You are on page 1of 47

Date Printed: 05/23/2018 Product: 0918A1NL

Safety Data Sheet

prepared to UN GHS Revision 3

1. Identification of the Substance/Mixture and the Company/Undertaking

1.1 Product Identifier 0918A1NL

Product Name: CARBOGUARD 1340 PART A Revision Date: 05/23/2018


Supercedes Date: 01/20/2016
Component of multicomponent
1.2 Relevant identified uses of the industrial coatings - Industrial
substance or mixture and uses use.
advised against

1.3 Details of the supplier of the safety data sheet

Manufacturer: Carboline Company


2150 Schuetz Road
St. Louis, MO USA 63146

Regulatory / Technical Information:


Contact Carboline Technical Services at
1-800-848-4645

Schlereth, Ken - ehs@stoncor.com


Datasheet Produced by:

1.4 CHEMTREC 1-800-424-9300 (Inside US)


Emergency telephone number: CHEMTREC +1 703 5273887 (Outside US)
HEALTH - Pittsburgh Poison Control 1-412-681-6669

2. Hazard Identification

2.1 Classification of the substance or mixture

Hazardous to the aquatic environment, Chronic, category 2


Eye Irritation, category 2
Skin Irritation, category 2
Skin Sensitizer, category 1

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Date Printed: 05/23/2018 Product: 0918A1NL

2.2 Label elements

Symbol(s) of Product

Signal Word
warning

Named Chemicals on Label


EPOXY RESIN

HAZARD STATEMENTS

Skin Irritation, category 2 H315 Causes skin irritation.


Skin Sensitizer, category 1 H317 May cause an allergic skin reaction.
Eye Irritation, category 2 H319 Causes serious eye irritation.
Hazardous to the aquatic environment, H411 Toxic to aquatic life with long lasting effects.
Chronic, category 2
PRECAUTION PHRASES
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/
face protection.
P302+352 IF ON SKIN: Wash with plenty of soap and water.
P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do so.
Continue rinsing.
P333+313 If skin irritation or rash occurs: Get medical advice/attention.
P391 Collect spillage.
2.3 Other hazards
No Information

Results of PBT and vPvB assessment:


The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.

3. Composition/Information On Ingredients
3.2 Mixtures
Hazardous Ingredients
CAS-No. Chemical Name %
25068-38-6 EPOXY RESIN 75-100
13463-67-7 TITANIUM DIOXIDE 10-25
1314-13-2 ZINC OXIDE 2.5-10

CAS-No. GHS Symbols GHS Hazard Statements M-Factors


25068-38-6 GHS07-GHS09 H315-317-319-411 0
13463-67-7 0
1314-13-2 GHS09 H400-410 0

Additional Information: The text for GHS Hazard Statements shown above (if any) is given in Section 16.

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Date Printed: 05/23/2018 Product: 0918A1NL

4. First-aid Measures
4.1 Description of First Aid Measures
AFTER INHALATION: Give oxygen or artificial respiration if needed. Remove person to fresh air. If signs/symptoms
continue, get medical attention.
AFTER SKIN CONTACT: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. If skin irritation persists, call a physician.
AFTER EYE CONTACT: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
AFTER INGESTION: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. If swallowed, call
a poison control centre or doctor immediately.

4.2 Most important symptoms and effects, both acute and delayed
May cause sensitization by skin contact. Irritating to eyes and skin. May be harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed

No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if
available, can be found in section 11.
When symptoms persist or in all cases of doubt seek medical advice.

5. Fire-fighting Measures
5.1 Extinguishing Media:
Carbon Dioxide, Dry Chemical, Foam, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: Beware of vapours accumulating to form explosive concentrations. Vapours
can accumulate in low areas. Vapors may spread long distances and ignite.

5.2 Special hazards arising from the substance or mixture


No Information

5.3 Advice for firefighters


In the event of fire, wear self-contained breathing apparatus. Evacuate personnel to safe areas. Use NIOSH approved
respiratory protection. Use water spray to cool unopened containers.

