9%
406.8 ± 0.1 101.325 1.03 ± 0.9%
494.0 ± 0.1 101.325 1.453 ± 0.9%
581.5 ± 0.1 101.325 1.93 ± 0.9%
D2 (1) deuterium 7782-39-0

Ar (2) argon 7440-37-1
Intradiffusion Coefficient: D12(xi); T = 300.0 ± 0.01 K; Method: CT Ref.: 1972H4
x2 p [atm] D · 104 [m2/s]
0.0796 1.0017 0.5956 ± 0.2%
0.2000 1.0008 0.5966 ± 0.2%
0.2994 0.9994 0.5997 ± 0.2%
0.4019 0.9958 0.6012 ± 0.2%
0.4918 0.9876 0.6093 ± 0.2%
0.6023 0.9959 0.6023 ± 0.2%
0.7016 0.9991 0.6033 ± 0.2%
0.8017 0.9979 0.6043 ± 0.2%
0.9512 1.0020 0.6043 ± 0.2%
0.9528 1.0036 0.6028 ± 0.2%

2 Diffusion of deuterium (1); argon (2)
D2 (1) deuterium 7782-39-0

Ar (2) argon 7440-37-1
x2 p [kPa] D · 104 [m2/s]
0.0796 101.325 0.5967 ± 0.2%
0.2000 101.325 0.5970 ± 0.2%
0.2994 101.325 0.5994 ± 0.2%
0.4019 101.325 0.5987 ± 0.2%
0.4918 101.325 0.6017 ± 0.2%
0.6023 101.325 0.6004 ± 0.2%
0.7016 101.325 0.6028 ± 0.2%
0.8017 101.325 0.6030 ± 0.2%
0.9512 101.325 0.6055 ± 0.2%
0.9528 101.325 0.6050 ± 0.2%
D2 (1) deuterium 7782-39-0

Ar (2) argon 7440-37-1
0.5956 0.0098 0.10%
Comment: T = 300 K; D12 [m2/s] = D · 10–4
D2 (1) deuterium 7782-39-0

Ar (2) argon 7440-37-1
Mutual Diffusion
0.5942 0.0723 1.9456 0.04%
Comment: T = 300 K; D12 [m2/s] = D · 10–4
References
1972H4 Harris, K.R., Bell, T.N., Dunlop, P.J.: Can. J. Phys. 50 (1972) 1644–1647.
1982T6 Trengove, R.D., Dunlop, P.J.: Ber. Bunsenges. Phys. Chem. 86 (1982) 628–632.

Diffusion of deuterium (1); carbon dioxide (2) 1
Diffusion of deuterium (1); carbon dioxide (2)

Gaseous Mixtures
D2 (1) deuterium 7782-39-0

T [K] p [kPa] D · 104 [m2/s]
174.4 101.325 0.176 ± 0.9%
293.8 101.325 0.474 ± 0.9%
488.2 101.325 1.19 ± 0.9%
D2 (1) deuterium 7782-39-0

T [K] p [kPa] D · 104 [m2/s]
174.4 101.325 0.174 ± 0.9%
203.2 101.325 0.231 ± 0.9%
233.2 101.325 0.301 ± 0.9%
263.2 101.325 0.376 ± 0.9%
293.8 101.325 0.467 ± 0.9%
415.6 101.325 0.880 ± 0.9%
488.2 101.325 1.18 ± 0.9%
581.2 101.325 1.60 ± 0.9%
Reference

Diffusion of deuterium (1); krypton (2) 1
Diffusion of deuterium (1); krypton (2)

Gaseous Mixtures
D2 (1) deuterium 782-39-0

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
124.0 ± 0.1 101.325 0.105 ± 0.9%
295.7 ± 0.1 101.325 0.517 ± 0.9%
295.7 ± 0.1 101.325 0.518 ± 0.9%
511.0 ± 0.1 101.325 1.37 ± 0.9%

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
124.0 ± 0.1 101.325 0.105 ± 0.9%
173.4 ± 0.1 101.325 0.194 ± 0.9%
203.8 ± 0.1 101.325 0.257 ± 0.9%
243.4 ± 0.1 101.325 0.355 ± 0.9%
295.7 ± 0.1 101.325 0.504 ± 0.9%
295.7 ± 0.1 101.325 0.508 ± 0.9%
418.0 ± 0.1 101.325 0.941 ± 0.9%
511.0 ± 0.1 101.325 1.35 ± 0.9%
601.0 ± 0.1 101.325 1.786 ± 0.9%

Kr (2) krypton 7439-90-9
Mutual Diffusion
0.5182 0.0270 0.4908 0.05%
Comment: T = 300 K; D12[m2/s] = D · 10–4
References

Diffusion of deuterium (1); nitrogen (2) 1
Diffusion of deuterium (1); nitrogen (2)

Gaseous Mixtures
D2 (1) deuterium 7782-39-0

N2 (2) nitrogen 7727-37-9
x2 p [atm] D · 104 [m2/s]
0.1011 1.0071 0.5741 ± 0.2%
0.1016 1.0064 0.5741 ± 0.2%
0.2004 1.0010 0.5791 ± 0.2%
0.2115 1.0149 0.5712 ± 0.2%
0.2518 1.0032 0.5785 ± 0.2%
0.3018 1.0026 0.5794 ± 0.2%
0.3033 1.0045 0.5790 ± 0.2%
0.4004 1.0017 0.5806 ± 0.2%
0.5000 1.0000 0.5798 ± 0.2%
0.5996 1.0008 0.5804 ± 0.2%
0.6984 1.0010 0.5819 ± 0.2%
0.7993 1.0010 0.5828 ± 0.2%
0.8974 1.0093 0.5780 ± 0.2%
0.9422 1.0098 0.5795 ± 0.2%
0.9508 1.0005 0.5845 ± 0.2%
D2 (1) deuterium 7782-39-0

N2 (2) nitrogen 7727-37-9
x2 p [kPa] D · 104 [m2/s]
0.1011 101.325 0.5781 ± 0.2%
0.1016 101.325 0.5777 ± 0.2%
0.2004 101.325 0.5796 ± 0.2%
0.2115 101.325 0.5797 ± 0.2%
0.2518 101.325 0.5804 ± 0.2%
0.3018 101.325 0.5809 ± 0.2%
0.3033 101.325 0.5816 ± 0.2%
0.4004 101.325 0.5816 ± 0.2%
0.5000 101.325 0.5798 ± 0.2%
0.5996 101.325 0.5809 ± 0.2%
0.6984 101.325 0.5825 ± 0.2%
0.7993 101.325 0.5833 ± 0.2%
0.8974 101.325 0.5834 ± 0.2%
0.9422 101.325 0.5852 ± 0.2%
0.9508 101.325 0.5848 ± 0.2%

2 Diffusion of deuterium (1); nitrogen (2)
D2 (1) deuterium 7782-39-0

N2 (2) nitrogen 7727-37-9
0.5781 0.0066 0.12%
Comment: T = 300 K; D12 [m2/s] = D · 10–4
D2 (1) deuterium 7782-39-0

N2 (2) nitrogen 7727-37-9
Mutual Diffusion
0.5796 0.0809 2.1965 0.08%
Comment: T = 300 K; D12 [m2/s] = D · 10–4;
A = 0.18609 – 0.6009 · 10–3 · T + 6.3767 · 10–6 · T 2 [277 - 323 K]; ΔT = ±1 mK
References
1187–1190.

Diffusion of deuterium (1); neon (2) 1
Diffusion of deuterium (1); neon (2)

Gaseous Mixtures
D2 (1) deuterium 7782-39-0

Ne (2) neon 7440-01-9
x2 p [kPa] D · 104 [m2/s]
0.1286 101.325 0.8742 ± 0.2%
0.2173 101.325 0.8754 ± 0.2%
0.3267 101.325 0.8773 ± 0.2%
0.7361 101.325 0.8840 ± 0.2%
0.8209 101.325 0.8838 ± 0.2%
0.9066 101.325 0.8854 ± 0.2%
D2 (1) deuterium 7782-39-0

Ne (2) neon 7440-01-9
x2 p [atm] D · 104 [m2/s]
0.1286 1.5185 0.5757 ± 0.2%
0.2173 1.4730 0.5943 ± 0.2%
0.3267 1.5358 0.5712 ± 0.2%
0.7361 1.4758 0.5990 ± 0.2%
0.8209 1.4601 0.6053 ± 0.2%
0.9066 1.4583 0.7407 ± 0.2%
D2 (1) deuterium 7782-39-0

Ne (2) neon 7440-01-9
0.8724 0.0146 0.04%
Comment: T = 300 K; D12 [m2/s] = D · 10–4
D2 (1) deuterium 7782-39-0

Ne (2) neon 7440-01-9
Equation: D = A (1 + B x /(1 + C x)).0 Range: 0.0 < x1 < 1
0.8713 0.0421 0.8133 0.05%
Comment: T = 300 K; D12 [m2/s] = D · 10–4
References

2 Diffusion of deuterium (1); neon (2)

Diffusion of deuterium (1); oxygen (2) 1
Diffusion of deuterium (1); oxygen (2)

Gaseous Mixtures
D2 (1) deuterium 7782-39-0

O2 (2) oxygen 7782-44-7
Coefficient: D12(x1); Method: TB
Mutual Diffusion Ref.: 1983T10
0.6069 0.0704 1.9893 0.09%
Comment: T = 300 K; D12 [m2/s] = D · 10–4;
A = –0.31675 + 2.7974 · 10–3 · T + 0.9396 · 10–6 · T 2 [277 - 323 K]; ΔT = ±1 mK
Reference
1187–1190.

Diffusion of deuterium (1); xenon (2) 1
Diffusion of deuterium (1); xenon (2)

Gaseous Mixtures
D2 (1) deuterium 7782-39-0

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
165.2 ± 0.1 101.325 0.1503 ± 0.9%
297.5 ± 0.1 101.325 0.4465 ± 0.9%
297.5 ± 0.1 101.325 0.4465 ± 0.9%
593.2 ± 0.1 101.325 1.168 ± 0.9%
D2 (1) deuterium 7782-39-0

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
127.0 ± 0.1 101.325 0.0931 ± 0.9%
165.2 ± 0.1 101.325 0.150 ± 0.9%
203.6 ± 0.1 101.325 0.221 ± 0.9%
234.3 ± 0.1 101.325 0.282 ± 0.9%
297.5 ± 0.1 101.325 0.438 ± 0.9%
297.5 ± 0.1 101.325 0.435 ± 0.9%
400.2 ± 0.1 101.325 0.749 ± 0.9%
503.0 ± 0.1 101.325 1.132 ± 0.9%
593.2 ± 0.1 101.325 1.530 ± 0.9%
D2 (1) deuterium 7782-39-0

Xe (2) xenon 7440-63-3
Mutual Diffusion
0.4465 0.0262 1.2125 0.06%
Comment: T = 300 K; D12 [m2/s] = D · 10–4
References

Diffusion of sulfur hexafluoride (1); argon (2) 1
Diffusion of sulfur hexafluoride (1); argon (2)

Gaseous Mixtures

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
298.7 101.325 0.078*
298.7 101.325 0.079

Ar (2) argon 7440-37-1
Mutual Diffusion Coefficient: D12(x1); Method: CT Ref.: 1984T5
0.0859 0 0 0.13%
Comment: T = 300 K

Ar (2) argon 7440-37-1
Mutual DiffusionCoefficient: D12(T ); Method: CT Ref.: 1984T5
–0.3714 0.4612 0.8416 0.06%
Comment: x1 = 0.00; D12 [m2/s] = D · 10–4
References

Diffusion of sulfur hexafluoride (1); helium (2) 1
Diffusion of sulfur hexafluoride (1); helium (2)

Gaseous Mixtures

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
294.6 101.325 0.377*
294.6 101.325 0.395

He (2) helium 7440-59-7
Mutual Diffusion
Coefficient: D12(x1); Method: CT Ref.: 1984T5
0.3894 0.2488 5.0188 0.05%
Comment: T = 300 K

He (2) helium 7440-59-7
–12.4536 12.6897 1.4807 0.04%
Comment: x1 = 0.00; D12 [m2/s] = D · 10–4
References

Diffusion of sulfur hexafluoride (1); krypton (2) 1
Diffusion of sulfur hexafluoride (1); krypton (2)

Gaseous Mixtures

Kr (2) krypton 7439-90-9
0.0598 0 0 0.17%
Comment: T = 300 K

Kr (2) krypton 7439-90-9
–0.6505 0.6252 0.5276 0.06%
Comment: x1 = 0.00; D12 [m2/s] = D · 10–4
Reference

Diffusion of sulfur hexafluoride (1); nitrogen (2) 1
Diffusion of sulfur hexafluoride (1); nitrogen (2)

Gaseous Mixtures

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
294.2 101.325 0.092*
294.2 101.325 0.093
Reference

Diffusion of sulfur hexafluoride (1); neon (2) 1
Diffusion of sulfur hexafluoride (1); neon (2)

Gaseous Mixtures

Ne (2) neon 7440-01-9
Coefficient: D12(x1); Method: CT
0.1572 0.06166 2.1557 0.06%
Comment: T = 300 K

Ne (2) neon 7440-01-9
–2.1936 2.9142 1.0182 0.03%
Comment: x1 = 0.00; D12 [m2/s] = D · 10–4
Reference

Diffusion of sulfur hexafluoride (1); xenon (2) 1
Diffusion of sulfur hexafluoride (1); xenon (2)

Gaseous Mixtures

Xe (2) xenon 7440-63-3
0.0460 0 0 0.15%
Comment: T = 300 K
Reference

Diffusion of hydrogen atom (1); argon (2) 1
Diffusion of hydrogen atom (1); argon (2)

Gaseous Mixtures
H (1) hydrogen atom 12385-13-6

Ar (2) argon 7440-37-1
1.45 1.597
Reference

Diffusion of hydrogen atom (1); hydrogen (2) 1
Diffusion of hydrogen atom (1); hydrogen (2)

Gaseous Mixtures

H2 (2) hydrogen 1333-74-0
11.3 1.728
Reference

Diffusion of hydrogen atom (1); helium (2) 1
Diffusion of hydrogen atom (1); helium (2)

Gaseous Mixtures

He (2) helium 7440-59-7
14.2 1.732
Reference

Diffusion of hydrogen (1); Air (2) 1
Diffusion of hydrogen (1); Air (2)

Gaseous Mixtures
H2 (1) hydrogen 1333-74-0

Air (2) air 132259-10-0
5
3.64 1.750
Reference

Diffusion of hydrogen (1); argon (2) 1
Diffusion of hydrogen (1); argon (2)

Gaseous Mixtures
H2 (1) hydrogen 1333-74-0

Ar (2) argon 7440-37-1
x2 p [kPa] D · 104 [m2/s]
0.0501 101.325 0.8228 ± 0.2%
0.2144 101.325 0.8274 ± 0.2%
0.2983 101.325 0.8269 ± 0.2%
0.3002 101.325 0.8293 ± 0.2%
0.4016 101.325 0.8299 ± 0.2%
0.5011 101.325 0.8299 ± 0.2%
0.6016 101.325 0.8327 ± 0.2%
0.7015 101.325 0.8339 ± 0.2%
0.8015 101.325 0.8356 ± 0.2%
0.9510 101.325 0.8379 ± 0.2%
H2 (1) hydrogen 1333-74-0

Ar (2) argon 7440-37-1
x2 p [atm] D · 104 [m2/s]
0.0501 1.0060 0.8179 ± 0.2%
0.2144 1.0179 0.8129 ± 0.2%
0.2983 0.9982 0.8284 ± 0.2%
0.3002 1.0006 0.8288 ± 0.2%
0.4016 1.0034 0.8271 ± 0.2%
0.5011 0.9978 0.8317 ± 0.2%
0.6016 0.9980 0.8344 ± 0.2%
0.7015 0.9974 0.8360 ± 0.2%
0.8015 0.9989 0.8365 ± 0.2%
0.9510 1.0018 0.8363 ± 0.2%
H2 (1) hydrogen 1333-74-0

Ar (2) argon 7440-37-1
x2 p [kPa] D · 104 [m2/s]
0.0776 101.325 0.8226 ± 0.1%
0.0779 101.325 0.8229 ± 0.1%
0.0791 101.325 0.8249 ± 0.1%
0.3044 101.325 0.8297 ± 0.1%
0.5162 101.325 0.8325 ± 0.1%
0.6990 101.325 0.8348 ± 0.1%
0.9209 101.325 0.8375 ± 0.1%

2 Diffusion of hydrogen (1); argon (2)
H2 (1) hydrogen 1333-74-0

Ar (2) argon 7440-37-1
0.8231 0.0156 0.08%
Comment: T = 300 K; D12 [m2/s] = D · 10–4
H2 (1) hydrogen 1333-74-0

Ar (2) argon 7440-37-1
Mutual Diffusion
0.8240 0.0538 1.2193 0.02%
Comment: T = 300 K; experimental error: ±0.1%
References
1981T2 Trengove, R.D., Dunlop, P.J.: Proc. 8th Int. Symp. on Therophysical Properties, Sengers, J.V.
(ed), New York: ASME, 1981, p. 289–296.

Diffusion of hydrogen (1); methane (2) 1
Diffusion of hydrogen (1); methane (2)

Gaseous Mixtures
H2 (1) hydrogen 1333-74-0

CH4 (2) methane 74-82-8
Mutual Diffusion Coefficient: D12(T ); Method: CT Ref.: 1974G4
T [K] p [Torr] D · 104 [m2/s]
298.0 730.8 0.7811
378.3 737.8 1.153
438.4 742.7 1.490
H2 (1) hydrogen 1333-74-0

CH4 (2) methane 74-82-8
Intradiffusion Coefficient: D12(T ); Method: CORR Ref.: 1972M1
17.5 11/6
H2 (1) hydrogen 1333-74-0

CH4 (2) methane 74-82-8
5
3.13 1.765
References

Diffusion of hydrogen (1); carbon monoxide (2) 1
Diffusion of hydrogen (1); carbon monoxide (2)

Gaseous Mixtures
H2 (1) hydrogen 1333-74-0

Equation: ln (D · p) = ln A + B · ln T – ln [ ln(C/T ) ]2 – E/T – F/T 2 Range: 65 < T/K < 10000
3 –8
Parameter: A · 10 B C · 10 E F
15.39 1.548 0.318 –2.80 1067.0
Reference

Diffusion of hydrogen (1); carbon dioxide (2) 1
Diffusion of hydrogen (1); carbon dioxide (2)

Gaseous Mixtures
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
174.4 101.325 0.238 ± 0.9%
203.0 101.325 0.314 ± 0.9%
233.2 101.325 0.407 ± 0.9%
263.2 101.325 0.509 ± 0.9%
291.5 101.325 0.613 ± 0.9%
415.6 101.325 1.17 ± 0.9%
489.0 101.325 1.58 ± 0.9%
580.7 101.325 2.16 ± 0.9%
H2 (1) hydrogen 1333-74-0

Intradiffusion Coefficient: D12(T ); Method: TB Ref.: 1974L11
T [K] p [kPa] D · 104 [m2/s]
174.4 101.325 0.242 ± 0.9%
291.5 101.325 0.623 ± 0.9%
489.0 101.325 1.59 ± 0.9%
H2 (1) hydrogen 1333-74-0

3.14 1.750 11.7
References

Diffusion of hydrogen (1); ethane (2) 1
Diffusion of hydrogen (1); ethane (2)

Gaseous Mixtures
H2 (1) hydrogen 1333-74-0

C2H6 (2) ethane 74-84-0
Mutual Diffusion Coefficient: D12(T ); Method: CT Ref.: 1974G4
T [K] p [Torr] D · 104 [m2/s]
298.0 738.7 0.5708
378.3 740.6 0.8646
438.4 734.3 1.129
Reference

Diffusion of hydrogen (1); propane (2) 1
Diffusion of hydrogen (1); propane (2)

Gaseous Mixtures
H2 (1) hydrogen 1333-74-0

C3H8 (2) propane 74-98-6
T [K] p [Torr] D · 104 [m2/s]
298.0 732.7 0.4712
378.1 736.6 0.7103
438.5 739.9 0.9190
Reference

Diffusion of hydrogen (1); butane (2) 1
Diffusion of hydrogen (1); butane (2)

Gaseous Mixtures
H2 (1) hydrogen 1333-74-0

C4H10 (2) butane 106-97-8
T [K] p [Torr] D · 104 [m2/s]
298.0 736.5 0.3997
378.2 738.8 0.6155
438.4 735.9 0.8010
Reference

Diffusion of hydrogen (1); 2-methyl-propane (2) 1
Diffusion of hydrogen (1); 2-methyl-propane (2)

Gaseous Mixtures
H2 (1) hydrogen 1333-74-0

T [K] p [Torr] D · 104 [m2/s]
298.0 741.5 0.3924
378.2 729.0 0.6202
438.4 738.2 0.8051
Reference

Diffusion of hydrogen (1); 2,2-dimethyl-propane (2) 1
Diffusion of hydrogen (1); 2,2-dimethyl-propane (2)

Gaseous Mixtures
H2 (1) hydrogen 1333-74-0

T [K] p [Torr] D · 104 [m2/s]
298.0 733.1 0.3515
378.3 740.6 0.5443
438.4 741.7 0.7136
Reference

Diffusion of hydrogen (1); deuterium (2) 1
Diffusion of hydrogen (1); deuterium (2)

Gaseous Mixtures
H2 (1) hydrogen 1333-74-0

D2 (2) deuterium 7782-39-0
Mutual Diffusion Coefficient: D12(T ); Method: CT Ref.: 1987D6
T [K] p [kPa] D · 104 [m2/s]
273.15 ± 0.001 101.325 1.111 ± 0.5%
280.00 ± 0.001 101.325 1.164 ± 0.5%
290.00 ± 0.001 101.325 1.238 ± 0.5%
300.00 ± 0.001 101.325 1.306 ± 0.5%
310.00 ± 0.001 101.325 1.386 ± 0.5%
320.00 ± 0.001 101.325 1.468 ± 0.5%
H2 (1) hydrogen 1333-74-0

D2 (2) deuterium 7782-39-0
Parameter: A · 103 B C · 10–8 E F
24.7 1.500 0.0636 6.072 38.10
H2 (1) hydrogen 1333-74-0

D2 (2) deuterium 7782-39-0
Mutual DiffusionCoefficient: D12(T ); Method: CT Ref.: 1987D6
0.0568 0.0731 1.1484 0.18%
Comment: x1 = 0.50
References
1987D6 Dunlop, P.J., Bignell, C.M., Taylor, W.L., Meyer, B.A.: J. Chem. Phys. 87 (1987) 3591–3593.

Diffusion of hydrogen (1); helium (2) 1
Diffusion of hydrogen (1); helium (2)

Gaseous Mixtures
H2 (1) hydrogen 1333-74-0

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
300.2 101.325 2.10
360.8 101.325 2.90
410.2 101.325 3.72
470.8 101.325 4.77
520.9 101.325 5.90
580.2 101.325 7.24
640.8 101.325 8.72
700.1 101.325 10.50
750.2 101.325 12.20
801.3 101.325 14.10
860.2 101.325 16.54
902.5 101.325 18.70
950.4 101.325 21.20
1001.2 101.325 24.10
1080.3 101.325 27.90
H2 (1) hydrogen 1333-74-0

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
300.2 101.325 1.03
360.8 101.325 1.42
410.2 101.325 1.79
470.8 101.325 2.32
520.9 101.325 2.90
580.2 101.325 3.56
640.8 101.325 4.28
700.1 101.325 5.12
750.2 101.325 5.80
801.3 101.325 6.90
860.2 101.325 8.01
902.5 101.325 9.20
950.4 101.325 10.28
1001.2 101.325 11.66
1080.3 101.325 13.58

2 Diffusion of hydrogen (1); helium (2)
H2 (1) hydrogen 1333-74-0

He (2) helium 7440-59-7
Intradiffusion Coefficient: D12(T ); Method: DB Ref.: 2004A3
T [K] p [kPa] D · 104 [m2/s]
300.2 101.325 1.60
360.8 101.325 2.13
410.2 101.325 2.66
470.8 101.325 3.30
520.9 101.325 3.93
580.2 101.325 4.68
640.8 101.325 5.79
700.1 101.325 6.65
750.2 101.325 7.48
801.3 101.325 8.35
860.2 101.325 9.52
902.5 101.325 10.18
950.4 101.325 11.15
1001.2 101.325 12.15
1080.3 101.325 13.12
References
2001A1 Al'zhanov, K.Z., Musenov, K.K.: Prom. Teplotekhn. 23 (2001) 122–125.
83–88.

Diffusion of hydrogen (1); sulfur hexafluoride (2) 1
Diffusion of hydrogen (1); sulfur hexafluoride (2)

Gaseous Mixtures
H2 (1) hydrogen 1333-74-0

5
7.82 1.570 102.3
Reference

Diffusion of hydrogen (1); krypton (2) 1
Diffusion of hydrogen (1); krypton (2)

Gaseous Mixtures
H2 (1) hydrogen 1333-74-0

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
163.5 101.325 0.240 ± 0.9%
295.7 101.325 0.729 ± 0.9%
482.5 101.325 1.746 ± 0.9%
H2 (1) hydrogen 1333-74-0

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
128.3 101.325 0.150 ± 0.9%
163.5 101.325 0.236 ± 0.9%
203.1 101.325 0.352 ± 0.9%
243.4 101.325 0.488 ± 0.9%
295.7 101.325 0.706 ± 0.9%
386.2 101.325 1.13 ± 0.9%
482.5 101.325 1.684 ± 0.9%
577.4 101.325 2.34 ± 0.9%
H2 (1) hydrogen 1333-74-0

Kr (2) krypton 7439-90-9
Mutual Diffusion
0.7240 0.0577 1.6003 0.03%
References
(ed), New York: ASME, 1981, p. 289–296.

Diffusion of hydrogen (1); nitrogen (2) 1
Diffusion of hydrogen (1); nitrogen (2)

Gaseous Mixtures
H2 (1) hydrogen 1333-74-0

N2 (2) nitrogen 7727-37-9
Mutual Diffusion Coefficient: D12(xi); T = 300 ± 0.001 K; Method: CT Ref.: 1972C2
x2 p [kPa] D · 104 [m2/s]
0.0652 101.325 0.7835
0.0761 101.325 0.7840
0.0812 101.325 0.7844
0.0814 101.325 0.7854
0.0819 101.325 0.7852
0.0997 101.325 0.7854
0.1111 101.325 0.7821
0.1284 101.325 0.7839
0.1802 101.325 0.7869
0.4911 101.325 0.7896
0.4921 101.325 0.7908
0.5112 101.325 0.7891
0.5115 101.325 0.7918
0.5123 101.325 0.7908
0.8236 101.325 0.7960
0.9110 101.325 0.7985
0.9417 101.325 0.7973
0.9420 101.325 0.7989
0.9428 101.325 0.7981
0.9462 101.325 0.7971
0.9473 101.325 0.7977
Comment: accuracy: ±0.2%
H2 (1) hydrogen 1333-74-0

N2 (2) nitrogen 7727-37-9
19.3 11/6
H2 (1) hydrogen 1333-74-0

N2 (2) nitrogen 7727-37-9
15.39 1.548 0.316 –2.80 1067.0

2 Diffusion of hydrogen (1); nitrogen (2)
H2 (1) hydrogen 1333-74-0

N2 (2) nitrogen 7727-37-9
0.78300 0.01430 0.0009
0.7828 0.0159 0.0008
Comment: T = 300 K; D12 [m2/s] = D · 10–4
H2 (1) hydrogen 1333-74-0

N2 (2) nitrogen 7727-37-9
0.7828 0.0159 0.10%
Comment: T = 300 K; D12 [m2/s] = D · 10–4
H2 (1) hydrogen 1333-74-0

N2 (2) nitrogen 7727-37-9
0.7844 0.0560 1.8416 0.11%
2 –4
Comment: T = 300 K; D12 [m /s] = D · 10 ;
A = 0.40343 – 1.7745 · 10–3 · T + 10.1492 · 10–6 · T 2 [277 - 323 K]; ΔT = ±1 mK
References
1972C2 Carson, P.J., Dunlop, P.J., Bell, T.N.: J. Chem. Phys. 56 (1972) 531–536.
1187–1190.

Diffusion of hydrogen (1); neon (2) 1
Diffusion of hydrogen (1); neon (2)

Gaseous Mixtures
H2 (1) hydrogen 1333-74-0

Ne (2) neon 7440-01-9
Mutual Diffusion Coefficient: D12(xi); T = 300 ± 0.01 K; Method: CT Ref.: 1972H4
x2 p [atm] D · 104 [m2/s]
0.1029 1.5809 0.7455 ± 0.2%
0.1039 1.6117 0.7310 ± 0.2%
0.7088 1.5600 0.7680 ± 0.2%
0.7795 1.5608 0.7702 ± 0.2%
0.7960 1.5578 0.7708 ± 0.2%
0.8881 1.5380 0.7828 ± 0.2%
H2 (1) hydrogen 1333-74-0

Ne (2) neon 7440-01-9
Intradiffusion Coefficient: D12(xi); T = 300 ± 0.01 K; Method: CT Ref.: 1972H4
x2 p [kPa] D · 104 [m2/s]
0.1029 101.325 1.1785 ± 0.2%
0.1039 101.325 1.1782 ± 0.2%
0.7088 101.325 1.1982 ± 0.2%
0.7795 101.325 1.2022 ± 0.2%
0.7960 101.325 1.2008 ± 0.2%
0.8881 101.325 1.2040 ± 0.2%
H2 (1) hydrogen 1333-74-0

Ne (2) neon 7440-01-9
1.1749 0.0332 0.04%
Comment: T = 300 K; D12 [m2/s] = D · 10–4
Reference

Diffusion of hydrogen (1); oxygen (2) 1
Diffusion of hydrogen (1); oxygen (2)

Gaseous Mixtures
H2 (1) hydrogen 1333-74-0

O2 (2) oxygen 7782-44-7
5
4.17 1.732
H2 (1) hydrogen 1333-74-0

O2 (2) oxygen 7782-44-7
Mutual Diffusion
0.8266 0.0664 2.0245 0.10%
Comment: T = 300 K; D12 [m2/s] = D · 10–4;
A = –0.28930 + 2.8065 · 10–3 · T + 3.0415 · 10–6 · T 2 [277 - 323 K]; ΔT = ±1 mK
References
1187–1190.

Diffusion of hydrogen (1); xenon (2) 1
Diffusion of hydrogen (1); xenon (2)

Gaseous Mixtures
H2 (1) hydrogen 1333-74-0

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
127.7 ± 0.1 101.325 0.1355 ± 0.9%
163.0 ± 0.1 101.325 0.2076 ± 0.9%
202.4 ± 0.1 101.325 0.309 ± 0.9%
243.1 ± 0.1 101.325 0.426 ± 0.9%
296.0 ± 0.1 101.325 0.609 ± 0.9%
296.0 ± 0.1 101.325 0.608 ± 0.9%
405.0 ± 0.1 101.325 1.077 ± 0.9%
497.3 ± 0.1 101.325 1.554 ± 0.9%
583.0 ± 0.1 101.325 2.055 ± 0.9%
H2 (1) hydrogen 1333-74-0

Xe (2) xenon 7440-63-3
Mutual Diffusion
0.6233 0.0665 1.2689 0.06%
Comment: T = 300 K; experimental error: ± 0.1%
References
(ed), New York: ASME, 1981, p. 289–296.

Diffusion of water (1); carbon dioxide (2) 1
Diffusion of water (1); carbon dioxide (2)

Gaseous Mixtures
H 2O (1) water 7732-18-5

9.24 1.500 307.9
Reference

Diffusion of helium (1); Air (2) 1
Diffusion of helium (1); Air (2)

Gaseous Mixtures
He (1) helium 7440-59-7

Air (2) air 132259-10-0
5
3.78 1.729
Reference

Diffusion of helium (1); argon (2) 1
Diffusion of helium (1); argon (2)

Gaseous Mixtures
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
Mutual Diffusion Coefficient: D12(xi); T = 300.00 ± 0.0005 K; Method: TB Ref.: 1972C4
x2 p [kPa] D · 104 [m2/s]
0.0642 101.325 0.7335 ± 0.1%
0.0650 101.325 0.7324 ± 0.1%
0.0797 101.325 0.7333 ± 0.1%
0.0797 101.325 0.7350 ± 0.1%
0.0798 101.325 0.7345 ± 0.1%
0.0798 101.325 0.7344 ± 0.1%
0.0798 101.325 0.7332 ± 0.1%
0.0798 101.325 0.7353 ± 0.1%
0.0799 101.325 0.7332 ± 0.1%
0.0802 101.325 0.7345 ± 0.1%
0.0804 101.325 0.7326 ± 0.1%
0.0807 101.325 0.7341 ± 0.1%
0.0817 101.325 0.7340 ± 0.1%
0.0820 101.325 0.7336 ± 0.1%
0.0821 101.325 0.7330 ± 0.1%
0.0822 101.325 0.7335 ± 0.1%
0.0822 101.325 0.7334 ± 0.1%
0.0823 101.325 0.7337 ± 0.1%
0.0822 101.325 0.7336 ± 0.1%
0.0824 101.325 0.7336 ± 0.1%
0.1862 101.325 0.7377 ± 0.1%
0.2716 101.325 0.7400 ± 0.1%
0.2779 101.325 0.7402 ± 0.1%
0.3440 101.325 0.7417 ± 0.1%
0.3708 101.325 0.7412 ± 0.1%
0.3970 101.325 0.7445 ± 0.1%
0.4638 101.325 0.7449 ± 0.1%
0.4643 101.325 0.7460 ± 0.1%
0.4647 101.325 0.7452 ± 0.1%
0.4971 101.325 0.7456 ± 0.1%
0.4971 101.325 0.7463 ± 0.1%
0.4989 101.325 0.7467 ± 0.1%
0.5003 101.325 0.7475 ± 0.1%
0.5317 101.325 0.7472 ± 0.1%
0.5965 101.325 0.7482 ± 0.1%
0.6280 101.325 0.7477 ± 0.1%
0.7531 101.325 0.7513 ± 0.1%
0.8135 101.325 0.7517 ± 0.1%
0.8485 101.325 0.7522 ± 0.1%
0.9136 101.325 0.7530 ± 0.1%
(continued)
2 Diffusion of helium (1); argon (2)
0.9176 101.325 0.7544 ± 0.1%

0.9176 101.325 0.7545 ± 0.1%
0.9178 101.325 0.7528 ± 0.1%
0.9178 101.325 0.7533 ± 0.1%
0.9180 101.325 0.7526 ± 0.1%
0.9612 101.325 0.7535 ± 0.1%
0.9614 101.325 0.7533 ± 0.1%
0.9615 101.325 0.7548 ± 0.1%
0.9616 101.325 0.7537 ± 0.1%
0.9617 101.325 0.7538 ± 0.1%
0.9617 101.325 0.7551 ± 0.1%
Comment: data set recommended for calibration
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
Intradiffusion Coefficient: D12(xi); T = 300 ± 0.001 K; Method: CT Ref.: 1972C2
x2 p [kPa] D · 104 [m2/s]
0.0819 101.325 0.7356
0.0864 101.325 0.7375
0.0871 101.325 0.7375
0.2723 101.325 0.7437
0.5572 101.325 0.7508
0.5596 101.325 0.7516
0.7519 101.325 0.7544
0.9380 101.325 0.7563
0.9450 101.325 0.7565
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0317
100.0 101.325 0.1144
150.0 101.325 0.2343
200.0 101.325 0.3844
250.0 101.325 0.5610
300.0 101.325 0.7619
273.15 101.325 0.6511
293.15 101.325 0.7330
313.15 101.325 0.8186
333.15 101.325 0.9083
353.15 101.325 1.0017
373.15 101.325 1.0987
423.15 101.325 1.3559
473.15 101.325 1.6336
523.15 101.325 1.9312
(continued)
573.15 101.325 2.2485

623.15 101.325 2.5849
673.15 101.325 2.9402
723.15 101.325 3.3141
773.15 101.325 3.7062
873.15 101.325 4.5440
973.15 101.325 5.4514
1073.15 101.325 6.4265
1173.15 101.325 7.4677
1273.15 101.325 8.5733
1773.15 101.325 15.0259
2273.15 101.325 22.9313
2773.15 101.325 32.2006
3273.15 101.325 42.7685
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0317
100.0 101.325 0.1139
150.0 101.325 0.2325
200.0 101.325 0.3810
250.0 101.325 0.5555
300.0 101.325 0.7543
273.15 101.325 0.6447
293.15 101.325 0.7257
313.153 101.325 0.8105
333.15 101.325 0.8992
353.15 101.325 0.9916
373.15 101.325 1.0875
423.15 101.325 1.3419
473.15 101.325 1.6167
523.15 101.325 1.9115
573.15 101.325 2.2257
623.15 101.325 2.5590
673.15 101.325 2.9112
723.15 101.325 3.2817
773.15 101.325 3.6705
873.15 101.325 4.5011
973.15 101.325 5.4010
1073.15 101.325 6.3681
1173.15 101.325 7.4009
1273.15 101.325 8.4977
1773.15 101.325 14.9005
2273.15 101.325 22.7477
(continued)

2773.15 101.325 31.9512

3273.15 101.325 42.4467
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0316
100.0 101.325 0.1132
150.0 101.325 0.2305
200.0 101.325 0.3769
250.0 101.325 0.5491
300.0 101.325 0.7455
273.15 101.325 0.6371
293.15 101.325 0.7172
313.15 101.325 0.8011
333.15 101.325 0.8886
353.15 101.325 0.9798
373.15 101.325 1.0744
423.15 101.325 1.3256
473.15 101.325 1.5971
523.15 101.325 1.8884
573.15 101.325 2.1991
623.15 101.325 2.5289
673.15 101.325 2.8773
723.15 101.325 3.2441
773.15 101.325 3.6289
873.15 101.325 4.4513
973.15 101.325 5.3424
1073.15 101.325 6.3003
1173.15 101.325 7.3233
1273.15 101.325 8.4099
1773.15 101.325 14.7552
2273.15 101.325 22.5350
2773.15 101.325 31.6625
3273.15 101.325 42.0742
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
Intradiffusion Coefficient: D12(T ); Method: TB Ref.: 1983T6
T [K] p [kPa] D · 104 [m2/s]
358.0 ± 0.1% 101.325 1.044 ± 3%
403.0 ± 0.1% 101.325 1.264 ± 3%
500.0 ± 0.1% 101.325 1.799 ± 3%
570.0 ± 0.1% 101.325 2.270 ± 3%
(continued)
646.0 ± 0.1% 101.325 2.723 ± 3%

653.0 ± 0.1% 101.325 2.850 ± 3%
790.0 ± 0.1% 101.325 3.933 ± 3%
799.0 ± 0.1% 101.325 4.188 ± 3%
871.0 ± 0.1% 101.325 4.680 ± 3%
941.0 ± 0.1% 101.325 5.333 ± 3%
1021.0 ± 0.1% 101.325 6.130 ± 3%
1089.0 ± 0.1% 101.325 7.007 ± 3%
1172.0 ± 0.1% 101.325 7.891 ± 3%
1248.0 ± 0.1% 101.325 9.121 ± 3%
1249.0 ± 0.1% 101.325 8.884 ± 3%
1252.0 ± 0.1% 101.325 9.080 ± 3%
1292.0 ± 0.1% 101.325 9.347 ± 3%
1305.0 ± 0.1% 101.325 9.235 ± 3%
1306.0 ± 0.1% 101.325 9.583 ± 3%
1357.0 ± 0.1% 101.325 10.316 ± 3%
Comment: D12 at equimolar composition, accurate data in good agreement with Marrero and Mason
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
Intradiffusion Coefficient: D12(xi); T = 300 K; Method: CT Ref.: 1976S13
x2 p [atm] D · 104 [m2/s]
0.1 1 0.7400
0.1 2 0.3702
0.1 3 0.2464
0.1 4 0.1848
0.1 5 0.1479
0.1 7 0.1057
0.1 9 0.0822
Comment: calculated from data of (p · D12)
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
Intradiffusion Coefficient: D12(xi); T = 300 K; Method: TB Ref.: 1976Y2
x2 p [kPa] D · 104 [m2/s]
0.063 101.325 0.7383 ± 0.2%
0.125 101.325 0.7421 ± 0.2%
0.250 101.325 0.7459 ± 0.2%
0.500 101.325 0.7512 ± 0.2%
0.500 101.325 0.7517 ± 0.2%
0.750 101.325 0.7565 ± 0.2%
0.875 101.325 0.7570 ± 0.2%
0.938 101.325 0.7579 ± 0.2%

He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
Intradiffusion Coefficient: D2T(x1); T = 160 K; Method: INS Ref.: 1996S6
x1 p [bar] D · 109 [m2/s]
0.565 600 28.0
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
298.1 101.325 0.772*
298.1 101.325 0.758
298.1 101.325 0.750*
298.1 101.325 0.737
298.5 101.325 0.788*
298.5 101.325 0.744
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
Intradiffusion Coefficient: D12(xi); T = 300.0 K; Method: TB Ref.: 1976Y2
x2 p [kPa] D · 104 [m2/s]
0.071 101.325 0.7380 ± 0.2%
0.075 101.325 0.7401 ± 0.2%
0.125 101.325 0.7421 ± 0.2%
0.215 101.325 0.7455 ± 0.2%
0.218 101.325 0.7468 ± 0.2%
0.288 101.325 0.7469 ± 0.2%
0.355 101.325 0.7497 ± 0.2%
0.423 101.325 0.7516 ± 0.2%
0.593 101.325 0.7561 ± 0.2%
0.708 101.325 0.7592 ± 0.2%
0.717 101.325 0.7580 ± 0.2%
0.780 101.325 0.7593 ± 0.2%
0.810 101.325 0.7585 ± 0.2%
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
300 101.325 0.731
350 101.325 0.946
400 101.325 1.18
450 101.325 1.44
500 101.325 1.72
(continued)

550 101.325 2.02

600 101.325 2.33
650 101.325 2.63
700 101.325 3.00
750 101.325 3.37
800 101.325 3.75
850 101.325 4.16
900 101.325 4.56
950 101.325 4.99
1000 101.325 5.42
1050 101.325 5.84
1100 101.325 6.33
1150 101.325 6.84
1200 101.325 7.33
1250 101.325 7.87
1300 101.325 8.38
1350 101.325 8.90
1400 101.325 9.45
Comment: accuracy: ±(0.5–1)%; argon concentration: 1.5%
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
Mutual Diffusion
Coefficient: D12(x2); Method: TB Ref.: 1977A5
0.7385 0.1016 1.9275 0.02%
Comment: T = 300.00 K; highly precise data
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
20.3 11/6
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
3 –8
Parameter: A · 10 B C · 10 E
15.21 1.552 0.410 1.71

He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
Mutual Diffusion
Coefficient: D12(x2); Method: CT Ref.: 1974S3
0.7335 0.0650 0.9527 0.12
Comment: T = 300 K
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
Mutual DiffusionCoefficient: D12(x2); Method: CT Ref.: 1973H3
Equation: D = A + B x + C x2 Range: 0.0 < x2 < 1.0
0.73234 0.03669 –0.01237 0.0005
0.73340 0.04327 –0.02035 0.0006
0.7308 0.03779 –0.01429 *
Comment: T = 300 K; D12 [m2/s] = D · 10–4;
*: systematic difference of 0.2% to 0.3%
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
Mutual Diffusion
0.73440 0.08460 1.4825 0.06%
Comment: T = 300 K; D12 [m2/s] = D · 10–4
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
–6.9068 1.23353 4.8998 0.05%
Comment: x2 = 0.15; D12 [m2/s] = D · 10–4
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
Mutual DiffusionCoefficient: D12(x2); Method: CT Ref.: 1977A5
0.7344 0.0846 1.4825 0.06%
Comment: T = 300.00 K; recommended data for calibration, superior to previously reported results
(higher accuracy)

He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
Mutual Diffusion
Coefficient: D12(x2); Method: TB Ref.: 1972C4
0.7308 0.03779 –0.01429 0.07%
Comment: T = 300 K; D12 [m2/s] = D · 10–4 correlation recommended for calibration
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
Mutual Diffusion
Coefficient: D12(x2); Method: TB Ref.: 1991K1
0.7344 0.08460 1.4825 0.06%
Comment: T = 300 K; accuracy of data: 0.3%
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
Mutual Diffusion Coefficient: D12(x2); Method: CT Ref.: 1976Y2
Parameter: A B C
0.7356 0.0756 1.062
0.7355 0.0762 1.434*
2 –4
Comment: T = 300 K; D12 [m /s] = D · 10 ;
*: shearing cell measurements
References
1972C4 Carson, P.J., Yabsley, M.A., Dunlop, P.J.: Chem. Phys. Lett. 15 (1972) 436–438.
1972C2 Carson, P.J., Dunlop, P.J., Bell, T.N.: J. Chem. Phys. 56 (1972) 531–536.
Data 13 (1984) 229–303.
1983T6 Taylor, W.L., Cain, D.: J. Chem. Phys. 78 (1983) 6220–6227.
1976S13 Staker, G.R., Dunlop, P.J.: Chem. Phys. Lett. 42 (1976) 419–422.
1976Y2 Yabsley, M.A., Dunlop, P.J.: Physica A 85 (1976) 160–174.
1996S6 Smorenburg, H.E., Clarijs, M.C., Crevecoeur, R.M., de Schepper, I.M.: Phys. Lett. A 224 (1996)
104–108.
1977A5 Arora, P.S., Shankland, I.R., Bell, T.N., Yabsley, M.A., Dunlop, P.J.: Rev. Sci. Instrum. 48
(1977) 673–674.
1974S3 Staker, G.R., Yabsley, M.A., Symons, J.M., Dunlop, P.J.: J. Chem. Soc. Faraday Trans. 1 70
(1974) 825–831.
1991K1 Keil, M., Danielson, L.J., Dunlop, P.J.: J. Chem. Phys. 94 (1991) 296–309.

Diffusion of helium (1); trifluoro-chloro-methane (2) 1
Diffusion of helium (1); trifluoro-chloro-methane (2)

Gaseous Mixtures
He (1) helium 7440-59-7

CClF3 (2) trifluoro-chloro-methane 75-72-9
Mutual Diffusion Coefficient: D12(xi); T = 300.00 ± 0.001 K; Method: CT Ref.: 1973Y5
x2 p [kPa] D · 104 [m2/s]
0.0499 101.325 0.4194 ± 0.1%
0.0518 101.325 0.4185 ± 0.1%
0.0547 101.325 0.4191 ± 0.1%
0.0793 101.325 0.4186 ± 0.1%
0.1305 101.325 0.4220 ± 0.1%
0.1956 101.325 0.4239 ± 0.1%
0.2910 101.325 0.4256 ± 0.1%
0.3975 101.325 0.4265 ± 0.1%
0.5052 101.325 0.4274 ± 0.1%
0.5385 101.325 0.4281 ± 0.1%
0.5996 101.325 0.4291 ± 0.1%
0.6468 101.325 0.4301 ± 0.1%
0.8996 101.325 0.4307 ± 0.1%
0.9495 101.325 0.4311 ± 0.1%
0.9754 101.325 0.4304 ± 0.1%
He (1) helium 7440-59-7

Mutual Diffusion
Coefficient: D12(x2); Method: CT Ref.: 1973Y5
0.4161 0.05959 2.985 0.15%
Comment: T = 300 K; D12 [m2/s] = D · 10–4
Reference
1973Y5 Yabsley, M.A., Carson, P.J., Dunlop, P.J.: J. Phys. Chem. 77 (1973) 703–704.

Diffusion of helium (1); tetrafluoro-methane (2) 1
Diffusion of helium (1); tetrafluoro-methane (2)

Gaseous Mixtures
He (1) helium 7440-59-7

Mutual Diffusion Coefficient: D12(xi); T = 300 K; Method: CT Ref.: 1977B2
x2 p [atm] D · 104 [m2/s]
0.1 1 0.4856
0.1 2 0.2424
0.1 3 0.1614
0.1 4 0.1211
0.1 5 0.0968
0.1 7 0.0691
0.1 9 0.0536
He (1) helium 7440-59-7

Mutual Diffusion
0.4809 0.1145 2.2777 0.07%
Comment: T = 300 K;
He (1) helium 7440-59-7

T = 200.0 K 0.2450 0.1145 2.2777 0.1%
T = 230.0 K 0.3091 0.1145 2.2777 0.1%
T = 260.0 K 0.3789 0.1145 2.2777 0.1%
T = 280.0 K 0.4295 0.1145 2.2777 0.1%
T = 290.0 K 0.4545 0.1145 2.2777 0.1%
T = 300.0 K 0.4804 0.1145 2.2777 0.1%
T = 310.0 K 0.5083 0.1145 2.2777 0.1%
T = 320.0 K 0.5350 0.1145 2.2777 0.1%
T = 360.0 K 0.6479 0.1145 2.2777 0.1%
T = 380.0 K 0.7085 0.1145 2.2777 0.1%
T = 400.0 K 0.7710 0.1145 2.2777 0.1%

2 Diffusion of helium (1); tetrafluoro-methane (2)
He (1) helium 7440-59-7

1.0049 0.1010 4.6078 0.05%
References
1977B2 Bell, T.N., Shankland, I.R., Dunlop, P.J.: Chem. Phys. Lett. 45 (1977) 445–448.
1987D8 Dunlop, P.J., Robjohns, H.L., Bignell, C.M.: Ber. Bunsenges. Phys. Chem. 91 (1987) 156–159.

Diffusion of helium (1); trifluoro-methane (2) 1
Diffusion of helium (1); trifluoro-methane (2)

Gaseous Mixtures
He (1) helium 7440-59-7

CHF3 (2) trifluoro-methane 75-46-7
Mutual Diffusion Ref.: 1990D6
0.5103 0.0897 1.5130 0.05%
Comment: T = 300 K; ΔT = ±0.002 K; precision of D12 = ±0.3%
Reference
1990D6 Dunlop, P.J., Bignell, C.M.: J. Chem. Phys. 93 (1990) 2701–2703.

Diffusion of helium (1); fluoro-methane (2) 1
Diffusion of helium (1); fluoro-methane (2)

Gaseous Mixtures
He (1) helium 7440-59-7

CH3F (2) fluoro-methane 593-53-3
0.6113 0.0693 1.5496 0.03%
Reference

Diffusion of helium (1); methane (2) 1
Diffusion of helium (1); methane (2)

Gaseous Mixtures
He (1) helium 7440-59-7

CH4 (2) methane 74-82-8
Mutual Diffusion Coefficient: D12(T ); Method: GC Ref.: 1979Y1
T [K] p [atm] D · 107 [m2/s]
303.15 ± 0.02 47.65 14.48 ± 0.08
303.15 ± 0.02 56.16 12.31 ± 0.07
303.15 ± 0.02 71.48 9.721 ± 0.04
303.15 ± 0.02 82.37 8.386 ± 0.07
303.15 ± 0.02 93.94 7.384 ± 0.05
303.15 ± 0.02 95.30 7.240 ± 0.03
303.15 ± 0.02 98.71 7.042 ± 0.07
303.15 ± 0.02 100.75 6.858 ± 0.03
303.15 ± 0.02 111.64 6.228 ± 0.04
He (1) helium 7440-59-7

CH4 (2) methane 74-82-8
x2 p [atm] D · 104 [m2/s]
0.1 1 0.6842
0.1 2 0.3414
0.1 3 0.2275
0.1 4 0.1707
0.1 5 0.1365
0.1 7 0.0974
0.1 9 0.0757
He (1) helium 7440-59-7

CH4 (2) methane 74-82-8
T [K] p [atm] D · 107 [m2/s]
283.15 ± 0.02 1.743 0.6160 ± 0.0014
288.15 ± 0.02 1.743 0.6316 ± 0.0009
293.15 ± 0.02 1.743 0.6489 ± 0.0009
298.15 ± 0.02 1.743 0.6736 ± 0.0022
303.15 ± 0.02 1.743 0.6929 ± 0.0018
313.15 ± 0.02 1.743 0.7285 ± 0.0017
323.15 ± 0.02 1.743 0.7682 ± 0.0022
328.15 ± 0.02 1.743 0.7895 ± 0.0033
333.15 ± 0.02 1.743 0.8078 ± 0.0034

2 Diffusion of helium (1); methane (2)
He (1) helium 7440-59-7

CH4 (2) methane 74-82-8
19.0 11/6
He (1) helium 7440-59-7

CH4 (2) methane 74-82-8
5
3.13 1.750
He (1) helium 7440-59-7

CH4 (2) methane 74-82-8
Equation: log (D) = A + B log (T ) Range: 283.15 < T/K < 333.15
Parameter: A B r
–4.3256 1.6783 0.9986
Comment: r = correlation coefficient
He (1) helium 7440-59-7

CH4 (2) methane 74-82-8
Mutual Diffusion
0.6802 0.0457 1.5110 0.04%
Comment: T = 300 K
He (1) helium 7440-59-7

CH4 (2) methane 74-82-8
0.6808 0.0457 1.5110 0.04%
He (1) helium 7440-59-7

CH4 (2) methane 74-82-8
Mutual Diffusion Coefficient: D12(T ); Method: TB Ref.: 1980A9
(continued)
–0.9002 1.3483 4.1171 0.04%

He (1) helium 7440-59-7

CH4 (2) methane 74-82-8
Mutual Diffusion
Coefficient: D12(x1); Method: CT Ref.: 1982T7
0.6802 0.0457 1.5110 0.04%
Comment: T = 300 K; D12 [m2/s] = D · 10–4;
A = –8.5062 · 10–2 + 13.09723 · 10–4 · T + 4.1352 · 10–6 · T 2 [277 - 320 K]
References
1979Y1 Yang, F.J., Hawkes, S.J.: J. Chem. Eng. Data 24 (1979) 354–356.
951–955.

Diffusion of helium (1); carbon monoxide (2) 1
Diffusion of helium (1); carbon monoxide (2)

Gaseous Mixtures
He (1) helium 7440-59-7

Mutual Diffusion Coefficient: D12(xi); T = 355.6 ± 0.05 K; Method: TB Ref.: 1998G5
x2 p [kPa] D · 104 [m2/s]
0.2667 101.325 0.949
0.5040 101.325 0.955
0.7612 101.325 0.960
He (1) helium 7440-59-7

x2 p [kPa] D · 104 [m2/s]
0.2667 101.325 0.896
0.5040 101.325 0.904
0.7612 101.325 0.908
He (1) helium 7440-59-7

x2 p [kPa] D · 104 [m2/s]
0.2667 101.325 0.837
0.5040 101.325 0.842
0.7612 101.325 0.846
He (1) helium 7440-59-7

x2 p [kPa] D · 104 [m2/s]
0.2667 101.325 0.782
0.5040 101.325 0.788
0.7612 101.325 0.792
He (1) helium 7440-59-7

x2 p [kPa] D · 104 [m2/s]
0.2667 101.325 0.738
0.5040 101.325 0.741
0.7612 101.325 0.744

2 Diffusion of helium (1); carbon monoxide (2)
He (1) helium 7440-59-7

Equation: ln (D · p) = ln A + B · ln T – ln [ ln(C/T ) ]2 Range: 77 < T/K < 10000
Parameter: A · 103 B C · 10–8
15.8 1.524 0.265
2
Comment: x1 = 0.50; D12(T ) · p [atm · cm /s] = (D · p); Marrero‐Mason group II
He (1) helium 7440-59-7

Mutual Diffusion
0.7023 0.05521 1.0284 0.05%
Comment: T = 300 K; D12 [m2/s] = D · 10–4;
A = –0.02038 + 0.9211 · 10–3 · T + 4.9595 · 10–6 · T 2 [277 - 323 K]; ΔT = 1 mK
References
Zolotoukhina, A.F.: Mol. Phys. 94 (1998) 605–622.
450–453.

Diffusion of helium (1); carbon oxide sulfide (2) 1
Diffusion of helium (1); carbon oxide sulfide (2)

Gaseous Mixtures
He (1) helium 7440-59-7

COS (2) carbon oxide sulfide 463-58-1
0.5401 0.1133 2.4846 0.06%
Comment: T = 300 K; D12 [m2/s] = D · 10–4;
A = –0.5076 · 10–1 + 0.8955 · 10–3 · T + 2.9762 · 10–6 · T 2 [280 - 400 K]; ΔA = ±0.04%
Reference

Diffusion of helium (1); carbon dioxide (2) 1
Diffusion of helium (1); carbon dioxide (2)

Gaseous Mixtures
He (1) helium 7440-59-7

x2 p [atm] D · 104 [m2/s]
0.1 1 0.6072
0.1 2 0.3028
0.1 3 0.2019
0.1 4 0.1513
0.1 5 0.1209
0.1 7 0.0863
0.1 9 0.067
He (1) helium 7440-59-7

T [K] p [kPa] D · 104 [m2/s]
173.2 101.325 0.251 ± 0.9%
294.6 101.325 0.607 ± 0.9%
595.9 101.325 2.023 ± 0.9%
He (1) helium 7440-59-7

T [K] p [kPa] D · 104 [m2/s]
173.2 101.325 0.249 ± 0.9%
203.2 101.325 0.323 ± 0.9%
233.2 101.325 0.410 ± 0.9%
263.2 101.325 0.506 ± 0.9%
294.6 101.325 0.600 ± 0.9%
409.3 101.325 1.03 ± 0.9%
510.9 101.325 1.50 ± 0.9%
595.9 101.325 1.968 ± 0.9%
He (1) helium 7440-59-7

Intradiffusion Coefficient: D1T(x1); T = 299.65 ± 0.5 K; Method: GC Ref.: 1962G3
x1 p [kPa] D · 104 [m2/s]
0.000 101.325 0.694 ± 0.002
0.182 101.325 0.739 ± 0.003
(continued)

2 Diffusion of helium (1); carbon dioxide (2)
0.321 101.325 0.685 ± 0.007

0.392 101.325 0.725 ± 0.009
0.492 101.325 0.731 ± 0.004
0.582 101.325 0.756 ± 0.005
0.632 101.325 0.761 ± 0.008
0.719 101.325 0.775 ± 0.008
0.821 101.325 0.789 ± 0.009
0.874 101.325 0.726 ± 0.009
He (1) helium 7440-59-7

x1 p [kPa] D · 104 [m2/s]
0.182 101.325 0.688 ± 0.004
0.321 101.325 0.634 ± 0.007
0.392 101.325 0.676 ± 0.005
0.492 101.325 0.666 ± 0.008
0.582 101.325 0.691 ± 0.006
0.632 101.325 0.698 ± 0.006
0.719 101.325 0.688 ± 0.005
0.821 101.325 0.696 ± 0.008
0.874 101.325 0.705 ± 0.009
1.000 101.325 0.723 ± 0.003
He (1) helium 7440-59-7

Intradiffusion Coefficient: D12(xi); T = 300 ± 0.001 K; Method: CT Ref.: 1972H3
x2 p [kPa] D · 104 [m2/s]
0.0522 101.325 0.6039 ± 0.1%
0.0558 101.325 0.6050 ± 0.1%
0.0604 101.325 0.6036 ± 0.1%
0.4468 101.325 0.6103 ± 0.1%
0.4828 101.325 0.6108 ± 0.1%
0.5082 101.325 0.6110 ± 0.1%
0.5084 101.325 0.6070 ± 0.1%
0.7516 101.325 0.6137 ± 0.1%
0.9402 101.325 0.6158 ± 0.1%
0.9408 101.325 0.6177 ± 0.1%
0.9415 101.325 0.6178 ± 0.1%
He (1) helium 7440-59-7

3.31 1.720

He (1) helium 7440-59-7

0.6031 0.0145 0.0014
Comment: T = 300 K; D12 [m2/s] = D · 10–4
He (1) helium 7440-59-7

Mutual Diffusion
0.6029 0.0905 2.3952 0.04%
He (1) helium 7440-59-7

–8.1267 12.3002 3.5624 0.06%
2 –4
Comment: x2 = 0.15; D12 [m /s] = D · 10
He (1) helium 7440-59-7

0.6029 0.0905 2.3952 0.04%
(higher accuracy)
He (1) helium 7440-59-7

Mutual Diffusion
Coefficient: D12(x1); Method: TB Ref.: 1995D4
0.6030 0.0905 2.3952 0.04%
Comment: T = 300 K; D12 [m2/s] = D · 10–4;
A = –0.7769 · 10–1 + 1.1931 · 10–3 · T + 3.5881 · 10–6 · T 2 [220 - 400 K]; ΔA = ±0.04%

He (1) helium 7440-59-7

Mutual Diffusion
0.6064 0.1082 2.7165 0.02%
References
1962G3 Giddings, J.C., Seager, S.L.: Ind. Eng. Chem. Fundam. 4 (1962) 277–283.
1972H3 Harris, K.R., Bell, T.N., Dunlop, P.J.: Can. J. Chem. 50 (1972) 1874–1876.
478–480.
(1977) 673–674.

Diffusion of helium (1); 1,1,1-trifluoro-ethane (2) 1
Diffusion of helium (1); 1,1,1-trifluoro-ethane (2)

Gaseous Mixtures
He (1) helium 7440-59-7

C2F3H3 (2) 1,1,1-trifluoro-ethane 420-46-2
0.4160 0.1504 3.187 0.06%
Comment: T = 300.0 K; D12 [m2/s] = D · 10–4;
A = –0.0968 + 1.134 · 10–3 · T + 1.929 · 10–6 · T 2 [280 - 320 K]; ΔA = 0.05%
Reference


Gaseous Mixtures
He (1) helium 7440-59-7

0.4148 0.1055 2.064 0.04%
Comment: T = 300.0 K; D12 [m2/s] = D · 10–4;
A = –0.1775 + 1.696 · 10–3 · T + 0.929 · 10–6 · T 2 [280 - 320 K]; ΔA = ±0.06%
Reference

Diffusion of helium (1); 1,1,1,2-tetrafluoro-ethane (2) 1
Diffusion of helium (1); 1,1,1,2-tetrafluoro-ethane (2)

Gaseous Mixtures
He (1) helium 7440-59-7

C2F4H2 (2) 1,1,1,2-tetrafluoro-ethane 811-97-2
0.3960 0.1022 1.770 0.07%
Comment: T = 300.0 K; D12 [m2/s] = D · 10–4;
A = –0.1142 + 1.251 · 10–3 · T + 1.500 · 10–6 · T 2 [280 - 320 K]; ΔA = ±0.03%
Reference

Diffusion of helium (1); hexafluoro-ethane (2) 1
Diffusion of helium (1); hexafluoro-ethane (2)

Gaseous Mixtures
He (1) helium 7440-59-7

C2F6 (2) hexafluoro-ethane 76-16-4
x2 p [atm] D · 104 [m2/s]
0.075 1 0.3700
0.075 2 0.1845
0.075 3 0.1228
0.075 4 0.092
0.075 5 0.0735
0.075 7 0.0524
0.075 9 0.0407
He (1) helium 7440-59-7

x2 p [atm] D · 104 [m2/s]
0.1 1 0.5033
0.1 2 0.2511
0.1 3 0.1671
0.1 4 0.1252
0.1 5 0.100
0.1 7 0.0713
0.1 9 0.0553
He (1) helium 7440-59-7

0.3658 0.1518 2.519 0.07%
Comment: T = 300.0 K; D12 [m2/s] = D · 10–4;
A = –0.0514 + 0.798 · 10–3 · T + 1.988 · 10–6 · T 2 [280 - 320 K]; ΔA = ±0.07%
He (1) helium 7440-59-7

Mutual Diffusion
0.3658 0.1518 2.5190 0.07%

2 Diffusion of helium (1); hexafluoro-ethane (2)
References

Diffusion of helium (1); 1,1,1,2,2-pentafluoro-ethane (2) 1
Diffusion of helium (1); 1,1,1,2,2-pentafluoro-ethane (2)

Gaseous Mixtures
He (1) helium 7440-59-7

C2HF5 (2) 1,1,1,2,2-pentafluoro-ethane 354-33-6
0.3790 0.1871 3.197 0.10%
Comment: T = 300.0 K; D12 [m2/s] = D · 10–4;
A = –0.0551 + 0.826 · 10–3 · T + 2.071 · 10–6 · T 2 [280 - 320 K]; ΔA = ±0.04%
Reference

Diffusion of helium (1); ethyne (2) 1
Diffusion of helium (1); ethyne (2)

Gaseous Mixtures
He (1) helium 7440-59-7

C2H2 (2) ethyne 74-86-2
0.5936 0.0588 2.0201 0.04%
Reference


Gaseous Mixtures
He (1) helium 7440-59-7

C2H2F4 (2) 1,1,2,2-tetrafluoro-ethane 359-35-3
0.3970 0.1150 1.690 0.06%
Comment: T = 300.0 K; D12 [m2/s] = D · 10–4;
A = –0.0654 + 0.900 · 10–3 · T + 2.143 · 10–6 · T 2 [280 - 320 K]; ΔA = ±0.04%
Reference

Diffusion of helium (1); ethene (2) 1
Diffusion of helium (1); ethene (2)

Gaseous Mixtures
He (1) helium 7440-59-7

C2H4 (2) ethene 74-85-1
0.5415 0.0650 1.7888 0.03%
Reference

Diffusion of helium (1); 1,1-difluoro-ethane (2) 1
Diffusion of helium (1); 1,1-difluoro-ethane (2)

Gaseous Mixtures
He (1) helium 7440-59-7

C2H4F2 (2) 1,1-difluoro-ethane 75-37-6
0.4365 0.1223 2.485 0.04%
Comment: T = 300.0 K; D12 [m2/s] = D · 10–4;
A = 0.1873 – 0.732 · 10–3 · T + 5.214 · 10–6 · T 2 [280 - 320 K]; ΔA = ±0.08%
Reference

Diffusion of helium (1); fluoro-ethane (2) 1
Diffusion of helium (1); fluoro-ethane (2)

Gaseous Mixtures
He (1) helium 7440-59-7

C2H5F (2) fluoro-ethane 353-36-6
0.4650 0.1034 2.591 0.05%
Comment: T = 300.0 K; D12 [m2/s] = D · 10–4;
A = –0.0564 +0.945 · 10–3 · T + 2.643 · 10–6 · T 2 [280 - 320 K]; ΔA = ±0.05%
Reference

Diffusion of helium (1); ethane (2) 1
Diffusion of helium (1); ethane (2)

Gaseous Mixtures
He (1) helium 7440-59-7

C2H6 (2) ethane 74-84-0
0.4998 0.0883 2.650 0.01%
Comment: T = 300.0 K; D12 [m2/s] = D · 10–4;
A = –0.0651 + 1.002 · 10–3 · T + 2.940 · 10–6 · T 2 [280 - 320 K]; ΔA = ±0.04%
He (1) helium 7440-59-7

C2H6 (2) ethane 74-84-0
Mutual Diffusion
0.4998 0.0883 2.6496 0.01%
References

Diffusion of helium (1); octafluoro-propane (2) 1
Diffusion of helium (1); octafluoro-propane (2)

Gaseous Mixtures
He (1) helium 7440-59-7

C3F8 (2) octafluoro-propane 76-19-7
x2 p [atm] D · 104 [m2/s]
0.05 1 0.3080
0.05 2 0.1537
0.05 3 0.1023
0.05 4 0.0765
0.05 5 0.0611
0.05 7 0.0435
He (1) helium 7440-59-7

Mutual Diffusion
0.3050 0.1901 3.8932 0.06%
References

Diffusion of helium (1); cyclopropane (2) 1
Diffusion of helium (1); cyclopropane (2)

Gaseous Mixtures
He (1) helium 7440-59-7

C3H6 (2) cyclopropane 75-19-4
0.4469 0.0887 2.0339 0.04%
Reference

Diffusion of helium (1); propane (2) 1
Diffusion of helium (1); propane (2)

Gaseous Mixtures
He (1) helium 7440-59-7

C3H8 (2) propane 74-98-6
x2 p [atm] D · 104 [m2/s]
0.1 1 0.4097
0.1 2 0.2041
0.1 3 0.1358
0.1 4 0.1014
0.1 5 0.0809
0.1 7 0.0574
0.1 9 0.0443
He (1) helium 7440-59-7

C3H8 (2) propane 74-98-6
Mutual Diffusion
0.4070 0.0675 1.6370 0.04%
References

Diffusion of helium (1); octafluoro-cyclobutane (2) 1
Diffusion of helium (1); octafluoro-cyclobutane (2)

Gaseous Mixtures
He (1) helium 7440-59-7

C4F8 (2) octafluoro-cyclobutane 115-25-3
0.2877 0.2133 5.5377 0.05%
Reference

Diffusion of helium (1); buta-1,3-diene (2) 1
Diffusion of helium (1); buta-1,3-diene (2)

Gaseous Mixtures
He (1) helium 7440-59-7

C4H6 (2) buta-1,3-diene 106-99-0
0.3804 0.1060 0 0.01%
Comment: T = 300 K; ΔT = ±0.002 K; precision of D12 = ±0.3%; applies only to x2 = 0.15
Reference

Diffusion of helium (1); butane (2) 1
Diffusion of helium (1); butane (2)

Gaseous Mixtures
He (1) helium 7440-59-7

C4H10 (2) butane 106-97-8
x2 p [atm] D · 104 [m2/s]
0.075 1 0.3500
0.075 2 0.1740
0.075 3 0.1158
0.075 4 0.0864
0.075 5 0.0688
He (1) helium 7440-59-7

C4H10 (2) butane 106-97-8
Mutual Diffusion
0.3478 0.0858 2.1167 0.05%
References

Diffusion of helium (1); sulfur hexafluoride (2) 1
Diffusion of helium (1); sulfur hexafluoride (2)

Gaseous Mixtures
He (1) helium 7440-59-7

x2 p [kPa] D · 104 [m2/s]
0.0574 101.325 0.3903 ± 0.1%
0.0629 101.325 0.3905 ± 0.1%
0.1194 101.325 0.3907 ± 0.1%
0.3023 101.325 0.3938 ± 0.1%
0.4011 101.325 0.3937 ± 0.1%
0.5001 101.325 0.3960 ± 0.1%
0.6998 101.325 0.3978 ± 0.1%
0.7868 101.325 0.3980 ± 0.1%
0.9378 101.325 0.4002 ± 0.1%
0.9404 101.325 0.4026 ± 0.1%
He (1) helium 7440-59-7

Mutual Diffusion Coefficient: D12(xi); T = 300.0 K; Method: CT Ref.: 1977B2
x2 p [kPa] D · 104 [m2/s]
0.1 1 0.3961
0.1 2 0.1972
0.1 3 0.1312
0.1 4 0.0982
0.1 5 0.0782
0.1 7 0.0557
0.1 9 0.0432
He (1) helium 7440-59-7

5
3.87 1.627
He (1) helium 7440-59-7

0.3895 0.0121 0.0008
Comment: T = 300 K; D12 [m2/s] = D · 10–4

2 Diffusion of helium (1); sulfur hexafluoride (2)
References

Diffusion of helium (1); hydrogen (2) 1
Diffusion of helium (1); hydrogen (2)

Gaseous Mixtures
He (1) helium 7440-59-7

H2 (2) hydrogen 1333-74-0
Mutual Diffusion Coefficient: D12(T ); Method: TB Ref.: 1995T2
T [K] p [kPa] D · 104 [m2/s]
251 ± 0.05 101.325 1.166
251 ± 0.05 101.325 1.167
297 ± 0.05 101.325 1.597
297 ± 0.05 101.325 1.606
297 ± 0.05 101.325 1.595
297 ± 0.05 101.325 1.580
299 ± 0.05 101.325 1.584
350 ± 0.05 101.325 2.118
350 ± 0.05 101.325 2.062
Comment: composition x1 = 0.50; accuracy: ±0.3%
He (1) helium 7440-59-7

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
273.15 ± 0.001 101.325 1.375 ± 0.3%
280.00 ± 0.001 101.325 1.430 ± 0.3%
290.00 ± 0.001 101.325 1.520 ± 0.3%
300.00 ± 0.001 101.325 1.605 ± 0.3%
310.00 ± 0.001 101.325 1.696 ± 0.3%
320.00 ± 0.001 101.325 1.790 ± 0.3%
He (1) helium 7440-59-7

H2 (2) hydrogen 1333-74-0
Mutual Diffusion Coefficient: D12(T ); Method: TB Ref.: 1971W4
T [K] p [kPa] D · 104 [m2/s]
77.1 101.325 0.155 ± 3%
296.5 101.325 1.57 ± 3%
381.8 101.325 2.44 ± 3%
513.6 101.325 4.04 ± 3%
631.9 101.325 5.65 ± 3%
796.0 101.325 8.47 ± 3%
917.0 101.325 10.4 ± 3%

2 Diffusion of helium (1); hydrogen (2)
He (1) helium 7440-59-7

H2 (2) hydrogen 1333-74-0
x1 p [Torr] D · 104 [m2/s]
0.7731 801.8 1.46 ± 0.218%
0.4785 800.2 1.42 ± 0.321%
0.2899 801.6 1.42 ± 0.227%
0.1244 807.1 1.39 ± 0.654%
He (1) helium 7440-59-7

H2 (2) hydrogen 1333-74-0
x1 p [Torr] D · 104 [m2/s]
0.7533 57.0 11.5 ± 0.97%
0.7245 106.8 7.19 ± 0.62%
0.7318 205.3 5.33 ± 0.62%
0.7533 403.4 2.83 ± 0.53%
0.7731 801.8 1.46 ± 0.22%
0.7942 1196.4 0.988 ± 0.21%
He (1) helium 7440-59-7

H2 (2) hydrogen 1333-74-0
T [K] p [Torr] D · 104 [m2/s]
278.02 ± 0.01 803.1 1.29 ± 0.71%
298.12 ± 0.01 801.8 1.45 ± 0.20%
308.19 ± 0.01 808.2 1.50 ± 0.33%
He (1) helium 7440-59-7

H2 (2) hydrogen 1333-74-0
27.0 1.510 0.0534
He (1) helium 7440-59-7

H2 (2) hydrogen 1333-74-0
0.0104 0.1691 1.2089 0.08%
Comment: x1 = 0.50

He (1) helium 7440-59-7

H2 (2) hydrogen 1333-74-0
Mutual Diffusion Coefficient: D12(T ); Method: TB Ref.: 1971W4
Equation: log (D ) = A + B log (T ) Range: 77.0 < T/K < 920.0
Parameter: A · 104 B Std-Dev
–4.016 1.703 1.2%
References
1995T2 Taylor, W.L., Hurly, J.J., Meyer, B.A., Dunlop, P.J.: J. Chem. Phys. 103 (1995) 6959–6965.
1971W4 Weissman, S.: J. Chem. Phys. 55 (1971) 5839–5840.

Diffusion of helium (1); deuterium (2) 1
Diffusion of helium (1); deuterium (2)

Gaseous Mixtures
He (1) helium 7440-59-7

D2 (2) deuterium 7782-39-0
T [K] p [kPa] D · 104 [m2/s]
77.2 101.325 0.131 ± 0.9%
132.5 101.325 0.324 ± 0.9%
183.6 101.325 0.596 ± 0.9%
233.4 101.325 0.851 ± 0.9%
295.3 101.325 1.29 ± 0.9%
401.2 101.325 2.17 ± 0.9%
470.7 101.325 2.88 ± 0.9%
592.1 101.325 4.29 ± 0.9%
He (1) helium 7440-59-7

D2 (2) deuterium 7782-39-0
T [K] p [atm] D · 104 [m2/s]
273.15 ± 0.001 101.325 1.128 ± 0.3%
280.00 ± 0.001 101.325 1.170 ± 0.3%
290.00 ± 0.001 101.325 1.235 ± 0.3%
300.00 ± 0.001 101.325 1.308 ± 0.3%
310.00 ± 0.001 101.325 1.383 ± 0.3%
320.00 ± 0.001 101.325 1.462 ± 0.3%
Comment: x1 = 0.50
He (1) helium 7440-59-7

D2 (2) deuterium 7782-39-0
Mutual Diffusion Coefficient: D12(xi); T = 298 ± 0.05 K; Method: TB Ref.: 1995T2
x1 p [atm] D · 104 [m2/s]
0.50 0.526 1.283
0.50 0.526 1.309
0.50 0.527 1.270
0.50 0.527 1.304
0.50 0.528 1.280
0.50 0.532 1.283
0.50 0.532 1.305
0.50 0.659 1.290
0.50 0.659 1.314
0.50 0.659 1.302
0.50 0.659 1.307
(continued)

2 Diffusion of helium (1); deuterium (2)
0.50 50.0 1.303

0.50 50.0 1.324
He (1) helium 7440-59-7

D2 (2) deuterium 7782-39-0
T [K] p [kPa] D · 104 [m2/s]
252 ± 0.05 101.325 0.971
254 ± 0.05 101.325 0.952
296 ± 0.05 101.325 1.284
296 ± 0.05 101.325 1.284
357 ± 0.05 101.325 1.764
357 ± 0.05 101.325 1.770
357 ± 0.05 101.325 1.759
He (1) helium 7440-59-7

D2 (2) deuterium 7782-39-0
1.1978 –0.6579 2.3144 0.06%
Comment: x1 = 0.50
References

Diffusion of helium (1); ammonia (2) 1
Diffusion of helium (1); ammonia (2)

Gaseous Mixtures
He (1) helium 7440-59-7

H 3N (2) ammonia 7664-41-7
0.7450 0.0420 1.053 0.1%
Comment: T = 300.0 K; D12 [m2/s] = D · 10–4;
A = –1.3157 · 10–1 + 1.6943 · 10–3 · T + 4.1115 · 10–6 · T 2 [280 - 400 K]; ΔA = ±0.07%
Reference

Diffusion of helium (1); helium-3 (2) 1
Diffusion of helium (1); helium-3 (2)

Gaseous Mixtures
He (1) helium 7440-59-7

He-3 (2) helium-3 14762-55-1
T [K] p [kPa] D · 104 [m2/s]
273.15 ± 0.001 101.325 1.574 ± 0.3%
280.00 ± 0.001 101.325 1.644 ± 0.3%
290.00 ± 0.001 101.325 1.745 ± 0.3%
300.00 ± 0.001 101.325 1.846 ± 0.3%
310.00 ± 0.001 101.325 1.948 ± 0.3%
320.00 ± 0.001 101.325 2.060 ± 0.3%
Comment: composition x1 = 0.50
He (1) helium 7440-59-7

He-3 (2) helium-3 14762-55-1
0.2478 0.3573 1.1357 0.08%
Comment: x1 = 0.50
Reference

Diffusion of helium (1); krypton (2) 1
Diffusion of helium (1); krypton (2)

Gaseous Mixtures
He (1) helium 7440-59-7

Kr (2) krypton 7439-90-9
Mutual Diffusion Coefficient: D12(xi); T = 300 ± 0.001 K; Method: CT Ref.: 1972C3
x2 p [atm] D · 104 [m2/s]
0.0340 0.8801 0.7195 ± 0.2%
0.0735 0.8716 0.7278 ± 0.2%
0.1250 0.8800 0.7231 ± 0.2%
0.1313 0.8934 0.7115 ± 0.2%
0.2107 0.8541 0.7487 ± 0.2%
0.3520 0.8806 0.7330 ± 0.2%
0.3924 0.8806 0.7338 ± 0.2%
0.4393 0.8800 0.7351 ± 0.2%
0.4957 0.8792 0.7391 ± 0.2%
0.6003 0.8812 0.7384 ± 0.2%
0.6649 0.8753 0.7447 ± 0.2%
0.7280 0.8789 0.7429 ± 0.2%
0.8422 0.8350 0.7815 ± 0.2%
0.9011 0.8578 0.7622 ± 0.2%
0.9660 0.8798 0.7459 ± 0.2%
He (1) helium 7440-59-7

Kr (2) krypton 7439-90-9
Mutual Diffusion Coefficient: D12(xi); T 304.65 ± 0.05 K; Method: TB Ref.: 1962S5
x1 p [kPa] D · 104 [m2/s]
0.00 101.325 0.1035 ± 1%
0.0893 101.325 0.112 ± 1%
0.2606 101.325 0.131 ± 1%
0.5063 101.325 0.176 ± 1%
0.7954 101.325 0.311 ± 1%
1.000 101.325 0.660 ± 1%
85
Comment: Kr diffusing into mixture He - Kr
He (1) helium 7440-59-7

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
126.5 ± 0.1 101.325 0.152 ± 0.9%
294.5 ± 0.1 101.325 0.647 ± 0.9%
294.5 ± 0.1 101.325 0.648 ± 0.9%
775.9 ± 0.1 101.325 3.36 ± 0.9%

2 Diffusion of helium (1); krypton (2)
He (1) helium 7440-59-7

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0272
100.0 101.325 0.0976
150.0 101.325 0.1992
200.0 101.325 0.3262
250.0 101.325 0.4756
300.0 101.325 0.6459
273.15 101.325 0.5519
293.15 101.325 0.6214
313.15 101.325 0.6940
333.15 101.325 0.7697
353.15 101.325 0.8486
373.15 101.325 0.9307
423.15 101.325 1.1497
473.15 101.325 1.3879
523.15 101.325 1.6448
573.15 101.325 1.9195
623.15 101.325 2.2117
673.15 101.325 2.5207
723.15 101.325 2.8463
773.15 101.325 3.1880
873.15 101.325 3.9186
973.15 101.325 4.7102
1073.15 101.325 5.5611
1173.15 101.325 6.4695
1273.15 101.325 7.4342
1773.15 101.325 13.0628
2273.15 101.325 19.9557
2773.15 101.325 28.0352
3273.15 101.325 37.2446
He (1) helium 7440-59-7

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0272
100.0 101.325 0.0982
150.0 101.325 0.2011
200.0 101.325 0.3301
250.0 101.325 0.4818
300.0 101.325 0.6544
273.15 101.325 0.5592
293.15 101.325 0.6295
313.15 101.325 0.7031
(continued)
333.15 101.325 0.7797

353.15 101.325 0.8595
373.15 101.325 0.9424
423.15 101.325 1.1637
473.15 101.325 1.4045
523.15 101.325 1.6641
573.15 101.325 1.9419
623.15 101.325 2.2373
673.15 101.325 2.5498
723.15 101.325 2.8790
773.15 101.325 3.2246
873.15 101.325 3.9633
973.15 101.325 4.7637
1073.15 101.325 5.6239
1173.15 101.325 6.5421
1273.15 101.325 7.5172
1773.15 101.325 13.2041
2273.15 101.325 20.1653
2773.15 101.325 28.3219
3273.15 101.325 37.6162
He (1) helium 7440-59-7

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0272
100.0 101.325 0.0987
150.0 101.325 0.2027
200.0 101.325 0.3333
250.0 101.325 0.4868
300.0 101.325 0.6614
273.15 101.325 0.5651
293.15 101.325 0.6363
313.15 101.325 0.7106
333.15 101.325 0.7880
353.15 101.325 0.8685
373.15 101.325 0.9521
423.15 101.325 1.1753
473.15 101.325 1.4182
523.15 101.325 1.6802
573.15 101.325 1.9605
623.15 101.325 2.2587
673.15 101.325 2.5741
723.15 101.325 2.9064
773.15 101.325 3.2552
873.15 101.325 4.0008
973.15 101.325 4.8086
(continued)
1073.15 101.325 5.6767

1173.15 101.325 6.6033
1273.15 101.325 7.5870
1773.15 101.325 13.3233
2273.15 101.325 20.3422
2773.15 101.325 28.5640
3273.15 101.325 37.9301
He (1) helium 7440-59-7

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
300 101.325 0.632
350 101.325 0.819
400 101.325 1.015
450 101.325 1.235
500 101.325 1.485
550 101.325 1.730
600 101.325 2.005
650 101.325 2.29
700 101.325 2.59
750 101.325 2.93
800 101.325 3.26
850 101.325 3.60
900 101.325 3.97
950 101.325 4.34
1000 101.325 4.71
1050 101.325 5.09
1100 101.325 5.50
Comment: accuracy: ±(0.5–1)%; krypton concentration: 1.5%
He (1) helium 7440-59-7

Kr (2) krypton 7439-90-9
x2 p [atm] D · 104 [m2/s]
0.1 1 0.6417
0.1 2 0.3203
0.1 3 0.2136
0.1 4 0.1602
0.1 5 0.1281
0.1 7 0.0914
0.1 9 0.0711

He (1) helium 7440-59-7

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
126.5 ± 0.1 101.325 0.151 ± 0.9%
164.0 ± 0.1 101.325 0.234 ± 0.9%
203.5 ± 0.1 101.325 0.338 ± 0.9%
242.8 ± 0.1 101.325 0.459 ± 0.9%
294.5 ± 0.1 101.325 0.633 ± 0.9%
294.5 ± 0.1 101.325 0.637 ± 0.9%
395.3 ± 0.1 101.325 1.042 ± 0.9%
501.0 ± 0.1 101.325 1.57 ± 0.9%
591.3 ± 0.1 101.325 2.074 ± 0.9%
698.2 ± 0.1 101.325 2.74 ± 0.9%
775.9 ± 0.1 101.325 3.27 ± 0.9%
He (1) helium 7440-59-7

Kr (2) krypton 7439-90-9
17.9 11/6
He (1) helium 7440-59-7

Kr (2) krypton 7439-90-9
10.61 1.609 1.42 –32.65 2036.0
2
Comment: x1 = 0.50; D12(T ) · p [atm · cm /s] = (D · p); Marrero‐Mason group I
He (1) helium 7440-59-7

Kr (2) krypton 7439-90-9
Mutual Diffusion
0.6332 0.0916 1.5391 0.10
Comment: T = 300 K

He (1) helium 7440-59-7

Kr (2) krypton 7439-90-9
–12.3666 1.52792 3.3999 0.03%
2 –4
Comment: x2 = 0.10; D12 [m /s] = D · 10
He (1) helium 7440-59-7

Kr (2) krypton 7439-90-9
Mutual Diffusion
0.63562 0.04991 1.0381 0.06%
Comment: T = 300 K; D12 [m2/s] = D · 10–4
He (1) helium 7440-59-7

Kr (2) krypton 7439-90-9
Mutual Diffusion
0.6356 0.07852 1.0381 0.06%
Comment: T = 300 K; accuracy of data: 0.3%
He (1) helium 7440-59-7

Kr (2) krypton 7439-90-9
Mutual Diffusion
Coefficient: D12(x2); Method: TB Ref.: 1972C3
0.63088 0.04800 –0.02421 0.0009
Comment: T = 300 K; D12 [m2/s] = D · 10–4
References
1972C3 Carson, P.J., Dunlop, P.J.: Chem. Phys. Lett. 14 (1972) 377–379.
1962S5 Srivastava, B.N., Paul, R.: Physica 28 (1962) 646–652.
Data 13 (1984) 229–303.
(1974) 825–831.

Diffusion of helium (1); nitrogen oxide (2) 1
Diffusion of helium (1); nitrogen oxide (2)

Gaseous Mixtures
He (1) helium 7440-59-7

NO (2) nitrogen oxide 10102-43-9
0.7239 0.0932 2.261 0.07%
Comment: T = 300.0 K; D12 [m2/s] = D · 10–4;
A = –2.2440 · 10–1 – 0.6346 · 10–3 · T + 0.7714 · 10–5 · T 2 [280 - 320 K]; ΔA = ±0.02%
Reference

Diffusion of helium (1); nitrogen (2) 1
Diffusion of helium (1); nitrogen (2)

Gaseous Mixtures
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
294.5 101.325 0.699*
294.5 101.325 0.687
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
x2 p [atm] D · 104 [m2/s]
0.1 1 0.7112
0.1 2 0.3553
0.1 3 0.2368
0.1 4 0.1776
0.1 5 0.1421
0.1 7 0.1015
0.1 9 0.0790
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
x2 p [atm] D · 104 [m2/s]
0.0822 5.049 0.140
0.9497 5.002 0.143
0.0851 5.004 0.141
0.9079 5.089 0.1409
0.9331 5.101 0.1407
0.9499 5.008 0.143
0.7044 4.919 0.1455
0.3172 5.076 0.140
0.1729 5.032 0.1408
0.7991 4.915 0.1457
0.9403 3.004 0.239
0.9302 1.00 0.7195
0.9604 7.004 0.1025
0.9601 9.007 0.0798
0.0800 9.000 0.0785
0.9699 11.001 0.0653
0.0746 10.996 0.0643
(continued)

2 Diffusion of helium (1); nitrogen (2)
0.9702 10.998 0.0653

0.0709 12.511 0.0566
0.6668 8.998 0.0794
0.3731 8.998 0.0791
0.7398 7.002 0.1021
0.5019 7.258 0.0981
0.2994 7.003 0.1015
0.0989 0.999 0.7080
0.3771 1.001 0.7134
0.6530 1.000 0.7167
0.9300 1.000 0.7196
0.8000 1.000 0.7188
0.5000 1.000 0.7150
0.2997 1.000 0.7132
0.1001 1.000 0.7065
0.9301 1.000 0.7196
0.1999 1.000 0.7096
0.9400 3.000 0.2393
0.1000 3.000 0.2354
0.7998 3.000 0.2391
0.2000 3.000 0.2365
0.5000 3.000 0.2382
0.6500 3.000 0.2386
0.2983 2.993 0.2377
0.6503 1.000 0.7170
0.3768 1.000 0.7140
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
x1 p [kPa] D · 104 [m2/s]
0.000 101.325 0.833 ± 0.007
0.178 101.325 0.852 ± 0.003
0.342 101.325 0.834 ± 0.007
0.490 101.325 0.830 ± 0.003
0.644 101.325 0.835 ± 0.006
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
x1 p [kPa] D · 104 [m2/s]
0.178 101.325 0.859 ± 0.004
0.342 101.325 0.849 ± 0.003
0.490 101.325 0.843 ± 0.007
0.644 101.325 0.859 ± 0.003
1.000 101.325 0.808 ± 0.006

He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
15.8 1.524 0.265
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
20.4 11/6
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
Mutual Diffusion Coefficient: D12(x2); Method: CT Ref.: 1976S12
0.7100 0.0267 0.565 0.04*
0.7091 0.0389 1.250 0.09*
0.7107 0.0317 1.093 0.04*
Comment: T = 300 K; *: percentage deviation of D12 at x2 = 0.5; ΔT = ±0.001 K
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
–15.2693 18.0450 3.3999 0.04%
Comment: x2 = 0.20; D12 [m2/s] = D · 10–4
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
Mutual Diffusion
0.7067 0.0676 1.4883 0.04%
2 –4
Comment: T = 300 K; D12 [m /s] = D · 10

He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
0.7067 0.0676 1.4883 0.04%
(higher accuracy)
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
Mutual Diffusion
0.7067 0.0676 1.4883 0.04%
Comment: T = 300.0 K; D12 [m2/s] = D · 10–4;
A = –0.148236 + 1.76579 · 10–3 · T + 3.6152 · 10–6 · T 2 [277 - 323 K]; ΔA = ±0.04%
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
Mutual Diffusion
0.7129 0.0576 1.2505 0.04%
Comment: T = 300 K; highly precise data
References
1975S10 Staker, G.R., Dunlop, P.J., Harris, K.R., Bell, T.N.: Chem. Phys. Lett. 32 (1975) 561–565.
1976S12 Staker, G.R., Dunlop, P.J.: Rev. Sci. Instrum. 47 (1976) 1190–1192.
478–480.
(1977) 673–674.

Diffusion of helium (1); nitrous oxide (2) 1
Diffusion of helium (1); nitrous oxide (2)

Gaseous Mixtures
He (1) helium 7440-59-7

x2 p [kPa] D · 104 [m2/s]
0.0556 101.325 0.5941 ± 0.1%
0.1119 101.325 0.5937 ± 0.1%
0.4977 101.325 0.5986 ± 0.1%
0.5005 101.325 0.6012 ± 0.1%
0.5016 101.325 0.6016 ± 0.1%
0.9404 101.325 0.6049 ± 0.1%
0.9405 101.325 0.6070 ± 0.1%
He (1) helium 7440-59-7

x2 p [atm] D · 104 [m2/s]
0.1 1 0.5991
0.1 2 0.2991
0.1 3 0.1993
0.1 4 0.1494
0.1 5 0.1194
0.1 7 0.0850
0.1 9 0.0661
He (1) helium 7440-59-7

0.5930 0.0144 0.0014
Comment: T = 300 K; D12 [m2/s] = D · 10–4
He (1) helium 7440-59-7

Mutual Diffusion
0.5935 0.0552 1.2273 0.08%
2 –4
Comment: T = 300.0 K; D12 [m /s] = D · 10 ;
A = –0.8621 · 10–1 + 1.2326 · 10–3 · T + 3.4405 · 10–6 · T 2 [280 - 400 K]; ΔA = ±0.05%

2 Diffusion of helium (1); nitrous oxide (2)
References

Diffusion of helium (1); neon (2) 1
Diffusion of helium (1); neon (2)

Gaseous Mixtures
He (1) helium 7440-59-7

Ne (2) neon 7440-01-9
T [K] p [kPa] D · 104 [m2/s]
388 101.325 1.772
446 101.325 2.219
548 101.325 3.100
586 101.325 3.434
669 101.325 4.171
670 101.325 4.269
771 101.325 5.490
866 101.325 6.627
882 101.325 6.840
947 101.325 8.074
952 101.325 7.727
1014 101.325 9.285
1027 101.325 9.314
1075 101.325 10.142
1129 101.325 10.791
1199 101.325 12.360
Comment: D12 at equimolar composition
He (1) helium 7440-59-7

Ne (2) neon 7440-01-9
Mutual Diffusion Coefficient: D12(xi); T = 300.00 ± 0.001 K; Method: CT Ref.: 1972Y1
x2 p [kPa] D · 104 [m2/s]
0.0969 101.325 1.0954 ± 0.2%
0.2245 101.325 1.1000 ± 0.2%
0.3376 101.325 1.1055 ± 0.2%
0.3824 101.325 1.1042 ± 0.2%
0.4312 101.325 1.1091 ± 0.2%
0.4530 101.325 1.1092 ± 0.2%
0.5182 101.325 1.1045 ± 0.2%
0.6009 101.325 1.1073 ± 0.2%
0.6710 101.325 1.1112 ± 0.2%
0.7011 101.325 1.1122 ± 0.2%
0.7786 101.325 1.1134 ± 0.2%
0.8078 101.325 1.1165 ± 0.2%
0.8978 101.325 1.1181 ± 0.2%
0.9148 101.325 1.1197 ± 0.2%

2 Diffusion of helium (1); neon (2)
He (1) helium 7440-59-7

Ne (2) neon 7440-01-9
T [K] p [kPa] D · 104 [m2/s]
300 101.325 1.10
350 101.325 1.43
400 101.325 1.78
450 101.325 2.15
500 101.325 2.57
550 101.325 3.00
600 101.325 3.50
650 101.325 3.97
700 101.325 4.49
750 101.325 5.02
800 101.325 5.61
850 101.325 6.23
900 101.325 6.83
950 101.325 7.46
1000 101.325 8.12
1050 101.325 8.82
1100 101.325 9.49
1150 101.325 10.21
1200 101.325 10.98
1250 101.325 11.73
1300 101.325 12.48
1350 101.325 13.33
1400 101.325 14.16
Comment: accuracy: ±(0.5–1)%; neon concentration: 1.5%
He (1) helium 7440-59-7

Ne (2) neon 7440-01-9
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0507
100.0 101.325 0.1726
150.0 101.325 0.3439
200.0 101.325 0.5573
250.0 101.325 0.8095
300.0 101.325 1.0964
273.15 101.325 0.9382
293.15 101.325 1.0552
313.15 101.325 1.1774
333.15 101.325 1.3049
353.15 101.325 1.4376
373.15 101.325 1.5754
423.15 101.325 1.9420
473.15 101.325 2.3395
523.15 101.325 2.7671
(continued)
573.15 101.325 3.2241

623.15 101.325 3.7098
673.15 101.325 4.2236
723.15 101.325 4.7650
773.15 101.325 5.3334
873.15 101.325 6.5496
973.15 101.325 7.8687
1073.15 101.325 9.2882
1173.15 101.325 10.8053
1273.15 101.325 12.4181
1773.15 101.325 21.8530
2273.15 101.325 33.4500
2773.15 101.325 47.0840
3273.15 101.325 62.6642
Comment: x1 = 0.75; extended data set from a correlation, accuracy: ±1.0%
He (1) helium 7440-59-7

Ne (2) neon 7440-01-9
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0508
100.0 101.325 0.1739
150.0 101.325 0.3471
200.0 101.325 0.5627
250.0 101.325 0.8178
300.0 101.325 1.1079
273.15 101.325 0.9480
293.15 101.325 1.0662
313.15 101.325 1.1897
333.15 101.325 1.3185
353.15 101.325 1.4525
373.15 101.325 1.5916
423.15 101.325 1.9615
473.15 101.325 2.3625
523.15 101.325 2.7937
573.15 101.325 3.2544
623.15 101.325 3.7441
673.15 101.325 4.2620
723.15 101.325 4.8076
773.15 101.325 5.3805
873.15 101.325 6.6060
973.15 101.325 7.9352
1073.15 101.325 9.3651
1173.15 101.325 10.8934
1273.15 101.325 12.5178
1773.15 101.325 22.0184
2273.15 101.325 33.6920
(continued)

2773.15 101.325 47.4122

3273.15 101.325 63.0872
He (1) helium 7440-59-7

Ne (2) neon 7440-01-9
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0510
100.0 101.325 0.1751
150.0 101.325 0.3500
200.0 101.325 0.5675
250.0 101.325 0.8252
300.0 101.325 1.1182
273.15 101.325 0.9567
293.15 101.325 1.0761
313.15 101.325 1.2007
333.15 101.325 1.3307
353.15 101.325 1.4658
373.15 101.325 1.6061
423.15 101.325 1.9790
473.15 101.325 2.3830
523.15 101.325 2.8174
573.15 101.325 3.2816
623.15 101.325 3.7747
673.15 101.325 4.2963
723.15 101.325 4.8458
773.15 101.325 5.4226
873.15 101.325 6.6565
973.15 101.325 7.9946
1073.15 101.325 9.4340
1173.15 101.325 10.9723
1273.15 101.325 12.6071
1773.15 101.325 22.1668
2273.15 101.325 33.9092
2773.15 101.325 47.7071
3273.15 101.325 63.4673
He (1) helium 7440-59-7

Ne (2) neon 7440-01-9
x2 p [atm] D · 104 [m2/s]
0.1 1 1.1018
0.1 2 0.5504
0.1 3 0.3672
0.1 4 0.2752
(continued)
0.1 5 0.2204
0.1 7 0.1574
0.1 9 0.123
He (1) helium 7440-59-7

Ne (2) neon 7440-01-9
31.2 11/6
He (1) helium 7440-59-7

Ne (2) neon 7440-01-9
3 –8
Parameter: A · 10 B C · 10 E
25.41 1.509 0.212 1.87
He (1) helium 7440-59-7

Ne (2) neon 7440-01-9
Mutual Diffusion
1.0928 0.0412 0.2995 0.09
Comment: T = 300 K
He (1) helium 7440-59-7

Ne (2) neon 7440-01-9
–1.5186 1.30600 8.0695 0.06%
Comment: x2 = 0.15; D12 [m2/s] = D · 10–4
He (1) helium 7440-59-7

Ne (2) neon 7440-01-9
Mutual Diffusion
1.0936 0.06100 1.0017 0.04%
Comment: T = 300 K; D12 [m2/s] = D · 10–4

He (1) helium 7440-59-7

Ne (2) neon 7440-01-9
Mutual Diffusion Coefficient: D12(x2); Method: CT Ref.: 1972Y1
1.0944 0.0260 0.14%
Comment: T = 300 K; D12 [m2/s] = D · 10–4
He (1) helium 7440-59-7

Ne (2) neon 7440-01-9
Parameter: A · 103 B C · 10–8 E Std-Dev
26.81 1.500 0.212 –0.7510 2.1%
He (1) helium 7440-59-7

Ne (2) neon 7440-01-9
Mutual Diffusion
1.093 0.06100 1.0017 0.04%
Comment: T = 300 K; accuracy of data: ±0.3%
He (1) helium 7440-59-7

Ne (2) neon 7440-01-9
Mutual Diffusion
1.1765 0.0773 1.0695 0.05%
References
1983T7 Taylor, W.L., Cain, D.: High Temperatures-High Pressures 15 (1983) 433–439.
1972Y1 Yabsley, M.A., Dunlop, P.J.: Phys. Lett. A 38 (1972) 247–248.
Data 13 (1984) 229–303.
(1974) 825–831.
(ed), New York: ASME, 1981, p. 289–296.

Diffusion of helium (1); oxygen (2) 1
Diffusion of helium (1); oxygen (2)

Gaseous Mixtures
He (1) helium 7440-59-7

O2 (2) oxygen 7782-44-7
Mutual Diffusion Coefficient: D12(xi); T = 300 K; Method: TB Ref.: 1976Y2
x2 p [kPa] D · 104 [m2/s]
0.030 101.325 0.7478 ± 0.2%
0.063 101.325 0.7490 ± 0.2%
0.063 101.325 0.7498 ± 0.2%
0.125 101.325 0.7517 ± 0.2%
0.125 101.325 0.7519 ± 0.2%
0.250 101.325 0.7551 ± 0.2%
0.250 101.325 0.7553 ± 0.2%
0.500 101.325 0.7597 ± 0.2%
0.500 101.325 0.7604 ± 0.2%
0.500 101.325 0.7604 ± 0.2%
0.500 101.325 0.7608 ± 0.2%
0.750 101.325 0.7637 ± 0.2%
0.750 101.325 0.7639 ± 0.2%
0.875 101.325 0.7656 ± 0.2%
0.938 101.325 0.7665 ± 0.2%
He (1) helium 7440-59-7

O2 (2) oxygen 7782-44-7
Mutual Diffusion Coefficient: D12(xi); T = 300 K; Method: TB Ref.: 1976Y2
x2 p [kPa] D · 104 [m2/s]
0.064 101.325 0.7529 ± 0.2%
0.171 101.325 0.7572 ± 0.2%
0.183 101.325 0.7553 ± 0.2%
0.222 101.325 0.7571 ± 0.2%
0.240 101.325 0.7572 ± 0.2%
0.281 101.325 0.7598 ± 0.2%
0.346 101.325 0.7604 ± 0.2%
0.373 101.325 0.7614 ± 0.2%
0.124 101.325 0.7556 ± 0.2%
0.466 101.325 0.7618 ± 0.2%
0.543 101.325 0.7647 ± 0.2%
0.570 101.325 0.7645 ± 0.2%
0.632 101.325 0.7658 ± 0.2%
0.649 101.325 0.7662 ± 0.2%
0.709 101.325 0.7664 ± 0.2%
0.784 101.325 0.7684 ± 0.2%
0.788 101.325 0.7669 ± 0.2%
0.915 101.325 0.7688 ± 0.2%

2 Diffusion of helium (1); oxygen (2)
He (1) helium 7440-59-7

O2 (2) oxygen 7782-44-7
x2 p [atm] D · 104 [m2/s]
0.1 1 0.7496
0.1 2 0.3745
0.1 3 0.2496
0.1 4 0.1873
0.1 5 0.150
0.1 7 0.1070
0.1 9 0.0833
He (1) helium 7440-59-7

O2 (2) oxygen 7782-44-7
Mutual Diffusion
0.7513 0.0583 1.0929 0.04%
He (1) helium 7440-59-7

O2 (2) oxygen 7782-44-7
4.37 1.710
2
He (1) helium 7440-59-7

O2 (2) oxygen 7782-44-7
Mutual Diffusion
0.7441 0.0662 1.3716 0.05%
Comment: T = 300.00 K
He (1) helium 7440-59-7

O2 (2) oxygen 7782-44-7
–3.5920 3.1673 1.7869 0.09%

He (1) helium 7440-59-7

O2 (2) oxygen 7782-44-7
0.7469 0.0564 1.1270 0.03%
(higher accuracy)
He (1) helium 7440-59-7

O2 (2) oxygen 7782-44-7
Mutual Diffusion Coefficient: D12(x2); Method: TB Ref.: 1976Y2
Parameter: A B C
0.7506 0.0506 0.947
0.7469 0.0564 1.127*
Comment: T = 300.00 K; D12 [m2/s] = D · 10–4;
*: shearing cell measurements
He (1) helium 7440-59-7

O2 (2) oxygen 7782-44-7
Mutual Diffusion
0.7441 0.0662 1.3716 0.05%
Comment: T = 300.0 K; D12 [m2/s] = D · 10–4;
A = –0.15263 + 1.7813 · 10–3 · T + 4.0344 · 10–6 · T 2 [277 - 323 K]
He (1) helium 7440-59-7

O2 (2) oxygen 7782-44-7
0.7441 0.0662 1.372 0.05%
Comment: T = 300 K; D12 [m2/s] = D · 10–4;
A = –1.5263 · 10–1 + 1.7810 · 10–3 · T + 0.4034 · 10–5 · T 2 [280 - 320 K]; ΔA = ±0.07%
References
1976Y2 Yabsley, M.A., Dunlop, P.J.: Physica A 85 (1976) 160–174.
(1977) 673–674.
450–453.


Diffusion of helium (1); tritium (2) 1
Diffusion of helium (1); tritium (2)

Gaseous Mixtures
He (1) helium 7440-59-7

T2 (2) tritium 10028-17-8
T [K] p [kPa] D · 104 [m2/s]
297 ± 0.05 101.325 1.184
298 ± 0.05 101.325 1.177
Reference

Diffusion of helium (1); xenon (2) 1
Diffusion of helium (1); xenon (2)

Gaseous Mixtures
He (1) helium 7440-59-7

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0234
100.0 101.325 0.0838
150.0 101.325 0.1707
200.0 101.325 0.2791
250.0 101.325 0.4068
300.0 101.325 0.5522
273.15 101.325 0.4719
293.15 101.325 0.5313
313.15 101.325 0.5933
333.15 101.325 0.6582
353.15 101.325 0.7257
373.15 101.325 0.7959
423.15 101.325 0.9825
473.15 101.325 1.1846
523.15 101.325 1.4018
573.15 101.325 1.6336
623.15 101.325 1.8797
673.15 101.325 2.1398
723.15 101.325 2.4135
773.15 101.325 2.7006
873.15 101.325 3.3139
973.15 101.325 3.9781
1073.15 101.325 4.6917
1173.15 101.325 5.4532
1273.15 101.325 6.2617
1773.15 101.325 10.9751
2273.15 101.325 16.7417
2773.15 101.325 23.4955
3273.15 101.325 31.1880
He (1) helium 7440-59-7

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0235
100.0 101.325 0.0844
150.0 101.325 0.1724
200.0 101.325 0.2826
(continued)
2 Diffusion of helium (1); xenon (2)
250.0 101.325 0.4122

300.0 101.325 0.5597
273.15 101.325 0.4783
293.15 101.325 0.5385
313.15 101.325 0.6014
333.15 101.325 0.6671
353.15 101.325 0.7356
373.15 101.325 0.8067
423.15 101.325 0.9958
473.15 101.325 1.2006
523.15 101.325 1.4206
573.15 101.325 1.6553
623.15 101.325 1.9045
673.15 101.325 2.1678
723.15 101.325 2.4448
773.15 101.325 2.7354
873.15 101.325 3.3561
973.15 101.325 4.0282
1073.15 101.325 4.7500
1173.15 101.325 5.5203
1273.15 101.325 6.3379
1773.15 101.325 11.1031
2273.15 101.325 16.9303
2773.15 101.325 23.7526
3273.15 101.325 31.5207
He (1) helium 7440-59-7

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0235
100.0 101.325 0.0848
150.0 101.325 0.1739
200.0 101.325 0.2855
250.0 101.325 0.4167
300.0 101.325 0.5658
273.15 101.325 0.4836
293.15 101.325 0.5444
313.15 101.325 0.6080
333.15 101.325 0.6744
353.15 101.325 0.7436
373.15 101.325 0.8155
423.15 101.325 1.0067
473.15 101.325 1.2137
523.15 101.325 1.4360
573.15 101.325 1.6732
623.15 101.325 1.9249
(continued)
673.15 101.325 2.1909

723.15 101.325 2.4707
773.15 101.325 2.7642
873.15 101.325 3.3909
973.15 101.325 4.0695
1073.15 101.325 4.7982
1173.15 101.325 5.5757
1273.15 101.325 6.4010
1773.15 101.325 11.2090
2273.15 101.325 17.0866
2773.15 101.325 23.9658
3273.15 101.325 31.7968
He (1) helium 7440-59-7

Xe (2) xenon 7440-63-3
x2 p [atm] D · 104 [m2/s]
0.1 1 0.5477
0.1 2 0.2732
0.1 3 0.1821
0.1 4 0.1364
0.1 5 0.1090
0.1 7 0.0778
0.1 9 0.0604
He (1) helium 7440-59-7

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
300 101.325 0.537
350 101.325 0.696
400 101.325 0.871
450 101.325 1.065
500 101.325 1.27
550 101.325 1.485
600 101.325 1.72
650 101.325 1.96
700 101.325 2.22
750 101.325 2.48
800 101.325 2.77
850 101.325 3.04
900 101.325 3.35
950 101.325 3.67
1000 101.325 4.00

He (1) helium 7440-59-7

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
127.0 ± 0.1 101.325 0.127 ± 0.9%
163.9 ± 0.1 101.325 0.197 ± 0.9%
203.3 ± 0.1 101.325 0.281 ± 0.9%
237.0 ± 0.1 101.325 0.367 ± 0.9%
294.6 ± 0.1 101.325 0.532 ± 0.9%
294.6 ± 0.1 101.325 0.529 ± 0.9%
406.8 ± 0.1 101.325 0.918 ± 0.9%
494.0 ± 0.1 101.325 1.265 ± 0.9%
581.5 ± 0.1 101.325 1.666 ± 0.9%
685.9 ± 0.1 101.325 2.22 ± 0.9%
778.1 ± 0.1 101.325 2.73 ± 0.9%
He (1) helium 7440-59-7

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
163.9 ± 0.1 101.325 0.201 ± 0.9%
294.6 ± 0.1 101.325 0.549 ± 0.9%
294.6 ± 0.1 101.325 0.549 ± 0.9%
778.1 ± 0.1 101.325 2.84 ± 0.9%
He (1) helium 7440-59-7

Xe (2) xenon 7440-63-3
15.6 11/6
He (1) helium 7440-59-7

Xe (2) xenon 7440-63-3
Equation: ln (D · p) = ln A + B· ln T – ln [ ln(C/T ) ]2 – E/T – F/T 2 Range: 169 < T/K < 10000
7.981 1.644 4.02 –68.87 5416.0

He (1) helium 7440-59-7

Xe (2) xenon 7440-63-3
Mutual Diffusion
0.5405 0.0757 1.0421 0.14
Comment: T = 300 K
He (1) helium 7440-59-7

Xe (2) xenon 7440-63-3
–0.6411 0.61811 4.0915 0.05%
Comment: x2 = 0.10; D12 [m2/s] = D · 10–4
He (1) helium 7440-59-7

Xe (2) xenon 7440-63-3
Equation: ln (D · p) = ln A + B · ln T – ln [ ln(C/T) ]2 – E/T – F/T2 Range: 350 < T/K < 1250
Parameter: A · 103 B C · 10–8 E F · 10–4 Std-Dev
3.060 1.760 4.02 –223.4 2.442 1.8%
He (1) helium 7440-59-7

Xe (2) xenon 7440-63-3
Mutual Diffusion
0.54290 0.07936 1.0677 0.07%
Comment: T = 300.0 K; D12 [m2/s] = D · 10–4
He (1) helium 7440-59-7

Xe (2) xenon 7440-63-3
Mutual Diffusion Ref.: 1991K1
0.5429 0.07936 1.0677 0.07%
Comment: T = 300.0 K; accuracy of data: ±0.3%
References
Data 13 (1984) 229–303.

(1974) 825–831.
1983T7 Taylor, W.L., Cain, D.: High Temperatures-High Pressures 15 (1983) 433–439.

Diffusion of helium-3 (1); hydrogen (2) 1
Diffusion of helium-3 (1); hydrogen (2)

Gaseous Mixtures
He-3 (1) helium-3 14762-55-1

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
273.15 ± 0.001 101.325 1.446 ± 0.8%
280.00 ± 0.001 101.325 1.505 ± 0.8%
290.00 ± 0.001 101.325 1.605 ± 0.8%
300.00 ± 0.001 101.325 1.697 ± 0.8%
310.00 ± 0.001 101.325 1.778 ± 0.8%
320.00 ± 0.001 101.325 1.886 ± 0.8%
He-3 (1) helium-3 14762-55-1

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
250 ± 0.05 101.325 1.277
251 ± 0.05 101.325 1.236
296 ± 0.05 101.325 1.652
298 ± 0.05 101.325 1.635
348 ± 0.05 101.325 2.216
349 ± 0.05 101.325 2.244
He-3 (1) helium-3 14762-55-1

H2 (2) hydrogen 1333-74-0
–0.7025 0.6629 0.4523 0.20%
Comment: x1 = 0.50
References

Diffusion of helium-3 (1); deuterium (2) 1
Diffusion of helium-3 (1); deuterium (2)

Gaseous Mixtures
He-3 (1) helium-3 14762-55-1

D2 (2) deuterium 7782-39-0
T [K] p [kPa] D · 104 [m2/s]
238 ± 0.05 101.325 0.952
238 ± 0.05 101.325 0.941
240 ± 0.05 101.325 0.963
297 ± 0.05 101.325 1.411
297 ± 0.05 101.325 1.387
297 ± 0.05 101.325 1.399
351 ± 0.05 101.325 1.838
352 ± 0.05 101.325 1.841
352 ± 0.05 101.325 1.829
He-3 (1) helium-3 14762-55-1

D2 (2) deuterium 7782-39-0
Mutual Diffusion Coefficient: D12(xi); T = 297 ± 0.05 K; Method: TB Ref.: 1995T2
x1 p [atm] D · 104 [m2/s]
0.50 101.325 1.411
0.50 101.325 1.387
0.50 101.325 1.399
0.65 101.325 1.352
0.65 101.325 1.342
0.78 101.325 1.371
0.88 101.325 1.372
0.88 101.325 1.399
0.95 101.325 1.372
He-3 (1) helium-3 14762-55-1

D2 (2) deuterium 7782-39-0
T [K] p [kPa] D · 104 [m2/s]
273.15 ± 0.001 101.325 1.217 ± 0.3%
280.00 ± 0.001 101.325 1.262 ± 0.3%
290.00 ± 0.001 101.325 1.339 ± 0.3%
300.00 ± 0.001 101.325 1.416 ± 0.3%
310.00 ± 0.001 101.325 1.500 ± 0.3%
320.00 ± 0.001 101.325 1.578 ± 0.3%

2 Diffusion of helium-3 (1); deuterium (2)
He-3 (1) helium-3 14762-55-1

D2 (2) deuterium 7782-39-0
0.2707 –0.0239 1.3530 0.11%
Comment: x1 = 0.50
References

Diffusion of helium-3 (1); helium (2) 1
Diffusion of helium-3 (1); helium (2)

Gaseous Mixtures
He-3 (1) helium-3 14762-55-1

He (2) helium 7440-59-7
Equation: ln (D · p) = ln A + B · ln T – ln [ ln(C/T ) ]2 – E/T – F/T 2 Range: 1.74 < T/K < 10000
3 –8
Parameter: A · 10 B C · 10 E F
32.4 1.501 0.0448 –0.9630 1.894
He-3 (1) helium-3 14762-55-1

He (2) helium 7440-59-7
Equation: ln (D · p) = ln A + B · ln T Range: 14.4 < T/K < 90.0
0.156 1.636
Reference

Diffusion of helium-3 (1); tritium (2) 1
Diffusion of helium-3 (1); tritium (2)

Gaseous Mixtures
He-3 (1) helium-3 14762-55-1

T2 (2) tritium 10028-17-8
T [K] p [kPa] D · 104 [m2/s]
294 ± 0.05 101.325 1.291
297 ± 0.05 101.325 1.268
Reference

Diffusion of krypton (1); argon (2) 1
Diffusion of krypton (1); argon (2)

Gaseous Mixtures
Kr (1) krypton 7439-90-9

Ar (2) argon 7440-37-1
Mutual Diffusion Coefficient: D12(T ); Method: TB Ref.: 1968V1
T [K] p [kPa] D · 106 [atm · m2/s]
169.3 101.325 4.72 ± 0.03
231.1 101.325 8.60 ± 0.05
295.0 101.325 13.58 ± 0.07
400.0 101.325 23.66 ± 0.13
Comment: D12 at x2 = 0.50 given as (D12 · p) in [m2 · atm/s]
Kr (1) krypton 7439-90-9

Ar (2) argon 7440-37-1
Intradiffusion Coefficient: D1T(x1); T = 302.6 K; Method: TB Ref.: 1964W2
x1 p [kPa] D · 104 [m2/s]
0.25 101.325 0.1149 ± 0.0072
0.50 101.325 0.1089 ± 0.0033
0.75 101.325 0.1055 ± 0.0042
Comment: 85Kr as trace in binary mixture
References

Diffusion of krypton (1); methane (2) 1
Diffusion of krypton (1); methane (2)

Gaseous Mixtures
Kr (1) krypton 7439-90-9

CH4 (2) methane 74-82-8
0.1786 0.0008 0.02%
Comment: T = 300 K; D12 [m2/s] = D · 10–4;
A = –4.3961 · 10–2 + 3.6896 · 10–4 · T + 1.2438 · 10–6 · T 2 [277 - 320 K]
Reference
1982T7 Trengove, R.D., Robjohns, H.L., Dunlop, P.J.: Ber. Bunsenges. Phys. Chem. 86 (1982) 951–955.

Diffusion of krypton (1); carbon monoxide (2) 1
Diffusion of krypton (1); carbon monoxide (2)

Gaseous Mixtures
Kr (1) krypton 7439-90-9

5
0.653 1.766
Kr (1) krypton 7439-90-9

0.1626 0.0055 0.07%
Comment: T = 300.0 K; D12 [m2/s] = D · 10–4;
A = –0.01486 + 0.1841 · 10–3 · T + 1.3552 · 10–6 · T 2 [277 - 323 K]
References
450–453.

Diffusion of krypton (1); carbon dioxide (2) 1
Diffusion of krypton (1); carbon dioxide (2)

Gaseous Mixtures
Kr (1) krypton 7439-90-9

T [K] p [kPa] D · 104 [m2/s]
173.2 101.325 0.0391 ± 0.9%
203.2 101.325 0.0543 ± 0.9%
233.2 101.325 0.0720 ± 0.9%
263.2 101.325 0.0911 ± 0.9%
293.2 101.325 0.112 ± 0.9%
409.3 101.325 0.214 ± 0.9%
510.9 101.325 0.322 ± 0.9%
595.9 101.325 0.422 ± 0.9%
662.9 101.325 0.504 ± 0.9%
776.1 101.325 0.657 ± 0.9%
Kr (1) krypton 7439-90-9

T [K] p [kPa] D · 104 [m2/s]
173.2 101.325 0.0395 ± 0.9%
293.2 101.325 0.111 ± 0.9%
595.9 101.325 0.417 ± 0.9%
Kr (1) krypton 7439-90-9

Mutual DiffusionCoefficient: D12(T ); Method: TB Ref.: 1981R1
–11.6740 8.1128 0.1029 0.11%
Comment: x1 = 0.25
Kr (1) krypton 7439-90-9

Mutual Diffusion Coefficient: D12(x1); Method: TB Ref.: 1981R1
0.1167 0.0092 0.0 0.03%
Comment: T = 300 K

2 Diffusion of krypton (1); carbon dioxide (2)
References

Diffusion of krypton (1); hydrogen (2) 1
Diffusion of krypton (1); hydrogen (2)

Gaseous Mixtures
Kr (1) krypton 7439-90-9

H2 (2) hydrogen 1333-74-0
17.1 11/6
Kr (1) krypton 7439-90-9

H2 (2) hydrogen 1333-74-0
18.2 1.564 1.69 26.4
Reference

Diffusion of krypton (1); ammonia (2) 1
Diffusion of krypton (1); ammonia (2)

Gaseous Mixtures
Kr (1) krypton 7439-90-9

H 3N (2) ammonia 7664-41-7
0.1837 0.0 0.0 0.1%
Comment: T = 300 K; D12 [m2/s] = D · 10–4;
A = –0.3303 · 10–1 + 0.2985 · 10–3 · T + 1.4214 · 10–6 · T 2 [280 - 400 K]; ΔA = ±0.08%
Reference

Diffusion of krypton (1); helium (2) 1
Diffusion of krypton (1); helium (2)

Gaseous Mixtures
Kr (1) krypton 7439-90-9

He (2) helium 7440-59-7
x1 p [kPa] D · 104 [m2/s]
0.50 101.325 0.1571 ± 0.012
Comment: 85 Kr as trace in binary mixture
Kr (1) krypton 7439-90-9

He (2) helium 7440-59-7
T [K] p [kPa] D · 106 [atm · m2/s]
111.7 101.325 11.97 ± 0.10
169.3 101.325 24.79 ± 0.15
295.0 101.325 64.3 ± 0.4
400.0 101.325 105.9 ± 0.6
References

Diffusion of krypton (1); nitrogen (2) 1
Diffusion of krypton (1); nitrogen (2)

Gaseous Mixtures
Kr (1) krypton 7439-90-9

N2 (2) nitrogen 7727-37-9
3.91 11/6
Kr (1) krypton 7439-90-9

N2 (2) nitrogen 7727-37-9
0.653 1.766
Kr (1) krypton 7439-90-9

N2 (2) nitrogen 7727-37-9
0.1595 0.0058 0.0 0.02%
Comment: T = 300 K; D12 [m2/s] = D · 10–4;
A = –0.042460 + 0.37360 · 10–3 · T + 0.9987 · 10–6 · T 2 [277 - 323 K]; ΔA = ± 0.02%
References

Diffusion of krypton (1); neon (2) 1
Diffusion of krypton (1); neon (2)

Gaseous Mixtures
Kr (1) krypton 7439-90-9

Ne (2) neon 7440-01-9
x1 p [kPa] D · 104 [m2/s]
0.25 101.325 0.170 ± 0.011
0.50 101.325 0.134 ± 0.007
0.75 101.325 0.1131 ± 0.0067
Kr (1) krypton 7439-90-9

Ne (2) neon 7440-01-9
T [K] p [kPa] D · 106 [atm · m2/s]
111.7 101.325 4.43 ± 0.03
169.3 101.325 9.65 ± 0.05
295.0 101.325 25.66 ± 0.14
400.0 101.325 43.8 ± 0.3
Kr (1) krypton 7439-90-9

Ne (2) neon 7440-01-9
Mutual Diffusion Coefficient: D12(T ); x1 = 0.50; Method: TB Ref.: 1968M5
T [K] p [kPa] D · 104 [m2/s]
270.0 ± 0.1 101.325 0.223
290.0 ± 0.1 101.325 0.244
310.0 ± 0.1 101.325 0.265
330.0 ± 0.1 101.325 0.288
350.0 ± 0.1 101.325 0.313
References
1968M5 Mathur, B.P., Saxena, S.C.: Appl. Sci. Res. 18 (1968) 325–335.

Diffusion of krypton (1); oxygen (2) 1
Diffusion of krypton (1); oxygen (2)

Gaseous Mixtures
Kr (1) krypton 7439-90-9

O2 (2) oxygen 7782-44-7
0.1578 0.0063 0.0 0.03%
Comment: T = 300 K; D12 [m2/s] = D · 10–4;
A = –0.2053 · 10–1 + 0.2304 · 10–3 · T + 0.1214 · 10–5 · T 2 [280 - 320 K]; ΔA = ± 0.03%
Reference

Diffusion of krypton (1); xenon (2) 1
Diffusion of krypton (1); xenon (2)

Gaseous Mixtures
Kr (1) krypton 7439-90-9

Xe (2) xenon 7440-63-3
x1 p [kPa] D · 104 [m2/s]
0.25 101.325 0.0773 ± 0.004
0.50 101.325 0.0865 ± 0.010
0.75 101.325 0.091 ± 0.007
Kr (1) krypton 7439-90-9

Xe (2) xenon 7440-63-3
Mutual Diffusion Coefficient:: D12(T ); Method: CORR Ref.: 1984K4
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0025
100.0 101.325 0.0091
150.0 101.325 0.0197
200.0 101.325 0.0346
250.0 101.325 0.0535
300.0 101.325 0.0763
273.15 101.325 0.0636
293.15 101.325 0.0730
313.15 101.325 0.0829
333.15 101.325 0.0933
353.15 101.325 0.1043
373.15 101.325 0.1158
423.15 101.325 0.1467
473.15 101.325 0.1806
523.15 101.325 0.2174
573.15 101.325 0.2569
623.15 101.325 0.2990
673.15 101.325 0.3435
723.15 101.325 0.3905
773.15 101.325 0.4397
873.15 101.325 0.5448
973.15 101.325 0.6584
1073.15 101.325 0.7799
1173.15 101.325 0.9091
1273.15 101.325 1.0456
1773.15 101.325 1.8314
2273.15 101.325 2.7777
2773.15 101.325 3.8793
3273.15 101.325 5.1401

2 Diffusion of krypton (1); xenon (2)
Kr (1) krypton 7439-90-9

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0025
100.0 101.325 0.0091
150.0 101.325 0.0197
200.0 101.325 0.0346
250.0 101.325 0.0535
300.0 101.325 0.0763
273.15 101.325 0.0636
293.15 101.325 0.0730
313.15 101.325 0.0829
333.15 101.325 0.0933
353.15 101.325 0.1043
373.15 101.325 0.1158
423.15 101.325 0.1468
473.15 101.325 0.1808
523.15 101.325 0.2177
573.15 101.325 0.2572
623.15 101.325 0.2994
673.15 101.325 0.3441
723.15 101.325 0.3912
773.15 101.325 0.4407
873.15 101.325 0.5462
973.15 101.325 0.6602
1073.15 101.325 0.7823
1173.15 101.325 0.9121
1273.15 101.325 1.0492
1773.15 101.325 1.8388
2273.15 101.325 2.7892
2773.15 101.325 3.8939
3273.15 101.325 5.1576
Kr (1) krypton 7439-90-9

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0025
100.0 101.325 0.0091
150.0 101.325 0.0197
200.0 101.325 0.0346
250.0 101.325 0.0535
300.0 101.325 0.0763
273.15 101.325 0.0636
293.15 101.325 0.0730
313.15 101.325 0.0829
(continued)
333.15 101.325 0.0934

353.15 101.325 0.1044
373.15 101.325 0.1159
423.15 101.325 0.1469
473.15 101.325 0.1809
523.15 101.325 0.2179
573.15 101.325 0.2575
623.15 101.325 0.2998
673.15 101.325 0.3447
723.15 101.325 0.3919
773.15 101.325 0.4415
873.15 101.325 0.5474
973.15 101.325 0.6619
1073.15 101.325 0.7845
1173.15 101.325 0.9148
1273.15 101.325 1.0526
1773.15 101.325 1.8458
2273.15 101.325 2.8000
2773.15 101.325 3.9075
3273.15 101.325 5.1740
Kr (1) krypton 7439-90-9

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
163.2 101.325 0.0238 ± 0.9%
203.6 101.325 0.0366 ± 0.9%
243.4 101.325 0.0522 ± 0.9%
297.4 101.325 0.0758 ± 0.9%
402.1 101.325 0.137 ± 0.9%
484.4 101.325 0.192 ± 0.9%
589.5 101.325 0.278 ± 0.9%
682.2 101.325 0.359 ± 0.9%
767.6 101.325 0.435 ± 0.9%
Kr (1) krypton 7439-90-9

Xe (2) xenon 7440-63-3
2.00 11/6

Kr (1) krypton 7439-90-9

Xe (2) xenon 7440-63-3
2.933 1.608 128.0 52.7
2
References
Data 13 (1984) 229–303.

Diffusion of nitrogen atom (1); nitrogen (2) 1
Diffusion of nitrogen atom (1); nitrogen (2)

Gaseous Mixtures
N (1) nitrogen atom 17778-88-0

N2 (2) nitrogen 7727-37-9
1.32 1.774
Reference

Diffusion of nitrogen (1); argon (2) 1
Diffusion of nitrogen (1); argon (2)

Gaseous Mixtures
N2 (1) nitrogen 7727-37-9

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
296.2 101.325 0.195*
296.2 101.325 0.194
297.6 101.325 0.190*
297.6 101.325 0.191
483.2 101.325 0.446*
483.2 101.325 0.444
N2 (1) nitrogen 7727-37-9

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
300.4 101.325 0.21
350.2 101.325 0.27
400.7 101.325 0.34
450.2 101.325 0.41
552.0 101.325 0.58
600.2 101.325 0.68
660.1 101.325 0.79
700.1 101.325 0.88
759.0 101.325 1.01
800.3 101.325 1.11
860.1 101.325 1.22
900.2 101.325 1.31
960.4 101.325 1.53
1000.4 101.325 1.88
N2 (1) nitrogen 7727-37-9

Ar (2) argon 7440-37-1
Intradiffusion Coefficient: D12· p (n); T = (232.16 ± 0.005) K; Method: CT Ref.: 1980S6
n [1/10–25 m3] p [atm] D · 104 [atm · m2/s]
4.547 2.001 0.2326 ± 0.2%
6.821 3.001 0.2318 ± 0.2%
11.372 5.001 0.2316 ± 0.2%
13.654 6.004 0.2316 ± 0.2%
15.935 7.005 0.2314 ± 0.2%
18.211 8.004 0.2313 ± 0.2%
(continued)

2 Diffusion of nitrogen (1); argon (2)
20.497 9.007 0.2307 ± 0.2%

22.769 10.003 0.2312 ± 0.2%
25.067 11.010 0.2304 ± 0.2%
27.340 12.006 0.2308 ± 0.2%
29.618 13.004 0.2300 ± 0.2%
31.920 14.011 0.2300 ± 0.2%
34.206 15.011 0.2298 ± 0.2%
36.483 16.007 0.2301 ± 0.2%
38.768 17.006 0.2299 ± 0.2%
41.058 18.006 0.2301 ± 0.2%
43.348 19.007 0.2292 ± 0.2%
45.661 20.016 0.2295 ± 0.2%
N2 (1) nitrogen 7727-37-9

Ar (2) argon 7440-37-1
n [1/10–25 m3] p [atm] D · 104 [atm · m2/s]
2.448 1.000 0.2034 ± 0.2%
2.448 1.000 0.2038 ± 0.2%
2.448 1.000 0.2038 ± 0.2%
2.448 1.000 0.2039 ± 0.2%
2.448 1.000 0.2035 ± 0.2%
2.448 1.000 0.2034 ± 0.2%
2.448 1.000 0.2037 ± 0.2%
2.448 1.000 0.2036 ± 0.2%
4.894 1.999 0.2035 ± 0.2%
4.893 1.998 0.2034 ± 0.2%
7.347 2.999 0.2033 ± 0.2%
7.345 2.999 0.2036 ± 0.2%
9.805 4.001 0.2032 ± 0.2%
9.805 4.001 0.2031 ± 0.2%
12.266 5.003 0.2029 ± 0.2%
14.718 6.001 0.2030 ± 0.2%
14.718 6.001 0.2031 ± 0.2%
14.724 6.004 0.2029 ± 0.2%
17.179 7.002 0.2027 ± 0.2%
17.179 7.002 0.2028 ± 0.2%
19.652 8.006 0.2024 ± 0.2%
20.875 8.503 0.2020 ± 0.2%
20.875 8.503 0.2019 ± 0.2%
22.110 9.004 0.2019 ± 0.2%
24.577 10.005 0.2017 ± 0.2%
27.052 11.008 0.2016 ± 0.2%
29.516 12.006 0.2014 ± 0.2%
31.993 13.008 0.2015 ± 0.2%
34.474 14.011 0.2011 ± 0.2%
36.939 15.007 0.2010 ± 0.2%
(continued)
39.427 16.011 0.2008 ± 0.2%

41.906 17.011 0.2006 ± 0.2%
44.388 18.011 0.2004 ± 0.2%
46.884 19.016 0.2004 ± 0.2%
49.347 20.007 0.2003 ± 0.2%
51.839 21.009 0.1998 ± 0.2%
54.334 22.011 0.2000 ± 0.2%
54.220 21.965 0.1995 ± 0.2%
56.706 22.963 0.1995 ± 0.2%
56.826 23.013 0.1995 ± 0.2%
59.192 23.960 0.1994 ± 0.2%
61.663 24.950 0.1995 ± 0.2%
61.658 24.948 0.1993 ± 0.2%
N2 (1) nitrogen 7727-37-9

Ar (2) argon 7440-37-1
0.2034 0.0041 0.0 0.04%
(higher accuracy)
N2 (1) nitrogen 7727-37-9

Ar (2) argon 7440-37-1
0.2046 0.0069 0.0 0.02%
References
83–88.
1977A5 Arora, P.S., Shankland, I.R., Bell, T.N., Yabsley, M.A., Dunlop, P.J.: Rev. Sci. Instrum. 48 (1977)
673–674.

Diffusion of nitrogen (1); tetrafluoro-methane (2) 1
Diffusion of nitrogen (1); tetrafluoro-methane (2)

Gaseous Mixtures
N2 (1) nitrogen 7727-37-9

Mutual Diffusion Coefficient: D12(T ); x1 = 0.50; Method: CORR Ref.: 1990B5
T [K] p [kPa] D · 104 [m2/s]
200.0 101.325 0.0623
250.0 101.325 0.0938
300.0 101.325 0.1300
273.15 101.325 0.1100
293.15 101.325 0.1248
313.15 101.325 0.1403
333.15 101.325 0.1565
353.15 101.325 0.1733
373.15 101.325 0.1908
423.15 101.325 0.2373
473.15 101.325 0.2875
523.15 101.325 0.3414
573.15 101.325 0.3988
623.15 101.325 0.4595
673.15 101.325 0.5235
723.15 101.325 0.5907
773.15 101.325 0.6610
873.15 101.325 0.8108
973.15 101.325 0.9725
1073.15 101.325 1.1456
1173.15 101.325 1.3299
1273.15 101.325 1.5244
1773.15 101.325 2.6749
2273.15 101.325 4.1132
2773.15 101.325 5.7999
3273.15 101.325 7.7096
Reference
1990B5 Bzowski, J., Kestin, J., Mason, E.A., Uribe, F. J.: J. Phys. Chem. Ref. Data 19 (1990)
1179–1232.

Diffusion of nitrogen (1); methane (2) 1
Diffusion of nitrogen (1); methane (2)

Gaseous Mixtures
N2 (1) nitrogen 7727-37-9

CH4 (2) methane 74-82-8
T [K] p [kPa] D · 104 [m2/s]
200.0 101.325 0.1105
250.0 101.325 0.1666
300.0 101.325 0.2312
273.15 101.325 0.1955
293.15 101.325 0.2219
313.15 101.325 0.2495
333.15 101.325 0.2784
353.15 101.325 0.3084
373.15 101.325 0.3396
423.15 101.325 0.4225
473.15 101.325 0.5122
523.15 101.325 0.6083
573.15 101.325 0.7106
623.15 101.325 0.8189
673.15 101.325 0.9331
723.15 101.325 1.0530
773.15 101.325 1.1785
873.15 101.325 1.4458
973.15 101.325 1.7341
1073.15 101.325 2.0430
1173.15 101.325 2.3717
1273.15 101.325 2.7199
1773.15 101.325 4.7533
2273.15 101.325 7.2727
2773.15 101.325 10.2435
3273.15 101.325 13.6386
Reference
1179–1232.

Diffusion of nitrogen (1); carbon monoxide (2) 1
Diffusion of nitrogen (1); carbon monoxide (2)

Gaseous Mixtures
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
100.0 101.325 0.0279
150.0 101.325 0.0613
200.0 101.325 0.1041
250.0 101.325 0.1551
300.0 101.325 0.2135
273.15 101.325 0.1812
293.15 101.325 0.2051
313.15 101.325 0.2300
333.15 101.325 0.2560
353.15 101.325 0.2831
373.15 101.325 0.3111
423.15 101.325 0.3857
473.15 101.325 0.4662
523.15 101.325 0.5526
573.15 101.325 0.6445
623.15 101.325 0.7419
673.15 101.325 0.8446
723.15 101.325 0.9524
773.15 101.325 1.0654
873.15 101.325 1.3062
973.15 101.325 1.5663
1073.15 101.325 1.8451
1173.15 101.325 2.1425
1273.15 101.325 2.4583
1773.15 101.325 4.3105
2273.15 101.325 6.6074
2773.15 101.325 9.3333
3273.15 101.325 12.4747
N2 (1) nitrogen 7727-37-9

4.40 1.576 1.57 –36.2 3825.0
2

2 Diffusion of nitrogen (1); carbon monoxide (2)
References
1179–1232.

Diffusion of nitrogen (1); carbon dioxide (2) 1
Diffusion of nitrogen (1); carbon dioxide (2)

Gaseous Mixtures
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
250.0 101.325 0.1180
300.0 101.325 0.1652
273.15 101.325 0.1391
293.15 101.325 0.1583
313.15 101.325 0.1785
333.15 101.325 0.1997
353.15 101.325 0.2217
373.15 101.325 0.2446
423.15 101.325 0.3055
473.15 101.325 0.3714
523.15 101.325 0.4422
573.15 101.325 0.5175
623.15 101.325 0.5973
673.15 101.325 0.6814
723.15 101.325 0.7697
773.15 101.325 0.8621
873.15 101.325 1.0588
973.15 101.325 1.2709
1073.15 101.325 1.4979
1173.15 101.325 1.7394
1273.15 101.325 1.9950
1773.15 101.325 3.4746
2273.15 101.325 5.2816
2773.15 101.325 7.4049
3273.15 101.325 9.8285
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
300.4 101.325 0.17
350.6 101.325 0.22
400.7 101.325 0.28
451.2 101.325 0.34
500.8 101.325 0.40
559.0 101.325 0.50
600.4 101.325 0.56
652.0 101.325 0.64
700.6 101.325 0.73
(continued)
2 Diffusion of nitrogen (1); carbon dioxide (2)
800.9 101.325 0.92

854.0 101.325 1.02
900.2 101.325 1.12
970.2 101.325 1.26
1000.8 101.325 1.35
N2 (1) nitrogen 7727-37-9

3.15 1.570 113.6
N2 (1) nitrogen 7727-37-9

0.1683 0.0 0.0 0.03%
2 –4
Comment: T = 300.0 K; D12 [m /s] = D · 10 ;
A = –0.6386 · 10–1 + 0.5011 · 10–3 · T + 0.9094 · 10–6 · T 2 [277 - 323 K]; ΔA = ±0.04%
References
1179–1232.
83–88.

Diffusion of nitrogen (1); ethene (2) 1
Diffusion of nitrogen (1); ethene (2)

Gaseous Mixtures
N2 (1) nitrogen 7727-37-9

C2H4 (2) ethene 74-85-1
T [K] p [kPa] D · 104 [m2/s]
250.0 101.325 0.1212
300.0 101.325 0.1692
273.15 101.325 0.1426
293.15 101.325 0.1622
313.15 101.325 0.1828
333.15 101.325 0.2043
353.15 101.325 0.2267
373.15 101.325 0.2499
423.15 101.325 0.3118
473.15 101.325 0.3787
523.15 101.325 0.4505
573.15 101.325 0.5269
623.15 101.325 0.6079
673.15 101.325 0.6932
723.15 101.325 0.7828
773.15 101.325 0.8765
873.15 101.325 1.0761
973.15 101.325 1.2913
1073.15 101.325 1.5217
1173.15 101.325 1.7668
1273.15 101.325 2.0263
Reference
1179–1232.

Diffusion of nitrogen (1); ethane (2) 1
Diffusion of nitrogen (1); ethane (2)

Gaseous Mixtures
N2 (1) nitrogen 7727-37-9

C2H6 (2) ethane 74-84-0
T [K] p [kPa] D · 104 [m2/s]
250.0 101.325 0.1107
300.0 101.325 0.1544
273.15 101.325 0.1302
293.15 101.325 0.1481
313.15 101.325 0.1669
333.15 101.325 0.1865
353.15 101.325 0.2069
373.15 101.325 0.2281
423.15 101.325 0.2845
473.15 101.325 0.3455
523.15 101.325 0.4109
573.15 101.325 0.4806
623.15 101.325 0.5544
673.15 101.325 0.6322
723.15 101.325 0.7139
773.15 101.325 0.7993
873.15 101.325 0.9812
973.15 101.325 1.1774
1073.15 101.325 1.3875
1173.15 101.325 1.6110
1273.15 101.325 1.8476
Reference
1179–1232.

Diffusion of nitrogen (1); butane (2) 1
Diffusion of nitrogen (1); butane (2)

Gaseous Mixtures
N2 (1) nitrogen 7727-37-9

C4H10 (2) butane 106-97-8
T [K] p [Torr] D · 104 [m2/s]
298.1 740.7 0.1012
298.2 734.3 0.1021
378.2 737.6 0.1596
438.3 730.9 0.2106
Reference

Diffusion of nitrogen (1); sulfur hexafluoride (2) 1
Diffusion of nitrogen (1); sulfur hexafluoride (2)

Gaseous Mixtures
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
250.0 101.325 0.0741
300.0 101.325 0.1028
273.15 101.325 0.0869
293.15 101.325 0.0987
313.15 101.325 0.1110
333.15 101.325 0.1239
353.15 101.325 0.1373
373.15 101.325 0.1512
423.15 101.325 0.1881
473.15 101.325 0.2281
523.15 101.325 0.2710
573.15 101.325 0.3166
623.15 101.325 0.3650
673.15 101.325 0.4159
723.15 101.325 0.4694
773.15 101.325 0.5254
873.15 101.325 0.6446
973.15 101.325 0.7731
1073.15 101.325 0.9108
1173.15 101.325 1.0573
1273.15 101.325 1.2124
1773.15 101.325 2.1147
2273.15 101.325 3.2216
2773.15 101.325 4.5146
3273.15 101.325 5.9806
N2 (1) nitrogen 7727-37-9

5
1.66 1.590 119.4
References
1179–1232.

Diffusion of nitrogen (1); hydrogen (2) 1
Diffusion of nitrogen (1); hydrogen (2)

Gaseous Mixtures
N2 (1) nitrogen 7727-37-9

H2 (2) hydrogen 1333-74-0
Mutual Diffusion Coefficient: D12· p (T ); Method: TB Ref.: 1966V1
T [K] p [kPa] D · 106 [atm · m2/s]
5.25 ± 0.01 101.325 4.70 ± 0.04
77.35 ± 0.01 101.325 6.71 ± 0.02
90.2 ± 0.01 101.325 9.00 ± 0.05
169.3 ± 0.01 101.325 28.94 ± 0.15
294.8 ± 0.01 101.325 76.64 ± 0.20
Comment: D at x2 = 0.50 given as (D12· p) in [m2 · atm/s]
N2 (1) nitrogen 7727-37-9

H2 (2) hydrogen 1333-74-0
T [K] p [Torr] D · 104 [m2/s]
288.20 ± 0.01 805.6 0.659 ± 0.17%
298.18 ± 0.01 808.1 0.707 ± 0.13%
308.20 ± 0.01 806.3 0.774 ± 0.25%
318.24 ± 0.01 804.1 0.814 ± 0.37%
318.26 ± 0.01 806.3 0.803 ± 0.52%
N2 (1) nitrogen 7727-37-9

H2 (2) hydrogen 1333-74-0
x1 p [Torr] D · 104 [m2/s]
0.8129 29.2 14.2 ± 0.73%
0.9031 58.4 7.78 ± 1.15%
0.8098 99.0 4.85 ± 0.65%
0.8052 112.3 4.53 ± 0.82%
0.7806 207.8 2.64 ± 0.57%
0.8031 409.4 1.35 ± 0.40%
0.8398 759.9 0.729 ± 0.27%
0.8398 808.1 0.707 ± 0.13%
0.8810 1204.4 0.468 ± 0.16%
N2 (1) nitrogen 7727-37-9

H2 (2) hydrogen 1333-74-0
x1 p [Torr] D · 104 [m2/s]
0.9331 758.6 0.736 ± 0.268%
(continued)

2 Diffusion of nitrogen (1); hydrogen (2)
0.8707 757.9 0.737 ± 0.145%

0.8358 756.8 0.729 ± 0.174%
0.1734 759.9 0.731 ± 0.380%
0.0792 757.8 0.742 ± 0.386%
0.8988 758.0 0.767 ± 0.180%
0.3374 758.6 0.772 ± 0.507%
0.8398 808.1 0.707 ± 0.128%
0.5194 804.1 0.725 ± 0.231%
0.3109 805.0 0.726 ± 0.217%
0.2085 805.4 0.707 ± 0.498%
0.2095 804.3 0.695 ± 0.568%
References
1966V1 van Heijningen, R.J.J., Feberwee, A., van Oosten, A., Beenakker, J.J.M.: Physica 32 (1966)
1649–1662.

Diffusion of nitrogen (1); water (2) 1
Diffusion of nitrogen (1); water (2)

Gaseous Mixtures
N2 (1) nitrogen 7727-37-9

H 2O (2) water 7732-18-5
0.187 2.072
Reference

Diffusion of nitrogen (1); helium (2) 1
Diffusion of nitrogen (1); helium (2)

Gaseous Mixtures
N2 (1) nitrogen 7727-37-9

He (2) helium 7440-59-7
T [K] p [Torr] D · 104 [m2/s]
277.75 ± 0.01 804.0 0.584 ± 0.24%
287.91 ± 0.01 803.3 0.620 ± 0.16%
298.20 ± 0.01 803.2 0.651 ± 0.15%
308.21 ± 0.01 808.5 0.696 ± 0.17%
318.28 ± 0.01 803.8 0.743 ± 0.31%
328.55 ± 0.01 806.3 0.749 ± 0.19%
N2 (1) nitrogen 7727-37-9

He (2) helium 7440-59-7
x1 p [Torr] D · 104 [m2/s]
0.8104 803.2 0.647 ± 0.169%
0.3026 806.3 0.622 ± 0.234%
0.2059 806.5 0.607 ± 0.276%
0.1030 806.0 0.589 ± 0.293%
N2 (1) nitrogen 7727-37-9

He (2) helium 7440-59-7
x1 p [Torr] D · 104 [m2/s]
0.8071 28.7 11.1 ± 1.25%
0.8046 108.4 3.96 ± 0.55%
0.8227 209.1 2.33 ± 0.21%
0.7897 211.5 2.40 ± 0.26%
0.7868 406.1 1.27 ± 0.23%
0.8499 803.2 0.651 ± 0.15%
0.8791 1205.3 0.440 ± 0.09%
Reference

Diffusion of nitrogen (1); nitrogen oxide (2) 1
Diffusion of nitrogen (1); nitrogen oxide (2)

Gaseous Mixtures
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
150.0 101.325 0.0605
200.0 101.325 0.1036
250.0 101.325 0.1551
300.0 101.325 0.2143
273.15 101.325 0.1816
293.15 101.325 0.2058
313.15 101.325 0.2310
333.15 101.325 0.2574
353.15 101.325 0.2849
373.15 101.325 0.3134
423.15 101.325 0.3890
473.15 101.325 0.4708
523.15 101.325 0.5585
573.15 101.325 0.6518
623.15 101.325 0.7506
673.15 101.325 0.8548
723.15 101.325 0.9642
773.15 101.325 1.0787
873.15 101.325 1.3228
973.15 101.325 1.5862
1073.15 101.325 1.8686
1173.15 101.325 2.1692
1273.15 101.325 2.4886
1773.15 101.325 4.3820
2273.15 101.325 6.7474
2773.15 101.325 9.5519
3273.15 101.325 12.7738
Reference
1179–1232.

Diffusion of nitrogen (1); nitrous oxide (2) 1
Diffusion of nitrogen (1); nitrous oxide (2)

Gaseous Mixtures
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
300.0 101.325 0.1662
273.15 101.325 0.1398
293.15 101.325 0.1593
313.15 101.325 0.1797
333.15 101.325 0.2011
353.15 101.325 0.2233
373.15 101.325 0.2465
423.15 101.325 0.3082
473.15 101.325 0.3749
523.15 101.325 0.4466
573.15 101.325 0.5229
623.15 101.325 0.6037
673.15 101.325 0.6889
723.15 101.325 0.7784
773.15 101.325 0.8720
873.15 101.325 1.0712
973.15 101.325 1.2861
1073.15 101.325 1.5160
1173.15 101.325 1.7605
1273.15 101.325 2.0193
1773.15 101.325 3.5170
2273.15 101.325 5.3396
2773.15 101.325 7.4753
3273.15 101.325 9.9101
Reference
1179–1232.

Diffusion of nitrogen (1); oxygen (2) 1
Diffusion of nitrogen (1); oxygen (2)

Gaseous Mixtures
N2 (1) nitrogen 7727-37-9

O2 (2) oxygen 7782-44-7
Mutual Diffusion Coefficient: D12 · p (n); T = (323.16 ± 0.005) K; Method: CT Ref.: 1980S6
n [1/10–25 m3] p [atm] D · 104 [atm · m2/s]
4.546 2.001 0.2497 ± 0.2%
6.822 3.002 0.2497 ± 0.2%
11.377 5.003 0.2495 ± 0.2%
13.651 6.002 0.2491 ± 0.2%
15.930 7.003 0.2489 ± 0.2%
22.772 10.004 0.2484 ± 0.2%
25.057 11.005 0.2480 ± 0.2%
27.340 12.005 0.2486 ± 0.2%
29.619 13.003 0.2476 ± 0.2%
31.908 14.004 0.2482 ± 0.2%
34.199 15.007 0.2476 ± 0.2%
36.483 16.006 0.2479 ± 0.2%
38.768 17.004 0.2471 ± 0.2%
41.055 18.003 0.2472 ± 0.2%
43.343 19.003 0.2474 ± 0.2%
45.647 20.008 0.2465 ± 0.2%
N2 (1) nitrogen 7727-37-9

O2 (2) oxygen 7782-44-7
n [1/10–25 m3] p [atm] D · 104 [atm · m2/s]
2.448 1.000 0.2189 ± 0.2%
2.447 1.000 0.2194 ± 0.2%
2.449 1.001 0.2194 ± 0.2%
2.448 1.000 0.2192 ± 0.2%
4.895 1.999 0.2190 ± 0.2%
4.898 2.000 0.2189 ± 0.2%
7.348 3.000 0.2189 ± 0.2%
9.806 4.002 0.2188 ± 0.2%
9.805 4.001 0.2189 ± 0.2%
12.262 5.002 0.2183 ± 0.2%
12.261 5.001 0.2189 ± 0.2%
14.718 6.001 0.2183 ± 0.2%
14.721 6.003 0.2181 ± 0.2%
17.182 7.003 0.2178 ± 0.2%
17.181 7.003 0.2180 ± 0.2%
19.646 8.004 0.2174 ± 0.2%
19.646 8.004 0.2175 ± 0.2%
(continued)
2 Diffusion of nitrogen (1); oxygen (2)
22.108 9.004 0.2174 ± 0.2%

22.107 9.003 0.2173 ± 0.2%
24.574 10.004 0.2174 ± 0.2%
24.576 10.005 0.2173 ± 0.2%
27.040 11.004 0.2172 ± 0.2%
29.515 12.006 0.2172 ± 0.2%
31.940 12.987 0.2167 ± 0.2%
31.943 12.988 0.2164 ± 0.2%
34.428 13.993 0.2167 ± 0.2%
34.394 13.979 0.2164 ± 0.2%
36.869 14.979 0.2163 ± 0.2%
39.336 15.975 0.2160 ± 0.2%
39.336 15.975 0.2160 ± 0.2%
39.341 15.977 0.2162 ± 0.2%
41.808 16.972 0.2160 ± 0.2%
41.808 16.972 0.2159 ± 0.2%
44.289 17.972 0.2155 ± 0.2%
44.289 17.972 0.2157 ± 0.2%
46.763 18.968 0.2154 ± 0.2%
46.763 18.968 0.2156 ± 0.2%
46.760 18.967 0.2154 ± 0.2%
46.760 18.967 0.2153 ± 0.2%
51.728 20.965 0.2151 ± 0.2%
54.215 21.964 0.2150 ± 0.2%
54.215 21.964 0.2148 ± 0.2%
57.930 23.455 0.2147 ± 0.2%
61.660 24.950 0.2145 ± 0.2%
61.660 24.950 0.2144 ± 0.2%
N2 (1) nitrogen 7727-37-9

O2 (2) oxygen 7782-44-7
Intradiffusion Coefficient: D12(T ); x1 = 0.50; Method: CORR Ref.: 1990B5
T [K] p [kPa] D · 104 [m2/s]
150.0 101.325 0.0611
200.0 101.325 0.1046
250.0 101.325 0.1565
300.0 101.325 0.2161
273.15 101.325 0.1832
293.15 101.325 0.2075
313.15 101.325 0.2329
333.15 101.325 0.2595
353.15 101.325 0.2871
373.15 101.325 0.3158
423.15 101.325 0.3920
473.15 101.325 0.4744
523.15 101.325 0.5626
573.15 101.325 0.6565
(continued)
623.15 101.325 0.7560

673.15 101.325 0.8609
723.15 101.325 0.9711
773.15 101.325 1.0864
873.15 101.325 1.3321
973.15 101.325 1.5975
1073.15 101.325 1.8818
1173.15 101.325 2.1846
1273.15 101.325 2.5064
1773.15 101.325 4.4076
2273.15 101.325 6.7683
2773.15 101.325 9.5545
3273.15 101.325 12.7435
N2 (1) nitrogen 7727-37-9

O2 (2) oxygen 7782-44-7
1.13 1.724
N2 (1) nitrogen 7727-37-9

O2 (2) oxygen 7782-44-7
0.2192 0.0 0.0 0.16%
2 –4
Comment: T = 300.0 K; D12 [m /s] = D · 10 ;
A = –0.7682 · 10–1 + 0.6737 · 10–2 · T + 1.0456 · 10–6 · T 2 [277 - 323 K]; ΔA = ± 0.05%
References
1179–1232.

Diffusion of nitrogen (1); xenon (2) 1
Diffusion of nitrogen (1); xenon (2)

Gaseous Mixtures
N2 (1) nitrogen 7727-37-9

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
129.7 ± 0.1 101.325 0.0269 ± 0.9%
163.0 ± 0.1 101.325 0.0421 ± 0.9%
202.4 ± 0.1 101.325 0.0636 ± 0.9%
243.1 ± 0.1 101.325 0.0899 ± 0.9%
296.0 ± 0.1 101.325 0.1293 ± 0.9%
296.0 ± 0.1 101.325 0.1298 ± 0.9%
405.0 ± 0.1 101.325 0.232 ± 0.9%
497.3 ± 0.1 101.325 0.330 ± 0.9%
583.0 ± 0.1 101.325 0.440 ± 0.9%
663.2 ± 0.1 101.325 0.560 ± 0.9%
777.7 ± 0.1 101.325 0.737 ± 0.9%
N2 (1) nitrogen 7727-37-9

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
163.0 ± 0.1 101.325 0.0423 ± 0.9%
296.0 ± 0.1 101.325 0.1312 ± 0.9%
296.0 ± 0.1 101.325 0.1308 ± 0.9%
583.0 ± 0.1 101.325 0.445 ± 0.9%
Reference

Diffusion of neon (1); argon (2) 1
Diffusion of neon (1); argon (2)

Gaseous Mixtures
Ne (1) neon 7440-01-9

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0115
100.0 101.325 0.0443
150.0 101.325 0.0947
200.0 101.325 0.1594
250.0 101.325 0.2366
300.0 101.325 0.3249
273.15 101.325 0.2762
293.15 101.325 0.3122
313.15 101.325 0.3499
333.15 101.325 0.3892
353.15 101.325 0.4301
373.15 101.325 0.4725
423.15 101.325 0.5849
473.15 101.325 0.7063
523.15 101.325 0.8363
573.15 101.325 0.9747
623.15 101.325 1.1214
673.15 101.325 1.2761
723.15 101.325 1.4388
773.15 101.325 1.6091
873.15 101.325 1.9717
973.15 101.325 2.3628
1073.15 101.325 2.7816
1173.15 101.325 3.2278
1273.15 101.325 3.7006
1773.15 101.325 6.4492
2273.15 101.325 9.8031
2773.15 101.325 13.7245
3273.15 101.325 18.1849
Ne (1) neon 7440-01-9

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0115
100.0 101.325 0.0444
150.0 101.325 0.0948
200.0 101.325 0.1597
(continued)
2 Diffusion of neon (1); argon (2)
250.0 101.325 0.2373

300.0 101.325 0.3262
273.15 101.325 0.2771
293.15 101.325 0.3134
313.15 101.325 0.3513
333.15 101.325 0.3908
353.15 101.325 0.4319
373.15 101.325 0.4746
423.15 101.325 0.5877
473.15 101.325 0.7099
523.15 101.325 0.8406
573.15 101.325 0.9798
623.15 101.325 1.1273
673.15 101.325 1.2828
723.15 101.325 1.4465
773.15 101.325 1.6178
873.15 101.325 1.9825
973.15 101.325 2.3757
1073.15 101.325 2.7968
1173.15 101.325 3.2452
1273.15 101.325 3.7203
1773.15 101.325 6.4814
2273.15 101.325 9.8498
2773.15 101.325 13.7875
3273.15 101.325 18.2659
Ne (1) neon 7440-01-9

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0115
100.0 101.325 0.0444
150.0 101.325 0.0949
200.0 101.325 0.1601
250.0 101.325 0.2380
300.0 101.325 0.3273
273.15 101.325 0.2780
293.15 101.325 0.3144
313.15 101.325 0.3525
333.15 101.325 0.3923
353.15 101.325 0.4336
373.15 101.325 0.4765
423.15 101.325 0.5903
473.15 101.325 0.7132
523.15 101.325 0.8447
573.15 101.325 0.9846
623.15 101.325 1.1328
(continued)
673.15 101.325 1.2891

723.15 101.325 1.4536
773.15 101.325 1.6259
873.15 101.325 1.9925
973.15 101.325 2.3878
1073.15 101.325 2.8109
1173.15 101.325 3.2614
1273.15 101.325 3.7387
1773.15 101.325 6.5116
2273.15 101.325 9.8935
2773.15 101.325 13.8466
3273.15 101.325 18.3419
Ne (1) neon 7440-01-9

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
300 101.325 0.323
350 101.325 0.421
400 101.325 0.525
450 101.325 0.635
500 101.325 0.765
550 101.325 0.892
600 101.325 1.045
650 101.325 1.200
700 101.325 1.355
750 101.325 1.520
800 101.325 1.675
850 101.325 1.87
900 101.325 2.04
950 101.325 2.23
1000 101.325 2.43
1050 101.325 2.62
1100 101.325 2.85
1150 101.325 3.09
1200 101.325 3.31
1250 101.325 3.54
1300 101.325 3.78
1350 101.325 4.00
1400 101.325 4.24
Comment: accuracy: ±(0.5–1)%; argon concentration: 1.0%

Ne (1) neon 7440-01-9

Ar (2) argon 7440-37-1
Intradiffusion Coefficient: D12(xi); T = 300.0 K; Method: TB Ref.: 1989D2
x2 p [kPa] D · 104 [m2/s]
0.10* 101.325 0.3247 ± 0.1%
0.06** 101.325 0.3236 ± 0.1%
0.04*** 101.325 0.3147 ± 0.1%
Comment: *: 20Ne used; **: natural Ne used; ***: 22Ne used
Ne (1) neon 7440-01-9

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
297.0 101.325 0.311*
297.0 101.325 0.309
*: at trace concentration of (1); exp. deviation: ± 1%
Ne (1) neon 7440-01-9

Ar (2) argon 7440-37-1
Intradiffusion Coefficient: D12(T ); Method: TB Ref.: 1983T6
T [K] p [kPa] D · 104 [m2/s]
357.0 ± 0.1% 101.325 0.454 ± 3%
441.0 ± 0.1% 101.325 0.625 ± 3%
541.0 ± 0.1% 101.325 0.907 ± 3%
656.0 ± 0.1% 101.325 1.291 ± 3%
661.0 ± 0.1% 101.325 1.318 ± 3%
768.0 ± 0.1% 101.325 1.639 ± 3%
861.0 ± 0.1% 101.325 2.047 ± 3%
907.0 ± 0.1% 101.325 2.222 ± 3%
1022.0 ± 0.1% 101.325 2.686 ± 3%
1100.0 ± 0.1% 101.325 3.075 ± 3%
1201.0 ± 0.1% 101.325 3.605 ± 3%
Ne (1) neon 7440-01-9

Ar (2) argon 7440-37-1
8.26 11/6

Ne (1) neon 7440-01-9

Ar (2) argon 7440-37-1
Equation: ln (D · p) = ln A + B · ln T – ln [ ln(C/T ) ]2 – E/T – F/ T 2 Range: 90 < T/K < 10000
8.779 1.546 1.94 1.82 1170.0
2
Ne (1) neon 7440-01-9

Ar (2) argon 7440-37-1
Mutual Diffusion Coefficient: D12(x2); Method: CT Ref.: 1974S3
0.3228 0.0123 0.0 0.08%
Comment: T = 300 K
Ne (1) neon 7440-01-9

Ar (2) argon 7440-37-1
–6.1238 0.70962 1.9148 0.04%
Comment: x2 = 0.15; D12 [m2/s] = D · 10–4
Ne (1) neon 7440-01-9

Ar (2) argon 7440-37-1
0.32340 0.00910 0.0 0.07%
Comment: T = 300.0 K; D12 [m2/s] = D · 10–4
Ne (1) neon 7440-01-9

Ar (2) argon 7440-37-1
–6.124 7.0962 1.9148 0.04%
Comment: x2 = 0.15; D12 [m2/s] = D · 10–4
Ne (1) neon 7440-01-9

Ar (2) argon 7440-37-1
(continued)
0.3234 0.0091 0.0 0.07%

Comment: T = 300 K; D12 [m2/s] = D · 10–4
References
Data 13 (1984) 229–303.
1989D2 Dunlop, P.J., Bignell, C.M.: Physica A 157 (1989) 1259–1260.
(1974) 825–831.
1978A9 Arora, P.S., Carson, P.J., Dunlop, P.J.: Chem. Phys. Lett. 54 (1978) 117–119.

Diffusion of neon (1); tetrafluoro-methane (2) 1
Diffusion of neon (1); tetrafluoro-methane (2)

Gaseous Mixtures
Ne (1) neon 7440-01-9

T = 200.0 K 0.1002 0.0078 1.612 0.1%
T = 230.0 K 0.1283 0.0078 1.612 0.1%
T = 260.0 K 0.1584 0.0078 1.612 0.1%
T = 280.0 K 0.1793 0.0078 1.612 0.1%
T = 300.0 K 0.2020 0.0078 1.612 0.1%
T = 320.0 K 0.2252 0.0078 1.612 0.1%
T = 360.0 K 0.2748 0.0078 1.612 0.1%
T = 380.0 K 0.3003 0.0078 1.612 0.1%
T = 400.0 K 0.3274 0.0078 1.612 0.1%
Reference

Diffusion of neon (1); methane (2) 1
Diffusion of neon (1); methane (2)

Gaseous Mixtures
Ne (1) neon 7440-01-9

CH4 (2) methane 74-82-8
0.3568 0.0018 0.0 0.02%
Comment: T = 300 K; D12 [m2/s] = D · 10–4;
A = –16.6726 · 10–2 + 15.8005 · 10–4 · T + 0.5491 · 10–6 · T 2 [277 - 320 K]
Reference

Diffusion of neon (1); carbon monoxide (2) 1
Diffusion of neon (1); carbon monoxide (2)

Gaseous Mixtures
Ne (1) neon 7440-01-9

0.3446 0.0034 0.0 0.06%
Comment: T = 300 K; D12 [m2/s] = D · 10–4;
A = –0.10900 + 1.1047 · 10–3 · T + 1.3536 · 10–6 · T 2 [277 - 323 K]
Reference

Diffusion of neon (1); carbon dioxide (2) 1
Diffusion of neon (1); carbon dioxide (2)

Gaseous Mixtures
Ne (1) neon 7440-01-9

T [K] p [kPa] D · 104 [m2/s]
176.1 101.325 0.1034 ± 0.9%
296.6 101.325 0.272 ± 0.9%
586.8 101.325 0.916 ± 0.9%
Ne (1) neon 7440-01-9

T [K] p [kPa] D · 104 [m2/s]
176.1 101.325 0.1032 ± 0.9%
201.2 101.325 0.131 ± 0.9%
231.3 101.325 0.171 ± 0.9%
263.2 101.325 0.217 ± 0.9%
296.6 101.325 0.271 ± 0.9%
417.9 101.325 0.500 ± 0.9%
484.1 101.325 0.651 ± 0.9%
586.8 101.325 0.912 ± 0.9%
Ne (1) neon 7440-01-9

1.07 1.776
Ne (1) neon 7440-01-9

–4.5415 5.6597 1.6546 0.06%
Comment: x2 = 0.15

2 Diffusion of neon (1); carbon dioxide (2)
Ne (1) neon 7440-01-9

0.2731 0.0058 0.0 0.05%
Comment: T = 300 K
References

Diffusion of neon (1); sulfur hexafluoride (2) 1
Diffusion of neon (1); sulfur hexafluoride (2)

Gaseous Mixtures
Ne (1) neon 7440-01-9

Mutual Diffusion Coefficient: D12(xi); T = 300.0 K; Method: TB Ref.: 1989D2
x2 p [kPa] D · 104 [m2/s]
0.1* 101.325 0.1584 ± 0.1%
0.06** 101.325 0.1576 ± 0.1%
0.04*** 101.325 0.1521 ± 0.1%
Reference

Diffusion of neon (1); hydrogen (2) 1
Diffusion of neon (1); hydrogen (2)

Gaseous Mixtures
Ne (1) neon 7440-01-9

H2 (2) hydrogen 1333-74-0
30.1 11/6
Ne (1) neon 7440-01-9

H2 (2) hydrogen 1333-74-0
5.95 1.731
Reference

Diffusion of neon (1); helium (2) 1
Diffusion of neon (1); helium (2)

Gaseous Mixtures
Ne (1) neon 7440-01-9

He (2) helium 7440-59-7
T [K] p [kPa] D · 106 [atm · m2/s]
65.35 ± 0.01 101.325 8.34 ± 0.08
77.35 ± 0.01 101.325 11.25 ± 0.05
90.2 ± 0.01 101.325 14.58 ± 0.08
169.3 ± 0.01 101.325 42.4 ± 0.2
295.0 ± 0.01 101.325 106.8 ± 0.6
Comment: D at x2 = 0.50 given as (D12 · p) in [m2 · atm/s]
Reference

Diffusion of neon (1); krypton (2) 1
Diffusion of neon (1); krypton (2)

Gaseous Mixtures
Ne (1) neon 7440-01-9

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0093
100.0 101.325 0.0361
150.0 101.325 0.0773
200.0 101.325 0.1305
250.0 101.325 0.1942
300.0 101.325 0.2672
273.15 101.325 0.2269
293.15 101.325 0.2567
313.15 101.325 0.2878
333.15 101.325 0.3203
353.15 101.325 0.3541
373.15 101.325 0.3892
423.15 101.325 0.4822
473.15 101.325 0.5827
523.15 101.325 0.6902
573.15 101.325 0.8046
623.15 101.325 0.9258
673.15 101.325 1.0536
723.15 101.325 1.1879
773.15 101.325 1.3287
873.15 101.325 1.6289
973.15 101.325 1.9533
1073.15 101.325 2.3011
1173.15 101.325 2.6717
1273.15 101.325 3.0646
1773.15 101.325 5.3488
2273.15 101.325 8.1346
2773.15 101.325 11.3896
3273.15 101.325 15.0898
Ne (1) neon 7440-01-9

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0093
100.0 101.325 0.0361
150.0 101.325 0.0775
200.0 101.325 0.1310
(continued)
2 Diffusion of neon (1); krypton (2)
250.0 101.325 0.1952

300.0 101.325 0.2688
273.15 101.325 0.2281
293.15 101.325 0.2582
313.15 101.325 0.2896
333.15 101.325 0.3225
353.15 101.325 0.3566
373.15 101.325 0.3920
423.15 101.325 0.4860
473.15 101.325 0.5875
523.15 101.325 0.6961
573.15 101.325 0.8117
623.15 101.325 0.9339
673.15 101.325 1.0628
723.15 101.325 1.1983
773.15 101.325 1.3404
873.15 101.325 1.6433
973.15 101.325 1.9705
1073.15 101.325 2.3212
1173.15 101.325 2.6948
1273.15 101.325 3.0909
1773.15 101.325 5.3927
2273.15 101.325 8.1990
2773.15 101.325 11.4771
3273.15 101.325 15.2029
Ne (1) neon 7440-01-9

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0093
100.0 101.325 0.0361
150.0 101.325 0.0776
200.0 101.325 0.1314
250.0 101.325 0.1960
300.0 101.325 0.2703
273.15 101.325 0.2293
293.15 101.325 0.2596
313.15 101.325 0.2913
333.15 101.325 0.3244
353.15 101.325 0.3588
373.15 101.325 0.3946
423.15 101.325 0.4894
473.15 101.325 0.5918
523.15 101.325 0.7014
573.15 101.325 0.8180
623.15 101.325 0.9413
(continued)
673.15 101.325 1.0712

723.15 101.325 1.2078
773.15 101.325 1.3510
873.15 101.325 1.6563
973.15 101.325 1.9860
1073.15 101.325 2.3394
1173.15 101.325 2.7158
1273.15 101.325 3.1147
1773.15 101.325 5.4326
2273.15 101.325 8.2575
2773.15 101.325 11.5567
3273.15 101.325 15.3059
Ne (1) neon 7440-01-9

Kr (2) krypton 7439-90-9
Intradiffusion Coefficient: D12(xi); T = 300.0 K; Method: TB Ref.: 1989D2
x2 p [kPa] D · 104 [m2/s]
0.1* 101.325 0.2643 ± 0.1%
0.06** 101.325 0.2632 ± 0.1%
0.04*** 101.325 0.2543 ± 0.1%
Ne (1) neon 7440-01-9

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
124.0 ± 0.1 101.325 0.0565 ± 0.9%
296.7 ± 0.1 101.325 0.263 ± 0.9%
296.7 ± 0.1 101.325 0.261 ± 0.9%
770.7 ± 0.1 101.325 1.39 ± 0.9%
Ne (1) neon 7440-01-9

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
124.0 ± 0.1 101.325 0.0564 ± 0.9%
172.8 ± 0.1 101.325 0.1005 ± 0.9%
203.8 ± 0.1 101.325 0.1335 ± 0.9%
243.4 ± 0.1 101.325 0.1830 ± 0.9%
296.7 ± 0.1 101.325 0.259 ± 0.9%
296.7 ± 0.1 101.325 0.258 ± 0.9%
418.0 ± 0.1 101.325 0.474 ± 0.9%
511.0 ± 0.1 101.325 0.668 ± 0.9%
601.0 ± 0.1 101.325 0.882 ± 0.9%
(continued)

697.0 ± 0.1 101.325 1.133 ± 0.9%

770.6 ± 0.1 101.325 1.35 ± 0.9%
Ne (1) neon 7440-01-9

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
300 101.325 0.262
350 101.325 0.342
400 101.325 0.431
450 101.325 0.526
500 101.325 0.627
550 101.325 0.737
600 101.325 0.850
650 101.325 0.985
700 101.325 1.098
750 101.325 1.240
800 101.325 1.38
850 101.325 1.53
900 101.325 1.69
950 101.325 1.83
1000 101.325 2.01
1050 101.325 2.17
1100 101.325 2.35
1150 101.325 2.52
1200 101.325 2.71
1250 101.325 2.89
1300 101.325 3.11
1350 101.325 3.30
1400 101.325 3.51
Comment: accuracy: ±(0.5–1)%; krypton concentration: 1.0%
Ne (1) neon 7440-01-9

Kr (2) krypton 7439-90-9
6.79 11/6
Ne (1) neon 7440-01-9

Kr (2) krypton 7439-90-9
(continued)

8.520 1.555 6.73 20.4

Ne (1) neon 7440-01-9

Kr (2) krypton 7439-90-9
–2.2749 0.39265 1.8708 0.07%
Comment: x2 = 0.15; D12 [m2/s] = D · 10–4
Ne (1) neon 7440-01-9

Kr (2) krypton 7439-90-9
0.26290 0.01750 0.0 0.04%
Comment: T = 300.0 K; D12 [m2/s] = D · 10–4
References
Data 13 (1984) 229–303.

