1

Section A

Answer all the questions in this section in the spaces provided.

The total mark for this section is 45.

A1.The electronic configurations of five atoms are shown.

(a) Which electronic configuration represents each of the following descriptions?

Each electronic configuration may be used once, more than once or not at all.

(i) a sodium atom

....................................................................................................................................... [1]

(ii) an atom of a reactive non-metallic element

....................................................................................................................................... [1]

(iii) an atom with a proton (atomic) number of 12

....................................................................................................................................... [1]

(iv) an atom of a noble gas which is used to fill balloons

....................................................................................................................................... [1]

(v) an atom which forms a noble gas electronic configuration when it gains two electrons

....................................................................................................................................... [1]
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(b) Chlorine has two naturally occurring isotopes.

One isotope of chlorine is represented by the symbol shown.

37
17Cl

(i) Deduce the number of neutrons in one atom of this isotope of chlorine.

....................................................................................................................................... [1]

(ii) Chlorine has diatomic molecules.

What is the meaning of the term diatomic?

....................................................................................................................................... [1]
[Total: 7]

A2. Farmers add fertilizers such as ammonium sulfate to the soil to increase the rate of plant growth.

(a) Write the formulae of the ions present in ammonium sulfate.

................................................................... and ................................................................... [2]

(b) Describe a test for ammonium ions.

Test ............................................................................................................................................

observation ............................................................................................................................... [2]

(c) When ammonia dissolves in water, ammonium ions and hydroxide ions are formed.

Write the ionic equation for the reaction of aqueous ammonia with sulfuric acid.

............................................................................................................................................... [1]

[Total: 5]
 4

A3.Magnesium reacts with aqueous copper(II) sulfate.

Mg(s) + CuSO4(aq) MgSO4(aq) + Cu(s)

(a) (i) Explain by referring to the equation, why this is a redox reaction.

...........................................................................................................................................

....................................................................................................................................... [2]

(ii) Construct the ionic equation for this reaction.

....................................................................................................................................... [1]

(b) Pure copper can be made by the electrolysis of aqueous copper(II) sulfate, using one pure

copper electrode and one impure copper electrode.

Draw a labelled diagram of this electrolysis.

[3]

(c) What observations are made when adding aqueous ammonia to a solution containing

copper(II) ions, slowly with mixing, until no further change occurs?

...................................................................................................................................................

...................................................................................................................................................

............................................................................................................................................... [2]
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(d) Blocks of magnesium are attached to underground pipes made of iron to stop them rusting.

Explain how the magnesium stops the pipes rusting.

...................................................................................................................................................

...................................................................................................................................................

............................................................................................................................................... [2]

[Total: 10]

A4. Plants contain many different types of carbon compounds.

(a) Carbon compounds are made in plants by photosynthesis.

Write the overall equation for photosynthesis and state the conditions required for this process.

...................................................................................................................................................

...................................................................................................................................................

............................................................................................................................................... [3]

(b) Starch is a polymer found in plants. Starch can be hydrolysed.

(i) Give the name of the product formed when starch is hydrolysed.

....................................................................................................................................... [1]

(ii) Give the reagent and conditions needed to hydrolyse starch.

....................................................................................................................................... [2]
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(c) When wood chips are heated in the absence of air, a colourless distillate is formed.

The distillate contains ethanoic acid, esters and other organic compounds.

(i) Ethanoic acid reacts with calcium hydroxide to form a salt and water.

Give the name and formula of the salt formed.

name .................................................................................................................................

formula .......................................................................................................................... [2]

(ii) One of the esters in the distillate has the molecular formula, C4H8O2.

Draw the structure of an ester with this formula, showing all the atoms and all the bonds.

[1]

(iii) The distillate also contains a compound with the following composition.

element percentage by mass

 7

Deduce the empirical formula of this compound.

empirical formula ...........................................................[2]

[Total: 11]

A5. (a) Two students set up tubes as shown.

Four minutes after setting up the experiment, the litmus paper in tube 1 turns red.

Seven minutes after setting up the experiment, the litmus paper in tube 2 turns red.
 8

Use the kinetic particle theory to explain

(i) how the gases move through the tubes,

...........................................................................................................................................

...........................................................................................................................................

...........................................................................................................................................

....................................................................................................................................... [2]

(ii) why the gases take different times to reach the litmus paper.

...........................................................................................................................................

....................................................................................................................................... [1]

(b) A gas syringe is filled with 80 cm3 of hydrogen chloride gas at 20 °C.

The syringe is placed in some hot water at 50 °C.

The atmospheric pressure does not change but the volume of the gas in the syringe increases to 88
cm3.

Use the kinetic particle theory to explain why the volume increases.

...................................................................................................................................................

...................................................................................................................................................

...................................................................................................................................................

............................................................................................................................................... [2]

[Total: 5]
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A6 When one mole of sulfur burns, 247 kJ of energy is released.

S(s) + O2 (g) SO2(g)

(a) Calculate the energy released when 9.60 g of sulfur is burnt.

[2]

(b) When sulfur dioxide is passed through aqueous sodium hydroxide, sodium hydrogensulfite is

formed. Sodium hydrogensulfite contains the hydrogensulfite ion, HSO3–.

Construct the ionic equation for this reaction.

............................................................................................................................................... [1]

(c) The hydrogensulfite ion is a weaker acid than ethanoic acid.

Samples of 0.1 g of magnesium are added separately to 0.1 mol / dm3 ethanoic acid and

0.1 mol / dm3 hydrogensulfite ions.

Explain why the reaction is faster with ethanoic acid.

...................................................................................................................................................