6. Accidental Release Measures


6.1 Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation. Evacuate personnel to safe areas. Remove all sources of ignition. To avoid ignition of vapours
by static electricity discharge, all metal parts of the equipment must be grounded. Wear personal protective equipment. For
personal protection see section 8.
6.2 Environmental precautions
Do not allow material to contaminate ground water system. Prevent product from entering drains.
6.3 Methods and material for containment and cleaning up
Prevent further leakage or spillage if safe to do so. Contain spillage, soak up with non-combustible absorbent material, (e.g.
sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations
(see section 13).
6.4 Reference to other sections

Please refer to disposal requirements or country specific disposal requirements for this material. See Section 13 for further
information.

7. Handling and Storage


7.1 Precautions for safe handling

INSTRUCTIONS FOR SAFE HANDLING : Keep containers dry and tightly closed to avoid moisture absorption and
contamination. Prepare the working solution as given on the label(s) and/or the user instructions. Ensure all equipment is

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Date Printed: 05/23/2018 Product: 0918A1NL

electrically grounded before beginning transfer operations. Do not get in eyes, on skin, or on clothing. Use only with
adequate ventilation/personal protection. Avoid breathing vapors, mist or gas. Wash thoroughly after handling.
PROTECTION AND HYGIENE MEASURES : Handle in accordance with good industrial hygiene and safety practice. Wash
hands before breaks and at the end of workday. When using, do not eat, drink or smoke.

7.2 Conditions for safe storage, including any incompatibilities


CONDITIONS TO AVOID: Heat, flames and sparks.
STORAGE CONDITIONS: Keep container closed when not in use. Store in a dry, well ventilated place away from sources of
heat, ignition and direct sunlight.
7.3 Specific end use(s)

No specific advice for end use available.

8. Exposure Controls/Personal Protection


8.1 Control parameters

Ingredients with Occupational Exposure Limits


(US)

Name ACGIH TLV- ACGIH TLV- OSHA PEL- OSHA PEL-


CAS-No. TWA STEL TWA CEILING
EPOXY RESIN N/E N/E N/E N/E
TITANIUM DIOXIDE 10 MGM3 N/E 10 MGM3 N/E
ZINC OXIDE 2 MGM3 10 MGM3 5 MGM3 N/E

FURTHER INFORMATION: Refer to the regulatory exposure limits for the workforce enforced in each country.

8.2 Exposure controls


Personal Protection
RESPIRATORY PROTECTION: In order to avoid inhalation of spray-mist and sanding dust, all spraying and sanding must
be done wearing adequate respirator. Use only with ventilation to keep levels below exposure guidelines reported in this
document. User should test and monitor exposure levels to ensure all personnel are below guidelines. If not sure, or not able
to monitor, use State or federally approved supplied air respirator. For silica containing coatings in a liquid state, and/or if no
exposure limits are established above, air-supplied respirators are generally not required.
EYE PROTECTION: Ensure that eyewash stations and safety showers are close to the workstation location. Safety glasses
with side-shields.
HAND PROTECTION: Gloves should be discarded and replaced if there is any indication of degradation or chemical
breakthrough. Impervious gloves. Request information on glove permeation properties from the glove supplier. Lightweight
protective clothing
OTHER PROTECTIVE EQUIPMENT: No Information
ENGINEERING CONTROLS: Avoid contact with skin, eyes and clothing. Use only in an area equipped with explosion proof
exhaust ventilation. Ensure adequate ventilation, especially in confined areas.