Diffusion of neon (1); nitrogen (2) 1
Diffusion of neon (1); nitrogen (2)

Gaseous Mixtures
Ne (1) neon 7440-01-9

N2 (2) nitrogen 7727-37-9
0.3398 0.0 0.0 0.03%
Comment: T = 300 K; D12 [m2/s] = D · 10–4;
A = –0.091510 + 0.95686 · 10–3 · T + 1.6037 · 10–6 · T 2 [277 - 323 K]; ΔA = ±0.03%
Ne (1) neon 7440-01-9

N2 (2) nitrogen 7727-37-9
8.69 11/6
Ne (1) neon 7440-01-9

N2 (2) nitrogen 7727-37-9
1.59 1.743
References

Diffusion of neon (1); oxygen (2) 1
Diffusion of neon (1); oxygen (2)

Gaseous Mixtures
Ne (1) neon 7440-01-9

O2 (2) oxygen 7782-44-7
0.3438 0.0018 0.0 0.05%
Comment: T = 300 K; D12 [m2/s] = D · 10–4;
A = –0.4420 · 10–1 + 0.6621 · 10–3 · T + 0.2104 · 10–5 · T 2 [280 - 320 K]; ΔA = ±0.05%
Reference

Diffusion of neon (1); xenon (2) 1
Diffusion of neon (1); xenon (2)

Gaseous Mixtures
Ne (1) neon 7440-01-9

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0079
100.0 101.325 0.0305
150.0 101.325 0.0653
200.0 101.325 0.1104
250.0 101.325 0.1642
300.0 101.325 0.2260
273.15 101.325 0.1919
293.15 101.325 0.2171
313.15 101.325 0.2435
333.15 101.325 0.2710
353.15 101.325 0.2997
373.15 101.325 0.3293
423.15 101.325 0.4081
473.15 101.325 0.4932
523.15 101.325 0.5842
573.15 101.325 0.6811
623.15 101.325 0.7837
673.15 101.325 0.8919
723.15 101.325 1.0057
773.15 101.325 1.1249
873.15 101.325 1.3783
973.15 101.325 1.6507
1073.15 101.325 1.9416
1173.15 101.325 2.2508
1273.15 101.325 2.5778
1773.15 101.325 4.4729
2273.15 101.325 6.7795
2773.15 101.325 9.4726
3273.15 101.325 12.5326
Ne (1) neon 7440-01-9

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0079
100.0 101.325 0.0305
150.0 101.325 0.06555
200.0 101.325 0.1108
(continued)
2 Diffusion of neon (1); xenon (2)
250.0 101.325 0.1652

300.0 101.325 0.2277
273.15 101.325 0.1932
293.15 101.325 0.2187
313.15 101.325 0.2454
333.15 101.325 0.2732
353.15 101.325 0.3022
373.15 101.325 0.3322
423.15 101.325 0.4120
473.15 101.325 0.4981
523.15 101.325 0.5902
573.15 101.325 0.6883
623.15 101.325 0.7920
673.15 101.325 0.9013
723.15 101.325 1.0164
773.15 101.325 1.1372
873.15 101.325 1.3940
973.15 101.325 1.6699
1073.15 101.325 1.9643
1173.15 101.325 2.2769
1273.15 101.325 2.6074
1773.15 101.325 4.5210
2273.15 101.325 6.8485
2773.15 101.325 9.5649
3273.15 101.325 12.6507
Ne (1) neon 7440-01-9

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
50.0 101.325 0.0079
100.0 101.325 0.0305
150.0 101.325 0.0656
200.0 101.325 0.1113
250.0 101.325 0.1661
300.0 101.325 0.2291
273.15 101.325 0.1943
293.15 101.325 0.2200
313.15 101.325 0.2470
333.15 101.325 0.2751
353.15 101.325 0.3044
373.15 101.325 0.3347
423.15 101.325 0.4153
473.15 101.325 0.5024
523.15 101.325 0.5955
573.15 101.325 0.6945
623.15 101.325 0.7992
(continued)
673.15 101.325 0.9096

723.15 101.325 1.0259
773.15 101.325 1.1480
873.15 101.325 1.4078
973.15 101.325 1.6867
1073.15 101.325 1.9842
1173.15 101.325 2.2999
1273.15 101.325 2.6335
1773.15 101.325 4.5633
2273.15 101.325 6.9090
2773.15 101.325 9.6460
3273.15 101.325 12.7546
Ne (1) neon 7440-01-9

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
165.2 ± 0.1 101.325 0.0779 ± 0.9%
297.2 ± 0.1 101.325 0.2233 ± 0.9%
297.5 ± 0.1 101.325 0.2229 ± 0.9%
777.8 ± 0.1 101.325 1.208 ± 0.9%
Ne (1) neon 7440-01-9

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
127.0 ± 0.1 101.325 0.0473 ± 0.9%
165.2 ± 0.1 101.325 0.0769 ± 0.9%
203.6 ± 0.1 101.325 0.112 ± 0.9%
234.3 ± 0.1 101.325 0.1434 ± 0.9%
297.5 ± 0.1 101.325 0.2183 ± 0.9%
297.5 ± 0.1 101.325 0.2185 ± 0.9%
400.2 ± 0.1 101.325 0.372 ± 0.9%
503.0 ± 0.1 101.325 0.550 ± 0.9%
593.2 ± 0.1 101.325 0.735 ± 0.9%
698.1 ± 0.1 101.325 0.974 ± 0.9%
777.8 ± 0.1 101.325 1.175 ± 0.9%
Ne (1) neon 7440-01-9

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
300 101.325 0.219
(continued)

350 101.325 0.286

400 101.325 0.359
450 101.325 0.440
500 101.325 0.523
550 101.325 0.615
600 101.325 0.710
650 101.325 0.810
700 101.325 0.920
750 101.325 1.025
800 101.325 1.155
850 101.325 1.280
900 101.325 1.405
950 101.325 1.535
1000 101.325 1.675
1050 101.325 1.815
1100 101.325 1.96
1150 101.325 2.11
1200 101.325 2.26
1250 101.325 2.41
1300 101.325 2.58
1350 101.325 2.75
1400 101.325 2.92
Ne (1) neon 7440-01-9

Xe (2) xenon 7440-63-3
5.84 11/6
Ne (1) neon 7440-01-9

Xe (2) xenon 7440-63-3
6.747 1.584 19.0 10.1
2

Ne (1) neon 7440-01-9

Xe (2) xenon 7440-63-3
–8.2455 0.75183 0.8749 0.04%
2 –4
Comment: x2 = 0.08; D12 [m /s] = D · 10
Ne (1) neon 7440-01-9

Xe (2) xenon 7440-63-3
Mutual Diffusion
0.22124 0.03263 0.5313 0.02%
Comment: T = 300.0 K; D12 [m2/s] = D · 10–4
References
Data 13 (1984) 229–303.

Diffusion of oxygen atom (1); argon (2) 1
Diffusion of oxygen atom (1); argon (2)

Gaseous Mixtures
O (1) oxygen atom 17778-80-2

Ar (2) argon 7440-37-1
0.751 1.841
Reference

Diffusion of oxygen atom (1); helium (2) 1
Diffusion of oxygen atom (1); helium (2)

Gaseous Mixtures
O (1) oxygen atom 17778-80-2

He (2) helium 7440-59-7
4.68 1.749
Reference

Diffusion of oxygen atom (1); nitrogen (2) 1
Diffusion of oxygen atom (1); nitrogen (2)

Gaseous Mixtures
O (1) oxygen atom 17778-80-2

N2 (2) nitrogen 7727-37-9
1.32 1.774
Reference

Diffusion of oxygen atom (1); oxygen (2) 1
Diffusion of oxygen atom (1); oxygen (2)

Gaseous Mixtures
O (1) oxygen atom 17778-80-2

O2 (2) oxygen 7782-44-7
1.32 1.774
Reference

Diffusion of oxygen (1); argon (2) 1
Diffusion of oxygen (1); argon (2)

Gaseous Mixtures
O2 (1) oxygen 7782-44-7

Ar (2) argon 7440-37-1
Diffusivity of (1) in mixture: D1eff (x1); T = (298.15 ± 2.0) K; Method: CC Ref.: 1968Y1
x1 p [kPa] D · 104 [m2/s]
0.065 101.325 0.23
0.065 101.325 0.34
0.065 101.325 0.31
0.21 101.325 0.28
0.27 101.325 0.39
0.27 101.325 0.40
0.40 101.325 0.27
0.40 101.325 0.34
Comment: atomic O diffusing in mixture
O2 (1) oxygen 7782-44-7

Ar (2) argon 7440-37-1
n [1/10–25 m3] p [atm] D · 104 [atm · m2/s]
2.449 1.000 0.2035 ± 0.2%
2.448 1.000 0.2035 ± 0.2%
2.447 0.999 0.2040 ± 0.2%
4.899 2.000 0.2036 ± 0.2%
7.354 3.000 0.2035 ± 0.2%
7.354 3.000 0.2035 ± 0.2%
9.813 4.001 0.2030 ± 0.2%
12.277 5.002 0.2028 ± 0.2%
12.280 5.003 0.2027 ± 0.2%
14.744 6.003 0.2025 ± 0.2%
17.211 7.004 0.2021 ± 0.2%
17.214 7.005 0.2025 ± 0.2%
19.683 8.004 0.2021 ± 0.2%
22.154 9.004 0.2019 ± 0.2%
22.162 9.007 0.2020 ± 0.2%
24.640 10.008 0.2015 ± 0.2%
24.638 10.006 0.2009 ± 0.2%
27.113 11.005 0.2015 ± 0.2%
32.082 13.005 0.2011 ± 0.2%
37.072 15.009 0.2007 ± 0.2%
42.069 17.010 0.2007 ± 0.2%
47.075 19.010 0.2001 ± 0.2%
(continued)

2 Diffusion of oxygen (1); argon (2)
52.092 21.009 0.1996 ± 0.2%

57.119 23.007 0.1991 ± 0.2%
62.190 25.017 0.1987 ± 0.2%
References
1968Y1 Yolles, R.S., Wise, H.: J. Chem. Phys. 48 (1968) 5109–5113.

Diffusion of oxygen (1); carbon dioxide (2) 1
Diffusion of oxygen (1); carbon dioxide (2)

Gaseous Mixtures
O2 (1) oxygen 7782-44-7

5
1.56 1.661 61.3
O2 (1) oxygen 7782-44-7

0.1693 0.0 0.0 0.07%
Comment: T = 300.0 K; D12 [m2/s] = D · 10–4;
A = –0.8201 · 10–1 + 0.6281 · 10–3 · T + 0.6995 · 10–6 · T 2 [277 - 323 K]; ΔA = ±0.08%
References

Diffusion of oxygen (1); sulfur hexafluoride (2) 1
Diffusion of oxygen (1); sulfur hexafluoride (2)

Gaseous Mixtures
O2 (1) oxygen 7782-44-7

5
2.65 1.522 129.0
Reference

Diffusion of oxygen (1); hydrogen (2) 1
Diffusion of oxygen (1); hydrogen (2)

Gaseous Mixtures
O2 (1) oxygen 7782-44-7

H2 (2) hydrogen 1333-74-0
x1 p [Torr] D · 104 [m2/s]
0.7705 28.5 14.5 ± 1.32%
0.7336 56.8 7.82 ± 1.58%
0.7695 204.1 2.56 ± 0.50%
0.7788 403.7 1.40 ± 0.26%
0.8308 802.1 0.774 ± 0.13%
0.8698 1202.9 0.507 ± 0.13%
O2 (1) oxygen 7782-44-7

H2 (2) hydrogen 1333-74-0
x1 p [Torr] D · 104 [m2/s]
0.9784 803.3 0.761 ± 0.766%
0.8308 802.1 0.774 ± 0.133%
0.5162 798.6 0.753 ± 0.200%
0.3134 805.3 0.757 ± 0.228%
0.2085 805.2 0.749 ± 0.226%
0.1121 803.6 0.745 ± 0.682%
O2 (1) oxygen 7782-44-7

H2 (2) hydrogen 1333-74-0
T [K] p [Torr] D · 104 [m2/s]
287.82 ± 0.01 802.5 0.685 ± 0.23%
298.17 ± 0.01 802.1 0.774 ± 0.13%
308.19 ± 0.01 807.0 0.790 ± 0.22%
318.26 ± 0.01 803.1 0.871 ± 1.02%
Reference

Diffusion of oxygen (1); water (2) 1
Diffusion of oxygen (1); water (2)

Gaseous Mixtures
O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
0.189 2.072
2.78 1.632*
Comment: x1 = 0.50; D12(T ) · p [atm · cm2/s] = (D · p);
*: temperature range 450 to 1070 K
Reference

Diffusion of oxygen (1); helium (2) 1
Diffusion of oxygen (1); helium (2)

Gaseous Mixtures
O2 (1) oxygen 7782-44-7

He (2) helium 7440-59-7
x1 p [kPa] D · 104 [m2/s]
0.025 101.325 0.65
0.025 101.325 0.64
0.064 101.325 0.48
0.087 101.325 0.57
0.113 101.325 0.52
0.27 101.325 0.43
0.42 101.325 0.47
0.57 101.325 0.38
0.58 101.325 0.39
0.58 101.325 0.33
0.71 101.325 0.34
O2 (1) oxygen 7782-44-7

He (2) helium 7440-59-7
Intradiffusion Coefficient: D1T(x2); T = (298.15 ± 0.5) K; Method: TB Ref.: 1973H9
x2 p [kPa] D · 104 [m2/s]
0.000 101.325 0.199
0.201 101.325 0.236
0.444 101.325 0.304
0.606 101.325 0.359
0.750 101.325 0.443
0.900 101.325 0.547
O2 (1) oxygen 7782-44-7

He (2) helium 7440-59-7
Intradiffusion Coefficient: D12(xi); T = (298.15 ± 0.5) K; Method: TB Ref.: 1973H9
x2 p [kPa] D · 104 [m2/s]
0.504 101.325 0.682
0.696 101.325 0.747
0.898 101.325 0.778
O2 (1) oxygen 7782-44-7

He (2) helium 7440-59-7
x1 p [Torr] D · 104 [m2/s]
0.8286 29.4 11.7 ± 0.43%
(continued)

2 Diffusion of oxygen (1); helium (2)
0.7424 104.0 4.48 ± 0.40%

0.7798 206.9 2.54 ± 0.27%
0.7776 404.7 1.34 ± 0.20%
0.8361 802.1 0.693 ± 0.12%
0.8819 1203.8 0.458 ± 0.13%
O2 (1) oxygen 7782-44-7

He (2) helium 7440-59-7
x1 p [Torr] D · 104 [m2/s]
0.8420 802.1 0.693 ± 0.153%
0.5186 801.8 0.693 ± 0.162%
0.3126 806.4 0.692 ± 0.169%
0.2065 803.8 0.694 ± 0.244%
0.1074 802.9 0.690 ± 0.422%
Comment: for experimental details see [1975K4]
O2 (1) oxygen 7782-44-7

He (2) helium 7440-59-7
T [K] p [Torr] D · 104 [m2/s]
287.78 ± 0.01 803.6 0.638 ± 0.22%
298.18 ± 0.01 802.1 0.693 ± 0.15%
308.19 ± 0.01 806.2 0.733 ± 0.16%
318.25 ± 0.01 803.7 0.746 ± 0.25%
References
1973H9 Hirakawa, H., Kamei, Y., Sugisaki, M., Oishi, Y.: Bull. Chem. Soc. Jpn. 46 (1973) 2659–2662.
1975K4 Kerl, K., Joswig, U.: Z. Phys. Chem. Neue Folge 97 (1975) 139–154.

Diffusion of oxygen (1); krypton (2) 1
Diffusion of oxygen (1); krypton (2)

Gaseous Mixtures
O2 (1) oxygen 7782-44-7

Kr (2) krypton 7439-90-9
x1 p [kPa] D · 104 [m2/s]
0.29 101.325 0.181
0.33 101.325 0.104
0.35 101.325 0.108
0.35 101.325 0.097
0.45 101.325 0.201
0.64 101.325 0.225
Reference

Diffusion of oxygen (1); nitrogen (2) 1
Diffusion of oxygen (1); nitrogen (2)

Gaseous Mixtures
O2 (1) oxygen 7782-44-7

N2 (2) nitrogen 7727-37-9
x1 p [Torr] D · 104 [m2/s]
0.7399 405.7 0.346 ± 0.42%
0.9131 604.3 0.250 ± 1.01%
0.8578 604.6 0.259 ± 1.06%
0.9019 1004.3 0.176 ± 0.32%
0.9140 1197.8 0.141 ± 0.94%
O2 (1) oxygen 7782-44-7

N2 (2) nitrogen 7727-37-9
x1 p [Torr] D · 104 [m2/s]
0.8835 807.9 0.255 ± 0.56%
0.5385 804.9 0.252 ± 0.40%
O2 (1) oxygen 7782-44-7

N2 (2) nitrogen 7727-37-9
T [K] p [Torr] D · 104 [m2/s]
288.34 ± 0.01 801.9 0.244 ± 0.63%
298.18 ± 0.01 807.9 0.255 ± 0.56%
328.61 ± 0.01 805.0 0.294 ± 1.24%
Reference

Diffusion of sulfur dioxide (1); krypton (2) 1
Diffusion of sulfur dioxide (1); krypton (2)

Gaseous Mixtures
O 2S (1) sulfur dioxide 7446-09-5

Kr (2) krypton 7439-90-9
Integral Diffusion Coefficient: D (xi); T = (313.15 ± 0.05) K; Method: TB Ref.: 1966S4
x1 p [Torr] D · 104 [m2/s]
0.0000 30.70 0.1018 ± 1%
0.2556 32.88 0.0970 ± 1%
0.4959 25.53 0.0932 ± 1%
0.7343 22.19 0.0894 ± 1%
1.0000 30.54 0.0859 ± 1%
Comment: 85Kr diffusing in mixture
Reference
1966S4 Saran, A., Singh, Y.: Can. J. Chem. 44 (1966) 2222–2223.

Diffusion of xenon (1); argon (2) 1
Diffusion of xenon (1); argon (2)

Gaseous Mixtures
Xe (1) xenon 7440-63-3

Ar (2) argon 7440-37-1
T [K] p [kPa]
344.0 ± 0.1% 101.325 0.146 ± 3%
431.0 ± 0.1% 101.325 0.232 ± 3%
500.0 ± 0.1% 101.325 0.291 ± 3%
513.0 ± 0.1% 101.325 0.294 ± 3%
571.0 ± 0.1% 101.325 0.387 ± 3%
592.0 ± 0.1% 101.325 0.405 ± 3%
656.0 ± 0.1% 101.325 0.471 ± 3%
732.0 ± 0.1% 101.325 0.592 ± 3%
767.0 ± 0.1% 101.325 0.648 ± 3%
822.0 ± 0.1% 101.325 0.717 ± 3%
890.0 ± 0.1% 101.325 0.820 ± 3%
948.0 ± 0.1% 101.325 0.908 ± 3%
1013.0 ± 0.1% 101.325 1.050 ± 3%
1106.0 ± 0.1% 101.325 1.159 ± 3%
1137.0 ± 0.1% 101.325 1.232 ± 3%
1244.0 ± 0.1% 101.325 1.470 ± 3%
1256.0 ± 0.1% 101.325 1.493 ± 3%
Xe (1) xenon 7440-63-3

Ar (2) argon 7440-37-1
x1 p [kPa] D · 104 [m2/s]
0.75 101.325 0.08614 ± 0.00682
0.50 101.325 0.09490 ± 0.0173
0.25 101.325 0.1042 ± 0.0144
Comment: 133Xe diffusing in mixture
Xe (1) xenon 7440-63-3

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 106 [atm · m2/s]
169.3 101.325 3.76 ± 0.03
231.1 101.325 6.91 ± 0.04
295.0 101.325 11.10 ± 0.06
400.0 101.325 19.54 ± 0.12

2 Diffusion of xenon (1); argon (2)
References

Diffusion of xenon (1); methane (2) 1
Diffusion of xenon (1); methane (2)

Gaseous Mixtures
Xe (1) xenon 7440-63-3

CH4 (2) methane 74-82-8
0.1481 0.0128 0.0 0.03%
Comment: T = 300 K; D12 [m2/s] = D · 10–4;
A = –0.4314 · 10–2 + 0.8834 · 10–4 · T + 1.3999 · 10–6 · T 2 [277 - 320 K]
Reference

Diffusion of xenon (1); carbon monoxide (2) 1
Diffusion of xenon (1); carbon monoxide (2)

Gaseous Mixtures
Xe (1) xenon 7440-63-3

0.1339 0.0045 0.0 0.08%
Comment: T = 300 K; D12 [m2/s] = D · 10–4;
A = –0.06576 + 0.4963 · 10–3 · T + 0.5621 · 10–6 · T 2 [277 - 323 K]
Reference

Diffusion of xenon (1); carbon dioxide (2) 1
Diffusion of xenon (1); carbon dioxide (2)

Gaseous Mixtures
Xe (1) xenon 7440-63-3

T [K] p [kPa] D · 104 [m2/s]
175.0 101.325 0.0311 ± 0.9%
203.4 101.325 0.0425 ± 0.9%
233.1 101.325 0.0564 ± 0.9%
263.2 101.325 0.0723 ± 0.9%
291.7 101.325 0.0881 ± 0.9%
407.2 101.325 0.168 ± 0.9%
498.8 101.325 0.243 ± 0.9%
593.2 101.325 0.328 ± 0.9%
674.4 101.325 0.408 ± 0.9%
776.9 101.325 0.527 ± 0.9%
Xe (1) xenon 7440-63-3

T [K] p [kPa] D · 104 [m2/s]
175.0 101.325 0.0311 ± 0.9%
291.7 101.325 0.0883 ± 0.9%
593.2 101.325 0.332 ± 0.9%
Xe (1) xenon 7440-63-3

0.09362 0.0069 0.0 0.04%
Comment: T = 300 K
Xe (1) xenon 7440-63-3

0.9705 –0.5260 1.1091 0.07%
Comment: x1 = 0.20

2 Diffusion of xenon (1); carbon dioxide (2)
References

Diffusion of xenon (1); hydrogen (2) 1
Diffusion of xenon (1); hydrogen (2)

Gaseous Mixtures
Xe (1) xenon 7440-63-3

Ar (2) hydrogen 1333-74-0
Mutual Diffusion Coefficient: D12(T ); Method: TB Ref.: 1972M1
15.1 11/6
Xe (1) xenon 7440-63-3

Ar (2) hydrogen 1333-74-0
3.68 1.712 16.9
Reference

Diffusion of xenon (1); ammonia (2) 1
Diffusion of xenon (1); ammonia (2)

Gaseous Mixtures
Xe (1) xenon 7440-63-3

H 3N (2) ammonia 7664-41-7
0.1518 0.0 0.0 0.1%
Comment: T = 300.0 K; D12 [m2/s] = D · 10–4;
A = –0.3625 · 10–1 + 0.2824 · 10–3 · T + 1.1543 · 10–6 · T 2 [280 - 400 K]; ΔA = ± 0.08%
Reference

Diffusion of xenon (1); helium (2) 1
Diffusion of xenon (1); helium (2)

Gaseous Mixtures
Xe (1) xenon 7440-63-3

He (2) helium 7440-59-7
T [K] p [kPa] D · 106 [atm · m2/s]
169.3 101.325 21.34 ± 0.15
231.1 101.325 35.7 ± 0.2
295.0 101.325 54.9 ± 0.3
400.0 101.325 91.8 ± 0.6
Xe (1) xenon 7440-63-3

He (2) helium 7440-59-7
x1 p [kPa] D · 104 [m2/s]
0.80 101.325 0.1051 ± 0.0116
0.50 101.325 0.1228 ± 0.0140
0.25 101.325 0.1801 ± 0.0123
0.125 101.325 0.2603 ± 0.0045
References

Diffusion of xenon (1); krypton (2) 1
Diffusion of xenon (1); krypton (2)

Gaseous Mixtures
Xe (1) xenon 7440-63-3

Kr (2) krypton 7439-90-9
x1 p [kPa] D · 104 [m2/s]
0.75 101.325 0.07311 ± 0.0058
0.25 101.325 0.07887 ± 0.00716
0.10 101.325 0.08506 ± 0.0313
Xe (1) xenon 7440-63-3

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 106 [atm · m2/s]
169.3 101.325 2.51 ± 0.03
231.1 101.325 4.68 ± 0.04
295.0 101.325 7.43 ± 0.07
400.0 101.325 13.15 ± 0.12
References

Diffusion of xenon (1); nitrogen (2) 1
Diffusion of xenon (1); nitrogen (2)

Gaseous Mixtures
Xe (1) xenon 7440-63-3

N2 (2) nitrogen 7727-37-9
Equatxion: (D · p) = A · T c
3.29 11/6
Xe (1) xenon 7440-63-3

N2 (2) nitrogen 7727-37-9
0.470 1.789
Xe (1) xenon 7440-63-3

N2 (2) nitrogen 7727-37-9
0.1317 0.0064 0.0 0.08%
Comment: T = 300.0 K; D12 [m2/s] = D · 10–4;
A = –0.003067 + 0.08819 · 10–3 · T + 1.2029 · 10–6 · T 2 [277 - 323 K]; ΔA = ±0.02%
References

Diffusion of xenon (1); neon (2) 1
Diffusion of xenon (1); neon (2)

Gaseous Mixtures
Xe (1) xenon 7440-63-3

Ne (2) neon 7440-01-9
x1 p [kPa] D · 104 [m2/s]
0.50 101.325 0.1075 ± 0.0122
0.25 101.325 0.1400 ± 0.0103
Xe (1) xenon 7440-63-3

Ne (2) neon 7440-01-9
T [K] p [kPa] D · 106 [atm · m2/s]
169.3 101.325 8.16 ± 0.05
231.1 101.325 14.16 ± 0.09
295.0 101.325 21.84 ± 0.12
400.0 101.325 36.8 ± 0.2
References

Diffusion of xenon (1); oxygen (2) 1
Diffusion of xenon (1); oxygen (2)

Gaseous Mixtures
Xe (1) xenon 7440-63-3

O2 (2) oxygen 7782-44-7
0.1296 0.0077 0.0 0.04%
Comment: T = 300.0 K; D12 [m2/s] = D · 10–4;
A = –0.1238 · 10–1 + 0.1521 · 10–3 · T + 0.1071 · 10–5 · T 2 [280 - 320 K]; ΔA = ± 0.04%
Reference

Diffusion of propan-2-one (1); carbon dioxide (2) 1
Diffusion of propan-2-one (1); carbon dioxide (2)

Data extract from of Landolt-Börnstein IV/15A, Chapter 4.1.1: Diffusion of Gas/
Vapor in Liquid

Mutual Diffusion Coefficient: D12(φi); T = (303.15 ± 0.5) K; Method: TAYLOR Ref.: 1991U1
φ1 p [MPa] D · 109 [m2/s]
0.025 9.0 3.74 ± 0.11
0.082 9.0 2.05 ± 0.06
Comment: φ1 volume fraction

Intradiffusion Coefficient: D12(φi); T = (313.15 ± 0.5) K; Method: TAYLOR Ref.: 1991U1
φ1 p [MPa] D · 109 [m2/s]
0.025 9.0 7.45 ± 0.22
Reference
1991U1 Umezawa, S., Nagashima, A.: High Temperatures-High Pressures 23 (1991) 705–710.


Vapor in Liquid
C6H6 (1) benzene 71-43-2

Mutual Diffusion Coefficient: D12(φi); T = (303.15 ± 0.5) K; Method: TAYLOR Ref.: 1991U1
φ1 p [MPa] D · 109 [m2/s]
0.025 9.0 3.18 ± 0.09
0.082 9.0 1.86 ± 0.05
Reference
1991U1 Umezawa, S., Nagashima, A.: High Temperatures-High Pressures 23 (1991) 705–710.

Diffusion of pheno (1); carbon dioxide (2) 1
Diffusion of pheno (1); carbon dioxide (2)

Vapor in Liquid
C6H6O (1) phenol 108-95-2

Mutual Diffusion Coefficient: D12(ci); T = 313.15 K; Method: TAYLOR Ref.: 2004F2
c1 [mol/dm3] p [MPa] D · 108 [m2/s]
–7
1.1 · 10 17.87 1.146
1.1 · 10–7 17.87 1.180
0.56 · 10–6 17.87 1.249
1.1 · 10–6 17.87 1.214
–5
0.56 · 10 17.87 1.235
1.1 · 10–5 17.87 1.224
0.56 · 10–4 17.87 1.221
1.1 · 10–4 17.87 1.222
–3
0.56 · 10 17.87 1.166
1.1 · 10–3 17.87 1.131
0.005 17.87 0.727
0.009 17.87 0.484
Comment: concentration c1 = injected amount
Reference
2004F2 Funazukuri, T., Kong, C.Y., Kagei, S.: Fluid Phase Equilib. 220 (2004) 181–188.

Diffusion of cis-octadec-9-enoic acid methyl ester (1); carbon dioxide (2) 1
Diffusion of cis-octadec-9-enoic acid methyl ester (1);

carbon dioxide (2)
Vapor in Liquid
C19H36O2 (1) cis-octadec-9-enoic acid methyl ester 112-62-9

Mutual Diffusion Coefficient: D12(xi); T = 313.15 K; Method: PF Ref.: 1999T2
x1 p [MPa] D · 109 [m2/s]
0.00213 10.6 6.37
0.00298 10.6 5.47
0.00309 10.6 5.04
0.00403 10.6 4.57
0.00475 10.6 3.57
0.00639 10.6 2.01
0.00306 11.5 5.91
0.00414 11.5 5.03
0.00703 11.5 3.41
0.00817 11.5 2.52
0.01031 11.5 1.44
Comment: steady state parallel plate apparatus; diffusion in supercritical fluid carbon dioxide

Intradiffusion Coefficient: D12(di); T = 313.2 K; Method: PF Ref.: 1999T2
d1 [kg/m3] p [MPa] D · 109 [m2/s]
28.9 10.6 2.01 ± 5%
21.4 10.6 3.57 ± 5%
17.8 10.6 4.57 ± 5%
14.0 10.6 5.04 ± 5%
13.3 10.6 5.47 ± 5%
9.6 10.6 6.37 ± 5%
19.8 11.5 5.03 ± 5%
19.7 13.7 4.75 ± 5%
4.1 14.0 7.52 ± 5%
Comment: steady state parallel plate apparatus; diffusion in supercritical fluid carbon dioxide
Reference
1999T2 Tuan, D.Q., Zollweg, J.A., Rizvi, S.S.: Ind. Eng. Chem. Res. 38 (1999) 2787–2793.

Diffusion of decamethyl-ferrocene (1); trifluoro-methane (2) 1
Diffusion of decamethyl-ferrocene (1); trifluoro-methane

(2)
Vapor in Liquid
C20H30Fe (1) decamethyl-ferrocene 12126-50-0

Mutual Diffusion Coefficient: D12(ci); T = 261.9 K; Method: EA V Ref.: 2004G1
c1 [mol/dm3] p [bar] D · 109 [m2/s]
–6
4.34 · 10 82.07 2.5
4.34 · 10–6 142.23 2.6
4.34 · 10–6 178.83 2.3
Comment: supporting electrolyte: 1% tetrabutyl-ammonium hexafluorophosphate

Intradiffusion Coefficient: D12(ci); T = 282.4 K; Method: EA V Ref.: 2004G1
c1 [mol/dm3] p [bar] D · 109 [m2/s]
4.34 · 10–6 42.73 4.6
4.34 · 10–6 60.61 4.1
–6
4.34 · 10 96.93 3.6
4.34 · 10–6 115.60 3.5
4.34 · 10–6 178.71 2.9

c1 [mol/dm3] p [bar] D · 109 [m2/s]
3.50· 10–6 60.45 5.7
–6
3.50· 10 65.26 5.2
3.50· 10–6 74.95 5.1
3.50· 10–6 94.42 5.0
3.50· 10–6 114.33 5.0
3.50· 10–6 149.78 4.7

c1 [mol/dm3] p [bar] D · 109 [m2/s]
–6
4.83 · 10 84.49 13.0
4.83 · 10–6 88.42 12.0
4.83 · 10–6 96.57 9.8
4.83 · 10–6 104.80 9.6
(continued)
2 Diffusion of decamethyl-ferrocene (1); trifluoro-methane (2)
4.83 · 10–6 116.64 8.1

4.83 · 10–6 133.09 7.2
4.83 · 10–6 156.61 7.3
1.23 · 10–6 77.383 13.8
–6
1.23 · 10 77.38 14.8
1.23 · 10–6 84.69 11.9
1.23 · 10–6 96.61 9.6
1.23 · 10–6 117.35 8.7
1.23 · 10–6 117.35 8.6
1.23 · 10–6 156.85 7.4
1.23 · 10–6 156.85 7.6
Reference
2004G1 Goldfarb, D.L., Corti, H.R.: J. Phys. Chem. B 108 (2004) 3368–3375.

Diffusion of decamethyl-ferrocenium hexafluorophosphate (1); trifluoro-methane (2) 1
Diffusion of decamethyl-ferrocenium hexafluorophosphate

(1); trifluoro-methane (2)
Vapor in Liquid
C20H30Fe*F6P (1) decamethyl-ferrocenium hexafluorophosphate 54182-44-4

Mutual Diffusion Coefficient: D12(ci); T = 282.45 K; Method: EA V Ref.: 2004G1
c1 [mol/dm3] p [bar] D · 109 [m2/s]
–6
4.64· 10 60.61 4.3
4.64· 10–6 96.93 3.1
4.64· 10–6 115.6 2.9
4.64· 10–6 178.71 2.9

c1 [mol/dm3] p [bar] D · 109 [m2/s]
3.50· 10–6 60.57 5.4
–6
3.50· 10 65.27 5.0
3.50· 10–6 74.28 5.1
3.50· 10–6 94.82 4.5
3.50· 10–6 114.77 4.4
3.50· 10–6 148.86 4.0

c1 [mol/dm3] p [bar] D · 109 [m2/s]
4.64· 10–6 51.23 2.8
4.64· 10–6 101.85 2.7
4.64· 10–6 179.58 2.1

c1 [mol/dm3] p [bar] D · 109 [m2/s]
1.55 · 10–6 103.88 7.3
–6
1.55 · 10 115.76 6.9
1.55 · 10–6 132.37 6.9
1.55 · 10–6 132.37 6.6
1.55 · 10–6 156.97 6.2
(continued)
2 Diffusion of decamethyl-ferrocenium hexafluorophosphate (1); trifluoro-methane (2)
1.01 · 10–6 76.66 12.3

1.01 · 10–6 76.66 11.7
1.01 · 10–6 76.66 10.7
1.01 · 10–6 80.64 11.5
–6
1.01 · 10 80.64 10.6
1.01 · 10–6 84.61 10.5
1.01 · 10–6 84.61 9.8
1.01 · 10–6 88.74 9.9
–6
1.01 · 10 96.65 9.2
1.01 · 10–6 104.60 8.7
1.01 · 10–6 116.88 8.1
1.01 · 10–6 132.21 8.0
1.01 · 10–6 157.33 7.1
4.99 · 10–6 88.70 9.2
4.99 · 10–6 88.70 9.5
4.99 · 10–6 96.53 8.9
4.99 · 10–6 96.53 8.7
–6
4.99 · 10 104.64 8.1
4.99 · 10–6 116.40 8.0
4.99 · 10–6 132.21 6.5
4.99 · 10–6 157.25 6.5
Comment: supporting electrolyte: 1% tetrabutyl–ammonium hexafluorophosphate
Reference
2004G1 Goldfarb, D.L., Corti, H.R.: J. Phys. Chem. B 108 (2004) 3368–3375.


Vapor in Liquid
H 2O (1) water 7732-18-5

Intradiffusion Coefficient: D1T(T ); Method: NMR FG Ref.: 2003X1
T [K] p [bar] D · 108 [m2/s]
308.15 ± 0.1 134.7 2.81
308.15 ± 0.1 149.0 2.63
308.15 ± 0.1 163.3 2.31
308.15 ± 0.1 189.1 2.20
308.15 ± 0.1 214.3 2.02
308.15 ± 0.1 242.8 1.94
308.15 ± 0.1 268.7 1.89
308.15 ± 0.1 298.0 1.82
298.15 ± 0.1 133.3 2.07
298.15 ± 0.1 148.3 1.88
298.15 ± 0.1 164.6 1.72
298.15 ± 0.1 189.1 1.61
298.15 ± 0.1 217.7 1.57
298.15 ± 0.1 241.5 1.52
298.15 ± 0.1 272.8 1.41
298.15 ± 0.1 297.3 1.36
283.15 ± 0.1 132.0 1.32
283.15 ± 0.1 148.3 1.27
283.15 ± 0.1 162.6 1.24
283.15 ± 0.1 189.8 1.16
283.15 ± 0.1 217.7 1.11
283.15 ± 0.1 144.9 1.07
283.15 ± 0.1 168.7 1.01
283.15 ± 0.1 298.0 0.96
Reference
2003X1 Xu, B., Nagashima, K., DeSimone, J.M., Johnson, C.S.: J. Phys. Chem. A 107 (2003) 1–3.

Diffusion of argon (1); tris-nonafluorobutyl-amine (2) 1
Diffusion of argon (1); tris-nonafluorobutyl-amine (2)

Vapor in Liquid
Ar (1) argon 7440-37-1

C12F27N (2) tris-nonafluorobutyl-amine 311-89-7
Mutual Diffusion Coefficient: D12(xi); T = (298.15 ± 0.01) K; Method: DIA Ref.: 1971P5
x1 p [kPa] D · 104 [m2/s]
0.006105 101.325 3.83
0.006105 101.325 3.74
Reference
1971P5 Powell, R.J., Hildebrand, J.H.: J. Chem. Phys. 55 (1971) 4715–4716.

Diffusion of tetrafluoro-methane (1); tris-nonafluorobutyl-amine (2) 1
Diffusion of tetrafluoro-methane (1); tris-nonafluorobutyl-

amine (2)
Vapor in Liquid

x1 p [kPa] D · 104 [m2/s]
0.01481 101.325 2.15
0.01481 101.325 2.15
Reference

Diffusion of methane (1); tris-nonafluorobutyl-amine (2) 1
Diffusion of methane (1); tris-nonafluorobutyl-amine (2)

Vapor in Liquid
CH4 (1) methane 74-82-8

x1 p [kPa] D · 104 [m2/s]
0.006883 101.325 3.14
0.006883 101.325 3.21
Reference

Diffusion of methane (1); tetradecanenitrile (2) 1
Diffusion of methane (1); tetradecanenitrile (2)

Vapor in Liquid
CH4 (1) methane 74-82-8

C14H27N (2) tetradecanenitrile 629-63-0
Intradiffusion Coefficient: D1T(T ); Method: NMR FG Ref.: 1997T1
T [K] p [MPa] D · 109 [m2/s]
325.1 150 2.95 ± 2%
355.1 150 4.11 ± 2%
387.1 150 5.59 ± 2%
422.1 150 7.35 ± 2%
Comment: mole fraction x2 = 0.66
Reference
1997T1 Tarassov, I.N., Wappmann, S., Lüdemann, H.-D.: Pol. J. Chem. 71 (1997) 1763–1776.

Diffusion of methane (1); tetradecane (2) 1
Diffusion of methane (1); tetradecane (2)

Vapor in Liquid
CH4 (1) methane 74-82-8

C14H30 (2) tetradecane 629-59-4
T [K] p [MPa] D · 108 [m2/s]
296.1 50 1.19 ± 2%
313.1 50 1.42 ± 2%
333.1 50 1.73 ± 2%
364.1 50 2.49 ± 2%
404.1 50 3.35 ± 2%
456.1 50 4.34 ± 2%
296.1 100 0.87 ± 2%
313.1 100 1.02 ± 2%
333.1 100 1.24 ± 2%
364.1 100 1.74 ± 2%
404.1 100 2.21 ± 2%
456.1 100 2.85 ± 2%
296.1 150 0.68 ± 2%
313.1 150 0.80 ± 2%
333.1 150 0.97 ± 2%
364.1 150 1.34 ± 2%
404.1 150 1.69 ± 2%
456.1 150 2.16 ± 2%
296.1 200 0.54 ± 2%
313.1 200 0.67 ± 2%
333.1 200 0.80 ± 2%
364.1 200 1.02 ± 2%
404.1 200 1.34 ± 2%
456.1 200 1.74 ± 2%
CH4 (1) methane 74-82-8

T [K] p [MPa] D · 109 [m2/s]
296.1 50 2.81 ± 2%
313.1 50 3.54 ± 2%
333.1 50 4.42 ± 2%
364.1 50 6.67 ± 2%
404.1 50 9.34 ± 2%
456.1 50 13.05 ± 2%
296.1 100 2.03 ± 2%
313.1 100 2.56 ± 2%
333.1 100 3.23 ± 2%
(continued)
2 Diffusion of methane (1); tetradecane (2)
364.1 100 4.81 ± 2%

404.1 100 6.38 ± 2%
456.1 100 8.81 ± 2%
296.1 150 1.68 ± 2%
313.1 150 2.02 ± 2%
333.1 150 2.52 ± 2%
364.1 150 3.70 ± 2%
404.1 150 4.98 ± 2%
456.1 150 6.46 ± 2%
296.1 200 1.28 ± 2%
313.1 200 1.67 ± 2%
333.1 200 1.99 ± 2%
364.1 200 2.79 ± 2%
404.1 200 3.74 ± 2%
456.1 200 5.19 ± 2%
CH4 (1) methane 74-82-8

T [K] p [MPa] D · 109 [m2/s]
294.5 50 5.89 ± 2%
313.1 50 7.10 ± 2%
333.1 50 8.94 ± 2%
363.1 50 11.71 ± 2%
403.1 50 15.67 ± 2%
455.1 50 22.15 ± 2%
294.5 100 4.23 ± 2%
313.1 100 5.23 ± 2%
333.1 100 6.41 ± 2%
363.1 100 8.47 ± 2%
403.1 100 11.31 ± 2%
455.1 100 15.47 ± 2%
294.5 150 3.16 ± 2%
313.1 150 4.23 ± 2%
333.1 150 4.96 ± 2%
363.1 150 6.59 ± 2%
455.1 150 12.13 ± 2%
CH4 (1) methane 74-82-8

T [K] p [MPa] D · 1010 [m2/s]
294.5 50 13.77 ± 2%
313.1 50 17.60 ± 2%
333.1 50 22.55 ± 2%
(continued)
363.1 50 30.76 ± 2%
403.1 50 42.67 ± 2%
455.1 50 62.10 ± 2%
294.5 100 9.94 ± 2%
313.1 100 12.97 ± 2%
363.1 100 21.14 ± 2%
403.1 100 29.21 ± 2%
455.1 100 42.43 ± 2%
294.5 150 7.25 ± 2%
313.1 150 9.83 ± 2%
333.1 150 11.97 ± 2%
363.1 150 16.46 ± 2%
455.1 150 31.38 ± 2%
CH4 (1) methane 74-82-8

T [K] p [MPa] D · 109 [m2/s]
295.5 50 3.84 ± 2%
313.1 50 4.86 ± 2%
333.1 50 6.14 ± 2%
363.1 50 8.59 ± 2%
403.5 50 12.43 ± 2%
453.1 50 16.89 ± 2%
295.5 100 2.68 ± 2%
313.1 100 3.33 ± 2%
333.1 100 4.53 ± 2%
363.1 100 6.30 ± 2%
403.5 100 9.03 ± 2%
453.1 100 12.41 ± 2%
295.5 150 1.95 ± 2%
313.1 150 2.54 ± 2%
333.1 150 3.39 ± 2%
363.1 150 4.78 ± 2%
403.5 150 7.34 ± 2%
453.1 150 9.86 ± 2%
304.1 200 3.74 ± 2%
333.1 200 2.74 ± 2%
363.1 200 3.89 ± 2%
403.5 200 5.63 ± 2%
453.1 200 8.06 ± 2%

4 Diffusion of methane (1); tetradecane (2)
CH4 (1) methane 74-82-8

T [K] p [MPa] D · 1010 [m2/s]
295.5 50 8.27 ± 2%
313.1 50 10.57 ± 2%
333.1 50 14.41 ± 2%
363.1 50 21.42 ± 2%
403.5 50 31.69 ± 2%
453.1 50 45.06 ± 2%
295.5 100 5.99 ± 2%
313.1 100 7.09 ± 2%
333.1 100 10.22 ± 2%
363.1 100 15.29 ± 2%
403.5 100 22.50 ± 2%
453.1 100 34.22 ± 2%
295.5 150 3.97 ± 2%
313.1 150 5.34 ± 2%
333.1 150 7.68 ± 2%
363.1 150 11.77 ± 2%
403.5 150 18.50 ± 2%
453.1 150 25.92 ± 2%
304.1 200 3.74 ± 2%
333.1 200 6.00 ± 2%
363.1 200 8.86 ± 2%
403.5 200 13.30 ± 2%
453.1 200 21.05 ± 2%
CH4 (1) methane 74-82-8

T [K] p [MPa] D · 109 [m2/s]
293.1 50 3.37 ± 2%
325.1 50 5.22 ± 2%
355.1 50 7.34 ± 2%
387.1 50 9.95 ± 2%
422.1 50 12.71 ± 2%
453.1 50 15.76 ± 2%
293.1 100 2.37 ± 2%
325.1 100 3.71 ± 2%
355.1 100 5.33 ± 2%
387.1 100 7.25 ± 2%
422.1 100 9.38 ± 2%
453.1 100 11.21 ± 2%
325.1 150 2.95 ± 2%
355.1 150 4.11 ± 2%
(continued)

387.1 150 5.59 ± 2%

422.1 150 7.35 ± 2%
CH4 (1) methane 74-82-8

T [K] p [MPa] D · 1010 [m2/s]
293.1 50 7.18 ± 2%
325.1 50 12.10 ± 2%
355.1 50 17.32 ± 2%
387.1 50 24.30 ± 2%
422.1 50 33.29 ± 2%
453.1 50 41.22 ± 2%
293.1 100 4.94 ± 2%
325.1 100 8.65 ± 2%
355.1 100 12.54 ± 2%
387.1 100 19.51 ± 2%
422.1 100 23.14 ± 2%
453.1 100 28.74 ± 2%
325.1 150 7.24 ± 2%
355.1 150 9.27 ± 2%
387.1 150 14.09 ± 2%
422.1 150 18.54 ± 2%
Reference
1997T1 Tarassov, I.N., Wappmann, S., Lüdemann, H.-D.: Pol. J. Chem. 71 (1997) 1763–1776.

Diffusion of carbondioxide (1); heptane (2) 1
Diffusion of carbondioxide (1); heptane (2)

Vapor in Liquid

C7H16 (2) heptane 142-82-5
Mutual Diffusion Coefficient: D12(xi); T = (283.05 ± 0.1) K; Method: DLS Ref.: 1984S5
x1 p [MPa] D · 109 [m2/s]
0.30 ± 0.01 1.72 4.74 ± 0.20*
0.53 ± 0.01 2.67 4.28 ± 0.05
0.60 ± 0.01 2.98 4.06 ± 0.05
0.69 ± 0.01 3.29 3.70 ± 0.05
0.74 ± 0.01 3.56 3.47 ± 0.05
0.84 ± 0.01 3.75 3.62 ± 0.05
0.89 ± 0.01 4.07 4.89 ± 0.10*
Comment: *: T = 283.15 K

C7H16 (2) heptane 142-82-5
x1 p [MPa] D · 109 [m2/s]
0.30 ± 0.01 1.90 5.63 ± 0.15*
0.53 ± 0.01 3.04 5.00 ± 0.05
0.60 ± 0.01 3.48 4.62 ± 0.05
0.69 ± 0.01 3.87 4.39 ± 0.05
0.74 ± 0.01 4.29 4.13 ± 0.05
0.84 ± 0.01 4.66 4.45 ± 0.05
0.89 ± 0.01 5.03 5.46 ± 0.10
Comment: *: T = 293.05 K

C7H16 (2) heptane 142-82-5
x1 p [MPa] D · 109 [m2/s]
0.30 ± 0.01 2.13 6.61 ± 0.13*
0.53 ± 0.01 3.42 5.73 ± 0.05
0.60 ± 0.01 4.01 5.39 ± 0.05
0.69 ± 0.01 4.46 5.19 ± 0.05
0.74 ± 0.01 5.06 4.77 ± 0.05**
0.84 ± 0.01 5.69 5.12 ± 0.05
0.89 ± 0.01 6.24 6.16 ± 0.10***
Comment: *: T = 303.05 K; **: T = 302.15 K; ***: T = 302.65 K

2 Diffusion of carbondioxide (1); heptane (2)

C7H16 (2) heptane 142-82-5
x1 p [MPa] D · 109 [m2/s]
0.30 ± 0.01 2.34 6.65 ± 0.30
0.53 ± 0.01 3.77 6.53 ± 0.05
0.60 ± 0.01 4.55 6.17 ± 0.05
0.69 ±0.01 5.06 5.90 ± 0.05
0.74 ± 0.01 5.87 5.40 ± 0.05
0.84 ± 0.01 6.85 5.60 ± 0.05
0.89 ± 0.01 7.31 5.92 ± 0.20

C7H16 (2) heptane 142-82-5
x1 p [MPa] D · 109 [m2/s]
0.30 ± 0.01 2.56 7.72 ± 0.13
0.53 ± 0.01 4.07 7.30 ± 0.05
0.60 ± 0.01 5.05 6.96 ± 0.05
0.69 ± 0.01 5.59 6.60 ± 0.10*
0.74 ± 0.01 6.60 6.14 ± 0.10*
Comment: *: T = 323.25 K
Reference
1984S5 Saad, H., Gulari, E.: J. Phys. Chem. 88 (1984) 136–139.

Diffusion of deuterium (1); tris-nonafluorobutyl-amine (2) 1
Diffusion of deuterium (1); tris-nonafluorobutyl-amine (2)

Vapor in Liquid
D2 (1) deuterium 7782-39-0

x1 p [kPa] D · 104 [m2/s]
0.001603 101.325 6.65
0.001603 101.325 6.61
Reference

Diffusion of hydrogen (1); tris-nonafluorobutyl-amine (2) 1
Diffusion of hydrogen (1); tris-nonafluorobutyl-amine (2)

Vapor in Liquid
H2 (1) hydrogen 1333-74-0

x1 p [kPa] D · 104 [m2/s]
0.001552 101.325 8.21
0.001552 101.325 8.30
Reference

Diffusion of ammonia (1); trimethylamine (2) 1
Diffusion of ammonia (1); trimethylamine (2)

Vapor in Liquid
H 3N (1) ammonia 7664-41-7

C3H9N (2) trimethylamine 75-50-3
Intradiffusion Coefficient: D1T(T ); Method: NMR FG Ref.: 1999C1
T [K] p [MPa] D · 109 [m2/s]
425 ± 0.5 10 68.6 ± 5%
373 ± 0.5 10 30.2 ± 5%
334 ± 0.5 10 19.6 ± 5%
299 ± 0.5 10 12.9 ± 5%
273 ± 0.5 10 9.07 ± 5%
242 ± 0.5 10 5.57 ± 5%
212 ± 0.5 10 2.99 ± 5%
425 ± 0.5 20 44.3 ± 5%
373 ± 0.5 20 26.8 ± 5%
334 ± 0.5 20 17.8 ± 5%
299 ± 0.5 20 12.0 ± 5%
425 ± 0.5 50 29.9 ± 5%
373 ± 0.5 50 20.5 ± 5%
334 ± 0.5 50 14.3 ± 5%
299 ± 0.5 50 10.2 ± 5%
273 ± 0.5 50 7.24 ± 5%
242 ± 0.5 50 4.45 ± 5%
212 ± 0.5 50 2.37 ± 5%
425 ± 0.5 100 22.1 ± 5%
373 ± 0.5 100 15.5 ± 5%
334 ± 0.5 100 11.3 ± 5%
299 ± 0.5 100 8.00 ± 5%
273 ± 0.5 100 5.89 ± 5%
242 ± 0.5 100 3.51 ± 5%
212 ± 0.5 100 1.86 ± 5%
425 ± 0.5 150 17.5 ± 5%
373 ± 0.5 150 12.7 ± 5%
334 ± 0.5 150 9.25 ± 5%
299 ± 0.5 150 6.59 ± 5%
273 ± 0.5 150 4.87 ± 5%
242 ± 0.5 150 2.85 ± 5%
212 ± 0.5 150 1.47 ± 5%
425 ± 0.5 200 15.1 ± 5%
373 ± 0.5 200 10.9 ± 5%
334 ± 0.5 200 7.96 ± 5%
299 ± 0.5 200 5.59 ± 5%
273 ± 0.5 200 4.11 ± 5%
242 ± 0.5 200 2.35 ± 5%
212 ± 0.5 200 1.22 ± 5%

2 Diffusion of ammonia (1); trimethylamine (2)
H 3N (1) ammonia 7664-41-7

C3H9N (2) trimethylamine 75-50-3
Intradiffusion Coefficient: D2T(T ); Method: NMR FG Ref.: 1999C1
T [K] p [MPa] D · 109 [m2/s]
373 ± 0.5 10 17.6 ± 5%
334 ± 0.5 10 11.5 ± 5%
299 ± 0.5 10 7.38 ± 5%
273 ± 0.5 10 5.26 ± 5%
242 ± 0.5 10 3.26 ± 5%
212 ± 0.5 10 1.81 ± 5%
425 ± 0.5 20 25.0 ± 5%
373 ± 0.5 20 15.3 ± 5%
334 ± 0.5 20 10.3 ± 5%
299 ± 0.5 20 6.84 ± 5%
425 ± 0.5 50 16.6 ± 5%
373 ± 0.5 50 11.6 ± 5%
334 ± 0.5 50 8.05 ± 5%
299 ± 0.5 50 5.57 ± 5%
273 ± 0.5 50 4.04 ± 5%
242 ± 0.5 50 2.50 ± 5%
212 ± 0.5 50 1.34 ± 5%
425 ± 0.5 100 12.3 ± 5%
373 ± 0.5 100 8.61 ± 5%
334 ± 0.5 100 6.18 ± 5%
299 ± 0.5 100 4.34 ± 5%
273 ± 0.5 100 3.12 ± 5%
242 ± 0.5 100 1.89 ± 5%
212 ± 0.5 100 1.04 ± 5%
425 ± 0.5 150 9.84 ± 5%
373 ± 0.5 150 6.95 ± 5%
334 ± 0.5 150 4.98 ± 5%
299 ± 0.5 150 3.52 ± 5%
273 ±0.5 150 2.50 ± 5%
242 ± 0.5 150 1.51 ± 5%
212 ± 0.5 150 0.786 ± 5%
425 ± 0.5 200 8.29 ± 5%
373 ± 0.5 200 5.82 ± 5%
334 ± 0.5 200 4.19 ± 5%
299 ± 0.5 200 2.92 ± 5%
273 ± 0.5 200 2.06 ± 5%
242 ± 0.5 200 1.21 ± 5%
212 ± 0.5 200 0.619 ± 5%
Reference
1999C1 Chen, L., Gross, T., Lüdemann, H.-D.: Phys. Chem. Chem. Phys. 1 (1999) 3503–3508.

Diffusion of helium (1); tris-nonafluorobutyl-amine (2) 1
Diffusion of helium (1); tris-nonafluorobutyl-amine (2)

Vapor in Liquid
He (1) helium 7440-59-7

x1 p [kPa] D · 104 [m2/s]
0.001167 101.325 13.76
0.001167 101.325 13.81
Reference

Diffusion of helium-3 (1); tris-nonafluorobutyl-amine (2) 1
Diffusion of helium-3 (1); tris-nonafluorobutyl-amine (2)

Vapor in Liquid
He-3 (1) helium-3 4762-55-1

x1 p [kPa] D · 104 [m2/s]
0.001102 101.325 14.23
0.001102 101.325 14.41
Reference

Diffusion of krypton (1); tris-nonafluorobutyl-amine (2) 1
Diffusion of krypton (1); tris-nonafluorobutyl-amine (2)

Vapor in Liquid
Kr (1) krypton 7439-90-9

x1 p [kPa] D · 104 [m2/s]
0.01115 101.325 2.93
0.01115 101.325 2.92
Reference

Diffusion of dinitrogen tetraoxide (1); nitricacid (2) 1
Diffusion of dinitrogen tetraoxide (1); nitricacid (2)

Vapor in Liquid
N2O4 (1) dinitrogen tetraoxide 10544-72-6

HNO3 (2) nitric acid 7697-37-2
Mutual Diffusion Coefficient: D12(xi); T = (373.15 ± 1.0) K; Method: NMR FG Ref.: 1988I1
x2 p [kPa] D · 109 [m2/s]
0.0325 101.325 10.0 ± 5%
6854 101.325 3.70 ± 5%
0.8536 101.325 3.88 ± 5%
1.00 101.325 4.02 ± 5%

x2 p [kPa] D · 109 [m2/s]
0.0325 101.325 7.72 ± 5%
0.6854 101.325 2.75 ± 5%
0.8536 101.325 2.95 ± 5%
1.00 101.325 3.15 ± 5%

x2 p [kPa] D · 109 [m2/s]
0.0325 101.325 6.01 ± 5%
0.6854 101.325 1.93 ± 5%
0.8536 101.325 2.26 ± 5%
1.00 101.325 2.36 ± 5%

x2 p [kPa] D · 109 [m2/s]
0.0325 101.325 4.55 ± 5%
0.6854 101.325 1.33 ± 5%
0.8536 101.325 1.62 ± 5%
1.00 101.325 1.70 ± 5%

2 Diffusion of dinitrogen tetraoxide (1); nitricacid (2)

x2 p [kPa] D · 109 [m2/s]
0.0325 101.325 3.72 ± 5%
0.6854 101.325 0.92 ± 5%
0.8536 101.325 1.23 ± 5%
1.00 101.325 1.30 ± 5%
Reference
1988I1 Idiyatullin, Z.S., Razinov, A.I.: Vestsi Akad. Navuk BSSR, Ser. Fiz.-Energ. Navuk (1988) 87–90.

Diffusion of neon (1); tris-nonafluorobutyl-amine (2) 1
Diffusion of neon (1); tris-nonafluorobutyl-amine (2)

Vapor in Liquid
Ne (1) neon 7440-01-9

x1 p [kPa] D · 104 [m2/s]
0.001679 101.325 6.34
0.001679 101.325 6.37
Reference

Diffusion of oxygen (1); quinoline (2) 1
Diffusion of oxygen (1); quinoline (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

C9H7N (2) quinoline 91-22-5
Mutual Diffusion Coefficient: D12(ci); T = (298.15 ± 1.0) K; Method: EA RDE Ref.: 1999W1
c1 [mol/l] p [kPa] D · 109 [m2/s]
0.00149 ± 0.00013 101.325 1.71 ± 0.21
Comment: solution containing 0.1 M tetra(n-butyl)ammonium perchlorate as supporting electrolyte
Reference
1999W1 Wu, J.F., Che, Y., Okajima, T., Matsumoto, F., Tokuda, K., Ohsaka, T.: Anal. Chem. 71 (1999)
4056–4060.

Diffusion of oxygen (1); isoquinoline (2) 1
Diffusion of oxygen (1); isoquinoline (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

C9H7N (2) isoquinoline 119-65-3
c1 [mol/l] p [kPa] D · 109 [m2/s]
0.00120 ± 0.00013 101.325 0.81 ± 0.05
Reference
4056–4060.

Diffusion of oxygen (1); 2-methyl-quinoline (2) 1
Diffusion of oxygen (1); 2-methyl-quinoline (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

C10H9N (2) 2-methyl-quinoline 91-63-4
c1 [mol/l] p [kPa] D · 109 [m2/s]
0.00652 ± 0.00039 101.325 0.11 ± 0.05
Reference
4056–4060.


Vapor in Liquid
O2 (1) oxygen 7782-44-7

c1 [mol/l] p [kPa] D · 109 [m2/s]
0.00510 ± 0.00056 101.325 0.28 ± 0.04
Reference
4056–4060.


Vapor in Liquid
O2 (1) oxygen 7782-44-7

c1 [mol/l] p [kPa] D · 109 [m2/s]
0.0106 ± 0.00060 101.325 0.097 ± 0.007
Reference
4056–4060.


Vapor in Liquid
O2 (1) oxygen 7782-44-7

c1 [mol/l] p [kPa] D · 109 [m2/s]
0.00460 ± 0.00013 101.325 0.20 ± 0.02
Reference
4056–4060.


Vapor in Liquid
O2 (1) oxygen 7782-44-7

c1 [mol/l] p [kPa] D · 109 [m2/s]
0.00435 ± 0.00024 101.325 0.31 ± 0.05
Reference
4056–4060.


Vapor in Liquid
O2 (1) oxygen 7782-44-7

c1 [mol/l] p [kPa] D · 109 [m2/s]
0.00340 ± 0.00028 101.325 0.98 ± 0.19
Reference
4056–4060.


Mixtures at infinite solution
Ar (1) argon 7440-37-1

CH4 (2) methane 74-82-8
Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TB Ref.: 1987D4
T [K] Type D · 104 [m2/s]
200.0 D01(2) 0.1031 ± 0.3%
230.0 D01(2) 0.1348 ± 0.3%
260.0 D01(2) 0.1692 ± 0.3%
280.0 D01(2) 0.1912 ± 0.3%
290.0 D01(2) 0.2052 ± 0.3%
300.0 D01(2) 0.2195 ± 0.3%
310.0 D01(2) 0.2346 ± 0.3%
320.0 D01(2) 0.2428 ± 0.3%
360.0 D01(2) 0.3050 ± 0.3%
380.0 D01(2) 0.3357 ± 0.3%
400.0 D01(2) 0.3676 ± 0.3%
Ar (1) argon 7440-37-1

CH4 (2) methane 74-82-8
Diffusion Coefficient at infinite dilution: D01(2) (T ); Method: TB Ref.: 1982T7
–3.2510 3.7440 1.5525 0.05%
Comment: D01(2) [m2/s] = D · 10–4
Ar (1) argon 7440-37-1

CH4 (2) methane 74-82-8
Diffusion Coefficient at infinite dilution: D01(2) (T ); Method: TB Ref.: 1987D4
Equation: D = A + B · T + C · T2 + E · T3 Range: 200 < T/K < 400
Parameter: A · 102 B · 104 C · 106 E · 1010 Std-Dev
–3.559 3.8246 1.5474 0.434 0.06%
Comment: D01(2) [m2/s] = D · 10–4
References


Ar (1) argon 7440-37-1

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TB Ref.: 1974L12
T [K] Type D · 104 [m2/s]
175.3 D02(1) 0.0554 ± 0.9%
203.4 D02(1) 0.0739 ± 0.9%
233.1 D02(1) 0.0968 ± 0.9%
263.2 D02(1) 0.123 ± 0.9%
296.0 D02(1) 0.156 ± 0.9%
418.2 D02(1) 0.292 ± 0.9%
181.2 D02(1) 0.380 ± 0.9%
587.2 D02(1) 0.534 ± 0.9%
670.8 D02(1) 0.669 ± 0.9%
775.8 D02(1) 0.865 ± 0.9%
Comment: trace component concentration 2.5%
Ar (1) argon 7440-37-1

Diffusion Coefficient at infinite dilution: D01(2) (T ); Method: CT Ref.: 1984R3
–2.4447 1.7934 –1.5545 0.08%
References
1974L12 Loiko, A.E., Ivakin, B.S., Suetin, P.E.: Sov. Phys. Tech. Phys. 19 (1974) 434.


Ar (1) argon 7440-37-1

H2 (2) hydrogen 1333-74-0
T [K] Type D · 104 [m2/s]
200.0 D01(2) 0.4033 ± 0.3%
230.0 D01(2) 0.5155 ± 0.3%
260.0 D01(2) 0.6408 ± 0.3%
277.8 D01(2) 0.7197 ± 0.3%
280.0 D01(2) 0.7312 ± 0.3%
281.3 D01(2) 0.7368 ± 0.3%
285.2 D01(2) 0.7536 ± 0.3%
288.9 D01(2) 0.7701 ± 0.3%
293.2 D01(2) 0.7903 ± 0.3%
300.0 D01(2) 0.8240 ± 0.3%
301.5 D01(2) 0.8298 ± 0.3%
305.2 D01(2) 0.8483 ± 0.3%
309.2 D01(2) 0.8687 ± 0.3%
310.0 D01(2) 0.8696 ± 0.3%
313.5 D01(2) 0.8894 ± 0.3%
318.2 D01(2) 0.9129 ± 0.3%
323.0 D01(2) 0.9375 ± 0.3%
340.0 D01(2) 1.0221 ± 0.3%
Ar (1) argon 7440-37-1

H2 (2) hydrogen 1333-74-0
Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: CT Ref.: 1987D3
T [K] Type D · 104 [m2/s]
240.0 D01(2) 0.5562 ± 0.3%
250.0 D01(2) 0.5978 ± 0.3%
260.0 D01(2) 0.6406 ± 0.3%
270.0 D01(2) 0.6847 ± 0.3%
280.0 D01(2) 0.7299 ± 0.3%
290.0 D01(2) 0.7762 ± 0.3%
300.0 D01(2) 0.8236 ± 0.3%
310.0 D01(2) 0.8719 ± 0.3%
320.0 D01(2) 0.9242 ± 0.3%
References
1987D7 Dunlop, P.J., Robjohns, H.L., Bignell, C.M.: J. Chem. Phys. 86 (1987) 2922–2926.
1987D3 Dunlop, P.J.: Physica A 145 (1987) 597–598.


Ar (1) argon 7440-37-1

H 3N (2) ammonia 7664-41-7
T [K] Type D · 104 [m2/s]
280.0 ± 0.002 D01(2) 0.2017 ± 0.3%
290.0 ± 0.002 D01(2) 0.2154 ± 0.3%
300.0 ± 0.002 D01(2) 0.2288 ± 0.3%
310.0 ± 0.002 D01(2) 0.2447 ± 0.3%
320.0 ± 0.002 D01(2) 0.2590 ± 0.3%
340.0 ± 0.002 D01(2) 0.2902 ± 0.3%
360.0 ± 0.002 D01(2) 0.3205 ± 0.3%
380.0 ± 0.002 D01(2) 0.3532 ± 0.3%
400.0 ± 0.002 D01(2) 0.3872 ± 0.3%
Ar (1) argon 7440-37-1

H 3N (2) ammonia 7664-41-7
–0.8384 0.6491 1.3200 0.13%
Comment: D01(2) [m2/s] = D · 10–4
Reference


Ar (1) argon 7440-37-1

N2 (2) nitrogen 7727-37-9
Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TB Ref.: 1985T5
T [K] Type D · 104 [m2/s]
195.10 ± 0.002 D02(1) 0.0928
205.20 ± 0.002 D02(1) 0.1020
218.07 ± 0.002 D02(1) 0.1143
237.05 ± 0.002 D02(1) 0.1333
252.69 ± 0.002 D02(1) 0.1496
280.00 ± 0.002 D02(1) 0.1793
290.00 ± 0.002 D02(1) 0.1912
300.00 ± 0.002 D02(1) 0.2033
310.00 ± 0.002 D02(1) 0.2156
320.00 ± 0.002 D02(1) 0.2280
356.07 ± 0.002 D02(1) 0.2758
373.09 ± 0.002 D02(1) 0.2988
385.49 ± 0.002 D02(1) 0.3164
400.21 ± 0.002 D02(1) 0.3381
Comment: see Erratum [1987T3]: new measurements due to minor calibration problems
Ar (1) argon 7440-37-1

N2 (2) nitrogen 7727-37-9
T [K] Type D · 104 [m2/s]
200.0 ± 0.002 D02(1) 0.09742
230.0 ± 0.002 D02(1) 0.1257
260.0 ± 0.002 D02(1) 0.1575
280.0 ± 0.002 D02(1) 0.1793
290.0 ± 0.002 D02(1) 0.1912
300.0 ± 0.002 D02(1) 0.2033
310.0 ± 0.002 D02(1) 0.2156
320.0 ± 0.002 D02(1) 0.2280
360.0 ± 0.002 D02(1) 0.2805
380.0 ± 0.002 D02(1) 0.3080
400.0 ± 0.002 D02(1) 0.3365
Comment: new measurements due to minor calibration problems (Erratum for [1985T5])

Ar (1) argon 7440-37-1

N2 (2) nitrogen 7727-37-9
–8.6126 7.1359 0.8375 0.06%
Comment: D01(2) [m2/s] = D · 10–4
Ar (1) argon 7440-37-1

N2 (2) nitrogen 7727-37-9
–0.212 0.0029 0.2653 –1.427 0.04%
Comment: D02(1) [m2/s] = D · 10–4
References
1985T5 Trengove, R.D., Harris, K.R., Robjohns, H.L., Dunlop, P.J.: Physica A 131 (1985) 506–519.


Ar (1) argon 7440-37-1

O2 (2) oxygen 7782-44-7
T [K] Type D · 104 [m2/s]
195.10 ± 0.002 D02(1) 0.0922
205.20 ± 0.002 D02(1) 0.1015
218.07 ± 0.002 D02(1) 0.1137
234.22 ± 0.002 D02(1) 0.1297
246.00 ± 0.002 D02(1) 0.1421
264.85 ± 0.002 D02(1) 0.1627
280.00 ± 0.002 D02(1) 0.1794
290.00 ± 0.002 D02(1) 0.1914
300.00 ± 0.002 D02(1) 0.2035
310.00 ± 0.002 D02(1) 0.2160
320.00 ± 0.002 D02(1) 0.2287
333.15 ± 0.002 D02(1) 0.2461
343.15 ± 0.002 D02(1) 0.2589
353.22 ± 0.002 D02(1) 0.2725
373.09 ± 0.002 D02(1) 0.3006
385.49 ± 0.002 D02(1) 0.3181
400.21 ± 0.002 D02(1) 0.3398
Ar (1) argon 7440-37-1

O2 (2) oxygen 7782-44-7
T [K] Type D · 104 [m2/s]
200.0 ± 0.002 D02(1) 0.09658
230.0 ± 0.002 D02(1) 0.1253
260.0 ± 0.002 D02(1) 0.1572
280.0 ± 0.002 D02(1) 0.1794
290.0 ± 0.002 D02(1) 0.1914
300.0 ± 0.002 D02(1) 0.2035
310.0 ± 0.002 D02(1) 0.2160
320.0 ± 0.002 D02(1) 0.2287
360.0 ± 0.002 D02(1) 0.2816
380.0 ± 0.002 D02(1) 0.3096
400.0 ± 0.002 D02(1) 0.3388

2 Diffusion of argon (1); oxygen (2)
Ar (1) argon 7440-37-1

O2 (2) oxygen 7782-44-7
–0.5029 0.4609 0.1284 0.04%
Comment: D01(2) [m2/s] = D · 10–4; precision: ±0.1%
Ar (1) argon 7440-37-1

O2 (2) oxygen 7782-44-7
2 3 6 9
–0.784 0.0951 0.2342 –1.033 0.04%
Comment: D02(1) [m2/s] = D · 10–4; Erratum [1987T3]: due to minor calibration problems data are replaced
References


Ar (1) argon 7440-37-1

Xe (2) xenon 7440-63-3
T [K] Type D · 104 [m2/s]
128.0 D02(1) 0.0219 ± 0.9%
163.4 D02(1) 0.0361 ± 0.9%
203.1 D02(1) 0.0541 ± 0.9%
243.4 D02(1) 0.0773 ± 0.9%
290.3 D02(1) 0.107 ± 0.9%
384.4 D02(1) 0.182 ± 0.9%
483.5 D02(1) 0.277 ± 0.9%
578.7 D02(1) 0.384 ± 0.9%
673.7 D02(1) 0.502 ± 0.9%
764.9 D02(1) 0.631 ± 0.9%
Ar (1) argon 7440-37-1

Xe (2) xenon 7440-63-3
T [K] Type D · 104 [m2/s]
163.4 D01(2) 0.0359 ± 0.9%
290.3 D01(2) 0.107 ± 0.9%
764.9 D01(2) 0.640 ± 0.9%
Reference


CH4 (1) methane 74-82-8

He (2) helium 7440-59-7
T [K] Type D · 104 [m2/s]
200.0 D01(2) 0.3461 ± 0.3%
230.0 D01(2) 0.4372 ± 0.3%
260.0 D01(2) 0.5367 ± 0.3%
280.0 D01(2) 0.6065 ± 0.3%
290.0 D01(2) 0.6427 ± 0.3%
300.0 D01(2) 0.6799 ± 0.3%
310.0 D01(2) 0.7182 ± 0.3%
320.0 D01(2) 0.7576 ± 0.3%
360.0 D01(2) 0.9208 ± 0.3%
380.0 D01(2) 1.0074 ± 0.3%
400.0 D01(2) 1.0986 ± 0.3%
CH4 (1) methane 74-82-8

He (2) helium 7440-59-7
–7.417 12.843 4.0480 1.731 0.04%
0 2 –4
Comment: D 1(2) [m /s] = D · 10
Reference

Diffusion of methane (1); octane (2) 1
Diffusion of methane (1); octane (2)

CH4 (1) methane 74-82-8

C8H18 (2) octane 111-65-9
Diffusion Coefficient at infinite dilution: p = 1.72 MPa; Method: TAYLOR Ref.: 1989E6
T [K] Type D · 109 [m2/s]
304 D01(2) 6.67 ± 0.01
333 D01(2) 9.52
335 D01(2) 9.75 ± 0.01
361 D01(2) 12.71 ± 0.06
373 D01(2) 14.25
387 D01(2) 16.29 ± 0.05
403 D01(2) 18.41
411 D01(2) 19.75 ± 0.10
435 D01(2) 24.04 ± 0.21
Reference
1989E6 Erkey, C., Akgerman, A.: AIChE J. 35 (1989) 443–448.

Diffusion of carbon monoxide (1); eicosane (2) 1
Diffusion of carbon monoxide (1); eicosane (2)


C20H42 (2) eicosane 112-95-8
Diffusion Coefficient at infinite dilution: p = 200 psia; Method: TAYLOR Ref.: 1988R6
T [K] Type D · 109 [m2/s]
374.25 D01(2) 6.04 ± 0.07
412.45 D01(2) 8.95 ± 0.18
449.75 D01(2) 12.23 ± 0.05
494.75 D01(2) 17.36 ± 0.35
533.45 D01(2) 23.24 ± 0.76
Reference
1988R6 Rodden, J.B., Erkey, C., Akgerman, A.: J. Chem. Eng. Data 33 (1988) 344–347.

Diffusion of carbon dioxide (1); eicosane (2) 1
Diffusion of carbon dioxide (1); eicosane (2)


C20H42 (2) eicosane 112-95-8
T [K] Type D · 109 [m2/s]
374.25 D01(2) 5.41 ± 0.03
412.45 D01(2) 8.05 ± 0.25
449.75 D01(2) 10.74 ± 0.06
494.75 D01(2) 15.19 ± 0.20
533.45 D01(2) 20.02 ± 0.27
Reference

Diffusion of chloro-ethene (1); water (2) 1
Diffusion of chloro-ethene (1); water (2)

C2H3Cl (1) chloro-ethene 75-01-4

H 2O (2) water 7732-18-5
Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: OEC Ref.: 1974H1
T [K] Type D · 109 [m2/s]
298.15 D01(2) 1.34 ± 4%
323.15 D01(2) 2.42 ± 4%
348.15 D01(2) 3.67 ± 4%
Reference
1974H1 Hayduk, W., Laudie, H.: AIChE J. 20 (1974) 611–615.

Diffusion of ethene (1); cyclohexane (2) 1
Diffusion of ethene (1); cyclohexane (2)

C2H4 (1) ethene 74-85-1

C6H12 (2) cyclohexane 110-82-7
Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TAYLOR Ref.: 1985C12
T [K] Type D · 109 [m2/s]
280.5 D01(2) 2.35 ± 0.01
298.2 D01(2) 3.20 ± 0.03
323.2 D01(2) 4.67 ± 0.09
343.2 D01(2) 6.08 ± 0.06
363.2 D01(2) 7.89 ± 0.07
Reference
1985C12 Chen, H.C., Chen, S.H.: Chem. Eng. Science 40 (1985) 521–526.

Diffusion of ethane (1); cyclohexane (2) 1
Diffusion of ethane (1); cyclohexane (2)

C2H6 (1) ethane 74-84-0

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TAYLOR Ref.: 1985C12
T [K] Type D · 109 [m2/s]
280.5 D01(2) 2.13 ± 0.01
298.2 D01(2) 2.92 ± 0.01
323.2 D01(2) 4.48 ± 0.02
343.2 D01(2) 5.66 ± 0.02
363.2 D01(2) 7.27 ± 0.05
Reference
1985C12 Chen, H.C., Chen, S.H.: Chem. Eng. Science 40 (1985) 521–526.

Diffusion of ethane (1); octane (2) 1
Diffusion of ethane (1); octane (2)

C2H6 (1) ethane 74-84-0

C8H18 (2) octane 111-65-9
T [K] Type D · 109 [m2/s]
304 D01(2) 4.89 ± 0.02
335 D01(2) 7.14 ± 0.01
361 D01(2) 9.23 ± 0.11
387 D01(2) 12.00 ± 0.08
411 D01(2) 14.77 ± 0.04
435 D01(2) 17.97 ± 0.12
Reference

Diffusion of propane (1); hexadecane (2) 1
Diffusion of propane (1); hexadecane (2)

C3H8 (1) propane 74-98-6

T [K] Type D · 109 [m2/s]
298.15 ± 0.01 D01(2) 1.48 ± 0.02
Reference
1973H5 Hayduk, W., Castaneda, R., Bromfield, H., Perras, R.R.: AIChE J. 19 (1973) 859–861.

Diffusion of propane (1); butan-1-ol (2) 1
Diffusion of propane (1); butan-1-ol (2)

C3H8 (1) propane 74-98-6

C4H10O (2) butan-1-ol 71-36-3
T [K] Type D · 109 [m2/s]
273.15 ± 0.01 D01(2) 1.02 ± 0.01
298.15 ± 0.01 D01(2) 1.57 ± 0.04
323.15 ± 0.01 D01(2) 2.17 ± 0.08
Reference

Diffusion of propane (1); hexane (2) 1
Diffusion of propane (1); hexane (2)

C3H8 (1) propane 74-98-6

C6H14 (2) hexane 110-54-3
T [K] Type D · 109 [m2/s]
298.15 ± 0.01 D01(2) 4.87 ± 0.20
Reference

Diffusion of propane (1); chlorobenzene (2) 1
Diffusion of propane (1); chlorobenzene (2)

C3H8 (1) propane 74-98-6

C6H5Cl (2) chlorobenzene 108-90-7
T [K] Type D · 109 [m2/s]
273.15 ± 0.01 D01(2) 2.08 ± 0.01
298.15 ± 0.01 D01(2) 2.77 ± 0.09
323.15 ± 0.01 D01(2) 3.35 ± 0.10
Reference

Diffusion of propane (1); heptane (2) 1
Diffusion of propane (1); heptane (2)

C3H8 (1) propane 74-98-6

C7H16 (2) heptane 142-82-5
T [K] Type D · 109 [m2/s]
298.15 ± 0.01 D01(2) 4.40 ± 0.08
Reference

Diffusion of propane (1); octane (2) 1
Diffusion of propane (1); octane (2)

C3H8 (1) propane 74-98-6

C8H18 (2) octane 111-65-9
T [K] Type D · 109 [m2/s]
298.15 ± 0.01 D01(2) 3.83 ± 0.17
C3H8 (1) propane 74-98-6

C8H18 (2) octane 111-65-9
T [K] Type D · 109 [m2/s]
304 D01(2) 4.00 ± 0.04
335 D01(2) 5.92 ± 0.00
361 D01(2) 7.79 ± 0.01
387 D01(2) 10.01 ± 0.03
411 D01(2) 12.32 ± 0.07
435 D01(2) 15.16 ± 0.10
References


D2 (1) deuterium 7782-39-0

T [K] Type D · 104 [m2/s]
174.4 D01(2) 0.176 ± 0.9%
293.8 D01(2) 0.474 ± 0.9%
488.2 D01(2) 1.19 ± 0.9%
D2 (1) deuterium 7782-39-0

T [K] Type D · 104 [m2/s]
174.4 D02(1) 0.174 ± 0.9%
203.2 D02(1) 0.231 ± 0.9%
233.2 D02(1) 0.301 ± 0.9%
263.2 D02(1) 0.376 ± 0.9%
293.8 D02(1) 0.467 ± 0.9%
415.6 D02(1) 0.880 ± 0.9%
488.2 D02(1) 1.18 ± 0.9%
581.2 D02(1) 1.60 ± 0.9%
Reference



Ar (2) argon 7440-37-1
Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: CT Ref.: 1984T5
T [K] Type D · 104 [m2/s]
280 ± 0.001 D01(2) 0.0752
300 ± 0.001 D01(2) 0.0859
320 ± 0.001 D01(2) 0.0972

Ar (2) argon 7440-37-1
Diffusion Coefficient at infinite dilution: D01(2) (T ); Method: CT Ref.: 1984T5
–0.3714 0.4612 0.8416 0.06%
Reference



He (2) helium 7440-59-7
T [K] Type D · 104 [m2/s]
280 ± 0.001 D01(2) 0.3469
290 ± 0.001 D01(2) 0.3680
300 ± 0.001 D01(2) 0.3894
320 ± 0.001 D01(2) 0.4331

He (2) helium 7440-59-7
–12.4536 12.6897 1.4807 0.04%
Reference

Diffusion of sulfur hexafluoride (1); krypton (2) 1
Diffusion of sulfur hexafluoride (1); krypton (2)


Kr (2) krypton 7439-90-9
T [K] Type D · 104 [m2/s]
280 ± 0.001 D01(2) 0.0524
300 ± 0.001 D01(2) 0.0597
320 ± 0.001 D01(2) 0.0675

Kr (2) krypton 7439-90-9
–0.6505 0.6252 0.5276 0.06%
Reference

Diffusion of sulfur hexafluoride (1); neon (2) 1
Diffusion of sulfur hexafluoride (1); neon (2)


Ne (2) neon 7440-01-9
T [K] Type D · 104 [m2/s]
280 ± 0.001 D01(2) 0.1394
300 ± 0.001 D01(2) 0.1572
320 ± 0.001 D01(2) 0.1756

Ne (2) neon 7440-01-9
–2.1936 2.9142 1.0182 0.03%
Reference

Diffusion of sulfur hexafluoride (1); xenon (2) 1
Diffusion of sulfur hexafluoride (1); xenon (2)


Xe (2) xenon 7440-63-3
–2.3356 1.7272 0.2053 0.08%
Reference


H2 (1) hydrogen 1333-74-0

Ar (2) argon 7440-37-1
0.2656 0.5036 7.1737 0.05%
H2 (1) hydrogen 1333-74-0

Ar (2) argon 7440-37-1
0.5528 –0.3790 1.2179 –0.7932 0.10%
Comment: precision of data: ± 0.3%
References
(ed), New York: ASME, 1981, p. 289–296.


H2 (1) hydrogen 1333-74-0

T [K] Type D · 104 [m2/s]
174.4 D01(2) 0.242 ± 0.9%
291.5 D01(2) 0.623 ± 0.9%
489.0 D01(2) 1.59 ± 0.9%
H2 (1) hydrogen 1333-74-0

T [K] Type D · 104 [m2/s]
174.4 D02(1) 0.238 ± 0.9%
203.0 D02(1) 0.314 ± 0.9%
233.2 D02(1) 0.407 ± 0.9%
263.2 D02(1) 0.509 ± 0.9%
291.5 D02(1) 0.612 ± 0.9%
415.6 D02(1) 1.17 ± 0.9%
489.0 D02(1) 1.58 ± 0.9%
580.7 D02(1) 2.16 ± 0.9%
Reference

Diffusion of hydrogen (1); eicosane (2) 1
Diffusion of hydrogen (1); eicosane (2)

H2 (1) hydrogen 1333-74-0

C20H42 (2) eicosane 112-95-8
T [K] Type D · 109 [m2/s]
374.25 D01(2) 16.27 ± 0.98
412.45 D01(2) 24.10 ± 0.30
449.75 D01(2) 33.53 ± 0.61
494.75 D01(2) 46.62 ± 0.77
533.45 D01(2) 67.19 ± 3.21
Reference


H2 (1) hydrogen 1333-74-0

Kr (2) krypton 7439-90-9
T [K] Type D · 104 [m2/s]
163.5 D01(2) 0.240 ± 0.9%
295.7 D01(2) 0.729 ± 0.9%
482.5 D01(2) 1.746 ± 0.9%
H2 (1) hydrogen 1333-74-0

Kr (2) krypton 7439-90-9
T [K] Type D · 104 [m2/s]
128.3 D02(1) 0.150 ± 0.9%
163.5 D02(1) 0.236 ± 0.9%
203.1 D02(1) 0.352 ± 0.9%
243.4 D02(1) 0.488 ± 0.9%
295.7 D02(1) 0.706 ± 0.9%
386.2 D02(1) 1.13 ± 0.9%
482.5 D02(1) 1.684 ± 0.9%
577.4 D02(1) 2.34 ± 0.9%
H2 (1) hydrogen 1333-74-0

Kr (2) krypton 7439-90-9
–1.1147 1.3241 4.8648 0.05%
H2 (1) hydrogen 1333-74-0

Kr (2) krypton 7439-90-9
0.5952 –0.5883 1.1985 –0.8807 0.09%
Comment: precision of data: ±0.3%
References
1981T2

2 Diffusion of hydrogen (1); krypton (2)
Trengove, R.D., Dunlop, P.J.: Proc. 8th Int. Symp. on Therophysical Properties, Sengers, J.V.
(ed), New York: ASME, 1981, p. 289–296.


H2 (1) hydrogen 1333-74-0

Ne (2) neon 7440-01-9
–0.6268 1.6616 8.2189 0.04%
H2 (1) hydrogen 1333-74-0

Ne (2) neon 7440-01-9
1.7957 –1.4279 2.0688 –1.6187 0.06%
References
(ed), New York: ASME, 1981, p. 289–296.

Diffusion of hydrogen (1); xenon (2) 1
Diffusion of hydrogen (1); xenon (2)

H2 (1) hydrogen 1333-74-0

Xe (2) xenon 7440-63-3
–0.2719 0.6684 4.9914 0.08%
H2 (1) hydrogen 1333-74-0

Xe (2) xenon 7440-63-3
0.4114 –0.3607 0.9590 –0.6416 0.07%
References
(ed), New York: ASME, 1981, p. 289–296.


He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] Type D · 104 [m2/s]
195.10 ± 0.002 D02(1) 0.3550
205.20 ± 0.002 D02(1) 0.3872
218.07 ± 0.002 D02(1) 0.4293
234.22 ± 0.002 D02(1) 0.4850
255.50 ± 0.002 D02(1) 0.5612
270.42 ± 0.002 D02(1) 0.6186
277.48 ± 0.002 D02(1) 0.6448
280.00 ± 0.002 D02(1) 0.6536
290.00 ± 0.002 D02(1) 0.6935
300.00 ± 0.002 D02(1) 0.7344
310.00 ± 0.002 D02(1) 0.7761
320.00 ± 0.002 D02(1) 0.8189
333.15 ± 0.002 D02(1) 0.8771
343.15 ± 0.002 D02(1) 0.9193
353.22 ± 0.002 D02(1) 0.9659
356.07 ± 0.002 D02(1) 0.9822
373.09 ± 0.002 D02(1) 1.062
385.49 ± 0.002 D02(1) 1.119
400.21 ± 0.002 D02(1) 1.193
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] Type D · 104 [m2/s]
200.0 ± 0.002 D02(1) 0.3721
230.0 ± 0.002 D02(1) 0.4695
260.0 ± 0.002 D02(1) 0.5771
280.0 ± 0.002 D02(1) 0.6536
290.0 ± 0.002 D02(1) 0.6935
300.0 ± 0.002 D02(1) 0.7344
310.0 ± 0.002 D02(1) 0.7761
320.0 ± 0.002 D02(1) 0.8189
360.0 ± 0.002 D02(1) 0.9942
380.0 ± 0.002 D02(1) 1.0883
400.0 ± 0.002 D02(1) 1.1856
Comment: Erratum for [1985T5]

He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TB Ref.: 1991K1
T [K] Type D · 104 [m2/s]
220.0 ± 0.002 D02(1) 0.4347
240.0 ± 0.002 D02(1) 0.5042
260.0 ± 0.002 D02(1) 0.5769
280.0 ± 0.002 D02(1) 0.6538
300.0 ± 0.002 D02(1) 0.7340
320.0 ± 0.002 D02(1) 0.8191
340.0 ± 0.002 D02(1) 0.9056
360.0 ± 0.002 D02(1) 0.9987
380.0 ± 0.002 D02(1) 1.0933
400.0 ± 0.002 D02(1) 1.1920
Comment: accuracy: 0.3%
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: CT Ref.: 1977A5
T [K] Type D · 104 [m2/s]
300.00 ± 0.001 D02(1) 0.7344 ± 0.06%
Comment: recommended data for calibration, superior to previously reported results (higher accuracy)
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
Diffusion Coefficient at infinite dilution: D02(1) (T ); Method: TB Ref.: 1991K1
–0.8376 1.3377 4.6307 0.03%
Comment: accuracy of data: ±0.3%
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
–0.382 0.5053 0.7560 –3.483 0.06%
References
673–674.

Diffusion of helium (1); tetrafluoro-methane (2) 1
Diffusion of helium (1); tetrafluoro-methane (2)

He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
280.0 ± 0.002 D01(2) 0.4295 ± 0.3%
300.0 ± 0.002 D01(2) 0.4804 ± 0.3%
320.0 ± 0.002 D01(2) 0.5350 ± 0.3%
340.0 ± 0.002 D01(2) 0.5907 ± 0.3%
360.0 ± 0.002 D01(2) 0.6479 ± 0.3%
380.0 ± 0.002 D01(2) 0.7085 ± 0.3%
400.0 ± 0.002 D01(2) 0.7710 ± 0.3%
He (1) helium 7440-59-7

Diffusion Coefficient at infinite dilution: Method: TB Ref.: 1996D4
T [K] Type D · 104 [m2/s]
300 D01(2) 0.4809
300 D02(1) 0.4948
400 D01(2) 0.7710
He (1) helium 7440-59-7

–0.6408 0.1004 0.2708 0.00
References

Diffusion of helium (1); trifluoro-methane (2) 1
Diffusion of helium (1); trifluoro-methane (2)

He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
300 D01(2) 0.5103
300 D02(1) 0.5285
400 D01(2) 0.8231
He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
280.0 ± 0.002 D01(2) 0.4549 ± 0.3%
300.0 ± 0.002 D01(2) 0.5103 ± 0.3%
320.0 ± 0.002 D01(2) 0.5689 ± 0.3%
340.0 ± 0.002 D01(2) 0.6294 ± 0.3%
360.0 ± 0.002 D01(2) 0.6917 ± 0.3%
380.0 ± 0.002 D01(2) 0.7562 ± 0.3%
400.0 ± 0.002 D01(2) 0.8231 ± 0.3%
He (1) helium 7440-59-7

–1.0291 0.1236 0.2696 0.02%
References

Diffusion of helium (1); difluoro-methane (2) 1
Diffusion of helium (1); difluoro-methane (2)

He (1) helium 7440-59-7

CH2F2 (2) difluoro-methane 75-10-5
T [K] Type D · 104 [m2/s]
300 D01(2) 0.5520
300 D02(1) 0.5678
400 D01(2) 0.8904
Reference

Diffusion of helium (1); fluoro-methane (2) 1
Diffusion of helium (1); fluoro-methane (2)

He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
300 D01(2) 0.6113
300 D02(1) 0.6279
400 D01(2) 0.9837
He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
280.0 ± 0.002 D01(2) 0.5464 ± 0.3%
300.0 ± 0.002 D01(2) 0.6116 ± 0.3%
320.0 ± 0.002 D01(2) 0.6813 ± 0.3%
340.0 ± 0.002 D01(2) 0.7525 ± 0.3%
360.0 ± 0.002 D01(2) 0.8276 ± 0.3%
380.0 ± 0.002 D01(2) 0.9039 ± 0.3%
400.0 ± 0.002 D01(2) 0.9839 ± 0.3%
He (1) helium 7440-59-7

–0.8796 0.1298 0.3456 0.04%
References


He (1) helium 7440-59-7

CH4 (2) methane 74-82-8
T [K] Type D · 104 [m2/s]
300 D01(2) 0.6808
300 D02(1) 0.6932
400 D01(2) 1.1007
He (1) helium 7440-59-7

CH4 (2) methane 74-82-8
T [K] Type D · 104 [m2/s]
280.0 ± 0.002 D01(2) 0.6075 ± 0.3%
300.0 ± 0.002 D01(2) 0.6811 ± 0.3%
320.0 ± 0.002 D01(2) 0.7591 ± 0.3%
340.0 ± 0.002 D01(2) 0.8398 ± 0.3%
360.0 ± 0.002 D01(2) 0.9237 ± 0.3%
380.0 ± 0.002 D01(2) 1.0100 ± 0.3%
400.0 ± 0.002 D01(2) 1.1007 ± 0.3%
He (1) helium 7440-59-7

CH4 (2) methane 74-82-8
–8.5062 13.0972 4.1352 0.05%
Comment: D01(2) [m2/s] = D · 10–4
He (1) helium 7440-59-7

CH4 (2) methane 74-82-8
–0.9159 0.1367 0.4034 0.04%
References


He (1) helium 7440-59-7

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TB Ref.: 1998G5
T [K] Type D · 104 [m2/s]
307.8 ± 0.05 D02(1) 0.735
318.8 ± 0.05 D02(1) 0.777
331.9 ± 0.05 D02(1) 0.832
344.6 ± 0.05 D02(1) 0.890
355.6 ± 0.05 D02(1) 0.944
Reference
Zolotoukhina, A.F.: Mol. Phys. 94 (1998) 605–622.

Diffusion of helium (1); carbon oxide sulfide (2) 1
Diffusion of helium (1); carbon oxide sulfide (2)

He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
280.0 ± 0.002 D01(2) 0.4330 ± 0.3%
300.0 ± 0.002 D01(2) 0.4863 ± 0.3%
320.0 ± 0.002 D01(2) 0.5406 ± 0.3%
340.0 ± 0.002 D01(2) 0.5974 ± 0.3%
360.0 ± 0.002 D01(2) 0.6572 ± 0.3%
380.0 ± 0.002 D01(2) 0.7195 ± 0.3%
400.0 ± 0.002 D01(2) 0.7836 ± 0.3%
He (1) helium 7440-59-7

Diffusion Coefficient at infinite dilution: D01(2) (T ); Method: CT Ref.: 1995D4
–0.5076 0.8955 2.9762 0.04%
Comment: D01(2) [m2/s] = D · 10–4
Reference


He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
173.2 D01(2) 0.251 ± 0.9%
294.6 D01(2) 0.607 ± 0.9%
595.9 D01(2) 2.023 ± 0.9%
He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
195.10 ± 0.002 D02(1) 0.2927
205.20 ± 0.002 D02(1) 0.3188
218.07 ± 0.002 D02(1) 0.3539
234.22 ± 0.002 D02(1) 0.3991
255.50 ± 0.002 D02(1) 0.4620
280.00 ± 0.002 D02(1) 0.5366
290.00 ± 0.002 D02(1) 0.5689
300.00 ± 0.002 D02(1) 0.6023
310.00 ± 0.002 D02(1) 0.6356
320.00 ± 0.002 D02(1) 0.6704
337.90 ± 0.002 D02(1) 0.7362
373.09 ± 0.002 D02(1) 0.8708
385.49 ± 0.002 D02(1) 0.9179
400.21 ± 0.002 D02(1) 0.9780
He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
200.0 ± 0.002 D02(1) 0.3052
230.0 ± 0.002 D02(1) 0.3858
260.0 ± 0.002 D02(1) 0.4739
280.0 ± 0.002 D02(1) 0.5366
290.0 ± 0.002 D02(1) 0.5689
300.0 ± 0.002 D02(1) 0.6023
310.0 ± 0.002 D02(1) 0.6356
320.0 ± 0.002 D02(1) 0.6704
360.0 ± 0.002 D02(1) 0.8134
(continued)

380.0 ± 0.002 D02(1) 0.8915

400.0 ± 0.002 D02(1) 0.9717
He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
300.00 ± 0.001 D02(1) 0.6029 ± 0.04%
He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
220.0 ± 0.002 D01(2) 0.3581 ± 0.3%
240.0 ± 0.002 D01(2) 0.4159 ± 0.3%
260.0 ± 0.002 D01(2) 0.4752 ± 0.3%
280.0 ± 0.002 D01(2) 0.5373 ± 0.3%
300.0 ± 0.002 D01(2) 0.6030 ± 0.3%
320.0 ± 0.002 D01(2) 0.6712 ± 0.3%
340.0 ± 0.002 D01(2) 0.7434 ± 0.3%
360.0 ± 0.002 D01(2) 0.8166 ± 0.3%
380.0 ± 0.002 D01(2) 0.8938 ± 0.3%
400.0 ± 0.002 D01(2) 0.9738 ± 0.3%
He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
173.2 D02(1) 0.249 ± 0.9%
203.2 D02(1) 0.323 ± 0.9%
233.2 D02(1) 0.410 ± 0.9%
263.2 D02(1) 0.506 ± 0.9%
294.6 D02(1) 0.600 ± 0.9%
409.3 D02(1) 1.03 ± 0.9%
510.9 D02(1) 1.50 ± 0.9%
595.9 D02(1) 1.968 ± 0.9%

He (1) helium 7440-59-7

–0.7769 1.1931 3.5881 0.04%
Comment: D01(2) [m2/s] = D · 10–4
He (1) helium 7440-59-7

–7.725 1.2204 0.3398 0.261 0.06%
References
(1977) 673–674.


He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
300 D01(2) 0.4148
300 D02(1) 0.4291
400 D01(2) 0.6629
He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
280.0 D01(2) 0.3700
290.0 D01(2) 0.3927
300.0 D01(2) 0.4150
310.0 D01(2) 0.4370
320.0 D01(2) 0.4605
References


He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
280.0 D01(2) 0.3719
290.0 D01(2) 0.3942
300.0 D01(2) 0.4165
310.0 D01(2) 0.4405
320.0 D01(2) 0.4633
He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
300 D01(2) 0.4160
300 D02(1) 0.4315
400 D01(2) 0.6656
References


He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
300 D01(2) 0.3960
300 D02(1) 0.4106
400 D01(2) 0.6342
He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
280.0 D01(2) 0.3536
290.0 D01(2) 0.3750
300.0 D01(2) 0.3960
310.0 D01(2) 0.4177
320.0 D01(2) 0.4398
References

Diffusion of helium (1); hexafluoro-ethane (2) 1
Diffusion of helium (1); hexafluoro-ethane (2)

He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
280.0 D01(2) 0.3278
290.0 D01(2) 0.3472
300.0 D01(2) 0.3658
310.0 D01(2) 0.3870
320.0 D01(2) 0.4076
He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
300 D01(2) 0.3658
300 D02(1) 0.3816
400 D01(2) 0.5857
He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
280.0 ± 0.002 D01(2) 0.3278 ± 0.3%
300.0 ± 0.002 D01(2) 0.3658 ± 0.3%
320.0 ± 0.002 D01(2) 0.4076 ± 0.3%
340.0 ± 0.002 D01(2) 0.4493 ± 0.3%
360.0 ± 0.002 D01(2) 0.4932 ± 0.3%
380.0 ± 0.002 D01(2) 0.5389 ± 0.3%
400.0 ± 0.002 D01(2) 0.5857 ± 0.3%
He (1) helium 7440-59-7

–0.5140 0.0798 0.1988 0.07%
References

2 Diffusion of helium (1); hexafluoro-ethane (2)

Diffusion of helium (1); 1,1,1,2,2-pentafluoro-ethane (2) 1
Diffusion of helium (1); 1,1,1,2,2-pentafluoro-ethane (2)

He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
300 D01(2) 0.3790
300 D02(1) 0.3959
400 D01(2) 0.6063
He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
280.0 D01(2) 0.3387
290.0 D01(2) 0.3587
300.0 D01(2) 0.3790
310.0 D01(2) 0.4004
320.0 D01(2) 0.4213
References


He (1) helium 7440-59-7

C2H2 (2) ethyne 74-86-2
T [K] Type D · 104 [m2/s]
280.0 ± 0.002 D01(2) 0.5300 ± 0.3%
300.0 ± 0.002 D01(2) 0.5936 ± 0.3%
320.0 ± 0.002 D01(2) 0.6630 ± 0.3%
340.0 ± 0.002 D01(2) 0.7332 ± 0.3%
360.0 ± 0.002 D01(2) 0.8059 ± 0.3%
380.0 ± 0.002 D01(2) 0.8815 ± 0.3%
400.0 ± 0.002 D01(2) 0.9612 ± 0.3%
He (1) helium 7440-59-7

C2H2 (2) ethyne 74-86-2
–0.8814 0.1236 0.3467 0.07%
Reference


He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
300 D01(2) 0.3970
300 D02(1) 0.4144
400 D01(2) 0.6329
He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
280.0 D01(2) 0.3548 ± 0.3%
290.0 D01(2) 0.3758 ± 0.3%
300.0 D01(2) 0.3974 ± 0.3%
310.0 D01(2) 0.4200 ± 0.3%
320.0 D01(2) 0.4420 ± 0.3%
References


He (1) helium 7440-59-7

C2H4 (2) ethene 74-85-1
T [K] Type D · 104 [m2/s]
280.0 ± 0.002 D01(2) 0.4835 ± 0.3%
300.0 ± 0.002 D01(2) 0.5417 ± 0.3%
320.0 ± 0.002 D01(2) 0.6043 ± 0.3%
340.0 ± 0.002 D01(2) 0.6673 ± 0.3%
360.0 ± 0.002 D01(2) 0.7340 ± 0.3%
380.0 ± 0.002 D01(2) 0.8034 ± 0.3%
400.0 ± 0.002 D01(2) 0.8754 ± 0.3%
He (1) helium 7440-59-7

C2H4 (2) ethene 74-85-1
–0.6297 0.1031 0.3286 0.04%
Reference

Diffusion of helium (1); 1,1-difluoro-ethane (2) 1
Diffusion of helium (1); 1,1-difluoro-ethane (2)

He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
280.0 D01(2) 0.3912 ± 0.3%
290.0 D01(2) 0.4140 ± 0.3%
300.0 D01(2) 0.4365 ± 0.3%
310.0 D01(2) 0.4621 ± 0.3%
320.0 D01(2) 0.4870 ± 0.3%
He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
300 D01(2) 0.4365
300 D02(1) 0.4518
400 D01(2) 0.6993
References

Diffusion of helium (1); fluoro-ethane (2) 1
Diffusion of helium (1); fluoro-ethane (2)

He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
280.0 D01(2) 0.4153 ± 0.3%
290.0 D01(2) 0.4405 ± 0.3%
300.0 D01(2) 0.4647 ± 0.3%
310.0 D01(2) 0.4906 ± 0.3%
320.0 D01(2) 0.5168 ± 0.3%
He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
300 D01(2) 0.4650
300 D02(1) 0.4781
400 D01(2) 0.7448
References


He (1) helium 7440-59-7

C2H6 (2) ethane 74-84-0
T [K] Type D · 104 [m2/s]
280.0 ± 0.002 D01(2) 0.4458 ± 0.3%
300.0 ± 0.002 D01(2) 0.4998 ± 0.3%
320.0 ± 0.002 D01(2) 0.5570 ± 0.3%
340.0 ± 0.002 D01(2) 0.6151 ± 0.3%
360.0 ± 0.002 D01(2) 0.6761 ± 0.3%
380.0 ± 0.002 D01(2) 0.7404 ± 0.3%
400.0 ± 0.002 D01(2) 0.8059 ± 0.3%
He (1) helium 7440-59-7

C2H6 (2) ethane 74-84-0
T [K] Type D · 104 [m2/s]
300 D01(2) 0.4998
300 D02(1) 0.5119
400 D01(2) 0.8059
He (1) helium 7440-59-7

C2H6 (2) ethane 74-84-0
–0.6514 0.1002 0.2940 0.04%
References

Diffusion of helium (1); octafluoro-propane (2) 1
Diffusion of helium (1); octafluoro-propane (2)

He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
280.0 ± 0.002 D01(2) 0.2725 ± 0.3%
300.0 ± 0.002 D01(2) 0.3050 ± 0.3%
320.0 ± 0.002 D01(2) 0.3392 ± 0.3%
340.0 ± 0.002 D01(2) 0.3745 ± 0.3%
360.0 ± 0.002 D01(2) 0.4106 ± 0.3%
380.0 ± 0.002 D01(2) 0.4480 ± 0.3%
400.0 ± 0.002 D01(2) 0.4878 ± 0.3%
He (1) helium 7440-59-7

–0.4727 0.0689 0.1619 0.06%
Reference

Diffusion of helium (1); cyclopropane (2) 1
Diffusion of helium (1); cyclopropane (2)

He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
280.0 ± 0.002 D01(2) 0.3991 ± 0.3%
300.0 ± 0.002 D01(2) 0.4471 ± 0.3%
320.0 ± 0.002 D01(2) 0.4986 ± 0.3%
340.0 ± 0.002 D01(2) 0.5504 ± 0.3%
360.0 ± 0.002 D01(2) 0.6050 ± 0.3%
380.0 ± 0.002 D01(2) 0.6620 ± 0.3%
400.0 ± 0.002 D01(2) 0.7203 ± 0.3%
He (1) helium 7440-59-7

–0.6891 0.0966 0.2518 0.04%
Reference

Diffusion of helium (1); propane (2) 1
Diffusion of helium (1); propane (2)

He (1) helium 7440-59-7

C3H8 (2) propane 74-98-6
T [K] Type D · 104 [m2/s]
280.0 ± 0.002 D01(2) 0.3635 ± 0.3%
300.0 ± 0.002 D01(2) 0.4072 ± 0.3%
320.0 ± 0.002 D01(2) 0.4525 ± 0.3%
340.0 ± 0.002 D01(2) 0.4995 ± 0.3%
360.0 ± 0.002 D01(2) 0.5484 ± 0.3%
380.0 ± 0.002 D01(2) 0.6015 ± 0.3%
400.0 ± 0.002 D01(2) 0.6556 ± 0.3%
He (1) helium 7440-59-7

C3H8 (2) propane 74-98-6
–0.0053 0.05114 0.2821 0.07%
Reference

Diffusion of helium (1); octafluoro-cyclobutane (2) 1
Diffusion of helium (1); octafluoro-cyclobutane (2)

He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
280.0 ± 0.002 D01(2) 0.2566 ± 0.3%
300.0 ± 0.002 D01(2) 0.2879 ± 0.3%
320.0 ± 0.002 D01(2) 0.3202 ± 0.3%
340.0 ± 0.002 D01(2) 0.3540 ± 0.3%
360.0 ± 0.002 D01(2) 0.3888 ± 0.3%
380.0 ± 0.002 D01(2) 0.4248 ± 0.3%
400.0 ± 0.002 D01(2) 0.4623 ± 0.3%
He (1) helium 7440-59-7

–0.5145 0.0671 0.1533 0.02%
Reference

Diffusion of helium (1); buta-1,3-diene (2) 1
Diffusion of helium (1); buta-1,3-diene (2)

He (1) helium 7440-59-7

C4H6 (2) buta-1,3-diene 106-99-0
T [K] Type D · 104 [m2/s]
280.0 ± 0.002 D01(2) 0.3394 ± 0.3%
300.0 ± 0.002 D01(2) 0.3804 ± 0.3%
320.0 ± 0.002 D01(2) 0.4241 ± 0.3%
340.0 ± 0.002 D01(2) 0.4688 ± 0.3%
360.0 ± 0.002 D01(2) 0.5147 ± 0.3%
380.0 ± 0.002 D01(2) 0.5631 ± 0.3%
400.0 ± 0.002 D01(2) 0.6131 ± 0.3%
He (1) helium 7440-59-7

C4H6 (2) buta-1,3-diene 106-99-0
–0.6288 0.0846 0.2110 0.04%
Reference

Diffusion of helium (1); butane (2) 1
Diffusion of helium (1); butane (2)

He (1) helium 7440-59-7

C4H10 (2) butane 106-97-8
T [K] Type D · 104 [m2/s]
280.0 ± 0.002 D01(2) 0.3104 ± 0.3%
300.0 ± 0.002 D01(2) 0.3480 ± 0.3%
320.0 ± 0.002 D01(2) 0.3878 ± 0.3%
340.0 ± 0.002 D01(2) 0.4282 ± 0.3%
360.0 ± 0.002 D01(2) 0.4704 ± 0.3%
380.0 ± 0.002 D01(2) 0.5150 ± 0.3%
400.0 ± 0.002 D01(2) 0.5601 ± 0.3%
He (1) helium 7440-59-7

C4H10 (2) butane 106-97-8
–0.5546 0.0764 0.1938 0.04%
Reference


He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
200.0 ± 0.002 D02(1) 0.1984
230.0 ± 0.002 D02(1) 0.2501
260.0 ± 0.002 D02(1) 0.3071
280.0 ± 0.002 D02(1) 0.3469
290.0 ± 0.002 D02(1) 0.3680
300.0 ± 0.002 D02(1) 0.3894
310.0 ± 0.002 D02(1) 0.4111
320.0 ± 0.002 D02(1) 0.4332
360.0 ± 0.002 D02(1) 0.5260
380.0 ± 0.002 D02(1) 0.5754
400.0 ± 0.002 D02(1) 0.6259
He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
195.10 ± 0.002 D02(1) 0.1899
205.20 ± 0.002 D02(1) 0.2057
218.07 ± 0.002 D02(1) 0.2284
234.22 ± 0.002 D02(1) 0.2585
252.69 ± 0.002 D02(1) 0.2932
280.00 ± 0.002 D02(1) 0.3469
290.00 ± 0.002 D02(1) 0.3680
300.00 ± 0.002 D02(1) 0.3894
310.00 ± 0.002 D02(1) 0.4111
320.00 ± 0.002 D02(1) 0.4332
337.90 ± 0.002 D02(1) 0.4758
356.07 ± 0.002 D02(1) 0.5190
373.09 ± 0.002 D02(1) 0.5593
385.49 ± 0.002 D02(1) 0.5912
400.21 ± 0.002 D02(1) 0.6281

2 Diffusion of helium (1); sulfur hexafluoride (2)
He (1) helium 7440-59-7

–1.336 0.4085 0.3525 –1.378 0.03%
Comment: D02(1) [m2/s] = D · 10–4; Erratum [1987T3]: due to calibration problems data are replaced
References


He (1) helium 7440-59-7

H2 (2) hydrogen 1333-74-0
T [K] Type D · 104 [m2/s]
280.0 D01(2) 1.428 ± 0.3%
290.0 D01(2) 1.513 ± 0.3%
300.0 D01(2) 1.603 ± 0.3%
310.0 D01(2) 1.695 ± 0.3%
320.0 D01(2) 1.785 ± 0.3%
Reference


He (1) helium 7440-59-7

D2 (2) deuterium 7782-39-0
T [K] Type D · 104 [m2/s]
77.2 D01(2) 0.131 ± 0.9%
132.5 D01(2) 0.324 ± 0.9%
183.6 D01(2) 0.569 ± 0.9%
233.4 D01(2) 0.851 ± 0.9%
295.3 D01(2) 1.29 ± 0.9%
401.2 D01(2) 2.17 ± 0.9%
470.7 D01(2) 2.88 ± 0.9%
592.1 D01(2) 4.29 ± 0.9%
Reference


He (1) helium 7440-59-7

H 3N (2) ammonia 7664-41-7
T [K] Type D · 104 [m2/s]
280.0 ± 0.002 D01(2) 0.6647 ± 0.3%
290.0 ± 0.002 D01(2) 0.7052 ± 0.3%
300.0 ± 0.002 D01(2) 0.7472 ± 0.3%
310.0 ± 0.002 D01(2) 0.7891 ± 0.3%
320.0 ± 0.002 D01(2) 0.8321 ± 0.3%
340.0 ± 0.002 D01(2) 0.9207 ± 0.3%
360.0 ± 0.002 D01(2) 1.0093 ± 0.3%
380.0 ± 0.002 D01(2) 1.1058 ± 0.3%
400.0 ± 0.002 D01(2) 1.2046 ± 0.3%
He (1) helium 7440-59-7

H 3N (2) ammonia 7664-41-7
–1.3157 1.6943 4.1115 0.07%
Comment: D01(2) [m2/s] = D · 10–4
Reference


He (1) helium 7440-59-7

Kr (2) krypton 7439-90-9
T [K] Type D · 104 [m2/s]
220.0 ± 0.002 D02(1) 0.3767 ± 0.3%
240.0 ± 0.002 D02(1) 0.4368 ± 0.3%
260.0 ± 0.002 D02(1) 0.4997 ± 0.3%
280.0 ± 0.002 D02(1) 0.5662 ± 0.3%
300.0 ± 0.002 D02(1) 0.6359 ± 0.3%
320.0 ± 0.002 D02(1) 0.7093 ± 0.3%
340.0 ± 0.002 D02(1) 0.7850 ± 0.3%
360.0 ± 0.002 D02(1) 0.8643 ± 0.3%
380.0 ± 0.002 D02(1) 0.9453 ± 0.3%
400.0 ± 0.002 D02(1) 1.0307 ± 0.3%
He (1) helium 7440-59-7

Kr (2) krypton 7439-90-9
–0.8289 1.2351 3.8731 0.05%
Reference


He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
280.0 ± 0.001 D01(2) 0.6515
290.0 ± 0.001 D01(2) 0.6893
300.0 ± 0.001 D01(2) 0.7280
310.0 ± 0.001 D01(2) 0.7693
320.0 ± 0.001 D01(2) 0.8112
He (1) helium 7440-59-7

2.2440 –0.6346 0.7714 0.02%
Reference


He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
T [K] Type D · 104 [m2/s]
300.00 ± 0.001 D02(1) 0.7067 ± 0.04%
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
T [K] Type D · 104 [m2/s]
195.10 ± 0.002 D02(1) 0.3444
205.20 ± 0.002 D02(1) 0.3752
218.07 ± 0.002 D02(1) 0.4159
234.22 ± 0.002 D02(1) 0.4689
255.50 ± 0.002 D02(1) 0.5427
280.00 ± 0.002 D02(1) 0.6296
290.00 ± 0.002 D02(1) 0.6679
300.00 ± 0.002 D02(1) 0.7068
310.00 ± 0.002 D02(1) 0.7466
320.00 ± 0.002 D02(1) 0.7870
337.90 ± 0.002 D02(1) 0.8638
356.07 ± 0.002 D02(1) 0.9424
373.09 ± 0.002 D02(1) 1.018
385.49 ± 0.002 D02(1) 1.073
400.21 ± 0.002 D02(1) 1.144
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
T [K] Type D · 104 [m2/s]
200.0 ± 0.002 D02(1) 0.3596
230.0 ± 0.002 D02(1) 0.4538
260.0 ± 0.002 D02(1) 0.5565
280.0 ± 0.002 D02(1) 0.6296
290.0 ± 0.002 D02(1) 0.6679
300.0 ± 0.002 D02(1) 0.7068
310.0 ± 0.002 D02(1) 0.7466
320.0 ± 0.002 D02(1) 0.7870
360.0 ± 0.002 D02(1) 0.9556
(continued)

380.0 ± 0.002 D02(1) 1.0461

400.0 ± 0.002 D02(1) 1.1390
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
–14.8236 17.6579 3.6152 0.04%
Comment: D01(2) [m2/s] = D · 10–4
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
–2.984 0.8061 0.6115 –2.068 0.04%
References
673–674.

Diffusion of helium (1); nitrous oxide (2) 1
Diffusion of helium (1); nitrous oxide (2)

He (1) helium 7440-59-7

T [K] Type D · 104 [m2/s]
280.0 ± 0.002 D01(2) 0.5287 ± 0.3%
300.0 ± 0.002 D01(2) 0.5930 ± 0.3%
320.0 ± 0.002 D01(2) 0.6608 ± 0.3%
340.0 ± 0.002 D01(2) 0.7306 ± 0.3%
360.0 ± 0.002 D01(2) 0.8032 ± 0.3%
380.0 ± 0.002 D01(2) 0.8791 ± 0.3%
400.0 ± 0.002 D01(2) 0.9573 ± 0.3%
He (1) helium 7440-59-7

–0.8621 1.2326 3.4405 0.05%
Comment: D01(2) [m2/s] = D · 10–4
Reference


He (1) helium 7440-59-7

Ne (2) neon 7440-01-9
T [K] Type D · 104 [m2/s]
220.0 ± 0.002 D02(1) 0.6501 ± 0.3%
240.0 ± 0.002 D02(1) 0.7537 ± 0.3%
260.0 ± 0.002 D02(1) 0.8624 ± 0.3%
280.0 ± 0.002 D02(1) 0.9761 ± 0.3%
300.0 ± 0.002 D02(1) 1.0948 ± 0.3%
320.0 ± 0.002 D02(1) 1.2225 ± 0.3%
340.0 ± 0.002 D02(1) 1.3521 ± 0.3%
360.0 ± 0.002 D02(1) 1.4914 ± 0.3%
380.0 ± 0.002 D02(1) 1.6331 ± 0.3%
400.0 ± 0.002 D02(1) 1.7802 ± 0.3%
He (1) helium 7440-59-7

Ne (2) neon 7440-01-9
Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TB Ref.: 1969M7
T [K] Type D · 104 [m2/s]
273 D02(1) 0.929 ± 0.004
315 D02(1) 1.159 ± 0.010
334 D02(1) 1.318 ± 0.004
354 D02(1) 1.428 ± 0.010
374 D02(1) 1.567 ± 0.023
394 D02(1) 1.670 ± 0.031
He (1) helium 7440-59-7

Ne (2) neon 7440-01-9
–1.0832 1.8905 7.0814 0.05%
He (1) helium 7440-59-7

Ne (2) neon 7440-01-9
Diffusion Coefficientat infinite dilution: D02(1) (T ); Method: TB Ref.: 1969M7
Equation: log (D) = A + B log (T ) Range: 273 < T/K < 394
–4.0051 1.631 1%
Comment: D02(1) [m2/s] = D · 10–4

References
1969M7 Malinauskas, A.P., Silverman, M.D.: J. Chem. Phys. 50 (1969) 3263–3270.


He (1) helium 7440-59-7

O2 (2) oxygen 7782-44-7
T [K] Type D · 104 [m2/s]
195.10 ± 0.002 D02(1) 0.3644
205.20 ± 0.002 D02(1) 0.3957
218.07 ± 0.002 D02(1) 0.4378
234.22 ± 0.002 D02(1) 0.4934
255.50 ± 0.002 D02(1) 0.5710
280.00 ± 0.002 D02(1) 0.6624
290.00 ± 0.002 D02(1) 0.7032
300.00 ± 0.002 D02(1) 0.7448
310.00 ± 0.002 D02(1) 0.7873
320.00 ± 0.002 D02(1) 0.8305
337.90 ± 0.002 D02(1) 0.9104
356.07 ± 0.002 D02(1) 0.9939
373.09 ± 0.002 D02(1) 1.072
385.49 ± 0.002 D02(1) 1.135
400.21 ± 0.002 D02(1) 1.208
He (1) helium 7440-59-7

O2 (2) oxygen 7782-44-7
T [K] Type D · 104 [m2/s]
200.0 ± 0.002 D02(1) 0.3766
230.0 ± 0.002 D02(1) 0.4778
260.0 ± 0.002 D02(1) 0.5867
280.0 ± 0.002 D02(1) 0.6624
290.0 ± 0.002 D02(1) 0.7032
300.0 ± 0.002 D02(1) 0.7448
310.0 ± 0.002 D02(1) 0.7873
320.0 ± 0.002 D02(1) 0.8305
360.0 ± 0.002 D02(1) 1.0082
380.0 ± 0.002 D02(1) 1.1020
400.0 ± 0.002 D02(1) 1.2033

He (1) helium 7440-59-7

O2 (2) oxygen 7782-44-7
T [K] Type D · 104 [m2/s]
300.00 ± 0.001 D02(1) 0.7469 ± 0.03%
He (1) helium 7440-59-7

O2 (2) oxygen 7782-44-7
–1.5263 1.7810 0.4034 0.07%
He (1) helium 7440-59-7

O2 (2) oxygen 7782-44-7
–8.825 1.4141 0.4570 –0.098 0.09%
References
673–674.


He (1) helium 7440-59-7

Xe (2) xenon 7440-63-3
T [K] Type D · 104 [m2/s]
220.0 ± 0.002 D02(1) 0.3214 ± 0.3%
240.0 ± 0.002 D02(1) 0.3726 ± 0.3%
260.0 ± 0.002 D02(1) 0.4260 ± 0.3%
280.0 ± 0.002 D02(1) 0.4832 ± 0.3%
300.0 ± 0.002 D02(1) 0.5422 ± 0.3%
320.0 ± 0.002 D02(1) 0.6048 ± 0.3%
340.0 ± 0.002 D02(1) 0.6690 ± 0.3%
360.0 ± 0.002 D02(1) 0.7363 ± 0.3%
380.0 ± 0.002 D02(1) 0.8053 ± 0.3%
400.0 ± 0.002 D02(1) 0.8771 ± 0.3%
He (1) helium 7440-59-7

Xe (2) xenon 7440-63-3
–0.7585 1.0958 3.2188 0.05%
Reference


Kr (1) krypton 7439-90-9

Ar (2) argon 7440-37-1
T [K] Type D · 104 [m2/s]
200.0 D01(2) 0.06540 ± 0.3%
230.0 D01(2) 0.08546 ± 0.3%
260.0 D01(2) 0.1077 ± 0.3%
280.0 D01(2) 0.1235 ± 0.3%
290.0 D01(2) 0.1318 ± 0.3%
300.0 D01(2) 0.1404 ± 0.3%
310.0 D01(2) 0.1492 ± 0.3%
320.0 D01(2) 0.1583 ± 0.3%
360.0 D01(2) 0.1958 ± 0.3%
380.0 D01(2) 0.2160 ± 0.3%
400.0 D01(2) 0.2369 ± 0.3%
Kr (1) krypton 7439-90-9

Ar (2) argon 7440-37-1
–0.755 0.7568 1.5523 –5.348 0.04%
0 2 –4
Comment: D 1(2) [m /s] = D · 10
Reference


Kr (1) krypton 7439-90-9

CH4 (2) methane 74-82-8
T [K] Type D · 104 [m2/s]
200.0 D01(2) 0.08274 ± 0.3%
230.0 D01(2) 0.1086 ± 0.3%
260.0 D01(2) 0.1367 ± 0.3%
280.0 D01(2) 0.1569 ± 0.3%
290.0 D01(2) 0.1676 ± 0.3%
300.0 D01(2) 0.1787 ± 0.3%
310.0 D01(2) 0.1900 ± 0.3%
320.0 D01(2) 0.2015 ± 0.3%
360.0 D01(2) 0.2497 ± 0.3%
380.0 D01(2) 0.2754 ± 0.3%
400.0 D01(2) 0.3025 ± 0.3%
Kr (1) krypton 7439-90-9

CH4 (2) methane 74-82-8
–4.3961 3.6896 1.2438 0.03%
Comment: D01(2) [m2/s] = D · 10–4
Kr (1) krypton 7439-90-9

CH4 (2) methane 74-82-8
–1.201 1.1774 1.8919 –5.531 0.06%
Comment: D01(2) [m2/s] = D · 10–4
References


Kr (1) krypton 7439-90-9

T [K] Type D · 104 [m2/s]
173.2 D01(2) 0.0391 ± 0.9%
203.2 D01(2) 0.0543 ± 0.9%
233.2 D01(2) 0.0720 ± 0.9%
263.2 D01(2) 0.0911 ± 0.9%
293.2 D01(2) 0.112 ± 0.9%
409.3 D01(2) 0.214 ± 0.9%
510.9 D01(2) 0.322 ± 0.9%
595.9 D01(2) 0.422 ± 0.9%
662.9 D01(2) 0.504 ± 0.9%
776.1 D01(2) 0.657 ± 0.9%
Kr (1) krypton 7439-90-9

T [K] Type D · 104 [m2/s]
173.2 D02(1) 0.0395 ± 0.9%
293.2 D02(1) 0.111 ± 0.9%
595.9 D02(1) 0.417 ± 0.9%
Reference


Kr (1) krypton 7439-90-9

H2 (2) hydrogen 1333-74-0
T [K] Type D · 104 [m2/s]
240.0 D01(2) 0.4869 ± 0.3%
250.0 D01(2) 0.5239 ± 0.3%
260.0 D01(2) 0.5619 ± 0.3%
270.0 D01(2) 0.6010 ± 0.3%
280.0 D01(2) 0.6411 ± 0.3%
290.0 D01(2) 0.6820 ± 0.3%
300.0 D01(2) 0.7239 ± 0.3%
310.0 D01(2) 0.7665 ± 0.3%
320.0 D01(2) 0.8099 ± 0.3%
Kr (1) krypton 7439-90-9

H2 (2) hydrogen 1333-74-0
T [K] Type D · 104 [m2/s]
200.0 D01(2) 0.3506 ± 0.3%
230.0 D01(2) 0.4516 ± 0.3%
260.0 D01(2) 0.5620 ± 0.3%
278.0 D01(2) 0.6320 ± 0.3%
280.0 D01(2) 0.6403 ± 0.3%
280.2 D01(2) 0.6418 ± 0.3%
282.9 D01(2) 0.6526 ± 0.3%
291.2 D01(2) 0.6895 ± 0.3%
295.0 D01(2) 0.7021 ± 0.3%
300.0 D01(2) 0.7240 ± 0.3%
302.7 D01(2) 0.7355 ± 0.3%
307.2 D01(2) 0.7540 ± 0.3%
310.0 D01(2) 0.7658 ± 0.3%
311.1 D01(2) 0.7713 ± 0.3%
314.8 D01(2) 0.7867 ± 0.3%
319.2 D01(2) 0.8063 ± 0.3%
323.2 D01(2) 0.8253 ± 0.3%
340.0 D01(2) 0.8983 ± 0.3%
References

Diffusion of krypton (1); ammonia (2) 1
Diffusion of krypton (1); ammonia (2)

Kr (1) krypton 7439-90-9

H 3N (2) ammonia 7664-41-7
T [K] Type D · 104 [m2/s]
280.0 ± 0.002 D01(2) 0.1619 ± 0.3%
290.0 ± 0.002 D01(2) 0.1731 ± 0.3%
300.0 ± 0.002 D01(2) 0.1843 ± 0.3%
310.0 ± 0.002 D01(2) 0.1961 ± 0.3%
320.0 ± 0.002 D01(2) 0.2084 ± 0.3%
340.0 ± 0.002 D01(2) 0.2330 ± 0.3%
360.0 ± 0.002 D01(2) 0.2582 ± 0.3%
380.0 ± 0.002 D01(2) 0.2855 ± 0.3%
400.0 ± 0.002 D01(2) 0.3140 ± 0.3%
Kr (1) krypton 7439-90-9

H 3N (2) ammonia 7664-41-7
–0.3303 0.2985 1.4214 0.08%
Comment: D01(2) [m2/s] = D · 10–4
Reference


Kr (1) krypton 7439-90-9

N2 (2) nitrogen 7727-37-9
–4.2460 3.7360 0.9987 0.02%
Comment: D01(2) [m2/s] = D · 10–4
Reference


Kr (1) krypton 7439-90-9

O2 (2) oxygen 7782-44-7
T [K] Type D · 104 [m2/s]
280.0 ± 0.001 D01(2) 0.1392 ± 0.1%
290.0 ± 0.001 D01(2) 0.1484 ± 0.1%
300.0 ± 0.001 D01(2) 0.1578 ± 0.1%
310.0 ± 0.001 D01(2) 0.1677 ± 0.1%
320.0 ± 0.001 D01(2) 0.1775 ± 0.1%
Kr (1) krypton 7439-90-9

O2 (2) oxygen 7782-44-7
Diffusion Coefficient at infinite dilution: D01(2) (T ); Method: CT Ref.: 1992D6
–0.2053 0.2304 0.1214 0.03%
Reference


Kr (1) krypton 7439-90-9

Xe (2) xenon 7440-63-3
T [K] Type D · 104 [m2/s]
163.2 D02(1) 0.0288 ± 0.9%
203.6 D02(1) 0.0366 ± 0.9%
243.4 D02(1) 0.0522 ± 0.9%
297.4 D02(1) 0.0758 ± 0.9%
402.1 D02(1) 0.137 ± 0.9%
484.4 D02(1) 0.192 ± 0.9%
589.5 D02(1) 0.278 ± 0.9%
682.2 D02(1) 0.359 ± 0.9%
767.6 D02(1) 0.435 ± 0.9%
Reference


N2 (1) nitrogen 7727-37-9

Ar (2) argon 7440-37-1
T [K] Type D · 104 [m2/s]
300.00 ± 0.001 D02(1) 0.2034 ± 0.04%
Reference
673–674.


N2 (1) nitrogen 7727-37-9

Diffusion Coefficient at infinite dilution: D01(2) (T ); Method: TB Ref.: 1984R3
–0.6386 0.5011 0.9094 0.04%
Reference


N2 (1) nitrogen 7727-37-9

O2 (2) oxygen 7782-44-7
Diffusion Coefficient at infinite dilution: D01(2) (T ); Method: TB Ref.: 1984R3
–0.7682 0.6737 1.0456 0.05%
Reference


Ne (1) neon 7440-01-9

Ar (2) argon 7440-37-1
T [K] Type D · 104 [m2/s]
220.0 D01(2) 0.1889 ± 0.3%
240.0 D01(2) 0.2203 ± 0.3%
260.0 D01(2) 0.2531 ± 0.3%
280.0 D01(2) 0.2875 ± 0.3%
300.0 D01(2) 0.3236 ± 0.3%
320.0 D01(2) 0.3607 ± 0.3%
340.0 D01(2) 0.3996 ± 0.3%
360.0 D01(2) 0.4408 ± 0.3%
380.0 D01(2) 0.4817 ± 0.3%
400.0 D01(2) 0.5261 ± 0.3%
Ne (1) neon 7440-01-9

Ar (2) argon 7440-37-1
T [K] Type D · 104 [m2/s]
273 D02(1) 0.272 ± 0.003
273 D02(1) 0.276 ± 0.002
273 D02(1) 0.271 ± 0.003
315 D02(1) 0.357 ± 0.005
334 D02(1) 0.375 ± 0.003
354 D02(1) 0.420 ± 0.004
354 D02(1) 0.424 ± 0.009
374 D02(1) 0.458 ± 0.004
374 D02(1) 0.459 ± 0.001
394 D02(1) 0.506 ± 0.004
394 D02(1) 0.505 ± 0.006
394 D02(1) 0.512 ± 0.006
Ne (1) neon 7440-01-9

Ar (2) argon 7440-37-1
–4.6357 1.672 1%
Comment: D02(1) [m2/s] = D · 10–4

Ne (1) neon 7440-01-9

Ar (2) argon 7440-37-1
–5.482 6.880 1.909 0.06%
References

Diffusion of neon (1); tetrafluoro-methane (2) 1
Diffusion of neon (1); tetrafluoro-methane (2)

Ne (1) neon 7440-01-9

Diffusion Coefficient at infinite dilution: p = 1 bar; Method: TB Ref.: 1987D8
T [K] Type D · 104 [m2/s]
200.0 ± 0.002 D01(2) 0.1002 ± 0.3%
230.0 ± 0.002 D01(2) 0.1283 ± 0.3%
260.0 ± 0.002 D01(2) 0.1584 ± 0.3%
280.0 ± 0.002 D01(2) 0.1793 ± 0.3%
300.0 ± 0.002 D01(2) 0.2020 ± 0.3%
320.0 ± 0.002 D01(2) 0.2252 ± 0.3%
360.0 ± 0.002 D01(2) 0.2748 ± 0.3%
380.0 ± 0.002 D01(2) 0.3003 ± 0.3%
400.0 ± 0.002 D01(2) 0.3274 ± 0.3%
Reference

Diffusion of neon (1); methane (2) 1
Diffusion of neon (1); methane (2)

Ne (1) neon 7440-01-9

CH4 (2) methane 74-82-8
–16.6726 15.8005 0.5491 0.06%
Comment: D01(2) [m2/s] = D · 10–4
Reference


Ne (1) neon 7440-01-9

Diffusion Coefficient at infinite dilution p = 101.325 kPa; Method: TB Ref.: 1974L12
T [K] Type D · 104 [m2/s]
176.1 D02(1) 0.1032 ± 0.9%
201.2 D02(1) 0.131 ± 0.9%
231.3 D02(1) 0.171 ± 0.9%
263.2 D02(1) 0.217 ± 0.9%
296.6 D02(1) 0.271 ± 0.9%
417.9 D02(1) 0.500 ± 0.9%
484.1 D02(1) 0.651 ± 0.9%
586.8 D02(1) 0.912 ± 0.9%
Ne (1) neon 7440-01-9

T [K] Type D · 104 [m2/s]
176.1 D01(2) 0.1034 ± 0.9%
296.6 D01(2) 0.272 ± 0.9%
586.8 D01(2) 0.916 ± 0.9%
Reference


Ne (1) neon 7440-01-9

H2 (2) hydrogen 1333-74-0
T [K] Type D · 104 [m2/s]
240.0 D01(2) 0.8112 ± 0.3%
250.0 D01(2) 0.8688 ± 0.3%
260.0 D01(2) 0.9277 ± 0.3%
270.0 D01(2) 0.9879 ± 0.3%
280.0 D01(2) 1.0494 ± 0.3%
290.0 D01(2) 1.1122 ± 0.3%
300.0 D01(2) 1.1764 ± 0.3%
310.0 D01(2) 1.2420 ± 0.3%
Ne (1) neon 7440-01-9

H2 (2) hydrogen 1333-74-0
T [K] Type D · 104 [m2/s]
200.0 D01(2) 0.5922 ± 0.3%
230.0 D01(2) 0.7481 ± 0.3%
260.0 D01(2) 0.9226 ± 0.3%
278.0 D01(2) 1.0337 ± 0.3%
280.0 D01(2) 1.0462 ± 0.3%
281.2 D01(2) 1.0548 ± 0.3%
285.3 D01(2) 1.0803 ± 0.3%
289.1 D01(2) 1.1054 ± 0.3%
292.8 D01(2) 1.1283 ± 0.3%
296.0 D01(2) 1.1497 ± 0.3%
300.0 D01(2) 1.1761 ± 0.3%
308.2 D01(2) 1.2291 ± 0.3%
310.0 D01(2) 1.2447 ± 0.3%
312.2 D01(2) 1.2556 ± 0.3%
316.3 D01(2) 1.2854 ± 0.3%
320.3 D01(2) 1.3127 ± 0.3%
323.2 D01(2) 1.3331 ± 0.3%
References


Ne (1) neon 7440-01-9

Kr (2) krypton 7439-90-9
T [K] Type D · 104 [m2/s]
273 D02(1) 0.225 ± 0.001
273 D02(1) 0.221 ± 0.002
273 D02(1) 0.224 ± 0.004
273 D02(1) 0.223 ± 0.003
273 D02(1) 0.222 ± 0.001
273 D02(1) 0.219 ± 0.004
315 D02(1) 0.289 ± 0.003
334 D02(1) 0.314 ± 0.003
354 D02(1) 0.355 ± 0.002
374 D02(1) 0.393 ± 0.003
394 D02(1) 0.416 ± 0.003
Ne (1) neon 7440-01-9

Kr (2) krypton 7439-90-9
T [K] Type D · 104 [m2/s]
220.0 D01(2) 0.1534 ± 0.3%
240.0 D01(2) 0.1787 ± 0.3%
260.0 D01(2) 0.2053 ± 0.3%
280.0 D01(2) 0.2335 ± 0.3%
300.0 D01(2) 0.2624 ± 0.3%
320.0 D01(2) 0.2931 ± 0.3%
340.0 D01(2) 0.3253 ± 0.3%
360.0 D01(2) 0.3580 ± 0.3%
380.0 D01(2) 0.3923 ± 0.3%
400.0 D01(2) 0.4282 ± 0.3%
Ne (1) neon 7440-01-9

Kr (2) krypton 7439-90-9
–4.9332 1.757 1%
Comment: D02(1) [m2/s] = D · 10–4

Ne (1) neon 7440-01-9

Kr (2) krypton 7439-90-9
–4.094 5.292 1.609 0.04%
References


Ne (1) neon 7440-01-9

N2 (2) nitrogen 7727-37-9
–9.1510 9.5686 1.6037 0.03%
Comment: D01(2) [m2/s] = D · 10–4
Reference

Diffusion of neon (1); oxygen (2) 1
Diffusion of neon (1); oxygen (2)

Ne (1) neon 7440-01-9

O2 (2) oxygen 7782-44-7
T [K] Type D · 104 [m2/s]
280.0 ± 0.001 D01(2) 0.3062 ± 0.1%
290.0 ± 0.001 D01(2) 0.3245 ± 0.1%
300.0 ± 0.001 D01(2) 0.3438 ± 0.1%
310.0 ± 0.001 D01(2) 0.3633 ± 0.1%
320.0 ± 0.001 D01(2) 0.3830 ± 0.1%
Ne (1) neon 7440-01-9

O2 (2) oxygen 7782-44-7
–0.4420 0.6621 0.2104 0.05%
Reference


Ne (1) neon 7440-01-9

Xe (2) xenon 7440-63-3
T [K] Type D · 104 [m2/s]
273 D02(1) 0.193 ± 0.001
315 D02(1) 0.248 ± 0.002
334 D02(1) 0.268 ± 0.001
354 D02(1) 0.306 ± 0.004
374 D02(1) 0.328 ± 0.002
394 D02(1) 0.358 ± 0.003
Ne (1) neon 7440-01-9

Xe (2) xenon 7440-63-3
T [K] Type D · 104 [m2/s]
220.0 D01(2) 0.1291 ± 0.3%
240.0 D01(2) 0.1504 ± 0.3%
260.0 D01(2) 0.1730 ± 0.3%
280.0 D01(2) 0.1965 ± 0.3%
300.0 D01(2) 0.2210 ± 0.3%
320.0 D01(2) 0.2472 ± 0.3%
340.0 D01(2) 0.2738 ± 0.3%
360.0 D01(2) 0.3016 ± 0.3%
380.0 D01(2) 0.3306 ± 0.3%
400.0 D01(2) 0.3603 ± 0.3%
Ne (1) neon 7440-01-9

Xe (2) xenon 7440-63-3
–4.8308 1.690 1%
Comment: D02(1) [m2/s] = D · 10–4
Ne (1) neon 7440-01-9

Xe (2) xenon 7440-63-3
–3.714 4.633 1.327 0.05%

References


O2 (1) oxygen 7782-44-7

Diffusion Coefficient at infinite dilution: D01(2) (T ); Method: CT Ref.: 1984R3
–0.8201 0.6281 0.6995 0.08%
Reference

Diffusion of sulfur dioxide (1); air (2) 1
Diffusion of sulfur dioxide (1); air (2)


Air (2) air 132259-10-0
Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: ABSORB Ref.: 1971F4
T [K] Type D · 104 [m2/s]
293.15 D01(2) 0.13279 ± 0.76 · 10–3
293.15 D01(2) 0.13460 ± 0.92 · 10–3
293.15 D01(2) 0.12957 ± 0.52 · 10–3
293.15 D01(2) 0.13321 ± 0.36 · 10–3
293.15 D01(2) 0.13179 ± 0.69 · 10–3
293.15 D01(2) 0.13105 ± 0.50 · 10–3
293.15 D01(2) 0.13208 ± 0.39 · 10–3
293.15 D01(2) 0.13204 ± 0.19 · 10–3*
Comment: concentration of (1) = 3.8 mg/m3;
*: weighted mean
Reference
1971F4 Fish, B.R., Durham, J.L.: Environ. Lett. 2 (1971) 13–21.

Diffusion of xenon (1); methane (2) 1
Diffusion of xenon (1); methane (2)

Xe (1) xenon 7440-63-3

CH4 (2) methane 74-82-8
T [K] Type D · 104 [m2/s]
200.0 D01(2) 0.06818 ± 0.3%
230.0 D01(2) 0.08943 ± 0.3%
260.0 D01(2) 0.1133 ± 0.3%
280.0 D01(2) 0.1302 ± 0.3%
290.0 D01(2) 0.1390 ± 0.3%
300.0 D01(2) 0.1482 ± 0.3%
310.0 D01(2) 0.1576 ± 0.3%
320.0 D01(2) 0.1648 ± 0.3%
360.0 D01(2) 0.2086 ± 0.3%
380.0 D01(2) 0.2308 ± 0.3%
400.0 D01(2) 0.2536 ± 0.3%
Xe (1) xenon 7440-63-3

CH4 (2) methane 74-82-8
–0.4314 0.8834 1.3999 0.04%
Comment: D01(2) [m2/s] = D · 10–4
Xe (1) xenon 7440-63-3

CH4 (2) methane 74-82-8
–1.066 1.1082 1.4596 –2.108 0.05%
Comment: D01(2) [m2/s] = D · 10–4
References

Diffusion of xenon (1); carbon dioxide (2) 1
Diffusion of xenon (1); carbon dioxide (2)

Xe (1) xenon 7440-63-3

T [K] Type D · 104 [m2/s]
175.0 D01(2) 0.0311 ± 0.9%
203.4 D01(2) 0.0425 ± 0.9%
233.1 D01(2) 0.0564 ± 0.9%
263.2 D01(2) 0.0723 ± 0.9%
291.7 D01(2) 0.0881 ± 0.9%
407.2 D01(2) 0.168 ± 0.9%
498.8 D01(2) 0.243 ± 0.9%
593.2 D01(2) 0.328 ± 0.9%
674.4 D01(2) 0.408 ± 0.9%
776.9 D01(2) 0.527 ± 0.9%
Xe (1) xenon 7440-63-3

T [K] Type D · 104 [m2/s]
175.0 D02(1) 0.0311 ± 0.9%
291.7 D02(1) 0.0883 ± 0.9%
593.2 D02(1) 0.332 ± 0.9%
Reference


Xe (1) xenon 7440-63-3

H2 (2) hydrogen 1333-74-0
Diffusion Coefficient at infinite dilution p = 101.325 kPa; Method: CT Ref.: 1987D3
T [K] Type D · 104 [m2/s]
240.0 D01(2) 0.4183 ± 0.3%
250.0 D01(2) 0.4501 ± 0.3%
260.0 D01(2) 0.4829 ± 0.3%
270.0 D01(2) 0.5166 ± 0.3%
280.0 D01(2) 0.5512 ± 0.3%
290.0 D01(2) 0.5866 ± 0.3%
300.0 D01(2) 0.6228 ± 0.3%
310.0 D01(2) 0.6598 ± 0.3%
320.0 D01(2) 0.6975 ± 0.3%
Xe (1) xenon 7440-63-3

H2 (2) hydrogen 1333-74-0
T [K] Type D · 104 [m2/s]
200.0 D01(2) 0.3013 ± 0.3%
230.0 D01(2) 0.3873 ± 0.3%
260.0 D01(2) 0.4831 ± 0.3%
280.0 D01(2) 0.5513 ± 0.3%
283.6 D01(2) 0.5636 ± 0.3%
287.2 D01(2) 0.5772 ± 0.3%
290.7 D01(2) 0.5893 ± 0.3%
295.6 D01(2) 0.6070 ± 0.3%
300.0 D01(2) 0.6233 ± 0.3%
304.1 D01(2) 0.6369 ± 0.3%
308.0 D01(2) 0.6520 ± 0.3%
310.0 D01(2) 0.6598 ± 0.3%
312.0 D01(2) 0.6664 ± 0.3%
316.3 D01(2) 0.6835 ± 0.3%
319.2 D01(2) 0.6946 ± 0.3%
323.2 D01(2) 0.7109 ± 0.3%
340.0 D01(2) 0.7746 ± 0.3%
References

Diffusion of xenon (1); ammonia (2) 1
Diffusion of xenon (1); ammonia (2)

Xe (1) xenon 7440-63-3

H 3N (2) ammonia 7664-41-7
T [K] Type D · 104 [m2/s]
280.0 ± 0.002 D01(2) 0.1333 ± 0.3%
290.0 ± 0.002 D01(2) 0.1427 ± 0.3%
300.0 ± 0.002 D01(2) 0.1523 ± 0.3%
310.0 ± 0.002 D01(2) 0.1622 ± 0.3%
320.0 ± 0.002 D01(2) 0.1725 ± 0.3%
340.0 ± 0.002 D01(2) 0.1936 ± 0.3%
360.0 ± 0.002 D01(2) 0.2146 ± 0.3%
380.0 ± 0.002 D01(2) 0.2376 ± 0.3%
400.0 ± 0.002 D01(2) 0.2616 ± 0.3%
Xe (1) xenon 7440-63-3

H 3N (2) ammonia 7664-41-7
–0.3625 0.2824 1.1543 0.08%
Comment: D01(2) [m2/s] = D · 10–4
Reference


Xe (1) xenon 7440-63-3

N2 (2) nitrogen 7727-37-9
–0.3067 0.8819 1.2029 0.02%
Comment: D01(2) [m2/s] = D · 10–4
Reference

Diffusion of xenon (1); oxygen (2) 1
Diffusion of xenon (1); oxygen (2)

Xe (1) xenon 7440-63-3

O2 (2) oxygen 7782-44-7
T [K] Type D · 104 [m2/s]
280.0 ± 0.001 D01(2) 0.1142 ± 0.1%
290.0 ± 0.001 D01(2) 0.1219 ± 0.1%
300.0 ± 0.001 D01(2) 0.1296 ± 0.1%
310.0 ± 0.001 D01(2) 0.1378 ± 0.1%
320.0 ± 0.001 D01(2) 0.1460 ± 0.1%
Xe (1) xenon 7440-63-3

O2 (2) oxygen 7782-44-7
–0.1238E 0.1521 0.1071 0.04%
Reference

Diffusion of ethene (1); ethane (2); hydrogen (3) 1
Diffusion of ethene (1); ethane (2); hydrogen (3)

Data extract from of Landolt-Börnstein IV/15A, Chapter 4.1.3: Diffusion in
C2H4 (1) ethene 74-85-1

C2H6 (2) ethane 74-84-0
H2 (3) hydrogen 1333-74-0
Effective Diffusion Coefficients in mixture: Dieff; Method: RFGC Ref.: 1983K1
eff 9 2
T [K] p [kPa] D1 · 10 [m /s] D2eff · 109 [m2/s]
298 101.325 5.54 ± 0.15 6.00 ± 0.07
Comment: 0.5 cm3 of gas mixture (1:1 w/w) of components (1) and (2) injected in carrier (3)
Reference
1983K1 Karaiskakis, G., Katsanos, N.A., Niotis, A.: Chromatographia 17 (1983) 310–312.

Diffusion of ethene (1); butane (2); hydrogen (3) 1
Diffusion of ethene (1); butane (2); hydrogen (3)

C2H4 (1) ethene 74-85-1

C4H10 (2) butane 106-97-8
H2 (3) hydrogen 1333-74-0
T [K] p [kPa] D1eff · 109 [m2/s] D2eff · 109 [m2/s]
296 101.325 5.86 ± 0.37 3.81 ± 0.13
Reference

Diffusion of ethane (1); butane (2); hydrogen (3) 1
Diffusion of ethane (1); butane (2); hydrogen (3)

C2H6 (1) ethane 74-84-0

C4H10 (2) butane 106-97-8
H2 (3) hydrogen 1333-74-0
292 101.325 5.34 ± 0.09 3.79 ± 0.08
292 101.325 5.03 ± 0.17 3.60 ± 0.14
Reference

Diffusion of ethane (1); butane (2); helium (3) 1
Diffusion of ethane (1); butane (2); helium (3)

C2H6 (1) ethane 74-84-0

C4H10 (2) butane 106-97-8
He (3) helium 7440-59-7
294 101.325 4.94 ± 0.07 5.06 ± 0.07
Reference

Diffusion of ethane (1); butane (2); nitrogen (3) 1
Diffusion of ethane (1); butane (2); nitrogen (3)

C2H6 (1) ethane 74-84-0

C4H10 (2) butane 106-97-8
N2 (3) nitrogen 7727-37-9
296 101.325 1.66 ± 0.04 1.18 ± 0.03
Reference

Diffusion of benzoic acid (1); carbon dioxide (2); methanol (3) 1
Diffusion of benzoic acid (1); carbon dioxide (2);

methanol (3)
C7H6O2 (1) benzoic acid 65-85-0

Diffusion Coefficient at infinite dilution: D01(23) (T ); Method: TAYLOR Ref.: 1990S6
T [K] p [bar] D01(23) · 109 [m2/s]
308.15 ± 0.05 173 5.75 ± 0.42
318.15 ± 0.05 173 6.13 ± 0.51
328.15 ± 0.05 173 6.69 ± 0.60
Comment: diffusion in supercritical fluid system with x3 = 0.055
Reference
1990S6 Smith, S.A., Shenai, V., Matthews, M.A.: J. Supercrit. Fluids 3 (1990) 175–179.

Diffusion of acridine (1); carbon dioxide (2); methanol (3) 1
Diffusion of acridine (1); carbon dioxide (2); methanol (3)

C13H9N (1) acridine 260-94-6

T [K] p [bar] D01(23) · 109 [m2/s]
308.15 ± 0.05 173 5.65 ± 0.60
318.15 ± 0.05 173 6.96 ± 0.40
328.15 ± 0.05 173 7.78 ± 0.90
Reference

Diffusion of phenanthrene (1); carbon dioxide (2); methanol (3) 1
Diffusion of phenanthrene (1); carbon dioxide (2); methanol (3)


T [K] p [bar] D01(23) · 109 [m2/s]
308.15 ± 0.05 173 7.77 ± 0.40
318.15 ± 0.05 173 9.36 ± 1.10
328.15 ± 0.05 173 10.0 ± 1.20
Reference

Diffusion of krypton (1); helium (2); argon (3) 1
Diffusion of krypton (1); helium (2); argon (3)

Kr (1) krypton 7439-90-9

He (2) helium 7440-59-7
Ar (3) argon 7440-37-1
Intradiffusion Coefficient: D1T (xi); T = 302.6 K; Method: TB Ref.: 1964W2
x1 x2 p [Torr] D1T · 104 [m2/s]
0.333 0.333 62.61 0.1469 ± 0.0074
Comment: 85Kr as trace in ternary mixture
Reference

Diffusion of krypton (1); helium (2); neon (3) 1
Diffusion of krypton (1); helium (2); neon (3)

Kr (1) krypton 7439-90-9

He (2) helium 7440-59-7
Ne (3) neon 7440-01-9
x1 x2 p [Torr] D1T · 104 [m2/s]
0.333 0.333 73.51 0.1793 ± 0.0060
Reference

Diffusion of krypton (1); helium (2); xenon (3) 1
Diffusion of krypton (1); helium (2); xenon (3)

Kr (1) krypton 7439-90-9

He (2) helium 7440-59-7
Xe (3) xenon 7440-63-3
x1 x2 p [Torr] D1T · 104 [m2/s]
0.333 0.333 64.72 0.1168 ± 0.0045
Reference

Diffusion of krypton (1); neon (2); xenon (3) 1
Diffusion of krypton (1); neon (2); xenon (3)

Kr (1) krypton 7439-90-9

Ne (2) neon 7440-01-9
Xe (3) xenon 7440-63-3
x1 x2 p [Torr] D1T · 104 [m2/s]
0.333 0.333 57.81 0.1067 ± 0.0043
Reference

Diffusion of krypton (1); helium (2); neon (3); xenon (4) 1
Diffusion of krypton (1); helium (2); neon (3); xenon (4)

Kr (1) krypton 7439-90-9

He (2) helium 7440-59-7
Ne (3) neon 7440-01-9
Xe (4) xenon 7440-63-3
x1 x2 x3 p [kPa] D1T · 104 [m2/s]
0.25 0.25 0.25 101.325 0.1411 ± 0.0113
Comment: 85Kr as trace in quaternary mixture
Reference

Diffusion of krypton (1); neon (2); argon (3); helium (4) 1
Diffusion of krypton (1); neon (2); argon (3); helium (4)

Kr (1) krypton 7439-90-9

Ne (2) neon 7440-01-9
Ar (3) argon 7440-37-1
He (4) helium 7440-59-7
x1 x2 x3 p [kPa] D1T · 104 [m2/s]
0.25 0.25 0.25 101.325 0.1650 ± 0.025
Comment: 85Kr as trace in quaternary mixture
Reference

Diffusion of air (1); argon (2) 1
Diffusion of air (1); argon (2)

Vapor in Gas
Air (1) air 132259-10-0

Ar (2) argon 7440-37-1
Diffusion of gas(1) in gas(2): D*12(T ); Method: ARF Ref.: 1980P5
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.190
Reference
1980P5 Pathak, B.K., Singh, P.C., Singh, V.N.: Indian J. Technol. 18 (1980) 380–381.

Diffusion of air (1); bromine (2) 1
Diffusion of air (1); bromine (2)

Vapor in Gas
Air (1) air 132259-10-0

Br2 (2) bromine 7726-95-6
Diffusion of gas(1) in gas(2): D*12(T ); Method: No Info Ref.: 1966F1
T [K] p [kPa] D · 104 [m2/s]
293.0 101.325 0.091
Comment: review of previous experimental results
Reference
1966F1 Fuller, E.N., Schettler, P.D., Giddings, J.C.: Ind. Eng. Chem. 58 (1966) 19–27.

Diffusion of air (1); cyanogen chloride (2) 1
Diffusion of air (1); cyanogen chloride (2)

Vapor in Gas
Air (1) air 132259-10-0

CClN (2) cyanogen chloride 506-77-4
T [K] p [kPa] D · 104 [m2/s]
273.0 101.325 0.111
Reference

Diffusion of air (1); trichloro-nitro-methane (2) 1
Diffusion of air (1); trichloro-nitro-methane (2)

Vapor in Gas
Air (1) air 132259-10-0

CCl3NO2 (2) trichloro-nitro-methane 76-06-2
T [K] p [kPa] D · 104 [m2/s]
298.0 101.325 0.088
Reference

Diffusion of air (1); hydrogen cyanide (2) 1
Diffusion of air (1); hydrogen cyanide (2)

Vapor in Gas
Air (1) air 132259-10-0

CHN (2) hydrogen cyanide 74-90-8
T [K] p [kPa] D · 104 [m2/s]
293.0 101.325 0.173
Reference

Diffusion of air (1); methane (2) 1
Diffusion of air (1); methane (2)

Vapor in Gas
Air (1) air 132259-10-0

CH4 (2) methane 74-82-8
T [K] p [kPa] D · 104 [m2/s]
289.0 101.325 0.219
294.6 101.325 0.224
Reference

Diffusion of air (1); carbon dioxide (2) 1
Diffusion of air (1); carbon dioxide (2)

Vapor in Gas
Air (1) air 132259-10-0

T [K] p [kPa] D · 104 [m2/s]
276.2 101.325 0.142
293.0 101.325 0.165
317.2 101.325 0.1772
Air (1) air 132259-10-0

Diffusion of gas(1) in gas(2): D*12(T ); Method: No Info Ref.: 1976C9
T [K] p [kPa] D · 104 [m2/s]
276.2 101.325 0.1420 ± 0.0007
317.2 101.325 0.1772 ± 0.0017
Air (1) air 132259-10-0

Diffusion of gas(1) in gas(2): D*12(T ); Method: CT Ref.: 1964H4
T [K] p [kPa] D · 104 [m2/s]
276.2 101.325 0.1420 ± 0.0007
317.2 101.325 0.1772 ± 0.0017
Air (1) air 132259-10-0

Diffusion of gas(1) in gas(2): D*12(T ); Method: INT Ref.: 1961S1
T [K] p [Torr] D · 104 [m2/s]
288.6 690 0.172 ± 0.001
References
1976C9 Cussler, E.L.: Multicomponent Diffusion, Amsterdam: Elsevier, 1976.
1964H4 Holsen, J.N., Strunk, M.R.: Ind. Eng. Chem. Fundam. 3 (1964) 143–146.
1961S1 Suetin, P.E., Ivakin, B.A.: Sov. Phys. Tech. Phys. 6 (1961) 359–361.

Diffusion of air (1); ethyne (2) 1
Diffusion of air (1); ethyne (2)

Vapor in Gas
Air (1) air 132259-10-0

C2H2 (2) ethyne 74-86-2
T [K] p [Torr] D · 104 [m2/s]
287.6 690 0.227 ± 0.002
Reference

Diffusion of air (1); ethanol (2) 1
Diffusion of air (1); ethanol (2)

Vapor in Gas
Air (1) air 132259-10-0

T [K] p [kPa] D · 104 [m2/s]
298.2 101.325 0.135
Air (1) air 132259-10-0

T [K] p [kPa] D · 104 [m2/s]
273.0 101.325 0.102
References

Diffusion of air (1); propan-2-ol (2) 1
Diffusion of air (1); propan-2-ol (2)

Vapor in Gas
Air (1) air 132259-10-0

C3H8O (2) propan-2-ol 67-63-0
T [K] p [kPa] D · 104 [m2/s]
299.1 101.325 0.099
312.6 101.325 0.107
333.2 101.325 0.121
Reference

Diffusion of air (1); butan-1-ol (2) 1
Diffusion of air (1); butan-1-ol (2)

Vapor in Gas
Air (1) air 132259-10-0

C4H10O (2) butan-1-ol 71-36-3
T [K] p [kPa] D · 104 [m2/s]
299.1 101.325 0.087
312.6 101.325 0.092
333.2 101.325 0.104
Reference

Diffusion of air (1); butan-2-ol (2) 1
Diffusion of air (1); butan-2-ol (2)

Vapor in Gas
Air (1) air 132259-10-0

C4H10O (2) butan-2-ol 78-92-2
T [K] p [kPa] D · 104 [m2/s]
299.1 101.325 0.089
312.6 101.325 0.096
333.2 101.325 0.108
Reference

Diffusion of air (1); acetic acid ethyl ester (2) 1
Diffusion of air (1); acetic acid ethyl ester (2)

Vapor in Gas
Air (1) air 132259-10-0

C4H8O2 (2) acetic acid ethyl ester 141-78-6
T [K] p [kPa] D · 104 [m2/s]
299.1 101.325 0.087
312.6 101.325 0.094
333.2 101.325 0.106
Reference

Diffusion of air (1); pentan-2-ol (2) 1
Diffusion of air (1); pentan-2-ol (2)

Vapor in Gas
Air (1) air 132259-10-0

C5H12O (2) pentan-2-ol 6032-29-7
T [K] p [kPa] D · 104 [m2/s]
299.1 101.325 0.071
312.6 101.325 0.076
333.2 101.325 0.086
Reference

Diffusion of air (1); chlorobenzene (2) 1
Diffusion of air (1); chlorobenzene (2)

Vapor in Gas
Air (1) air 132259-10-0

T [K] p [kPa] D · 104 [m2/s]
299.1 101.325 0.074
312.6 101.325 0.079
333.2 101.325 0.090
Reference

Diffusion of air (1); nitrobenzene (2) 1
Diffusion of air (1); nitrobenzene (2)

Vapor in Gas
Air (1) air 132259-10-0

C6H5NO2 (2) nitrobenzene 98-95-3
T [K] p [kPa] D · 104 [m2/s]
298.2 101.325 0.0855
Reference

Diffusion of air (1); benzene (2) 1
Diffusion of air (1); benzene (2)

Vapor in Gas
Air (1) air 132259-10-0

C6H6 (2) benzene 71-43-2
T [K] p [kPa] D · 104 [m2/s]
298.2 101.325 0.0962
308.0 101.325 0.1021
Reference

Diffusion of air (1); aniline (2) 1
Diffusion of air (1); aniline (2)

Vapor in Gas
Air (1) air 132259-10-0

C6H7N (2) aniline 62-53-3
T [K] p [kPa] D · 104 [m2/s]
299.1 101.325 0.074
312.6 101.325 0.079
333.2 101.325 0.090
Reference

Diffusion of air (1); toluene (2) 1
Diffusion of air (1); toluene (2)

Vapor in Gas
Air (1) air 132259-10-0

C7H8 (2) toluene 108-88-3
T [K] p [kPa] D · 104 [m2/s]
299.1 101.325 0.086
312.5 101.325 0.092
333.2 101.325 0.104
Reference

Diffusion of air (1); biphenyl (2) 1
Diffusion of air (1); biphenyl (2)

Vapor in Gas
Air (1) air 132259-10-0

C12H10 (2) biphenyl 92-52-4
T [K] p [kPa] D · 104 [m2/s]
490.0 101.325 0.160
Reference

Diffusion of air (1); chlorine (2) 1
Diffusion of air (1); chlorine (2)

Vapor in Gas
Air (1) air 132259-10-0

Cl2 (2) chlorine 7782-50-5
T [K] p [kPa] D · 104 [m2/s]
293.0 101.325 0.124
Reference

Diffusion of air (1); phosgene (2) 1
Diffusion of air (1); phosgene (2)

Vapor in Gas
Air (1) air 132259-10-0

Cl2CO (2) phosgene 75-44-5
T [K] p [kPa] D · 104 [m2/s]
273.0 101.325 0.095
Reference

Diffusion of air (1); sulfur hexafluoride (2) 1
Diffusion of air (1); sulfur hexafluoride (2)

Vapor in Gas
Air (1) air 132259-10-0

T [K] p [Torr] D · 104 [m2/s]
289.8 690 0.106 ± 0.001
Reference


Vapor in Gas
Air (1) air 132259-10-0

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 104 [m2/s]
298.2 101.325 0.260
299.1 101.325 0.258
312.6 101.325 0.277
333.2 101.325 0.305
Air (1) air 132259-10-0

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 104 [m2/s]
289.1 101.325 0.282
References

Diffusion of air (1); ammonia (2) 1
Diffusion of air (1); ammonia (2)

Vapor in Gas
Air (1) air 132259-10-0

H 3N (2) ammonia 7664-41-7
T [K] p [kPa] D · 104 [m2/s]
295.1 101.325 0.247
Reference

Diffusion of air (1); helium (2) 1
Diffusion of air (1); helium (2)

Vapor in Gas
Air (1) air 132259-10-0

He (2) helium 7440-59-7
Diffusion of gas(1) in gas(2): D*12(T ); Method: RFGC Ref.: 1984K1
T [K] p [kPa] D · 105 [m2/s]
294.0 101.325 6.64 ± 0.07
Air (1) air 132259-10-0

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
276.2 101.325 0.6242 ± 0.0002
317.2 101.325 0.7652 ± 0.0018
346.2 101.325 0.9019 ± 0.0006
References
1984K1 Karaiskakis, G., Niotis, A., Katsanos, N.A.: J. Chromatogr. Sci. 22 (1984) 554–558.

Diffusion of air (1); oxygen (2) 1
Diffusion of air (1); oxygen (2)

Vapor in Gas
Air (1) air 132259-10-0

O2 (2) oxygen 7782-44-7
T [K] p [kPa] D · 104 [m2/s]
273.0 101.325 0.1775
Reference

Diffusion of air (1); sulfur dioxide (2) 1
Diffusion of air (1); sulfur dioxide (2)

Vapor in Gas
Air (1) air 132259-10-0

T [K] p [kPa] D · 104 [m2/s]
293.0 101.325 0.122
Reference

Diffusion of argon-37 (1); argon (2) 1
Diffusion of argon-37 (1); argon (2)

Vapor in Gas
Ar (1) argon-37 13994-71-3

Ar (2) argon 7440-37-1
Diffusion of gas(1) in gas(2): D*12(T ); Method: OEC Ref.: 1960C1
T [K] p [atm] D · 104 [m2/s]
84.56 ± 0.04 2.0 1.53 ± 0.03
87.98 ± 0.05 2.0 1.73 ± 0.10
87.12 ± 0.05 2.0 1.71 ± 0.10
86.96 ± 0.05 2.0 1.71 ± 0.10
90.10 ± 0.05 2.0 1.89 ± 0.08
90.10 ± 0.05 2.0 2.10 ± 0.10
Comment: 37Ar diffusing in normal Ar
Reference
1960C1 Cini-Castagnoli, G., Ricci, F.P.: Nuovo Cimento 15 (1960) 795–805.

Diffusion of argon (1); tetrachloro-methane (2) 1
Diffusion of argon (1); tetrachloro-methane (2)

Vapor in Gas
Ar (1) argon 7440-37-1

CCl4 (2) tetrachloro-methane 56-23-5
T [K] p [kPa] D · 104 [m2/s]
373.15 ± 0.1 101.325 0.110
Reference
1981P3 Pathak, B.K., Singh, V.N., Singh, P.C.: Can. J. Chem. Eng. 59 (1981) 362–365.


Vapor in Gas
Ar (1) argon 7440-37-1

CH4 (2) methane 74-82-8
Diffusion of gas(1) in gas(2): D*12(T ); Method: TB Ref.: 1975Z2
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.210 ± 2%
Ar (1) argon 7440-37-1

CH4 (2) methane 74-82-8
Diffusion of gas(1) in gas(2): D*12(T ); Method: CT Ref.: 1969I1
T [K] p [atm] D · 104 [m2/s]
296.15 20.4 0.867 ± 2.2%
296.15 31.0 0.544 ± 2.9%
296.15 41.2 0.359 ± 2.2%
296.15 61.3 0.246 ± 0.4%
296.15 82.0 0.164 ± 2.4%
296.15 102.0 0.120 ± 3.3%
296.15 143.0 0.0897 ± 2.9%
References
1975Z2 Zhavrin, Yu.I., Kosov, N.D., Novosad, Z.I.: Zh. Fiz. Khim. 49 (1975) 706–709.
1969I1 Islam, M., Stryland, J.C.: Physica 45 (1969) 115–126.

Diffusion of argon (1); carbon monoxide (2) 1
Diffusion of argon (1); carbon monoxide (2)

Vapor in Gas
Ar (1) argon 7440-37-1

T [K] p [kPa] D · 104 [m2/s]
295.7 101.325 0.188
Reference


Vapor in Gas
Ar (1) argon 7440-37-1

Diffusion of gas(1) in gas(2): D*12(T ); Method: No Stand Ref.: 1997A1
T [K] p [kPa] D · 104 [m2/s]
300.4 101.325 0.15
406.3 101.325 0.27
450.6 101.325 0.31
500.1 101.325 0.37
550.8 101.325 0.44
600.9 101.325 0.52
680.2 101.325 0.63
700.8 101.325 0.68
750.2 101.325 0.75
800.6 101.325 0.85
840.2 101.325 0.92
900.3 101.325 1.06
960.2 101.325 1.18
1000.7 101.325 1.24
1060.8 101.325 1.36
Comment: method of stationary flowing, data of unknown quality
Ar (1) argon 7440-37-1

Diffusion of gas(1) in gas(2): D*12(T ); Method: TB Ref.: 1982B3
T [K] p [MPa] D · 107 [m2/s]
273.2 1.0 12.9 ± 4%
273.15 2.0 6.1 ± 4%
273.15 3.0 3.8 ± 4%
273.2 3.4 3.2 ± 4%
293.2 1.0 14.5 ± 4%
293.2 2.0 7.2 ± 4%
293.2 3.0 4.6 ± 4%
293.2 4.0 3.3 ± 4%
293.2 5.0 2.3 ± 4%
293.2 5.5 2.1 ± 4%
303.2 1.0 16.2 ± 4%
303.2 2.0 7.8 ± 4%
303.2 3.0 5.0 ± 4%
303.2 4.0 3.6 ± 4%
303.2 5.0 2.6 ± 4%
303.2 5.5 2.3 ± 4%

2 Diffusion of argon (1); carbon dioxide (2)
Ar (1) argon 7440-37-1

T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.146
Ar (1) argon 7440-37-1

T [K] p [kPa] D · 104 [m2/s]
276.2 101.325 0.1326
317.2 101.325 0.1652
Ar (1) argon 7440-37-1

Diffusion of gas(1) in gas(2): D*12(T ); Method: TB Ref.: 1977K1
T [K] p [kPa] D · 104 [m2/s]
216.6 101.325 0.075 ± 3%
217.8 101.325 0.086 ± 3%
217.9 101.325 0.086 ± 3%
218.5 101.325 0.088 ± 3%
220.3 101.325 0.090 ± 3%
225.5 101.325 0.092 ± 3%
Ar (1) argon 7440-37-1

T [K] p [Torr] D · 104 [m2/s]
288.6 690 0.149 ± 0.001
Ar (1) argon 7440-37-1

Diffusion of gas(1) in gas(2): D*12(T ); Method: TB Ref.: 1977I1
T [K] p [bar] D · 104 [m2/s]
273.2 1.03 0.128 ± 2%
273.2 4.90 0.0267 ± 2%
273.2 10.8 0.0115 ± 2%
273.2 15.7 0.00785 ± 2%
273.2 20.6 0.00579 ± 2%
273.2 25.5 0.00455 ± 2%
273.2 30.1 0.00368 ± 2%
References
1997A1 Al'zhanov, K.Z.: Dokl. Minist. Nauki-Akad. Nauk Resp. Kaz. 5 (1997) 40–45.

1982B3 Bibolov, S.K.: Gidroaerodinam. i Diffuziya, Alma-Ata 37 (1982) 37–40.

1977K1 Karpushin, A.G., Kosov, N.D., Moldabekova, M.S.: Prikl. Teor. Fiz. 9 (1977) 105–110.
1977I1 Ivakin, B.A., Loiko, A.E., Suetin, P.E.: Zh. Tekh. Fiz. 47 (1977) 873–876.

Diffusion of argon (1); ethyne (2) 1
Diffusion of argon (1); ethyne (2)

Vapor in Gas
Ar (1) argon 7440-37-1

C2H2 (2) ethyne 74-86-2
T [K] p [Torr] D · 104 [m2/s]
287.2 690 0.167 ± 0.001
Reference

Diffusion of argon (1); propan-2-one (2) 1
Diffusion of argon (1); propan-2-one (2)

Vapor in Gas
Ar (1) argon 7440-37-1

T [K] p [kPa] D · 104 [m2/s]
363.15 ± 0.1 101.325 0.139
Reference

Diffusion of argon (1); propane (2) 1
Diffusion of argon (1); propane (2)

Vapor in Gas
Ar (1) argon 7440-37-1

C3H8 (2) propane 74-98-6
Diffusion of gas(1) in gas(2): D*12(T ); Method: CT Ref.: 2003B1
T [K] p [kPa] D · 104 [m2/s]
294 101.325 4.33*
Comment: *: data of D*12 are (ρ · D*12 ) in [mol/m · s]
Reference
2003B1 Baranski, J., Bich, E., Vogel, E., Lehmann, J.K.: Int. J. Thermophys. 24 (2003) 1207–1220.

