Professional Documents
Culture Documents
net/publication/322180658
CITATIONS READS
2 474
1 author:
M. M. Al Naddaf
Yarmouk University
11 PUBLICATIONS 49 CITATIONS
SEE PROFILE
Some of the authors of this publication are also working on these related projects:
hydric dilatation of building stone cepted 20 February 2008 THE EFFECT OF SALTS ON THERMAL AND HYDRIC DILATATION OF POROUS BUILDING STONE View project
All content following this page was uploaded by M. M. Al Naddaf on 02 April 2019.
h i g h l i g h t s
This study compares a new technique to measure W_value and saturation coefficient of building materials with conventional methods.
The new technique can measure the capillary absorption coefficient and saturation coefficient of building materials automatically and continuously.
The new method is accurate, fast and save efforts.
The new method is combatable with the conventional methods.
a r t i c l e i n f o a b s t r a c t
Article history: This study compares a new automated technique, developed by the author, with DIN 52617, the conven-
Received 11 September 2017 tional technique used to measure the capillary water absorption coefficient (W_value), and with DIN
Received in revised form 19 November 2017 52620 used to measure the capillary saturation (CS) of building materials. For this study, two different
Accepted 20 November 2017
types of stone samples (sandstone from Petra and limestone from northern Jordan) and two types of mor-
tars (air lime mortar and Portland cement (Type A) mortar) were taken into consideration. For compar-
ison reasons, the selection of samples ensured considerable differences in their physical properties. All
Keywords:
the samples were measured to determine their W_value and CS by using the conventional technique
Capillary water absorption coefficient
Capillary saturation
(DIN 52617 and DIN 52620), then compared to the devised technique. The obtained results showed that
Automatic measurement there is no significant differences between the two techniques, and thus indicate that the new technique
Capillary rise method is highly compatible with the DIN 52617 and DIN 52620.
Limestone Ó 2017 Elsevier Ltd. All rights reserved.
Sandstone
Portland cement mortar
Air mortar
https://doi.org/10.1016/j.conbuildmat.2017.11.110
0950-0618/Ó 2017 Elsevier Ltd. All rights reserved.
640 M. Al-Naddaf / Construction and Building Materials 160 (2018) 639–643
2.2. Methods during the measurement, but allowing air trapped in the pores to
escape.
2.2.1. Capillary rise method (CRM) The samples were fixed on a special beaker with a wide neck
In order to examine the validity of the newly devised technique, using impermeable and consistent Plastiline to avoid the leakage
the results of capillary absorption values (W_value) and capillary of water between the sample and the beaker. The beaker was
saturation obtained by the new technique were compared to those equipped with a glass tube with a valve, reaching to the bottom
obtained by applying the CRM, taking into account the fact that the of the sample to prevent the air from being entrapped below the
later technique is the most precise and is frequently used for mea- sample. The beaker was connected to a glass tube, which was filled
suring the W_value of building materials [6]. CRM measurements with water (Fig. 2), and a digital displacement tracer was fixed hor-
were performed as recommended by Von Plehwe-Leisen et al. izontally on the tube. When absorbed by the sample, the water
[28] and Courard and Darimont [6] according to DIN 52617 as level in the tube dropped. AmemoÒ 8690 instrument for measured
follows: data acquisition, with data logger function, was used in this study
Drill cores of known diameters and weights were put on a dis- to automatically and continuously (each minute) record water
tilled water-saturated towel, after removing surface water which level in the tube. The relative humidity and temperature in the
has not been absorbed using a humid cloth; the weight increase lab were also recorded. The ACAM used an Almemo displacement
of the sample was then recorded after fixed contact times. Follow- tracer (TR50) with a resolution of 1 lm. The diameter of the tube,
ing this, the relation between the square root of time (h) (x-axis) on which the tracer was fixed, was 27.9 mm. Consequently, each
and weight increase per area (kg/m2) (y-axis) was drawn; the slope millimetre displacement means water absorption equals to 0.611
p
of this relationship equals to the W_value. ml (g). The relation between the square root of time ( h) and
2 2
the water level decrease per sample area (l/m or kg/m ) was plot-
weight increaseðkgÞ ted; the slope of this relationship equals to W_value.