9. Physical and Chemical Properties


9.1 Information on basic physical and chemical properties
Appearance: Viscous Amber Or White

Physical State Liquid

Odor Epoxy
Odor threshold N/D

pH N/D
Melting point / freezing point (°C) N/D

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Boiling point/range (°C) 176 F (80 C) - 513 F (267 C)


Flash Point, (°C) 97
Evaporation rate Slower Than Ether

Flammability (solid, gas) Not determined

Upper/lower flammability or explosive 0.9 - 7.1


limits
Vapour Pressure, mmHg N/D
Vapour density Heavier than Air
Relative density Not determined
Solubility in / Miscibility with water N/D
Partition coefficient: n-octanol/water Not determined
Auto-ignition temperature (°C) Not determined
Decomposition temperature (°C) Not determined
Viscosity Unknown
Explosive properties Not determined
Oxidising properties Not determined

9.2 Other information


VOC Content g/l: 0

Specific Gravity (g/cm3) app 1.16

10. Stability and Reactivity


10.1 Reactivity
No reactivity hazards known under normal storage and use conditions.

10.2 Chemical stability


Stable under normal conditions.

10.3 Possibility of hazardous reactions


Hazardous polymerisation does not occur.

10.4 Conditions to avoid


Heat, flames and sparks.

10.5 Incompatible materials


Strong oxidizing agents.

10.6 Hazardous decomposition products


Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx), dense black smoke.

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Date Printed: 05/23/2018 Product: 0918A1NL

11. Toxicological Information


11.1 Information on toxicological effects
Acute Toxicity:
Oral LD50: N/D
Inhalation LC50: N/D

Irritation: Unknown

Corrosivity: Unknown

Sensitization: Unknown

Repeated dose toxicity: Unknown

Carcinogenicity: Unknown

Mutagenicity: Unknown

Toxicity for reproduction: Unknown

If no information is available above under Acute Toxicity then the acute effects of this product have not been tested.
Data on individual components are tabulated below:

CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50


23000 mg/kg, dermal,
25068-38-6 EPOXY RESIN 11400 mg/kg, rat, oral
rabbit
>20 mL/kg skin, sensitizer

13463-67-7 TITANIUM DIOXIDE 25000 mg/kg, oral (rat) Not Available Not Available

1314-13-2 ZINC OXIDE 15000 mg/kg, oral, rat Not Available Not Available

Additional Information:
The classification(s) is/are relevant when exposed to these respirable substances in dust or powder form only, including cured
product that is subject to sanding, grinding, cutting, or other surface preparation activities. This product may contain Titanium
Dioxide, which is listed by IARC as possibly carcinogenic to humans (Group 2B). This listing is based on inadequate evidence of
carcinogenicity in humans and sufficient evidence in experimental animals.

12. Ecological Information


12.1 Toxicity:

EC50 48hr (Daphnia): Unknown


IC50 72hr (Algae): Unknown

LC50 96hr (fish): Unknown

12.2 Persistence and degradability: Unknown

12.3 Bioaccumulative potential: Unknown

12.4 Mobility in soil: Unknown

12.5 Results of PBT and vPvB The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.
assessment:

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Date Printed: 05/23/2018 Product: 0918A1NL

12.6 Other adverse effects: Unknown

CAS-No. Chemical Name EC50 48hr IC50 72hr LC50 96hr

25068-38-6 EPOXY RESIN 2.1 mg/l (daphnia) 11 mg/l (algae) 1.3 mg/l (fish)
13463-67-7 TITANIUM DIOXIDE No information No information No information
1314-13-2 ZINC OXIDE No information No information No information

13. Disposal Considerations


13.1 WASTE TREATMENT METHODS: Do not burn, or use a cutting torch on, the empty drum. If recycling is not practicable,
dispose of in compliance with local regulations. Dispose of in accordance with local regulations. Empty containers should be
taken to an approved waste handling site for recycling or disposal.