Diffusion of argon (1); methyl-cyclopentane (2) 1
Diffusion of argon (1); methyl-cyclopentane (2)

Vapor in Gas
Ar (1) argon 7440-37-1

C6H12 (2) methyl-cyclopentane 96-37-7
T [K] p [kPa] D · 104 [m2/s]
287.1 101.325 0.0731
Reference

Diffusion of argon (1); cyclohexane (2) 1
Diffusion of argon (1); cyclohexane (2)

Vapor in Gas
Ar (1) argon 7440-37-1

T [K] p [kPa] D · 104 [m2/s]
288.7 101.325 0.0719
Reference

Diffusion of argon (1); 2,3-dimethyl-butane (2) 1
Diffusion of argon (1); 2,3-dimethyl-butane (2)

Vapor in Gas
Ar (1) argon 7440-37-1

C6H14 (2) 2,3-dimethyl-butane 79-29-8
T [K] p [kPa] D · 104 [m2/s]
288.9 101.325 0.0657
Reference

Diffusion of argon (1); hexane (2) 1
Diffusion of argon (1); hexane (2)

Vapor in Gas
Ar (1) argon 7440-37-1

C6H14 (2) hexane 110-54-3
T [K] p [kPa] D · 104 [m2/s]
288.6 101.325 0.0663
Ar (1) argon 7440-37-1

C6H14 (2) hexane 110-54-3
T [K] p [kPa] D · 104 [m2/s]
373.15 ± 0.1 101.325 0.103
References

Diffusion of argon (1); nitrobenzene (2) 1
Diffusion of argon (1); nitrobenzene (2)

Vapor in Gas
Ar (1) argon 7440-37-1

T [K] p [kPa] D · 104 [m2/s]
493.15 ± 0.1 101.325 0.179
Reference


Vapor in Gas
Ar (1) argon 7440-37-1

C6H6 (2) benzene 71-43-2
T [K] p [kPa] D · 104 [m2/s]
373.15 ± 0.1 101.325 0.120
Reference

Diffusion of argon (1); aniline (2) 1
Diffusion of argon (1); aniline (2)

Vapor in Gas
Ar (1) argon 7440-37-1

T [K] p [kPa] D · 104 [m2/s]
473.15 ± 0.1 101.325 0.180
Reference

Diffusion of argon (1); heptane (2) 1
Diffusion of argon (1); heptane (2)

Vapor in Gas
Ar (1) argon 7440-37-1

C7H16 (2) heptane 142-82-5
T [K] p [kPa] D · 104 [m2/s]
303.2 101.325 0.0658
Reference

Diffusion of argon (1); 2,4-dimethyl-pentane (2) 1
Diffusion of argon (1); 2,4-dimethyl-pentane (2)

Vapor in Gas
Ar (1) argon 7440-37-1

C7H16 (2) 2,4-dimethyl-pentane 108-08-7
T [K] p [kPa] D · 104 [m2/s]
303.2 101.325 0.0655
Reference

Diffusion of argon (1); toluene (2) 1
Diffusion of argon (1); toluene (2)

Vapor in Gas
Ar (1) argon 7440-37-1

C7H8 (2) toluene 108-88-3
T [K] p [kPa] D · 104 [m2/s]
393.15 ± 0.1 101.325 0.119
Reference

Diffusion of argon (1); 2,2,4-trimethyl-pentane (2) 1
Diffusion of argon (1); 2,2,4-trimethyl-pentane (2)

Vapor in Gas
Ar (1) argon 7440-37-1

C8H18 (2) 2,2,4-trimethyl-pentane 540-84-1
T [K] p [kPa] D · 104 [m2/s]
303.2 101.325 0.0599
Reference

Diffusion of argon (1); octane (2) 1
Diffusion of argon (1); octane (2)

Vapor in Gas
Ar (1) argon 7440-37-1

C8H18 (2) octane 111-65-9
T [K] p [kPa] D · 104 [m2/s]
303.2 101.325 0.0587
Reference

Diffusion of argon (1); hydrogen-deuterium (2) 1
Diffusion of argon (1); hydrogen-deuterium (2)

Vapor in Gas
Ar (1) argon 7440-37-1

Diffusion of gas(1) in gas(2): D*12(T ); Method: TB Ref.: 1985W6
T [K] p [kPa] D
419.24 101.325 0.564 ± 0.0015
398.51 101.325 0.615 ± 0.0015
373.16 101.325 0.687 ± 0.0015
348.27 101.325 0.772 ± 0.0015
324.28 101.325 0.871 ± 0.0015
271.64 101.325 1.182 ± 0.001.5
252.68 101.325 1.341 ± 0.001.5
237.21 101.325 1.499 ± 0.001.5
299.16 101.325 0.6882 · 10–4*
Comment: relative diffusion coefficients [D(299.16 K) / D(T )] are given as D*12;
Quasi–Lorentzian mixtures; *: absolute value in [m2/s]
Reference
1985W6 Wahby, A.S.M.: Physica C 133 (1985) 93–101.

Diffusion of argon (1); deuterium (2) 1
Diffusion of argon (1); deuterium (2)

Vapor in Gas
Ar (1) argon 7440-37-1

D2 (2) deuterium 7782-39-0
T [K] p [kPa] D
419.23 101.325 0.564 ± 0.0015
398.52 101.325 0.614 ± 0.0015
373.17 101.325 0.685 ± 0.0015
348.28 101.325 0.771 ± 0.0015
324.26 101.325 0.870 ± 0.0015
271.62 101.325 1.183 ± 0.0015
252.66 101.325 1.344 ± 0.0015
237.22 101.325 1.504 ± 0.0015
299.16 101.325 0.5913 · 10–4*
Quasi–Lorentzian mixtures;
*: absolute value in [m2/s]
Reference

Diffusion of argon (1); sulfur hexafluoride (2) 1
Diffusion of argon (1); sulfur hexafluoride (2)

Vapor in Gas
Ar (1) argon 7440-37-1

T [K] p [Torr] D · 104 [m2/s]
287.2 690 0.0871 ± 0.0007
Ar (1) argon 7440-37-1

Diffusion of gas(1) in gas(2): D*12(T ); Method: TB Ref.: 1981L8
T [K] p [kPa] D · 104 [m2/s]
186.5 101.325 0.0352 ± 1.5%
191.3 101.325 0.0380 ± 1.5%
222.3 101.325 0.0488 ± 1.5%
253.1 101.325 0.0628 ± 1.5%
293.9 101.325 0.0831 ± 1.5%
351.7 101.325 0.118 ± 1.5%
439.6 101.325 0.174 ± 1.5%
554.9 101.325 0.271 ± 1.5%
References
1981L8 Loiko, A.E., Ivakin, B.A., Usenko, V.V.: Sov. Phys. Tech. Phys. 26 (1981) 256.


Vapor in Gas
Ar (1) argon 7440-37-1

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D
237.23 101.325 1.501 ± 0.0015
252.67 101.325 1.342 ± 0.0015
271.63 101.325 1.182 ± 0.0015
324.27 101.325 0.871 ± 0.0015
348.26 101.325 0.772 ± 0.0015
373.18 101.325 0.687 ± 0.0015
398.50 101.325 0.615 ± 0.0015
419.22 101.325 0.565 ± 0.0015
Comment: relative diffusion coefficients [D(T0) /D(T )] are given as D*12;
T0 = (299.19 ± 0.15) K; D(T0) = 0.7896 · 10–4 [m2/s]
Ar (1) argon 7440-37-1

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
299.16 ± 0.15 101.325 0.7896
Ar (1) argon 7440-37-1

H2 (2) hydrogen 1333-74-0
Integral Diffusion Coefficient: D(T ); Method: M-INT Ref.: 1965C2
T [K] p [kPa] D · 105 [m2/s]
293.15 101.325 0.73 ± 0.03
References
1985W1 Wahby, A.S.M., Los, J.: Physica C 128 (1985) 243–252.
1965C2 Cordes, H., Kerl, K.: Z. Phys. Chem. Neue Folge 45 (1965) 370–377.


Vapor in Gas
Ar (1) argon 7440-37-1

H 3N (2) ammonia 7664-41-7
T [K] p [kPa] D · 104 [m2/s]
295.1 101.325 0.232
Ar (1) argon 7440-37-1

H 3N (2) ammonia 7664-41-7
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.250
References

Diffusion of argon (1); helium (2)

Vapor in Gas
Ar (1) argon 7440-37-1

He (2) helium 7440-59-7
Diffusion of gas(1) in gas(2): D*12(T ); x1 = 0.100; Method: OEC Ref.: 1974D4
T [K] p [atm] D · 106 [m2/s]
298.15 ± 0.1 50.0 1.28 ± 4%
298.15 ± 0.1 50.0 1.36 ± 4%
298.15 ± 0.1 60.0 1.13 ± 4%
298.15 ± 0.1 70.0 1.00 ± 4%
298.15 ± 0.1 80.0 0.850 ± 4%
298.15 ± 0.1 90.0 0.730 ± 4%
298.15 ± 0.1 100.0 0.655 ± 4%
298.15 ± 0.1 110.0 0.620 ± 4%
298.15 ± 0.1 120.0 0.550 ± 4%
298.15 ± 0.1 140.0 0.490 ± 4%
298.15 ± 0.1 147.0 0.460 ± 4%
298.15 ± 0.1 147.0 0.455 ± 4%
Ar (1) argon 7440-37-1

He (2) helium 7440-59-7
Diffusion of gas(1) in gas(2): D*12(T ); Method: OEC Ref.: 1974D4
T [K] p [atm] D · 107 [m2/s]
298.15 272 2.80
298.15 408 1.85
298.15 543 1.37
298.15 681 1.13
298.15 818 0.95
298.15 1090 0.75
298.15 1360 0.65
Ar (1) argon 7440-37-1

He (2) helium 7440-59-7
Integral Diffusion Coefficient: D(T ); Method: OEC Ref.: 1974D4
145 ± 1.0 86 ± 1 4.94
160 ± 1.0 86 ± 1 4.77
170 ± 1.0 86 ± 1 4.77
180 ± 1.0 86 ± 1 4.88
200 ± 1.0 86 ± 1 5.70
220 ± 1.0 86 ± 1 5.91
Comment: mole fraction x1 = 0.900 in mixture; data at constant density ρA = (86 ± 1) amagat

Ar (1) argon 7440-37-1

He (2) helium 7440-59-7
Integral Diffusion Coefficient: D(T ); Method: OEC Ref.: 1974D4
290 ± 1.0 92 ± 1 6.81 ± 4%
280 ± 1.0 92 ± 1 6.97 ± 4%
270 ± 1.0 92 ± 1 6.01 ± 4%
260 ± 1.0 92 ± 1 6.12 ± 4%
250 ± 1.0 92 ± 1 5.79 ± 4%
240 ± 1.0 92 ± 1 5.42 ± 4%
230 ± 1.0 92 ± 1 5.27 ± 4%
220 ± 1.0 92 ± 1 5.07 ± 4%
210 ± 1.0 92 ± 1 4.80 ± 4%
200 ± 1.0 92 ± 1 4.89 ± 4%
190 ± 1.0 92 ± 1 4.69 ± 4%
180 ± 1.0 92 ± 1 4.41 ± 4%
170 ± 1.0 92 ± 1 4.31 ± 4%
160 ± 1.0 92 ± 1 4.01 ± 4%
150 ± 1.0 92 ± 1 3.95 ± 4%
140 ± 1.0 92 ± 1 4.01 ± 4%
130 ± 1.0 92 ± 1 3.80 ± 4%
120 ± 1.0 92 ± 1 3.50 ± 4%
109 ± 1.0 92 ± 1 3.30 ± 4%
100 ± 1.0 92 ± 1 2.86 ± 4%
90 ± 1.0 92 ± 1 2.78 ± 4%
80 ± 1.0 92 ± 1 2.56 ± 4%
Comment: mole fraction x1 = 0.060 in mixture; data at constant density ρA = (92 ± 1) amagat
Ar (1) argon 7440-37-1

He (2) helium 7440-59-7
T [K] p [atm] D · 106 [m2/s]
219.15 ± 0.1 50.0 0.805 ± 4%
219.15 ± 0.1 60.0 0.650 ± 4%
219.15 ± 0.1 70.0 0.595 ± 4%
219.15 ± 0.1 80.0 0.495 ± 4%
219.15 ± 0.1 90.0 0.440 ± 4%
219.15 ± 0.1 100.0 0.410 ± 4%
219.15 ± 0.1 100.0 0.410 ± 4%
219.15 ± 0.1 106.0 0.380 ± 4%
219.15 ± 0.1 120.0 0.355 ± 4%
Comment: mole fraction x1 = 0.100 in mixture

Ar (1) argon 7440-37-1

He (2) helium 7440-59-7
T [K] p [atm] D · 106 [m2/s]
170 ± 1.0 40.0 0.670 ± 4%
170 ± 1.0 50.0 0.545 ± 4%
170 ± 1.0 60.0 0.445 ± 4%
170 ± 1.0 70.0 0.390 ± 4%
170 ± 1.0 80.0 0.345 ± 4%
170 ± 1.0 90.0 0.315 ± 4%
170 ± 1.0 100.0 0.285 ± 4%
170 ± 1.0 110.0 0.270 ± 4%
Ar (1) argon 7440-37-1

He (2) helium 7440-59-7
T [K] p [atm] D · 106 [m2/s]
99 ± 1.0 40.0 0.275 ± 4%
99 ± 1.0 50.0 0.220 ± 4%
99 ± 1.0 60.0 0.190 ± 4%
99 ± 1.0 70.0 0.175 ± 4%
99 ± 1.0 80.0 0.155 ± 4%
99 ± 1.0 90.0 0.145 ± 4%
99 ± 1.0 100.0 0.130 ± 4%
99 ± 1.0 110.0 0.125 ± 4%
99 ± 1.0 120.0 0.120 ± 4%
99 ± 1.0 130.0 0.120 ± 4%
Ar (1) argon 7440-37-1

He (2) helium 7440-59-7
Diffusion of gas(1) in gas(2): D*12(T ); Method: TAYLOR Ref.: 1970H8
T [K] p [atm] D · 104 [m2/s]
248.15 ± 0.01 9.97 0.0541
248.15 ± 0.01 29.9 0.0184
248.15 ± 0.01 49.8 0.0111
248.15 ± 0.01 59.8 0.00931
273.15 ± 0.01 9.97 0.0634
273.15 ± 0.01 29.9 0.0215
273.15 ± 0.01 49.8 0.0130
273.15 ± 0.01 59.8 0.0109
298.15 ± 0.01 9.97 0.0742
298.15 ± 0.01 29.9 0.0249
298.15 ± 0.01 49.8 0.0152
298.15 ± 0.01 59.8 0.0127
323.15 ± 0.01 9.97 0.0851
(continued)
323.15 ± 0.01 29.9 0.0288

323.15 ± 0.01 49.8 0.0175
323.15 ± 0.01 59.8 0.0145
Ar (1) argon 7440-37-1

He (2) helium 7440-59-7
Diffusion of gas(1) in gas(2): D*12(T ); Method: GC Ref.: 2004K5
T [K] p [atm] D · 104 [m2/s]
298.0 59.8 0.0127
Ar (1) argon 7440-37-1

He (2) helium 7440-59-7
T [K] p [kPa] D · 105 [m2/s]
296.4 101.325 6.86 ± 0.03
References
1974D4 De Paz, M., Tantalo, F., Varni, G.: J. Chem. Phys. 61 (1974) 3875–3880.
1970H8 Hu, A.T.-Ch., Kobayashi, R.: J. Chem. Eng. Data 15 (1970) 328–335.
2004K5 Karaiskakis, G., Gavril, D.: J. Chromatogr. A 1037 (2004) 147–189.

Diffusion of argon (1); krypton (2) 1
Diffusion of argon (1); krypton (2)

Vapor in Gas
Ar (1) argon 7440-37-1

Kr (2) krypton 7439-90-9
Diffusion of gas(1) in gas(2): D*12(T ); Method: TB Ref.: 1979C3
T [K] p [kPa] D · 104 [m2/s]
339.0 ± 0.2% 101.325 0.184 ± 1.5%
458.5 ± 0.2% 101.325 0.318 ± 1.5%
599.8 ± 0.2% 101.325 0.503 ± 1.5%
821.3 ± 0.2% 101.325 0.882 ± 1.5%
1009.0 ± 0.2% 101.325 1.27 ± 1.5%
1195.2 ± 0.2% 101.325 1.72 ± 1.5%
Ar (1) argon 7440-37-1

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
199.5 101.325 0.0720
273.0 101.325 0.126
273.0 101.325 0.119
288.0 101.325 0.128
303.0 101.325 0.140
318.0 101.325 0.153
353.0 101.325 0.197
373.0 101.325 0.216
473.0 101.325 0.327
References
1979C3 Cain, D., Taylor, W.L.: J. Chem. Phys. 71 (1979) 3601–3607.

Diffusion of argon (1); nitrogen oxide (2) 1
Diffusion of argon (1); nitrogen oxide (2)

Vapor in Gas
Ar (1) argon 7440-37-1

T [K] p [Torr] D
420.49 340 0.54722
398.45 340 0.60139
373.27 340 0.67445
348.62 340 0.76123
324.59 340 0.86417
271.50 340 1.19110
255.47 340 1.33040
237.33 340 1.52190
Comment: relative diffusion coefficients [D(T0) /D(T )] are given as D*12; T0 = 299.14 K
Reference
1974W1 Wahby, A.S.M., Boerboom, A.J.H., Los, J.: Physica 75 (1974) 573–582.


Vapor in Gas
Ar (1) argon 7440-37-1

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D
445.26 ± 0.02 101.325 0.508 ± 0.1%
420.52 ± 0.02 101.325 0.551 ± 0.1%
398.34 ± 0.02 101.325 0.613 ± 0.1%
376.36 ± 0.02 101.325 0.682 ± 0.1%
352.45 ± 0.02 101.325 0.759 ± 0.1%
329.52 ± 0.02 101.325 0.862 ± 0.1%
276.41 ± 0.02 101.325 1.168 ± 0.1%
255.47 ± 0.02 101.325 1.340 ± 0.1%
235.61 ± 0.02 101.325 1.548 ± 0.1%
212.43 ± 0.02 101.325 1.852 ± 0.1%
299.16 ± 0.02 101.325 0.1974 · 10–4*
Quasi–Lorentzian mixtures;
Ar (1) argon 7440-37-1

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D
445.37 ± 0.02 101.325 0.504 ± 0.1%
420.62 ± 0.02 101.325 0.548 ± 0.1%
398.44 ± 0.02 101.325 0.610 ± 0.1%
376.28 ± 0.02 101.325 0.672 ± 0.1%
352.52 ± 0.02 101.325 0.750 ± 0.1%
329.48 ± 0.02 101.325 0.855 ± 0.1%
276.35 ± 0.02 101.325 1.164 ± 0.1%
255.58 ± 0.02 101.325 1.335 ± 0.1%
235.54 ± 0.02 101.325 1.541 ± 0.1%
212.32 ± 0.02 101.325 1.848 ± 0.1%
299.16 ± 0.02 101.325 0.2014 · 10–4*
Lorentzian mixtures;

Ar (1) argon 7440-37-1

N2 (2) nitrogen 7727-37-9
T [K] p [MPa] D · 106 [m2/s]
344.0 0.8 3.02 ± 5%
344.0 0.8 3.15 ± 5%
Ar (1) argon 7440-37-1

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.211 ± 2%
Ar (1) argon 7440-37-1

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.1 101.325 0.189
References
1978K3 Kolk, J.F.M., Matulewicz, E.R.A., Moulijn, J.A.: J. Chromatogr. 160 (1978) 11–28.

Diffusion of argon (1); neon (2) 1
Diffusion of argon (1); neon (2)

Vapor in Gas
Ar (1) argon 7440-37-1

Ne (2) neon 7440-01-9
T [K] p [kPa] D · 104 [m2/s]
296.0 101.325 0.315 ± 2%
356.2 101.325 0.437 ± 2%
520.1 101.325 0.822 ± 2%
696.0 101.325 1.34 ± 2%
843.4 101.325 1.86 ± 2%
1010.9 101.325 2.51 ± 2%
1184.4 101.325 3.30 ± 2%
1363.4 101.325 4.05 ± 2%
Reference
1974W5 Weissman, S.: Phys. Fluids 17 (1974) 254–255.


Vapor in Gas
Ar (1) argon 7440-37-1

O2 (2) oxygen 7782-44-7
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.1 101.325 0.196
Reference

Diffusion of argon (1); sulfur dioxide (2) 1
Diffusion of argon (1); sulfur dioxide (2)

Vapor in Gas
Ar (1) argon 7440-37-1

T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.1 101.325 0.130
Reference


Vapor in Gas
Ar (1) argon 7440-37-1

Xe (2) xenon 7440-63-3
Diffusion of gas(1) in gas(2): D*12(T ); Method: TB Ref.: 1965M1
T [K] p [kPa] D · 104 [m2/s]
273.3 ± 0.1 101.325 0.0935
315.0 ± 0.1 101.325 0.1326
354.1 ± 0.1 101.325 0.1620
394.1 ± 0.1 101.325 0.1920
Ar (1) argon 7440-37-1

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
194.7 101.325 0.0508
273.2 101.325 0.0962
329.9 101.325 0.1366
378.0 101.325 0.1759
References
1965M1 Malinauskas, A.P.: J. Chem. Phys. 42 (1965) 156–159.

Diffusion of bromine (1); air (2) 1
Diffusion of bromine (1); air (2)

Vapor in Gas
Br2 (1) bromine 7726-95-6

Air (2) air 132259-10-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: STEFAN Ref.: 1968L3
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 10.64 ± 0.072
Reference
1968L3 Lugg, G.A.: Anal. Chem. 40 (1968) 1072–1077.

Diffusion of bromine (1); hydrogen (2) 1
Diffusion of bromine (1); hydrogen (2)

Vapor in Gas
Br2 (1) bromine 7726-95-6

H2 (2) hydrogen 1333-74-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: No Info Ref.: 1997B6
T [K] p [kPa] D · 106 [m2/s]
273.2 101.325 56.30
Reference
1997B6 Berezhnoi, A.N., Semenov, A.V.: Binary diffusion coefficients of liquid vapors in gases, New
York: Begell House, 1997.

Diffusion of dichloro-difluoro-methane (1); air (2) 1
Diffusion of dichloro-difluoro-methane (1); air (2)

Vapor in Gas
CCl2F2 (1) dichloro-difluoro-methane 75-71-8

Air (2) air 132259-10-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: TAYLOR Ref.: 1994M1
T [K] p [kPa] D · 104 [m2/s]
273.15 101.325 0.0873 ± 2%
273.15 101.325 0.0886 ± 2%
303.15 101.325 0.105 ± 2%
303.15 101.325 0.103 ± 2%
303.15 101.325 0.106 ± 2%
303.15 101.325 0.105 ± 2%
333.15 101.325 0.121 ± 2%
333.15 101.325 0.126 ± 2%
333.15 101.325 0.124 ± 2%
333.15 101.325 0.125 ± 2%
363.15 101.325 0.146 ± 2%
363.15 101.325 0.142 ± 2%
363.15 101.325 0.144 ± 2%
393.15 101.325 0.166 ± 2%
393.15 101.325 0.165 ± 2%
423.15 101.325 0.189 ± 2%
423.15 101.325 0.187 ± 2%
453.15 101.325 0.213 ± 2%
453.15 101.325 0.214 ± 2%

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
273.15 ± 0.5 101.325 0.0873 ± 2%
273.15 ± 0.5 101.325 0.0886 ± 2%
303.15 ± 0.5 101.325 0.105 ± 2%
303.15 ± 0.5 101.325 0.103 ± 2%
303.15 ± 0.5 101.325 0.106 ± 2%
303.15 ± 0.5 101.325 0.105 ± 2%
333.15 ± 0.5 101.325 0.121 ± 2%
333.15 ± 0.5 101.325 0.126 ± 2%
333.15 ± 0.5 101.325 0.124 ± 2%
333.15 ± 0.5 101.325 0.125 ± 2%
363.15 ± 0.5 101.325 0.146 ± 2%
363.15 ± 0.5 101.325 0.142 ± 2%
363.15 ± 0.5 101.325 0.144 ± 2%
393.15 ± 0.5 101.325 0.166 ± 2%
393.15 ± 0.5 101.325 0.165 ± 2%
(continued)
2 Diffusion of dichloro-difluoro-methane (1); air (2)
423.15 ± 0.5 101.325 0.189 ± 2%

423.15 ± 0.5 101.325 0.187 ± 2%
453.15 ± 0.5 101.325 0.213 ± 2%
453.15 ± 0.5 101.325 0.214 ± 2%
References
1994M1 Matsunaga, N., Hori, M., Nagashima, A.: Trans. Jap. Soc. Mech. Eng. B 60 (1994) 504–507.
1993M3 Matsunaga, N., Hori, M., Nagashima A.: High Temperatures-High Pressures 25 (1993)
185–192.

Diffusion of dichloro-difluoro-methane (1); argon (2) 1
Diffusion of dichloro-difluoro-methane (1); argon (2)

Vapor in Gas

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.0903
303.15 101.325 0.0890
303.15 101.325 0.0892
303.15 101.325 0.0901
333.15 101.325 0.106
333.15 101.325 0.105
363.15 101.325 0.123
363.15 101.325 0.122
393.15 101.325 0.140
393.15 101.325 0.139
423.15 101.325 0.164
423.15 101.325 0.158
423.15 101.325 0.161
453.15 101.325 0.183
453.15 101.325 0.179
Reference
2003M2 Matsunaga, N., Hori, M., Nagashima, A.: Netsu Bussei 17 (2003) 154–161.

Diffusion of dichloro-difluoro-methane (1); carbon dioxide (2) 1
Diffusion of dichloro-difluoro-methane (1); carbon dioxide

(2)
Vapor in Gas

T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.0676
303.15 101.325 0.0667
333.15 101.325 0.0814
333.15 101.325 0.0802
363.15 101.325 0.0967
363.15 101.325 0.0946
393.15 101.325 0.110
393.15 101.325 0.109
423.15 101.325 0.125
423.15 101.325 0.123
453.15 101.325 0.142
Reference

Diffusion of dichloro-difluoro-methane (1); ethanol (2) 1
Diffusion of dichloro-difluoro-methane (1); ethanol (2)

Vapor in Gas

T [K] p [kPa] D · 104 [m2/s]
298.2 101.325 0.0475
Reference

Diffusion of dichloro-difluoro-methane (1); propane (2) 1
Diffusion of dichloro-difluoro-methane (1); propane (2)

Vapor in Gas

C3H8 (2) propane 74-98-6
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.0553
303.15 101.325 0.0542
333.15 101.325 0.0648
333.15 101.325 0.0656
363.15 101.325 0.0771
363.15 101.325 0.0773
393.15 101.325 0.0901
393.15 101.325 0.0899
393.15 101.325 0.0913
423.15 101.325 0.104
423.15 101.325 0.105
423.15 101.325 0.102
453.15 101.325 0.120
453.15 101.325 0.118
Reference

Diffusion of dichloro-difluoro-methane (1); benzene (2) 1
Diffusion of dichloro-difluoro-methane (1); benzene (2)

Vapor in Gas

C6H6 (2) benzene 71-43-2
T [K] p [kPa] D · 104 [m2/s]
298.2 101.325 0.0385
Reference

Diffusion of dichloro-difluoro-methane (1); water (2) 1
Diffusion of dichloro-difluoro-methane (1); water (2)

Vapor in Gas

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 104 [m2/s]
298.2 101.325 0.105
Reference

Diffusion of dichloro-difluoro-methane (1); nitrogen (2) 1
Diffusion of dichloro-difluoro-methane (1); nitrogen (2)

Vapor in Gas

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.103
333.15 101.325 0.123
363.15 101.325 0.144
363.15 101.325 0.145
363.15 101.325 0.142
393.15 101.325 0.164
423.15 101.325 0.187
453.15 101.325 0.213
Reference

Diffusion of dichloro-difluoro-methane (1); neon (2) 1
Diffusion of dichloro-difluoro-methane (1); neon (2)

Vapor in Gas

Ne (2) neon 7440-01-9
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.154
303.15 101.325 0.152
333.15 101.325 0.180
333.15 101.325 0.178
363.15 101.325 0.206
363.15 101.325 0.204
393.15 101.325 0.238
393.15 101.325 0.239
423.15 101.325 0.263
423.15 101.325 0.269
453.15 101.325 0.298
Reference

Diffusion of dichloro-difluoro-methane (1); oxygen (2) 1
Diffusion of dichloro-difluoro-methane (1); oxygen (2)

Vapor in Gas

O2 (2) oxygen 7782-44-7
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.103
333.15 101.325 0.122
363.15 101.325 0.142
393.15 101.325 0.164
423.15 101.325 0.188
453.15 101.325 0.211
Reference

Diffusion of trichloro-fluoro-methane (1); air (2) 1
Diffusion of trichloro-fluoro-methane (1); air (2)

Vapor in Gas
CCl3F (1) trichloro-fluoro-methane 75-69-4

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
303.15 ± 0.5 101.325 0.0940 ± 2%
303.15 ± 0.5 101.325 0.0926 ± 2%
313.15 ± 0.5 101.325 0.0985 ± 2%
313.15 ± 0.5 101.325 0.100 ± 2%
313.15 ± 0.5 101.325 0.0992 ± 2%
333.15 ± 0.5 101.325 0.111 ± 2%
333.15 ± 0.5 101.325 0.113 ± 2%
363.15 ± 0.5 101.325 0.128 ± 2%
363.15 ± 0.5 101.325 0.131 ± 2%
363.15 ± 0.5 101.325 0.128 ± 2%
393.15 ± 0.5 101.325 0.149 ± 2%
393.15 ± 0.5 101.325 0.149 ± 2%
423.15 ± 0.5 101.325 0.171 ± 2%
423.15 ± 0.5 101.325 0.171 ± 2%
453.15 ± 0.5 101.325 0.195 ± 2%
453.15 ± 0.5 101.325 0.190 ± 2%
453.15 ± 0.5 101.325 0.191 ± 2%

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.0940 ± 2%
303.15 101.325 0.0926 ± 2%
313.15 101.325 0.0985 ± 2%
313.15 101.325 0.100 ± 2%
313.15 101.325 0.0992 ± 2%
333.15 101.325 0.111 ± 2%
333.15 101.325 0.113 ± 2%
333.15 101.325 0.111 ± 2%
363.15 101.325 0.128 ± 2%
363.15 101.325 0.131 ± 2%
393.15 101.325 0.149 ± 2%
393.15 101.325 0.149 ± 2%
423.15 101.325 0.171 ± 2%
423.15 101.325 0.171 ± 2%
453.15 101.325 0.195 ± 2%
453.15 101.325 0.190 ± 2%
453.15 101.325 0.191 ± 2%

2 Diffusion of trichloro-fluoro-methane (1); air (2)
References
1993M3 Matsunaga, N., Hori, M., Nagashima, A.: High Temperatures-High Pressures 25 (1993)
185–192.

Diffusion of trichloro-nitro-methane (1); air (2) 1
Diffusion of trichloro-nitro-methane (1); air (2)

Vapor in Gas
CCl3NO2 (1) trichloro-nitro-methane 76-06-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 8.11 ± 0.096
Reference

Diffusion of tetrachloro-methane (1); air (2) 1
Diffusion of tetrachloro-methane (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
293.15 101.325 0.1200

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 8.28 ± 0.063

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.2 ± 1.0 101.325 0.0759 ± 0.0017

Air (2) air 132259-10-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: STEFAN Ref.: 1971W2
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.02 101.325 7.59 ± 0.08
308.15 ± 0.02 101.325 8.00
313.15 ± 0.02 101.325 8.45
328.15 ± 0.02 101.325 8.89
338.15 ± 0.02 101.325 9.33
348.15 ± 0.02 101.325 9.79
Comment: Values corrected for gas imperfection
References
1985I1 Iiyasov, L.V., Negrtov, Y.B.: Zavod. Lab. 51 (1985) 32–34.
1971C5 Cowie, M., Watts, H.: Can. J. Chem. 49 (1971) 74–77.

Diffusion of tetrachloro-methane (1); tetrafluoro-methane (2) 1
Diffusion of tetrachloro-methane (1); tetrafluoro-methane

(2)
Vapor in Gas

Diffusion of gas(1) in gas(2): D*12(T ); Method: CT Ref.: 1988T3
T [K] p [bar] D · 104 [m2/s]
298.20 ± 0.01 100 0.0404 ± 1%
Reference
1988T3 Tominaga, T., Park, T., Rettich, T.R., Battino, R., Wilhelm, E.: J. Chem. Eng. Data 33 (1988)
479–481.

Diffusion of tetrachloro-methane (1); methane (2) 1
Diffusion of tetrachloro-methane (1); methane (2)

Vapor in Gas

CH4 (2) methane 74-82-8
T [K] p [bar] D · 104 [m2/s]
283.15 ± 0.01 100 0.0786 ± 1%
Reference
479–481.

Diffusion of tetrachloro-methane (1); carbon dioxide (2) 1
Diffusion of tetrachloro-methane (1); carbon dioxide (2)

Vapor in Gas

Diffusion of gas(1) in gas(2): D*12(T ); Method: GC Ref.: 1970N1
T [K] p [kPa] D · 104 [m2/s]
363.3 ± 0.2 101.325 0.085
384.3 ± 0.2 101.325 0.093
403.1 ± 0.2 101.325 0.100
423.0 ± 0.2 101.325 0.111
Reference
1970N1 Nagata, I., Hasegawa, T.: J. Chem. Eng. Jpn. 3 (1970) 143–145.

Diffusion of tetrachloro-methane (1); nitrogen (2) 1
Diffusion of tetrachloro-methane (1); nitrogen (2)

Vapor in Gas

N2 (2) nitrogen 7727-37-9
Diffusion of gas(1) in gas(2): D*12(T ); Method: STEFAN Ref.: 1981S5
T [K] p [MPa] D · 104 [m2/s]
298.15 0.1013 84.2 ± 5%
298.15 0.196 42.5 ± 5%
298.15 0.294 28.6 ± 5%
298.15 0.981 8.24 ± 5%
298.15 2.45 3.22 ± 5%
298.15 5.34 1.35 ± 5%
323.15 0.104 99.1 ± 5%
323.15 0.196 47.2 ± 5%
323.15 0.294 31.3 ± 5%
323.15 0.392 22.8 ± 5%
323.15 0.981 8.75 ± 5%
323.15 2.45 3.96 ± 5%
323.15 5.54 1.86 ± 5%

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
363.7 ± 0.2 101.325 0.113
383.2 ± 0.2 101.325 0.124
403.2 ± 0.2 101.325 0.134
423.2 ± 0.2 101.325 0.147
References
1981S5 Semenov, A.V., Berezhnoi, A.N.: Zh. Fiz. Khim. 55 (1981) 2396–2398.

Diffusion of tetrafluoro-methane (1); argon (2) 1
Diffusion of tetrafluoro-methane (1); argon (2)

Vapor in Gas

Ar (2) argon 7440-37-1
Diffusion of gas(1) in gas(2): D*12(T ); Method: NMR FG Ref.: 1963R2
T [K] p [kPa] D · 109 [m2/s]
70 ± 0.25 101.325 0.137
72 ± 0.25 101.325 0.330
75 ± 0.25 101.325 0.599
77 ± 0.25 101.325 0.694
81 ± 0.25 101.325 0.913
85 ± 0.25 101.325 1.09
87 ± 0.25 101.325 1.15
89 ± 0.25 101.325 1.42
91 ± 0.25 101.325 1.38
93 ± 0.25 101.325 1.60
97 ± 0.25 101.325 1.72
101 ± 0.25 101.325 1.87
101.5 ± 0.25 101.325 1.88
105.5 ± 0.25 101.325 1.88
109 ± 0.25 101.325 1.84
109.5 ± 0.25 101.325 1.95
111 ± 0.25 101.325 1.70
113 ± 0.25 101.325 1.21
117 ± 0.25 101.325 1.46
121 ± 0.25 101.325 1.51
125 ± 0.25 101.325 1.68
130 ± 0.25 101.325 1.74
133 ± 0.25 101.325 1.84
Reference

Diffusion of tetrafluoro-methane (1); helium (2) 1
Diffusion of tetrafluoro-methane (1); helium (2)

Vapor in Gas

He (2) helium 7440-59-7
Diffusion of gas(1) in gas(2): D*12(T ); Method: GC Ref.: 1970B6
T [K] p [atm] D · 107 [m2/s]
298.15 272 1.85
298.15 408 1.22
298.15 543 0.94
298.15 681 0.78
298.15 818 0.65
298.15 1090 0.57
298.15 1360 0.54
Reference
1970B6 Balenovic, Z., Myers, M.N., Giddings, J.C.: J. Chem. Phys. 52 (1970) 915–922.

Diffusion of tribromo-methane (1); air (2) 1
Diffusion of tribromo-methane (1); air (2)

Vapor in Gas
CHBr3 (1) tribromo-methane 75-25-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.67 ± 0.115
Reference

Diffusion of chloro-difluoro-methane (1); air (2) 1
Diffusion of chloro-difluoro-methane (1); air (2)

Vapor in Gas
CHClF2 (1) chloro-difluoro-methane 75-45-6

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
273.15 101.325 0.105 ± 2%
273.15 101.325 0.103 ± 2%
273.15 101.325 0.104 ± 2%
303.15 101.325 0.122 ± 2%
303.15 101.325 0.123 ± 2%
303.15 101.325 0.123 ± 2%
303.15 101.325 0.122 ± 2%
303.15 101.325 0.016 ± 2%
333.15 101.325 0.147 ± 2%
333.15 101.325 0.146 ± 2%
333.15 101.325 0.146 ± 2%
333.15 101.325 0.145 ± 2%
363.15 101.325 0.168 ± 2%
363.15 101.325 0.170 ± 2%
393.15 101.325 0.195 ± 2%
393.15 101.325 0.195 ± 2%
393.15 101.325 0.194 ± 2%
423.15 101.325 0.219 ± 2%
423.15 101.325 0.217 ± 2%
453.15 101.325 0.245 ± 2%
453.15 101.325 0.244 ± 2%

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
273.15 ± 0.5 101.325 0.105 ± 2%
273.15 ± 0.5 101.325 0.103 ± 2%
273.15 ± 0.5 101.325 0.104 ± 2%
303.15 ± 0.5 101.325 0.122 ± 2%
303.15 ± 0.5 101.325 0.123 ± 2%
303.15 ± 0.5 101.325 0.123 ± 2%
303.15 ± 0.5 101.325 0.122 ± 2%
303.15 ± 0.5 101.325 0.126 ± 2%
333.15 ± 0.5 101.325 0.147 ± 2%
333.15 ± 0.5 101.325 0.146 ± 2%
333.15 ± 0.5 101.325 0.146 ± 2%
333.15 ± 0.5 101.325 0.145 ± 2%
363.15 ± 0.5 101.325 0.168 ± 2%
(continued)
2 Diffusion of chloro-difluoro-methane (1); air (2)
363.15 ± 0.5 101.325 0.170 ± 2%

393.15 ± 0.5 101.325 0.195 ± 2%
393.15 ± 0.5 101.325 0.195 ± 2%
393.15 ± 0.5 101.325 0.194 ± 2%
423.15 ± 0.5 101.325 0.219 ± 2%
423.15 ± 0.5 101.325 0.217 ± 2%
453.15 ± 0.5 101.325 0.245 ± 2%
453.15 ± 0.5 101.325 0.244 ± 2%
References
1994M4 Mills, R., Malhotra, R., Woolf, L.A., Miller, D.G.: J. Phys. Chem. 98 (1994) 5565–5575.
185–192.

Diffusion of chloro-difluoro-methane (1); argon (2) 1
Diffusion of chloro-difluoro-methane (1); argon (2)

Vapor in Gas

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.107
303.15 101.325 0.105
333.15 101.325 0.123
333.15 101.325 0.125
363.15 101.325 0.144
363.15 101.325 0.145
393.15 101.325 0.169
393.15 101.325 0.166
423.15 101.325 0.190
453.15 101.325 0.210
453.15 101.325 0.211
Reference

Diffusion of chloro-difluoro-methane (1); propane (2) 1
Diffusion of chloro-difluoro-methane (1); propane (2)

Vapor in Gas

C3H8 (2) propane 74-98-6
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.0651
303.15 101.325 0.0656
303.15 101.325 0.0668
333.15 101.325 0.0766
333.15 101.325 0.0782
333.15 101.325 0.0795
363.15 101.325 0.0937
363.15 101.325 0.0930
393.15 101.325 0.109
393.15 101.325 0.105
423.15 101.325 0.123
453.15 101.325 0.137
Reference

Diffusion of chloro-difluoro-methane (1); nitrogen (2) 1
Diffusion of chloro-difluoro-methane (1); nitrogen (2)

Vapor in Gas

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.124
333.15 101.325 0.147
333.15 101.325 0.144
363.15 101.325 0.171
393.15 101.325 0.195
393.15 101.325 0.190
423.15 101.325 0.220
423.15 101.325 0.218
453.15 101.325 0.242
453.15 101.325 0.249
Reference

Diffusion of chloro-difluoro-methane (1); neon (2) 1
Diffusion of chloro-difluoro-methane (1); neon (2)

Vapor in Gas

Ne (2) neon 7440-01-9
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.183
303.15 101.325 0.184
303.15 101.325 0.185
333.15 101.325 0.216
333.15 101.325 0.211
363.15 101.325 0.248
393.15 101.325 0.281
393.15 101.325 0.275
423.15 101.325 0.311
423.15 101.325 0.308
453.15 101.325 0.353
453.05 101.325 0.347
Reference

Diffusion of chloro-difluoro-methane (1); oxygen (2) 1
Diffusion of chloro-difluoro-methane (1); oxygen (2)

Vapor in Gas

O2 (2) oxygen 7782-44-7
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.123
333.15 101.325 0.145
363.15 101.325 0.169
363.15 101.325 0.171
393.15 101.325 0.194
423.15 101.325 0.219
423.15 101.325 0.221
453.15 101.325 0.246
453.15 101.325 0.247
Reference

Diffusion of trichloro-methane (1); air (2) 1
Diffusion of trichloro-methane (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.02 101.325 8.88 ± 0.074
308.15 ± 0.02 101.325 9.34
318.15 ± 0.02 101.325 9.81
328.15 ± 0.02 101.325 10.28

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.2 ± 1.0 101.325 0.0862 ± 0.0015

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 8.88 ± 0.187
References

Diffusion of trichloro-methane (1); carbon dioxide (2) 1
Diffusion of trichloro-methane (1); carbon dioxide (2)

Vapor in Gas

T [K] p [kPa] D · 104 [m2/s]
363.3 ± 0.2 101.325 0.110
383.3 ± 0.2 101.325 0.120
403.8 ± 0.2 101.325 0.129
Reference

Diffusion of trichloro-methane (1); helium (2) 1
Diffusion of trichloro-methane (1); helium (2)

Vapor in Gas

He (2) helium 7440-59-7
Diffusion of gas(1) in gas(2): D*12(T ); Method: TAYLOR Ref.: 1969F2
T [K] p [kPa] D · 104 [m2/s]
429.1 ± 0.2 101.325 0.624 ± 0.012
Reference
1969F2 Fuller, E.N., Ensley, K., Giddings, J.C.: J. Phys. Chem. 73 (1969) 3679–3685.

Diffusion of trichloro-methane (1); nitrogen (2) 1
Diffusion of trichloro-methane (1); nitrogen (2)

Vapor in Gas

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
361.0 ± 0.2 101.325 0.135
383.2 ± 0.2 101.325 0.143
403.2 ± 0.2 101.325 0.161
418.2 ± 0.2 101.325 0.173
Reference

Diffusion of bromo-chloro-methane (1); air (2) 1
Diffusion of bromo-chloro-methane (1); air (2)

Vapor in Gas
CH2BrCl (1) bromo-chloro-methane 74-97-5

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 9.53 ± 0.063
Reference

Diffusion of dibromo-methane (1); helium (2) 1
Diffusion of dibromo-methane (1); helium (2)

Vapor in Gas
CH2Br2 (1) dibromo-methane 74-95-3

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
427.7 ± 0.2 101.325 0.665 ± 0.007
Reference

Diffusion of dichloro-methane (1); air (2) 1
Diffusion of dichloro-methane (1); air (2)

Vapor in Gas
CH2Cl2 (1) dichloro-methane 75-09-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
288.15 ± 0.02 101.325 9.70
298.15 ± 0.02 101.325 10.16 ± 0.13
308.15 ± 0.02 101.325 10.64

Air (2) air 132259-10-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: OTE Ref.: 2004K6
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.0881 ± 0.0002
299.35 101.325 0.1095 ± 0.0011

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.2 ± 1.0 101.325 0.1042 ± 0.0049

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 10.37 ± 0.490
References
2004K6 Kwon, K.C., Ibrahim, T.H., Park, Y., Simmons, C.M.: Adv. Environ. Res. 8 (2004) 667–678.

Diffusion of dichloro-methane (1); helium (2) 1
Diffusion of dichloro-methane (1); helium (2)

Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
427.5 ± 0.2 101.325 0.750 ± 0.009
Reference

Diffusion of difluoro-methane (1); air (2) 1
Diffusion of difluoro-methane (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
273.15 101.325 0.1305
303.15 101.325 0.1565
333.15 101.325 0.187
333.15 101.325 0.192
363.15 101.325 0.223
393.15 101.325 0.2585
423.15 101.325 0.297
423.15 101.325 0.304
453.15 101.325 0.346
453.15 101.325 0.335
Reference

Diffusion of difluoro-methane (1); propane (2) 1
Diffusion of difluoro-methane (1); propane (2)

Vapor in Gas

C3H8 (2) propane 74-98-6
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.0865
303.15 101.325 0.0856
333.15 101.325 0.105
363.15 101.325 0.125
363.15 101.325 0.128
393.15 101.325 0.149
393.15 101.325 0.148
423.15 101.325 0.169
423.15 101.325 0.173
453.15 101.325 0.196
453.15 101.325 0.199
Reference

Diffusion of difluoro-methane (1); helium (2) 1
Diffusion of difluoro-methane (1); helium (2)

Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
430.8 ± 0.2 101.325 0.874 ± 0.030
Reference

Diffusion of difluoro-methane (1); neon (2) 1
Diffusion of difluoro-methane (1); neon (2)

Vapor in Gas

Ne (2) neon 7440-01-9
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.240
303.15 101.325 0.239
303.15 101.325 0.237
333.15 101.325 0.281
333.15 101.325 0.278
363.15 101.325 0.323
363.15 101.325 0.324
393.15 101.325 0.375
393.15 101.325 0.370
423.15 101.325 0.417
423.15 101.325 0.414
Reference

Diffusion of diiodo-methane (1); air (2) 1
Diffusion of diiodo-methane (1); air (2)

Vapor in Gas
CH2I2 (1) diiodo-methane 75-11-6

Air (2) air 132259-10-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: No Info Ref.: 1979M1
T [K] p [kPa] D · 106 [m2/s]
298.2 101.325 6.0 ± 0.5
CH2I2 (1) diiodo-methane 75-11-6

Air (2) air 132259-10-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: No Stand Ref.: 2000E1
T [K] p [kPa] D · 104 [m2/s]
294.15 101.325 0.118
Comment: hanging drop evaporation
References
1979M1 Masliyah, J.H., Labrenz, A.J., Fedorkiw, E.: J. Chem. Eng. Data 24 (1979) 83–84.
2000E1 Erbil, H.Y., Dogan, M.: Langmuir 16 (2000) 9267–9273.

Diffusion of formic acid (1); air (2) 1
Diffusion of formic acid (1); air (2)

Vapor in Gas
CH2O2 (1) formic acid 64-18-6

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 15.30 ± 0.154
CH2O2 (1) formic acid 64-18-6

Air (2) air 132259-10-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: No Info Ref.: 1997G1
T [K] p [kPa] D · 104 [m2/s]
290.15 ± 1.0 101.325 0.127 ± 0.005
References
1997G1 Gibson, L.T., Cooksey, B.G., Littlejohn, D., Tennent, N.H.: Anal. Chim. Acta 341 (1997) 1–10.

Diffusion of chloro-methane (1); air (2) 1
Diffusion of chloro-methane (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.2 ± 1.0 101.325 0.1434 ± 0.0024
Reference

Diffusion of iodo-methane (1); helium (2) 1
Diffusion of iodo-methane (1); helium (2)

Vapor in Gas
CH3I (1) iodo-methane 74-88-4

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
431.2 ± 0.2 101.325 0.783 ± 0.016
Reference

Diffusion of nitromethane (1); air (2) 1
Diffusion of nitromethane (1); air (2)

Vapor in Gas
CH3NO2 (1) nitromethane 75-52-5

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
292.85 101.325 0.093
Reference

Diffusion of methane-t (1); argon (2) 1
Diffusion of methane-t (1); argon (2)

Vapor in Gas
CH3T (1) methane-t 676-51-7

Ar (2) argon 7440-37-1
Diffusion of gas(1) in gas(2): D*12(T ); Method: PF Ref.: 1974T6
T [K] p [atm] D · 107 [m2/s]
348.15 14.41 19.6
348.15 14.41 19.7
348.15 50.0 5.76
348.15 101.8 2.66
348.15 151.0 1.88
348.15 202.6 1.33
348.15 247.1 1.17

Ar (2) argon 7440-37-1
T [K] p [atm] D · 107 [m2/s]
323.15 14.41 17.1
323.15 14.41 17.0
323.15 14.44 17.1
323.15 50.1 4.91
323.15 50.9 4.71
323.15 99.2 2.54
323.15 101.8 2.48
323.15 149.8 1.61
323.15 200.4 1.21
323.15 201.8 1.19
323.15 235.8 1.08
323.15 253.5 0.974

Ar (2) argon 7440-37-1
T [K] p [atm] D · 107 [m2/s]
298.15 14.45 15.8
298.15 14.47 15.2
298.15 14.58 14.9
298.15 48.9 4.53
298.15 49.7 4.51
298.15 50.9 4.44
298.15 101.5 2.23
298.15 109.0 2.05
298.15 144.3 1.49
(continued)

2 Diffusion of methane-t (1); argon (2)
298.15 196.4 1.12

298.15 245.6 0.885
Reference

Diffusion of methane-t (1); tetrafluoro-methane (2) 1
Diffusion of methane-t (1); tetrafluoro-methane (2)

Vapor in Gas

T [K] p [atm] D · 104 [m2/s]
298.15 ± 0.01 2.05 0.0688
298.15 ± 0.01 6.78 0.0204
298.15 ± 0.01 20.4 0.00643
298.15 ± 0.01 33.9 0.00373
298.15 ± 0.01 47.5 0.00240
298.15 ± 0.01 61.1 0.00177
Reference

Diffusion of methane-t (1); methane (2) 1
Diffusion of methane-t (1); methane (2)

Vapor in Gas

CH4 (2) methane 74-82-8
T [K] p [atm] D · 104 [m2/s]
298.15 ± 0.01 2.04 0.106
298.15 ± 0.01 6.78 0.0319
298.15 ± 0.01 20.4 0.0100
298.15 ± 0.01 33.9 0.00598
298.15 ± 0.01 47.5 0.00429
298.15 ± 0.01 61.12 0.00323
Reference

Diffusion of methane (1); air (2) 1
Diffusion of methane (1); air (2)

Vapor in Gas
CH4 (1) methane 74-82-8

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
293.15 101.325 0.2300
CH4 (1) methane 74-82-8

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.2 ± 1.0 101.325 0.2168 ± 0.0032
CH4 (1) methane 74-82-8

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
273.15 101.325 0.201 ± 2%
273.15 101.325 0.202 ± 2%
303.15 101.325 0.242 ± 2%
303.15 101.325 0.249 ± 2%
303.15 101.325 0.245 ± 2%
303.15 101.325 0.241 ± 2%
333.15 101.325 0.287 ± 2%
333.15 101.325 0.292 ± 2%
333.15 101.325 0.290 ± 2%
333.15 101.325 0.291 ± 2%
363.15 101.325 0.347 ± 2%
363.15 101.325 0.342 ± 2%
363.15 101.325 0.342 ± 2%
393.15 101.325 0.391 ± 2%
393.15 101.325 0.394 ± 2%
423.15 101.325 0.445 ± 2%
423.15 101.325 0.448 ± 2%
453.15 101.325 0.509 ± 2%
453.15 101.325 0.514 ± 2%
References
1998M2 Matsunaga, N., Hori, M., Nagashima, A.: High Temperatures-High Pressures 30 (1998) 77–83.

Diffusion of methane (1); argon (2) 1
Diffusion of methane (1); argon (2)

Vapor in Gas
CH4 (1) methane 74-82-8

Ar (2) argon 7440-37-1
Diffusion of gas(1) in gas(2): D*12(T ); Method: TAYLOR Ref.: 1974W3
T [K] p [bar] D · 104 [m2/s]
308.1 1.013 0.231
323.1 1.013 0.242
374.1 1.013 0.322
426.2 1.013 0.412
475.7 1.013 0.512
526.1 1.013 0.613
574.9 1.013 0.688
628.2 1.013 0.829
673.2 1.013 0.941
Comment: accuracy: ±2%
CH4 (1) methane 74-82-8

Ar (2) argon 7440-37-1
Diffusion of gas(1) in gas(2): D*12(T ); Method: OTE Ref.: 1970J1
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.02 101.325 0.202
CH4 (1) methane 74-82-8

Ar (2) argon 7440-37-1
Diffusion of gas(1) in gas(2): D*12(T ); Method: NMR FG Ref.: 1963R2
T [K] p [kPa] D · 109 [m2/s]
77 ± 0.25 101.325 0.92
77.5 ± 0.25 101.325 1.00
79 ± 0.25 101.325 1.10
81 ± 0.25 101.325 1.32
83 ± 0.25 101.325 1.53
85 ± 0.25 101.325 1.68
87 ± 0.25 101.325 1.96
89 ± 0.25 101.325 2.09
91 ± 0.25 101.325 2.24
93 ± 0.25 101.325 2.41
95 ± 0.25 101.325 2.55
97 ± 0.25 101.325 2.74
99 ± 0.25 101.325 2.94
101 ± 0.25 101.325 3.23
103 ± 0.25 101.325 3.39
105 ± 0.25 101.325 3.53
(continued)

2 Diffusion of methane (1); argon (2)
107 ± 0.25 101.325 3.87

109 ± 0.25 101.325 4.06
References
1974W3 Wakeham, W.A., Slater, D.H.: J. Phys. B 7 (1974) 297–306.
1970J1 Jacobs, T., Peeters, L., Vermant, J.: Bull. Soc. Chim. Belg. 79 (1970) 337–342.

Diffusion of methane (1); tetrafluoro-methane (2)

Vapor in Gas
CH4 (1) methane 74-82-8

T [K] p [kPa] D · 104 [m2/s]
298.2 ± 0.1 101.325 0.122 ± 0.001
352.6 ± 0.1 101.325 0.167 ± 0.001
382.5 ± 0.1 101.325 0.192 ± 0.001
Reference

Diffusion of methane (1); carbon monoxide (2) 1
Diffusion of methane (1); carbon monoxide (2)

Vapor in Gas
CH4 (1) methane 74-82-8

T [K] p [kPa] D · 104 [m2/s]
298.2 ± 0.1 101.325 0.220 ± 0.001
352.6 ± 0.1 101.325 0.295 ± 0.001
382.5 ± 0.1 101.325 0.333 ± 0.001
Reference

Diffusion of methane (1); ethane (2) 1
Diffusion of methane (1); ethane (2)

Vapor in Gas
CH4 (1) methane 74-82-8

C2H6 (2) ethane 74-84-0
T [K] p [bar] D · 107 [m2/s]
313.15 68.95 2.10
313.15 137.9 0.84
313.15 275.8 0.43
313.15 551.58 0.30
313.15 689.48 0.27
333.15 68.95 2.33
333.15 137.9 0.99
333.15 275.8 0.50
333.15 551.58 0.34
333.15 689.48 0.31
350.37 68.95 2.49
350.37 137.9 1.13
350.37 275.8 0.58
350.37 551.58 0.39
350.37 689.48 0.36
CH4 (1) methane 74-82-8

C2H6 (2) ethane 74-84-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: GC Ref.: 1967G7
T [K] p [kPa] D · 104 [m2/s]
298 101.325 0.153
References
1960B4 Berry, V.J., Koeller, R.C.: AIChE J. 6 (1960) 274–280.
1967G7 Gover, T.A.: J. Chem. Educ. 44 (1967) 409–411.

Diffusion of methane (1); propane (2) 1
Diffusion of methane (1); propane (2)

Vapor in Gas
CH4 (1) methane 74-82-8

C3H8 (2) propane 74-98-6
Diffusion of gas(1) in gas(2): D*12(T ); Method: DIA Ref.: 1968G1
T [K] p [MPa] D · 105 [m2/s]
344.26 ± 0.01 4.115 0.0554
344.26 ± 0.01 4.115 0.0647
344.26 ± 0.01 4.115 0.0664
Reference
1968G1 Gavalas, G.R., Reamer, H.H., Sage, B.H.: Ind. Eng. Chem. Fundam. 7 (1968) 306–312.

Diffusion of methane (1); hydrogen (2) 1
Diffusion of methane (1); hydrogen (2)

Vapor in Gas
CH4 (1) methane 74-82-8

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.73
CH4 (1) methane 74-82-8

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 107 [m2/s]
293.0 101.325 699.0 ± 3.0
CH4 (1) methane 74-82-8

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
273.0 101.325 0.625
298.0 101.325 0.726
References
1961F1 Fejes, P., Czárán, L.: Acta Chim. Hung. 29 (1961) 171–187.
1982K4 Katsanos, N.A., Karaiskakis, G.: J. Chromatogr. 237 (1982) 1–14.

Diffusion of methane (1); water (2) 1
Diffusion of methane (1); water (2)

Vapor in Gas
CH4 (1) methane 74-82-8

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 104 [m2/s]
307.7 101.325 0.292
328.8 101.325 0.331
352.3 101.325 0.356
Reference


Vapor in Gas
CH4 (1) methane 74-82-8

He (2) helium 7440-59-7
T [K] p [kPa] D · 107 [m2/s]
295.7 101.325 527.0 ± 3.0
295.0 101.325 520.0 ± 1.0
296.0 101.325 522.0 ± 1.0
296.0 101.325 514.0 ± 0.2
296.7 101.325 522.0 ± 3.0
CH4 (1) methane 74-82-8

He (2) helium 7440-59-7
T [K] p [atm] D · 107 [m2/s]
298.15 272 2.43
298.15 408 1.62
298.15 543 1.22
298.15 681 0.98
298.15 818 0.85
298.15 1090 0.74
298.15 1360 0.71
CH4 (1) methane 74-82-8

He (2) helium 7440-59-7
Diffusion of gas(1) in gas(2): D*12(T ); Method: GC Ref.: 1976Y5
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.02 101.325 0.6776 ± 0.00141
298.15 ± 0.02 101.325 0.6735 ± 0.000788
Comment: measured with continuous and arrested elution
<Table ID=4_531" Float="Yes">
CH4 (1) methane 74-82-8

He (2) helium 7440-59-7
Diffusion of gas(1) in gas(2): D*12(T ); Method: TAYLOR Ref.: 1974G7
T [K] p [kPa] D · 104 [m2/s]
373.15 ± 0.10 101.325 1.002 ± 0.005

2 Diffusion of methane (1); helium (2)
CH4 (1) methane 74-82-8

He (2) helium 7440-59-7
Diffusion of gas(1) in gas(2): D*12(T ); Method: ARF Ref.: 1986M3
T [K] p [psia] D · 104 [m2/s]
297.15 ± 2.0 30.9 0.292 ± 2%
373.15 ± 2.0 30.8 0.423 ± 2%
CH4 (1) methane 74-82-8

He (2) helium 7440-59-7
T [K] p [atm] D · 104 [m2/s]
248.15 ± 0.01 9.97 0.0501
248.15 ± 0.01 29.9 0.0169
248.15 ± 0.01 49.8 0.0103
248.15 ± 0.01 59.8 0.00872
273.15 ± 0.01 9.97 0.0588
273.15 ± 0.01 29.9 0.0198
273.15 ± 0.01 49.8 0.0119
273.15 ± 0.01 59.8 0.0101
298.15 ± 0.01 9.97 0.0681
298.15 ± 0.01 29.9 0.0229
298.15 ± 0.01 49.8 0.0139
298.15 ± 0.01 59.8 0.0117
323.15 ± 0.01 9.97 0.0781
323.15 ± 0.01 29.9 0.0265
323.15 ± 0.01 49.8 0.0159
323.15 ± 0.01 59.8 0.0134
CH4 (1) methane 74-82-8

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
373.0 101.325 1.005
References
1976Y5 Yang, F., Hawkes, S., Lindstrom, F.T.: J. Am. Chem. Soc. 98 (1976) 5101–5107.
1974G7 Grushka, E., Schnipelsky, P.: J. Phys. Chem. 78 (1974) 1428–1431.
1986M3 McCoy, B.J., Moffat, A.J.: Chem. Eng. Commun. 47 (1986) 219–224.

Diffusion of methane (1); nitrogen (2) 1
Diffusion of methane (1); nitrogen (2)

Vapor in Gas
CH4 (1) methane 74-82-8

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 107 [m2/s]
273.15 101.325 0.205 ± 2%
273.15 101.325 0.206 ± 2%
303.15 101.325 0.242 ± 2%
303.15 101.325 0.247 ± 2%
303.15 101.325 0.243 ± 2%
303.15 101.325 0.243 ± 2%
333.15 101.325 0.287 ± 2%
333.15 101.325 0.292 ± 2%
333.15 101.325 0.289 ± 2%
333.15 101.325 0.289 ± 2%
363.15 101.325 0.342 ± 2%
363.15 101.325 0.338 ± 2%
393.15 101.325 0.397 ± 2%
393.15 101.325 0.394 ± 2%
423.15 101.325 0.447 ± 2%
423.15 101.325 0.446 ± 2%
453.15 101.325 0.516 ± 2%
453.15 101.325 0.516 ± 2%
CH4 (1) methane 74-82-8

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 107 [m2/s]
296.0 101.325 272.0 ± 4.0
CH4 (1) methane 74-82-8

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
298.2 ± 0.1 101.325 0.216 ± 0.001
352.6 ± 0.1 101.325 0.287 ± 0.001
382.5 ± 0.1 101.325 0.332 ± 0.001

2 Diffusion of methane (1); nitrogen (2)
CH4 (1) methane 74-82-8

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.02 101.325 0.210
References

Diffusion of methane (1); oxygen (2) 1
Diffusion of methane (1); oxygen (2)

Vapor in Gas
CH4 (1) methane 74-82-8

O2 (2) oxygen 7782-44-7
T [K] p [kPa] D · 104 [m2/s]
273.15 101.325 0.203 ± 2%
273.15 101.325 0.206 ± 2%
303.15 101.325 0.245 ± 2%
303.15 101.325 0.246 ± 2%
333.15 101.325 0.295 ± 2%
333.15 101.325 0.296 ± 2%
333.15 101.325 0.290 ± 2%
363.15 101.325 0.343 ± 2%
363.15 101.325 0.342 ± 2%
393.15 101.325 0.400 ± 2%
393.15 101.325 0.397 ± 2%
393.15 101.325 0.389 ± 2%
423.15 101.325 0.451 ± 2%
423.15 101.325 0.450 ± 2%
453.15 101.325 0.512 ± 2%
453.15 101.325 0.509 ± 2%
Reference

Diffusion of methanol (1); air (2) 1
Diffusion of methanol (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: STEFAN Ref.: 1960A2
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 2.0 101.325 0.156 ± 0.008
298.15 ± 2.0 101.325 0.155 ± 0.012
298.15 ± 2.0 101.325 0.151 ± 0.030

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.1690 ± 0.0012

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 15.20 ± 0.155

Air (2) air 132259-10-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: INT Ref.: 1977B8
T [K] p [kPa] D · 106 [m2/s]
298.2 101.325 14.87

Air (2) air 132259-10-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: STEFAN Ref.: 1977M1
T [K] p [kPa] D · 104 [m2/s]
326.95 ± 0.2 101.325 0.1170 ± 0.0013

Air (2) air 132259-10-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: OEC Ref.: 1969K9
T [K] p [kPa] D · 104 [m2/s]
295.45 ± 0.3 101.325 0.159 ± 5%

2 Diffusion of methanol (1); air (2)
References
1960A2 Altshuller, A.P., Cohen, I.R.: Anal. Chem. 32 (1960) 802–810.
1977B8 Black, W.Z., Somers, R.L.: Rev. Sci. Instrum. 48 (1977) 476–481.
1977M1 Mato, F., Bueno, J.L.: Anales Quimica 73 (1977) 108–113.
1969K9 Katan, T.: J. Chem. Phys. 50 (1969) 233–238.

Diffusion of methanol (1); carbon dioxide (2) 1
Diffusion of methanol (1); carbon dioxide (2)

Vapor in Gas

Diffusion of gas(1) in gas(2): D*12(T ); Method: STEFAN Ref.: 1984B5
T [K] p [MPa] D · 106 [m2/s]
298.15 2.92 0.736 ± 4%
298.15 3.95 0.493 ± 4%
298.15 4.71 0.517 ± 4%
323.15 2.95 0.719 ± 4%
323.15 3.85 0.604 ± 4%
323.15 5.09 0.570 ± 4%
323.15 6.00 0.657 ± 4%

T [K] p [MPa] D · 107 [m2/s]
298.15 0.1023 124 ± 5%
298.15 0.866 20.7 ± 5%
298.15 2.92 7.07 ± 5%
298.15 3.95 4.86 ± 5%
298.15 4.71 5.12 ± 5%
323.15 0.1013 138 ± 5%
323.15 1.53 15.3 ± 5%
323.15 2.95 7.28 ± 5%
323.15 3.87 6.15 ± 5%
323.15 5.09 5.82 ± 5%
323.15 6.00 6.39 ± 5%
References
1984B5 Berezhnoi, A.N., Semenov, A.V.: Zh. Tekh. Fiz. 54 (1984) 2369–2371.

Diffusion of methanol (1); hydrogen (2) 1
Diffusion of methanol (1); hydrogen (2)

Vapor in Gas

H2 (2) hydrogen 1333-74-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: GC Ref.: 1968H3
T [K] p [kPa] D · 104 [m2/s]
353.15 101.325 0.9370 ± 0.0097
373.15 101.325 1.0200 ± 0.0473
393.15 101.325 1.1420 ± 0.0480
423.15 101.325 1.2483 ± 0.0843

H2 (2) hydrogen 1333-74-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: GC Ref.: 1975M11
T [K] p [kPa] D · 107 [m2/s]
353 101.325 0.9370 ± 1.0%
373 101.325 1.0200 ± 4.6%
393 101.325 1.1420 ± 4.2%
423 101.325 1.2483 ± 6.8%
Comment: data review
References
1968H3 Huang, T.C., Sheng, S.J., Yang, F.J.F.: J. Chin. Chem. Soc. Taipei 15 (1968) 127–139.
1975M11 Maynard, V.R., Grushka, E.: Adv. Chromatogr. 12 (1975) 99–140.

Diffusion of methanol (1); helium (2) 1
Diffusion of methanol (1); helium (2)

Vapor in Gas

He (2) helium 7440-59-7
Diffusion of gas(1) in gas(2): D*12(T ); Method: GC Ref.: 1963S1
T [K] p [kPa] D · 104 [m2/s]
423.15 101.325 1.032 ± 0.022
443.15 101.325 1.135 ± 0.019
463.15 101.325 1.218 ± 0.021
483.15 101.325 1.335 ± 0.036
503.15 101.325 1.389 ± 0.015
523.15 101.325 1.475 ± 0.009

He (2) helium 7440-59-7
Diffusion of gas(1) in gas(2): D*12(T ); Method: GC Ref.: 1989A1
T [K] p [kPa] D · 109 [m2/s]
333.15 101.325 7.94
Comment: reverse flow gas chromatography
References
1963S1 Seager, S.L., Geertson, L.R., Giddings, J.C.: J. Chem. Eng. Data 8 (1963) 168–169.
1989A1 Agathonos, P., Karaiskakis, G.: J. Chem. Soc. Faraday Trans. 1 85 (1989) 1357–1363.

Diffusion of methanol (1); nitrogen (2) 1
Diffusion of methanol (1); nitrogen (2)

Vapor in Gas

N2 (2) nitrogen 7727-37-9
T [K] p [MPa] D · 107 [m2/s]
298 0.1025 163.2
298 0.197 93.0
298 0.393 40.5
298 2.45 6.11
298 4.91 2.96
323 0.1017 207.8
323 0.393 50.6
323 2.45 7.62
323 4.91 3.77
323 7.38 2.47
348 0.197 118.0
348 0.393 65.0
348 2.45 9.72
348 4.91 4.79
348 7.38 3.17
298 7.85 1.89
298 9.81 1.45
323 9.81 1.81
348 9.81 2.34

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
355.0 101.325 0.250 ± 10%

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 106 [m2/s]
293.2 101.325 15.52
298.2 101.325 16.53
303.2 101.325 17.52
313.2 101.325 18.94
323.2 101.325 20.86
333.2 101.325 22.40

2 Diffusion of methanol (1); nitrogen (2)
References
1974B11 Bikbulatov, A.Sh., Berezhnoi, A.N., Usmanov, A.G.: Zh. Fiz. Khim. 48 (1974) 2320–2323.

Diffusion of carbon monoxide (1); argon (2) 1
Diffusion of carbon monoxide (1); argon (2)

Vapor in Gas

Ar (2) argon 7440-37-1
Diffusion of gas(1) in gas(2): D*12(T ); Method: INT Ref.: 1963I1
T [K] p [kPa] D · 104 [m2/s]
295.7 101.325 0.188 ± 0.001

Ar (2) argon 7440-37-1
Diffusion of gas(1) in gas(2): D*12(T ); Method: CT Ref.: 1978W5
T [K] p [Torr] D · 104 [m2/s]
298.15 ± 0.05 746 0.202 ± 0.006
310.15 ± 0.05 746 0.215 ± 0.004

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
295.7 101.325 0.188 ± 0.001
Comment: optical method
References
1963I1 Ivakin, B.A., Suetin, P.E.: Zh. Tekh. Fiz. 33 (1963) 1007–1010.
1978W5 Worth, H., Nüsse, W., Piiper, J.: Respir. Physiol. 32 (1978) 15–26.
1964I3 Ivakin, B.A., Suetin, P.E.: Sov. Phys. Tech. Phys. (English Transl.) 8 (1964) 748–751.

Diffusion of carbon monoxide (1); carbon monoxide (2) 1
Diffusion of carbon monoxide (1); carbon monoxide (2)

Vapor in Gas

Diffusion of gas(1) in gas(2): D*12(T ); Method: TB Ref.: 1970V3
T [K] p [kPa] D · 104 [m2/s]
273.2 101.325 0.1827
319.6 101.325 0.2402
373.0 101.325 0.3134
273.2 101.325 0.1827*
319.6 101.325 0.2406*
373.0 101.325 0.3145*
Comment: isotopic mixture 12C18O in CO;
*: isotopic mixture 13C16O in CO

T [K] p [kPa] D · 104 [m2/s]
233.17 101.325 1.5555 ± 0.1%
244.88 101.325 1.4230 ± 0.1%
261.77 101.325 1.2604 ± 0.1%
274.43 101.325 1.1588 ± 0.1%
330.07 101.325 0.8377 ± 0.1%
352.95 101.325 0.7458 ± 0.1%
364.20 101.325 0.7054 ± 0.1%
373.55 101.325 0.6762 ± 0.1%
385.25 101.325 0.6410 ± 0.1%
397.29 101.325 0.6079 ± 0.1%
408.37 101.325 0.5805 ± 0.1%
421.80 101.325 0.5491 ± 0.1%
298.15 101.325 0.2131 · 10–4*
*: absolute value in [m2/s]; isotopic mixture 13C16O in12C16O

T [K] p [kPa] D
233.17 101.325 1.5525 ± 0.1%
244.88 101.325 1.4217 ± 0.1%
330.07 101.325 0.8385 ± 0.1%
352.95 101.325 0.7467 ± 0.1%
364.20 101.325 0.7075 ± 0.1%
(continued)

2 Diffusion of carbon monoxide (1); carbon monoxide (2)
375.55 101.325 0.6774 ± 0.1%

385.25 101.325 0.6425 ± 0.1%
397.29 101.325 0.6099 ± 0.1%
408.37 101.325 0.5819 ± 0.1%
421.80 101.325 0.5509 ± 0.1%
298.15 101.325 0.2142 · 10–4*
*: absolute value in [m2/s]; isotopic mixture12C18O in12C16O
Reference

Diffusion of carbon monoxide (1); carbon dioxide (2) 1
Diffusion of carbon monoxide (1); carbon dioxide (2)

Vapor in Gas

T [K] p [kPa] D · 104 [m2/s]
296.1 101.325 0.152 ± 0.001

T [K] p [kPa] D · 104 [m2/s]
296.1 101.325 0.152

T [K] p [Torr] D · 104 [m2/s]
310.15 ± 0.05 746 0.179 ± 0.003

T [K] p [kPa] D · 104 [m2/s]
296.1 101.325 0.152 ± 0.001
References

Diffusion of carbon monoxide (1); sulfur hexafluoride (2) 1
Diffusion of carbon monoxide (1); sulfur hexafluoride (2)

Vapor in Gas

T [K] p [kPa] D · 104 [m2/s]
296.8 101.325 0.0887 ± 0.0008

T [K] p [kPa] D · 104 [m2/s]
296.8 101.325 0.0887 ± 0.0008

T [K] p [kPa] D · 104 [m2/s]
296.8 101.325 0.0887

T [K] p [Torr] D · 104 [m2/s]
298.15 ± 0.05 746 0.0968 ± 0.0022
310.15 ± 0.05 746 0.101 ± 0.002
References

Diffusion of carbon monoxide (1); hydrogen (2) 1
Diffusion of carbon monoxide (1); hydrogen (2)

Vapor in Gas

H2 (2) hydrogen 1333-74-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: RFGC Ref.: 2004G2
T [K] p [kPa] D · 105 [m2/s]
315.2 101.325 8.20 ± 0.02
320.0 101.325 8.42 ± 0.03
324.7 101.325 8.63 ± 0.01
329.4 101.325 8.83 ± 0.02
334.2 101.325 9.03 ± 0.04
339.0 101.325 9.31 ± 0.01
343.9 101.325 9.54 ± 0.02

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
295.6 101.325 0.743 ± 0.006

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
295.6 101.325 0.743 ± 0.006

H2 (2) hydrogen 1333-74-0
T [K] p [Torr] D · 104 [m2/s]
310.15 ± 0.05 746 0.832 ± 0.005
References
2004G2 Gavril, D., Atta, K.R., Karaiskakis, G.: Fluid Phase Equilib. 218 (2004) 177–188.

Diffusion of carbon monoxide (1); ammonia (2) 1
Diffusion of carbon monoxide (1); ammonia (2)

Vapor in Gas

H 3N (2) ammonia 7664-41-7
T [K] p [kPa] D · 104 [m2/s]
295.1 101.325 0.240
Reference

Diffusion of carbon monoxide (1); helium (2) 1
Diffusion of carbon monoxide (1); helium (2)

Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 105 [m2/s]
315.2 101.325 7.54 ± 0.05
320.0 101.325 7.75 ± 0.03
324.7 101.325 7.96 ± 0.01
329.4 101.325 8.18 ± 0.03
334.2 101.325 8.36 ± 0.01
339.0 101.325 8.59 ± 0.02
343.9 101.325 8.82 ± 0.02

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
295.6 101.325 0.702 ± 0.006

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
295.6 101.325 0.702 ± 0.006

He (2) helium 7440-59-7
T [K] p [Torr] D · 104 [m2/s]
298.15 ± 0.05 746 0.693 ± 0.008
310.15 ± 0.05 746 0.752 ± 0.008
References

Diffusion of carbon monoxide (1); nitrogen (2) 1
Diffusion of carbon monoxide (1); nitrogen (2)

Vapor in Gas

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D
233.17 101.325 1.5505 ± 0.1%
244.88 101.325 1.4197 ± 0.1%
261.77 101.325 1.2594 ± 0.1%
274.43 101.325 1.1573 ± 0.1%
330.07 101.325 0.8374 ± 0.1%
352.95 101.325 0.7451 ± 0.1%
364.20 101.325 0.7063 ± 0.1%
373.55 101.325 0.6759 ± 0.1%
385.25 101.325 0.6413 ± 0.1%
397.29 101.325 0.6089 ± 0.1%
408.37 101.325 0.5807 ± 0.1%
421.80 101.325 0.5494 ± 0.1%
298.15 101.325 0.2113 · 10–4*
*: absolute value in [m2/s]; isotopic mixture 13C 16O in 14N2

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D
233.17 101.325 1.5493 ± 0.1%
244.88 101.325 1.4190 ± 0.1%
330.07 101.325 0.8379 ± 0.1%
352.95 101.325 0.7464 ± 0.1%
364.20 101.325 0.7069 ± 0.1%
373.55 101.325 0.6770 ± 0.1%
385.25 101.325 0.6419 ± 0.1%
397.29 101.325 0.6091 ± 0.1%
408.37 101.325 0.5812 ± 0.1%
421.80 101.325 0.5502 ± 0.1%
298.15 101.325 0.2109 · 10–4*
*: absolute value in [m2/s]; isotopic mixture 12C18O in 14N2

2 Diffusion of carbon monoxide (1); nitrogen (2)

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
273.2 101.325 0.1809
319.6 101.325 0.2380
373.0 101.325 0.3108
273.2 101.325 0.1811*
319.6 101.325 0.2385*
373.0 101.325 0.3117*
Comment: isotopic mixture 12C 18O in N2;
*: isotopic mixture 13C 16O in N2

N2 (2) nitrogen 7727-37-9
T [K] p [Torr] D · 104 [m2/s]
298.15 ± 0.05 746 0.218 ± 0.002
310.15 ± 0.05 746 0.237 ± 0.003

N2 (2) nitrogen 7727-37-9
Diffusion of gas(1) in gas(2): D*12(T ); Method: CT Ref.: 1963A2
T [K] p [kPa] D · 104 [m2/s]
194.7 ± 0.01 101.325 0.1054 ± 1%
273.2 ± 0.01 101.325 0.1864 ± 1%
319.6 ± 0.01 101.325 0.2424 ± 1%
373.0 ± 0.01 101.325 0.3184 ± 1%

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
273.2 101.325 0.192

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
295.8 101.325 0.212 ± 0.002


N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
295.8 101.325 0.212 ± 0.002
References
1963A2 Amdur, I., Shuler, L.M.: J. Chem. Phys. 38 (1963) 188–192.

Diffusion of carbon monoxide (1); oxygen (2) 1
Diffusion of carbon monoxide (1); oxygen (2)

Vapor in Gas

O2 (2) oxygen 7782-44-7
T [K] p [Torr] D · 104 [m2/s]
310.15 ± 0.05 746 0.247 ± 0.005
Reference

Diffusion of carbon dioxide (1); air (2) 1
Diffusion of carbon dioxide (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
293.15 101.325 0.1590

Air (2) air 132259-10-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: No Info Ref.: 1955W2
T [K] p [kPa] D · 104 [m2/s]
293.0 101.325 0.151
400.0 101.325 0.273
600.0 101.325 0.555
800.0 101.325 0.915
1000.0 101.325 1.32
1300.0 101.325 1.97
1500.0 101.325 2.45
Comment: smoothed data

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
273.15 101.325 0.147 ± 2%
273.15 101.325 0.146 ± 2%
303.15 101.325 0.180 ± 2%
303.15 101.325 0.178 ± 2%
333.15 101.325 0.213 ± 2%
333.15 101.325 0.214 ± 2%
363.15 101.325 0.246 ± 2%
363.15 101.325 0.246 ± 2%
393.15 101.325 0.285 ± 2%
393.15 101.325 0.289 ± 2%
423.15 101.325 0.321 ± 2%
423.15 101.325 0.328 ± 2%
453.15 101.325 0.361 ± 2%
453.15 101.325 0.365 ± 2%
References
1955W2 Wilke, C.R., Lee, C.Y.: Ind. Eng. Chem. 47 (1955) 1253–1257.

Diffusion of carbon dioxide (1); argon (2)

Vapor in Gas

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
288.6 ± 0.1 101.325 0.135 ± 2%
328.0 ± 0.1 101.325 0.185 ± 2%
348.0 ± 0.1 101.325 0.208 ± 2%
373.0 ± 0.1 101.325 0.235 ± 2%
410.0 ± 0.1 101.325 0.280 ± 2%
455.0 ± 0.1 101.325 0.336 ± 2%
473.0 ± 0.1 101.325 0.363 ± 2%

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
276.2 101.325 0.1326 ± 0.0012
317.2 101.325 0.1652 ± 0.0016
References

Diffusion of carbon dioxide (1); methane (2)

Vapor in Gas

CH4 (2) methane 74-82-8
T [K] p [atm] D · 107 [m2/s]
298.15 14.41 12.4
298.15 14.43 12.7
298.15 50.7 3.46
298.15 50.7 3.47
298.15 101.0 1.62
298.15 102.4 1.63
298.15 142.7 1.16
298.15 149.6 1.10
298.15 198.7 0.806
298.15 251.7 0.659

CH4 (2) methane 74-82-8
T [K] p [atm] D · 107 [m2/s]
348.15 14.41 15.9
348.15 14.43 16.1
348.15 50.5 4.49
348.15 50.9 4.27
348.15 51.6 4.45
348.15 105.2 2.10
348.15 151.7 1.44
348.15 201.5 1.07
348.15 204.2 1.06
348.15 250.0 0.924
348.15 251.0 0.900

CH4 (2) methane 74-82-8
Diffusion of gas(1) in gas(2): D*12(T ); Method: TB Ref.: 1954J1
T [K] p [atm] D · 103 [m2/s]
298.15 40 2.15
298.15 70 1.00
298.15 70.5 1.02
298.15 100 0.562
298.15 150 0.264
298.15 150 0.278
298.15 150 0.270
(continued)

298.15 225 0.150

323.15 40 2.59
323.15 70 1.33
323.15 70 1.28
323.15 100 0.815
323.15 100 0.83
323.15 100 0.78
323.15 150 0.485
323.15 150 0.455
323.15 220 0.245
323.15 225 0.225
Comment: equimolar mixture of both gases

CH4 (2) methane 74-82-8
Diffusion of gas(1) in gas(2): D*12(T ); Method: TB Ref.: 1954J1
T [K] p [atm] D · 103 [m2/s]
298.15 40 2.15
298.15 70 0.93
298.15 70 0.85
298.15 100 0.384
298.15 100 0.420
298.15 120 0.259
298.15 150 0.160
298.15 190 0.101
323.15 50 2.60
323.15 60 1.45
323.15 70 1.25
323.15 90 0.80
323.15 100 0.65
323.15 120 0.490
323.15 150 0.272
323.15 225 0.143

CH4 (2) methane 74-82-8
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.17

CH4 (2) methane 74-82-8
T [K] p [atm] D · 103 [m2/s]
323.15 14.41 14.0
(continued)
323.15 14.41 14.5

323.15 50.8 4.02
323.15 101.8 1.90
323.15 152.3 1.27
323.15 200.5 0.961
323.15 201.3 0.953
323.15 250.8 0.762
323.15 251.2 0.763

CH4 (2) methane 74-82-8
T [K] p [kPa] D · 104 [m2/s]
293.1 101.325 0.181
307.3 101.325 0.200
317.4 101.325 0.204
367.9 101.325 0.271
References
1970T1 Takahashi, S., Iwasaki, H.: Bull. Chem. Res. (Tohoku Univ.) 20 (1970) 27–36.
1954J1 Jeffries, Q.R., Drickamer, H.G.: J. Chem. Phys. 22 (1954) 436–437.

Diffusion of carbon dioxide (1); carbon monoxide (2) 1
Diffusion of carbon dioxide (1); carbon monoxide (2)

Vapor in Gas

T [K] p [kPa] D · 104 [m2/s]
296.1 ± 0.1 101.325 0.152 ± 2%
315.4 ± 0.1 101.325 0.185 ± 2%
348.0 ± 0.1 101.325 0.222 ± 2%
373.0 ± 0.1 101.325 0.253 ± 2%
410.0 ± 0.1 101.325 0.295 ± 2%
455.0 ± 0.1 101.325 0.359 ± 2%
473.0 ± 0.1 101.325 0.381 ± 2%
Reference

Diffusion of carbon dioxide (1); carbon dioxide C14 (2) 1
Diffusion of carbon dioxide (1); carbon dioxide C14 (2)

Vapor in Gas

CO2 (2) carbon dioxide C14 51-90-1
Diffusion of gas(1) in gas(2): D*12(T ); Method: PF Ref.: 1955O1
T [K] p [atm] D · 107 [m2/s]
273.15 ± 0.1 14.30 5.98
273.15 ± 0.1 6.06 15.01
273.15 ± 0.1 25.50 2.902
273.35 ± 0.1 7.80 11.26
308.05 ± 0.1 11.20 10.16
308.15 ± 0.1 40.98 2.347
308.15 ± 0.1 58.45 1.378
308.15 ± 0.1 24.79 4.285
308.15 ± 0.1 69.95 0.942
308.15 ± 0.1 89.28 0.2869
308.15 ± 0.1 78.59 0.649
308.15 ± 0.1 77.57 0.594
308.15 ± 0.1 79.34 0.457
308.15 ± 0.1 98.05 0.2732
308.15 ± 0.1 86.01 0.309
308.15 ± 0.1 69.68 0.932
308.15 ± 0.1 88.26 0.2973
308.15 ± 0.1 69.81 0.926
373.15 ± 0.1 21.61 7.68
373.15 ± 0.1 41.29 3.90
373.15 ± 0.1 30.98 5.29
373.15 ± 0.1 71.11 2.088
373.15 ± 0.1 102.2 1.316
373.15 ± 0.1 135.7 0.888
373.15 ± 0.1 204.8 0.497
373.15 ± 0.1 171.7 0.638
373.15 ± 0.1 14.54 11.21
Comment: 12CO2 diffusing into 14CO2
Reference
1955O1 O´Hern, H.A., Martin, J.J.: Ind. Eng. Chem. 47 (1955) 2081–2087.

Diffusion of carbon dioxide (1); oxirane (2) 1
Diffusion of carbon dioxide (1); oxirane (2)

Vapor in Gas

C2H4O (2) oxirane 75-21-8
T [K] p [kPa] D · 104 [m2/s]
298.0 101.325 0.0918
Reference

Diffusion of carbon dioxide (1); propane (2) 1
Diffusion of carbon dioxide (1); propane (2)

Vapor in Gas

C3H8 (2) propane 74-98-6
T [K] p [kPa] D · 104 [m2/s]
298.0 101.325 0.0863
Reference

Diffusion of carbon dioxide (1); propan-1-ol (2) 1
Diffusion of carbon dioxide (1); propan-1-ol (2)

Vapor in Gas

C3H8O (2) propan-1-ol 71-23-8
Diffusion of gas(1) in gas(2): D*12(T ); Method: DIA Ref.: 1975T1
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.05 101.325 3.17
Reference
1975T1 Takeuchi, H., Fujine, M., Sato, T., Onda, K.: J. Chem. Eng. Jpn. 8 (1975) 252–253.

Diffusion of carbon dioxide (1); sulfur hexafluoride (2) 1
Diffusion of carbon dioxide (1); sulfur hexafluoride (2)

Vapor in Gas

T [K] p [Torr] D · 104 [m2/s]
290.8 690 0.0713 ± 0.0007

T [K] p [kPa] D · 107 [m2/s]
290.8 ± 0.1 101.325 0.0647 ± 2%
328.0 ± 0.1 101.325 0.0774 ± 2%
348.0 ± 0.1 101.325 0.0872 ± 2%
373.0 ± 0.1 101.325 0.0980 ± 2%
410.0 ± 0.1 101.325 0.118 ± 2%
447.0 ± 0.1 101.325 0.143 ± 2%
472.0 ± 0.1 101.325 0.151 ± 2%
References

Diffusion of carbon dioxide (1); hydrogen (2) 1
Diffusion of carbon dioxide (1); hydrogen (2)

Vapor in Gas

H2 (2) hydrogen 1333-74-0
T [K] p [Torr] D · 104 [m2/s]
310.15 ± 0.05 746 0.673 ± 0.003

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 105 [m2/s]
315.2 101.325 7.00 ± 0.04
320.0 101.325 7.24 ± 0.03
324.7 101.325 7.38 ± 0.02
329.4 101.325 7.61 ± 0.03
334.2 101.325 7.82 ± 0.02
339.0 101.325 7.96 ± 0.02
343.9 101.325 8.20 ± 0.05

H2 (2) hydrogen 1333-74-0
T [K] p [Torr] D · 104 [m2/s]
299.65 642.2 0.793 ± 0.003
298.15 760.0 0.665

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
273.2 101.325 0.550
288.2 101.325 0.619
293.2 101.325 0.60
298.2 101.325 0.646
References

Diffusion of carbon dioxide (1); water (2) 1
Diffusion of carbon dioxide (1); water (2)

Vapor in Gas

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 104 [m2/s]
307.5 101.325 0.202
328.6 101.325 0.211
352.4 101.325 0.245
Reference

Diffusion of carbon dioxide (1); helium (2) 1
Diffusion of carbon dioxide (1); helium (2)

Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 105 [m2/s]
315.2 101.325 6.31 ± 0.02
320.0 101.325 6.46 ± 0.03
329.4 101.325 6.82 ± 0.04
324.7 101.325 6.64 ± 0.02
334.2 101.325 6.97 ± 0.03
339.0 101.325 7.16 ± 0.01
343.9 101.325 7.33 ± 0.01

He (2) helium 7440-59-7
T [K] p [kPa] D · 105 [m2/s]
297.5 101.325 5.74 ± 0.02
References

Diffusion of carbon dioxide (1); nitrogen (2)

Vapor in Gas

N2 (2) nitrogen 727-37-9
T [K] p [kPa] D · 104 [m2/s]
324.0 101.325 0.186 ± 4.1%

N2 (2) nitrogen 727-37-9
T [K] p [kPa] D · 104 [m2/s]
273.15 101.325 0.148 ± 2%
273.15 101.325 0.146 ± 2%
303.15 101.325 0.177 ± 2%
303.15 101.325 0.179 ± 2%
333.15 101.325 0.214 ± 2%
333.15 101.325 0.212 ± 2%
363.15 101.325 0.243 ± 2%
363.15 101.325 0.253 ± 2%
363.15 101.325 0.248 ± 2%
393.15 101.325 0.286 ± 2%
393.15 101.325 0.292 ± 2%
423.15 101.325 0.323 ± 2%
423.15 101.325 0.323 ± 2%
453.15 101.325 0.363 ± 2%
453.15 101.325 0.377 ± 2%

N2 (2) nitrogen 727-37-9
T [K] p [kPa] D · 104 [m2/s]
290.4 ± 0.1 101.325 0.135 ± 2%
315.4 ± 0.1 101.325 0.184 ± 2%
348.0 ± 0.1 101.325 0.223 ± 2%
373.0 ± 0.1 101.325 0.258 ± 2%
410.0 ± 0.1 101.325 0.307 ± 2%
455.0 ± 0.1 101.325 0.361 ± 2%
473.0 ± 0.1 101.325 0.386 ± 2%


N2 (2) nitrogen 727-37-9
T [K] p [Torr] D · 104 [m2/s]
298.75 644.6 0.214 ± 0.003
298.15 760.0 0.181

N2 (2) nitrogen 727-37-9
T [K] p [kPa] D · 104 [m2/s]
273.2 101.325 0.144
288.2 101.325 0.158
293.2 101.325 0.16
298.2 101.325 0.165

N2 (2) nitrogen 727-37-9
T [K] p [Torr] D · 104 [m2/s]
310.15 ± 0.05 746 0.181 ± 0.002
References

Diffusion of carbon dioxide (1); nitrous oxide (2) 1
Diffusion of carbon dioxide (1); nitrous oxide (2)

Vapor in Gas

T [K] p [kPa] D · 104 [m2/s]
194.8 101.325 0.0531
273.2 101.325 0.0989
287.3 101.325 0.1070
298.0 101.325 0.1170
312.8 101.325 0.1280
362.8 101.325 0.1683

T [K] p [Torr] D · 104 [m2/s]
194.8 ± 0.01 203.7 0.0531 ± 1.5%
273.2 ± 0.01 319.7 0.0996 ± 1.5%
312.8 ± 0.01 510.0 0.1280 ± 1.5%
312.8 ± 0.01 323.3 0.1280 ± 1.5%
362.6 ± 0.01 507.4 0.1683 ± 1.5%
References
1952A1 Amdur, I., Irvine jr., J.W., Mason, E.A., Ross, J.: J. Chem. Phys. 20 (1952) 436–443.

Diffusion of carbon dioxide (1); oxygen (2) 1
Diffusion of carbon dioxide (1); oxygen (2)

Vapor in Gas

O2 (2) oxygen 7782-44-7
T [K] p [kPa] D · 104 [m2/s]
273.2 101.325 0.139
293.2 101.325 0.16

O2 (2) oxygen 7782-44-7
T [K] p [Torr] D · 104 [m2/s]
310.15 ± 0.05 746 0.170 ± 0.005

O2 (2) oxygen 7782-44-7
T [K] p [kPa] D · 104 [m2/s]
273.15 101.325 0.148 ± 2%
273.15 101.325 0.150 ± 2%
303.15 101.325 0.180 ± 2%
303.15 101.325 0.179 ± 2%
333.15 101.325 0.214 ± 2%
333.15 101.325 0.214 ± 2%
363.15 101.325 0.251 ± 2%
363.15 101.325 0.252 ± 2%
393.15 101.325 0.292 ± 2%
393.15 101.325 0.291 ± 2%
423.15 101.325 0.330 ± 2%
423.15 101.325 0.330 ± 2%
453.15 101.325 0.373 ± 2%
453.15 101.325 0.370 ± 2%
References

Diffusion of carbon disulfide (1); air (2) 1
Diffusion of carbon disulfide (1); air (2)

Vapor in Gas
CS2 (1) carbon disulfide 75-15-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 10.45 ± 0.121

Air (2) air 132259-10-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: STEFAN Ref.: 1977N1
T [K] p [kPa] D · 104 [m2/s]
263.15 ± 0.03 101.325 0.0884 ± 0.0001
268.15 ± 0.03 101.325 0.0910 ± 0.0000
273.15 ± 0.03 101.325 0.0936 ± 0.0000
278.15 ± 0.03 101.325 0.0960 ± 0.0002
283.15 ± 0.03 101.325 0.0993 ± 0.0004
288.15 ± 0.03 101.325 0.1020 ± 0.0003
293.15 ± 0.03 101.325 0.1049 ± 0.0000
298.15 ± 0.03 101.325 0.1085 ± 0.0001
303.15 ± 0.03 101.325 0.1113 ± 0.0000
308.15 ± 0.03 101.325 0.1154 ± 0.0002
313.15 ± 0.03 101.325 0.1185 ± 0.0001

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.35 101.325 0.1078 ± 0.0013
References
1977N1 Nagasaka, M., Hirai, H.: J. Chem. Eng. Jpn. 10 (1977) 253–257.

Diffusion of carbon disulfide (1); argon (2) 1
Diffusion of carbon disulfide (1); argon (2)

Vapor in Gas

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
263.15 ± 0.03 101.325 0.0786 ± 0.0002
268.15 ± 0.03 101.325 0.0807 ± 0.0003
273.15 ± 0.03 101.325 0.0833 ± 0.0001
278.15 ± 0.03 101.325 0.0864 ± 0.0003
283.15 ± 0.03 101.325 0.0890 ± 0.0002
288.15 ± 0.03 101.325 0.0912 ± 0.0002
293.15 ± 0.03 101.325 0.0937 ± 0.0001
298.15 ± 0.03 101.325 0.0963 ± 0.0002
303.15 ± 0.03 101.325 0.0999 ± 0.0003
308.15 ± 0.03 101.325 0.1029 ± 0.0001
313.15 ± 0.03 101.325 0.1063 ± 0.0000
Reference

Diffusion of carbon disulfide (1); hydrogen (2) 1
Diffusion of carbon disulfide (1); hydrogen (2)

Vapor in Gas

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
263.15 ± 0.03 101.325 0.368 ± 0.001
268.15 ± 0.03 101.325 0.377 ± 0.002
273.15 ± 0.03 101.325 0.391 ± 0.001
278.15 ± 0.03 101.325 0.402 ± 0.001
283.15 ± 0.03 101.325 0.416 ± 0.001
288.15 ± 0.03 101.325 0.428 ± 0.001
293.15 ± 0.03 101.325 0.442 ± 0.001
298.15 ± 0.03 101.325 0.455 ± 0.002
303.15 ± 0.03 101.325 0.469 ± 0.001
308.15 ± 0.03 101.325 0.484 ± 0.001
313.15 ± 0.03 101.325 0.497 ± 0.001
Reference

Diffusion of carbon disulfide (1); helium (2) 1
Diffusion of carbon disulfide (1); helium (2)

Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
263.05 ± 0.03 101.325 0.333 ± 0.001
268.15 ± 0.03 101.325 0.343 ± 0.001
273.15 ± 0.03 101.325 0.353 ± 0.001
278.15 ± 0.03 101.325 0.365 ± 0.001
283.15 ± 0.03 101.325 0.377 ± 0.001
288.15 ± 0.03 101.325 0.387 ± 0.001
293.15 ± 0.03 101.325 0.399 ± 0.000
298.15 ± 0.03 101.325 0.415 ± 0.000
303.15 ± 0.03 101.325 0.425 ± 0.001
308.15 ± 0.03 101.325 0.437 ± 0.001
313.15 ± 0.03 101.325 0.449 ± 0.001
Reference

Diffusion of carbon disulfide (1); nitrogen oxide (2) 1
Diffusion of carbon disulfide (1); nitrogen oxide (2)

Vapor in Gas

T [K] p [kPa] D · 104 [m2/s]
263.15 ± 0.03 101.325 0.0888 ± 0.0001
268.15 ± 0.03 101.325 0.0916 ± 0.0000
273.15 ± 0.03 101.325 0.0942 ± 0.0003
278.15 ± 0.03 101.325 0.0977 ± 0.0000
283.15 ± 0.03 101.325 0.1008 ± 0.0004
288.15 ± 0.03 101.325 0.1036 ± 0.0001
293.15 ± 0.03 101.325 0.1070 ± 0.0002
298.15 ± 0.03 101.325 0.1103 ± 0.0003
303.15 ± 0.03 101.325 0.1124 ± 0.0003
308.15 ± 0.03 101.325 0.1156 ± 0.0001
313.15 ± 0.03 101.325 0.1197 ± 0.0005
Reference

Diffusion of 1-chloro-1,1,2,2,2-pentafluoro-ethane (1); air (2) 1
Diffusion of 1-chloro-1,1,2,2,2-pentafluoro-ethane (1); air

(2)
Vapor in Gas
C2ClF5 (1) 1-chloro-1,1,2,2,2-pentafluoro-ethane 76-15-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
273.15 ± 0.5 101.325 0.0796 ± 2%
273.15 ± 0.5 101.325 0.0783 ± 2%
303.15 ± 0.5 101.325 0.0952 ± 2%
303.15 ± 0.5 101.325 0.0929 ± 2%
333.15 ± 0.5 101.325 0.112 ± 2%
333.15 ± 0.5 101.325 0.111 ± 2%
333.15 ± 0.5 101.325 0.112 ± 2%
333.15 ± 0.5 101.325 0.110 ± 2%
363.15 ± 0.5 101.325 0.128 ± 2%
363.15 ± 0.5 101.325 0.131 ± 2%
363.15 ± 0.5 101.325 0.128 ± 2%
393.15 ± 0.5 101.325 0.149 ± 2%
393.15 ± 0.5 101.325 0.151 ± 2%
393.15 ± 0.5 101.325 0.148 ± 2%
423.15 ± 0.5 101.325 0.171 ± 2%
423.15 ± 0.5 101.325 0.168 ± 2%
453.15 ± 0.5 101.325 0.186 ± 2%
453.15 ± 0.5 101.325 0.192 ± 2%
453.15 ± 0.5 101.325 0.191 ± 2%
C2ClF5 (1) 1-chloro-1,1,2,2,2-pentafluoro-ethane 76-15-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
273.15 101.325 0.0796 ± 2%
273.15 101.325 0.0783 ± 2%
303.15 101.325 0.0952 ± 2%
303.15 101.325 0.0929 ± 2%
333.15 101.325 0.112 ± 2%
333.15 101.325 0.111 ± 2%
333.15 101.325 0.112 ± 2%
333.15 101.325 0.110 ± 2%
363.15 101.325 0.128 ± 2%
363.15 101.325 0.131 ± 2%
363.15 101.325 0.128 ± 2%
393.15 101.325 0.149 ± 2%
393.15 101.325 0.151 ± 2%
(continued)

2 Diffusion of 1-chloro-1,1,2,2,2-pentafluoro-ethane (1); air (2)
393.15 101.325 0.148 ± 2%

423.15 101.325 0.171 ± 2%
423.15 101.325 0.168 ± 2%
453.15 101.325 0.189 ± 2%
453.15 101.325 0.192 ± 2%
453.15 101.325 0.191 ± 2%
References
185–192.

Diffusion of 1,2-dichloro-1,1,2,2-tetrafluoro-ethane (1); air (2) 1
Diffusion of 1,2-dichloro-1,1,2,2-tetrafluoro-ethane (1);

air (2)
Vapor in Gas
C2Cl2F4 (1) 1,2-dichloro-1,1,2,2-tetrafluoro-ethane 76-14-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
303.15 ± 0.5 101.325 0.0884 ± 2%
303.15 ± 0.5 101.325 0.0864 ± 2%
333.15 ± 0.5 101.325 0.103 ± 2%
333.15 ± 0.5 101.325 0.101 ± 2%
333.15 ± 0.5 101.325 0.104 ± 2%
333.15 ± 0.5 101.325 0.102 ± 2%
363.15 ± 0.5 101.325 0.120 ± 2%
363.15 ± 0.5 101.325 0.122 ± 2%
363.15 ± 0.5 101.325 0.118 ± 2%
393.15 ± 0.5 101.325 0.136 ± 2%
393.15 ± 0.5 101.325 0.139 ± 2%
393.15 ± 0.5 101.325 0.137 ± 2%
423.15 ± 0.5 101.325 0.158 ± 2%
423.15 ± 0.5 101.325 0.158 ± 2%
453.15 ± 0.5 101.325 0.173 ± 2%
453.15 ± 0.5 101.325 0.180 ± 2%
453.15 ± 0.5 101.325 0.177 ± 2%

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.0884 ± 2%
303.15 101.325 0.0864 ± 2%
333.15 101.325 0.103 ± 2%
333.15 101.325 0.101 ± 2%
333.15 101.325 0.104 ± 2%
333.15 101.325 0.102 ± 2%
363.15 101.325 0.120 ± 2%
363.15 101.325 0.122 ± 2%
363.15 101.325 0.118 ± 2%
393.15 101.325 0.136 ± 2%
393.15 101.325 0.139 ± 2%
393.15 101.325 0.137 ± 2%
423.15 101.325 0.158 ± 2%
423.15 101.325 0.158 ± 2%
453.15 101.325 0.173 ± 2%
(continued)

2 Diffusion of 1,2-dichloro-1,1,2,2-tetrafluoro-ethane (1); air (2)
453.15 101.325 0.180 ± 2%

453.15 101.325 0.177 ± 2%
References
185–192.

Diffusion of 1,1,2-trichloro-1,2,2-trifluoro-ethane (1); air (2) 1
Diffusion of 1,1,2-trichloro-1,2,2-trifluoro-ethane (1); air

(2)
Vapor in Gas
C2Cl3F3 (1) 1,1,2-trichloro-1,2,2-trifluoro-ethane 76-13-1

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
323.15 ± 0.5 101.325 0.0901 ± 2%
323.15 ± 0.5 101.325 0.0919 ± 2%
333.15 ± 0.5 101.325 0.0938 ± 2%
333.15 ± 0.5 101.325 0.0962 ± 2%
333.15 ± 0.5 101.325 0.0943 ± 2%
363.15 ± 0.5 101.325 0.113 ± 2%
363.15 ± 0.5 101.325 0.112 ± 2%
363.15 ± 0.5 101.325 0.113 ± 2%
363.15 ± 0.5 101.325 0.112 ± 2%
393.15 ± 0.5 101.325 0.129 ± 2%
393.15 ± 0.5 101.325 0.128 ± 2%
423.15 ± 0.5 101.325 0.146 ± 2%
423.15 ± 0.5 101.325 0.149 ± 2%
423.15 ± 0.5 101.325 0.145 ± 2%
453.15 ± 0.5 101.325 0.168 ± 2%
453.15 ± 0.5 101.325 0.164 ± 2%
453.15 ± 0.5 101.325 0.166 ± 2%
C2Cl3F3 (1) 1,1,2-trichloro-1,2,2-trifluoro-ethane 76-13-1

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
323.15 101.325 0.0901 ± 2%
323.15 101.325 0.0919 ± 2%
333.15 101.325 0.0938 ± 2%
333.15 101.325 0.0962 ± 2%
333.15 101.325 0.0943 ± 2%
363.15 101.325 0.113 ± 2%
363.15 101.325 0.112 ± 2%
363.15 101.325 0.113 ± 2%
363.15 101.325 0.112 ± 2%
393.15 101.325 0.129 ± 2%
393.15 101.325 0.128 ± 2%
423.15 101.325 0.146 ± 2%
423.15 101.325 0.149 ± 2%
423.15 101.325 0.145 ± 2%
453.15 101.325 0.168 ± 2%
(continued)

2 Diffusion of 1,1,2-trichloro-1,2,2-trifluoro-ethane (1); air (2)
453.15 101.325 0.164 ± 2%

453.15 101.325 0.166 ± 2%
References
185–192.

Diffusion of 1,1,2,2-tetrachloro-ethene (1); air (2) 1
Diffusion of 1,1,2,2-tetrachloro-ethene (1); air (2)

Vapor in Gas
C2Cl4 (1) 1,1,2,2-tetrachloro-ethene 127-18-4

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.0711 ± 2%
318.15 101.325 0.0803 ± 2%
358.15 101.325 0.1006 ± 2%

Air (2) air 132259-10-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: STEFAN Ref.: 1987P1
T [K] p [kPa] D · 106 [m2/s]
283.04 ± 0.005 101.325 6.558 ± 0.5%
298.15 ± 0.005 101.325 7.207 ± 0.5%
313.15 ± 0.005 101.325 7.816 ± 0.5%
328.15 ± 0.005 101.325 8.562 ± 0.5%
343.15 ± 0.005 101.325 9.363 ± 0.5%

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
371.65 ± 0.2 101.325 0.1250 ± 0.0019

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.97 ± 0.023
References
1987P1 Park, T., Rettich, T.R., Battino, R., Wilhelm, E.: Mat. Chem. Phys. 16 (1987) 397–410.

Diffusion of 1,1,2,2-tetrachloro-ethene (1); tetrafluoro-methane (2) 1
Diffusion of 1,1,2,2-tetrachloro-ethene (1); tetrafluoro-

methane (2)
Vapor in Gas

T [K] p [bar] D · 104 [m2/s]
283.10 ± 0.01 100 0.0350 ± 1%
298.20 ± 0.01 100 0.0384 ± 1%
313.17 ± 0.01 100 0.0403 ± 1%
328.13 ± 0.01 100 0.0445 ± 1%
343.14 ± 0.01 100 0.0483 ± 1%
Reference
479–481.

Diffusion of 1,1,2,2-tetrachloro-ethene (1); methane (2) 1
Diffusion of 1,1,2,2-tetrachloro-ethene (1); methane (2)

Vapor in Gas

CH4 (2) methane 74-82-8
T [K] p [bar] D · 104 [m2/s]
283.14 ± 0.01 100 0.0737 ± 1%
298.14 ± 0.01 100 0.0815 ± 1%
313.12 ± 0.01 100 0.0896 ± 1%
328.15 ± 0.01 100 0.0983 ± 1%
343.14 ± 0.01 100 0.1066 ± 1%
Reference
479–481.

Diffusion of 1,1,1-trifluoro-ethane (1); air (2) 1
Diffusion of 1,1,1-trifluoro-ethane (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.116
333.15 101.325 0.136
363.15 101.325 0.160
393.15 101.325 0.183
423.15 101.325 0.211
453.15 101.325 0.236
453.15 101.325 0.238
Reference

Diffusion of 1,1,1,2-tetrafluoro-ethane (1); air (2) 1
Diffusion of 1,1,1,2-tetrafluoro-ethane (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
273.15 101.325 0.0934 ± 2%
273.15 101.325 0.0937 ± 2%
303.15 101.325 0.110 ± 2%
303.15 101.325 0.109 ± 2%
333.15 101.325 0.130 ± 2%
333.15 101.325 0.131 ± 2%
363.15 101.325 0.152 ± 2%
363.15 101.325 0.152 ± 2%
393.15 101.325 0.176 ± 2%
393.15 101.325 0.173 ± 2%
423.15 101.325 0.199 ± 2%
423.15 101.325 0.197 ± 2%

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
273.15 ± 0.5 101.325 0.0934 ± 2%
273.15 ± 0.5 101.325 0.0937 ± 2%
303.15 ± 0.5 101.325 0.110 ± 2%
303.15 ± 0.5 101.325 0.109 ± 2%
333.15 ± 0.5 101.325 0.130 ± 2%
333.15 ± 0.5 101.325 0.131 ± 2%
363.15 ± 0.5 101.325 0.152 ± 2%
363.15 ± 0.5 101.325 0.152 ± 2%
393.15 ± 0.5 101.325 0.176 ± 2%
393.15 ± 0.5 101.325 0.173 ± 2%
423.15 ± 0.5 101.325 0.199 ± 2%
423.15 ± 0.5 101.325 0.197 ± 2%
References
185–192.

Diffusion of 2-chloro-1,1,1,2-tetrafluoro-ethane (1); air (2) 1
Diffusion of 2-chloro-1,1,1,2-tetrafluoro-ethane (1); air (2)

Vapor in Gas
C2HClF4 (1) 2-chloro-1,1,1,2-tetrafluoro-ethane 2837-89-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.0961
303.15 101.325 0.0955
333.15 101.325 0.113
363.15 101.325 0.134
393.15 101.325 0.155
423.15 101.325 0.177
423.15 101.325 0.173
453.15 101.325 0.198
453.15 101.325 0.195
Reference

Diffusion of 2,2-dichloro-1,1,1-trifluoro-ethane (1); air (2) 1
Diffusion of 2,2-dichloro-1,1,1-trifluoro-ethane (1); air (2)

Vapor in Gas
C2HCl2F3 (1) 2,2-dichloro-1,1,1-trifluoro-ethane 306-83-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.0896 ± 2%
303.15 101.325 0.0884 ± 2%
313.15 101.325 0.0945 ± 2%
313.15 101.325 0.0954 ± 2%
333.15 101.325 0.104 ± 2%
333.15 101.325 0.107 ± 2%
363.15 101.325 0.121 ± 2%
363.15 101.325 0.123 ± 2%
363.15 101.325 0.123 ± 2%
393.15 101.325 0.138 ± 2%
393.15 101.325 0.142 ± 2%
393.15 101.325 0.139 ± 2%
423.15 101.325 0.159 ± 2%
423.15 101.325 0.161 ± 2%
453.15 101.325 0.179 ± 2%
453.15 101.325 0.181 ± 2%
C2HCl2F3 (1) 2,2-dichloro-1,1,1-trifluoro-ethane 306-83-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
303.15 ± 0.5 101.325 0.0896 ± 2%
303.15 ± 0.5 101.325 0.0884 ± 2%
313.15 ± 0.5 101.325 0.0945 ± 2%
313.15 ± 0.5 101.325 0.0954 ± 2%
333.15 ± 0.5 101.325 0.104 ± 2%
333.15 ± 0.5 101.325 0.107 ± 2%
363.15 ± 0.5 101.325 0.121 ± 2%
363.15 ± 0.5 101.325 0.123 ± 2%
363.15 ± 0.5 101.325 0.123 ± 2%
393.15 ± 0.5 101.325 0.138 ± 2%
393.15 ± 0.5 101.325 0.142 ± 2%
393.15 ± 0.5 101.325 0.139 ± 2%
423.15 ± 0.5 101.325 0.159 ± 2%
423.15 ± 0.5 101.325 0.161 ± 2%
453.15 ± 0.5 101.325 0.179 ± 2%
453.15 ± 0.5 101.325 0.181 ± 2%

2 Diffusion of 2,2-dichloro-1,1,1-trifluoro-ethane (1); air (2)
References
185–192.

Diffusion of 1,1,2-trichloro-ethene (1); air (2) 1
Diffusion of 1,1,2-trichloro-ethene (1); air (2)

Vapor in Gas
C2HCl3 (1) 1,1,2-trichloro-ethene 79-01-6

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.0800 ± 2%
348.15 101.325 0.1069 ± 2%
C2HCl3 (1) 1,1,2-trichloro-ethene 79-01-6

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 8.75 ± 0.023
References

Diffusion of pentachloro-ethane (1); air (2) 1
Diffusion of pentachloro-ethane (1); air (2)

Vapor in Gas
C2HCl5 (1) pentachloro-ethane 76-01-7

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.73 ± 0.036
Reference

Diffusion of 1,1,1,2,2-pentafluoro-ethane (1); air (2) 1
Diffusion of 1,1,1,2,2-pentafluoro-ethane (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.104
333.15 101.325 0.123
363.15 101.325 0.143
393.15 101.325 0.165
423.15 101.325 0.186
453.15 101.325 0.212
453.15 101.325 0.209
Reference

Diffusion of ethyne (1); air (2) 1
Diffusion of ethyne (1); air (2)

Vapor in Gas
C2H2 (1) ethyne 74-86-2

Air (2) air 132259-10-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: TB Ref.: 1972E2
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.1457 ± 0.0015
Reference
1972E2 Elliott, R.W., Watts, H.: Can. J. Chem. 50 (1972) 31–34.

Diffusion of ethyne (1); ethene (2) 1
Diffusion of ethyne (1); ethene (2)

Vapor in Gas
C2H2 (1) ethyne 74-86-2

C2H4 (2) ethene 74-85-1
T [K] p [kPa] D · 104 [m2/s]
298.2 ± 0.1 101.325 0.137 ± 0.001
352.6 ± 0.1 101.325 0.185 ± 0.001
382.5 ± 0.1 101.325 0.210 ± 0.001
Reference

Diffusion of 1,2-dibromo-ethene (1); air (2) 1
Diffusion of 1,2-dibromo-ethene (1); air (2)

Vapor in Gas
C2H2Br2 (1) 1,2-dibromo-ethene 540-49-8

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 8.26 ± 0.064
Reference

Diffusion of 1,1,2,2-tetrachloro-ethane (1); air (2) 1
Diffusion of 1,1,2,2-tetrachloro-ethane (1); air (2)

Vapor in Gas
C2H2Cl4 (1) 1,1,2,2-tetrachloro-ethane 79-34-5

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.22 ± 0.041
Reference

Diffusion of chloro-ethene (1); nitrogen (2) 1
Diffusion of chloro-ethene (1); nitrogen (2)

Vapor in Gas

N2 (2) nitrogen 7727-37-9
Diffusion of gas(1) in gas(2): D*12(T ); Method: RFGC Ref.: 2001R1
T [K] p [kPa] D · 104 [m2/s]
324.05 101.325 0.140
324.40 101.325 0.140
329.00 101.325 0.143
329.05 101.325 0.143
334.65 101.325 0.147
339.35 101.325 0.151
339.55 101.325 0.152
345.55 101.325 0.157
345.90 101.325 0.158
324.25 101.325 0.140
328.90 101.325 0.144
334.70 101.325 0.147
339.30 101.325 0.151
346.00 101.325 0.157
328.80 101.325 0.143
334.50 101.325 0.148
339.20 101.325 0.151
345.85 101.325 0.157
Reference
2001R1 Rashid, A.K., Gavril, D., Katsanos, N.A., Karaiskakis, G.: J. Chromatogr. A 934 (2001) 31–49.

Diffusion of 1,1,1-trichloro-ethane (1); air (2) 1
Diffusion of 1,1,1-trichloro-ethane (1); air (2)

Vapor in Gas
C2H3Cl3 (1) 1,1,1-trichloro-ethane 71-55-6

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.94 ± 0.077

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
283.04 ± 0.005 101.325 7.228 ± 0.5%
298.18 ± 0.005 101.325 7.994 ± 0.5%
313.15 ± 0.005 101.325 8.761 ± 0.5%
328.15 ± 0.005 101.325 9.457 ± 0.5%
343.15 ± 0.005 101.325 9.940 ± 0.5%

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.0793 ± 2%
338.15 101.325 0.0971 ± 2%
References

Diffusion of 1,1,1-trichloro-ethane (1); tetrafluoro-methane (2) 1
Diffusion of 1,1,1-trichloro-ethane (1); tetrafluoro-

methane (2)
Vapor in Gas

T [K] p [bar] D · 104 [m2/s]
283.10 ± 0.01 100 0.0392 ± 1%
293.15 ± 0.01 100 0.0417 ± 1%
313.17 ± 0.01 100 0.0472 ± 1%
328.13 ± 0.01 100 0.0506 ± 1%
343.14 ± 0.01 100 0.0569 ± 1%
Reference
479–481.

Diffusion of 1,1,2-trichloro-ethane (1); air (2) 1
Diffusion of 1,1,2-trichloro-ethane (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.92 ± 0.071
Reference

Diffusion of ethene (1); air (2) 1
Diffusion of ethene (1); air (2)

Vapor in Gas
C2H4 (1) ethene 74-85-1

Air (2) air 132259-10-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: ARF Ref.: 1994S3
T [K] p [kPa] D · 107 [m2/s]
196.8 101.325 82.2 ± 0.4%
211.6 101.325 94.9 ± 0.3%
221.5 101.325 102.8 ± 0.7%
232.3 101.325 112.4 ± 0.2%
252.3 101.325 130.6 ± 0.3%
273.3 101.325 149.3 ± 0.3%
284.0 101.325 161.7 ± 0.3%
295.1 101.325 172.1 ± 0.7%
C2H4 (1) ethene 74-85-1

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.1655 ± 0.0021
C2H4 (1) ethene 74-85-1

Air (2) air 132259-10-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: DB Ref.: 1994S3
T [K] p [kPa] D · 104 [m2/s]
203.3 101.325 74.5 ± 0.6%
208.1 101.325 78.3 ± 0.3%
216.6 101.325 85.7 ± 0.4%
225.8 101.325 93.4 ± 0.3%
235.7 101.325 101.5 ± 0.3%
244.9 101.325 107.3 ± 0.8%
249.7 101.325 110.9 ± 0.4%
264.0 101.325 126.3 ± 0.4%
278.6 101.325 139.1 ± 0.3%
293.5 101.325 156.6 ± 0.7%
References
1994S3 Schweighoefer, S.: Ph.D. Thesis, Bonn, 1994.

Diffusion of ethene (1); propene (2) 1
Diffusion of ethene (1); propene (2)

Vapor in Gas
C2H4 (1) ethene 74-85-1

C3H6 (2) propene 115-07-1
T [K] p [MPa] D · 106 [m2/s]
344.0 0.80 1.48 ± 5%
344.0 0.80 1.42 ± 5%
Reference

Diffusion of ethene (1); hydrogen (2) 1
Diffusion of ethene (1); hydrogen (2)

Vapor in Gas
C2H4 (1) ethene 74-85-1

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 107 [m2/s]
293.0 101.325 525.0 ± 5.0
Reference

Diffusion of ethene (1); water (2) 1
Diffusion of ethene (1); water (2)

Vapor in Gas
C2H4 (1) ethene 74-85-1

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 104 [m2/s]
307.8 101.325 0.204
328.5 101.325 0.233
352.3 101.325 0.247
Reference

Diffusion of ethene (1); helium (2) 1
Diffusion of ethene (1); helium (2)

Vapor in Gas
C2H4 (1) ethene 74-85-1

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
296.8 ± 0.1 101.325 0.525 ± 0.004
322.9 ± 0.1 101.325 0.599 ± 0.001
336.0 ± 0.1 101.325 0.649 ± 0.001
348.1 ± 0.1 101.325 0.674 ± 0.002
361.3 ± 0.1 101.325 0.726 ± 0.002
373.9 ± 0.1 101.325 0.780 ± 0.006
399.9 ± 0.1 101.325 0.860 ± 0.019
426.9 ± 0.1 101.325 0.932 ± 0.003
476.5 ± 0.1 101.325 1.112 ± 0.010
C2H4 (1) ethene 74-85-1

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
296.8 101.325 0.525 ± 0.004
322.9 101.325 0.599 ± 0.001
336.0 101.325 0.649 ± 0.001
348.1 101.325 0.674 ± 0.002
361.3 101.325 0.726 ± 0.002
373.9 101.325 0.780 ± 0.006
399.9 101.325 0.860 ± 0.019
426.9 101.325 0.932 ± 0.003
476.5 101.325 1.112 ± 0.010
C2H4 (1) ethene 74-85-1

He (2) helium 7440-59-7
T [K] p [kPa] D · 107 [m2/s]
296.0 101.325 558.0 ± 4.0
C2H4 (1) ethene 74-85-1

He (2) helium 7440-59-7
T [K] p [kPa] D · 105 [m2/s]
297.8 101.325 5.50 ± 0.05

2 Diffusion of ethene (1); helium (2)
C2H4 (1) ethene 74-85-1

He (2) helium 7440-59-7
T [K] p [MPa] D · 106 [m2/s]
344.0 0.80 7.87 ± 5%
344.0 0.80 7.84 ± 5%
References

Diffusion of ethene (1); nitrogen (2) 1
Diffusion of ethene (1); nitrogen (2)

Vapor in Gas
C2H4 (1) ethene 74-85-1

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 107 [m2/s]
292.0 101.325 161.0 ± 0.4
292.0 101.325 156.0 ± 0.4
296.0 101.325 168.0 ± 2.0
C2H4 (1) ethene 74-85-1

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
322.8 101.325 0.189 ± 0.00008
344.7 101.325 0.213 ± 0.0001
364.2 101.325 0.234 ± 0.0003
387.6 101.325 0.260 ± 0.0003
407.5 101.325 0.286 ± 0.0004
428.9 101.325 0.306 ± 0.0003
449.8 101.325 0.335 ± 0.0009
C2H4 (1) ethene 74-85-1

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
291.0 101.325 0.160
296.0 101.325 0.186
C2H4 (1) ethene 74-85-1

N2 (2) nitrogen 7727-37-9
Diffusion of gas(1) in gas(2): D*12(T ); Method: ARF Ref.: 1981K1
T [K] p [kPa] D · 104 [m2/s]
296 101.325 0.186
Comment: stopped flow technique
C2H4 (1) ethene 74-85-1

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 105 [m2/s]
322.8 101.325 1.89 ± 0.0008
344.7 101.325 2.13 ± 0.001
(continued)

2 Diffusion of ethene (1); nitrogen (2)
364.2 101.325 2.34 ± 0.003

387.6 101.325 2.60 ± 0.003
407.5 101.325 2.86 ± 0.004
428.9 101.325 3.06 ± 0.003
449.8 101.325 3.35 ± 0.009
C2H4 (1) ethene 74-85-1

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
322.8 ± 0.1 101.325 0.189 ± 0.00008
344.7 ± 0.1 101.325 0.213 ± 0.0001
364.2 ± 0.1 101.325 0.234 ± 0.0003
387.6 ± 0.1 101.325 0.260 ± 0.0003
407.5 ± 0.1 101.325 0.286 ± 0.0004
428.9 ± 0.1 101.325 0.306 ± 0.0003
449.8 ± 0.1 101.325 0.335 ± 0.0009
C2H4 (1) ethene 74-85-1

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
298.2 ± 0.1 101.325 0.170 ± 0.001
373.2 ± 0.1 101.325 0.253 ± 0.001
References
1981K1 Katsanos, N.A., Karaiskakis, G., Vattis, A., Lycourghiotis, A.: Chromatographia 14 (1981)
695–698.

Diffusion of 1,1-dichloro-ethane (1); air (2) 1
Diffusion of 1,1-dichloro-ethane (1); air (2)

Vapor in Gas
C2H4Cl2 (1) 1,1-dichloro-ethane 75-34-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 107 [m2/s]
298.15 101.325 0.0883 ± 2%
338.15 101.325 0.1177 ± 2%

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 9.19 ± 0.081
References

Diffusion of 1,2-dichloro-ethane (1); air (2) 1
Diffusion of 1,2-dichloro-ethane (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 9.07 ± 0.027
Reference

Diffusion of 1,2-dichloro-ethane (1); helium (2) 1
Diffusion of 1,2-dichloro-ethane (1); helium (2)

Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
427.1 ± 0.2 101.325 0.683 ± 0.006
Reference

Diffusion of 1,2-difluoro-ethane (1); helium (2) 1
Diffusion of 1,2-difluoro-ethane (1); helium (2)

Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
429.6 ± 0.2 101.325 0.754 ± 0.015
Reference

Diffusion of acetic acid (1); air (2) 1
Diffusion of acetic acid (1); air (2)

Vapor in Gas
C2H4O2 (1) acetic acid 64-19-7

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
290.15 ± 1.0 101.325 0.110 ± 0.003

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
297.85 101.325 0.0975 ± 0.0096
298.15 101.325 0.0968 ± 0.0082

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 12.35 ± 0.150
References
1997G1 Gibson, L.T., Cooksey, B.G., Littlejohn, D., Tennent, N.H.: Anal. Chim. Acta 341 (1997) 1–10.

Diffusion of formic acid methyl ester (1); air (2) 1
Diffusion of formic acid methyl ester (1); air (2)

Vapor in Gas
C2H4O2 (1) formic acid methyl ester 107-31-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 10.90 ± 0.088
Reference

Diffusion of bromo-ethane (1); air (2) 1
Diffusion of bromo-ethane (1); air (2)

Vapor in Gas
C2H5Br (1) bromo-ethane 74-96-4

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 9.89 ± 0.106

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
297.2 101.325 10.18
References
1969G9 Grob, A.K., El-Wakil, M.M.: J. Heat Transfer 91C (1969) 259–266.

Diffusion of bromo-ethane (1); helium (2) 1
Diffusion of bromo-ethane (1); helium (2)

Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
427.7 ± 0.2 101.325 0.740 ± 0.011
Reference

Diffusion of 2-chloro-ethanol (1); air (2) 1
Diffusion of 2-chloro-ethanol (1); air (2)

Vapor in Gas
C2H5ClO (1) 2-chloro-ethanol 107-07-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 9.64 ± 0.036
Reference

Diffusion of iodo-ethane (1); helium (2) 1
Diffusion of iodo-ethane (1); helium (2)

Vapor in Gas
C2H5I (1) iodo-ethane 75-03-6

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
428.4 ± 0.2 101.325 0.648 ± 0.013
Reference

Diffusion of ethane (1); air (2) 1
Diffusion of ethane (1); air (2)

Vapor in Gas
C2H6 (1) ethane 74-84-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.1531 ± 0.0038
Reference

Diffusion of ethane (1); argon (2) 1
Diffusion of ethane (1); argon (2)

Vapor in Gas
C2H6 (1) ethane 74-84-0

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.02 101.325 0.112
C2H6 (1) ethane 74-84-0

Ar (2) argon 7440-37-1
Diffusion of gas(1) in as(2): D*12(T ); Method: TAYLOR Ref.: 1974W3
T [K] p [bar] D · 104 [m2/s]
306.9 1.013 0.150
323.2 1.013 0.165
372.9 1.013 0.206
425.8 1.013 0.265
475.7 1.013 0.321
523.2 1.013 0.369
576.2 1.013 0.453
626.5 1.013 0.522
673.2 1.013 0.594
References

Diffusion of ethane (1); carbon dioxide (2) 1
Diffusion of ethane (1); carbon dioxide (2)

Vapor in Gas
C2H6 (1) ethane 74-84-0

T [K] p [kPa] D · 104 [m2/s]
298 101.325 0.122
Reference

Diffusion of ethane (1); ethyne (2) 1
Diffusion of ethane (1); ethyne (2)

Vapor in Gas
C2H6 (1) ethane 74-84-0

C2H2 (2) ethyne 74-86-2
T [K] p [kPa] D · 104 [m2/s]
298.2 ± 0.1 101.325 0.131 ± 0.001
352.6 ± 0.1 101.325 0.180 ± 0.001
382.5 ± 0.1 101.325 0.203 ± 0.001
Reference

Diffusion of ethane (1); ethene (2) 1
Diffusion of ethane (1); ethene (2)

Vapor in Gas
C2H6 (1) ethane 74-84-0

C2H4 (2) ethene 74-85-1
T [K] p [kPa] D · 104 [m2/s]
298.2 ± 0.1 101.325 0.114 ± 0.001
352.6 ± 0.1 101.325 0.161 ± 0.001
382.5 ± 0.1 101.325 0.189 ± 0.001
Reference

Diffusion of ethane (1); propane (2) 1
Diffusion of ethane (1); propane (2)

Vapor in Gas
C2H6 (1) ethane 74-84-0

C3H8 (2) propane 74-98-6
T [K] p [kPa] D · 104 [m2/s]
298 101.325 0.078
Reference

Diffusion of ethane (1); hydrogen (2) 1
Diffusion of ethane (1); hydrogen (2)

Vapor in Gas
C2H6 (1) ethane 74-84-0

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 107 [m2/s]
297.0 101.325 548.0 ± 5.0
C2H6 (1) ethane 74-84-0

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 109 [m2/s]
297 101.325 5.56 ± 0.13
C2H6 (1) ethane 74-84-0

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.54
References

Diffusion of ethane (1); helium (2) 1
Diffusion of ethane (1); helium (2)

Vapor in Gas
C2H6 (1) ethane 74-84-0

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
296.7 101.325 0.491 ± 0.002
322.6 101.325 0.556 ± 0.002
344.0 101.325 0.618 ± 0.003
364.4 101.325 0.684 ± 0.003
385.3 101.325 0.745 ± 0.006
407.3 101.325 0.807 ± 0.004
426.3 101.325 0.878 ± 0.008
447.3 101.325 0.941 ± 0.005
C2H6 (1) ethane 74-84-0

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
296.7 ± 0.1 101.325 0.491 ± 0.002
322.6 ± 0.1 101.325 0.556 ± 0.002
344.0 ± 0.1 101.325 0.618 ± 0.003
364.4 ± 0.1 101.325 0.684 ± 0.003
385.3 ± 0.1 101.325 0.745 ± 0.006
407.3 ± 0.1 101.325 0.807 ± 0.004
426.3 ± 0.1 101.325 0.878 ± 0.008
447.3 ± 0.1 101.325 0.941 ± 0.005
C2H6 (1) ethane 74-84-0

He (2) helium 7440-59-7
T [K] p [atm] D · 107 [m2/s]
298.15 272 1.77
298.15 408 1.22
298.15 543 0.94
298.15 681 0.77
298.15 818 0.68
298.15 1090 0.60
298.15 1360 0.58

2 Diffusion of ethane (1); helium (2)
C2H6 (1) ethane 74-84-0

He (2) helium 7440-59-7
T [K] p [psia] D · 104 [m2/s]
296.15 ± 2.0 30.8 0.223 ± 2%
373.15 ± 2.0 30.8 0.314 ± 2%
C2H6 (1) ethane 74-84-0

He (2) helium 7440-59-7
T [K] p [kPa] D · 107 [m2/s]
295.6 101.325 518.0 ± 3.0
C2H6 (1) ethane 74-84-0

He (2) helium 7440-59-7
T [K] p [kPa] D · 105 [m2/s]
295.8 101.325 4.92 ± 0.03
References

Diffusion of ethane (1); nitrogen (2) 1
Diffusion of ethane (1); nitrogen (2)

Vapor in Gas
C2H6 (1) ethane 74-84-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
322.8 ± 0.1 101.325 0.172 ± 0.0002
345.7 ± 0.1 101.325 0.193 ± 0.0002
365.0 ± 0.1 101.325 0.214 ± 0.0007
388.5 ± 0.1 101.325 0.242 ± 0.0003
407.6 ± 0.1 101.325 0.256 ± 0.0002
427.5 ± 0.1 101.325 0.282 ± 0.0004
449.3 ± 0.1 101.325 0.303 ± 0.0005
C2H6 (1) ethane 74-84-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 105 [m2/s]
322.8 101.325 1.72 ± 0.002
345.7 101.325 1.93 ± 0.002
365.0 101.325 2.14 ± 0.007
388.5 101.325 2.42 ± 0.003
407.6 101.325 2.56 ± 0.002
427.5 101.325 2.82 ± 0.004
449.3 101.325 3.03 ± 0.005
C2H6 (1) ethane 74-84-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
322.8 101.325 0.172 ± 0.0002
345.7 101.325 0.193 ± 0.0002
365.0 101.325 0.214 ± 0.0007
388.5 101.325 0.242 ± 0.0003
407.6 101.325 0.256 ± 0.0002
427.5 101.325 0.282 ± 0.0004
449.3 101.325 0.303 ± 0.0005
C2H6 (1) ethane 74-84-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.14

2 Diffusion of ethane (1); nitrogen (2)
C2H6 (1) ethane 74-84-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.02 101.325 0.143
C2H6 (1) ethane 74-84-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 107 [m2/s]
293.0 101.325 142.0 ± 0.03
References

Diffusion of ethanol (1); air (2) 1
Diffusion of ethanol (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 11.81 ± 0.128

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
295.45 ± 0.3 101.325 0.116 ± 5%

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.05 101.325 0.1318 ± 0.0045

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
293.15 101.325 0.1120

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
335.85 ± 0.2 101.325 0.1222 ± 0.0013
References

Diffusion of ethanol (1); argon (2) 1
Diffusion of ethanol (1); argon (2)

Vapor in Gas

Ar (2) argon 7440-37-1
Integral Diffusion Coefficient: D(T ); Method: STEFAN Ref.: 1978K7
T [K] p [kPa] D · 104 [m2/s]
300.0 101.325 0.101 ± 0.008
300.0 101.325 0.109 ± 0.010
Reference
1978K7 Kurlapov, L.I., Chernyak, S.N.: J. Eng. Phys. Thermophys. 35 (1978) 287–291.

Diffusion of ethanol (1); carbon dioxide (2) 1
Diffusion of ethanol (1); carbon dioxide (2)

Vapor in Gas

T [K] p [kPa] D · 104 [m2/s]
298.8 101.325 0.080 ± 0.019
298.8 101.325 0.060 ± 0.013
Reference
1977K8 Kurlapov, L.I., Chernyak, S.N.: Prikl. Teor. Fiz. 10 (1977) 146–151.

Diffusion of ethanol (1); hydrogen (2) 1
Diffusion of ethanol (1); hydrogen (2)

Vapor in Gas

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
353 101.325 0.7200 ± 1.4%
373 101.325 0.7820 ± 1.3%
393 101.325 0.8420 ± 0.61%
423 101.325 0.9460 ± 2.8%
453 101.325 1.0770 ± 4.9%

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
353.15 101.325 0.7200 ± 0.0100
373.15 101.325 0.7820 ± 0.0102
393.15 101.325 0.8420 ± 0.0051
423.15 101.325 0.9460 ± 0.0261
453.15 101.325 1.0770 ± 0.0530
References

Diffusion of ethanol (1); helium (2) 1
Diffusion of ethanol (1); helium (2)

Vapor in Gas

He (2) helium 7440-59-7
Diffusion of gas(1) in gas(2): D*12(T ); Method: RF-GC Ref.: 1989A1
T [K] p [kPa] D · 109 [m2/s]
298.2 101.325 3.92

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
423.15 101.325 0.821 ± 0.009
443.15 101.325 0.862 ± 0.010
463.15 101.325 0.925 ± 0.015
483.15 101.325 0.997 ± 0.031
503.15 101.325 1.048 ± 0.005
523.15 101.325 1.173 ± 0.004

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.2 101.325 0.496
References
1967H3 Hargrove, G.L., Sawyer, D.T.: Anal. Chem. 39 (1967) 244–246.

Diffusion of ethanol (1); nitrogen (2) 1
Diffusion of ethanol (1); nitrogen (2)

Vapor in Gas

N2 (2) nitrogen 7727-37-9
T [K] p [MPa] D · 107 [m2/s]
298 0.1022 130.6
298 0.197 65.6
298 0.393 32.1
298 0.98 12.25
298 2.45 4.54
298 4.91 2.27
298 8.88 1.23
323 0.1010 155.0
323 0.197 77.8
323 0.98 14.6
323 2.45 5.64
323 4.91 2.76
323 8.88 1.50
349 0.197 94.0
349 0.393 45.6
349 0.98 17.8
349 2.45 6.90
349 4.91 3.42
349 8.88 1.87

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 106 [m2/s]
293.2 101.325 13.00
298.2 101.325 13.17
303.2 101.325 14.25
313.2 101.325 15.36
323.2 101.325 15.45
333.2 101.325 17.20
343.2 101.325 18.23
References

Diffusion of ethane-1,2-diol (1); air (2) 1
Diffusion of ethane-1,2-diol (1); air (2)

Vapor in Gas
C2H6O2 (1) ethane-1,2-diol 107-21-1

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 10.05 ± 0.381
Reference

Diffusion of ethane-1,2-diol (1); carbon dioxide (2) 1
Diffusion of ethane-1,2-diol (1); carbon dioxide (2)

Vapor in Gas
C2H6O2 (1) ethane-1,2-diol 107-21-1

T [K] p [kPa] D · 106 [m2/s]
323.2 101.325 8.68
348.2 101.325 10.86
373.2 101.325 13.03
398.2 101.325 15.30
423.2 101.325 17.47
448.2 101.325 19.73
473.2 101.325 21.90
Reference

Diffusion of ethane-1,2-diol (1); nitrogen (2) 1
Diffusion of ethane-1,2-diol (1); nitrogen (2)

Vapor in Gas
C2H6O2 (1) ethane-1,2-diol 107-21-1

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 106 [m2/s]
375.2 101.325 20.40
404.2 101.325 24.70
438.2 101.325 29.40
472.2 101.325 34.30
Reference

Diffusion of ethane-1,2-diamine (1); air (2) 1
Diffusion of ethane-1,2-diamine (1); air (2)

Vapor in Gas
C2H8N2 (1) ethane-1,2-diamine 107-15-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 10.09 ± 0.201
Reference

Diffusion of acrylonitrile (1); air (2) 1
Diffusion of acrylonitrile (1); air (2)

Vapor in Gas
C3H3N (1) acrylonitrile 107-13-1

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 10.59 ± 0.032
Reference

Diffusion of propyne (1); air (2) 1
Diffusion of propyne (1); air (2)

Vapor in Gas
C3H4 (1) propyne 74-99-7

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.1316 ± 0.0011
Reference

Diffusion of propadiene (1); air (2) 1
Diffusion of propadiene (1); air (2)

Vapor in Gas
C3H4 (1) propadiene 463-49-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.1392 ± 0.0018
Reference

Diffusion of 1,2-dibromo-3-chloro-propane (1); air (2) 1
Diffusion of 1,2-dibromo-3-chloro-propane (1); air (2)

Vapor in Gas
C3H5Br2Cl (1) 1,2-dibromo-3-chloro-propane 96-12-8

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.86 ± 0.037
Reference

Diffusion of 3-chloro-prop-1-ene (1); air (2) 1
Diffusion of 3-chloro-prop-1-ene (1); air (2)

Vapor in Gas
C3H5Cl (1) 3-chloro-prop-1-ene 107-05-1

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 9.75 ± 0.052
Reference

Diffusion of propene (1); air (2) 1
Diffusion of propene (1); air (2)

Vapor in Gas
C3H6 (1) propene 115-07-1

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.1318 ± 0.0017
Reference

Diffusion of cyclopropane (1); air (2) 1
Diffusion of cyclopropane (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.1277 ± 0.0012
Reference

Diffusion of propene (1); hydrogen (2) 1
Diffusion of propene (1); hydrogen (2)

Vapor in Gas
C3H6 (1) propene 115-07-1

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 107 [m2/s]
296.0 101.325 485.0 ± 3.0
Reference

Diffusion of propene (1); helium (2) 1
Diffusion of propene (1); helium (2)

Vapor in Gas
C3H6 (1) propene 115-07-1

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
345.0 ± 0.1 101.325 0.528 ± 0.0007
365.5 ± 0.1 101.325 0.584 ± 0.001
388.0 ± 0.1 101.325 0.642 ± 0.001
407.7 ± 0.1 101.325 0.690 ± 0.001
428.0 ± 0.1 101.325 0.750 ± 0.002
449.4 ± 0.1 101.325 0.819 ± 0.003
C3H6 (1) propene 115-07-1

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
345.0 101.325 0.528 ± 0.0007
365.5 101.325 0.584 ± 0.001
388.0 101.325 0.642 ± 0.001
407.7 101.325 0.690 ± 0.001
428.0 101.325 0.750 ± 0.002
449.4 101.325 0.819 ± 0.003
C3H6 (1) propene 115-07-1

He (2) helium 7440-59-7
T [K] p [MPa] D · 104 [m2/s]
344.0 0.80 8.57 ± 5%
344.0 0.80 6.33 ± 5%
C3H6 (1) propene 115-07-1

He (2) helium 7440-59-7
T [K] p [kPa] D · 105 [m2/s]
297.0 101.325 4.41 ± 0.02
C3H6 (1) propene 115-07-1

He (2) helium 7440-59-7
T [K] p [kPa] D · 107 [m2/s]
291.0 101.325 412.0 ± 4.0

2 Diffusion of propene (1); helium (2)
References

Diffusion of propene (1); nitrogen (2) 1
Diffusion of propene (1); nitrogen (2)

Vapor in Gas
C3H6 (1) propene 115-07-1

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
322.8 ± 0.1 101.325 0.143 ± 0.0002
344.6 ± 0.1 101.325 0.164 ± 0.0001
387.4 ± 0.1 101.325 0.202 ± 0.0002
406.4 ± 0.1 101.325 0.220 ± 0.0004
428.9 ± 0.1 101.325 0.243 ± 0.0003
459.0 ± 0.1 101.325 0.266 ± 0.0002
C3H6 (1) propene 115-07-1

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
322.8 101.325 0.143 ± 0.0002
344.6 101.325 0.164 ± 0.0001
387.4 101.325 0.200 ± 0.0002
406.4 101.325 0.220 ± 0.0004
428.9 101.325 0.243 ± 0.0003
459.0 101.325 0.266 ± 0.0002
C3H6 (1) propene 115-07-1

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
296.0 101.325 0.127 ± 0.0027
296.0 101.325 0.130
296.0 101.325 0.129
296.0 101.325 0.124
C3H6 (1) propene 115-07-1

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
296 101.325 0.127 ± 0.0027
Comment: stopped flow technique

2 Diffusion of propene (1); nitrogen (2)
C3H6 (1) propene 115-07-1

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 107 [m2/s]
298.0 101.325 124.0 ± 0.4
References
695–698.

Diffusion of 2-bromo-1-chloro-propane (1); helium (2) 1
Diffusion of 2-bromo-1-chloro-propane (1); helium (2)

Vapor in Gas
C3H6BrCl (1) 2-bromo-1-chloro-propane 3017-95-6

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
427.2 ± 0.2 101.325 0.570 ± 0.016
Reference

Diffusion of 1,2-dichloro-propane (1); air (2) 1
Diffusion of 1,2-dichloro-propane (1); air (2)

Vapor in Gas
C3H6Cl2 (1) 1,2-dichloro-propane 78-87-5

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.94 ± 0.147
Reference

Diffusion of propan-2-one (1); air (2) 1
Diffusion of propan-2-one (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
297.45 101.325 0.1008 ± 0.0004
299.25 101.325 0.1117 ± 0.0005

Air (2) air 132259-10-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: OTE Ref.: 1997B6
T [K] p [MPa] D · 107 [m2/s]
314 0.1013 122.0
314 0.203 65.4
314 0.392 28.0
314 0.686 16.0
314 1.08 10.4
314 2.06 4.74
314 3.04 2.62
314 4.02 1.78

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 10.49 ± 0.057

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
293.15 101.325 0.1260
References

Diffusion of prop-2-en-1-ol (1); air (2) 1
Diffusion of prop-2-en-1-ol (1); air (2)

Vapor in Gas
C3H6O (1) prop-2-en-1-ol 107-18-6

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 10.21 ± 0.035
Reference

Diffusion of propan-2-one (1); argon (2) 1
Diffusion of propan-2-one (1); argon (2)

Vapor in Gas

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 107 [m2/s]
283.2 101.325 87.5
299.5 101.325 98
300.0 101.325 98.00 ± 2%
301.0 101.325 99.18 ± 2%
323.0 101.325 112.7 ± 2%
363.0 101.325 139*
383.0 101.325 152.0 ± 2%
403.0 101.325 168.7 ± 2%
423.0 101.325 184.7 ± 2%
Comment: *: ref. data

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
300.0 101.325 0.098 ± 0.002
300.0 101.325 0.098 ± 0.003

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 107 [m2/s]
298.15 ± 0.2 101.325 0.115 ± 0.003
372.65 ± 0.2 101.325 0.175 ± 0.003
423.15 ± 0.2 101.325 0.213 ± 0.002
473.15 ± 0.2 101.325 0.249 ± 0.003
References
1985B6 Bereznoj, A.N., Shekurov, V.N.: J. Eng. Phys. Thermophys. 49 (1985) 266–270.


Vapor in Gas

T [K] p [kPa] D · 104 [m2/s]
299.0 101.325 0.070 ± 0.003
299.0 101.325 0.073 ± 0.002
Reference

Diffusion of propan-2-one (1); helium (2) 1
Diffusion of propan-2-one (1); helium (2)

Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.2 101.325 0.411 ± 0.014
372.65 ± 0.2 101.325 0.638 ± 0.017
423.15 ± 0.2 101.325 0.754 ± 0.014
473.15 ± 0.2 101.325 0.889 ± 0.017

He (2) helium 7440-59-7
Diffusion of gas(1) in gas(2): D*12(T ); Method: RF GC Ref.: 1989A1
T [K] p [kPa] D · 109 [m2/s]
318.2 101.325 4.02
References

Diffusion of propan-2-one (1); nitrogen (2) 1
Diffusion of propan-2-one (1); nitrogen (2)

Vapor in Gas

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
343.1 ± 0.2 101.325 0.140
363.1 ± 0.2 101.325 0.154
383.2 ± 0.2 101.325 0.170

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
353.0 101.325 0.135 ± 5.2%
References

Diffusion of acetic acid methyl ester (1); air (2) 1
Diffusion of acetic acid methyl ester (1); air (2)

Vapor in Gas
C3H6O2 (1) acetic acid methyl ester 79-20-9

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 9.78 ± 0.152
Reference

Diffusion of formic acid ethyl ester (1); air (2) 1
Diffusion of formic acid ethyl ester (1); air (2)

Vapor in Gas
C3H6O2 (1) formic acid ethyl ester 109-94-4

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 9.76 ± 0.086
Reference

Diffusion of propionic acid (1); air (2) 1
Diffusion of propionic acid (1); air (2)

Vapor in Gas
C3H6O2 (1) propionic acid 79-09-4

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 9.52 ± 0.083
Reference

Diffusion of formic acid ethyl ester (1); carbon dioxide (2) 1
Diffusion of formic acid ethyl ester (1); carbon dioxide (2)

Vapor in Gas

T [K] p [kPa] D · 104 [m2/s]
333.5 ± 0.2 101.325 0.099
348.3 ± 0.2 101.325 0.105
362.9 ± 0.2 101.325 0.116
Reference

Diffusion of acetic acid methyl ester (1); carbon dioxide (2) 1
Diffusion of acetic acid methyl ester (1); carbon dioxide (2)

Vapor in Gas

T [K] p [kPa] D · 104 [m2/s]
363.3 ± 0.2 101.325 0.114
383.2 ± 0.2 101.325 0.126
Reference

Diffusion of formic acid ethyl ester (1); nitrogen (2) 1
Diffusion of formic acid ethyl ester (1); nitrogen (2)

Vapor in Gas

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
343.7 ± 0.2 101.325 0.131
363.2 ± 0.2 101.325 0.143
383.2 ± 0.2 101.325 0.158
403.2 ± 0.2 101.325 0.168
Reference

Diffusion of acetic acid methyl ester (1); nitrogen (2) 1
Diffusion of acetic acid methyl ester (1); nitrogen (2)

Vapor in Gas

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
363.5 ± 0.2 101.325 0.171
383.1 ± 0.2 101.325 0.192
403.4 ± 0.2 101.325 0.209

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
357.0 101.325 0.168 ± 14%
References

Diffusion of 1-bromo-propane (1); air (2) 1
Diffusion of 1-bromo-propane (1); air (2)

Vapor in Gas
C3H7Br (1) 1-bromo-propane 106-94-5

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 8.75 ± 0.044
Reference

Diffusion of 2-bromo-propane (1); air (2) 1
Diffusion of 2-bromo-propane (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 9.14 ± 0.077
Reference

Diffusion of 1-bromo-propane (1); helium (2) 1
Diffusion of 1-bromo-propane (1); helium (2)

Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
428.2 ± 0.2 101.325 0.592 ± 0.009
Reference

Diffusion of 2-bromo-propane (1); helium (2) 1
Diffusion of 2-bromo-propane (1); helium (2)

Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
428.0 ± 0.2 101.325 0.606 ± 0.012
Reference

Diffusion of 1-chloro-propane (1); helium (2) 1
Diffusion of 1-chloro-propane (1); helium (2)

Vapor in Gas
C3H7Cl (1) 1-chloro-propane 540-54-5

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
427.5 ± 0.2 101.325 0.631 ± 0.009
Reference

Diffusion of 1-iodo-propane (1); air (2) 1
Diffusion of 1-iodo-propane (1); air (2)

Vapor in Gas
C3H7I (1) 1-iodo-propane 107-08-4

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 8.68 ± 0.082
Reference

Diffusion of 2-iodo-propane (1); air (2) 1
Diffusion of 2-iodo-propane (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 8.78 ± 0.119
Reference

Diffusion of 1-iodo-propane (1); helium (2) 1
Diffusion of 1-iodo-propane (1); helium (2)

Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
430.0 ± 0.2 101.325 0.579 ± 0.007
Reference

Diffusion of 2-iodo-propane (1); helium (2) 1
Diffusion of 2-iodo-propane (1); helium (2)

Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
430.2 ± 0.2 101.325 0.579 ± 0.012
Reference

Diffusion of N,N-dimethyl-formamide (1); air (2) 1
Diffusion of N,N-dimethyl-formamide (1); air (2)

Vapor in Gas
C3H7NO (1) N,N-dimethyl-formamide 68-12-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 9.73 ± 0.079
Reference

Diffusion of propane (1); argon (2) 1
Diffusion of propane (1); argon (2)

Vapor in Gas
C3H8 (1) propane 74-98-6

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.02 101.325 0.091
C3H8 (1) propane 74-98-6

Ar (2) argon 7440-37-1
T [K] p [bar] D · 104 [m2/s]
305.6 1.013 0.113
325.9 1.013 0.124
374.8 1.013 0.163
427.1 1.013 0.209
477.9 1.013 0.256
524.2 1.013 0.297
580.4 1.013 0.355
626.9 1.013 0.399
679.0 1.013 0.461
References

Diffusion of propane (1); hydrogen (2) 1
Diffusion of propane (1); hydrogen (2)

Vapor in Gas
C3H8 (1) propane 74-98-6

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.44
Reference

Diffusion of propane (1); helium (2) 1
Diffusion of propane (1); helium (2)

Vapor in Gas
C3H8 (1) propane 74-98-6

He (2) helium 7440-59-7
T [K] p [atm] D · 107 [m2/s]
298.15 272 1.51
298.15 408 1.05
298.15 543 0.80
298.15 681 0.66
298.15 818 0.58
298.15 1090 0.52
298.15 1360 0.50
C3H8 (1) propane 74-98-6

He (2) helium 7440-59-7
T [K] p [kPa] D · 105 [m2/s]
294.7 101.325 4.50 ± 0.04
C3H8 (1) propane 74-98-6

He (2) helium 7440-59-7
T [K] p [psia] D · 104 [m2/s]
296.15 ± 2.0 30.5 0.178 ± 2%
373.15 ± 2.0 31.5 0.252 ± 2%
References

Diffusion of propane (1); nitrogen (2) 1
Diffusion of propane (1); nitrogen (2)

Vapor in Gas
C3H8 (1) propane 74-98-6

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.11
C3H8 (1) propane 74-98-6

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.02 101.325 0.155
References

Diffusion of propan-1-ol (1); air (2) 1
Diffusion of propan-1-ol (1); air (2)

Vapor in Gas
C3H8O (1) propan-1-ol 71-23-8

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 9.93 ± 0.074
C3H8O (1) propan-1-ol 71-23-8

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
349.85 ± 0.2 101.325 0.1257 ± 0.0014
C3H8O (1) propan-1-ol 71-23-8

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
297.95 101.325 0.1051 ± 0.0030
References

Diffusion of propan-2-ol (1); air (2) 1
Diffusion of propan-2-ol (1); air (2)

Vapor in Gas
C3H8O (1) propan-2-ol 67-63-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 10.13 ± 0.392
C3H8O (1) propan-2-ol 67-63-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
349.85 ± 0.2 101.325 0.1219 ± 0.0013
C3H8O (1) propan-2-ol 67-63-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
293.15 101.325 0.0900
References

Diffusion of propan-1-ol (1); carbon dioxide (2) 1
Diffusion of propan-1-ol (1); carbon dioxide (2)

Vapor in Gas
C3H8O (1) propan-1-ol 71-23-8

T [K] p [kPa] D · 106 [m2/s]
323.2 101.325 8.03
343.9 101.325 8.87
369.9 101.325 10.61
C3H8O (1) propan-1-ol 71-23-8

T [K] p [kPa] D · 107 [m2/s]
293.2 101.325 62.80 ± 2%
323.2 101.325 80.3 ± 2%
343.9 101.325 88.72 ± 2%
369.9 101.325 106.1 ± 2%
395.9 101.325 118.8 ± 2%
424.2 101.325 135.3 ± 2%
443.0 101.325 146.1 ± 2%
References


Vapor in Gas
C3H8O (1) propan-2-ol 67-63-0

T [K] p [kPa] D · 104 [m2/s]
362.8 ± 0.2 101.325 0.110
383.5 ± 0.2 101.325 0.120
403.3 ± 0.2 101.325 0.135
418.1 ± 0.2 101.325 0.145
Reference

Diffusion of propan-1-ol (1); helium (2) 1
Diffusion of propan-1-ol (1); helium (2)

Vapor in Gas
C3H8O (1) propan-1-ol 71-23-8

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
423.15 101.325 0.676 ± 0.016
443.15 101.325 0.711 ± 0.007
463.15 101.325 0.761 ± 0.018
483.15 101.325 0.829 ± 0.005
503.15 101.325 0.896 ± 0.005
523.15 101.325 0.959 ± 0.001
C3H8O (1) propan-1-ol 71-23-8

He (2) helium 7440-59-7
T [K] p [kPa] D · 107 [m2/s]
253.2 101.325 243.2
293.2 101.325 337.7
313.2 101.325 390.3
314.0 101.325 400*
314.2 101.325 399.0
323.2 101.325 404.6 ± 2%
333.2 101.325 452.1
333.2 101.325 432*
334.0 101.325 449*
334.2 101.325 459.0
353.2 101.325 473.5 ± 2%
353.2 101.325 518.1
353.6 101.325 485.1 ± 2%
363.2 101.325 540.4
392.0 101.325 597.0 ± 2%
423.2 101.325 676 *
423.9 101.325 657.1 ± 2%
443.2 101.325 711*
463.2 101.325 761*
483.2 101.325 829*
503.2 101.325 896*
523.2 101.325 959*

2 Diffusion of propan-1-ol (1); helium (2)
C3H8O (1) propan-1-ol 71-23-8

He (2) helium 7440-59-7
T [K] p [MPa] D · 107 [m2/s]
314 0.1012 400.0
314 0.102 386.0
314 0.392 103.0
314 0.98 42.0
314 1.86 22.3
314 3.48 11.9
334 0.102 450.0
334 0.222 214.0
334 0.392 119.4
334 0.98 48.2
334 1.86 25.7
334 3.48 13.8
References

Diffusion of propan-2-ol (1); helium (2) 1
Diffusion of propan-2-ol (1); helium (2)

Vapor in Gas
C3H8O (1) propan-2-ol 67-63-0

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
423.15 101.325 0.677 ± 0.022
443.15 101.325 0.732 ± 0.005
463.15 101.325 0.784 ± 0.006
483.15 101.325 0.834 ± 0.011
503.15 101.325 0.882 ± 0.006
523.15 101.325 0.988 ± 0.020
C3H8O (1) propan-2-ol 67-63-0

He (2) helium 7440-59-7
T [K] p [MPa] D · 107 [m2/s]
314 0.100 378.0
314 0.242 154.0
314 0.392 96.1
314 0.98 38.4
314 1.86 20.4
314 3.48 10.9
334 0.100 420.0
334 0.227 188.4
334 0.392 109.6
334 0.98 44.1
334 1.86 23.4
334 3.48 12.7
References

Diffusion of propan-1-ol (1); nitrogen (2) 1
Diffusion of propan-1-ol (1); nitrogen (2)

Vapor in Gas
C3H8O (1) propan-1-ol 71-23-8

N2 (2) nitrogen 7727-37-9
T [K] p [MPa] D · 107 [m2/s]
314 0.100 116.5
314 0.392 26.9
314 0.98 10.1
314 1.86 5.07
314 3.48 2.63
334 0.100 135.0
334 0.102 131.0
334 0.392 30.2
334 0.98 11.2
334 1.86 5.62
334 3.48 2.95
C3H8O (1) propan-1-ol 71-23-8

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 106 [m2/s]
253.2 101.325 7.05
293.2 101.325 9.80
303.2 101.325 10.50
313.2 101.325 11.36
333.2 101.325 13.18
353.2 101.325 15.43
363.2 101.325 16.47
Reference

Diffusion of propan-2-ol (1); nitrogen (2) 1
Diffusion of propan-2-ol (1); nitrogen (2)

Vapor in Gas
C3H8O (1) propan-2-ol 67-63-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
362.9 ± 0.2 101.325 0.159
383.2 ± 0.2 101.325 0.168
C3H8O (1) propan-2-ol 67-63-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
357.0 101.325 0.146 ± 3.5%
C3H8O (1) propan-2-ol 67-63-0

N2 (2) nitrogen 7727-37-9
T [K] p [MPa] D · 107 [m2/s]
314 0.1005 108.5
314 0.102 105.0
314 0.392 24.2
314 0.98 9.12
314 1.86 4.48
314 3.48 2.34
334 0.101 119.0
334 0.392 27.5
334 0.98 10.35
334 1.86 5.24
334 3.48 2.69
References

Diffusion of propane-1,2-diol (1); air (2) 1
Diffusion of propane-1,2-diol (1); air (2)

Vapor in Gas
C3H8O2 (1) propane-1,2-diol 57-55-6

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 8.79 ± 0.025
Reference

Diffusion of 2-methoxy-ethanol (1); air (2) 1
Diffusion of 2-methoxy-ethanol (1); air (2)

Vapor in Gas
C3H8O2 (1) 2-methoxy-ethanol 109-86-4

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 8.84 ± 0.058
Reference

Diffusion of buta-1,3-diene (1); air (2) 1
Diffusion of buta-1,3-diene (1); air (2)

Vapor in Gas
C4H6 (1) buta-1,3-diene 106-99-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.2 101.325 0.1158 ± 0.0018
Reference

Diffusion of but-1-yne (1); air (2) 1
Diffusion of but-1-yne (1); air (2)

Vapor in Gas
C4H6 (1) but-1-yne 107-00-6

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.2 101.325 0.1163 ± 0.0020
Reference

Diffusion of trans-but-2-ene (1); air (2) 1
Diffusion of trans-but-2-ene (1); air (2)

Vapor in Gas
C4H8 (1) trans-but-2-ene 624-64-6

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.2 101.325 0.1131 ± 0.0012
Reference

Diffusion of cis-but-2-ene (1); air (2) 1
Diffusion of cis-but-2-ene (1); air (2)

Vapor in Gas
C4H8 (1) cis-but-2-ene 590-18-1

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.2 101.325 0.1087 ± 0.0013
Reference

Diffusion of 2-methyl-propene (1); air (2) 1
Diffusion of 2-methyl-propene (1); air (2)

Vapor in Gas
C4H8 (1) 2-methyl-propene 115-11-7

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.2 101.325 0.1072 ± 0.0032
Reference

Diffusion of but-1-ene (1); air (2) 1
Diffusion of but-1-ene (1); air (2)

Vapor in Gas
C4H8 (1) but-1-ene 106-98-9

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.2 101.325 0.1092 ± 0.0016
Reference

Diffusion of 2-methyl-propene (1); ethene (2) 1
Diffusion of 2-methyl-propene (1); ethene (2)

Vapor in Gas

C2H4 (2) ethene 74-85-1
T [K] p [kPa] D · 106 [m2/s]
344.0 101.325 1.45 ± 5%
Reference

Diffusion of cis-but-2-ene (1); ethene (2) 1
Diffusion of cis-but-2-ene (1); ethene (2)

Vapor in Gas
C4H8 (1) cis-but-2-ene 590-18-1

C2H4 (2) ethene 74-85-1
T [K] p [kPa] D · 106 [m2/s]
344.0 101.325 1.33 ± 5%
Reference

Diffusion of 2-methyl-propene (1); helium (2) 1
Diffusion of 2-methyl-propene (1); helium (2)

Vapor in Gas

He (2) helium 440-59-7
T [K] p [kPa] D · 105 [m2/s]
293.0 101.325 3.83 ± 0.03
Reference

Diffusion of cis-but-2-ene (1); helium (2) 1
Diffusion of cis-but-2-ene (1); helium (2)

Vapor in Gas
C4H8 (1) cis-but-2-ene 590-18-1

He (2) helium 7440-59-7
T [K] p [kPa] D · 105 [m2/s]
291.8 101.325 3.56 ± 0.02
C4H8 (1) cis-but-2-ene 590-18-1

He (2) helium 7440-59-7
T [K] p [MPa] D · 106 [m2/s]
344.0 0.80 5.54 ± 5%
344.0 0.80 5.31 ± 5%
References

Diffusion of but-1-ene (1); helium (2) 1
Diffusion of but-1-ene (1); helium (2)

Vapor in Gas
C4H8 (1) but-1-ene 106-98-9

He (2) helium 7440-59-7
T [K] p [kPa] D · 105 [m2/s]
291.0 101.325 3.53 ± 0.02
Reference

Diffusion of trans-but-2-ene (1); helium (2) 1
Diffusion of trans-but-2-ene (1); helium (2)

Vapor in Gas
C4H8 (1) trans-but-2-ene 624-64-6

He (2) helium 7440-59-7
T [K] p [kPa] D · 105 [m2/s]
292.0 101.325 3.65 ± 0.03
Reference

Diffusion of bis-(2-chloro-ethyl) ether (1); air (2) 1
Diffusion of bis-(2-chloro-ethyl) ether (1); air (2)

Vapor in Gas
C4H8Cl2O (1) bis-(2-chloro-ethyl) ether 111-44-4

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.94 ± 0.107
Reference

Diffusion of butan-2-one (1); air (2) 1
Diffusion of butan-2-one (1); air (2)

Vapor in Gas
C4H8O (1) butan-2-one 78-93-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 9.03 ± 0.027
Reference

Diffusion of isobutyric acid (1); air (2) 1
Diffusion of isobutyric acid (1); air (2)

Vapor in Gas
C4H8O2 (1) isobutyric acid 79-31-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.85 ± 0.065
Reference

Diffusion of butyric acid (1); air (2) 1
Diffusion of butyric acid (1); air (2)

Vapor in Gas
C4H8O2 (1) butyric acid 107-92-6

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.75 ± 0.070
Reference

Diffusion of propionic acid methyl ester (1); air (2) 1
Diffusion of propionic acid methyl ester (1); air (2)

Vapor in Gas
C4H8O2 (1) propionic acid methyl ester 554-12-1

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 8.62 ± 0.132
Reference

Diffusion of 1,4-dioxane (1); air (2) 1
Diffusion of 1,4-dioxane (1); air (2)

Vapor in Gas
C4H8O2 (1) 1,4-dioxane 123-91-1

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
283.10 ± 0.005 101.325 6.773 ± 0.5%
298.18 ± 0.005 101.325 7.710 ± 0.5%
313.16 ± 0.005 101.325 8.825 ± 0.5%
328.13 ± 0.005 101.325 10.035 ± 0.5%
343.19 ± 0.005 101.325 11.156 ± 0.5%
C4H8O2 (1) 1,4-dioxane 123-91-1

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 9.22 ± 0.057
References

Diffusion of formic acid propyl ester (1); air (2) 1
Diffusion of formic acid propyl ester (1); air (2)

Vapor in Gas
C4H8O2 (1) formic acid propyl ester 110-74-7

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 8.31 ± 0.081
Reference

Diffusion of acetic acid ethyl ester (1); air (2) 1
Diffusion of acetic acid ethyl ester (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 8.61 ± 0.140

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
295.45 ± 0.3 101.325 0.0849 ± 5%

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.45 101.325 0.0884 ± 0.0016
References

Diffusion of acetic acid ethyl ester (1); nitrogen (2) 1
Diffusion of acetic acid ethyl ester (1); nitrogen (2)

Vapor in Gas

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
355.0 101.325 0.137 ± 12%
Reference

Diffusion of 1-bromo-butane (1); helium (2) 1
Diffusion of 1-bromo-butane (1); helium (2)

Vapor in Gas
C4H9Br (1) 1-bromo-butane 109-65-9

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
426.6 ± 0.2 101.325 0.545 ± 0.006
Reference

Diffusion of 2-bromo-butane (1); helium (2) 1
Diffusion of 2-bromo-butane (1); helium (2)

Vapor in Gas
C4H9Br (1) 2-bromo-butane 78-76-2

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
427.2 ± 0.2 101.325 0.553 ± 0.013
Reference

Diffusion of 1-chloro-butane (1); helium (2) 1
Diffusion of 1-chloro-butane (1); helium (2)

Vapor in Gas
C4H9Cl (1) 1-chloro-butane 109-69-3

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
429.2 ± 0.2 101.325 0.555 ± 0.010
Reference

Diffusion of 2-chloro-butane (1); helium (2) 1
Diffusion of 2-chloro-butane (1); helium (2)

Vapor in Gas
C4H9Cl (1) 2-chloro-butane 78-86-4

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
429.1 ± 0.2 101.325 0.561 ± 0.008
Reference

Diffusion of 1-iodo-butane (1); helium (2) 1
Diffusion of 1-iodo-butane (1); helium (2)

Vapor in Gas
C4H9I (1) 1-iodo-butane 542-69-8

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
428.1 ± 0.2 101.325 0.524 ± 0.007
Reference

Diffusion of 2-iodo-butane (1); helium (2) 1
Diffusion of 2-iodo-butane (1); helium (2)

Vapor in Gas
C4H9I (1) 2-iodo-butane 513-48-4

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
427.1 ± 0.2 101.325 0.545 ± 0.013
Reference

Diffusion of butane (1); air (2) 1
Diffusion of butane (1); air (2)

Vapor in Gas
C4H10 (1) butane 106-97-8

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.2 101.325 0.1021 ± 0.0013
Reference

Diffusion of 2-methyl-propane (1); argon (2) 1
Diffusion of 2-methyl-propane (1); argon (2)

Vapor in Gas

Ar (2) argon 7440-37-1
T [K] p [bar] D · 104 [m2/s]
305.5 1.013 0.0890
321.7 1.013 0.102
374.5 1.013 0.131
426.2 1.013 0.161
478.0 1.013 0.196
578.1 1.013 0.261
622.9 1.013 0.308
673.2 1.013 0.348
Reference

Diffusion of butane (1); argon (2) 1
Diffusion of butane (1); argon (2)

Vapor in Gas
C4H10 (1) butane 106-97-8

Ar (2) argon 7440-37-1
T [K] p [bar] D · 104 [m2/s]
306.5 1.013 0.091
322.6 1.013 0.102
374.8 1.013 0.133
426.6 1.013 0.164
476.8 1.013 0.204
578.2 1.013 0.270
622.8 1.013 0.319
673.2 1.013 0.356
C4H10 (1) butane 106-97-8

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.2 101.325 0.104 ± 0.004
372.65 ± 0.2 101.325 0.139 ± 0.003
423.15 ± 0.2 101.325 0.170 ± 0.003
473.15 ± 0.2 101.325 0.209 ± 0.006
C4H10 (1) butane 106-97-8

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.02 101.325 0.082
References

Diffusion of butane (1); propan-2-ol (2) 1
Diffusion of butane (1); propan-2-ol (2)

Vapor in Gas
C4H10 (1) butane 106-97-8

C3H8O (2) propan-2-ol 67-63-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: TAYLOR Ref.: 1989B2
T [K] p [kPa] D · 109 [m2/s]
300.0 101.325 1.37 ± 0.04
Reference
1989B2 Bartle, K.D., Clifford, A.A., Mills, D., Moulder, R.: J. Chem. Soc. Faraday Trans. 1 85 (1989)
2347–2353.