...................................................................................................................................................

...................................................................................................................................................

............................................................................................................................................... [2]
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(d) Calculate the volume of 0.10 mol / dm3 sodium hydroxide which contains 3.2 g of sodium hydroxide.

volume of aqueous sodium hydroxide = ..................... cm3 [2]

[Total: 7]
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Section B
Answer three questions from this section in the spaces provided.
The total mark for this section is 30.

B7.Aqueous hydrogen peroxide is used to sterilise contact lenses.

At room temperature aqueous hydrogen peroxide decomposes very slowly to form water and oxygen.

The decomposition can be represented by the equation below.

(a) Explain why this reaction is exothermic in terms of the energy changes that take place

during bond breaking and bond making.

…………………………………………………………………………………………………………….

…………………………………………………………………………………………………………….

……………………………………………………………………………………………………………. [2]

(b) Draw the energy profile diagram for the decomposition of hydrogen peroxide.

Label on the diagram the activation energy and the enthalpy change.

[3]
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(c) Nickel is a transition element. It is manufactured in a four-stage process from nickel(II)

sulphide, NiS.

• Stage 1 – nickel(II) sulphide is heated in air to form nickel(II) oxide and sulphur dioxide.

• Stage 2 – nickel(II) oxide is heated with carbon to give impure nickel.

• Stage 3 – impure nickel is reacted with carbon monoxide to make nickel tetracarbonyl,

Ni(CO)4.

• Stage 4 – nickel tetracarbonyl is decomposed to give pure nickel.

(a) (i) Construct the balanced equation for the reaction in stage 1.

(ii) Calculate the mass of sulphur dioxide that is formed when 182 kg of nickel sulphide is heated in air.

[3]
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(e) In an experiment, small amounts of three metals were added to three aqueous metalm nitrate
solutions.n The results are shown in the table.

Predict the observations when nickel is added to separate solutions of zinc nitrate and copper(II)
nitrate.

…………………………………………………………………………………………………………….

…………………………………………………………………………………………………………….

……………………………………………………………………………………………………………. [2]

[Total 10]

B8 Fertilisers are soluble salts containing one or more of the essential elements required for plant

growth.

(a) Ammonium chloride can be prepared by the reaction between aqueous ammonia and

hydrochloric acid.

Write an ionic equation for this reaction.

[1]
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(b) State suitable reagents and outline the experimental procedure by which a pure sample of the

fertiliser potassium chloride could be prepared in the laboratory.

…………………………………………………………………………………………………………….

…………………………………………………………………………………………………………….

…………………………………………………………………………………………………………….

…………………………………………………………………………………………………………….

…………………………………………………………………………………………………………….

…………………………………………………………………………………………………………….

……………………………………………………………………………………………………………. [4]

(c) Potassium sulphate can be prepared by the reaction between dilute sulphuric acid and potassium
carbonate.

H2SO4 + K2CO3 K2SO4 + CO2 + H2O

Calculate the mass of potassium sulphate that can be prepared from 3.45 g of potassium

carbonate.

[3]
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(d) Give electronic structures, including the charges, of the ions present in potassium chloride.

[2]

[Total 10]

B9 The table shows the formula of the first three members of the alcohol homologous series.

(a) Deduce the general formula for the alcohol homologous series. [1]

(b) Name the products of the complete combustion of methanol.

[1]

(c) Ethanol can be manufactured from either ethene or glucose.

(i) Write an equation for the production of ethanol from ethene and state the conditions under which the
reaction takes place.

[2]
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(ii) The fermentation of glucose can be represented by the following equation.

C6H12O6 2C2H5OH + 2CO2

Calculate the maximum mass of ethanol that could be made from 36 tonnes of glucose.

[3]

(iii) Explain why ethanol made from ethene is a non-renewable fuel but that made from

Glucose is a renewable fuel.

…………………………………………………………………………………………………………….

…………………………………………………………………………………………………………….

…………………………………………………………………………………………………………….

……………………………………………………………………………………………………………. [2]

(d) Propanol reacts in a similar way to ethanol.

Name the organic product of the reaction between propanol and warm acidified potassium

dichromate(VI).

……………………………………………………………………………………………………………. [1]

[Total: 10]
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B10 An antacid tablet contains a mixture of magnesium hydroxide, Mg(OH)2, and calcium

carbonate, CaCO3.

Stomach acid contains dilute hydrochloric acid.

A student adds a 0.500 g antacid tablet to 50.0 cm3 of 1.00 mol / dm3 hydrochloric acid, HCl.

The acid is in excess.

The graph shows how the total volume of gas produced at r.t.p. changes with time.
 18

(a) Describe, with the aid of a labelled diagram, the apparatus needed to collect this data.

[2]

(b) (i) Write equations for the reactions of HCl with Mg(OH)2 and also with CaCO3.

Mg(OH)2

..................................................................................................................................

CaCO3

............................................................................................................................. [2]

(ii) Calculate the amount, in moles, of carbon dioxide formed at r.t.p. once the reaction had stopped.

amount in moles = .................................................. [2]

 19

(iii) Calculate the mass of CaCO3 in the tablet.

mass of CaCO3 = .............................................. g [2]

(c) The student repeats the experiment. This time she uses a 0.500 g antacid tablet and

3 3 3
50.0 cm of 2.00 mol / dm HCl instead of 50.0 cm of 1.00 mol / dm3 HCl.

Describe and explain what will happen to the rate of reaction.

..........................................................................................................................................

..........................................................................................................................................

..........................................................................................................................................

..................................................................................................................................... [2]

[Total: 10]