14. Transport Information


14.1 UN number UN3082
14.2 UN proper shipping name Environmentally Hazardous Substance, Liquid, N.O.S.
Technical name (Epoxy Resin)
14.3 Transport hazard class(es) 9
Subsidiary shipping hazard N/A
14.4 Packing group III
14.5 Environmental hazards Marine Pollutant: Yes (Epoxy Resin)
14.6 Special precautions for user Unknown
EmS-No.: F-A, S-F

14.7 Transport in bulk according to Annex II Unknown


of MARPOL 73/78 and the IBC code

15. Regulatory Information


15.1 Safety, health and environmental regulations/legislation for the substance or mixture:

U.S. Federal Regulations: As follows -


CERCLA - Sara Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Skin Corrosion or Irritation, Respiratory or Skin Sensitization, Serious eye damage or eye irritation
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS-No.
ZINC OXIDE 1314-13-2
Toxic Substances Control Act:
All components of this product are either listed on the TSCA Inventory or are exempt.

This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:

No TSCA 12(b) components exist in this product.

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U.S. State Regulations: As follows -


New Jersey Right-to-Know:

The following materials are non-hazardous, but are among the top five components in this product.

Chemical Name CAS-No.


AMORPHOUS SILICA 7631-86-9
ALUMINUM HYDROXIDE 21645-51-2
Pennsylvania Right-To-Know

The following non-hazardous ingredients are present in the product at greater than 3%.

No PA Right-To-Know components exist in this product.


California Proposition 65:

Warning
Warning: The following ingredients present in the product are known to the state of California to cause Cancer:

Chemical Name CAS-No.


TITANIUM DIOXIDE 13463-67-7
DIISONONYL PHTHALATE 28553-12-0
CARBON BLACK 1333-86-4
ETHYL BENZENE 100-41-4
CUMENE 98-82-8

Warning
Warning: The following ingredients present in the product are known to the state of California to cause birth defects, or other
reproductive hazards.

No Proposition 65 Reproductive Toxins exist in this product.

International Regulations: As follows -


* Canadian DSL:

No Information

15.2 Chemical Safety Assessment:


No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

16. Other Information


Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.

Reasons for revision

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Date Printed: 05/23/2018 Product: 0918A1NL
No Information

The information contained herein is, to the best of our knowledge and belief accurate. However,
since the conditions of handling and use are beyond our control, we make no guarantee of results,
and assume no liability for damages incurred by use of this material. It is the responsibility of
the user to comply with all applicable federal, state, and local laws and regulations.

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Date Printed: 05/23/2018 Product: 0918A1NL

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Date Printed: 05/23/2018 Product: 0918B1NL

Safety Data Sheet

prepared to UN GHS Revision 3

1. Identification of the Substance/Mixture and the Company/Undertaking

1.1 Product Identifier 0918B1NL

Product Name: CARBOGUARD 1340 PART B Revision Date: 05/23/2018


Supercedes Date: 07/27/2016
Component of multicomponent
1.2 Relevant identified uses of the industrial coatings - Industrial
substance or mixture and uses use.
advised against

1.3 Details of the supplier of the safety data sheet

Manufacturer: Carboline Company


2150 Schuetz Road
St. Louis, MO USA 63146

Regulatory / Technical Information:


Contact Carboline Technical Services at
1-800-848-4645

Schlereth, Ken - ehs@stoncor.com


Datasheet Produced by:

1.4 CHEMTREC 1-800-424-9300 (Inside US)


Emergency telephone number: CHEMTREC +1 703 5273887 (Outside US)
HEALTH - Pittsburgh Poison Control 1-412-681-6669

2. Hazard Identification

2.1 Classification of the substance or mixture

Acute Toxicity, Inhalation, category 2


Hazardous to the aquatic environment, Acute, category 1
Hazardous to the aquatic environment, Chronic, category 1
Reproductive Toxicity, category 1A
Skin Corrosion, category 1
Skin Sensitizer, category 1

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Date Printed: 05/23/2018 Product: 0918B1NL

2.2 Label elements

Symbol(s) of Product

Signal Word
danger

Named Chemicals on Label


BISPHENOL A, BENZYL ALCOHOL, DIETHYLENETRIAMINE, TOFA, REACTION PRODUCTS WITH TEPA, 4-NONYL
PHENOL, BRANCHED
HAZARD STATEMENTS

Acute Toxicity, Oral, category 4 H302 Harmful if swallowed.