Diffusion of butane (1); hydrogen (2) 1
Diffusion of butane (1); hydrogen (2)

Vapor in Gas
C4H10 (1) butane 106-97-8

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.40
C4H10 (1) butane 106-97-8

H2 (2) hydrogen 1333-74-0
T p [kPa] D · 107 [m2/s]
296.0 101.325 386.0 ± 3.0
References

Diffusion of butane (1); helium (2) 1
Diffusion of butane (1); helium (2)

Vapor in Gas
C4H10 (1) butane 106-97-8

He (2) helium 7440-59-7
T [K] p [kPa] D · 107 [m2/s]
290.0 101.325 333.0 ± 3.0
C4H10 (1) butane 106-97-8

He (2) helium 7440-59-7
T [K] p [psia] D · 104 [m2/s]
297.15 ± 2.0 30.8 0.152 ± 2%
373.15 ± 2.0 31.3 0.224 ± 2%
C4H10 (1) butane 106-97-8

He (2) helium 7440-59-7
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.2 101.325 0.364 ± 0.001
372.65 ± 0.2 101.325 0.477 ± 0.010
423.15 ± 0.2 101.325 0.634 ± 0.006
473.15 ± 0.2 101.325 0.797 ± 0.006
C4H10 (1) butane 106-97-8

He (2) helium 7440-59-7
T [K] p [atm] D · 107 [m2/s]
298.15 272 1.30
298.15 408 0.91
298.15 543 0.70
298.15 681 0.58
298.15 818 0.51
298.15 1090 0.46
298.15 1360 0.44
References

Diffusion of 2-methyl-propane (1); helium (2) 1
Diffusion of 2-methyl-propane (1); helium (2)

Vapor in Gas

He (2) helium 7440-59-7
T [K] p [MPa] D · 106 [m2/s]
344.0 0.80 5.20 ± 5%
344.0 0.80 5.17 ± 5%
Reference

Diffusion of butane (1); nitrogen (2) 1
Diffusion of butane (1); nitrogen (2)

Vapor in Gas
C4H10 (1) butane 106-97-8

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 107 [m2/s]
295.5 101.325 98.0 ± 0.2
C4H10 (1) butane 106-97-8

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.02 101.325 0.092
C4H10 (1) butane 106-97-8

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.2 101.325 0.0954
C4H10 (1) butane 106-97-8

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.07
References

Diffusion of butan-1-ol (1); air (2) 1
Diffusion of butan-1-ol (1); air (2)

Vapor in Gas
C4H10O (1) butan-1-ol 71-36-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
371.65 ± 0.2 101.325 0.212 ± 0.004
C4H10O (1) butan-1-ol 71-36-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 8.61 ± 0.092
C4H10O (1) butan-1-ol 71-36-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
292.95 101.325 0.106
C4H10O (1) butan-1-ol 71-36-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
297.95 101.325 0.0815 ± 0.0023
References

Diffusion of butan-2-ol (1); air (2) 1
Diffusion of butan-2-ol (1); air (2)

Vapor in Gas
C4H10O (1) butan-2-ol 78-92-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 8.91 ± 0.070
C4H10O (1) butan-2-ol 78-92-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
349.85 ± 0.2 101.325 0.1362 ± 0.0015
References

Diffusion of 2-methyl-propan-1-ol (1); air (2) 1
Diffusion of 2-methyl-propan-1-ol (1); air (2)

Vapor in Gas
C4H10O (1) 2-methyl-propan-1-ol 78-83-1

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
371.65 ± 0.2 101.325 0.1527 ± 0.0017

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 8.80 ± 0.165
References

Diffusion of 2-methyl-propan-2-ol (1); air (2) 1
Diffusion of 2-methyl-propan-2-ol (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
349.85 ± 0.2 101.325 0.1329 ± 0.0015

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 8.73 ± 0.008
References

Diffusion of diethyl ether (1); air (2) 1
Diffusion of diethyl ether (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 9.18 ± 0.080
Reference

Diffusion of diethyl ether (1); argon (2) 1
Diffusion of diethyl ether (1); argon (2)

Vapor in Gas

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.2 101.325 0.0849 ± 0.0016
372.65 ± 0.2 101.325 0.116 ± 0.003
423.15 ± 0.2 101.325 0.165 ± 0.003
473.15 ± 0.2 101.325 0.203 ± 0.008

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
300.0 101.325 0.0919 ± 0.0013
300.0 101.325 0.099 ± 0.003
References

Diffusion of diethyl ether (1); carbon dioxide (2) 1
Diffusion of diethyl ether (1); carbon dioxide (2)

Vapor in Gas

Diffusion of gas(1) in gas(2): D*12(T ); Method: STEFAN Ref.: 1977K8
T [K] p [kPa] D · 104 [m2/s]
298.4 101.325 0.0648 ± 0.0019
298.4 101.325 0.0644 ± 0.0011
Reference

Diffusion of butan-1-ol (1); carbon dioxide (2) 1
Diffusion of butan-1-ol (1); carbon dioxide (2)

Vapor in Gas
C4H10O (1) butan-1-ol 71-36-3

T [K] p [kPa] D · 104 [m2/s]
302.2 101.325 55.11 ± 2%
325.0 101.325 67.25 ± 2%
343.9 101.325 75.04 ± 2%
369.9 101.325 88.09 ± 2%
371.2 101.325 87.07 ± 2%
381.2 101.325 95.00 ± 2%
395.9 101.325 102.1 ± 2%
418.8 101.325 114.1 ± 2%
424.2 101.325 117.0 ± 2%
443.0 101.325 124.0 ± 2%
C4H10O (1) butan-1-ol 71-36-3

T [K] p [kPa] D · 106 [m2/s]
302.2 101.325 5.51
325.2 101.325 6.72
343.9 101.325 7.50
369.9 101.325 8.81
371.2 101.325 8.71
381.2 101.325 9.50
References

Diffusion of butan-1-ol (1); hydrogen (2) 1
Diffusion of butan-1-ol (1); hydrogen (2)

Vapor in Gas
C4H10O (1) butan-1-ol 71-36-3

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
373 101.325 0.6479
393 101.325 0.7110 ± 3.2%
423 101.325 0.7983 ± 2.2%
453 101.325 0.9097 ± 4.0%
483 101.325 1.0240 ± 5.4%
C4H10O (1) butan-1-ol 71-36-3

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
393.15 101.325 0.7110 ± 0.0227
423.15 101.325 0.7983 ± 0.0177
453.15 101.325 0.9097 ± 0.0362
483.15 101.325 1.0240 ± 0.0549
References

Diffusion of butan-2-ol (1); hydrogen (2) 1
Diffusion of butan-2-ol (1); hydrogen (2)

Vapor in Gas
C4H10O (1) butan-2-ol 78-92-2

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
373 101.325 0.6290
393 101.325 0.6760 ± 1.6%
423 101.325 0.7850 ± 3.9%
453 101.325 0.8730 ± 3.9%
483 101.325 0.9690 ± 0.63%
C4H10O (1) butan-2-ol 78-92-2

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
393.15 101.325 0.6760 ± 0.0110
423.15 101.325 0.7850 ± 0.0309
453.15 101.325 0.8730 ± 0.0337
483.15 101.325 0.9690 ± 0.0061
References

Diffusion of diethyl ether (1); hydrogen (2) 1
Diffusion of diethyl ether (1); hydrogen (2)

Vapor in Gas

H2 (2) hydrogen 1333-74-0
T [K] p [MPa] D · 107 [m2/s]
273 2.06 14.2
273 5.00 5.81
273 9.91 3.10
293 2.06 16.21
293 5.00 6.65
293 9.91 3.50
293 19.72 1.93
323 2.06 20.8
323 5.00 8.76
323 9.91 4.60
323 19.72 2.51
323 29.51 1.78
Reference
1974K11 Kalandarov, Y.N., Golubev, I.F.: Tr. Inst. Azotn. Prom. Prod. Organ. Sint. 1974 (1974) 14–28.

Diffusion of 2-methyl-propan-1-ol (1); helium (2) 1
Diffusion of 2-methyl-propan-1-ol (1); helium (2)

Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 107 [m2/s]
313.2 101.325 277.5 ± 2%
334.0 101.325 331.0*
333.2 101.325 320.1 ± 2%
353.2 101.325 355.1 ± 2%
354.0 101.325 355*
373.2 101.325 416.6 ± 2%
424.0 101.325 553.3 ± 2%

He (2) helium 7440-59-7
T [K] p [MPa] D · 107 [m2/s]
334 0.1011 331.0
334 0.102 322.0
334 0.392 83.0
334 0.98 32.7
334 1.86 16.9
334 3.48 9.01
354 0.100 359.0
354 0.102 355.0
354 0.392 89.7
354 0.98 35.4
354 1.86 18.8
354 3.48 9.77
References

Diffusion of butan-2-ol (1); helium (2) 1
Diffusion of butan-2-ol (1); helium (2)

Vapor in Gas
C4H10O (1) butan-2-ol 78-92-2

He (2) helium 7440-59-7
Diffusion of gas(1) in gas(2): D*12(T ); Method: RF GC Ref.: 1975M11
T [K] p [kPa] D · 109 [m2/s]
333.2 101.325 3.37
Reference

Diffusion of butan-1-ol (1); helium (2) 1
Diffusion of butan-1-ol (1); helium (2)

Vapor in Gas
C4H10O (1) butan-1-ol 71-36-3

He (2) helium 7440-59-7
T [K] p [kPa] D · 107 [m2/s]
313.2 101.325 287.9 ± 2%
323.2 101.325 319.0 ± 2%
333.2 101.325 338.7 ± 2%
353.2 101.325 393.4 ± 2%
373.2 101.325 440.1 ± 2%
392.0 101.325 503.0 ± 2%
423.2 101.325 587*
423.9 101.325 591.0 ± 2%
443.2 101.325 653*
463.2 101.325 689*
483.2 101.325 746*
503.2 101.325 792*
523.2 101.325 841*
C4H10O (1) butan-1-ol 71-36-3

He (2) helium 7440-59-7
T [K] p [MPa] D · 107 [m2/s]
334 0.100 357.0
334 0.102 343.0
334 0.392 87.1
334 0.98 34.5
334 1.86 17.9
334 3.48 9.55
354 0.1013 392.0
354 0.100 382.0
354 0.392 97.7
354 0.98 38.1
354 1.86 19.9
354 3.48 10.7
C4H10O (1) butan-1-ol 71-36-3

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
423.15 101.325 0.587 ± 0.011
443.15 101.325 0.653 ± 0.006
(continued)

2 Diffusion of butan-1-ol (1); helium (2)
463.15 101.325 0.689 ± 0.006

483.15 101.325 0.746 ± 0.006
503.15 101.325 0.792 ± 0.009
523.15 101.325 0.841 ± 0.001
References

Diffusion of diethyl ether (1); helium (2) 1
Diffusion of diethyl ether (1); helium (2)

Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.2 101.325 0.310 ± 0.001
372.65 ± 0.2 101.325 0.460 ± 0.010
423.15 ± 0.2 101.325 0.607 ± 0.008
473.15 ± 0.2 101.325 0.745 ± 0.029
Reference

Diffusion of butan-1-ol (1); nitrogen (2) 1
Diffusion of butan-1-ol (1); nitrogen (2)

Vapor in Gas
C4H10O (1) butan-1-ol 71-36-3

N2 (2) nitrogen 7727-37-9
Diffusion of gas(1) in gas(2): D*12(T ); Method: No Info Ref.: 1967H3
T [K] p [kPa] D · 106 [m2/s]
253.2 101.325 4.92
283.2 101.325 6.98
293.2 101.325 7.63
303.2 101.325 8.53
303.4 101.325 8.41
313.2 101.325 9.20
314.7 101.325 9.28
333.2 101.325 10.88
353.2 101.325 12.57
373.2 101.325 13.96
C4H10O (1) butan-1-ol 71-36-3

N2 (2) nitrogen 7727-37-9
T [K] p [MPa] D · 107 [m2/s]
334 0.1013 110.0
334 0.1033 106.5
334 0.392 24.5
334 0.98 8.91
334 1.86 4.41
334 3.48 2.19
354 0.1013 117.5
354 0.102 118.5
354 0.392 27.5
354 0.98 10.0
354 1.86 4.95
354 3.48 2.50
References

Diffusion of 2-methyl-propan-1-ol (1); nitrogen (2) 1
Diffusion of 2-methyl-propan-1-ol (1); nitrogen (2)

Vapor in Gas

N2 (2) nitrogen 7727-37-9
T [K] p [MPa] D · 107 [m2/s]
334 0.102 96.2
334 0.392 21.8
334 0.862 9.15
334 1.86 3.89
334 3.48 1.95
354 0.102 103.3
354 0.1025 104.0
354 0.392 26.0
354 0.98 8.71
354 1.86 4.26
354 3.48 2.10
Reference

Diffusion of diethyl ether (1); nitrogen (2) 1
Diffusion of diethyl ether (1); nitrogen (2)

Vapor in Gas

N2 (2) nitrogen 7727-37-9
T [K] p [MPa] D · 107 [m2/s]
273 2.06 3.67
273 5.00 1.46
273 9.91 0.745
293 2.06 4.18
293 5.00 1.65
293 9.91 0.853
293 19.72 0.490
323 2.06 5.10
323 5.00 2.02
323 9.91 1.05
323 19.72 0.613
323 29.51 0.452
363 2.06 6.39
363 5.00 2.52
363 9.91 1.34
363 19.72 0.810
363 29.51 0.581

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
296.0 101.325 0.0889

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
296 101.325 0.0889
296 101.325 0.0927
References
695–698.

Diffusion of 2-ethoxy-ethanol (1); air (2) 1
Diffusion of 2-ethoxy-ethanol (1); air (2)

Vapor in Gas
C4H10O2 (1) 2-ethoxy-ethanol 110-80-5

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.88 ± 0.046
Reference

Diffusion of 2-(2-hydroxy-ethoxy)-ethanol (1); air (2) 1
Diffusion of 2-(2-hydroxy-ethoxy)-ethanol (1); air (2)

Vapor in Gas
C4H10O3 (1) 2-(2-hydroxy-ethoxy)-ethanol 111-46-6

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.30 ± 0.071
Reference

Diffusion of 2-(2-hydroxy-ethoxy)-ethanol (1); carbon dioxide (2) 1
Diffusion of 2-(2-hydroxy-ethoxy)-ethanol (1); carbon

dioxide (2)
Vapor in Gas

T [K] p [kPa] D · 106 [m2/s]
323.2 101.325 8.60
348.2 101.325 10.57
373.2 101.325 12.63
398.2 101.325 15.20
423.2 101.325 16.57
448.2 101.325 19.61
473.2 101.325 21.62
Reference

Diffusion of 2-(2-hydroxy-ethoxy)-ethanol (1); nitrogen (2) 1
Diffusion of 2-(2-hydroxy-ethoxy)-ethanol (1); nitrogen (2)

Vapor in Gas

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 106 [m2/s]
375.2 101.325 18.40
404.2 101.325 22.70
438.2 101.325 26.70
472.2 101.325 30.70
Reference

Diffusion of isobutylamine (1); air (2) 1
Diffusion of isobutylamine (1); air (2)

Vapor in Gas
C4H11N (1) isobutylamine 78-81-9

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 9.00 ± 0.114
Reference

Diffusion of diethylamine (1); air (2) 1
Diffusion of diethylamine (1); air (2)

Vapor in Gas
C4H11N (1) diethylamine 109-89-7

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 9.93 ± 0.050
C4H11N (1) diethylamine 109-89-7

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.35 101.325 0.0934 ± 0.0013
References

Diffusion of butylamine (1); air (2) 1
Diffusion of butylamine (1); air (2)

Vapor in Gas
C4H11N (1) butylamine 109-73-9

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 8.72 ± 0.231
Reference

Diffusion of 1,1,1,2,2,3,4,5,5,5-decafluoro-pentane (1); air (2) 1
Diffusion of 1,1,1,2,2,3,4,5,5,5-decafluoro-pentane (1); air

(2)
Vapor in Gas
C5H2F10 (1) 1,1,1,2,2,3,4,5,5,5-decafluoro-pentane 138495-42-8

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
333.15 101.325 0.0805
333.15 101.325 0.0794
363.15 101.325 0.0948
363.15 101.325 0.0942
363.15 101.325 0.0937
393.15 101.325 0.108
423.15 101.325 0.123
423.15 101.325 0.125
453.15 101.325 0.139
Reference

Diffusion of cyanoacetic acid ethyl ester (1); air (2) 1
Diffusion of cyanoacetic acid ethyl ester (1); air (2)

Vapor in Gas
C5H7NO2 (1) cyanoacetic acid ethyl ester 105-56-6

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.10 ± 0.025
Reference

Diffusion of 2-methyl-buta-1,3-diene (1); air (2) 1
Diffusion of 2-methyl-buta-1,3-diene (1); air (2)

Vapor in Gas
C5H8 (1) 2-methyl-buta-1,3-diene 78-79-5

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
288.15 ± 0.1 101.325 0.0905 ± 0.0007
Reference

Diffusion of pent-1-ene (1); air (2) 1
Diffusion of pent-1-ene (1); air (2)

Vapor in Gas
C5H10 (1) pent-1-ene 109-67-1

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.2 101.325 0.0958 ± 0.0011
Reference

Diffusion of cyclopentane (1); air (2) 1
Diffusion of cyclopentane (1); air (2)

Vapor in Gas
C5H10 (1) cyclopentane 287-92-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.2 101.325 0.0919 ± 0.0025
Reference

Diffusion of pentan-2-one (1); air (2) 1
Diffusion of pentan-2-one (1); air (2)

Vapor in Gas
C5H10O (1) pentan-2-one 107-87-9

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.93 ± 0.061
Reference

Diffusion of formic acid isobutyl ester (1); air (2) 1
Diffusion of formic acid isobutyl ester (1); air (2)

Vapor in Gas
C5H10O2 (1) formic acid isobutyl ester 542-55-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.84 ± 0.179
Reference

Diffusion of propionic acid ethyl ester (1); air (2) 1
Diffusion of propionic acid ethyl ester (1); air (2)

Vapor in Gas
C5H10O2 (1) propionic acid ethyl ester 105-37-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.66 ± 0.376
Reference

Diffusion of butyric acid methyl ester (1); air (2) 1
Diffusion of butyric acid methyl ester (1); air (2)

Vapor in Gas
C5H10O2 (1) butyric acid methyl ester 623-42-7

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.45 ± 0.092
Reference

Diffusion of acetic acid propyl ester (1); air (2) 1
Diffusion of acetic acid propyl ester (1); air (2)

Vapor in Gas
C5H10O2 (1) acetic acid propyl ester 109-60-4

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.68 ± 0.098
Reference

Diffusion of acetic acid isopropyl ester (1); air (2) 1
Diffusion of acetic acid isopropyl ester (1); air (2)

Vapor in Gas
C5H10O2 (1) acetic acid isopropyl ester 108-21-4

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.70 ± 0.103
Reference

Diffusion of 3-methyl-butyric acid (1); air (2) 1
Diffusion of 3-methyl-butyric acid (1); air (2)

Vapor in Gas
C5H10O2 (1) 3-methyl-butyric acid 503-74-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.53 ± 0.279
Reference

Diffusion of isobutyric acid methyl ester (1); air (2) 1
Diffusion of isobutyric acid methyl ester (1); air (2)

Vapor in Gas
C5H10O2 (1) isobutyric acid methyl ester 547-63-7

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.48 ± 0.078
Reference

Diffusion of 1-chloro-pentane (1); helium (2) 1
Diffusion of 1-chloro-pentane (1); helium (2)

Vapor in Gas
C5H11Cl (1) 1-chloro-pentane 543-59-9

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
428.2 ± 0.2 101.325 0.518 ± 0.004
Reference

Diffusion of 2-methyl-butane (1); air (2) 1
Diffusion of 2-methyl-butane (1); air (2)

Vapor in Gas
C5H12 (1) 2-methyl-butane 78-78-4

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
288.2 101.325 7.74
293.2 101.325 7.82
C5H12 (1) 2-methyl-butane 78-78-4

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.2 101.325 0.0935 ± 0.0020
References

Diffusion of pentane (1); air (2) 1
Diffusion of pentane (1); air (2)

Vapor in Gas
C5H12 (1) pentane 109-66-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
258.15 101.325 0.0676 ± 0.0009
263.15 101.325 0.0703 ± 0.0000
268.15 101.325 0.0732 ± 0.0004
273.15 101.325 0.0751 ± 0.0005
278.15 101.325 0.0772 ± 0.0005
283.15 101.325 0.0804 ± 0.0001
288.15 101.325 0.0825 ± 0.0004
293.15 101.325 0.0851 ± 0.0002
298.15 101.325 0.0877 ± 0.0002
Comment: average deviation ±(0.3–0.7)%
C5H12 (1) pentane 109-66-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
293.15 101.325 0.0798
C5H12 (1) pentane 109-66-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 8.42 ± 0.182
References
1973N1 Nagasaka, M.: J. Chem. Eng. Data 18 (1973) 388–390.

Diffusion of 2,2-dimethyl-propane (1); air (2) 1
Diffusion of 2,2-dimethyl-propane (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.2 101.325 0.0877 ± 0.0021
Reference

Diffusion of pentane (1); argon (2) 1
Diffusion of pentane (1); argon (2)

Vapor in Gas
C5H12 (1) pentane 109-66-0

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
258.15 101.325 0.0597 ± 0.0005
263.15 101.325 0.0618 ± 0.0009
268.15 101.325 0.0649 ± 0.0003
273.15 101.325 0.0670 ± 0.0000
278.15 101.325 0.0695 ± 0.0001
283.15 101.325 0.0720 ± 0.0002
288.15 101.325 0.0743 ± 0.0000
293.15 101.325 0.0770 ± 0.0001
298.15 101.325 0.0792 ± 0.0007
C5H12 (1) pentane 109-66-0

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.2 101.325 0.0890 ± 0.0008
372.65 ± 0.2 101.325 0.115 ± 0.009
423.15 ± 0.2 101.325 0.149 ± 0.003
473.15 ± 0.2 101.325 0.786 ± 0.004
C5H12 (1) pentane 109-66-0

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 107 [m2/s]
258.2 101.325 59.7*
263.2 101.325 61.8*
268.2 101.325 64.9*
273.2 101.325 67.0*
278.2 101.325 69.5*
283.2 101.325 72.0*
288.2 101.325 74.3*
293.2 101.325 77.0*
298.2 101.325 79.2*
298.2 101.325 89.0*
301.0 101.325 80.20 ± 2%
323.0 101.325 95.63 ± 2%
353.0 101.325 109.0 ± 2%
353.2 101.325 107.5*
(continued)

2 Diffusion of pentane (1); argon (2)
372.7 101.325 115*

383.0 101.325 124.3 ± 2%
403.0 101.325 138.7 ± 2%
423.0 101.325 152.2 ± 2%
423.2 101.325 149*
473.2 101.325 189*
References

Diffusion of pentane (1); carbon dioxide (2) 1
Diffusion of pentane (1); carbon dioxide (2)

Vapor in Gas
C5H12 (1) pentane 109-66-0

T [K] p [MPa] D · 107 [m2/s]
311.15 0.1013 67.6 ± 5%
311.15 1.08 6.34 ± 5%
311.15 2.14 3.11 ± 5%
311.15 3.32 2.23 ± 5%
311.15 4.10 1.82 ± 5%
311.15 5.24 0.980 ± 5%
344.15 0.1013 83.2 ± 5%
344.15 0.97 9.13 ± 5%
344.15 2.99 3.02 ± 5%
344.15 4.06 2.29 ± 5%
344.15 5.59 2.04 ± 5%
344.15 6.91 1.70 ± 5%
344.15 7.50 1.01 ± 5%
344.15 9.12 0.016 ± 5%
C5H12 (1) pentane 109-66-0

Diffusion of gas(1) in gas(2): D*12(T ); Method: TAYLOR Ref.: 1984S6
T [K] p [MPa] D · 107 [m2/s]
299 0.190 33.78
299 0.255 23.60
299 0.519 13.34
330 0.182 43.16
330 0.265 28.41
330 0.421 19.82
368 0.265 36.72
368 0.519 24.03
368 0.570 17.20
422 0.265 44.31
422 0.421 29.58
422 0.547 22.19
C5H12 (1) pentane 109-66-0

T [K] p [MPa] D · 107 [m2/s]
299 0.100 65.51
330 0.100 78.32
(continued)

2 Diffusion of pentane (1); carbon dioxide (2)
368 0.100 95.70

422 0.100 120.0
C5H12 (1) pentane 109-66-0

T [K] p [bar] D · 107 [m2/s]
323.15 1.0 74.2
323.15 10.6 7.29
323.15 19.2 3.75
323.15 27.7 2.89
323.15 40.2 1.96
323.15 49.2 1.74
323.15 74.0 1.83
323.15 80.5 2.05
C5H12 (1) pentane 109-66-0

T [K] p [MPa] D · 106 [m2/s]
323.15 2.77 0.279 ± 4%
323.15 4.02 0.189 ± 4%
323.15 4.92 0.166 ± 4%
323.15 7.40 0.192 ± 4%
323.15 8.05 0.211 ± 4%
344.15 2.99 0.295 ± 4%
344.15 4.06 0.235 ± 4%
344.15 5.59 0.176 ± 4%
344.15 6.91 0.178 ± 4%
344.15 7.50 0.208 ± 4%
C5H12 (1) pentane 109-66-0

T [K] p [kPa] D · 107 [m2/s]
287.0 101.325 60.5 ± 2%
299.0 101.325 65.5 ± 2%
302.0 101.325 66.12 ± 2%
311.0 101.325 67.6 ± 2%
323.0 101.325 74.2 ± 2%
344.0 101.325 83.2 ± 2%
345.0 101.325 81.71 ± 2%
368.0 101.325 94.44 ± 2%
396.0 101.325 106.6 ± 2%
425.0 101.325 123.4 ± 2%

References
1984S6 Shekurov, V.N., Berezhnoi, A.N.: Teplo-Massoobmen Khim. Tekhnol. (1984) 35–38.
1984B5 Berezhnoi, A.N., Semenov, A.V.: Zh. Tekh. Fiz. 54 (1984) 2369–2371.

Diffusion of pentane (1); propan-2-ol (2) 1
Diffusion of pentane (1); propan-2-ol (2)

Vapor in Gas
C5H12 (1) pentane 109-66-0

C3H8O (2) propan-2-ol 67-63-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: TAYLOR Ref.: 1989B2
T [K] p [kPa] D · 109 [m2/s]
300.0 101.325 1.26 ± 0.04
Reference
2347–2353.

Diffusion of pentane (1); hydrogen (2) 1
Diffusion of pentane (1); hydrogen (2)

Vapor in Gas
C5H12 (1) pentane 109-66-0

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
258.15 101.325 0.2633 ± 0.0004
263.15 101.325 0.2741 ± 0.0006
268.15 101.325 0.2826 ± 0.0014
273.15 101.325 0.2925 ± 0.0006
278.15 101.325 0.3035 ± 0.0005
283.15 101.325 0.3128 ± 0.0006
288.15 101.325 0.3214 ± 0.0006
293.15 101.325 0.3327 ± 0.0003
298.15 101.325 0.3404 ± 0.0009
C5H12 (1) pentane 109-66-0

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
353.15 101.325 0.4895 ± 0.0075
373.15 101.325 0.5324 ± 0.0206
393.15 101.325 0.5830 ± 0.0250
423.15 101.325 0.6300 ± 0.0004
453.15 101.325 0.7425 ± 0.0035
C5H12 (1) pentane 109-66-0

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
353 101.325 0.4895 ± 1.5%
373 101.325 0.5324 ± 3.9%
393 101.325 0.5830 ± 4.3%
423 101.325 0.6300 ± 0.06%
453 101.325 0.7425 ± 0.47%
References

Diffusion of pentane (1); helium (2) 1
Diffusion of pentane (1); helium (2)

Vapor in Gas
C5H12 (1) pentane 109-66-0

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
258.15 101.325 0.2343 ± 0.0010
263.15 101.325 0.2437 ± 0.0011
268.15 101.325 0.2535 ± 0.0006
273.15 101.325 0.2632 ± 0.0013
278.15 101.325 0.2707 ± 0.0005
283.15 101.325 0.2786 ± 0.0014
288.15 101.325 0.2865 ± 0.0006
293.15 101.325 0.2957 ± 0.0004
298.15 101.325 0.3044 ± 0.0003
C5H12 (1) pentane 109-66-0

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.2 101.325 0.288 ± 0.001
372.65 ± 0.2 101.325 0.422 ± 0.003
423.15 ± 0.2 101.325 0.565 ± 0.007
473.15 ± 0.2 101.325 0.695 ± 0.012
C5H12 (1) pentane 109-66-0

He (2) helium 7440-59-7
T [K] p [MPa] D · 107 [m2/s]
353.5 0.100 400.0
353.5 0.206 190.1
353.5 0.445 90.0
353.5 0.446 88.75
353.5 0.609 67.27
353.5 0.706 58.74
353.5 0.794 62.40
353.5 0.956 44.39
353.5 1.04 38.7
391.6 0.100 470.0
391.6 0.183 251.2
391.6 0.225 209.0
391.6 0.359 128.3
391.6 0.447 107.4
(continued)

2 Diffusion of pentane (1); helium (2)
391.6 0.584 81.91

391.6 0.794 63.43
391.6 0.997 51.42
424.3 0.100 530.1
424.3 0.108 473.4
424.3 0.296 181.2
424.3 0.402 134.3
424.3 0.578 95.49
424.3 0.706 79.80
424.3 0.995 57.73
References

Diffusion of pentane (1); nitrogen (2) 1
Diffusion of pentane (1); nitrogen (2)

Vapor in Gas
C5H12 (1) pentane 109-66-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
258.15 101.325 0.0675 ± 0.0001
263.15 101.325 0.0702 ± 0.0000
268.15 101.325 0.0721 ± 0.0000
273.15 101.325 0.0749 ± 0.0001
278.15 101.325 0.0782 ± 0.0001
283.15 101.325 0.0807 ± 0.0001
288.15 101.325 0.0830 ± 0.0002
293.15 101.325 0.0860 ± 0.0001
298.15 101.325 0.0885 ± 0.0001
C5H12 (1) pentane 109-66-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
304.55 ± 0.05 101.325 0.0864 ± 0.0019
C5H12 (1) pentane 109-66-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
353.0 101.325 0.136
References
1973P6 Pommersheim, J.M., Ranck, B.A.: Ind. Eng. Chem. Fundam. 12 (1973) 246–250.

Diffusion of pentan-1-ol (1); air (2) 1
Diffusion of pentan-1-ol (1); air (2)

Vapor in Gas
C5H12O (1) pentan-1-ol 71-41-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.16 ± 0.233
Reference

Diffusion of pentan-2-ol (1); air (2) 1
Diffusion of pentan-2-ol (1); air (2)

Vapor in Gas
C5H12O (1) pentan-2-ol 6032-29-7

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.28 ± 0.064
Reference

Diffusion of pentan-1-ol (1); helium (2) 1
Diffusion of pentan-1-ol (1); helium (2)

Vapor in Gas
C5H12O (1) pentan-1-ol 71-41-0

He (2) helium 7440-59-7
T [K] p [kPa] D · 106 [m2/s]
253.2 101.325 13.32
293.2 101.325 18.56
313.2 101.325 21.95
333.2 101.325 25.41
353.2 101.325 28.79
354.2 101.325 28.20
393.2 101.325 37.23
403.2 101.325 38.18
C5H12O (1) pentan-1-ol 71-41-0

He (2) helium 7440-59-7
T [K] p [MPa] D · 107 [m2/s]
354 0.1012 285.0
354 0.1012 280.0
354 0.392 68.7
354 0.98 26.6
354 1.86 13.4
354 3.48 6.99
C5H12O (1) pentan-1-ol 71-41-0

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
423.15 101.325 0.507 ± 0.005
443.15 101.325 0.536 ± 0.004
463.15 101.325 0.578 ± 0.013
483.15 101.325 0.636 ± 0.007
503.15 101.325 0.666 ± 0.005
523.15 101.325 0.729 ± 0.007
References

Diffusion of 3-methyl-butan-1-ol (1); helium (2) 1
Diffusion of 3-methyl-butan-1-ol (1); helium (2)

Vapor in Gas
C5H12O (1) 3-methyl-butan-1-ol 123-51-3

He (2) helium 7440-59-7
T [K] p [MPa] D · 107 [m2/s]
354 0.1006 259.0
354 0.1012 262.0
354 0.392 63.1
354 0.98 23.9
354 1.86 12.2
354 3.48 6.31
Reference

Diffusion of 3-methyl-butan-1-ol (1); nitrogen (2) 1
Diffusion of 3-methyl-butan-1-ol (1); nitrogen (2)

Vapor in Gas
C5H12O (1) 3-methyl-butan-1-ol 123-51-3

N2 (2) nitrogen 7727-37-9
T [K] p [MPa] D · 107 [m2/s]
354 0.100 83.0
354 0.1012 82.0
354 0.392 17.3
354 0.98 6.16
354 1.86 2.95
354 3.48 1.48
Reference

Diffusion of pentan-1-ol (1); nitrogen (2) 1
Diffusion of pentan-1-ol (1); nitrogen (2)

Vapor in Gas
C5H12O (1) pentan-1-ol 71-41-0

N2 (2) nitrogen 7727-37-9
T [K] p [MPa] D · 107 [m2/s]
354 0.1012 92.0
354 0.1012 91.0
354 0.392 19.7
354 0.98 7.03
354 1.86 3.35
354 3.48 1.66
Reference

Diffusion of hexafluoro-benzene (1); helium (2) 1
Diffusion of hexafluoro-benzene (1); helium (2)

Vapor in Gas
C6F6 (1) hexafluoro-benzene 392-56-3

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
428.7 ± 0.2 101.325 0.453 ± 0.008
Reference

Diffusion of 1,2-dichloro-benzene (1); air (2) 1
Diffusion of 1,2-dichloro-benzene (1); air (2)

Vapor in Gas
C6H4Cl2 (1) 1,2-dichloro-benzene 95-50-1

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
313.15 ± 0.005 101.325 8.268 ± 0.5%
328.14 ± 0.005 101.325 8.781 ± 0.5%
342.78 ± 0.005 101.325 9.380 ± 0.5%
Reference

Diffusion of 1,3-dichloro-benzene (1); air (2) 1
Diffusion of 1,3-dichloro-benzene (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
313.15 ± 0.005 101.325 7.724 ± 0.5%
328.14 ± 0.005 101.325 8.286 ± 0.5%
342.78 ± 0.005 101.325 9.014 ± 0.5%
Reference

Diffusion of bromobenzene (1); helium (2) 1
Diffusion of bromobenzene (1); helium (2)

Vapor in Gas
C6H5Br (1) bromobenzene 108-86-1

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
427.1 ± 0.2 101.325 0.543 ± 0.010
Reference

Diffusion of chlorobenzene (1); air (2) 1
Diffusion of chlorobenzene (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
283.04 ± 0.005 101.325 7.039 ± 0.5%
298.18 ± 0.005 101.325 7.879 ± 0.5%
313.15 ± 0.005 101.325 8.621 ± 0.5%
328.13 ± 0.005 101.325 9.353 ± 0.5%
342.78 ± 0.005 101.325 10.211 ± 0.5%

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.47 ± 0.186
References

Diffusion of chlorobenzene (1); helium (2) 1
Diffusion of chlorobenzene (1); helium (2)

Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
430.9 ± 0.2 101.325 0.542 ± 0.006
Reference

Diffusion of fluorobenzene (1); helium (2) 1
Diffusion of fluorobenzene (1); helium (2)

Vapor in Gas
C6H5F (1) fluorobenzene 462-06-6

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
429.7 ± 0.2 101.325 0.566 ± 0.008
Reference

Diffusion of nitrobenzene (1); air (2) 1
Diffusion of nitrobenzene (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.21 ± 0.021
Reference

Diffusion of nitrobenzene (1); hydrogen (2) 1
Diffusion of nitrobenzene (1); hydrogen (2)

Vapor in Gas

H2 (2) hydrogen 1333-74-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: ARF Ref.: 1977C3
T [K] p [kPa] D · 104 [m2/s]
488.15 101.325 0.750
523.15 101.325 0.899
568.15 101.325 1.014
Reference
1977C3 Choudhary, V.R., Parande, M.G.: J. Chromatogr. 132 (1977) 344–348.

Diffusion of benzene (1); air (2) 1
Diffusion of benzene (1); air (2)

Vapor in Gas
C6H6 (1) benzene 71-43-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
283.2 101.325 8.10
283.2 101.325 8.34
293.2 101.325 9.00
297.2 101.325 9.21
303.2 101.325 9.20
312.6 101.325 9.96
313.2 101.325 9.90
314.2 101.325 10.23
316.2 101.325 10.28
323.2 101.325 10.75
333.2 101.325 11.15
343.2 101.325 11.70
353.2 101.325 12.30
C6H6 (1) benzene 71-43-2

Air (2) air 132259-10-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: ARF Ref.: 1994G3
T [K] p [kPa] D · 106 [m2/s]
268.15 101.325 7.18 ± 0.07
283.15 101.325 7.89 ± 0.10
298.15 101.325 8.25 ± 0.34
298.15 101.325 8.49 ± 0.09
313.15 101.325 9.57 ± 0.12
C6H6 (1) benzene 71-43-2

Air (2) air 132259-10-0
T [K] p [MPa] D · 107 [m2/s]
314 0.104 99.7
314 0.294 32.1
314 0.392 23.9
314 0.784 12.3
314 0.981 10.1
314 1.57 6.09
314 1.95 4.58
314 4.99 1.49

2 Diffusion of benzene (1); air (2)
C6H6 (1) benzene 71-43-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
300.05 ± 0.1 101.325 0.0926 ± 0.0022
333.95 ± 0.1 101.325 0.1148 ± 0.0010
303.15 ± 0.1 101.325 0.0951 ± 0.0040
C6H6 (1) benzene 71-43-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
353.25 ± 1.0 101.325 0.1218
361.25 ± 1.0 101.325 0.1320
C6H6 (1) benzene 71-43-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
296.85 101.325 0.0938 ± 0.0005
C6H6 (1) benzene 71-43-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.1 101.325 0.0927 ± 2.9%
C6H6 (1) benzene 71-43-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
295.45 ± 0.3 101.325 0.0904 ± 5%
C6H6 (1) benzene 71-43-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
297.2 101.325 9.10

Diffusion of benzene (1); air (2) 3
C6H6 (1) benzene 71-43-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 9.32 ± 0.149
C6H6 (1) benzene 71-43-2

Air (2) air 132259-10-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: STEFAN Ref.: 1980C5
T [K] p [kPa] D · 104 [m2/s]
340.15 ± 0.1 101.325 0.1193 ± 1.5%
C6H6 (1) benzene 71-43-2

Air (2) air 132259-10-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: No Info Ref.: 1962V1
T [K] p [kPa] D · 106 [m2/s]
273.2 101.325 7.83
298.2 101.325 9.29
323.2 101.325 10.80
348.2 101.325 12.40
References
1994G3 Gustafson, K.E., Dickhut, R.M.: J. Chem. Eng. Data 39 (1994) 286–289.
1981A1 Alvarez, R., Bueno, J.L., Coca, J.: J. Chem. Eng. Jpn. 14 (1981) 239–241.
1967B3 Ben Aim, R., Eggarter, P., Krasuk, J.H.: Chim. Ind. Genie Chim. 97 (1967) 1638–1645.
1980C5 Coca, J., Bueno, J.L., Alvarez, R.: Ind. Eng. Chem. Fundam. 19 (1980) 219–221.
1962V1 Vasilevskaya, Y.D.: Izv. Vyssh. Uchebn. Zaved. Neft Gaz 5 (1962) 59–64.

Diffusion of benzene (1); argon (2) 1
Diffusion of benzene (1); argon (2)

Vapor in Gas
C6H6 (1) benzene 71-43-2

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 107 [m2/s]
288.7 101.325 77.4 ± 2%
290.9 101.325 79.36 ± 2%
299.7 101.325 83.0 ± 2%
301.0 101.325 83.11 ± 2%
311.0 101.325 89.68 ± 2%
323.0 101.325 95.26 ± 2%
353.0 101.325 115.6 ± 2%
373.0 101.325 120.0*
383.0 101.325 137.1 ± 2%
403.0 101.325 149.0 ± 2%
423.0 101.325 159.1 ± 2%
443.0 101.325 176.8 ± 2%
C6H6 (1) benzene 71-43-2

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
300.0 101.325 0.083 ± 0.003
300.0 101.325 0.084 ± 0.003
C6H6 (1) benzene 71-43-2

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
288 ± 0.5 101.325 0.107
293 ± 0.5 101.325 0.113
298 ± 0.5 101.325 0.115
303 ± 0.5 101.325 0.116
308 ± 0.5 101.325 0.119
313 ± 0.5 101.325 0.125
323 ± 0.5 101.325 0.136
330 ± 0.5 101.325 0.149
333 ± 0.5 101.325 0.149
338 ± 0.5 101.325 0.159
343 ± 0.5 101.325 0.168

2 Diffusion of benzene (1); argon (2)
C6H6 (1) benzene 71-43-2

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.2 101.325 0.108 ± 0.001
372.65 ± 0.2 101.325 0.142 ± 0.002
423.15 ± 0.2 101.325 0.169 ± 0.001
473.15 ± 0.2 101.325 0.212 ± 0.003
References
1972B4 Bogatyrev, A.F., Bondareva, E.N.: Prikl. Teor. Fiz. (1972), No. 4, 208–212.


Vapor in Gas
C6H6 (1) benzene 71-43-2

T [K] p [kPa] D · 106 [m2/s]
290.0 101.325 5.99
299.4 101.325 6.34
300.0 101.325 6.32
302.0 101.325 6.31
303.2 101.325 6.57
314.5 101.325 6.91
318.0 101.325 7.22
318.2 101.325 7.22
325.0 101.325 7.56
329.3 101.325 7.53
345.0 101.325 8.76
C6H6 (1) benzene 71-43-2

T [K] p [kPa] D · 106 [m2/s]
290.0 101.325 59.9 ± 2%
292.9 101.325 60.9 ± 2%
298.9 101.325 61.0 ± 2%
299.4 101.325 63.4 ± 2%
302.0 101.325 63.06 ± 2%
303.0 101.325 65.7 ± 2%
303.2 101.325 65.70 ± 2%
314.5 101.325 69.1 ± 2%
318.0 101.325 72.22 ± 2%
318.0 101.325 71.5 ± 2%
325.0 101.325 75.55 ± 2%
329.3 101.325 73.3 ± 2%
345.0 101.325 87.60 ± 2%
368.0 101.325 98.68 ± 2%
381.0 101.325 106.2 ± 2%
396.0 101.325 113.0 ± 2%
414.0 101.325 124.3 ± 2%
422.0 101.325 128.8 ± 2%

2 Diffusion of benzene (1); carbon dioxide (2)
C6H6 (1) benzene 71-43-2

T [K] p [kPa] D · 104 [m2/s]
298.9 101.325 0.061 ± 0.002
C6H6 (1) benzene 71-43-2

T [K] p [MPa] D · 107 [m2/s]
303.15 0.1013 65.7 ± 5%
303.15 0.784 7.74 ± 5%
303.15 2.06 2.02 ± 5%
303.15 4.11 0.341 ± 5%
C6H6 (1) benzene 71-43-2

T [K] p [MPa] D · 107 [m2/s]
300 0.277 25.44
300 0.519 14.72
300 0.537 13.46
324.6 0.279 29.50
324.6 0.443 17.77
345 0.280 31.85
345 0.439 20.28
345 0.516 16.49
369 0.280 33.31
369 0.308 30.38
369 0.440 23.96
369 0.510 18.91
422 0.281 41.77
422 0.443 29.30
422 0.495 25.02
C6H6 (1) benzene 71-43-2

T [K] p [kPa] D · 104 [m2/s]
363.6 ± 0.2 101.325 0.105
378.0 ± 0.2 101.325 0.116
393.7 ± 0.2 101.325 0.122
408.2 ± 0.2 101.325 0.130
422.8 ± 0.2 101.325 0.150

C6H6 (1) benzene 71-43-2

T [K] p [MPa] D · 107 [m2/s]
300 0.100 64.00
324.6 0.100 76.56
345 0.100 88.77
369 0.100 100.0
422 0.100 130.5
References

Diffusion of benzene (1); sulfur hexafluoride (2) 1
Diffusion of benzene (1); sulfur hexafluoride (2)

Vapor in Gas
C6H6 (1) benzene 71-43-2

T [K] p [kPa] D · 106 [m2/s]
283.13 ± 0.002 101.325 3.30 ± 1%
298.22 ± 0.002 101.325 3.63 ± 1%
313.17 ± 0.002 101.325 4.00 ± 1%
328.17 ± 0.002 101.325 4.39 ± 1%
343.17 ± 0.002 101.325 4.78 ± 1%
Reference
1975B2 Battino, R., Wilhelm, E.: Monatsh. Chem. 106 (1975) 347–353.

Diffusion of benzene (1); hydrogen (2) 1
Diffusion of benzene (1); hydrogen (2)

Vapor in Gas
C6H6 (1) benzene 71-43-2

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
373.15 ± 0.1 101.325 0.550
388.15 ± 0.1 101.325 0.591
393.15 ± 0.1 101.325 0.617
398.15 ± 0.1 101.325 0.621
403.15 ± 0.1 101.325 0.640
408.15 ± 0.1 101.325 0.657
413.15 ± 0.1 101.325 0.673
418.15 ± 0.1 101.325 0.701
423.15 ± 0.1 101.325 0.751
C6H6 (1) benzene 71-43-2

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
373 101.325 0.5840 ± 1.5%
393 101.325 0.6500 ± 2.2%
423 101.325 0.7410 ± 1.1%
453 101.325 0.8220 ± 2.2%
483 101.325 0.8940 ± 0.94%
C6H6 (1) benzene 71-43-2

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
373.15 101.325 0.5840 ± 0.0091
393.15 101.325 0.6500 ± 0.0143
423.15 101.325 0.7410 ± 0.0078
453.15 101.325 0.8220 ± 0.0184
483.15 101.325 0.8940 ± 0.0084
C6H6 (1) benzene 71-43-2

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
292.6 ± 0.5 101.325 0.320
298 ± 0.5 101.325 0.320
(continued)

2 Diffusion of benzene (1); hydrogen (2)
303 ± 0.5 101.325 0.354

310 ± 0.5 101.325 0.372
311 ± 0.5 101.325 0.386
318 ± 0.5 101.325 0.431
C6H6 (1) benzene 71-43-2

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
423.15 101.325 0.610 ± 0.002
443.15 101.325 0.662 ± 0.001
463.15 101.325 0.715 ± 0.003
483.15 101.325 0.766 ± 0.012
503.15 101.325 0.815 ± 0.012
523.15 101.325 0.861 ± 0.001
References
1982P1 Pathak, B.K., Singh, V.N., Singh, P.C.: Indian J. Technol. 20 (1982) 200–202.

Diffusion of benzene (1); helium (2) 1
Diffusion of benzene (1); helium (2)

Vapor in Gas
C6H6 (1) benzene 71-43-2

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.2 101.325 0.367 ± 0.009
372.65 ± 0.2 101.325 0.498 ± 0.018
423.15 ± 0.2 101.325 0.614 ± 0.001
473.15 ± 0.2 101.325 0.778 ± 0.016
C6H6 (1) benzene 71-43-2

He (2) helium 7440-59-7
T [K] p [MPa] D · 107 [m2/s]
353.5 0.100 444.7
353.5 0.221 203.5
353.5 0.451 98.52
353.5 0.661 66.80
353.5 0.788 57.97
353.5 0.903 48.00
353.5 0.951 48.57
353.5 1.01 43.84
370.3 0.100 496.0
370.3 0.201 248.0
370.3 0.233 209.3
370.3 0.390 127.4
370.3 0.397 121.5
370.3 0.640 79.30
370.3 0.788 60.58
370.3 1.01 50.78
392 0.100 544.0
392 0.200 264.0
392 0.221 237.9
392 0.340 148.5
392 0.397 134.5
392 0.640 86.55
392 0.957 52.94
423.2 0.101 620.7
423.2 0.201 303.0
423.2 0.292 204.4

2 Diffusion of benzene (1); helium (2)
C6H6 (1) benzene 71-43-2

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.2 101.325 0.367
References

Diffusion of benzene (1); nitrogen (2) 1
Diffusion of benzene (1); nitrogen (2)

Vapor in Gas
C6H6 (1) benzene 71-43-2

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
353.0 101.325 0.133 ± 2.2%
C6H6 (1) benzene 71-43-2

N2 (2) nitrogen 7727-37-9
T [K] p [MPa] D · 107 [m2/s]
298 0.1012 94.4
298 0.197 45.8
298 2.55 2.93
298 5.00 1.41
298 7.85 0.86
315 0.197 52.8
315 0.393 26.5
315 2.55 3.53
315 5.00 1.74
315 7.75 1.09
353 0.197 65.0
353 0.393 31.4
353 2.55 4.41
353 5.00 2.24
353 7.85 1.37
353 9.81 1.07
C6H6 (1) benzene 71-43-2

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
373.15 ± 0.1 101.325 0.130
388.15 ± 0.1 101.325 0.149
393.15 ± 0.1 101.325 0.150
398.15 ± 0.1 101.325 0.156
403.15 ± 0.1 101.325 0.159
408.15 ± 0.1 101.325 0.169
413.15 ± 0.1 101.325 0.172
418.15 ± 0.1 101.325 0.180
423.15 ± 0.1 101.325 0.189

2 Diffusion of benzene (1); nitrogen (2)
C6H6 (1) benzene 71-43-2

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
288 ± 0.5 101.325 0.0905
293 ± 0.5 101.325 0.0959
298 ± 0.5 101.325 0.0947
303 ± 0.5 101.325 0.102
308 ± 0.5 101.325 0.104
313 ± 0.5 101.325 0.105
C6H6 (1) benzene 71-43-2

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
364.2 ± 0.2 101.325 0.129
378.2 ± 0.2 101.325 0.140
393.4 ± 0.2 101.325 0.154
408.2 ± 0.2 101.325 0.163
423.2 ± 0.2 101.325 0.165
References
1982P1 Pathak, B.K., Singh, V.N., Singh, P.C.: Indian J. Technol. 20 (1982) 200–202.

Diffusion of aniline (1); air (2) 1
Diffusion of aniline (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.35 ± 0.089
Reference

Diffusion of aniline (1); hydrogen (2) 1
Diffusion of aniline (1); hydrogen (2)

Vapor in Gas

H2 (2) hydrogen 1333-74-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: ARF Ref.: 1977C3
T [K] p [kPa] D · 104 [m2/s]
483.15 101.325 0.805
523.15 101.325 0.926
563.15 101.325 1.027
Reference
1977C3 Choudhary, V.R., Parande, M.G.: J. Chromatogr. 132 (1977) 344–348.

Diffusion of 4-methyl-pent-3-en-2-one (1); air (2) 1
Diffusion of 4-methyl-pent-3-en-2-one (1); air (2)

Vapor in Gas
C6H10O (1) 4-methyl-pent-3-en-2-one 141-79-7

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.60 ± 0.015
Reference

Diffusion of cyclohexane (1); air (2) 1
Diffusion of cyclohexane (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
293.15 101.325 0.0720

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
273.2 101.325 6.50
298.2 101.325 7.66
323.2 101.325 8.90
348.2 101.325 10.30

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
283.2 101.325 6.96
293.2 101.325 7.45
303.2 101.325 7.81
313.2 101.325 8.29
References

Diffusion of hex-1-ene (1); air (2) 1
Diffusion of hex-1-ene (1); air (2)

Vapor in Gas
C6H12 (1) hex-1-ene 592-41-6

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
293.15 ± 0.1 101.325 0.0788 ± 0.0035
303.15 ± 0.1 101.325 0.0829 ± 0.0015
Reference

Diffusion of cyclohexane (1); carbon dioxide (2) 1
Diffusion of cyclohexane (1); carbon dioxide (2)

Vapor in Gas

T [K] p [kPa] D · 104 [m2/s]
363.1 ± 0.2 101.325 0.098
383.0 ± 0.2 101.325 0.108
403.4 ± 0.2 101.325 0.114
423.4 ± 0.2 101.325 0.126
Reference

Diffusion of cyclohexane (1); sulfur hexafluoride (2) 1
Diffusion of cyclohexane (1); sulfur hexafluoride (2)

Vapor in Gas

T [K] p [kPa] D · 104 [m2/s]
283.13 ± 0.002 101.325 2.92 ± 1%
298.22 ± 0.002 101.325 3.24 ± 1%
313.17 ± 0.002 101.325 3.58 ± 1%
328.17 ± 0.002 101.325 3.92 ± 1%
343.17 ± 0.002 101.325 4.26 ± 1%
Reference

Diffusion of cyclohexane (1); hydrogen (2) 1
Diffusion of cyclohexane (1); hydrogen (2)

Vapor in Gas

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
373 101.325 0.5140 ± 2.5%
393 101.325 0.5960 ± 0.67%
423 101.325 0.6742 ± 1.6%
453 101.325 0.7818 ± 2.7%

H2 (2) hydrogen 1333-74-0
T [K] p [MPa] D · 107 [m2/s]
303 2.06 17.1
303 5.00 6.90
303 9.91 3.46
323 2.06 18.7
323 5.00 7.56
323 9.91 3.81
323 19.72 1.942
353 2.06 21.7
353 5.00 8.72
353 9.91 4.46
353 19.72 2.31
353 29.51 1.70

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
373.15 101.325 0.5140 ± 0.0127
393.15 101.325 0.5960 ± 0.0040
423.15 101.325 0.6742 ± 0.0109
453.15 101.325 0.7818 ± 0.0210
References

Diffusion of cyclohexane (1); nitrogen (2) 1
Diffusion of cyclohexane (1); nitrogen (2)

Vapor in Gas

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
363.2 ± 0.2 101.325 0.124
383.2 ± 0.2 101.325 0.134
403.2 ± 0.2 101.325 0.149
Reference

Diffusion of 4-methyl-pentan-2-one (1); air (2) 1
Diffusion of 4-methyl-pentan-2-one (1); air (2)

Vapor in Gas
C6H12O (1) 4-methyl-pentan-2-one 108-10-1

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
293.15 101.325 0.081
Reference

Diffusion of acetic acid butyl ester (1); air (2) 1
Diffusion of acetic acid butyl ester (1); air (2)

Vapor in Gas
C6H12O2 (1) acetic acid butyl ester 123-86-4

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
293.05 101.325 0.069

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.72 ± 0.072
References

Diffusion of formic acid pentyl ester (1); air (2) 1
Diffusion of formic acid pentyl ester (1); air (2)

Vapor in Gas
C6H12O2 (1) formic acid pentyl ester 638-49-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.63 ± 0.129
Reference

Diffusion of formic acid isopentyl ester (1); air (2) 1
Diffusion of formic acid isopentyl ester (1); air (2)

Vapor in Gas
C6H12O2 (1) formic acid isopentyl ester 110-45-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.75 ± 0.048
Reference

Diffusion of 4-hydroxy-4-methyl-pentan-2-one (1); air (2) 1
Diffusion of 4-hydroxy-4-methyl-pentan-2-one (1); air (2)

Vapor in Gas
C6H12O2 (1) 4-hydroxy-4-methyl-pentan-2-one 123-42-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.47 ± 0.038
Reference

Diffusion of acetic acid isobutyl ester (1); air (2) 1
Diffusion of acetic acid isobutyl ester (1); air (2)

Vapor in Gas
C6H12O2 (1) acetic acid isobutyl ester 110-19-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.90 ± 0.176
Reference

Diffusion of butyric acid ethyl ester (1); air (2) 1
Diffusion of butyric acid ethyl ester (1); air (2)

Vapor in Gas
C6H12O2 (1) butyric acid ethyl ester 105-54-4

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.69 ± 0.041
Reference

Diffusion of pentanoic acid methyl ester (1); air (2) 1
Diffusion of pentanoic acid methyl ester (1); air (2)

Vapor in Gas
C6H12O2 (1) pentanoic acid methyl ester 624-24-8

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.65 ± 0.026
Reference

Diffusion of 4-methyl-pentanoic acid (1); air (2) 1
Diffusion of 4-methyl-pentanoic acid (1); air (2)

Vapor in Gas
C6H12O2 (1) 4-methyl-pentanoic acid 646-07-1

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 5.96 ± 0.038
Reference

Diffusion of isobutyric acid ethyl ester (1); air (2) 1
Diffusion of isobutyric acid ethyl ester (1); air (2)

Vapor in Gas
C6H12O2 (1) isobutyric acid ethyl ester 97-62-1

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.75 ± 0.074
Reference

Diffusion of hexanoic acid (1); air (2) 1
Diffusion of hexanoic acid (1); air (2)

Vapor in Gas
C6H12O2 (1) hexanoic acid 142-62-1

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.02 ± 0.106
Reference

Diffusion of acetic acid 2-ethoxy-ethyl ester (1); air (2) 1
Diffusion of acetic acid 2-ethoxy-ethyl ester (1); air (2)

Vapor in Gas
C6H12O3 (1) acetic acid 2-ethoxy-ethyl ester 111-15-9

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.10 ± 0.026
Reference

Diffusion of 1-bromo-hexane (1); helium (2) 1
Diffusion of 1-bromo-hexane (1); helium (2)

Vapor in Gas
C6H13Br (1) 1-bromo-hexane 111-25-1

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
427.5 ± 0.2 101.325 0.461 ± 0.008
Reference


Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
427.9 ± 0.2 101.325 0.470 ± 0.012
Reference


Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
428.5 ± 0.2 101.325 0.469 ± 0.004
Reference

Diffusion of 1-fluoro-hexane (1); helium (2) 1
Diffusion of 1-fluoro-hexane (1); helium (2)

Vapor in Gas
C6H13F (1) 1-fluoro-hexane 373-14-8

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
431.6 ± 0.2 101.325 0.492 ± 0.006
Reference

Diffusion of hexane (1); air (2) 1
Diffusion of hexane (1); air (2)

Vapor in Gas
C6H14 (1) hexane 110-54-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
293.2 101.325 7.55
293.2 101.325 7.58
303.2 101.325 7.93
313.2 101.325 8.52
333.2 101.325 9.58
C6H14 (1) hexane 110-54-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
297.2 101.325 7.81
297.2 101.325 7.78
C6H14 (1) hexane 110-54-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
273.2 101.325 6.46
283.2 101.325 7.43
323.2 101.325 8.45
C6H14 (1) hexane 110-54-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.1 101.325 0.0797
303.15 ± 0.1 101.325 0.0811 ± 0.044
321.65 ± 0.1 101.325 0.0889 ± 0.0026
322.65 ± 0.1 101.325 0.0903 ± 0.0028
323.40 ± 0.1 101.325 0.0903
C6H14 (1) hexane 110-54-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
299.15 101.325 0.0834 ± 0.0005

2 Diffusion of hexane (1); air (2)
C6H14 (1) hexane 110-54-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
293.15 101.325 0.0775
C6H14 (1) hexane 110-54-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.32 ± 0.066
References

Diffusion of 3-methyl-pentane (1); argon (2) 1
Diffusion of 3-methyl-pentane (1); argon (2)

Vapor in Gas
C6H14 (1) 3-methyl-pentane 96-14-0

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
306.5 ± 0.1 101.325 0.0742 ± 0.44%
372.9 ± 0.1 101.325 0.1061 ± 0.50%
Reference

Diffusion of 2-methyl-pentane (1); argon (2) 1
Diffusion of 2-methyl-pentane (1); argon (2)

Vapor in Gas

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
306.5 ± 0.1 101.325 0.0747 ± 0.63%
372.9 ± 0.1 101.325 0.1068 ± 0.42%
Reference

Diffusion of 2,3-dimethyl-butane (1); argon (2) 1
Diffusion of 2,3-dimethyl-butane (1); argon (2)

Vapor in Gas

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
306.5 ± 0.1 101.325 0.0773 ± 0.81%
372.9 ± 0.1 101.325 0.1105 ± 0.36%
Reference

Diffusion of 2,2-dimethyl-butane (1); argon (2) 1
Diffusion of 2,2-dimethyl-butane (1); argon (2)

Vapor in Gas

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
306.5 ± 0.1 101.325 0.0778 ± 0.73%
372.9 ± 0.1 101.325 0.1112 ± 0.54%
Reference

Diffusion of hexane (1); argon (2) 1
Diffusion of hexane (1); argon (2)

Vapor in Gas
C6H14 (1) hexane 110-54-3

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
306.5 ± 0.1 101.325 0.0734 ± 0.71%
372.9 ± 0.1 101.325 0.1049 ± 0.60%
C6H14 (1) hexane 110-54-3

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.2 101.325 0.0845 ± 0.0028
372.65 ± 0.2 101.325 0.107 ± 0.001
423.15 ± 0.2 101.325 0.145 ± 0.003
473.15 ± 0.2 101.325 0.174 ± 0.005
C6H14 (1) hexane 110-54-3

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 107 [m2/s]
288.6 101.325 66.2*
298.2 101.325 84.5*
301.0 101.325 70.76 ± 2%
306.5 101.325 73.4*
323.0 101.325 81.63 ± 2%
353.0 101.325 97.09 ± 2%
353.2 101.325 93.4 ± 2%
372.7 101.325 107*
372.9 101.325 104.9*
383.0 101.325 111.4 ± 2%
403.0 101.325 120.9 ± 2%
423.0 101.325 132.6 ± 2%
423.2 101.325 145*
73.2 101.325 174*
References

Diffusion of hexane (1); methane (2) 1
Diffusion of hexane (1); methane (2)

Vapor in Gas
C6H14 (1) hexane 110-54-3

CH4 (2) methane 74-82-8
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.01 101.325 0.08664
303.15 ± 0.01 101.325 0.08936
313.15 ± 0.01 101.325 0.09493
323.15 ± 0.01 101.325 0.10065
333.15 ± 0.01 101.325 0.10650
Comment: average deviation: ±0.77%
Reference
1965K2 Kohn, J.P., Romero, N.: J. Chem. Eng. Data 10 (1965) 125–128.

Diffusion of 3-methyl-pentane (1); methane (2) 1
Diffusion of 3-methyl-pentane (1); methane (2)

Vapor in Gas

CH4 (2) methane 74-82-8
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.01 101.325 0.08756
303.15 ± 0.01 101.325 0.09028
313.15 ± 0.01 101.325 0.09591
323.15 ± 0.01 101.325 0.10164
333.15 ± 0.01 101.325 0.10752
Comment: average deviation: ±0.77%
Reference
1965K2 Kohn, J.P., Romero, N.: J. Chem. Eng. Data 10 (1965) 125–128.

Diffusion of hexane (1); carbon dioxide (2) 1
Diffusion of hexane (1); carbon dioxide (2)

Vapor in Gas
C6H14 (1) hexane 110-54-3

T [K] p [kPa] D · 107 [m2/s]
287.0 101.325 51.47 ± 2%
302.0 101.325 58.46 ± 2%
323.2 101.325 66.12 ± 2%
333.2 101.325 70.07 ± 2%
345.0 101.325 72.16 ± 2%
368.0 101.325 82.89 ± 2%
381.0 101.325 90.79 ± 2%
396.0 101.325 99.77 ± 2%
425.0 101.325 111.9 ± 2%
440.0 101.325 120.2 ± 2%
450.0 101.325 125.6 ± 2%
Reference

Diffusion of hexane (1); hydrogen (2) 1
Diffusion of hexane (1); hydrogen (2)

Vapor in Gas
C6H14 (1) hexane 110-54-3

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
353.15 101.325 0.4990 ± 0.0047
373.15 101.325 0.4740 ± 0.0071
393.15 101.325 0.5310 ± 0.0020
423.15 101.325 0.5923 ± 0.0018
453.15 101.325 0.6520 ± 0.0000
C6H14 (1) hexane 110-54-3

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
353 101.325 0.4990 ± 0.94%
373 101.325 0.4740 ± 1.5%
393 101.325 0.5310 ± 0.38%
423 101.325 0.5923 ± 0.30%
453 101.325 0.6520
References

Diffusion of hexane (1); helium (2) 1
Diffusion of hexane (1); helium (2)

Vapor in Gas
C6H14 (1) hexane 110-54-3

He (2) helium 7440-59-7
T [K] p [kPa] D · 109 [m2/s]
333.2 101.325 3.20
318.2 101.325 3.05
298.2 101.325 2.47
C6H14 (1) hexane 110-54-3

He (2) helium 7440-59-7
T [K] p [MPa] D · 107 [m2/s]
353.5 0.100 346.0
353.5 0.149 244.2
353.5 0.204 185.6
353.5 0.461 78.68
353.5 0.593 64.07
353.5 0.664 55.04
353.5 0.788 48.42
391.4 0.100 424.3
391.4 0.181 221.4
391.4 0.272 158.0
391.4 0.351 123.7
391.4 0.703 62.89
391.4 0.982 47.47
424.3 0.100 501.0
424.3 0.198 254.7
424.3 0.306 151.7
424.3 0.569 87.37
424.3 0.787 63.43
424.3 0.997 47.42
C6H14 (1) hexane 110-54-3

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.2 101.325 0.273 ± 0.005
372.65 ± 0.2 101.325 0.390 ± 0.006
423.15 ± 0.2 101.325 0.513 ± 0.013
473.15 ± 0.2 101.325 0.629 ± 0.012

2 Diffusion of hexane (1); helium (2)
References

Diffusion of hexane (1); nitrogen (2) 1
Diffusion of hexane (1); nitrogen (2)

Vapor in Gas
C6H14 (1) hexane 110-54-3

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104[m2/s]
288.6 101.325 0.0757 ± 0.0004
Reference

Diffusion of diisopropyl ether (1); air (2) 1
Diffusion of diisopropyl ether (1); air (2)

Vapor in Gas
C6H14O (1) diisopropyl ether 108-20-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.83 ± 0.051
Reference

Diffusion of hexan-1-ol (1); air (2) 1
Diffusion of hexan-1-ol (1); air (2)

Vapor in Gas
C6H14O (1) hexan-1-ol 111-27-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.21 ± 0.201
Reference

Diffusion of 2-methyl-pentan-2-ol (1); air (2) 1
Diffusion of 2-methyl-pentan-2-ol (1); air (2)

Vapor in Gas
C6H14O (1) 2-methyl-pentan-2-ol 590-36-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.18 ± 0.063
Reference

Diffusion of 2-ethyl-butan-1-ol (1); air (2) 1
Diffusion of 2-ethyl-butan-1-ol (1); air (2)

Vapor in Gas
C6H14O (1) 2-ethyl-butan-1-ol 97-95-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.56 ± 0.071
Reference

Diffusion of hexan-1-ol (1); helium (2) 1
Diffusion of hexan-1-ol (1); helium (2)

Vapor in Gas
C6H14O (1) hexan-1-ol 111-27-3

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
423.15 101.325 0.469 ± 0.007
443.15 101.325 0.496 ± 0.007
463.15 101.325 0.531 ± 0.001
483.15 101.325 0.584 ± 0.012
503.15 101.325 0.631 ± 0.004
523.15 101.325 0.686 ± 0.003
Reference

Diffusion of 2-(2-ethoxy-ethoxy)-ethanol (1); air (2) 1
Diffusion of 2-(2-ethoxy-ethoxy)-ethanol (1); air (2)

Vapor in Gas
C6H14O3 (1) 2-(2-ethoxy-ethoxy)-ethanol 111-90-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.10 ± 0.053
Reference

Diffusion of triethylene glycol (1); air (2) 1
Diffusion of triethylene glycol (1); air (2)

Vapor in Gas
C6H14O4 (1) triethylene glycol 112-27-6

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 5.90 ± 0.059
Reference

Diffusion of triethylene glycol (1); carbon dioxide (2) 1
Diffusion of triethylene glycol (1); carbon dioxide (2)

Vapor in Gas

T [K] p [kPa] D · 106 [m2/s]
323.2 101.325 5.46
348.2 101.325 7.12
373.2 101.325 8.72
398.2 101.325 10.75
423.2 101.325 12.48
448.2 101.325 14.88
473.2 101.325 16.45
Reference

Diffusion of triethylene glycol (1); nitrogen (2) 1
Diffusion of triethylene glycol (1); nitrogen (2)

Vapor in Gas

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 106 [m2/s]
375.2 101.325 16.30
404.2 101.325 19.80
438.2 101.325 23.30
472.2 101.325 26.20
Reference

Diffusion of triethyl-amine (1); air (2) 1
Diffusion of triethyl-amine (1); air (2)

Vapor in Gas
C6H15N (1) triethyl-amine 121-44-8

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.54 ± 0.045
Reference

Diffusion of phosphoric acid triethyl ester (1); air (2) 1
Diffusion of phosphoric acid triethyl ester (1); air (2)

Vapor in Gas
C6H15O4P (1) phosphoric acid triethyl ester 78-40-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 5.52 ± 0.016
Reference

Diffusion of benzonitrile (1); air (2) 1
Diffusion of benzonitrile (1); air (2)

Vapor in Gas
C7H5N (1) benzonitrile 100-47-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.10 ± 0.020
Reference

Diffusion of chloromethyl-benzene (1); air (2) 1
Diffusion of chloromethyl-benzene (1); air (2)

Vapor in Gas
C7H7Cl (1) chloromethyl-benzene 100-44-7

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.13 ± 0.059
Reference

Diffusion of 4-chloro-toluene (1); air (2) 1
Diffusion of 4-chloro-toluene (1); air (2)

Vapor in Gas
C7H7Cl (1) 4-chloro-toluene 106-43-4

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.21 ± 0.027
Reference


Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.45 ± 0.094
Reference


Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.88 ± 0.025
Reference

Diffusion of 4-fluoro-toluene (1); helium (2) 1
Diffusion of 4-fluoro-toluene (1); helium (2)

Vapor in Gas
C7H7F (1) 4-fluoro-toluene 352-32-9

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
431.6 ± 0.2 101.325 0.508 ± 0.006
Reference

Diffusion of toluene (1); air (2) 1
Diffusion of toluene (1); air (2)

Vapor in Gas
C7H8 (1) toluene 108-88-3

Air (2) air 132259-10-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: STEFAN Ref.: 2002E1
T [K] p [kPa] D · 106 [m2/s]
274.15 101.325 6.11
280.15 101.325 6.70
289.15 101.325 7.27
299.15 101.325 8.11
306.15 101.325 8.76
290.65 101.325 7.17
295.65 101.325 7.33
299.65 101.325 8.03
305.15 101.325 8.40
306.15 101.325 8.55
C7H8 (1) toluene 108-88-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.1 101.325 0.0908
318.15 ± 0.1 101.325 0.0961
318.15 ± 0.1 101.325 0.0970
C7H8 (1) toluene 108-88-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
268.15 101.325 4.07 ± 0.59
283.15 101.325 5.80 ± 0.24
298.15 101.325 6.98 ± 0.13
313.15 101.325 8.19 ± 0.24
C7H8 (1) toluene 108-88-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
383.55 ± 1.0 101.325 0.1310
389.55 ± 1.0 101.325 0.1355

2 Diffusion of toluene (1); air (2)
C7H8 (1) toluene 108-88-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
273.2 101.325 7.09
293.2 101.325 8.00
C7H8 (1) toluene 108-88-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
292.95 101.325 0.089
C7H8 (1) toluene 108-88-3

Air (2) air 132259-10-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: INT Ref.: 1977B8
T [K] p [kPa] D · 106 [m2/s]
298.2 101.325 8.13
C7H8 (1) toluene 108-88-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 8.49 ± 0.149
C7H8 (1) toluene 108-88-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
293.15 101.325 0.0780
C7H8 (1) toluene 108-88-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
373.15 ± 0.1 101.325 0.1284 ± 1.5%
C7H8 (1) toluene 108-88-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
297.15 101.325 0.0859 ± 0.0044

Diffusion of toluene (1); air (2) 3
C7H8 (1) toluene 108-88-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
371.65 ± 0.2 101.325 0.0819 ± 0.0010
References
2002E1 Erbil, H.Y., Avci, Y.: Langmuir 18 (2002) 5113–5119.
1981A1 Alvarez, R., Bueno, J.L., Coca, J.: J. Chem. Eng. Jpn. 14 (1981) 239–241.
1977B8 Black, W.Z., Somers, R.L.: Rev. Sci. Instrum. 48 (1977) 476–481.
1980C5 Coca, J., Bueno, J.L., Alvarez, R.: Ind. Eng. Chem. Fundam. 19 (1980) 219–221.

Diffusion of toluene (1); argon (2) 1
Diffusion of toluene (1); argon (2)

Vapor in Gas
C7H8 (1) toluene 108-88-3

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 107 [m2/s]
292.0 101.325 64.6 ± 2%
301.0 101.325 70.69 ± 2%
323.0 101.325 82.30 ± 2%
353.0 101.325 99.87 ± 2%
383.0 101.325 110.8 ± 2%
393.0 101.325 119.0*
403.0 101.325 126.3 ± 2%
423.0 101.325 139.2 ± 2%
Reference

Diffusion of toluene (1); carbon dioxide (2) 1
Diffusion of toluene (1); carbon dioxide (2)

Vapor in Gas
C7H8 (1) toluene 108-88-3

T [K] p [kPa] D · 107 [m2/s]
302.0 101.325 57.00 ± 2%
345.0 101.325 77.10 ± 2%
368.0 101.325 87.37 ± 2%
423.2 101.325 115.0 ± 2%
443.0 101.325 123.8 ± 2%
C7H8 (1) toluene 108-88-3

Diffusion of gas(1) in gas(2): D*12(T ); Method: GEL Ref.: 1995L6
T [K] p [atm] D · 108 [m2/s]
301.4 54.3 13.49
301.4 74.2 1.095
301.4 82.5 0.833
301.4 118.8 0.575
308.4 54.3 31.14
308.4 64.2 9.602
308.4 69.2 9.120
308.4 74.2 5.569
308.4 82.5 1.056
308.4 94.0 1.015
308.4 118.8 0.9912
318.5 54.3 37.47
318.5 74.2 12.67
318.5 94.0 2.958
318.5 118.8 1.577
References
1995L6 Lee, C.H., Holder, G.D.: Ind. Eng. Chem. Res. 34 (1995) 906–914.

Diffusion of toluene (1); sulfur hexafluoride (2) 1
Diffusion of toluene (1); sulfur hexafluoride (2)

Vapor in Gas
C7H8 (1) toluene 108-88-3

T [K] p [kPa] D · 106 [m2/s]
298.22 ± 0.002 101.325 3.06 ± 1%
313.17 ± 0.002 101.325 3.44 ± 1%
328.17 ± 0.002 101.325 3.84 ± 1%
343.17 ± 0.002 101.325 4.18 ± 1%
Reference

Diffusion of toluene (1); hydrogen (2) 1
Diffusion of toluene (1); hydrogen (2)

Vapor in Gas
C7H8 (1) toluene 108-88-3

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
393.15 101.325 0.6170 ± 0.0477
423.15 101.325 0.6724 ± 0.0050
453.15 101.325 0.7440 ± 0.0115
483.15 101.325 0.8197 ± 0.0402
C7H8 (1) toluene 108-88-3

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
373 101.325 0.5834
393 101.325 0.6170 ± 7.7%
423 101.325 0.6724 ± 0.74%
453 101.325 0.7440 ± 1.5%
483 101.325 0.8197 ± 4.9%
References

Diffusion of toluene (1); helium (2) 1
Diffusion of toluene (1); helium (2)

Vapor in Gas
C7H8 (1) toluene 108-88-3

He (2) helium 7440-59-7
T [K] p [MPa] D · 107 [m2/s]
370.3 0.100 401.0
370.3 0.204 194.6
370.3 0.326 130.8
370.3 0.451 93.6
370.3 0.639 69.32
370.3 0.951 46.80
391.9 0.100 450.0
391.9 0.221 201.6
391.9 0.408 114.5
391.9 0.640 73.20
391.9 0.969 51.82
391.9 1.39 36.36
C7H8 (1) toluene 108-88-3

He (2) helium 7440-59-7
T [K] p [kPa] D · 107 [m2/s]
293.2 101.325 250.3 ± 2%
323.2 101.325 303.1 ± 2%
353.2 101.325 369.0 ± 2%
370.3 101.325 395.7 ± 2%
373.6 101.325 411.5 ± 2%
391.9 101.325 444.1 ± 2%
423.2 101.325 501.3 ± 2%
References

Diffusion of benzyl alcohol (1); air (2) 1
Diffusion of benzyl alcohol (1); air (2)

Vapor in Gas
C7H8O (1) benzyl alcohol 100-51-6

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.12 ± 0.063
Reference

Diffusion of methyl-cyclohexane (1); air (2) 1
Diffusion of methyl-cyclohexane (1); air (2)

Vapor in Gas
C7H14 (1) methyl-cyclohexane 108-87-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
283.2 101.325 5.71
293.2 101.325 6.15
303.2 101.325 6.60
313.2 101.325 7.06
Reference

Diffusion of methyl-cyclohexane (1); sulfur hexafluoride (2) 1
Diffusion of methyl-cyclohexane (1); sulfur hexafluoride (2)

Vapor in Gas

T [K] p [kPa] D · 106 [m2/s]
283.13 ± 0.002 101.325 2.50 ± 1%
298.22 ± 0.002 101.325 2.81 ± 1%
313.17 ± 0.002 101.325 3.15 ± 1%
328.17 ± 0.002 101.325 3.45 ± 1%
343.17 ± 0.002 101.325 3.83 ± 1%
Reference

Diffusion of butyric acid propyl ester (1); air (2) 1
Diffusion of butyric acid propyl ester (1); air (2)

Vapor in Gas
C7H14O2 (1) butyric acid propyl ester 105-66-8

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.10 ± 0.048
Reference

Diffusion of isobutyric acid isopropyl ester (1); air (2) 1
Diffusion of isobutyric acid isopropyl ester (1); air (2)

Vapor in Gas
C7H14O2 (1) isobutyric acid isopropyl ester 617-50-5

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.38 ± 0.100
Reference

Diffusion of isobutyric acid propyl ester (1); air (2) 1
Diffusion of isobutyric acid propyl ester (1); air (2)

Vapor in Gas
C7H14O2 (1) isobutyric acid propyl ester 644-49-5

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.22 ± 0.130
Reference

Diffusion of propionic acid butyl ester (1); air (2) 1
Diffusion of propionic acid butyl ester (1); air (2)

Vapor in Gas
C7H14O2 (1) propionic acid butyl ester 590-01-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.08 ± 0.029
Reference

Diffusion of propionic acid isobutyl ester (1); air (2) 1
Diffusion of propionic acid isobutyl ester (1); air (2)

Vapor in Gas
C7H14O2 (1) propionic acid isobutyl ester 540-42-1

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.11 ± 0.022
Reference

Diffusion of pentanoic acid ethyl ester (1); air (2) 1
Diffusion of pentanoic acid ethyl ester (1); air (2)

Vapor in Gas
C7H14O2 (1) pentanoic acid ethyl ester 539-82-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.03 ± 0.144
Reference

Diffusion of hexanoic acid methyl ester (1); air (2) 1
Diffusion of hexanoic acid methyl ester (1); air (2)

Vapor in Gas
C7H14O2 (1) hexanoic acid methyl ester 106-70-7

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.10 ± 0.018
Reference

Diffusion of acetic acid pentyl ester (1); air (2) 1
Diffusion of acetic acid pentyl ester (1); air (2)

Vapor in Gas
C7H14O2 (1) acetic acid pentyl ester 628-63-7

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.10 ± 0.037
Reference

Diffusion of heptane (1); air (2) 1
Diffusion of heptane (1); air (2)

Vapor in Gas
C7H16 (1) heptane 142-82-5

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
289.95 ± 0.1 101.325 0.0705 ± 0.0024
337.75 ± 0.1 101.325 0.0847 ± 0.0038
C7H16 (1) heptane 142-82-5

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
283.2 101.325 6.78
293.2 101.325 7.36
297.2 101.325 7.11
303.2 101.325 7.97
305.2 101.325 8.01
313.2 101.325 8.36
316.8 101.325 8.50
323.2 101.325 8.90
329.8 101.325 9.66
363.2 101.325 10.55
371.6 101.325 10.80
C7H16 (1) heptane 142-82-5

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
297.85 101.325 0.0693 ± 0.0009
297.95 101.325 0.0725 ± 0.0009
298.15 101.325 0.0730 ± 0.0009
298.85 101.325 0.0777 ± 0.0009
297.75 101.325 0.0734 ± 0.0009
299.15 101.325 0.0725 ± 0.0009
298.85 101.325 0.0727 ± 0.0009
298.65 101.325 0.0744 ± 0.0009
298.75 101.325 0.0769 ± 0.0009

2 Diffusion of heptane (1); air (2)
C7H16 (1) heptane 142-82-5

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
293.15 101.325 0.0690
C7H16 (1) heptane 142-82-5

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
292.85 101.325 0.074
C7H16 (1) heptane 142-82-5

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
273.2 101.325 5.94
References

Diffusion of heptane (1); argon (2) 1
Diffusion of heptane (1); argon (2)

Vapor in Gas
C7H16 (1) heptane 142-82-5

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
290.4 101.325 61.4 ± 2%
293.5 101.325 63.2 ± 2%
301.0 101.325 65.68 ± 2%
303.2 101.325 65.8*
323.0 101.325 75.30 ± 2%
353.0 101.325 87.97 ± 2%
353.2 101.325 84.6*
383.0 101.325 101.3 ± 2%
403.0 101.325 111.1 ± 2%
423.0 101.325 120.0 ± 2%
443.0 101.325 134.0 ± 2%
Reference

Diffusion of heptane (1); carbon dioxide (2) 1
Diffusion of heptane (1); carbon dioxide (2)

Vapor in Gas
C7H16 (1) heptane 142-82-5

T [K] p [kPa] D · 104 [m2/s]
290.4 101.325 47.6 ± 2%
293.2 101.325 49.0 ± 2%
302.0 101.325 50.53 ± 2%
345.0 101.325 66.06 ± 2%
368.0 101.325 74.00 ± 2%
381.0 101.325 80.43 ± 2%
396.0 101.325 88.66 ± 2%
425.0 101.325 95.72 ± 2%
Reference

Diffusion of heptane (1); helium (2) 1
Diffusion of heptane (1); helium (2)

Vapor in Gas
C7H16 (1) heptane 142-82-5

He (2) helium 7440-59-7
T [K] p [MPa] D · 107 [m2/s]
370.2 0.100 354.0
370.2 0.149 231.5
370.2 0.223 157.0
370.2 0.406 85.50
370.2 0.637 55.61
370.2 0.977 35.87
391.8 0.100 387.2
391.8 0.149 252.6
391.8 0.180 211.0
391.8 0.347 114.1
391.8 0.451 86.12
391.8 0.691 56.59
391.8 0.977 41.90
423.2 0.101 405.6
423.2 0.149 281.7
423.2 0.289 134.7
423.2 0.406 106.6
423.2 0.560 80.62
423.2 1.00 44.68
423.2 1.38 31.52
C7H16 (1) heptane 142-82-5

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
373.15 ± 0.10 101.325 0.3544 ± 0.62%
References

Diffusion of 3-methyl-hexane (1); helium (2) 1
Diffusion of 3-methyl-hexane (1); helium (2)

Vapor in Gas
C7H16 (1) 3-methyl-hexane 589-34-4

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
373.15 ± 0.10 101.325 0.3586 ± 0.36%
Reference

Diffusion of 2-methyl-hexane (1); helium (2) 1
Diffusion of 2-methyl-hexane (1); helium (2)

Vapor in Gas
C7H16 (1) 2-methyl-hexane 591-76-4

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
373.15 ± 0.10 101.325 0.3626 ± 0.54%
Reference

Diffusion of 2,4-dimethyl-pentane (1); helium (2) 1
Diffusion of 2,4-dimethyl-pentane (1); helium (2)

Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
373.15 ± 0.10 101.325 0.3635 ± 0.27%
Reference


Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
373.15 ± 0.10 101.325 0.3720 ± 0.11%
Reference

Diffusion of 2,2,3-trimethyl-butane (1); helium (2) 1
Diffusion of 2,2,3-trimethyl-butane (1); helium (2)

Vapor in Gas
C7H16 (1) 2,2,3-trimethyl-butane 464-06-2

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
373.15 ± 0.10 101.325 0.3858 ± 0.32%
Reference


Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
373.15 ± 0.10 101.325 0.3758 ± 0.61%
Reference


Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
373.15 ± 0.10 101.325 0.3843 ± 0.59%
Reference

Diffusion of heptane (1); nitrogen (2) 1
Diffusion of heptane (1); nitrogen (2)

Vapor in Gas
C7H16 (1) heptane 142-82-5

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
303.0 101.325 0.743 ± 0.0012
C7H16 (1) heptane 142-82-5

N2 (2) nitrogen 7727-37-9
T [K] p [MPa] D · 107 [m2/s]
303 0.1015 89.8
303 0.197 41.3
303 0.98 6.33
303 2.45 2.18
303 4.91 0.97
303 7.37 0.61
303 9.81 0.43
363 0.197 49.9
363 0.98 8.13
363 2.45 2.92
363 4.91 1.33
363 7.37 0.84
References

Diffusion of heptan-1-ol (1); air (2) 1
Diffusion of heptan-1-ol (1); air (2)

Vapor in Gas
C7H16O (1) heptan-1-ol 111-70-6

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 5.54 ± 0.041
Reference

Diffusion of styrene (1); air (2) 1
Diffusion of styrene (1); air (2)

Vapor in Gas
C8H8 (1) styrene 100-42-5

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.01 ± 0.076
Reference

Diffusion of 1,3-dimethyl-benzene (1); air (2) 1
Diffusion of 1,3-dimethyl-benzene (1); air (2)

Vapor in Gas
C8H10 (1) 1,3-dimethyl-benzene 108-38-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.88 ± 0.101
Reference


Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.27 ± 0.036
Reference

Diffusion of ethylbenzene (1); air (2) 1
Diffusion of ethylbenzene (1); air (2)

Vapor in Gas
C8H10 (1) ethylbenzene 100-41-4

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 7.55 ± 0.076
Reference


Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.70 ± 0.040
Reference

Diffusion of 1,3-dimethyl-benzene (1); carbon dioxide (2) 1
Diffusion of 1,3-dimethyl-benzene (1); carbon dioxide (2)

Vapor in Gas

T [K] p [kPa] D · 107 [m2/s]
302.0 101.325 48.72 ± 2%
325.0 101.325 57.24 ± 2%
368.0 101.325 75.38 ± 2%
381.0 101.325 79.48 ± 2%
396.0 101.325 87.85 ± 2%
425.0 101.325 98.88 ± 2%
Reference

Diffusion of ethylbenzene (1); carbon dioxide (2) 1
Diffusion of ethylbenzene (1); carbon dioxide (2)

Vapor in Gas

T [K] p [kPa] D · 107 [m2/s]
301.2 101.325 49.31 ± 2%
324.4 101.325 58.40 ± 2%
345.0 101.325 65.60 ± 2%
368.0 101.325 76.27 ± 2%
413.9 101.325 94.96 ± 2%
425.0 101.325 99.03 ± 2%
Reference


Vapor in Gas

T [K] p [kPa] D · 107 [m2/s]
302.0 101.325 50.90 ± 2%
345.0 101.325 69.61 ± 2%
368.0 101.325 78.14 ± 2%
381.0 101.325 84.27 ± 2%
396.0 101.325 90.45 ± 2%
425.0 101.325 101.2 ± 2%
Reference

Diffusion of oct-1-ene (1); air (2) 1
Diffusion of oct-1-ene (1); air (2)

Vapor in Gas
C8H16 (1) oct-1-ene 111-66-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
313.15 ± 0.1 101.325 0.0708 ± 0.0012
370.15 ± 0.2 101.325 0.0933 ± 0.012
Reference

Diffusion of trans-1,2-dimethyl-cyclohexane (1); argon (2) 1
Diffusion of trans-1,2-dimethyl-cyclohexane (1); argon (2)

Vapor in Gas
C8H16 (1) trans-1,2-dimethyl-cyclohexane 6876-23-9

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
313.15 ± 0.01 101.325 0.0656
328.15 ± 0.01 101.325 0.0721
343.26 ± 0.01 101.325 0.0780
Reference
1987P2 Park, T., Rettich, T.R., Battino, R., Wilhelm, E.: J. Chem. Eng. Data 32 (1987) 191–193.

Diffusion of cyclooctane (1); argon (2) 1
Diffusion of cyclooctane (1); argon (2)

Vapor in Gas
C8H16 (1) cyclooctane 292-64-8

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
313.15 ± 0.01 101.325 0.0673
328.15 ± 0.01 101.325 0.0730
343.15 ± 0.01 101.325 0.0780
Reference

Diffusion of cyclooctane (1); methane (2) 1
Diffusion of cyclooctane (1); methane (2)

Vapor in Gas

CH4 (2) methane 74-82-8
T [K] p [kPa] D · 104 [m2/s]
313.30 ± 0.01 101.325 0.0826
328.16 ± 0.01 101.325 0.0900
343.33 ± 0.01 101.325 0.0972
Reference

Diffusion of trans-1,2-dimethyl-cyclohexane (1); methane (2) 1
Diffusion of trans-1,2-dimethyl-cyclohexane (1); methane

(2)
Vapor in Gas

CH4 (2) methane 74-82-8
T [K] p [kPa] D · 104 [m2/s]
313.30 ± 0.01 101.325 0.0818
328.16 ± 0.01 101.325 0.0903
343.33 ± 0.01 101.325 0.0962
Reference

Diffusion of trans-1,2-dimethyl-cyclohexane (1); sulfur hexafluoride (2) 1
Diffusion of trans-1,2-dimethyl-cyclohexane (1); sulfur

hexafluoride (2)
Vapor in Gas

T [K] p [kPa] D · 104 [m2/s]
313.15 ± 0.01 101.325 0.0294
328.14 ± 0.01 101.325 0.0316
343.29 ± 0.01 101.325 0.0346
Reference

Diffusion of cyclooctane (1); sulfur hexafluoride (2) 1
Diffusion of cyclooctane (1); sulfur hexafluoride (2)

Vapor in Gas

T [K] p [kPa] D · 104 [m2/s]
313.15 ± 0.01 101.325 0.0298
328.14 ± 0.01 101.325 0.0319
343.29 ± 0.01 101.325 0.0355
Reference

Diffusion of cyclooctane (1); helium (2) 1
Diffusion of cyclooctane (1); helium (2)

Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
328.15 ± 0.01 101.325 0.2934
343.36 ± 0.01 101.325 0.3192
Reference

Diffusion of trans-1,2-dimethyl-cyclohexane (1); helium (2) 1
Diffusion of trans-1,2-dimethyl-cyclohexane (1); helium (2)

Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
313.17 ± 0.01 101.325 0.2615
328.15 ± 0.01 101.325 0.2857
343.36 ± 0.01 101.325 0.3000
Reference

Diffusion of isobutyric acid isobutyl ester (1); air (2) 1
Diffusion of isobutyric acid isobutyl ester (1); air (2)

Vapor in Gas
C8H16O2 (1) isobutyric acid isobutyl ester 97-85-8

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 5.51 ± 0.179
Reference

Diffusion of pentanoic acid propyl ester (1); air (2) 1
Diffusion of pentanoic acid propyl ester (1); air (2)

Vapor in Gas
C8H16O2 (1) pentanoic acid propyl ester 141-06-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 5.56 ± 0.065
Reference

Diffusion of butyric acid isobutyl ester (1); air (2) 1
Diffusion of butyric acid isobutyl ester (1); air (2)

Vapor in Gas
C8H16O2 (1) butyric acid isobutyl ester 539-90-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 5.59 ± 0.069
Reference

Diffusion of propionic acid pentyl ester (1); air (2) 1
Diffusion of propionic acid pentyl ester (1); air (2)

Vapor in Gas
C8H16O2 (1) propionic acid pentyl ester 624-54-4

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 5.59 ± 0.070
Reference

Diffusion of 2,2,4-trimethyl-pentane (1); air (2) 1
Diffusion of 2,2,4-trimethyl-pentane (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
297.35 101.325 0.0678 ± 0.0009
298.25 101.325 0.0653 ± 0.0005
Reference

Diffusion of octane (1); air (2) 1
Diffusion of octane (1); air (2)

Vapor in Gas
C8H18 (1) octane 111-65-9

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.2 101.325 6.26
313.2 101.325 7.06
323.2 101.325 7.12
333.2 101.325 7.80
348.2 101.325 8.02
353.2 101.325 8.80
373.2 101.325 8.95
C8H18 (1) octane 111-65-9

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
293.15 101.325 0.0550
C8H18 (1) octane 111-65-9

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
292.65 101.325 0.085
C8H18 (1) octane 111-65-9

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.16 ± 0.169
References

Diffusion of octane (1); argon (2) 1
Diffusion of octane (1); argon (2)

Vapor in Gas
C8H18 (1) octane 111-65-9

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 107 [m2/s]
293.2 101.325 53.7 ± 2%
301.0 101.325 55.37 ± 2%
303.0 101.325 62.6*
303.2 101.325 58.7*
323.0 101.325 67.13 ± 2%
333.2 101.325 68.98 ± 2%
333.6 101.325 68.88 ± 2%
353.0 101.325 81.27 ± 2%
353.2 101.325 72.2*
383.0 101.325 89.94 ± 2%
403.0 101.325 101.6 ± 2%
423.0 101.325 112.6 ± 2%
443.0 101.325 120.1 ± 2%
Reference

Diffusion of 2,2,4-trimethyl-pentane (1); argon (2) 1
Diffusion of 2,2,4-trimethyl-pentane (1); argon (2)

Vapor in Gas

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 107 [m2/s]
301.0 101.325 57.97 ± 2%
303.2 101.325 61.8*
303.4 101.325 59.9 ± 2%
323.0 101.325 69.44 ± 2%
353.0 101.325 82.16 ± 2%
382.8 101.325 92.38 ± 2%
383.0 101.325 93.74 ± 2%
403.0 101.325 104.6 ± 2%
423.0 101.325 112.5 ± 2%
Reference

Diffusion of octane (1); carbon dioxide (2) 1
Diffusion of octane (1); carbon dioxide (2)

Vapor in Gas
C8H18 (1) octane 111-65-9

T [K] p [kPa] D · 107 [m2/s]
302.0 101.325 44.41 ± 2%
345.0 101.325 59.72 ± 2%
368.0 101.325 69.08 ± 2%
381.0 101.325 72.98 ± 2%
396.0 101.325 77.10 ± 2%
425.0 101.325 92.99 ± 2%
Reference

Diffusion of 2,2,4-trimethyl-pentane (1); helium (2) 1
Diffusion of 2,2,4-trimethyl-pentane (1); helium (2)

Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
373.15 ± 0.1 101.325 0.3455 ± 0.0011
Reference
1973G5 Grushka, E., Maynard, V.R.: J. Phys. Chem. 77 (1973) 1437–1442.

Diffusion of octane (1); helium (2) 1
Diffusion of octane (1); helium (2)

Vapor in Gas
C8H18 (1) octane 111-65-9

He (2) helium 7440-59-7
T [K] p [MPa] D · 107 [m2/s]
370.2 0.100 320.3
370.2 0.149 202.4
370.2 0.223 139.8
370.2 0.406 81.45
370.2 0.657 53.46
370.2 0.977 34.92
392.0 0.101 336.5
392.0 0.180 180.5
392.0 0.346 106.8
392.0 0.406 88.23
392.0 0.671 54.65
392.0 0.976 38.89
392.0 1.39 26.50
423.2 0.101 391.4
423.2 0.148 249.6
423.2 0.286 135.5
423.2 0.405 103.5
423.2 0.794 50.38
423.2 0.985 47.79
423.2 1.38 32.61
C8H18 (1) octane 111-65-9

He (2) helium 7440-59-7
T [K] p [kPa] D · 107 [m2/s]
290.4 101.325 193 ± 2%
323.2 101.325 240.1 ± 2%
353.2 101.325 296.9 ± 2%
373.2 101.325 320.3 ± 2%
392.0 101.325 336.5 ± 2%
423.2 101.325 391.4 ± 2%
435.0 101.325 412.2 ± 2%
447.0 101.325 432.4 ± 2%

2 Diffusion of octane (1); helium (2)
C8H18 (1) octane 111-65-9

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
373.15 ± 0.1 101.325 0.3161 ± 0.0033
References

Diffusion of 3-methyl-heptane (1); helium (2) 1
Diffusion of 3-methyl-heptane (1); helium (2)

Vapor in Gas
C8H18 (1) 3-methyl-heptane 589-81-1

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
373.15 ± 0.1 101.325 0.3334 ± 0.0009
Reference

Diffusion of 2,4-dimethyl-hexane (1); helium (2) 1
Diffusion of 2,4-dimethyl-hexane (1); helium (2)

Vapor in Gas
C8H18 (1) 2,4-dimethyl-hexane 589-43-5

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
373.15 ± 0.1 101.325 0.3340 ± 0.0008
Reference

Diffusion of 3-ethyl-hexane (1); helium (2) 1
Diffusion of 3-ethyl-hexane (1); helium (2)

Vapor in Gas
C8H18 (1) 3-ethyl-hexane 619-99-8

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
373.15 ± 0.1 101.325 0.3363 ± 0.0007
Reference

Diffusion of 3-ethyl-2-methyl-pentane (1); helium (2) 1
Diffusion of 3-ethyl-2-methyl-pentane (1); helium (2)

Vapor in Gas
C8H18 (1) 3-ethyl-2-methyl-pentane 609-26-7

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
373.15 ± 0.1 101.325 0.3398 ± 0.0004
Reference

Diffusion of 2,3-dimethyl-hexane (1); helium (2) 1
Diffusion of 2,3-dimethyl-hexane (1); helium (2)

Vapor in Gas
C8H18 (1) 2,3-dimethyl-hexane 584-94-1

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
373.15 ± 0.1 101.325 0.3420 ± 0.0006
Reference

Diffusion of octan-1-ol (1); air (2) 1
Diffusion of octan-1-ol (1); air (2)

Vapor in Gas
C8H18O (1) octan-1-ol 111-87-5

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 5.06 ± 0.057
Reference

Diffusion of dibutyl ether (1); air (2) 1
Diffusion of dibutyl ether (1); air (2)

Vapor in Gas
C8H18O (1) dibutyl ether 142-96-1

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 5.36 ± 0.049
Reference

Diffusion of diphosphoric acid tetraethyl ester (1); air (2) 1
Diffusion of diphosphoric acid tetraethyl ester (1); air (2)

Vapor in Gas
C8H20O7P2 (1) diphosphoric acid tetraethyl ester 107-49-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 4.75 ± 0.030
Reference

Diffusion of octamethyl-cyclotetrasiloxane (1); air (2) 1
Diffusion of octamethyl-cyclotetrasiloxane (1); air (2)

Vapor in Gas
C8H24O4Si4 (1) octamethyl-cyclotetrasiloxane 556-67-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
313.15 ± 0.005 101.325 3.724 ± 0.5%
328.14 ± 0.005 101.325 4.288 ± 0.5%
342.78 ± 0.005 101.325 4.717 ± 0.5%
Reference

Diffusion of 2,4-diisocyanato-1-methyl-benzene (1); air (2) 1
Diffusion of 2,4-diisocyanato-1-methyl-benzene (1); air (2)

Vapor in Gas
C9H6N2O2 (1) 2,4-diisocyanato-1-methyl-benzene 584-84-9

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 5.83 ± 0.038
Reference

Diffusion of acetic acid benzyl ester (1); air (2) 1
Diffusion of acetic acid benzyl ester (1); air (2)

Vapor in Gas
C9H10O2 (1) acetic acid benzyl ester 140-11-4

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.00 ± 0.016
Reference

Diffusion of propylbenzene (1); air (2) 1
Diffusion of propylbenzene (1); air (2)

Vapor in Gas
C9H12 (1) propylbenzene 103-65-1

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.69 ± 0.098
Reference

Diffusion of 1,2,4-trimethyl-benzene (1); air (2) 1
Diffusion of 1,2,4-trimethyl-benzene (1); air (2)

Vapor in Gas
C9H12 (1) 1,2,4-trimethyl-benzene 95-63-6

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.42 ± 0.029
Reference

Diffusion of 1,3,5-trimethyl-benzene (1); air (2) 1
Diffusion of 1,3,5-trimethyl-benzene (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.63 ± 0.064
Reference

Diffusion of 1-methylethyl-benzene (1); air (2) 1
Diffusion of 1-methylethyl-benzene (1); air (2)

Vapor in Gas
C9H12 (1) 1-methylethyl-benzene 98-82-8

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.77 ± 0.056
Reference

Diffusion of 3,5,5-trimethyl-cyclohex-2-enone (1); air (2) 1
Diffusion of 3,5,5-trimethyl-cyclohex-2-enone (1); air (2)

Vapor in Gas
C9H14O (1) 3,5,5-trimethyl-cyclohex-2-enone 78-59-1

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.02 ± 0.019
Reference

Diffusion of butyric acid pentyl ester (1); air (2) 1
Diffusion of butyric acid pentyl ester (1); air (2)

Vapor in Gas
C9H18O2 (1) butyric acid pentyl ester 540-18-1

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 4.86 ± 0.112
Reference

Diffusion of pentanoic acid isobutyl ester (1); air (2) 1
Diffusion of pentanoic acid isobutyl ester (1); air (2)

Vapor in Gas
C9H18O2 (1) pentanoic acid isobutyl ester 10588-10-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 4.94 ± 0.097
Reference

Diffusion of isobutyric acid pentyl ester (1); air (2) 1
Diffusion of isobutyric acid pentyl ester (1); air (2)

Vapor in Gas
C9H18O2 (1) isobutyric acid pentyl ester 2445-72-9

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 4.96 ± 0.078
Reference

Diffusion of nonane (1); air (2) 1
Diffusion of nonane (1); air (2)

Vapor in Gas
C9H20 (1) nonane 111-84-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.2 101.325 5.65
313.2 101.325 6.21
323.2 101.325 6.40
333.2 101.325 7.08
343.2 101.325 7.23
353.2 101.325 7.88
373.2 101.325 8.07
413.2 101.325 10.35
423.2 101.325 10.67
C9H20 (1) nonane 111-84-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
292.85 101.325 0.089
References

Diffusion of nonane (1); argon (2) 1
Diffusion of nonane (1); argon (2)

Vapor in Gas
C9H20 (1) nonane 111-84-2

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 107 [m2/s]
301.0 101.325 51.33 ± 2%
323.0 101.325 62.01 ± 2%
353.0 101.325 74.15 ± 2%
383.0 101.325 84.01 ± 2%
403.0 101.325 93.96 ± 2%
423.0 101.325 102.1 ± 2%
Reference

Diffusion of nonane (1); carbon dioxide (2) 1
Diffusion of nonane (1); carbon dioxide (2)

Vapor in Gas
C9H20 (1) nonane 111-84-2

T [K] p [kPa] D · 107 [m2/s]
302.0 101.325 42.41 ± 2%
323.0 101.325 50.01 ± 2%
345.0 101.325 57.60 ± 2%
368.0 101.325 66.41 ± 2%
381.0 101.325 71.79 ± 2%
396.0 101.325 75.99 ± 2%
425.0 101.325 86.84 ± 2%
Reference

Diffusion of nonane (1); helium (2) 1
Diffusion of nonane (1); helium (2)

Vapor in Gas
C9H20 (1) nonane 111-84-2

He (2) helium 7440-59-7
T [K] p [MPa] D · 107 [m2/s]
370.2 0.149 190.6
370.2 0.266 112.1
370.2 0.570 55.7
370.2 1.018 31.03
392.2 0.101 321.1
392.2 0.201 157.6
392.2 0.457 72.24
392.2 0.921 38.47
423.2 0.101 359.0
423.2 0.286 129.0
423.2 0.575 67.36
423.2 1.05 39.25
Reference
1996S9 Shekurov, V.N., Semenov, A.V., Berezhnoi, A.N.: Zh. Fiz. Khim. 70 (1996) 53–56.

Diffusion of naphthalene (1); air (2) 1
Diffusion of naphthalene (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 101.325 8.36 ± 1.02
313.15 101.325 9.02 ± 0.67

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.0677 ± 3.12%
303.15 101.325 0.0701 ± 3.12%

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
303.2 101.325 0.086 ± 4.1%
References
1996C4 Chen, P.-H., Miao, J.-M., Jian, C.-S.: Rev. Sci. Instrum. 67 (1996) 2831–2836.
1984C1 Caldwell, L.: J. Chem. Eng. Data 29 (1984) 60–62.


Vapor in Gas

Diffusion of gas(1) in gas(2): D*12(T ); Method: STEFAN Ref.: 1975V2
T [K] p [atm] D · 107 [m2/s]
313.15 5.92 7.9 ± 10%
313.15 8.8 5.4 ± 10%
313.15 9.78 4.7 ± 10%
313.15 14.7 3.3 ± 10%
313.15 22.5 1.8 ± 10%
313.15 28.0 1.3 ± 10%
313.15 32.2 1.2 ± 10%
313.15 44.8 0.75 ± 10%

Diffusion of gas(1) in gas(2): D*12(T ); Method: OEC Ref.: 1964I1
T [K] p [atm] D · 108 [m2/s]
308.15 82.0 1.53
308.15 84.5 1.26
308.15 88.0 1.14
308.15 100 1.09
308.15 135 0.94
308.15 200 0.87
308.15 300 0.77

T [K] p [atm] D · 108 [m2/s]
318.15 109 1.27
318.15 118 1.13
318.15 130 1.07
318.15 152 1.00
318.15 200 0.94
318.15 280 0.79
328.15 115 1.68
328.15 120 1.50
328.15 132 1.13
328.15 150 1.07
238.15 164 1.02
328.15 200 0.89

2 Diffusion of naphthalene (1); carbon dioxide (2)

Diffusion of gas(1) in gas(2): D*12(T ); Method: GC Ref.: 1995L6
T [K] p [atm] D · 108 [m2/s]
300.9 82.5 1.095
300.9 94.0 1.026
300.9 148.6 0.687
308.2 82.5 1.956
308.2 94.0 1.690
308.2 148.6 0.832

T [K] p [atm] D · 107 [m2/s]
293.15 6.85 4.8 ± 5%
293.15 12.8 2.5 ± 5%
293.15 20.6 1.43 ± 5%
293.15 28.4 0.98 ± 5%
293.15 30.0 0.94 ± 5%
293.15 36.1 0.72 ± 5%
293.15 40.0 0.59 ± 5%
293.15 44.8 0.47 ± 5%
293.15 49.7 0.42 ± 5%
293.15 55.5 0.32 ± 5%

T [K] p [atm] D · 107 [m2/s]
303.15 5.70 6.6 ± 10%
303.15 10.8 3.4 ± 10%
303.15 15.9 2.3 ± 10%
303.15 20.3 1.6 ± 10%
303.15 28.0 1.1 ± 10%
303.15 36.0 0.81 ± 10%

Diffusion of gas(1) in gas(2): D*12(T ); Method: OEC Ref.: 1971T7
T [K] ρ [g/cm3] D · 109 [m2/s]
308.15 ± 0.005 0.250 4.8 ± 0.2
308.15 ± 0.005 0.350 1.4 ± 0.3
(continued)

308.15 ± 0.005 0.460 0.06 ± 0.3

308.15 ± 0.005 0.560 3.6 ± 0.3
308.15 ± 0.005 0.592 6.9 ± 0.2
Comment: diffusion near the liquid-gas critical point at ρ = 0.460 g/cm3
References
1975V2 Vinkler, E.G., Morozov, V.S.: Zh. Fiz. Khim. 49 (1975) 2398–2400.
1964I1 Iomtev, M.B., Tsekhanskaya, Y.V.: Zh. Fiz. Khim. 38 (1964) 896–900.
1995L6 Lee, C.H., Holder, G.D.: Ind. Eng. Chem. Res. 34 (1995) 906–914.
1971T7 Tsekhanskaya, Yu.: Russ. J. Phys. Chem. 45 (1971) 744.

Diffusion of naphthalene (1); ethene (2) 1
Diffusion of naphthalene (1); ethene (2)

Vapor in Gas

C2H4 (2) ethene 74-85-1
T [K] p [atm] D · 108 [m2/s]
285.15 65.0 1.82
285.15 75.0 1.70
285.15 80.0 1.60
285.15 90.0 1.51
285.15 109 1.38
285.15 145 1.27
285.15 190 1.05
285.15 240 0.95
285.15 300 0.84
308.15 80.0 3.20
308.15 90.0 2.30
308.15 100 2.14
308.15 109 1.86
308.15 145 1.46
308.15 190 1.33
Reference
1964I1 Iomtev, M.B., Tsekhanskaya, Y.V.: Zh. Fiz. Khim. 38 (1964) 896–900.

Diffusion of naphthalene (1); hydrogen (2) 1
Diffusion of naphthalene (1); hydrogen (2)

Vapor in Gas

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
303.2 101.325 0.301 ± 4.1%
Reference
1984C1 Caldwell, L.: J. Chem. Eng. Data 29 (1984) 60–62.

Diffusion of naphthalene (1); nitrogen (2) 1
Diffusion of naphthalene (1); nitrogen (2)

Vapor in Gas

N2 (2) nitrogen 7727-37-9
T [K] p [atm] D · 107 [m2/s]
303.15 3.40 18.5 ± 5%
303.15 8.72 7.3 ± 5%
303.15 10.6 5.9 ± 5%
303.15 15.4 4.1 ± 5%
303.15 20.3 3.0 ± 5%
303.15 25.1 2.55 ± 5%
303.15 30.6 2.12 ± 5%
303.15 35.0 1.71 ± 5%
303.15 39.3 1.56 ± 5%
303.15 39.9 1.55 ± 5%
303.15 54.5 1.19 ± 5%
303.15 64.1 1.01 ± 5%
303.15 73.7 0.90 ± 5%
303.15 83.4 0.81 ± 5%

N2 (2) nitrogen 7727-37-9
T [K] p [atm] D · 107 [m2/s]
313.15 2.15 31.6 ± 5%
313.15 2.92 23.3 ± 5%
313.15 3.33 20.1 ± 5%
313.15 5.82 10.8 ± 5%
313.15 8.7 7.5 ± 5%
313.15 12.8 5.1 ± 5%
313.15 18.7 3.74 ± 5%
313.15 24.6 2.72 ± 5%
313.15 30.6 2.22 ± 5%
313.15 39.3 1.73 ± 5%
313.15 42.2 1.56 ± 5%
313.15 47.0 1.40 ± 5%
313.15 53.8 1.28 ± 5%
313.15 54.5 1.26 ± 5%
313.15 62.5 1.14 ± 5%
313.15 93.5 0.72 ± 5%
313.15 123.8 0.58 ± 5%

2 Diffusion of naphthalene (1); nitrogen (2)

N2 (2) nitrogen 7727-37-9
T [K] p [atm] D · 106 [m2/s]
298.15 3.33 1.86
298.15 1.00 6.2 ± 0.2
References
1975V2 Vinkler, E.G., Morozov, V.S.: Zh. Fiz. Khim. 49 (1975) 2398–2400.
1975M12 Morozov, V.S., Vinkler, E.G.: Russ. J. Phys. Chem. 49 (1975) 1404–1405.

Diffusion of 1-isopropyl-4-methyl-benzene (1); air (2) 1
Diffusion of 1-isopropyl-4-methyl-benzene (1); air (2)

Vapor in Gas
C10H14 (1) 1-isopropyl-4-methyl-benzene 99-87-6

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 6.30 ± 0.028
Reference

Diffusion of decane (1); air (2) 1
Diffusion of decane (1); air (2)

Vapor in Gas
C10H22 (1) decane 124-18-5

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
313.05 ± 0.1 101.325 0.0606 ± 0.0046
333.65 ± 0.1 101.325 0.0686 ± 0.0010
359.55 ± 0.1 101.325 0.0771 ± 0.0051
359.55 ± 0.1 101.325 0.0790 ± 0.0060
359.55 ± 0.1 101.325 0.0810 ± 0.0033
359.55 ± 0.1 101.325 0.0765 ± 0.0016
359.55 ± 0.1 101.325 0.0760 ± 0.0006
359.55 ± 0.1 101.325 0.0771 ± 0.0016
359.55 ± 0.1 101.325 0.0758 ± 0.0014
391.15 ± 0.2 101.325 0.0864 ± 0.0007
422.25 ± 0.2 101.325 0.0920 ± 0.0013
422.25 ± 0.2 101.325 0.0937 ± 0.0012
C10H22 (1) decane 124-18-5

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
323.2 101.325 6.03
333.2 101.325 6.38
348.2 101.325 6.80
353.2 101.325 7.08
373.2 101.325 7.58
References

Diffusion of decane (1); carbon dioxide (2) 1
Diffusion of decane (1); carbon dioxide (2)

Vapor in Gas
C10H22 (1) decane 124-18-5

T [K] p [kPa] D · 107 [m2/s]
301.2 101.325 36.00 ± 2%
344.6 101.325 49.64 ± 2%
369.9 101.325 59.10 ± 2%
396.2 101.325 67.38 ± 2%
424.0 101.325 75.99 ± 2%
443.2 101.325 83.79 ± 2%
C10H22 (1) decane 124-18-5

T [K] p [MPa] D · 107 [m2/s]
370.2 0.100 260.0
370.2 0.135 196.3
370.2 0.246 102.6
370.2 0.448 65.81
370.2 0.647 47.70
370.2 0.957 32.60
392.0 0.101 284.2
392.0 0.177 163.2
392.0 0.246 123.5
392.0 0.343 90.51
392.0 0.664 47.20
392.0 0.957 36.21
423.2 0.101 335.9
423.2 0.135 247.1
423.2 0.246 142.4
423.2 0.448 82.77
423.2 1.01 39.61
423.2 1.39 29.14
References

Diffusion of decane (1); nitrogen (2) 1
Diffusion of decane (1); nitrogen (2)

Vapor in Gas
C10H22 (1) decane 124-18-5

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
364.6 101.325 0.0841 ± 0.0017
C10H22 (1) decane 124-18-5

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 106 [m2/s]
344.2 101.325 6.75
362.7 101.325 7.66
373.2 101.325 8.15
393.2 101.325 9.03
403.2 101.325 9.48
423.2 101.325 10.37
References

Diffusion of 1-(1,1-dimethyl-ethyl)-4-methyl-benzene (1); air (2) 1
Diffusion of 1-(1,1-dimethyl-ethyl)-4-methyl-benzene (1);

air (2)
Vapor in Gas
C11H16 (1) 1-(1,1-dimethyl-ethyl)-4-methyl-benzene 98-51-1

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 5.71 ± 0.031
Reference

Diffusion of undecane (1); air (2) 1
Diffusion of undecane (1); air (2)

Vapor in Gas
C11H24 (1) undecane 1120-21-4

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
323.2 101.325 6.16
353.2 101.325 6.72
Reference

Diffusion of acenaphthylene (1); air (2) 1
Diffusion of acenaphthylene (1); air (2)

Vapor in Gas
C12H8 (1) acenaphthylene 208-96-8

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 101.325 6.07 ± 0.12
313.15 101.325 6.69 ± 0.19
Reference

Diffusion of phthalic acid diethyl ester (1); air (2) 1
Diffusion of phthalic acid diethyl ester (1); air (2)

Vapor in Gas
C12H14O4 (1) phthalic acid diethyl ester 84-66-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 4.97 ± 0.033
Reference

Diffusion of dodecane (1); air (2) 1
Diffusion of dodecane (1); air (2)

Vapor in Gas
C12H26 (1) dodecane 112-40-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
333.2 101.325 5.69
353.2 101.325 6.09
Reference

Diffusion of phosphoric acid tributyl ester (1); air (2) 1
Diffusion of phosphoric acid tributyl ester (1); air (2)

Vapor in Gas
C12H27O3P (1) phosphoric acid tributyl ester 102-85-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 4.32 ± 0.044
Reference

Diffusion of anthracene (1); air (2) 1
Diffusion of anthracene (1); air (2)

Vapor in Gas
C14H10 (1) anthracene 120-12-7

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
273.15 101.325 5.91 ± 0.09
283.15 101.325 6.39 ± 0.16
298.15 101.325 6.69 ± 0.06
313.15 101.325 8.04 ± 0.22
Reference

Diffusion of phenanthrene (1); air (2) 1
Diffusion of phenanthrene (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
283.15 101.325 6.10 ± 0.27
298.15 101.325 6.54 ± 0.24
313.15 101.325 7.78 ± 0.15
Reference

Diffusion of pyrene (1); air (2) 1
Diffusion of pyrene (1); air (2)

Vapor in Gas
C16H10 (1) pyrene 129-00-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
273.15 101.325 6.24 ± 0.06
283.15 101.325 6.97 ± 0.21
298.15 101.325 6.68 ± 0.05
313.15 101.325 7.76 ± 0.08
Reference

Diffusion of phthalic acid dibutyl ester (1); air (2) 1
Diffusion of phthalic acid dibutyl ester (1); air (2)

Vapor in Gas
C16H22O4 (1) phthalic acid dibutyl ester 84-74-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 4.21 ± 0.042
Reference

Diffusion of phthalic acid dibutyl ester (1); nitrogen (2) 1
Diffusion of phthalic acid dibutyl ester (1); nitrogen (2)

Vapor in Gas
C16H22O4 (1) phthalic acid dibutyl ester 84-74-2

N2 (2) nitrogen 7727-37-9
Diffusion of gas(1) in gas(2): D*12(T ); Method: POINT Ref.: 1979R5
T [K] p [kPa] D · 106 [m2/s]
298.15 101.325 3.67
Comment: method: droplet evaporation rate
Reference
1979R5 Ravindran, P., Davis, E.J., Ray, A.K.: AIChE J. 25 (1979) 966–975.

Diffusion of bis-(2-ethylhexyl) phosphate (1); air (2) 1
Diffusion of bis-(2-ethylhexyl) phosphate (1); air (2)

Vapor in Gas
C16H35O4P (1) bis-(2-ethylhexyl) phosphate 298-07-7

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 3.94 ± 0.046
Reference

Diffusion of 1,2-benzanthracene (1); air (2) 1
Diffusion of 1,2-benzanthracene (1); air (2)

Vapor in Gas
C18H12 (1) 1,2-benzanthracene 56-55-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
283.15 101.325 7.18 ± 0.60
298.15 101.325 7.22 ± 0.49
313.15 101.325 7.93 ± 0.12
Reference

Diffusion of decanedioic acid dibutyl ester (1); carbon dioxide (2) 1
Diffusion of decanedioic acid dibutyl ester (1); carbon

dioxide (2)
Vapor in Gas
C18H34O4 (1) decanedioic acid dibutyl ester 109-43-3

T [K] p [kPa] D · 106 [m2/s]
298.15 101.325 1.95
Reference

Diffusion of decanedioic acid dibutyl ester (1); helium (2) 1
Diffusion of decanedioic acid dibutyl ester (1); helium (2)

Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 106 [m2/s]
298.15 101.325 13.6
Reference

Diffusion of decanedioic acid dibutyl ester (1); nitrogen (2) 1
Diffusion of decanedioic acid dibutyl ester (1); nitrogen (2)

Vapor in Gas

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 106 [m2/s]
298.15 101.325 3.02
Reference

Diffusion of 4,5-benzopyrene (1); air (2) 1
Diffusion of 4,5-benzopyrene (1); air (2)

Vapor in Gas
C20H12 (1) 4,5-benzopyrene 192-97-2

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 101.325 6.28 ± 0.28
Reference

Diffusion of tricresyl phosphate (1); air (2) 1
Diffusion of tricresyl phosphate (1); air (2)

Vapor in Gas
C21H21O4P (1) tricresyl phosphate 1330-78-5

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 4.38 ± 0.116
Reference

Diffusion of phthalic acid diisooctyl ester (1); air (2) 1
Diffusion of phthalic acid diisooctyl ester (1); air (2)

Vapor in Gas
C24H38O4 (1) phthalic acid diisooctyl ester 27554-26-3

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 3.37 ± 0.060
Reference

Diffusion of phthalic acid bis-(2-ethyl-hexyl) ester (1); carbon dioxide (2) 1
Diffusion of phthalic acid bis-(2-ethyl-hexyl) ester (1);

carbon dioxide (2)
Vapor in Gas
C24H38O4 (1) phthalic acid bis-(2-ethyl-hexyl) ester 117-81-7

T [K] p [kPa] D · 106 [m2/s]
298.15 101.325 1.98
Reference

Diffusion of phthalic acid bis-(2-ethyl-hexyl) ester (1); helium (2) 1

helium (2)
Vapor in Gas

He (2) helium 7440-59-7
T [K] p [kPa] D · 106 [m2/s]
298.15 101.325 13.2
Reference

Diffusion of phthalic acid bis-(2-ethyl-hexyl) ester (1); nitrogen (2) 1

nitrogen (2)
Vapor in Gas

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 106 [m2/s]
298.15 101.325 3.08
Reference

Diffusion of chlorine (1); argon (2) 1
Diffusion of chlorine (1); argon (2)

Vapor in Gas
Cl2 (1) chlorine 7782-50-5

Ar (2) argon 7440-37-1
Diffusion of gas(1) in gas(2): D*12(T ); Method: No Stand Ref.: 1978J2
T [K] p [kPa] D · 104 [m2/s]
295 101.325 0.26 ± 0.05
Comment: chlorine atoms diffusing in Ar
Reference
1978J2 Judeikis, H.S., Wun, M.: J. Chem. Phys. 68 (1978) 4123–4127.

Diffusion of hydrogen-deuterium (1); deuterium (2) 1
Diffusion of hydrogen-deuterium (1); deuterium (2)

Vapor in Gas

D2 (2) deuterium 7782-39-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: CT Ref.: 1970M10
T [K] p [kPa] D · 104 [m2/s]
297.15 101.325 1.126 ± 0.011
Reference
1970M10 Müller, K.P., Klemm, A.: Z. Naturforsch. A 25 (1970) 243–246.

Diffusion of deuterium (1); air (2) 1
Diffusion of deuterium (1); air (2)

Vapor in Gas
D2 (1) deuterium 7782-39-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
296.8 101.325 0.565
D2 (1) deuterium 7782-39-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
296.8 101.325 0.565 ± 0.005
D2 (1) deuterium 7782-39-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
296.8 101.325 0.565 ± 0.005
References

Diffusion of deuterium (1); argon (2) 1
Diffusion of deuterium (1); argon (2)

Vapor in Gas
D2 (1) deuterium 7782-39-0

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
296.8 101.325 0.575 ± 0.005
D2 (1) deuterium 7782-39-0

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
296.8 101.325 0.575
D2 (1) deuterium 7782-39-0

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
296.8 101.325 0.575 ± 0.005
References

Diffusion of deuterium (1); carbon monoxide (2) 1
Diffusion of deuterium (1); carbon monoxide (2)

Vapor in Gas

T [K] p [kPa] D · 104 [m2/s]
295.7 101.325 0.549

T [K] p [kPa] D · 104 [m2/s]
295.7 101.325 0.549 ± 0.005

T [K] p [kPa] D · 104 [m2/s]
295.7 101.325 0.549 ± 0.005
References


Vapor in Gas
D2 (1) deuterium 7782-39-0

T [K] p [kPa] D · 104 [m2/s]
295.7 101.325 0.474
D2 (1) deuterium 7782-39-0

T [K] p [kPa] D · 104 [m2/s]
295.7 101.325 0.474 ± 0.004
D2 (1) deuterium 7782-39-0

T [K] p [kPa] D · 104 [m2/s]
295.7 101.325 0.474 ± 0.004
References

Diffusion of deuterium (1); heptane (2) 1
Diffusion of deuterium (1); heptane (2)

Vapor in Gas
D2 (1) deuterium 7782-39-0

C7H16 (2) heptane 142-82-5
T [K] p [kPa] D · 104 [m2/s]
303.2 101.325 0.218
Reference

Diffusion of deuterium (1); 2,4-dimethyl-pentane (2) 1
Diffusion of deuterium (1); 2,4-dimethyl-pentane (2)

Vapor in Gas
D2 (1) deuterium 7782-39-0

T [K] p [kPa] D · 104 [m2/s]
303.2 101.325 0.224
Reference

Diffusion of deuterium (1); 2,2,4-trimethyl-pentane (2) 1
Diffusion of deuterium (1); 2,2,4-trimethyl-pentane (2)

Vapor in Gas
D2 (1) deuterium 7782-39-0

T [K] p [kPa] D · 104 [m2/s]
303.2 101.325 0.212
Reference

Diffusion of deuterium (1); octane (2) 1
Diffusion of deuterium (1); octane (2)

Vapor in Gas
D2 (1) deuterium 7782-39-0

C8H18 (2) octane 111-65-9
T [K] p [kPa] D · 104 [m2/s]
303.2 101.325 0.208
Reference

Diffusion of deuterium (1); hydrogen-deuterium (2) 1
Diffusion of deuterium (1); hydrogen-deuterium (2)

Vapor in Gas
D2 (1) deuterium 7782-39-0

T [K] p [kPa] D
419.37 101.325 0.56877 ± 0.002
398.72 101.325 0.61736 ± 0.002
374.43 101.325 0.68544 ± 0.002
348.68 101.325 0.77318 ± 0.002
324.48 101.325 0.87313 ± 0.002
271.54 101.325 1.1784 ± 0.002
253.56 101.325 1.3214 ± 0.002
237.64 101.325 1.4742 ± 0.002
297 101.325 1.126 · 10-4*
Reference
1974W8 Wahby, S.M., Boerboom, J.H., Los, J.: Physica 74 (1974) 85–96.

Diffusion of deuterium (1); deuterium-tritium (2) 1
Diffusion of deuterium (1); deuterium-tritium (2)

Vapor in Gas
D2 (1) deuterium 7782-39-0

DT (2) deuterium-tritium 14885-61-1
T [K] p [kPa] D · 104 [m2/s]
297.15 101.325 0.989 ± 0.020
D2 (1) deuterium 7782-39-0

Diffusion of gas(1) in gas(2): D*12(T ); Method: CT Ref.: 1965R5
T [K] p [kPa] D · 104 [m2/s]
297.15 101.325 0.989 ± 2%
References
1965R5 Reichenbacher, W., Müller, K.P., Klemm, A.: Z. Naturforsch. A 20 (1965) 1529–1536.

Diffusion of deuterium (1); sulfur hexafluoride (2) 1
Diffusion of deuterium (1); sulfur hexafluoride (2)

Vapor in Gas
D2 (1) deuterium 7782-39-0

T [K] p [kPa] D · 104 [m2/s]
295.7 101.325 0.305 ± 0.002
D2 (1) deuterium 7782-39-0

T [K] p [kPa] D · 104 [m2/s]
295.7 101.325 0.305 ± 0.002
D2 (1) deuterium 7782-39-0

T [K] p [kPa] D · 104 [m2/s]
295.7 101.325 0.305
D2 (1) deuterium 7782-39-0

T [K] p [kPa] D · 104 [m2/s]
222.6 101.325 0.193 ± 1.5%
255.5 101.325 0.246 ± 1.5%
293.8 101.325 0.314 ± 1.5%
380.5 101.325 0.492 ± 1.5%
418.6 101.325 0.587 ± 1.5%
505.1 101.325 0.817 ± 1.5%
562.9 101.325 0.958 ± 1.5%
References

Diffusion of deuterium (1); hydrogen-tritium (2) 1
Diffusion of deuterium (1); hydrogen-tritium (2)

Vapor in Gas
D2 (1) deuterium 7782-39-0

HT (2) hydrogen-tritium 14885-60-0
T [K] p [kPa] D · 104 [m2/s]
297.15 101.325 1.044 ± 2%
D2 (1) deuterium 7782-39-0

T [K] p [kPa] D · 104 [m2/s]
297.15 101.325 1.044 ± 0.021
D2 (1) deuterium 7782-39-0

T [K] p [kPa] D · 104 [m2/s]
194.7 101.325 0.705
273.2 101.325 1.258
References
1965A3 Amdur, I., Beatty, J.W.: J. Chem. Phys. 42 (1965) 3361–3364.

Diffusion of deuterium (1); hydrogen (2) 1
Diffusion of deuterium (1); hydrogen (2)

Vapor in Gas
D2 (1) deuterium 7782-39-0

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
295.5 101.325 1.25 ± 0.02
D2 (1) deuterium 7782-39-0

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
295.5 101.325 1.25 ± 0.02
References

Diffusion of deuterium (1); ammonia (2) 1
Diffusion of deuterium (1); ammonia (2)

Vapor in Gas
D2 (1) deuterium 7782-39-0

H 3N (2) ammonia 7664-41-7
T [K] p [kPa] D · 104 [m2/s]
296.8 101.325 0.630 ± 0.005
D2 (1) deuterium 7782-39-0

H 3N (2) ammonia 7664-41-7
T [K] p [kPa] D · 104 [m2/s]
296.8 101.325 0.630 ± 0.005
D2 (1) deuterium 7782-39-0

H 3N (2) ammonia 7664-41-7
T [K] p [kPa] D · 104 [m2/s]
296.8 101.325 0.630
References

Diffusion of deuterium (1); helium (2) 1
Diffusion of deuterium (1); helium (2)

Vapor in Gas
D2 (1) deuterium 7782-39-0

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
295.1 101.325 1.25 ± 0.01
D2 (1) deuterium 7782-39-0

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
295.1 101.325 1.25 ± 0.01
D2 (1) deuterium 7782-39-0

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
295.1 101.325 1.25
References

Diffusion of deuterium (1); krypton (2) 1
Diffusion of deuterium (1); krypton (2)

Vapor in Gas
D2 (1) deuterium 7782-39-0

Kr (2) krypton 7439-90-9
Integral Diffusion Coefficient: D(T ); Method: TB Ref.: 1964M6
T [K] p [kPa] D · 104 [m2/s]
255 101.325 0.438
255 101.325 0.395
295.8 101.325 0.516
295.8 101.325 0.488
297.6 101.325 0.508
297.6 101.325 0.500
362 101.325 0.758
362 101.325 0.741
Reference
1964M6 Mason, E.A., Islam, M., Weissman, S.: Phys. Fluids 7 (1964) 1011–1022.

Diffusion of deuterium (1); nitrogen (2) 1
Diffusion of deuterium (1); nitrogen (2)

Vapor in Gas
D2 (1) deuterium 7782-39-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
296.8 101.325 0.542 ± 0.005
D2 (1) deuterium 7782-39-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
296.8 101.325 0.542 ± 0.005
D2 (1) deuterium 7782-39-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
296.8 101.325 0.542
References

Diffusion of deuterium (1); neon (2) 1
Diffusion of deuterium (1); neon (2)

Vapor in Gas
D2 (1) deuterium 7782-39-0

Ne (2) neon 7440-01-9
T [K] p [kPa] D · 104 [m2/s]
295.5 101.325 0.866 ± 0.6%
379.0 101.325 1.308 ± 0.6%
484.5 101.325 2.013 ± 0.6%
575.5 101.325 2.688 ± 0.6%
667.0 101.325 3.444 ± 0.6%
D2 (1) deuterium 7782-39-0

Ne (2) neon 7440-01-9
Diffusion of gas(1) in gas(2): D*12(T ); Method: TB Ref.: 1990S1
T [K] p [kPa] D · 104 [m2/s]
115.0 ± 0.3 101.325 0.163 ± 1.5%
155.0 ± 0.3 101.325 0.286 ± 1.5%
197.0 ± 0.3 101.325 0.434 ± 1.5%
232.0 ± 0.3 101.325 0.569 ± 1.5%
295.0 ± 0.3 101.325 0.875 ± 1.5%
References
1975K1 Kalinin, B.A., Suetin, P.E.: Heat Transfer Sov. Res. 7 (1975) 146–150.
1990S1 Saha, P.B., Sanyal, S.K.: J. Indian Chem. Soc. 67 (1990) 245–247.

Diffusion of deuterium (1); tritium (2) 1
Diffusion of deuterium (1); tritium (2)

Vapor in Gas
D2 (1) deuterium 7782-39-0

T2 (2) tritium 10028-17-8
T [K] p [kPa] D · 104 [m2/s]
297.15 101.325 0.956 ± 0.019
D2 (1) deuterium 7782-39-0

T2 (2) tritium 10028-17-8
T [K] p [kPa] D · 104 [m2/s]
297.15 101.325 0.956 ± 2%
D2 (1) deuterium 7782-39-0

T2 (2) tritium 10028-17-8
Diffusion of gas(1) in gas(2): D*12(T ); Method: TB Ref.: 1965A3
T [K] p [kPa] D · 104 [m2/s]
194.7 101.325 0.722
273.2 101.325 1.255
352.8 101.325 1.904
References

Diffusion of methane-d3 (1); argon (2) 1
Diffusion of methane-d3 (1); argon (2)

Vapor in Gas
D3CH (1) methane-d3 676-80-2

Ar (2) argon 7440-37-1
T [K] p [kPa] D
233.17 101.325 1.5777
244.88 101.325 1.4398
261.77 101.325 1.2723
274.43 101.325 1.1643
330.07 101.325 0.8301
352.95 101.325 0.7350
364.20 101.325 0.6944
373.55 101.325 0.6641
385.25 101.325 0.6284
397.29 101.325 0.5946
408.37 101.325 0.5660
421.80 101.325 0.5351
298.15 101.325 0.203 · 10–4*
Reference

Diffusion of methane-d3 (1); neon (2) 1
Diffusion of methane-d3 (1); neon (2)

Vapor in Gas
D3CH (1) methane-d3 676-80-2

Ne (2) neon 7440-01-9
T [K] p [kPa] D
233.17 101.325 1.5176
244.88 101.325 1.3988
261.77 101.325 1.2496
274.43 101.325 1.1531
330.07 101.325 0.8441
352.95 101.325 0.7535
364.20 101.325 0.7151
373.55 101.325 0.6849
385.25 101.325 0.6507
397.29 101.325 0.6181
408.37 101.325 0.5903
421.80 101.325 0.5584
298.15 101.325 0.331 · 10–4*
Reference

Diffusion of methane-d4 (1); methane-d3 (2) 1
Diffusion of methane-d4 (1); methane-d3 (2)

Vapor in Gas
D 4C (1) methane-d4 558-20-3

D3CH (2) methane-d3 676-80-2
T [K] p [kPa] D
233.17 101.325 1.5870
244.88 101.325 1.4450
261.77 101.325 1.2759
274.43 101.325 1.1669
330.07 101.325 0.8298
352.95 101.325 0.7342
364.20 101.325 0.6933
373.55 101.325 0.6631
385.25 101.325 0.6272
397.29 101.325 0.5939
408.37 101.325 0.5655
421.80 101.325 0.5329
298.15 101.325 0.207 · 10–4*
Reference

Diffusion of sulfur hexafluoride (1); air (2) 1
Diffusion of sulfur hexafluoride (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.0985
303.15 101.325 0.100
333.15 101.325 0.116
363.15 101.325 0.135
393.15 101.325 0.154
423.15 101.325 0.177
453.15 101.325 0.191
Reference


Vapor in Gas

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
287.2 ± 0.1 101.325 0.0791 ± 2%
328.0 ± 0.1 101.325 0.100 ± 2%
348.0 ± 0.1 101.325 0.112 ± 2%
373.0 ± 0.1 101.325 0.127 ± 2%
410.0 ± 0.1 101.325 0.151 ± 2%
447.0 ± 0.1 101.325 0.183 ± 2%
472.0 ± 0.1 101.325 0.200 ± 2%

Ar (2) argon 7440-37-1
T [K] p [Torr] D · 104 [m2/s]
298.15 ± 0.05 746 0.0848 ± 0.0004
310.15 ± 0.05 746 0.0908 ± 0.0008
References

Diffusion of sulfur hexafluoride (1); methane (2) 1
Diffusion of sulfur hexafluoride (1); methane (2)

Vapor in Gas

CH4 (2) methane 74-82-8
T [K] p [Torr] D · 104 [m2/s]
298.15 ± 0.05 746 0.1103 ± 0.0004
310.15 ± 0.05 746 0.116 ± 0.002
Reference

Diffusion of sulfur hexafluoride (1); carbon monoxide (2) 1
Diffusion of sulfur hexafluoride (1); carbon monoxide (2)

Vapor in Gas

T [K] p [kPa] D · 104 [m2/s]
296.8 ± 0.1 101.325 0.0887 ± 2%
315.4 ± 0.1 101.325 0.105 ± 2%
348.0 ± 0.1 101.325 0.125 ± 2%
373.4 ± 0.1 101.325 0.144 ± 2%
410.0 ± 0.1 101.325 0.174 ± 2%
455.0 ± 0.1 101.325 0.212 ± 2%
473.0 ± 0.1 101.325 0.222 ± 2%
Reference

Diffusion of sulfur hexafluoride (1); carbon dioxide (2) 1
Diffusion of sulfur hexafluoride (1); carbon dioxide (2)

Vapor in Gas

T [K] p [Torr] D · 104 [m2/s]
298.15 ± 0.05 746 0.0694 ± 0.0019
310.15 ± 0.05 746 0.0764 ± 0.0011
Reference

Diffusion of sulfur hexafluoride (1); hexane (2) 1
Diffusion of sulfur hexafluoride (1); hexane (2)

Vapor in Gas

C6H14 (2) hexane 110-54-3
T [K] p [kPa] D · 104 [m2/s]
283.15 ± 0.002 101.325 0.0285 ± 1%
298.18 ± 0.002 101.325 0.0316 ± 1%
313.16 ± 0.002 101.325 0.0351 ± 1%
328.15 ± 0.002 101.325 0.0380 ± 1%
Reference
1975W1 Wilhelm, E., Battino, R.: J. Chem. Eng. Data 20 (1975) 399–402.

Diffusion of sulfur hexafluoride (1); heptane (2) 1
Diffusion of sulfur hexafluoride (1); heptane (2)

Vapor in Gas

C7H16 (2) heptane 142-82-5
T [K] p [kPa] D · 104 [m2/s]
283.15 ± 0.002 101.325 0.0242 ± 1%
298.18 ± 0.002 101.325 0.0275 ± 1%
313.16 ± 0.002 101.325 0.0311 ± 1%
328.15 ± 0.002 101.325 0.0344 ± 1%
343.11 ± 0.002 101.325 0.0374 ± 1%
Reference

Diffusion of sulfur hexafluoride (1); 2,2,4-trimethyl-pentane (2) 1
Diffusion of sulfur hexafluoride (1); 2,2,4-trimethyl-

pentane (2)
Vapor in Gas

T [K] p [kPa] D · 104 [m2/s]
298.18 ± 0.002 101.325 0.0253 ± 1%
313.16 ± 0.002 101.325 0.0285 ± 1%
328.15 ± 0.002 101.325 0.0308 ± 1%
343.11 ± 0.002 101.325 0.0336 ± 1%
Reference

Diffusion of sulfur hexafluoride (1); octane (2) 1
Diffusion of sulfur hexafluoride (1); octane (2)

Vapor in Gas

C8H18 (2) octane 111-65-9
T [K] p [kPa] D · 104 [m2/s]
283.15 ± 0.002 101.325 0.0219 ± 1%
298.18 ± 0.002 101.325 0.0244 ± 1%
313.16 ± 0.002 101.325 0.0277 ± 1%
328.15 ± 0.002 101.325 0.0311 ± 1%
343.11 ± 0.002 101.325 0.0336 ± 1%
Reference

Diffusion of sulfur hexafluoride (1); hydrogen (2) 1
Diffusion of sulfur hexafluoride (1); hydrogen (2)

Vapor in Gas

H2 (2) hydrogen 1333-74-0
T [K] p [Torr] D · 104 [m2/s]
298.15 ± 0.05 746 0.447 ± 0.007
310.15 ± 0.05 746 0.474 ± 0.006
Reference


Vapor in Gas

He (2) helium 7440-59-7
T [K] p [Torr] D · 104 [m2/s]
298.15 ± 0.05 746 0.388 ± 0.006
310.15 ± 0.05 746 0.423 ± 0.004
Reference

Diffusion of sulfur hexafluoride (1); nitrogen (2) 1
Diffusion of sulfur hexafluoride (1); nitrogen (2)

Vapor in Gas

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
289.8 ± 0.1 101.325 0.104 ± 2%
328.0 ± 0.1 101.325 0.115 ± 2%
348.0 ± 0.1 101.325 0.130 ± 2%
373.0 ± 0.1 101.325 0.147 ± 2%
410.0 ± 0.1 101.325 0.179 ± 2%
455.0 ± 0.1 101.325 0.218 ± 2%
473.0 ± 0.1 101.325 0.231 ± 2%

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.100
303.15 101.325 0.0976
333.15 101.325 0.116
363.15 101.325 0.135
393.15 101.325 0.154
423.15 101.325 0.175
453.15 101.325 0.190

N2 (2) nitrogen 7727-37-9
T [K] p [Torr] D · 104 [m2/s]
298.15 ± 0.05 746 0.0991 ± 0.0020
310.15 ± 0.05 746 0.105 ± 0.002
References

Diffusion of sulfur hexafluoride (1); oxygen (2) 1
Diffusion of sulfur hexafluoride (1); oxygen (2)

Vapor in Gas

O2 (2) oxygen 7782-44-7
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.0967
303.15 101.325 0.0979
303.15 101.325 0.100
333.15 101.325 0.117
363.15 101.325 0.134
393.15 101.325 0.155
423.15 101.325 0.177
423.15 101.325 0.181
423.15 101.325 0.182
453.15 101.325 0.202

O2 (2) oxygen 7782-44-7
T [K] p [Torr] D · 104 [m2/s]
298.15 ± 0.05 746 0.0969 ± 0.0015
310.15 ± 0.05 746 0.0988 ± 0.0010
References

Diffusion of hydrogen atom (1); argon (2) 1
Diffusion of hydrogen atom (1); argon (2)

Vapor in Gas

Ar (2) argon 7440-37-1
Diffusion of gas(1) in gas(2): D*12(T ); Method: No Stand Ref.: 1982C3
T [K] p [kPa] D · 104 [m2/s]
294.0 101.325 1.61 ± 0.04
Reference
1982C3 Clifford, A.A., Gray, P., Mason, R.S., Waddicor, J.I.: Proc. R. Soc. A 380 (1982) 241–258.

Diffusion of hydrogen atom (1); hydrogen (2) 1
Diffusion of hydrogen atom (1); hydrogen (2)

Vapor in Gas

H2 (2) hydrogen 1333-74-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: CC Ref.: 1961W2
T [K] p [kPa] D · 104 [m2/s]
293.0 101.325 1.80
349.0 101.325 2.32
372.0 101.325 3.00
375.0 101.325 2.55
422.0 101.325 3.17
455.0 101.325 40.5
498.0 101.325 3.85
518.0 101.325 4.68
666.0 101.325 5.58
719.0 101.325 7.38

H2 (2) hydrogen 1333-74-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: CC Ref.: 1969S5
T [K] p [kPa] D · 104 [m2/s]
293.0 ± 3.0 101.325 1.80 ± 0.13
349.0 ± 3.0 101.325 2.32 ± 0.13
372.0 ± 3.0 101.325 3.01 ± 0.13
375.0 ± 3.0 101.325 2.56 ± 0.13
422.0 ± 3.0 101.325 3.16 ± 0.13
455.0 ± 3.0 101.325 4.05 ± 0.13
498.0 ± 3.0 101.325 3.86 ± 0.13
518.0 ± 3.0 101.325 4.68 ± 0.13
666.0 ± 3.0 101.325 5.58 ± 0.13
719.0 ± 3.0 101.325 7.39 ± 0.13
References
1961W2 Wise, H.: J. Chem. Phys. 34 (1961) 2139.
1969S5 Sancier, K.M., Wise, H.: J. Chem. Phys. 51 (1969) 1434–1438.

Diffusion of hydrogen atom (1); nitrogen (2) 1
Diffusion of hydrogen atom (1); nitrogen (2)

Vapor in Gas

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
294.0 101.325 1.35 ± 0.03
Reference
1982C3 Clifford, A.A., Gray, P., Mason, R.S., Waddicor, J.I.: Proc. R. Soc. A 380 (1982) 241–258.

Diffusion of nitric acid (1); air (2) 1
Diffusion of nitric acid (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: ABSORB Ref.: 1986D3
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.118 ± 0.003

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
297.15 101.325 0.0398 ± 0.0001
299.15 101.325 0.0407 ± 0.0017
303.15 101.325 0.0419 ± 0.0007
308.15 101.325 0.0423 ± 0.0007
318.15 101.325 0.0440 ± 0.0015
References
1986D3 Durham, J.L., Stockburger, L.: Atmos. Environ. 20 (1986) 559–563.
1992D1 de Andrade, J.B., de Aragao, N.M., Araujo, F.R.J.: Int. J. Environ. Anal. Chem. 49 (1992)
103–109.

Diffusion of hydrogen-tritium (1); argon (2) 1
Diffusion of hydrogen-tritium (1); argon (2)

Vapor in Gas

Ar (2) argon 7440-37-1
T [K] p [atm] D · 109 [m2/s]
85.17 ± 0.05 2.0 2.69 ± 0.10
85.12 ± 0.05 2.0 2.91 ± 0.10
90.11 ± 0.05 2.0 3.36 ± 0.10
90.11 ± 0.05 2.0 3.38 ± 0.10
87.24 ± 0.05 2.0 3.01 ± 0.14
87.26 ± 0.05 2.0 3.02 ± 0.16
88.01 ± 0.05 2.0 3.23 ± 0.04
88.01 ± 0.05 2.0 3.21 ± 0.22
88.00 ± 0.05 2.0 3.34 ± 0.25
Reference

Diffusion of hydrogen (1); air (2) 1
Diffusion of hydrogen (1); air (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

Air (2) air 132259-10-0
T [K] p [Torr] D · 104 [m2/s]
291.5 700 0.760 ± 0.007
H2 (1) hydrogen 1333-74-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.820
333.15 101.325 0.975
333.15 101.325 0.961
363.15 101.325 1.12
393.15 101.325 1.29
423.15 101.325 1.46
453.15 101.325 1.65
H2 (1) hydrogen 1333-74-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
273 101.325 0.66 ± 0.02
H2 (1) hydrogen 1333-74-0

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
303.15 100658.3 0.767
References
1960S1 Suetin, P.E., Shchegolev, G.T., Klestov, R.A.: Sov. Phys. Tech. Phys. 4 (1960) 964–969.
1980P4 Pathak, B.K., Singh, P.C., Singh, V.A.N.: Can. J. Chem. Eng. 58 (1980) 38–40.


Vapor in Gas
H2 (1) hydrogen 1333-74-0

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
105.0 101.325 0.115 ± 3%
105.5 101.325 0.124 ± 3%
106.2 101.325 0.140 ± 3%
107.0 101.325 0.147 ± 3%
109.0 101.325 0.153 ± 3%
110.2 101.325 0.152 ± 3%
110.6 101.325 0.155 ± 3%
114.7 101.325 0.166 ± 3%
H2 (1) hydrogen 1333-74-0

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
291.0 ± 0.1 101.325 0.764 ± 2%
313.0 ± 0.1 101.325 0.874 ± 2%
344.8 ± 0.1 101.325 1.08 ± 2%
373.0 ± 0.1 101.325 1.26 ± 2%
404.0 ± 0.1 101.325 1.46 ± 2%
436.0 ± 0.1 101.325 1.68 ± 2%
473.0 ± 0.1 101.325 1.96 ± 2%
H2 (1) hydrogen 1333-74-0

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
287.9 101.325 0.8280
354.2 101.325 1.111
418.0 101.325 1.714
H2 (1) hydrogen 1333-74-0

Ar (2) argon 7440-37-1
T [K] p [atm] D · 107 [m2/s]
298.15 272 1.83
298.15 408 1.15
298.15 543 0.92
(continued)

298.15 681 0.76

298.15 818 0.65
298.15 1090 0.52
298.15 1360 0.45
H2 (1) hydrogen 1333-74-0

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
293.7 101.325 0.781
292.5 101.325 0.760
H2 (1) hydrogen 1333-74-0

Ar (2) argon 7440-37-1
Diffusion of gas(1) in gas(2): D*12(T ); Method: DB Ref.: 1975A6
T [K] p [kPa] D · 104 [m2/s]
295.3 ± 0.1 101.325 0.82 ± 2%
H2 (1) hydrogen 1333-74-0

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
303.15 100658.3 0.793
H2 (1) hydrogen 1333-74-0

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 107 [m2/s]
291.7 ± 0.3 101.325 0.791 ± 1.0%
377.0 ± 0.3 101.325 1.227 ± 1.0%
492.0 ± 0.3 101.325 2.021 ± 1.0%
470.3 ± 0.3 101.325 1.871 ± 1.0%
470.0 ± 0.3 101.325 1.858 ± 1.0%
475.3 ± 0.3 101.325 1.939 ± 1.0%
476.2 ± 0.3 101.325 1.969 ± 1.0%
523.0 ± 0.3 101.325 2.284 ± 1.0%
522.0 ± 0.3 101.325 2.256 ± 1.0%
575.5 ± 0.3 101.325 2.675 ± 1.0%
570.5 ± 0.3 101.325 2.603 ± 1.0%
296.4 ± 0.3 101.325 0.823 ± 1.0%
381.5 ± 0.3 101.325 1.295 ± 1.0%
476.5 ± 0.3 101.325 1.948 ± 1.0%
476.5 ± 0.3 101.325 1.896 ± 1.0%
478.0 ± 0.3 101.325 1.964 ± 1.0%
572.0 ± 0.3 101.325 2.591 ± 1.0%
(continued)
573.0 ± 0.3 101.325 2.612 ± 1.0%

695.0 ± 0.3 101.325 3.692 ± 1.0%
695.0 ± 0.3 101.325 3.743 ± 1.0%
H2 (1) hydrogen 1333-74-0

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 107 [m2/s]
291.7 ± 0.5 101.325 0.791 ± 1.0%
377.0 ± 0.5 101.325 1.227 ± 1.0%
492.0 ± 0.5 101.325 2.021 ± 1.0%
470.3 ± 0.5 101.325 1.871 ± 1.0%
470.0 ± 0.5 101.325 1.858 ± 1.0%
475.3 ± 0.5 101.325 1.936 ± 1.0%
476.2 ± 0.5 101.325 1.936 ± 1.0%
523.0 ± 0.5 101.325 2.284 ± 1.0%
522.0 ± 0.5 101.325 2.256 ± 1.0%
575.5 ± 0.5 101.325 2.675 ± 1.0%
570.5 ± 0.5 101.325 2.603 ± 1.0%
H2 (1) hydrogen 1333-74-0

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 107 [m2/s]
296.4 ± 0.5 101.325 0.823 ± 1.0%
381.5 ± 0.5 101.325 1.295 ± 1.0%
476.5 ± 0.5 101.325 1.948 ± 1.0%
476.5 ± 0.5 101.325 1.896 ± 1.0%
478.0 ± 0.5 101.325 1.964 ± 1.0%
572.0 ± 0.5 101.325 2.591 ± 1.0%
573.0 ± 0.5 101.325 2.612 ± 1.0%
695.0 ± 0.5 101.325 3.692 ± 1.0%
695.0 ± 0.5 101.325 3.743 ± 1.0%
H2 (1) hydrogen 1333-74-0

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 107 [m2/s]
295.0 101.325 0.807 ± 0.6%
380.0 101.325 1.261 ± 0.6%
476.0 101.325 1.918 ± 0.6%
523.0 101.325 2.275 ± 0.6%
573.0 101.325 2.619 ± 0.6%
692.5 101.325 3.684 ± 0.6%

H2 (1) hydrogen 1333-74-0

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 107 [m2/s]
118.0 ± 0.3 101.325 0.151 ± 1.5%
154.0 ± 0.3 101.325 0.247 ± 1.5%
197.0 ± 0.3 101.325 0.391 ± 1.5%
231.0 ± 0.3 101.325 0.510 ± 1.5%
296.0 ± 0.3 101.325 0.821 ± 1.5%
H2 (1) hydrogen 1333-74-0

Ar (2) argon 7440-37-1
T [K] p [Torr] D · 104 [m2/s]
291.0 700 0.830 ± 0.006
H2 (1) hydrogen 1333-74-0

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.86 ± 2%
References
1964M7 Mason, E.A., Weissman, S., Wendt, R.P.: Phys. Fluids 7 (1964) 174–179.
1975A6 Al'zhanov, K.Z., Kosov, N.D.: Zh. Tekhn. Fiz. 45 (1975) 1133–1134.
1971S8 Suetin, P.E., Kalinin, B.A., Loiko, A.E.: Sov. Phys. Tech. Phys. 15 (1971) 1349–1354.

Diffusion of hydrogen (1); dichloro-difluoro-methane (2) 1
Diffusion of hydrogen (1); dichloro-difluoro-methane (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.1 101.325 0.325
Reference
1991M2 Monfort, J.-P., Pellegatta, J.-L.: J. Chem. Eng. Data 36 (1991) 135–137.

Diffusion of hydrogen (1); methane (2) 1
Diffusion of hydrogen (1); methane (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

CH4 (2) methane 74-82-8
Diffusion of gas(1) in gas(2): D*12(T ); Method: ABSORB Ref.: 1981M4
T [K] p [atm] D · 107 [m2/s]
65.0 5.0 8.3 ± 0.3
65.0 10.0 4.3 ± 0.3
65.0 15.0 2.8 ± 0.2
65.0 20.0 2.1 ± 0.1
65.0 30.0 1.4 ± 0.1
65.0 40.0 1.1 ± 0.1
65.0 50.0 1.2
65.0 60.0 1.2
65.0 70.0 1.0
65.0 80.0 1.0
77.5 5.0 11.5 ± 0.1
77.5 10.0 6.0 ± 0.2
77.5 15.0 4.0 ± 0.2
77.5 20.0 3.1 ± 0.2
77.5 30.0 2.1 ± 0.1
77.5 40.0 1.5 ± 0.1
77.5 50.0 1.3
77.5 60.0 1.1
77.5 70.0 0.9
H2 (1) hydrogen 1333-74-0

CH4 (2) methane 74-82-8
Diffusion of gas(1) in gas(2): D*12(T ); Method: DLS Ref.: 1973C3
T [K] p [psi] D · 104 [m2/s]
299.15 25 0.440 ± 0.04
299.15 39 0.325 ± 0.04
299.15 54 0.205 ± 0.04
299.15 71 0.172 ± 0.04
H2 (1) hydrogen 1333-74-0

CH4 (2) methane 74-82-8
T [K] p [kPa] D · 104 [m2/s]
305.0 101.325 0.860
319.5 101.325 0.902
334.0 101.325 0.961
343.0 101.325 1.044

2 Diffusion of hydrogen (1); methane (2)
H2 (1) hydrogen 1333-74-0

CH4 (2) methane 74-82-8
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.76 ± 2%
H2 (1) hydrogen 1333-74-0

CH4 (2) methane 74-82-8
T [K] p [kPa] D · 104 [m2/s]
298.0 101.325 0.726
References
1981M4 Morozov, V.S., Pronskaja, A.Ja., Gubanova, G.N., Kisjuk, V.F.: Zh. Fiz. Khim. 55 (1981)
1304–1306.
1973C3 Cardamone, M.J., Eastman, D.P.: J. Chem. Phys. 59 (1973) 553–554.
1978A4 Amouroux, J., Sanchez, B., Saint Yrieix, A.: Bull. Soc. Chim. Fr. 11 (1978) I-462–I-466.

Diffusion of hydrogen (1); carbon monoxide (2) 1
Diffusion of hydrogen (1); carbon monoxide (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
295.6 101.325 0.743
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
295.6 ± 0.1 101.325 0.743 ± 2%
315.0 ± 0.1 101.325 0.856 ± 2%
345.0 ± 0.1 101.325 0.979 ± 2%
374.5 ± 0.1 101.325 1.14 ± 2%
401.0 ± 0.1 101.325 1.27 ± 2%
436.0 ± 0.1 101.325 1.49 ± 2%
471.0 ± 0.1 101.325 1.68 ± 2%
References


Vapor in Gas
H2 (1) hydrogen 1333-74-0

T [K] p [atm] D · 106 [m2/s]
304.3 ± 0.1 10 5.71 ± 3%
313.0 ± 0.1 10 5.82 ± 3%
323.0 ± 0.1 10 6.31 ± 3%
353.0 ± 0.1 10 8.30 ± 3%
304.3 ± 0.1 20 2.82 ± 3%
313.0 ± 0.1 20 2.94 ± 3%
323.0 ± 0.1 20 3.30 ± 3%
353.0 ± 0.1 20 4.27 ± 3%
304.3 ± 0.1 30 1.86 ± 3%
313.0 ± 0.1 30 1.98 ± 3%
323.0 ± 0.1 30 2.24 ± 3%
353.0 ± 0.1 30 2.85 ± 3%
304.3 ± 0.1 40 1.33 ± 3%
313.0 ± 0.1 40 1.43 ± 3%
323.0"± 0.1 40 1.59 ± 3%
353.0 ± 0.1 40 2.13 ± 3%
304.3 ± 0.1 50 1.01 ± 3%
313.0 ± 0.1 50 1.11 ± 3%
323.0 ± 0.1 50 1.19 ± 3%
353.0 ± 0.1 50 1.70 ± 3%
304.3 ± 0.1 60 0.81 ± 3%
313.0 ± 0.1 60 0.87 ± 3%
323.0 ± 0.1 60 0.96 ± 3%
353.0 ± 0.1 60 1.30 ± 3%
304.3 ± 0.1 70 0.60 ± 3%
313.0 ± 0.1 70 0.70 ± 3%
323.0 ± 0.1 70 0.83 ± 3%
353.0 ± 0.1 70 1.12 ± 3%
H2 (1) hydrogen 1333-74-0

T [K] p [atm] D · 106 [m2/s]
304.3 ± 0.1 10 5.71 ± 3%
304.3 ± 0.1 20 2.82 ± 3%
304.3 ± 0.1 30 1.86 ± 3%
304.3 ± 0.1 40 1.33 ± 3%
304.3 ± 0.1 50 1.01 ± 3%
304.3 ± 0.1 60 0.81 ± 3%
(continued)
2 Diffusion of hydrogen (1); carbon dioxide (2)
304.3 ± 0.1 67.5 0.65 ± 3%

304.3 ± 0.1 70 0.60 ± 3%
304.3 ± 0.1 71.25 0.58 ± 3%
304.3 ± 0.1 72.5 0.54 ± 3%
304.3 ± 0.1 73.75 0.51 ± 3%
304.3 ± 0.1 75.0 0.46 ± 3%
304.3 ± 0.1 77.5 0.42 ± 3%
304.3 ± 0.1 80 0.44 ± 3%
H2 (1) hydrogen 1333-74-0

T [K] p [atm] D · 106 [m2/s]
313.0 ± 0.1 10 5.82 ± 3%
313.0 ± 0.1 20 2.94 ± 3%
313.0 ± 0.1 30 1.98 ± 3%
313.0 ± 0.1 40 1.43 ± 3%
313.0 ± 0.1 50 1.11 ± 3%
313.0 ± 0.1 60 0.87 ± 3%
313.0 ± 0.1 65 0.79 ± 3%
313.0 ± 0.1 70 0.70 ± 3%
313.0 ± 0.1 80 0.53 ± 3%
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
291.9 ± 0.1 101.325 0.599 ± 2%
313.0 ± 0.1 101.325 0.701 ± 2%
344.8 ± 0.1 101.325 0.850 ± 2%
373.0 ± 0.1 101.325 0.968 ± 2%
404.0 ± 0.1 101.325 1.15 ± 2%
436.0 ± 0.1 101.325 1.28 ± 2%
473.0 ± 0.1 101.325 1.47 ± 2%
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
302.0 101.325 0.719

H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
295.3 ± 0.1 101.325 0.68 ± 2%
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.638
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
289.2 101.325 0.619
298.0 101.325 0.646
298.2 101.325 0.665
H2 (1) hydrogen 1333-74-0

Diffusion of gas(1) in gas(2): D*12(T ); Method: PF Ref.: 1969S6
T [K] p [kPa] D · 104 [m2/s]
455 ± 1.0 101.325 1.43
488 ± 1.0 101.325 1.68
575 ± 1.0 101.325 2.21
682 ± 1.0 101.325 3.07
802 ± 1.0 101.325 3.95
907 ± 1.0 101.325 4.89
989 ± 1.0 101.325 5.76
Comment: average error: ±2%
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
273 101.325 0.58 ± 0.01

4 Diffusion of hydrogen (1); carbon dioxide (2)
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
291.9 101.325 0.650 ± 0.006
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
216.6 101.325 0.335 ± 3%
216.9 101.325 0.355 ± 3%
216.8 101.325 0.355 ± 3%
217.4 101.325 0.368 ± 3%
218.0 101.325 0.375 ± 3%
218.7 101.325 0.400 ± 3%
220.2 101.325 0.408 ± 3%
225.1 101.325 0.428 ± 3%
H2 (1) hydrogen 1333-74-0

T [K] p [atm] D · 104 [m2/s]
323 1 0.7700
363 1 0.9500
323 25 0.02200
363 25 0.03047
323 50 0.01090
363 50 0.01440
323 100 0.00435
363 100 0.00651
H2 (1) hydrogen 1333-74-0

Diffusion of gas(1) in gas(2): D*12(T ); Method: DB Ref.: 1970K7
T [K] p [kPa] D · 104 [m2/s]
196 101.325 0.328
207 101.325 0.352
215 101.325 0.369
228 101.325 0.411
233 101.325 0.421
252 101.325 0.486
264 101.325 0.520
273 101.325 0.560
288 101.325 0.607
298 101.325 0.644

References
1975B5 Berestenko, V.M., Kosov, N.D.: Heat Transfer Sov. Res. 7 (1975) 42–45.
1969S6 Schneider, M., Schäfer, K.: Ber. Bunsenges. Phys. Chem. 73 (1969) 702–706.
1964B5 Bondarenko, A.G., Golubew, I.F.: Gaz. Promysl. 9 (1964) 50–54.
1970K7 Kosov, N.D., Zhalgasov, A.: Zh. Tekh. Fiz. 40 (1970) 1325–1327.

Diffusion of hydrogen (1); 1,2-dichloro-1,1,2,2-tetrafluoro-ethane (2) 1
Diffusion of hydrogen (1); 1,2-dichloro-1,1,2,2-tetrafluoro-

ethane (2)
Vapor in Gas
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.1 101.325 0.297
Reference

Diffusion of hydrogen (1); ethane (2) 1
Diffusion of hydrogen (1); ethane (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

C2H6 (2) ethane 74-84-0
T [K] p [kPa] D · 104 [m2/s]
298.0 101.325 0.537
H2 (1) hydrogen 1333-74-0

C2H6 (2) ethane 74-84-0
T [K] p [kPa] D · 104 [m2/s]
305.5 101.325 0.639
319.5 101.325 0.671
334.0 101.325 0.722
References

Diffusion of hydrogen (1); ethanol (2) 1
Diffusion of hydrogen (1); ethanol (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
363.15 ± 0.1 101.325 0.698
Reference

Diffusion of hydrogen (1); propan-2-one (2) 1
Diffusion of hydrogen (1); propan-2-one (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
363.15 ± 0.1 101.325 0.600
Reference

Diffusion of hydrogen (1); propane (2) 1
Diffusion of hydrogen (1); propane (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

C3H8 (2) propane 74-98-6
T [K] p [kPa] D · 104 [m2/s]
305.0 101.325 0.528
319.5 101.325 0.571
334.0 101.325 0.598
Reference

Diffusion of hydrogen (1); butane (2) 1
Diffusion of hydrogen (1); butane (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

C4H10 (2) butane 106-97-8
T [K] p [kPa] D · 104 [m2/s]
287.9 101.325 0.361
354.2 101.325 0.507
430.0 101.325 0.763
H2 (1) hydrogen 1333-74-0

C4H10 (2) butane 106-97-8
T [K] p [kPa] D · 104 [m2/s]
305.0 101.325 0.479
319.5 101.325 0.517
334.0 101.325 0.555
343.0 101.325 0.579
References

Diffusion of hydrogen (1); thiophene (2) 1
Diffusion of hydrogen (1); thiophene (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

C4H4S (2) thiophene 110-02-1
T [K] p [kPa] D · 104 [m2/s]
302.2 101.325 0.40
Reference

Diffusion of hydrogen (1); tetrahydro-thiophene (2) 1
Diffusion of hydrogen (1); tetrahydro-thiophene (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

C4H8S (2) tetrahydro-thiophene 110-01-0
T [K] p [kPa] D · 104 [m2/s]
318.4 101.325 0.412
Reference

Diffusion of hydrogen (1); pyridine (2) 1
Diffusion of hydrogen (1); pyridine (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

C5H5N (2) pyridine 110-86-1
T [K] p [kPa] D · 104 [m2/s]
317.9 101.325 0.437
Reference

Diffusion of hydrogen (1); piperidine (2) 1
Diffusion of hydrogen (1); piperidine (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

C5H11N (2) piperidine 110-89-4
T [K] p [kPa] D · 104 [m2/s]
314.7 101.325 0.403
Reference

Diffusion of hydrogen (1); nitrobenzene (2) 1
Diffusion of hydrogen (1); nitrobenzene (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
493.15 ± 0.1 101.325 0.820
Reference

Diffusion of hydrogen (1); benzene (2) 1
Diffusion of hydrogen (1); benzene (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

C6H6 (2) benzene 71-43-2
T [K] p [kPa] D · 104 [m2/s]
311.3 101.325 0.4036
H2 (1) hydrogen 1333-74-0

C6H6 (2) benzene 71-43-2
T [K] p [kPa] D · 104 [m2/s]
373.15 ± 0.1 101.325 0.550
References

Diffusion of hydrogen (1); aniline (2) 1
Diffusion of hydrogen (1); aniline (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
473.15 ± 0.1 101.325 0.800
Reference

Diffusion of hydrogen (1); cyclohexane (2) 1
Diffusion of hydrogen (1); cyclohexane (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
288.5 101.325 0.319
Reference

Diffusion of hydrogen (1); methyl-cyclopentane (2) 1
Diffusion of hydrogen (1); methyl-cyclopentane (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
288.5 101.325 0.318
Reference

Diffusion of hydrogen (1); 2,3-dimethyl-butane (2) 1
Diffusion of hydrogen (1); 2,3-dimethyl-butane (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
288.8 101.325 0.301
Reference

Diffusion of hydrogen (1); hexane (2) 1
Diffusion of hydrogen (1); hexane (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

C6H14 (2) hexane 110-54-3
T [K] p [kPa] D · 104 [m2/s]
288.7 101.325 0.290
H2 (1) hydrogen 1333-74-0

C6H14 (2) hexane 110-54-3
T [K] p [kPa] D · 104 [m2/s]
373.15 ± 0.1 101.325 0.460
References

Diffusion of hydrogen (1); toluene (2) 1
Diffusion of hydrogen (1); toluene (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

C7H8 (2) toluene 108-88-3
T [K] p [kPa] D · 104 [m2/s]
393.15 ± 0.1 101.325 0.542
Reference

Diffusion of hydrogen (1); 2,4-dimethyl-pentane (2) 1
Diffusion of hydrogen (1); 2,4-dimethyl-pentane (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
303.3 101.325 0.297
Reference

Diffusion of hydrogen (1); heptane (2) 1
Diffusion of hydrogen (1); heptane (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

C7H16 (2) heptane 142-82-5
T [K] p [kPa] D · 104 [m2/s]
303.2 101.325 0.283
Reference

Diffusion of hydrogen (1); 2,2,4-trimethyl-pentane (2) 1
Diffusion of hydrogen (1); 2,2,4-trimethyl-pentane (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
303.2 101.325 0.292
Reference

Diffusion of hydrogen (1); octane (2) 1
Diffusion of hydrogen (1); octane (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

C8H18 (2) octane 111-65-9
T [K] p [kPa] D · 104 [m2/s]
303.2 101.325 0.277
Reference

Diffusion of hydrogen (1); 2,3,3-trimethyl-heptane (2) 1
Diffusion of hydrogen (1); 2,3,3-trimethyl-heptane (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

C10H22 (2) 2,3,3-trimethyl-heptane 52896-93-2
T [K] p [kPa] D · 104 [m2/s]
363.9 101.325 0.270
Reference

Diffusion of hydrogen (1); decane (2) 1
Diffusion of hydrogen (1); decane (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

C10H22 (2) decane 124-18-5
T [K] p [kPa] D · 104 [m2/s]
364.1 101.325 0.306
Reference

Diffusion of hydrogen (1); dodecane (2) 1
Diffusion of hydrogen (1); dodecane (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

C12H26 (2) dodecane 112-40-3
T [K] p [kPa] D · 104 [m2/s]
399.6 101.325 0.308
Reference

Diffusion of hydrogen (1); hydrogen-deuterium (2) 1
Diffusion of hydrogen (1); hydrogen-deuterium (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D
419.59 101.325 0.56650 ± 2.0 · 10–3
398.52 101.325 0.61737 ± 2.0 · 10–3
373.63 101.325 0.68805 ± 2.0 · 10–3
348.55 101.325 0.77286 ± 2.0 · 10–3
324.54 101.325 0.87314 ± 2.0 · 10–3
271.42 101.325 1.1789 ± 2.0 · 10–3
253.51 101.325 1.3218 ± 2.0 · 10–3
237.44 101.325 1.4748 ± 2.0 · 10–3
297.0 101.325 1.349 · 10–4*
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
297.15 101.325 1.349 ± 0.013
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
297.15 101.325 1.212 ± 2%
References

Diffusion of hydrogen (1); deuterium (2) 1
Diffusion of hydrogen (1); deuterium (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

D2 (2) deuterium 7782-39-0
T [K] p [kPa] D · 104 [m2/s]
115.0 ± 0.3 101.325 0.253 ± 1.5%
155.0 ± 0.3 101.325 0.418 ± 1.5%
197.0 ± 0.3 101.325 0.649 ± 1.5%
232.0 ± 0.3 101.325 0.857 ± 1.5%
295.0 ± 0.3 101.325 1.280 ± 1.5%
H2 (1) hydrogen 1333-74-0

D2 (2) deuterium 7782-39-0
T [K] p [kPa] D · 104 [m2/s]
297.15 101.325 1.268 ± 0.013
H2 (1) hydrogen 1333-74-0

D2 (2) deuterium 7782-39-0
T [K] p [kPa] D
419.41 101.325 0.57308 ± 2.0 · 10–3
398.29 101.325 0.62268 ± 2.0 · 10–3
373.44 101.325 0.69373 ± 2.0 · 10–3
348.95 101.325 0.77405 ± 2.0 · 10–3
324.38 101.325 0.87424 ± 2.0 · 10–3
270.98 101.325 1.1789 ± 2.0 · 10–3
252.80 101.325 1.3261 ± 2.0 · 10–3
237.61 101.325 1.4705 ± 2.0 · 10–3
297.0 101.325 1.268 · 10–4*
H2 (1) hydrogen 1333-74-0

D2 (2) deuterium 7782-39-0
Diffusion of zas(1) in gas(2): D*12(T ); Method: No Info Ref.: 1966F1
T [K] p [kPa] D · 104 [m2/s]
288.2 101.325 1.2400
295.5 101.325 1.2500

2 Diffusion of hydrogen (1); deuterium (2)
H2 (1) hydrogen 1333-74-0

D2 (2) deuterium 7782-39-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: DB Ref.: 1958B1
T [K] p [kPa] D · 104 [m2/s]
20.4 101.325 0.00706 ± 2.5%
65.1 101.325 0.0871 ± 2%
76.6 101.325 0.116 ± 2%
85.0 101.325 0.149 ± 4.7%
192.0 101.325 0.583 ± 2%
273.0 101.325 1.113 ± 0.3%
288.0 101.325 1.24
293.2 101.325 1.21
296.0 101.325 1.27 ± 3%
References
1970S1 Suetin, P.E., Loiko, A.E., Kalinin, B.A., Gerasimov, Yu.F.: J. Eng. Phys. Thermophys. 19
(1970) 933–935.
1958B1 Bendt, P.J.: Phys. Rev. 110 (1958) 85–89.

Diffusion of hydrogen (1); deuterium-tritium (2) 1
Diffusion of hydrogen (1); deuterium-tritium (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
297.15 101.325 1.212 ± 0.024
Reference

Diffusion of hydrogen (1); sulfur hexafluoride (2) 1
Diffusion of hydrogen (1); sulfur hexafluoride (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

T [K] p [Torr] D · 104 [m2/s]
290.0 700 0.471 ± 0.004
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
186.8 101.325 0.196 ± 1.5%
222.7 101.325 0.270 ± 1.5%
255.7 101.325 0.345 ± 1.5%
293.7 101.325 0.443 ± 1.5%
379.2 101.325 0.693 ± 1.5%
445.7 101.325 0.923 ± 1.5%
505.9 101.325 1.14 ± 1.5%
563.2 101.325 1.33 ± 1.5%
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
286.2 101.325 0.396
306.9 101.325 0.458
370.8 101.325 0.647
418.0 101.325 0.838
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
290.0 ± 0.1 101.325 0.434 ± 2%
313.0 ± 0.1 101.325 0.488 ± 2%
344.4 ± 0.1 101.325 0.570 ± 2%
376.0 ± 0.1 101.325 0.662 ± 2%
401.0 ± 0.1 101.325 0.750 ± 2%
429.0 ± 0.1 101.325 0.855 ± 2%
473.0 ± 0.1 101.325 1.03 ± 2%

2 Diffusion of hydrogen (1); sulfur hexafluoride (2)
References

Diffusion of hydrogen (1); hydrogen-tritium (2) 1
Diffusion of hydrogen (1); hydrogen-tritium (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
297.15 101.325 1.274 ± 2%
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
194.7 101.325 0.696
273.2 101.325 1.202
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 104 [m2/s]
297.15 101.325 1.274 ± 0.025
References

Diffusion of hydrogen (1); water (2) 1
Diffusion of hydrogen (1); water (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 104 [m2/s]
307.3 101.325 1.02
328.6 101.325 1.121
352.7 101.325 1.20
Reference

Diffusion of hydrogen (1); ammonia (2) 1
Diffusion of hydrogen (1); ammonia (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

H 3N (2) ammonia 7664-41-7
T [K] p [kPa] D · 104 [m2/s]
273.0 101.325 0.7454
293.0 101.325 0.8337
296.8 101.325 0.8560
333.0 101.325 1.021
413.0 101.325 1.435
533.0 101.325 2.149
H2 (1) hydrogen 1333-74-0

H 3N (2) ammonia 7664-41-7
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.830
References

Diffusion of hydrogen (1); helium (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
291.4 ± 0.3 101.325 1.521 ± 0.7%
291.5 ± 0.3 101.325 1.531 ± 0.7%
375.3 ± 0.3 101.325 2.333 ± 0.7%
373.7 ± 0.3 101.325 2.355 ± 0.7%
472.6 ± 0.3 101.325 3.508 ± 0.7%
470.6 ± 0.3 101.325 3.516 ± 0.7%
471.2 ± 0.3 101.325 3.501 ± 0.7%
477.0 ± 0.3 101.325 3.583 ± 0.7%
523.8 ± 0.3 101.325 4.334 ± 0.7%
523.8 ± 0.3 101.325 4.329 ± 0.7%
570.0 ± 0.3 101.325 4.917 ± 0.7%
570.0 ± 0.3 101.325 4.922 ± 0.7%
296.4 ± 0.3 101.325 1.569 ± 0.7%
380.0 ± 0.3 101.325 2.399 ± 0.7%
381.5 ± 0.3 101.325 2.443 ± 0.7%
381.5 ± 0.3 101.325 2.451 ± 0.7%
477.5 ± 0.3 101.325 3.591 ± 0.7%
477.5 ± 0.3 101.325 3.573 ± 0.7%
574.0 ± 0.3 101.325 4.845 ± 0.7%
574.0 ± 0.3 101.325 4.895 ± 0.7%
692.5 ± 0.3 101.325 6.821 ± 0.7%
695.0 ± 0.3 101.325 6.831 ± 0.7%
H2 (1) hydrogen 1333-74-0

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
291.4 ± 0.5 101.325 1.521 ± 0.7%
291.5 ± 0.5 101.325 1.531 ± 0.7%
375.3 ± 0.5 101.325 2.333 ± 0.7%
373.7 ± 0.5 101.325 2.355 ± 0.7%
472.6 ± 0.5 101.325 3.508 ± 0.7%
470.6 ± 0.5 101.325 3.516 ± 0.7%
471.2 ± 0.5 101.325 3.501 ± 0.7%
477.0 ± 0.5 101.325 3.583 ± 0.7%
523.8 ± 0.5 101.325 4.334 ± 0.7%
523.8 ± 0.5 101.325 4.329 ± 0.7%
570.0 ± 0.5 101.325 4.917 ± 0.7%
570.0 ± 0.5 101.325 4.922 ± 0.7%

2 Diffusion of hydrogen (1); helium (2)
H2 (1) hydrogen 1333-74-0

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
296.4 ± 0.5 101.325 1.569 ± 0.7%
380.0 ± 0.5 101.325 2.399 ± 0.7%
381.5 ± 0.5 101.325 2.443 ± 0.7%
381.5 ± 0.5 101.325 2.451 ± 0.7%
477.5 ± 0.5 101.325 3.591 ± 0.7%
477.5 ± 0.5 101.325 5.573 ± 0.7%
574.0 ± 0.5 101.325 4.845 ± 0.7%
574.0 ± 0.5 101.325 4.895 ± 0.7%
692.5 ± 0.5 101.325 6.821 ± 0.7%
695.0 ± 0.5 101.325 6.831 ± 0.7%
H2 (1) hydrogen 1333-74-0

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
118.0 ± 0.3 101.325 0.318 ± 1.5%
143.0 ± 0.3 101.325 0.443 ± 1.5%
177.0 ± 0.3 101.325 0.657 ± 1.5%
225.0 ± 0.3 101.325 0.985 ± 1.5%
296.0 ± 0.3 101.325 1.550 ± 1.5%
H2 (1) hydrogen 1333-74-0

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
295.0 101.325 1.550 ± 0.6%
380.0 101.325 2.401 ± 0.6%
476.0 101.325 3.554 ± 0.6%
573.0 101.325 4.890 ± 0.6%
692.5 101.325 6.760 ± 0.6%
H2 (1) hydrogen 1333-74-0

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
298.2 101.325 1.1320

H2 (1) hydrogen 1333-74-0

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
273 101.325 1.21 ± 0.04
H2 (1) hydrogen 1333-74-0

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
292.4 101.325 1.502 ± 0.017
H2 (1) hydrogen 1333-74-0

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 1.61 ± 2%
References
1970S1 Suetin, P.E., Loiko, A.E., Kalinin, B.A., Gerasimov, Yu.F.: J. Eng. Phys. Thermophys. 19 (1970)
933–935.


