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5-Binary Solid Solutions
5-Binary Solid Solutions
http://www.eng.usf.edu/~campbell/ThermoI/ThermoI_mod.html
MSE 2090: Introduction to Materials Science Chapter 9, Phase Diagrams 7
A pure substance is heated at constant pressure
Tb
α+L
Liquidus
L
Temperature
liquid solution
α+L
Solidus
liquid solution
α +
crystallites of
solid solution
A 20 40 60 80 B
polycrystal
solid solution Composition, wt %
Xliquid
B
XB Xsolid
B
α α+β
β
Wα Wβ
Mass fractions:
WL = S / (R+S) = (Cα - Co) / (Cα - CL) = 0.68
Liquidus
liquid
Solidus
Temperature, °C
Solvus
α+β
Composition, wt% Ag
Eutectic isotherm
Composition, wt% Sn
•A
•B
•C
L → α +L→ α
α +L
α +β
L → α +β
Wβ = P / (P+Q+R) (β phase)
intermetallic
compound
Cu-Zn
Eutectoid
Temperature
l
γ +l
γ l +β
Eutectic
temperature
γ +β
α+γ
Eutectoid α β
temperature
α +β
Eutectoid Eutectic
composition composition
Composition
α + liquid liquid
α +β
β β + liquid
Congruent Ni-Ti
melting of γ
γ → α + γ → α + Fe3C
γ → γ + Fe3C → α + Fe3C
Fraction of pearlite:
F = C − Ph + 2
P = const
F = C − Ph + 1
C=2
F = 3 − Ph