Acute Toxicity, Dermal, category 4 H312 Harmful in contact with skin.
Skin Corrosion, category 1 H314-1 Causes severe skin burns and eye damage.
Skin Sensitizer, category 1 H317 May cause an allergic skin reaction.
Acute Toxicity, Inhalation, category 2 H330-2 Fatal if inhaled.
Reproductive Toxicity, category 1A H360-1A May damage fertility or the unborn child.
Hazardous to the aquatic environment, H400 Very toxic to aquatic life.
Acute, category 1
Hazardous to the aquatic environment, H410 Very toxic to aquatic life with long lasting effects.
Chronic, category 1
PRECAUTION PHRASES
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/
face protection.
P284 Wear respiratory protection.
P301+310 IF SWALLOWED: Immediately call a POISON CENTER or
doctor/physician.
P301+330+331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+352 IF ON SKIN: Wash with plenty of soap and water.
P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a
position comfortable for breathing.
P305+P351+P3 IF IN EYES: Rinse cautiously with water for several minutes.
38 Remove contact lenses, if present and easy to do so.
Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention
P312 Call a POISON CENTER or doctor/physician if you feel
unwell.
P333+313 If skin irritation or rash occurs: Get medical advice/attention.
P352 Wash with plenty of soap and water.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
P403+233 Store in a well-ventilated place. Keep container tightly
closed.

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2.3 Other hazards


No Information

Results of PBT and vPvB assessment:


The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.

3. Composition/Information On Ingredients
3.2 Mixtures
Hazardous Ingredients
CAS-No. Chemical Name %
100-51-6 BENZYL ALCOHOL 50-75
68953-36-6 TOFA, REACTION PRODUCTS WITH TEPA 10-25
111-40-0 DIETHYLENETRIAMINE 2.5-10
80-05-7 BISPHENOL A 2.5-10
84852-15-3 4-NONYL PHENOL, BRANCHED 1.0-2.5

CAS-No. GHS Symbols GHS Hazard Statements M-Factors


100-51-6 GHS07 H302-312-319-332 0
68953-36-6 GHS05-GHS07-GHS09 H314-317-400-410 0
111-40-0 GHS05-GHS06 H302-312-314-317-330-335 0
80-05-7 GHS05-GHS07-GHS08-GHS09 H317-318-335-360-411 0
84852-15-3 GHS05-GHS07-GHS08-GHS09 H302-314-361-400-410 0

Additional Information: The text for GHS Hazard Statements shown above (if any) is given in Section 16.

4. First-aid Measures
4.1 Description of First Aid Measures
AFTER INHALATION: Give oxygen or artificial respiration if needed. Remove person to fresh air. If signs/symptoms
continue, get medical attention.
AFTER SKIN CONTACT: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. If skin irritation persists, call a physician.
AFTER EYE CONTACT: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
AFTER INGESTION: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. If swallowed, call
a poison control centre or doctor immediately.

4.2 Most important symptoms and effects, both acute and delayed
Irritating to eyes and skin. May be harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed

No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if
available, can be found in section 11.
When symptoms persist or in all cases of doubt seek medical advice.

5. Fire-fighting Measures
5.1 Extinguishing Media:
Carbon Dioxide, Dry Chemical, Foam, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: Beware of vapours accumulating to form explosive concentrations. Vapours
can accumulate in low areas. Vapors may spread long distances and ignite.

5.2 Special hazards arising from the substance or mixture


No Information

5.3 Advice for firefighters


In the event of fire, wear self-contained breathing apparatus. Evacuate personnel to safe areas. Use NIOSH approved
respiratory protection. Use water spray to cool unopened containers.