Vapor in Gas
H2 (1) hydrogen 1333-74-0

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
249 101.325 0.595
249 101.325 0.535
268 101.325 0.645
268 101.325 0.593
289 101.325 0.688
289 101.325 0.663
295.6 101.325 0.726
295.6 101.325 0.687
296.0 101.325 0.705
296.0 101.325 0.693
343 101.325 0.911
343 101.325 0.891
359 101.325 1.016
359 101.325 0.994
371 101.325 1.042
371 101.325 1.027
412 101.325 1.324
412 101.325 1.304
Reference

Diffusion of hydrogen (1); nitrogen (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
295.3 101.325 0.82 ± 2%
H2 (1) hydrogen 1333-74-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
297.0 101.325 0.809 ± 2%
362.0 101.325 1.12 ± 2%
427.0 101.325 1.48 ± 2%
478.5 101.325 1.79 ± 2%
512.0 101.325 2.00 ± 2%
566.5 101.325 2.37 ± 2%
600.0 101.325 2.61 ± 2%
649.0 101.325 2.95 ± 2%
684.0 101.325 3.22 ± 2%
728.0 101.325 3.56 ± 2%
770.0 101.325 3.91 ± 2%
814.0 101.325 4.27 ± 2%
H2 (1) hydrogen 1333-74-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
289.2 ± 0.1 101.325 0.737 ± 2%
345.8 ± 0.1 101.325 0.849 ± 2%
347.6 ± 0.1 101.325 0.991 ± 2%
373.0 ± 0.1 101.325 1.15 ± 2%
401.0 ± 0.1 101.325 1.30 ± 2%
436.0 ± 0.1 101.325 1.45 ± 2%
471.0 ± 0.1 101.325 1.71 ± 2%
H2 (1) hydrogen 1333-74-0

N2 (2) nitrogen 7727-37-9
T [K] p [atm] D · 107 [m2/s]
298.15 272 2.20
298.15 408 1.40
(continued)

298.15 543 1.05

298.15 681 0.87
298.15 818 0.76
298.15 1090 0.63
298.15 1360 0.59
H2 (1) hydrogen 1333-74-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
273.2 101.325 0.674
288.2 101.325 0.743
293.2 101.325 0.76
H2 (1) hydrogen 1333-74-0

N2 (2) nitrogen 7727-37-9
Diffusion of gas(1) in gas(2): D*12(T ); Method: TB Ref.: 1970N2
T [K] p [kPa] D · 104 [m2/s]
275.00 ± 0.1 101.325 0.635 ± 1%
295.00 ± 0.1 101.325 0.735 ± 1%
320.00 ± 0.1 101.325 0.855 ± 1%
340.00 ± 0.1 101.325 0.950 ± 1%
360.00 ± 0.1 101.325 1.05 ± 1%
H2 (1) hydrogen 1333-74-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
444 ± 1.0 101.325 1.49
509 ± 1.0 101.325 1.91
550 ± 1.0 101.325 2.16
558 ± 1.0 101.325 2.18
616 ± 1.0 101.325 2.64
647 ± 1.0 101.325 2.87
692 ± 1.0 101.325 3.19
753 ± 1.0 101.325 3.60
824 ± 1.0 101.325 4.16
919 ± 1.0 101.325 4.84
1016 ± 1.0 101.325 5.79
1137 ± 1.0 101.325 7.26
1237 ± 1.0 101.325 8.11
1302 ± 1.0 101.325 8.71

H2 (1) hydrogen 1333-74-0

N2 (2) nitrogen 7727-37-9
T [K] p [bar] D · 107 [m2/s]
313.15 68.95 11.5
313.15 172.37 4.62
313.15 344.74 2.40
313.15 517.10 1.66
313.15 689.48 1.32
332.59 68.95 12.5
332.59 172.37 4.98
332.59 344.74 2.59
332.59 517.10 1.76
332.59 689.48 1.40
350.37 68.95 13.5
350.37 172.37 5.40
350.37 344.74 2.83
350.37 517.10 1.95
350.37 689.48 1.54
H2 (1) hydrogen 1333-74-0

N2 (2) nitrogen 7727-37-9
T [K] p [atm] D · 104 [m2/s]
302.15 1.0039 0.828 ± 0.010
302.15 1.0039 0.836 ± 0.015
304.0 1.0039 0.797
307.0 1.0039 0.879
H2 (1) hydrogen 1333-74-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
273.9 ± 0.1 101.325 0.659 ± 1%
293.8 ± 0.1 101.325 0.742 ± 1%
311.6 ± 0.1 101.325 0.822 ± 1%
338.2 ± 0.1 101.325 0.942 ± 1%
365.4 ± 0.1 101.325 1.08 ± 1%
H2 (1) hydrogen 1333-74-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
193.0 101.325 0.3680
200.0 101.325 0.4010
253.0 101.325 0.60
(continued)
273.0 101.325 0.7080

287.5 101.325 0.7430
294.0 101.325 0.7630
297.2 101.325 0.7790
300.0 101.325 0.80
303.5 101.325 0.8520
322.0 101.325 0.9030
398.0 101.325 1.2890
400.0 101.325 1.270
450.0 101.325 1.541
506.0 101.325 1.883
573.0 101.325 2.417
H2 (1) hydrogen 1333-74-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.824
303.15 101.325 0.817
333.15 101.325 0.963
333.15 101.325 0.957
333.15 101.325 0.967
363.15 101.325 1.11
393.15 101.325 1.27
423.15 101.325 1.45
453.15 101.325 1.61
453.15 101.325 1.64
H2 (1) hydrogen 1333-74-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
304.2 ± 0.1 101.325 0.806
307.2 ± 0.1 101.325 0.831
H2 (1) hydrogen 1333-74-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.792

H2 (1) hydrogen 1333-74-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
293.0 101.325 0.7975 ± 1.9%
H2 (1) hydrogen 1333-74-0

N2 (2) nitrogen 7727-37-9
T [K] p [Torr] D · 104 [m2/s]
289.2 700 0.800 ± 0.007
H2 (1) hydrogen 1333-74-0

N2 (2) nitrogen 7727-37-9
T [K] p [Torr] D · 104 [m2/s]
298.15 700 0.83 ± 2%
H2 (1) hydrogen 1333-74-0

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
324.0 101.325 0.876 ± 3.6%
References
1974K9 Kosov, N.D., Solonitsyn, B.P.: Zh. Tekh. Fiz. 44 (1974) 855–857.
1970N2 Nain, V.P.S., Saxena, S.C.: Appl. Sci. Res. 23 (1970) 121–133.
1960B4 Berry, V.J., Koeller, R.C.: AIChE J. 6 (1960) 274–280.
1978A4 Amouroux, J., Sanchez, B., Saint Yrieix, A.: Bull. Soc. Chim. Fr. 11 (1978) I-462-I-466.
1960G1 Giddings, J.C., Seager, S.L.: J. Chem. Phys. 33 (1960) 1579–1580.


Vapor in Gas
H2 (1) hydrogen 1333-74-0

Ne (2) neon 7440-01-9
T [K] p [kPa] D · 104 [m2/s]
115.0 ± 0.3 101.325 0.225 ± 1.5%
155.0 ± 0.3 101.325 0.392 ± 1.5%
197.0 ± 0.3 101.325 0.588 ± 1.5%
232.0 ± 0.3 101.325 0.778 ± 1.5%
295.0 ± 0.3 101.325 1.170 ± 1.5%
H2 (1) hydrogen 1333-74-0

Ne (2) neon 7440-01-9
T [K] p [kPa] D · 104 [m2/s]
295.5 101.325 1.161 ± 0.6%
379.0 101.325 1.768 ± 0.6%
484.0 101.325 2.688 ± 0.6%
575.0 101.325 3.585 ± 0.6%
680.5 101.325 4.680 ± 0.6%
References
933–935.

Diffusion of hydrogen (1); oxygen (2) 1
Diffusion of hydrogen (1); oxygen (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

O2 (2) oxygen 7782-44-7
T [K] p [kPa] D · 104 [m2/s]
303.15 100658.38 0.823
H2 (1) hydrogen 1333-74-0

O2 (2) oxygen 7782-44-7
T [K] p [kPa] D · 104 [m2/s]
273.2 101.325 0.697
H2 (1) hydrogen 1333-74-0

O2 (2) oxygen 7782-44-7
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.865
303.15 101.325 0.852
333.15 101.325 1.01
363.15 101.325 1.19
393.15 101.325 1.36
423.15 101.325 1.54
453.15 101.325 1.74
H2 (1) hydrogen 1333-74-0

O2 (2) oxygen 7782-44-7
T [K] p [kPa] D · 104 [m2/s]
276.1 ± 0.1 101.325 0.695 ± 1%
296.5 ± 0.1 101.325 0.780 ± 1%
318.2 ± 0.1 101.325 0.887 ± 1%
337.3 ± 0.1 101.325 0.978 ± 1%
365.6 ± 0.1 101.325 1.12 ± 1%
H2 (1) hydrogen 1333-74-0

O2 (2) oxygen 7782-44-7
T [K] p [kPa] D · 104 [m2/s]
280.00 ± 0.1 101.325 0.707 ± 1%
295.00 ± 0.1 101.325 0.778 ± 1%
(continued)

2 Diffusion of hydrogen (1); oxygen (2)
320.00 ± 0.1 101.325 0.898 ± 1%

340.00 ± 0.1 101.325 0.994 ± 1%
360.00 ± 0.1 101.325 1.09 ± 1%
Comment: smoothed data set
H2 (1) hydrogen 1333-74-0

O2 (2) oxygen 7782-44-7
Diffusion of gas(1) in gas(2): D*12(T ); Method: DB Ref.: 1968Z1
T [K] p [kPa] D · 104 [m2/s]
298 ± 1.0 101.325 0.804
273 ± 1.0 101.325 0.679 ± 1%
250 ± 1.0 101.325 0.591 ± 1%
230 ± 1.0 101.325 0.525 ± 1%
209 ± 1.0 101.325 0.428 ± 1%
150 ± 1.0 101.325 0.269 ± 1%
120 ± 1.0 101.325 0.199 ± 1%
103 ± 1.0 101.325 0.156 ± 1%
References
1968Z1 Zhalgasov, A., Kosov, N.D.: Izv. Akad. Nauk Kaz. SSR Ser. Fiz. Mat. 6 (1968) 76–78.

Diffusion of hydrogen (1); tritium (2) 1
Diffusion of hydrogen (1); tritium (2)

Vapor in Gas
H2 (1) hydrogen 1333-74-0

T2 (2) tritium 10028-17-8
T [K] p [kPa] D · 104 [m2/s]
297.15 101.325 1.207 ± 2%
H2 (1) hydrogen 1333-74-0

T2 (2) tritium 10028-17-8
T [K] p [kPa] D · 104 [m2/s]
194.7 101.325 0.705
273.2 101.325 1.188
352.8 101.325 1.824
H2 (1) hydrogen 1333-74-0

T2 (2) tritium 10028-17-8
T [K] p [kPa] D · 104 [m2/s]
297.15 101.325 1.207 ± 0.030
References

Diffusion of water (1); air (2) 1
Diffusion of water (1); air (2)

Vapor in Gas
H 2O (1) water 7732-18-5

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
293.15 101.325 0.249
294.35 101.325 0.250
H 2O (1) water 7732-18-5

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
423.15 101.325 0.524 ± 3%
References

Diffusion of water (1); argon (2) 1
Diffusion of water (1); argon (2)

Vapor in Gas
H 2O (1) water 7732-18-5

Ar (2) argon 7440-37-1
Diffusion of gas(1) in gas(2): D*12(T ); Method: STEFAN Ref.: 1969O1
T [K] p [kPa] D · 104 [m2/s]
282.0 ± 0.01 101.325 0.218 ± 2%
298.0 ± 0.01 101.325 0.250 ± 2%
327.5 ± 0.01 101.325 0.295 ± 2%
353.0 ± 0.01 101.325 0.348 ± 2%
H 2O (1) water 7732-18-5

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
423.15 101.325 0.496 ± 3%
References
1969O1 O'Connell, J.P., Gillespie, M.D., Krostek, W.D., Prausnitz, J.M.: J. Chem. Phys. 73 (1969)
2000–2004.

Diffusion of water (1); methane (2) 1
Diffusion of water (1); methane (2)

Vapor in Gas
H 2O (1) water 7732-18-5

CH4 (2) methane 74-82-8
T [K] p [kPa] D · 104 [m2/s]
283.0 ± 0.01 101.325 0.234 ± 2%
303.0 ± 0.01 101.325 0.267 ± 2%
323.0 ± 0.01 101.325 0.298 ± 2%
Reference
2000–2004.


Vapor in Gas
H 2O (1) water 7732-18-5

T [K] p [kPa] D · 104 [m2/s]
393.8 ± 0.2 101.325 0.297
408.5 ± 0.2 101.325 0.311
423.3 ± 0.2 101.325 0.333
H 2O (1) water 7732-18-5

T [K] p [kPa] D · 104 [m2/s]
423.15 101.325 0.359 ± 3%
References

Diffusion of water (1); hydrogen (2) 1
Diffusion of water (1); hydrogen (2)

Vapor in Gas
H 2O (1) water 7732-18-5

H2 (2) hydrogen 1333-74-0
T [K] p [MPa] D · 107 [m2/s]
321.15 2.553 32.8
321.15 2.553 30.4
321.15 5.005 13.4
321.15 5.005 13.5
321.15 9.908 6.0
321.15 9.908 6.8
321.15 9.908 6.6
321.15 19.714 2.6
321.15 29.520 2.1
341.15 2.553 68.6
341.15 2.553 64.8
341.15 2.553 63.2
341.15 2.553 62.7
341.15 5.005 35.0
341.15 5.005 33.0
341.15 5.005 33.5
341.15 9.908 17.8
341.15 9.908 17.4
341.15 19.714 10.9
341.15 19.714 9.4
341.15 29.520 6.8
341.15 29.520 6.1
Reference

Diffusion of water (1); helium (2) 1
Diffusion of water (1); helium (2)

Vapor in Gas
H 2O (1) water 7732-18-5

He (2) helium 7440-59-7
Diffusion of gas(1) in gas(2): D*12(T ); Method: BUBBLE Ref.: 1997L10
T [K] p [bar] D
239.7 11.0 7.0 ± 0.4
235.8 26.6 6.3 ± 0.6
238.8 43.6 6.2 ± 0.4
255.9 10.7 7.6 ± 0.4
255.8 26.5 7.4 ± 0.4
255.6 42.1 7.3 ± 0.7
Comment: droplet growth as measuring method; D = (p · D*12) in [Pa · m2/s]
Reference
1997L10 Luijten, C.C.M., Bosschaart, K.J., Van Dongen, M.E.H.: Int. J. Heat Mass Transfer 40 (1997)
3497–3502.

Diffusion of water (1); nitrogen (2) 1
Diffusion of water (1); nitrogen (2)

Vapor in Gas
H 2O (1) water 7732-18-5

N2 (2) nitrogen 7727-37-9
Diffusion of gas(1) in gas(2): D*12(T ); Method: BUBBLE Ref.: 1997L10
T [K] p [bar] D
237.5 11.2 1.5 ± 0.1
237.1 27.9 1.4 ± 0.1
238.3 44.9 1.4 ± 0.1
255.2 10.6 1.9 ± 0.1
254.6 26.7 1.9 ± 0.1
254.2 43.0 1.8 ± 0.1
Comment: droplet growth as measuring method; D = (p · D*12) in [Pa · m2/s]
H 2O (1) water 7732-18-5

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
393.2 ± 0.2 101.325 0.441
408.2 ± 0.2 101.325 0.464
423.4 ± 0.2 101.325 0.508
H 2O (1) water 7732-18-5

N2 (2) nitrogen 7727-37-9
Diffusion of gas(1) in gas(2): D*12(T ); Method: OEC Ref.: 1979F6
T [K] p [kPa] D · 104 [m2/s]
317.05 ± 0.1 101.325 0.284 ± 1%
315.35 ± 0.1 101.325 0.285 ± 1%
313.35 ± 0.1 101.325 0.276 ± 1%
312.45 ± 0.1 101.325 0.273 ± 1%
308.65 ± 0.1 101.325 0.269 ± 1%
306.15 ± 0.1 101.325 0.263 ± 1%
304.75 ± 0.1 101.325 0.259 ± 1%
303.15 ± 0.1 101.325 0.257 ± 1%
302.65 ± 0.1 101.325 0.260 ± 1%
300.15 ± 0.1 101.325 0.258 ± 1%
299.35 ± 0.1 101.325 0.248 ± 1%
H 2O (1) water 7732-18-5

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
282.0 ± 0.01 101.325 0.221 ± 2%
(continued)

2 Diffusion of water (1); nitrogen (2)
298.0 ± 0.01 101.325 0.253 ± 2%

327.5 ± 0.01 101.325 0.305 ± 2%
353.0 ± 0.01 101.325 0.360 ± 2%
373.0 ± 0.01 101.325 0.396 ± 2%
H 2O (1) water 7732-18-5

N2 (2) nitrogen 7727-37-9
Diffusion of gas(1) in gas(2): D*12(T ); Method: BACK Ref.: 1978M8
T [K] p [kPa] D · 104 [m2/s]
294 101.325 0.244 ± 0.004
H 2O (1) water 7732-18-5

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
423.15 101.325 0.508 ± 3%
References
1997L10 Luijten, C.C.M., Bosschaart, K.J., Van Dongen, M.E.H.: Int. J. Heat Mass Transfer 40 (1997)
3497–3502.
1979F6 Finch, A., Gardner, P.J., Tarbox, E., Yardley, S.: J. Chem. Soc. Faraday Trans. 1 75 (1979)
545–549.
2000–2004.
1978M8 Merlivat, L.: J. Chem. Phys. 69 (1978) 2864–2871.

Diffusion of water (1); oxygen (2) 1
Diffusion of water (1); oxygen (2)

Vapor in Gas
H 2O (1) water 7732-18-5

O2 (2) oxygen 7782-44-7
T [K] p [kPa] D · 104 [m2/s]
423.15 101.325 0.538 ± 3%
Reference

Diffusion of sulfuric acid (1); nitrogen (2) 1
Diffusion of sulfuric acid (1); nitrogen (2)

Vapor in Gas
H2O4S (1) sulfuric acid 7664-93-9

N2 (2) nitrogen 7727-37-9
Diffusion of gas(1) in gas(2): D*12(T ); Method: LAM Ref.: 2000H1
T [K] p [kPa] D
298 101.325 0.094 ± 0.006
Comment: vapor of sulfuric acid diffusing into nitrogen; (p · D) given in [atm · cm2/s]
Reference
2000H1 Hanson, D.R., Eisele, F.: J. Phys. Chem. A 104 (2000) 1715–1719.

Diffusion of ammonia (1); air (2) 1
Diffusion of ammonia (1); air (2)

Vapor in Gas
H 3N (1) ammonia 7664-41-7

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
295.1 101.325 0.247 ± 0.002
H 3N (1) ammonia 7664-41-7

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
295.1 101.325 0.247 ± 0.002
References

Diffusion of ammonia (1); argon (2) 1
Diffusion of ammonia (1); argon (2)

Vapor in Gas
H 3N (1) ammonia 7664-41-7

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
254.7 ± 0.5 101.325 0.150 ± 1%
275.1 ± 0.5 101.325 0.175 ± 1%
308.1 ± 0.5 101.325 0.222 ± 1%
333.0 ± 0.5 101.325 0.253 ± 1%
H 3N (1) ammonia 7664-41-7

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
295.1 101.325 0.232 ± 0.002
H 3N (1) ammonia 7664-41-7

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
295.1 101.325 0.232 ± 0.002
References
1962S6 Srivastava, B.N., Srivastava, I.B.: J. Chem. Phys. 36 (1962) 2616–2620.

Diffusion of ammonia (1); carbon monoxide (2) 1
Diffusion of ammonia (1); carbon monoxide (2)

Vapor in Gas
H 3N (1) ammonia 7664-41-7

T [K] p [kPa] D · 104 [m2/s]
295.1 101.325 0.240 ± 0.002
H 3N (1) ammonia 7664-41-7

T [K] p [kPa] D · 104 [m2/s]
295.1 101.325 0.240 ± 0.002
References

Diffusion of ammonia (1); diethyl ether (2) 1
Diffusion of ammonia (1); diethyl ether (2)

Vapor in Gas
H 3N (1) ammonia 7664-41-7

T [K] p [kPa] D · 104 [m2/s]
288.3 101.325 0.0999 ± 2%
299.7 101.325 0.1078 ± 2%
311.9 101.325 0.1148 ± 2%
324.3 101.325 0.1235 ± 2%
337.5 101.325 0.1374 ± 2%
Reference

Diffusion of ammonia (1); sulfur hexafluoride (2) 1
Diffusion of ammonia (1); sulfur hexafluoride (2)

Vapor in Gas
H 3N (1) ammonia 7664-41-7

T [K] p [kPa] D · 104 [m2/s]
296.6 101.325 0.109 ± 0.001
H 3N (1) ammonia 7664-41-7

T [K] p [kPa] D · 104 [m2/s]
296.6 101.325 0.109 ± 0.001
H 3N (1) ammonia 7664-41-7

T [K] p [kPa] D · 104 [m2/s]
296.6 101.325 0.109
References

Diffusion of ammonia (1); hydrogen (2) 1
Diffusion of ammonia (1); hydrogen (2)

Vapor in Gas
H 3N (1) ammonia 7664-41-7

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
263 101.325 0.57 ± 3%
328 101.325 0.90 ± 3%
395 101.325 1.35 ± 3%
473 101.325 1.86 ± 3%
H 3N (1) ammonia 7664-41-7

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
296.8 101.325 0.856 ± 0.007
H 3N (1) ammonia 7664-41-7

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
296.8 101.325 0.856 ± 0.007
References
1959S1 Schäfer, K.: Z. Elektrochem. 63 (1959) 111–117.

Diffusion of ammonia (1); helium (2) 1
Diffusion of ammonia (1); helium (2)

Vapor in Gas
H 3N (1) ammonia 7664-41-7

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
296.6 101.325 0.831 ± 0.007
H 3N (1) ammonia 7664-41-7

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
296.6 101.325 0.831 ± 0.007
References

Diffusion of ammonia (1); krypton (2) 1
Diffusion of ammonia (1); krypton (2)

Vapor in Gas
H 3N (1) ammonia 7664-41-7

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
254.7 ± 0.5 101.325 0.121 ± 1%
275.1 ± 0.5 101.325 0.142 ± 1%
308.1 ± 0.5 101.325 0.178 ± 1%
333.0 ± 0.5 101.325 0.208 ± 1%
Reference

Diffusion of ammonia (1); nitrogen (2) 1
Diffusion of ammonia (1); nitrogen (2)

Vapor in Gas
H 3N (1) ammonia 7664-41-7

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
295.1 101.325 0.248 ± 0.02
H 3N (1) ammonia 7664-41-7

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
295.1 101.325 0.248 ± 0.02
References

Diffusion of helium (1); air (2) 1
Diffusion of helium (1); air (2)

Vapor in Gas
He (1) helium 7440-59-7

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
276.2 101.325 0.6242
317.2 101.325 0.7652
346.2 101.325 0.9019
He (1) helium 7440-59-7

Air (2) air 132259-10-0
T [K] p [Torr] D · 104 [m2/s]
287.0 690 0.759 ± 0.006
He (1) helium 7440-59-7

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
287.0 ± 0.1 101.325 0.689 ± 2%
315.6 ± 0.1 101.325 0.785 ± 2%
348.4 ± 0.1 101.325 0.920 ± 2%
374.5 ± 0.1 101.325 1.04 ± 2%
400.0 ± 0.1 101.325 1.17 ± 2%
430.0 ± 0.1 101.325 1.32 ± 2%
469.0 ± 0.1 101.325 1.52 ± 2%
He (1) helium 7440-59-7

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
276.2 101.325 0.6242 ± 0.0002
317.2 101.325 0.7652 ± 0.0018
346.2 101.325 0.9019 ± 0.0006
He (1) helium 7440-59-7

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
273 101.325 0.63 ± 0.01

2 Diffusion of helium (1); air (2)
References


Vapor in Gas
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
Diffusion of gas(1) in gas(2): D*12(T ); Method: TB Ref.: 1970D6
T [K] p [kPa] D · 104 [m2/s]
305.3 ± 0.1 101.325 0.758
305.6 ± 0.1 101.325 0.762
306.4 ± 0.1 101.325 0.793
311.8 ± 0.1 101.325 0.814
314.8 ± 0.1 101.325 0.838
334.6 ± 0.1 101.325 0.894
Comment: uncertainty: ±(2–3)%
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
301.0 101.325 0.755 ± 0.6%
374.0 101.325 1.084 ± 0.6%
479.5 101.325 1.652 ± 0.6%
676.5 101.325 2.958 ± 0.6%
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
292 ± 1.0 101.325 0.730
320 ± 1.0 101.325 0.848
339 ± 1.0 101.325 1.11
448 ± 1.0 101.325 1.51
525 ± 1.0 101.325 1.89
612 ± 1.0 101.325 2.48
725 ± 1.0 101.325 3.30
840 ± 1.0 101.325 4.28
978 ± 1.0 101.325 5.45
1142 ± 1.0 101.325 7.00
1310 ± 1.0 101.325 8.70

He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
Diffusion of gas(1) in gas(2): D*12(T ); Method: TB Ref.: 1986P9
T [K] p [MPa] D · 106 [m2/s]
140 5.0 0.265
140 7.5 0.0960
140 12.5 0.0662
140 15.0 0.0461
150 5.0 0.284
150 7.5 0.111
150 10.0 0.0861
150 12.5 0.0710
150 15.0 0.0612
160 5.0 0.303
160 7.5 0.127
160 10.0 0.106
160 12.5 0.08543
160 15.0 0.0753
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] p [Torr] D · 104 [m2/s]
296.15 760.0 0.729
296.15 639.2 0.866 ± 0.009
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] p [MPa] D · 106 [m2/s]
344.0 0.8 11.0 ± 5%
344.0 0.8 10.8 ± 5%
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
Diffusion of gas(1) in gas(2): D*12(T ); Method: BACK Ref.: 1980Z4
T [K] p [kPa] D · 104 [m2/s]
298.0 101.325 0.912 ± 0.6%
352.0 101.325 1.00 ± 0.0%
399.5 101.325 1.40 ± 1.1%
445.5 101.325 1.59 ± 0.5%
496.0 101.325 1.98 ± 0.8%
545.5 101.325 2.20 ± 0.7%
593.5 101.325 2.58 ± 0.5%
642.0 101.325 2.72 ± 0.3%
691.0 101.325 3.19 ± 0.1%
(continued)
738.0 101.325 3.59 ± 0.3%

784.5 101.325 3.92 ± 0.0%
831.0 101.325 4.37 ± 0.7%
878.5 101.325 4.72 ± 0.4%
927.0 101.325 5.29 ± 0.1%
973.5 101.325 5.49 ± 0.2%
1021 101.325 6.18 ± 0.7%
1072 101.325 6.64 ± 0.2%
1122 101.325 7.22 ± 0.6%
1168 101.325 7.64 ± 0.3%
1217 101.325 8.31 ± 0.7%
1272 101.325 8.86 ± 0.8%
Comment: mixture at equimolar composition
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] p [atm] D · 104 [m2/s]
303 1 0.784 ± 0.008
324 1 0.847 ± 0.015
402 1 1.22 ± 0.04
500 1 1.75 ± 0.02
600 1 2.52 ± 0.04
698 1 3.05 ± 0.14
806 1 4.05 ± 0.10
Comment: estimated uncertainty ±(3 – 5)%
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] p [atm] D · 107 [m2/s]
298.15 272 1.95
298.15 408 1.25
298.15 543 0.95
298.15 681 0.78
298.15 818 0.65
298.15 1090 0.53
298.15 1360 0.45
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
118.0 ± 0.3 101.325 0.153 ± 1.5%
143.0 ± 0.3 101.325 0.212 ± 1.5%
177.0 ± 0.3 101.325 0.304 ± 1.5%
(continued)
225.0 ± 0.3 101.325 0.463 ± 1.5%

296.0 ± 0.3 101.325 0.735 ± 1.5%
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
293.3 ± 0.3 101.325 0.736 ± 1.1%
294.0 ± 0.3 101.325 0.732 ± 1.1%
373.7 ± 0.3 101.325 1.097 ± 1.1%
473.4 ± 0.3 101.325 1.598 ± 1.1%
472.8 ± 0.3 101.325 1.600 ± 1.1%
478.2 ± 0.3 101.325 1.602 ± 1.1%
477.4 ± 0.3 101.325 1.592 ± 1.1%
477.0 ± 0.3 101.325 1.616 ± 1.1%
523.2 ± 0.3 101.325 1.867 ± 1.1%
523.2 ± 0.3 101.325 1.882 ± 1.1%
571.4 ± 0.3 101.325 2.143 ± 1.1%
296.3 ± 0.3 101.325 0.724 ± 1.1%
296.3 ± 0.3 101.325 0.731 ± 1.1%
380.0 ± 0.3 101.325 1.092 ± 1.1%
381.0 ± 0.3 101.325 1.092 ± 1.1%
381.0 ± 0.3 101.325 1.078 ± 1.1%
477.0 ± 0.3 101.325 1.600 ± 1.1%
477.0 ± 0.3 101.325 1.595 ± 1.1%
573.5 ± 0.3 101.325 2.172 ± 1.1%
573.5 ± 0.3 101.325 2.166 ± 1.1%
692.5 ± 0.3 101.325 2.945 ± 1.1%
692.5 ± 0.3 101.325 2.884 ± 1.1%
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
293.3 ± 0.5 101.325 0.736 ± 1.1%
294.0 ± 0.5 101.325 0.732 ± 1.1%
373.7 ± 0.5 101.325 1.097 ± 1.1%
473.4 ± 0.5 101.325 1.598 ± 1.1%
472.8 ± 0.5 101.325 1.600 ± 1.1%
478.2 ± 0.5 101.325 1.602 ± 1.1%
477.4 ± 0.5 101.325 1.592 ± 1.1%
477.0 ± 0.5 101.325 1.616 ± 1.1%
523.2 ± 0.5 101.325 1.867 ± 1.1%
523.2 ± 0.5 101.325 1.882 ± 1.1%
571.4 ± 0.5 101.325 2.143 ± 1.1%

He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
296.3 ± 0.5 101.325 0.724 ± 1.1%
296.3 ± 0.5 101.325 0.731 ± 1.1%
380.0 ± 0.5 101.325 1.092 ± 1.1%
381.0 ± 0.5 101.325 1.092 ± 1.1%
381.0 ± 0.5 101.325 1.078 ± 1.1%
477.0 ± 0.5 101.325 1.600 ± 1.1%
477.0 ± 0.5 101.325 1.595 ± 1.1%
573.5 ± 0.5 101.325 2.172 ± 1.1%
573.5 ± 0.5 101.325 2.166 ± 1.1%
692.5 ± 0.5 101.325 2.945 ± 1.1%
692.5 ± 0.5 101.325 2.884 ± 1.1%
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
273.2 ± 0.1 101.325 0.645
315.1 ± 0.1 101.325 0.831
315.1 ± 0.1 101.325 0.835
323.1 ± 0.1 101.325 0.853
333.2 ± 0.1 101.325 0.932
353.2 ± 0.1 101.325 0.985
353.3 ± 0.1 101.325 1.005
393.9 ± 0.1 101.325 1.203
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.729 ± 0.009
323.15 101.325 0.809 ± 0.010
353.15 101.325 0.978 ± 0.010
383.15 101.325 1.122 ± 0.014
413.15 101.325 1.237 ± 0.014
443.15 101.325 1.401 ± 0.020
473.15 101.325 1.612 ± 0.014
498.15 101.325 1.728 ± 0.023

He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] p [bar] D · 104 [m2/s]
273.2 1.00 0.656 ± 2%
273.2 10.8 0.0605 ± 2%
273.2 20.3 0.0316 ± 2%
273.2 30.1 0.0211 ± 2%
273.2 40.0 0.0154 ± 2%
273.2 51.6 0.0120 ± 2%
273.2 60.1 0.0101 ± 2%
273.2 70.1 0.00860 ± 2%
273.2 88.0 0.00673 ± 2%
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
276.2 101.325 0.6460 ± 0.0014
317.2 101.325 0.7968 ± 0.0009
346.2 101.325 0.9244 ± 0.0029
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
287.0 ± 0.1 101.325 0.685 ± 2%
313.0 ± 0.1 101.325 0.815 ± 2%
343.0 ± 0.1 101.325 0.961 ± 2%
373.0 ± 0.1 101.325 1.11 ± 2%
401.0 ± 0.1 101.325 1.26 ± 2%
434.0 ± 0.1 101.325 1.45 ± 2%
464.6 ± 0.1 101.325 1.61 ± 2%
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
273 ± 0.1 101.325 0.637 ± 0.001
315 ± 0.1 101.325 0.822 ± 0.013
334 ± 0.1 101.325 0.870 ± 0.011
354 ± 0.1 101.325 0.998 ± 0.009
374 ± 0.1 101.325 1.086 ± 0.008
394 ± 0.1 101.325 1.186 ± 0.008

He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
276.2 101.325 0.646
287.9 101.325 0.697
296.2 101.325 0.729
298.2 101.325 0.725
298.2 101.325 0.754
317.2 101.325 0.7968
323.2 101.325 0.8090
346.2 101.325 0.9244
353.2 101.325 0.978
354.2 101.325 0.979
383.2 101.325 1.122
413.2 101.325 1.237
418.0 101.325 1.398
443.2 101.325 1.401
473.2 101.325 1.612
498.2 101.325 1.728
500.0 101.325 1.86
1000.0 101.325 6.25
1100.0 101.325 7.38
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
Diffusion of gas(1) in gas(2): D*12(T ); Method: TB Ref.: 1990T1
T [K] p [kPa] D · 104 [m2/s]
674 ± 3% 101.325 3.016 ± 3.5%
750 ± 3% 101.325 3.635 ± 3.5%
955 ± 3% 101.325 5.107 ± 3.5%
1037 ± 3% 101.325 6.209 ± 3.5%
1100 ± 3% 101.325 7.022 ± 3.5%
1178 ± 3% 101.325 8.118 ± 3.5%
1200 ± 3% 101.325 8.254 ± 3.5%
1242 ± 3% 101.325 8.103 ± 3.5%
1250 ± 3% 101.325 8.786 ± 3.5%
1375 ± 3% 101.325 10.513 ± 3.5%
1438 ± 3% 101.325 11.158 ± 3.5%
1600 ± 3% 101.325 12.805 ± 3.5%
1700 ± 3% 101.325 15.357 ± 3.5%
1900 ± 3% 101.325 17.845 ± 3.5%
2050 ± 3% 101.325 21.344 ± 3.5%

He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.742 ± 0.007
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
Diffusion of gas(1) in gas(2): D*12(T ); Method: INT Ref.: 1995K8
T [K] p [kPa] D · 104 [m2/s]
295.0 101.325 0.741 ± 0.015
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] p [Torr] D · 104 [m2/s]
287.0 690 0.754 ± 0.009
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
295.3 ± 0.1 101.325 0.74 ± 2%
He (1) helium 7440-59-7

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.76 ± 2%
References
1970D6 DuBro, G.A., Weissman, S.: Phys. Fluids 13 (1970) 2682–2688.
1986P9 Pugach, A.K., Lenskii, L.R.: Cholodinaja technika i technologija 43 (1986) 58–63.
1980Z4 Zwakhals, C.J., Reus, K.W.: Physica C 100 (1980) 231–244.
1972L3 Liner, J.C., Weissman, S.: J. Chem. Phys. 56 (1972) 2288–2290.

1990T1 Taylor, W.L., Wyrick, S.B., Hurly, J.J., Meeks, F.R.: J. Chem. Phys. 92 (1990) 6786–6793.
1994K8 Kosov, N.D., Poyarkov, I.V.: Izmer. Tekh. 5 (1994) 61–63.
1995K8 Kosov, N.D., Poyarkov, I.V.: Meas. Tech. 38 (1995) 1394–1396.

Diffusion of helium (1); dichloro-difluoro-methane (2) 1
Diffusion of helium (1); dichloro-difluoro-methane (2)

Vapor in Gas
He (1) helium 7440-59-7

T [K] p [kPa] D · 104 [m2/s]
298.05 ± 0.1 101.325 0.320
Reference


Vapor in Gas
He (1) helium 7440-59-7

CH4 (2) methane 74-82-8
T [K] p [kPa] D · 104 [m2/s]
373.0 101.325 1.005
He (1) helium 7440-59-7

CH4 (2) methane 74-82-8
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.68 ± 2%
He (1) helium 7440-59-7

CH4 (2) methane 74-82-8
Diffusion of gas(1) in gas(2): D*12(T ); Method: INT Ref.: 1995K8
T [K] p [kPa] D · 104 [m2/s]
295.0 101.325 0.650 ± 0.015
He (1) helium 7440-59-7

CH4 (2) methane 74-82-8
T [K] p [Torr] D · 104 [m2/s]
298.15 ± 0.05 746 0.709 ± 0.015
310.15 ± 0.05 746 0.752 ± 0.014
References
1995K8 Kosov, N.D., Poyarkov, I.V.: Meas. Tech. 38 (1995) 1394–1396.

Diffusion of helium (1); methanol (2) 1
Diffusion of helium (1); methanol (2)

Vapor in Gas
He (1) helium 7440-59-7

T [K] p [kPa] D · 104 [m2/s]
423.2 101.325 1.032
463.2 101.325 1.218
503.2 101.325 1.389
523.2 101.325 1.475
Reference


Vapor in Gas
He (1) helium 7440-59-7

T [K] p [kPa] D · 104 [m2/s]
295.6 101.325 0.702
He (1) helium 7440-59-7

T [K] p [kPa] D · 104 [m2/s]
295.6 ± 0.1 101.325 0.702 ± 2%
314.8 ± 0.1 101.325 0.788 ± 2%
345.0 ± 0.1 101.325 0.914 ± 2%
374.5 ± 0.1 101.325 1.05 ± 2%
400.0 ± 0.1 101.325 1.17 ± 2%
436.0 ± 0.1 101.325 1.35 ± 2%
470.0 ± 0.1 101.325 1.54 ± 2%
References


Vapor in Gas
He (1) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
273 101.325 0.54 ± 0.01
He (1) helium 7440-59-7

T [K] p [kPa] D · 104 [m2/s]
295.3 ± 0.1 101.325 0.59 ± 2%
He (1) helium 7440-59-7

T [K] p [Torr] D · 104 [m2/s]
287.0 690 0.652 ± 0.005
He (1) helium 7440-59-7

T [K] p [MPa] D · 106 [m2/s]
273.2 1.0 5.01 ± 3%
273.2 1.5 3.27 ± 3%
273.2 2.0 2.34 ± 3%
273.2 2.5 1.80 ± 3%
273.2 2.8 1.56 ± 3%
273.2 3.0 1.42 ± 3%
273.2 3.2 1.29 ± 3%
273.2 3.4 1.17 ± 3%
273.2 3.46 1.14 ± 3%
273.2 3.48 1.13 ± 3%
303.2 1.0 6.14 ± 3%
303.2 2.0 2.98 ± 3%
303.2 3.0 1.86 ± 3%
303.2 4.0 1.28 ± 3%
303.2 5.0 0.928 ± 3%
303.2 6.0 0.673 ± 3%
303.2 6.5 0.565 ± 3%
303.2 6.8 0.506 ± 3%
303.2 7.0 0.446 ± 3%
(continued)

323.2 1.0 6.85 ± 3%

323.2 2.0 3.35 ± 3%
323.2 3.0 2.07 ± 3%
323.2 4.0 1.49 ± 3%
323.2 5.0 1.13 ± 3%
323.2 6.0 0.882 ± 3%
323.2 7.0 0.520 ± 3%
He (1) helium 7440-59-7

T [K] p [atm] D · 104 [m2/s]
304.3 ± 0.1 10 0.0510 ± 3%
313.0 ± 0.1 10 0.0540 ± 3%
323.0 ± 0.1 10 0.0570 ± 3%
304.3 ± 0.1 20 0.0253 ± 3%
313.0 ± 0.1 20 0.0265 ± 3%
323.0 ± 0.1 20 0.0283 ± 3%
353.0 ± 0.1 20 0.0358 ± 3%
304.3 ± 0.1 30 0.0160 ± 3%
313.0 ± 0.1 30 0.0170 ± 3%
323.0 ± 0.1 30 0.0182 ± 3%
353.0 ± 0.1 30 0.0235 ± 3%
304.3 ± 0.1 40 0.0117 ± 3%
313.0 ± 0.1 40 0.0120 ± 3%
323.0 ± 0.1 40 0.0136 ± 3%
353.0 ± 0.1 40 0.0176 ± 3%
He (1) helium 7440-59-7

T [K] p [atm] D · 106 [m2/s]
304.3 ± 0.1 50 0.85 ± 3%
313.0 ± 0.1 50 0.96 ± 3%
323.0 ± 0.1 50 1.08 ± 3%
353.0 ± 0.1 50 1.41 ± 3%
304.3 ± 0.1 60 0.66 ± 3%
313.0 ± 0.1 60 0.75 ± 3%
323.0 ± 0.1 60 0.84 ± 3%
353.0 ± 0.1 60 1.17 ± 3%
304.3 ± 0.1 65 0.57 ± 3%
313.0 ± 0.1 65 0.67 ± 3%
304.3 ± 0.1 70 0.51 ± 3%
313.0 ± 0.1 70 0.58 ± 3%
323.0 ± 0.1 70 0.67 ± 3%
353.0 ± 0.1 70 0.96 ± 3%

He (1) helium 7440-59-7

T [K] p [atm] D · 106 [m2/s]
304.3 ± 0.1 10 5.10 ± 3%
304.3 ± 0.1 20 2.53 ± 3%
304.3 ± 0.1 30 1.60 ± 3%
304.3 ± 0.1 40 1.17 ± 3%
304.3 ± 0.1 50 0.85 ± 3%
304.3 ± 0.1 60 0.66 ± 3%
304.3 ± 0.1 65 0.57 ± 3%
304.3 ± 0.1 70 0.51 ± 3%
304.3 ± 0.1 71.25 0.47 ± 3%
304.3 ± 0.1 72.5 0.46 ± 3%
304.3 ± 0.1 73.75 0.44 ± 3%
304.3 ± 0.1 75.0 0.42 ± 3%
304.3 ± 0.1 77.5 0.40 ± 3%
304.3 ± 0.1 80 0.40 ± 3%
304.3 ± 0.1 85 0.36 ± 3%
313.0 ± 0.1 10 5.40 ± 3%
313.0 ± 0.1 20 2.65 ± 3%
313.0 ± 0.1 30 1.70 ± 3%
313.0 ± 0.1 40 1.20 ± 3%
313.0 ± 0.1 50 0.96 ± 3%
313.0 ± 0.1 60 0.75 ± 3%
313.0 ± 0.1 65 0.67 ± 3%
313.0 ± 0.1 67.5 0.61 ± 3%
313.0 ± 0.1 70 0.58 ± 3%
313.0 ± 0.1 72.5 0.53 ± 3%
313.0 ± 0.1 75.0 0.50 ± 3%
313.0 ± 0.1 80 0.46 ± 3%
313.0 ± 0.1 90 0.37 ± 3%
He (1) helium 7440-59-7

T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.612 ± 0.003
323.15 101.325 0.678 ± 0.012
353.15 101.325 0.800 ± 0.013
383.15 101.325 0.884 ± 0.003
413.15 101.325 1.040 ± 0.011
443.15 101.325 1.133 ± 0.018
473.15 101.325 1.279 ± 0.019
498.15 101.325 1.414 ± 0.023

He (1) helium 7440-59-7

T [K] p [Torr] D · 104 [m2/s]
298.15 ± 0.05 746 0.599 ± 0.010
310.15 ± 0.05 746 0.662 ± 0.007
He (1) helium 7440-59-7

T [K] p [bar] D · 104 [m2/s]
273.2 1.02 0.525 ± 2%
273.2 4.91 0.106 ± 2%
273.2 10.8 0.0466 ± 2%
273.2 15.7 0.0314 ± 2%
273.2 20.6 0.0230 ± 2%
273.2 25.5 0.0178 ± 2%
273.2 30.5 0.0145 ± 2%
He (1) helium 7440-59-7

T [K] p [kPa] D · 104 [m2/s]
287.0 ± 0.1 101.325 0.592 ± 2%
318.0 ± 0.1 101.325 0.684 ± 2%
344.8 ± 0.1 101.325 0.782 ± 2%
373.0 ± 0.1 101.325 0.897 ± 2%
400.0 ± 0.1 101.325 1.02 ± 2%
429.0 ± 0.1 101.325 1.13 ± 2%
464.6 ± 0.1 101.325 1.28 ± 2%
He (1) helium 7440-59-7

T [K] p [kPa] D · 104 [m2/s]
276.2 101.325 0.5312
298.2 101.325 0.6120
317.2 101.325 0.6607
323.2 101.325 0.6780
346.2 101.325 0.7646
353.2 101.325 0.800
383.2 101.325 0.884
413.2 101.325 1.040
443.2 101.325 1.133
473.2 101.325 1.279
498.2 101.325 1.414
He (1) helium 7440-59-7

T [K] p [kPa] D · 104 [m2/s]
297.5 101.325 0.605 ± 2%
361.5 101.325 0.838 ± 2%
414.5 101.325 1.06 ± 2%
463.5 101.325 1.28 ± 2%
510.0 101.325 1.48 ± 2%
555.0 101.325 1.74 ± 2%
598.0 101.325 1.98 ± 2%
641.0 101.325 2.21 ± 2%
683.5 101.325 2.47 ± 2%
725.5 101.325 2.74 ± 2%
766.0 101.325 3.01 ± 2%
810.5 101.325 3.30 ± 2%
He (1) helium 7440-59-7

T [K] p [kPa] D · 104 [m2/s]
313.8 ± 0.2 101.325 0.633
324.3 ± 0.2 101.325 0.668
332.3 ± 0.2 101.325 0.720
342.3 ± 0.2 101.325 0.746
353.1 ± 0.2 101.325 0.794
364.5 ± 0.2 101.325 0.816
He (1) helium 7440-59-7

T [K] p [kPa] D · 104 [m2/s]
216.6 101.325 0.326 ± 3%
216.8 101.325 0.337 ± 3%
217.7 101.325 0.349 ± 3%
218.5 101.325 0.363 ± 3%
219.8 101.325 0.373 ± 3%
221.7 101.325 0.377 ± 3%
225.1 101.325 0.385 ± 3%
He (1) helium 7440-59-7

T [K] p [kPa] D · 104 [m2/s]
276.2 101.325 0.5312 ± 0.0021
(continued)

317.2 101.325 0.6607 ± 0.0029

346.2 101.325 0.7646 ± 0.0029
He (1) helium 7440-59-7

T [K] p [atm] D · 104 [m2/s]
248.15 ± 0.01 9.97 0.0522
248.15 ± 0.01 29.9 0.0177
248.15 ± 0.01 49.8 0.0107
248.15 ± 0.01 59.8 0.00889
273.15 ± 0.01 9.97 0.0607
273.15 ± 0.01 29.9 0.0206
273.15 ± 0.01 49.8 0.0124
273.15 ± 0.01 59.8 0.0105
323.15 ± 0.01 9.97 0.0820
323.15 ± 0.01 29.9 0.0272
323.15 ± 0.01 49.8 0.0166
323.15 ± 0.01 59.8 0.0140
He (1) helium 7440-59-7

T [K] p [kPa] D · 104 [m2/s]
320.0 101.325 0.750
324.5 101.325 0.765
346.0 101.325 0.789
References
1982K3 Karpusin, A.G., Bibolov, S.K.: J. Eng. Phys. Thermophys. 43 (1982) 443–447.

Diffusion of helium (1); 1,2-dichloro-1,1,2,2-tetrafluoro-ethane (2) 1
Diffusion of helium (1); 1,2-dichloro-1,1,2,2-tetrafluoro-

ethane (2)
Vapor in Gas
He (1) helium 7440-59-7

T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.1 101.325 0.280
Reference


Vapor in Gas
He (1) helium 7440-59-7

C2H2 (2) ethyne 74-86-2
T [K] p [Torr] D · 104 [m2/s]
289.8 690 0.644 ± 0.006
Reference


Vapor in Gas
He (1) helium 7440-59-7

C2H4 (2) ethene 74-85-1
T [K] p [kPa] D · 104 [m2/s]
322.7 ± 0.1 101.325 0.620
Reference


Vapor in Gas
He (1) helium 7440-59-7

C2H6 (2) ethane 74-84-0
T [K] p [kPa] D · 104 [m2/s]
322.7 ± 0.1 101.325 0.582
Reference

Diffusion of helium (1); ethanol (2) 1
Diffusion of helium (1); ethanol (2)

Vapor in Gas
He (1) helium 7440-59-7

T [K] p [kPa] D · 104 [m2/s]
298.2 101.325 0.494
423.2 101.325 0.821
463.2 101.325 0.925
503.2 101.325 1.048
523.2 101.325 1.173
Reference

Diffusion of helium (1); propan-1-ol (2) 1
Diffusion of helium (1); propan-1-ol (2)

Vapor in Gas
He (1) helium 7440-59-7

C3H8O (2) propan-1-ol 71-23-8
T [K] p [kPa] D · 104 [m2/s]
423.2 101.325 0.676
463.2 101.325 0.761
503.2 101.325 0.896
523.2 101.325 0.959
Reference

Diffusion of helium (1); propan-2-ol (2) 1
Diffusion of helium (1); propan-2-ol (2)

Vapor in Gas
He (1) helium 7440-59-7

C3H8O (2) propan-2-ol 67-63-0
T [K] p [kPa] D · 104 [m2/s]
423.2 101.325 0.677
463.2 101.325 0.784
503.2 101.325 0.882
523.2 101.325 0.988
Reference

Diffusion of helium (1); butan-1-ol (2) 1
Diffusion of helium (1); butan-1-ol (2)

Vapor in Gas
He (1) helium 7440-59-7

C4H10O (2) butan-1-ol 71-36-3
T [K] p [kPa] D · 104 [m2/s]
423.2 101.325 0.587
463.2 101.325 0.689
503.2 101.325 0.792
523.2 101.325 0.841
Reference

Diffusion of helium (1); pentan-1-ol (2) 1
Diffusion of helium (1); pentan-1-ol (2)

Vapor in Gas
He (1) helium 7440-59-7

C5H12O (2) pentan-1-ol 71-41-0
T [K] p [kPa] D · 104 [m2/s]
423.2 101.325 0.507
463.2 101.325 0.578
503.2 101.325 0.666
523.2 101.325 0.729
Reference

Diffusion of helium (1); nitrobenzene (2) 1
Diffusion of helium (1); nitrobenzene (2)

Vapor in Gas
He (1) helium 7440-59-7

T [K] p [kPa] D · 104 [m2/s]
298.2 101.325 0.372
Reference

Diffusion of helium (1); benzene (2) 1
Diffusion of helium (1); benzene (2)

Vapor in Gas
He (1) helium 7440-59-7

C6H6 (2) benzene 71-43-2
T [K] p [kPa] D · 104 [m2/s]
298.2 101.325 0.384
423.2 101.325 0.610
463.2 101.325 0.715
503.2 101.325 0.815
523.2 101.325 0.861
Reference

Diffusion of helium (1); hexane (2) 1
Diffusion of helium (1); hexane (2)

Vapor in Gas
He (1) helium 7440-59-7

C6H14 (2) hexane 110-54-3
T [K] p [kPa] D · 104 [m2/s]
417.0 101.325 0.574
Reference

Diffusion of helium (1); hexan-1-ol (2) 1
Diffusion of helium (1); hexan-1-ol (2)

Vapor in Gas
He (1) helium 7440-59-7

C6H14O (2) hexan-1-ol 111-27-3
T [K] p [kPa] D · 104 [m2/s]
423.2 101.325 0.469
463.2 101.325 0.531
503.2 101.325 0.631
523.2 101.325 0.686
Reference

Diffusion of helium (1); heptane (2) 1
Diffusion of helium (1); heptane (2)

Vapor in Gas
He (1) helium 7440-59-7

C7H16 (2) heptane 142-82-5
T [K] p [kPa] D · 104 [m2/s]
303.2 101.325 0.265
Reference

Diffusion of helium (1); 2,4-dimethyl-pentane (2) 1
Diffusion of helium (1); 2,4-dimethyl-pentane (2)

Vapor in Gas
He (1) helium 7440-59-7

T [K] p [kPa] D · 104 [m2/s]
303.2 101.325 0.263
Reference

Diffusion of helium (1); octane (2) 1
Diffusion of helium (1); octane (2)

Vapor in Gas
He (1) helium 7440-59-7

C8H18 (2) octane 111-65-9
T [K] p [kPa] D · 104 [m2/s]
303.2 101.325 0.248
Reference

Diffusion of helium (1); 2,2,4-trimethyl-pentane (2) 1
Diffusion of helium (1); 2,2,4-trimethyl-pentane (2)

Vapor in Gas
He (1) helium 7440-59-7

T [K] p [kPa] D · 104 [m2/s]
303.2 101.325 0.253
Reference

Diffusion of helium (1); hydrogen-deuterium (2) 1
Diffusion of helium (1); hydrogen-deuterium (2)

Vapor in Gas
He (1) helium 7440-59-7

T [K] p [kPa] D
419.11 101.325 0.57359 ± 2.0 · 10–3
397.65 101.325 0.62498 ± 2.0 · 10–3
373.65 101.325 0.69255 ± 2.0 · 10–3
348.45 101.325 0.77797 ± 2.0 · 10–3
324.15 101.325 0.87755 ± 2.0 · 10–3
270.61 101.325 1.1824 ± 2.0 · 10–3
253.54 101.325 1.3153 ± 2.0 · 10–3
237.15 101.325 1.4696 ± 2.0 · 10–3
297.0 101.325 1.3914 · 10–4*
He (1) helium 7440-59-7

T [K] p [kPa] D
419.55 101.325 0.573 ± 1.5 · 10–3
398.65 101.325 0.623 ± 1.5 · 10–3
373.60 101.325 0.693 ± 1.5 · 10–3
348.41 101.325 0.778 ± 1.5 · 10–3
324.35 101.325 0.875 ± 1.5 · 10–3
270.73 101.325 1.179 ± 1.5 · 10–3
252.33 101.325 1.324 ± 1.5 · 10–3
237.85 101.325 1.459 ± 1.5 · 10–3
299.16 101.325 1.3760 · 10–4 *
Quasi-Lorentzian mixtures;
References


Vapor in Gas
He (1) helium 7440-59-7

D2 (2) deuterium 7782-39-0
T [K] p [kPa] D
419.63 101.325 0.56895 ± 2.0 · 10–3
398.68 101.325 0.61879 ± 2.0 · 10–3
373.59 101.325 0.68981 ± 2.0 · 10–3
348.38 101.325 0.77559 ± 2.0 · 10–3
324.79 101.325 0.87264 ± 2.0 · 10–3
270.71 101.325 1.1818 ± 2.0 · 10–3
255.20 101.325 1.3026 ± 2.0 · 10–3
237.26 101.325 1.4751 ± 2.0 · 10–3
297.0 101.325 1.2852 · 10–4 *
He (1) helium 7440-59-7

D2 (2) deuterium 7782-39-0
T [K] p [kPa] D
419.56 101.325 0.571 ± 1.5 · 10–3
398.67 101.325 0.622 ± 1.5 · 10–3
373.63 101.325 0.692 ± 1.5 · 10–3
348.43 101.325 0.777 ± 1.5 · 10–3
324.37 101.325 0.875 ± 1.5 · 10–3
270.75 101.325 1.180 ± 1.5 · 10–3
252.32 101.325 1.326 ± 1.5 · 10–3
237.88 101.325 1.462 ± 1.5 · 10–3
299.16 101.325 1.2728 · 10–4 *
References


Vapor in Gas
He (1) helium 7440-59-7

T [K] p [kPa] D · 104 [m2/s]
192.1 101.325 0.188 ± 1.5%
222.4 101.325 0.244 ± 1.5%
252.7 101.325 0.301 ± 1.5%
294.0 101.325 0.393 ± 1.5%
384.0 101.325 0.623 ± 1.5%
472.2 101.325 0.890 ± 1.5%
554.9 101.325 1.16 ± 1.5%
572.1 101.325 1.25 ± 1.5%
He (1) helium 7440-59-7

T [K] p [Torr] D · 104 [m2/s]
290.5 700 0.421 ± 0.003
He (1) helium 7440-59-7

T [K] p [kPa] D · 104 [m2/s]
290.5 ± 0.1 101.325 0.388 ± 2%
313.0 ± 0.1 101.325 0.430 ± 2%
344.4 ± 0.1 101.325 0.517 ± 2%
376.3 ± 0.1 101.325 0.601 ± 2%
399.4 ± 0.1 101.325 0.669 ± 2%
430.0 ± 0.1 101.325 0.755 ± 2%
464.6 ± 0.1 101.325 0.855 ± 2%
References

Diffusion of helium (1); hydrogen-tritium (2) 1
Diffusion of helium (1); hydrogen-tritium (2)

Vapor in Gas
He (1) helium 7440-59-7

T [K] p [kPa] D · 104 [m2/s]
194.7 101.325 0.745
323.4 101.325 1.743
373.6 101.325 2.255
Reference
1965A4 Amdur, I., Malinauskas, A.P.: J. Chem. Phys. 42 (1965) 3355–3360.


Vapor in Gas
He (1) helium 7440-59-7

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D
419.56 101.325 0.56766 ± 2.0 · 10–3
399.67 101.325 0.61602 ± 2.0 · 10–3
373.61 101.325 0.69148 ± 2.0 · 10–3
348.43 101.325 0.77619 ± 2.0 · 10–3
324.37 101.325 0.87373 ± 2.0 · 10–3
270.77 101.325 1.1829 ± 2.0 · 10–3
255.30 101.325 1.3057 ± 2.0 · 10–3
237.86 101.325 1.4692 ± 2.0 · 10–3
297.0 101.325 1.5603 · 10–4 *
He (1) helium 7440-59-7

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
299.16 ± 0.15 101.325 1.5305
He (1) helium 7440-59-7

H2 (2) hydrogen 1333-74-0
T [K] p [Torr] D · 104 [m2/s]
298.15 ± 0.05 746 1.624 ± 0.033
310.15 ± 0.05 746 1.682 ± 0.022
He (1) helium 7440-59-7

H2 (2) hydrogen 1333-74-0
T [K] p [Torr] D · 104 [m2/s]
298.15 642.5 1.339 ± 0.046
298.15 760.0 1.132

2 Diffusion of helium (1); hydrogen (2)
He (1) helium 7440-59-7

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D
237.87 101.325 1.461 ± 1.5 · 10–3
252.31 101.325 1.325 ± 1.5 · 10–3
270.76 101.325 1.179 ± 1.5 · 10–3
324.38 101.325 0.875 ± 1.5 · 10–3
348.42 101.325 0.777 ± 1.5 · 10–3
373.62 101.325 0.693 ± 1.5 · 10–3
398.66 101.325 0.622 ± 1.5 · 10–3
419.57 101.325 0.572 ± 1.5 · 10–3
299.19 ± 0.15 101.325 1.5305 · 10–4 *
Comment: relative diffusion coefficients [D(T0 ) / D(T )] are given as D*12; T0 = (299.19 ± 0.15) K;
He (1) helium 7440-59-7

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
194.7 101.325 0.760
194.7 101.325 0.745
273.2 101.325 1.299
273.2 101.325 1.292
323.4 101.325 1.746
323.4 101.325 1.743
373.6 101.325 2.246
373.6 101.325 2.255
He (1) helium 7440-59-7

H2 (2) hydrogen 1333-74-0
T [K] p [atm] D · 104 [m2/s]
313.0 ± 0.1 20 0.0690 ± 3%
313.0 ± 0.1 30 0.0469 ± 3%
313.0 ± 0.1 40 0.0347 ± 3%
313.0 ± 0.1 50 0.0280 ± 3%
313.0 ± 0.1 60 0.0240 ± 3%
313.0 ± 0.1 70 0.0210 ± 3%
313.0 ± 0.1 80 0.0182 ± 3%
313.0 ± 0.1 90 0.0164 ± 3%
313.0 ± 0.1 100 0.0149 ± 3%
313.0 ± 0.1 110 0.0134 ± 3%
313.0 ± 0.1 120 0.0124 ± 3%
313.0 ± 0.1 130 0.0118 ± 3%
313.0 ± 0.1 140 0.0112 ± 3%
353.0 ± 0.1 20 0.0825 ± 3%
(continued)
353.0 ± 0.1 30 0.0540 ± 3%

353.0 ± 0.1 40 0.0429 ± 3%
353.0 ± 0.1 50 0.0356 ± 3%
353.0 ± 0.1 60 0.0296 ± 3%
353.0 ± 0.1 70 0.0268 ± 3%
353.0 ± 0.1 80 0.0232 ± 3%
353.0 ± 0.1 90 0.0218 ± 3%
353.0 ± 0.1 100 0.0185 ± 3%
353.0 ± 0.1 110 0.0175 ± 3%
353.0 ± 0.1 120 0.0165 ± 3%
353.0 ± 0.1 130 0.0149 ± 3%
353.0 ± 0.1 140 0.0134 ± 3%
References

Diffusion of helium (1); water (2) 1
Diffusion of helium (1); water (2)

Vapor in Gas
He (1) helium 7440-59-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 104 [m2/s]
298.2 101.325 0.908
307.2 101.325 0.902
328.5 101.325 1.011
352.5 101.325 1.121
Reference


Vapor in Gas
He (1) helium 7440-59-7

H 3N (2) ammonia 7664-41-7
T [K] p [kPa] D · 104 [m2/s]
296.6 101.325 0.831
297.1 101.325 0.842
He (1) helium 7440-59-7

H 3N (2) ammonia 7664-41-7
T [K] p [Torr] D · 104 [m2/s]
297.05 640.1 0.923 ± 0.007
References

Diffusion of helium (1); helium-3 (2) 1
Diffusion of helium (1); helium-3 (2)

Vapor in Gas
He (1) helium 7440-59-7

He-3 (2) helium-3 14762-55-1
T [K] p [atm] D · 104 [m2/s]
303 1 1.88 ± 0.09
403 1 3.06 ± 0.04
500 1 4.39 ± 0.08
600 1 6.08 ± 0.17
698 1 7.56 ± 0.14
806 1 9.63 ± 0.38
Comment: estimated uncertainty ±(3–5)%
Reference


Vapor in Gas
He (1) helium 7440-59-7

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
307.0 101.325 0.680 ± 0.8%
351.5 101.325 0.881 ± 1.2%
398.5 101.325 1.09 ± 0.1%
448.0 101.325 1.33 ± 0.4%
496.0 101.325 1.56 ± 1.2%
547.5 101.325 1.85 ± 0.6%
595.0 101.325 2.14 ± 0.5%
645.0 101.325 2.43 ± 0.9%
692.0 101.325 2.73 ± 0.0%
738.5 101.325 3.09 ± 0.2%
785.5 101.325 3.36 ± 0.4%
836.0 101.325 3.66 ± 0.5%
879.5 101.325 4.07 ± 0.3%
927.5 101.325 4.51 ± 0.7%
974.0 101.325 4.80 ± 0.4%
1025 101.325 5.26 ± 0.7%
1072 101.325 5.66 ± 0.3%
1119 101.325 6.11 ± 0.2%
1170 101.325 6.50 ± 0.5%
1218 101.325 7.20 ± 0.6%
1274 101.325 7.71 ± 0.4%
He (1) helium 7440-59-7

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
358.1 ± 0.2% 101.325 0.879 ± 1.5%
497.9 ± 0.2% 101.325 1.54 ± 1.5%
647.9 ± 0.2% 101.325 2.42 ± 1.5%
798.4 ± 0.2% 101.325 3.39 ± 1.5%
998.2 ± 0.2% 101.325 4.94 ± 1.5%
1194.2 ± 0.2% 101.325 6.89 ± 1.5%
References


Vapor in Gas
He (1) helium 7440-59-7

T [K] p [Torr] D
420.36 340 0.56848
398.22 340 0.62193
373.50 340 0.69159
348.32 340 0.77596
324.35 340 0.87369
271.25 340 1.17700
255.50 340 1.30070
237.28 340 1.47240
Comment: relative diffusion coefficients [D(T0 ) / D(T )] are given as D*12; T0 = 299.14 K
Reference


Vapor in Gas
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
T [K] p [Torr] D · 104 [m2/s]
298.15 ± 0.05 746 0.702 ± 0.013
310.15 ± 0.05 746 0.743 ± 0.013
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
Diffusion of gas(1) in gas(2): D*12(T ); Method: PF Ref.: 1969E1
T [K] p [kPa] D · 104 [m2/s]
297.0 101.325 0.707
340.0 101.325 0.891
415.0 101.325 1.271
460.0 101.325 1.493
575.0 101.325 2.128
750.0 101.325 3.235
882.0 101.325 4.204
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
T [K] p [atm] D · 104 [m2/s]
303 1 0.750 ± 0.007
324 1 0.798 ± 0.018
403 1 1.13 ± 0.02
500 1 1.65 ± 0.02
600 1 2.20 ± 0.02
698 1 2.81 ± 0.02
806 1 3.75 ± 0.09
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.73 ± 2%

He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D
212.24 101.325 1.783 ± 1.5 · 10–3
235.66 101.325 1.493 ± 1.5 · 10–3
255.72 101.325 1.296 ± 1.5 · 10–3
276.32 101.325 1.138 ± 1.5 · 10–3
329.64 101.325 0.756 ± 1.5 · 10–3
352.23 101.325 0.752 ± 1.5 · 10–3
376.45 101.325 0.672 ± 1.5 · 10–3
398.68 101.325 0.609 ± 1.5 · 10–3
420.67 101.325 0.556 ± 1.5 · 10–3
445.32 101.325 0.504 ± 1.5 · 10–3
299.19 ± 0.15 101.325 0.7345 · 10–4 *
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D
212.33 101.325 1.778 ± 1.5 · 10–3
235.56 101.325 1.490 ± 1.5 · 10–3
255.64 101.325 1.294 ± 1.5 · 10–3
276.41 101.325 1.137 ± 1.5 · 10–3
329.58 101.325 0.757 ± 1.5 · 10–3
352.42 101.325 0.758 ± 1.5 · 10–3
376.26 101.325 0.674 ± 1.5 · 10–3
398.63 101.325 0.612 ± 1.5 · 10–3
420.54 101.325 0.560 ± 1.5 · 10–3
445.22 101.325 0.505 ± 1.5 · 10–3
299.19 ± 0.15 101.325 0.7033 · 10–4 *
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
299.16 ± 0.15 101.325 0.7345
299.16 ± 0.15 101.325 0.7033

He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
T [K] p [Torr] D · 104 [m2/s]
297.75 644.9 0.808 ± 0.006
298.15 760.0 0.687
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
293.0 101.325 0.705
300.0 101.325 0.743
323.2 101.325 0.766
353.2 101.325 0.893
383.2 101.325 1.077
413.2 101.325 1.200
443.2 101.325 1.289
473.2 101.325 1.569
498.2 101.325 1.65
600.0 101.325 2.40
900.0 101.325 4.76
1200.0 101.325 7.74
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
310.2 ± 0.2 101.325 0.784
315.2 ± 0.2 101.325 0.812
323.2 ± 0.2 101.325 0.858
330.2 ± 0.2 101.325 0.867
334.4 ± 0.2 101.325 0.898
340.2 ± 0.2 101.325 0.927
346.2 ± 0.2 101.325 0.948
353.9 ± 0.2 101.325 0.978
359.5 ± 0.2 101.325 1.025
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.687 ± 0.006
323.15 101.325 0.766 ± 0.008
353.15 101.325 0.893 ± 0.005
383.15 101.325 1.077 ± 0.020
(continued)
413.15 101.325 1.200 ± 0.019

443.15 101.325 1.289 ± 0.014
473.15 101.325 1.569 ± 0.007
498.15 101.325 1.650 ± 0.021
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
T [K] p [atm] D · 107 [m2/s]
298.15 272 2.00
298.15 408 1.23
298.15 543 0.91
298.15 681 0.73
298.15 818 0.62
298.15 1090 0.53
298.15 1360 0.50
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
296.0 101.325 0.707 ± 2%
355.0 101.325 0.948 ± 2%
416.5 101.325 1.22 ± 2%
464.5 101.325 1.48 ± 2%
509.5 101.325 1.71 ± 2%
557.5 101.325 2.00 ± 2%
601.5 101.325 2.26 ± 2%
640.5 101.325 2.50 ± 2%
686.0 101.325 2.79 ± 2%
717.0 101.325 3.00 ± 2%
771.0 101.325 3.38 ± 2%
812.0 101.325 3.66 ± 2%
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
289.4 ± 0.1 101.325 0.651 ± 2%
315.6 ± 0.1 101.325 0.788 ± 2%
348.4 ± 0.1 101.325 0.915 ± 2%
374.5 ± 0.1 101.325 1.07 ± 2%
400.0 ± 0.1 101.325 1.15 ± 2%
433.0 ± 0.1 101.325 1.31 ± 2%
470.0 ± 0.1 101.325 1.53 ± 2%

He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
293.0 101.325 0.605 ± 3.6%
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
T [K] p [Torr] D · 104 [m2/s]
289.4 690 0.717 ± 0.024
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
295.3 ± 0.1 101.325 0.72 ± 2%
He (1) helium 7440-59-7

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.679 ± 0.003
References
1969E1 Ellis, C.S., Holsen, J.N.: Ind. Eng. Chem. Fundam. 8 (1969) 787–791.
1994K8 Kosov, N.D., Poyarkov, I.V.: Izmer. Tekh. 5 (1994) 61–63.


Vapor in Gas
He (1) helium 7440-59-7

Ne (2) neon 7440-01-9
T [K] p [kPa] D · 104 [m2/s]
299.0 101.325 1.116 ± 0.6%
374.0 101.325 1.614 ± 0.6%
479.5 101.325 2.433 ± 0.6%
573.5 101.325 3.290 ± 0.6%
683.0 101.325 4.450 ± 0.6%
He (1) helium 7440-59-7

Ne (2) neon 7440-01-9
T [K] p [kPa] D · 104 [m2/s]
76.6 ± 0.1 101.325 0.107
87.2 ± 0.1 101.325 0.130
194.8 ± 0.1 101.325 0.543
301.0 ± 0.1 101.325 1.08
303.9 ± 0.1 101.325 1.10
305.0 ± 0.1 101.325 1.11
313.8 ± 0.1 101.325 1.16
324.5 ± 0.1 101.325 1.26
334.5 ± 0.1 101.325 1.33
335.2 ± 0.1 101.325 1.29
343.5 ± 0.1 101.325 1.37
360.5 ± 0.1 101.325 1.46
364.6 ± 0.1 101.325 1.47
He (1) helium 7440-59-7

Ne (2) neon 7440-01-9
T [K] p [kPa] D · 104 [m2/s]
118.0 ± 0.3 101.325 0.232 ± 1.5%
154.0 ± 0.3 101.325 0.361 ± 1.5%
197.0 ± 0.3 101.325 0.557 ± 1.5%
231.0 ± 0.3 101.325 0.716 ± 1.5%
296.0 ± 0.3 101.325 1.080 ± 1.5%
References

933–935.


Vapor in Gas
He (1) helium 7440-59-7

O2 (2) oxygen 7782-44-7
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.729 ± 0.010
323.15 101.325 0.809 ± 0.007
353.15 101.325 0.987 ± 0.003
383.15 101.325 1.120 ± 0.016
413.15 101.325 1.245 ± 0.014
443.15 101.325 1.420 ± 0.008
473.15 101.325 1.595 ± 0.026
498.15 101.325 1.683 ± 0.018
He (1) helium 7440-59-7

O2 (2) oxygen 7782-44-7
T [K] p [Torr] D · 104 [m2/s]
287.0 690 0.644 ± 0.006
He (1) helium 7440-59-7

O2 (2) oxygen 7782-44-7
T [K] p [Torr] D · 104 [m2/s]
297.35 647.0 0.840 ± 0.011
298.15 760.0 0.718
He (1) helium 7440-59-7

O2 (2) oxygen 7782-44-7
T [K] p [kPa] D · 104 [m2/s]
298.2 101.325 0.737
298.2 101.325 0.718
323.2 101.325 0.809
353.2 101.325 0.987
383.2 101.325 1.120
413.2 101.325 1.245
443.2 101.325 1.420
473.2 101.325 1.595
498.2 101.325 1.683

References

Diffusion of helium (1); tritium (2) 1
Diffusion of helium (1); tritium (2)

Vapor in Gas
He (1) helium 7440-59-7

T2 (2) tritium 10028-17-8
T [K] p [kPa] D · 104 [m2/s]
194.7 101.325 0.760
323.2 101.325 1.746
373.6 101.325 2.246
Reference


Vapor in Gas
He (1) helium 7440-59-7

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
297.0 101.325 0.568 ± 1.4%
349.5 101.325 0.686 ± 3.4%
407.3 101.325 0.965 ± 1.3%
445.5 101.325 1.09 ± 0.9%
495.5 101.325 1.27 ± 1.9%
544.5 101.325 1.50 ± 0.6%
593.5 101.325 1.78 ± 1.5%
641.0 101.325 1.98 ± 0.8%
696.2 101.325 2.37 ± 2.1%
736.5 101.325 2.48 ± 0.5%
785.4 101.325 2.77 ± 0.9%
831.7 101.325 2.96 ± 0.4%
878.0 101.325 3.33 ± 1.3%
925.5 101.325 3.48 ± 0.9%
927.0 101.325 3.93 ± 0.5%
1022 101.325 4.12 ± 0.7%
1067 101.325 4.65 ± 1.4%
1118 101.325 4.85 ± 0.4%
1166 101.325 5.46 ± 1.3%
1221 101.325 5.69 ± 0.3%
1270 101.325 6.51 ± 3.0%
He (1) helium 7440-59-7

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
273.3 ± 0.1 101.325 0.473
315.0 ± 0.1 101.325 0.572
354.2 ± 0.1 101.325 0.721
394.0 ± 0.1 101.325 0.882
References

Diffusion of helium-3 (1); helium (2) 1
Diffusion of helium-3 (1); helium (2)

Vapor in Gas
He-3 (1) helium-3 14762-55-1

He (2) helium 7440-59-7
Diffusion of gas(1) in gas(2): D*12(T ); Method: DB Ref.: 1958B1
T [K] p [kPa] D · 104 [m2/s]
14.4 101.325 0.0124
19.6 101.325 0.0199
64.8 101.325 0.147
76.1 101.325 0.187
192.0 101.325 0.843
296.0 101.325 1.68
He-3 (1) helium-3 14762-55-1

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
76.5 101.325 0.178
87.2 101.325 0.218
195.4 101.325 0.878
304.2 101.325 1.79
313.8 101.325 1.90
324.7 101.325 1.97
342.1 101.325 2.18
344.0 101.325 2.18
428.3 101.325 3.30
582.9 101.325 5.57
740.0 101.325 8.43
888.3 101.325 11.8
References
1958B1 Bendt, P.J.: Phys. Rev. 110 (1958) 85–89.

Diffusion of mercury (1); air (2) 1
Diffusion of mercury (1); air (2)

Vapor in Gas
Hg (1) mercury 7439-97-6

Air (2) air 132259-10-0
Diffusion of gas(1) in gas(2): D*12(T ); Method: OTE Ref.: 1999M1
T [K] p [kPa] D · 104 [m2/s]
273.15 101.325 0.1194
Hg (1) mercury 7439-97-6

Air (2) air 132259-10-0
T [K] p [kPa] D · 106 [m2/s]
298.15 ± 0.05 101.325 14.23 ± 0.031
References
1999M1 Massman, W.J.: Atmos. Environ. 33 (1999) 453–457.

Diffusion of mercury (1); argon (2) 1
Diffusion of mercury (1); argon (2)

Vapor in Gas
Hg (1) mercury 7439-97-6

Ar (2) argon 7440-37-1
Integral Diffusion Coefficient: D(T ); Method: STEFAN Ref.: 1991G1
T [K] p [atm] D · 104 [m2/s]
449.2 ± 1 1 0.235
479.2 ± 1 1 0.267
508.2 ± 1 1 0.295
525.2 ± 1 1 0.309
538.2 ± 1 1 0.318
569.2 ± 1 1 0.348
590.2 ± 1 1 0.368
Reference
1991G1 Gardner, P.J., Pang, P., Preston, S.R.: J. Chem. Eng. Data 36 (1991) 265–268.

Diffusion of mercury (1); carbon dioxide (2) 1
Diffusion of mercury (1); carbon dioxide (2)

Vapor in Gas
Hg (1) mercury 7439-97-6

T [K] p [atm] D · 104 [m2/s]
431.2 ± 1 1 0.234
451.7 ± 1 1 0.238
471.2 ± 1 1 0.241
491.2 ± 1 1 0.283
501.2 ± 1 1 0.284
533.2 ± 1 1 0.313
551.2 ± 1 1 0.324
573.2 ± 1 1 0.350
Reference

Diffusion of mercury (1); hydrogen (2) 1
Diffusion of mercury (1); hydrogen (2)

Vapor in Gas
Hg (1) mercury 7439-97-6

H2 (2) hydrogen 1333-74-0
T [K] p [atm] D · 104 [m2/s]
421.2 ± 1 1 1.13
429.2 ± 1 1 1.19
450.2 ± 1 1 1.29
469.2 ± 1 1 1.39
480.2 ± 1 1 1.41
510.2 ± 1 1 1.61
539.2 ± 1 1 1.66
569.2 ± 1 1 1.86
589.2 ± 1 1 1.91
Reference

Diffusion of mercury (1); helium (2) 1
Diffusion of mercury (1); helium (2)

Vapor in Gas
Hg (1) mercury 7439-97-6

He (2) helium 7440-59-7
T [K] p [atm] D · 104 [m2/s]
430.2 ± 1 1 1.12
448.7 ± 1 1 1.18
468.7 ± 1 1 1.28
497.2 ± 1 1 1.37
507.2 ± 1 1 1.48
527.7 ± 1 1 1.54
546.2 ± 1 1 1.63
565.2 ± 1 1 1.74
Reference

Diffusion of mercury (1); nitrogen (2) 1
Diffusion of mercury (1); nitrogen (2)

Vapor in Gas
Hg (1) mercury 7439-97-6

N2 (2) nitrogen 7727-37-9
T [K] p [atm] D · 104 [m2/s]
429.2 ± 1 1 0.273
450.2 ± 1 1 0.302
479.2 ± 1 1 0.340
509.2 ± 1 1 0.378
519.2 ± 1 1 0.396
540.2 ± 1 1 0.410
570.2 ± 1 1 0.455
590.2 ± 1 1 0.482
Hg (1) mercury 7439-97-6

N2 (2) nitrogen 7727-37-9
Diffusion of gas(1) in gas(2): D*12(T ); Method: OTE Ref.: 1999M1
T [K] p [kPa] D · 104 [m2/s]
273.15 101.325 0.1211
References
1999M1 Massman, W.J.: Atmos. Environ. 33 (1999) 453–457.

Diffusion of sodium iodide (1); argon (2) 1
Diffusion of sodium iodide (1); argon (2)

Vapor in Gas
INa (1) sodium iodide 7681-82-5

Ar (2) argon 7440-37-1
Diffusion of gas(1) in gas(2): D*12(T ); Method: STEFAN Ref.: 2001T1
T [K] p [kPa] D · 104 [m2/s]
933 101.325 0.71
933 101.325 0.62
945 101.325 0.78
945 101.325 0.87
958 101.325 0.57
958 101.325 0.58
958 101.325 0.93
984 101.325 0.80
984 101.325 0.79
984 101.325 0.57
Reference
2001T1 Tashiro, S., Sagawa, N.: J. Nucl. Sci. Technol. 38 (2001) 551–556.

Diffusion of sodium iodide (1); krypton (2) 1
Diffusion of sodium iodide (1); krypton (2)

Vapor in Gas

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
933 101.325 0.57
958 101.325 0.44
958 101.325 0.43
971 101.325 0.47
971 101.325 0.43
984 101.325 0.54
984 101.325 0.69
984 101.325 0.48
Reference

Diffusion of sodium iodide (1); xenon (2) 1
Diffusion of sodium iodide (1); xenon (2)

Vapor in Gas

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
933 101.325 0.40
945 101.325 0.39
945 101.325 0.37
945 101.325 0.53
958 101.325 0.38
Reference


Vapor in Gas
Kr (1) krypton 7439-90-9

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
300.0 101.325 0.137 ± 2.5%
345.0 101.325 0.191 ± 2.9%
349.5 101.325 0.187 ± 3.3%
447.0 101.325 0.289 ± 2.1%
497.8 101.325 0.366 ± 1.7%
546.3 101.325 0.424 ± 0.6%
595.0 101.325 0.486 ± 2.0%
639.0 101.325 0.542 ± 1.3%
642.8 101.325 0.541 ± 0.1%
691.0 101.325 0.618 ± 1.1%
738.5 101.325 0.677 ± 0.8%
788.0 101.325 0.755 ± 0.1%
832.0 101.325 0.856 ± 0.0%
879.0 101.325 0.930 ± 0.2%
926.5 101.325 1.03 ± 0.7%
975.0 101.325 1.11 ± 1.1%
1025 101.325 1.23 ± 0.2%
1073 101.325 1.30 ± 0.4%
1121 101.325 1.42 ± 0.7%
1170 101.325 1.52 ± 0.8%
1221 101.325 1.61 ± 0.5%
1274 101.325 1.71 ± 1.4%
Kr (1) krypton 7439-90-9

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
273 ± 0.1 101.325 0.115 ± 0.001
273 ± 0.1 101.325 0.117 ± 0.002
315 ± 0.1 101.325 0.154 ± 0.003
334 ± 0.1 101.325 0.176 ± 0.002
354 ± 0.1 101.325 0.197 ± 0.000
374 ± 0.1 101.325 0.207 ± 0.006
394 ± 0.1 101.325 0.235 ± 0.002

2 Diffusion of krypton (1); argon (2)
Kr (1) krypton 7439-90-9

Ar (2) argon 7440-37-1
T [K] p [atm] D · 109 [m2/s]
85.44 ± 0.05 2.0 1.35 ± 0.10
86.10 ± 0.05 2.0 1.40 ± 0.10
86.38 ± 0.05 2.0 1.38 ± 0.06
87.94 ± 0.05 2.0 1.54 ± 0.08
90.20 ± 0.05 2.0 1.62 ± 0.05
90.20 ± 0.05 2.0 1.72 ± 0.04
Kr (1) krypton 7439-90-9

Ar (2) argon 7440-37-1
Diffusion of gas(1) in gas(2): D*12(T ); Method: PF Ref.: 1962D3
T [K] p [atm] D · 107 [m2/s]
248.15 13.73 7.29
248.15 41.84 2.364
248.15 66.53 1.513
248.15 92.60 1.058
248.15 132.7 0.735
248.15 185.2 0.545
Kr (1) krypton 7439-90-9

Ar (2) argon 7440-37-1
T [K] p [atm] D · 107 [m2/s]
308.15 14.44 9.94
308.15 28.59 5.30
308.15 41.26 3.446
308.15 41.77 3.556
308.15 41.97 3.496
308.15 57.68 2.714
308.15 68.84 2.151
308.15 102.8 1.487
308.15 132.8 1.171
Kr (1) krypton 7439-90-9

Ar (2) argon 7440-37-1
T [K] p [atm] D · 107 [m2/s]
308.25 2.525 5.602
308.25 2.593 5.540
308.25 4.219 3.397
308.25 5.185 2.819
308.25 9.240 1.563
308.25 14.92 0.9876
(continued)
308.25 25.09 0.5701

308.25 43.46 0.3347
Kr (1) krypton 7439-90-9

Ar (2) argon 7440-37-1
T [K] p [atm] D · 107 [m2/s]
308.15 7.15 20.06
308.15 11.00 13.50
308.15 11.00 13.19
308.15 11.02 13.19
308.15 20.63 7.135
308.15 20.65 7.102
308.15 34.49 4.279
308.15 48.42 3.030
308.15 48.44 3.049
308.15 73.42 2.028
308.15 73.48 2.041
308.15 133.02 1.132
308.15 133.12 1.128
308.15 133.15 1.121
308.15 133.15 1.135
308.15 133.21 1.132
308.15 133.22 1.138
308.15 133.32 1.143
308.15 103.65 1.447
308.15 174.5 0.8754
308.15 206.5 0.7259
308.15 206.5 0.7474
308.15 242.8 0.6434
308.15 272.9 0.5516
308.15 272.9 0.5801
308.15 302.8 0.5281
308.15 333.1 0.4914
308.15 375.7 0.4451
308.15 375.8 0.4320
308.15 410.1 0.4216
Kr (1) krypton 7439-90-9

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 109 [m2/s]
87.6 ± 0.05 101.325 1.575 ± 0.042
Comment: 85Kr as tracer diffusing in Ar

4 Diffusion of krypton (1); argon (2)
Kr (1) krypton 7439-90-9

Ar (2) argon 7440-37-1
Diffusion of gas(1) in gas(2): D*12(T ); Method: CT Ref.: 1990D7
T [K] p [kPa] D · 104 [m2/s]
300.0 ± 0.001 101.325 0.1403 ± 0.2%
Comment: 85Kr diffusing in Ar
Kr (1) krypton 7439-90-9

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
302.6 101.325 0.1376 ± 0.0067
References

Diffusion of krypton (1); tetrafluoro-methane (2) 1
Diffusion of krypton (1); tetrafluoro-methane (2)

Vapor in Gas
Kr (1) krypton 7439-90-9

Diffusion of gas(1) in gas(2): D*12(T ); Method: OEC Ref.: 1978R4
T [K] p [atm] D · 108 [m2/s]
243.39 18.35 24.5 ± 1.5
243.44 30.52 11.9 ± 0.9
243.44 37.28 8.9 ± 0.5
243.53 44.67 6.3 ± 0.6
243.24 46.28 5.9 ± 0.2
243.19 52.35 4.3 ± 0.3
243.24 53.11 3.90 ± 0.15
243.20 63.07 2.7 ± 0.3
243.23 71.53 2.2 ± 0.3
243.05 73.11 2.05 ± 0.10
243.22 83.26 1.7 ± 0.1
243.18 83.90 1.76 ± 0.09
243.49 115.35 1.44 ± 0.04
243.38 125.50 1.485 ± 0.025
Comment: Kr in Kr - CF4 mixture at very low Kr concentration (0.01%)
Reference
1978R4 Ricci, F.P., Ricci, M.A., Rocca, D.: Physica A 92 (1978) 475–482.

Diffusion of krypton (1); trichloro-methane (2) 1
Diffusion of krypton (1); trichloro-methane (2)

Vapor in Gas
Kr (1) krypton 7439-90-9

T [K] p [kPa] D · 104 [m2/s]
283.6 ± 0.05 101.325 0.0468 ± 1%
293.1 ± 0.05 101.325 0.0501 ± 1%
303.2 ± 0.05 101.325 0.0537 ± 1%
313.0 ± 0.05 101.325 0.0572 ± 1%
Reference
1966S5 Srivastava, B.N., Saran, A.: Physica 32 (1966) 110–118.


Vapor in Gas
Kr (1) krypton 7439-90-9

CH4 (2) methane 74-82-8
T [K] p [atm] D · 107 [m2/s]
206.1 14.0 5.190 ± 0.096
202.8 30.0 2.09 ± 0.02
201.7 34.2 1.74 ± 0.03
201.8 38.9 1.41 ± 0.04
201.8 52.1 0.818 ± 0.03
202.2 56.8 0.566 ± 0.002
201.8 58.3 0.547 ± 0.013
201.4 62.2 0.402 ± 0.013
202.8 66.1 0.428 ± 0.008
203.0 69.3 0.384 ± 0.002
201.5 67.4 0.345 ± 0.006
203.2 74.1 0.356 ± 0.006
201.3 80.9 0.316 ± 0.007
203.2 81.7 0.313 ± 0.005
203.2 85.6 0.331 ± 0.007
202.2 101.0 0.250 ± 0.003
201.9 129.0 0.225 ± 0.003
188.0 93.5 0.210 ± 0.003
185.0 185.0 0.179 ± 0.003
Comment: 85K in Kr - CH4 mixtures at very low concentration of Kr
Reference
1977D1 De Santis, A., Ricci, F.P.: Physica A 87 (1977) 404–410.

Diffusion of krypton (1); carbon monoxide (2) 1
Diffusion of krypton (1); carbon monoxide (2)

Vapor in Gas
Kr (1) krypton 7439-90-9

T [K] p [kPa] D · 104 [m2/s]
274.2 ± 0.05 101.325 0.130 ± 1%
288.2 ± 0.05 101.325 0.144 ± 1%
303.2 ± 0.05 101.325 0.157 ± 1%
318.8 ± 0.5 101.325 0.173 ± 1%
Reference
1967S3 Singh, Y., Saran, A., Srivastava, B.N.: J. Phys. Soc. Jpn. 23 (1967) 1110–1113.


Vapor in Gas
Kr (1) krypton 7439-90-9

T [K] p [atm] D · 107 [m2/s]
308.15 5.765 20.47
308.15 13.66 8.408
308.15 21.55 5.046
308.15 30.36 3.485
308.15 43.80 2.251
308.15 57.48 1.535
308.15 57.89 1.522
Reference

Diffusion of krypton (1); ethene (2) 1
Diffusion of krypton (1); ethene (2)

Vapor in Gas
Kr (1) krypton 7439-90-9

C2H4 (2) ethene 74-85-1
T [K] p [atm] D · 107 [m2/s]
298.15 13.69 7.975
298.15 30.25 3.179
298.15 45.80 1.823
298.15 62.07 0.9800
298.15 70.07 0.6401
298.15 79.94 0.5002
298.15 89.46 0.4517
298.15 112.12 0.3815
Reference

Diffusion of krypton (1); propan-2-one (2) 1
Diffusion of krypton (1); propan-2-one (2)

Vapor in Gas
Kr (1) krypton 7439-90-9

T [K] p [kPa] D · 104 [m2/s]
283.5 ± 0.05 101.325 0.0609 ± 1%
293.3 ± 0.05 101.325 0.0654 ± 1%
303.2 ± 0.05 101.325 0.0699 ± 1%
313.0 ± 0.05 101.325 0.0746 ± 1%
Reference
1966S5 Srivastava, B.N., Saran, A.: Physica 32 (1966) 110–118.

Diffusion of krypton (1); diethyl ether (2) 1
Diffusion of krypton (1); diethyl ether (2)

Vapor in Gas
Kr (1) krypton 7439-90-9

T [K] p [kPa] D · 104 [m2/s]
274.3 ± 0.05 101.325 0.0429 ± 1%
288.1 ± 0.05 101.325 0.0479 ± 1%
303.2 ± 0.05 101.325 0.0534 ± 1%
318.2 ± 0.05 101.325 0.0588 ± 1%
Reference
1966S3 Srivastava, B.N., Saran, A.: Can. J. Phys. 44 (1966) 2595–2600.

Diffusion of krypton (1); hydrogen-deuterium (2) 1
Diffusion of krypton (1); hydrogen-deuterium (2)

Vapor in Gas
Kr (1) krypton 7439-90-9

T [K] p [kPa] D
419.31 101.325 0.563 ± 1.5 · 10–3
398.40 101.325 0.613 ± 1.5 · 10–3
373.34 101.325 0.685 ± 1.5 · 10–3
348.45 101.325 0.769 ± 1.5 · 10–3
324.43 101.325 0.870 ± 1.5 · 10–3
271.73 101.325 1.183 ± 1.5 · 10–3
252.63 101.325 1.344 ± 1.5 · 10–3
237.53 101.325 1.499 ± 1.5 · 10–3
299.16 101.325 0.5788 · 10–4 *
Quasi-Lorentzian mixtures; *: absolute value in [m2/s]
Reference

Diffusion of krypton (1); deuterium (2) 1
Diffusion of krypton (1); deuterium (2)

Vapor in Gas
Kr (1) krypton 7439-90-9

D2 (2) deuterium 7782-39-0
T [K] p [kPa] D
419.33 101.325 0.562 ± 1.5 · 10–3
398.42 101.325 0.612 ± 1.5 · 10–3
373.31 101.325 0.683 ± 1.5 · 10–3
348.46 101.325 0.768 ± 1.5 · 10–3
324.45 101.325 0.869 ± 1.5 · 10–3
271.76 101.325 1.183 ± 1.5 · 10–3
252.60 101.325 1.345 ± 1.5 · 10–3
237.56 101.325 1.501 ± 1.5 · 10–3
299.16 101.325 0.5062 · 10–4 *
Reference


Vapor in Gas
Kr (1) krypton 7439-90-9

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
299.16 ± 0.15 101.325 0.7064
Kr (1) krypton 7439-90-9

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
296 101.325 0.685 ± 2%
Kr (1) krypton 7439-90-9

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D
237.55 101.325 1.502 ± 1.5 · 10–3
252.61 101.325 1.346 ± 1.5 · 10–3
271.75 101.325 1.183 ± 1.5 · 10–3
324.46 101.325 0.869 ± 1.5 · 10–3
348.48 101.325 0.769 ± 1.5 · 10–3
373.32 101.325 0.684 ± 1.5 · 10–3
398.41 101.325 0.613 ± 1.5 · 10–3
419.34 101.325 0.563 ± 1.5 · 10–3
299.19 ± 0.15 101.325 0.7064 · 10–4 *
References
1968A3 Annis, B.K., Humphreys, A.E., Mason, E.A.: Phys. Fluids 11 (1968) 2122–2131.

Diffusion of krypton (1); helium (2) 1
Diffusion of krypton (1); helium (2)

Vapor in Gas
Kr (1) krypton 7439-90-9

He (2) helium 7440-59-7
T [K] p [atm] D · 107 [m2/s]
308.25 3.709 16.92
308.25 4.471 14.08
308.25 6.743 9.48
308.25 20.55 3.222
308.25 30.74 2.170
308.25 52.06 1.338
308.25 60.15 1.150
Kr (1) krypton 7439-90-9

He (2) helium 7440-59-7
T [K] p [atm] D · 107 [m2/s]
308.15 24.81 27.22
308.15 60.17 11.56
308.15 91.50 7.695
308.15 111.51 6.354
308.15 130.28 5.565
308.15 186.09 4.101
308.15 211.94 3.574
308.15 240.2 3.268
308.15 279.0 2.801
308.15 312.1 2.563
308.15 353.6 2.326
308.15 415.1 2.057
Kr (1) krypton 7439-90-9

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
273 ± 0.1 101.325 0.535 ± 0.010
315 ± 0.1 101.325 0.668 ± 0.005
334 ± 0.1 101.325 0.769 ± 0.012
354 ± 0.1 101.325 0.827 ± 0.003
374 ± 0.1 101.325 0.904 ± 0.014
394 ± 0.1 101.325 0.992 ± 0.012

2 Diffusion of krypton (1); helium (2)
Kr (1) krypton 7439-90-9

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
302.6 101.325 0.625 ± 0.017
Kr (1) krypton 7439-90-9

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
296 101.325 0.605 ± 2%
References
1968A3 Annis, B.K., Humphreys, A.E., Mason, E.A.: Phys. Fluids 11 (1968) 2122–2131.

Diffusion of krypton (1); nitrogen oxide (2) 1
Diffusion of krypton (1); nitrogen oxide (2)

Vapor in Gas
Kr (1) krypton 7439-90-9

T [K] p [kPa] D · 104 [m2/s]
274.3 ± 0.05 101.325 0.128 ± 1%
288.2 ± 0.05 101.325 0.138 ± 1%
303.2 ± 0.05 101.325 0.156 ± 1%
318.2 ± 0.05 101.325 0.171 ± 1%
Kr (1) krypton 7439-90-9

T [K] p [Torr] D
420.52 340 0.54251
398.38 340 0.59712
373.56 340 0.66974
348.62 340 0.75772
324.40 340 0.86293
271.68 340 1.19270
255.44 340 1.33550
237.42 340 1.53010
Comment: relative diffusion coefficients [D(T0 ) / D(T )] are given as D*12; T0 = 299.14 K
References
1967S3 Singh, Y., Saran, A., Srivastava, B.N.: J. Phys. Soc. Jpn. 23 (1967) 1110–1113.


Vapor in Gas
Kr (1) krypton 7439-90-9

N2 (2) nitrogen 7727-37-9
T [K] p [atm] D · 107 [m2/s]
248.25 7.37 15.49
248.25 22.18 5.10
248.25 42.22 2.844
248.25 103.08 1.098
248.25 131.6 0.944
248.25 207.7 0.655
308.25 3.137 5.011
308.25 4.933 3.263
308.25 7.614 2.131
308.25 22.10 0.7434
308.25 24.14 0.7014
308.25 34.93 0.4738
308.15 17.88 8.845
308.15 24.55 6.591
308.15 34.93 4.714
308.15 69.33 2.438
308.15 135.74 1.289
308.15 203.8 0.9192
308.15 273.5 0.7175
308.15 339.7 0.6287
308.15 408.4 0.5487
Kr (1) krypton 7439-90-9

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D
445.52 ± 0.02 101.325 0.505 ± 0.1%
420.34 ± 0.02 101.325 0.551 ± 0.1%
298.58 ± 0.02 101.325 0.614 ± 0.1%
376.33 ± 0.02 101.325 0.675 ± 0.1%
352.36 ± 0.02 101.325 0.759 ± 0.1%
329.53 ± 0.02 101.325 0.854 ± 0.1%
276.44 ± 0.02 101.325 1.165 ± 0.1%
255.72 ± 0.02 101.325 1.337 ± 0.1%
235.42 ± 0.02 101.325 1.549 ± 0.1%
212.28 ± 0.02 101.325 1.859 ± 0.1%
299.16 ± 0.02 101.325 0.1578 · 10–4 *
Comment: relative diffusion coefficients [D(299.16 K) / D(T )] are given as D*12; Lorentzian mixtures;

2 Diffusion of krypton (1); nitrogen (2)
Kr (1) krypton 7439-90-9

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D
445.61 ± 0.02 101.325 0.506 ± 0.1%
420.42 ± 0.02 101.325 0.559 ± 0.1%
398.63 ± 0.02 101.325 0.618 ± 0.1%
376.25 ± 0.02 101.325 0.678 ± 0.1%
352.43 ± 0.02 101.325 0.766 ± 0.1%
329.62 ± 0.02 101.325 0.860 ± 0.1%
276.51 ± 0.02 101.325 1.169 ± 0.1%
255.68 ± 0.02 101.325 1.341 ± 0.1%
235.37 ± 0.02 101.325 1.552 ± 0.1%
212.32 ± 0.02 101.325 1.863 ± 0.1%
299.16 ± 0.02 101.325 0.1545 · 10–4 *
Kr (1) krypton 7439-90-9

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 109 [m2/s]
77.6 ± 0.053 101.325 2.446 ± 0.032
Comment: 85Kr diffusing in nitrogen
References

Diffusion of krypton (1); neon (2) 1
Diffusion of krypton (1); neon (2)

Vapor in Gas
Kr (1) krypton 7439-90-9

Ne (2) neon 7440-01-9
T [K] p [kPa] D · 104 [m2/s]
302.6 101.325 0.2488 ± 0.0262
Kr (1) krypton 7439-90-9

Ne (2) neon 7440-01-9
T [K] p [kPa] D · 104 [m2/s]
269.0 101.325 0.252 ± 5.8%
402.0 101.325 0.412 ± 2.3%
443.0 101.325 0.485 ± 1.2%
492.7 101.325 0.595 ± 2.0%
544.9 101.325 0.714 ± 0.9%
593.0 101.325 0.794 ± 1.5%
640.0 101.325 0.956 ± 0.6%
688.1 101.325 1.07 ± 1.3%
735.2 101.325 1.20 ± 0.4%
779.0 101.325 1.33 ± 1.0%
830.2 101.325 1.54 ± 0.3%
877.0 101.325 1.66 ± 0.5%
923.0 101.325 1.75 ± 1.2%
971.0 101.325 1.96 ± 1.3%
1021 101.325 2.12 ± 3.6%
1071 101.325 2.28 ± 2.0%
1119 101.325 2.49 ± 2.0%
1169 101.325 2.66 ± 1.0%
1220 101.325 2.70 ± 2.3%
1271 101.325 2.97 ± 1.2%
References


Vapor in Gas
Kr (1) krypton 7439-90-9

O2 (2) oxygen 7782-44-7
T [K] p [kPa] D · 109 [m2/s]
77.6 ± 0.05 101.325 1.497 ± 0.037
87.6 ± 0.05 101.325 1.979 ± 0.042
Comment: 85Kr diffusing as tracer
Reference

Diffusion of krypton (1); sulfur dioxide (2) 1
Diffusion of krypton (1); sulfur dioxide (2)

Vapor in Gas
Kr (1) krypton 7439-90-9

T [K] p [kPa] D · 104 [m2/s]
274.2 ± 0.05 101.325 0.0712 ± 1%
288.2 ± 0.05 101.325 0.0783 ± 1%
303.2 ± 0.05 101.325 0.0864 ± 1%
318.1 ± 0.05 101.325 0.0942 ± 1%
Reference
1966S3 Srivastava, B.N., Saran, A.: Can. J. Phys. 44 (1966) 2595–2600.


Vapor in Gas
Kr (1) krypton 7439-90-9

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
297.7 101.325 0.072 ± 3.4%
348.7 101.325 0.081 ± 3.8%
395.9 101.325 0.132 ± 1.5%
446.8 101.325 0.164 ± 1.6%
495.1 101.325 0.191 ± 2.2%
546.4 101.325 0.234 ± 0.3%
593.7 101.325 0.262 ± 3.9%
641.1 101.325 0.323 ± 3.1%
690.1 101.325 0.357 ± 2.9%
735.8 101.325 0.386 ± 1.0%
784.3 101.325 0.454 ± 0.4%
831.9 101.325 0.498 ± 2.7%
877.5 101.325 0.539 ± 0.6%
927.5 101.325 0.600 ± 4.0%
973.8 101.325 0.654 ± 1.1%
1025 101.325 0.723 ± 1.0%
1073 101.325 0.769 ± 2.6%
1123 101.325 0.849 ± 0.6%
1172 101.325 0.899 ± 3.7%
1218 101.325 0.971 ± 1.2%
1223 101.325 0.983 ± 0.5%
1270 101.325 1.04 ± 0.6%
Kr (1) krypton 7439-90-9

Xe (2) xenon 7440-63-3
T [K] p [atm] D · 106 [m2/s]
298.26 ± 0.05 3.947 1.8539 ± 0.0067
298.23 ± 0.05 3.957 1.8413 ± 0.0056
298.04 ± 0.05 6.926 1.0380 ± 0.0019
298.21 ± 0.05 9.378 0.7561 ± 0.0015
298.21 ± 0.05 9.396 0.7512 ± 0.0028
298.25 ± 0.05 11.736 0.5939 ± 0.0012
298.20 ± 0.05 14.143 0.48523 ± 0.00097
298.23 ± 0.05 14.147 0.48337 ± 0.00076
298.18 ± 0.05 14.868 0.45612 ± 0.00099
298.28 ± 0.05 14.883 0.4572 ± 0.0012
298.25 ± 0.05 16.837 0.39883 ± 0.00069
(continued)
298.17 ± 0.05 16.846 0.39713 ± 0.00086

298.21 ± 0.05 19.260 0.34179 ± 0.00039
298.22 ± 0.05 19.313 0.33912 ± 0.00054
298.14 ± 0.05 19.311 0.33934 ± 0.00094
298.27 ± 0.05 19.766 0.33223 ± 0.00077
298.24 ± 0.05 22.270 0.28935 ± 0.00046
298.22 ± 0.05 22.270 0.28971 ± 0.00041
298.25 ± 0.05 23.990 0.26460 ± 0.00058
298.25 ± 0.05 24.843 0.25312 ± 0.00036
298.24 ± 0.05 27.461 0.22510 ± 0.00042
298.19 ± 0.05 28.295 0.21718 ± 0.00037
298.20 ± 0.05 29.113 0.20970 ± 0.00036
298.31 ± 0.05 29.383 0.20644 ± 0.00039
298.19 ± 0.05 29.379 0.20680 ± 0.00042
298.16 ± 0.05 29.378 0.20634 ± 0.00042
298.20 ± 0.05 31.773 0.18760 ± 0.00024
298.23 ± 0.05 31.811 0.18740 ± 0.00032
298.17 ± 0.05 32.878 0.17846 ± 0.00036
298.22 ± 0.05 33.800 0.17375 ± 0.00027
298.16 ± 0.05 33.850 0.17323 ± 0.00027
298.16 ± 0.05 34.398 0.1696 ± 0.0011
298.26 ± 0.05 36.757 0.15500 ± 0.00034
298.22 ± 0.05 36.959 0.15418 ± 0.00049
298.11 ± 0.05 39.617 0.1394 ± 0.0020
298.16 ± 0.05 39.815 0.1399 ± 0.0022
298.22 ± 0.05 41.234 0.13320 ± 0.00034
298.06 ± 0.05 44.184 0.1185 ± 0.0016
298.11 ± 0.05 44.303 0.1197 ± 0.0019
298.21 ± 0.05 45.539 0.11469 ± 0.00028
298.11 ± 0.05 47.053 0.10952 ± 0.00067
298.16 ± 0.05 51.840 0.0920 ± 0.0012
298.15 ± 0.05 53.485 0.08595 ± 0.00048
298.06 ± 0.05 56.540 0.07692 ± 0.00024
298.11 ± 0.05 57.833 0.07288 ± 0.00046
298.06 ± 0.05 59.429 0.06728 ± 0.00022
298.06 ± 0.05 60.894 0.06456 ± 0.00041
298.06 ± 0.05 61.643 0.06203 ± 0.00041
298.06 ± 0.05 62.770 0.05637 ± 0.00050
298.06 ± 0.05 67.701 0.0408 ± 0.0013
Comment: 85Kr in Kr - Xe mixtures at very low concentration of Kr
Kr (1) krypton 7439-90-9

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
302.6 101.325 0.0823 ± 0.014

Kr (1) krypton 7439-90-9

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
358.6 ± 0.2% 101.325 0.113 ± 1.5%
507.9 ± 0.2% 101.325 0.210 ± 1.5%
599.7 ± 0.2% 101.325 0.293 ± 1.5%
715.3 ± 0.2% 101.325 0.401 ± 1.5%
807.2 ± 0.2% 101.325 0.494 ± 1.5%
911.6 ± 0.2% 101.325 0.621 ± 1.5%
994.3 ± 0.2% 101.325 0.712 ± 1.5%
1112.5 ± 0.2% 101.325 0.889 ± 1.5%
1119.0 ± 0.2% 101.325 0.996 ± 1.5%
References
1979C1 Codastefano, P., Rocca, D., Zanza, V.: Physica A 96 (1979) 454–464.

Diffusion of nitrogen atom (1); nitrogen (2) 1
Diffusion of nitrogen atom (1); nitrogen (2)

Vapor in Gas
N (1) nitrogen atom 17778-88-0

N2 (2) nitrogen 7727-37-9
Diffusion of gas(1) in gas(2): D*12(T ); Method: No Stand Ref.: 1964M8
T [K] p [Torr] D · 102 [m2/s]
280 1.0 2.21
Reference
1964M8 Morgan, J.E., Schiff, H.I.: Can. J. Chem. 42 (1964) 2300–2306.


Vapor in Gas
N2 (1) nitrogen 7727-37-9

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
293.0 101.325 0.194
N2 (1) nitrogen 7727-37-9

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
300.4 101.325 0.21
350.2 101.325 0.27
400.7 101.325 0.34
450.2 101.325 0.41
552.0 101.325 0.58
600.2 101.325 0.68
660.1 101.325 0.79
700.1 101.325 0.88
759.0 101.325 1.01
800.3 101.325 1.11
860.1 101.325 1.22
900.2 101.325 1.31
960.4 101.325 1.53
1000.4 101.325 1.88
References

Diffusion of nitrogen (1); dichloro-difluoro-methane (2) 1
Diffusion of nitrogen (1); dichloro-difluoro-methane (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
297.65 ± 0.1 101.325 0.091
N2 (1) nitrogen 7727-37-9

Diffusion of gas(1) in gas(2): D*12(T ); Method: No Stand Ref.: 1982P4
T [K] p [kPa] D · 106 [m2/s]
292.0 101.325 9.23 ± 4%
Comment: derived from thermal conductivity
References
1982P4 Peters, H.C., Breunese, J.N., Hermans, L.J.F.: Int. J. Thermophys. 3 (1982) 27–34.

Diffusion of nitrogen (1); trichloro-fluoro-methane (2) 1
Diffusion of nitrogen (1); trichloro-fluoro-methane (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

Diffusion of gas(1) in gas(2): D*12(T ); Method: No Stand Ref.: 1982P4
T [K] p [kPa] D · 106 [m2/s]
292.0 101.325 7.73 ± 2%
Comment: derived from thermal conductivity
Reference
1982P4 Peters, H.C., Breunese, J.N., Hermans, L.J.F.: Int. J. Thermophys. 3 (1982) 27–34.

Diffusion of nitrogen (1); chloro-methane (2) 1
Diffusion of nitrogen (1); chloro-methane (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

Diffusion of gas(1) in gas(2): D*12(T ); Method: STEFAN Ref.: 1978H10
T [K] p [kPa] D · 104 [m2/s]
298.2 ± 0.2 101.325 0.129 ± 2%
313.2 ± 0.2 101.325 0.140 ± 2%
333.2 ± 0.2 101.325 0.157 ± 2%
353.2 ± 0.2 101.325 0.179 ± 2%
373.2 ± 0.2 101.325 0.193 ± 2%
Reference
1978H10 Hsieh, M.W., Cheh, H.Y.: Ind. Eng. Chem. Fundam. 17 (1978) 210–212.

Diffusion of nitrogen (1); methane (2) 1
Diffusion of nitrogen (1); methane (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

CH4 (2) methane 74-82-8
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.220 ± 2%
N2 (1) nitrogen 7727-37-9

CH4 (2) methane 74-82-8
Diffusion of gas(1) in gas(2): D*12(T ); Method: STEFAN Ref.: 1978H10
T [K] p [kPa] D · 104 [m2/s]
298.2 ± 0.2 101.325 0.214 ± 2%
323.2 ± 0.2 101.325 0.250 ± 2%
348.2 ± 0.2 101.325 0.283 ± 2%
373.2 ± 0.2 101.325 0.323 ± 2%
384.2 ± 0.2 101.325 0.339 ± 2%
References
1978H10 Hsieh, M.W., Cheh, H.Y.: Ind. Eng. Chem. Fundam. 17 (1978) 210–212.

Diffusion of nitrogen (1); carbon monoxide (2) 1
Diffusion of nitrogen (1); carbon monoxide (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
289.5 101.325 0.211
295.8 101.325 0.212
Reference


Vapor in Gas
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
289.2 101.325 0.158
293.0 101.325 0.163
298.0 101.325 0.165
298.0 101.325 0.167
298.2 101.325 0.163
298.2 101.325 0.181
300.0 101.325 0.173
600.0 101.325 0.605
900.0 101.325 1.217
1200.0 101.325 1.976
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
300.4 101.325 0.17
350.6 101.325 0.22
400.7 101.325 0.28
451.2 101.325 0.34
500.8 101.325 0.40
559.0 101.325 0.50
600.4 101.325 0.56
652.0 101.325 0.64
700.6 101.325 0.73
800.9 101.325 0.92
854.0 101.325 1.02
900.2 101.325 1.12
970.2 101.325 1.26
1000.8 101.325 1.35
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
313.7 ± 0.2 101.325 0.201
323.2 ± 0.2 101.325 0.209
(continued)

2 Diffusion of nitrogen (1); carbon dioxide (2)
332.6 ± 0.2 101.325 0.232

342.6 ± 0.2 101.325 0.238
354.2 ± 0.2 101.325 0.251
365.1 ± 0.2 101.325 0.269
N2 (1) nitrogen 7727-37-9

T [K] p [Torr] D · 104 [m2/s]
297.15 642.0 0.192 ± 0.001
298.15 760.0 0.163
N2 (1) nitrogen 7727-37-9

Diffusion of gas(1) in gas(2): D*12(T ); Method: PF Ref.: 1969E1
T [K] p [kPa] D · 104 [m2/s]
298.0 101.325 0.167
340.0 101.325 0.211
416.0 101.325 0.286
483.0 101.325 0.423
590.0 101.325 0.575
749.0 101.325 0.843
880.0 101.325 1.050
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
273 ± 1.0 101.325 0.145
296 ± 1.0 101.325 0.171
381 ± 1.0 101.325 0.263
441 ± 1.0 101.325 0.343
514 ± 1.0 101.325 0.452
550 ± 1.0 101.325 0.511
633 ± 1.0 101.325 0.652
674 ± 1.0 101.325 0.730
730 ± 1.0 101.325 0.839
741 ± 1.0 101.325 0.865
794 ± 1.0 101.325 0.974
905 ± 1.0 101.325 1.20
1005 ± 1.0 101.325 1.42
1107 ± 1.0 101.325 1.68
1223 ± 1.0 101.325 1.98
1307 ± 1.0 101.325 2.20

N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
216.6 101.325 0.095 ± 3%
216.9 101.325 0.105 ± 3%
216.8 101.325 0.103 ± 3%
217.3 101.325 0.110 ± 3%
218.5 101.325 0.110 ± 3%
220.2 101.325 0.110 ± 3%
225.4 101.325 0.117 ± 3%
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
304.0 101.325 0.171
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.1 101.325 0.168
References
1969E1 Ellis, C.S., Holsen, J.N.: Ind. Eng. Chem. Fundam. 8 (1969) 787–791.

Diffusion of nitrogen (1); 1,2-dichloro-1,1,2,2-tetrafluoro-ethane (2) 1
Diffusion of nitrogen (1); 1,2-dichloro-1,1,2,2-tetrafluoro-

ethane (2)
Vapor in Gas
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.1 101.325 0.082
Reference

Diffusion of nitrogen (1); ethene (2) 1
Diffusion of nitrogen (1); ethene (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

C2H4 (2) ethene 74-85-1
T [K] p [kPa] D · 104 [m2/s]
293.2 ± 0.1 101.325 0.180
N2 (1) nitrogen 7727-37-9

C2H4 (2) ethene 74-85-1
T [K] p [kPa] D · 104 [m2/s]
302.6 ± 0.2 101.325 0.170 ± 0.0034
N2 (1) nitrogen 7727-37-9

C2H4 (2) ethene 74-85-1
T [K] p [kPa] D · 104 [m2/s]
291.2 101.325 0.163
298.0 101.325 0.163
References

Diffusion of nitrogen (1); ethane (2) 1
Diffusion of nitrogen (1); ethane (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

C2H6 (2) ethane 74-84-0
T [K] p [kPa] D · 104 [m2/s]
298.0 101.325 0.148
Reference

Diffusion of nitrogen (1); ethanol (2) 1
Diffusion of nitrogen (1); ethanol (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
363.15 ± 0.1 101.325 0.180
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
299.0 101.325 0.097 ± 0.006
299.0 101.325 0.117 ± 0.008
References
1978K4 Kosov, N.D., Kurlapov, L.I., Chernyak, S.N.: Zh. Fiz. Khim. 52 (1978) 1721–1724.

Diffusion of nitrogen (1); propan-2-one (2) 1
Diffusion of nitrogen (1); propan-2-one (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
363.15 ± 0.1 101.325 0.150
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
300.0 101.325 0.107 ± 0.003
300.0 101.325 0.107 ± 0.002
References

Diffusion of nitrogen (1); butane (2) 1
Diffusion of nitrogen (1); butane (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

C4H10 (2) butane 106-97-8
Diffusion of gas(1) in gas(2): D*12(T ); Method: CT Ref.: 1973G4
T [K] p [Torr] D · 104 [m2/s]
298.15 740.7 0.10117 ± 5.0 · 10–9
Comment: improved interferometric method; values of p · D*12(T ) given
N2 (1) nitrogen 7727-37-9

C4H10 (2) butane 106-97-8
T [K] p [kPa] D · 104 [m2/s]
302.4 ± 0.2 101.325 0.100 ± 0.0015
N2 (1) nitrogen 7727-37-9

C4H10 (2) butane 106-97-8
T [K] p [kPa] D · 104 [m2/s]
298.0 101.325 0.096
References
1973G4 Gotoh, S., Manner, M., Sørensen, J.P., Stewart, W.E.: Ind. Eng. Chem. Fundam. 12 (1973)
119–123.

Diffusion of nitrogen (1); 2-methyl-propane (2) 1
Diffusion of nitrogen (1); 2-methyl-propane (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
298.0 101.325 0.0905
Reference

Diffusion of nitrogen (1); diethyl ether (2) 1
Diffusion of nitrogen (1); diethyl ether (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
299.0 101.325 0.098 ± 0.005
299.0 101.325 0.104 ± 0.006
Reference

Diffusion of nitrogen (1); thiophene (2) 1
Diffusion of nitrogen (1); thiophene (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
302.1 101.325 0.0992
Reference

Diffusion of nitrogen (1); tetrahydro-thiophene (2) 1
Diffusion of nitrogen (1); tetrahydro-thiophene (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
318.5 101.325 0.0985
Reference

Diffusion of nitrogen (1); pyridine (2) 1
Diffusion of nitrogen (1); pyridine (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
317.9 101.325 0.1068
Reference

Diffusion of nitrogen (1); piperidine (2) 1
Diffusion of nitrogen (1); piperidine (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
314.9 101.325 0.0953
Reference

Diffusion of nitrogen (1); nitrobenzene (2) 1
Diffusion of nitrogen (1); nitrobenzene (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
493.15 ± 0.1 101.325 0.200
Reference

Diffusion of nitrogen (1); benzene (2) 1
Diffusion of nitrogen (1); benzene (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

C6H6 (2) benzene 71-43-2
T [K] p [kPa] D · 104 [m2/s]
300.0 101.325 0.090 ± 0.002
300.0 101.325 0.092 ± 0.002
N2 (1) nitrogen 7727-37-9

C6H6 (2) benzene 71-43-2
T [K] p [kPa] D · 104 [m2/s]
373.15 ± 0.1 101.325 0.130
N2 (1) nitrogen 7727-37-9

C6H6 (2) benzene 71-43-2
T [K] p [kPa] D · 104 [m2/s]
311.3 101.325 0.1022
References

Diffusion of nitrogen (1); aniline (2) 1
Diffusion of nitrogen (1); aniline (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
473.15 ± 0.1 101.325 0.190
Reference

Diffusion of nitrogen (1); methyl-cyclopentane (2) 1
Diffusion of nitrogen (1); methyl-cyclopentane (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
288.6 101.325 0.0760
Reference

Diffusion of nitrogen (1); cyclohexane (2) 1
Diffusion of nitrogen (1); cyclohexane (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
288.6 101.325 0.0760
Reference

Diffusion of nitrogen (1); hexane (2) 1
Diffusion of nitrogen (1); hexane (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

C6H14 (2) hexane 110-54-3
T [K] p [kPa] D · 104 [m2/s]
373.15 ± 0.1 101.325 0.112
N2 (1) nitrogen 7727-37-9

C6H14 (2) hexane 110-54-3
T [K] p [kPa] D · 104 [m2/s]
288.6 101.325 0.0757
References

Diffusion of nitrogen (1); 2,3-dimethyl-butane (2) 1
Diffusion of nitrogen (1); 2,3-dimethyl-butane (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
288.7 101.325 0.0751
Reference

Diffusion of nitrogen (1); toluene (2) 1
Diffusion of nitrogen (1); toluene (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

C7H8 (2) toluene 108-88-3
T [K] p [kPa] D · 104 [m2/s]
393.15 ± 0.1 101.325 0.140
Reference

Diffusion of nitrogen (1); heptane (2) 1
Diffusion of nitrogen (1); heptane (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

C7H16 (2) heptane 142-82-5
T [K] p [kPa] D · 104 [m2/s]
303.2 101.325 0.0740
Reference

Diffusion of nitrogen (1); 2,4-dimethyl-pentane (2) 1
Diffusion of nitrogen (1); 2,4-dimethyl-pentane (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
303.1 101.325 0.0744
Reference

Diffusion of nitrogen (1); 2,2,4-trimethyl-pentane (2) 1
Diffusion of nitrogen (1); 2,2,4-trimethyl-pentane (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
303.3 101.325 0.0713
Reference

Diffusion of nitrogen (1); octane (2) 1
Diffusion of nitrogen (1); octane (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

C8H18 (2) octane 111-65-9
T [K] p [kPa] D · 104 [m2/s]
303.1 101.325 0.0726
Reference

Diffusion of nitrogen (1); 2,3,3-trimethyl-heptane (2) 1
Diffusion of nitrogen (1); 2,3,3-trimethyl-heptane (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

C10H22 (2) 2,3,3-trimethyl-heptane 52896-93-2
T [K] p [kPa] D · 104 [m2/s]
363.8 101.325 0.0684
Reference

Diffusion of nitrogen (1); decane (2) 1
Diffusion of nitrogen (1); decane (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

C10H22 (2) decane 124-18-5
T [K] p [kPa] D · 104 [m2/s]
363.6 101.325 0.0841
Reference

Diffusion of nitrogen (1); dodecane (2) 1
Diffusion of nitrogen (1); dodecane (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

C12H26 (2) dodecane 112-40-3
T [K] p [kPa] D · 104 [m2/s]
399.4 101.325 0.0813
Reference

Diffusion of nitrogen (1); sulfur hexafluoride (2) 1
Diffusion of nitrogen (1); sulfur hexafluoride (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

T [K]a p [Torr] D · 104 [m2/s]
289.8 690 0.114 ± 0.001
Reference

Diffusion of nitrogen (1); hydrogen (2) 1
Diffusion of nitrogen (1); hydrogen (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
298.15 101.325 0.78
N2 (1) nitrogen 7727-37-9

H2 (2) hydrogen 1333-74-0
T [K] p [atm] D · 104 [m2/s]
273 1 0.710
298 1 0.800
323 1 0.940
363 1 1.150
473 1 1.860
273 50 0.01140
298 50 0.01340
323 50 0.01570
363 50 0.01870
473 50 0.02893
273 100 0.00570
298 100 0.00651
323 100 0.00771
363 100 0.00982
473 100 0.01425
273 200 0.00281
298 200 0.00328
323 200 0.00401
363 200 0.00499
473 200 0.00737
273 300 0.00199
363 300 0.00340
N2 (1) nitrogen 7727-37-9

H2 (2) hydrogen 1333-74-0
Integral Diffusion Coefficient: D(T ); Method: M-INT Ref.: 1965C2
T [K] p [kPa] D · 104 [m2/s]
293.15 101.325 0.68 ± 0.003

2 Diffusion of nitrogen (1); hydrogen (2)
N2 (1) nitrogen 7727-37-9

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.804
303.15 101.325 0.791
333.15 101.325 0.946
363.15 101.325 1.10
393.15 101.325 1.24
423.15 101.325 1.41
453.15 101.325 1.60
453.15 101.325 1.57
N2 (1) nitrogen 7727-37-9

H2 (2) hydrogen 1333-74-0
T [K] p [Torr] D · 104 [m2/s]
297.15 649.1 0.914 ± 0.019
273.15 760.0 0.687
References
1964B5 Bondarenko, A.G., Golubew, I.F.: Gaz. Promysl. 9 (1964) 50–54.
1965C2 Cordes, H., Kerl, K.: Z. Phys. Chem. Neue Folge 45 (1965) 370–377.


Vapor in Gas
N2 (1) nitrogen 7727-37-9

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 104 [m2/s]
307.6 101.325 0.256
328.6 101.325 0.303
352.2 101.325 0.359
Reference

Diffusion of nitrogen (1); hydrogen sulfide (2) 1
Diffusion of nitrogen (1); hydrogen sulfide (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

H 2S (2) hydrogen sulfide 7783-06-4
Diffusion of gas(1) in gas(2): D*12(T ); Method: ABSORB Ref.: 1981M4
T [K] p [atm] D · 107 [m2/s]
178.0 5.9 6.9 ± 0.3
178.0 10.7 3.5 ± 0.2
178.0 20.6 2.1 ± 0.2
178.0 30.5 1.4 ± 0.1
178.0 40.3 0.96 ± 0.10
178.0 50.0 0.86 ± 0.10
178.0 59.1 0.66 ± 0.10
178.0 79.1 0.53 ± 0.09
Reference
1981M4 Morozov, V.S., Pronskaja, A.Ja., Gubanova, G.N., Kisjuk, V.F.: Zh. Fiz. Khim. 55 (1981)
1304–1306.

Diffusion of nitrogen (1); ammonia (2) 1
Diffusion of nitrogen (1); ammonia (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

H 3N (2) ammonia 7664-41-7
T [K] p [kPa] D · 104 [m2/s]
295.1 101.325 0.248
N2 (1) nitrogen 7727-37-9

H 3N (2) ammonia 7664-41-7
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.1 101.325 0.254
References

Diffusion of nitrogen (1); helium (2) 1
Diffusion of nitrogen (1); helium (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

He (2) helium 7440-59-7
T [K] p [atm] D · 107 [m2/s]
298.15 272 2.65
298.15 408 1.78
298.15 543 1.32
298.15 681 1.09
298.15 818 0.94
298.15 1090 0.74
298.15 1360 0.72
N2 (1) nitrogen 7727-37-9

He (2) helium 7440-59-7
T [K] p [kPa] D · 105 [m2/s]
298.4 101.325 6.59 ± 0.12
N2 (1) nitrogen 7727-37-9

He (2) helium 7440-59-7
T [K] p [MPa] D · 106 [m2/s]
344.0 0.8 10.2 ± 5%
N2 (1) nitrogen 7727-37-9

He (2) helium 7440-59-7
T [K] p [Torr] D · 104 [m2/s]
295.75 646.4 0.833 ± 0.007
298.15 760.0 0.717
N2 (1) nitrogen 7727-37-9

He (2) helium 7440-59-7
T [K] p [kPa] D
233.17 101.325 1.5500 ± 0.1%
244.88 101.325 1.4195 ± 0.1%
261.77 101.325 1.2592 ± 0.1%
274.43 101.325 1.1572 ± 0.1%
330.07 101.325 0.8379 ± 0.1%
(continued)

2 Diffusion of nitrogen (1); helium (2)
352.95 101.325 0.7452 ± 0.1%

364.20 101.325 0.7059 ± 0.1%
373.55 101.325 0.6754 ± 0.1%
385.25 101.325 0.6410 ± 0.1%
397.29 101.325 0.6082 ± 0.1%
408.37 101.325 0.5799 ± 0.1%
421.80 101.325 0.5486 ± 0.1%
298.15 101.325 0.2094 · 10–4
isotopic mixture 14N - 15N in 14N2;
References


Vapor in Gas
N2 (1) nitrogen 7727-37-9

O2 (2) oxygen 7782-44-7
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.1 101.325 0.200
N2 (1) nitrogen 7727-37-9

O2 (2) oxygen 7782-44-7
T [K] p [Torr] D · 104 [m2/s]
290.4 690 0.149 ± 0.001
N2 (1) nitrogen 7727-37-9

O2 (2) oxygen 7782-44-7
T [K] p [kPa] D · 104 [m2/s]
273.2 101.325 0.181
293.2 101.325 0.22
References

Diffusion of nitrogen (1); sulfur dioxide (2) 1
Diffusion of nitrogen (1); sulfur dioxide (2)

Vapor in Gas
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
298.15 ± 0.1 101.325 0.130
Reference

Diffusion of nitrous oxide (1); air (2) 1
Diffusion of nitrous oxide (1); air (2)

Vapor in Gas

Air (2) air 132259-10-0
T [K] p [kPa] D · 104 [m2/s]
273.15 101.325 0.144 ± 2%
273.15 101.325 0.144 ± 2%
303.15 101.325 0.175 ± 2%
303.15 101.325 0.173 ± 2%
333.15 101.325 0.206 ± 2%
333.15 101.325 0.210 ± 2%
363.15 101.325 0.244 ± 2%
363.15 101.325 0.246 ± 2%
393.15 101.325 0.284 ± 2%
393.15 101.325 0.283 ± 2%
423.15 101.325 0.319 ± 2%
423.15 101.325 0.324 ± 2%
453.15 101.325 0.359 ± 2%
453.15 101.325 0.362 ± 2%
Reference

Diffusion of nitrous oxide (1); oxirane (2) 1
Diffusion of nitrous oxide (1); oxirane (2)

Vapor in Gas

C2H4O (2) oxirane 75-21-8
T [K] p [kPa] D · 104 [m2/s]
298.0 101.325 0.0914
Reference

Diffusion of nitrous oxide (1); propane (2) 1
Diffusion of nitrous oxide (1); propane (2)

Vapor in Gas

C3H8 (2) propane 74-98-6
T [K] p [kPa] D · 104 [m2/s]
298.0 101.325 0.086
Reference

Diffusion of nitrous oxide (1); nitrogen (2) 1
Diffusion of nitrous oxide (1); nitrogen (2)

Vapor in Gas

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
273.15 101.325 0.144 ± 2%
273.15 101.325 0.144 ± 2%
303.15 101.325 0.173 ± 2%
303.15 101.325 0.175 ± 2%
303.15 101.325 0.178 ± 2%
333.15 101.325 0.210 ± 2%
333.15 101.325 0.210 ± 2%
333.15 101.325 0.210 ± 2%
363.15 101.325 0.244 ± 2%
363.15 101.325 0.245 ± 2%
393.15 101.325 0.284 ± 2%
393.15 101.325 0.285 ± 2%
423.15 101.325 0.321 ± 2%
423.15 101.325 0.323 ± 2%
453.15 101.325 0.367 ± 2%
453.15 101.325 0.370 ± 2%
Reference

Diffusion of nitrous oxide (1); oxygen (2) 1
Diffusion of nitrous oxide (1); oxygen (2)

Vapor in Gas

O2 (2) oxygen 7782-44-7
T [K] p [kPa] D · 104 [m2/s]
273.15 101.325 0.145 ± 2%
273.15 101.325 0.146 ± 2%
303.15 101.325 0.175 ± 2%
303.15 101.325 0.177 ± 2%
333.15 101.325 0.208 ± 2%
333.15 101.325 0.211 ± 2%
363.15 101.325 0.244 ± 2%
363.15 101.325 0.246 ± 2%
393.15 101.325 0.284 ± 2%
393.15 101.325 0.281 ± 2%
393.15 101.325 0.282 ± 2%
423.15 101.325 0.325 ± 2%
423.15 101.325 0.323 ± 2%
453.15 101.325 0.360 ± 2%
453.15 101.325 0.366 ± 2%
Reference

Diffusion of sodium (1); neon (2) 1
Diffusion of sodium (1); neon (2)

Vapor in Gas
Na (1) sodium 7440-23-5

Ne (2) neon 7440-01-9
T [K] p [kPa] D · 104 [m2/s]
300 101.325 0.35 ± 0.08
Comment: 20Na atoms diffusing in Ne
Reference
1975C8 Coolen, F.C.M., Hagedoorn, H.L.: Physica B+C 79 (1975) 402–408.

Diffusion of neon (1); nitrogen oxide (2) 1
Diffusion of neon (1); nitrogen oxide (2)

Vapor in Gas
Ne (1) neon 7440-01-9

T [K] p [Torr] D
420.51 340 0.56155
398.38 340 0.61527
373.33 340 0.68655
348.28 340 0.77309
324.58 340 0.87088
271.55 340 1.17970
255.67 340 1.30820
237.42 340 1.48580
Comment: relative diffusion coefficients [D(299.14 K) / D(T )] are given as D*12
Reference


Vapor in Gas
Ne (1) neon 7440-01-9

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
275.00 ± 0.1 101.325 0.270 ± 1%
295.00 ± 0.1 101.325 0.310 ± 1%
320.00 ± 0.1 101.325 0.355 ± 1%
340.00 ± 0.1 101.325 0.390 ± 1%
360.00 ± 0.1 101.325 0.425 ± 1%
Ne (1) neon 7440-01-9

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
118.0 ± 0.3 101.325 0.0606 ± 1.5%
154.0 ± 0.3 101.325 0.0984 ± 1.5%
197.0 ± 0.3 101.325 0.155 ± 1.5%
231.0 ± 0.3 101.325 0.207 ± 1.5%
296.0 ± 0.3 101.325 0.317 ± 1.5%
Ne (1) neon 7440-01-9

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
90.0 101.325 0.0360
194.5 101.325 0.153
273.0 101.325 0.271
273.0 101.325 0.276
288.0 101.325 0.300
303.0 101.325 0.327
318.0 101.325 0.357
353.0 101.325 0.414
473.0 101.325 0.671
Ne (1) neon 7440-01-9

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
297.0 101.325 0.301 ± 0.8%
349.5 101.325 0.413 ± 1.0%
(continued)

397.0 101.325 0.562 ± 2.4%

448.2 101.325 0.661 ± 1.1%
550.0 101.325 0.805 ± 1.5%
548.0 101.325 0.954 ± 0.9%
646.0 101.325 1.23 ± 2.3%
691.5 101.325 1.30 ± 4.8%
738.5 101.325 1.51 ± 0.6%
787.0 101.325 1.74 ± 0.3%
831.5 101.325 1.89 ± 0.4%
880.0 101.325 2.10 ± 1.2%
927.5 101.325 2.21 ± 0.2%
975.0 101.325 2.38 ± 0.9%
1023 101.325 2.59 ± 0.5%
1070 101.325 2.72 ± 0.6%
1118 101.325 3.04 ± 0.2%
1169 101.325 3.34 ± 0.7%
1221 101.325 3.86 ± 2.5%
1274 101.325 4.12 ± 1.4%
Ne (1) neon 7440-01-9

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
303.15 101.325 0.331 ± 2%
303.15 101.325 0.324 ± 2%
303.15 101.325 0.337 ± 2%
Ne (1) neon 7440-01-9

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
300.0 101.325 0.325 ± 0.6%
374.0 101.325 0.474 ± 0.6%
479.0 101.325 0.721 ± 0.6%
573.0 101.325 0.973 ± 0.6%
680.0 101.325 1.302 ± 0.6%
Ne (1) neon 7440-01-9

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
277.4 ± 0.1 101.325 0.279 ± 1%
294.5 ± 0.1 101.325 0.306 ± 1%
312.0 ± 0.1 101.325 0.338 ± 1%
(continued)

335.3 ± 0.1 101.325 0.380 ± 1%

365.6 ± 0.1 101.325 0.441 ± 1%
Ne (1) neon 7440-01-9

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
303.15 ± 0.5 101.325 0.331 ± 2%
303.15 ± 0.5 101.325 0.324 ± 2%
303.15 ± 0.5 101.325 0.337 ± 2%
References
1970H9 Hawke, J.G., White, I.: J. Phys. Chem. 74 (1970) 2788–2793.
185–192.


Vapor in Gas
Ne (1) neon 7440-01-9

Integral Diffusion Coefficient: D(T ); Method: TB Ref.: 1961W3
T [K] p [kPa] D · 104 [m2/s]
242.3 101.325 0.173 ± 4%
249.8 101.325 0.189 ± 4%
255.53 101.325 0.210 ± 4%
258.4 101.325 0.204 ± 4%
294.9 101.325 0.267 ± 4%
296.1 101.325 0.276 ± 4%
366.0 101.325 0.351 ± 4%
381.7 101.325 0.421 ± 4%
397.7 101.325 0.450 ± 4%
398.5 101.325 0.470 ± 4%
426.0 101.325 0.521 ± 4%
427.2 101.325 0.515 ± 4%
Ne (1) neon 7440-01-9

T [K] p [kPa] D · 104 [m2/s]
293.15 101.325 0.251
303.15 101.325 0.267
References
1961W3 Weissman, S., Saxena, S.C., Mason, E.A.: Phys. Fluids 4 (1961) 643–648.
1967B5 Breetveld, J.D., DiPippo, R., Kestin, J.: J. Chem. Phys. 46 (1967) 1541.

Diffusion of neon (1); hydrogen-deuterium (2) 1
Diffusion of neon (1); hydrogen-deuterium (2)

Vapor in Gas
Ne (1) neon 7440-01-9

T [K] p [kPa] D
419.15 ± 0.02 101.325 0.56984 ± 1.5 · 10–3
398.32 ± 0.02 101.325 0.62029 ± 1.5 · 10–3
373.43 ± 0.02 101.325 0.69074 ± 1.5 · 10–3
348.26 ± 0.02 101.325 0.77590 ± 1.5 · 10–3
324.30 ± 0.02 101.325 0.87394 ± 1.5 · 10–3
270.68 ± 0.02 101.325 1.18230 ± 1.5 · 10–3
252.52 ± 0.02 101.325 1.32840 ± 1.5 · 10–3
237.48 ± 0.02 101.325 1.47290 ± 1.5 · 10–3
299.16 ± 0.02 101.325 0.9442 · 10–4 *
Ne (1) neon 7440-01-9

T [K] p [kPa] D
419.26 101.325 0.572 ± 1.5 · 10–3
398.41 101.325 0.622 ± 1.5 · 10–3
373.36 101.325 0.693 ± 1.5 · 10–3
348.32 101.325 0.777 ± 1.5 · 10–3
324.45 101.325 0.874 ± 1.5 · 10–3
270.84 101.325 1.180 ± 1.5 · 10–3
252.74 101.325 1.324 ± 1.5 · 10–3
237.54 101.325 1.468 ± 1.5 · 10–3
299.16 101.325 0.9128 · 10–4 *
References
1981W7 Wahby, A.S.M., Los, J.: Physica A 105 (1981) 264–270.

Diffusion of neon (1); deuterium (2) 1
Diffusion of neon (1); deuterium (2)

Vapor in Gas
Ne (1) neon 7440-01-9

D2 (2) deuterium 7782-39-0
T [K] p [kPa] D
419.37 ± 0.02 101.325 0.56880 ± 1.5 · 10–3
398.54 ± 0.02 101.325 0.61924 ± 1.5 · 10–3
373.43 ± 0.02 101.325 0.69031 ± 1.5 · 10–3
348.48 ± 0.02 101.325 0.77481 ± 1.5 · 10–3
324.28 ± 0.02 101.325 0.87376 ± 1.5 · 10–3
270.72 ± 0.02 101.325 1.18210 ± 1.5 · 10–3
252.68 ± 0.02 101.325 1.32730 ± 1.5 · 10–3
237.60 ± 0.02 101.325 1.47220 ± 1.5 · 10–3
299.16 ± 0.02 101.325 0.8273 · 10–4 *
Ne (1) neon 7440-01-9

D2 (2) deuterium 7782-39-0
T [K] p [kPa] D
419.27 101.325 0.571 ± 1.5 · 10–3
398.44 101.325 0.621 ± 1.5 · 10–3
373.39 101.325 0.692 ± 1.5 · 10–3
348.31 101.325 0.776 ± 1.5 · 10–3
324.47 101.325 0.874 ± 1.5 · 10–3
270.86 101.325 1.181 ± 1.5 · 10–3
252.71 101.325 1.326 ± 1.5 · 10–3
237.53 101.325 1.471 ± 1.5 · 10–3
299.16 101.325 0.9128 · 10–4 *
Reference


Vapor in Gas
Ne (1) neon 7440-01-9

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
275.8 ± 0.1 101.325 0.989 ± 1%
289.2 ± 0.1 101.325 1.03 ± 1%
308.4 ± 0.1 101.325 1.19 ± 1%
337.0 ± 0.1 101.325 1.39 ± 1%
365.7 ± 0.1 101.325 1.60 ± 1%
Ne (1) neon 7440-01-9

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
275.00 ± 0.1 101.325 0.953 ± 1%
295.00 ± 0.1 101.325 1.10 ± 1%
320.00 ± 0.1 101.325 1.27 ± 1%
340.00 ± 0.1 101.325 1.41 ± 1%
360.00 ± 0.1 101.325 1.55 ± 1%
Ne (1) neon 7440-01-9

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D
237.51 101.325 1.468 ± 1.5 · 10–3
252.72 101.325 1.323 ± 1.5 · 10–3
270.86 101.325 1.179 ± 1.5 · 10–3
324.47 101.325 0.874 ± 1.5 · 10–3
348.30 101.325 0.777 ± 1.5 · 10–3
373.35 101.325 0.693 ± 1.5 · 10–3
398.42 101.325 0.622 ± 1.5 · 10–3
419.24 101.325 0.571 ± 1.5 · 10–3
299.19 ± 0.15 101.325 1.0892 · 10–4 *
Comment: relative diffusion coefficients [D(299.19 ± 0.15 K) / D(T )] are given as D*12;
Ne (1) neon 7440-01-9

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
299.16 ± 0.15 101.325 1.0892

2 Diffusion of neon (1); hydrogen (2)
Ne (1) neon 7440-01-9

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D
419.28 ± 0.02 101.325 0.56894 ± 1.5 · 10–3
398.45 ± 0.02 101.325 0.61942 ± 1.5 · 10–3
373.38 ± 0.02 101.325 0.69028 ± 1.5 · 10–3
348.32 ± 0.02 101.325 0.77524 ± 1.5 · 10–3
324.48 ± 0.02 101.325 0.87286 ± 1.5 · 10–3
270.85 ± 0.02 101.325 1.18150 ± 1.5 · 10–3
252.70 ± 0.02 101.325 1.32780 ± 1.5 · 10–3
237.52 ± 0.02 101.325 1.47390 ± 1.5 · 10–3
299.16 ± 0.02 101.325 1.1271 · 10–4 *
References

Diffusion of neon (1); helium (2) 1
Diffusion of neon (1); helium (2)

Vapor in Gas
Ne (1) neon 7440-01-9

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
297.0 101.325 1.05 ± 0.8%
348.3 101.325 1.44 ± 1.5%
397.3 101.325 1.80 ± 1.6%
446.5 101.325 2.18 ± 0.8%
497.5 101.325 2.44 ± 1.6%
548.5 101.325 3.03 ± 1.5%
597.1 101.325 3.98 ± 2.6%
644.0 101.325 4.22 ± 1.7%
692.0 101.325 4.74 ± 1.4%
739.0 101.325 5.00 ± 2.4%
787.0 101.325 5.69 ± 0.3%
833.5 101.325 6.04 ± 2.8%
879.0 101.325 7.11 ± 0.8%
926.5 101.325 7.71 ± 0.9%
975.0 101.325 8.63 ± 1.2%
1070 101.325 10.0 ± 2.0%
1119 101.325 10.4 ± 1.2%
1167 101.325 11.4 ± 0.3%
1217 101.325 12.3 ± 0.9%
1268 101.325 13.0 ± 0.0%
Ne (1) neon 7440-01-9

He (2) helium 7440-59-7
307 ± 1.0 138* 6.68 ± 4%
307 ± 1.0 98 9.97 ± 4%
307 ± 1.0 80 11.48 ± 4%
270 ± 1.0 144 5.85 ± 4%
270 ± 1.0 122 6.96 ± 4%
270 ± 1.0 92 9.37 ± 4%
240 ± 1.0 142 5.47 ± 4%
240 ± 1.0 116 6.76 ± 4%
240 ± 1.0 93 8.68 ± 4%
210 ± 1.0 142 5.10 ± 4%
210 ± 1.0 116 6.02 ± 4%
210 ± 1.0 91 7.80 ± 4%
180 ± 1.0 143 4.67 ± 4%
(continued)
2 Diffusion of neon (1); helium (2)
180 ± 1.0 116 5.34 ± 4%

180 ± 1.0 92 6.72 ± 4%
150 ± 1.0 143 3.77 ± 4%
150 ± 1.0 117 4.96 ± 4%
150 ± 1.0 92 6.15 ± 4%
120 ± 1.0 142 3.57 ± 4%
120 ± 1.0 116 4.36 ± 4%
120 ± 1.0 92 5.29 ± 4%
90 ± 1.0 143 2.81 ± 4%
90 ± 1.0 114 3.56 ± 4%
90 ± 1.0 92 4.16 ± 4%
References
1974D4 De Paz, M., Tantalo, F., Varni, G.: J. Chem. Phys. 61 (1974) 3875–3880.


Vapor in Gas
Ne (1) neon 7440-01-9

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
273.0 101.325 0.223
288.0 101.325 0.240
303.0 101.325 0.266
318.0 101.325 0.284
Ne (1) neon 7440-01-9

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
350.2 ± 0.2% 101.325 0.362 ± 1.5%
497.1 ± 0.2% 101.325 0.633 ± 1.5%
652.1 ± 0.2% 101.325 1.01 ± 1.5%
796.4 ± 0.2% 101.325 1.45 ± 1.5%
911.5 ± 0.2% 101.325 1.78 ± 1.5%
1222.4 ± 0.2% 101.325 3.00 ± 1.5%
References


Vapor in Gas
Ne (1) neon 7440-01-9

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D
212.18 101.325 1.815 ± 1.5 · 10–3
235.43 101.325 1.523 ± 1.5 · 10–3
255.64 101.325 1.364 ± 1.5 · 10–3
276.25 101.325 1.150 ± 1.5 · 10–3
329.54 101.325 0.845 ± 1.5 · 10–3
352.44 101.325 0.751 ± 1.5 · 10–3
376.53 101.325 0.671 ± 1.5 · 10–3
398.36 101.325 0.608 ± 1.5 · 10–3
420.48 101.325 0.555 ± 1.5 · 10–3
445.46 101.325 0.499 ± 1.5 · 10–3
299.19 ± 0.15 101.325 0.3323 · 10–4 *
Ne (1) neon 7440-01-9

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D
212.24 101.325 1.809 ± 1.5 · 10–3
235.26 101.325 1.519 ± 1.5 · 10–3
255.44 101.325 1.366 ± 1.5 · 10–3
276.33 101.325 1.154 ± 1.5 · 10–3
329.48 101.325 0.848 ± 1.5 · 10–3
352.51 101.325 0.759 ± 1.5 · 10–3
376.46 101.325 0.678 ± 1.5 · 10–3
398.28 101.325 0.618 ± 1.5 · 10–3
420.45 101.325 0.558 ± 1.5 · 10–3
445.34 101.325 0.500 ± 1.5 · 10–3
299.19 ± 0.15 101.325 0.3253 · 10–4 *
Ne (1) neon 7440-01-9

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
299.16 ± 0.15 101.325 0.3323
299.16 ± 0.15 101.325 0.3253

2 Diffusion of neon (1); nitrogen (2)
Reference

Diffusion of neon-22 (1); neon-20 (2) 1
Diffusion of neon-22 (1); neon-20 (2)

Vapor in Gas
Ne (1) neon-22 13886-72-1

Ne (2) neon-20 13981-34-5
T [K] p [kPa] D · 104 [m2/s]
295.6 101.325 0.494 ± 0.8%
349.9 101.325 0.689 ± 1.2%
400.4 101.325 0.897 ± 0.6%
447.4 101.325 1.05 ± 0.9%
500.4 101.325 1.20 ± 0.6%
547.0 101.325 1.38 ± 0.7%
596.2 101.325 1.60 ± 0.8%
645.4 101.325 1.97 ± 1.2%
692.5 101.325 2.10 ± 3.5%
738.1 101.325 2.40 ± 0.7%
784.4 101.325 2.67 ± 1.4%
839.5 101.325 2.93 ± 0.7%
877.9 101.325 3.21 ± 0.2%
930.3 101.325 3.50 ± 0.4%
973.6 101.325 3.83 ± 0.2%
1026 101.325 4.17 ± 0.6%
1071 101.325 4.52 ± 0.2%
1129 101.325 4.84 ± 0.5%
1170 101.325 5.26 ± 0.4%
1219 101.325 5.56 ± 0.5%
Comment: mixture at equimolar composition; 22Ne diffusing in 20Ne
Reference


Vapor in Gas
Ne (1) neon 7440-01-9

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
275.3 ± 0.1 101.325 0.193 ± 1%
291.6 ± 0.1 101.325 0.216 ± 1%
308.4 ± 0.1 101.325 0.242 ± 1%
333.6 ± 0.1 101.325 0.280 ± 1%
362.5 ± 0.1 101.325 0.314 ± 1%
Ne (1) neon 7440-01-9

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
275.00 ± 0.1 101.325 0.190 ± 1%
295.00 ± 0.1 101.325 0.210 ± 1%
320.00 ± 0.1 101.325 0.260 ± 1%
340.00 ± 0.1 101.325 0.290 ± 1%
360.00 ± 0.1 101.325 0.315 ± 1%
Ne (1) neon 7440-01-9

Xe (2) xenon 7440-63-3
T [K] p [kPa] D · 104 [m2/s]
297.0 101.325 0.214 ± 1.0%
353.0 101.325 0.308 ± 2.3%
396.9 101.325 0.383 ± 1.0%
447.0 101.325 0.480 ± 0.4%
495.5 101.325 0.548 ± 1.1%
551.5 101.325 0.635 ± 0.4%
595.0 101.325 0.647 ± 1.6%
647.0 101.325 0.794 ± 1.4%
691.0 101.325 0.890 ± 0.2%
742.5 101.325 1.01 ± 1.2%
784.0 101.325 1.15 ± 1.1%
837.0 101.325 1.28 ± 0.1%
880.5 101.325 1.40 ± 0.5%
926.5 101.325 1.47 ± 1.7%
974.0 101.325 1.64 ± 0.6%
1024 101.325 1.72 ± 2.1%
1071 101.325 2.02 ± 1.1%
1119 101.325 2.09 ± 1.6%
(continued)

1169 101.325 2.25 ± 1.3%

1218 101.325 2.44 ± 1.4%
1270 101.325 2.61 ± 1.4%
References

Diffusion of oxygen atom (1); argon (2) 1
Diffusion of oxygen atom (1); argon (2)

Vapor in Gas
O (1) oxygen atom 17778-80-2

Ar (2) argon 7440-37-1
T [K] p [Torr] D · 102 [m2/s]
280 1.0 2.09
O (1) oxygen atom 17778-80-2

Ar (2) argon 7440-37-1
Diffusion of gas(1) in gas(2): D*12(T ); Method: CC Ref.: 1968Y1
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 2.0 101.325 0.35 ± 0.03
References

Diffusion of oxygen atom (1); helium (2) 1
Diffusion of oxygen atom (1); helium (2)

Vapor in Gas
O (1) oxygen atom 17778-80-2

He (2) helium 7440-59-7
T [K] p [Torr] D · 102 [m2/s]
280 1.0 7.0
O (1) oxygen atom 17778-80-2

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
298.15 ± 2.0 101.325 0.64 ± 0.16
O (1) oxygen atom 17778-80-2

He (2) helium 7440-59-7
Diffusion of gas(1) in gas(2): D*12(T ); Method: No Stand Ref.: 1978J2
T [K] p [kPa] D · 104 [m2/s]
295 101.325 1.08 ± 0.12
References
1978J2 Judeikis, H.S., Wun, M.: J. Chem. Phys. 68 (1978) 4123–4127.

Diffusion of oxygen atom (1); krypton (2) 1
Diffusion of oxygen atom (1); krypton (2)

Vapor in Gas
O (1) oxygen atom 17778-80-2

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 102 [m2/s]
298.15 ± 2.0 101.325 0.10 ± 0.02
Reference

Diffusion of oxygen atom (1); nitrogen (2) 1
Diffusion of oxygen atom (1); nitrogen (2)

Vapor in Gas
O (1) oxygen atom 17778-80-2

N2 (2) nitrogen 7727-37-9
T [K] p [Torr] D · 102 [m2/s]
280 1.0 2.18
Reference

Diffusion of oxygen atom (1); oxygen (2) 1
Diffusion of oxygen atom (1); oxygen (2)

Vapor in Gas
O (1) oxygen atom 17778-80-2

O2 (2) oxygen 7782-44-7
T [K] p [Torr] D · 102 [m2/s]
280 1.0 2.22
O (1) oxygen atom 17778-80-2

O2 (2) oxygen 7782-44-7
T [K] p [kPa] D · 102 [m2/s]
298.15 ± 2.0 101.325 0.26 ± 0.07
References


Vapor in Gas
O2 (1) oxygen 7782-44-7

T [K] p [kPa] D · 104 [m2/s]
202 101.325 0.085
209 101.325 0.089
218 101.325 0.095
230 101.325 0.105
250 101.325 0.125
260 101.325 0.136
273 101.325 0.139
297 101.325 0.170
O2 (1) oxygen 7782-44-7

T [K] p [MPa] D · 107 [m2/s]
273.2 1.0 14.2 ± 4%
273.2 2.0 6.7 ± 4%
273.2 3.0 4.2 ± 4%
273.2 3.4 3.6 ± 4%
293.2 1.0 16.1 ± 4%
293.2 2.0 8.0 ± 4%
293.2 3.0 5.1 ± 4%
293.2 4.0 3.5 ± 4%
293.2 5.0 2.6 ± 4%
293.2 5.4 2.3 ± 4%
303.2 1.0 17.5 ± 4%
303.2 2.0 8.5 ± 4%
303.2 3.0 5.5 ± 4%
303.2 4.0 3.8 ± 4%
303.2 5.0 2.9 ± 4%
303.2 6.0 2.2 ± 4%
O2 (1) oxygen 7782-44-7

T [K] p [Torr] D · 104 [m2/s]
287.8 690 0.170 ± 0.001
References

2 Diffusion of oxygen (1); carbon dioxide (2)
1970K7 Kosov, N.D., Zhalgasov, A.: Zh. Tekh. Fiz. 40 (1970) 1325–1327.
1982B3 Bibolov, S.K.: Gidroaerodinam. i Diffuziya, Alma-Ata 37 (1982) 37–40.

Diffusion of oxygen (1); ethyne (2) 1
Diffusion of oxygen (1); ethyne (2)

Vapor in Gas
O2 (1) oxygen 7782-44-7

C2H2 (2) ethyne 74-86-2
T [K] p [Torr] D · 104 [m2/s]
287.0 690 0.223 ± 0.002
Reference

Diffusion of oxygen (1); thiophene (2) 1
Diffusion of oxygen (1); thiophene (2)

Vapor in Gas
O2 (1) oxygen 7782-44-7

T [K] p [kPa] D · 104 [m2/s]
302.1 101.325 0.0975
Reference

Diffusion of oxygen (1); tetrahydro-thiophene (2) 1
Diffusion of oxygen (1); tetrahydro-thiophene (2)

Vapor in Gas
O2 (1) oxygen 7782-44-7

T [K] p [kPa] D · 104 [m2/s]
318.5 101.325 0.0983
Reference

Diffusion of oxygen (1); pyridine (2) 1
Diffusion of oxygen (1); pyridine (2)

Vapor in Gas
O2 (1) oxygen 7782-44-7

T [K] p [kPa] D · 104 [m2/s]
318.3 101.325 0.1050
Reference

Diffusion of oxygen (1); piperidine (2) 1
Diffusion of oxygen (1); piperidine (2)

Vapor in Gas
O2 (1) oxygen 7782-44-7

T [K] p [kPa] D · 104 [m2/s]
315.0 101.325 0.0953
Reference

Diffusion of oxygen (1); benzene (2) 1
Diffusion of oxygen (1); benzene (2)

Vapor in Gas
O2 (1) oxygen 7782-44-7

C6H6 (2) benzene 71-43-2
T [K] p [kPa] D · 104 [m2/s]
311.3 101.325 0.1011
Reference

Diffusion of oxygen (1); cyclohexane (2) 1
Diffusion of oxygen (1); cyclohexane (2)

Vapor in Gas
O2 (1) oxygen 7782-44-7

T [K] p [kPa] D · 104 [m2/s]
288.6 101.325 0.0744
Reference

Diffusion of oxygen (1); methyl-cyclopentane (2) 1
Diffusion of oxygen (1); methyl-cyclopentane (2)

Vapor in Gas
O2 (1) oxygen 7782-44-7

T [K] p [kPa] D · 104 [m2/s]
287.1 101.325 0.0742
Reference

Diffusion of oxygen (1); hexane (2) 1
Diffusion of oxygen (1); hexane (2)

Vapor in Gas
O2 (1) oxygen 7782-44-7

C6H14 (2) hexane 110-54-3
T [K] p [kPa] D · 104 [m2/s]
288.6 101.325 0.0753
Reference

Diffusion of oxygen (1); 2,3-dimethyl-butane (2) 1
Diffusion of oxygen (1); 2,3-dimethyl-butane (2)

Vapor in Gas
O2 (1) oxygen 7782-44-7

T [K] p [kPa] D · 104 [m2/s]
288.4 101.325 0.0753
Reference

Diffusion of oxygen (1); octane (2) 1
Diffusion of oxygen (1); octane (2)

Vapor in Gas
O2 (1) oxygen 7782-44-7

C8H18 (2) octane 111-65-9
T [K] p [kPa] D · 104 [m2/s]
303.1 101.325 0.0705
Reference

Diffusion of oxygen (1); 2,2,4-trimethyl-pentane (2) 1
Diffusion of oxygen (1); 2,2,4-trimethyl-pentane (2)

Vapor in Gas
O2 (1) oxygen 7782-44-7

T [K] p [kPa] D · 104 [m2/s]
303.0 101.325 0.0705
Reference

Diffusion of oxygen (1); sulfur hexafluoride (2) 1
Diffusion of oxygen (1); sulfur hexafluoride (2)

Vapor in Gas
O2 (1) oxygen 7782-44-7

T [K] p [Torr] D · 104 [m2/s]
287.0 690 0.109 ± 0.002
Reference

Diffusion of oxygen (1); hydrogen (2) 1
Diffusion of oxygen (1); hydrogen (2)

Vapor in Gas
O2 (1) oxygen 7782-44-7

H2 (2) hydrogen 1333-74-0
T [K] p [Torr] D · 104 [m2/s]
310.15 ± 0.05 746 0.893 ± 0.019
Reference


Vapor in Gas
O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 104 [m2/s]
308.1 101.325 0.282
329.0 101.325 0.318
352.4 101.325 0.352
Reference

Diffusion of oxygen (1); helium (2) 1
Diffusion of oxygen (1); helium (2)

Vapor in Gas
O2 (1) oxygen 7782-44-7

He (2) helium 7440-59-7
T [K] p [Torr] D · 104 [m2/s]
296.85 647.0 0.860 ± 0.005
298.15 760.0 0.737
O2 (1) oxygen 7782-44-7

He (2) helium 7440-59-7
T [K] p [kPa] D · 105 [m2/s]
292.2 101.325 6.73 ± 0.04
O2 (1) oxygen 7782-44-7

He (2) helium 7440-59-7
Diffusion of gas(1) in gas(2): D*12(T ); Method: TAYLOR Ref.: 1983P6
T [K] n [1016cm–3] D · 104 [m2/s]
294.0 3.31 * 733.0 ± 4.7
294.0 16.32 355.3 ± 1.4
294.0 1.67 1474 ± 30
294.0 6.42 444.6 ± 2.0
294.0 13.15 345.1 ± 1.4
294.0 19.98 381.1 ± 2.7
294.0 27.06 452.3 ± 2.3
294.0 23.62 411.7 ± 2.7
294.0 4.97 531.6 ± 3.8
294.0 25.17 433.1 ± 3.0
294.0 13.20 220.7 ± 0.6
294.0 26.77 158.1 ± 1.3
294.0 6.65 385.9 ± 2.2
294.0 6.71 636.5 ± 4.8
294.0 12.87 828.4 ± 6.6
294.0 13.54 198.6 ± 3.2
294.0 27.30 160.2 ± 4.5
Comment: Oxygen O(3P) diffusing in He,
*: Number density of He n = N/v in [1.0 · 1016/cm3] is given
References
1983P6 Plumb, I.C., Ryan, K.R., Barton, N.G.: Int. J. Chem. Kinet. 15 (1983) 1081–1097.

Diffusion of oxygen (1); nitrogen (2) 1
Diffusion of oxygen (1); nitrogen (2)

Vapor in Gas
O2 (1) oxygen 7782-44-7

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
298.0 101.325 0.23 ± 4.3%
324.0 101.325 0.258 ± 6.6%
O2 (1) oxygen 7782-44-7

N2 (2) nitrogen 7727-37-9
T [K] p [Torr] D · 104 [m2/s]
310.15 ± 0.05 746 0.256 ± 0.002
References

Diffusion of sulfur dioxide (1); carbon dioxide (2) 1
Diffusion of sulfur dioxide (1); carbon dioxide (2)

Vapor in Gas

T [K] p [kPa] D · 104 [m2/s]
263 101.325 0.064 ± 3%
343 101.325 0.108 ± 3%
473 101.325 0.195 ± 3%
Reference

Diffusion of sulfur dioxide (1); hydrogen (2) 1
Diffusion of sulfur dioxide (1); hydrogen (2)

Vapor in Gas

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
263 101.325 0.43 ± 3%
323 101.325 0.61 ± 3%
473 101.325 1.23 ± 3%
Reference

Diffusion of phosphorus (1); argon (2) 1
Diffusion of phosphorus (1); argon (2)

Vapor in Gas
P (1) phosphorus 7723-14-0

Ar (2) argon 7440-37-1
T [K] p [atm] D · 104 [m2/s]
800 ± 2 20 0.0290 ± 5%
820 ± 2 20 0.0301 ± 5%
840 ± 2 20 0.0316 ± 5%
800 ± 2 30 0.0196 ± 5%
820 ± 2 30 0.0205 ± 5%
840 ± 2 30 0.0215 ± 5%
800 ± 2 40 0.0148 ± 5%
820 ± 2 40 0.0158 ± 5%
840 ± 2 40 0.0165 ± 5%
Reference
1969K8 Kuz'min, V.N., Nashel'skii, A.Ya.: Izv. Akad. Nauk SSSR Neorg. Mater. 5 (1969) 962–963.

Diffusion of rubidium (1); nitrogen (2) 1
Diffusion of rubidium (1); nitrogen (2)

Vapor in Gas
Rb (1) rubidium 7440-17-7

N2 (2) nitrogen 7727-37-9
Diffusion of gas(1) in gas(2): D*12(T ); Method: NMR FG Ref.: 2000I1
T [K] p [kPa] D · 104 [m2/s]
333.15 101.325 0.159 ± 0.004
Reference
2000I1 Ishikawa, K., Yabuzaki, T.: Phys. Rev. A 62 (2000) 065401/1-065401/4.

Diffusion of tritium (1); argon (2) 1
Diffusion of tritium (1); argon (2)

Vapor in Gas
T2 (1) tritium 10028-17-8

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
295.1 101.325 0.488
294.4 101.325 0.501
Reference

Diffusion of tritium (1); carbon dioxide (2) 1
Diffusion of tritium (1); carbon dioxide (2)

Vapor in Gas
T2 (1) tritium 10028-17-8

T [K] p [kPa] D · 104 [m2/s]
297.6 101.325 0.419
298.2 101.325 0.421
Reference

Diffusion of tritium (1); deuterium (2) 1
Diffusion of tritium (1); deuterium (2)

Vapor in Gas
T2 (1) tritium 10028-17-8

D2 (2) deuterium 7782-39-0
T [K] p [kPa] D · 104 [m2/s]
295.0 ± 0.1 101.325 1.477
295.0 ± 0.1 101.325 1.462
295.0 ± 0.1 101.325 1.467
Reference
1965M9 Mason, E.A., Annis, B.K., Islam, M.: J. Chem. Phys. 42 (1965) 3364–3366.

Diffusion of tritium (1); hydrogen (2) 1
Diffusion of tritium (1); hydrogen (2)

Vapor in Gas
T2 (1) tritium 10028-17-8

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
295.0 ± 0.1 101.325 1.442
295.0 ± 0.1 101.325 1.435
295.0 ± 0.1 101.325 1.445
Reference

Diffusion of tritium (1); krypton (2) 1
Diffusion of tritium (1); krypton (2)

Vapor in Gas
T2 (1) tritium 10028-17-8

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
252 101.325 0.352
252 101.325 0.323
294.6 101.325 0.437
294.6 101.325 0.414
294.4 101.325 0.433
294.4 101.325 0.426
346 101.325 0.571
346 101.325 0.567
Reference

Diffusion of tritium (1); nitrogen (2) 1
Diffusion of tritium (1); nitrogen (2)

Vapor in Gas
T2 (1) tritium 10028-17-8

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 104 [m2/s]
296.7 101.325 0.521
297.3 101.325 0.518
Reference

Diffusion of xenon (1); argon (2) 1
Diffusion of xenon (1); argon (2)

Vapor in Gas
Xe (1) xenon 7440-63-3

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
298.0 101.325 0.105 ± 1.7%
348.0 101.325 0.145 ± 0.5%
398.3 101.325 0.187 ± 0.8%
447.5 101.325 0.238 ± 0.2%
496.2 101.325 0.283 ± 0.7%
547.0 101.325 0.348 ± 2.1%
595.5 101.325 0.412 ± 1.7%
643.0 101.325 0.432 ± 0.5%
692.3 101.325 0.482 ± 2.1%
735.0 101.325 0.538 ± 0.3%
783.0 101.325 0.596 ± 1.0%
831.5 101.325 0.682 ± 0.5%
879.0 101.325 0.693 ± 0.8%
926.0 101.325 0.783 ± 1.0%
973.0 101.325 0.886 ± 0.4%
1023 101.325 0.980 ± 0.0%
1071 101.325 1.07 ± 0.9%
1119 101.325 1.16 ± 1.2%
1167 101.325 1.23 ± 0.1%
1219 101.325 1.35 ± 0.2%
1272 101.325 1.39 ± 0.6%
Xe (1) xenon 7440-63-3

Ar (2) argon 7440-37-1
T [K] p [kPa] D · 104 [m2/s]
302.6 101.325 0.1268 ± 0.0158
References

Diffusion of xenon (1); hydrogen-deuterium (2) 1
Diffusion of xenon (1); hydrogen-deuterium (2)

Vapor in Gas
Xe (1) xenon 7440-63-3

T [K] p [kPa] D
419.37 ± 0.02 101.325 0.55532 ± 1.5 · 10–3
398.54 ± 0.02 101.325 0.60637 ± 1.5 · 10–3
373.43 ± 0.02 101.325 0.67854 ± 1.5 · 10–3
348.48 ± 0.02 101.325 0.76500 ± 1.5 · 10–3
324.28 ± 0.02 101.325 0.86799 ± 1.5 · 10–3
270.72 ± 0.02 101.325 1.19170 ± 1.5 · 10–3
252.68 ± 0.02 101.325 1.34690 ± 1.5 · 10–3
237.60 ± 0.02 101.325 1.50600 ± 1.5 · 10–3
299.16 ± 0.02 101.325 0.4896 · 10–4 *
Xe (1) xenon 7440-63-3

T [K] p [kPa] D
419.43 101.325 0.560 ± 1.5 · 10–3
398.34 101.325 0.610 ± 1.5 · 10–3
373.31 101.325 0.682 ± 1.5 · 10–3
348.23 101.325 0.768 ± 1.5 · 10–3
324.22 101.325 0.869 ± 1.5 · 10–3
270.62 101.325 1.193 ± 1.5 · 10–3
252.73 101.325 1.348 ± 1.5 · 10–3
237.26 101.325 1.510 ± 1.5 · 10–3
299.16 101.325 0.4800 · 10–4 *
References

Diffusion of xenon (1); deuterium (2) 1
Diffusion of xenon (1); deuterium (2)

Vapor in Gas
Xe (1) xenon 7440-63-3

D2 (2) deuterium 7782-39-0
T [K] p [kPa] D
419.59 ± 0.02 101.325 0.55311 ± 1.5 · 10–3
398.28 ± 0.02 101.325 0.60654 ± 1.5 · 10–3
373.27 ± 0.02 101.325 0.67843 ± 1.5 · 10–3
348.26 ± 0.02 101.325 0.76596 ± 1.5 · 10–3
324.18 ± 0.02 101.325 0.86808 ± 1.5 · 10–3
270.49 ± 0.02 101.325 1.19430 ± 1.5 · 10–3
252.86 ± 0.02 101.325 1.3460 ± 1.5 · 10–3
237.12 ± 0.02 101.325 1.5087 ± 1.5 · 10–3
299.16 ± 0.02 101.325 0.4256 · 10–4 *
Xe (1) xenon 7440-63-3

D2 (2) deuterium 7782-39-0
T [K] p [kPa] D
419.42 101.325 0.559 ± 1.5 · 10–3
398.32 101.325 0.609 ± 1.5 · 10–3
373.24 101.325 0.681 ± 1.5 · 10–3
348.21 101.325 0.768 ± 1.5 · 10–3
324.23 101.325 0.868 ± 1.5 · 10–3
270.64 101.325 1.194 ± 1.5 · 10–3
252.70 101.325 1.350 ± 1.5 · 10–3
237.28 101.325 1.511 ± 1.5 · 10–3
299.16 101.325 0.4177 · 10–4 *
References


Vapor in Gas
Xe (1) xenon 7440-63-3

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D
419.42 ± 0.02 101.325 0.55390 ± 1.5 · 10–3
398.35 ± 0.02 101.325 0.60576 ± 1.5 · 10–3
373.22 ± 0.02 101.325 0.67870 ± 1.5 · 10–3
348.18 ± 0.02 101.325 0.76634 ± 1.5 · 10–3
324.25 ± 0.02 101.325 0.86813 ± 1.5 · 10–3
270.67 ± 0.02 101.325 1.19310 ± 1.5 · 10–3
252.72 ± 0.02 101.325 1.34770 ± 1.5 · 10–3
237.28 ± 0.02 101.325 1.51010 ± 1.5 · 10–3
299.16 ± 0.02 101.325 0.5952 · 10–4 *
Xe (1) xenon 7440-63-3

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
275.00 ± 0.1 101.325 0.535 ± 1%
295.00 ± 0.1 101.325 0.627 ± 1%
320.00 ± 0.1 101.325 0.740 ± 1%
340.00 ± 0.1 101.325 0.830 ± 1%
360.00 ± 0.1 101.325 0.920 ± 1%
Xe (1) xenon 7440-63-3

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
275.3 ± 0.1 101.325 0.543 ± 1%
297.7 ± 0.1 101.325 0.649 ± 1%
317.5 ± 0.1 101.325 0.721 ± 1%
338.4 ± 0.1 101.325 0.819 ± 1%
363.7 ± 0.1 101.325 0.919 ± 1%
Xe (1) xenon 7440-63-3

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D · 104 [m2/s]
299.16 ± 0.15 101.325 0.5855

2 Diffusion of xenon (1); hydrogen (2)
Xe (1) xenon 7440-63-3

H2 (2) hydrogen 1333-74-0
T [K] p [kPa] D
237.29 101.325 1.513 ± 1.5 · 10–3
252.71 101.325 1.351 ± 1.5 · 10–3
270.65 101.325 1.192 ± 1.5 · 10–3
324.24 101.325 0.869 ± 1.5 · 10–3
348.20 101.325 0.768 ± 1.5 · 10–3
373.23 101.325 0.682 ± 1.5 · 10–3
398.33 101.325 0.616 ± 1.5 · 10–3
419.41 101.325 0.560 ± 1.5 · 10–3
299.19 ± 0.15 101.325 0.5855 · 10–4 *
References

Diffusion of xenon (1); helium (2) 1
Diffusion of xenon (1); helium (2)

Vapor in Gas
Xe (1) xenon 7440-63-3

He (2) helium 7440-59-7
T [K] p [kPa] D · 104 [m2/s]
302.6 101.325 0.535 ± 0.055
Reference

Diffusion of xenon (1); krypton (2) 1
Diffusion of xenon (1); krypton (2)

Vapor in Gas
Xe (1) xenon 7440-63-3

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
302.6 101.325 0.0823 ± 0.0014
Xe (1) xenon 7440-63-3

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
273 ± 0.1 101.325 0.0646 ± 0.0004
315 ± 0.1 101.325 0.0835 ± 0.0005
334 ± 0.1 101.325 0.0944 ± 0.0001
354 ± 0.1 101.325 0.1076 ± 0.0013
374 ± 0.1 101.325 0.1165 ± 0.0006
394 ± 0.1 101.325 0.1256 ± 0.0008
Xe (1) xenon 7440-63-3

Kr (2) krypton 7439-90-9
T [K] p [kPa] D · 104 [m2/s]
273 ± 0.1 101.325 0.0645 ± 0.0001
273 ± 0.1 101.325 0.0667 ± 0.0009
315 ± 0.1 101.325 0.0847 ± 0.0013
315 ± 0.1 101.325 0.0853 ± 0.0007
334 ± 0.1 101.325 0.0956 ± 0.0013
354 ± 0.1 101.325 0.1059 ± 0.0017
354 ± 0.1 101.325 0.1063 ± 0.0019
374 ± 0.1 101.325 0.1200 ± 0.0006
394 ± 0.1 101.325 0.1273 ± 0.0017
394 ± 0.1 101.325 0.1303 ± 0.0007
References


Vapor in Gas
Xe (1) xenon 7440-63-3

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D
445.46 ± 0.02 101.325 0.508 ± 0.1%
420.53 ± 0.02 101.325 0.554 ± 0.1%
398.26 ± 0.02 101.325 0.618 ± 0.1%
376.63 ± 0.02 101.325 0.676 ± 0.1%
352.53 ± 0.02 101.325 0.764 ± 0.1%
329.66 ± 0.02 101.325 0.857 ± 0.1%
276.73 ± 0.02 101.325 1.172 ± 0.1%
255.28 ± 0.02 101.325 1.355 ± 0.1%
235.24 ± 0.02 101.325 1.569 ± 0.1%
212.36 ± 0.02 101.325 1.884 ± 0.1%
299.16 ± 0.02 101.325 0.1300 · 10–4 *
Xe (1) xenon 7440-63-3

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D
445.38 ± 0.02 101.325 0.517 ± 0.1%
420.45 ± 0.02 101.325 0.558 ± 0.1%
398.32 ± 0.02 101.325 0.620 ± 0.1%
376.58 ± 0.02 101.325 0.680 ± 0.1%
352.47 ± 0.02 101.325 0.769 ± 0.1%
329.72 ± 0.02 101.325 0.860 ± 0.1%
276.81 ± 0.02 101.325 1.178 ± 0.1%
255.34 ± 0.02 101.325 1.359 ± 0.1%
235.31 ± 0.02 101.325 1.571 ± 0.1%
212.44 ± 0.02 101.325 1.889 ± 0.1%
299.16 ± 0.02 101.325 0.1274 · 10-4 *
Reference

Diffusion of xenon (1); neon (2) 1
Diffusion of xenon (1); neon (2)

Vapor in Gas
Xe (1) xenon 7440-63-3

Ne (2) neon 7440-01-9
T [K] p [kPa] D · 104 [m2/s]
302.6 101.325 0.2297 ± 0.0268
Xe (1) xenon 7440-63-3

Ne (2) neon 7440-01-9
T [K] p [kPa] D · 104 [m2/s]
303.6 101.325 0.226 ± 2%
371.3 101.325 0.327 ± 2%
495.5 101.325 0.541 ± 2%
586.1 101.325 0.703 ± 2%
687.2 101.325 0.911 ± 2%
790.4 101.325 1.19 ± 2%
922.0 101.325 1.53 ± 2%
References
1970W2 Weissman, S., DuBro, G.A.: 5th Proc. Symp. Thermophys. Prop. (1970); Bonilla, C.F. (ed.),
New York: ASME, 1970, p. 78–83.