W value ¼ 0:5
areaðm2 Þ timeðh Þ When no more pores to be fulfilled, the tracer would stop mov-
ing; the total moving distance was recorded, and the amount of
The W_value was calculated by a special Excel formula.
absorbed water was calculated. The capillary saturation (CS) was
One the other hand, the capillary saturation was measured
calculated by applying the following equation:
according to DIN 52620 as follows:
A dry sample of a known weight was put on a water-saturated
towel; the weight of the sample was periodically measured until
total mov ement of the tracer ðmmÞ 0:611
there was no more increase. When the pores in the specimen were Capillary saturation ð%Þ ¼
dry weight ðgÞ
fully filled, the wet weight was recorded, and the capillary satura-
tion was calculated by applying the following equation: 100%
wet weight dry weight The temperature and relative humidity were kept constant; 20
Capillary saturation ð%Þ ¼ 100%
dry weight ± 2 °C and 65 ± 5%, respectively during the measurements. The sys-
tem was equipped with a burette to supply water before the mea-
surement starts; this burette was kept closed during the
2.2.2. Automated capillary absorption measurement (ACAM) measurement. Each sample was measured at least 5 times by
To measure the W_value of porous building materials continu- CRM and 5 times by ACAM. The average W_value for each sample
ously and automatically, a new technique was developed. This obtained by each method was calculated.
technique was adopted and used by Al-Naddaf [3] to overcome The measurement period in the 2 methods varied depending on
the problem of the inaccuracy of the results due to salt dissolution the nature of the samples; pores in the samples with a high capil-
in the pores of the tested building materials during the lary water absorption (air lime mortar samples) required a shorter
measurements. time to fulfil. Therefore, the measurement was stopped after about
The specimens used for the purpose of this study were drill one hour, while the pores in sandstone and Portland cement mor-
cores of about 5.5 cm diameter and a length ranging between 7 tar required a longer time to fulfil, 2.5–3 h. In the case of samples
and 10 cm; excluding one base, the samples were covered with with low capillary absorption (the limestone samples), the mea-
Parafilm to avoid lateral penetration and evaporation of water surement period extended to more than 24 h.
Table 1
Physical properties of the studied samples.
Sample No. Sample type Water uptake under atmospheric Water uptake under Open porosity Absolute density Apparent density
pressure (M%)** vacuum (M%)** (%)*** (g/cm3)**** (g/cm3)****
LM1 Air lime mortar (1:1)* 12.58 12.86 24.84 2.57 1.93
LM2 Air lime mortar (2:1)* 16.64 16.92 30.50 2.59 1.80
LM3 Air lime mortar (3:1)* 23.94 24.56 38.66 2.57 1.57
PCM1 Portland Cement mortar (1:1)* 8.92 9.02 18.23 2.47 2.02
PCM2 Portland Cement mortar (2:1)* 10.12 10.22 20.38 2.50 1.99
PCM3 Portland Cement mortar (3:1)* 10.63 10.81 21.39 2.52 1.98
S.St1 Sandstone 4.89 6.30 13.68 2.51 2.17
S.St2 Sandstone 4.96 6.21 13.43 2.50 2.16
S.St3 Sandstone 5.19 6.84 14.72 2.53 2.15
An3 Limestone 0.50 0.56 1.49 2.71 2.67
Ds2 Limestone 2.85 3.32 8.09 2.65 2.44
AB1 Limestone 4.29 4.82 11.28 2.64 2.34
*
Mixing ratio (Aggregate: Binding material).
**
According to DIN 52103.
***
According to Rilem tests No. I.1.
****
According to Rilem tests No. I.2.
642 M. Al-Naddaf / Construction and Building Materials 160 (2018) 639–643
Table 2
Comparison between the experimental (ACAM) and (CRM) results.
3. Results and discussion To test the validity of the new method (ACAM) to measure the
capillary saturation (CS), CS results measured by ACAM were com-
The physical properties of the studied samples varied consider- pared with those obtained by CRM. The average CS of the studied
ably; their porosity ranging between 1.49 and 38.66% and the samples measured by CRM varied considerably; it ranged between
water uptake under atmospheric pressure ranging from 0.5 to 0.41% and 18.73%; samples with the highest CS were those made of
23.94% while the water uptake under vacuum varied from 0.56 air lime mortar, while limestone samples had the lowest CS. How-
to 24.56%. Samples with the lowest water uptake and porosity ever, the results obtained by applying ACAM do not deviate signif-
were the limestone samples while those with the highest values icantly; the difference percentage between the results of the two
for these properties were the air lime mortar. methods, except for sample AN3, is less than 3%. The coefficient
The average W_values of the studied samples measured by of determination for the two types of measurements is almost 1
applying the CRM ranged between 0.01 and 25.72 kg/m2 h0.5. Sam- (Fig. 3B).