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Date Printed: 05/23/2018 Product: 0918B1NL

6. Accidental Release Measures


6.1 Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation. Evacuate personnel to safe areas. Remove all sources of ignition. To avoid ignition of vapours
by static electricity discharge, all metal parts of the equipment must be grounded. Wear personal protective equipment. For
personal protection see section 8.
6.2 Environmental precautions
Do not allow material to contaminate ground water system. Prevent product from entering drains.
6.3 Methods and material for containment and cleaning up

Prevent further leakage or spillage if safe to do so. Contain spillage, soak up with non-combustible absorbent material, (e.g.
sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations
(see section 13).
6.4 Reference to other sections

Please refer to disposal requirements or country specific disposal requirements for this material. See Section 13 for further
information.

7. Handling and Storage


7.1 Precautions for safe handling

INSTRUCTIONS FOR SAFE HANDLING : Keep containers dry and tightly closed to avoid moisture absorption and
contamination. Prepare the working solution as given on the label(s) and/or the user instructions. Ensure all equipment is
electrically grounded before beginning transfer operations. Do not get in eyes, on skin, or on clothing. Use only with
adequate ventilation/personal protection. Avoid breathing vapors, mist or gas. Wash thoroughly after handling.
PROTECTION AND HYGIENE MEASURES : Handle in accordance with good industrial hygiene and safety practice. Wash
hands before breaks and at the end of workday. When using, do not eat, drink or smoke.

7.2 Conditions for safe storage, including any incompatibilities


CONDITIONS TO AVOID: Heat, flames and sparks.
STORAGE CONDITIONS: Keep container closed when not in use. Store in a dry, well ventilated place away from sources of
heat, ignition and direct sunlight.
7.3 Specific end use(s)

No specific advice for end use available.

8. Exposure Controls/Personal Protection


8.1 Control parameters

Ingredients with Occupational Exposure Limits


(US)

Name ACGIH TLV- ACGIH TLV- OSHA PEL- OSHA PEL-


CAS-No. TWA STEL TWA CEILING
BENZYL ALCOHOL N/E N/E N/E N/E
TOFA, REACTION PRODUCTS WITH TEPA N/E N/E N/E N/E
DIETHYLENETRIAMINE 1 PPM N/E 4 MGM3 N/E
BISPHENOL A N/E N/E N/E N/E
4-NONYL PHENOL, BRANCHED N/E N/E N/E N/E

FURTHER INFORMATION: Refer to the regulatory exposure limits for the workforce enforced in each country.

8.2 Exposure controls


Personal Protection
RESPIRATORY PROTECTION: In order to avoid inhalation of spray-mist and sanding dust, all spraying and sanding must
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Date Printed: 05/23/2018 Product: 0918B1NL

be done wearing adequate respirator. Use only with ventilation to keep levels below exposure guidelines reported in this
document. User should test and monitor exposure levels to ensure all personnel are below guidelines. If not sure, or not able
to monitor, use State or federally approved supplied air respirator. For silica containing coatings in a liquid state, and/or if no
exposure limits are established above, air-supplied respirators are generally not required.
EYE PROTECTION: Ensure that eyewash stations and safety showers are close to the workstation location. Safety glasses
with side-shields.
HAND PROTECTION: Gloves should be discarded and replaced if there is any indication of degradation or chemical
breakthrough. Impervious gloves. Request information on glove permeation properties from the glove supplier. Lightweight
protective clothing
OTHER PROTECTIVE EQUIPMENT: No Information
ENGINEERING CONTROLS: Avoid contact with skin, eyes and clothing. Use only in an area equipped with explosion proof
exhaust ventilation. Ensure adequate ventilation, especially in confined areas.