Diffusion of zinc (1); argon (2) 1
Diffusion of zinc (1); argon (2)

Vapor in Gas
Zn (1) zinc 7440-66-6

Ar (2) argon 7440-37-1
T [K] p [atm] D · 104 [m2/s]
819.5 ± 1 1 0.930
859.4 ± 1 1 0.982
872.6 ± 1 1 1.03
887.6 ± 1 1 0.917
917.3 ± 1 1 1.12
955.9 ± 1 1 1.17
989.0 ± 1 1 1.23
1031.6 ± 1 1 1.34
1064.0 ± 1 1 1.43
1096.6 ± 1 1 1.50
1119.0 ± 1 1 1.58
1140.4 ± 1 1 1.61
Reference

Diffusion of zinc (1); hydrogen (2) 1
Diffusion of zinc (1); hydrogen (2)

Vapor in Gas
Zn (1) zinc 7440-66-6

H2 (2) hydrogen 1333-74-0
T [K] p [atm] D · 104 [m2/s]
780.1 ± 1 1 4.08
818.2 ± 1 1 4.37
847.9 ± 1 1 4.73
907.9 ± 1 1 5.18
946.5 ± 1 1 5.47
977.4 ± 1 1 5.74
998.9 ± 1 1 5.93
1031.6 ± 1 1 6.22
1052.8 ± 1 1 6.45
1084.8 ± 1 1 6.81
1117.9 ± 1 1 7.18
Reference

Diffusion of zinc (1); helium (2) 1
Diffusion of zinc (1); helium (2)

Vapor in Gas
Zn (1) zinc 7440-66-6

He (2) helium 7440-59-7
T [K] p [atm] D · 104 [m2/s]
828.8 ± 1 1 3.53
858.8 ± 1 1 3.70
887.5 ± 1 1 3.95
916.6 ± 1 1 4.16
946.3 ± 1 1 4.32
977.4 ± 1 1 4.62
1009.4 ± 1 1 4.84
1042.1 ± 1 1 5.12
1074.5 ± 1 1 5.36
1117.8 ± 1 1 5.72
Reference

Diffusion of zinc (1); nitrogen (2) 1
Diffusion of zinc (1); nitrogen (2)

Vapor in Gas
Zn (1) zinc 7440-66-6

N2 (2) nitrogen 7727-37-9
T [K] p [atm] D · 104 [m2/s]
800.9 ± 1 1 11.13
848.9 ± 1 1 1.28
878.1 ± 1 1 1.33
897.3 ± 1 1 1.39
927.5 ± 1 1 1.44
957.4 ± 1 1 1.51
989.2 ± 1 1 1.58
1031.3 ± 1 1 1.69
1073.9 ± 1 1 1.82
1107.2 ± 1 1 1.97
1135.0 ± 1 1 2.15
Reference

Diffusion of tetrachloro-methane (1); carbon dioxide (2) 1
Diffusion of tetrachloro-methane (1); carbon dioxide (2)

Supercritical Fluid Systems

Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: TAYLOR Ref.: 1990E4
T [K] p [MPa] D · 109 [m2/s]
298.15 ± 0.2 10.25 0.96 ± 5%
298.15 ± 0.2 14.75 0.77 ± 5%
309.15 ± 0.2 10.25 0.96 ± 5%
309.15 ± 0.2 14.75 0.77 ± 5%
Reference
1990E4 Erkey, C., Gadalla, H., Akgerman, A.: J. Supercrit. Fluids 3 (1990) 180–185.

Diffusion of tetrachloro-methane (1); sulfur hexafluoride (2) 1
Diffusion of tetrachloro-methane (1); sulfur hexafluoride (2)


Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: TAYLOR Ref.: 1987K3
T [K] p [bar] D · 108 [m2/s]
328 35.0 4.10
328 42.0 3.12
328 46.7 2.00
328 51.2 1.43
328 72.2 1.05
328 98.3 0.92
328 143.5 0.78
Comment: solute (1) in supercritical SF6
Reference
1987K3 Kopner, A., Hamm, A., Ellert, J., Feist, R., Schneider, G.M.: Chem. Eng. Science 42 (1987)
2213–2218.

Diffusion of trichloro-methane (1); carbon dioxide (2) 1
Diffusion of trichloro-methane (1); carbon dioxide (2)


Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: No Info Ref.: 1998S5
T [K] p [bar] D · 109 [m2/s]
313.15 160.0 13.3

Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: TAYLOR Ref.: 1996F5
T [K] p [MPa] D · 109 [m2/s]
313.2 16.0 13.3 ± 3%
References
1998S5 Suarez, J.J., Medina, I., Bueno, J.L.: Fluid Phase Equilib. 153 (1998) 167–212.
1996F5 Funazukuri, T.: J. Chem. Eng. Jpn. 29 (1996) 191–192.

Diffusion of dichloro-methane (1); carbon dioxide (2) 1
Diffusion of dichloro-methane (1); carbon dioxide (2)


T [K] p [MPa] D · 109 [m2/s]
313.2 16.0 14.4 ± 3%

Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: No Info Ref.: 1996F5
T [K] p [bar] D · 109 [m2/s]
313.15 160.0 14.4
Reference

Diffusion of methanol (1); carbon dioxide (2) 1
Diffusion of methanol (1); carbon dioxide (2)


Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: TAYLOR Ref.: 1995M3
T [K] p [MPa] D · 108 [m2/s]
313.8 8.31 2.81
313.3 10.14 2.28
313.2 12.10 2.17
314.1 14.10 1.85
313.2 16.02 1.78
323.5 8.52 3.06
323.3 10.36 2.63
322.9 12.11 2.30
324.1 14.04 2.03
333.2 8.12 3.21
333.2 10.23 2.86
333.2 12.13 2.48
333.2 14.07 2.12
343.2 10.27 3.20
343.2 12.07 3.06
343.2 14.15 2.49
Reference
1995M3 Mei, D.H., Liu, H.Q., Wang, W.C.: J. Chem. Ind. Eng. (China) 46 (1995) 357–364.

Diffusion of ethanol (1); carbon dioxide (2) 1
Diffusion of ethanol (1); carbon dioxide (2)


T [K] p [MPa] D · 108 [m2/s]
313.7 8.24 2.58
313.3 10.14 2.08
313.3 12.14 2.00
314.1 14.16 1.73
323.3 8.29 2.87
323.3 10.30 2.39
322.8 12.10 2.17
324.1 14.08 1.91
333.2 8.11 2.97
333.2 10.24 2.49
333.2 12.11 2.40
333.2 14.21 2.05
343.2 8.17 3.22
343.2 10.29 2.87
343.2 12.09 2.47
343.2 14.17 2.28
Reference

Diffusion of propan-2-one (1); trifluoro-chloro-methane (2) 1
Diffusion of propan-2-one (1); trifluoro-chloro-methane (2)


T [K] p [bar] D · 108 [m2/s]
313.15 44.5 4.02
313.15 45.9 3.29
313.15 47.0 3.10
313.15 49.1 2.45
313.15 50.6 2.11
313.15 51.9 2.06
313.15 55.6 1.86
313.15 58.0 1.81
313.15 69.0 1.61
313.15 81.0 1.45
Comment: solute (1) in supercritical CClF3
Reference
2213–2218.



T [K] p [MPa] D · 108 [m2/s]
308.15 7.94 3.360
308.15 7.97 3.106
308.15 7.97 3.145
308.15 8.05 2.653
308.15 8.06 2.969
308.15 8.06 2.750
308.15 8.07 2.979
308.15 8.08 2.890
308.15 8.17 2.780
308.15 8.17 2.916
308.15 8.26 2.964
308.15 8.26 2.676
308.15 8.33 2.707
308.15 8.36 2.513
308.15 8.36 2.428
308.15 8.44 2.399
308.15 8.44 2.816
308.15 8.53 2.461
308.15 8.62 2.218
308.15 8.70 2.294
308.15 8.72 2.290
308.15 8.73 2.127
308.15 8.79 1.964
308.15 8.82 2.289
308.15 8.90 2.201
308.15 9.00 2.130
308.15 9.00 1.986
308.15 9.01 1.963
308.15 9.19 1.865
308.15 9.21 2.039
308.15 9.22 2.024
308.15 9.40 1.954
308.15 9.40 1.988
308.15 9.41 2.036
308.15 9.42 2.106
308.15 9.50 2.031
308.15 9.51 1.933
308.15 9.60 1.872
308.15 9.60 1.935
308.15 9.61 2.044
(continued)
2 Diffusion of propan-2-one (1); carbon dioxide (2)
308.15 9.70 1.912

308.15 9.74 1.883
308.15 9.78 1.989
308.15 9.81 1.838
308.15 9.83 1.896
308.15 9.88 1.837
308.15 9.91 1.839
308.15 9.91 1.882
308.15 9.96 1.925
308.15 10.03 1.769
308.15 10.40 1.723
308.15 11.38 1.631
308.15 12.36 1.581
308.15 13.34 1.553
308.15 14.81 1.484
308.15 14.81 1.465
308.15 16.77 1.397
308.15 17.26 1.427
308.15 19.71 1.358
308.15 22.17 1.309
308.15 24.62 1.245
308.15 24.62 1.261
308.15 26.58 1.204
308.15 26.58 1.231
308.15 29.52 1.171
308.15 31.48 1.133
308.15 34.42 1.110
308.15 37.37 1.096
308.15 37.37 1.099
308.15 38.35 1.045
308.15 38.35 1.068
308.15 39.33 1.068
308.15 39.33 1.075
308.15 40.11 1.065
308.15 40.11 1.060
Comment: poly(ethylene glycol) coated capillary column

T [K] p [MPa] D · 108 [m2/s]
313.15 8.04 2.857
313.15 8.14 3.728
313.15 8.34 2.985
313.15 8.53 3.956
313.15 8.53 3.051
313.15 8.83 2.647
313.15 8.83 2.684
(continued)
313.15 8.93 2.930

313.15 8.93 3.042
313.15 8.93 2.677
313.15 9.04 2.710
313.15 9.14 2.735
313.15 9.24 2.630
313.15 9.32 2.449
313.15 9.33 2.589
313.15 9.42 2.813
313.15 9.44 2.337
313.15 9.44 2.670
313.15 9.51 2.542
313.15 9.81 2.213
313.15 10.01 2.121
313.15 10.13 2.121
313.15 10.99 1.933
313.15 11.28 2.038
313.15 12.06 1.780
313.15 12.26 1.932
313.15 13.24 1.811
313.15 14.03 1.703
313.15 14.22 1.609
313.15 14.22 1.676
313.15 14.22 1.679
313.15 15.20 1.650
313.15 15.99 1.602
313.15 17.16 1.562
313.15 17.95 1.488
313.15 19.91 1.458
313.15 20.11 1.488
313.15 21.87 1.424
313.15 24.62 1.349
313.15 28.54 1.268
313.15 28.54 1.266
313.15 31.78 1.184
313.15 32.46 1.216
313.15 32.46 1.201
313.15 33.84 1.188
313.15 37.37 1.147

T [K] p [MPa] D · 108 [m2/s]
308.15 ± 0.01 11.43 1.620
308.15 ± 0.01 13.97 1.481
308.15 ± 0.01 16.09 1.430
(continued)
308.15 ± 0.01 16.10 1.396

308.15 ± 0.01 16.10 1.411
308.15 ± 0.01 16.12 1.422
308.15 ± 0.01 16.85 1.370
308.15 ± 0.01 19.78 1.312
308.15 ± 0.01 24.63 1.230
308.15 ± 0.01 29.60 1.146
308.15 ± 0.01 34.49 1.087
313.15 ± 0.01 14.43 1.619
313.15 ± 0.01 14.45 1.580
313.15 ± 0.01 16.13 1.528
313.15 ± 0.01 16.15 1.535
313.15 ± 0.01 16.16 1.553
313.15 ± 0.01 16.42 1.501
313.15 ± 0.01 25.29 1.269
318.15 ± 0.01 11.49 1.998
318.15 ± 0.01 13.23 1.848
318.15 ± 0.01 16.17 1.655
318.15 ± 0.01 18.92 1.529
318.15 ± 0.01 19.80 1.503
318.15 ± 0.01 24.70 1.376
318.15 ± 0.01 29.55 1.311
318.15 ± 0.01 34.56 1.208
323.15 ± 0.01 11.12 2.536
323.15 ± 0.01 12.07 2.234
323.15 ± 0.01 13.13 2.008
323.15 ± 0.01 15.12 1.896
323.15 ± 0.01 16.10 1.805
323.15 ± 0.01 19.00 1.669
323.15 ± 0.01 21.41 1.596
323.15 ± 0.01 24.61 1.494
323.15 ± 0.01 29.49 1.347
323.15 ± 0.01 34.53 1.274
328.15 ± 0.01 15.10 2.073
328.15 ± 0.01 16.91 1.880
328.15 ± 0.01 19.79 1.740
328.15 ± 0.01 23.92 1.592
328.15 ± 0.01 29.52 1.456
328.15 ± 0.01 34.52 1.367

Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: GC Ref.: 1990D3
T [K] p [MPa] D · 108 [m2/s]
313.5 16 1.84 ± 6%
313.5 15 1.90 ± 6%
313.5 14 2.03 ± 6%
(continued)
313.5 13.5 2.04 ± 6%

313.5 13 2.10 ± 6%
313.5 12.5 2.17 ± 6%
313.5 12 2.23 ± 6%
313.5 11 2.49 ± 6%
313.5 10 2.92 ± 6%

Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: TAYLOR Ref.: 1992U1
T [K] p [MPa] D · 109 [m2/s]
299.15 ± 0.1 9.0 14.3 ± 3%
299.15 ± 0.1 10.5 14.2 ± 3%
303.15 ± 0.1 10.5 15.2 ± 3%
305.65 ± 0.1 10.5 16.2 ± 3%
308.15 ± 0.1 10.5 17.6 ± 3%

Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: TAYLOR Ref.: 1987S4
T [K] p [bar] D · 109 [m2/s]
303.15 ± 0.2 115 14.0 ± 0.5
303.15 ± 0.2 190 11.7 ± 0.5
313.15 ± 0.2 160 14.7 ± 0.4
313.15 ± 0.2 250 12.7 ± 0.4
333.15 ± 0.2 130 27.4 ± 0.3
333.15 ± 0.2 165 21.9 ± 0.9
333.15 ± 0.2 265 15.2 ± 0.5

T [K] p [MPa] D · 108 [m2/s]
313.15 11.64 1.843 ± 0.83%
313.15 12.61 1.768 ± 1.19%
313.15 13.54 1.731 ± 3.03%
313.15 14.37 1.675 ± 0.96%
313.15 14.43 1.664 ± 0.61%
313.15 16.13 1.592 ± 0.15%
313.15 17.37 1.540 ± 0.96%
313.15 17.87 1.505 ± 0.62%
313.15 20.11 1.443 ± 0.86%
313.15 21.90 1.387 ± 0.88%
313.15 24.68 1.338 ± 0.43%
313.15 25.09 1.337 ± 0.09%
(continued)

313.15 25.30 1.349 ± 0.49%

313.15 28.58 1.267 ± 0.53%

Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: TAYLOR Ref.: 1996N1
T [K] p [MPa] D · 108 [m2/s]
314.25 9.22 26.9 ± 3%
314.25 9.32 26.4 ± 3%
314.25 9.51 25.9 ± 3%
314.25 9.81 25.5 ± 3%
314.25 10.00 24.2 ± 3%
314.25 10.20 21.7 ± 3%
314.25 10.49 22.3 ± 3%
314.25 10.98 18.1 ± 3%
314.25 11.28 18.5 ± 3%
314.25 11.47 19.7 ± 3%
314.25 11.57 18.2 ± 3%
314.25 11.96 17.3 ± 3%
314.25 12.26 17.3 ± 3%
314.25 12.94 16.4 ± 3%
314.25 13.44 15.7 ± 3%
314.25 14.02 15.0 ± 3%
314.25 14.32 15.5 ± 3%
314.25 14.91 14.0 ± 3%
314.25 15.40 13.6 ± 3%
314.25 15.59 13.4 ± 3%
314.25 15.89 13.9 ± 3%
314.25 16.38 12.6 ± 3%
314.25 16.57 12.8 ± 3%
314.25 17.36 12.0 ± 3%
314.25 17.55 12.6 ± 3%
314.25 17.85 13.4 ± 3%
314.25 18.53 12.2 ± 3%
314.25 19.32 12.0 ± 3%
Comment: 1.0 microliter injected into carrier

Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: TAYLOR Ref.: 1996N1
T [K] p [MPa] D · 108 [m2/s]
314.25 9.02 16.7 ± 3%
314.25 9.12 17.9 ± 3%
314.25 9.17 18.0 ± 3%
314.25 9.22 17.5 ± 3%
314.25 9.32 16.6 ± 3%
314.25 9.41 21.1 ± 3%
(continued)
314.25 9.51 21.2 ± 3%

314.25 9.61 21.6 ± 3%
314.25 9.90 22.8 ± 3%
314.25 10.00 22.7 ± 3%
314.25 10.10 21.7 ± 3%
314.25 10.20 21.8 ± 3%
314.25 10.40 22.5 ± 3%
314.25 10.49 21.2 ± 3%
314.25 11.28 22.0 ± 3%
314.25 11.77 19.6 ± 3%
314.25 11.77 20.6 ± 3%
314.25 11.77 20.1 ± 3%
314.25 12.16 18.9 ± 3%
314.25 12.26 18.8 ± 3%
314.25 12.36 19.0 ± 3%
314.25 12.45 18.8 ± 3%
314.25 12.75 19.2 ± 3%
314.25 12.85 18.6 ± 3%
314.25 13.14 18.5 ± 3%
314.25 13.73 17.3 ± 3%
314.25 14.32 16.7 ± 3%
314.25 14.61 16.5 ± 3%
314.25 15.40 16.5 ± 3%
314.25 15.98 15.0 ± 3%
314.25 16.97 14.6 ± 3%
314.25 18.34 13.3 ± 3%
Comment: 5.7 microliter injected into carrier

T [K] p [MPa] D · 109 [m2/s]
313.2 16.0 13.8 ± 3%

T [K] p [bar] D · 109 [m2/s]
313.15 160.0 13.8

T [K] p [atm] D · 109 [m2/s]
313.15 160 13.5 ± 0.064

References
2000F6 Funazukuri, T., Kong, C.Y., Kagei, S.: Int. J. Thermophys. 21 (2000) 651–669.
1990D3 Dahmen, N., Kordikowski, A., Schneider, G.M.: J. Chromatogr. 505 (1990) 169–178.
1992U1 Umezawa, S., Nagashima, A.: J. Supercrit. Fluids 5 (1992) 242–250.
1987S4 Sassiat, P.R., Mourier, P., Caude, M.H., Rosset, R.H.: Anal. Chem. 59 (1987) 1164–1170.
2004K4 Kong, C.Y., Funazukuri, T., Kagei, S.: J. Chromatogr. A 1035 (2004) 177–193.
1996N1 Nishiumi, H., Fujita, M., Agou, K.: Fluid Phase Equilib. 117 (1996) 356–363.
1998S7 Souvignet, I., Olesik, S.V.: Anal. Chem. 70 (1998) 2783–2788.


C3H8O (1) propan-1-ol 71-23-8

T [K] p [MPa] D · 108 [m2/s]
313.8 8.23 2.28
313.2 10.13 1.72
313.6 12.00 1.58
313.2 14.11 1.54
323.3 8.34 2.57
323.3 10.34 1.85
325.8 12.09 1.63
324.1 14.10 1.57
333.2 8.15 2.95
333.2 10.21 2.04
333.2 12.11 1.82
333.2 14.07 1.69
343.2 8.18 2.75
343.2 10.26 2.45
343.2 12.01 1.95
343.2 14.13 1.67
Reference

Diffusion of butan-2-one (1); carbon dioxide (2) 1
Diffusion of butan-2-one (1); carbon dioxide (2)

C4H8O (1) butan-2-one 78-93-3

T [K] p [MPa] D · 108 [m2/s]
308.15 ± 0.01 8.33 1.875
308.15 ± 0.01 8.64 1.951
308.15 ± 0.01 9.07 1.759
308.15 ± 0.01 9.74 1.640
308.15 ± 0.01 11.43 1.502
308.15 ± 0.01 13.97 1.389
308.15 ± 0.01 16.82 1.256
308.15 ± 0.01 19.78 1.203
308.15 ± 0.01 24.67 1.113
308.15 ± 0.01 29.56 1.045
308.15 ± 0.01 34.51 1.003
313.15 ± 0.01 13.33 1.599
313.15 ± 0.01 16.42 1.413
313.15 ± 0.01 19.75 1.307
313.15 ± 0.01 24.56 1.209
313.15 ± 0.01 29.52 1.124
313.15 ± 0.01 34.47 1.074
318.15 ± 0.01 13.23 1.699
318.15 ± 0.01 16.15 1.567
318.15 ± 0.01 18.94 1.418
318.15 ± 0.01 19.83 1.372
318.15 ± 0.01 24.66 1.253
318.15 ± 0.01 29.53 1.174
318.15 ± 0.01 34.53 1.104
323.15 ± 0.01 12.07 2.181
323.15 ± 0.01 13.12 1.962
323.15 ± 0.01 16.11 1.705
323.15 ± 0.01 19.00 1.539
323.15 ± 0.01 21.42 1.454
323.15 ± 0.01 24.62 1.383
323.15 ± 0.01 29.51 1.261
323.15 ± 0.01 34.53 1.216
328.15 ± 0.01 15.13 1.856
328.15 ± 0.01 16.91 1.754
328.15 ± 0.01 19.77 1.611
328.15 ± 0.01 23.93 1.452
328.15 ± 0.01 29.54 1.331
328.15 ± 0.01 34.52 1.245

2 Diffusion of butan-2-one (1); carbon dioxide (2)
C4H8O (1) butan-2-one 78-93-3

T [K] p [MPa] D · 108 [m2/s]
314.5 18 1.75 ± 6%
314.5 17 1.70 ± 6%
314.5 16 1.79 ± 6%
314.5 15 1.86 ± 6%
314.5 14 1.90 ± 6%
314.5 13 2.13 ± 6%
314.5 12.5 2.18 ± 6%
314.5 12 2.20 ± 6%
314.5 11.5 2.49 ± 6%
314.5 11 2.55 ± 6%
314.5 10.5 2.59 ± 6%
314.5 10.2 2.94 ± 6%
314.5 10 2.86 ± 6%
314.5 9.7 3.42 ± 6%
314.5 9.5 3.46 ± 6%
C4H8O (1) butan-2-one 78-93-3

T [K] p [bar] D · 109 [m2/s]
313.15 160 13.7
C4H8O (1) butan-2-one 78-93-3

T [K] p [MPa] D · 109 [m2/s]
313.2 16.0 13.7 ± 3%
References

Diffusion of tetrahydrofuran (1); carbon dioxide (2) 1
Diffusion of tetrahydrofuran (1); carbon dioxide (2)

C4H8O (1) tetrahydrofuran 109-99-9

T [K] p [atm] D · 108 [m2/s]
313.15 80 3.723
313.15 100 2.110
313.15 120 1.741
313.15 140 1.561
313.15 160 1.417
323.15 80 4.608
323.15 100 3.182
323.15 120 2.125
323.15 140 1.788
323.15 160 1.687
333.15 80 5.235
333.15 100 3.573
333.15 120 2.708
333.15 140 2.006
333.15 160 1.981
Reference
1998S6 Silva, C.M., Macedo, E.A.: Ind. Eng. Chem. Res. 37 (1998) 1490–1498.

Diffusion of acetic acid ethyl ester (1); carbon dioxide (2) 1
Diffusion of acetic acid ethyl ester (1); carbon dioxide (2)


Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: TAYLOR Ref.: 1995L1
T [K] p [bar] D · 108 [m2/s]
308 ± 0.2 80.4 2.71 ± 10%
308 ± 0.2 89.0 1.82 ± 5%
308 ± 0.2 102.8 1.53 ± 5%
308 ± 0.2 129.7 1.41 ± 5%
308 ± 0.2 143.0 1.38 ± 5%
318 ± 0.2 75.6 3.80 ± 10%
318 ± 0.2 89.1 2.73 ± 10%
318 ± 0.2 95.6 2.44 ± 10%
318 ± 0.2 116.6 1.62 ± 5%
318 ± 0.2 143.0 1.52 ± 5%
328 ± 0.2 88.1 3.23 ± 10%
328 ± 0.2 101.5 2.45 ± 10%
328 ± 0.2 115.9 2.24 ± 10%
328 ± 0.2 129.4 1.88 ± 5%
328 ± 0.2 142.8 1.70 ± 5%

T [K] p [bar] D · 109 [m2/s]
313.15 160 12.2

T [K] p [MPa] D · 109 [m2/s]
313.2 16 12.2 ± 3%
References
1995L1 Lai, C.C., Tang, C.S.: Ind. Eng. Chem. Res. 34 (1995) 674–680.

Diffusion of 1,4-dioxane (1); carbon dioxide (2) 1
Diffusion of 1,4-dioxane (1); carbon dioxide (2)

C4H8O2 (1) 1,4-dioxane 123-91-1

T [K] p [bar] D · 109 [m2/s]
313.15 160.0 11.8
C4H8O2 (1) 1,4-dioxane 123-91-1

T [K] p [MPa] D · 109 [m2/s]
313.2 16 11.8 ± 3%
References

Diffusion of diethyl ether (1); carbon dioxide (2) 1
Diffusion of diethyl ether (1); carbon dioxide (2)


T [K] p [atm] D · 108 [m2/s]
313.15 80 3.255
313.15 100 2.069
313.15 120 1.571
313.15 140 1.406
313.15 160 1.391
323.15 80 3.910
323.15 100 2.812
323.15 120 1.935
323.15 140 1.751
323.15 160 1.584
333.15 80 4.998
333.15 100 3.228
333.15 120 2.410
333.15 140 1.900
333.15 160 1.831

T [K] p [bar] D · 109 [m2/s]
313.15 160 13.3

T [K] p [MPa] D · 109 [m2/s]
313.2 16 13.3 ± 3%
References

Diffusion of butan-1-ol (1); carbon dioxide (2) 1
Diffusion of butan-1-ol (1); carbon dioxide (2)

C4H10O (1) butan-1-ol 71-36-3

T [K] p [MPa] D · 108 [m2/s]
313.6 8.20 1.74
313.2 10.13 1.30
313.8 12.26 1.11
313.2 14.11 0.96
323.1 8.31 1.95
323.3 10.35 1.60
322.9 12.18 1.26
324.1 14.04 1.14
333.2 8.15 2.33
333.2 10.17 1.76
333.2 12.11 1.45
333.2 14.07 1.34
343.2 8.17 2.66
343.2 10.25 2.14
343.2 12.10 1.84
343.2 14.13 1.43
Reference

Diffusion of 1,1,1,5,5,5-hexafluoro-pentan-2,4-dione (1); carbon dioxide (2) 1
Diffusion of 1,1,1,5,5,5-hexafluoro-pentan-2,4-dione (1);

carbon dioxide (2)
C5H2F6O2 (1) 1,1,1,5,5,5-hexafluoro-pentan-2,4-dione 1522-22-1

Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: TAYLOR Ref.: 2001Y1
T [K] p [bar] D · 109 [m2/s]
308.15 109.6 9.85 ± 0.16
308.15 120.7 9.75 ± 0.90
308.15 155.1 8.90 ± 0.15
308.15 186.9 7.99 ± 0.39
308.15 213.1 7.06 ± 0.22
313.15 104.1 11.2 ± 0.6
313.15 116.9 10.7 ± 0.7
313.15 153.8 9.33 ± 0.47
313.15 187.2 8.55 ± 0.40
313.15 211.0 7.37 ± 0.29
318.15 106.2 12.8 ± 0.9
318.15 121.0 11.8 ± 0.6
318.15 153.8 10.6 ± 0.7
318.15 191.0 8.72 ± 0.27
318.15 222.0 8.62 ± 0.26
Reference
2001Y1 Yang, X.N., Matthews, M.A.: J. Chem. Eng. Data 46 (2001) 588–595.

Diffusion of 1,1,1-trifluoro-pentan-2,4-dione (1); carbon dioxide (2) 1
Diffusion of 1,1,1-trifluoro-pentan-2,4-dione (1); carbon

dioxide (2)
C5H5F3O2 (1) 1,1,1-trifluoro-pentan-2,4-dione 367-57-7

T [K] p [bar] D · 109 [m2/s]
308.15 107.6 11.9 ± 0.2
308.15 126.2 10.9 ± 0.1
308.15 153.1 10.3 ± 0.1
308.15 183.8 9.45 ± 0.06
308.15 215.1 8.98 ± 0.12
313.15 108.9 13.5 ± 0.2
313.15 123.7 12.4 ± 0.3
313.15 149.8 11.6 ± 0.3
313.15 178.6 11.0 ± 0.4
313.15 109.6 9.45 ± 0.55
318.15 106.9 17.2 ± 0.3
318.15 127.6 13.9 ± 0.2
318.15 157.9 12.3 ± 0.1
318.15 188.2 11.1 ± 0.2
318.15 215.8 10.4 ± 0.1
Reference

Diffusion of cyclopentanone (1); carbon dioxide (2) 1
Diffusion of cyclopentanone (1); carbon dioxide (2)

C5H8O (1) cyclopentanone 120-92-3

T [K] p [bar] D · 109 [m2/s]
314.0 100 17.46
314.0 105 16.28
314.0 110 15.33
314.0 115 15.03
314.0 125 13.74
314.0 135 13.20
314.0 150 12.81
314.0 180 11.36
Comment: supercritical fluid chromatography; exp. error: 6%; erratum [1990D1] data corrected
Reference
1990D2 Dahmen, N., Dülberg, A., Schneider, G.M.: Ber. Bunsenges. Phys. Chem. 94 (1990) 384–386.
1990D1 Dahmen, N., Dülberg, A., Schneider, G.M.: Ber. Bunsenges. Phys. Chem. 94 (1990) 710.

Diffusion of pentan-3-one (1); carbon dioxide (2) 1
Diffusion of pentan-3-one (1); carbon dioxide (2)

C5H10O (1) pentan-3-one 96-22-0

T [K] p [MPa] D · 108 [m2/s]
308.15 ± 0.01 8.65 1.731
308.15 ± 0.01 9.08 1.676
308.15 ± 0.01 9.74 1.522
308.15 ± 0.01 11.43 1.368
308.15 ± 0.01 13.97 1.271
308.15 ± 0.01 16.84 1.161
308.15 ± 0.01 19.77 1.129
308.15 ± 0.01 24.65 1.033
308.15 ± 0.01 29.58 0.965
308.15 ± 0.01 34.51 0.921
313.15 ± 0.01 11.47 1.537
313.15 ± 0.01 13.34 1.466
313.15 ± 0.01 16.42 1.307
313.15 ± 0.01 19.74 1.187
313.15 ± 0.01 24.57 1.115
313.15 ± 0.01 29.51 1.042
313.15 ± 0.01 34.48 0.980
318.15 ± 0.01 11.49 1.801
318.15 ± 0.01 13.24 1.601
318.15 ± 0.01 16.15 1.455
318.15 ± 0.01 18.91 1.307
318.15 ± 0.01 19.83 1.283
318.15 ± 0.01 24.69 1.165
318.15 ± 0.01 29.53 1.105
318.15 ± 0.01 34.57 1.036
323.15 ± 0.01 12.07 1.969
323.15 ± 0.01 13.12 1.802
323.15 ± 0.01 15.14 1.581
323.15 ± 0.01 16.11 1.571
323.15 ± 0.01 19.00 1.437
323.15 ± 0.01 21.42 1.353
323.15 ± 0.01 24.60 1.267
323.15 ± 0.01 29.52 1.163
323.15 ± 0.01 34.53 1.100
328.15 ± 0.01 15.10 1.762
328.15 ± 0.01 16.90 1.675
328.15 ± 0.01 19.76 1.496
328.15 ± 0.01 23.94 1.369
328.15 ± 0.01 34.49 1.101

2 Diffusion of pentan-3-one (1); carbon dioxide (2)
C5H10O (1) pentan-3-one 96-22-0

T [K] p [MPa] D · 108 [m2/s]
313.5 16 1.72 ± 6%
313.5 15 1.77 ± 6%
313.5 14 1.86 ± 6%
313.5 13.5 1.93 ± 6%
313.5 13 1.96 ± 6%
313.5 12.5 2.07 ± 6%
313.5 12 2.05 ± 6%
313.5 11 2.32 ± 6%
313.5 10 2.68 ± 6%
314.5 17 1.68 ± 6%
314.5 16 1.61 ± 6%
314.5 15 1.81 ± 6%
314.5 14 1.97 ± 6%
314.5 13 1.93 ± 6%
314.5 12 2.09 ± 6%
314.5 11.5 2.22 ± 6%
314.5 11 2.58 ± 6%
314.5 10.5 2.55 ± 6%
314.5 10.2 2.74 ± 6%
314.5 10 3.17 ± 6%
C5H10O (1) pentan-3-one 96-22-0

T [K] p [bar] D · 109 [m2/s]
314.0 100 18.54
314.0 105 17.29
314.0 110 15.49
314.0 115 14.88
314.0 125 14.15
314.0 135 13.20
314.0 150 12.18
314.0 180 11.47
Comment: supercritical fluid chromatography; exp. error: 6%; erratum [1990D1] data corrected
References

Diffusion of pentan-2-one (1); carbon dioxide (2) 1
Diffusion of pentan-2-one (1); carbon dioxide (2)

C5H10O (1) pentan-2-one 107-87-9

T [K] p [MPa] D · 108 [m2/s]
314.5 18 1.53 ± 6%
314.5 17 1.69 ± 6%
314.5 16 1.69 ± 6%
314.5 15 1.84 ± 6%
314.5 14 1.81 ± 6%
314.5 13 1.93 ± 6%
314.5 12.5 1.97 ± 6%
314.5 12 2.12 ± 6%
314.5 11.5 2.24 ± 6%
314.5 11 2.25 ± 6%
314.5 10.5 2.58 ± 6%
314.5 10.2 3.28 ± 6%
314.5 10 2.79 ± 6%
314.5 9.7 3.28 ± 6%
314.5 9.5 3.30 ± 6%
C5H10O (1) pentan-2-one 107-87-9

T [K] p [MPa] D · 108 [m2/s]
308.15 ± 0.01 8.88 1.563
308.15 ± 0.01 9.36 1.645
308.15 ± 0.01 9.86 1.471
308.15 ± 0.01 10.76 1.405
313.15 ± 0.01 7.60 2.541
313.15 ± 0.01 9.32 1.952
313.15 ± 0.01 10.08 1.708
313.15 ± 0.01 11.45 1.551
313.15 ± 0.01 12.54 1.470
313.15 ± 0.01 13.80 1.404
313.15 ± 0.01 14.80 1.367
313.15 ± 0.01 16.42 1.281
313.15 ± 0.01 18.68 1.220
313.15 ± 0.01 20.54 1.168
313.15 ± 0.01 23.02 1.119
313.15 ± 0.01 26.68 1.072
313.15 ± 0.01 29.25 1.048
314.5 ± 0.01 10.44 1.752
(continued)

2 Diffusion of pentan-2-one (1); carbon dioxide (2)
314.5 ± 0.01 11.55 1.609

314.5 ± 0.01 12.82 1.508
314.5 ± 0.01 14.30 1.421
314.5 ± 0.01 15.63 1.374
314.5 ± 0.01 17.27 1.297
314.5 ± 0.01 19.20 1.224
References

Diffusion of pentane (1); carbon dioxide (2)

C5H12 (1) pentane 109-66-0

T [K] p [MPa] D · 109 [m2/s]
299.15 ± 0.1 9.0 13.7 ± 3%
299.15 ± 0.1 10.5 13.0 ± 3%
303.15 ± 0.1 10.5 14.1 ± 3%
305.65 ± 0.1 10.5 15.7 ± 3%
308.15 ± 0.1 10.5 17.6 ± 3%
Reference

Diffusion of pentan-1-ol (1); carbon dioxide (2) 1
Diffusion of pentan-1-ol (1); carbon dioxide (2)

C5H12O (1) pentan-1-ol 71-41-0

T [K] p [MPa] D · 108 [m2/s]
313.5 8.20 1.59
313.23 10.11 1.27
313.4 12.13 1.16
313.1 14.08 1.01
323.3 8.20 1.88
323.3 10.34 1.45
323.3 12.14 1.19
324.1 14.09 1.04
333.2 8.10 1.94
333.2 10.15 1.52
333.2 12.08 1.38
333.2 14.10 1.21
343.2 8.17 2.00
343.2 10.17 1.92
343.2 12.05 1.73
343.2 14.12 1.44
Reference

Diffusion of 1,3-dibromo-benzene (1); trifluoro-chloro-methane (2) 1
Diffusion of 1,3-dibromo-benzene (1); trifluoro-chloro-

methane (2)
C6H4Br2 (1) 1,3-dibromo-benzene 108-36-1

T [K] p [bar] D · 108 [m2/s]
318.15 47.3 1.88
318.15 50.7 1.68
318.15 52.2 1.32
318.15 53.8 1.30
318.15 55.7 1.29
318.15 57.9 1.25
318.15 60.8 1.11
318.15 64.7 1.07
318.15 70.4 0.87
318.15 78.7 0.88
318.15 91.0 0.83
318.15 109.1 0.70
Comment: solute (1) in supercritical CClF3
Reference
2213–2218.

Diffusion of 1,2-dichloro-benzene (1); carbon dioxide (2) 1
Diffusion of 1,2-dichloro-benzene (1); carbon dioxide (2)


Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: TAYLOR Ref.: 2002G1
T [K] p [MPa] D · 109 [m2/s]
313.0 15 10.41
313.0 20 9.53
313.0 25 8.86
313.0 30 8.59
313.0 35 8.12
323.0 15 12.56
323.0 20 10.81
323.0 25 10.24
323.0 30 9.26
323.0 35 9.18
333.0 15 15.76
333.0 20 12.58
333.0 25 11.39
333.0 30 10.44
333.0 35 10.02
Comment: reproducibility ±2%
Reference
2002G1 González, L.M., Bueno, J.L., Medina, I.: J. Supercrit. Fluids 24 (2002) 219–229.

Diffusion of 1,4-dichloro-benzene (1); carbon dioxide (2) 1
Diffusion of 1,4-dichloro-benzene (1); carbon dioxide (2)


T [K] p [bar] D · 109 [m2/s]
298.15 148.24 8.47 ± 0.27
298.15 126.86 9.05 ± 0.07
298.15 103.42 9.81 ± 0.01
298.15 92.39 10.2 ± 0.3
308.15 170.99 9.06 ± 0.12
308.15 148.24 9.47 ± 0.35
308.15 126.86 9.98 ± 0.04
308.15 103.42 11.2 ± 0.2
308.15 92.39 12.4 ± 0.1
308.15 82.74 14.0 ± 0.2
318.15 170.99 11.6 ± 0.27
318.15 148.24 12.3 ± 0.07
318.15 126.86 13.8 ± 0.01
318.15 103.42 17.3 ± 0.3
Reference
2000F4 Fu, H., Coelho, L.A.F., Matthews, M.A.: J. Supercrit. Fluids 18 (2000) 141–155.

Diffusion of bromobenzene (1); carbon dioxide (2) 1
Diffusion of bromobenzene (1); carbon dioxide (2)


T [K] p [bar] D · 109 [m2/s]
313.15 150.0 11.7
313.15 200.0 11.1
313.15 250.0 10.1
313.15 350.0 8.4
323.15 150.0 14.8
323.15 250.0 10.1
Reference

Diffusion of chlorobenzene (1); carbon dioxide (2) 1
Diffusion of chlorobenzene (1); carbon dioxide (2)


T [K] p [bar] D · 109 [m2/s]
313.15 150.0 12.0
313.15 200.0 11.0
313.15 250.0 10.2
313.15 300.0 9.1
313.15 350.0 8.9
323.15 150.0 15.5
Reference

Diffusion of iodobenzene (1); carbon dioxide (2) 1
Diffusion of iodobenzene (1); carbon dioxide (2)

C6H5I (1) iodobenzene 591-50-4

T [K] p [bar] D · 109 [m2/s]
313.15 150.0 10.3
313.15 200.0 10.2
313.15 250.0 8.9
313.15 300.0 8.3
313.15 350.0 8.0
323.15 250.0 13.9
Reference

Diffusion of nitrobenzene (1); carbon dioxide (2) 1
Diffusion of nitrobenzene (1); carbon dioxide (2)


T [K] p [bar] D · 109 [m2/s]
313.15 150.0 10.7
313.15 250.0 9.5
313.15 350.0 8.0
323.15 150.0 12.7
323.15 200.0 11.0
323.15 250.0 10.2
323.15 300.0 9.3
323.15 350.0 8.9

T [K] p [MPa] D · 109 [m2/s]
313 15 10.66 ± 2%
313 20 9.77 ± 2%
313 25 8.95 ± 2%
313 30 8.37 ± 2%
313 35 7.98 ± 2%
323 15 12.70 ± 2%
323 20 11.00 ± 2%
323 25 10.22 ± 2%
323 30 9.33 ± 2%
323 35 8.86 ± 2%
333 15 13.97 ± 2%
333 20 12.51 ± 2%
333 25 11.55 ± 2%
333 30 10.60 ± 2%
333 35 10.06 ± 2%
References
2001G1 Gonzalez, L.M., Bueno, J.L., Medina, I.: Ind. Eng. Chem. Res. 40 (2001) 3711–3716.


C6H6 (1) benzene 71-43-2

T [K] p [MPa] D · 108 [m2/s]
308.15 5.99 6.411
308.15 5.99 6.442
308.15 6.43 4.996
308.15 6.44 5.663
308.15 6.67 6.073
308.15 7.03 4.918
308.15 7.03 4.928
308.15 7.21 4.542
308.15 7.52 2.964
308.15 7.53 2.453
308.15 7.56 2.437
308.15 7.58 3.110
308.15 7.58 3.384
308.15 7.59 3.408
308.15 7.59 3.423
308.15 7.59 3.028
308.15 7.61 2.965
308.15 8.11 2.424
308.15 8.12 2.401
308.15 8.30 2.270
308.15 8.41 2.253
308.15 8.44 2.152
308.15 8.44 2.153
308.15 8.48 2.096
308.15 8.85 2.018
308.15 8.87 1.927
308.15 8.88 1.922
308.15 9.00 1.935
308.15 9.41 1.814
308.15 9.79 1.720
308.15 9.92 1.792
308.15 10.10 1.744
308.15 10.59 1.663
308.15 11.08 1.655
308.15 11.66 1.623
308.15 12.11 1.588
308.15 12.53 1.599
308.15 13.11 1.529
308.15 13.57 1.571
308.15 13.94 1.487
(continued)
308.15 14.48 1.509

308.15 15.75 1.403
308.15 16.10 1.445
308.15 16.70 1.427
308.15 18.16 1.385
308.15 19.03 1.337
308.15 20.16 1.352
308.15 21.09 1.302
308.15 22.13 1.294
308.15 25.14 1.244
308.15 25.18 1.256
308.15 25.18 1.236
308.15 27.72 1.217
308.15 30.29 1.204
Comment: D*1(2) at infinite dilution of (1) in (2)
C6H6 (1) benzene 71-43-2

T [K] p [MPa] D · 108 [m2/s]
313.15 7.55 5.047
313.15 7.62 4.769
313.15 7.62 4.331
313.15 7.66 4.272
313.15 8.80 2.344
313.15 9.02 2.341
313.15 9.29 2.270
313.15 9.58 2.158
313.15 9.92 2.060
313.15 10.32 1.943
313.15 10.70 1.914
313.15 11.07 1.876
313.15 11.09 1.858
313.15 11.57 1.809
313.15 12.13 1.745
313.15 12.20 1.727
313.15 13.11 1.716
313.15 13.22 1.690
313.15 13.30 1.672
313.15 13.62 1.680
313.15 14.40 1.616
313.15 14.42 1.612
313.15 16.08 1.571
313.15 16.11 1.531
313.15 16.12 1.540
313.15 16.13 1.531
313.15 16.16 1.538
313.15 16.43 1.568
(continued)
313.15 18.16 1.468

313.15 20.08 1.405
313.15 20.16 1.402
313.15 21.17 1.388
313.15 21.18 1.381
313.15 22.12 1.353
313.15 22.15 1.371
313.15 25.17 1.262
313.15 25.19 1.285
313.15 25.27 1.316
313.15 27.71 1.233
313.15 30.28 1.213
313.15 34.48 1.162
C6H6 (1) benzene 71-43-2

T [K] p [MPa] D · 108 [m2/s]
318.15 9.28 2.479
318.15 9.60 2.389
318.15 9.94 2.333
318.15 10.18 2.465
318.15 11.00 2.170
318.15 11.96 1.991
318.15 13.01 1.876
318.15 14.03 1.806
318.15 15.08 1.713
318.15 16.05 1.664
318.15 17.00 1.619
318.15 17.98 1.571
318.15 19.06 1.534
318.15 20.06 1.498
318.15 20.56 1.511
318.15 21.07 1.466
318.15 22.03 1.454
318.15 23.03 1.429
318.15 24.08 1.391
318.15 25.00 1.376
318.15 25.96 1.367
318.15 27.07 1.369
318.15 27.98 1.329
318.15 29.03 1.317
318.15 30.18 1.291

C6H6 (1) benzene 71-43-2

T [K] p [MPa] D · 108 [m2/s]
323.15 10.09 2.456
323.15 10.28 2.385
323.15 10.49 2.330
323.15 10.67 2.345
323.15 10.88 2.367
323.15 11.12 2.596
323.15 11.47 2.408
323.15 11.95 2.327
323.15 12.08 2.318
323.15 13.13 2.110
323.15 14.00 1.957
323.15 15.13 1.887
323.15 15.33 1.879
323.15 16.07 1.835
323.15 17.06 1.768
323.15 18.03 1.709
323.15 19.00 1.644
323.15 20.00 1.595
323.15 21.09 1.560
323.15 22.05 1.566
323.15 23.05 1.548
323.15 24.07 1.477
323.15 25.03 1.449
323.15 26.09 1.444
323.15 27.06 1.425
323.15 28.01 1.404
323.15 28.96 1.367
323.15 30.19 1.356
328.15 9.05 3.150
328.15 9.74 2.854
328.15 9.98 2.749
328.15 9.99 2.740
328.15 10.64 2.600
328.15 11.24 2.466
328.15 11.56 2.460
328.15 12.07 2.464
328.15 12.55 2.388
328.15 13.14 2.325
328.15 13.43 2.231
328.15 14.10 2.159
328.15 15.08 2.040
328.15 16.13 1.919
328.15 16.90 1.894
328.15 17.16 1.865
(continued)

328.15 17.99 1.840

328.15 19.03 1.762
328.15 19.78 1.715
328.15 20.06 1.770
328.15 21.03 1.672
328.15 21.99 1.638
328.15 23.03 1.584
328.15 23.96 1.598
328.15 24.68 1.571
328.15 25.75 1.528
328.15 26.83 1.517
328.15 29.23 1.454
C6H6 (1) benzene 71-43-2

Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: GC Ref.: 2002F1
T [K] p [MPa] D · 108 [m2/s]
313.15 12 1.631
323.15 12 2.112
313.15 14 1.476
323.15 14 1.723
313.15 15 1.294
333.15 15 2.046
313.15 16 1.297
C6H6 (1) benzene 71-43-2

Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: TAYLOR Ref.: 1999A4
T [K] p [MPa] D · 109 [m2/s]
313.15 ± 0.1 7.86 24.02 ± 1.05
313.15 ± 0.1 8.37 23.39 ± 0.68
313.15 ± 0.1 8.81 20.86 ± 0.92
313.15 ± 0.1 9.35 19.47 ± 0.33
313.15 ± 0.1 9.76 17.52 ± 0.34
313.15 ± 0.1 10.30 16.15 ± 0.61
313.15 ± 0.1 10.79 15.55 ± 0.08
313.15 ± 0.1 11.82 14.25 ± 0.31
313.15 ± 0.1 12.81 13.20 ± 0.22
313.15 ± 0.1 13.61 12.75 ± 0.05
313.15 ± 0.1 14.71 12.45 ± 0.11
313.15 ± 0.1 15.69 12.38 ± 0.19
313.15 ± 0.1 16.67 11.82 ± 0.18
313.15 ± 0.1 17.56 11.28 ± 0.16
Comment: injection volume of benzene sample: 0.7 microliter

C6H6 (1) benzene 71-43-2

T [K] p [MPa] D · 109 [m2/s]
313.15 ± 0.1 7.87 22.46 ± 0.46
313.15 ± 0.1 8.38 22.55 ± 0.23
313.15 ± 0.1 8.88 22.93 ± 0.13
313.15 ± 0.1 9.38 20.88 ± 0.66
313.15 ± 0.1 9.89 18.80 ± 0.17
313.15 ± 0.1 10.37 17.16 ± 2.01
313.15 ± 0.1 13.73 13.13 ± 0.00
313.15 ± 0.1 10.37 18.45 ± 1.59
313.15 ± 0.1 10.85 16.78 ± 0.47
313.15 ± 0.1 11.91 15.00 ± 0.48
313.15 ± 0.1 12.80 13.12 ± 0.74
313.15 ± 0.1 14.66 12.93 ± 0.22
313.15 ± 0.1 15.71 12.08 ± 0.23
313.15 ± 0.1 16.67 11.62 ± 0.19
313.15 ± 0.1 17.63 11.55 ± 0.05
C6H6 (1) benzene 71-43-2

T [K] p [MPa] D · 109 [m2/s]
313.15 ± 0.1 7.90 9.61 ± 0.47
313.15 ± 0.1 8.30 11.99 ± 0.13
313.15 ± 0.1 8.72 14.54 ± 0.21
313.15 ± 0.1 9.33 20.10 ± 0.47
313.15 ± 0.1 9.70 20.63 ± 0.68
313.15 ± 0.1 10.25 20.07 ± 0.35
313.15 ± 0.1 10.64 19.73 ± 0.40
313.15 ± 0.1 11.71 18.08 ± 0.12
313.15 ± 0.1 12.69 16.62 ± 0.12
313.15 ± 0.1 13.68 15.65 ± 0.14
313.15 ± 0.1 14.71 14.61 ± 0.10
313.15 ± 0.1 15.61 14.70 ± 0.21
313.15 ± 0.1 16.65 14.12 ± 0.16
313.15 ± 0.1 17.75 13.20 ± 0.28
C6H6 (1) benzene 71-43-2

T [K] p [MPa] D · 109 [m2/s]
313.15 ± 0.1 7.92 3.38 ± 0.38
313.15 ± 0.1 8.44 6.21 ± 0.78
(continued)
313.15 ± 0.1 8.83 10.29 ± 0.81

313.15 ± 0.1 9.33 12.48 ± 0.72
313.15 ± 0.1 9.86 13.39 ± 1.00
313.15 ± 0.1 10.30 12.77 ± 0.47
313.15 ± 0.1 10.80 14.49 ± 0.30
313.15 ± 0.1 11.68 14.96 ± 0.25
313.15 ± 0.1 12.88 15.16 ± 0.36
313.15 ± 0.1 13.74 14.34 ± 0.04
313.15 ± 0.1 14.65 13.85 ± 0.22
313.15 ± 0.1 15.59 13.59 ± 0.05
313.15 ± 0.1 16.75 13.07 ± 0.15
313.15 ± 0.1 17.45 12.94 ± 0.40
C6H6 (1) benzene 71-43-2

T [K] p [MPa] D · 108 [m2/s]
313.9 8.32 2.85
313.3 10.16 2.10
313.3 12.13 1.66
314.1 14.12 1.42
313.2 16.10 1.36
323.5 8.43 2.92
323.2 10.38 2.57
322.9 12.18 1.87
324.1 14.03 1.64
333.2 8.17 2.94
333.2 10.27 2.56
333.2 12.03 2.27
333.2 14.11 2.03
343.2 10.29 2.67
343.2 12.11 2.61
343.2 14.01 2.34
C6H6 (1) benzene 71-43-2

Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: GC Ref.: 1994S5
T [K] p [bar] D · 109 [m2/s]
313.15 150 12.99 ± 4%
313.15 200 11.20 ± 4%
313.15 250 10.27 ± 4%
313.15 300 9.67 ± 4%
313.15 350 9.01 ± 4%
323.15 150 15.58 ± 4%
323.15 200 12.97 ± 4%
323.15 250 11.72 ± 4%
(continued)
323.15 300 11.10 ± 4%

323.15 350 10.58 ± 4%
333.15 150 18.18 ± 4%
333.15 200 15.40 ± 4%
333.15 250 13.60 ± 4%
333.15 300 12.44 ± 4%
333.15 350 11.57 ± 4%
C6H6 (1) benzene 71-43-2

T [K] p [bar] D · 109 [m2/s]
313.15 150 12.99
313.15 200 11.20
313.15 250 10.27
313.15 300 9.67
313.15 350 9.01
323.15 150 15.58
323.15 200 12.97
323.15 250 11.72
323.15 300 11.10
323.15 350 10.58
333.15 150 18.18
333.15 200 15.40
333.15 250 13.60
333.15 300 12.44
333.15 350 11.57
Comment: benzene in supercritical CO2; reproducibility: ±1%
C6H6 (1) benzene 71-43-2

T [K] p [MPa] D · 109 [m2/s]
314.14 ± 0.07 10.00 1.98 ± 0.06
314.14 ± 0.07 13.53 1.51 ± 0.03
307.94 ± 0.02 9.68 1.49 ± 0.05
307.93 ± 0.01 12.46 1.37 ± 0.02
307.93 ± 0.02 9.68 1.59 ± 0.04
307.92 ± 0.02 9.68 1.74 ± 0.09
309.67 ± 0.03 10.24 1.62 ± 0.04
309.68 ± 0.03 10.24 1.53 ± 0.02
309.66 ± 0.02 10.25 1.49 ± 0.03

C6H6 (1) benzene 71-43-2

T [K] p [MPa] D · 109 [m2/s]
299.15 ± 0.1 9.0 14.3 ± 3%
299.15 ± 0.1 10.5 14.0 ± 3%
303.15 ± 0.1 10.5 15.0 ± 3%
305.65 ± 0.1 10.5 15.8 ± 3%
308.15 ± 0.1 10.5 17.4 ± 3%
C6H6 (1) benzene 71-43-2

T [K] p [bar] D · 109 [m2/s]
313.15 150 12.99
313.15 200 11.20
313.15 250 10.27
313.15 300 9.67
313.15 350 9.01
323.15 150 15.58
323.15 200 12.97
323.15 250 11.72
323.15 300 11.10
323.15 350 10.58
333.15 150 18.18
333.15 200 15.40
333.15 250 13.60
333.15 300 12.44
333.15 350 11.57
C6H6 (1) benzene 71-43-2

T [K] p [MPa] D · 109 [m2/s]
313 16.0 12.4 ± 0.4
313 25.0 11.5 ± 0.2
C6H6 (1) benzene 71-43-2

T [K] p [MPa] D · 109 [m2/s]
298.15 ± 0.2 10.5 1.16 ± 5%
298.15 ± 0.2 14.75 1.12 ± 5%
298.15 ± 0.2 21.0 0.81 ± 5%
298.15 ± 0.2 25.25 0.75 ± 5%
309.15 ± 0.2 9.0 1.81 ± 5%
(continued)
309.15 ± 0.2 10.5 1.67 ± 5%

309.15 ± 0.2 14.75 1.36 ± 5%
309.15 ± 0.2 25.0 0.95 ± 5%
C6H6 (1) benzene 71-43-2

T [K] p [bar] D · 109 [m2/s]
303.15 ± 0.2 115 13.8 ± 0.3
303.15 ± 0.2 190 11.5 ± 0.1
313.15 ± 0.2 110 21.3 ± 0.3
313.15 ± 0.2 130 16.5 ± 0.3
313.15 ± 0.2 155 14.9 ± 0.2
313.15 ± 0.2 160 14.5 ± 0.8
313.15 ± 0.2 215 12.8 ± 0.3
313.15 ± 0.2 250 11.5 ± 0.1
333.15 ± 0.2 130 25.8 ± 1.0
333.15 ± 0.2 165 21.0 ± 0.8
333.15 ± 0.2 265 14.8 ± 0.2
C6H6 (1) benzene 71-43-2

T [K] p [bar] D · 108 [m2/s]
308.15 110 1.46 ± 3%
313.15 110 1.58 ± 3%
318.15 110 1.97 ± 3%
323.15 110 2.16 ± 3%
328.15 110 2.76 ± 3%
308.15 130 1.37 ± 3%
313.15 130 1.40 ± 3%
318.15 130 1.60 ± 3%
323.15 130 1.88 ± 3%
328.15 130 1.94 ± 3%
C6H6 (1) benzene 71-43-2

T [K] p [bar] D · 108 [m2/s]
313.15 80 2.99 ± 4%
313.15 85 2.37 ± 4%
313.15 87.5 2.28 ± 4%
313.15 88 2.22 ± 4%
313.15 90 1.93 ± 4%
313.15 92 2.01 ± 3%
313.15 95 1.83 ± 3%
(continued)
313.15 95 1.89 ± 3%
313.15 100 1.67 ± 3%
313.15 110 1.58 ± 3%
313.15 130 1.39 ± 3%
313.15 160 1.29 ± 3%
C6H6 (1) benzene 71-43-2

T [K] p [bar] D · 109 [m2/s]
313.15 160.0 14.1
C6H6 (1) benzene 71-43-2

T [K] p [atm] D · 109 [m2/s]
313.15 160 13.6 ± 0.13
C6H6 (1) benzene 71-43-2

T [K] p [bar] D · 109 [m2/s]
313.25 ± 0.2 160.3 12.6
C6H6 (1) benzene 71-43-2

T [K] p [MPa] D · 109 [m2/s]
313.2 16.0 14.1 ± 3%
C6H6 (1) benzene 71-43-2

T [K] p [MPa] D · 108 [m2/s]
313.4 ± 0.1 16.2 1.28
References
2002F1 Filho, C.A., Silva, C.M., Quadri, M.B., Macedo, E.A.: J. Chem. Eng. Data 47 (2002)
1351–1354.
1999A4 Ago, K., Nishiumi, H.: J. Chem. Eng. Jpn. 32 (1999) 563–568.
1994S5 Suarez, J.J., Bueno, J.L., Medina, I., Martinez, J.L.: Afinidad 51 (1994) 132–142.
1993S9 Suárez, J.J., Bueno, J.L., Medina, I.: Chem. Eng. Science 48 (1993) 2419–2427.

1993S6 Levelt Sengers, J.M.H., Deiters, U.K., Klask, U., Swidersky, P., Schneider, G.M.: Int. J. Ther-
mophys. 14 (1993) 893–922.
1992S4 Suarez, J.J., Bueno, J.L., Medina, I., Dizy, J.: Afinidad 438 (1992) 101–113.
1992F2 Funazukuri, T., Ishiwata, Y., Wakao, N.: AIChE J. 38 (1992) 1761–1768.
1990E4 Erkey, C., Gadalla, H., Akgerman, A.: J. Supercrit. Fluids 3 (1990) 180–185.
1979S7 Swaid, I., Schneider, G.M.: Ber. Bunsenges. Phys. Chem. 83 (1979) 969–974.
1983L3 Lauer, H.H., McManigill, D., Board, R.D.: Anal. Chem. 55 (1983) 1370–1375.
1989F3 Funazukuri, T., Hachisu, S., Wakao, N.: Anal. Chem. 61 (1989) 118–122.

Diffusion of benzene (1); 2,3-dimethyl-butane (2) 1
Diffusion of benzene (1); 2,3-dimethyl-butane (2)

C6H6 (1) benzene 71-43-2

T [K] p [MPa] D · 109 [m2/s]
523.2 ± 0.2 15.32 25.0 ± 2%
523.2 ± 0.2 10.23 28.9 ± 2%
523.2 ± 0.2 6.897 33.9 ± 2%
523.2 ± 0.2 5.352 38.9 ± 2%
535.2 ± 0.2 15.90 26.6 ± 2%
535.2 ± 0.2 12.44 29.0 ± 2%
535.2 ± 0.2 8.145 35.0 ± 2%
535.2 ± 0.2 6.276 40.1 ± 2%
548.2 ± 0.2 14.37 29.8 ± 2%
548.2 ± 0.2 9.938 35.3 ± 2%
548.2 ± 0.2 7.614 40.4 ± 2%
Comment: tracer diffusion in supercritical solvent
Reference
1985S7 Sun, C.K.J., Chen, S.H.: AIChE J. 31 (1985) 1904–1910.

Diffusion of benzene (1); sulfur hexafluoride (2) 1
Diffusion of benzene (1); sulfur hexafluoride (2)

C6H6 (1) benzene 71-43-2

T [K] p [bar] D · 108 [m2/s]
328 35.0 5.60
328 42.0 3.80
328 45.5 2.77
328 46.7 2.52
328 48.3 1.95
328 51.2 1.77
328 72.2 1.32
328 98.3 1.14
328 143.5 0.95
C6H6 (1) benzene 71-43-2

T [K] p [MPa] D · 109 [m2/s]
303.15 4.5 10.3 ± 3%
313.15 4.5 12.3 ± 3%
323.15 4.5 17.4 ± 3%
303.15 5.0 10.1 ± 3%
313.15 5.0 11.8 ± 3%
323.15 5.0 15.2 ± 3%
328.15 5.0 18.6 ± 3%
333.15 5.0 24.6 ± 3%
303.15 6.0 9.80 ± 3%
313.15 6.0 11.1 ± 3%
323.15 6.0 13.4 ± 3%
333.15 6.0 17.3 ± 3%
303.15 9.0 9.30 ± 3%
313.15 9.0 10.1 ± 3%
323.15 9.0 11.2 ± 3%
333.15 9.0 12.9 ± 3%
References
2213–2218.
1993U1 Umezawa, S., Tomita, S., Nagashima, A.: Trans. Jap. Soc. Mech. Eng. B 59 (1993) 499–506.

Diffusion of phenol (1); carbon dioxide (2) 1
Diffusion of phenol (1); carbon dioxide (2)

C6H6O (1) phenol 108-95-2

T [K] p [MPa] D · 109 [m2/s]
308.15 ± 0.01 8.72 16.14
308.15 ± 0.01 8.89 15.78
308.15 ± 0.01 9.08 15.38
308.15 ± 0.01 9.30 14.92
308.15 ± 0.01 9.50 14.60
308.15 ± 0.01 9.68 14.50
308.15 ± 0.01 9.86 14.17
308.15 ± 0.01 10.10 13.89
308.15 ± 0.01 10.60 13.50
308.15 ± 0.01 11.60 12.91
308.15 ± 0.01 12.55 12.45
308.15 ± 0.01 13.54 12.02
308.15 ± 0.01 14.98 11.62
308.15 ± 0.01 16.10 11.42
308.15 ± 0.01 17.40 11.04
308.15 ± 0.01 19.61 10.67
308.15 ± 0.01 20.20 10.56
308.15 ± 0.01 22.63 10.10
308.15 ± 0.01 25.25 9.83
308.15 ± 0.01 28.47 9.52
308.15 ± 0.01 30.28 9.44
313.15 ± 0.01 10.10 16.88
313.15 ± 0.01 10.60 16.01
313.15 ± 0.01 11.60 14.90
313.15 ± 0.01 12.55 14.08
313.15 ± 0.01 13.54 13.52
313.15 ± 0.01 13.54 13.54
313.15 ± 0.01 14.40 13.06
313.15 ± 0.01 14.98 12.85
313.15 ± 0.01 16.10 12.40
313.15 ± 0.01 17.40 12.17
313.15 ± 0.01 19.61 11.58
313.15 ± 0.01 20.06 11.50
313.15 ± 0.01 22.63 11.07
313.15 ± 0.01 25.25 10.63
313.15 ± 0.01 28.47 10.33
313.15 ± 0.01 30.28 10.18
318.15 ± 0.01 11.60 17.51
318.15 ± 0.01 12.55 16.13
318.15 ± 0.01 13.54 15.33
(continued)
2 Diffusion of phenol (1); carbon dioxide (2)
318.15 ± 0.01 14.98 14.48

318.15 ± 0.01 16.10 13.85
318.15 ± 0.01 17.40 13.41
318.15 ± 0.01 19.61 12.68
318.15 ± 0.01 22.63 11.99
318.15 ± 0.01 25.25 11.47
318.15 ± 0.01 28.47 11.02
318.15 ± 0.01 30.28 10.82
323.15 ± 0.01 12.55 19.09
323.15 ± 0.01 13.54 17.57
323.15 ± 0.01 14.98 16.21
323.15 ± 0.01 16.10 15.46
323.15 ± 0.01 17.40 14.86
323.15 ± 0.01 19.61 14.05
323.15 ± 0.01 22.63 13.15
323.15 ± 0.01 25.25 12.52
323.15 ± 0.01 28.47 11.95
323.15 ± 0.01 30.28 11.81
328.15 ± 0.01 17.40 16.64
328.15 ± 0.01 19.61 15.47
328.15 ± 0.01 22.63 14.40
328.15 ± 0.01 25.25 13.75
328.15 ± 0.01 28.47 13.14
328.15 ± 0.01 30.28 12.78
C6H6O (1) phenol 108-95-2

T [K] p [MPa] D · 108 [m2/s]
313.15 ± 0.01 10.58 1.604 ± 3.7%
313.15 ± 0.01 13.03 1.378 ± 3.7%
313.15 ± 0.01 14.07 1.325 ± 3.7%
313.15 ± 0.01 14.84 1.295 ± 3.7%
313.15 ± 0.01 15.54 1.268 ± 3.7%
313.15 ± 0.01 16.00 1.247 ± 3.7%
313.15 ± 0.01 17.08 1.216 ± 3.7%
313.15 ± 0.01 19.08 1.164 ± 3.7%
313.15 ± 0.01 22.10 1.113 ± 3.7%
313.15 ± 0.01 26.05 1.060 ± 3.7%
313.15 ± 0.01 30.25 1.016 ± 3.7%
C6H6O (1) phenol 108-95-2

Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: TAYLOR Ref.: 2002C3
T [K] p [bar] D · 109 [m2/s]
298.15 ± 0.05 148.24 8.98 ± 0.11
(continued)
Diffusion of phenol (1); carbon dioxide (2) 3
298.15 ± 0.05 126.88 9.10 ± 0.16

298.15 ± 0.05 103.42 9.33 ± 0.30
298.15 ± 0.05 92.39 9.65 ± 0.19
298.15 ± 0.05 82.74 10.81 ± 0.32
318.15 ± 0.05 170.36 12.18 ± 0.38
318.15 ± 0.05 147.95 14.26 ± 0.61
C6H6O (1) phenol 108-95-2

T [K] p [bar] D · 108 [m2/s]
308 ± 0.2 80.4 2.07 ± 5%
308 ± 0.2 85.6 1.62 ± 5%
308 ± 0.2 89.3 1.53 ± 5%
308 ± 0.2 102.8 1.36 ± 5%
308 ± 0.2 116.1 1.26 ± 5%
308 ± 0.2 129.8 1.19 ± 5%
308 ± 0.2 143.1 1.15 ± 5%
313 ± 0.2 88.3 2.20 ± 5%
313 ± 0.2 101.9 1.57 ± 5%
313 ± 0.2 115.8 1.52 ± 5%
313 ± 0.2 129.7 1.35 ± 5%
313 ± 0.2 144.6 1.34 ± 5%
318 ± 0.2 89.2 2.55 ± 5%
318 ± 0.2 103.1 1.98 ± 5%
318 ± 0.2 117.7 1.66 ± 5%
318 ± 0.2 131.3 1.48 ± 5%
318 ± 0.2 144.6 1.45 ± 5%
328 ± 0.2 103.5 2.62 ± 5%
328 ± 0.2 116.9 2.27 ± 5%
328 ± 0.2 130.8 2.02 ± 5%
328 ± 0.2 144.2 1.82 ± 5%
C6H6O (1) phenol 108-95-2

T [K] p [MPa] D · 108 [m2/s]
313.15 11.64 1.529 ± 0.16%
313.15 12.61 1.388 ± 0.25%
313.15 13.54 1.370 ± 0.15%
313.15 14.37 1.328 ± 0.14%
313.15 14.43 1.306 ± 0.19%
313.15 16.13 1.261 ± 0.31%
313.15 17.37 1.237 ± 0.12%
313.15 17.87 1.218 ± 0.12%
313.15 20.11 1.176 ± 0.16%
313.15 21.90 1.128 ± 0.03%
(continued)
4 Diffusion of phenol (1); carbon dioxide (2)
313.15 24.68 1.093 ± 0.13%

313.15 25.09 1.083 ± 0.25%
313.15 25.30 1.078 ± 0.16%
313.15 28.58 1.039 ± 0.06%
Comment: phenol as tracer (0.032 micromol) loaded
References
2000F5 Funazukuri, T., Kong, C.Y., Murooka, N., Kagei, S.: Ind. Eng. Chem. Res. 39 (2000)
4462–4469.
2002F3 Funazukuri, T., Kong, C.Y., Kagei, S.: Fluid Phase Equilib. 194-197 (2002) 1169–1178.
2002C3 Coelho, L.A.F., de Oliveira, J.V., Tavares, F.W., Matthews, M.A.: Fluid Phase Equilib. 194-197
(2002) 1131–1140.
2004K4 Kong, C.Y., Funazukuri, T., Kagei, S.: J. Chromatogr. A 1035 (2004) 177–193.

Diffusion of hexane (1); carbon dioxide (2) 1
Diffusion of hexane (1); carbon dioxide (2)

C6H14 (1) hexane 110-54-3

T [K] p [MPa] D · 109 [m2/s]
299.15 ± 0.1 9.0 13.7 ± 3%
299.15 ± 0.1 10.5 13.0 ± 3%
303.15 ± 0.1 10.5 14.0 ± 3%
305.65 ± 0.1 10.5 15.4 ± 3%
308.15 ± 0.1 10.5 17.6 ± 3%
Reference

Diffusion of hexane (1); sulfur hexafluoride (2) 1
Diffusion of hexane (1); sulfur hexafluoride (2)

C6H14 (1) hexane 110-54-3

T [K] p [MPa] D · 109 [m2/s]
303.15 4.5 11.2 ± 3%
313.15 4.5 13.0 ± 3%
323.15 4.5 18.3 ± 3%
303.15 5.0 11.0 ± 3%
313.15 5.0 12.6 ± 3%
323.15 5.0 16.0 ± 3%
328.15 5.0 19.4 ± 3%
333.15 5.0 24.6 ± 3%
303.15 6.0 10.7 ± 3%
313.15 6.0 12.0 ± 3%
323.15 6.0 14.1 ± 3%
333.15 6.0 18.2 ± 3%
303.15 9.0 10.3 ± 3%
313.15 9.0 11.1 ± 3%
323.15 9.0 12.2 ± 3%
333.15 9.0 13.7 ± 3%
Reference

Diffusion of diisopropyl ether (1); carbon dioxide (2) 1
Diffusion of diisopropyl ether (1); carbon dioxide (2)

C6H14O (1) diisopropyl ether 108-20-3

T [K] p [atm] D · 108 [m2/s]
313.15 80 2.961
313.15 100 1.663
313.15 120 1.426
313.15 140 1.225
313.15 160 1.182
323.15 80 3.730
323.15 100 2.651
323.15 120 1.823
323.15 140 1.706
323.15 160 1.379
333.15 80 4.897
333.15 100 3.500
333.15 120 2.406
333.15 140 2.057
333.15 160 1.529
Reference

Diffusion of benzaldehyde (1); carbon dioxide (2) 1
Diffusion of benzaldehyde (1); carbon dioxide (2)

C7H6O (1) benzaldehyde 100-52-7

T [K] p [MPa] D · 109 [m2/s]
313.2 16.0 10.9 ± 3%
C7H6O (1) benzaldehyde 100-52-7

T [K] p [bar] D · 109 [m2/s]
313.15 160.0 10.9
References

Diffusion of benzoic acid (1); carbon dioxide (2) 1
Diffusion of benzoic acid (1); carbon dioxide (2)


T [K] p [bar] D · 109 [m2/s]
293.15 131.00 7.12 ± 0.30
293.15 113.76 7.68 ± 0.16
293.15 92.39 8.09 ± 0.13
293.15 82.74 8.73 ± 0.47
298.15 131.00 7.80 ± 0.07
298.15 113.76 8.20 ± 0.41
298.15 92.39 9.96 ± 0.13
298.15 82.47 10.6 ± 0.8
298.15 71.02 12.3 ± 0.8
308.15 170.99 8.95 ± 0.15
308.15 148.24 9.78 ± 0.35
308.15 126.86 10.4 ± 0.1
308.15 103.42 11.2 ± 0.4
308.15 92.39 12.8 ± 0.2
308.15 89.63 13.6 ± 0.1
308.15 88.25 15.1 ± 0.4
308.15 82.74 16.2 ± 0.4

T [K] p [atm] D · 109 [m2/s]
308 170 9.7 ± 0.4
308 272 8.9 ± 0.2
318 170 11.9 ± 0.3
318 272 10.4 ± 0.2
328 170 12.9 ± 0.4
328 272 12.1 ± 0.3

T [K] p [atm] D · 109 [m2/s]
308 170 7.2 ± 0.2
308 272 6.0 ± 0.1
318 170 8.4 ± 0.3
318 272 6.8 ± 0.2
(continued)

2 Diffusion of benzoic acid (1); carbon dioxide (2)
328 170 9.7 ± 0.3

328 272 8.0 ± 0.3
Comment: carbon dioxide contains 5 mole percent methanol

T [K] p [bar] D · 109 [m2/s]
308.15 172.3 9.7
308.15 175.6 8.9
318.15 172.5 11.9
318.15 275.6 10.4
328.15 172.5 12.9
328.15 275.6 12.1

T [K] p [bar] D · 109 [m2/s]
308.15 173.0 5.7
308.15 275.6 6.0
318.15 172.5 8.4
318.15 173.0 6.1
318.15 275.6 6.8
326.15 172.3 7.2
328.15 172.5 9.7
328.15 173.0 6.7
328.15 275.6 8.0
Comment: diffusion in supercritical carbon dioxide; 5% ethanol as modifier

Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: OTE Ref.: 1986D1
T [K] p [bar] D · 109 [m2/s]
318.2 160 4.90
318.2 200 4.27
328.2 160 9.14
328.2 200 6.83

T [K] p [bar] D · 109 [m2/s]
298.8 71 13.4 ± 1.9
317.8 102 19.4 ± 3.1
(continued)

Diffusion of benzoic acid (1); carbon dioxide (2) 3
318.1 141 14.3 ± 1.0

318.7 160 13.1 ± 1.1
318.1 161 12.6 ± 1.2
318.1 201 12.3 ± 0.4
318.1 251 10.9 ± 0.2
References
1993S10 Shenai, V.M., Hamilton, B.L., Matthews, M.A.: Supercritical Fluid Engineering Science; Kiran,
E., Brenneke, J.F. (eds.), ACS Symposium Series 514 (1993) 92–103.
1986D1 Debenedetti, P.G., Reid, R.C.: AIChE J. 32 (1986) 2034–2046.
1994C7 Catchpole, O.J., King, M.B.: Ind. Eng. Chem. Res. 33 (1994) 1828–1837.

Diffusion of benzoic acid (1); sulfur hexafluoride (2) 1
Diffusion of benzoic acid (1); sulfur hexafluoride (2)


T [K] p [bar] D · 109 [m2/s]
328.2 65 9.26
328.2 80 8.61
328.2 120 7.02
338.2 65 13.40
338.2 80 10.70
338.2 120 8.15
Reference

Diffusion of 2-nitro-anisole (1); carbon dioxide (2) 1
Diffusion of 2-nitro-anisole (1); carbon dioxide (2)

C7H7NO3 (1) 2-nitro-anisole 91-23-6

T [K] p [MPa] D · 109 [m2/s]
313.0 15 9.30
313.0 20 8.32
313.0 25 7.45
313.0 30 7.19
313.0 35 6.87
323.0 15 10.92
323.0 20 9.53
323.0 25 8.87
323.0 30 8.11
323.0 35 7.67
333.0 15 13.05
333.0 20 10.90
333.0 25 9.96
333.0 30 8.99
333.0 35 8.63
Reference

Diffusion of toluene (1); carbon dioxide (2)

C7H8 (1) toluene 108-88-3

T [K] p [bar] D · 108 [m2/s]
308 ± 0.2 75.1 2.81 ± 10%
308 ± 0.2 80.4 2.35 ± 10%
308 ± 0.2 85.6 1.83 ± 5%
308 ± 0.2 89.3 1.67 ± 5%
308 ± 0.2 102.8 1.55 ± 5%
308 ± 0.2 116.1 1.38 ± 5%
308 ± 0.2 129.8 1.37 ± 5%
308 ± 0.2 143.1 1.30 ± 5%
318 ± 0.2 75.8 3.32 ± 10%
318 ± 0.2 89.2 2.89 ± 10%
318 ± 0.2 103.1 1.93 ± 5%
318 ± 0.2 116.6 1.61 ± 5%
318 ± 0.2 129.8 1.54 ± 5%
318 ± 0.2 143.1 1.63 ± 5%
328 ± 0.2 88.3 3.11 ± 10%
328 ± 0.2 101.7 2.49 ± 10%
328 ± 0.2 129.0 1.97 ± 5%
328 ± 0.2 142.4 1.82 ± 5%
C7H8 (1) toluene 108-88-3

T [K] ρ [kg/m3 ] D · 109 [m2/s]
313.95 746.0 13.0
313.95 801.0 12.3
313.95 893.0 12.1
313.95 867.0 12.0
313.95 890.0 11.9
313.95 910.0 11.9
C7H8 (1) toluene 108-88-3

T [K] p [bar] D · 109 [m2/s]
313.15 150 12.23 ± 4%
313.15 200 11.86 ± 4%
313.15 250 10.39 ± 4%
313.15 300 9.75 ± 4%
(continued)

2 Diffusion of toluene (1); carbon dioxide (2)
313.15 350 9.32 ± 4%

323.15 150 15.26 ± 4%
323.15 200 12.99 ± 4%
323.15 250 11.93 ± 4%
323.15 300 10.94 ± 4%
323.15 350 10.32 ± 4%
333.15 150 17.18 ± 4%
333.15 200 14.81 ± 4%
333.15 250 13.42 ± 4%
333.15 300 12.21 ± 4%
333.15 350 11.41 ± 4%
C7H8 (1) toluene 108-88-3

T [K] p [MPa] D · 109 [m2/s]
313.73 ± 0.07 13.52 1.42 ± 0.01
306.76 ± 0.02 13.40 1.23 ± 0.02
306.78 ± 0.02 10.63 1.41 ± 0.06
306.12 ± 0.02 10.37 1.44 ± 0.03
308.36 ± 0.27 10.37 1.45 ± 0.02
307.93 ± 0.05 9.68 1.51 ± 0.03
307.90 ± 0.01 13.43 1.29 ± 0.02
307.91 ± 0.01 13.43 1.30 ± 0.02
C7H8 (1) toluene 108-88-3

T [K] p [bar] D · 109 [m2/s]
313.15 150 12.73
313.15 200 11.86
313.15 250 10.39
313.15 300 9.75
313.15 350 9.32
323.15 150 15.26
323.15 200 12.99
323.15 250 11.93
323.15 300 10.94
323.15 350 10.32
333.15 150 17.18
333.15 200 14.53
333.15 250 13.42
333.15 300 12.21
333.15 350 11.41

C7H8 (1) toluene 108-88-3

T [K] p [bar] D · 109 [m2/s]
313.15 150 12.23
313.15 200 11.86
313.15 250 10.39
313.15 300 9.75
313.15 350 9.32
323.15 150 15.26
323.15 200 12.99
323.15 250 11.93
323.15 300 10.94
323.15 350 10.32
333.15 150 17.18
333.15 200 14.81
333.15 250 13.42
333.15 300 12.21
333.15 350 11.41
Comment: toluene in supercritical CO2; reproducibility: ±1%
C7H8 (1) toluene 108-88-3

T [K] p [MPa] D · 109 [m2/s]
313.2 16.0 12.7 ± 3%
C7H8 (1) toluene 108-88-3

T [K] p [bar] D · 109 [m2/s]
313.15 160.0 12.7
References
1993S6 Levelt Sengers, J.M.H., Deiters, U.K., Klask, U., Swidersky, P., Schneider, G.M.: Int. J. Ther-
mophys. 14 (1993) 893–922.

Diffusion of toluene (1); 2,3-dimethyl-butane (2) 1
Diffusion of toluene (1); 2,3-dimethyl-butane (2)

C7H8 (1) toluene 108-88-3

T [K] p [MPa] D · 109 [m2/s]
523.2 ± 0.2 15.32 23.0 ± 2%
523.2 ± 0.2 10.23 26.4 ± 2%
523.2 ± 0.2 6.897 30.8 ± 2%
535.2 ± 0.2 15.90 24.4 ± 2%
535.2 ± 0.2 12.44 27.0 ± 2%
535.2 ± 0.2 8.145 31.3 ± 2%
535.2 ± 0.2 6.276 36.8 ± 2%
548.2 ± 0.2 14.37 28.1 ± 2%
548.2 ± 0.2 9.938 32.7 ± 2%
548.2 ± 0.2 7.614 38.7 ± 2%
Reference

Diffusion of toluene (1); sulfur hexafluoride (2) 1
Diffusion of toluene (1); sulfur hexafluoride (2)

C7H8 (1) toluene 108-88-3

T [K] p [bar] D · 108 [m2/s]
328 35.0 4.50
328 42.0 3.32
328 44.0 2.84
328 45.5 2.28
328 46.7 2.04
328 48.3 1.79
328 51.2 1.60
328 58.2 1.43
328 72.2 1.21
328 98.3 1.05
328 143.5 0.90
Reference
2213–2218.

Diffusion of anisole (1); carbon dioxide (2) 1
Diffusion of anisole (1); carbon dioxide (2)

C7H8O (1) anisole 100-66-3

T [K] p [MPa] D · 109 [m2/s]
313 15 11.78 ± 2%
313 20 10.15 ± 2%
313 25 9.25 ± 2%
313 30 8.70 ± 2%
313 35 8.23 ± 2%
323 15 13.17 ± 2%
323 20 11.30 ± 2%
323 25 10.33 ± 2%
323 30 9.54 ± 2%
323 35 8.93 ± 2%
333 15 14.97 ± 2%
333 20 13.27 ± 2%
333 25 11.76 ± 2%
333 30 10.83 ± 2%
333 35 10.16 ± 2%
Reference

Diffusion of cycloheptanone (1); carbon dioxide (2) 1
Diffusion of cycloheptanone (1); carbon dioxide (2)

C7H12O (1) cycloheptanone 502-42-1

T [K] p [bar] D · 109 [m2/s]
314.0 100 16.12
314.0 105 14.01
314.0 110 13.87
314.0 115 13.87
314.0 125 12.30
314.0 135 11.47
314.0 150 10.91
314.0 180 9.776
Comment: supercritical fluid chromatography; exp. error: ±6%; erratum [1990D1] data corrected
References

Diffusion of heptan-2-one (1); carbon dioxide (2) 1
Diffusion of heptan-2-one (1); carbon dioxide (2)

C7H14O (1) heptan-2-one 110-43-0

T [K] p [MPa] D · 108 [m2/s]
314.5 18 1.40 ± 6%
314.5 17 1.42 ± 6%
314.5 16 1.46 ± 6%
314.5 15 1.49 ± 6%
314.5 14 1.60 ± 6%
314.5 13 1.72 ± 6%
314.5 12.5 1.71 ± 6%
314.5 12 1.81 ± 6%
314.5 11.5 2.01 ± 6%
314.5 11 2.11 ± 6%
314.5 10.5 2.27 ± 6%
314.5 10 2.71 ± 6%
314.5 9.7 2.70 ± 6%
314.5 9.5 2.92 ± 6%
Reference


C7H14O (1) heptan-3-one 106-35-4

T [K] p [bar] D · 109 [m2/s]
314.0 100 15.80
314.0 105 14.44
314.0 110 14.01
314.0 115 13.06
314.0 125 12.06
314.0 135 11.70
314.0 150 10.38
314.0 180 9.488
References


C7H14O (1) heptan-4-one 123-19-3

T [K] p [MPa] D · 108 [m2/s]
313.5 16 1.59 ± 6%
313.5 15 1.64 ± 6%
313.5 14 1.70 ± 6%
313.5 13.5 1.76 ± 6%
313.5 13 1.79 ± 6%
313.5 12.5 1.87 ± 6%
313.5 12 1.91 ± 6%
313.5 11 2.11 ± 6%
313.5 10 2.43 ± 6%
Reference

Diffusion of 2,4-dimethyl-pentan-3-one (1); carbon dioxide (2) 1
Diffusion of 2,4-dimethyl-pentan-3-one (1);

carbon dioxide (2)
C7H14O (1) 2,4-dimethyl-pentan-3-one 565-80-0

T [K] p [MPa] D · 108 [m2/s]
313.5 16 1.58 ± 6%
313.5 15 1.60 ± 6%
313.5 14 1.70 ± 6%
313.5 13.5 1.73 ± 6%
313.5 13 1.77 ± 6%
313.5 12.5 1.83 ± 6%
313.5 12 1.89 ± 6%
313.5 11 2.10 ± 6%
313.5 10 2.45 ± 6%
Reference

Diffusion of heptane (1); carbon dioxide (2) 1
Diffusion of heptane (1); carbon dioxide (2)

C7H16 (1) heptane 142-82-5

T [K] p [MPa] D · 109 [m2/s]
299.15 ± 0.1 9.0 13.4 ± 3%
299.15 ± 0.1 10.5 12.6 ± 3%
303.15 ± 0.1 10.5 14.0 ± 3%
305.65 ± 0.1 10.5 15.4 ± 3%
308.15 ± 0.1 10.5 17.1 ± 3%
Reference

Diffusion of 1,1,1-trifluoro-4-(2-thienyl)-butan-2,4-dione (1); carbon dioxide (2) 1
Diffusion of 1,1,1-trifluoro-4-(2-thienyl)-butan-2,4-dione
(1); carbon dioxide (2)
C8H5F3O2S (1) 1,1,1-trifluoro-4-(2-thienyl)-butan-2,4-dione 326-91-0

T [K] p [bar] D · 109 [m2/s]
308.15 105.5 9.91 ± 0.06
308.15 119.3 8.47 ± 0.39
308.15 153.1 7.73 ± 0.20
308.15 190.3 6.90 ± 0.11
308.15 224.1 6.44 ± 0.23
313.15 106.2 10.1 ± 0.7
313.15 122.0 8.93 ± 0.27
313.15 155.8 7.82 ± 0.14
313.15 189.6 7.68 ± 0.25
313.15 215.5 6.62 ± 0.38
318.15 105.5 12.4 ± 0.5
318.15 123.4 9.93 ± 0.18
318.15 149.6 8.74 ± 0.22
318.15 188.9 7.82 ± 0.27
318.15 220.6 7.12 ± 0.35
Reference

Diffusion of indole (1); carbon dioxide (2) 1
Diffusion of indole (1); carbon dioxide (2)

C8H7N (1) indole 120-72-9

T [K] p [MPa] D · 109 [m2/s]
313 16.0 10.4 ± 0.1
313 25.0 9.22 ± 0.06
Reference

Diffusion of styrene (1); carbon dioxide (2) 1
Diffusion of styrene (1); carbon dioxide (2)

C8H8 (1) styrene 100-42-5

T [K] p [bar] D · 109 [m2/s]
313.15 150 7.7
313.15 200 7.4
313.15 250 6.7
323.15 150 10.6
Reference

Diffusion of 1,4-dimethyl-benzene (1); trifluoro-chloro-methane (2) 1
Diffusion of 1,4-dimethyl-benzene (1); trifluoro-chloro-

methane (2)

T [K] p [bar] D · 108 [m2/s]
318.15 47.3 2.42
318.15 49.1 2.15
318.15 52.2 1.62
318.15 53.8 1.64
318.15 57.9 1.40
318.15 64.7 1.26
318.15 78.7 1.13
318.15 109.1 1.05
Reference
2213–2218.



T [K] p [bar] D · 109 [m2/s]
313.15 160.0 12.1
313.15 160.0 11.5

T [K] p [MPa] D · 109 [m2/s]
313.2 16.0 11.5 ± 3%
References



T [K] p [bar] D · 109 [m2/s]
313.15 160.0 11.9
313.15 160.0 12.0

T [K] p [MPa] D · 109 [m2/s]
313.2 16.0 12.0 ± 3%
References



T [K] p [bar] D · 109 [m2/s]
313.15 150.0 12.2
313.15 160.0 11.0
313.15 160.0 12.1
313.15 200.0 11.2
313.15 250.0 9.9
323.15 150.0 14.9

T [K] p [MPa] D · 109 [m2/s]
313.2 16.0 11.0 ± 3%
References

Diffusion of ethylbenzene (1); carbon dioxide (2) 1
Diffusion of ethylbenzene (1); carbon dioxide (2)


T [K] p [bar] D · 109 [m2/s]
313.15 150 12.15 ± 4%
313.15 200 11.02 ± 4%
313.15 250 9.59 ± 4%
313.15 300 9.04 ± 4%
313.15 350 8.79 ± 4%
323.15 150 14.68 ± 4%
323.15 200 12.56 ± 4%
323.15 250 11.26 ± 4%
323.15 300 10.40 ± 4%
323.15 350 9.79 ± 4%
333.15 150 17.15 ± 4%
333.15 200 14.53 ± 4%
333.15 250 12.56 ± 4%
333.15 300 11.59 ± 4%
333.15 350 10.83 ± 4%

T [K] p [bar] D · 109 [m2/s]
313.15 150 12.15
313.15 200 11.02
313.15 250 9.59
313.15 300 9.04
313.15 350 8.79
323.15 150 14.68
323.15 200 12.56
323.15 250 11.26
323.15 300 10.40
323.15 350 9.79
333.15 150 17.15
333.15 200 14.53
333.15 250 12.56
333.15 300 11.59
333.15 350 10.83
Comment: ethylbenzene in supercritical CO2; reproducibility: ±1%

2 Diffusion of ethylbenzene (1); carbon dioxide (2)

T [K] p [bar] D · 109 [m2/s]
313.15 150 12.15
313.15 200 11.02
313.15 250 9.59
313.15 300 9.04
313.15 350 8.79
323.15 150 14.68
323.15 200 12.56
323.15 250 11.26
323.15 300 10.40
323.15 350 9.79
333.15 150 17.15
333.15 200 14.53
333.15 250 12.56
333.15 300 11.59
333.15 350 10.83

T [K] p [MPa] D · 109 [m2/s]
313.2 16.0 11.6 ± 3%

T [K] p [bar] D · 109 [m2/s]
313.15 160.0 11.6
References

Diffusion of 1,4-dimethyl-benzene (1); sulfur hexafluoride (2) 1
Diffusion of 1,4-dimethyl-benzene (1); sulfur hexafluoride

(2)

T [K] p [bar] D · 108 [m2/s]
283.15 30.0 0.61
283.15 40.0 0.58
283.15 60.0 0.56
283.15 90.0 0.52
283.15 120.0 0.48
283.15 150.0 0.45
293.15 30.0 0.78
293.15 40.0 0.73
293.15 60.0 0.67
293.15 90.0 0.58
293.15 120.0 0.54
293.15 150.0 0.51
303.15 35.0 0.93
303.15 40.0 0.89
303.15 60.0 0.79
303.15 90.0 0.69
303.15 120.0 0.61
313.15 40.0 1.14
313.15 50.0 1.00
313.15 60.0 0.93
313.15 90.0 0.82
313.15 120.0 0.73
323.15 40.7 2.12
323.15 42.0 1.73
323.15 44.5 1.44
323.15 45.0 1.41
323.15 49.5 1.26
323.15 50.0 1.26
323.15 60.0 1.11
323.15 61.0 1.11
323.15 84.4 0.97
323.15 90.0 0.93
323.15 120.0 0.86
328.15 35.0 4.23
328.15 42.0 3.06
328.15 44.0 2.74
328.15 45.5 1.96
328.15 46.7 1.82
(continued)

2 Diffusion of 1,4-dimethyl-benzene (1); sulfur hexafluoride (2)
328.15 48.3 1.62

328.15 51.2 1.49
328.15 58.2 1.32
328.15 72.2 1.14
328.15 98.3 0.99
328.15 143.5 0.85
338.15 50.4 2.66
338.15 53.2 2.28
338.15 55.8 1.99
338.15 59.5 1.80
338.15 65.5 1.54
338.15 76.3 1.33
338.15 94.7 1.17
338.15 125.8 1.01
Reference
2213–2218.

Diffusion of 1,3,7-trimethyl-2,6-dioxopurine (1); carbon dioxide (2) 1
Diffusion of 1,3,7-trimethyl-2,6-dioxopurine (1); carbon

dioxide (2)
C8H10N4O2 (1) 1,3,7-trimethyl-2,6-dioxopurine 58-08-2

T [K] p [bar] D · 108 [m2/s]
308 ± 0.2 80.3 1.24 ± 5%
308 ± 0.2 82.3 1.17 ± 5%
308 ± 0.2 85.7 1.08 ± 5%
308 ± 0.2 88.8 1.03 ± 5%
308 ± 0.2 102.7 0.97 ± 5%
308 ± 0.2 115.9 0.91 ± 5%
308 ± 0.2 129.6 0.89 ± 5%
308 ± 0.2 142.9 0.87 ± 5%
313 ± 0.2 88.6 1.34 ± 5%
313 ± 0.2 102.0 1.11 ± 5%
313 ± 0.2 115.6 1.02 ± 5%
313 ± 0.2 129.5 0.96 ± 5%
313 ± 0.2 143.4 0.91 ± 5%
318 ± 0.2 95.6 1.58 ± 5%
318 ± 0.2 103.0 1.34 ± 5%
318 ± 0.2 116.5 1.14 ± 5%
318 ± 0.2 129.7 1.06 ± 5%
318 ± 0.2 142.9 1.00 ± 5%
328 ± 0.2 115.6 1.65 ± 5%
328 ± 0.2 129.6 1.39 ± 5%
328 ± 0.2 142.7 1.20 ± 5%
Comment: caffeine in supercritical CO2

Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: STEFAN Ref.: 1987K2
T [K] p [bar] D · 108 [m2/s]
333.15 ± 0.1 168.6 1.229
333.15 ± 0.1 138.0 1.992
323.15 ± 0.1 136.9 1.506
333.15 ± 0.1 168.6 1.215
333.15 ± 0.1 168.6 1.247

2 Diffusion of 1,3,7-trimethyl-2,6-dioxopurine (1); carbon dioxide (2)

T [K] p [bar] D · 109 [m2/s]
313.25 ± 0.2 160.3 8.7 ± 2.9%
References
1987K2 Knaff, G., Schlünder, E.U.: Chem. Eng. Process. 21 (1987) 101–105.

Diffusion of 2,4-dimethyl-phenol (1); carbon dioxide (2) 1
Diffusion of 2,4-dimethyl-phenol (1); carbon dioxide (2)

C8H10O (1) 2,4-dimethyl-phenol 105-67-9

T [K] p [MPa] D · 109 [m2/s]
313 15 9.64 ± 2%
313 20 8.89 ± 2%
313 25 8.32 ± 2%
313 30 7.81 ± 2%
313 35 7.50 ± 2%
323 15 11.36 ± 2%
323 20 10.16 ± 2%
323 25 9.28 ± 2%
323 30 8.61 ± 2%
323 35 8.34 ± 2%
333 15 12.95 ± 2%
333 20 11.85 ± 2%
333 25 10.84 ± 2%
333 30 10.00 ± 2%
333 35 9.56 ± 2%
Reference

Diffusion of oct-1-ene (1); carbon dioxide (2) 1
Diffusion of oct-1-ene (1); carbon dioxide (2)

C8H16 (1) oct-1-ene 111-66-0

T [K] p [MPa] D · 109 [m2/s]
313.2 16.0 9.40 ± 3%
Reference

Diffusion of oct-1-ene (1); ethane (2) 1
Diffusion of oct-1-ene (1); ethane (2)

C8H16 (1) oct-1-ene 111-66-0

C2H6 (2) ethane 74-84-0
T [K] p [bar] D · 108 [m2/s]
523 144.7896 4.37 ± 0.139
533 144.7896 5.45 ± 0.0779
523 124.1054 4.49 ± 0.524
533 124.1054 5.27 ± 0.0676
523 103.4212 4.99 ± 0.606
533 103.4212 5.71 ± 0.668
543 103.4212 6.29 ± 0.734
523 82.7369 6.10 ± 0.99
533 82.7369 5.90 ± 0.66
543 82.7369 6.00 ± 0.45
523 62.0527 7.03 ± 0.246
533 62.0527 6.91 ± 0.240
543 62.0527 6.70 ± 0.278
Reference
1995E1 Eaton, A., Bukur, D.B., Akgerman, A.: J. Chem. Eng. Data 40 (1995) 1293–1297.

Diffusion of octane (1); carbon dioxide (2) 1
Diffusion of octane (1); carbon dioxide (2)

C8H18 (1) octane 111-65-9

Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: ABSORB Ref.: 1996W3
T [K] p [MPa] D · 109 [m2/s]
290.0 1.265 4.580
290.0 1.843 2.789
290.0 2.358 3.419
290.0 3.061 3.989
290.0 3.673 5.313
311.0 0.747 4.956
311.0 1.667 6.918
311.0 1.769 8.105
311.0 2.048 3.981
311.0 3.103 4.606
C8H18 (1) octane 111-65-9

T [K] p [MPa] D · 109 [m2/s]
299.15 ± 0.1 9.0 13.2 ± 3%
299.15 ± 0.1 10.5 12.4 ± 3%
303.15 ± 0.1 10.5 13.5 ± 3%
305.65 ± 0.1 10.5 15.2 ± 3%
308.15 ± 0.1 10.5 17.1 ± 3%
References
1996W3 Wang, L.S., Lang, Z.X., Guo, T.M.: Fluid Phase Equilib. 117 (1996) 364–372.

Diffusion of octane (1); sulfur hexafluoride (2) 1
Diffusion of octane (1); sulfur hexafluoride (2)

C8H18 (1) octane 111-65-9

T [K] p [MPa] D · 109 [m2/s]
303.15 4.5 10.4 ± 3%
313.15 4.5 12.0 ± 3%
323.15 4.5 16.0 ± 3%
303.15 5.0 10.2 ± 3%
313.15 5.0 11.7 ± 3%
323.15 5.0 14.2 ± 3%
328.15 5.0 17.0 ± 3%
333.15 5.0 21.1 ± 3%
303.15 6.0 10.0 ± 3%
313.15 6.0 11.1 ± 3%
323.15 6.0 12.7 ± 3%
333.15 6.0 16.0 ± 3%
303.15 9.0 9.55 ± 3%
313.15 9.0 10.3 ± 3%
323.15 9.0 11.2 ± 3%
333.15 9.0 12.5 ± 3%
Reference

Diffusion of octan-1-ol (1); carbon dioxide (2) 1
Diffusion of octan-1-ol (1); carbon dioxide (2)

C8H18O (1) octan-1-ol 111-87-5

T [K] p [MPa] D · 108 [m2/s]
313.8 8.21 1.58
313.3 10.15 1.15
313.5 12.09 1.08
313.1 14.06 0.98
323.3 8.29 1.71
323.3 10.30 1.20
322.8 12.10 1.15
324.1 14.08 0.99
333.2 8.15 1.81
333.2 10.17 1.46
333.2 12.11 1.30
333.2 14.07 1.19
343.2 8.16 1.86
343.2 10.29 1.64
343.2 12.11 1.55
343.2 14.01 1.35
Reference

Diffusion of 1-methylethyl-benzene (1); carbon dioxide (2) 1
Diffusion of 1-methylethyl-benzene (1); carbon dioxide (2)


T [K] p [bar] D · 109 [m2/s]
313.15 150 11.61 ± 4%
313.15 200 10.30 ± 4%
313.15 250 9.53 ± 4%
313.15 300 8.68 ± 4%
313.15 350 8.14 ± 4%
323.15 150 13.43 ± 4%
323.15 200 11.79 ± 4%
323.15 250 10.39 ± 4%
323.15 300 9.93 ± 4%
323.15 350 9.45 ± 4%
333.15 150 15.95 ± 4%
333.15 200 13.46 ± 4%
333.15 250 11.78 ± 4%
333.15 300 10.67 ± 4%
333.15 350 9.92 ± 4%

T [K] p [bar] D · 109 [m2/s]
313.15 150 11.61
313.15 200 10.30
313.15 250 9.53
313.15 300 8.68
313.15 350 8.14
323.15 150 13.43
323.15 200 11.79
323.15 250 10.39
323.15 300 9.93
323.15 350 9.45
333.15 150 15.95
333.15 200 13.46
333.15 250 11.78
333.15 300 10.67
333.15 350 9.92
Comment: t1-methylethyl-benzene in supercritical CO2; reproducibility: ±1%

2 Diffusion of 1-methylethyl-benzene (1); carbon dioxide (2)

T [K] p [bar] D · 109 [m2/s]
313.15 150 11.51
313.15 200 10.10
313.15 250 9.51
313.15 300 8.86
313.15 350 8.14
323.15 150 13.43
323.15 200 11.79
323.15 250 10.39
323.15 300 9.93
323.15 350 9.45
333.15 150 15.95
333.15 200 13.46
333.15 250 11.78
333.15 300 10.67
333.15 350 9.92

T [K] p [MPa] D · 109 [m2/s]
313.2 16.0 10.5 ± 3%

T [K] p [bar] D · 109 [m2/s]
313.15 160.0 10.5
References

Diffusion of propylbenzene (1); carbon dioxide (2) 1
Diffusion of propylbenzene (1); carbon dioxide (2)


T [K] p [bar] D · 109 [m2/s]
313.15 150 11.61
313.15 200 10.55
313.15 250 9.53
313.15 300 9.01
313.15 350 8.66
323.15 150 13.53
323.15 200 11.90
323.15 250 10.60
323.15 300 10.09
323.15 350 9.60
333.15 150 15.04
333.15 200 13.41
333.15 250 11.88
333.15 300 10.80
333.15 350 9.99

T [K] p [bar] D · 108 [m2/s]
308.15 110 1.17 ± 3%
313.15 110 1.26 ± 3%
318.15 110 1.49 ± 3%
323.15 110 1.68 ± 3%
328.15 110 1.99 ± 3%
308.15 130 1.07 ± 3%
313.15 130 1.14 ± 3%
318.15 130 1.26 ± 3%
323.15 130 1.44 ± 3%
328.15 130 1.48 ± 3%

T [K] p [bar] D · 108 [m2/s]
313.15 85 1.99 ± 4%
313.15 87.5 1.67 ± 4%
313.15 88 1.83 ± 4%
(continued)

2 Diffusion of propylbenzene (1); carbon dioxide (2)
313.15 90 1.61 ± 4%
313.15 92 1.51 ± 3%
313.15 95 1.50 ± 3%
313.15 95 1.54 ± 3%
313.15 100 1.39 ± 3%
313.15 110 1.26 ± 3%
313.15 130 1.14 ± 3%
313.15 160 1.05 ± 3%

T [K] p [bar] D · 109 [m2/s]
313.15 150 11.61 ± 4%
313.15 200 10.55 ± 4%
313.15 250 9.53 ± 4%
313.15 300 9.01 ± 4%
313.15 350 8.66 ± 4%
323.15 150 13.53 ± 4%
323.15 200 11.90 ± 4%
323.15 250 10.60 ± 4%
323.15 300 10.09 ± 4%
323.15 350 9.69 ± 4%
333.15 150 15.94 ± 4%
333.15 200 13.41 ± 4%
333.15 250 11.88 ± 4%
333.15 300 10.80 ± 4%
333.15 350 9.99 ± 4%

T [K] p [bar] D · 109 [m2/s]
313.15 150 11.61
313.15 200 10.55
313.15 250 9.53
313.15 300 9.01
313.15 350 8.66
323.15 150 13.53
323.15 200 11.90
323.15 250 10.60
323.15 300 10.09
323.15 350 9.69
333.15 150 15.94
333.15 200 13.41
333.15 250 11.88
(continued)

Diffusion of propylbenzene (1); carbon dioxide (2) 3
333.15 300 10.80

333.15 350 9.99
Comment: propylbenzne in supercritical CO2; reproducibility: ±1%

T [K] p [MPa] D · 109 [m2/s]
313.2 16.0 10.9 ± 3%

T [K] p [bar] D · 109 [m2/s]
313.15 160.0 10.9
References

Diffusion of 1,3,5-trimethyl-benzene (1); carbon dioxide (2) 1
Diffusion of 1,3,5-trimethyl-benzene (1); carbon dioxide (2)


T [K] p [bar] D · 108 [m2/s]
308.15 110 1.08 ± 3%
313.15 110 1.20 ± 3%
318.15 110 1.35 ± 3%
323.15 110 1.64 ± 3%
328.15 110 1.87 ± 3%
308.15 130 1.01 ± 3%
313.15 130 1.10 ± 3%
318.15 130 1.21 ± 3%
323.15 130 1.29 ± 3%
328.15 130 1.42 ± 3%

T [K] p [bar] D · 108 [m2/s]
313.15 85 1.79 ± 4%
313.15 87.5 1.60 ± 4%
313.15 90 1.44 ± 4%
313.15 92 1.40 ± 3%
313.15 95 1.39 ± 3%
313.15 95 1.38 ± 3%
313.15 100 1.26 ± 3%
313.15 110 1.20 ± 3%
313.15 130 1.10 ± 3%
313.15 160 1.00 ± 3%

T [K] p [bar] D · 109 [m2/s]
303.15 ± 0.2 115 10.6 ± 0.2
303.15 ± 0.2 190 8.7 ± 0.2
313.15 ± 0.2 160 10.5 ± 0.6
313.15 ± 0.2 250 9.1 ± 0.1
333.15 ± 0.2 130 20.9 ± 1.0
333.15 ± 0.2 165 16.3 ± 0.8
333.15 ± 0.2 265 11.6 ± 0.4

2 Diffusion of 1,3,5-trimethyl-benzene (1); carbon dioxide (2)

T [K] p [bar] D · 109 [m2/s]
313.15 150.0 10.9
313.15 160.0 10.1
313.15 160.0 11.0
313.15 200.0 9.8
313.15 250.0 9.1
323.15 150.0 12.6
323.15 200.0 11.1
323.15 250.0 9.3
323.15 300.0 8.6

T [K] p [MPa] D · 109 [m2/s]
313.2 16.0 10.1 ± 3%
References

Diffusion of 1,3,5-trimethyl-benzene (1); sulfur hexafluoride (2) 1
Diffusion of 1,3,5-trimethyl-benzene (1); sulfur

hexafluoride (2)

T [K] p [bar] D · 108 [m2/s]
328 35.0 3.07
328 42.0 2.71
328 44.0 2.14
328 45.5 1.72
328 46.7 1.63
328 48.3 1.42
328 51.2 1.35
328 58.2 1.14
328 72.2 1.04
328 98.3 0.88
328 143.5 0.74
Reference
2213–2218.

Diffusion of cyclononanone (1); carbon dioxide (2) 1
Diffusion of cyclononanone (1); carbon dioxide (2)

C9H16O (1) cyclononanone 3350-30-9

T [K] p [bar] D · 109 [m2/s]
314.0 100 14.58
314.0 105 13.74
314.0 110 12.18
314.0 115 11.59
314.0 125 11.25
314.0 135 10.91
314.0 150 9.393
314.0 180 9.025
References

Diffusion of nonan-2-one (1); carbon dioxide (2) 1
Diffusion of nonan-2-one (1); carbon dioxide (2)

C9H18O (1) nonan-2-one 821-55-6

T [K] p [MPa] D · 108 [m2/s]
314.5 18 1.31 ± 6%
314.5 17 1.29 ± 6%
314.5 16 1.19 ± 6%
314.5 15 1.42 ± 6%
314.5 14 1.44 ± 6%
314.5 13 1.48 ± 6%
314.5 12.5 1.64 ± 6%
314.5 12 1.76 ± 6%
314.5 11.5 1.74 ± 6%
314.5 11 1.92 ± 6%
314.5 10.5 2.00 ± 6%
314.5 10.2 2.15 ± 6%
314.5 10 2.16 ± 6%
Reference

Diffusion of nonan-5-one (1); carbon dioxide (2) 1
Diffusion of nonan-5-one (1); carbon dioxide (2)

C9H18O (1) nonan-5-one 502-56-7

T [K] p [MPa] D · 108 [m2/s]
314.5 18 1.20 ± 6%
314.5 17 1.35 ± 6%
314.5 16 1.29 ± 6%
314.5 15 1.35 ± 6%
314.5 14 1.44 ± 6%
314.5 13 1.51 ± 6%
314.5 12.5 1.63 ± 6%
314.5 12 1.59 ± 6%
314.5 11.5 1.77 ± 6%
314.5 11 1.86 ± 6%
314.5 10.5 1.99 ± 6%
314.5 10.2 2.19 ± 6%
314.5 10 2.23 ± 6%
C9H18O (1) nonan-5-one 502-56-7

T [K] p [bar] D · 109 [m2/s]
314.0 100 15.49
314.0 105 14.30
314.0 110 12.55
314.0 115 11.94
314.0 125 11.47
314.0 135 10.38
314.0 150 9.875
314.0 180 8.846
Comment: supercritical fluid chromatography; experimental error: ±6%
References

Diffusion of 2,2,4,4-tetramethyl-pentan-3-one (1); carbon dioxide (2) 1
Diffusion of 2,2,4,4-tetramethyl-pentan-3-one (1); carbon

dioxide (2)
C9H18O (1) 2,2,4,4-tetramethyl-pentan-3-one 815-24-7

T [K] p [MPa] D · 108 [m2/s]
313.5 16 1.43 ± 6%
313.5 15 1.44 ± 6%
313.5 14 1.54 ± 6%
313.5 13.5 1.58 ± 6%
313.5 13 1.63 ± 6%
313.5 12.5 1.67 ± 6%
313.5 12 1.78 ± 6%
313.5 11 1.91 ± 6%
313.5 10 2.22 ± 6%
Reference

Diffusion of nonane (1); carbon dioxide (2) 1
Diffusion of nonane (1); carbon dioxide (2)

C9H20 (1) nonane 111-84-2

T [K] p [MPa] D · 109 [m2/s]
299.15 ± 0.1 9.0 12.9 ± 3%
299.15 ± 0.1 10.5 12.1 ± 3%
303.15 ± 0.1 10.5 13.3 ± 3%
305.65 ± 0.1 10.5 14.9 ± 3%
308.15 ± 0.1 10.5 16.7 ± 3%
Reference

Diffusion of nonan-1-ol (1); carbon dioxide (2) 1
Diffusion of nonan-1-ol (1); carbon dioxide (2)

C9H20O (1) nonan-1-ol 143-08-8

T [K] p [MPa] D · 108 [m2/s]
313.8 8.30 1.33
313.3 10.14 1.03
313.4 12.15 0.96
313.2 14.11 0.88
323.5 8.43 1.50
323.2 10.38 1.12
322.9 12.18 0.99
324.1 14.03 0.94
333.2 8.15 1.70
333.2 10.21 1.30
333.2 12.11 1.12
333.2 14.07 1.05
343.2 8.17 1.72
343.2 10.27 1.46
343.2 12.07 1.39
343.2 14.16 1.14
Reference



Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: STEFAN Ref.: 2003O1
T [K] p [atm] D · 108 [m2/s]
308.15 ± 0.02 80 2.505
308.15 ± 0.02 80 2.281
308.15 ± 0.02 100 1.552
308.15 ± 0.02 100 1.484
308.15 ± 0.02 120 1.067
308.15 ± 0.02 120 1.065
323.15 ± 0.02 80 5.562
323.15 ± 0.02 80 5.631
323.15 ± 0.02 100 3.074
323.15 ± 0.02 100 3.075
323.15 ± 0.02 120 2.025
323.15 ± 0.02 120 1.954
338.15 ± 0.02 80 6.786
338.15 ± 0.02 80 6.747
338.15 ± 0.02 100 4.487
338.15 ± 0.02 100 4.487
338.15 ± 0.02 120 1.943
338.15 ± 0.02 120 1.945

Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: NMR FG Ref.: 1989L1
T [K] p [bar] D · 109 [m2/s]
308.15 ± 0.2 100 13.3 ± 5%
308.15 ± 0.2 150 11.4 ± 5%
308.15 ± 0.2 200 9.68 ± 5%
308.15 ± 0.2 250 9.19 ± 5%
308.15 ± 0.2 300 8.13 ± 5%
308.15 ± 0.2 400 7.38 ± 5%
308.15 ± 0.2 500 7.05 ± 5%
308.15 ± 0.2 750 6.15 ± 5%
308.15 ± 0.2 1000 5.48 ± 5%
328.15 ± 0.2 120 17.4 ± 5%
328.15 ± 0.2 135 15.8 ± 5%
328.15 ± 0.2 160 13.1 ± 5%
328.15 ± 0.2 200 11.0 ± 5%
328.15 ± 0.2 250 9.87 ± 5%
328.15 ± 0.2 300 8.89 ± 5%
328.15 ± 0.2 400 8.07 ± 5%
(continued)
328.15 ± 0.2 500 7.47 ± 5%

328.15 ± 0.2 600 7.14 ± 5%
328.15 ± 0.2 1000 5.98 ± 5%
351.15 ± 0.2 20 1.59 ± 5%
351.15 ± 0.2 40 1.85 ± 5%
351.15 ± 0.2 80 2.11 ± 5%
351.15 ± 0.2 120 2.47 ± 5%
351.15 ± 0.2 160 2.59 ± 5%
351.15 ± 0.2 200 2.65 ± 5%

T [K] p [MPa] D · 109 [m2/s]
313 16.0 11.2 ± 0.5
313 25.0 9.43 ± 0.05

Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: STEFAN Ref.: 1998H7
T [K] p [MPa] D · 108 [m2/s]
308.2 ± 0.2 7.21 3.83 ± 5%
308.2 ± 0.2 7.50 3.32 ± 5%
308.2 ± 0.2 7.70 3.23 ± 5%
308.2 ± 0.2 7.86 2.91 ± 5%
308.2 ± 0.2 7.92 2.40 ± 5%
308.2 ± 0.2 7.99 2.04 ± 5%
308.2 ± 0.2 8.02 1.86 ± 5%
308.2 ± 0.2 8.03 1.59 ± 5%
308.2 ± 0.2 8.12 1.28 ± 5%
308.2 ± 0.2 8.14 1.22 ± 5%
308.2 ± 0.2 8.18 1.31 ± 5%
308.2 ± 0.2 8.21 1.42 ± 5%
308.2 ± 0.2 8.70 1.53 ± 5%
308.2 ± 0.2 11.8 1.13 ± 5%
308.2 ± 0.2 15.2 1.06 ± 5%
Comment: insufficient accuracy of data, remeasured in [1999H4]

T [K] p [bar] D · 109 [m2/s]
288.35 ± 0.2 172.0 8.43 ± 2.9%
298.35 ± 0.2 170.6 9.68 ± 2.9%
313.25 ± 0.2 160.3 11.2 ± 2.9%
313.65 ± 0.2 171.3 11.6 ± 2.9%
(continued)
328.05 ± 0.2 170.6 13.4 ± 2.9%

293.25 ± 0.2 67.2 10.9 ± 2.9%
298.15 ± 0.2 90.7 11.0 ± 2.9%
313.55 ± 0.2 163.8 11.4 ± 2.9%
328.05 ± 0.2 238.9 12.0 ± 2.9%
288.25 ± 0.2 111.4 9.16 ± 2.9%
298.25 ± 0.2 179.6 9.46 ± 2.9%
313.55 ± 0.2 351.3 9.80 ± 2.9%
323.05 ± 0.2 351.3 10.4 ± 2.9%
313.85 ± 0.2 116.2 12.8 ± 2.9%
320.15 ± 0.2 142.0 13.2 ± 2.9%

T [K] p [MPa] D · 108 [m2/s]
308.2 ± 0.2 7.70 2.99 ± 4%
308.2 ± 0.2 7.92 2.75 ± 4%
308.2 ± 0.2 7.94 2.50 ± 4%
308.2 ± 0.2 7.97 2.29 ± 4%
308.2 ± 0.2 7.99 1.96 ± 4%
308.2 ± 0.2 8.02 1.75 ± 4%
308.2 ± 0.2 8.03 1.56 ± 4%
308.2 ± 0.2 8.07 1.45 ± 4%
308.2 ± 0.2 8.10 1.37 ± 4%
308.2 ± 0.2 8.12 1.27 ± 4%
308.2 ± 0.2 8.13 1.12 ± 4%
308.2 ± 0.2 8.14 1.22 ± 4%
308.2 ± 0.2 8.15 1.25 ± 4%
308.2 ± 0.2 8.18 1.30 ± 4%
308.2 ± 0.2 8.23 1.28 ± 4%
308.2 ± 0.2 8.54 1.25 ± 4%
308.2 ± 0.2 8.80 1.23 ± 4%
308.2 ± 0.2 10.4 1.11 ± 4%
308.2 ± 0.2 11.8 1.09 ± 4%
308.2 ± 0.2 13.3 1.01 ± 4%
308.2 ± 0.2 15.2 0.93 ± 4%
308.2 ± 0.2 20.0 0.85 ± 4%
318.2 ± 0.2 8.75 2.80 ± 4%
318.2 ± 0.2 9.23 2.61 ± 4%
318.2 ± 0.2 9.35 2.28 ± 4%
318.2 ± 0.2 9.60 1.86 ± 4%
318.2 ± 0.2 9.79 1.77 ± 4%
318.2 ± 0.2 9.92 1.61 ± 4%
318.2 ± 0.2 10.3 1.50 ± 4%
318.2 ± 0.2 10.6 1.38 ± 4%
318.2 ± 0.2 11.1 1.26 ± 4%
(continued)

318.2 ± 0.2 11.8 1.25 ± 4%

318.2 ± 0.2 13.7 1.12 ± 4%
318.2 ± 0.2 15.3 1.10 ± 4%
318.2 ± 0.2 19.9 0.95 ± 4%

Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: STEFAN Ref.: 1987K2
T [K] p [bar] D · 108 [m2/s]
308.15 ± 0.1 118 1.136
308.15 ± 0.1 167 0.939
308.15 ± 0.1 226 0.841
318.15 ± 0.1 118 1.356
318.15 ± 0.1 167 1.077
318.15 ± 0.1 226 0.895
328.15 ± 0.1 118 1.590
328.15 ± 0.1 167 1.097
328.15 ± 0.1 226 0.878
328.15 ± 0.1 226 0.859
328.15 ± 0.1 226 0.864

T [K] p [bar] D · 109 [m2/s]
303.15 ± 0.2 115 11.3 ± 0.2
303.15 ± 0.2 190 9.3 ± 0.2
313.15 ± 0.2 110 15.6 ± 0.3
313.15 ± 0.2 130 12.7 ± 0.3
313.15 ± 0.2 155 11.7 ± 0.2
313.15 ± 0.2 160 11.6 ± 0.5
313.15 ± 0.2 215 10.2 ± 0.3
313.15 ± 0.2 250 9.6 ± 0.1
333.15 ± 0.2 130 21.9 ± 0.9
333.15 ± 0.2 165 18.3 ± 0.4
333.15 ± 0.2 265 12.3 ± 0.6

Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: OEC Ref.: 1994C7
T [K] p [bar] D · 109 [m2/s]
318.1 160 11.3 ± 1.1


T [K] p [MPa] D · 108 [m2/s]
313.2 ± 0.1 16.2 1.16

T [K] p [atm] D · 109 [m2/s]
313.15 160 10.9 ± 0.012
References
2003O1 Ozguler, E.I., Sunol, S.G., Sunol, A.K.: Ind. Eng. Chem. Res. 42 (2003) 4389–4397.
1989L1 Lamb, D.M., Adamy, S.T., Woo, K.W., Jonas, J.: J. Phys. Chem. 93 (1989) 5002–5005.
1998H7 Higashi, H., Iwai, Y., Takahashi, Y., Uchida, H., Arai, Y.: Fluid Phase Equilib. 144 (1998)
269–278.
1999H4 Higashi, H., Iwai, Y., Nakamura, Y., Yamamoto, S., Arai, Y.: Fluid Phase Equilib. 166 (1999)
101–110.
1987K2 Knaff, G., Schlünder, E.U.: Chem. Eng. Process. 21 (1987) 101–105.

Diffusion of naphthalene (1); 2,3-dimethyl-butane (2) 1
Diffusion of naphthalene (1); 2,3-dimethyl-butane (2)


T [K] p [MPa] D · 109 [m2/s]
523.2 ± 0.2 15.32 19.9 ± 2%
523.2 ± 0.2 10.23 23.0 ± 2%
523.2 ± 0.2 6.897 26.5 ± 2%
523.2 ± 0.2 5.352 31.0 ± 2%
535.2 ± 0.2 15.90 21.6 ± 2%
535.2 ± 0.2 8.145 27.8 ± 2%
548.2 ± 0.2 14.37 24.0 ± 2%
548.2 ± 0.2 9.938 28.1 ± 2%
548.2 ± 0.2 7.614 32.1 ± 2%
Reference

Diffusion of naphthalene (1); sulfur hexafluoride (2) 1
Diffusion of naphthalene (1); sulfur hexafluoride (2)


T [K] p [bar] D · 109 [m2/s]
318.2 65 8.85
318.2 80 8.33
318.2 120 6.80
328.2 65 13.80
328.2 80 11.70
Reference

1
Diffusion of bis(1,1,1-trifluoro-pentan-2,4-dionato-O,O')
copper (1); carbon dioxide (2)
C10H8CuF6O4 (1) bis(1,1,1-trifluoro-pentan-2,4-dionato-O,O') copper 14324-82-4

T [K] p [bar] D · 109 [m2/s]
308.15 108.2 8.77 ± 0.36
308.15 119.3 7.49 ± 0.53
308.15 130.3 6.81 ± 0.19
308.15 157.2 6.07 ± 0.42
313.15 108.9 9.30 ± 0.11
313.15 119.3 9.16 ± 0.17
313.15 154.4 7.76 ± 0.15
318.15 109.6 11.1 ± 0.3
318.15 122.0 9.95 ± 0.26
318.15 128.2 9.34 ± 0.10
318.15 155.1 8.81 ± 0.28
318.15 165.5 8.44 ± 0.10
Reference

Diffusion of naphthalen-2-ol (1); carbon dioxide (2) 1
Diffusion of naphthalen-2-ol (1); carbon dioxide (2)

C10H8O (1) naphthalen-2-ol 135-19-3

T [K] p [bar] D · 109 [m2/s]
308.2 150 7.03
308.2 200 6.63
308.2 250 6.45
318.2 165 7.43
318.2 250 7.00
Reference

Diffusion of naphthalene-d8 (1); ethene (2) 1
Diffusion of naphthalene-d8 (1); ethene (2)

C10D8 (1) naphthalene-d8 1146-65-2

C2H4 (2) ethene 74-85-1
Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: NMR FG Ref.: 1989L1
T [K] p [bar] D · 109 [m2/s]
318.15 ± 0.2 300 12.0 ± 5%
318.15 ± 0.2 400 10.4 ± 5%
318.15 ± 0.2 600 9.08 ± 5%
318.15 ± 0.2 800 8.68 ± 5%
318.15 ± 0.2 1000 8.42 ± 5%
351.15 ± 0.2 20 2.20 ± 5%
351.15 ± 0.2 40 2.61 ± 5%
351.15 ± 0.2 80 3.44 ± 5%
351.15 ± 0.2 120 4.38 ± 5%
351.15 ± 0.2 160 5.18 ± 5%
Reference
1989L1 Lamb, D.M., Adamy, S.T., Woo, K.W., Jonas, J.: J. Phys. Chem. 93 (1989) 5002–5005.

Diffusion of 1,1-dimethylethyl-benzene (1); carbon dioxide (2) 1
Diffusion of 1,1-dimethylethyl-benzene (1); carbon dioxide

(2)
C10H14 (1) 1,1-dimethylethyl-benzene 98-06-6

T [K] p [MPa] D · 109 [m2/s]
313.0 15 10.73
313.0 20 9.15
313.0 25 8.12
313.0 30 7.36
313.0 35 6.86
323.0 15 12.47
323.0 20 10.56
323.0 25 9.80
323.0 30 8.36
323.0 35 8.08
333.0 15 15.58
333.0 20 12.35
333.0 25 11.19
333.0 30 10.19
333.0 35 9.51
Reference

Diffusion of tricyclo[3.3.1.1(3.7)]-decanone (1); carbon dioxide (2) 1
Diffusion of tricyclo[3.3.1.1(3.7)]-decanone (1); carbon

dioxide (2)
C10H14O (1) tricyclo[3.3.1.1(3.7)]-decanone 700-58-3

T [K] p [MPa] D · 108 [m2/s]
313.5 15 1.44 ± 6%
313.5 14 1.50 ± 6%
313.5 13.5 1.59 ± 6%
313.5 13 1.59 ± 6%
313.5 12.5 1.64 ± 6%
313.5 12 1.68 ± 6%
313.5 11 1.77 ± 6%
Reference

Diffusion of 4-isopropenyl-1-methyl-cyclohexene (1); carbon dioxide (2) 1
Diffusion of 4-isopropenyl-1-methyl-cyclohexene (1);

carbon dioxide (2)
C10H16 (1) 4-isopropenyl-1-methyl-cyclohexene 138-86-3

T [K] p [bar] D · 109 [m2/s]
313.15 160.0 10.4

T [K] p [MPa] D · 109 [m2/s]
313 16.0 10.9 ± 0.33
313 25.0 8.66 ± 0.08

T [K] p [MPa] D · 109 [m2/s]
313.2 16.0 10.4 ± 3%
References

Diffusion of (R)-(+)-limonene (1); carbon dioxide (2) 1
Diffusion of (R)-(+)-limonene (1); carbon dioxide (2)

C10H16 (1) (R)-(+)-limonene 5989-27-5

T [K] p [MPa] D · 108 [m2/s]
313.15 12 1.141
323.15 12 1.436
333.15 12 2.110
313.15 14 1.050
323.15 14 1.280
333.15 14 1.706
313.15 16 1.016
323.15 16 1.191
333.15 16 1.529
313.15 18 0.972
323.15 18 1.146
333.15 18 1.422
313.15 20 0.946
323.15 20 1.047
333.15 20 1.266
Reference
2003F1 Filho, C.A., Silva, C.M., Quadri, M.B., Macedo, E.A.: Fluid Phase Equilib. 204 (2003) 65–73.

Diffusion of 2,6,6-trimethylbicyclo[3.1.1]hept-2-ene (1); carbon dioxide (2) 1
Diffusion of 2,6,6-trimethylbicyclo[3.1.1]hept-2-ene (1);

carbon dioxide (2)
C10H16 (1) 2,6,6-trimethylbicyclo[3.1.1]hept-2-ene 80-56-8

T [K] p [MPa] D · 108 [m2/s]
313.15 12 1.17 ± 0.03
323.15 12 1.63 ± 0.02
333.15 12 2.37 ± 0.13
313.15 14 0.980 ± 0.02
323.15 14 1.261 ± 0.013
333.15 14 1.677 ± 0.015
313.15 16 0.947 ± 0.007
323.15 16 1.205 ± 0.018
333.15 16 1.474 ± 0.013
313.15 18 0.930 ± 0.003
323.15 18 1.133 ± 0.003
333.15 18 1.386 ± 0.006
313.15 20 0.890 ± 0.006
323.15 20 1.080 ± 0.002
333.15 20 1.319 ± 0.008
Reference
2004S2 Silva, C.M., Filho, C.A., Quadri, M.B., Macedo, E.A.: J. Supercrit. Fluids 32 (2004) 167–175.

Diffusion of 6,6-dimethyl-2-methylene-bicyclo[3.1.1]heptane (1); carbon dioxide (2) 1
Diffusion of 6,6-dimethyl-2-methylene-bicyclo[3.1.1]
heptane (1); carbon dioxide (2)
C10H16 (1) 6,6-dimethyl-2-methylene-bicyclo[3.1.1]heptane 127-91-3

T [K] p [MPa] D · 108 [m2/s]
313.15 12 1.21 ± 0.03
323.15 12 1.56 ± 0.03
333.15 12 2.12 ± 0.09
313.15 14 1.15 ± 0.02
323.15 14 1.38 ± 0.05
333.15 14 1.79 ± 0.04
313.15 16 1.056 ± 0.006
323.15 16 1.27 ± 0.03
333.15 16 1.60 ± 0.03
313.15 18 0.9841 ± 0.0017
323.15 18 1.178 ± 0.017
333.15 18 1.466 ± 0.013
313.15 20 0.943 ± 0.006
323.15 20 1.127 ± 0.018
333.15 20 1.44 ± 0.05
Reference
2004S2 Silva, C.M., Filho, C.A., Quadri, M.B., Macedo, E.A.: J. Supercrit. Fluids 32 (2004) 167–175.

Diffusion of 3,7-dimethyl-octa-2,6-dienal (1); carbon dioxide (2) 1
Diffusion of 3,7-dimethyl-octa-2,6-dienal (1); carbon

dioxide (2)
C10H16O (1) 3,7-dimethyl-octa-2,6-dienal 5392-40-5

T [K] p [MPa] D · 108 [m2/s]
313.15 12 1.054
323.15 12 1.428
333.15 12 1.990
313.15 14 0.972
323.15 14 1.234
333.15 14 1.619
313.15 16 0.900
323.15 16 1.142
333.15 16 1.368
313.15 18 0.862
323.15 18 1.094
333.15 18 1.290
313.15 20 0.810
323.15 20 0.956
333.15 20 1.122
Reference
2003F1 Filho, C.A., Silva, C.M., Quadri, M.B., Macedo, E.A.: Fluid Phase Equilib. 204 (2003) 65–73.

Diffusion of (+-)-3,7-dimethyl-octa-1,6-dien-3-ol (1); carbon dioxide (2) 1
Diffusion of (+-)-3,7-dimethyl-octa-1,6-dien-3-ol (1);

carbon dioxide (2)
C10H18O (1) (+–)-3,7-dimethyl-octa-1,6-dien-3-ol 78-70-6

Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: GC Ref.: 2002F1
T [K] p [MPa] D · 108 [m2/s]
313.15 12 1.154
323.15 12 1.565
333.15 12 1.985
313.15 14 0.998
323.15 14 1.289
333.15 14 1.551
313.15 16 0.943
323.15 16 1.140
333.15 16 1.347
313.15 18 0.886
323.15 18 1.112
333.15 18 1.274
313.15 20 0.799
323.15 20 1.003
333.15 20 1.140
Reference
2002F1 Filho, C.A., Silva, C.M., Quadri, M.B., Macedo, E.A.: J. Chem. Eng. Data 47 (2002) 1351–1354.

Diffusion of decane (1); carbon dioxide (2) 1
Diffusion of decane (1); carbon dioxide (2)

C10H22 (1) decane 124-18-5

T [K] p [MPa] D · 109 [m2/s]
299.15 ± 0.1 9.0 12.5 ± 3%
299.15 ± 0.1 10.5 11.8 ± 3%
303.15 ± 0.1 10.5 13.0 ± 3%
305.65 ± 0.1 10.5 14.6 ± 3%
308.15 ± 0.1 10.5 16.1 ± 3%
Reference

Diffusion of decane (1); sulfur hexafluoride (2) 1
Diffusion of decane (1); sulfur hexafluoride (2)

C10H22 (1) decane 124-18-5

T [K] p [MPa] D · 109 [m2/s]
303.15 4.5 9.33 ± 3%
313.15 4.5 10.4 ± 3%
323.15 4.5 13.5 ± 3%
303.15 5.0 9.20 ± 3%
313.15 5.0 10.1 ± 3%
323.15 5.0 12.1 ± 3%
328.15 5.0 14.3 ± 3%
333.15 5.0 17.9 ± 3%
303.15 6.0 8.99 ± 3%
313.15 6.0 9.70 ± 3%
323.15 6.0 10.9 ± 3%
333.15 6.0 13.5 ± 3%
303.15 9.0 8.61 ± 3%
313.15 9.0 9.22 ± 3%
323.15 9.0 9.90 ± 3%
333.15 9.0 10.7 ± 3%
Reference

Diffusion of 2-methyl-1,4-naphthoquinone (1); carbon dioxide (2) 1
Diffusion of 2-methyl-1,4-naphthoquinone (1); carbon

dioxide (2)
C11H8O2 (1) 2-methyl-1,4-naphthoquinone 58-27-5

T [K] p [MPa] D · 108 [m2/s]
313.15 ± 0.01 8.96 1.707 ± 3.7%
313.15 ± 0.01 8.99 1.663 ± 3.7%
313.15 ± 0.01 9.00 1.705 ± 3.7%
313.15 ± 0.01 9.50 1.430 ± 3.7%
313.15 ± 0.01 10.00 1.325 ± 3.7%
313.15 ± 0.01 11.01 1.197 ± 3.7%
313.15 ± 0.01 12.00 1.132 ± 3.7%
313.15 ± 0.01 13.00 1.083 ± 3.7%
313.15 ± 0.01 14.00 1.051 ± 3.7%
313.15 ± 0.01 15.08 1.020 ± 3.7%
313.15 ± 0.01 17.00 0.971 ± 3.7%
313.15 ± 0.01 18.77 0.936 ± 3.7%
313.15 ± 0.01 21.00 0.897 ± 3.7%
313.15 ± 0.01 22.97 0.870 ± 3.7%
313.15 ± 0.01 25.05 0.851 ± 3.7%
313.15 ± 0.01 26.95 0.832 ± 3.7%
313.15 ± 0.01 30.02 0.810 ± 3.7%

T [K] p [MPa] D · 109 [m2/s]
313 16.0 9.28 ± 0.17
313 25.0 7.92 ± 0.08
References

Diffusion of cis-3-methyl-2-pent-2-enyl-cyclopent-2-enone (1); carbon dioxide (2) 1
Diffusion of cis-3-methyl-2-pent-2-enyl-cyclopent-
2-enone (1); carbon dioxide (2)
C11H16O (1) cis-3-methyl-2-pent-2-enyl-cyclopent-2-enone 488-10-8

T [K] p [MPa] D · 109 [m2/s]
313 16.0 8.78 ± 0.08
313 25.0 7.53 ± 0.08
Reference

Diffusion of undecan-6-one (1); carbon dioxide (2) 1
Diffusion of undecan-6-one (1); carbon dioxide (2)

C11H22O (1) undecan-6-one 927-49-1

T [K] p [MPa] D · 108 [m2/s]
314.5 18 1.12 ± 6%
314.5 17 1.19 ± 6%
314.5 16 1.20 ± 6%
314.5 15 1.27 ± 6%
314.5 14 1.35 ± 6%
314.5 13 1.38 ± 6%
314.5 12.5 1.45 ± 6%
314.5 12 1.48 ± 6%
314.5 11.5 1.56 ± 6%
314.5 11 1.68 ± 6%
314.5 10.5 1.96 ± 6%
314.5 10.2 2.06 ± 6%
314.5 10 1.97 ± 6%
Reference

Diffusion of undecane (1); carbon dioxide (2) 1
Diffusion of undecane (1); carbon dioxide (2)

C11H24 (1) undecane 1120-21-4

T [K] p [MPa] D · 109 [m2/s]
299.15 ± 0.1 9.0 12.2 ± 3%
299.15 ± 0.1 10.5 11.5 ± 3%
303.15 ± 0.1 10.5 12.7 ± 3%
305.65 ± 0.1 10.5 14.5 ± 3%
308.15 ± 0.1 10.5 16.1 ± 3%
Reference

Diffusion of biphenyl (1); carbon dioxide (2) 1
Diffusion of biphenyl (1); carbon dioxide (2)

C12H10 (1) biphenyl 92-52-4

T [K] p [bar] D · 109 [m2/s]
293.15 148.24 7.52 ± 0.10
293.15 126.86 7.81 ± 0.12
293.15 103.42 8.22 ± 0.08
293.15 92.39 8.56 ± 0.01
293.15 82.74 8.94 ± 0.06
293.15 71.02 9.64 ± 0.34
298.15 148.24 8.28 ± 0.29
298.15 126.86 8.60 ± 0.20
298.15 103.42 9.03 ± 0.32
298.15 92.39 9.40 ± 0.21
298.15 89.63 10.4 ± 0.4
298.15 82.74 11.5 ± 0.3
308.15 170.99 8.75 ± 0.23
308.15 148.24 9.19 ± 0.02
308.15 126.86 10.1 ± 0.1
308.15 103.42 11.0 ± 0.1
308.15 92.39 12.3 ± 0.1
308.15 88.25 13.1 ± 0.1
308.15 86.18 13.5 ± 0.2
308.15 82.74 13.8 ± 0.4
318.15 170.99 10.4 ± 0.1
318.15 148.24 11.6 ± 0.1
318.15 126.86 12.7 ± 0.1
318.15 103.42 16.6 ± 0.1
323.15 148.24 12.5 ± 0.6
323.15 126.86 14.3 ± 0.4
323.15 103.42 18.1 ± 1.0
Reference

Diffusion of 2,3-dimethyl-naphthalene (1); carbon dioxide (2) 1
Diffusion of 2,3-dimethyl-naphthalene (1); carbon dioxide

(2)
C12H12 (1) 2,3-dimethyl-naphthalene 581-40-8

T [K] p [MPa] D · 108 [m2/s]
308.2 ± 0.2 9.90 1.10 ± 4%
308.2 ± 0.2 14.3 0.88 ± 4%
308.2 ± 0.2 19.4 0.81 ± 4%
Reference
101–110.


(2)

T [K] p [MPa] D · 108 [m2/s]
308.2 ± 0.2 9.10 1.18 ± 5%
308.2 ± 0.2 14.6 0.96 ± 5%
308.2 ± 0.2 19.5 0.82 ± 5%

T [K] p [MPa] D · 108 [m2/s]
308.2 ± 0.2 9.10 1.07 ± 4%
308.2 ± 0.2 14.6 0.91 ± 4%
308.2 ± 0.2 19.5 0.78 ± 4%
References
269–278.
101–110.


(2)

T [K] p [MPa] D · 108 [m2/s]
308.2 ± 0.2 10.7 1.11 ± 5%
308.2 ± 0.2 15.0 0.94 ± 5%
308.2 ± 0.2 20.0 0.87 ± 5%

T [K] p [MPa] D · 108 [m2/s]
308.2 ± 0.2 10.7 1.02 ± 4%
308.2 ± 0.2 15.0 0.86 ± 4%
308.2 ± 0.2 20.0 0.79 ± 4%
References
269–278.
101–110.

Diffusion of dodecane (1); carbon dioxide (2) 1
Diffusion of dodecane (1); carbon dioxide (2)

C12H26 (1) dodecane 112-40-3

T [K] p [MPa] D · 109 [m2/s]
299.15 ± 0.1 9.0 11.3 ± 3%
299.15 ± 0.1 10.5 11.0 ± 3%
303.15 ± 0.1 10.5 12.0 ± 3%
305.65 ± 0.1 10.5 13.9 ± 3%
308.15 ± 0.1 10.5 15.7 ± 3%
Reference

Diffusion of dodecane (1); sulfur hexafluoride (2) 1
Diffusion of dodecane (1); sulfur hexafluoride (2)

C12H26 (1) dodecane 112-40-3

T [K] p [MPa] D · 109 [m2/s]
303.15 4.5 7.69 ± 3%
313.15 4.5 8.61 ± 3%
323.15 4.5 10.9 ± 3%
303.15 5.0 7.58 ± 3%
313.15 5.0 8.42 ± 3%
323.15 5.0 9.88 ± 3%
328.15 5.0 11.5 ± 3%
333.15 5.0 14.3 ± 3%
303.15 6.0 7.42 ± 3%
313.15 6.0 8.11 ± 3%
323.15 6.0 9.01 ± 3%
333.15 6.0 10.9 ± 3%
303.15 9.0 7.18 ± 3%
313.15 9.0 7.65 ± 3%
323.15 9.0 8.20 ± 3%
333.15 9.0 8.81 ± 3%
Reference

Diffusion of acridine (1); carbon dioxide (2) 1
Diffusion of acridine (1); carbon dioxide (2)

C13H9N (1) acridine 260-94-6

T [K] p [atm] D · 109 [m2/s]
308 170 7.7 ± 0.3
308 272 6.7 ± 0.1
318 170 8.9 ± 0.3
318 272 7.7 ± 0.1
328 170 10.3 ± 0.1
328 272 8.9 ± 0.2
C13H9N (1) acridine 260-94-6

T [K] p [atm] D · 109 [m2/s]
308 170 7.1 ± 0.1
308 272 6.3 ± 0.1
318 170 8.2 ± 0.2
318 272 7.2 ± 0.1
328 170 9.2 ± 0.2
328 272 8.2 ± 0.2
C13H9N (1) acridine 260-94-6

T [K] p [bar] D · 109 [m2/s]
308.15 172.5 7.7
308.15 275.6 6.7
318.15 172.5 8.9
318.15 275.6 7.7
328.15 172.5 10.3
328.15 275.6 8.9
C13H9N (1) acridine 260-94-6

T [K] p [bar] D · 109 [m2/s]
308.15 172.5 7.1
308.15 173.0 5.6
308.15 275.6 6.3
(continued)

2 Diffusion of acridine (1); carbon dioxide (2)
318.15 172.5 8.2

318.15 173.0 7.0
318.15 275.6 7.2
328.15 172.5 9.2
328.15 173.0 7.8
328.15 275.6 8.2
Comment: diffusion in supercritical carbon dioxide with 5% ethanol as modifier
References

Diffusion of phenanthrene (1); carbon dioxide (2) 1
Diffusion of phenanthrene (1); carbon dioxide (2)


T [K] p [bar] D · 109 [m2/s]
303.15 ± 0.2 115 8.9 ± 0.3
303.15 ± 0.2 190 8.5 ± 0.2
313.15 ± 0.2 160 9.6 ± 0.5
313.15 ± 0.2 250 8.2 ± 0.2
333.15 ± 0.2 130 18.4 ± 0.3
333.15 ± 0.2 165 15.2 ± 0.9
333.15 ± 0.2 265 10.7 ± 0.2

T [K] p [atm] D · 109 [m2/s]
308 170 9.6 ± 0.4
308 272 8.4 ± 0.2
318 170 11.4 ± 0.4
318 272 9.2 ± 0.2
328 170 12.6 ± 0.3
328 272 10.3 ± 0.2

T [K] p [atm] D · 109 [m2/s]
308 170 8.8 ± 0.2
308 272 7.4 ± 0.1
318 170 10.1 ± 0.3
318 272 8.4 ± 0.2
328 170 11.9 ± 0.5
328 272 9.4 ± 0.2

T [K] p [bar] D · 109 [m2/s]
308.15 172.5 9.6
308.15 275.6 8.4
(continued)

2 Diffusion of phenanthrene (1); carbon dioxide (2)
318.15 172.5 11.4

318.15 275.6 9.2
328.15 172.5 12.6
328.15 275.6 10.3

T [K] p [bar] D · 109 [m2/s]
308.15 172.5 8.8
308.15 173.0 7.8
308.15 275.6 7.4
318.15 172.5 10.1
318.15 173.0 9.4
318.15 175.6 8.4
328.15 172.5 11.9
328.15 173.0 10.0
Comment: diffusion in supercritical carbon dioxide with 5% ethanol as modifier
References

Diffusion of phenanthrene (1); 2,3-dimethyl-butane (2) 1
Diffusion of phenanthrene (1); 2,3-dimethyl-butane (2)


T [K] p [MPa] D · 109 [m2/s]
523.2 ± 0.2 15.32 17.2 ± 2%
523.2 ± 0.2 10.23 19.7 ± 2%
523.2 ± 0.2 6.897 22.4 ± 2%
523.2 ± 0.2 5.352 25.9 ± 2%
535.2 ± 0.2 15.90 18.3 ± 2%
535.2 ± 0.2 12.44 20.0 ± 2%
535.2 ± 0.2 8.145 23.2 ± 2%
535.2 ± 0.2 6.276 26.6 ± 2%
548.2 ± 0.2 14.37 20.5 ± 2%
548.2 ± 0.2 9.938 23.7 ± 2%
548.2 ± 0.2 7.614 26.7 ± 2%
Reference

1
Diffusion of sodium 4-(4'-dimethylaminophenylazo)-

benzene-1-sulfonate (1); carbon dioxide (2)
C14H14N3NaO3S (1) sodium 4-(4'-dimethylaminophenylazo)-benzene-1-sulfonate 547-58-0

T [K] p [bar] D · 109 [m2/s]
308.15 ± 0.05 222 1.7 ± 5%
308.15 ± 0.05 222 7.3 ± 5%
308.15 ± 0.05 222 7.3 ± 5%
308.15 ± 0.05 222 7.1 ± 5%
313.15 ± 0.05 214 7.8 ± 5%
313.15 ± 0.05 214 7.7 ± 5%
313.15 ± 0.05 163 9.0 ± 5%
313.15 ± 0.05 163 8.4 ± 5%
313.15 ± 0.05 163 9.3 ± 5%
313.15 ± 0.05 163 8.8 ± 5%
313.15 ± 0.05 163 8.2 ± 5%
313.15 ± 0.05 115 11.2 ± 5%
313.15 ± 0.05 115 11.6 ± 5%
313.15 ± 0.05 115 10.5 ± 5%
313.15 ± 0.05 115 11.1 ± 5%
313.15 ± 0.05 103 12.5 ± 5%
313.15 ± 0.05 103 13.0 ± 5%
313.15 ± 0.05 103 12.2 ± 5%
313.15 ± 0.05 97 13.1 ± 5%
313.15 ± 0.05 97 12.6 ± 5%
313.15 ± 0.05 97 12.4 ± 5%
313.15 ± 0.05 97 12.3 ± 5%
313.15 ± 0.05 97 12.2 ± 5%
C14H14N3NaO3S (1) sodium 4-(4'-dimethylaminophenylazo)-benzene-1-sulfonate 547-58-0

T [K] p [bar] D · 109 [m2/s]
293.15 227 6.1 ± 5%
293.15 227 5.8 ± 5%
293.15 227 6.3 ± 5%
293.15 227 6.2 ± 5%
293.15 182 6.3 ± 5%
293.15 182 6.5 ± 5%
293.15 182 6.7 ± 5%
293.15 182 6.6 ± 5%
293.15 182 6.4 ± 5%
(continued)

2
293.15 146 6.8 ± 5%

293.15 146 6.9 ± 5%
293.15 146 6.7 ± 5%
293.15 146 6.5 ± 5%
293.15 117 7.1 ± 5%
293.15 117 7.2 ± 5%
293.15 117 6.9 ± 5%
293.15 117 6.8 ± 5%
293.15 117 7.0 ± 5%
293.15 96 7.2 ± 5%
293.15 96 7.6 ± 5%
293.15 96 7.3 ± 5%
293.15 96 7.4 ± 5%
293.15 96 7.3 ± 5%
293.15 88 8.6 ± 5%
293.15 88 9.1 ± 5%
293.15 88 8.8 ± 5%
293.15 205 6.2 ± 5%
293.15 205 6.6 ± 5%
293.15 205 6.3 ± 5%
293.15 205 6.9 ± 5%
293.15 205 6.4 ± 5%
293.15 88 6.4 ± 5%
293.15 88 6.5 ± 5%
Reference
2003M1 Matthews, M.A., Becnel, J.M.: J. Chem. Eng. Data 48 (2003) 1413–1417.

Diffusion of dibenzyl ether (1); carbon dioxide (2) 1
Diffusion of dibenzyl ether (1); carbon dioxide (2)

C14H14O (1) dibenzyl ether 103-50-4

T [K] p [MPa] D · 109 [m2/s]
313.2 16.0 9.32 ± 3%
C14H14O (1) dibenzyl ether 103-50-4

T [K] p [bar] D · 109 [m2/s]
313.15 160.0 9.3
References

Diffusion of tetradecane (1); carbon dioxide (2) 1
Diffusion of tetradecane (1); carbon dioxide (2)


T [K] p [MPa] D · 109 [m2/s]
299.15 ± 0.1 9.0 9.53 ± 3%
299.15 ± 0.1 10.5 9.41 ± 3%
303.15 ± 0.1 10.5 10.9 ± 3%
305.65 ± 0.1 10.5 12.4 ± 3%
308.15 ± 0.1 10.5 14.1 ± 3%
Reference

Diffusion of tetradecane (1); sulfur hexafluoride (2) 1
Diffusion of tetradecane (1); sulfur hexafluoride (2)


T [K] p [MPa] D · 109 [m2/s]
303.15 4.5 5.71 ± 3%
313.15 4.5 6.49 ± 3%
323.15 4.5 8.02 ± 3%
303.15 5.0 5.66 ± 3%
313.15 5.0 6.32 ± 3%
323.15 5.0 7.35 ± 3%
328.15 5.0 8.52 ± 3%
333.15 5.0 10.1 ± 3%
303.15 6.0 5.41 ± 3%
313.15 6.0 6.09 ± 3%
323.15 6.0 6.82 ± 3%
333.15 6.0 8.02 ± 3%
303.15 9.0 5.21 ± 3%
313.15 9.0 5.63 ± 3%
323.15 9.0 6.15 ± 3%
333.15 9.0 6.69 ± 3%
Reference

Diffusion of cis-9-tetradecenoic acid methyl ester (1); carbon dioxide (2) 1
Diffusion of cis-9-tetradecenoic acid methyl ester (1);

carbon dioxide (2)
C15H28O2 (1) cis-9-tetradecenoic acid methyl ester 56219-06-8

T [K] p [MPa] D · 109 [m2/s]
313 16.0 7.18 ± 0.20
313 25.0 6.03 ± 0.05
Reference

Diffusion of tetradecanoic acid methyl ester (1); carbon dioxide (2) 1
Diffusion of tetradecanoic acid methyl ester (1); carbon

dioxide (2)
C15H30O2 (1) tetradecanoic acid methyl ester 124-10-7

Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: OEC Ref.: 1993L8
T [K] p [bar] D · 109 [m2/s]
313.15 70 1.6
313.15 80 1.5
313.15 90 1.6
323.15 70 2.2
323.15 80 2.2
333.15 80 3.2
Reference
1993L8 Lockeman, C.A., Schlünder, E.-U.: J. of Energy, Heat and Mass Transfer 15 (1993) 125–133.

Diffusion of pyrene (1); carbon dioxide (2) 1
Diffusion of pyrene (1); carbon dioxide (2)

C16H10 (1) pyrene 129-00-0

T [K] p [bar] D · 109 [m2/s]
303.15 ± 0.2 115 9.3 ± 0.2
313.15 ± 0.2 250 7.9 ± 0.1
333.15 ± 0.2 165 14.4 ± 0.6
Reference

Diffusion of cis-hexadec-9-enoic acid methyl ester (1); carbon dioxide (2) 1
Diffusion of cis-hexadec-9-enoic acid methyl ester (1);

carbon dioxide (2)
C17H32O2 (1) cis-hexadec-9-enoic acid methyl ester 1120-25-8

T [K] p [MPa] D · 109 [m2/s]
313.2 ± 0.1 16.0 6.83 ± 0.07
Reference
1991F4 Funazukuri, T., Hachisu, S., Wakao, N.: Ind. Eng. Chem. Res. 30 (1991) 1323–1329.

Diffusion of hexadecanoic acid methyl ester (1); carbon dioxide (2) 1
Diffusion of hexadecanoic acid methyl ester (1); carbon

dioxide (2)
C17H34O2 (1) hexadecanoic acid methyl ester 112-39-0

T [K] p [bar] D · 109 [m2/s]
313.15 70 2.1
313.15 80 2.1
313.15 90 1.8
323.15 70 2.7
323.15 80 2.5
323.15 90 2.4
323.15 100 2.0
323.15 110 1.9
323.15 120 1.95
323.15 130 2.0
333.15 89 4.8
Reference

Diffusion of 1,2-benzophenantrene (1); carbon dioxide (2) 1
Diffusion of 1,2-benzophenantrene (1); carbon dioxide (2)

C18H12 (1) 1,2-benzophenantrene 218-01-9

T [K] p [bar] D · 109 [m2/s]
303.15 ± 0.2 190 7.1 ± 0.1
313.15 ± 0.2 160 8.6 ± 0.6
131.15 ± 0.2 250 7.4 ± 0.1
333.15 ± 0.2 265 9.6 ± 0.2
Reference

Diffusion of 4'-(pentyloxy)-[1,1'-biphenyl]-4-carbonitrile (1); carbon dioxide (2) 1
Diffusion of 4'-(pentyloxy)-[1,1'-biphenyl]-4-carbonitrile
C18H19NO (1) 4'-(pentyloxy)-[1,1'-biphenyl]-4-carbonitrile 52364-71-3

T [K] p [MPa] D · 108 [m2/s]
314.5 18 0.86 ± 6%
314.5 17 0.89 ± 6%
314.5 16 0.89 ± 6%
314.5 15 0.93 ± 6%
314.5 14 0.96 ± 6%
314.5 13 1.06 ± 6%
Reference

Diffusion of N-(4-methoxybenzylidene)-4-n-butylaniline (1); carbon dioxide (2) 1
Diffusion of N-(4-methoxybenzylidene)-4-n-butylaniline
C18H21NO (1) N-(4-methoxybenzylidene)-4-n-butylaniline 26227-73-6

T [K] p [MPa] D · 108 [m2/s]
313.5 16 1.00 ± 6%
313.5 15 1.04 ± 6%
313.5 14 1.10 ± 6%
313.5 13 1.15 ± 6%
313.5 12 1.23 ± 6%
Reference

Diffusion of cis,cis,cis-octadeca-6,9,12-trienoic acid (1); carbon dioxide (2) 1
Diffusion of cis,cis,cis-octadeca-6,9,12-trienoic acid (1);

carbon dioxide (2)
C18H30O2 (1) cis,cis,cis-octadeca-6,9,12-trienoic acid 506-26-3

Diffusion of solute(1) in fluid(2): D*1(2)(T ); Method: TAYLOR Ref.: 2000R2
T [K] p [MPa] D · 109 [m2/s]
323.15 36.0 2.56 ± 0.12
Reference
2000R2 Rezaei, K.A., Temelli, F.: J. Supercrit. Fluids 17 (2000) 35–44.