ples with the lowest W_value were the limestone samples with an
average value ranging between 0.01 and 0.96 kg/m2 h0.5, while the 4. Conclusions
samples with the highest W_values were those made of air lime
mortar with values ranges between 13.71 and 25.72 kg/m2 h0.5 The results of this study show that the examined technique
(Table 2). measuring automatically the capillary water absorption coefficient
There were no significant differences between the W_value cal- of building materials (ACAM) is highly compatible with the con-
culated by CRM and that calculated by ACAM; the difference ventional method (CRM) as the difference between the results
between the two methods ranged between 0.5 and 10%. The rela- obtained by the two techniques is not significant.
tionship between the results of the two methods was drawn and However, as the W_value of building materials decreases, the
the coefficient of determination (R2) was calculated. An R2 of 1.0 difference in the percentages between the two methods increases;
indicates that the regression line perfectly fits the data [19]. From the empirical formula that represents the relationship between the
this relationship and the calculated coefficient of determination results of the two methods can be written as follows:
(0.999), it can be inferred that the two measurement methods
are compatible (Fig. 3A).
W v alueðACAMÞ ¼ ð1:003 W v alueðCRMÞ Þ 0:044:
M. Al-Naddaf / Construction and Building Materials 160 (2018) 639–643 643
30 25
y = 1.0036x - 0.0448 A B
y = 1.0129x - 0.0491
25 R² = 0.9998 20 R² = 0.9995
CS % (ACAM metod)
20
15
15
10
10
5 5
0 0
0 10 20 30 0 5 10 15 20
W_value (CRM method) CS % (CRM method)
Fig. 3. Relationship between the results of the CRM and ACAM methods. A for W_value and B for CS.
The same can be said about the capillary saturation, but with [13] I. Hammer, Preservation of wall paintings and other surfaces of architecture
affected by salts, interdisciplinary remarks to interpretation of the physical
minor differences; the following empirical formula shows the rela-
system and the damage processes, in: The Proceedings of the Congress LCP 95
tionship between the results of the two methods: ‘‘Conservation and Restoration of Cultural Heritage”, Montreux, 1995, pp. 575–
CS(ACAM) = (1.012 * CS(CRM)) 0.049. This shows that as the cap- 599.
illary saturation decreases, the difference percentage between the [14] J. Heiman, How useful is the short-term testing in the assessment of the long-
term durability of sandstone? in: The Proceedings of the 6th International
two methods increases. Congress on Deterioration and Conservation of Stone, Nicholas Copernicus
University, Torun, Poland, 1988, pp. 356–366.
[15] M. Holubec, P. Matiašovský, Determination of the liquid water diffusivity
Acknowledgment building materials using TDR method, Build. Res. J. 60 (1–2) (2012) 89–108.
[16] N. Karagiannis, M. Karoglou, A. Bakolas, A. Moropoulou, Building materials
capillary rise coefficient: concepts, determination and parameters involved, in:
I am highly grateful to Yarmouk University for supporting this
J. Delgado (Ed.), New Approaches to Building Pathology and Durability.
study. I thank three anonymous reviewers for their comments that Building Pathology and Rehabilitation, Springer, Singapore, 2016.
greatly improved the manuscript. [17] R.M.H. Lawrence, P. Walker, The impact of the water/lime ratio on the
structural characteristics of air lime mortars, in: D.F. D’Ayala, E. Fodde (Eds.),
Structural Analysis of Historic Construction, Taylor & Francis, London, 2008,
References pp. 885–889.
[18] H. Ling, M. Tao, R. Snethlage, The sandstone varieties in Dafosi Grotto.
Entwicklung und Erprobung von Konservierungstechnologien für Kunst - und
[1] M. Al-Naddaf, Weathering Mechanisms: Technical Investigation in Relation to
Kulturgüter der Provinz Shaanxi/VR China, in: Prepr. Contr. Zweite Konferenz
the Conservation of the Sandstone Monuments in Petra, Jordan, Mensch and
zur chinesisch-deutschen Zusammenarbeit in der Denkmalpflege, München,
Buch Verlag, Berlin, 2002.
1993.
[2] M. Al-Naddaf, The effect of salts on thermal and hydric dilatation of porous
[19] N.J.D. Nagelkerke, Maximum likelihood estimation of functional relationships,
building stone, Archaeometry 51 (3) (2009) 495–505.
Lecture Notes Stat. 69 (1992). Springer-Verlag, Berlin Heidelberg.