9. Physical and Chemical Properties


9.1 Information on basic physical and chemical properties
Appearance: Viscous Brown Liquid

Physical State Liquid


Odor Faint Amine
Odor threshold N/D
pH N/D
Melting point / freezing point (°C) N/D
Boiling point/range (°C) 149 F (65 C) - 500 F (260 C)
Flash Point, (°C) 97
Evaporation rate Slower Than Ether

Flammability (solid, gas) Not determined

Upper/lower flammability or explosive 1.3 - 36.0


limits
Vapour Pressure, mmHg N/D
Vapour density Heavier than Air
Relative density Not determined
Solubility in / Miscibility with water N/D
Partition coefficient: n-octanol/water Not determined
Auto-ignition temperature (°C) Not determined
Decomposition temperature (°C) Not determined
Viscosity Unknown
Explosive properties Not determined
Oxidising properties Not determined

9.2 Other information


VOC Content g/l: 0

Specific Gravity (g/cm3) 1.02

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10. Stability and Reactivity


10.1 Reactivity
No reactivity hazards known under normal storage and use conditions.

10.2 Chemical stability


Stable under normal conditions.

10.3 Possibility of hazardous reactions


Hazardous polymerisation does not occur.

10.4 Conditions to avoid


Heat, flames and sparks.

10.5 Incompatible materials


Strong oxidizing agents.

10.6 Hazardous decomposition products


Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx), dense black smoke.

11. Toxicological Information


11.1 Information on toxicological effects
Acute Toxicity:
Oral LD50: N/D
Inhalation LC50: N/D

Irritation: Unknown

Corrosivity: Unknown

Sensitization: Unknown

Repeated dose toxicity: Unknown

Carcinogenicity: Unknown

Mutagenicity: Unknown

Toxicity for reproduction: Unknown

If no information is available above under Acute Toxicity then the acute effects of this product have not been tested.
Data on individual components are tabulated below:

CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50


2000 mg/kg, dermal,
100-51-6 BENZYL ALCOHOL 1230 mg/kg rat, oral
rabbit
4176 mg/l / 4h, Inh, Rat

68953-36-6 TOFA, REACTION PRODUCTS WITH TEPA 4750 mg/kg oral, rat Not Available

1045 mg/kg, dermal,


111-40-0 DIETHYLENETRIAMINE 1080 mg/kg, oral, rat
rabbit
0.07 mg/l, 4 hr, Inh, Rat

80-05-7 BISPHENOL A 11400 mg/kg, oral, rat Not Available Not Available

84852-15-3 4-NONYL PHENOL, BRANCHED 1620 mg/kg oral Not Available

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Additional Information:
No Information

12. Ecological Information


12.1 Toxicity:

EC50 48hr (Daphnia): Unknown


IC50 72hr (Algae): Unknown

LC50 96hr (fish): Unknown

12.2 Persistence and degradability: Unknown

12.3 Bioaccumulative potential: Unknown

12.4 Mobility in soil: Unknown

12.5 Results of PBT and vPvB The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.
assessment:

12.6 Other adverse effects: Unknown

CAS-No. Chemical Name EC50 48hr IC50 72hr LC50 96hr

100-51-6 BENZYL ALCOHOL 230 mg/l (Daphnia) 700 mg/l (Algae) 10 mg/l (Fish)
68953-36-6 TOFA, REACTION PRODUCTS WITH TEPA No information No information No information
111-40-0 DIETHYLENETRIAMINE 32 mg/l (Daphnia) 1164 mg/l (Algae) 430 mg/l (Fish)
80-05-7 BISPHENOL A No information No information No information
84852-15-3 4-NONYL PHENOL, BRANCHED No information No information No information

13. Disposal Considerations


13.1 WASTE TREATMENT METHODS: Do not burn, or use a cutting torch on, the empty drum. If recycling is not practicable,
dispose of in compliance with local regulations. Dispose of in accordance with local regulations. Empty containers should be
taken to an approved waste handling site for recycling or disposal.