Diffusion of cis,cis,cis-octadeca-9,12,15-trienoic acid (1);

carbon dioxide (2)

T [K] p [MPa] D · 108 [m2/s]
308.15 ± 0.01 8.50 0.912
308.15 ± 0.01 9.09 0.838
308.15 ± 0.01 9.98 0.756
308.15 ± 0.01 11.05 0.716
308.15 ± 0.01 13.00 0.661
308.15 ± 0.01 15.98 0.606
308.15 ± 0.01 20.04 0.571
308.15 ± 0.01 25.02 0.525
308.15 ± 0.01 30.06 0.506
313.21 ± 0.01 10.00 0.921
313.21 ± 0.01 11.45 0.806
313.21 ± 0.01 12.01 0.788
313.21 ± 0.01 12.02 0.797
313.21 ± 0.01 14.00 0.709
313.21 ± 0.01 15.00 0.689
313.21 ± 0.01 15.98 0.672
313.21 ± 0.01 16.01 0.674
313.21 ± 0.01 18.09 0.642
313.21 ± 0.01 20.07 0.615
313.21 ± 0.01 21.02 0.612
313.21 ± 0.01 22.06 0.598
313.21 ± 0.01 24.09 0.595
313.21 ± 0.01 26.02 0.575
313.21 ± 0.01 28.01 0.555
313.21 ± 0.01 30.04 0.535
323.15 ± 0.01 12.93 0.912
323.15 ± 0.01 13.99 0.847
323.15 ± 0.01 16.00 0.786
323.15 ± 0.01 18.56 0.739
323.15 ± 0.01 22.00 0.686
323.15 ± 0.01 25.02 0.670
323.15 ± 0.01 28.01 0.634
323.15 ± 0.01 30.10 0.606
333.15 ± 0.01 14.00 1.082
333.15 ± 0.01 14.93 1.013
333.15 ± 0.01 15.97 0.962
333.15 ± 0.01 17.97 0.872
333.15 ± 0.01 20.02 0.825
(continued)

2 Diffusion of cis,cis,cis-octadeca-9,12,15-trienoic acid (1); carbon dioxide (2)
333.15 ± 0.01 21.99 0.777

333.15 ± 0.01 24.00 0.771
333.15 ± 0.01 25.00 0.730
333.15 ± 0.01 26.00 0.740
333.15 ± 0.01 27.02 0.698
333.15 ± 0.01 28.50 0.686
333.15 ± 0.01 30.00 0.709
333.15 ± 0.01 30.05 0.672
343.15 ± 0.01 15.89 1.151
343.15 ± 0.01 16.65 1.104
343.15 ± 0.01 17.18 1.071
343.15 ± 0.01 17.99 1.038
343.15 ± 0.01 19.42 0.974
343.15 ± 0.01 20.99 0.915
343.15 ± 0.01 22.95 0.869
343.15 ± 0.01 25.93 0.821
343.15 ± 0.01 27.96 0.805
343.15 ± 0.01 30.14 0.770

T [K] p [MPa] D · 108 [m2/s]
313.21 ± 0.01 9.49 0.947 ± 4.3%
313.21 ± 0.01 10.04 0.874 ± 4.3%
313.21 ± 0.01 10.99 0.803 ± 4.3%
313.21 ± 0.01 12.00 0.770 ± 4.3%
313.21 ± 0.01 14.02 0.717 ± 4.3%
313.21 ± 0.01 15.98 0.675 ± 4.3%
313.21 ± 0.01 17.98 0.647 ± 4.3%
313.21 ± 0.01 20.00 0.613 ± 4.3%
313.21 ± 0.01 21.99 0.597 ± 4.3%
313.21 ± 0.01 24.00 0.577 ± 4.3%
313.21 ± 0.01 26.01 0.563 ± 4.3%
313.21 ± 0.01 27.99 0.546 ± 4.3%
313.21 ± 0.01 30.04 0.549 ± 4.3%
313.21 ± 0.01 30.11 0.539 ± 4.3%
323.15 ± 0.01 12.02 0.890 ± 4.3%
323.15 ± 0.01 12.51 0.915 ± 4.3%
323.15 ± 0.01 13.00 0.886 ± 4.3%
323.15 ± 0.01 14.00 0.858 ± 4.3%
323.15 ± 0.01 16.00 0.776 ± 4.3%
323.15 ± 0.01 18.00 0.739 ± 4.3%
323.15 ± 0.01 20.01 0.706 ± 4.3%
323.15 ± 0.01 22.00 0.683 ± 4.3%
323.15 ± 0.01 24.00 0.657 ± 4.3%
323.15 ± 0.01 26.00 0.637 ± 4.3%
(continued)
323.15 ± 0.01 28.02 0.312 ± 4.3%

323.15 ± 0.01 30.29 0.590 ± 4.3%
333.15 ± 0.01 13.89 0.959 ± 4.3%
333.15 ± 0.01 14.48 0.999 ± 4.3%
333.15 ± 0.01 15.00 0.967 ± 4.3%
333.15 ± 0.01 15.98 0.933 ± 4.3%
333.15 ± 0.01 18.00 0.866 ± 4.3%
333.15 ± 0.01 20.00 0.828 ± 4.3%
333.15 ± 0.01 20.05 0.817 ± 4.3%
333.15 ± 0.01 22.00 0.782 ± 4.3%
333.15 ± 0.01 24.02 0.758 ± 4.3%
333.15 ± 0.01 26.06 0.721 ± 4.3%
333.15 ± 0.01 27.02 0.714 ± 4.3%
333.15 ± 0.01 28.02 0.703 ± 4.3%
333.15 ± 0.01 29.04 0.699 ± 4.3%
333.15 ± 0.01 30.07 0.682 ± 4.3%
343.15 ± 0.01 16.20 1.017 ± 4.3%
343.15 ± 0.01 16.21 1.039 ± 4.3%
343.15 ± 0.01 16.99 1.019 ± 4.3%
343.15 ± 0.01 17.99 0.985 ± 4.3%
343.15 ± 0.01 18.00 0.984 ± 4.3%
343.15 ± 0.01 18.99 0.943 ± 4.3%
343.15 ± 0.01 20.00 0.901 ± 4.3%
343.15 ± 0.01 20.04 0.918 ± 4.3%
343.15 ± 0.01 22.00 0.871 ± 4.3%
343.15 ± 0.01 24.00 0.837 ± 4.3%
343.15 ± 0.01 26.01 0.811 ± 4.3%
343.15 ± 0.01 26.99 0.788 ± 4.3%
343.15 ± 0.01 28.01 0.777 ± 4.3%
343.15 ± 0.01 29.05 0.781 ± 4.3%
343.15 ± 0.01 30.03 0.764 ± 4.3%

T [Kz] p [MPa] D · 108 [m2/s]
314.5 18 0.78 ± 6%
314.5 17 0.81 ± 6%
314.5 16 0.81 ± 6%
314.5 14 0.92 ± 6%
314.5 13 1.00 ± 6%

4 Diffusion of cis,cis,cis-octadeca-9,12,15-trienoic acid (1); carbon dioxide (2)

T [K] p [MPa] D · 109 [m2/s]
323.15 36.0 2.02 ± 0.17
References

Diffusion of cis,cis-octadeca-9,12-dienoic acid (1); carbon dioxide (2) 1
Diffusion of cis,cis-octadeca-9,12-dienoic acid (1); carbon

dioxide (2)
C18H32O2 (1) cis,cis-octadeca-9,12-dienoic acid 60-33-3

T [K] p [MPa] D · 108 [m2/s]
308.15 ± 0.01 8.50 0.870 ± 4.3%
308.15 ± 0.01 8.97 0.831 ± 4.3%
308.15 ± 0.01 10.00 0.753 ± 4.3%
308.15 ± 0.01 11.02 0.733 ± 4.3%
308.15 ± 0.01 12.00 0.689 ± 4.3%
308.15 ± 0.01 14.00 0.645 ± 4.3%
308.15 ± 0.01 16.01 0.613 ± 4.3%
308.15 ± 0.01 17.47 0.602 ± 4.3%
308.15 ± 0.01 18.02 0.590 ± 4.3%
308.15 ± 0.01 20.00 0.585 ± 4.3%
308.15 ± 0.01 21.00 0.571 ± 4.3%
308.15 ± 0.01 22.03 0.569 ± 4.3%
308.15 ± 0.01 25.00 0.526 ± 4.3%
308.15 ± 0.01 26.00 0.520 ± 4.3%
308.15 ± 0.01 28.05 0.505 ± 4.3%
308.15 ± 0.01 30.30 0.496 ± 4.3%
C18H32O2 (1) cis,cis-octadeca-9,12-dienoic acid 60-33-3

T [K] p [MPa] D · 109 [m2/s]
323.15 36.0 3.33 ± 0.35
References

Diffusion of cis-octadec-9-enoic acid (1); carbon dioxide (2) 1
Diffusion of cis-octadec-9-enoic acid (1); carbon dioxide (2)

C18H34O2 (1) cis-octadec-9-enoic acid 112-80-1

T [K] p [bar] D · 109 [m2/s]
313.15 75 1.6
313.15 100 1.5
313.15 125 1.6
313.15 150 1.6
323.15 100 2.0
323.15 125 2.1
333.15 100 2.5

T [K] p [bar] D · 109 [m2/s]
308.1 201 5.59 ± 0.11
308.1 251 4.80 ± 0.12

T [K] p [MPa] D · 109 [m2/s]
323.15 36.0 3.57 ± 0.18

T [K] p [MPa] D · 108 [m2/s]
313.21 ± 0.01 9.46 0.943
313.21 ± 0.01 9.48 0.928
313.21 ± 0.01 9.49 0.929
313.21 ± 0.01 9.51 0.935
313.21 ± 0.01 10.01 0.880
313.21 ± 0.01 11.02 0.807
313.21 ± 0.01 11.99 0.763
313.21 ± 0.01 14.01 0.705
313.21 ± 0.01 15.96 0.670
313.21 ± 0.01 16.01 0.667
313.21 ± 0.01 18.00 0.630
313.21 ± 0.01 20.01 0.606
(continued)

2 Diffusion of cis-octadec-9-enoic acid (1); carbon dioxide (2)
313.21 ± 0.01 21.98 0.585

313.21 ± 0.01 23.99 0.575
313.21 ± 0.01 25.06 0.562
313.21 ± 0.01 25.06 0.565
313.21 ± 0.01 26.00 0.554
313.21 ± 0.01 27.99 0.543
313.21 ± 0.01 30.10 0.529

T [K] p [MPa] D · 108 [m2/s]
313.5 16 1.08 ± 6%
313.5 14 1.19 ± 6%
313.5 13.5 1.29 ± 6%
313.5 13 1.37 ± 6%
313.5 12 1.54 ± 6%
References

Diffusion of octadecanoic acid (1); carbon dioxide (2) 1
Diffusion of octadecanoic acid (1); carbon dioxide (2)

C18H36O2 (1) octadecanoic acid 57-11-4

T [K] p [MPa] D · 108 [m2/s]
313.5 16 1.10 ± 6%
313.5 15 1.15 ± 6%
313.5 14 1.19 ± 6%
313.5 13 1.28 ± 6%
Reference

Diffusion of cis-octadeca-6,9,12-trienoic acid methyl ester (1); carbon dioxide (2) 1
Diffusion of cis-octadeca-6,9,12-trienoic acid methyl ester

C19H32O2 (1) cis-octadeca-6,9,12-trienoic acid methyl ester 16326-32-2

T [K] p [MPa] D · 109 [m2/s]
313.2 ± 0.1 16.0 6.64 ± 0.09
Reference

Diffusion of cis,cis-octadeca-9,12-dienoic acid methyl ester (1); carbon dioxide (2) 1
Diffusion of cis,cis-octadeca-9,12-dienoic acid methyl

ester (1); carbon dioxide (2)
C19H34O2 (1) cis,cis-octadeca-9,12-dienoic acid methyl ester 112-63-0

T [K] p [MPa] D · 109 [m2/s]
308.2 ± 0.1 14.0 6.30 ± 0.06
308.2 ± 0.1 16.0 6.20 ± 0.08
313.2 ± 0.1 16.0 6.52 ± 0.07
318.2 ± 0.1 16.0 7.17 ± 0.11
308.2 ± 0.1 19.0 5.78 ± 0.09
313.2 ± 0.1 19.0 6.17 ± 0.07
318.2 ± 0.1 19.0 6.68 ± 0.15
323.2 ± 0.1 19.0 7.13 ± 0.18
328.2 ± 0.1 19.0 7.86 ± 0.11
323.2 ± 0.1 21.5 6.92 ± 0.13
328.2 ± 0.1 24.0 7.14 ± 0.16
313.2 ± 0.1 25.0 5.76 ± 0.06
318.2 ± 0.1 25.0 6.05 ± 0.09
323.2 ± 0.1 25.0 6.30 ± 0.14
328.2 ± 0.1 25.0 6.66 ± 0.08
313.2 ± 0.1 30.0 5.42 ± 0.06
328.2 ± 0.1 30.0 6.16 ± 0.11
313.2 ± 0.1 33.6 5.10 ± 0.08
318.2 ± 0.1 33.6 5.41 ± 0.09

T [K] p [MPa] D · 109 [m2/s]
313.2 ± 0.1 16.0 6.52 ± 0.07

T [K] p [MPa] D · 109 [m2/s]
313 16.0 6.50

2 Diffusion of cis,cis-octadeca-9,12-dienoic acid methyl ester (1); carbon dioxide (2)

Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: TAYLOR Ref.: 1989F3
Equation: D = A · exp[ – B / RT ] Range: 308 < T/K < 328
Parameter: ρ [g cm–3] A · 108 B
0.800 3.68 4520
7
p [MPa] A · 10 B
19.0 8.44 1280
Comment: diffusion in supercritical carbon dioxide
References

Diffusion of cis-octadec-9-enoic acid methyl ester (1); carbon dioxide (2) 1
Diffusion of cis-octadec-9-enoic acid methyl ester (1);

carbon dioxide (2)

T [K] p [MPa] D · 108 [m2/s]
313.21 ± 0.01 8.00 1.694
313.21 ± 0.01 8.18 1.550
313.21 ± 0.01 8.37 1.529
313.21 ± 0.01 8.48 1.445
313.21 ± 0.01 8.50 1.430
313.21 ± 0.01 8.50 1.436
313.21 ± 0.01 8.62 1.375
313.21 ± 0.01 8.70 1.295
313.21 ± 0.01 8.77 1.219
313.21 ± 0.01 8.80 1.152
313.21 ± 0.01 8.92 1.118
313.21 ± 0.01 8.99 1.092
313.21 ± 0.01 9.01 1.122
313.21 ± 0.01 9.01 1.107
313.21 ± 0.01 9.21 1.064
313.21 ± 0.01 9.33 1.027
313.21 ± 0.01 9.57 0.976
313.21 ± 0.01 10.00 0.925
313.21 ± 0.01 11.00 0.864

T [K] p [MPa] D · 109 [m2/s]
313 16.0 6.55

T [K] p [MPa] D · 109 [m2/s]
313.2 ± 0.1 16.0 6.59 ± 0.05

2 Diffusion of cis-octadec-9-enoic acid methyl ester (1); carbon dioxide (2)

T [K] p [MPa] D · 109 [m2/s]
323.15 36.0 4.65 ± 0.08
References

Diffusion of trans-octadec-9-enoic acid methyl ester (1); carbon dioxide (2) 1
Diffusion of trans-octadec-9-enoic acid methyl ester (1);

carbon dioxide (2)
C19H36O2 (1) trans-octadec-9-enoic acid methyl ester 1937-62-8

T [K] p [MPa] D · 109 [m2/s]
313.2 ± 0.1 16.0 6.24 ± 0.08
Reference

Diffusion of cis-5,8,11,14,17-eicosapentaenoic acid (1); carbon dioxide (2) 1
Diffusion of cis-5,8,11,14,17-eicosapentaenoic acid (1);

carbon dioxide (2)
C20H30O2 (1) cis-5,8,11,14,17-eicosapentaenoic acid 10417-94-4

T [K] p [MPa] D · 108 [m2/s]
308.15 ± 0.01 8.68 0.843
308.15 ± 0.01 9.57 0.753
308.15 ± 0.01 10.00 0.731
308.15 ± 0.01 11.57 0.664
308.15 ± 0.01 13.57 0.620
308.15 ± 0.01 15.69 0.588
308.15 ± 0.01 16.00 0.581
308.15 ± 0.01 18.05 0.557
308.15 ± 0.01 20.01 0.541
308.15 ± 0.01 22.00 0.525
308.15 ± 0.01 24.97 0.511
308.15 ± 0.01 27.14 0.502
313.21 ± 0.01 9.98 0.862
313.21 ± 0.01 10.55 0.820
313.21 ± 0.01 10.96 0.784
313.21 ± 0.01 11.45 0.759
313.21 ± 0.01 11.98 0.742
313.21 ± 0.01 12.01 0.745
313.21 ± 0.01 12.04 0.723
313.21 ± 0.01 12.87 0.709
313.21 ± 0.01 13.98 0.675
313.21 ± 0.01 16.00 0.631
313.21 ± 0.01 17.99 0.605
313.21 ± 0.01 20.07 0.583
313.21 ± 0.01 22.01 0.568
313.21 ± 0.01 24.02 0.549
313.21 ± 0.01 26.02 0.533
313.21 ± 0.01 28.04 0.524
313.21 ± 0.01 30.00 0.506
323.15 ± 0.01 12.20 0.929
323.15 ± 0.01 12.96 0.871
323.15 ± 0.01 14.06 0.824
323.15 ± 0.01 16.00 0.747
323.15 ± 0.01 17.42 0.714
323.15 ± 0.01 19.93 0.656
323.15 ± 0.01 24.96 0.608
323.15 ± 0.01 30.06 0.561
333.15 ± 0.01 13.77 1.036
(continued)

2 Diffusion of cis-5,8,11,14,17-eicosapentaenoic acid (1); carbon dioxide (2)
333.15 ± 0.01 15.01 0.944

333.15 ± 0.01 17.90 0.820
333.15 ± 0.01 20.02 0.780
333.15 ± 0.01 21.98 0.736
333.15 ± 0.01 24.08 0.700
333.15 ± 0.01 25.94 0.667
333.15 ± 0.01 28.05 0.646
333.15 ± 0.01 30.15 0.628
343.15 ± 0.01 15.82 1.083
343.15 ± 0.01 16.62 1.031
343.15 ± 0.01 18.52 0.931
343.15 ± 0.01 20.03 0.875
343.15 ± 0.01 21.96 0.819
343.15 ± 0.01 24.18 0.784
343.15 ± 0.01 25.99 0.756
343.15 ± 0.01 28.12 0.718
343.15 ± 0.01 30.07 0.694
Reference

Diffusion of all-cis-eicosa-5,8,11,14-tetraenoic acid (1); carbon dioxide (2) 1
Diffusion of all-cis-eicosa-5,8,11,14-tetraenoic acid (1);

carbon dioxide (2)
C20H32O2 (1) all-cis-eicosa-5,8,11,14-tetraenoic acid 506-32-1

T [K] p [MPa] D · 108 [m2/s]
308.15 ± 0.01 9.50 0.750 ± 4.3%
308.15 ± 0.01 10.00 0.717 ± 4.3%
308.15 ± 0.01 10.52 0.703 ± 4.3%
308.15 ± 0.01 10.87 0.675 ± 4.3%
308.15 ± 0.01 11.00 0.658 ± 4.3%
308.15 ± 0.01 11.50 0.657 ± 4.3%
308.15 ± 0.01 12.01 0.670 ± 4.3%
308.15 ± 0.01 12.02 0.648 ± 4.3%
308.15 ± 0.01 12.49 0.627 ± 4.3%
308.15 ± 0.01 12.99 0.618 ± 4.3%
308.15 ± 0.01 14.00 0.617 ± 4.3%
308.15 ± 0.01 15.99 0.590 ± 4.3%
308.15 ± 0.01 17.99 0.563 ± 4.3%
308.15 ± 0.01 20.01 0.548 ± 4.3%
308.15 ± 0.01 22.00 0.538 ± 4.3%
308.15 ± 0.01 24.00 0.525 ± 4.3%
308.15 ± 0.01 26.00 0.511 ± 4.3%
308.15 ± 0.01 28.01 0.502 ± 4.3%
308.15 ± 0.01 30.24 0.499 ± 4.3%
308.15 ± 0.01 30.49 0.485 ± 4.3%
313.21 ± 0.01 9.50 0.904 ± 4.3%
313.21 ± 0.01 10.00 0.841 ± 4.3%
313.21 ± 0.01 11.01 0.776 ± 4.3%
313.21 ± 0.01 12.01 0.710 ± 4.3%
313.21 ± 0.01 14.00 0.666 ± 4.3%
313.21 ± 0.01 16.00 0.629 ± 4.3%
313.21 ± 0.01 18.00 0.606 ± 4.3%
313.21 ± 0.01 20.00 0.578 ± 4.3%
313.21 ± 0.01 22.01 0.564 ± 4.3%
313.21 ± 0.01 24.01 0.553 ± 4.3%
313.21 ± 0.01 26.01 0.536 ± 4.3%
313.21 ± 0.01 28.02 0.524 ± 4.3%
313.21 ± 0.01 30.04 0.510 ± 4.3%
313.21 ± 0.01 30.13 0.510 ± 4.3%
323.15 ± 0.01 12.01 0.902 ± 4.3%
323.15 ± 0.01 12.50 0.907 ± 4.3%
323.15 ± 0.01 13.02 0.866 ± 4.3%
323.15 ± 0.01 13.48 0.828 ± 4.3%
(continued)

2 Diffusion of all-cis-eicosa-5,8,11,14-tetraenoic acid (1); carbon dioxide (2)
323.15 ± 0.01 14.01 0.815 ± 4.3%

323.15 ± 0.01 15.99 0.744 ± 4.3%
323.15 ± 0.01 18.00 0.703 ± 4.3%
323.15 ± 0.01 20.02 0.678 ± 4.3%
323.15 ± 0.01 21.99 0.642 ± 4.3%
323.15 ± 0.01 24.00 0.621 ± 4.3%
323.15 ± 0.01 26.00 0.602 ± 4.3%
323.15 ± 0.01 28.02 0.588 ± 4.3%
323.15 ± 0.01 30.05 0.564 ± 4.3%
323.15 ± 0.01 30.06 0.582 ± 4.3%
333.15 ± 0.01 13.89 1.053 ± 4.3%
333.15 ± 0.01 15.03 0.916 ± 4.3%
333.15 ± 0.01 15.50 0.904 ± 4.3%
333.15 ± 0.01 16.98 0.847 ± 4.3%
333.15 ± 0.01 17.50 0.832 ± 4.3%
333.15 ± 0.01 19.01 0.791 ± 4.3%
333.15 ± 0.01 19.99 0.767 ± 4.3%
333.15 ± 0.01 22.01 0.726 ± 4.3%
333.15 ± 0.01 24.00 0.701 ± 4.3%
333.15 ± 0.01 26.01 0.681 ± 4.3%
333.15 ± 0.01 26.06 0.678 ± 4.3%
333.15 ± 0.01 28.03 0.668 ± 4.3%
333.15 ± 0.01 30.16 0.649 ± 4.3%
343.15 ± 0.01 16.20 1.005 ± 4.3%
343.15 ± 0.01 16.99 0.957 ± 4.3%
343.15 ± 0.01 17.49 0.945 ± 4.3%
343.15 ± 0.01 18.01 0.914 ± 4.3%
343.15 ± 0.01 18.99 0.893 ± 4.3%
343.15 ± 0.01 19.99 0.861 ± 4.3%
343.15 ± 0.01 21.00 0.846 ± 4.3%
343.15 ± 0.01 22.01 0.832 ± 4.3%
343.15 ± 0.01 22.98 0.787 ± 4.3%
343.15 ± 0.01 23.99 0.779 ± 4.3%
343.15 ± 0.01 26.00 0.758 ± 4.3%
343.15 ± 0.01 28.00 0.712 ± 4.3%
343.15 ± 0.01 28.05 0.730 ± 4.3%
343.15 ± 0.01 30.26 0.713 ± 4.3%
Reference

Diffusion of cis-octadec-9-enoic acid ethyl ester (1); carbon dioxide (2) 1
Diffusion of cis-octadec-9-enoic acid ethyl ester (1); carbon

dioxide (2)
C20H38O2 (1) cis-octadec-9-enoic acid ethyl ester 111-62-6

T [K] p [MPa] D · 108 [m2/s]
313.21 ± 0.01 8.60 1.359
313.21 ± 0.01 8.80 1.216
313.21 ± 0.01 9.00 1.087
313.21 ± 0.01 9.02 1.077
313.21 ± 0.01 11.00 0.856
C20H38O2 (1) cis-octadec-9-enoic acid ethyl ester 111-62-6

T [K] p [MPa] D · 109 [m2/s]
323.15 36.0 4.17 ± 0.05
References

1
Diffusion of cis-eicosa-5,8,11,14,17-pentaenoic acid methyl

C21H32O2 (1) cis-eicosa-5,8,11,14,17-pentaenoic acid methyl ester 2734-47-6

T [K] p [MPa] D · 109 [m2/s]
313.2 ± 0.1 16.0 6.36 ± 0.04
Reference

Diffusion of cis-11-icosenoic acid methyl ester (1); carbon dioxide (2) 1
Diffusion of cis-11-icosenoic acid methyl ester (1); carbon

dioxide (2)
C21H40O2 (1) cis-11-icosenoic acid methyl ester 2390-09-2

T [K] p [MPa] D · 108 [m2/s]
313 16.0 6.19 ± 0.27
313 25.0 5.25 ± 0.07
Reference

1
Diffusion of cis-octadec-9-enoic acid propane-1,2,3-triol

monoester (1); carbon dioxide (2)
C21H40O4 (1) cis-octadec-9-enoic acid propane-1,2,3-triol monoester 25496-72-4

T [K] p [MPa] D · 108 [m2/s]
313.21 ± 0.01 10.01 0.797
313.21 ± 0.01 10.50 0.767
313.21 ± 0.01 10.51 0.762
313.21 ± 0.01 10.98 0.725
313.21 ± 0.01 11.01 0.735
313.21 ± 0.01 11.01 0.741
313.21 ± 0.01 12.01 0.704
313.21 ± 0.01 14.00 0.645
313.21 ± 0.01 16.00 0.605
313.21 ± 0.01 20.00 0.555
313.21 ± 0.01 25.00 0.510
Reference

Diffusion of cis-4,7,10,13,16,19-docosahexaenoic acid (1); carbon dioxide (2) 1
Diffusion of cis-4,7,10,13,16,19-docosahexaenoic acid (1);

carbon dioxide (2)
C22H32O2 (1) cis-4,7,10,13,16,19-docosahexaenoic acid 6217-54-5

T [K] p [MPa] D · 108 [m2/s]
308.15 ± 0.01 9.27 0.725
308.15 ± 0.01 10.00 0.685
308.15 ± 0.01 11.50 0.635
308.15 ± 0.01 13.06 0.596
308.15 ± 0.01 15.04 0.564
308.15 ± 0.01 16.97 0.528
308.15 ± 0.01 20.02 0.507
308.15 ± 0.01 23.01 0.476
308.15 ± 0.01 26.03 0.458
308.15 ± 0.01 30.10 0.443
313.21 ± 0.01 10.83 0.750
313.21 ± 0.01 10.94 0.742
313.21 ± 0.01 11.45 0.714
313.21 ± 0.01 11.92 0.695
313.21 ± 0.01 11.99 0.688
313.21 ± 0.01 12.08 0.690
313.21 ± 0.01 12.87 0.667
313.21 ± 0.01 12.96 0.662
313.21 ± 0.01 12.98 0.666
313.21 ± 0.01 13.02 0.671
313.21 ± 0.01 13.45 0.652
313.21 ± 0.01 15.02 0.613
313.21 ± 0.01 16.01 0.601
313.21 ± 0.01 16.94 0.583
313.21 ± 0.01 19.05 0.557
313.21 ± 0.01 19.96 0.545
313.21 ± 0.01 22.96 0.522
313.21 ± 0.01 22.97 0.521
313.21 ± 0.01 23.03 0.521
313.21 ± 0.01 24.01 0.507
313.21 ± 0.01 26.51 0.492
313.21 ± 0.01 28.01 0.477
313.21 ± 0.01 29.10 0.472
313.21 ± 0.01 29.10 0.476
313.21 ± 0.01 30.08 0.467
323.15 ± 0.01 12.74 0.830
323.15 ± 0.01 13.29 0.800
323.15 ± 0.01 15.00 0.737
(continued)

2 Diffusion of cis-4,7,10,13,16,19-docosahexaenoic acid (1); carbon dioxide (2)
323.15 ± 0.01 15.99 0.700

323.15 ± 0.01 17.03 0.681
323.15 ± 0.01 17.43 0.664
323.15 ± 0.01 20.01 0.616
323.15 ± 0.01 24.98 0.561
323.15 ± 0.01 30.10 0.525
323.15 ± 0.01 30.12 0.523
333.15 ± 0.01 14.67 0.904
333.15 ± 0.01 16.07 0.832
333.15 ± 0.01 17.82 0.773
333.15 ± 0.01 20.01 0.726
333.15 ± 0.01 22.04 0.682
333.15 ± 0.01 24.05 0.651
333.15 ± 0.01 25.94 0.630
333.15 ± 0.01 28.04 0.604
333.15 ± 0.01 30.13 0.587
343.15 ± 0.01 16.61 0.962
343.15 ± 0.01 17.58 0.915
343.15 ± 0.01 18.50 0.873
343.15 ± 0.01 20.03 0.826
343.15 ± 0.01 22.00 0.780
343.15 ± 0.01 24.21 0.744
343.15 ± 0.01 26.01 0.712
343.15 ± 0.01 28.17 0.680
343.15 ± 0.01 30.06 0.664
Reference

Diffusion of retinol acetate (1); carbon dioxide (2) 1
Diffusion of retinol acetate (1); carbon dioxide (2)

C22H32O2 (1) retinol acetate 127-47-9

T [K] p [MPa] D · 109 [m2/s]
313 16.0 5.95 ± 0.11
313 25.0 5.47 ± 0.17
Reference

1
Diffusion of cis-docosa-4,7,10,13,16,19-hexaenoic acid

methyl ester (1); carbon dioxide (2)
C23H34O2 (1) cis-docosa-4,7,10,13,16,19-hexaenoic acid methyl ester 2566-90-7

T [K] p [MPa] D · 109 [m2/s]
313.2 ± 0.1 16.0 6.04 ± 0.04
Reference

Diffusion of cis-docos-13-enoic acid methyl ester (1); carbon dioxide (2) 1
Diffusion of cis-docos-13-enoic acid methyl ester (1); carbon

dioxide (2)
C23H44O2 (1) cis-docos-13-enoic acid methyl ester 1120-34-9

T [K] p [MPa] D · 109 [m2/s]
313 16.0 5.92 ± 0.30
313 25.0 5.08 ± 0.05
Reference

Diffusion of cis-tetracos-15-enoic acid methyl ester (1); carbon dioxide (2) 1
Diffusion of cis-tetracos-15-enoic acid methyl ester (1);

carbon dioxide (2)
C25H48O2 (1) cis-tetracos-15-enoic acid methyl ester 2733-88-2

T [K] p [MPa] D · 109 [m2/s]
313.2 ± 0.13 16.0 5.57 ± 0.09
Reference

Diffusion of D-alpha-tocopherol (1); carbon dioxide (2) 1
Diffusion of D-alpha-tocopherol (1); carbon dioxide (2)

C29H50O2 (1) D-alpha-tocopherol 59-02-9

T [K] p [MPa] D · 108 [m2/s]
308.15 8.51 0.845
308.15 8.90 0.785
308.15 9.12 0.760
308.15 9.79 0.714
308.15 10.57 0.676
308.15 10.96 0.661
308.15 13.04 0.615
308.15 14.09 0.596
308.15 16.06 0.570
308.15 16.17 0.564
308.15 18.06 0.545
308.15 20.04 0.527
308.15 22.09 0.506
308.15 24.03 0.494
308.15 26.02 0.482
308.15 28.06 0.470
308.15 30.31 0.456
313.15 9.96 0.850
313.15 10.34 0.807
313.15 11.00 0.759
313.15 12.02 0.711
313.15 16.17 0.630
313.15 16.20 0.620
313.15 20.00 0.564
313.15 22.11 0.541
313.15 24.19 0.529
313.15 26.11 0.519
313.15 28.08 0.505
313.15 30.25 0.497
313.15 30.27 0.496
323.15 12.72 0.892
323.15 13.08 0.864
323.15 13.50 0.834
323.15 14.05 0.802
323.15 14.45 0.783
323.15 15.04 0.765
323.15 15.63 0.746
323.15 16.27 0.726
323.15 16.95 0.713
323.15 18.56 0.681
(continued)
2 Diffusion of D-alpha-tocopherol (1); carbon dioxide (2)
323.15 20.03 0.663

323.15 22.07 0.630
323.15 24.20 0.612
323.15 26.08 0.600
323.15 28.08 0.579
323.15 30.20 0.568
333.15 17.93 0.821
333.15 19.92 0.771
333.15 22.05 0.729
333.15 23.95 0.700
333.15 25.97 0.676
333.15 28.03 0.657
333.15 30.00 0.635

T [K] p [MPa] D · 108 [m2/s]
313.15 ± 0.01 9.88 0.858 ± 3.7%
313.15 ± 0.01 11.90 0.713 ± 3.7%
313.15 ± 0.01 14.05 0.655 ± 3.7%
313.15 ± 0.01 16.40 0.616 ± 3.7%
313.15 ± 0.01 18.58 0.585 ± 3.7%
313.15 ± 0.01 21.53 0.544 ± 3.7%
313.15 ± 0.01 25.70 0.520 ± 3.7%
313.15 ± 0.01 30.13 0.495 ± 3.7%

T [K] p [MPa] D · 109 [m2/s]
313.15 ± 0.01 12.16 7.04
313.15 ± 0.01 12.20 6.98
313.15 ± 0.01 13.33 6.70
313.15 ± 0.01 14.30 6.49
313.15 ± 0.01 15.25 6.31
313.15 ± 0.01 16.17 6.29
313.15 ± 0.01 16.18 6.05
313.15 ± 0.01 16.20 6.07
313.15 ± 0.01 17.04 6.19
313.15 ± 0.01 17.73 5.99
313.15 ± 0.01 18.02 5.86
313.15 ± 0.01 18.91 5.83
313.15 ± 0.01 19.63 5.73
313.15 ± 0.01 20.03 5.63
(continued)
Diffusion of D-alpha-tocopherol (1); carbon dioxide (2) 3
313.15 ± 0.01 21.47 5.41

313.15 ± 0.01 21.95 5.17
313.15 ± 0.01 23.05 5.22
323.15 ± 0.01 16.05 7.29
323.15 ± 0.01 18.05 6.90
323.15 ± 0.01 20.08 6.61
323.15 ± 0.01 22.07 6.21

T [K] p [MPa] D · 109 [m2/s]
313 16.0 5.54 ± 0.11
313 25.0 5.03 ± 0.13
References
2003F4 Funazukuri, T., Kong, C.Y., Kagei, S.: J. Supercrit. Fluids 27 (2003) 85–96.
2000F5 Funazukuri, T., Kong, C.Y., Murooka, N., Kagei, S.: Ind. Eng. Chem. Res. 39 (2000) 4462–4469.

Diffusion of DL-alpha-tocopherol (1); carbon dioxide (2) 1
Diffusion of DL-alpha-tocopherol (1); carbon dioxide (2)

C29H50O2 (1) DL-alpha-tocopherol 10191-41-0

T [K] p [bar] D · 109 [m2/s]
308.1 201 5.69 ± 0.16
308.1 251 4.52 ± 0.10
Reference

1
Diffusion of 2,6,10,15,19,23-hexamethyl-2,6,10,14,18,22-
tetracosahexaene (1); carbon dioxide (2)
C30H50 (1) 2,6,10,15,19,23-hexamethyl-2,6,10,14,18,22-tetracosahexaene 111-02-4

T [K] p [MPa] D · 108 [m2/s]
314.5 18 0.68 ± 6%
314.5 17 0.71 ± 6%
314.5 16 0.66 ± 6%
314.5 15 0.71 ± 6%
314.5 13 0.78 ± 6%
Reference

Diffusion of 2-methyl-3-phytyl-1,4-naphthoquinone (1); carbon dioxide (2) 1
Diffusion of 2-methyl-3-phytyl-1,4-naphthoquinone (1);

carbon dioxide (2)
C31H46O2 (1) 2-methyl-3-phytyl-1,4-naphthoquinone 84-80-0

T [K] p [MPa] D · 109 [m2/s]
313 16.0 5.43 ± 0.13
313 25.0 4.95 ± 0.16
Reference

1
Diffusion of cis-octadec-9-enoic acid propane-1,2,3-triol

diester (1); carbon dioxide (2)
C39H72O5 (1) cis-octadec-9-enoic acid propane-1,2,3-triol diester 25637-84-7

T [K] p [MPa] D · 108 [m2/s]
313.21 ± 0.01 10.00 0.658
313.21 ± 0.01 10.50 0.629
313.21 ± 0.01 11.00 0.601
313.21 ± 0.01 12.02 0.575
313.21 ± 0.01 14.00 0.534
313.21 ± 0.01 14.02 0.538
313.21 ± 0.01 16.0 0.495
313.21 ± 0.01 20.00 0.448
313.21 ± 0.01 25.01 0.420
Reference

Diffusion of beta-carotene (1); carbon dioxide (2) 1
Diffusion of beta-carotene (1); carbon dioxide (2)

C40H56 (1) beta-carotene 7235-40-7

T [K] p [MPa] D · 108 [m2/s]
308.15 9.12 0.552
308.15 9.79 0.519
308.15 10.57 0.494
308.15 10.96 0.489
308.15 12.04 0.469
308.15 13.04 0.456
308.15 14.10 0.438
308.15 16.06 0.423
308.15 16.10 0.422
308.15 16.12 0.420
308.15 16.16 0.418
308.15 18.06 0.405
308.15 20.04 0.391
308.15 22.09 0.380
308.15 24.01 0.371
308.15 26.02 0.361
308.15 28.06 0.351
308.15 30.34 0.345
313.15 10.34 0.582
313.15 11.00 0.549
313.15 12.02 0.524
313.15 16.11 0.456
313.15 16.13 0.454
313.15 16.17 0.452
313.15 16.20 0.452
313.15 17.11 0.443
313.15 17.12 0.442
313.15 17.14 0.442
313.15 17.15 0.442
313.15 20.00 0.426
313.15 22.08 0.407
313.15 24.20 0.396
313.15 25.08 0.391
313.15 25.09 0.390
313.15 25.09 0.391
313.15 26.12 0.386
313.15 28.08 0.379
313.15 30.27 0.370
323.15 12.72 0.641
323.15 13.08 0.627
(continued)
2 Diffusion of beta-carotene (1); carbon dioxide (2)
323.15 13.50 0.605

323.15 14.05 0.592
323.15 14.45 0.580
323.15 15.04 0.565
323.15 15.63 0.552
323.15 16.27 0.540
323.15 16.95 0.526
323.15 18.56 0.501
323.15 20.03 0.494
323.15 22.05 0.472
323.15 24.23 0.456
323.15 26.10 0.440
323.15 28.08 0.433
323.15 30.20 0.424
333.15 17.93 0.596
333.15 19.92 0.564
333.15 22.05 0.540
333.15 23.95 0.521
333.15 25.97 0.504
333.15 28.03 0.491
333.15 30.00 0.477
333.15 30.06 0.479
333.15 30.07 0.478

T [K] p [MPa] D · 108 [m2/s]
313.15 ± 0.01 14.05 0.488 ± 3.7%
313.15 ± 0.01 16.40 0.460 ± 3.7%
313.15 ± 0.01 18.53 0.438 ± 3.7%
313.15 ± 0.01 21.53 0.417 ± 3.7%
313.15 ± 0.01 25.67 0.394 ± 3.7%
313.15 ± 0.01 30.15 0.372 ± 3.7%

T [K] p [MPa] D · 109 [m2/s]
313.15 ± 0.01 12.18 5.20
313.15 ± 0.01 12.19 5.14
313.15 ± 0.01 13.33 5.00
313.15 ± 0.01 14.31 4.74
313.15 ± 0.01 15.24 4.65
313.15 ± 0.01 16.14 4.51
(continued)
Diffusion of beta-carotene (1); carbon dioxide (2) 3
313.15 ± 0.01 16.19 4.53

313.15 ± 0.01 17.05 4.55
313.15 ± 0.01 17.73 4.41
313.15 ± 0.01 17.89 4.46
313.15 ± 0.01 18.02 4.47
313.15 ± 0.01 18.91 4.40
313.15 ± 0.01 19.63 4.22
313.15 ± 0.01 20.02 4.29
313.15 ± 0.01 21.47 4.14
313.15 ± 0.01 21.94 3.88
313.15 ± 0.01 23.04 3.94
323.15 ± 0.01 16.04 5.41
323.15 ± 0.01 18.06 5.11
323.15 ± 0.01 20.08 4.93
323.15 ± 0.01 22.08 4.58
References
2003F4 Funazukuri, T., Kong, C.Y., Kagei, S.: J. Supercrit. Fluids 27 (2003) 85–96.
2000F5 Funazukuri, T., Kong, C.Y., Murooka, N., Kagei, S.: Ind. Eng. Chem. Res. 39 (2000) 4462–4469.

Diffusion of trilinolenin (1); carbon dioxide (2) 1
Diffusion of trilinolenin (1); carbon dioxide (2)

C57H92O6 (1) trilinolenin 14465-68-0

T [K] p [MPa] D · 109 [m2/s]
323.15 36.0 2.23 ± 0.04
323.15 36.0 2.03 ± 0.12
Reference

1
Diffusion of cis-octadec-9-enoic acid propane-1,2,3-triyl

C57H104O6 (1) cis-octadec-9-enoic acid propane-1,2,3-triyl ester 122-32-7

T [K] p [MPa] D · 108 [m2/s]
313.21 ± 0.01 9.13 0.673
313.21 ± 0.01 9.50 0.607
313.21 ± 0.01 9.51 0.611
313.21 ± 0.01 10.00 0.577
313.21 ± 0.01 11.01 0.530
313.21 ± 0.01 12.01 0.495
313.21 ± 0.01 12.01 0.497
313.21 ± 0.01 12.99 0.478
313.21 ± 0.01 13.97 0.456
313.21 ± 0.01 14.02 0.454

T [K] p [bar] D · 109 [m2/s]
298.1 201 3.48 ± 0.07
298.1 251 3.17 ± 0.24
308.1 201 4.64 ± 0.16
308.1 251 3.55 ± 0.37
References

1
Diffusion of 2,3-dimethoxy-5-methyl-6-decaprenyl-1,4-
benzoquinone (1); carbon dioxide (2)
C59H90O4 (1) 2,3-dimethoxy-5-methyl-6-decaprenyl-1,4-benzoquinone 303-98-0

T [K] p [MPa] D · 108 [m2/s]
308.15 ± 0.01 8.51 0.560 ± 3.7%
308.15 ± 0.01 8.90 0.523 ± 3.7%
308.15 ± 0.01 9.12 0.511 ± 3.7%
308.15 ± 0.01 9.20 0.506 ± 3.7%
308.15 ± 0.01 9.62 0.490 ± 3.7%
308.15 ± 0.01 9.79 0.486 ± 3.7%
308.15 ± 0.01 10.00 0.476 ± 3.7%
308.15 ± 0.01 10.52 0.461 ± 3.7%
308.15 ± 0.01 11.47 0.441 ± 3.7%
308.15 ± 0.01 12.50 0.422 ± 3.7%
308.15 ± 0.01 13.49 0.411 ± 3.7%
308.15 ± 0.01 14.55 0.400 ± 3.7%
308.15 ± 0.01 15.54 0.391 ± 3.7%
308.15 ± 0.01 16.53 0.383 ± 3.7%
308.15 ± 0.01 18.00 0.375 ± 3.7%
308.15 ± 0.01 20.00 0.366 ± 3.7%
308.15 ± 0.01 22.00 0.351 ± 3.7%
308.15 ± 0.01 24.00 0.340 ± 3.7%
308.15 ± 0.01 26.97 0.331 ± 3.7%
308.15 ± 0.01 30.05 0.322 ± 3.7%
313.15 ± 0.01 9.90 0.570 ± 3.7%
313.15 ± 0.01 10.34 0.546 ± 3.7%
313.15 ± 0.01 10.42 0.539 ± 3.7%
313.15 ± 0.01 11.38 0.502 ± 3.7%
313.15 ± 0.01 12.02 0.486 ± 3.7%
313.15 ± 0.01 13.00 0.460 ± 3.7%
313.15 ± 0.01 14.02 0.453 ± 3.7%
313.15 ± 0.01 15.05 0.432 ± 3.7%
313.15 ± 0.01 16.04 0.422 ± 3.7%
313.15 ± 0.01 17.05 0.417 ± 3.7%
313.15 ± 0.01 17.06 0.416 ± 3.7%
313.15 ± 0.01 18.32 0.406 ± 3.7%
313.15 ± 0.01 19.02 0.416 ± 3.7%
313.15 ± 0.01 20.48 0.387 ± 3.7%
313.15 ± 0.01 21.50 0.392 ± 3.7%
313.15 ± 0.01 23.00 0.371 ± 3.7%
313.15 ± 0.01 25.65 0.356 ± 3.7%
(continued)

2
313.15 ± 0.01 28.05 0.347 ± 3.7%

313.15 ± 0.01 30.02 0.339 ± 3.7%

T [K] p [MPa] D · 108 [m2/s]
323.15 ± 0.01 12.72 0.614 ± 3.7%
323.15 ± 0.01 13.08 0.588 ± 3.7%
323.15 ± 0.01 13.50 0.576 ± 3.7%
323.15 ± 0.01 14.05 0.558 ± 3.7%
323.15 ± 0.01 14.45 0.546 ± 3.7%
323.15 ± 0.01 15.04 0.544 ± 3.7%
323.15 ± 0.01 15.63 0.522 ± 3.7%
323.15 ± 0.01 16.27 0.510 ± 3.7%
323.15 ± 0.01 16.95 0.499 ± 3.7%
323.15 ± 0.01 17.97 0.485 ± 3.7%
323.15 ± 0.01 18.56 0.477 ± 3.7%
323.15 ± 0.01 19.20 0.468 ± 3.7%
323.15 ± 0.01 20.00 0.465 ± 3.7%
323.15 ± 0.01 21.02 0.451 ± 3.7%
323.15 ± 0.01 21.95 0.441 ± 3.7%
323.15 ± 0.01 22.96 0.434 ± 3.7%
323.15 ± 0.01 24.00 0.432 ± 3.7%
323.15 ± 0.01 25.03 0.429 ± 3.7%
323.15 ± 0.01 26.00 0.423 ± 3.7%
323.15 ± 0.01 26.97 0.411 ± 3.7%
323.15 ± 0.01 28.00 0.406 ± 3.7%
323.15 ± 0.01 29.98 0.401 ± 3.7%
323.15 ± 0.01 30.18 0.395 ± 3.7%
333.15 ± 0.01 16.02 0.645 ± 3.7%
333.15 ± 0.01 17.02 0.612 ± 3.7%
333.15 ± 0.01 17.95 0.597 ± 3.7%
333.15 ± 0.01 19.93 0.558 ± 3.7%
333.15 ± 0.01 22.03 0.530 ± 3.7%
333.15 ± 0.01 23.95 0.529 ± 3.7%
333.15 ± 0.01 25.97 0.498 ± 3.7%
333.15 ± 0.01 28.03 0.479 ± 3.7%
333.15 ± 0.01 30.00 0.461 ± 3.7%

T [K] p [MPa] D · 108 [m2/s]
313.15 ± 0.01 12.06 0.480 ± 3.7%
(continued)
3
313.15 ± 0.01 14.01 0.448 ± 3.7%

313.15 ± 0.01 16.05 0.421 ± 3.7%
313.15 ± 0.01 17.00 0.413 ± 3.7%
313.15 ± 0.01 20.07 0.386 ± 3.7%
313.15 ± 0.01 21.02 0.385 ± 3.7%
313.15 ± 0.01 23.13 0.373 ± 3.7%
313.15 ± 0.01 25.65 0.359 ± 3.7%
313.15 ± 0.01 30.22 0.339 ± 3.7%
References
2002F4 Funazukuri, T., Kong, C.Y., Kagei, S.: Ind. Eng. Chem. Res. 41 (2002) 2812–2818.

1
Diffusion of 1,2,3-tri-[(cis,cis,cis,cis)-5,8,11,14-
eicosatetraenoyl]-glycerol (1); carbon dioxide (2)
C63H98O6 (1) 1,2,3-tri-[(cis,cis,cis,cis)-5,8,11,14- eicosatetraenoyl]-glycerol 23314-57-0

T [K] p [MPa] D · 109 [m2/s]
313.21 ± 0.1 9.95 5.464
313.21 ± 0.1 9.98 5.426
313.21 ± 0.1 10.00 5.418
313.21 ± 0.1 10.45 5.231
313.21 ± 0.1 10.84 5.071
313.21 ± 0.1 10.91 5.061
313.21 ± 0.1 11.00 5.082
313.21 ± 0.1 12.00 4.747
313.21 ± 0.1 12.00 4.771
313.21 ± 0.1 13.01 4.612
313.21 ± 0.1 15.98 4.246
313.21 ± 0.1 16.00 4.247
313.21 ± 0.1 16.00 4.253
313.21 ± 0.1 16.00 4.251
313.21 ± 0.1 17.99 4.077
313.21 ± 0.1 20.03 3.960
313.21 ± 0.1 21.00 3.901
313.21 ± 0.1 22.00 3.864
313.21 ± 0.1 23.03 3.788
313.21 ± 0.1 23.98 3.817
313.21 ± 0.1 26.00 3.749
313.21 ± 0.1 26.02 3.728
313.21 ± 0.1 26.05 3.694
313.21 ± 0.1 26.99 3.608
313.21 ± 0.1 28.01 3.596
313.21 ± 0.1 29.09 3.602
313.21 ± 0.1 30.24 3.568
Comment: poly(ethylene glycol) coated capillary column; uncertainty in D range from ± 4% to ± 2%
Reference
2005K1 Kong, C.Y., Withanage, N.R.W., Funazukuri, T., Kagei, S.: J. Chem. Eng. Data 50 (2005)
1635–1640.

Diffusion of 1,2,3-tri-[(cis)-13-docosenoyl]-glycerol (1); carbon dioxide (2) 1
Diffusion of 1,2,3-tri-[(cis)-13-docosenoyl]-glycerol (1);

carbon dioxide (2)
C69H128O6 (1) 1,2,3-tri-[(cis)-13-docosenoyl]-glycerol 2752-99-0

T [K] p [MPa] D · 109 [m2/s]
308.15 ± 0.1 8.26 5.155
308.15 ± 0.1 8.30 4.986
308.15 ± 0.1 8.46 4.726
308.15 ± 0.1 8.48 4.700
308.15 ± 0.1 8.50 4.744
308.15 ± 0.1 8.66 4.553
308.15 ± 0.1 8.80 4.483
308.15 ± 0.1 8.85 4.447
308.15 ± 0.1 8.98 4.470
308.15 ± 0.1 9.05 4.355
308.15 ± 0.1 9.10 4.360
308.15 ± 0.1 9.11 4.507
308.15 ± 0.1 9.11 4.383
308.15 ± 0.1 9.20 4.365
308.15 ± 0.1 9.31 4.350
308.15 ± 0.1 9.40 4.290
308.15 ± 0.1 9.40 4.305
308.15 ± 0.1 9.50 4.275
308.15 ± 0.1 9.51 4.377
308.15 ± 0.1 9.60 4.277
308.15 ± 0.1 10.00 4.205
308.15 ± 0.1 10.01 4.241
308.15 ± 0.1 10.51 4.141
308.15 ± 0.1 11.00 4.001
308.15 ± 0.1 11.00 4.037
308.15 ± 0.1 11.00 4.047
308.15 ± 0.1 11.51 3.962
308.15 ± 0.1 12.01 3.951
308.15 ± 0.1 12.50 3.852
308.15 ± 0.1 13.01 3.821
308.15 ± 0.1 14.01 3.729
308.15 ± 0.1 14.99 3.653
308.15 ± 0.1 16.00 3.588
308.15 ± 0.1 16.02 3.580
308.15 ± 0.1 17.52 3.501
308.15 ± 0.1 19.98 3.350
308.15 ± 0.1 23.01 3.225
308.15 ± 0.1 25.01 3.148
(continued)

2 Diffusion of 1,2,3-tri-[(cis)-13-docosenoyl]-glycerol (1); carbon dioxide (2)
308.15 ± 0.1 26.45 3.082

308.15 ± 0.1 27.03 3.065
308.15 ± 0.1 30.02 2.991
Comment: poly(ethylene glycol) coated capillary column; uncertainty in D range from ±4% to ±2%

T [K] p [MPa] D · 109 [m2/s]
313.21 ± 0.1 9.50 4.904
313.21 ± 0.1 9.51 4.922
313.21 ± 0.1 9.55 5.096
313.21 ± 0.1 9.57 4.844
313.21 ± 0.1 9.70 4.823
313.21 ± 0.1 9.84 4.777
313.21 ± 0.1 9.98 4.694
313.21 ± 0.1 10.00 4.651
313.21 ± 0.1 10.00 4.736
313.21 ± 0.1 10.05 4.868
313.21 ± 0.1 10.51 4.599
313.21 ± 0.1 11.00 4.572
313.21 ± 0.1 11.03 4.492
313.21 ± 0.1 11.09 4.445
313.21 ± 0.1 11.50 4.375
313.21 ± 0.1 12.00 4.307
313.21 ± 0.1 13.02 4.131
313.21 ± 0.1 13.50 4.088
313.21 ± 0.1 14.00 4.022
313.21 ± 0.1 14.50 3.996
313.21 ± 0.1 15.00 3.943
313.21 ± 0.1 15.52 3.904
313.21 ± 0.1 15.53 3.920
313.21 ± 0.1 15.97 3.884
313.21 ± 0.1 15.99 3.887
313.21 ± 0.1 16.00 3.883
313.21 ± 0.1 16.02 3.891
313.21 ± 0.1 16.96 3.791
313.21 ± 0.1 21.00 3.564
313.21 ± 0.1 24.95 3.368
313.21 ± 0.1 25.05 3.343
313.21 ± 0.1 27.00 3.287
313.21 ± 0.1 30.06 3.153

Diffusion of 1,2,3-tri-[(cis)-13-docosenoyl]-glycerol (1); carbon dioxide (2) 3

T [K] p [MPa] D · 109 [m2/s]
323.15 ± 0.1 11.98 5.287
323.15 ± 0.1 12.03 5.309
323.15 ± 0.1 12.50 5.120
323.15 ± 0.1 12.99 5.011
323.15 ± 0.1 13.00 5.040
323.15 ± 0.1 13.05 5.050
323.15 ± 0.1 13.31 4.975
323.15 ± 0.1 13.49 4.943
323.15 ± 0.1 14.00 4.804
323.15 ± 0.1 14.00 4.829
323.15 ± 0.1 14.53 4.722
323.15 ± 0.1 15.00 4.637
323.15 ± 0.1 15.03 4.603
323.15 ± 0.1 15.03 4.622
323.15 ± 0.1 15.52 4.560
323.15 ± 0.1 16.00 4.495
323.15 ± 0.1 16.51 4.470
323.15 ± 0.1 16.54 4.422
323.15 ± 0.1 17.00 4.409
323.15 ± 0.1 18.00 4.267
323.15 ± 0.1 18.50 4.239
323.15 ± 0.1 20.00 4.110
323.15 ± 0.1 22.01 3.978
323.15 ± 0.1 22.04 3.995
323.15 ± 0.1 24.99 3.819
323.15 ± 0.1 27.02 3.709
323.15 ± 0.1 30.03 3.603
Reference
1635–1640.

Diffusion of 1,2,3-tri-[(cis)-15-tetracosenoyl]-glycerol (1); carbon dioxide (2) 1
Diffusion of 1,2,3-tri-[(cis)-15-tetracosenoyl]-glycerol (1);

carbon dioxide (2)
C75H140O6 (1) 1,2,3-tri-[(cis)-15-tetracosenoyl]-glycerol 81913-24-8

T [K] p [MPa] D · 109 [m2/s]
308.15 ± 0.1 9.00 4.294
308.15 ± 0.1 10.00 3.961
308.15 ± 0.1 10.00 4.063
308.15 ± 0.1 10.02 4.032
308.15 ± 0.1 11.00 3.919
308.15 ± 0.1 11.01 3.866
308.15 ± 0.1 12.00 3.774
308.15 ± 0.1 12.49 3.706
308.15 ± 0.1 16.01 3.447
308.15 ± 0.1 20.00 3.258
308.15 ± 0.1 30.02 2.777
308.15 ± 0.1 30.03 2.806
313.15 ± 0.1 9.61 4.762
313.15 ± 0.1 9.70 4.689
313.15 ± 0.1 10.02 4.546
313.15 ± 0.1 10.48 4.429
313.15 ± 0.1 10.50 4.410
313.15 ± 0.1 11.00 4.331
313.15 ± 0.1 11.03 4.309
313.15 ± 0.1 11.50 4.199
313.15 ± 0.1 11.51 4.208
313.15 ± 0.1 14.00 3.892
313.15 ± 0.1 16.01 3.748
313.15 ± 0.1 20.00 3.459
313.15 ± 0.1 25.00 3.252
313.15 ± 0.1 30.05 3.113
323.15 ± 0.1 12.50 4.913
323.15 ± 0.1 13.00 4.848
323.15 ± 0.1 14.00 4.570
323.15 ± 0.1 15.01 4.456
323.15 ± 0.1 16.03 4.298
323.15 ± 0.1 16.98 4.260
323.15 ± 0.1 16.98 4.285
323.15 ± 0.1 17.04 4.299
323.15 ± 0.1 20.00 3.997
(continued)

2 Diffusion of 1,2,3-tri-[(cis)-15-tetracosenoyl]-glycerol (1); carbon dioxide (2)
323.15 ± 0.1 20.00 3.978

323.15 ± 0.1 25.04 3.695
323.15 ± 0.1 30.02 3.461
Reference
1635–1640.

Diffusion of air (1); formic acid methyl ester (2) 1
Diffusion of air (1); formic acid methyl ester (2)

Vapor in Liquid
Air (1) air 132259-10-0

C2H4O2 (2) formic acid methyl ester 107-31-3
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: STEFAN Ref.: 1997S4
T [K] p [kPa] D · 109 [m2/s]
298.55 101.325 1.020
298.55 101.325 1.022
273.15 101.325 0.872
Reference
1997S4 Slattery, J.C., Mhetar, V.R.: Chem. Eng. Sci. 52 (1997) 1511–1515.

Diffusion of air (1); furan (2) 1
Diffusion of air (1); furan (2)

Vapor in Liquid
Air (1) air 132259-10-0

C4H4O (2) furan 110-00-9
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: STEFAN Ref.: 1980B9
T [K] p [kPa] D · 104 [m2/s]
288.15 ± 0.1 101.325 0.0997 ± 1%
293.15 ± 0.1 101.325 0.1044 ± 1%
298.15 ± 0.1 101.325 0.1107 ± 1%
Reference
1980B9 Bueno, J.L., Coca, J., Alvarez, R., Villanueva, A.F.: J. Chem. Eng. Data 25 (1980) 27–28.

Diffusion of air (1); tetrahydrofuran (2) 1
Diffusion of air (1); tetrahydrofuran (2)

Vapor in Liquid
Air (1) air 132259-10-0

T [K] p [kPa] D · 104 [m2/s]
307.15 ± 0.1 101.325 0.1058 ± 1%
315.15 ± 0.1 101.325 0.1108 ± 1%
328.15 ± 0.1 101.325 0.1200 ± 1%
Reference

Diffusion of air (1); furfural (2) 1
Diffusion of air (1); furfural (2)

Vapor in Liquid
Air (1) air 132259-10-0

C5H4O2 (2) furfural 98-01-1
T [K] p [kPa] D · 104 [m2/s]
398.15 ± 0.1 101.325 0.1765 ± 1%
412.15 ± 0.1 101.325 0.1778 ± 1%
424.15 ± 0.1 101.325 0.1835 ± 1%
Reference

Diffusion of air (1); 2-methyl-furan (2) 1
Diffusion of air (1); 2-methyl-furan (2)

Vapor in Liquid
Air (1) air 132259-10-0

C5H6O (2) 2-methyl-furan 534-22-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: STEFAN Ref.: 1983A2
T [K] p [kPa] D · 104 [m2/s]
288.15 101.325 0.0786
293.15 101.325 0.0813
298.15 101.325 0.0841
322.15 101.325 0.0981
329.65 101.325 0.1027
334.15 101.325 0.1055
Reference
1983A2 Alvarez, R., Medina, I., Bueno, J.L., Coca, J.: J. Chem. Eng. Data 28 (1983) 155–156.

Diffusion of air (1); furan-2-yl-methanethiol (2) 1
Diffusion of air (1); furan-2-yl-methanethiol (2)

Vapor in Liquid
Air (1) air 132259-10-0

C5H6OS (2) furan-2-yl-methanethiol 98-02-2
T [K] p [kPa] D · 104 [m2/s]
398.15 ± 0.1 101.325 0.1189 ± 1%
412.15 ± 0.1 101.325 0.1269 ± 1%
424.15 ± 0.1 101.325 0.1409 ± 1%
Reference

Diffusion of air (1); 2-methyl-tetrahydro-furan (2) 1
Diffusion of air (1); 2-methyl-tetrahydro-furan (2)

Vapor in Liquid
Air (1) air 132259-10-0

C5H10O (2) 2-methyl-tetrahydro-furan 96-47-9
T [K] p [kPa] D · 104 [m2/s]
288.15 101.325 0.0801
293.15 101.325 0.0828
298.15 101.325 0.0825
322.15 101.325 0.0992
334.15 101.325 0.1067
344.85 101.325 0.1131
Reference

Diffusion of air (1); tetrahydrofuran-2-yl-methanol (2) 1
Diffusion of air (1); tetrahydrofuran-2-yl-methanol (2)

Vapor in Liquid
Air (1) air 132259-10-0

C5H10O2 (2) tetrahydrofuran-2-yl-methanol 97-99-4
T [K] p [kPa] D · 104 [m2/s]
398.15 ± 0.1 101.325 0.1275 ± 1%
412.15 ± 0.1 101.325 0.1316 ± 1%
424.15 ± 0.1 101.325 0.1356 ± 1%
Reference

Diffusion of air (1); 2,5-dimethyl-furan (2) 1
Diffusion of air (1); 2,5-dimethyl-furan (2)

Vapor in Liquid
Air (1) air 132259-10-0

C6H8O (2) 2,5-dimethyl-furan 625-86-5
T [K] p [kPa] D · 104 [m2/s]
288.15 101.325 0.0666
293.15 101.325 0.0689
298.15 101.325 0.0712
322.15 101.325 0.0825
338.15 101.325 0.0912
353.15 101.325 0.0985
Reference

Diffusion of air (1); 2,5-dimethyl-tetrahydro-furan (2) 1
Diffusion of air (1); 2,5-dimethyl-tetrahydro-furan (2)

Vapor in Liquid
Air (1) air 132259-10-0

C6H12O (2) 2,5-dimethyl-tetrahydro-furan 1003-38-9
T [K] p [kPa] D · 104 [m2/s]
288.15 101.325 0.0533
293.15 101.325 0.0552
298.15 101.325 0.0571
322.15 101.325 0.0666
338.15 101.325 0.0734
353.15 101.325 0.0800
Reference


Vapor in Liquid
Air (1) air 132259-10-0

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: BUBBLE Ref.: 1966W3
T [K] p [kPa] D · 109 [m2/s]
283.15 ± 0.1 101.325 2.0
293.15 ± 0.1 101.325 2.5
303.15 ± 0.1 101.325 3.2
313.15 ± 0.1 101.325 4.0
323.15 ± 0.1 101.325 4.9
333.15 ± 0.1 101.325 6.3
Air (1) air 132259-10-0

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: BUBBLE Ref.: 1981Z1
T [K] p [Torr] D · 109 [m2/s]
298.15 720 2.2
Air (1) air 132259-10-0

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: BUBBLE Ref.: 1962H3
T [K] p [kPa] D · 109 [m2/s]
292.75 101.325 2.3 ± 10%
Air (1) air 132259-10-0

H 2O (2) water 7732-18-5
Equation: D = A · exp[ B / RT ] Range: 283 < T/K < 333
4.1 4310 *
Comment: *: B in [cal/mol]
References
1966W3 Wise, D.L., Houghton, G.: Chem. Eng. Science 21 (1966) 999–1010.
1981Z1 Zurita, J.L., Sosa, A.B.A., Postigo, M.A., Katz, M.: An. Asoc. Quim. Argent. 69 (1981)
239–246.
1962H3 Houghton, G., Ritchi, P.D., Thomson, J.A.: Chem. Eng. Science 17 (1962) 221–227.

Diffusion of argon (1); tetrachloro-methane (2) 1
Diffusion of argon (1); tetrachloro-methane (2)

Vapor in Liquid
Ar (1) argon 7440-37-1

Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: OTE Ref.: 1987C1
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 3.11 ± 0.25 *
298.15 101.325 3.27 ± 0.13 **
298.15 101.325 3.46 ± 0.29 ***
Comment: *: open tube apparatus; **: capillary method; ***: combined measurements
Ar (1) argon 7440-37-1

Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: DIA Ref.: 1974H4
T [K] p [kPa] D · 109 [m2/s]
278.15 101.325 3.10
298.15 101.325 4.85
Ar (1) argon 7440-37-1

Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: OEC Ref.: 1968B7
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.01 101.325 3.71
298.15 ± 0.01 101.325 3.73
Ar (1) argon 7440-37-1

Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: DIA Ref.: 1964R3
T [K] p [kPa] D · 109 [m2/s]
273.15 101.325 2.44 ± 5%
298.15 101.325 3.63 ± 5%
Ar (1) argon 7440-37-1

Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: DIA Ref.: 1965N1
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 3.63
Comment: mole fraction x1 = 13.44 · 10–4

2 Diffusion of argon (1); tetrachloro-methane (2)
Ar (1) argon 7440-37-1

Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: TAYLOR Ref.: 1981E2
T [K] p [atm] D · 109 [m2/s]
298.15 3 3.79 ± 0.12
References
1987C1 Combs, R.J., Field, P.E.: J. Phys. Chem. 91 (1987) 1663–1668.
1974H4 Hildebrand, J.H., Lamoreaux, R.H.: Proc. Natl. Acad. Sci. USA 71 (1974) 3321–3324.
1968B7 Bennett, L., Ng, W.Y., Walkley, J.: J. Phys. Chem. 72 (1968) 4699–4700.
1964R3 Ross, M., Hildebrandt, J.H.: J. Chem. Phys. 40 (1964) 2397–2399.
1965N1 Nakanishi, K., Voigt, E.M., Hildebrand, J.H.: J. Chem. Phys. 42 (1965) 1860–1863.
1981E2 Evans, D.F., Tominaga, T., Davis, H.T.: J. Chem. Phys. 74 (1981) 1298–1305.

Diffusion of argon (1); methanol (2) 1
Diffusion of argon (1); methanol (2)

Vapor in Liquid
Ar (1) argon 7440-37-1

Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: TAYLOR Ref.: 1983C5
T [K] p [kPa] D · 109 [m2/s]
298 101.325 6.43 ± 0.004
313 101.325 7.6 ± 0.01
333 101.325 9.4 ± 0.01
383 101.325 15.3 ± 0.01
Comment: precision: ±1%
Ar (1) argon 7440-37-1

Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: CORR Ref.: 1985C7
3.477 6917
Comment: D = (D/T ) in [m2/s/K]; A in [m2/s/K]; B in [kJ/kg-mol]
References
1983C5 Chen, S.-H., Evans, D.F., Davis, H.T.: AIChE J. 29 (1983) 640–645.
1985C7 Chen, H.C., Chen, S.H.: Ind. Eng. Chem. Fundam. 24 (1985) 187–192.

Diffusion of argon (1); succinonitrile (2) 1
Diffusion of argon (1); succinonitrile (2)

Vapor in Liquid
Ar (1) argon 7440-37-1

C4H4N2 (2) succinonitrile 110-61-2
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: DIA Ref.: 1988C1
T [K] p [kPa] D · 1010 [m2/s]
331.08 ± 0.1 101.325 8.80
Reference
1988C1 Chopra, M.A., Glicksman, M.E., Singh, N.B.: J. Cryst. Growth 92 (1988) 543–546.

Diffusion of argon (1); butan-1-ol (2) 1
Diffusion of argon (1); butan-1-ol (2)

Vapor in Liquid
Ar (1) argon 7440-37-1

C4H10O (2) butan-1-ol 71-36-3
T [K] p [kPa] D · 109 [m2/s]
298 101.325 3.31 ± 0.001
333 101.325 5.38 ± 0.002
373 101.325 9.2 ± 0.01
433 101.325 17.2 ± 0.01
Ar (1) argon 7440-37-1

C4H10O (2) butan-1-ol 71-36-3
T [K] p [atm] D · 109 [m2/s]
298.15 3 3.44 ± 0.10
Ar (1) argon 7440-37-1

C4H10O (2) butan-1-ol 71-36-3
6.656 10210
References


Vapor in Liquid
Ar (1) argon 7440-37-1

C6H6 (2) benzene 71-43-2
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 6.65 ± 0.42 *
298.15 101.325 7.55 ± 0.51 **
298.15 101.325 8.70 ± 0.93 ***
Ar (1) argon 7440-37-1

C6H6 (2) benzene 71-43-2
T [K] p [atm] D · 109 [m2/s]
298.15 3 5.44 ± 0.10
Ar (1) argon 7440-37-1

C6H6 (2) benzene 71-43-2
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: DIA Ref.: 1968B7
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.01 101.325 11.2
References

Diffusion of argon (1); cyclohexane (2) 1
Diffusion of argon (1); cyclohexane (2)

Vapor in Liquid
Ar (1) argon 7440-37-1

T [K] p [atm] D · 109 [m2/s]
298.15 3 4.73 ± 0.10
Ar (1) argon 7440-37-1

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 4.7 ± 0.01
313.25 101.325 6.2 ± 0.01
333.35 101.325 8.2 ± 0.01
353.75 101.325 10.0 ± 0.01
374.05 101.325 12.4 ± 0.03
390.85 101.325 14.5 ± 0.03
415.85 101.325 17.0 ± 0.02
Comment: uncertainty: ±1% (less than ±3%)
Ar (1) argon 7440-37-1

4.651 8265
References
1981C2 Chen, S.H., Davis, H.T., Evans, D.F.: J. Chem. Phys. 75 (1981) 1422–1426.

Diffusion of argon (1); cyclohexanol (2) 1
Diffusion of argon (1); cyclohexanol (2)

Vapor in Liquid
Ar (1) argon 7440-37-1

C6H12O (2) cyclohexanol 108-93-0
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: KMD Ref.: 1974P2
T [K] p [kPa] D · 109 [m2/s]
303.15 101.325 0.80 ± 0.03
Comment: data are generally higher than literature values
Reference
1974P2 Pfeiffer, W.F., Krieger, I.M.: J. Phys. Chem. 78 (1974) 2516–2521.

Diffusion of argon (1); hexane (2) 1
Diffusion of argon (1); hexane (2)

Vapor in Liquid
Ar (1) argon 7440-37-1

C6H14 (2) hexane 110-54-3
T [K] p [atm] D · 109 [m2/s]
298.15 3 8.5 ± 0.2
Reference

Diffusion of argon (1); octane (2) 1
Diffusion of argon (1); octane (2)

Vapor in Liquid
Ar (1) argon 7440-37-1

C8H18 (2) octane 111-65-9
T [K] p [kPa] D · 109 [m2/s]
298 101.325 6.68 ± 0.003
333 101.325 9.9 ± 0.01
373 101.325 14.46 ± 0.004
403 101.325 18.0 ± 0.02
Ar (1) argon 7440-37-1

C8H18 (2) octane 111-65-9
3.226 6607
References
1982C1 Chen, S.-H., Davis, H.T., Evans, D.F.: J. Chem. Phys. 77 (1982) 2540–2544.

Diffusion of argon (1); octan-1-ol (2) 1
Diffusion of argon (1); octan-1-ol (2)

Vapor in Liquid
Ar (1) argon 7440-37-1

C8H18O (2) octan-1-ol 111-87-5
T [K] p [kPa] D · 109 [m2/s]
298 101.325 1.86 ± 0.001
313 101.325 2.48 ± 0.006
353 101.325 4.87 ± 0.004
391 101.325 7.8 ± 0.01
430 101.325 11.4 ± 0.02
Ar (1) argon 7440-37-1

C8H18O (2) octan-1-ol 111-87-5
T [K] p [atm] D · 109 [m2/s]
298.15 3 1.86 ± 0.05
Ar (1) argon 7440-37-1

C8H18O (2) octan-1-ol 111-87-5
7.376 11800
References

Diffusion of argon (1); decane (2) 1
Diffusion of argon (1); decane (2)

Vapor in Liquid
Ar (1) argon 7440-37-1

C10H22 (2) decane 124-18-5
T [K] p [kPa] D · 109 [m2/s]
298 101.325 4.87 ± 0.007
333 101.325 7.72 ± 0.007
433 101.325 19.3 ± 0.02
Ar (1) argon 7440-37-1

C10H22 (2) decane 124-18-5
T [K] p [atm] D · 109 [m2/s]
298.15 3 4.87 ± 0.07
Ar (1) argon 7440-37-1

C10H22 (2) decane 124-18-5
4.075 7959
References

Diffusion of argon (1); tris-nonafluorobutyl-amine (2) 1
Diffusion of argon (1); tris-nonafluorobutyl-amine (2)

Vapor in Liquid
Ar (1) argon 7440-37-1

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 2.75
Ar (1) argon 7440-37-1

T [K] p [kPa] D · 109 [m2/s]
278.15 101.325 2.20
288.15 101.325 2.50
298.15 101.325 6.21 *
308.15 101.325 4.20
Comment: *: probably not correct
References

Diffusion of argon (1); tetradecane (2) 1
Diffusion of argon (1); tetradecane (2)

Vapor in Liquid
Ar (1) argon 7440-37-1

T [K] p [kPa] D · 109 [m2/s]
298 101.325 3.40 ± 0.007
343 101.325 6.16 ± 0.007
374 101.325 8.35 ± 0.009
430 101.325 13.6 ± 0.02
Ar (1) argon 7440-37-1

T [K] p [atm] D · 109 [m2/s]
298.15 3 3.40 ± 0.07
Ar (1) argon 7440-37-1

3.181 8248
References

Diffusion of argon (1); tetrabutyl-stannane (2) 1
Diffusion of argon (1); tetrabutyl-stannane (2)

Vapor in Liquid
Ar (1) argon 7440-37-1

C16H36Sn (2) tetrabutyl-stannane 1461-25-2
T [K] p [atm] D · 109 [m2/s]
298.15 3 2.35 ± 0.15
Reference

Diffusion of argon (1); water (2) 1
Diffusion of argon (1); water (2)

Vapor in Liquid
Ar (1) argon 7440-37-1

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: LAM Ref.: 1962B1
T [K] p [kPa] D · 109 [m2/s]
288.15 101.325 1.43
288.15 101.325 1.79 *
293.15 101.325 1.68
293.15 101.325 1.94 *
298.15 101.325 1.92
298.15 101.325 2.02 *
Comment: *: wetted sphere measurements
Ar (1) argon 7440-37-1

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: DIA Ref.: 1978T1
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.05 101.325 2.22 ± 4%
Ar (1) argon 7440-37-1

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: CC Ref.: 1969B9
T [K] p [kPa] D · 109 [m2/s]
273.15 ± 0.1 101.325 0.633 ± 5%
298.15 ± 0.1 101.325 0.784 ± 5%
323.15 ± 0.1 101.325 1.32 ± 5%
Ar (1) argon 7440-37-1

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: OEC Ref.: 1973M1
T [K] p [kPa] D · 109 [m2/s]
273 ± 0.01 101.325 0.72
278 ± 0.01 101.325 0.85
283 ± 0.01 101.325 0.97
288 ± 0.01 101.325 1.09
293 ± 0.01 101.325 1.23
298 ± 0.01 101.325 1.44
303 ± 0.01 101.325 1.65
308 ± 0.01 101.325 1.82

2 Diffusion of argon (1); water (2)
Ar (1) argon 7440-37-1

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: No Info Ref.: 1964H2
T [K] p [kPa] D · 109 [m2/s]
294.85 101.325 2.0 ± 10%
298.15 101.325 1.46 ± 10%
Ar (1) argon 7440-37-1

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
283.15 ± 0.1 101.325 1.7
293.15 ± 0.1 101.325 2.3
303.15 ± 0.1 101.325 2.7
313.15 ± 0.1 101.325 3.8
323.15 ± 0.1 101.325 4.8
333.15 ± 0.1 101.325 6.7
Ar (1) argon 7440-37-1

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
303.15 101.325 3.1 ± 0.3
Ar (1) argon 7440-37-1

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
294.85 101.325 2.0 ± 10%
Ar (1) argon 7440-37-1

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: LAM Ref.: 1968D4
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.01 101.325 2.00
Comment: error about ±(10–15)%

Diffusion of argon (1); water (2) 3
Ar (1) argon 7440-37-1

H 2O (2) water 7732-18-5
10.6 4930 *
Ar (1) argon 7440-37-1

H 2O (2) water 7732-18-5
Diffusion of solute(1)
in liquid(2): D*1(2)(T ); Method: OEC Ref.: 1973M1
Equation: ln D = A – B / ( T – C ) Range: 273 < T/K < 308
Parameter: A B · 10–3 C
–3.6443 2.236 0.0
Comment: D*1(2) [m2/s] = D · 10–4
References
1962B1 Baird, M.H., Davidson, J.F.: Chem. Eng. Science 17 (1962) 473–480.
1978T1 Taira, Y., Matsuda, K., Nakanishi, K.: Bull. Chem. Soc. Jpn. 51 (1978) 1639–1643.
1969B9 Boerboom, A.J.H., Kleyn, G.: J. Chem. Phys. 50 (1969) 1086–1088.
1973M1 Maharajh, D.M., Walkley, J.: Can. J. Chem. 51 (1973) 944–952.
1964H2 Himmelblau, D.M.: Chem. Rev. 64 (1964) 527–550.
1968D4 Duda, J.L., Vrentas, J.S.: AIChE J. 14 (1968) 286–294.


Vapor in Liquid
Ar (1) argon 7440-37-1

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 109 [m2/s]
75.62 101.325 2.41
75.52 101.325 2.26
74.74 101.325 2.38
74.73 101.325 2.00
71.47 101.325 2.10
70.18 101.325 1.75
68.94 101.325 1.59
66.94 101.325 1.57
Reference

Diffusion of dichloro-difluoro-methane (1); water (2) 1
Diffusion of dichloro-difluoro-methane (1); water (2)

Vapor in Liquid

H 2O (2) water 7732-18-5
T [K] p [Torr] D · 109 [m2/s]
298.15 720 1.10
Reference
239–246.

Diffusion of tetrafluoro-methane (1); tetrachloro-methane (2) 1
Diffusion of tetrafluoro-methane (1); tetrachloro-methane

(2)
Vapor in Liquid

T [K] p [kPa] D · 109 [m2/s]
278.15 101.325 1.65
298.15 101.325 2.50

T [K] p [kPa] D · 109 [m2/s]
273.15 101.325 1.44 ± 5%
298.15 101.325 2.04 ± 5%

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 2.04
References

Diffusion of tetrafluoro-methane (1); benzene (2) 1
Diffusion of tetrafluoro-methane (1); benzene (2)

Vapor in Liquid

C6H6 (2) benzene 71-43-2
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: STEFAN Ref.: 1974W6
T [K] p [kPa] D · 104 [m2/s]
283.15 ± 0.002 101.325 0.0456
298.15 ± 0.002 101.325 0.0494
313.15 ± 0.002 101.325 0.0554
328.15 ± 0.002 101.325 0.0597
343.15 ± 0.002 101.325 0.0647
Comment: overall precision: ±1%

C6H6 (2) benzene 71-43-2
in liquid(2): D*1(2)(T ); Method: STEFAN Ref.: 1974W6
Equation: log D = log A + B · log T Range: 283 < T/K < 343
Parameter: A · 106 B Std-Dev.
1.3729 1.8435 0.0005
Reference
1974W6 Wilhelm, E., Battino, R., Carpenter, R.L.: J. Chem. Eng. Data 19 (1974) 245–247.

Diffusion of tetrafluoro-methane (1); cyclohexane (2) 1
Diffusion of tetrafluoro-methane (1); cyclohexane (2)

Vapor in Liquid

T [K] p [kPa] D · 104 [m2/s]
283.15 ± 0.002 101.325 0.0406
298.15 ± 0.002 101.325 0.0444
313.15 ± 0.002 101.325 0.0491
328.15 ± 0.002 101.325 0.0529
343.15 ± 0.002 101.325 0.0574

1.4946 1.8083 0.0002
Reference

Diffusion of tetrafluoro-methane (1); hexane (2) 1
Diffusion of tetrafluoro-methane (1); hexane (2)

Vapor in Liquid

C6H14 (2) hexane 110-54-3
T [K] p [kPa] D · 104 [m2/s]
283.15 ± 0.002 101.325 0.0388
298.15 ± 0.002 101.325 0.0429
313.15 ± 0.002 101.325 0.0485
328.15 ± 0.002 101.325 0.0522
Comment: overall precision: ±1%; corrected values for 1 atm are given in [1973W3]
References
1973W3 Wilhelm, E., Battino, R.: J. Chem. Eng. Data 18 (1973) 450.

Diffusion of tetrafluoro-methane (1); toluene (2) 1
Diffusion of tetrafluoro-methane (1); toluene (2)

Vapor in Liquid

C7H8 (2) toluene 108-88-3
T [K] p [kPa] D · 104 [m2/s]
283.15 ± 0.002 101.325 0.0387
298.15 ± 0.002 101.325 0.0435
313.15 ± 0.002 101.325 0.0481
328.15 ± 0.002 101.325 0.0526
343.15 ± 0.002 101.325 0.0578

C7H8 (2) toluene 108-88-3
0.35159 2.0572 0.0002
Reference

Diffusion of tetrafluoro-methane (1); methyl-cyclohexane (2) 1
Diffusion of tetrafluoro-methane (1); methyl-cyclohexane

(2)
Vapor in Liquid

T [K] p [kPa] D · 104 [m2/s]
283.15 ± 0.002 101.325 0.0341
298.15 ± 0.002 101.325 0.0384
313.15 ± 0.002 101.325 0.0443
328.15 ± 0.002 101.325 0.0475
343.15 ± 0.002 101.325 0.0516

0.16156 2.1734 0.0006
Reference

Diffusion of tetrafluoro-methane (1); heptane (2) 1
Diffusion of tetrafluoro-methane (1); heptane (2)

Vapor in Liquid

C7H16 (2) heptane 142-82-5
T [K] p [kPa] D · 104 [m2/s]
283.15 ± 0.002 101.325 0.0375
298.15 ± 0.002 101.325 0.0382
313.15 ± 0.002 101.325 0.0428
328.15 ± 0.002 101.325 0.0470
343.15 ± 0.002 101.325 0.0508
References

Diffusion of tetrafluoro-methane (1); octane (2) 1
Diffusion of tetrafluoro-methane (1); octane (2)

Vapor in Liquid

C8H18 (2) octane 111-65-9
T [K] p [kPa] D · 104 [m2/s]
283.15 ± 0.002 101.325 0.0274 ± 7%
298.15 ± 0.002 101.325 0.0356
313.15 ± 0.002 101.325 0.0422
328.15 ± 0.002 101.325 0.0435
343.15 ± 0.002 101.325 0.0467
References

Diffusion of tetrafluoro-methane (1); 2,2,4-trimethyl-pentane (2) 1
Diffusion of tetrafluoro-methane (1); 2,2,4-trimethyl-

pentane (2)
Vapor in Liquid

T [K] p [kPa] D · 104 [m2/s]
283.15 ± 0.002 101.325 0.0371
298.15 ± 0.002 101.325 0.0359
313.15 ± 0.002 101.325 0.0393
328.15 ± 0.002 101.325 0.0430
343.15 ± 0.002 101.325 0.0456
References

Diffusion of tetrafluoro-methane (1); tris-nonafluorobutyl-amine (2) 1
Diffusion of tetrafluoro-methane (1); tris-nonafluorobutyl-

amine (2)
Vapor in Liquid

T [K] p [kPa] D · 109 [m2/s]
278.15 101.325 1.13
288.15 101.325 1.50
298.15 101.325 2.15
308.15 101.325 3.04
308.15 101.325 3.07
Reference

Diffusion of dichloro-fluoro-methane (1); water (2) 1
Diffusion of dichloro-fluoro-methane (1); water (2)

Vapor in Liquid
CHCl2F (1) dichloro-fluoro-methane 75-43-4

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
283 ± 0.01 101.325 0.98
288 ± 0.01 101.325 1.20
293 ± 0.01 101.325 1.50
298 ± 0.01 101.325 1.80
303 ± 0.01 101.325 2.20
308 ± 0.01 101.325 2.60
CHCl2F (1) dichloro-fluoro-methane 75-43-4

H 2O (2) water 7732-18-5
0.5389 3.419 0.0
Comment: D*1(2) [m2/s] = D · 10–4
Reference

Diffusion of bromo-methane (1); water (2) 1
Diffusion of bromo-methane (1); water (2)

Vapor in Liquid
CH3Br (1) bromo-methane 74-83-9

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
283 ± 0.01 101.325 0.85
288 ± 0.01 101.325 1.03
293 ± 0.01 101.325 1.16
298 ± 0.01 101.325 1.35
303 ± 0.01 101.325 1.64
308 ± 0.01 101.325 2.00
CH3Br (1) bromo-methane 74-83-9

H 2O (2) water 7732-18-5
–3.4027 2.337 0.0
Comment: D*1(2) [m2/s] = D · 10–4
Reference

Diffusion of chloro-methane (1); water (2) 1
Diffusion of chloro-methane (1); water (2)

Vapor in Liquid

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
295.25 101.325 1.39 ± 4%

H 2O (2) water 7732-18-5
–0.7415 3.109 0.0
Comment: D*1(2) [m2/s] = D · 10–4
References

Diffusion of methane (1); tetrachloro-methane (2) 1
Diffusion of methane (1); tetrachloro-methane (2)

Vapor in Liquid
CH4 (1) methane 74-82-8

T [K] p [kPa] D · 109 [m2/s]
278.15 101.325 2.54
298.15 101.325 3.86
CH4 (1) methane 74-82-8

T [K] p [kPa] D · 109 [m2/s]
273.15 101.325 2.05 ± 5%
298.15 101.325 2.78 ± 5%
CH4 (1) methane 74-82-8

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 2.94
Comment: estimated accuracy ±3%
CH4 (1) methane 74-82-8

T [K] p [atm] D · 109 [m2/s]
298.15 3 3.08 ± 0.04
CH4 (1) methane 74-82-8

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 2.92
References
1968M1 Malik, V.K., Hayduk, W.: Can. J. Chem. Eng. 46 (1968) 462–466.

2 Diffusion of methane (1); tetrachloro-methane (2)

Diffusion of methane (1); methanol (2) 1
Diffusion of methane (1); methanol (2)

Vapor in Liquid
CH4 (1) methane 74-82-8

T [K] p [kPa] D · 109 [m2/s]
298 101.325 5.81 ± 0.007
313 101.325 7.05 ± 0.006
333 101.325 8.85 ± 0.008
383 101.325 14.9 ± 0.01
CH4 (1) methane 74-82-8

T [K] p [atm] D · 109 [m2/s]
298.15 3 4.55 ± 0.10
CH4 (1) methane 74-82-8

4.351 7712
References

Diffusion of methane (1); propan-2-one (2) 1
Diffusion of methane (1); propan-2-one (2)

Vapor in Liquid
CH4 (1) methane 74-82-8

T [K] p [atm] D · 109 [m2/s]
298.15 3 7.25 ± 0.14
Reference

Diffusion of methane (1); propan-1-ol (2) 1
Diffusion of methane (1); propan-1-ol (2)

Vapor in Liquid
CH4 (1) methane 74-82-8

C3H8O (2) propan-1-ol 71-23-8
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: ABSORB Ref.: 1967K4
T [K] p [kPa] D · 1011 [m2/s]
243.15 ± 0.02 101.325 126.0 ± 3%
233.15 ± 0.02 101.325 92.7 ± 3%
223.15 ± 0.02 101.325 64.9 ± 3%
213.15 ± 0.02 101.325 42.7 ± 3%
203.15 ± 0.02 101.325 28.1 ± 3%
193.15 ± 0.02 101.325 17.9 ± 3%
183.15 ± 0.02 101.325 10.6 ± 3%
173.15 ± 0.02 101.325 4.97 ± 3%
163.15 ± 0.02 101.325 2.87 ± 3%
153.15 ± 0.02 101.325 1.09 ± 3%
Reference
1967K4 Komarenko, V.G., Manzhelii, V.G., Radtsig, O.V.: Ukr. Fiz. Zh. 12 (1967) 47–51.

Diffusion of methane (1); propan-2-ol (2) 1
Diffusion of methane (1); propan-2-ol (2)

Vapor in Liquid
CH4 (1) methane 74-82-8

C3H8O (2) propan-2-ol 67-63-0
T [K] p [atm] D · 109 [m2/s]
298.15 3 3.18 ± 0.08
Reference

Diffusion of methane (1); butan-1-ol (2) 1
Diffusion of methane (1); butan-1-ol (2)

Vapor in Liquid
CH4 (1) methane 74-82-8

C4H10O (2) butan-1-ol 71-36-3
T [K] p [atm] D · 109 [m2/s]
298.15 3 2.66 ± 0.04
CH4 (1) methane 74-82-8

C4H10O (2) butan-1-ol 71-36-3
T [K] p [kPa] D · 109 [m2/s]
298 101.325 2.66 ± 0.004
333 101.325 4.94 ± 0.004
373 101.325 8.70 ± 0.005
433 101.325 16.8 ± 0.01
CH4 (1) methane 74-82-8

C4H10O (2) butan-1-ol 71-36-3
10.033 11690
References

Diffusion of methane (1); benzene (2) 1
Diffusion of methane (1); benzene (2)

Vapor in Liquid
CH4 (1) methane 74-82-8

C6H6 (2) benzene 71-43-2
T [K] p [kPa] D · 104 [m2/s]
283.15 ± 0.002 101.325 0.0900
298.15 ± 0.002 101.325 0.1018
313.15 ± 0.002 101.325 0.1062
328.15 ± 0.002 101.325 0.1188
343.15 ± 0.002 101.325 0.1272
CH4 (1) methane 74-82-8

C6H6 (2) benzene 71-43-2
T [K] p [atm] D · 109 [m2/s]
298.15 3 4.86 ± 0.06
CH4 (1) methane 74-82-8

C6H6 (2) benzene 71-43-2
4.2985 1.7638 0.0017
References

Diffusion of methane (1); cyclohexane (2) 1
Diffusion of methane (1); cyclohexane (2)

Vapor in Liquid
CH4 (1) methane 74-82-8

T [K] p [atm] D · 109 [m2/s]
298.15 3 4.10 ± 0.10
CH4 (1) methane 74-82-8

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 4.1 ± 0.01
313.25 101.325 5.46 ± 0.006
333.35 101.325 7.16 ± 0.003
353.75 101.325 9.26 ± 0.007
374.05 101.325 11.5 ± 0.03
390.85 101.325 13.4 ± 0.02
415.85 101.325 17.0 ± 0.03
CH4 (1) methane 74-82-8

T [K] p [kPa] D · 104 [m2/s]
283.15 ± 0.002 101.325 0.0793
298.15 ± 0.002 101.325 0.0883
313.15 ± 0.002 101.325 0.0927
328.15 ± 0.002 101.325 0.1042
343.15 ± 0.002 101.325 0.1109
CH4 (1) methane 74-82-8

6.163 9349

2 Diffusion of methane (1); cyclohexane (2)
CH4 (1) methane 74-82-8

4.3171 1.7413 0.0014
References

Diffusion of methane (1); hexane (2) 1
Diffusion of methane (1); hexane (2)

Vapor in Liquid
CH4 (1) methane 74-82-8

C6H14 (2) hexane 110-54-3
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: CC Ref.: 1972H6
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 8.64
CH4 (1) methane 74-82-8

C6H14 (2) hexane 110-54-3
T [K] p [atm] D · 109 [m2/s]
298.15 3 8.73 ± 0.05
CH4 (1) methane 74-82-8

C6H14 (2) hexane 110-54-3
T [K] p [kPa] D · 104 [m2/s]
283.15 ± 0.002 101.325 0.0752
298.15 ± 0.002 101.325 0.0821
313.15 ± 0.002 101.325 0.0920
328.15 ± 0.002 101.325 0.0999
References
1972H6 Hayduk, W., Buckley, W.D.: Chem. Eng. Science 27 (1972) 1997–2003.

Diffusion of methane (1); toluene (2) 1
Diffusion of methane (1); toluene (2)

Vapor in Liquid
CH4 (1) methane 74-82-8

C7H8 (2) toluene 108-88-3
T [K] p [kPa] D · 104 [m2/s]
283.15 ± 0.002 101.325 0.0809
298.15 ± 0.002 101.325 0.0917
313.15 ± 0.002 101.325 0.0956
328.15 ± 0.002 101.325 0.1065
343.15 ± 0.002 101.325 0.1146
CH4 (1) methane 74-82-8

C7H8 (2) toluene 108-88-3
3.8730 1.7635 0.0016
Reference

Diffusion of methane (1); methyl-cyclohexane (2) 1
Diffusion of methane (1); methyl-cyclohexane (2)

Vapor in Liquid
CH4 (1) methane 74-82-8

T [K] p [kPa] D · 104 [m2/s]
283.15 ± 0.002 101.325 0.0724
298.15 ± 0.002 101.325 0.0817
313.15 ± 0.002 101.325 0.0860
328.15 ± 0.002 101.325 0.0951
343.15 ± 0.002 101.325 0.1031
CH4 (1) methane 74-82-8

3.0763 1.7843 0.0011
Reference

Diffusion of methane (1); heptane (2) 1
Diffusion of methane (1); heptane (2)

Vapor in Liquid
CH4 (1) methane 74-82-8

C7H16 (2) heptane 142-82-5
T [K] p [kPa] D · 104 [m2/s]
283.15 ± 0.002 101.325 0.0714
298.15 ± 0.002 101.325 0.0791
313.15 ± 0.002 101.325 0.0838
328.15 ± 0.002 101.325 0.0911
343.15 ± 0.002 101.325 0.0991
CH4 (1) methane 74-82-8

C7H16 (2) heptane 142-82-5
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 7.52
References

Diffusion of methane (1); 2,2,4-trimethyl-pentane (2) 1
Diffusion of methane (1); 2,2,4-trimethyl-pentane (2)

Vapor in Liquid
CH4 (1) methane 74-82-8

T [K] p [kPa] D · 104 [m2/s]
283.15 ± 0.002 101.325 0.0662
298.15 ± 0.002 101.325 0.0727
313.15 ± 0.002 101.325 0.0770
328.15 ± 0.002 101.325 0.0867
343.15 ± 0.002 101.325 0.0948
References

Diffusion of methane (1); octane (2) 1
Diffusion of methane (1); octane (2)

Vapor in Liquid
CH4 (1) methane 74-82-8

C8H18 (2) octane 111-65-9
T [K] p [kPa] D · 109 [m2/s]
298 101.325 6.08 ± 0.003
333 101.325 9.45 ± 0.004
373 101.325 14.20 ± 0.003
403 101.325 18.1 ± 0.01
CH4 (1) methane 74-82-8

C8H18 (2) octane 111-65-9
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: MZ-INT Ref.: 1991K2
T [K] p [MPa] D · 109 [m2/s]
301.4 ± 0.1 1.72 6.3 ± 0.3
322.1 ± 0.1 1.72 8.4 ± 0.4
347.2 ± 0.2 1.72 10.9 ± 0.1
373.2 ± 0.1 1.72 14 ± 1
397.8 ± 0.3 1.72 20 ± 2
424.3 ± 0.1 1.72 25 ± 3
CH4 (1) methane 74-82-8

C8H18 (2) octane 111-65-9
T [K] p [kPa] D · 104 [m2/s]
283.15 ± 0.002 101.325 0.0657
298.15 ± 0.002 101.325 0.0721
313.15 ± 0.002 101.325 0.0782
328.15 ± 0.002 101.325 0.0827
343.15 ± 0.002 101.325 0.0912
CH4 (1) methane 74-82-8

C8H18 (2) octane 111-65-9
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 6.49

2 Diffusion of methane (1); octane (2)
CH4 (1) methane 74-82-8

C8H18 (2) octane 111-65-9
4.211 7490
References
1991K2 Killie, S., Hafskjold, B., Borgen, O., Kjelstrup, S., Hovde, E.: AIChE J. 37 (1991) 142–146.

Diffusion of methane (1); octan-1-ol (2) 1
Diffusion of methane (1); octan-1-ol (2)

Vapor in Liquid
CH4 (1) methane 74-82-8

C8H18O (2) octan-1-ol 111-87-5
T [K] p [kPa] D · 109 [m2/s]
298 101.325 1.45 ± 0.002
313 101.325 2.12 ± 0.003
353 101.325 4.4 ± 0.01
391 101.325 7.50 ± 0.009
430 101.325 10.7 ± 0.03
CH4 (1) methane 74-82-8

C8H18O (2) octan-1-ol 111-87-5
T [K] p [atm] D · 109 [m2/s]
298.15 3 1.39 ± 0.03
CH4 (1) methane 74-82-8

C8H18O (2) octan-1-ol 111-87-5
10.883 13290
References

Diffusion of methane (1); decane (2) 1
Diffusion of methane (1); decane (2)

Vapor in Liquid
CH4 (1) methane 74-82-8

C10H22 (2) decane 124-18-5
T [K] p [kPa] D · 109 [m2/s]
298 101.325 4.38 ± 0.006
333 101.325 7.16 ± 0.004
433 101.325 18.8 ± 0.002
CH4 (1) methane 74-82-8

C10H22 (2) decane 124-18-5
T [K] p [atm] D · 109 [m2/s]
298.15 3 4.38 ± 0.06
CH4 (1) methane 74-82-8

C10H22 (2) decane 124-18-5
4.731 8591
References

Diffusion of methane (1); tris-nonafluorobutyl-amine (2) 1
Diffusion of methane (1); tris-nonafluorobutyl-amine (2)

Vapor in Liquid
CH4 (1) methane 74-82-8

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 3.05
Reference

Diffusion of methane (1); dodecane (2) 1
Diffusion of methane (1); dodecane (2)

Vapor in Liquid
CH4 (1) methane 74-82-8

C12H26 (2) dodecane 112-40-3
T [K] p [kPa] D · 109 [m2/s]
273.15 101.325 3.15
298.15 101.325 3.94
323.15 101.325 5.17
Reference

Diffusion of methane (1); tetradecane (2)

Vapor in Liquid
CH4 (1) methane 74-82-8

T [K] p [kPa] D · 109 [m2/s]
298 101.325 2.78 ± 0.004
343 101.325 5.47 ± 0.004
374 101.325 7.80 ± 0.009
430 101.325 13.0 ± 0.01
CH4 (1) methane 74-82-8

T [K] p [atm] D · 109 [m2/s]
298.15 3 2.78 ± 0.04
CH4 (1) methane 74-82-8

4.441 9550
References

Diffusion of methane (1); hexadecane (2) 1
Diffusion of methane (1); hexadecane (2)

Vapor in Liquid
CH4 (1) methane 74-82-8

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 2.66
Reference

Diffusion of methane (1); tetrabutyl-stannane (2) 1
Diffusion of methane (1); tetrabutyl-stannane (2)

Vapor in Liquid
CH4 (1) methane 74-82-8

T [K] p [atm] D · 109 [m2/s]
298.15 3 2.22 ± 0.10
Reference

Diffusion of methane (1); water (2)

Vapor in Liquid
CH4 (1) methane 74-82-8

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.01 101.325 1.99 ± 0.06
313.15 ± 0.01 101.325 2.36 ± 0.05
CH4 (1) methane 74-82-8

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
273 ± 0.01 101.325 1.05
278 ± 0.01 101.325 1.10
283 ± 0.01 101.325 1.22
288 ± 0.01 101.325 1.33
293 ± 0.01 101.325 1.47
298 ± 0.01 101.325 1.64
303 ± 0.01 101.325 1.74
308 ± 0.01 101.325 1.96
CH4 (1) methane 74-82-8

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: OEC Ref.: 1965W4
T [K] p [kPa] D · 109 [m2/s]
297.95 ± 0.01 101.325 1.88 ± 0.01
308.25 ± 0.01 101.325 2.12 ± 0.03
315.75 ± 0.01 101.325 2.41 ± 0.02
CH4 (1) methane 74-82-8

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
283.15 ± 0.1 101.325 1.9
293.15 ± 0.1 101.325 2.4
303.15 ± 0.1 101.325 3.0
313.15 ± 0.1 101.325 4.2
323.15 ± 0.1 101.325 4.7
333.15 ± 0.1 101.325 6.7

2 Diffusion of methane (1); water (2)
CH4 (1) methane 74-82-8

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
277.15 101.325 0.85 ± 0.02
293.15 101.325 1.49 ± 0.04
313.15 101.325 2.38 ± 0.07
333.15 101.325 3.55 ± 0.15
CH4 (1) methane 74-82-8

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.02 101.325 1.84 ± 0.01
CH4 (1) methane 74-82-8

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: GC Ref.: 1973P5
T [K] p [kPa] D · 109 [m2/s]
290 101.325 1.07 ± 8%
CH4 (1) methane 74-82-8

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.05 101.325 1.88
CH4 (1) methane 74-82-8

H 2O (2) water 7732-18-5
7.0 4640 *
CH4 (1) methane 74-82-8

H 2O (2) water 7732-18-5
–5.8556 1.545 0.0
Comment: D*1(2) [m2/s] = D · 10–4

References
1967T5 Tham, M.J., Bhatia, K.K., Gubbins, K.E.: Chem. Eng. Science 22 (1967) 309–311.
1965W4 Witherspoon, P.A., Saraf, D.N.: J. Phys. Chem. 69 (1965) 3752–3755.
1969W2 Witherspoon, P.A., Bonoli, L.: Ind. Eng. Chem. Fundam. 8 (1969) 589–591.
1972T2 Tham, M.K., Gubbins, K.E.: J. Chem. Soc. Faraday Trans. 1 68 (1972) 1339–1346.
1973P5 Pratt, K.C., Slater, D.H., Wakeham, W.A.: Chem. Eng. Science 28 (1973) 1901–1903.

Diffusion of methanol (1); air (2) 1
Diffusion of methanol (1); air (2)

Vapor in Liquid

Air (2) air 132259-10-0
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: STEFAN Ref.: 1997S4
T [K] p [kPa] D · 109 [m2/s]
298.55 101.325 1.558
298.55 101.325 1.553
273.15 101.325 1.325
Reference
1997S4 Slattery, J.C., Mhetar, V.R.: Chem. Eng. Sci. 52 (1997) 1511–1515.

Diffusion of carbon monoxide (1); methanol (2) 1
Diffusion of carbon monoxide (1); methanol (2)

Vapor in Liquid

Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: ABSORB Ref.: 1996L5
T [K] p [kPa] D · 109 [m2/s]
298.85 101.325 5.0 ± 5%
303.15 101.325 5.9 ± 5%
313.15 101.325 6.3 ± 5%
323.15 101.325 7.5 ± 5%
333.15 101.325 7.8 ± 5%
343.15 101.325 8.5 ± 5%
353.15 101.325 9.0 ± 5%
363.15 101.325 9.5 ± 5%
Reference
1996L5 Liu, Q., Takemura, F., Yabe, A.: J. Chem. Eng. Data 41 (1996) 589–592.

Diffusion of carbon monoxide (1); toluene (2) 1
Diffusion of carbon monoxide (1); toluene (2)

Vapor in Liquid

C7H8 (2) toluene 108-88-3
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: TAYLOR Ref.: 1995S3
T [K] p [kPa] D · 109 [m2/s]
298.0 101.325 5.70
308.0 101.325 6.28
318.0 101.325 7.04
333.0 101.325 8.45
348.0 101.325 9.85
Comment: reproducibility ±(0.02 - 0.05) · 10–9 [m2/s]

C7H8 (2) toluene 108-88-3
Equation: ln D = ln A – B / RT Range: 298 < T/K < 348
277.0 1164.2
Reference
1995S3 Snijder, E.D., te Riele, M.J.M., Versteeg, G.F., van Swaaij, W.P.M.: J. Chem. Eng. Data 40 (1995)
37–39.

Diffusion of carbon monoxide (1); heptane (2) 1
Diffusion of carbon monoxide (1); heptane (2)

Vapor in Liquid

C7H16 (2) heptane 142-82-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: TAYLOR Ref.: 1987M8
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 1.0 1014 8.12 ± 0.2
427.15 ± 1.0 3448 25.3 ± 0.02
Reference
1987M8 Matthews, M.A., Rodden, J.B., Akgerman, A.: J. Chem. Eng. Data 32 (1987) 319–322.

Diffusion of carbon monoxide (1); dodecane (2) 1
Diffusion of carbon monoxide (1); dodecane (2)

Vapor in Liquid

C12H26 (2) dodecane 112-40-3
T [K] p [kPa] D · 109 [m2/s]
304.15 ± 1.0 1393 4.73 ± 0.21
372.15 ± 1.0 1412 10.7 ± 0.4
372.15 ± 1.0 3444 9.54 ± 0.25
445.15 ± 1.0 1445 16.4 ± 0.4
443.15 ± 1.0 3454 17.6 ± 0.2
513.15 ± 1.0 1451 27.0 ± 0.7
515.15 ± 1.0 3435 26.0 ± 1.5
567.15 ± 1.0 1463 43.4 ± 0.8
566.15 ± 1.0 3439 43.1 ± 1.3
Reference

Diffusion of carbon monoxide (1); hexadecane (2) 1
Diffusion of carbon monoxide (1); hexadecane (2)

Vapor in Liquid

T [K] p [kPa] D · 109 [m2/s]
323.15 ± 1.0 1421 4.01 ± 0.14
323.15 ± 1.0 3460 3.86 ± 0.07
371.15 ± 1.0 1404 6.72 ± 0.15
371.15 ± 1.0 3439 7.19 ± 0.18
443.15 ± 1.0 1397 13.6 ± 0.2
443.15 ± 1.0 3426 13.1 ± 0.5
513.15 ± 1.0 1412 22.5 ± 0.6
513.15 ± 1.0 3428 21.5 ± 0.1
564.15 ± 1.0 1404 32.3 ± 0.5
564.15 ± 1.0 3409 28.7 ± 0.7
Reference

Diffusion of carbon monoxide (1); octacosane (2) 1
Diffusion of carbon monoxide (1); octacosane (2)

Vapor in Liquid

C28H58 (2) octacosane 630-02-4
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: TAYLOR Ref.: 1988R5
T [K] p [MPa] D · 109 [m2/s]
371 ± 0.5 1.38 4.36 ± 0.16
414 ± 0.5 1.38 6.98 ± 0.05
455 ± 0.5 1.38 10.7 ± 0.01
495 ± 0.5 1.38 15.7 ± 0.50
534 ± 0.5 1.38 18.8 ± 0.19
Reference

Diffusion of carbon monoxide (1); water (2) 1
Diffusion of carbon monoxide (1); water (2)

Vapor in Liquid

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
283.15 ± 0.1 101.325 1.07 ± 2%
293.15 ± 0.1 101.325 2.03 ± 2%
303.15 ± 0.1 101.325 2.43 ± 2%
313.15 ± 0.1 101.325 3.62 ± 2%
323.15 ± 0.1 101.325 4.11 ± 2%
333.15 ± 0.1 101.325 5.68 ± 2%

H 2O (2) water 7732-18-5
40.7 5860 *
References

Diffusion of carbon monoxide (1); nitrogen (2)

Vapor in Liquid

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 109 [m2/s]
67.85 101.325 1.300 ± 0.15
70.28 101.325 1.440 ± 0.10
70.7 101.325 1.500 ± 0.10
71.3 101.325 1.650 ± 0.10
71.4 101.325 1.600 ± 0.10
73.72 101.325 1.818 ± 0.07
Reference
1964B4 Busca, G.L., Castagnoli, G.C.: Ric. Sci. Rend. 6 (1964) 57–61.

Diffusion of carbon oxide sulfide (1); water (2) 1
Diffusion of carbon oxide sulfide (1); water (2)

Vapor in Liquid

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: LAM Ref.: 1989A3
T [K] p [kPa] D · 109 [m2/s]
288.15 101.325 1.478 ± 5%
293.15 101.325 1.633 ± 5%
298.15 101.325 1.727 ± 5%
308.15 101.325 2.155 ± 5%

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: ABSORB Ref.: 1965S1
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 1.94
References
1989A3 Al-Ghawas, H.A., Ruiz-Ibanez, G., Sandall, O.C.: Chem. Eng. Science 44 (1989) 631–639.
1965S1 Sharma, M.M.: Trans. Faraday Soc. 61 (1965) 681–688.

Diffusion of carbon dioxide (1); kerosene (2) 1
Diffusion of carbon dioxide (1); kerosene (2)

Vapor in Liquid

(2) kerosene 8008-20-6
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: ABSORB Ref.: 1967D1
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 2.50
Reference
1967D1 Davies, G.A., Ponter, A.B., Craine, K.: Can. J. Chem. Eng. 45 (1967) 372–376.

Diffusion of carbon dioxide (1); tetrachloro-methane (2) 1
Diffusion of carbon dioxide (1); tetrachloro-methane (2)

Vapor in Liquid

T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.05 101.325 3.20
Reference

Diffusion of carbon dioxide (1); methanol (2) 1
Diffusion of carbon dioxide (1); methanol (2)

Vapor in Liquid

T [K] p [kPa] D · 109 [m2/s]
279.3 101.325 4.29 ± 0.02
298.2 101.325 5.55 ± 0.09
313.2 101.325 6.89 ± 0.07
333.2 101.325 8.44 ± 0.08
348.2 101.325 9.89 ± 0.07

T [K] p [bar] D · 109 [m2/s]
293 1 4.75
298 1 5.13
303 1 5.36
308 1 5.78
313 1 6.11
318 1 6.53
323 1 6.90
328 1 7.10
333 1 7.54

T [K] p [kPa] D · 109 [m2/s]
298.0 101.325 4.54

T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.05 101.325 4.95

2 Diffusion of carbon dioxide (1); methanol (2)

Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: ABSORB Ref.: 1981W3
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 8.37

2.22 9340
References
1985C6 Chen, B.H.C., Chen, S.H.: Chem. Eng. Sci. 40 (1985) 1735–1741.
1996F3 Frank, M.J.W., Kuipers, J.A.M., van Swaaij, W.P.M.: J. Chem. Eng. Data 41 (1996) 297–302.
1991L14 Littel, R.J., Versteeg, G.F., Van Swaaij, W.P.M.: Chem. Eng. Science 46 (1991) 3308–3313.
1981W3 Won, Y.S., Chung, D.K., Mills, A.F.: J. Chem. Eng. Data 26 (1981) 140–141.

Diffusion of carbon dioxide (1); ethanol (2) 1
Diffusion of carbon dioxide (1); ethanol (2)

Vapor in Liquid

Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: LAM Ref.: 1960O1
T [K] p [kPa] D · 109 [m2/s]
279.55 101.325 2.45
283.15 101.325 2.78
288.15 101.325 3.02
293.15 101.325 3.40

Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: CORR Ref.: 1972A3
T [K] p [kPa] D · 109 [m2/s]
279.55 101.325 2.45
283.15 101.325 2.78
288.15 101.325 3.02
293.15 101.325 3.40

T [K] p [kPa] D · 109 [m2/s]
298.1 101.325 4.11
308.0 101.325 4.70
313.0 101.325 5.05
323.1 101.325 5.77
333.0 101.325 6.51

T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.05 101.325 4.04

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 3.46

2 Diffusion of carbon dioxide (1); ethanol (2)

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 3.42

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 3.88

T [K] p [kPa] D · 109 [m2/s]
303.15 101.325 3.69

T [K] p [kPa] D · 109 [m2/s]
298.0 101.325 3.86

336.5 1314.7
References
1960O1 Onda, K., Okamoto, T., Yamaji, Y.: Kagaku Kogaku 24 (1960) 918–925.
1972A3 Akgerman, A., Gainer, J.L.: J. Chem. Eng. Data 17 (1972) 372–377.
1995S3 Snijder, E.D., te Riele, M.J.M., Versteeg, G.F., van Swaaij, W.P.M.: J. Chem. Eng. Data 40
(1995) 37–39.
1971D1 Dim, A., Gardner, G.R., Ponter, A.B., Wood, T.: J. Chem. Eng. Jpn. 4 (1971) 92–95.
1967D2 Davis, R.E., Horvath, G.L., Tobias, C.W.: Electrochim. Acta 12 (1967) 287–297.

Diffusion of carbon dioxide (1); dimethyl sulfoxide (2) 1
Diffusion of carbon dioxide (1); dimethyl sulfoxide (2)

Vapor in Liquid

C2H6OS (2) dimethyl sulfoxide 67-68-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: EA V Ref.: 1965R2
T [K] p [kPa] D · 1010 [m2/s]
298.15 101.325 1.5
Reference
1965R2 Roberts, J.L., Sawyer, D.T.: J. Electroanal. Chem. 9 (1965) 1–7.

Diffusion of carbon dioxide (1); propan-2-one (2) 1
Diffusion of carbon dioxide (1); propan-2-one (2)

Vapor in Liquid

T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.05 101.325 6.08
Reference

Diffusion of carbon dioxide (1); propan-1-ol (2) 1
Diffusion of carbon dioxide (1); propan-1-ol (2)

Vapor in Liquid

C3H8O (2) propan-1-ol 71-23-8
T [K] p [kPa] D · 109 [m2/s]
298.0 101.325 3.06
Reference

Diffusion of carbon dioxide (1); butan-2-one (2) 1
Diffusion of carbon dioxide (1); butan-2-one (2)

Vapor in Liquid

C4H8O (2) butan-2-one 78-93-3
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.05 101.325 4.81
Reference

Diffusion of carbon dioxide (1); butan-1-ol (2) 1
Diffusion of carbon dioxide (1); butan-1-ol (2)

Vapor in Liquid

C4H10O (2) butan-1-ol 71-36-3
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.05 101.325 2.55

C4H10O (2) butan-1-ol 71-36-3
T [K] p [kPa] D · 109 [m2/s]
298.0 101.325 2.50
References

Diffusion of carbon dioxide (1); 2-methyl-propan-1-ol (2) 1
Diffusion of carbon dioxide (1); 2-methyl-propan-1-ol (2)

Vapor in Liquid

T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.05 101.325 2.13

Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: LAM Ref.: 1963N1
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 2.07 ± 5%

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 2.20
References
1963N1 Norman, W.S., Sammak, F.Y.Y.: Trans. Inst. Chem. Eng. 41 (1963) 109–116.

Diffusion of carbon dioxide (1); pentan-3-one (2) 1
Diffusion of carbon dioxide (1); pentan-3-one (2)

Vapor in Liquid

C5H10O (2) pentan-3-one 96-22-0
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.05 101.325 4.67
Reference

Diffusion of carbon dioxide (1); pentan-1-ol (2) 1
Diffusion of carbon dioxide (1); pentan-1-ol (2)

Vapor in Liquid

C5H12O (2) pentan-1-ol 71-41-0
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.05 101.325 2.16

C5H12O (2) pentan-1-ol 71-41-0
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 1.88 ± 5%

C5H12O (2) pentan-1-ol 71-41-0
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 1.91
References

Diffusion of carbon dioxide (1); chlorobenzene (2) 1
Diffusion of carbon dioxide (1); chlorobenzene (2)

Vapor in Liquid

Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: DIA Ref.: 1992L9
T [K] p [kPa] D · 109 [m2/s]
298 101.325 3.69
298 101.325 3.93
Reference
1992L9 Littel, R.J., Versteeg, G.F., van Swaaij, W.P.M.: J. Chem. Eng. Data 37 (1992) 42–45.

Diffusion of carbon dioxide (1); benzene (2) 1
Diffusion of carbon dioxide (1); benzene (2)

Vapor in Liquid

C6H6 (2) benzene 71-43-2
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.05 101.325 4.05
298.15 ± 0.05 101.325 4.46
Reference

Diffusion of carbon dioxide (1); 4-methyl-pentan-2-one (2) 1
Diffusion of carbon dioxide (1); 4-methyl-pentan-2-one (2)

Vapor in Liquid

T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.05 101.325 4.40 ± 0.06
323.15 ± 0.05 101.325 6.47 ± 0.29
Reference
1973M2 McManamey, W.J., Woollen, J.M.: AIChE J. 19 (1973) 667–669.

Diffusion of carbon dioxide (1); hexane (2) 1
Diffusion of carbon dioxide (1); hexane (2)

Vapor in Liquid

C6H14 (2) hexane 110-54-3
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.05 101.325 8.20
Reference

Diffusion of carbon dioxide (1); toluene (2) 1
Diffusion of carbon dioxide (1); toluene (2)

Vapor in Liquid

C7H8 (2) toluene 108-88-3
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.05 101.325 4.6 ± 0.1
323.15 ± 0.05 101.325 6.69 ± 0.15

C7H8 (2) toluene 108-88-3
T [K] p [kPa] D · 109 [m2/s]
298.0 101.325 4.89
308.0 101.325 5.58
318.0 101.325 6.24
333.0 101.325 7.54
348.0 101.325 8.82

C7H8 (2) toluene 108-88-3
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.05 101.325 4.33
298.15 ± 0.05 101.325 4.61

C7H8 (2) toluene 108-88-3
T [K] p [kPa] D · 109 [m2/s]
298 ± 0.1 101.325 4.14
298 ± 0.1 101.325 3.91
308 ± 0.1 101.325 4.35
308 ± 0.1 101.325 4.48
318 ± 0.1 101.325 5.01
318 ± 0.1 101.325 4.94
328 ± 0.1 101.325 5.60
328 ± 0.1 101.325 5.54

2 Diffusion of carbon dioxide (1); toluene (2)

C7H8 (2) toluene 108-88-3
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 3.44 ± 2.4%

C7H8 (2) toluene 108-88-3
296.1 1224.5
References
1995S3 Snijder, E.D., te Riele, M.J.M., Versteeg, G.F., van Swaaij, W.P.M.: J. Chem. Eng. Data 40
(1995) 37–39.
1976S11 Sovova, H., Prochazka, J.: Chem. Eng. Science 31 (1976) 1091–1097.

Diffusion of carbon dioxide (1); heptane (2) 1
Diffusion of carbon dioxide (1); heptane (2)

Vapor in Liquid

C7H16 (2) heptane 142-82-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: NMR FG Ref.: 1987K1
T [K] p [kPa] D · 109 [m2/s]
283 101.325 6.11 ± 5%
293 101.325 6.89 ± 5%
303 101.325 7.69 ± 5%
313 101.325 8.58 ± 5%
323 101.325 9.30 ± 5%
333 101.325 10.38 ± 5%
343 101.325 11.36 ± 5%

C7H16 (2) heptane 142-82-5
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 5.79 ± 5%

C7H16 (2) heptane 142-82-5
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 6.03

C7H16 (2) heptane 142-82-5
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.05 101.325 6.89
References
1987K1 Khristoforov, A.V., Dautov, R.A.: Zh. Fiz. Khim. 61 (1987) 2656–2659.

Diffusion of carbon dioxide (1); heptan-1-ol (2) 1
Diffusion of carbon dioxide (1); heptan-1-ol (2)

Vapor in Liquid

C7H16O (2) heptan-1-ol 111-70-6
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 1.80
Comment: exp. method: laminar jet technique

C7H16O (2) heptan-1-ol 111-70-6
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.05 101.325 1.66
References

Diffusion of carbon dioxide (1); 1,4-dimethyl-benzene (2) 1
Diffusion of carbon dioxide (1); 1,4-dimethyl-benzene (2)

Vapor in Liquid

T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.05 101.325 4.37
Reference

Diffusion of carbon dioxide (1); 2,2,4-trimethyl-pentane (2) 1
Diffusion of carbon dioxide (1); 2,2,4-trimethyl-pentane (2)

Vapor in Liquid

T [K] p [kPa] D · 109 [m2/s]
280.7 101.325 5.07 ± 0.01
298.2 101.325 6.34 ± 0.05
323.2 101.325 8.34 ± 0.02
348.2 101.325 10.51 ± 0.04
373.2 101.325 13.2 ± 0.1
Reference

Diffusion of carbon dioxide (1); octan-1-ol (2) 1
Diffusion of carbon dioxide (1); octan-1-ol (2)

Vapor in Liquid

C8H18O (2) octan-1-ol 111-87-5
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.05 101.325 1.46 ± 0.07

C8H18O (2) octan-1-ol 111-87-5
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 1.46

C8H18O (2) octan-1-ol 111-87-5
T [K] p [kPa] D · 109 [m2/s]
298.0 101.325 1.53

C8H18O (2) octan-1-ol 111-87-5
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.05 101.325 1.50
References

Diffusion of carbon dioxide (1); 4-allyl-2-methoxy-phenol (2) 1
Diffusion of carbon dioxide (1); 4-allyl-2-methoxy-phenol

(2)
Vapor in Liquid

C10H12O2 (2) 4-allyl-2-methoxy-phenol 97-53-0
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 0.737 ± 5%
Reference

Diffusion of carbon dioxide (1); decahydro-naphthalene (2) 1
Diffusion of carbon dioxide (1); decahydro-naphthalene (2)

Vapor in Liquid

C10H18 (2) decahydro-naphthalene 91-17-8
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.05 101.325 2.33 ± 0.04
323.15 ± 0.05 101.325 3.25 ± 0.19
Reference

Diffusion of carbon dioxide (1); dodecane (2) 1
Diffusion of carbon dioxide (1); dodecane (2)

Vapor in Liquid

C12H26 (2) dodecane 112-40-3
T [K] p [kPa] D · 109 [m2/s]
304.15 ± 1.0 1393 3.90 ± 0.04
372.15 ± 1.0 1412 8.68 ± 0.1
372.15 ± 1.0 3444 8.68 ± 0.06
445.15 ± 1.0 1445 15.6 ± 0.2
443.15 ± 1.0 3454 15.6 ± 0.1
513.15 ± 1.0 1451 25.1 ± 0.1
515.15 ± 1.0 3435 24.7 ± 0.2
567.15 ± 1.0 1463 37.0 ± 0.4
566.15 ± 1.0 3439 34.9 ± 0.3
Reference

Diffusion of carbon dioxide (1); tetradecane (2) 1
Diffusion of carbon dioxide (1); tetradecane (2)

Vapor in Liquid

T [K] p [MPa] D · 109 [m2/s]
290.0 0.910 0.807
290.0 1.139 1.855
290.0 1.330 1.175
290.0 1.672 1.456
290.0 1.986 1.836
290.0 2.095 2.113
90.0 2.620 1.906
290.0 3.170 2.405
290.0 3.579 2.254
290.0 3.879 1.129
311.0 1.225 1.470
311.0 1.755 1.737
311.0 2.803 1.831
311.0 1.905 1.933
311.0 2.313 1.968
311.0 3.238 2.556
311.0 3.435 2.491
311.0 3.959 1.683
331.0 1.415 0.767
331.0 1.759 2.006
331.0 2.422 1.906
331.0 2.874 2.731
331.0 3.320 3.731
331.0 4.041 2.731

T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.05 101.325 2.95 ± 0.03
323.15 ± 0.05 101.325 3.96 ± 0.14
References
1996W3 Wang, L.S., Lang, Z.X., Guo, T.M.: Fluid Phase Equilib. 117 (1996) 364–372.

Diffusion of carbon dioxide (1); hexadecane (2) 1
Diffusion of carbon dioxide (1); hexadecane (2)

Vapor in Liquid

T [K] p [MPa] D · 109 [m2/s]
323.15 ± 1.0 1421 3.48 ± 0.03
323.15 ± 1.0 3460 3.47 ± 0.09
371.15 ± 1.0 1404 6.57 ± 0.01
371.15 ± 1.0 3439 6.53 ± 0.12
443.15 ± 1.0 1397 12.5 ± 0.1
443.15 ± 1.0 3426 12.4 ± 0.1
513.15 ± 1.0 1412 20.2 ± 0.2
513.15 ± 1.0 3428 19.9 ± 0.1
564.15 ± 1.0 1404 27.4 ± 0.1
564.15 ± 1.0 3409 27.2 ± 0.4
Reference

Diffusion of carbon dioxide (1); octacosane (2) 1
Diffusion of carbon dioxide (1); octacosane (2)

Vapor in Liquid

T [K] p [MPa] D · 109 [m2/s]
371 ± 0.5 1.38 3.80 ± 0.07
414 ± 0.5 1.38 6.12 ± 0.20
455 ± 0.5 1.38 8.99 ± 0.20
495 ± 0.5 1.38 12.7 ± 0.09
534 ± 0.5 1.38 15.5 ± 0.36
Reference

Diffusion of carbon dioxide (1); water (2)

Vapor in Liquid

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
303.15 101.325 2.229
308.15 101.325 2.511
313.15 101.325 2.800
Comment: reproducibility: ±3%; exp. error: ±2%

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
303.15 101.325 2.120 ± 2%
308.15 101.325 2.462 ± 2%
313.15 101.325 2.775 ± 2%

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
273.25 ± 0.1 101.325 0.99 ± 0.1
278.25 ± 0.1 101.325 0.98 ± 0.1
283.15 ± 0.1 101.325 1.46 ± 0.1
288.15 ± 0.1 101.325 1.87 ± 0.2

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
283.15 101.325 1.17
288.15 101.325 1.39
293.15 101.325 1.62
298.15 101.325 1.90
303.15 101.325 2.25

2 Diffusion of carbon dioxide (1); water (2)

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: DIA Ref.: 1970O2
T [K] p [kPa] D · 109 [m2/s]
278.15 101.325 0.97
283.15 101.325 1.17
288.15 101.325 1.45
298.15 101.325 1.94

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: ABSORB Ref.: 1964U1
T [K] p [kPa] D · 109 [m2/s]
279.65 101.325 1.145
298.15 101.325 1.850
308.15 101.325 2.179
325.15 101.325 3.613
338.15 101.325 4.296
Comment: no estimate on errors of D is given

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: ABSORB Ref.: 1994T2
T [K] p [kPa] D · 109 [m2/s]
293 ± 0.3 101.325 1.76
298 ± 0.3 101.325 1.94
303 ± 0.3 101.325 2.20
313 ± 0.3 101.325 2.93
333 ± 0.3 101.325 4.38
353 ± 0.3 101.325 6.58
368 ± 0.3 101.325 8.20
Comment: average STD = ±0.0071 · 10–9 [m2/s]

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
294.0 ± 0.1 101.325 1.74
301.5 ± 0.1 101.325 2.08
303.2 ± 0.1 101.325 2.18
311.5 ± 0.1 101.325 2.61
318.0 ± 0.1 101.325 3.00
Comment: exp. error: ±5%


H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: ABSORB Ref.: 2004M1
T [K] p [kPa] D · 109 [m2/s]
293 ± 0.2 101.325 1.71 ± 2%
298 ± 0.2 101.325 1.90 ± 2%
303 ± 0.2 101.325 2.13 ± 2%
308 ± 0.2 101.325 2.47 ± 2%
313 ± 0.2 101.325 2.86 ± 2%

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: LAM Ref.: 1965T3
T [K] p [kPa] D · 109 [m2/s]
291.65 ± 0.2 101.325 1.65 ± 1%
298.15 ± 0.2 101.325 1.95 ± 1%
307.85 ± 0.2 101.325 2.41 ± 1%
318.35 ± 0.2 101.325 3.03 ± 1%
328.05 ± 0.2 101.325 3.68 ± 1%
338.15 ± 0.2 101.325 4.40 ± 1%
348.25 ± 0.2 101.325 5.40 ± 1%

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
273 ± 0.01 101.325 1.00
278 ± 0.01 101.325 1.16
283 ± 0.01 101.325 1.32
288 ± 0.01 101.325 1.52
293 ± 0.01 101.325 1.74
298 ± 0.01 101.325 1.85
303 ± 0.01 101.325 2.19
308 ± 0.01 101.325 2.41

H 2O (2) water 7732-18-5
T [K] p [bar] D · 109 [m2/s]
298 1 1.97
308 1 2.49
318 1 3.07
328 1 3.67


H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
273.15 101.325 0.960
279.65 101.325 1.08
283.15 101.325 1.17
283.15 101.325 1.28 *
283.35 101.325 1.30
283.35 101.325 1.44 *
288.15 101.325 1.37
288.15 101.325 1.40
288.35 101.325 1.58 *
288.95 101.325 1.49
289.15 101.325 1.57
289.15 101.325 1.63
289.15 101.325 1.60
289.55 101.325 1.57
290.65 101.325 1.56 *
291.35 101.325 1.71 ± 1.0%
293.15 101.325 1.77
293.15 101.325 1.60 ± 5.0%
293.15 101.325 1.63
293.15 101.325 1.69 *
293.55 101.325 1.85
297.95 101.325 1.94
298.15 101.325 1.82
298.15 101.325 1.91
298.15 101.325 1.74
298.15 101.325 1.87 ± 3.0%
298.15 101.325 1.9 ± 8.0%
298.15 101.325 1.90 ± 5.0%
298.15 101.325 1.92
298.15 101.325 1.85
303.15 101.325 2.29 ± 10%
303.15 101.325 2.25
303.15 101.325 2.15 ± 5.0%
308.15 101.325 2.26
308.15 101.325 2.18
313.15 101.325 2.75
323.15 101.325 3.24
325.15 101.325 3.61
338.15 101.325 4.30
Comment: review of previous experimental results;
*: diffusion measured in agar media


H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
283 ± 0.01 101.325 0.83
288 ± 0.01 101.325 0.98
293 ± 0.01 101.325 1.18
298 ± 0.01 101.325 1.40
303 ± 0.01 101.325 1.65
308 ± 0.01 101.325 2.07

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: ABSORB Ref.: 2001A6
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.2 101.325 1.88 ± 2%
325.15 ± 0.2 101.325 3.45 ± 2%

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: BUBBLE Ref.: 1956G1
T [K] p [kPa] D · 109 [m2/s]
296.15 ± 0.02 101.325 2.35 ± 0.01
302.15 ± 0.02 101.325 2.71 ± 0.01
310.15 ± 0.02 101.325 3.013 ± 0.01

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.01 101.325 1.89 ± 0.10
313.15 ± 0.01 101.325 2.81 ± 0.10
333.15 ± 0.01 101.325 4.15 ± 0.24

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s
298.15 ± 0.01 101.325 1.98
313.15 ± 0.01 101.325 2.80
Comment: error about ±(10 - 15)%


H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 1.93

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: ABSORB Ref.: 1991X1
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.1 101.325 1.93 ± 5%

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: LAM Ref.: 1964C2
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 1.96

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: BUBBLE Ref.: 1969N6
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 1.99

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: OTE Ref.: 1988D3
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 1.98 ± 0.005

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.05 101.325 1.99 ± 3%

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 1.93


H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 1.98
Comment: Method: liquid jet absorption apparatus

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 2.00 ± 0.06

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: STEFAN Ref.: 1972C6
T [K] p [kPa] D · 109 [m2/s]
300.0 ± 0.05 101.325 2.15 ± 7.6%

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.0 101.325 1.92 ± 0.055

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: BUBBLE Ref.: 1980S1
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 1.86

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 1.97

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 1.63 ± 5%


H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 1.69 ± 2%

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 1.94

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: DIA Ref.: 1964V5
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.2 101.325 2.00 ± 3.5%

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 1.92 ± 2%
Comment: averaged over a larger set of concentrations

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
303.15 101.325 2.20
Comment: estimated accuracy: ±3%.

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
290 101.325 1.47 ± 8%

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: OTE Ref.: 1984H2
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.1 101.325 1.93 ± 3.3%


H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: No Info Ref.: 1930A1
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 1.74

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: ABSORB Ref.: 1987V4
Equation: D = A · exp[ B / T ] Range: 283 < T/K < 333
2.35 –2119.0 2%

H 2O (2) water 7732-18-5
Equation: D = A · exp[ B / T ] Range: 273.15 < T/K < 368.15
Parameter: A B
3073.7 –2197.5

H 2O (2) water 7732-18-5
2.35 –2119

H 2O (2) water 7732-18-5
–3.2164 2.264 0.0
Comment: D*1(2) [m2/s] = D · 10–4

H 2O (2) water 7732-18-5
Equation: D = A + B · c1 Range: 0.0 < c1 / mol· dm–3 < 3.25 · 10–4
Parameter: A · 109 B · 1015
1.98 –1.6646


H 2O (2) water 7732-18-5
1.81 16900
References
1996L4 Li, M.-H., Lee, W.-C.: J. Chem. Eng. Data 41 (1996) 551–556.
1970H9 Hawke, J.G., White, I.: J. Phys. Chem. 74 (1970) 2788–2793.
1970O2 Onda, K., Sada, E., Kobayashi, T., Ando, N., Kito, S.: Kagaku Kogaku 34 (1970) 603–607.
1964U1 Unver, A.A., Himmelblau, D.M.: J. Chem. Eng. Data 9 (1964) 428–431.
1994T2 Tamimi, A., Rinker, E.B., Sandall, O.C.: J. Chem. Eng. Data 39 (1994) 330–332.
1993S1 Saha, A.K., Bandyopadhyay, S.S., Biswas, A.K.: J. Chem. Eng. Data 38 (1993) 78–82.
2004M1 Mandal, B.P., Kundu, M., Padhiyar, N.U., Bandyopadhyay, S.S.: J. Chem. Eng. Data 49 (2004)
264–270.
1965T3 Thomas, W.J., Adams, M.J.: Trans. Faraday Soc. 61 (1965) 668–673.
1996F3 Frank, M.J.W., Kuipers, J.A.M., van Swaaij, W.P.M.: J. Chem. Eng. Data 41 (1996) 297–302.
2001A6 Abu-Arabi, M.K., Al-Jarrah, A.M., El-Eideh, M., Tamimi, A.: J. Chem. Eng. Data 46 (2001)
516–521.
1956G1 Gertz, K.H., Löschke, H.H.: Z. Naturforsch. B 11 (1956) 61–64.
1972O2 Onda, K., Takeuchi, H., Kobayashi, T.: Kagaku Kogaku 36 (1972) 903–907.
1991X1 Xu, S., Otto, F.D., Mather, A.E.: J. Chem. Eng. Data 36 (1991) 71–75.
1964C2 Clarke, J.K.A.: Ind. Eng. Chem. Fundam. 3 (1964) 239–245.
1969N6 Ng, W.Y., Walkley, J.: Can. J. Chem. 47 (1969) 1075–1077.
1988D3 Diaz, J.M., Vega, A., Coca, J.: J. Chem. Eng. Data 33 (1988) 10–12.
1985T1 Tang, A., Sandall, O.C.: J. Chem. Eng. Data 30 (1985) 189–191.
1972B3 Bjerle, I., Bengtsson, S., Farnkvist, K.: Chem. Eng. Science 27 (1972) 1853–1861.
1972C6 Choudhari, R.V., Doraiswamy, L.K.: J. Chem. Eng. Data 17 (1972) 428–432.
1967F2 Ferrell, R.T., Himmelblau, D.M.: J. Chem. Eng. Data 12 (1967) 111–115.
1980S1 Sada, E., Katoh, S., Yoshii, H., Yasuda, K.: J. Chem. Eng. Data 25 (1980) 341–343.
1989T2 Tomcej, R.A., Otto, F.D.: AIChE J. 35 (1989) 861–864.
1976S11 Sovova, H., Prochazka, J.: Chem. Eng. Science 31 (1976) 1091–1097.
1975S8 Simons, J., Ponter, A.B.: J. Chem. Eng. Jpn. 8 (1975) 347–350.
1964V5 Vivian, J.E., King, C.J.: AIChE J. 10 (1964) 220–221.
1965T1 Tang, Y.P., Himmelblau, D.M.: Chem. Eng. Science 20 (1965) 7–14.
1984H2 Halmour, N., Sandall, O.C.: J. Chem. Eng. Data 29 (1984) 20–22.
1930A1 Arnold, J.H.: J. Am. Chem. Soc. 52 (1930) 3937–3954.

1987V4 Versteeg, G.F., Blauwhoff, P.M.M., Van Swaaij, W.P.M.: Chem. Eng. Science 42 (1987)
1103–1119.

Diffusion of ethyne (1); water (2) 1
Diffusion of ethyne (1); water (2)

Vapor in Liquid
C2H2 (1) ethyne 74-86-2

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 1.80
C2H2 (1) ethyne 74-86-2

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
273.15 101.325 1.10
283.15 101.325 1.50
290.65 101.325 1.69
303.15 101.325 2.19
References

Diffusion of chloro-ethene (1); water (2) 1
Diffusion of chloro-ethene (1); water (2)

Vapor in Liquid

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: RFGC Ref.: 2004K5
T [K] p [kPa] D · 109 [m2/s]
324.15 101.325 2.11
329.05 101.325 1.75
339.55 101.325 0.84
345.45 101.325 0.66

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: RFGC Ref.: 2001R1
T [K] p [kPa] D · 108 [m2/s]
324.05 101.325 2.679
329.05 101.325 2.586
339.55 101.325 5.176
345.55 101.325 6.177
324.40 101.325 2.767
329.00 101.325 1.657
334.65 101.325 2.094
339.35 101.325 2.500
345.90 101.325 4.233
324.25 101.325 3.034
328.90 101.325 2.821
334.70 101.325 3.208
339.30 101.325 3.518
324.25 101.325 2.493
328.80 101.325 1.560
334.50 101.325 2.665
339.20 101.325 2.478
345.85 101.325 3.353
References
2001R1 Rashid, A.K., Gavril, D., Katsanos, N.A., Karaiskakis, G.: J. Chromatogr. A 934 (2001) 31–49.

Diffusion of ethene (1); methanol (2) 1
Diffusion of ethene (1); methanol (2)

Vapor in Liquid
C2H4 (1) ethene 74-85-1

T [K] p [kPa] D · 109 [m2/s]
279.3 101.325 3.55 ± 0.03
298.2 101.325 4.71 ± 0.06
313.2 101.325 5.75 ± 0.05
333.2 101.325 7.5 ± 0.1
348.2 101.325 8.97 ± 0.05
Reference

Diffusion of ethene (1); trans-1,2-dichloro-ethene (2) 1
Diffusion of ethene (1); trans-1,2-dichloro-ethene (2)

Vapor in Liquid
C2H4 (1) ethene 74-85-1

C2H2Cl2 (2) trans-1,2-dichloro-ethene 156-60-5
T [K] p [kPa] D · 109 [m2/s]
288.0 ± 0.05 101.325 2.75 ± 7.6%
292.0 ± 0.05 101.325 3.35 ± 7.6%
298.0 ± 0.05 101.325 3.84 ± 7.6%
303.0 ± 0.05 101.325 4.11 ± 7.6%
Reference

Diffusion of ethene (1); acetonitrile (2) 1
Diffusion of ethene (1); acetonitrile (2)

Vapor in Liquid
C2H4 (1) ethene 74-85-1

C2H3N (2) acetonitrile 75-05-8
T [K] p [kPa] D · 109 [m2/s]
280.6 101.325 4.95 ± 0.02
298.2 101.325 6.20 ± 0.03
323.2 101.325 8.26 ± 0.02
343.2 101.325 9.88 ± 0.08
363.2 101.325 11.87 ± 0.05
Reference

Diffusion of ethene (1); propan-2-ol (2) 1
Diffusion of ethene (1); propan-2-ol (2)

Vapor in Liquid
C2H4 (1) ethene 74-85-1

C3H8O (2) propan-2-ol 67-63-0
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: TAYLOR Ref.: 1989B2
T [K] p [kPa] D · 109 [m2/s]
300.0 101.325 2.0 ± 0.4
Reference
2347–2353.

Diffusion of ethene (1); tetrahydrofuran (2) 1
Diffusion of ethene (1); tetrahydrofuran (2)

Vapor in Liquid
C2H4 (1) ethene 74-85-1

T [K] p [kPa] D · 109 [m2/s]
300.0 101.325 3.8 ± 0.16
Reference
2347–2353.

Diffusion of ethene (1); nitrobenzene (2) 1
Diffusion of ethene (1); nitrobenzene (2)

Vapor in Liquid
C2H4 (1) ethene 74-85-1

T [K] p [kPa] D · 109 [m2/s]
303.0 ± 0.05 101.325 2.37 ± 7.6%
313.0 ± 0.05 101.325 2.71 ± 7.6%
323.0 ± 0.05 101.325 3.05 ± 7.6%
333.0 ± 0.05 101.325 3.29 ± 7.6%
Reference

Diffusion of ethene (1); cyclohexane (2) 1
Diffusion of ethene (1); cyclohexane (2)

Vapor in Liquid
C2H4 (1) ethene 74-85-1

T [K] p [kPa] D · 109 [m2/s]
280.6 101.325 2.35 ± 0.01
298.2 101.325 3.20 ± 0.03
323.2 101.325 4.67 ± 0.09
343.2 101.325 6.08 ± 0.06
363.2 101.325 7.89 ± 0.07
Reference

Diffusion of ethene (1); hexane (2) 1
Diffusion of ethene (1); hexane (2)

Vapor in Liquid
C2H4 (1) ethene 74-85-1

C6H14 (2) hexane 110-54-3
T [K] p [kPa] D · 109 [m2/s]
303.15 101.325 6.01
Reference

Diffusion of ethene (1); heptane (2) 1
Diffusion of ethene (1); heptane (2)

Vapor in Liquid
C2H4 (1) ethene 74-85-1

C7H16 (2) heptane 142-82-5
T [K] p [kPa] D · 109 [m2/s]
295.2 101.325 2.82 ± 0.37
Reference

Diffusion of ethene (1); 2,2,4-trimethyl-pentane (2) 1
Diffusion of ethene (1); 2,2,4-trimethyl-pentane (2)

Vapor in Liquid
C2H4 (1) ethene 74-85-1

T [K] p [kPa] D · 109 [m2/s]
280.7 101.325 4.09 ± 0.01
298.2 101.325 5.08 ± 0.03
323.2 101.325 6.88 ± 0.08
348.2 101.325 9.26 ± 0.06
373.2 101.325 12.05 ± 0.05
Reference

Diffusion of ethene (1); water (2) 1
Diffusion of ethene (1); water (2)

Vapor in Liquid
C2H4 (1) ethane 74-85-1

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.01 101.325 1.87
313.15 ± 0.01 101.325 2.53
Comment: error about ±(10–15 )%
C2H4 (1) ethane 74-85-1

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
279.85 101.325 0.682
298.55 101.325 1.085
308.15 101.325 1.396
325.15 101.325 2.020
338.15 101.325 2.579
Comment: no estimate on error of D is given
C2H4 (1) ethane 74-85-1

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
291 101.325 1.70 ± 8%
C2H4 (1) ethane 74-85-1

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: ABSORB Ref.: 1968H4
T [K] p [kPa] D · 109 [m2/s]
293.15 ± 0.01 101.325 1.41 ± 0.07
298.15 ± 0.01 101.325 1.51 ± 0.36
303.15 ± 0.01 101.325 1.78 ± 0.71
C2H4 (1) ethane 74-85-1

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
294.2 101.325 1.21
294.2 101.325 1.40

2 Diffusion of ethene (1); water (2)
C2H4 (1) ethane 74-85-1

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 1.36 ± 0.05
303.15 101.325 1.76 ± 0.05
C2H4 (1) ethane 74-85-1

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
288.15 101.325 1.10
288.15 101.325 1.31 *
293.15 101.325 1.32
293.15 101.325 1.68 *
298.15 101.325 1.59
298.15 101.325 2.00 *
References
1968H4 Huq, A., Wood, T.: J. Chem. Eng. Data 13 (1968) 256–259.
1966D3 Dun, P.W., Wood, T.: J. Appl. Chem. 16 (1966) 336–338.

Diffusion of ethane (1); tetrachloro-methane (2) 1
Diffusion of ethane (1); tetrachloro-methane (2)

Vapor in Liquid
C2H6 (1) ethane 74-84-0

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 2.36
308.15 101.325 2.79
Reference

Diffusion of ethane (1); methanol (2) 1
Diffusion of ethane (1); methanol (2)

Vapor in Liquid
C2H6 (1) ethane 74-84-0

T [K] p [kPa] D · 109 [m2/s]
279.3 101.325 3.30 ± 0.02
298.2 101.325 4.38 ± 0.03
313.2 101.325 5.29 ± 0.05
333.2 101.325 6.8 ± 0.1
348.2 101.325 8.19 ± 0.03
Reference

Diffusion of ethane (1); acetonitrile (2) 1
Diffusion of ethane (1); acetonitrile (2)

Vapor in Liquid
C2H6 (1) ethane 74-84-0

C2H3N (2) acetonitrile 75-05-8
T [K] p [kPa] D · 109 [m2/s]
280.6 101.325 4.58 ± 0.03
298.2 101.325 5.76 ± 0.01
323.2 101.325 7.61 ± 0.02
343.2 101.325 9.19 ± 0.07
363.2 101.325 11.1 ± 0.1
Reference

Diffusion of ethane (1); cyclohexane (2) 1
Diffusion of ethane (1); cyclohexane (2)

Vapor in Liquid
C2H6 (1) ethane 74-84-0

T [K] p [kPa] D · 109 [m2/s]
280.6 101.325 2.13 ± 0.01
298.2 101.325 2.92 ± 0.01
323.2 101.325 4.48 ± 0.02
343.2 101.325 5.66 ± 0.02
363.2 101.325 7.27 ± 0.05
Reference

Diffusion of ethane (1); heptane (2) 1
Diffusion of ethane (1); heptane (2)

Vapor in Liquid
C2H6 (1) ethane 74-84-0

C7H16 (2) heptane 142-82-5
T [K] p [kPa] D · 109 [m2/s]
303.15 101.325 5.60
313.15 101.325 6.70
Reference

Diffusion of ethane (1); 2,2,4-trimethyl-pentane (2) 1
Diffusion of ethane (1); 2,2,4-trimethyl-pentane (2)

Vapor in Liquid
C2H6 (1) ethane 74-84-0

T [K] p [kPa] D · 109 [m2/s]
280.7 101.325 3.68 ± 0.01
298.2 101.325 4.65 ± 0.01
323.2 101.325 6.45 ± 0.03
348.2 101.325 8.36 ± 0.05
373.2 101.325 10.9 ± 0.1
Reference

Diffusion of ethane (1); tris-nonafluorobutyl-amine (2) 1
Diffusion of ethane (1); tris-nonafluorobutyl-amine (2)

Vapor in Liquid
C2H6 (1) ethane 74-84-0

T [K] p [kPa] D · 109 [m2/s]
288.15 101.325 1.19
298.15 101.325 1.85
308.15 101.325 2.60
313.15 101.325 2.96
Reference

Diffusion of ethane (1); water (2) 1
Diffusion of ethane (1); water (2)

Vapor in Liquid
C2H6 (1) ethane 74-84-0

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
297.95 ± 0.01 101.325 1.52 ± 0.03
303.05 ± 0.01 101.325 1.59 ± 0.025
308.25 ± 0.01 101.325 1.72 ± 0.02
315.75 ± 0.01 101.325 1.95 ± 0.03
C2H6 (1) ethane 74-84-0

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
277.15 101.325 0.69 ± 0.01
293.15 101.325 1.20 ± 0.06
313.15 101.325 1.94 ± 0.04
333.15 101.325 2.94 ± 0.12
C2H6 (1) ethane 74-84-0

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.01 101.325 1.53 ± 0.03
313.15 ± 0.01 101.325 2.02 ± 0.10
C2H6 (1) ethane 74-84-0

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
288.15 101.325 1.16
288.15 101.325 1.40 *
293.15 101.325 1.40
293.15 101.325 1.68 *
298.15 101.325 1.71
298.15 101.325 1.88 *

2 Diffusion of ethane (1); water (2)
C2H6 (1) ethane 74-84-0

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
283.15 ± 0.1 101.325 1.6
293.15 ± 0.1 101.325 2.3
303.15 ± 0.1 101.325 2.8
313.15 ± 0.1 101.325 3.3
323.15 ± 0.1 101.325 4.1
333.15 ± 0.1 101.325 4.9
C2H6 (1) ethane 74-84-0

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: OEC Ref.: 1963S3
T [K] p [kPa] D · 109 [m2/s]
303.05 101.325 1.59 ± 0.01
C2H6 (1) ethane 74-84-0

H 2O (2) water 7732-18-5
Equation: D = A · exp[– B / RT ] Range: 283 < T/K < 333
2.0 3980 *
References
1963S3 Saraf, D.N., Witherspoon, P.A., Cohen, L.H.: Science 142 (1963) 955–956.

Diffusion of 2-amino-ethanol (1); water (2) 1
Diffusion of 2-amino-ethanol (1); water (2)

Vapor in Liquid
C2H7NO (1) 2-amino-ethanol 141-43-5

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 0.856
Reference
1968D2 da Silva, A.T., Danckwerts, P.V.: Inst. Chem. Eng., Symp. Ser. 28 (1968) 48–56.

Diffusion of propene (1); acetic acid (2) 1
Diffusion of propene (1); acetic acid (2)

Vapor in Liquid
C3H6 (1) propene 115-07-1

Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: CC Ref.: 1990W3
T [K] p [kPa] D · 109 [m2/s]
293.2 101.325 1.60 ± 0.03
298.2 101.325 1.76 ± 0.05
323.2 101.325 2.69 ± 0.09
Reference
1990W3 Wong, C.F., Hayduk, W.: Can. J. Chem. Eng. 68 (1990) 849–859.

Diffusion of propene (1); ethane-1,2-diol (2) 1
Diffusion of propene (1); ethane-1,2-diol (2)

Vapor in Liquid
C3H6 (1) propene 115-07-1

C2H6O2 (2) ethane-1,2-diol 107-21-1
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: TAYLOR Ref.: 1990W4
T [K] p [kPa] D · 109 [m2/s]
348.2 344.6 0.756 ± 0.003
323.2 379.0 0.437 ± 0.003
298.2 447.9 0.203 ± 0.001
323.2 1378.2 0.433 ± 0.002
348.2 1378.2 0.750 ± 0.002
323.2 2687.6 0.431 ± 0.002
348.2 2894.3 0.740 ± 0.008
298.2 3424.9 0.202 ± 0.001
298.2 3721.2 0.189 ± 0.001
323.2 4134.7 0.426 ± 0.005
348.2 4134.7 0.721 ± 0.008
298.2 6753.3 0.188 ± 0.001
348.2 6753.3 0.692 ± 0.001
323.2 6891.2 0.419 ± 0.002
Reference
1990W4 Wong, C.-F., Hayduk, W.: J. Chem. Eng. Data 35 (1990) 323–328.

Diffusion of propene (1); propan-2-one (2) 1
Diffusion of propene (1); propan-2-one (2)

Vapor in Liquid
C3H6 (1) propene 115-07-1

T [K] p [kPa] D · 109 [m2/s]
278.2 101.325 4.84 ± 0.07
288.2 101.325 5.44 ± 0.09
298.2 101.325 6.19 ± 0.09
Reference

Diffusion of propene (1); N,N-dimethyl-formamide (2) 1
Diffusion of propene (1); N,N-dimethyl-formamide (2)

Vapor in Liquid
C3H6 (1) propene 115-07-1

T [K] p [kPa] D · 109 [m2/s]
278.2 101.325 1.44 ± 0.03
298.2 101.325 1.88 ± 0.05
323.2 101.325 2.65 ± 0.06
Reference

Diffusion of propene (1); acetic acid ethyl ester (2) 1
Diffusion of propene (1); acetic acid ethyl ester (2)

Vapor in Liquid
C3H6 (1) propene 115-07-1

T [K] p [kPa] D · 109 [m2/s]
278.2 101.325 3.70 ± 0.09
288.2 101.325 4.29 ± 0.14
298.2 101.325 4.98 ± 0.13
323.2 101.325 6.86 ± 0.21
Reference

Diffusion of propene (1); butan-1-ol (2) 1
Diffusion of propene (1); butan-1-ol (2)

Vapor in Liquid
C3H6 (1) propene 115-07-1

C4H10O (2) butan-1-ol 71-36-3
T [K] p [kPa] D · 109 [m2/s]
278.2 101.325 0.83 ± 0.02
298.2 101.325 1.34 ± 0.03
323.2 101.325 2.36 ± 0.02
C3H6 (1) propene 115-07-1

C4H10O (2) butan-1-ol 71-36-3
T [K] p [kPa] D · 109 [m2/s]
298.2 101.325 1.35 ± 0.01
323.2 101.325 2.40 ± 0.04
298.2 137.8 1.35 ± 0.01
348.2 137.8 3.89 ± 0.03
323.2 172.3 2.40 ± 0.04
348.2 468.6 3.86 ± 0.07
298.2 1722.8 1.31 ± 0.01
323.2 2411.9 2.30 ± 0.04
348.2 3376.7 3.69 ± 0.04
298.2 3790.1 1.24 ± 0.03
323.2 3790.1 2.24 ± 0.05
348.2 5444.0 3.53 ± 0.05
298.2 5512.9 1.21 ± 0.02
323.2 5512.9 2.19 ± 0.02
323.2 6546.6 2.16 ± 0.02
348.2 6822.2 3.45 ± 0.04
298.2 6891.2 1.17 ± 0.03
References

Diffusion of propene (1); chlorobenzene (2) 1
Diffusion of propene (1); chlorobenzene (2)

Vapor in Liquid
C3H6 (1) propene 115-07-1

T [K] p [kPa] D · 109 [m2/s]
298.2 101.325 2.44 ± 0.01
323.2 101.325 3.40 ± 0.01
323.2 117.2 3.40 ± 0.01
348.2 117.2 4.35 ± 0.05
298.2 124.0 2.44 ± 0.01
298.2 1033.7 2.42 ± 0.01
348.2 1378.2 4.29 ± 0.07
323.2 1585.0 3.33 ± 0.03
348.2 2480.8 4.19 ± 0.03
298.2 3445.6 2.40 ± 0.01
323.2 4272.5 3.24 ± 0.02
348.2 4582.6 4.09 ± 0.04
323.2 5857.5 3.19 ± 0.02
298.2 6202.0 2.33 ± 0.02
348.2 6271.0 4.03 ± 0.02
C3H6 (1) propene 115-07-1

T [K] p [kPa] D · 109 [m2/s]
278.2 101.325 1.80 ± 0.06
298.2 101.325 2.41 ± 0.09
323.2 101.325 3.37 ± 0.06
References

Diffusion of propene (1); toluene (2) 1
Diffusion of propene (1); toluene (2)

Vapor in Liquid
C3H6 (1) propene 115-07-1

C7H8 (2) toluene 108-88-3
T [K] p [kPa] D · 109 [m2/s]
298 ± 0.1 101.325 2.20
298 ± 0.1 101.325 2.43
298 ± 0.1 101.325 2.18
308 ± 0.1 101.325 2.97
308 ± 0.1 101.325 2.89
308 ± 0.1 101.325 2.93
318 ± 0.1 101.325 3.85
318 ± 0.1 101.325 4.21
328 ± 0.1 101.325 5.07
328 ± 0.1 101.325 5.11
Reference

Diffusion of propene (1); octane (2) 1
Diffusion of propene (1); octane (2)

Vapor in Liquid
C3H6 (1) propene 115-07-1

C8H18 (2) octane 111-65-9
T [K] p [kPa] D · 109 [m2/s]
298.2 101.325 3.42 ± 0.00
323.2 101.325 4.78 ± 0.05
298.2 103.4 3.42 ± 0.00
323.2 103.4 4.78 ± 0.05
348.2 137.8 6.41 ± 0.06
348.2 1447.1 6.26 ± 0.08
298.2 2274.1 3.21 ± 0.03
323.2 2274.1 4.67 ± 0.05
348.2 2274.1 6.16 ± 0.02
298.2 3101.0 3.18 ± 0.02
323.2 3101.0 4.60 ± 0.04
348.2 3514.5 6.01 ± 0.06
323.2 4444.8 4.52 ± 0.04
298.2 5099.5 3.07 ± 0.03
323.2 5685.2 4.43 ± 0.04
348.2 5995.3 5.71 ± 0.04
298.2 6202.0 3.01 ± 0.03
348.2 6753.3 5.63 ± 0.05
323.2 6856.7 4.32 ± 0.01
C3H6 (1) propene 115-07-1

C8H18 (2) octane 111-65-9
T [K] p [kPa] D · 109 [m2/s]
278.2 101.325 2.59 ± 0.07
298.2 101.325 3.41 ± 0.09
323.2 101.325 4.78 ± 0.07
References

Diffusion of propene (1); hexadecane (2) 1
Diffusion of propene (1); hexadecane (2)

Vapor in Liquid
C3H6 (1) propene 115-07-1

T [K] p [kPa] D · 109 [m2/s]
323.9 101.325 5.41 ± 0.33
Reference

Diffusion of propene (1); water (2) 1
Diffusion of propene (1); water (2)

Vapor in Liquid
C3H6 (1) propene 115-07-1

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298 101.325 1.08
298 101.325 1.24
C3H6 (1) propene 115-07-1

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.2 101.325 1.44 ± 5%
C3H6 (1) propene 115-07-1

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
280.15 101.325 0.376
298.15 101.325 0.681
308.15 101.325 0.895
326.15 101.325 1.373
338.15 101.325 1.868
C3H6 (1) propene 115-07-1

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.01 101.325 1.10
313.15 ± 0.01 101.325 2.22
References

Diffusion of propan-2-one (1); succinonitrile (2) 1
Diffusion of propan-2-one (1); succinonitrile (2)

Vapor in Liquid

C4H4N2 (2) succinonitrile 110-61-2
T [K] p [kPa] D · 109 [m2/s]
331.08 ± 0.1 101.325 1.27
Reference

Diffusion of propane (1); propan-2-ol (2) 1
Diffusion of propane (1); propan-2-ol (2)

Vapor in Liquid
C3H8 (1) propane 74-98-6

C3H8O (2) propan-2-ol 67-63-0
T [K] p [kPa] D · 109 [m2/s]
300.0 101.325 1.57 ± 0.07
Reference
2347–2353.

Diffusion of propane (1); tetrahydrofuran (2) 1
Diffusion of propane (1); tetrahydrofuran (2)

Vapor in Liquid
C3H8 (1) propane 74-98-6

T [K] p [kPa] D · 109 [m2/s]
300.0 101.325 3.33 ± 0.10
Reference
2347–2353.

Diffusion of propane (1); heptan-1-ol (2) 1
Diffusion of propane (1); heptan-1-ol (2)

Vapor in Liquid
C3H8 (1) propane 74-98-6

C7H16O (2) heptan-1-ol 111-70-6
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 0.88
Reference

Diffusion of propane (1); octan-1-ol (2) 1
Diffusion of propane (1); octan-1-ol (2)

Vapor in Liquid
C3H8 (1) propane 74-98-6

C8H18O (2) octan-1-ol 111-87-5
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 0.81
Reference

Diffusion of propane (1); water (2) 1
Diffusion of propane (1); water (2)

Vapor in Liquid
C3H8 (1) propane 74-98-6

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.01 101.325 1.27 ± 0.04
313.15 ± 0.01 101.325 1.63 ± 0.09
C3H8 (1) propane 74-98-6

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
283.15 ± 0.1 101.325 1.3
293.15 ± 0.1 101.325 1.8
303.15 ± 0.1 101.325 2.4
313.15 ± 0.1 101.325 2.7
323.15 ± 0.1 101.325 3.5
333.15 ± 0.1 101.325 4.4
C3H8 (1) propane 74-98-6

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
303.05 101.325 1.28 ± 0.02
C3H8 (1) propane 74-98-6

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
277.15 101.325 0.55 ± 0.03
293.15 101.325 0.97 ± 0.02
313.15 101.325 1.77 ± 0.04
333.15 101.325 2.71 ± 0.05
C3H8 (1) propane 74-98-6

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
297.95 ± 0.01 101.325 1.21 ± 0.04
303.05 ± 0.01 101.325 1.27 ± 0.02
(continued)

2 Diffusion of propane (1); water (2)
308.25 ± 0.01 101.325 1.39 ± 0.01

315.75 ± 0.01 101.325 1.59 ± 0.02
C3H8 (1) propane 74-98-6

H 2O (2) water 7732-18-5
Equation: D = A · exp[–B / RT ] Range: 283 < T/K < 333
3.1 4350 *
References

Diffusion of 2-methyl-propene (1); 1,2-benzenedicarboxylic acid dinonyl ester (2) 1
Diffusion of 2-methyl-propene (1); 1,2-benzenedicarboxylic

acid dinonyl ester (2)
Vapor in Liquid

C26H42O4 (2) 1,2-benzenedicarboxylic acid dinonyl ester 84-76-4
T [K] p [atm] D · 109 [m2/s]
273.15 0.0395 0.026
288.15 0.0395 0.055
298.15 0.0395 0.088
323.15 0.0395 0.25
348.15 0.0395 0.61

C26H42O4 (2) 1,2-benzenedicarboxylic acid dinonyl ester 84-76-4
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: OEC Ref.: 1961H1
T [K] p [kPa] D · 1011 [m2/s]
273.15 ± 0.05 101.325 2.6 ± 5%
288.15 ± 0.05 101.325 5.5 ± 5%
298.15 ± 0.05 101.325 8.8 ± 5%
323.15 ± 0.05 101.325 25.0 ± 5%
348.15 ± 0.05 101.325 61.0 ± 5%
References
1961H1 Houghton, G., Kesten, A.S., Funk, J.E., Coull, J.: J. Phys. Chem. 65 (1961) 649–654.

Diffusion of but-1-ene (1); water (2) 1
Diffusion of but-1-ene (1); water (2)

Vapor in Liquid
C4H8 (1) but-1-ene 106-98-9

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
280.15 101.325 5.157
298.15 101.325 6.612
313.15 101.325 9.485
333.15 101.325 12.48
Reference

Diffusion of butane (1); tetrahydrofuran (2) 1
Diffusion of butane (1); tetrahydrofuran (2)

Vapor in Liquid
C4H10 (1) butane 106-97-8

T [K] p [kPa] D · 109 [m2/s]
300.0 101.325 3.01 ± 0.07
Reference
2347–2353.

Diffusion of butane (1); water (2) 1
Diffusion of butane (1); water (2)

Vapor in Liquid
C4H10 (1) butane 106-97-8

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
283.15 ± 0.1 101.325 0.83
293.15 ± 0.1 101.325 1.4
303.15 ± 0.1 101.325 1.9
313.15 ± 0.1 101.325 2.5
323.15 ± 0.1 101.325 3.3
333.15 ± 0.1 101.325 4.3
C4H10 (1) butane 106-97-8

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
277.15 101.325 0.50 ± 0.02
293.15 101.325 0.89 ± 0.04
313.15 101.325 1.59 ± 0.04
333.15 101.325 2.51 ± 0.05
C4H10 (1) butane 106-97-8

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
297.95 ± 0.01 101.325 0.96 ± 0.04
303.05 ± 0.01 101.325 1.03 ± 0.025
308.25 ± 0.01 101.325 1.12 ± 0.03
315.75 ± 0.01 101.325 1.28 ± 0.01
C4H10 (1) butane 106-97-8

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
303.05 101.325 1.03 ± 0.02
C4H10 (1) butane 106-97-8

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.01 101.325 0.97 ± 0.04

2 Diffusion of butane (1); water (2)
C4H10 (1) butane 106-97-8

H 2O (2) water 7732-18-5
38.4 6010 *
References

Diffusion of bis-(2-hydroxy-ethyl)-amine (1); water (2) 1
Diffusion of bis-(2-hydroxy-ethyl)-amine (1); water (2)

Vapor in Liquid
C4H11NO2 (1) bis-(2-hydroxy-ethyl)-amine 111-42-2

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 0.486
Reference

Diffusion of 2,2-dimethyl-propane (1); decane (2) 1
Diffusion of 2,2-dimethyl-propane (1); decane (2)

Vapor in Liquid

C10H22 (2) decane 124-18-5
T [K] p [atm] D · 109 [m2/s]
298.15 3 1.71 ± 0.01
Reference

Diffusion of 2,2-dimethyl-propane (1); tetradecane (2) 1
Diffusion of 2,2-dimethyl-propane (1); tetradecane (2)

Vapor in Liquid

T [K] p [atm] D · 109 [m2/s]
298.15 3 0.842 ± 0.006
Reference

Diffusion of 2,2-dimethyl-propane (1); water (2) 1
Diffusion of 2,2-dimethyl-propane (1); water (2)

Vapor in Liquid

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.02 101.325 0.97 ± 0.009
Reference
1972T2 Tham, M.K., Gubbins, K.E.: J. Chem. Soc. Faraday Trans. 1 68 (1972) 1339–1346.

Diffusion of pentane (1); water (2) 1
Diffusion of pentane (1); water (2)

Vapor in Liquid
C5H12 (1) pentane 109-66-0

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
277.15 101.325 0.46 ± 0.02
293.15 101.325 0.84 ± 0.04
313.15 101.325 1.49 ± 0.03
333.15 101.325 2.24 ± 0.10
Reference

Diffusion of bis-(2-hydroxy-propyl)-amine (1); water (2) 1
Diffusion of bis-(2-hydroxy-propyl)-amine (1); water (2)

Vapor in Liquid
C6H15NO2 (1) bis-(2-hydroxy-propyl)-amine 110-97-4

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 0.453
Reference

Diffusion of 1,4-dimethyl-benzene (1); trichloro-methane (2) 1
Diffusion of 1,4-dimethyl-benzene (1); trichloro-methane

(2)
Vapor in Liquid

Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: TAYLOR Ref.: 1975O2
T [K] p [kPa] D · 109 [m2/s]
276.5 ± 0.05 101.325 1.60
283 ± 0.05 101.325 1.90
293 ± 0.05 101.325 2.10
313 ± 0.05 101.325 2.50
Reference
1975O2 Ouano, A.C., Carothers, J.A.: J. Phys. Chem. 79 (1975) 1314–1318.

Diffusion of cis-octadec-9-enoic acid propane-1,2,3-triyl ester (1); tridecane (2) 1
Diffusion of cis-octadec-9-enoic acid propane-1,2,3-triyl

ester (1); tridecane (2)
Vapor in Liquid

C13H28 (2) tridecane 629-50-5
T [K] p [kPa] D · 1011 [m2/s]
298.15 101.325 18.45 ± 1%
Reference
1981A2 Amu, T.C.: J. Chem. Eng. Data 26 (1981) 241–242.

Diffusion of hydrogen chloride (1); trans-1,2-dichloro-ethene (2) 1
Diffusion of hydrogen chloride (1); trans-1,2-dichloro-

ethene (2)
Vapor in Liquid
ClH (1) hydrogen chloride 7647-01-0

C2H2Cl2 (2) trans-1,2-dichloro-ethene 156-60-5
T [K] p [kPa] D · 109 [m2/s]
288.0 ± 0.05 101.325 3.18 ± 7.6%
298.5 ± 0.05 101.325 3.89 ± 7.6%
303.0 ± 0.05 101.325 4.31 ± 7.6%
Reference

Diffusion of hydrogen chloride (1); ethane-1,2-diol (2) 1
Diffusion of hydrogen chloride (1); ethane-1,2-diol (2)

Vapor in Liquid

C2H6O2 (2) ethane-1,2-diol 107-21-1
Integral Diffusion Coefficient: D (T ); Method: DIA Ref.: 1973C9
T [K] c1 [mol·cm–3] D · 109 [m2/s]
298.15 ± 0.05 0.370 0.161 ± 0.5%
303.15 ± 0.05 0.358 0.175 ± 0.5%
308.15 ± 0.05 0.348 0.202 ± 0.5%
313.15 ± 0.05 0.336 0.239 ± 0.5%
318.15 ± 0.05 0.325 0.280 ± 0.5%
Comment: saturation concentration of solute in g-mol/cm3
Reference
1973C9 Clegg, G.T., Tehrani, M.A.: J. Chem. Eng. Data 18 (1973) 59–60.

Diffusion of hydrogen chloride (1); nitrobenzene (2) 1
Diffusion of hydrogen chloride (1); nitrobenzene (2)

Vapor in Liquid

T [K] p [kPa] D · 109 [m2/s]
299.0 ± 0.05 101.325 1.75 ± 7.6%
303.0 ± 0.05 101.325 2.15 ± 7.6%
313.0 ± 0.05 101.325 2.38 ± 7.6%
323.0 ± 0.05 101.325 2.68 ± 7.6%
331.5 ± 0.05 101.325 2.92 ± 7.6%
Reference

Diffusion of chlorine (1); tetrachloro-methane (2) 1
Diffusion of chlorine (1); tetrachloro-methane (2)

Vapor in Liquid
Cl2 (1) chlorine 7782-50-5

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 2.88
308.15 101.325 3.34
Cl2 (1) chlorine 7782-50-5

Integral Diffusion Coefficient: D (T ); Method: DIA Ref.: 1973C9
T [K] c1 [mol·cm–3] D · 109 [m2/s]
298.15 ± 0.05 0.130 2.88 ± 0.5%
303.15 ± 0.05 0.115 3.17 ± 0.5%
308.15 ± 0.05 0.104 3.34 ± 0.5%
313.15 ± 0.05 0.091 3.61 ± 0.5%
318.15 ± 0.05 0.079 3.86 ± 0.5%
Comment: saturation concentration of solute in g-mol/cm3
References
1973C9 Clegg, G.T., Tehrani, M.A.: J. Chem. Eng. Data 18 (1973) 59–60.

Diffusion of chlorine (1); water (2) 1
Diffusion of chlorine (1); water (2)

Vapor in Liquid
Cl2 (1) chlorine 7782-50-5

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 1.38
308.15 101.325 1.63
318.15 101.325 2.44
333.15 101.325 3.11
Cl2 (1) chlorine 7782-50-5

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
283.15 101.325 0.91
286.15 101.325 0.98
291.45 101.325 1.20
293.15 101.325 1.22
295.55 101.325 1.32
298.15 101.325 1.42
303.15 101.325 1.62
308.15 101.325 1.81
Cl2 (1) chlorine 7782-50-5

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s
283.15 101.325 0.91 ± 6%
283.15 101.325 0.97
286.15 101.325 0.98 ± 6%
288.15 101.325 1.14
288.15 101.325 1.13
289.45 101.325 1.27
291.45 101.325 1.20 ± 6%
293.15 101.325 1.22 ± 6%
298.15 101.325 1.42 ± 6%
298.15 101.325 1.51
298.15 101.325 1.48
303.15 101.325 1.74
303.15 101.325 1.62 ± 6%
308.15 101.325 1.81 ± 6%

2 Diffusion of chlorine (1); water (2)
Cl2 (1) chlorine 7782-50-5

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
303.0 ± 0.05 101.325 1.59 ± 7.6%
Cl2 (1) chlorine 7782-50-5

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 1.63
References
1985T1 Tang, A., Sandall, O.C.: J. Chem. Eng. Data 30 (1985) 189–191.
1959K1 Kramers, H., Douglas, R.A., Ulman, R.M.: Chem. Eng. Science 10 (1959) 190.

Diffusion of phosgene (1); water (2) 1
Diffusion of phosgene (1); water (2)

Vapor in Liquid
Cl2CO (1) phosgene 75-44-5

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: LAM Ref.: 1960M4
T [K] p [kPa] D · 109 [m2/s]
288.15 ± 0.2 101.325 0.96
298.15 ± 0.2 101.325 1.27
308.15 ± 0.2 101.325 1.61
318.65 ± 0.2 101.325 2.04
Reference
1960M4 Manogue, W.H., Pigford, R.L.: AIChE J. 6 (1960) 494–500.

Diffusion of deuterium (1); tetrachloro-methane (2) 1
Diffusion of deuterium (1); tetrachloro-methane (2)

Vapor in Liquid
D2 (1) deuterium 7782-39-0

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 7.80 ± 5%
D2 (1) deuterium 7782-39-0

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 7.70
References

Diffusion of deuterium (1); tris-nonafluorobutyl-amine (2) 1
Diffusion of deuterium (1); tris-nonafluorobutyl-amine (2)

Vapor in Liquid
D2 (1) deuterium 7782-39-0

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 5.54
Reference

Diffusion of sulfur hexafluoride (1); tetrachloro-methane (2) 1
Diffusion of sulfur hexafluoride (1); tetrachloro-methane (2)

Vapor in Liquid

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 1.78
308.15 101.325 2.07

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 1.71

Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: GEL Ref.: 1995K6
Equation: D = A · exp[–B / RT ] Range: 278.15 < T/K < 298.15
Parameter: A · 104 B · 10–3 Std-Dev.
0.029 19.3 4.5%
References
1995K6 King, D.B., Saltzman, E.S.: J. Geophys. Res. 100(C4) (1995) 7083–7088.

Diffusion of hydrogen (1); tetrachloro-methane (2) 1
Diffusion of hydrogen (1); tetrachloro-methane (2)

Vapor in Liquid
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 109 [m2/s]
278.15 101.325 7.64
298.15 101.325 12.0
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 109 [m2/s]
273.15 101.325 6.28 ± 5%
298.15 101.325 9.75 ± 5%
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 109 [m2/s]
298 101.325 9.87 ± 5.8%
Comment: method: dissolution of gas bubble in liquid
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 9.75
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 109 [m2/s]
298.0 ± 0.05 101.325 10.5 ± 5.8%
References
1971S9 Sporka, K., Hanika, J., Ruzicka, V., Halousek, M.: Collect. Czech. Chem. Commun. 36 (1971)
2130–2136.
1969S10 Sporka, K., Hanika, J., Ruzicka, V.: Collect. Czech. Chem. Commun. 34 (1969) 3145–3148.

Diffusion of hydrogen (1); methanol (2) 1
Diffusion of hydrogen (1); methanol (2)

Vapor in Liquid
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 109 [m2/s]
293 101.325 17.18 ± 4.5%
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 109 [m2/s]
293.0 ± 0.05 101.325 16.5 ± 4.5%
References
2130–2136.

Diffusion of hydrogen (1); ethanol (2) 1
Diffusion of hydrogen (1); ethanol (2)

Vapor in Liquid
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 109 [m2/s]
293 101.325 14.90 ± 5.8%
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 109 [m2/s]
293.0 ± 0.05 101.325 15.1 ± 5.8%
References
2130–2136.

Diffusion of hydrogen (1); propan-2-one (2) 1
Diffusion of hydrogen (1); propan-2-one (2)

Vapor in Liquid
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 109 [m2/s]
298 101.325 41.67 ± 8.10%
Reference
2130–2136.

Diffusion of hydrogen (1); propan-1-ol (2) 1
Diffusion of hydrogen (1); propan-1-ol (2)

Vapor in Liquid
H2 (1) hydrogen 1333-74-0

C3H8O (2) propan-1-ol 71-23-8
T [K] p [kPa] D · 109 [m2/s]
298 101.325 12.84 ± 6.2%
H2 (1) hydrogen 1333-74-0

C3H8O (2) propan-1-ol 71-23-8
T [K] p [kPa] D · 109 [m2/s]
298.0 ± 0.05 101.325 11.9 ± 6.2%
References
2130–2136.

Diffusion of hydrogen (1); 2-methyl-propan-1-ol (2) 1
Diffusion of hydrogen (1); 2-methyl-propan-1-ol (2)

Vapor in Liquid
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 109 [m2/s]
293 101.325 7.93 ± 3.9%
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 109 [m2/s]
293.0 ± 0.05 101.325 7.9 ± 3.9%
References
2130–2136.

Diffusion of hydrogen (1); pentan-1-ol (2) 1
Diffusion of hydrogen (1); pentan-1-ol (2)

Vapor in Liquid
H2 (1) hydrogen 1333-74-0

C5H12O (2) pentan-1-ol 71-41-0
T [K] p [kPa] D · 109 [m2/s]
293 101.325 16.35 ± 3.1%
H2 (1) hydrogen 1333-74-0

C5H12O (2) pentan-1-ol 71-41-0
T [K] p [kPa] D · 109 [m2/s]
293.0 ± 0.05 101.325 20.4 ± 3.1%
References
2130–2136.

Diffusion of hydrogen (1); 1,2-dichloro-benzene (2) 1
Diffusion of hydrogen (1); 1,2-dichloro-benzene (2)

Vapor in Liquid
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 109 [m2/s]
303.15 101.325 6.3 ± 0.1
Reference

Diffusion of hydrogen (1); benzene (2) 1
Diffusion of hydrogen (1); benzene (2)

Vapor in Liquid
H2 (1) hydrogen 1333-74-0

C6H6 (2) benzene 71-43-2
T [K] p [kPa] D · 109 [m2/s]
298 101.325 20.02 ± 6.90%
Reference
2130–2136.

Diffusion of hydrogen (1); cyclohexene (2) 1
Diffusion of hydrogen (1); cyclohexene (2)

Vapor in Liquid
H2 (1) hydrogen 1333-74-0

C6H10 (2) cyclohexene 110-83-8
T [K] p [kPa] D · 109 [m2/s]
298 101.325 22.44 ± 5.68%
Reference
2130–2136.

Diffusion of hydrogen (1); cyclohexane (2) 1
Diffusion of hydrogen (1); cyclohexane (2)

Vapor in Liquid
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 109 [m2/s]
298 101.325 9.63
298 101.325 9.11
298 101.325 9.21
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 109 [m2/s]
298 101.325 17.32 ± 7.40%
References
2130–2136.

Diffusion of hydrogen (1); cyclohexanol (2) 1
Diffusion of hydrogen (1); cyclohexanol (2)

Vapor in Liquid
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 109 [m2/s]
303.15 101.325 1.35 ± 0.06
Reference

Diffusion of hydrogen (1); hexane (2) 1
Diffusion of hydrogen (1); hexane (2)

Vapor in Liquid
H2 (1) hydrogen 1333-74-0

C6H14 (2) hexane 110-54-3
T [K] p [kPa] D · 109 [m2/s]
298 101.325 62.38 ± 7.6%
Reference
2130–2136.

Diffusion of hydrogen (1); heptane (2) 1
Diffusion of hydrogen (1); heptane (2)

Vapor in Liquid
H2 (1) hydrogen 1333-74-0

C7H16 (2) heptane 142-82-5
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 1.0 1014 24.0 ± 1.2
427.15 ± 1.0 3448 70.7 ± 0.3
H2 (1) hydrogen 1333-74-0

C7H16 (2) heptane 142-82-5
T [K] p [kPa] D · 109 [m2/s]
298 101.325 50.12 ± 11.9%
References
2130–2136.

Diffusion of hydrogen (1); octane (2) 1
Diffusion of hydrogen (1); octane (2)

Vapor in Liquid
H2 (1) hydrogen 1333-74-0

C8H18 (2) octane 111-65-9
T [K] p [kPa] D · 109 [m2/s]
298 101.325 44.89 ± 5.55%
Reference
2130–2136.

Diffusion of hydrogen (1); tris-nonafluorobutyl-amine (2) 1
Diffusion of hydrogen (1); tris-nonafluorobutyl-amine (2)

Vapor in Liquid
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 109 [m2/s]
278.15 101.325 6.59
283.15 101.325 6.98
298.15 101.325 8.21
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 6.52
References

Diffusion of hydrogen (1); dodecane (2) 1
Diffusion of hydrogen (1); dodecane (2)

Vapor in Liquid
H2 (1) hydrogen 1333-74-0

C12H26 (2) dodecane 112-40-3
T [K] p [kPa] D · 109 [m2/s]
304.15 ± 1.0 1393 10.9 ± 0.2
372.15 ± 1.0 1412 27.1 ± 1.2
372.15 ± 1.0 3444 24.9 ± 0.8
445.15 ± 1.0 1445 46.3 ± 0.03
443.15 ± 1.0 3454 41.0 ± 1.0
513.15 ± 1.0 1451 78.0 ± 4.8
515.15 ± 1.0 3435 70.3 ± 1.3
567.15 ± 1.0 1463 118 ± 2.0
566.15 ± 1.0 3439 112 ± 1.0
Reference

Diffusion of hydrogen (1); hexadecane (2) 1
Diffusion of hydrogen (1); hexadecane (2)

Vapor in Liquid
H2 (1) hydrogen 1333-74-0

T [K] p [kPa] D · 109 [m2/s]
323.15 ± 1.0 1421 10.5 ± 0.3
323.15 ± 1.0 3460 10.3 ± 0.6
371.15 ± 1.0 1404 20.8 ± 0.1
371.15 ± 1.0 3439 18.9 ± 0.4
443.15 ± 1.0 1397 35.1 ± 1.6
443.15 ± 1.0 3426 35.2 ± 2.5
513.15 ± 1.0 1412 51.2 ± 2.5
513.15 ± 1.0 3428 49.7 ± 1.7
564.15 ± 1.0 1404 69.0 ± 6.0
564.15 ± 1.0 3409 64.0 ± 4.3
Reference

Diffusion of hydrogen (1); octacosane (2) 1
Diffusion of hydrogen (1); octacosane (2)

Vapor in Liquid
H2 (1) hydrogen 1333-74-0

T [K] p [MPa] D · 109 [m2/s]
371 ± 0.5 1.38 13.4 ± 0.06
414 ± 0.5 1.38 20.5 ± 0.29
455 ± 0.5 1.38 29.3 ± 0.25
495 ± 0.5 1.38 41.0
534 ± 0.5 1.38 51.5 ± 0.27
Reference

Diffusion of hydrogen (1); water (2)

Vapor in Liquid
H2 (1) hydrogen 1333-74-0

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
288.15 101.325 3.30
288.15 101.325 3.67 *
293.15 101.325 3.66
293.15 101.325 4.48 *
298.15 101.325 4.27
298.15 101.325 5.26 *
H2 (1) hydrogen 1333-74-0

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
283.15 ± 0.1 101.325 4.6
293.15 ± 0.1 101.325 5.0
303.15 ± 0.1 101.325 7.0
313.15 ± 0.1 101.325 8.3
323.15 ± 0.1 101.325 9.7
333.15 ± 0.2 101.325 13.1
H2 (1) hydrogen 1333-74-0

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
294.15 101.325 3.81
298.15 101.325 4.06
302.15 101.325 4.38
306.15 101.325 4.70
310.15 101.325 5.07
H2 (1) hydrogen 1333-74-0

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: BUBBLE Ref.: 1981D3
T [K] p [kPa] D · 109 [m2/s]
293.15 ± 0.5 101.325 3.2 ± 0.2
303.15 ± 0.5 101.325 3.9 ± 0.2
313.15 ± 0.5 101.325 4.9 ± 0.3
(continued)

2 Diffusion of hydrogen (1); water (2)
323.15 ± 0.5 101.325 6.1 ± 0.4

333.15 ± 0.5 101.325 7.1 ± 0.5
H2 (1) hydrogen 1333-74-0

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: KMD Ref.: 1975S1
T [K] p [kPa] D · 109 [m2/s]
303.15 101.325 4.49
H2 (1) hydrogen 1333-74-0

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
303.15 101.325 6.4 ± 0.5
H2 (1) hydrogen 1333-74-0

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: EA RDE Ref.: 1970T3
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.01 101.325 3.7 ± 0.13
H2 (1) hydrogen 1333-74-0

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
294.0 ± 0.05 101.325 5.1 ± 1.8%
H2 (1) hydrogen 1333-74-0

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.2 101.325 4.8 ± 4%
H2 (1) hydrogen 1333-74-0

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
297.65 101.325 4.9 ± 10%

H2 (1) hydrogen 1333-74-0

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.2 101.325 4.8 ± 4%
H2 (1) hydrogen 1333-74-0

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 5.94
H2 (1) hydrogen 1333-74-0

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
273.15 101.325 1.96
283.15 101.325 4.34
283.15 101.325 2.80
286.15 101.325 6.72
287.15 101.325 3.41
289.15 101.325 4.73
290.15 101.325 5.13
290.65 101.325 3.40 *
294.15 101.325 5.15
296.15 101.325 3.85
297.65 101.325 4.9
298.15 101.325 3.37
298.15 101.325 7.07
298.15 101.325 3.49
298.65 101.325 4.08 *
303.15 101.325 4.49 *
H2 (1) hydrogen 1333-74-0

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
290.15 101.325 5.20
298.15 101.325 7.07
299.65 101.325 7.10

4 Diffusion of hydrogen (1); water (2)
H2 (1) hydrogen 1333-74-0

H 2O (2) water 7732-18-5
4.9 3960 *
References
1981D3 De Blok, W.J., Fortuin, J.M.H.: Chem. Eng. Science 36 (1981) 1687–1694.
1975S1 Sada, E., Kito, S., Oda, T., Ito, Y.: J. Chem. Eng. J. 10 (1975) 155–159.
1970T3 Tham, M.K., Walker, R.D., Gubbins, K.E.: J. Phys. Chem. 74 (1970) 1747–1751.