[3] M. Al-Naddaf, Quantifying the influence of Halite and Sylvite crystallization on
[20] T. Nishiura, Conservation of rock-cliff sculpture in Japan, in: Case Studies in the
capillary water absorption coefficient of sandstone, J. Am. Inst. Conserv. 50 (1)
Conservation of Stone and Wall Paintings, Contributions to the 1986 IIC
(2011) 1–13.
Congress, Bologna, 1986, pp. 155–158.
[4] G. Amoroso, V. Fassina, Stone Decay and Conservation, Elsevier, Amsterdam,
[21] R. Plagge, G. Scheffler, J. Grunewald, Automatische Messung des
1983.
Wasseraufnahmekoeffizienten und des kapillaren Wassergehaltes von
[5] D. Benavente, P. Lock, M.Á.G. Del Cura, S. Ordóñez, Predicting the capillary
porösen Baustoffen, Bauphysik 27 (6) (2005) 315–323.
imbibition of porous rocks from microstructure, Transp. Porous Media 49 (1)
[22] H. Plendreith, Problems in the conservation of monuments, in: Museum and
(2002) 59–76.
Monuments XI: The Conservation of Cultural Property, UNESCO, 1979, pp.
[6] L. Courard, A. Darimont, Appetency and adhesion: analysis of the kinetics of
124–134.
contact between concrete and repairing mortars, in: A. Katz, A. Bentur, M.
[23] R. Rossi-Manaresi, Scientific investigation in relation to the conservation of
Alexander, G. Arliguie (Eds.), Proceedings of the RILEM International
stone, in: N. Bromella, G. Thomson (Eds.), Science and Technology in the
Conference, Interfacial Transition Zone in Cementitious Composites, E&FN
Service of Conservation, Contributions to the 1982 IIC Congress, Washington,
Spon, Haïfa, pp. 185–94.
IIC, London, 1982, pp. 39–45.
[7] L. Courard, R. Degeimbre, A capillary action test for the investigation of
[24] Z. Suchorab, D. Majerek, P. Brzyski, H. Sobczuk, A. Raczkowski, Estimation of
adhesion in repair technology, Can. J. Civ. Eng. 30 (6) (2003) 1101–1110.
water absorption coefficient using the TDR method, in: Thermophysics, AIP
[8] M. Drdácký, M. Černý, Z. Slížková, P. Zíma, Microtube device for innovative
Conf. Proc., AIP, NY, 2017.
water uptake measurements, in: M. Krüger (Ed.), Proceedings of the European
[25] H. Svahn, Non-Destructive Field Tests in Stone Conservation: Final Report for
Workshop on Cultural Heritage Preservation – Berlin, September 26–28,
the Research and Development Project: Literature Study,
Fraunhofer IRB Verlag, Stuttgart, 2011, pp. 126–130.
Riksantikvarieämbetet, Stockholm, 2006.
[9] M. Drdácký, Z. Slížková, Enhanced affordable methods for assessing material
[26] D. Vandevoorde, V. Cnudde, J. Dewanckele, L. Brabant, M. de Bouw, V. Meynen,
characteristics and consolidation effects on stone and mortar, J. Geophys. Eng.
E. Verhaeven, Validation of in situ applicable measuring techniques for analysis
10 (6) (2013) 1–6.
of the water adsorption by stone, Procedia Chem. 8 (1) (2013) 317–327.
[10] R. Giorgi, P. Baglioni, M. Alesiani, S. Capuani, L. Manicini, B. Maraviglia, New
[27] D. Vandevoorde, M. Pamplona, O. Schalm, Y. Vanhellemont, V. Cnudde, E.
results in the application of innovative experimental techniques for
Verhaeven, Contact sponge method: performance of a promising tool for
investigation of stone decay’s processes, in: V. Fassina (ed.), 9th
measuring the initial water absorption, J. Cult. Herit. 10 (1) (2009) 41–47.
International Congress on Deterioration and Conservation of Stone, Venice,
[28] E. Von Plehwe-Leisen, E. Wendler, R. Snethlage, D. Klemm, H. Castello Branco,
2000, pp. 79–87.
A.F. Dos Santos, Investigation into water and humidity transport properties,
[11] C.A. Grissom, A.E. Charola, M.J. Washowiak, Measuring surface roughness on
IDEAS, in: Investigation into Device Against Environmental Attack on Stones; a
stone; back to basics Taylor & Francis, NY, Stud. Conserv. 45 (2) (2000) 73–84.
German–Brazilian Project, GKSS-Forschungszentrum Geesthacht GmbH,
[12] C. Hall, W.D. Hoff, Water Transport in Brick, Stone and Concrete, Taylor &
Germany, 1994, pp. 127–134.
Francis, NY, 2002.