Diffusion of hydrogen sulfide (1); water (2) 1
Diffusion of hydrogen sulfide (1); water (2)

Vapor in Liquid

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
293 ± 0.3 101.325 1.75
298 ± 0.3 101.325 1.93
303 ± 0.3 101.325 2.07
313 ± 0.3 101.325 2.55
333 ± 0.3 101.325 3.87
353 ± 0.3 101.325 4.62
368 ± 0.3 101.325 5.49
Comment: average standard deviation: ±0.0161 · 10–9 [m2/s]

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 1.63

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 2.16

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
303.0 ± 0.05 101.325 1.92 ± 7.6%

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 1.34
298.15 101.325 1.48

2 Diffusion of hydrogen sulfide (1); water (2)

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
288.65 101.325 1.43
289.15 101.325 1.77
298.15 101.325 1.36

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: OTE Ref.: 1984H2
T [K] p [kPa] D · 109 [m2/s]
288.15 ± 0.1 101.325 1.53 ± 3.3%
293.15 ± 0.1 101.325 1.75 ± 3.3%
298.15 ± 0.1 101.325 1.89 ± 3.3%
308.15 ± 0.1 101.325 2.32 ± 3.3%
References
1972O2 Onda, K., Takeuchi, H., Kobayashi, T.: Kagaku Kogaku 36 (1972) 903–907.
1984H2 Halmour, N., Sandall, O.C.: J. Chem. Eng. Data 29 (1984) 20–22.

Diffusion of ammonia (1); water (2) 1
Diffusion of ammonia (1); water (2)

Vapor in Liquid
H 3N (1) ammonia 7664-41-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
277.15 101.325 1.23
281.15 101.325 1.09
283.95 101.325 1.16
285.15 101.325 1.64
287.05 101.325 1.22
288.15 101.325 1.29
288.35 101.325 1.78
290.15 101.325 1.84
290.15 101.325 2.23
293.15 101.325 1.46
H 3N (1) ammonia 7664-41-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 1.632
H 3N (1) ammonia 7664-41-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 2.04
References

Diffusion of helium (1); tetrachloro-methane (2) 1
Diffusion of helium (1); tetrachloro-methane (2)

Vapor in Liquid
He (1) helium 7440-59-7

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 20.0
Reference

Diffusion of helium (1); ethanol (2) 1
Diffusion of helium (1); ethanol (2)

Vapor in Liquid
He (1) helium 7440-59-7

Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: KMD Ref.: 1967K5
T [K] p [kPa] D · 109 [m2/s]
302.75 ± 0.2 101.325 14.3 ± 1.2
Reference
1967K5 Krieger, I.M., Mulholland, G.W., Dickey, C.S.: J. Phys. Chem. 71 (1967) 1123–1129.

Diffusion of helium (1); tris-nonafluorobutyl-amine (2) 1
Diffusion of helium (1); tris-nonafluorobutyl-amine (2)

Vapor in Liquid
He (1) helium 7440-59-7

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 13.0
Reference

Diffusion of helium (1); water (2)

Vapor in Liquid
He (1) helium 7440-59-7

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: HOLO Ref.: 1997R4
T [K] p [bar] D · 109 [m2/s]
293.15 40.1 6.17 ± 2%
293.15 45.1 6.03 ± 2%
He (1) helium 7440-59-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
288.15 101.325 5.68
288.15 101.325 7.65 *
293.15 101.325 6.84
293.15 101.325 8.95 *
298.15 101.325 8.02
298.15 101.325 9.50 *
He (1) helium 7440-59-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
273.15 ± 0.1 101.325 1.70 ± 5%
298.15 ± 0.1 101.325 2.38 ± 5%
323.15 ± 0.1 101.325 2.80 ± 5%
He (1) helium 7440-59-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
283.15 ± 0.1 101.325 5.5
293.15 ± 0.1 101.325 6.8
303.15 ± 0.1 101.325 8.0
313.15 ± 0.1 101.325 8.8
323.15 ± 0.1 101.325 11.7
333.15 ± 0.1 101.325 14.9

2 Diffusion of helium (1); water (2)
He (1) helium 7440-59-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
295.25 101.325 5.8 ± 10%
He (1) helium 7440-59-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.2 101.325 6.3 ± 10%
He (1) helium 7440-59-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
295.25 101.325 5.8 ± 10%
He (1) helium 7440-59-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
302.75 ± 0.2 101.325 5.42 ± 0.33
He (1) helium 7440-59-7

H 2O (2) water 7732-18-5
T [K] p [MPa] D · 109 [m2/s]
293.15 4.01 6.17 ± 2%
293.15 4.51 6.03 ± 2%
He (1) helium 7440-59-7

H 2O (2) water 7732-18-5
3.0 3560 *
References
1997R4 Roetzel, W., Blömker, D., Czametzki, W.: High Temperatures-High Pressures 29 (1997)
149–154.

1997R3 Roetzel, W., Blomker, D., Czarnetzki, W.: Chem. Ing. Tech. 69 (1997) 674–678.

Diffusion of iodine (1); tetrachloro-methane (2) 1
Diffusion of iodine (1); tetrachloro-methane (2)

Vapor in Liquid
I2 (1) iodine 7553-56-2

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 1.50
308.15 101.325 1.80
Reference

Diffusion of krypton (1); tetrachloro-methane (2) 1
Diffusion of krypton (1); tetrachloro-methane (2)

Vapor in Liquid
Kr (1) krypton 7439-90-9

T [K] p [atm] D · 109 [m2/s]
298.15 3 2.86 ± 0.04
Reference

Diffusion of krypton (1); methanol (2) 1
Diffusion of krypton (1); methanol (2)

Vapor in Liquid
Kr (1) krypton 7439-90-9

T [K] p [atm] D · 109 [m2/s]
298.15 3 3.93 ± 0.08
Kr (1) krypton 7439-90-9

T [K] p [kPa] D · 109 [m2/s]
298 101.325 5.10 ± 0.003
313 101.325 6.06 ± 0.006
333 101.325 7.52 ± 0.004
383 101.325 12.4 ± 0.01
Kr (1) krypton 7439-90-9

3.035 7155
References

Diffusion of krypton (1); propan-2-one (2) 1
Diffusion of krypton (1); propan-2-one (2)

Vapor in Liquid
Kr (1) krypton 7439-90-9

T [K] p [atm] D · 109 [m2/s]
298.15 3 6.14 ± 0.09
Reference

Diffusion of krypton (1); propan-2-ol (2) 1
Diffusion of krypton (1); propan-2-ol (2)

Vapor in Liquid
Kr (1) krypton 7439-90-9

C3H8O (2) propan-2-ol 67-63-0
T [K] p [atm] D · 109 [m2/s]
298.15 3 2.53 ± 0.05
Reference

Diffusion of krypton (1); butan-1-ol (2) 1
Diffusion of krypton (1); butan-1-ol (2)

Vapor in Liquid
Kr (1) krypton 7439-90-9

C4H10O (2) butan-1-ol 71-36-3
T [K] p [kPa] D · 109 [m2/s]
298 101.325 2.19 ± 0.005
333 101.325 4.10 ± 0.002
373 101.325 7.1 ± 0.01
433 101.325 13.4 ± 0.04
Kr (1) krypton 7439-90-9

C4H10O (2) butan-1-ol 71-36-3
T [K] p [atm] D · 109 [m2/s]
298.15 3 2.19 ± 0.05
Kr (1) krypton 7439-90-9

C4H10O (2) butan-1-ol 71-36-3
7.469 11420
References

Diffusion of krypton (1); benzene (2) 1
Diffusion of krypton (1); benzene (2)

Vapor in Liquid
Kr (1) krypton 7439-90-9

C6H6 (2) benzene 71-43-2
T [K] p [atm] D · 109 [m2/s]
298.15 3 4.32 ± 0.07
Reference

Diffusion of krypton (1); cyclohexane (2) 1
Diffusion of krypton (1); cyclohexane (2)

Vapor in Liquid
Kr (1) krypton 7439-90-9

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 3.57 ± 0.003
313.25 101.325 4.70 ± 0.007
333.35 101.325 6.09 ± 0.006
353.75 101.325 7.7 ± 0.02
374.05 101.325 9.2 ± 0.01
390.85 101.325 11.0 ± 0.02
415.85 101.325 13.4 ± 0.03
Kr (1) krypton 7439-90-9

T [K] p [atm] D · 109 [m2/s]
298.15 3 3.57 ± 0.03
Kr (1) krypton 7439-90-9

3.814 8495
References

Diffusion of krypton (1); hexane (2) 1
Diffusion of krypton (1); hexane (2)

Vapor in Liquid
Kr (1) krypton 7439-90-9

C6H14 (2) hexane 110-54-3
T [K] p [atm] D · 109 [m2/s]
298.15 3 6.30 ± 0.16
Reference

Diffusion of krypton (1); octane (2) 1
Diffusion of krypton (1); octane (2)

Vapor in Liquid
Kr (1) krypton 7439-90-9

C8H18 (2) octane 111-65-9
T [K] p [kPa] D · 109 [m2/s]
298 101.325 5.00 ± 0.004
333 101.325 7.63 ± 0.001
373 101.325 10.96 ± 0.006
403 101.325 14.0 ± 0.01
Kr (1) krypton 7439-90-9

C8H18 (2) octane 111-65-9
2.704 6871
References

Diffusion of krypton (1); octan-1-ol (2) 1
Diffusion of krypton (1); octan-1-ol (2)

Vapor in Liquid
Kr (1) krypton 7439-90-9

C8H18O (2) octan-1-ol 111-87-5
T [K] p [kPa] D · 109 [m2/s]
298 101.325 0.19 ± 0.002
313 101.325 1.73 ± 0.004
353 101.325 3.72 ± 0.002
391 101.325 6.01 ± 0.007
430 101.325 8.9 ± 0.01
Kr (1) krypton 7439-90-9

C8H18O (2) octan-1-ol 111-87-5
T [K] p [atm] D · 109 [m2/s]
298.15 3 1.19 ± 0.02
Kr (1) krypton 7439-90-9

C8H18O (2) octan-1-ol 111-87-5
9.063 13330
References

Diffusion of krypton (1); decane (2) 1
Diffusion of krypton (1); decane (2)

Vapor in Liquid
Kr (1) krypton 7439-90-9

C10H22 (2) decane 124-18-5
T [K] p [kPa] D · 109 [m2/s]
298 101.325 3.51 ± 0.006
333 101.325 5.75 ± 0.03
433 101.325 14.6 ± 0.01
Kr (1) krypton 7439-90-9

C10H22 (2) decane 124-18-5
T [K] p [atm] D · 109 [m2/s]
298.15 3 3.51 ± 0.06
Kr (1) krypton 7439-90-9

C10H22 (2) decane 124-18-5
3.416 8319
References

Diffusion of krypton (1); tetradecane (2) 1
Diffusion of krypton (1); tetradecane (2)

Vapor in Liquid
Kr (1) krypton 7439-90-9

T [K] p [kPa] D · 109 [m2/s]
298 101.325 2.37 ± 0.002
343 101.325 4.46 ± 0.004
374 101.325 6.50 ± 0.004
430 101.325 10.0 ± 0.01
Kr (1) krypton 7439-90-9

T [K] p [atm] D · 109 [m2/s]
298.15 3 2.37 ± 0.02
Kr (1) krypton 7439-90-9

2.826 8813
References

Diffusion of krypton (1); tetrabutyl-stannane (2) 1
Diffusion of krypton (1); tetrabutyl-stannane (2)

Vapor in Liquid
Kr (1) krypton 7439-90-9

T [K] p [atm] D · 109 [m2/s]
298.15 3 1.73 ± 0.07
Reference

Diffusion of krypton (1); water (2) 1
Diffusion of krypton (1); water (2)

Vapor in Liquid
Kr (1) krypton 7439-90-9

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
273.15 ± 0.1 101.325 0.568 ± 5%
298.15 ± 0.1 101.325 0.803 ± 5%
323.15 ± 0.1 101.325 1.33 ± 5%
Kr (1) krypton 7439-90-9

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
283.15 ± 0.1 101.325 1.45 ± 2%
293.15 ± 0.1 101.325 1.68 ± 2%
303.15 ± 0.1 101.325 2.17 ± 2%
313.15 ± 0.1 101.325 2.77 ± 2%
323.15 ± 0.1 101.325 4.07 ± 2%
333.15 ± 0.1 101.325 5.54 ± 2%
Kr (1) krypton 7439-90-9

H 2O (2) water 7732-18-5
11.3 5110 *
References

Diffusion of nitrogen dioxide (1); water (2) 1
Diffusion of nitrogen dioxide (1); water (2)

Vapor in Liquid
NO2 (1) nitrogen dioxide 10102-44-0

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 1.23 ± 10%
303.15 101.325 1.59 ± 10%
Reference

Diffusion of nitrogen (1); tetrachloro-methane (2) 1
Diffusion of nitrogen (1); tetrachloro-methane (2)

Vapor in Liquid
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 3.64 ± 0.36 *
298.15 101.325 3.59 ± 0.28 **
298.15 101.325 3.56 ± 0.49 ***
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 109 [m2/s]
278.15 101.325 3.15
298.15 101.325 4.76
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.01 101.325 3.63
298.15 ± 0.01 101.325 3.79
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 109 [m2/s]
273.15 101.325 2.44 ± 5%
298.15 101.325 3.42 ± 5%
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 3.42

2 Diffusion of nitrogen (1); tetrachloro-methane (2)
N2 (1) nitrogen 7727-37-9

Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: GC Ref.: 1986A4
T [K] p [kPa] D · 104 [m2/s]
373 101.325 0.120 ± 2.5%
References
1986A4 Ashraf, S.M., Srivastava, R., Hussain, A.: J. Chem. Eng. Data 631 (1986) 100–102.

Diffusion of nitrogen (1); trichloro-methane (2) 1
Diffusion of nitrogen (1); trichloro-methane (2)

Vapor in Liquid
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
373 101.325 0.140 ± 2.5%
Reference

Diffusion of nitrogen (1); 1,1,2,2-tetrachloro-ethane (2) 1
Diffusion of nitrogen (1); 1,1,2,2-tetrachloro-ethane (2)

Vapor in Liquid
N2 (1) nitrogen 7727-37-9

C2H2Cl4 (2) 1,1,2,2-tetrachloro-ethane 79-34-5
T [K] p [kPa] D · 104 [m2/s]
423 101.325 0.143 ± 2.5%
Reference

Diffusion of nitrogen (1); ethane-1,2-diol (2) 1
Diffusion of nitrogen (1); ethane-1,2-diol (2)

Vapor in Liquid
N2 (1) nitrogen 7727-37-9

C2H6O2 (2) ethane-1,2-diol 107-21-1
T [K] p [kPa] D · 109 [m2/s]
303.15 101.325 0.50 ± 0.02
Reference

Diffusion of nitrogen (1); propan-2-one (2) 1
Diffusion of nitrogen (1); propan-2-one (2)

Vapor in Liquid
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
373 101.325 0.168 ± 2.5%
Reference

Diffusion of nitrogen (1); propan-1-ol (2) 1
Diffusion of nitrogen (1); propan-1-ol (2)

Vapor in Liquid
N2 (1) nitrogen 7727-37-9

C3H8O (2) propan-1-ol 71-23-8
T [K] p [kPa] D · 104 [m2/s]
373 101.325 0.153 ± 2.5%
Reference

Diffusion of nitrogen (1); butan-1-ol (2) 1
Diffusion of nitrogen (1); butan-1-ol (2)

Vapor in Liquid
N2 (1) nitrogen 7727-37-9

C4H10O (2) butan-1-ol 71-36-3
T [K] p [kPa] D · 104 [m2/s]
393 101.325 0.161 ± 2.5%
Reference

Diffusion of nitrogen (1); pentan-1-ol (2) 1
Diffusion of nitrogen (1); pentan-1-ol (2)

Vapor in Liquid
N2 (1) nitrogen 7727-37-9

C5H12O (2) pentan-1-ol 71-41-0
T [K] p [kPa] D · 104 [m2/s]
418 101.325 0.159 ± 2.5%
Reference

Diffusion of nitrogen (1); 1,2-dichloro-benzene (2) 1
Diffusion of nitrogen (1); 1,2-dichloro-benzene (2)

Vapor in Liquid
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 109 [m2/s]
303.15 101.325 4.0 ± 0.3
Reference

Diffusion of nitrogen (1); bromobenzene (2) 1
Diffusion of nitrogen (1); bromobenzene (2)

Vapor in Liquid
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
473 101.325 0.173 ± 2.5%
Reference

Diffusion of nitrogen (1); chlorobenzene (2) 1
Diffusion of nitrogen (1); chlorobenzene (2)

Vapor in Liquid
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
423 101.325 0.165 ± 2.5%
Reference

Diffusion of nitrogen (1); nitrobenzene (2) 1
Diffusion of nitrogen (1); nitrobenzene (2)

Vapor in Liquid
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
523 101.325 0.225 ± 2.5%
Reference

Diffusion of nitrogen (1); benzene (2) 1
Diffusion of nitrogen (1); benzene (2)

Vapor in Liquid
N2 (1) nitrogen 7727-37-9

C6H6 (2) benzene 71-43-2
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 5.83 ± 0.54 *
298.15 101.325 5.58 ± 0.53 **
298.15 101.325 5.35 ± 0.60 ***
N2 (1) nitrogen 7727-37-9

C6H6 (2) benzene 71-43-2
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.01 101.325 6.93 *
298.15 ± 0.01 101.325 7.20
298.15 ± 0.01 101.325 7.23
Comment: *: measured by diaphragma method
References

Diffusion of nitrogen (1); cyclohexanone (2) 1
Diffusion of nitrogen (1); cyclohexanone (2)

Vapor in Liquid
N2 (1) nitrogen 7727-37-9

C6H10O (2) cyclohexanone 108-94-1
T [K] p [kPa] D · 109 [m2/s]
303.15 101.325 3.7 ± 0.4
Reference

Diffusion of nitrogen (1); 4-methyl-pentan-2-one (2) 1
Diffusion of nitrogen (1); 4-methyl-pentan-2-one (2)

Vapor in Liquid
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 104 [m2/s]
423 101.325 0.141 ± 2.5%
Reference

Diffusion of nitrogen (1); cyclohexanol (2) 1
Diffusion of nitrogen (1); cyclohexanol (2)

Vapor in Liquid
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 109 [m2/s]
303.15 101.325 0.68 ± 0.03
Reference

Diffusion of nitrogen (1); hexan-1-ol (2) 1
Diffusion of nitrogen (1); hexan-1-ol (2)

Vapor in Liquid
N2 (1) nitrogen 7727-37-9

C6H14O (2) hexan-1-ol 111-27-3
T [K] p [kPa] D · 104 [m2/s]
433 101.325 0.141 ± 2.5%
Reference

Diffusion of nitrogen (1); 2-nitro-toluene (2) 1
Diffusion of nitrogen (1); 2-nitro-toluene (2)

Vapor in Liquid
N2 (1) nitrogen 7727-37-9

C7H7NO2 (2) 2-nitro-toluene 88-72-2
T [K] p [kPa] D · 104 [m2/s]
498 101.325 0.170 ± 2.5%
Reference

Diffusion of nitrogen (1); toluene (2) 1
Diffusion of nitrogen (1); toluene (2)

Vapor in Liquid
N2 (1) nitrogen 7727-37-9

C7H8 (2) toluene 108-88-3
T [K] p [kPa] D · 109 [m2/s]
298 101.325 6.19
298 101.325 6.07
N2 (1) nitrogen 7727-37-9

C7H8 (2) toluene 108-88-3
T [K] p [kPa] D · 109 [m2/s]
298.1 101.325 5.80
References
37–39.

Diffusion of nitrogen (1); heptan-1-ol (2) 1
Diffusion of nitrogen (1); heptan-1-ol (2)

Vapor in Liquid
N2 (1) nitrogen 7727-37-9

C7H16O (2) heptan-1-ol 111-70-6
T [K] p [kPa] D · 104 [m2/s]
453 101.325 0.145 ± 2.5%
Reference

Diffusion of nitrogen (1); octane (2) 1
Diffusion of nitrogen (1); octane (2)

Vapor in Liquid
N2 (1) nitrogen 7727-37-9

C8H18 (2) octane 111-65-9
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: MZ-INT Ref.: 1991K2
T [K] p [MPa] D · 109 [m2/s]
303.1 ± 0.1 15.0 5.5
324.8 ± 0.1 15.0 7.7 ± 0.9
373.2 ± 0.1 15.0 12.3 ± 0.1
399.3 ± 0.3 15.0 15.3 ± 0.3
423 ± 1 15.0 17 ± 1
Reference
1991K2 Killie, S., Hafskjold, B., Borgen, O., Kjelstrup, S., Hovde, E.: AIChE J. 37 (1991) 142–146.

Diffusion of nitrogen (1); octan-1-ol (2) 1
Diffusion of nitrogen (1); octan-1-ol (2)

Vapor in Liquid
N2 (1) nitrogen 7727-37-9

C8H18O (2) octan-1-ol 111-87-5
T [K] p [kPa] D · 104 [m2/s]
473 101.325 0.148 ± 2.5%
Reference

Diffusion of nitrogen (1); tris-nonafluorobutyl-amine (2) 1
Diffusion of nitrogen (1); tris-nonafluorobutyl-amine (2)

Vapor in Liquid
N2 (1) nitrogen 7727-37-9

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 2.35
Reference


Vapor in Liquid
N2 (1) nitrogen 7727-37-9

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 2.19
N2 (1) nitrogen 7727-37-9

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 2.12
303.15 101.325 2.67
N2 (1) nitrogen 7727-37-9

H 2O (2) water 7732-18-5
T [K] p [MPa] D · 109 [m2/s]
293.15 2.01 1.96 ± 2%
293.15 5.0 1.97 ± 2%
303.15 4.6 2.95 ± 2%
N2 (1) nitrogen 7727-37-9

H 2O (2) water 7732-18-5
T [K] p [Torr] D · 109 [m2/s]
298.15 720 2.2
N2 (1) nitrogen 7727-37-9

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
296.65 101.325 1.9 ± 10%
N2 (1) nitrogen 7727-37-9

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
302.75 ± 0.2 101.325 3.47 ± 0.22

2 Diffusion of nitrogen (1); water (2)
N2 (1) nitrogen 7727-37-9

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 1.90
N2 (1) nitrogen 7727-37-9

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
294.15 101.325 2.16
298.15 101.325 2.34
302.15 101.325 2.55
306.15 101.325 2.75
310.15 101.325 3.01
N2 (1) nitrogen 7727-37-9

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
303.15 101.325 3.3 ± 0.2
303.15 101.325 3.0 ± 0.1
N2 (1) nitrogen 7727-37-9

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
274.15 101.325 1.134 *
283.15 101.325 1.34 *
288.15 101.325 1.94
290.65 101.325 1.62 *
294.85 101.325 2.00
296.65 101.325 1.9 ± 10%
297.15 101.325 2.10 *
298.15 101.325 1.80 *
298.15 101.325 1.83
298.15 101.325 2.25 ± 5%
303.15 101.325 2.00 *
310.15 101.325 2.70 *

N2 (1) nitrogen 7727-37-9

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
283.15 101.325 1.29 ± 0.091
298.15 101.325 2.01 ± 0.100
313.15 101.325 2.83 ± 0.038
328.15 101.325 3.80 ± 0.084
N2 (1) nitrogen 7727-37-9

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
283.15 ± 0.1 101.325 1.8
293.15 ± 0.1 101.325 2.6
303.15 ± 0.1 101.325 3.5
313.15 ± 0.1 101.325 4.3
323.15 ± 0.1 101.325 5.1
333.15 ± 0.1 101.325 6.5
N2 (1) nitrogen 7727-37-9

H 2O (2) water 7732-18-5
T [K] p [bar] D · 109 [m2/s]
293.15 20.1 1.96 ± 2%
293.15 50.0 1.97 ± 2%
303.15 46.0 2.95 ± 2%
N2 (1) nitrogen 7727-37-9

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
288.15 101.325 1.37
288.15 101.325 1.78 *
293.15 101.325 1.66
293.15 101.325 2.08 *
298.15 101.325 1.94
298.15 101.325 2.24 *

4 Diffusion of nitrogen (1); water (2)
N2 (1) nitrogen 7727-37-9

H 2O (2) water 7732-18-5
7.9 4690 *
References
239–246.
149–154.

Diffusion of nitrous oxide (1); ethanol (2) 1
Diffusion of nitrous oxide (1); ethanol (2)

Vapor in Liquid

T [K] p [kPa] D · 109 [m2/s]
298.1 101.325 4.26
308.0 101.325 4.92
318.0 101.325 5.62
323.1 101.325 5.97
333.0 101.325 6.76

345.0 1310.4
Reference
37–39.

Diffusion of nitrous oxide (1); toluene (2) 1
Diffusion of nitrous oxide (1); toluene (2)

Vapor in Liquid

C7H8 (2) toluene 108-88-3
T [K] p [kPa] D · 109 [m2/s]
298 101.325 3.76
298 101.325 3.82

C7H8 (2) toluene 108-88-3
T [K] p [kPa] D · 109 [m2/s]
298.0 101.325 5.02
307.9 101.325 5.70
317.7 101.325 6.36
333.0 101.325 7.49
348.0 101.325 8.70

C7H8 (2) toluene 108-88-3
in liquid(2): D*1(2)(T ); Method:
Diffusion of solute(1) TAYLOR Ref.: 1995S3
228.1 1137.4
References
37–39.

Diffusion of nitrous oxide (1); water (2) 1
Diffusion of nitrous oxide (1); water (2)

Vapor in Liquid

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
303.15 101.325 2.04 ± 2%
308.15 101.325 2.29 ± 2%
313.15 101.325 2.66 ± 2%

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
294.0 ± 0.1 101.325 1.59 ± 5%
301.5 ± 0.1 101.325 1.95 ± 5%
303.2 ± 0.1 101.325 2.09 ± 5%
311.5 ± 0.1 101.325 2.51 ± 5%
318.0 ± 0.1 101.325 2.93 ± 5%

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
288.15 ± 0.30 101.325 1.285
293.15 ± 0.30 101.325 1.436
298.15 ± 0.30 101.325 1.569
303.15 ± 0.30 101.325 1.607
308.15 ± 0.30 101.325 1.634
313.15 ± 0.30 101.325 1.679
323.15 ± 0.30 101.325 1.868

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
288.15 101.325 1.62
293.15 101.325 2.11
298.15 101.325 2.57

2 Diffusion of nitrous oxide (1); water (2)

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 1.75

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
291.1 101.325 1.47
292 101.325 1.56
292.9 101.325 1.48
293 101.325 1.45
293 101.325 1.65
298 101.325 1.88
298 101.325 1.80
302.9 101.325 2.27
308 101.325 2.34
312.9 101.325 2.35
313 101.325 2.58
318 101.325 3.17
322.7 101.325 2.85
340 101.325 5.33
343 101.325 5.43
353 101.325 6.32
Comment: large scatter of data

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
303.15 101.325 2.009 ± 2%
308.15 101.325 2.302 ± 2%
313.15 101.325 2.648 ± 2%

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
303.15 101.325 2.114
308.15 101.325 2.338
313.15 101.325 2.701
Comment: reproducibility: ±3%; exp. error: ±2%


H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
283.15 ± 0.1 101.325 1.55 ± 2%
293.15 ± 0.1 101.325 2.07 ± 2%
303.15 ± 0.1 101.325 3.96 ± 2%
313.15 ± 0.1 101.325 5.16 ± 2%
323.15 ± 0.1 101.325 9.34 ± 2%
333.15 ± 0.1 101.325 13.6 ± 2%

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
293 ± 0.3 101.325 1.84
298 ± 0.3 101.325 1.88
303 ± 0.3 101.325 1.93
313 ± 0.3 101.325 2.61
333 ± 0.3 101.325 4.51
353 ± 0.3 101.325 6.50
368 ± 0.3 101.325 7.30
Comment: average standard deviation = 0.0024 · 10–9 [m2/s]

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: ABSORB Ref.: 2004M1
T [K] p [kPa] D · 109 [m2/s]
293 ± 0.2 101.325 1.54 ± 2%
298 ± 0.2 101.325 1.80 ± 2%
303 ± 0.2 101.325 1.98 ± 2%
308 ± 0.2 101.325 2.29 ± 2%
313 ± 0.2 101.325 2.58 ± 2%

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
287.15 101.325 0.73
288.15 101.325 1.62
289.35 101.325 1.56
293.15 101.325 2.11
298.15 101.325 2.57

4 Diffusion of nitrous oxide (1); water (2)

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.01 101.325 1.69
313.15 ± 0.01 101.325 2.55

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: OTE Ref.: 1988D3
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 1.61 ± 0.005

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.0 101.325 1.95

H 2O (2) water 7732-18-5
Equation: D = A · exp[ B / T ] Range: 288.15 < T/K < 368.15
Parameter: A B
4469.7 –2325.3

H 2O (2) water 7732-18-5
5.07 –2371
Comment: result of 29 data points from literature

H 2O (2) water 7732-18-5
3980 8360 *

References
2000K2 Ko, J.J., Li, M.H.: Chem. Eng. Science 55 (2000) 4139–4147.
1989A2 Al-Ghawas, H.A., Hagewiesche, D.P., Ruiz-Ibanez, G., Sandall, O.C.: J. Chem. Eng. Data 34
(1989) 385–391.
264–270.
516–521.

Diffusion of neon (1); tetrachloro-methane (2) 1
Diffusion of neon (1); tetrachloro-methane (2)

Vapor in Liquid
Ne (1) neon 7440-01-9

T [K] p [kPa] D · 109 [m2/s]
278.15 101.325 5.94
298.15 101.325 9.44
Ne (1) neon 7440-01-9

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 6.3
References

Diffusion of neon (1); tris-nonafluorobutyl-amine (2) 1
Diffusion of neon (1); tris-nonafluorobutyl-amine (2)

Vapor in Liquid
Ne (1) neon 7440-01-9

T [K] p [kPa] D · 109 [m2/s]
278.15 101.325 4.38
288.15 101.325 5.19
298.15 101.325 6.34
308.15 101.325 7.89
Ne (1) neon 7440-01-9

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 5.3
References

Diffusion of neon (1); water (2) 1
Diffusion of neon (1); water (2)

Vapor in Liquid
Ne (1) neon 7440-01-9

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: NMR FG Ref.: 1994H6
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 4.18 ± 0.20
Comment: older data of [1968W1] and [1969B9] appear to be in error
Ne (1) neon 7440-01-9

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
273.15 ± 0.1 101.325 1.23 ± 5%
298.15 ± 0.1 101.325 1.82 ± 5%
323.15 ± 0.1 101.325 2.47 ± 5%
Ne (1) neon 7440-01-9

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
283.15 ± 0.1 101.325 2.61 ± 2%
293.15 ± 0.1 101.325 3.00 ± 2%
303.15 ± 0.1 101.325 3.81 ± 2%
313.15 ± 0.1 101.325 5.39 ± 2%
323.15 ± 0.1 101.325 6.50 ± 2%
333.15 ± 0.1 101.325 8.08 ± 2%
Ne (1) neon 7440-01-9

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
295.35 101.325 2.8 ± 10%
Ne (1) neon 7440-01-9

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
295.35 101.325 2.8 ± 10%

2 Diffusion of neon (1); water (2)
Ne (1) neon 7440-01-9

H 2O (2) water 7732-18-5
6.6 4445 *
References
1994H6 Holz, M., Haselmeier, R., Mazitov, R.K., Weingärtner, H.: J. Am. Chem. Soc. 116 (1994)
801–802.

Diffusion of oxygen (1); tetrachloro-methane (2) 1
Diffusion of oxygen (1); tetrachloro-methane (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 3.40 ± 0.56 *
298.15 101.325 3.59 ± 0.52 **
298.15 101.325 3.79 ± 0.47 ***
O2 (1) oxygen 7782-44-7

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 3.82
References

Diffusion of oxygen (1); 1,2-dichloro-ethane (2) 1
Diffusion of oxygen (1); 1,2-dichloro-ethane (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: EA DME Ref.: 1990S2
T [K] p [kPa] D · 109 [m2/s]
293.2 ± 0.1 101.325 2.67
Reference
1990S2 Schumpe, A., Lühring, P.: J. Chem. Eng. Data 35 (1990) 24–25.

Diffusion of oxygen (1); ethanol (2) 1
Diffusion of oxygen (1); ethanol (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

T [K] p [kPa] D · 109 [m2/s]
302.75 ± 0.2 101.325 2.64 ± 0.14
Reference

Diffusion of oxygen (1); propan-2-one (2) 1
Diffusion of oxygen (1); propan-2-one (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

T [K] p [kPa] D · 109 [m2/s]
293.2 ± 0.1 101.325 6.68
293.2 ± 0.1 101.325 5.80
293.2 ± 0.1 101.325 5.08
Reference

Diffusion of oxygen (1); 1,4-dioxane (2) 1
Diffusion of oxygen (1); 1,4-dioxane (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

C4H8O2 (2) 1,4-dioxane 123-91-1
T [K] p [kPa] D · 109 [m2/s]
293.2 ± 0.1 101.325 1.92
293.2 ± 0.1 101.325 1.97
293.2 ± 0.1 101.325 2.01
Reference

Diffusion of oxygen (1); benzene (2) 1
Diffusion of oxygen (1); benzene (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

C6H6 (2) benzene 71-43-2
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 5.11 ± 0.39 *
298.15 101.325 4.86 ± 0.12 **
298.15 101.325 4.65 ± 0.27 ***
O2 (1) oxygen 7782-44-7

C6H6 (2) benzene 71-43-2
T [K] p [kPa] D · 109 [m2/s]
302.75 ± 0.2 101.325 2.89 ± 0.31
O2 (1) oxygen 7782-44-7

C6H6 (2) benzene 71-43-2
T [K] p [kPa] D · 109 [m2/s]
293.2 ± 0.1 101.325 3.46
References

1
Diffusion of oxygen (1); 1-ethyl-3-methylimidazolium bis-

((trifluoromethyl)-sulfonyl)-imide (2)
Vapor in Liquid
O2 (1) oxygen 7782-44-7

C6H11N2* (2) 1-ethyl-3-methylimidazolium bis- 174899-82-2
C2F6NO4S2 ((trifluoromethyl)-sulfonyl)-imide
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: EA ChA Ref.: 2003B5
T [K] p [kPa] D · 109 [m2/s]
293.15 ± 3.0 101.325 8.3
293.15 ± 3.0 101.325 7.3
Reference
2003B5 Buzzeo, M.C., Klymenko, O.V., Wadhawan, J.D., Hardacre, C., Seddon, K.R., Compton, R.G.: J.
Phys. Chem. A 107 (2003) 8872–8878.

Diffusion of oxygen (1); cyclohexane (2) 1
Diffusion of oxygen (1); cyclohexane (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: TAYLOR Ref.: 2000K3
T [K] p [kPa] D · 109 [m2/s]
294.2 101.325 4.75
294.2 101.325 4.65
O2 (1) oxygen 7782-44-7

T [K] p [kPa] D · 109 [m2/s]
302.75 ± 0.2 101.325 5.31 ± 0.17
O2 (1) oxygen 7782-44-7

T [K] p [kPa] D · 109 [m2/s]
293.2 ± 0.1 101.325 3.29
References
2000K3 Kowert, B.A., Dang, N.C., Reed, J.P., Sobush, K.T., Seele, L.G.: J. Phys. Chem. A 104 (2000)
8823–8828.

Diffusion of oxygen (1); hex-1-ene (2) 1
Diffusion of oxygen (1); hex-1-ene (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

C6H12 (2) hex-1-ene 592-41-6
T [K] p [kPa] D · 109 [m2/s]
298.2 101.325 10.92 ± 0.31
Reference
2002K5 Kowert, B.A., Sobush, K.T., Dang, N.C., Seele, L.G., Fuqua, C.F., Mapes, C.: Chem. Phys. Lett.
353 (2002) 95–99.

Diffusion of oxygen (1); acetic acid butyl ester (2) 1
Diffusion of oxygen (1); acetic acid butyl ester (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

T [K] p [kPa] D · 109 [m2/s]
293.2 ± 0.1 101.325 3.22
Reference

Diffusion of oxygen (1); hexane (2) 1
Diffusion of oxygen (1); hexane (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

C6H14 (2) hexane 110-54-3
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: No Stand Ref.: 2002O2
T [K] p [MPa] D · 109 [m2/s]
298.15 ± 0.2 0.1 15.7 ± 1.5
298.15 ± 0.2 50 9.62 ± 0.90
298.15 ± 0.2 100 6.95 ± 0.65
298.15 ± 0.2 150 5.30 ± 0.50
298.15 ± 0.2 200 4.21 ± 0.40
298.15 ± 0.2 250 3.44 ± 0.32
298.15 ± 0.2 300 2.81 ± 0.27
298.15 ± 0.2 350 2.33 ± 0.22
Comment: derived from fluorescence quenching
O2 (1) oxygen 7782-44-7

C6H14 (2) hexane 110-54-3
T [K] p [kPa] D · 109 [m2/s]
296.2 ± 0.5 101.325 9.96 ± 4%
295.7 ± 0.5 101.325 10.3 ± 4%
295.2 ± 0.5 101.325 9.45 ± 4%
296.2 ± 0.5 101.325 9.93 ± 4%
References
2002O2 Okamoto, M.: Int. J. Thermophys. 23 (2002) 421–435.
1999K1 Kowert, B.A., Dang, N.C.: J. Phys. Chem. 103 (1999) 779–781.

Diffusion of oxygen (1); toluene (2) 1
Diffusion of oxygen (1); toluene (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

C7H8 (2) toluene 108-88-3
T [K] p [kPa] D · 109 [m2/s]
293.2 ± 0.1 101.325 4.38
Reference

Diffusion of oxygen (1); methyl-cyclohexane (2) 1
Diffusion of oxygen (1); methyl-cyclohexane (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

T [K] p [kPa] D · 109 [m2/s]
293.2 101.325 5.39
294.2 101.325 5.43
295.2 101.325 5.94
295.2 101.325 5.74
Reference
8823–8828.

Diffusion of oxygen (1); heptane (2) 1
Diffusion of oxygen (1); heptane (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

C7H16 (2) heptane 142-82-5
T [K] p [kPa] D · 109 [m2/s]
292.7 101.325 7.89
291.2 101.325 7.66
Reference
8823–8828.

Diffusion of oxygen (1); 1,3-dimethyl-benzene (2) 1
Diffusion of oxygen (1); 1,3-dimethyl-benzene (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

T [K] p [kPa] D · 109 [m2/s]
293.2 ± 0.1 101.325 3.63
Reference

Diffusion of oxygen (1); ethylbenzene (2) 1
Diffusion of oxygen (1); ethylbenzene (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

T [K] p [kPa] D · 109 [m2/s]
293.2 ± 0.1 101.325 2.94
Reference

Diffusion of oxygen (1); oct-1-ene (2) 1
Diffusion of oxygen (1); oct-1-ene (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

C8H16 (2) oct-1-ene 111-66-0
T [K] p [kPa] D · 109 [m2/s]
298.2 101.325 7.32 ± 0.35
Reference
353 (2002) 95–99.

Diffusion of oxygen (1); octane (2) 1
Diffusion of oxygen (1); octane (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

C8H18 (2) octane 111-65-9
T [K] p [kPa] D · 109 [m2/s]
296.2 ± 0.5 101.325 6.89 ± 4%
296.2 ± 0.5 101.325 7.21 ± 4%
298.2 ± 0.5 101.325 7.04 ± 4%
298.7 ± 0.5 101.325 6.94 ± 4%
295.2 ± 0.5 101.325 7.04 ± 4%
Reference

Diffusion of oxygen (1); 2,2,4-trimethyl-pentane (2) 1
Diffusion of oxygen (1); 2,2,4-trimethyl-pentane (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

T [K] p [kPa] D · 109 [m2/s]
292.2 101.325 6.93
292.2 101.325 7.28
292.7 101.325 7.44
Reference
8823–8828.

Diffusion of oxygen (1); nonane (2) 1
Diffusion of oxygen (1); nonane (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

C9H20 (2) nonane 111-84-2
T [K] p [kPa] D · 109 [m2/s]
294.2 101.325 5.98
293.2 101.325 5.76
Reference
8823–8828.

Diffusion of oxygen (1); cis-decahydro-naphthalene (2) 1
Diffusion of oxygen (1); cis-decahydro-naphthalene (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

C10H18 (2) cis-decahydro-naphthalene 493-01-6
T [K] p [kPa] D · 109 [m2/s]
292.7 101.325 1.97
Reference
8823–8828.

Diffusion of oxygen (1); trans-decahydro-naphthalene (2) 1
Diffusion of oxygen (1); trans-decahydro-naphthalene (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

C10H18 (2) trans-decahydro-naphthalene 493-02-7
T [K] p [kPa] D · 109 [m2/s]
293.2 101.325 2.74
292.7 101.325 2.82
Reference
8823–8828.

Diffusion of oxygen (1); decahydro-naphthalene (2) 1
Diffusion of oxygen (1); decahydro-naphthalene (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

C10H18 (2) decahydro-naphthalene 91-17-8
T [K] p [kPa] D · 109 [m2/s]
293.2 ± 0.1 101.325 1.60
Reference

Diffusion of oxygen (1); dec-1-ene (2) 1
Diffusion of oxygen (1); dec-1-ene (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

C10H20 (2) dec-1-ene 872-05-9
T [K] p [kPa] D · 109 [m2/s]
297.2 101.325 5.54 ± 0.17
Reference
353 (2002) 95–99.

Diffusion of oxygen (1); butyl-cyclohexane (2) 1
Diffusion of oxygen (1); butyl-cyclohexane (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

C10H20 (2) butyl-cyclohexane 1678-93-9
T [K] p [kPa] D · 109 [m2/s]
297.2 101.325 4.13
296.7 101.325 3.97
297.2 101.325 4.38
Reference
8823–8828.

Diffusion of oxygen (1); decane (2) 1
Diffusion of oxygen (1); decane (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

C10H22 (2) decane 124-18-5
T [K] p [kPa] D · 109 [m2/s]
299.2 ± 0.5 101.325 5.52 ± 4%
297.2 ± 0.5 101.325 5.57 ± 4%
Reference

Diffusion of oxygen (1); undecane (2) 1
Diffusion of oxygen (1); undecane (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

C11H24 (2) undecane 1120-21-4
T [K] p [kPa] D · 109 [m2/s]
296.2 101.325 4.75
295.7 101.325 4.79
Reference
8823–8828.

Diffusion of oxygen (1); bicyclohexyl (2) 1
Diffusion of oxygen (1); bicyclohexyl (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

C12H22 (2) bicyclohexyl 92-51-3
T [K] p [kPa] D · 109 [m2/s]
297.2 101.325 2.10
297.2 101.325 2.21
Reference
8823–8828.

Diffusion of oxygen (1); dodec-1-ene (2) 1
Diffusion of oxygen (1); dodec-1-ene (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

C12H24 (2) dodec-1-ene 112-41-4
T [K] p [kPa] D · 109 [m2/s]
297.2 101.325 4.24 ± 0.16
Reference
353 (2002) 95–99.

Diffusion of oxygen (1); dodecane (2) 1
Diffusion of oxygen (1); dodecane (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

C12H26 (2) dodecane 112-40-3
T [K] p [kPa] D · 109 [m2/s]
294.7 ± 0.5 101.325 4.11 ± 4%
Reference

1
Diffusion of oxygen (1); triethyl-hexyl-ammonium bis

((trifluoromethyl)- sulfonyl)-imide (2)
Vapor in Liquid
O2 (1) oxygen 7782-44-7

C12H28N* (2) triethyl-hexyl-ammonium bis((trifluoromethyl)- 210230-46-9
C2F6NO4S2 sulfonyl)-imide
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: EA ChA Ref.: 2003B5
T [K] p [kPa] D · 109 [m2/s]
293.15 ± 3.0 101.325 1.5
293.15 ± 3.0 101.325 1.48
Reference
2003B5 Buzzeo, M.C., Klymenko, O.V., Wadhawan, J.D., Hardacre, C., Seddon, K.R., Compton, R.G.: J.
Phys. Chem. A 107 (2003) 8872–8878.

Diffusion of oxygen (1); tridecane (2) 1
Diffusion of oxygen (1); tridecane (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

C13H28 (2) tridecane 629-50-5
T [K] p [kPa] D · 109 [m2/s]
294.2 101.325 3.50
295.2 101.325 3.79
295.7 101.325 3.70
Reference
8823–8828.

Diffusion of oxygen (1); tetradec-1-ene (2) 1
Diffusion of oxygen (1); tetradec-1-ene (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

C14H28 (2) tetradec-1-ene 1120-36-1
T [K] p [kPa] D · 109 [m2/s]
297.2 101.325 3.31 ± 0.26
Reference
353 (2002) 95–99.

Diffusion of oxygen (1); tetradecane (2) 1
Diffusion of oxygen (1); tetradecane (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

T [K] p [kPa] D · 109 [m2/s]
295.7 ± 0.5 101.325 3.40 ± 4%
294.2 ± 0.5 101.325 3.20 ± 4%
Reference

Diffusion of oxygen (1); pentadecane (2) 1
Diffusion of oxygen (1); pentadecane (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

C15H32 (2) pentadecane 629-62-9
T [K] p [kPa] D · 109 [m2/s]
296.7 101.325 2.81
296.2 101.325 2.88
296.2 101.325 2.99
Reference
8823–8828.

Diffusion of oxygen (1); hexadec-1-ene (2) 1
Diffusion of oxygen (1); hexadec-1-ene (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

C16H32 (2) hexadec-1-ene 629-73-2
T [K] p [kPa] D · 109 [m2/s]
297.2 101.325 2.77 ± 0.14
Reference
353 (2002) 95–99.

Diffusion of oxygen (1); hexadecane (2) 1
Diffusion of oxygen (1); hexadecane (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

T [K] p [kPa] D · 109 [m2/s]
298.7 ± 0.5 101.325 2.59 ± 4%
298.7 ± 0.5 101.325 2.73 ± 4%
O2 (1) oxygen 7782-44-7

Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: PF Ref.: 1989J1
T [K] p [kPa] D · 109 [m2/s]
295.15 101.325 2.49
References
1989J1 Ju, L.-K., Ho, C.S.: Biotechnol. Bioeng. 34 (1989) 1221–1224.

Diffusion of oxygen (1); 2,6,10,15,19,23-hexamethyl-tetracosane (2) 1
Diffusion of oxygen (1); 2,6,10,15,19,23-hexamethyl-

tetracosane (2)
Vapor in Liquid
O2 (1) oxygen 7782-44-7

C30H62 (2) 2,6,10,15,19,23-hexamethyl-tetracosane 111-01-3
T [K] p [kPa] D · 1010 [m2/s]
294.15 101.325 8.23
Reference
8823–8828.


Vapor in Liquid
O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: LAM Ref.: 1970Z1
T [K] p [kPa] D · 109 [m2/s]
296.65 ± 0.5 101.325 2.20
293.15 ± 0.5 101.325 1.95
O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
294.15 101.325 2.33
298.15 101.325 2.51
302.15 101.325 2.72
306.15 101.325 2.95
310.15 101.325 3.21
O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
288.15 101.325 1.67
289.15 101.325 1.87
291.35 101.325 1.99
293.15 101.325 2.01
294.85 101.325 1.87
295.15 101.325 2.25
295.15 101.325 2.22
298.15 101.325 2.60
298.15 101.325 2.42
298.15 101.325 2.12
298.15 101.325 2.25
310.15 101.325 3.0
O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
283.15 101.325 1.54 ± 0.066
298.15 101.325 2.20 ± 0.072
(continued)

2 Diffusion of oxygen (1); water (2)
313.15 101.325 3.33 ± 0.125

328.15 101.325 4.50 ± 0.073
O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
288.15 101.325 1.51
288.15 101.325 1.78 *
293.15 101.325 1.76
293.15 101.325 2.22 *
298.15 101.325 2.03
298.15 101.325 2.55 *
O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: KMD Ref.: 1979W1
T [K] p [kPa] D · 109 [m2/s]
288.15 101.325 1.95 ± 0.07
298.15 101.325 2.72 ± 0.10
310.15 101.325 3.78 ± 0.20
O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
283.15 ± 0.1 101.325 1.7
293.15 ± 0.1 101.325 2.3
303.15 ± 0.1 101.325 2.8
313.15 ± 0.1 101.325 3.8
323.15 ± 0.1 101.325 4.2
333.15 ± 0.1 101.325 5.7
O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
T [K] p [bar] D · 109 [m2/s]
283.15 25.0 1.63 ± 2%
293.15 10.1 2.12 ± 2%
298.15 20.0 2.49 ± 2%
308.15 10.0 2.91 ± 2%

O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
T [K] p [MPa] D · 109 [m2/s]
183.15 2.5 1.63 ± 2%
193.15 1.01 2.12 ± 2%
298.15 2.0 2.49 ± 2%
303.15 1.0 2.91 ± 2%
O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
288.15 101.325 1.66
293.15 101.325 2.01
298.15 101.325 2.41
O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
303.15 101.325 3.5 ± 0.3
303.15 101.325 3.8 ± 0.2
O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: PF Ref.: 1989J1
T [K] p [kPa] D · 109 [m2/s]
295.15 101.325 2.11
O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.2 ± 0.5 101.325 2.31 ± 4%
O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: EA RDE Ref.: 1970T3
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.01 101.325 2.00 ± 0.07

O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.2 101.325 2.41 ± 3%
O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 1.80
O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.01 101.325 3.40 ± 2.5%
O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 2.65
O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
302.75 ± 0.2 101.325 3.49 ± 0.24
O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: EA DME Ref.: 1965G5
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 1.90
O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
296.95 101.325 2.3 ± 10%

O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 2.08
O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 ± 0.01 101.325 2.07
O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
303.0 ± 0.05 101.325 2.90 ± 7.6%
O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
4.2 4390 *
References
1970Z1 Zandi, I., Turner, C.D.: Chem. Eng. Science 25 (1970) 517–527.
1979W1 Ward, C.A., Tucker, A.S., So, C.-W.: J. Phys. Chem. 83 (1979) 543–550.
149–154.
1989J1 Ju, L.-K., Ho, C.S.: Biotechnol. Bioeng. 34 (1989) 1221–1224.
1970T3 Tham, M.K., Walker, R.D., Gubbins, K.E.: J. Phys. Chem. 74 (1970) 1747–1751.
1972H9 Hung, G.W., Dinius, R.H.: J. Chem. Eng. Data 17 (1972) 449–451.

1965G5 Gubbins, K.E., Walker, R.D.: J. Electrochem. Soc. 112 (1965) 469–471.

Diffusion of oxygen (1); antimony (2) 1
Diffusion of oxygen (1); antimony (2)

Vapor in Liquid
O2 (1) oxygen 7782-44-7

Sb (2) antimony 7440-36-0
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: EA Ch Ref.: 1980F2
3.07 3922
Reference
1980F2 Fitzner, K.: Z. Metallkd. 71 (1980) 178–181.

Diffusion of sulfur dioxide (1); heptane (2) 1
Diffusion of sulfur dioxide (1); heptane (2)

Vapor in Liquid

C7H16 (2) heptane 142-82-5
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 30.9 ± 10%
Reference

Diffusion of sulfur dioxide (1); water (2) 1
Diffusion of sulfur dioxide (1); water (2)

Vapor in Liquid

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 1.40
293.15 101.325 1.46
293.15 101.325 1.66
293.15 101.325 1.62
298.15 101.325 2.04
298.15 101.325 1.83
303.15 101.325 2.08
308.15 101.325 2.33
313.15 101.325 2.59

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: OEC Ref.: 1967E6
T [K] p [kPa] D · 109 [m2/s]
293.15 ± 0.1 101.325 1.45 ± 0.04

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 1.48 ± 10%
References
1967E6 Eriksen, T.: Chem. Eng. Science 22 (1967) 727–736.

Diffusion of ozone (1); water (2) 1
Diffusion of ozone (1); water (2)

Vapor in Liquid
O3 (1) ozone 10028-15-6

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: LAM Ref.: 1976M1
T [K] p [kPa] D · 109 [m2/s]
291.15 ± 0.1 101.325 1.19 ± 2%
293.65 ± 0.1 101.325 1.26 ± 2%
298.35 ± 0.1 101.325 1.47 ± 2%
303.55 ± 0.1 101.325 1.64 ± 2%
Reference
1976M1 Matrozov, V.I., Kashtanov, S.A., Stepanov, A.M., Tregubov, B.A.: Zh. Prikl. Khim. 49 (1976)
1070–1073.

Diffusion of tritium (1); nitrogen (2) 1
Diffusion of tritium (1); nitrogen (2)

Vapor in Liquid
T2 (1) tritium 10028-17-8

N2 (2) nitrogen 7727-37-9
T [K] p [kPa] D · 109 [m2/s]
72.82 101.325 3.69
71.20 101.325 3.40
70.20 101.325 2.88
70.08 101.325 3.16
67.40 101.325 2.81
Reference

Diffusion of xenon (1); tetrachloro-methane (2) 1
Diffusion of xenon (1); tetrachloro-methane (2)

Vapor in Liquid
Xe (1) xenon 7440-63-3

T [K] p [atm] D · 109 [m2/s]
298.15 3 2.50 ± 0.08
Xe (1) xenon 7440-63-3

T [K] p [MPa] D · 109 [m2/s]
298.15 ± 0.5 5.0 2.82 ± 10%
References
1995H13 Holz, M., Haselmeier, R., Klein, A., Mazitov, R.K.: Appl. Magn. Reson. 8 (1995) 501–519.

Diffusion of xenon (1); methanol (2) 1
Diffusion of xenon (1); methanol (2)

Vapor in Liquid
Xe (1) xenon 7440-63-3

T [K] p [kPa] D · 109 [m2/s]
298 101.325 3.97 ± 0.003
313 101.325 4.65 ± 0.006
333 101.325 5.85 ± 0.005
383 101.325 9.82 ± 0.004
Xe (1) xenon 7440-63-3

T [K] p [MPa] D · 109 [m2/s]
298.15 ± 0.5 5.0 3.90 ± 10%
Xe (1) xenon 7440-63-3

T [K] p [atm] D · 109 [m2/s]
298.15 3 2.92 ± 0.10
Xe (1) xenon 7440-63-3

2.586 7402
References

Diffusion of xenon (1); propan-2-one (2) 1
Diffusion of xenon (1); propan-2-one (2)

Vapor in Liquid
Xe (1) xenon 7440-63-3

T [K] p [atm] D · 109 [m2/s]
298.15 3 5.18 ± 0.05
Xe (1) xenon 7440-63-3

T [K] p [MPa] D · 109 [m2/s]
298.15 ± 0.5 5.0 5.32 ± 10%
References

Diffusion of xenon (1); N,N-dimethyl-formamide (2) 1
Diffusion of xenon (1); N,N-dimethyl-formamide (2)

Vapor in Liquid
Xe (1) xenon 7440-63-3

T [K] p [MPa] D · 109 [m2/s]
298.15 ± 0.5 5.0 2.98 ± 10%
Reference

Diffusion of xenon (1); propan-2-ol (2) 1
Diffusion of xenon (1); propan-2-ol (2)

Vapor in Liquid
Xe (1) xenon 7440-63-3

C3H8O (2) propan-2-ol 67-63-0
T [K] p [atm] D · 109 [m2/s]
298.15 3 1.76 ± 0.04
Reference

Diffusion of xenon (1); butan-1-ol (2) 1
Diffusion of xenon (1); butan-1-ol (2)

Vapor in Liquid
Xe (1) xenon 7440-63-3

C4H10O (2) butan-1-ol 71-36-3
T [K] p [kPa] D · 109 [m2/s]
298 101.325 1.62 ± 0.003
333 101.325 3.14 ± 0.004
373 101.325 5.60 ± 0.004
433 101.325 11.4 ± 0.01
Xe (1) xenon 7440-63-3

C4H10O (2) butan-1-ol 71-36-3
T [K] p [MPa] D · 109 [m2/s]
298.15 ± 0.5 5.0 2.30 ± 10%
Xe (1) xenon 7440-63-3

C4H10O (2) butan-1-ol 71-36-3
T [K] p [atm] D · 109 [m2/s]
298.15 3 1.62 ± 0.03
Xe (1) xenon 7440-63-3

C4H10O (2) butan-1-ol 71-36-3
8.485 12500
References

Diffusion of xenon (1); pentane (2) 1
Diffusion of xenon (1); pentane (2)

Vapor in Liquid
Xe (1) xenon 7440-63-3

C5H12 (2) pentane 109-66-0
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: No Stand Ref.: 1985P4
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 7.96 ± 4.2%
Comment: diffusion of gas through liquid capillary
Reference
1985P4 Pollack, G.L., Enyeart, J.J.: Phys. Rev. A 31 (1985) 980–984.

Diffusion of xenon (1); benzene (2) 1
Diffusion of xenon (1); benzene (2)

Vapor in Liquid
Xe (1) xenon 7440-63-3

C6H6 (2) benzene 71-43-2
T [K] p [atm] D · 109 [m2/s]
298.15 3 3.57 ± 0.04
Xe (1) xenon 7440-63-3

C6H6 (2) benzene 71-43-2
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: NMR FG Ref.: 1998W1
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 12.0 ± 2.0
Xe (1) xenon 7440-63-3

C6H6 (2) benzene 71-43-2
T [K] p [MPa] D · 109 [m2/s]
298.15 ± 0.5 5.0 3.58 ± 10%
References
1998W1 Wolber, J., Doran, S.J., Leach, M.O., Bifone, A.: Chem. Phys. Lett. 296 (1998) 391–396.

Diffusion of xenon (1); cyclohexane (2) 1
Diffusion of xenon (1); cyclohexane (2)

Vapor in Liquid
Xe (1) xenon 7440-63-3

T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 3.03 ± 0.005
313.25 101.325 3.55 ± 0.002
333.35 101.325 4.66 ± 0.005
353.75 101.325 5.95 ± 0.006
374.05 101.325 7.3 ± 0.01
390.85 101.325 8.7 ± 0.02
415.85 101.325 11.1 ± 0.01
Xe (1) xenon 7440-63-3

T [K] p [atm] D · 109 [m2/s]
298.15 3 3.03 ± 0.05
Xe (1) xenon 7440-63-3

3.104 8566
References

Diffusion of xenon (1); hexane (2) 1
Diffusion of xenon (1); hexane (2)

Vapor in Liquid
Xe (1) xenon 7440-63-3

C6H14 (2) hexane 110-54-3
T [K] p [atm] D · 109 [m2/s]
298.15 3 5.44 ± 0.04
Xe (1) xenon 7440-63-3

C6H14 (2) hexane 110-54-3
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 6.71 ± 4.2%
References

Diffusion of xenon (1); heptane (2) 1
Diffusion of xenon (1); heptane (2)

Vapor in Liquid
Xe (1) xenon 7440-63-3

C7H16 (2) heptane 142-82-5
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 5.54 ± 4.2%
Reference

Diffusion of xenon (1); 1-bromo-heptadecafluoro-octane (2) 1
Diffusion of xenon (1); 1-bromo-heptadecafluoro-octane (2)

Vapor in Liquid
Xe (1) xenon 7440-63-3

C8BrF17 (2) 1-bromo-heptadecafluoro-octane 423-55-2
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 4.5 ± 0.6
Reference

Diffusion of xenon (1); 1,4-dimethyl-benzene (2) 1
Diffusion of xenon (1); 1,4-dimethyl-benzene (2)

Vapor in Liquid
Xe (1) xenon 7440-63-3

T [K] p [MPa] D · 109 [m2/s]
298.15 ± 0.5 5.0 4.02 ± 10%
Reference

Diffusion of xenon (1); octane (2) 1
Diffusion of xenon (1); octane (2)

Vapor in Liquid
Xe (1) xenon 7440-63-3

C8H18 (2) octane 111-65-9
T [K] p [kPa] D · 109 [m2/s]
298 101.325 4.06 ± 0.002
333 101.325 6.12 ± 0.004
373 101.325 9.10 ± 0.004
403 101.325 11.80 ± 0.006
Xe (1) xenon 7440-63-3

C8H18 (2) octane 111-65-9
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: CT Ref.: 1990P9
T [K] p [kPa] D · 109 [m2/s]
283.15 101.325 3.93 ± 1.5%
293.15 101.325 4.37 ± 1.5%
303.15 101.325 5.15 ± 1.5%
313.15 101.325 6.02 ± 1.5%
Comment: Modification of Loschmidt cell with gas diffusing into liquid
Xe (1) xenon 7440-63-3

C8H18 (2) octane 111-65-9
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 4.53 ± 4.2%
Xe (1) xenon 7440-63-3

C8H18 (2) octane 111-65-9
2.574 7268
References
1990P9 Pollack, G.L., Kennan, R.P., Himm, J.F., Stump, D.R.: J. Chem. Phys. 92 (1990) 625–630.

Diffusion of xenon (1); octan-1-ol (2) 1
Diffusion of xenon (1); octan-1-ol (2)

Vapor in Liquid
Xe (1) xenon 7440-63-3

C8H18O (2) octan-1-ol 111-87-5
T [K] p [kPa] D · 109 [m2/s]
298 101.325 0.845 ± 0.0007
313 101.325 1.28 ± 0.002
353 101.325 2.76 ± 0.005
391 101.325 4.77 ± 0.006
430 101.325 7.25 ± 0.008
Xe (1) xenon 7440-63-3

C8H18O (2) octan-1-ol 111-87-5
T [K] p [atm] D · 109 [m2/s]
298.15 3 0.845 ± 0.007
Xe (1) xenon 7440-63-3

C8H18O (2) octan-1-ol 111-87-5
9.830 14370
References

Diffusion of xenon (1); nonane (2) 1
Diffusion of xenon (1); nonane (2)

Vapor in Liquid
Xe (1) xenon 7440-63-3

C9H20 (2) nonane 111-84-2
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 3.75 ± 4.2%
Xe (1) xenon 7440-63-3

C9H20 (2) nonane 111-84-2
T [K] p [MPa] D · 109 [m2/s]
298.15 ± 0.5 5.0 3.45 ± 10%
References

Diffusion of xenon (1); decane (2) 1
Diffusion of xenon (1); decane (2)

Vapor in Liquid
Xe (1) xenon 7440-63-3

C10H22 (2) decane 124-18-5
T [K] p [kPa] D · 109 [m2/s]
298 101.325 2.86 ± 0.003
333 101.325 4.60 ± 0.003
373 101.325 7.13 ± 0.005
433 101.325 12.2 ± 0.01
Xe (1) xenon 7440-63-3

C10H22 (2) decane 124-18-5
T [K] p [kPa] D · 109 [m2/s]
283.15 101.325 2.50 ± 1.5%
293.15 101.325 2.95 ± 1.5%
303.15 101.325 3.43 ± 1.5%
313.15 101.325 3.97 ± 1.5%
Xe (1) xenon 7440-63-3

C10H22 (2) decane 124-18-5
T [K] p [atm] D · 109 [m2/s]
298.15 3 2.86 ± 0.03
Xe (1) xenon 7440-63-3

C10H22 (2) decane 124-18-5
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 3.05 ± 4.2%
Xe (1) xenon 7440-63-3

C10H22 (2) decane 124-18-5
3.020 8549

2 Diffusion of xenon (1); decane (2)
References

Diffusion of xenon (1); undecane (2) 1
Diffusion of xenon (1); undecane (2)

Vapor in Liquid
Xe (1) xenon 7440-63-3

C11H24 (2) undecane 1120-21-4
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 2.52 ± 4.2%
Reference

Diffusion of xenon (1); dodecane (2) 1
Diffusion of xenon (1); dodecane (2)

Vapor in Liquid
Xe (1) xenon 7440-63-3

C12H26 (2) dodecane 112-40-3
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 2.29 ± 4.2%
Xe (1) xenon 7440-63-3

C12H26 (2) dodecane 112-40-3
T [K] p [MPa] D · 109 [m2/s]
298.15 ± 0.5 5.0 2.60 ± 10%
References

Diffusion of xenon (1); tridecane (2) 1
Diffusion of xenon (1); tridecane (2)

Vapor in Liquid
Xe (1) xenon 7440-63-3

C13H28 (2) tridecane 629-50-5
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 1.91 ± 4.2%
Reference

Diffusion of xenon (1); tetradecane (2) 1
Diffusion of xenon (1); tetradecane (2)

Vapor in Liquid
Xe (1) xenon 7440-63-3

T [K] p [kPa] D · 109 [m2/s]
283.15 101.325 1.32 ± 1.5%
293.15 101.325 1.57 ± 1.5%
303.15 101.325 1.90 ± 1.5%
313.15 101.325 2.25 ± 1.5%
Xe (1) xenon 7440-63-3

T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 1.67 ± 4.2%
Xe (1) xenon 7440-63-3

T [K] p [atm] D · 109 [m2/s]
298.15 3 1.72 ± 0.01
Xe (1) xenon 7440-63-3

3.047 9797
References

Diffusion of xenon (1); pentadecane (2) 1
Diffusion of xenon (1); pentadecane (2)

Vapor in Liquid
Xe (1) xenon 7440-63-3

C15H32 (2) pentadecane 629-62-9
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 1.45 ± 4.2%
Reference

Diffusion of xenon (1); hexadecane (2) 1
Diffusion of xenon (1); hexadecane (2)

Vapor in Liquid
Xe (1) xenon 7440-63-3

T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 1.27 ± 4.2%
Reference

Diffusion of xenon (1); tetrabutyl-stannane (2) 1
Diffusion of xenon (1); tetrabutyl-stannane (2)

Vapor in Liquid
Xe (1) xenon 7440-63-3

T [K] p [atm] D · 109 [m2/s]
298.15 3 1.34 ± 0.02
Reference

Diffusion of xenon (1); water (2) 1
Diffusion of xenon (1); water (2)

Vapor in Liquid
Xe (1) xenon 7440-63-3

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
283.15 ± 0.1 101.325 0.41 ± 2%
293.15 ± 0.1 101.325 0.60 ± 2%
303.15 ± 0.1 101.325 1.02 ± 2%
313.15 ± 0.1 101.325 1.56 ± 2%
323.15 ± 0.1 101.325 2.27 ± 2%
333.15 ± 0.1 101.325 3.98 ± 2%
Xe (1) xenon 7440-63-3

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
273.15 ± 0.1 101.325 0.542 ± 5%
298.15 ± 0.1 101.325 0.827 ± 5%
323.15 ± 0.1 101.325 1.48 ± 5%
Xe (1) xenon 7440-63-3

H 2O (2) water 7732-18-5
T [K] p [kPa] D · 109 [m2/s]
298.15 101.325 2.2 ± 0.4
Xe (1) xenon 7440-63-3

H 2O (2) water 7732-18-5
Diffusion of solute(1) in liquid(2): D*1(2)(T ); Method: TB Ref.: 1981P8
T [K] p [kPa] D · 109 [m2/s]
293.15 101.325 1.32 ± 0.05
Xe (1) xenon 7440-63-3

H 2O (2) water 7732-18-5
1200 8410 *

2 Diffusion of xenon (1); water (2)
References
1981P8 Pollack, G.L.: Phys. Rev. A 23 (1981) 2660–2663.

Diffusion of argon (1); water (2); ethanol (3) 1
Diffusion of argon (1); water (2); ethanol (3)

Data extract from of Landolt-Börnstein IV/15A, Chapter 6.1.1: Diffusion of Gas in
Solution
Ar (1) argon 7440-37-1

H 2O (2) water 7732-18-5
Diffusion of gas(1) in solution: D*1(23); p = 101.325 kPa; Method: DIA Ref.: 1978T1
T [K] x3 D · 109 [m2/s]
298.15 ± 0.05 0.000 2.22 ± 4%
298.15 ± 0.05 0.045 1.87 ± 4%
298.15 ± 0.05 0.090 1.53 ± 4%
298.15 ± 0.05 0.150 1.02 ± 4%
298.15 ± 0.05 0.250 1.12 ± 4%
Reference

Diffusion of argon (1); water (2); 1,4-dioxane (3) 1
Diffusion of argon (1); water (2); 1,4-dioxane (3)

Solution
Ar (1) argon 7440-37-1

H 2O (2) water 7732-18-5
C4H8O2 (3) 1,4-dioxane 123-91-1
T [K] x3 D · 109 [m2/s]
298.15 ± 0.05 0.000 2.22 ± 4%
298.15 ± 0.05 0.015 2.19 ± 4%
298.15 ± 0.05 0.060 2.09 ± 4%
298.15 ± 0.05 0.150 1.35 ± 4%
298.15 ± 0.05 0.200 1.54 ± 4%
298.15 ± 0.05 0.250 1.85 ± 4%
Reference

Diffusion of dichloro-difluoro-methane (1); water (2); saccharose (3) 1
Diffusion of dichloro-difluoro-methane (1); water (2);

saccharose (3)
Solution

H 2O (2) water 7732-18-5
C12H22O11 (3) saccharose 57-50-1
Diffusion of gas(1) in solution: D*1(23); p = 720 Torr; Method: BUBBLE Ref.: 1981Z1
T [K] w3 D · 109 [m2/s]
298.15 0.05 0.99
298.15 0.10 0.96
298.15 0.15 0.91
298.15 0.20 0.83
298.15 0.25 0.75
298.15 0.30 0.69
298.15 0.35 0.64
Reference
239–246.

Diffusion of methane (1); hexane (2); benzene (3) 1
Diffusion of methane (1); hexane (2); benzene (3)

Solution
CH4 (1) methane 74-82-8

C6H14 (2) hexane 110-54-3
C6H6 (3) benzene 71-43-2
Intradiffusion Coefficient: D1T (xi); T = 333.1 K; Method: NMR PG Ref.: 1996H5
x1 x2 p [MPa] D1T · 109 [m2/s] D2T · 109 [m2/s] D3T · 109 [m2/s]
0.00 0.50 30 4.2 4.3
0.00 0.50 40 3.8 4.0
0.00 0.50 50 3.5 3.8
0.22 0.39 30 11.8 5.3 5.8
0.22 0.39 40 10.2 5.2 5.3
0.22 0.39 50 9.6 4.5 5.0
0.32 0.34 30 13.5 6.6 6.7 *
0.32 0.34 40 12.4 5.8 6.1 *
0.32 0.34 50 11.6 5.1 5.7 *
0.62 0.19 30 27.0 13.3 13.3
0.62 0.19 40 23.0 11.9 11.9
0.62 0.19 50 22.0 10.5 11.5
0.70 0.15 30 31.0 15.1 15.1 **
0.70 0.15 40 27.0 13.8 13.8 **
0.70 0.15 50 24.0 12.3 12.3 **
0.80 0.10 30 45.0 19.9 23.0 **
0.80 0.10 40 36.0 15.4 18.7 **
0.80 0.10 50 30.0 13.1 15.9 **
Comment: *: T = 333.0 K; **: T = 333.2 K; accuracy: ±5%
CH4 (1) methane 74-82-8

C6H14 (2) hexane 110-54-3
C6H6 (3) benzene 71-43-2
Intradiffusion Coefficient: D1T (xi); T = 303.2 K; Method: NMR PG Ref.: 1996H5
x1 x2 p [MPa] D1T · 109 [m2/s] D2T · 109 [m2/s] D3T · 109 [m2/s]
0.00 0.50 30 2.9 3.0
0.00 0.50 40 2.9 2.8
0.00 0.50 50 2.7 2.8
0.22 0.39 30 8.4 3.9 4.1
0.22 0.39 40 7.9 3.6 3.9
0.22 0.39 50 7.6 3.5 3.7
0.32 0.34 30 10.0 4.8 4.9 *
0.32 0.34 40 9.6 4.3 4.5 *
0.32 0.34 50 8.5 4.1 4.2 *
0.62 0.19 30 20.0 9.4 10.1
0.62 0.19 40 18.8 8.8 8.9
0.62 0.19 50 17.3 8.4 8.7
0.70 0.15 30 23.0 12.1 11.9 **
(continued)
2 Diffusion of methane (1); hexane (2); benzene (3)
0.70 0.15 40 21.0 10.7 10.7 **

0.70 0.15 50 18.5 9.9 9.7 **
0.80 0.10 30 35.0 14.8 17.1 **
0.80 0.10 40 30.0 14.4 15.7 **
0.80 0.10 50 26.0 12.8 14.2 **
Comment: *: T = 303.1 K; **: T = 303.4 K; accuracy: ±5%
Reference
598–603.

Diffusion of methane (1); water (2); ethanol (3) 1
Diffusion of methane (1); water (2); ethanol (3)

Solution
CH4 (1) methane 74-82-8

H 2O (2) water 7732-18-5
T [K] x3 D · 109 [m2/s]
298.15 ± 0.05 0.000 1.88 ± 4%
298.15 ± 0.05 0.045 1.61 ± 4%
298.15 ± 0.05 0.090 1.04 ± 4%
298.15 ± 0.05 0.150 0.43 ± 4%
298.15 ± 0.05 0.200 0.52 ± 4%
298.15 ± 0.05 0.250 0.54 ± 4%
Reference

Diffusion of carbon oxide sulfide (1); water (2); ethane-1,2-diol (3) 1
Diffusion of carbon oxide sulfide (1); water (2); ethane-1,2-

diol (3)
Solution

H 2O (2) water 7732-18-5
C2H6O2 (3) ethane-1,2-diol 107-21-1
Diffusivity of gas(1) in solution: D1eff; p = 101.325 kPa; Method: LAM Ref.: 1989A3
T [K] w3 D · 109 [m2/s]
298.15 0.00 1.727 ± 5%
298.15 0.155 1.558 ± 5%
Reference
1989A3 Al-Ghawas, H.A., Ruiz-Ibanez, G., Sandall, O.C.: Chem. Eng. Sci. 44 (1989) 631–639.

1
Diffusion of carbon oxide sulfide (1); water (2); bis-(2-

hydroxy-ethyl)-methyl-amine (3)
Solution

H 2O (2) water 7732-18-5
C5H13NO2 (3) bis-(2-hydroxy-ethyl)-methyl-amine 105-59-9
T [K] w3 D · 109 [m2/s]
293.15 0.00 1.616 ± 5%
293.15 0.1527 1.275 ± 5%
293.15 0.2021 1.168 ± 5%
293.15 0.3021 0.943 ± 5%
298.15 0.00 1.783 ± 5%
298.15 0.1527 1.472 ± 5%
298.15 0.2021 1.364 ± 5%
298.15 0.3021 1.126 ± 5%
303.15 0.00 1.956 ± 5%
303.15 0.1527 1.672 ± 5%
303.15 0.2021 1.565 ± 5%
303.15 0.3021 1.314 ± 5%
308.15 0.00 2.134 ± 5%
308.15 0.1527 1.876 ± 5%
308.15 0.2021 1.769 ± 5%
308.15 0.3021 1.510 ± 5%
313.15 0.00 2.321 ± 5%
313.15 0.1527 2.086 ± 5%
313.15 0.2021 1.981 ± 5%
313.15 0.3021 1.716 ± 5%
Reference

Diffusion of carbon dioxide (1); tetrachloro-methane (2); benzene (3) 1
Diffusion of carbon dioxide (1); tetrachloro-methane (2);

benzene (3)
Solution

C6H6 (3) benzene 71-43-2
Diffusion of gas(1) in solution: D*1(23); p = 101.325 kPa; Method: ABSORB Ref.: 1982T1
T [K] x2 D · 109 [m2/s]
298 ± 0.1 0.00 3.85
298 ± 0.1 0.20 3.65
298 ± 0.1 0.40 3.60
298 ± 0.1 0.60 3.35
298 ± 0.1 0.80 3.25
298 ± 0.1 1.00 3.17
Reference
1982T1 Takahashi, M., Kobayashi, Y., Takeuchi, H.: J. Chem. Eng. Data 27 (1982) 328–331.

Diffusion of carbon dioxide (1); methanol (2); water (3) 1
Diffusion of carbon dioxide (1); methanol (2); water (3)

Solution

H 2O (3) water 7732-18-5
T [K] x2 D · 109 [m2/s]
298 ± 0.1 0.00 1.97
298 ± 0.1 0.20 1.98
298 ± 0.1 0.40 2.30
298 ± 0.1 0.60 2.76
298 ± 0.1 0.80 3.60
298 ± 0.1 1.00 4.54
Reference

Diffusion of carbon dioxide (1); ethanol (2); water (3) 1
Diffusion of carbon dioxide (1); ethanol (2); water (3)

Solution

H 2O (3) water 7732-18-5
T [K] x2 D · 109 [m2/s]
298 ± 0.1 0.00 1.97
298 ± 0.1 0.20 1.76
298 ± 0.1 0.40 2.06
298 ± 0.1 0.60 2.60
298 ± 0.1 0.80 3.05
298 ± 0.1 1.00 3.86
Reference

Diffusion of carbon dioxide (1); ethane-1,2-diol (2); water (3) 1
Diffusion of carbon dioxide (1); ethane-1,2-diol (2); water

(3)
Solution

C2H6O2 (2) ethane-1,2-diol 107-21-1
H 2O (3) water 7732-18-5
Diffusion of gas(1) in solution: D*1(23); p = 101.325 kPa; Method: ABSORB Ref.: 1981W3
T [K] x2 D · 109 [m2/s]
298.15 0.00 1.96
298.15 0.052 1.58
298.15 0.12 1.22
298.15 0.20 1.02
Reference

Diffusion of carbon dioxide (1); propan-1-ol (2); ethanol (3) 1
Diffusion of carbon dioxide (1); propan-1-ol (2); ethanol (3)

Solution

C3H8O (2) propan-1-ol 71-23-8
T [K] x2 D · 109 [m2/s]
298 ± 0.1 0.00 3.86
298 ± 0.1 0.20 3.72
298 ± 0.1 0.40 3.50
298 ± 0.1 0.60 3.33
298 ± 0.1 0.80 3.26
298 ± 0.1 1.00 3.06
Reference

Diffusion of carbon dioxide (1); propan-1-ol (2); benzene (3) 1
Diffusion of carbon dioxide (1); propan-1-ol (2); benzene

(3)
Solution

C3H8O (2) propan-1-ol 71-23-8
C6H6 (3) benzene 71-43-2
T [K] x2 D · 109 [m2/s]
298 ± 0.1 0.00 3.85
298 ± 0.1 0.20 3.95
298 ± 0.1 0.40 4.18
298 ± 0.1 0.60 4.20
298 ± 0.1 0.80 3.20
298 ± 0.1 1.00 3.06
Reference

Diffusion of carbon dioxide (1); propan-1-ol (2); water (3) 1
Diffusion of carbon dioxide (1); propan-1-ol (2); water (3)

Solution

C3H8O (2) propan-1-ol 71-23-8
H 2O (3) water 7732-18-5
T [K] x2 D · 109 [m2/s]
298 ± 0.1 0.00 1.97
298 ± 0.1 0.20 1.76
298 ± 0.1 0.40 2.04
298 ± 0.1 0.60 2.30
298 ± 0.1 0.80 2.69
298 ± 0.1 1.00 3.06

C3H8O (2) propan-1-ol 71-23-8
H 2O (3) water 7732-18-5
T [K] x2 D · 109 [m2/s]
298.15 0.0 1.95
298.15 0.02 1.71
298.15 0.05 1.43
298.15 0.10 1.42
298.15 0.20 1.57
298.15 0.50 1.93
298.15 1.00 2.73
References

Diffusion of carbon dioxide (1); 2-methyl-propan-1-ol (2); formamide (3) 1
Diffusion of carbon dioxide (1); 2-methyl-propan-1-ol (2);

formamide (3)
Solution

CH3NO (3) formamide 75-12-7
T [K] x2 D · 109 [m2/s]
298 ± 0.1 0.00 0.946
298 ± 0.1 0.20 1.15
298 ± 0.1 0.40 1.27
298 ± 0.1 0.60 1.49
298 ± 0.1 0.80 1.76
298 ± 0.1 1.00 2.02
Reference

Diffusion of carbon dioxide (1); octan-1-ol (2); tetrachloro-methane (3) 1
Diffusion of carbon dioxide (1); octan-1-ol (2); tetrachloro-

methane (3)
Solution

C8H18O (2) octan-1-ol 111-87-5
T [K] x2 D · 109 [m2/s]
298 ± 0.1 0.00 3.17
298 ± 0.1 0.20 2.70
298 ± 0.1 0.40 2.40
298 ± 0.1 0.60 1.96
298 ± 0.1 0.80 1.80
298 ± 0.1 1.00 1.53
Reference

Diffusion of carbon dioxide (1); water (2); ethane-1,2-diol (3) 1
Diffusion of carbon dioxide (1); water (2); ethane-1,2-diol

(3)
Solution

H 2O (2) water 7732-18-5
C2H6O2 (3) ethane-1,2-diol 107-21-1
Diffusion of gas(1) in solution: D*1(23); p = 101.325 kPa; Method: OEC Ref.: 1971H3
T [K] x3 D · 109 [m2/s]
298.15 0.00 1.98
298.15 0.257 0.894
298.15 0.270 0.808
298.15 0.572 0.554
298.15 0.572 0.582
298.15 0.618 0.549
298.15 0.824 0.408
298.15 0.997 0.280
298.15 0.997 0.283
298.15 1.00* 0.279

H 2O (2) water 7732-18-5
C2H6O2 (3) ethane-1,2-diol 107-21-1
Diffusion of gas(1) in solution: D*1(23); p = 101.325 kPa; Method: DIA Ref.: 1959C1
T [K] w3 D · 1010 [m2/s]
298.15 0.94 3.5
298.15 0.85 4.35
298.15 0.79 5.4
298.15 0.72 7.08
298.15 0.58 8.05
298.15 0.41 10.6
References
1971H3 Hayduk, W., Malik, V.K.: J. Chem. Eng. Data 16 (1971) 143–146.
1959C1 Calderbank, P.H.: Trans. Inst. Chem. Eng. 37 (1959) 173–185.

Diffusion of carbon dioxide (1); water (2); propane-1,2,3-triol (3) 1
Diffusion of carbon dioxide (1); water (2); propane-1,2,3-

triol (3)
Solution

H 2O (2) water 7732-18-5
C3H8O3 (3) propane-1,2,3-triol 56-81-5
Diffusion of gas(1) in solution: D*1(23); p = 101.325 kPa; Method: DIA Ref.: 1959C1
T [K] w3 D · 1010 [m2/s]
298.15 0.704 1.52
298.15 0.676 2.32
298.15 0.644 2.88
298.15 0.604 3.88
298.15 0.540 4.99
298.15 0.450 6.05
298.15 0.280 9.34
298.15 0.193 13.40
298.15 0.095 17.10

H 2O (2) water 7732-18-5
Diffusion of gas(1) in solution: D*1(23); p = 101.325 kPa; Method: OTE Ref.: 1988D3
T [K] x3 D · 109 [m2/s]
298.15 0.02 1.47 ± 0.005
298.15 0.04 1.19 ± 0.005
References
1959C1 Calderbank, P.H.: Trans. Inst. Chem. Eng. 37 (1959) 173–185.

Diffusion of carbon dioxide (1); water (2); 2-amino-2-methyl-propan-1-ol (3) 1
Diffusion of carbon dioxide (1); water (2); 2-amino-2-

methyl-propan-1-ol (3)
Solution

H 2O (2) water 7732-18-5
C4H11NO (3) 2-amino-2-methyl-propan-1-ol 124-68-5
Diffusivity of gas(1) in solution: D1eff; p = 101.325 kPa; Method: ABSORB Ref.: 1993S1
T [K] c3 [mol/l] D · 109 [m2/s]
294.0 ± 0.1 0.5 1.72 ± 5%
294.0 ± 0.1 1.0 1.42 ± 5%
294.0 ± 0.1 1.5 1.19 ± 5%
294.0 ± 0.1 2.0 0.96 ± 5%
301.5 ± 0.1 0.5 1.95 ± 5%
301.5 ± 0.1 1.0 1.65 ± 5%
301.5 ± 0.1 1.5 1.39 ± 5%
301.5 ± 0.1 2.0 1.17 ± 5%
311.5 ± 0.1 0.5 2.39 ± 5%
311.5 ± 0.1 1.0 2.06 ± 5%
311.5 ± 0.1 1.5 1.75 ± 5%
311.5 ± 0.1 2.0 1.51 ± 5%
318.0 ± 0.1 0.5 2.76 ± 5%
318.0 ± 0.1 1.0 2.34 ± 5%
318.0 ± 0.1 1.5 2.06 ± 5%
318.0 ± 0.1 2.0 1.71 ± 5%
Comment: values determined from N2O analogy

H 2O (2) water 7732-18-5
Diffusivity of gas(1) in solution: D1eff; p = 101.325 kPa; Method: ABSORB Ref.: 1991X1
T [K] c3 [mol/dm3] D · 109 [m2/s]
298.15 ± 0.1 2.0 0.73 ± 5%
308.15 ± 0.1 2.0 1.25 ± 5%
318.15 ± 0.1 2.0 1.75 ± 5%
328.15 ± 0.1 2.0 2.39 ± 5%
338.15 ± 0.1 2.0 3.20 ± 5%
348.15 ± 0.1 2.0 4.43 ± 5%
298.15 ± 0.1 3.0 0.78 ± 5%
308.15 ± 0.1 3.0 1.12 ± 5%
318.15 ± 0.1 3.0 1.58 ± 5%
328.15 ± 0.1 3.0 2.18 ± 5%
338.15 ± 0.1 3.0 2.95 ± 5%
348.15 ± 0.1 3.0 3.93 ± 5%

2 Diffusion of carbon dioxide (1); water (2); 2-amino-2-methyl-propan-1-ol (3)

H 2O (2) water 7732-18-5
Diffusion of gas(1) in solution: D*1(23); p = 101.325 kPa; Method: ABSORB Ref.: 1990B6
T [K] c3 [mol/dm3] D · 109 [m2/s]
298.15 0.202 1.89
298.15 0.206 1.89
298.15 0.298 1.87
298.15 0.308 1.86
298.15 0.400 1.84
298.15 0.401 1.84
298.15 0.816 1.67
298.15 0.810 1.68
298.15 1.556 1.33
298.15 1.487 1.36
298.15 2.310 1.02
298.15 2.373 0.99
References
1990B6 Bosch, H., Versteeg, G.F., van Swaaij, W.P.M.: Chem. Eng. Sci. 45 (1990) 1167–1173.

Diffusion of carbon dioxide (1); water (2); bis-(2-hydroxy-ethyl)-amine (3) 1
Diffusion of carbon dioxide (1); water (2); bis-(2-hydroxy-

ethyl)-amine (3)
Solution

H 2O (2) water 7732-18-5
Diffusion of gas(1) in solution: D*1(23); p = 101.325 kPa; Method: ABSORB Ref.: 2001A6
T [K] w3 D · 109 [m2/s]
288.15 0.100 1.1699
293.15 0.100 1.2862
298.15 0.100 1.4096
303.15 0.100 1.5402
305.15 0.100 1.5945
313.15 0.100 1.8232
315.15 0.100 1.8834
323.15 0.100 2.1358
332.15 0.100 2.4428
333.15 0.100 2.4784
353.15 0.100 3.2538
368.15 0.100 3.9140
288.15 0.200 1.1255
293.15 0.200 1.1898
298.15 0.200 1.2554
302.15 0.200 1.3088
303.15 0.200 1.3223
311.15 0.200 1.4318
313.15 0.200 1.4596
323.15 0.200 1.6014
327.15 0.200 1.6592
333.15 0.200 1.7472
353.15 0.200 2.0492
368.15 0.200 2.2834
288.15 0.300 0.8996
293.15 0.300 0.9543
298.15 0.300 1.0103
303.15 0.300 1.0676
312.15 0.300 1.1738
313.15 0.300 1.1859
320.15 0.300 1.2714
323.15 0.300 1.3087
332.15 0.300 1.4228
353.15 0.300 1.7009
368.15 0.300 1.9082
Comment: values fitted to experimental data

2 Diffusion of carbon dioxide (1); water (2); bis-(2-hydroxy-ethyl)-amine (3)

H 2O (2) water 7732-18-5
T [K] w3 D · 109 [m2/s]
303.15 ± 0.2 0.100 1.6191 ± 2%
305.15 ± 0.2 0.100 1.6197 ± 2%
313.15 ± 0.2 0.100 1.7491 ± 2%
315.15 ± 0.2 0.100 1.7825 ± 2%
323.15 ± 0.2 0.100 2.0886 ± 2%
332.15 ± 0.2 0.100 2.5791 ± 2%
302.15 ± 0.2 0.200 1.3273 ± 2%
311.15 ± 0.2 0.200 1.4178 ± 2%
313.15 ± 0.2 0.200 1.4459 ± 2%
327.15 ± 0.2 0.200 1.6462 ± 2%
333.15 ± 0.2 0.200 1.7702 ± 2%
303.15 ± 0.2 0.300 1.0783 ± 2%
312.15 ± 0.2 0.300 1.1458 ± 2%
320.15 ± 0.2 0.300 1.2947 ± 2%
323.15 ± 0.2 0.300 1.3042 ± 2%
332.15 ± 0.2 0.300 1.4217 ± 2%
Comment: diffusion in protonated solution of (3)
Reference
516–521.

Diffusion of carbon dioxide (1); water (2); pentane-1,5-diol (3) 1
Diffusion of carbon dioxide (1); water (2);

pentane-1,5-diol (3)
Solution

H 2O (2) water 7732-18-5
C5H12O2 (3) pentane-1,5-diol 111-29-5
T [K] x3 D · 109 [m2/s]
298.15 0.02 1.57 ± 0.005
298.15 0.04 1.28 ± 0.005
Reference

Diffusion of carbon dioxide (1); water (2); bis-(2-hydroxy-ethyl)-methyl-amine (3) 1

ethyl)-methyl-amine (3)
Solution

H 2O (2) water 7732-18-5
Diffusion of gas(1) in solution: D*1(23); p = 101.325 kPa; Method: ABSORB Ref.: 2000K2
T [K] c3 [mol/dm3] D · 109 [m2/s]
303.15 0.00 2.17 ± 2%
303.15 0.5 1.97 ± 2%
303.15 1.0 1.68 ± 2%
303.15 1.5 1.40 ± 2%
303.15 2.0 1.13 ± 2%
303.15 2.5 1.00 ± 2%
308.15 0.00 2.41 ± 2%
308.15 0.5 2.22 ± 2%
308.15 1.0 1.85 ± 2%
308.15 1.5 1.57 ± 2%
308.15 2.0 1.32 ± 2%
308.15 2.5 1.09 ± 2%
313.15 0.00 2.76 ± 2%
313.15 0.5 2.32 ± 2%
313.15 1.0 2.08 ± 2%
313.15 1.5 1.75 ± 2%
313.15 2.0 1.46 ± 2%
313.15 2.5 1.31 ± 2%

H 2O (2) water 7732-18-5
T [K] w3 D · 109 [m2/s]
288.15 ± 0.30 0.10 1.222
293.15 ± 0.30 0.10 1.379
298.15 ± 0.30 0.10 1.630
303.15 ± 0.30 0.10 1.925
308.15 ± 0.30 0.10 2.190
313.15 ± 0.30 0.10 2.600
318.15 ± 0.30 0.10 2.863
323.15 ± 0.30 0.10 3.154
288.15 ± 0.30 0.20 0.982
293.15 ± 0.30 0.20 1.180
298.15 ± 0.30 0.20 1.412
(continued)

2 Diffusion of carbon dioxide (1); water (2); bis-(2-hydroxy-ethyl)-methyl-amine (3)
303.15 ± 0.30 0.20 1.734

308.15 ± 0.30 0.20 2.091
313.15 ± 0.30 0.20 2.419
318.15 ± 0.30 0.20 2.634
323.15 ± 0.30 0.20 2.986
288.15 ± 0.30 0.30 0.831
293.15 ± 0.30 0.30 0.980
298.15 ± 0.30 0.30 1.197
303.15 ± 0.30 0.30 1.387
308.15 ± 0.30 0.30 1.721
313.15 ± 0.30 0.30 2.001
318.15 ± 0.30 0.30 2.196
323.15 ± 0.30 0.30 2.541
288.15 ± 0.30 0.40 0.688
293.15 ± 0.30 0.40 0.761
298.15 ± 0.30 0.40 0.924
303.15 ± 0.30 0.40 1.108
308.15 ± 0.30 0.40 1.471
313.15 ± 0.30 0.40 1.788
318.15 ± 0.30 0.40 1.979
323.15 ± 0.30 0.40 2.264
288.15 ± 0.30 0.50 0.384
293.15 ± 0.30 0.50 0.512
298.15 ± 0.30 0.50 0.622
303.15 ± 0.30 0.50 0.754
308.15 ± 0.30 0.50 0.940
313.15 ± 0.30 0.50 1.214
318.15 ± 0.30 0.50 1.421
323.15 ± 0.30 0.50 1.688
References
2000K2 Ko, J.J., Li, M.H.: Chem. Eng. Sci. 55 (2000) 4139–4147.
(1989) 385–391.

Diffusion of carbon dioxide (1); water (2); tris-(2-hydroxy-ethyl)-amine (3) 1
Diffusion of carbon dioxide (1); water (2); tris-(2-hydroxy-

ethyl)-amine (3)
Solution

H 2O (2) water 7732-18-5
C6H15NO3 (3) tris-(2-hydroxy-ethyl)-amine 102-71-6
T [K] w3 D · 109 [m2/s]
293.15 ± 0.2 0.100 1.29 ± 2%
303.15 ± 0.2 0.100 1.67 ± 2%
313.15 ± 0.2 0.100 2.14 ± 2%
323.15 ± 0.2 0.100 2.67 ± 2%
333.15 ± 0.2 0.100 3.27 ± 2%
293.15 ± 0.2 0.200 0.88 ± 2%
303.15 ± 0.2 0.200 1.15 ± 2%
313.15 ± 0.2 0.200 1.55 ± 2%
323.15 ± 0.2 0.200 1.99 ± 2%
333.15 ± 0.2 0.200 2.47 ± 2%
293.15 ± 0.2 0.300 0.58 ± 2%
303.15 ± 0.2 0.300 0.80 ± 2%
313.15 ± 0.2 0.300 1.08 ± 2%
323.15 ± 0.2 0.300 1.40 ± 2%
333.15 ± 0.2 0.300 1.78 ± 2%
Comment: diffusion in protonated solution of (3)

H 2O (2) water 7732-18-5
Diffusivity of gas(1) in solution: D1eff; p = 101.325 kPa; Method: BUBBLE Ref.: 1990S4
T [K] c3 [mol/dm3] D · 109 [m2/s]
293.15 0.010 1.68
293.15 0.050 1.67
293.15 0.100 1.66
293.15 0.250 1.62
293.15 0.500 1.55
303.15 0.010 2.14
303.15 0.050 2.12
303.15 0.100 2.10
303.15 0.250 2.05
303.15 0.500 1.97
313.15 0.010 2.67
313.15 0.050 2.65
313.15 0.100 2.63
(continued)

2 Diffusion of carbon dioxide (1); water (2); tris-(2-hydroxy-ethyl)-amine (3)
313.15 0.250 2.56

313.15 0.500 2.46
References
2001A5 Abu-Arabi, M.K., Tamimi, A., Al-Jarrah, A.M.: J. Chem. Eng. Data 46 (2001) 1125–1129.
1990S4 Sotelo, J.L., Benitez, F.J., Beltran-Heredia, J., Rodriguez, C.: AIChE J. 36 (1990) 1263–1266.

1
Diffusion of carbon dioxide (1); water (2); 2-amino-

ethanol (3); 2-amino-2-methyl-propan-1-ol (4)
Solution

H 2O (2) water 7732-18-5
eff
Diffusivity of gas(1) in solution: D1 ; p = 101.325 kPa; Method: ABSORB Ref.: 1995L7
T [K] w3 w4 D · 109 [m2/s]
303.15 0.30 0.0 1.659
303.15 0.24 0.06 1.587
303.15 0.18 0.12 1.486
303.15 0.12 0.18 1.422
303.15 0.06 0.24 1.324
303.15 0.0 0.30 1.154
308.15 0.30 0.0 1.818
308.15 0.24 0.06 1.749
308.15 0.18 0.12 1.624
308.15 0.12 0.18 1.538
308.15 0.06 0.24 1.419
308.15 0.0 0.30 1.239
313.15 0.30 0.0 1.947
313.15 0.24 0.06 1.873
313.15 0.18 0.12 1.737
313.15 0.12 0.18 1.629
313.15 0.06 0.24 1.518
313.15 0.0 0.30 1.332
Comment: diffusivity by N2O/CO2 analogy, estimated error ±2%, mass fraction wi
Reference
1995L7 Li, M.-H., Lai, M-D.: J. Chem. Eng. Data 40 (1995) 486–492.

1

ethanol (3); bis-(2-hydroxy-ethyl)-methyl-amine (4)
Solution

H 2O (2) water 7732-18-5
Diffusivity of gas(1) in solution: D1eff; p = 101.325 kPa; Method: ABSORB Ref.: 1995L7
T [K] w3 w4 D · 109 [m2/s]
303.15 0.30 0.0 1.659
303.15 0.24 0.06 1.587
303.15 0.18 0.12 1.486
303.15 0.12 0.18 1.422
303.15 0.06 0.24 1.324
303.15 0.0 0.30 1.154
308.15 0.30 0.0 1.818
308.15 0.24 0.06 1.749
308.15 0.18 0.12 1.624
308.15 0.12 0.18 1.538
308.15 0.06 0.24 1.419
308.15 0.0 0.30 1.239
313.15 0.30 0.0 1.947
313.15 0.24 0.06 1.873
313.15 0.18 0.12 1.737
313.15 0.12 0.18 1.629
313.15 0.06 0.24 1.518
313.15 0.0 0.30 1.332
Comment: diffusivity by N2O/CO2 analogy, estimated error ±2%, mass fraction wi
Reference

1

ethanol (3); tris-(2-hydroxy-ethyl)-amine (4)
Solution

H 2O (2) water 7732-18-5
Diffusion of gas(1) in solution: D*1(23); p = 101.325 kPa; Method: ABSORB Ref.: 2002H1
T [K] c3 c4 D · 109 [m2/s]
303.15 0.1 0.5 1.89 ± 2%
303.15 0.2 0.5 1.80 ± 2%
303.15 0.3 0.5 1.74 ± 2%
303.15 0.4 0.5 1.69 ± 2%
303.15 0.5 0.5 1.64 ± 2%
303.15 0.1 1.0 1.65 ± 2%
303.15 0.2 1.0 1.54 ± 2%
303.15 0.3 1.0 1.43 ± 2%
303.15 0.4 1.0 1.31 ± 2%
303.15 0.5 1.0 1.16 ± 2%
308.15 0.1 0.5 2.17 ± 2%
308.15 0.2 0.5 2.07 ± 2%
308.15 0.3 0.5 1.92 ± 2%
308.15 0.4 0.5 1.84 ± 2%
308.15 0.5 0.5 1.79 ± 2%
308.15 0.1 1.0 1.78 ± 2%
308.15 0.2 1.0 1.69 ± 2%
308.15 0.3 1.0 1.58 ± 2%
308.15 0.4 1.0 1.47 ± 2%
308.15 0.5 1.0 1.30 ± 2%
313.15 0.1 0.5 2.33 ± 2%
313.15 0.2 0.5 2.22 ± 2%
313.15 0.3 0.5 2.19 ± 2%
313.15 0.4 0.5 2.10 ± 2%
313.15 0.5 0.5 2.07 ± 2%
313.15 0.1 1.0 2.08 ± 2%
313.15 0.2 1.0 1.93 ± 2%
313.15 0.3 1.0 1.83 ± 2%
313.15 0.4 1.0 1.58 ± 2%
313.15 0.5 1.0 1.54 ± 2%
Comment: molarities ci in [mol/dm3]
Reference
2002H1 Horng, S.Y., Li, M.H.: Ind. Eng. Chem. Res. 41 (2002) 257–266.

1
Diffusion of carbon dioxide (1); water (2); 2-amino-2-

methyl-propan-1-ol (3); bis-(2-hydroxy-ethyl)-amine (4)
Solution

H 2O (2) water 7732-18-5
Diffusion of gas(1) in solution: D*1(23); p = 101.325 kPa; Method: ABSORB Ref.: 2004M1
T [K] w3 w4 D · 109 [m2/s]
293 ± 0.2 0.30 0.00 0.79 ± 2%
293 ± 0.2 0.285 0.015 0.80 ± 2%
293 ± 0.2 0.27 0.03 0.82 ± 2%
293 ± 0.2 0.255 0.045 0.86 ± 2%
293 ± 0.2 0.24 0.06 0.88 ± 2%
293 ± 0.2 0.255 0.075 0.89 ± 2%
293 ± 0.2 0.21 0.09 0.93 ± 2%
293 ± 0.2 0.00 0.30 1.16 ± 2%
298 ± 0.2 0.30 0.00 0.88 ± 2%
298 ± 0.2 0.285 0.015 0.89 ± 2%
298 ± 0.2 0.27 0.03 0.90 ± 2%
298 ± 0.2 0.255 0.045 0.92 ± 2%
298 ± 0.2 0.24 0.06 0.93 ± 2%
298 ± 0.2 0.255 0.075 0.96 ± 2%
298 ± 0.2 0.21 0.09 0.98 ± 2%
298 ± 0.2 0.00 0.30 1.18 ± 2%
303 ± 0.2 0.30 0.00 1.09 ± 2%
303 ± 0.2 0.285 0.015 1.10 ± 2%
303 ± 0.2 0.27 0.03 1.12 ± 2%
303 ± 0.2 0.255 0.045 1.13 ± 2%
303 ± 0.2 0.24 0.06 1.15 ± 2%
303 ± 0.2 0.225 0.075 1.16 ± 2%
303 ± 0.2 0.21 0.09 1.21 ± 2%
303 ± 0.2 0.00 0.30 1.35 ± 2%
308 ± 0.2 0.30 0.00 1.28 ± 2%
308 ± 0.2 0.285 0.015 1.29 ± 2%
308 ± 0.2 0.27 0.03 1.33 ± 2%
308 ± 0.2 0.255 0.045 1.34 ± 2%
308 ± 0.2 0.24 0.06 1.36 ± 2%
308 ± 0.2 0.225 0.075 1.37 ± 2%
308 ± 0.2 0.21 0.09 1.38 ± 2%
308 ± 0.2 0.00 0.30 1.49 ± 2%
313 ± 0.2 0.30 0.00 1.46 ± 2%
313 ± 0.2 0.285 0.015 1.47 ± 2%
313 ± 0.2 0.27 0.03 1.49 ± 2%
313 ± 0.2 0.255 0.045 1.51 ± 2%
(continued)

2
313 ± 0.2 0.24 0.06 1.53 ± 2%

313 ± 0.2 0.225 0.075 1.54 ± 2%
313 ± 0.2 0.21 0.09 1.57 ± 2%
313 ± 0.2 0.00 0.30 1.74 ± 2%
Comment: mass fraction wi

H 2O (2) water 7732-18-5
T [K] c3 c4 D · 109 [m2/s]
303.15 1.0 0.1 1.53 ± 2%
303.15 1.0 0.2 1.36 ± 2%
303.15 1.0 0.3 1.26 ± 2%
303.15 1.0 0.4 1.15 ± 2%
303.15 1.5 0.1 1.33 ± 2%
303.15 1.5 0.2 1.10 ± 2%
303.15 1.5 0.3 0.96 ± 2%
303.15 1.5 0.4 0.83 ± 2%
308.15 1.0 0.1 1.73 ± 2%
308.15 1.0 0.2 1.56 ± 2%
308.15 1.0 0.3 1.40 ± 2%
308.15 1.0 0.4 1.26 ± 2%
308.15 1.5 0.1 1.48 ± 2%
308.15 1.5 0.2 1.26 ± 2%
308.15 1.5 0.3 1.13 ± 2%
308.15 1.5 0.4 0.98 ± 2%
313.15 1.0 0.1 1.98 ± 2%
313.15 1.0 0.2 1.75 ± 2%
313.15 1.0 0.3 1.57 ± 2%
313.15 1.0 0.4 1.46 ± 2%
313.15 1.5 0.1 1.61 ± 2%
313.15 1.5 0.2 1.44 ± 2%
313.15 1.5 0.3 1.23 ± 2%
313.15 1.5 0.4 1.11 ± 2%
References
264–270.
2004W1 Wang, H.M., Li, M.H.: J. Chem. Eng. Jpn. 37 (2004) 267–278.

1

ethyl)-amine (3); 2-amino-2-methyl-propan-1-ol (4)
Solution

H 2O (2) water 7732-18-5
eff
T [K] w3 w4 D · 109 [m2/s]
303.15 0.24 0.06 1.223
303.15 0.18 0.12 1.192
303.15 0.12 0.18 1.177
303.15 0.06 0.24 1.150
308.15 0.24 0.06 1.363
308.15 0.18 0.12 1.334
308.15 0.12 0.18 1.297
308.15 0.06 0.24 1.261
313.15 0.24 0.06 1.515
313.15 0.18 0.12 1.483
313.15 0.12 0.18 1.444
313.15 0.06 0.24 1.403
Comment: diffusivity by N2O/CO2 analogy, mass fraction wi, estimated error ±3%
Reference

1

ethyl)-amine (3); bis-(2-hydroxy-ethyl)-methyl-amine (4)
Solution

H 2O (2) water 7732-18-5
eff
T [K] w3 w4 D · 109 [m2/s]
303.15 0.30 0.0 1.237
303.15 0.24 0.06 1.225
303.15 0.18 0.12 1.213
303.15 0.12 0.18 1.195
303.15 0.06 0.24 1.180
308.15 0.30 0.0 1.386
308.15 0.24 0.06 1.365
308.15 0.18 0.12 1.337
308.15 0.12 0.18 1.310
308.15 0.06 0.24 1.282
313.15 0.30 0.0 1.556
313.15 0.24 0.06 1.507
313.15 0.18 0.12 1.463
313.15 0.12 0.18 1.432
313.15 0.06 0.24 1.393
Comment: diffusivity by N2O/CO2 analogy, mass fraction wi, estimated error ±3%
Reference

1

ethyl)-methyl-amine (3); 2-amino-ethanol (4)
Solution

H 2O (2) water 7732-18-5
eff
Diffusivity of gas(1) in solution: D1 ; p = 101.325 kPa; Method: ABSORB Ref.: 1995H1
T [K] w3 w4 D · 109 [m2/s]
303 0.30 0.0 1.387
303 0.285 0.015 1.545
303 0.27 0.03 1.723
303 0.255 0.045 1.895
303 0.40 0.0 1.108
303 0.38 0.02 1.148
303 0.36 0.04 1.231
303 0.34 0.06 1.323
313 0.30 0.0 2.001
313 0.285 0.015 2.047
313 0.27 0.03 2.176
313 0.255 0.045 2.346
313 0.40 0.0 1.788
313 0.38 0.02 1.875
313 0.36 0.04 1.953
313 0.34 0.06 2.084
323 0.30 0.0 2.541
323 0.285 0.015 2.665
323 0.27 0.03 2.801
323 0.255 0.045 2.966
323 0.40 0.0 2.264
323 0.38 0.02 2.337
323 0.36 0.04 2.491
323 0.34 0.06 2.634
Comment: diffusivity by N2O/CO2 analogy, mass fraction wi
Reference
1995H1 Hagewiesche, D.P., Ashour, S.S., Sandall, O.C.: J. Chem. Eng. Data 40 (1995) 627–629.

1

ethyl)-methyl-amine (3); bis-(2-hydroxy-ethyl)-amine (4)
Solution

H 2O (2) water 7732-18-5
eff
Diffusivity of gas(1) in solution: D1 ; p = 101.325 kPa; Method: ABSORB Ref.: 2004M1
T [K] w3 w4 D · 109 [m2/s]
293 ± 0.2 0.30 0.00 0.93 ± 2%
293 ± 0.2 0.285 0.015 1.04 ± 2%
293 ± 0.2 0.27 0.03 1.06 ± 2%
293 ± 0.2 0.255 0.045 1.07 ± 2%
293 ± 0.2 0.24 0.06 1.07 ± 2%
293 ± 0.2 0.225 0.075 1.08 ± 2%
293 ± 0.2 0.21 0.09 1.09 ± 2%
293 ± 0.2 0.00 0.30 1.16 ± 2%
298 ± 0.2 0.30 0.00 0.98 ± 2%
298 ± 0.2 0.285 0.015 1.10 ± 2%
298 ± 0.2 0.27 0.03 1.10 ± 2%
298 ± 0.2 0.255 0.045 1.11 ± 2%
298 ± 0.2 0.24 0.06 1.12 ± 2%
298 ± 0.2 0.225 0.075 1.13 ± 2%
298 ± 0.2 0.21 0.09 1.14 ± 2%
298 ± 0.2 0.00 0.30 1.18 ± 2%
303 ± 0.2 0.30 0.00 1.18 ± 2%
303 ± 0.2 0.285 0.015 1.21 ± 2%
303 ± 0.2 0.27 0.03 1.22 ± 2%
303 ± 0.2 0.255 0.045 1.24 ± 2%
303 ± 0.2 0.24 0.06 1.26 ± 2%
303 ± 0.2 0.225 0.075 1.26 ± 2%
303 ± 0.2 0.21 0.09 1.28 ± 2%
303 ± 0.2 0.00 0.30 1.35 ± 2%
308 ± 0.2 0.30 0.00 1.25 ± 2%
308 ± 0.2 0.285 0.015 1.24 ± 2%
308 ± 0.2 0.27 0.03 1.26 ± 2%
308 ± 0.2 0.255 0.045 1.28 ± 2%
308 ± 0.2 0.24 0.06 1.32 ± 2%
308 ± 0.2 0.225 0.075 1.35 ± 2%
308 ± 0.2 0.21 0.09 1.37 ± 2%
308 ± 0.2 0.00 0.30 1.49 ± 2%
313 ± 0.2 0.30 0.00 1.34 ± 2%
313 ± 0.2 0.285 0.015 1.38 ± 2%
313 ± 0.2 0.27 0.03 1.41 ± 2%
313 ± 0.2 0.255 0.045 1.46 ± 2%
(continued)

2
313 ± 0.2 0.24 0.06 1.52 ± 2%

313 ± 0.2 0.225 0.075 1.54 ± 2%
313 ± 0.2 0.21 0.09 1.60 ± 2%
313 ± 0.2 0.00 0.30 0.74 ± 2%
Reference
264–270.

Diffusion of ethene (1); butan-1-ol (2); ethane-1,2-diol (3) 1
Diffusion of ethene (1); butan-1-ol (2); ethane-1,2-diol (3)

Solution
C2H4 (1) ethene 74-85-1

C4H10O (2) butan-1-ol 71-36-3
C2H6O2 (3) ethane-1,2-diol 107-21-1
Diffusion of gas(1) in solution: D*1(23); p = 101.325 kPa; Method: CC Ref.: 1979S1
T [K] x3 D · 109 [m2/s]
298.15 ± 0.01 0.0 2.31 ± 1.8%
298.15 ± 0.01 0.172 1.26 ± 1.8%
298.15 ± 0.01 0.239 1.08 ± 1.8%
298.15 ± 0.01 0.485 0.774 ± 1.8%
298.15 ± 0.01 0.658 0.623 ± 1.8%
298.15 ± 0.01 0.820 0.527 ± 1.8%
298.15 ± 0.01 1.0 0.333 ± 1.8%
Reference
1979S1 Sahgal, A., Hayduk, W.: J. Chem. Eng. Data 24 (1979) 222–227.

Diffusion of ethene (1); hexane (2); dodecane (3) 1
Diffusion of ethene (1); hexane (2); dodecane (3)

Solution
C2H4 (1) ethene 74-85-1

C6H14 (2) hexane 110-54-3
C12H26 (3) dodecane 112-40-3
Diffusion of gas(1) in solution: D*1(23); p = 101.325 kPa; Method: CC Ref.: 1979S1
T [K] x3 D · 109 [m2/s]
298.15 ± 0.01 0.0 7.82 ± 1.8%
298.15 ± 0.01 0.238 6.18 ± 1.8%
298.15 ± 0.01 0.434 5.27 ± 1.8%
298.15 ± 0.01 0.535 4.87 ± 1.8%
298.15 ± 0.01 0.814 3.86 ± 1.8%
298.15 ± 0.01 1.0 3.11 ± 1.8%
Reference
1979S1 Sahgal, A., Hayduk, W.: J. Chem. Eng. Data 24 (1979) 222–227.

Diffusion of benzene (1); methanol (2); water (3) 1
Diffusion of benzene (1); methanol (2); water (3)

Solution
C6H6 (1) benzene 71-43-2

H 2O (3) water 7732-18-5
Diffusion of gas(1) in solution: D*1(23); p = 101.325 kPa; Method: OTE Ref.: 1994G4
T [K] v2/v3 D · 109 [m2/s]
283.15 60/40 0.574 ± 0.040
298.15 60/40 0.867 ± 0.050
313.15 60/40 1.19 ± 0.04
Comment: v2/v3: volume ratio; concentration of (1): 1766 mg/l
Reference

Diffusion of benzene (1); hexane (2); cyclohexane (3) 1
Diffusion of benzene (1); hexane (2); cyclohexane (3)

Solution
C6H6 (1) benzene 71-43-2

C6H14 (2) hexane 110-54-3
Diffusion of gas(1) in solution: D*1(23); p = 101.325 kPa; Method: DIA Ref.: 1970L3
T [K] x1 x2 D · 109 [m2/s]
298.15 0.030 0.000 1.95
298.15 0.030 0.254 2.77
298.15 0.030 0.502 3.42
298.15 0.030 0.733 4.16
298.15 0.030 1.000 4.79
Comment: average error: 3%
Reference
1970L3 Leffler, J., Cullinan, H.T.: Ind. Eng. Chem. Fundam. 9 (1970) 88–93.

Diffusion of benzene (1); water (2); methanol (3) 1
Diffusion of benzene (1); water (2); methanol (3)

Solution
C6H6 (1) benzene 71-43-2

H 2O (2) water 7732-18-5
Diffusion of gas(1) in solution: D*1(23); p = 136 atm; Method: TAYLOR Ref.: 1994L10
T [K] x3 D · 109 [m2/s]
299.15 0.700 1.49
333.15 0.700 2.85
Reference
1994L10 Lee, S.T., Olesik, S.V.: Anal. Chem. 66 (1994) 4498–4506.

Diffusion of benzene (1); water (2); methanol (3); carbon dioxide (4) 1
Diffusion of benzene (1); water (2); methanol (3); carbon

dioxide (4)
Solution
C6H6 (1) benzene 71-43-2

H 2O (2) water 7732-18-5
Diffusion of gas(1) in solution: D*1(23); p = 136 atm; Method: ABSORB Ref.: 1994L10
T [K] x3 x4 D · 109 [m2/s]
299.15 0.490 0.300 3.03
331.15 0.490 0.300 12.62
Reference

Diffusion of indole (1); carbon dioxide (2); hexane (3) 1
Diffusion of indole (1); carbon dioxide (2); hexane (3)

Solution
C8H7N (1) indole 120-72-9

C6H14 (3) hexane 110-54-3
Diffusion of solute(1) in solution: D*1(23); T = 313.2 ± 0.1 K; Method: TAYLOR Ref.: 1999F3
p [MPa] x3 D · 109 [m2/s]
16.0 0.00 10.4 ± 0.13
16.0 0.050 10.3 ± 0.88
16.0 0.101 9.36 ± 0.20
16.0 0.201 7.95 ± 0.48
16.0 0.299 7.12 ± 0.25
16.0 0.499 5.66 ± 0.11
16.0 0.702 4.54 ± 0.07
16.0 0.796 4.19 ± 0.11
16.0 1.00 3.78 ± 0.04
25.0 0.00 9.22 ± 0.06
25.0 0.090 8.26 ± 0.13
25.0 0.181 7.36 ± 0.18
25.0 0.263 6.74 ± 0.11
25.0 0.423 5.53 ± 0.11
25.0 0.554 4.84 ± 0.05
25.0 0.771 3.98 ± 0.06
25.0 1.000 3.45 ± 0.05
Reference
1999F3 Funazukuri, T., Ishiwata, Y.: Fluid Phase Equilib. 164 (1999) 117–129.

Diffusion of 2-methyl-1,4-naphthoquinone (1); carbon dioxide (2); hexane (3) 1
Diffusion of 2-methyl-1,4-naphthoquinone (1); carbon

dioxide (2); hexane (3)
Solution

C6H14 (3) hexane 110-54-3
p [MPa] x3 D · 109 [m2/s]
16.0 0.00 9.36 ± 0.27
16.0 0.053 8.56 ± 0.65
16.0 0.0565 7.83 ± 0.26
16.0 0.0922 8.41 ± 0.59
16.0 0.110 7.92 ± 0.25
16.0 0.134 7.81 ± 0.43
16.0 0.166 6.86 ± 0.41
16.0 0.188 7.01 ± 0.47
16.0 0.201 7.06 ± 0.40
16.0 0.285 6.45 ± 0.30
16.0 0.299 6.14 ± 0.22
16.0 0.357 5.63 ± 0.16
16.0 0.453 4.94 ± 0.66
16.0 0.499 4.71 ± 0.78
16.0 0.580 4.39 ± 0.12
16.0 1.00 3.12 ± 0.04
20.0 0.00 8.56 ± 0.18
20.0 0.049 8.41 ± 0.25
20.0 0.101 7.52 ± 0.49
20.0 0.213 6.49 ± 0.15
20.0 0.297 6.12 ± 0.47
20.0 0.495 4.74 ± 0.33
20.0 0.696 4.14 ± 0.07
20.0 0.794 3.74 ± 0.18
20.0 1.000 3.16 ± 0.03
25.0 0.00 7.92 ± 0.08
25.0 0.093 6.93 ± 0.32
25.0 0.181 6.39 ± 0.16
25.0 0.263 5.81 ± 0.32
25.0 0.423 4.69 ± 0.11
25.0 0.554 4.27 ± 0.07
25.0 0.631 4.05 ± 0.08
25.0 0.647 3.92 ± 0.41
25.0 0.709 3.71 ± 0.09
25.0 1.000 3.07 ± 0.02

2 Diffusion of 2-methyl-1,4-naphthoquinone (1); carbon dioxide (2); hexane (3)
Reference

Diffusion of anthracene (1); water (2); methanol (3) 1
Diffusion of anthracene (1); water (2); methanol (3)

Solution

H 2O (2) water 7732-18-5
Diffusion of gas(1) in solution: D*1(23); p = 136 atm; Method: TAYLOR Ref.: 1994L10
T [K] x3 D · 109 [m2/s]
299.15 0.70 1.01
333.15 0.70 1.95
Reference

Diffusion of anthracene (1); water (2); methanol (3); carbon dioxide (4) 1
Diffusion of anthracene (1); water (2); methanol (3); carbon

dioxide (4)
Solution

H 2O (2) water 7732-18-5
Diffusion of gas(1) in solution: D*1(23); p = 136 atm; Method: ABSORB Ref.: 1994L10
T [K] x3 x4 D · 109 [m2/s]
299.15 0.490 0.300 2.02
331.15 0.490 0.300 7.00
Reference

1
Diffusion of cis,cis-octadeca-9,12-dienoic acid methyl

ester (1); carbon dioxide (2); hexane (3)
Solution

C6H14 (3) hexane 110-54-3
p [MPa] x3 D · 109 [m2/s]
16.0 0.0 6.52 ± 0.07
16.0 0.050 6.06 ± 0.14
16.0 0.101 4.96 ± 0.45
16.0 0.201 4.45 ± 0.59
16.0 0.299 3.90 ± 0.30
16.0 0.499 3.14 ± 0.27
16.0 0.702 2.38 ± 0.17
16.0 0.796 2.11 ± 0.02
16.0 1.00 1.90 ± 0.08
25.0 0.00 5.76 ± 0.05
25.0 0.093 4.88 ± 0.41
25.0 0.181 4.37 ± 0.21
25.0 0.263 3.68 ± 0.18
25.0 0.423 3.01 ± 0.04
25.0 0.554 2.67 ± 0.06
25.0 0.647 2.37 ± 0.06
25.0 1.000 1.82 ± 0.02
Reference

Diffusion of chlorine (1); water (2); hydrogen peroxide (3) 1
Diffusion of chlorine (1); water (2); hydrogen peroxide (3)

Solution
Cl2 (1) chlorine 7782-50-5

H 2O (2) water 7732-18-5
H2O2 (3) hydrogen peroxide 7722-84-1
Diffusivity of gas(1) in solution: D1eff; p = 101.325 kPa; Method: ABSORB Ref.: 1991R7
T [K] w3 D · 109 [m2/s]
263.15 0.35 0.240
273.15 0.35 0.353
283.15 0.35 0.394
293.15 0.35 0.499
Reference
1991R7 Ruiz-Ibanez, G., Bidarian, A., Davis, R.A., Sandall, O.C.: J. Chem. Eng. Data 36 (1991)
459–466.

Diffusion of hydrogen (1); water (2); ethanol (3) 1
Diffusion of hydrogen (1); water (2); ethanol (3)

Solution
H2 (1) hydrogen 1333-74-0

H 2O (2) water 7732-18-5
Diffusion of gas(1) in solution: D*1(23); p = 101.325 kPa; Method: KMD Ref.: 1975S1
T [K] x3 D · 109 [m2/s]
293.15 0.00 3.63
293.15 0.069 3.30
293.15 0.141 3.26
293.15 0.267 3.50
293.15 0.479 4.16
293.15 0.581 4.61
293.15 1.00 6.27
Reference
1975S1 Sada, E., Kito, S., Oda, T., Ito, Y.: Chem. Eng. J. 10 (1975) 155–159.

Diffusion of nitrogen (1); water (2); methanol (3) 1
Diffusion of nitrogen (1); water (2); methanol (3)

Solution
N2 (1) nitrogen 7727-37-9

H 2O (2) water 7732-18-5
T [K] x3 D · 109 [m2/s]
293.15 0.00 2.12
293.15 0.052 1.08
293.15 0.139 1.12
293.15 0.302 1.37
293.15 0.486 1.84
293.15 0.695 2.40
293.15 1.00 3.29
Reference

Diffusion of nitrogen (1); water (2); ethanol (3) 1
Diffusion of nitrogen (1); water (2); ethanol (3)

Solution
N2 (1) nitrogen 7727-37-9

H 2O (2) water 7732-18-5
T [K] x3 D · 109 [m2/s]
293.15 0.00 2.12
293.15 0.036 0.95
293.15 0.070 0.80
293.15 0.284 0.95
293.15 0.473 1.38
293.15 0.711 1.82
293.15 1.00 2.36
Reference

Diffusion of nitrous oxide (1); ethanol (2); bis-(2-hydroxy-ethyl)-amine (3) 1
Diffusion of nitrous oxide (1); ethanol (2); bis-(2-hydroxy-

ethyl)-amine (3)
Solution

T [K] c3 [mol/dm3] D · 109 [m2/s]
293.0 0.70 1.57
293.0 1.40 1.44
293.0 2.40 1.07
293.0 3.30 0.87
Reference
1991L14 Littel, R.J., Versteeg, G.F., Van Swaaij, W.P.M.: Chem. Eng. Sci. 46 (1991) 3308–3313.

1
Diffusion of nitrous oxide (1); water (2); 2-amino-

ethanesulfonic acid potassium salt (3)
Solution

H 2O (2) water 7732-18-5
C2H6KNO3S (3) 2-amino-ethanesulfonic acid potassium salt 22890-34-2
Diffusion of gas(1) in solution: D*1(23); p = 101.325 kPa; Method: DIA Ref.: 2001K4
T [K] c3 [mol/dm3] D · 109 [m2/s]
293 ± 0.1 0.487 1.533 ± 5%
293 ± 0.1 0.748 1.460 ± 5%
293 ± 0.1 0.991 1.346 ± 5%
293 ± 0.1 1.474 1.240 ± 5%
293 ± 0.1 1.972 1.141 ± 5%
293 ± 0.1 3.039 0.897 ± 5%
293 ± 0.1 3.469 0.812 ± 5%
296 ± 0.1 0.489 1.700 ± 5%
296 ± 0.1 0.991 1.484 ± 5%
296 ± 0.1 1.474 1.280 ± 5%
296 ± 0.1 1.972 1.220 ± 5%
296 ± 0.1 3.039 0.988 ± 5%
296 ± 0.1 3.469 0.870 ± 5%
299 ± 0.1 0.489 1.846 ± 5%
299 ± 0.1 0.995 1.622 ± 5%
299 ± 0.1 1.477 1.420 ± 5%
299 ± 0.1 1.969 1.275 ± 5%
299 ± 0.1 3.031 0.957 ± 5%
305 ± 0.1 0.477 1.980 ± 5%
305 ± 0.1 0.995 1.898 ± 5%
305 ± 0.1 1.477 1.570 ± 5%
305 ± 0.1 1.975 1.530 ± 5%
305 ± 0.1 3.031 1.430 ± 5%
308 ± 0.1 0.477 2.170 ± 5%
308 ± 0.1 1.469 1.770 ± 5%
308 ± 0.1 1.971 1.662 ± 5%
308 ± 0.1 3.031 1.320 ± 5%
Reference
2001K4 Kumar, P.S., Hogendoorn, J.A., Feron, P.H.M., Versteeg, G.F.: J. Chem. Eng. Data 46 (2001)
1357–1361.

Diffusion of nitrous oxide (1); water (2); ethane-1,2-diol (3) 1
Diffusion of nitrous oxide (1); water (2); ethane-1,2-diol (3)

Solution

H 2O (2) water 7732-18-5
C2H6O2 (3) ethane-1,2-diol 107-21-1
T [K] w3 D · 109 [m2/s]
298.15 0.00 1.569 ± 5%
298.15 0.155 1.401 ± 5%
Reference

Diffusion of nitrous oxide (1); water (2); 2-amino-ethanol (3) 1
Diffusion of nitrous oxide (1); water (2); 2-amino-ethanol

(3)
Solution

H 2O (2) water 7732-18-5
T [K] c3 [mol/dm3] D · 109 [m2/s]
303.15 0.5 1.98 ± 2%
303.15 1.0 1.86 ± 2%
303.15 1.5 1.75 ± 2%
303.15 2.0 1.70 ± 2%
303.15 2.5 1.67 ± 2%
303.15 3.0 1.63 ± 2%
303.15 5.0 1.41 ± 2%
308.15 0.5 2.16 ± 2%
308.15 1.0 2.09 ± 2%
308.15 1.5 2.01 ± 2%
308.15 2.0 1.95 ± 2%
308.15 2.5 1.89 ± 2%
308.15 3.0 1.86 ± 2%
308.15 5.0 1.61 ± 2%
313.15 0.5 2.46 ± 2%
313.15 1.0 2.38 ± 2%
313.15 1.5 2.30 ± 2%
313.15 2.0 2.24 ± 2%
313.15 2.5 2.22 ± 2%
313.15 3.0 2.16 ± 2%
313.15 5.0 1.91 ± 2%

H 2O (2) water 7732-18-5
Diffusion of gas(1) in solution: D*1(23); p = 101.325 kPa; Method: OTE Ref.: 1978S1
T [K] c3 [mol/l] D · 109 [m2/s]
298.15 0.0 1.78
298.15 0.731 1.74
298.15 1.364 1.63
298.15 2.023 1.46
298.15 2.766 1.24
298.15 3.361 1.15

2 Diffusion of nitrous oxide (1); water (2); 2-amino-ethanol (3)

H 2O (2) water 7732-18-5
Diffusion of gas(1) in solution: D*1(23); p = 101.325 kPa; Method: LAM Ref.: 1964C2
T [K] c3 [mol/l] D · 109 [m2/s]
298.15 ± 0.02 1.637 1.52
298.15 ± 0.02 3.283 1.39
298.15 ± 0.02 4.877 1.20
References
2001K2 Ko, J.J., Tsai, T.C., Lin, C.Y., Wang, H.M., Li, M.H.: J. Chem. Eng. Data 46 (2001) 160–165.
1978S1 Sada, E., Kumazawa, H., Butt, M.A.: J. Chem. Eng. Data 23 (1978) 161–163.
1964C2 Clarke, J.K.A.: Ind. Eng. Chem. Fundam. 3 (1964) 239–245.

Diffusion of nitrous oxide (1); water (2); ethane-1,2-diamine (3) 1
Diffusion of nitrous oxide (1); water (2); ethane-1,2-

diamine (3)
Solution

H 2O (2) water 7732-18-5
C2H8N2 (3) ethane-1,2-diamine 107-15-3
T [K] c3 [mol/l] D · 109 [m2/s]
298.15 0.618 1.91
298.15 1.373 1.67
298.15 1.821 1.44
298.15 2.350 1.30
298.15 3.369 1.09
Reference

Diffusion of nitrous oxide (1); water (2); propane-1,2,3-triol (3) 1
Diffusion of nitrous oxide (1); water (2); propane-

1,2,3-triol (3)
Solution

H 2O (2) water 7732-18-5
T [K] x3 D · 109 [m2/s]
298.15 0.02 1.29 ± 0.005
298.15 0.04 0.87 ± 0.005

H 2O (2) water 7732-18-5
Diffusion of gas(1) in solution: D*1(23); p = 101.325 kPa; Method: LAM Ref.: 1965T3
T [K] w3 D · 109 [m2/s]
293.15 ± 0.2 0.000 1.92 ± 1%
293.15 ± 0.2 0.040 1.69 ± 1%
293.15 ± 0.2 0.095 1.49 ± 1%
293.15 ± 0.2 0.136 1.37 ± 1%
293.15 ± 0.2 0.160 1.18 ± 1%
293.15 ± 0.2 0.227 0.995 ± 1%
Comment: concentration of (3) assumed as mass fraction w3: authors wrote "% glycerol"
References
1965T3 Thomas, W.J., Adams, M.J.: Trans. Faraday Soc. 61 (1965) 668–673.

Diffusion of nitrous oxide (1); water (2); 1-amino-propan-2-ol (3) 1
Diffusion of nitrous oxide (1); water (2); 1-amino-propan-

2-ol (3)
Solution

H 2O (2) water 7732-18-5
C3H9NO (3) 1-amino-propan-2-ol 78-96-6
T [K] c3 [mol/l] D · 109 [m2/s]
298.15 0.477 1.54
298.15 0.990 1.44
298.15 1.467 1.34
298.15 2.012 1.12
298.15 2.746 1.07
Reference

Diffusion of nitrous oxide (1); water (2); 2-amino-2-methyl-propan-1-ol (3) 1
Diffusion of nitrous oxide (1); water (2); 2-amino-2-methyl-

propan-1-ol (3)
Solution

H 2O (2) water 7732-18-5
Diffusivity of gas(1) in solution: D1eff; p = 101.325 kPa; Method: ABSORB Ref.: 1993S1
T [K] c3 [mol/l] D · 109 [m2/s]
294.0 ± 0.1 0.0 1.59 ± 5%
294.0 ± 0.1 0.5 1.57 ± 5%
294.0 ± 0.1 1.0 1.30 ± 5%
294.0 ± 0.1 1.5 1.09 ± 5%
294.0 ± 0.1 2.0 0.88 ± 5%
301.5 ± 0.1 0.0 1.95 ± 5%
301.5 ± 0.1 0.5 1.83 ± 5%
301.5 ± 0.1 1.0 1.55 ± 5%
301.5 ± 0.1 1.5 1.30 ± 5%
301.5 ± 0.1 2.0 1.10 ± 5%
311.5 ± 0.1 0.0 2.51 ± 5%
311.5 ± 0.1 0.5 2.30 ± 5%
311.5 ± 0.1 1.0 1.98 ± 5%
311.5 ± 0.1 1.5 1.68 ± 5%
311.5 ± 0.1 2.0 1.45 ± 5%
318.0 ± 0.1 0.0 2.93 ± 5%
318.0 ± 0.1 0.5 2.70 ± 5%
318.0 ± 0.1 1.0 2.29 ± 5%
318.0 ± 0.1 1.5 2.01 ± 5%
318.0 ± 0.1 2.0 1.67 ± 5%

H 2O (2) water 7732-18-5
Diffusivity of gas(1) in solution: D1eff; p = 101.325 kPa; Method: ABSORB Ref.: 1991X1
T [K] c3 [mol/dm3] D · 109 [m2/s]
298.35 ± 0.1 2.0 0.81 ± 5%
299.85 ± 0.1 2.0 0.91 ± 5%
301.25 ± 0.1 2.0 0.97 ± 5%
304.55 ± 0.1 2.0 1.02 ± 5%
313.45 ± 0.1 2.0 1.47 ± 5%
323.55 ± 0.1 2.0 2.09 ± 5%
333.85 ± 0.1 2.0 2.82 ± 5%
343.65 ± 0.1 2.0 3.88 ± 5%
347.95 ± 0.1 2.0 4.44 ± 5%
294.55 ± 0.1 3.0 0.59 ± 5%
(continued)

2 Diffusion of nitrous oxide (1); water (2); 2-amino-2-methyl-propan-1-ol (3)
296.55 ± 0.1 3.0 0.62 ± 5%

308.05 ± 0.1 3.0 1.06 ± 5%
318.75 ± 0.1 3.0 1.57 ± 5%
328.15 ± 0.1 3.0 2.27 ± 5%
337.95 ± 0.1 3.0 3.00 ± 5%
348.05 ± 0.1 3.0 4.07 ± 5%
348.65 ± 0.1 3.0 4.17 ± 5%

H 2O (2) water 7732-18-5
T [K] c3 [mol/dm3] D · 109 [m2/s]
303.15 0.5 1.76 ± 2%
303.15 1.0 1.62 ± 2%
303.15 1.5 1.44 ± 2%
303.15 2.0 1.17 ± 2%
303.15 2.5 1.01 ± 2%
308.15 0.5 1.99 ± 2%
308.15 1.0 1.81 ± 2%
308.15 1.5 1.60 ± 2%
308.15 2.0 1.36 ± 2%
308.15 2.5 1.17 ± 2%
313.15 0.5 2.28 ± 2%
313.15 1.0 2.06 ± 2%
313.15 1.5 1.76 ± 2%
313.15 2.0 1.61 ± 2%
313.15 2.5 1.32 ± 2%
References

Diffusion of nitrous oxide (1); water (2); 2-dimethylamino-ethanol (3) 1
Diffusion of nitrous oxide (1); water (2); 2-dimethylamino-

ethanol (3)
Solution

H 2O (2) water 7732-18-5
C4H11NO (3) 2-dimethylamino-ethanol 108-01-0
Diffusion of gas(1) in solution: D*1(23); p = 101.325 kPa; Method: ABSORB Ref.: 1988V2
T [K] c3 [mol/dm3] D · 109 [m2/s]
298 0.324 1.390
298 0.611 1.235
298 0.830 1.256
298 1.218 1.069
298 1.591 0.965
298 1.968 0.835
298 2.049 0.714
298 2.388 0.566
Reference

Diffusion of nitrous oxide (1); water (2); bis-(2-hydroxy-ethyl)-amine (3) 1
Diffusion of nitrous oxide (1); water (2); bis-(2-hydroxy-

ethyl)-amine (3)
Solution

H 2O (2) water 7732-18-5
T [K] c3 [mol/dm3] D · 109 [m2/s]
303.15 0.5 1.64 ± 2%
303.15 1.0 1.41 ± 2%
303.15 1.5 1.20 ± 2%
303.15 2.0 1.12 ± 2%
303.15 2.5 0.91 ± 2%
308.15 0.5 1.94 ± 2%
308.15 1.0 1.67 ± 2%
308.15 1.5 1.46 ± 2%
308.15 2.0 1.30 ± 2%
308.15 2.5 1.05 ± 2%
313.15 0.5 2.25 ± 2%
313.15 1.0 1.98 ± 2%
313.15 1.5 1.79 ± 2%
313.15 2.0 1.53 ± 2%
313.15 2.5 1.21 ± 2%

H 2O (2) water 7732-18-5
T [K] w3 D · 109 [m2/s]
293.15 0.10 1.23 ± 0.024
298.15 0.10 1.31 ± 0.003
303.15 0.10 1.51 ± 0.004
313.15 0.10 1.71 ± 0.014
333.15 0.10 2.91 ± 0.005
353.15 0.10 3.95 ± 0.034
368.15 0.10 4.23 ± 0.099
293.15 0.20 0.957 ± 0.005
298.15 0.20 0.984 ± 0.109
303.15 0.20 1.186 ± 0.009
313.15 0.20 1.57 ± 0.022
333.15 0.20 2.40 ± 0.041
353.15 0.20 3.48 ± 0.168
368.15 0.20 3.73 ± 0.183
293.15 0.30 0.569 ± 0.003
(continued)

2 Diffusion of nitrous oxide (1); water (2); bis-(2-hydroxy-ethyl)-amine (3)
298.15 0.30 0.693 ± 0.005

303.15 0.30 0.780 ± 0.006
313.15 0.30 1.17 ± 0.008
333.15 0.30 1.88 ± 0.025
353.15 0.30 2.88 ± 0.051
368.15 0.30 3.44 ± 0.197

H 2O (2) water 7732-18-5
Diffusion of gas(1) in solution: D*1(23); p = 101.325 kPa; Method: LAM Ref.: 1976S14
T [K] c3 [mol/l] D · 109 [m2/s]
298.15 0.498 1.66
298.15 0.981 1.56
298.15 1.922 1.40
298.15 2.808 1.26
298.15 3.457 1.04

H 2O (2) water 7732-18-5
T [K] c3 [mol/l] D · 109 [m2/s]
298.15 0.498 1.66
298.15 0.981 1.56
298.15 1.922 1.40
298.15 2.808 1.26
298.15 3.457 1.04
References
1976S14 Sada, E., Kumazawa, H., Butt, M.A.: Can. J. Chem. Eng. 54 (1976) 421–424.

Diffusion of nitrous oxide (1); water (2); pentane-1,5-diol (3) 1
Diffusion of nitrous oxide (1); water (2); pentane-1,5-diol

(3)
Solution

H 2O (2) water 7732-18-5
C5H12O2 (3) pentane-1,5-diol 111-29-5
T [K] x3 D · 109 [m2/s]
298.15 0.02 1.20 ± 0.005
298.15 0.04 1.02 ± 0.005
Reference

Diffusion of nitrous oxide (1); water (2); bis-(2-hydroxy-ethyl)-methyl-amine (3) 1

ethyl)-methyl-amine (3)
Solution

H 2O (2) water 7732-18-5
T [K] c3 [mol/dm3] D · 109 [m2/s]
303.15 0.00 2.04 ± 2%
303.15 0.5 1.85 ± 2%
303.15 1.0 1.58 ± 2%
303.15 1.5 1.32 ± 2%
303.15 2.0 1.06 ± 2%
303.15 2.5 0.94 ± 2%
308.15 0.00 2.29 ± 2%
308.15 0.5 2.11 ± 2%
308.15 1.0 1.76 ± 2%
308.15 1.5 1.49 ± 2%
308.15 2.0 1.26 ± 2%
308.15 2.5 1.04 ± 2%
313.15 0.00 2.66 ± 2%
313.15 0.5 2.24 ± 2%
313.15 1.0 2.01 ± 2%
313.15 1.5 1.69 ± 2%
313.15 2.0 1.41 ± 2%
313.15 2.5 1.26 ± 2%

H 2O (2) water 7732-18-5
T [K] w3 D · 109 [m2/s]
293.15 0.00 1.399 ± 5%
293.15 0.1527 1.104 ± 5%
293.15 0.2012 1.011 ± 5%
293.15 0.3021 0.816 ± 5%
298.15 0.00 1.493 ± 5%
298.15 0.1527 1.233 ± 5%
298.15 0.2021 1.142 ± 5%
298.15 0.3021 0.943 ± 5%
303.15 0.00 1.579 ± 5%
303.15 0.1527 1.350 ± 5%
303.15 0.2021 1.263 ± 5%
303.15 0.3021 1.061 ± 5%
(continued)

2 Diffusion of nitrous oxide (1); water (2); bis-(2-hydroxy-ethyl)-methyl-amine (3)
308.15 0.00 1.656 ± 5%

308.15 0.1527 1.456 ± 5%
308.15 0.2021 1.373 ± 5%
308.15 0.3021 1.172 ± 5%
313.15 0.00 1.725 ± 5%
313.15 0.1527 1.550 ± 5%
313.15 0.2021 1.472 ± 5%
313.15 0.3021 1.275 ± 5%

H 2O (2) water 7732-18-5
T [K] w3 D · 109 [m2/s]
293.15 0.10 1.36 ± 0.017
298.15 0.10 1.41 ± 0.007
303.15 0.10 1.60 ± 0.002
313.15 0.10 1.93 ± 0.012
333.15 0.10 3.20 ± 0.007
353.15 0.10 4.13 ± 0.005
368.15 0.10 4.86 ± 0.181
293.15 0.20 1.06 ± 0.005
298.15 0.20 1.11 ± 0.006
303.15 0.20 1.25 ± 0.021
313.15 0.20 1.67 ± 0.010
333.15 0.20 2.71 ± 0.005
353.15 0.20 3.93 ± 0.004
368.15 0.20 4.29 ± 0.020
293.15 0.30 0.611 ± 0.002
298.15 0.30 0.721 ± 0.002
303.15 0.30 0.807 ± 0.006
313.15 0.30 1.27 ± 0.008
333.15 0.30 2.02 ± 0.088
353.15 0.30 3.02 ± 0.254
368.15 0.30 3.71 ± 0.017
293.15 0.40 0.261 ± 0.003
298.15 0.40 0.377 ± 0.003
303.15 0.40 0.487 ± 0.03
313.15 0.40 0.803 ± 0.005
333.15 0.40 1.77 ± 0.013
353.15 0.40 2.58 ± 0.027
368.15 0.40 2.97 ± 0.035
293.15 0.50 0.117 ± 0.008
298.15 0.50 0.189 ± 0.001
303.15 0.50 0.228 ± 0.004
313.15 0.50 0.411 ± 0.004
333.15 0.50 0.971 ± 0.002
(continued)

353.15 0.50 1.230 ± 0.068

368.15 0.50 1.561 ± 0.049

H 2O (2) water 7732-18-5
T [K] w3 D · 109 [m2/s]
288.15 ± 0.30 0.10 1.047
293.15 ± 0.30 0.10 1.158
298.15 ± 0.30 0.10 1.325
303.15 ± 0.30 0.10 1.432
308.15 ± 0.30 0.10 1.479
313.15 ± 0.30 0.10 1.611
323.15 ± 0.30 0.10 1.764
288.15 ± 0.30 0.20 0.841
293.15 ± 0.30 0.20 0.991
298.15 ± 0.30 0.20 1.148
303.15 ± 0.30 0.20 1.290
308.15 ± 0.30 0.20 1.412
313.15 ± 0.30 0.20 1.499
323.15 ± 0.30 0.20 1.670
288.15 ± 0.30 0.30 0.712
293.15 ± 0.30 0.30 0.823
298.15 ± 0.30 0.30 0.973
303.15 ± 0.30 0.30 1.032
308.15 ± 0.30 0.30 1.162
313.15 ± 0.30 0.30 1.240
318.15 ± 0.30 0.30 1.303
323.15 ± 0.30 0.30 1.421
288.15 ± 0.30 0.40 0.589
293.15 ± 0.30 0.40 0.639
298.15 ± 0.30 0.40 0.751
303.15 ± 0.30 0.40 0.824
308.15 ± 0.30 0.40 0.993
313.15 ± 0.30 0.40 1.108
318.15 ± 0.30 0.40 1.174
323.15 ± 0.30 0.40 1.269
288.15 ± 0.30 0.50 0.329
293.15 ± 0.30 0.50 0.430
298.15 ± 0.30 0.50 0.506
303.15 ± 0.30 0.50 0.561
308.15 ± 0.30 0.50 0.635
313.15 ± 0.30 0.50 0.752
318.15 ± 0.30 0.50 0.843
323.15 ± 0.30 0.50 0.933

4 Diffusion of nitrous oxide (1); water (2); bis-(2-hydroxy-ethyl)-methyl-amine (3)

H 2O (2) water 7732-18-5
T [K] c3 [mol/dm3] D · 109 [m2/s]
293 0.348 1.46
293 0.415 1.32
293 0.716 1.22
293 0.793 1.16
293 1.102 1.26
293 1.386 0.81
298 0.237 1.88
298 0.407 1.32
298 0.511 1.44
298 0.706 1.36
298 0.966 1.32
298 1.056 1.32
298 1.060 1.25
298 1.177 1.16
298 1.440 1.02
298 1.591 1.06
298 1.925 1.64
298 2.056 0.95
298 2.196 0.77
308 0.625 1.98
308 0.817 1.87
308 1.251 1.64
308 1.320 1.64
308 1.457 1.54
308 1.675 1.43
308 1.781 1.38
308 1.849 1.31
318 0.488 2.46
318 0.946 2.18
318 1.493 2.06
318 1.985 1.68
318 2.589 1.47
318 2.865 1.10
333 0.764 3.34
333 1.287 3.13
333 2.068 2.37
333 2.593 2.09


H 2O (2) water 7732-18-5
Diffusivity of gas(1) in solution: D1eff; p = 101.325 kPa; Method: LAM Ref.: 1984H1
T [K] w3 D · 109 [m2/s]
288.15 ± 0.1 0.000 1.39 ± 5%
288.15 ± 0.1 0.100 1.21 ± 5%
288.15 ± 0.1 0.150 1.04 ± 5%
288.15 ± 0.1 0.200 0.898 ± 5%
293.15 ± 0.1 0.000 1.52 ± 5%
293.15 ± 0.1 0.100 1.24 ± 5%
293.15 ± 0.1 0.150 1.18 ± 5%
293.15 ± 0.1 0.200 1.01 ± 5%
298.15 ± 0.1 0.000 1.86 ± 5%
298.15 ± 0.1 0.100 1.46 ± 5%
298.15 ± 0.1 0.150 1.37 ± 5%
298.15 ± 0.1 0.200 1.16 ± 5%
308.15 ± 0.1 0.000 2.03 ± 5%
308.15 ± 0.1 0.100 1.74 ± 5%
308.15 ± 0.1 0.150 1.57 ± 5%
308.15 ± 0.1 0.200 1.30 ± 5%

H 2O (2) water 7732-18-5
T [K] w3 D · 109 [m2/s]
298.15 0.20 0.934
322.75 0.20 1.87
347.85 0.20 2.82
298.15 0.40 0.629
322.75 0.40 1.40
347.95 0.40 2.28
References
2000K2 Ko, J.J., Li, M.H.: Chem. Eng. Sci. 55 (2000) 4139–4147.
(1989) 385–391.
1984H1 Haimour, N., Sandall, O.C.: Chem. Eng. Sci. 39 (1984) 1791–1796.
1989T2 Tomcej, R.A., Otto, F.D.: AIChE J. 35 (1989) 861–864.

Diffusion of nitrous oxide (1); water (2); bis-(2-hydroxy-propyl)-amine (3) 1

propyl)-amine (3)
Solution

H 2O (2) water 7732-18-5
T [K] c3 [mol/dm3] D · 109 [m2/s]
303.15 0.5 1.74 ± 2%
303.15 1.0 1.42 ± 2%
303.15 1.5 1.22 ± 2%
303.15 2.0 0.97 ± 2%
303.15 2.5 0.75 ± 2%
308.15 0.5 2.15 ± 2%
308.15 1.0 1.70 ± 2%
308.15 1.5 1.53 ± 2%
308.15 2.0 1.18 ± 2%
308.15 2.5 0.89 ± 2%
313.15 0.5 2.44 ± 2%
313.15 1.0 1.93 ± 2%
313.15 1.5 1.63 ± 2%
313.15 2.0 1.27 ± 2%
313.15 2.5 0.97 ± 2%

H 2O (2) water 7732-18-5
T [K] c3 [mol/dm3] D · 109 [m2/s]
293 0.330 1.350
293 0.505 1.450
293 0.751 1.184
293 1.194 0.785
293 1.466 0.655
293 1.725 0.538
293 2.222 0.331

H 2O (2) water 7732-18-5
T [K] c3 [mol/l] D · 109 [m2/s]
298.15 0.396 1.54
(continued)

2 Diffusion of nitrous oxide (1); water (2); bis-(2-hydroxy-propyl)-amine (3)
298.15 0.830 1.41

298.15 1.107 1.20
298.15 1.410 0.90
298.15 1.663 0.77
References

Diffusion of nitrous oxide (1); water (2); tris-(2-hydroxy-ethyl)-amine (3) 1
Diffusion of nitrous oxide (1); water (2); tris-(2-hydroxy-

ethyl)-amine (3)
Solution

H 2O (2) water 7732-18-5
T [K] c3 [mol/dm3] D · 109 [m2/s]
303.15 0.5 1.89 ± 2%
303.15 1.0 1.69 ± 2%
303.15 1.5 1.57 ± 2%
303.15 2.0 1.30 ± 2%
303.15 2.5 1.04 ± 2%
308.15 0.5 2.20 ± 2%
308.15 1.0 1.80 ± 2%
308.15 1.5 1.76 ± 2%
308.15 2.0 1.42 ± 2%
308.15 2.5 1.12 ± 2%
313.15 0.5 2.35 ± 2%
313.15 1.0 2.15 ± 2%
313.15 1.5 1.84 ± 2%
313.15 2.0 1.65 ± 2%
313.15 2.5 1.35 ± 2%

H 2O (2) water 7732-18-5
T [K] c3 [mol/l] D · 109 [m2/s]
298.15 0.497 1.70
298.15 1.048 1.44
298.15 1.596 1.23
298.15 1.921 0.908

H 2O (2) water 7732-18-5
T [K] c3 [mol/l] D · 109 [m2/s]
298.15 0.497 1.70
298.15 1.048 1.44
298.15 1.596 1.23
298.15 1.921 0.91

2 Diffusion of nitrous oxide (1); water (2); tris-(2-hydroxy-ethyl)-amine (3)
References
1976S14 Sada, E., Kumazawa, H., Butt, M.A.: Can. J. Chem. Eng. 54 (1976) 421–424.

1

(3); 2-amino-2-methyl-propan-1-ol (4)
Solution

H 2O (2) water 7732-18-5
eff
T [K] w3 w4 D · 109 [m2/s]
303.15 0.30 0.0 1.559
303.15 0.24 0.06 1.509
303.15 0.18 0.12 1.420
303.15 0.12 0.18 1.324
303.15 0.06 0.24 1.214
303.15 0.0 0.30 1.047
308.15 0.30 0.0 1.731
308.15 0.24 0.06 1.628
308.15 0.18 0.12 1.567
308.15 0.12 0.18 1.458
308.15 0.06 0.24 1.353
308.15 0.0 0.30 1.157
313.15 0.30 0.0 1.879
313.15 0.24 0.06 1.804
313.15 0.18 0.12 1.726
313.15 0.12 0.18 1.599
313.15 0.06 0.24 1.490
313.15 0.0 0.30 1.303
Comment: mass fraction wi, estimated error ±2%
Reference

1

(3); bis-(2-hydroxy-ethyl)-methyl-amine (4)
Solution

H 2O (2) water 7732-18-5
T [K] w3 w4 D · 109 [m2/s]
303.15 0.30 0.0 1.559
303.15 0.24 0.06 1.491
303.15 0.18 0.12 1.396
303.15 0.12 0.18 1.336
303.15 0.06 0.24 1.244
303.15 0.0 0.30 1.084
308.15 0.30 0.0 1.731
308.15 0.24 0.06 1.665
308.15 0.18 0.12 1.546
308.15 0.12 0.18 1.464
308.15 0.06 0.24 1.351
308.15 0.0 0.30 1.180
313.15 0.30 0.0 1.879
313.15 0.24 0.06 1.807
313.15 0.18 0.12 1.676
313.15 0.12 0.18 1.572
313.15 0.06 0.24 1.465
313.15 0.0 0.30 1.285
Comment: mass fraction wi, estimated error ±2%
Reference

1

(3); tris-(2-hydroxy-ethyl)-amine (4)
Solution

H 2O (2) water 7732-18-5
Diffusion of gas(1) in solution: D*1(23); p = 101.325 kPa; Method: ABSORB Ref.: 2002H1
T [K] c3 c4 D · 109 [m2/s]
303.15 0.1 0.5 1.78 ± 2%
303.15 0.2 0.5 1.69 ± 2%
303.15 0.3 0.5 1.63 ± 2%
303.15 0.4 0.5 1.59 ± 2%
303.15 0.5 0.5 1.54 ± 2%
303.15 0.1 1.0 1.55 ± 2%
303.15 0.2 1.0 1.45 ± 2%
303.15 0.3 1.0 1.34 ± 2%
303.15 0.4 1.0 1.23 ± 2%
303.15 0.5 1.0 1.09 ± 2%
308.15 0.1 0.5 2.07 ± 2%
308.15 0.2 0.5 1.97 ± 2%
308.15 0.3 0.5 1.83 ± 2%
308.15 0.4 0.5 1.75 ± 2%
308.15 0.5 0.5 1.70 ± 2%
308.15 0.1 1.0 1.69 ± 2%
308.15 0.2 1.0 1.61 ± 2%
308.15 0.3 1.0 1.50 ± 2%
308.15 0.4 1.0 1.40 ± 2%
308.15 0.5 1.0 1.24 ± 2%
313.15 0.1 0.5 2.25 ± 2%
313.15 0.2 0.5 2.15 ± 2%
313.15 0.3 0.5 2.11 ± 2%
313.15 0.4 0.5 2.03 ± 2%
313.15 0.5 0.5 2.00 ± 2%
313.15 0.1 1.0 2.01 ± 2%
313.15 0.2 1.0 1.86 ± 2%
313.15 0.3 1.0 1.76 ± 2%
313.15 0.4 1.0 1.52 ± 2%
313.15 0.5 1.0 1.49 ± 2%
Reference
2002H1 Horng, S.Y., Li, M.H.: Ind. Eng. Chem. Res. 41 (2002) 257–266.

1
Diffusion of nitrous oxide (1); water (2); 2-amino-2-methyl-

propan-1-ol (3); bis-(2-hydroxy-ethyl)-amine (4)
Solution

H 2O (2) water 7732-18-5
T [K] w3 w4 D · 109 [m2/s]
293 ± 0.2 0.30 0.00 0.71 ± 2%
293 ± 0.2 0.285 0.015 0.72 ± 2%
293 ± 0.2 0.27 0.03 0.74 ± 2%
293 ± 0.2 0.255 0.045 0.77 ± 2%
293 ± 0.2 0.24 0.06 0.79 ± 2%
293 ± 0.2 0.225 0.075 0.80 ± 2%
293 ± 0.2 0.21 0.09 0.84 ± 2%
293 ± 0.2 0.00 0.30 1.04 ± 2%
298 ± 0.2 0.30 0.00 0.83 ± 2%
298 ± 0.2 0.285 0.015 0.84 ± 2%
298 ± 0.2 0.27 0.03 0.85 ± 2%
298 ± 0.2 0.255 0.045 0.87 ± 2%
298 ± 0.2 0.24 0.06 0.88 ± 2%
298 ± 0.2 0.225 0.075 0.91 ± 2%
298 ± 0.2 0.21 0.09 0.93 ± 2%
298 ± 0.2 0.00 0.30 1.12 ± 2%
303 ± 0.2 0.30 0.00 1.01 ± 2%
303 ± 0.2 0.285 0.015 1.02 ± 2%
303 ± 0.2 0.27 0.03 1.04 ± 2%
303 ± 0.2 0.255 0.045 1.05 ± 2%
303 ± 0.2 0.24 0.06 1.07 ± 2%
303 ± 0.2 0.225 0.075 1.08 ± 2%
303 ± 0.2 0.21 0.09 1.12 ± 2%
303 ± 0.2 0.00 0.30 1.25 ± 2%
308 ± 0.2 0.30 0.00 1.19 ± 2%
308 ± 0.2 0.285 0.015 1.20 ± 2%
308 ± 0.2 0.27 0.03 1.23 ± 2%
308 ± 0.2 0.255 0.045 1.24 ± 2%
308 ± 0.2 0.24 0.06 1.26 ± 2%
308 ± 0.2 0.225 0.075 1.27 ± 2%
308 ± 0.2 0.21 0.09 1.28 ± 2%
308 ± 0.2 0.00 0.30 1.38 ± 2%
313 ± 0.2 0.30 0.00 1.32 ± 2%
313 ± 0.2 0.285 0.015 1.33 ± 2%
313 ± 0.2 0.27 0.03 1.34 ± 2%
313 ± 0.2 0.255 0.045 1.36 ± 2%
(continued)

2
313 ± 0.2 0.24 0.06 1.38 ± 2%

313 ± 0.2 0.225 0.075 1.39 ± 2%
313 ± 0.2 0.21 0.09 1.42 ± 2%
313 ± 0.2 0.00 0.30 1.57 ± 2%

H 2O (2) water 7732-18-5
T [K] c3 c4 D · 109 [m2/s]
303.15 1.0 0.1 1.44 ± 2%
303.15 1.0 0.2 1.28 ± 2%
303.15 1.0 0.3 1.18 ± 2%
303.15 1.0 0.4 1.08 ± 2%
303.15 1.5 0.1 1.25 ± 2%
303.15 1.5 0.2 1.04 ± 2%
303.15 1.5 0.3 0.90 ± 2%
303.15 1.5 0.4 0.78 ± 2%
308.15 1.0 0.1 1.65 ± 2%
308.15 1.0 0.2 1.49 ± 2%
308.15 1.0 0.3 1.33 ± 2%
308.15 1.0 0.4 1.20 ± 2%
308.15 1.5 0.1 1.41 ± 2%
308.15 1.5 0.2 1.20 ± 2%
308.15 1.5 0.3 1.08 ± 2%
308.15 1.5 0.4 0.93 ± 2%
313.15 1.0 0.1 1.91 ± 2%
313.15 1.0 0.2 1.69 ± 2%
313.15 1.0 0.3 1.51 ± 2%
313.15 1.0 0.4 1.41 ± 2%
313.15 1.5 0.1 1.55 ± 2%
313.15 1.5 0.2 1.39 ± 2%
313.15 1.5 0.3 1.19 ± 2%
313.15 1.5 0.4 1.07 ± 2%
References
264–270.
2004W1 Wang, H.M., Li, M.H.: J. Chem. Eng. Jpn. 37 (2004) 267–278.

1

ethyl)-amine (3); 2-amino-2-methyl-propan-1-ol (4)
Solution

H 2O (2) water 7732-18-5
eff
T [K] w3 w4 D · 109 [m2/s]
303.15 0.24 0.06 1.149
303.15 0.18 0.12 1.120
303.15 0.12 0.18 1.106
303.15 0.06 0.24 1.080
308.15 0.24 0.06 1.298
308.15 0.18 0.12 1.270
308.15 0.12 0.18 1.235
308.15 0.06 0.24 1.201
313.15 0.24 0.06 1.462
313.15 0.18 0.12 1.431
313.15 0.12 0.18 1.393
313.15 0.06 0.24 1.354
Comment: mass fraction wi, reproducibility ±3%
Reference

1

ethyl)-amine (3); bis-(2-hydroxy-ethyl)-methyl-amine (4)
Solution

H 2O (2) water 7732-18-5
eff
T [K] w3 w4 D · 109 [m2/s]
303.15 0.30 0.0 1.162
303.15 0.24 0.06 1.151
303.15 0.18 0.12 1.140
303.15 0.12 0.18 1.123
303.15 0.06 0.24 1.109
308.15 0.30 0.0 1.320
308.15 0.24 0.06 1.300
308.15 0.18 0.12 1.273
308.15 0.12 0.18 1.247
308.15 0.06 0.24 1.221
313.15 0.30 0.0 1.501
313.15 0.24 0.06 1.454
313.15 0.18 0.12 1.412
313.15 0.12 0.18 1.382
313.15 0.06 0.24 1.344
Comment: mass fraction wi, reproducibility ±3%

H 2O (2) water 7732-18-5
eff
Diffusivity of gas(1) in solution: D1 ; p = 101.325 kPa; Method: ABSORB Ref.: 1995R1
T [K] w3/ w4 D · 109 [m2/s]
293.15 ± 0.1 0.0441 0.280 ± 0.021
313.15 ± 0.1 0.0441 0.420 ± 0.014
333.15 ± 0.1 0.0441 0.820 ± 0.028
353.15 ± 0.1 0.0441 1.30 ± 0.034
293.15 ± 0.1 0.2206 0.282 ± 0.012
313.15 ± 0.1 0.2206 0.418 ± 0.017
333.15 ± 0.1 0.2206 0.916 ± 0.031
353.15 ± 0.1 0.2206 1.10 ± 0.026
293.15 ± 0.1 0.4413 0.300 ± 0.013
313.15 ± 0.1 0.4413 0.470 ± 0.006
333.15 ± 0.1 0.4413 0.770 ± 0.019
353.15 ± 0.1 0.4413 1.06 ± 0.041
(continued)

2
293.15 ± 0.1 0.5883 0.244 ± 0.010

313.15 ± 0.1 0.5883 0.446 ± 0.016
333.15 ± 0.1 0.5883 0.965 ± 0.018
353.15 ± 0.1 0.5883 1.03 ± 0.023
Comment: realistic max. exp. error approx. ±10%, w3/w4 mass ratio
References
1995R1 Rinker, E.B., Russell, J.W., Tamimi, A., Sandall, O.C.: J. Chem. Eng. Data 40 (1995) 630–631.

1

ethyl)-methyl-amine (3); 2-amino-ethanol (4)
Solution

H 2O (2) water 7732-18-5
eff
Diffusivity of gas(1) in solution: D1 ; p = 101.325 kPa; Method: ABSORB Ref.: 1995H1
T [K] w3 w4 D · 109 [m2/s]
303 0.30 0.0 1.032
303 0.285 0.015 1.136
303 0.27 0.03 1.267
303 0.255 0.045 1.393
303 0.40 0.0 0.824
303 0.38 0.02 0.844
303 0.36 0.04 0.905
303 0.34 0.06 0.973
313 0.30 0.0 1.240
313 0.285 0.015 1.265
313 0.27 0.03 1.345
313 0.255 0.045 1.450
313 0.40 0.0 1.108
313 0.38 0.02 1.159
313 0.36 0.04 1.207
313 0.34 0.06 1.288
323 0.30 0.0 1.421
323 0.285 0.015 1.488
323 0.27 0.03 1.564
323 0.255 0.045 1.656
323 0.40 0.0 1.269
323 0.38 0.02 1.305
323 0.36 0.04 1.391
323 0.34 0.06 1.471
Reference
1995H1 Hagewiesche, D.P., Ashour, S.S., Sandall, O.C.: J. Chem. Eng. Data 40 (1995) 627–629.

1

ethyl)-methyl-amine (3); bis-(2-hydroxy-ethyl)-amine (4)
Solution

H 2O (2) water 7732-18-5
T [K] w3 w4 D · 109 [m2/s]
293 ± 0.2 0.30 0.00 0.84 ± 2%
293 ± 0.2 0.285 0.015 0.94 ± 2%
293 ± 0.2 0.27 0.03 0.95 ± 2%
293 ± 0.2 0.255 0.045 0.96 ± 2%
293 ± 0.2 0.24 0.06 0.96 ± 2%
293 ± 0.2 0.225 0.075 0.97 ± 2%
293 ± 0.2 0.21 0.09 0.98 ± 2%
293 ± 0.2 0.00 0.30 1.04 ± 2%
298 ± 0.2 0.30 0.00 0.93 ± 2%
298 ± 0.2 0.285 0.015 1.04 ± 2%
298 ± 0.2 0.27 0.03 1.04 ± 2%
298 ± 0.2 0.255 0.045 1.05 ± 2%
298 ± 0.2 0.24 0.06 1.06 ± 2%
298 ± 0.2 0.225 0.075 1.07 ± 2%
298 ± 0.2 0.21 0.09 1.08 ± 2%
298 ± 0.2 0.00 0.30 1.12 ± 2%
303 ± 0.2 0.30 0.00 1.10 ± 2%
303 ± 0.2 0.285 0.015 1.12 ± 2%
303 ± 0.2 0.27 0.03 1.13 ± 2%
303 ± 0.2 0.255 0.045 1.15 ± 2%
303 ± 0.2 0.24 0.06 1.17 ± 2%
303 ± 0.2 0.225 0.075 1.17 ± 2%
303 ± 0.2 0.21 0.09 1.19 ± 2%
303 ± 0.2 0.00 0.30 1.25 ± 2%
308 ± 0.2 0.30 0.00 1.16 ± 2%
308 ± 0.2 0.285 0.015 1.15 ± 2%
308 ± 0.2 0.27 0.03 1.17 ± 2%
308 ± 0.2 0.255 0.045 1.19 ± 2%
308 ± 0.2 0.24 0.06 1.22 ± 2%
308 ± 0.2 0.225 0.075 1.25 ± 2%
308 ± 0.2 0.21 0.09 1.27 ± 2%
308 ± 0.2 0.00 0.30 1.38 ± 2%
313 ± 0.2 0.30 0.00 1.21 ± 2%
313 ± 0.2 0.285 0.015 1.24 ± 2%
313 ± 0.2 0.27 0.03 1.27 ± 2%
313 ± 0.2 0.255 0.045 1.32 ± 2%
(continued)

2
313 ± 0.2 0.24 0.06 1.37 ± 2%

313 ± 0.2 0.225 0.075 1.39 ± 2%
313 ± 0.2 0.21 0.09 1.44 ± 2%
313 ± 0.2 0.00 0.30 1.57 ± 2%
Reference
264–270.

Diffusion of oxygen (1); benzene (2); cyclohexane (3) 1
Diffusion of oxygen (1); benzene (2); cyclohexane (3)

Solution
O2 (1) oxygen 7782-44-7

C6H6 (2) benzene 71-43-2
Diffusion of gas(1) in solution: D*1(23); p = 101.325 kPa; Method: EA DME Ref.: 1990S2
T [K] x3 D · 109 [m2/s]
293.2 ± 0.1 0.069 3.61
Reference

Diffusion of oxygen (1); toluene (2); ethanol (3) 1
Diffusion of oxygen (1); toluene (2); ethanol (3)

Solution
O2 (1) oxygen 7782-44-7

C7H8 (2) toluene 108-88-3
Diffusion of gas(1) in solution: D*1(23); p = 101.325 kPa; Method: EA DME Ref.: 1990S2
T [K] x1 D · 109 [m2/s]
293.2 ± 0.1 0.050 5.00
293.2 ± 0.1 0.136 5.13
293.2 ± 0.1 0.280 4.57
293.2 ± 0.1 0.550 4.30
293.2 ± 0.1 0.735 4.00
Reference

Diffusion of oxygen (1); water (2); methanol (3) 1
Diffusion of oxygen (1); water (2); methanol (3)

Solution
O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
T [K] x3 D · 109 [m2/s]
293.15 0.00 1.80
293.15 0.052 0.69
293.15 0.139 0.78
293.15 0.302 0.97
293.15 0.486 1.24
293.15 1.00 1.88
Reference

Diffusion of oxygen (1); water (2); ethanol (3) 1
Diffusion of oxygen (1); water (2); ethanol (3)

Solution
O2 (1) oxygen 7782-44-7

H 2O (2) water 7732-18-5
C2H6O (3)

(Landolt-Börnstein - Group IV Physical Chemistry 15A - Physical Chemistry) J. Winkelmann (Auth.), M.D. Lechner (Eds.) - Gases in Gases, Liquids and Their Mixtures-Springer-Verlag Berlin Heidelberg (20

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(Landolt-Börnstein - Group IV Physical Chemistry 15A - Physical Chemistry) J. Winkelmann (Auth.), M.D. Lechner (Eds.) - Gases in Gases, Liquids and Their Mixtures-Springer-Verlag Berlin Heidelberg (20

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Landolt-Börnstein / New Series

Numerical Data and Functional Relationships

Units and Fundamental Constants in Physics and Chemistry

Elementary Particles, Nuclei and Atoms (Group I)

Molecules and Radicals (Group II)

Condensed Matter (Group III)

Physical Chemistry (Group IV)

Astronomy and Astrophysics (Group VI)

Biophysics (Group VII)

Advanced Materials and Technologies (Group VIII)

Group IV: Physical Chemistry

Subvolume A: Gases in Gases, Liquids and their Mixtures

ISBN 978-3-540-62429-5 Springer Berlin Heidelberg New York

Library of Congress Cataloging in Publication Data

Springer is a part of Springer Science+Business Media

Cover layout: Erich Kirchner, Heidelberg

SPIN: 10559718 63/3020 - 5 4 3 2 1 0 – Printed on acid-free paper

Osnabrück, February 2007 The Editor

Landolt-Börnstein: Editorial Office

LB IV/15: Diffusion in Gases, Liquids and Electrolytes

3 Diffusion in pure gases

4 Diffusion in gaseous mixtures

5 Diffusion of gas/vapor in gas or liquid

6 Diffusion of gas in solution

1.1 Selection of data

Landolt-Börnstein DOI: 10.1007/978-3-540-49718-9_1

1.2 Definitions and units

DOI: 10.1007/978-3-540-49718-9_1 Landolt-Börnstein

Self-diffusion coefficient D1s

Interdiffusion coefficients Dij

which can be written in matrix form as

Landolt-Börnstein DOI: 10.1007/978-3-540-49718-9_1

Intradiffusion coefficients DiT and diffusion coefficients at infinite dilution D0i(j)

Fig. 1. Diffusion coefﬁcients in the

DOI: 10.1007/978-3-540-49718-9_1 Landolt-Börnstein

Integral diffusion coefficients

1.2.2 Temperature, pressure and density, concentration

Mole fraction xi, volume fraction φi and mass fraction wi

Molarity ci and molality mi

1.3 Arrangement of data

Landolt-Börnstein DOI: 10.1007/978-3-540-49718-9_1

1.4 Substances and nomenclature

1.5 Data reduction and correlations

DOI: 10.1007/978-3-540-49718-9_1 Landolt-Börnstein

Landolt-Börnstein DOI: 10.1007/978-3-540-49718-9_1

DOI: 10.1007/978-3-540-49718-9_1 Landolt-Börnstein

Landolt-Börnstein DOI: 10.1007/978-3-540-49718-9_2

2.1 NMR spin echo techniques

DOI: 10.1007/978-3-540-49718-9_2 Landolt-Börnstein

2.2 Optical methods

2.2.2 Holographic interferometry

Landolt-Börnstein DOI: 10.1007/978-3-540-49718-9_2

2.2.3 Light scattering

2.3 Capillary diffusion methods

DOI: 10.1007/978-3-540-49718-9_2 Landolt-Börnstein

where the An depend on the initial conditions.

2.3.2 Two-bulb method

2.3.3 Evaporation tube (Stefan cell)

Landolt-Börnstein DOI: 10.1007/978-3-540-49718-9_2

2.3.4 Open ended capillary

2.4 Chromatographic methods

A general solution has the form [1992D1]

DOI: 10.1007/978-3-540-49718-9_2 Landolt-Börnstein

DN2 O ¼ 2:35 106 exp½2119=ðT ½KÞ m2 s1 ; ð30Þ