14. Transport Information


14.1 UN number N/A
14.2 UN proper shipping name Not Regulated
Technical name N/A
14.3 Transport hazard class(es) None
Subsidiary shipping hazard N/A
14.4 Packing group N/A
14.5 Environmental hazards Unknown
14.6 Special precautions for user Unknown
EmS-No.: Unknown

14.7 Transport in bulk according to Annex II Unknown


of MARPOL 73/78 and the IBC code

15. Regulatory Information


Page 7 / 9
Date Printed: 05/23/2018 Product: 0918B1NL

15.1 Safety, health and environmental regulations/legislation for the substance or mixture:

U.S. Federal Regulations: As follows -


CERCLA - Sara Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Acute Toxicity (any route of exposure), Reproductive toxicity, Skin Corrosion or Irritation, Respiratory or Skin Sensitization
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS-No.
BISPHENOL A 80-05-7
4-NONYL PHENOL, BRANCHED 84852-15-3
Toxic Substances Control Act:
All components of this product are either listed on the TSCA Inventory or are exempt.

This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:

No TSCA 12(b) components exist in this product.


U.S. State Regulations: As follows -
New Jersey Right-to-Know:

The following materials are non-hazardous, but are among the top five components in this product.

Chemical Name CAS-No.


No NJ Right-To-Know components exist in this
product.
Pennsylvania Right-To-Know

The following non-hazardous ingredients are present in the product at greater than 3%.

No PA Right-To-Know components exist in this product.


California Proposition 65:

Warning
Warning: The following ingredients present in the product are known to the state of California to cause Cancer:

Chemical Name CAS-No.


FORMALDEHYDE 50-00-0

Warning
Warning: The following ingredients present in the product are known to the state of California to cause birth defects, or other
reproductive hazards.

Chemical Name CAS-No.


BISPHENOL A 80-05-7
METHYL ALCOHOL 67-56-1

Page 8 / 9
Date Printed: 05/23/2018 Product: 0918B1NL

International Regulations: As follows -


* Canadian DSL:

No Information

15.2 Chemical Safety Assessment:


No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

16. Other Information


Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H330 Fatal if inhaled.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H360 May damage fertility or the unborn child.
H361 Suspected of damaging fertility or the unborn child.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.

Reasons for revision


No Information

The information contained herein is, to the best of our knowledge and belief accurate. However,
since the conditions of handling and use are beyond our control, we make no guarantee of results,
and assume no liability for damages incurred by use of this material. It is the responsibility of
the user to comply with all applicable federal, state, and local laws and regulations.

Page 9 / 9
CHEMTREC Transportation
Emergency Phone: 800-424-
9300

Material Safety Pittsburgh Poison Control


Center
Health Emergency No.: 412-
Data Sheet 681-6669
NOTE: The CHEMTREC Transportation
Emergency Phone is to be used only in the
event of chemical emergencies involving a
spill, leak, fire, exposure or accident
involving chemicals

Section 1 - Chemical Product / Company Information

Product Name: URETHANE CONVERTER 811 Revision Date: 03/28/2011


Identification
PLMSDS 0856B1NL Supercedes : 09/01/2010
Number:
Product Catalyst for Polyurethane Products -
Use/Class: FOR INDUSTRIAL USE ONLY
Preparer: Regulatory, Department
Manufacturer: Carboline Company
2150 Schuetz Road
St. Louis, MO 63146
(800) 848-4645

Section 2 - Composition / Information On Ingredients

Chemical Name CAS Number Weight % Less Than ACGIH TLV-TWA ACGIH TLV-STEL OSHA PEL-TWA OSHA-CEIL
HOMOPOLYMER OF 28182-81-2 90.0 N/E N/E N/E N/E
HDI
N-BUTYL ACETATE 123-86-4 5.0 150 PPM 200 PPM 710 MG/M3 N/E
AROMATIC 64742-95-6 5.0 N/E N/E N/E N/E
HYDROCARBON
1,2,4 95-63-6 5.0 25 PPM N/E 125 MGM3 N/E
TRIMETHYLBENZENE
HEXAMETHYLENE 822-06-0 0.3 0.005 PPM N/E N/E N/E
DIISOCYANATE

Section 3 - Hazards Identification

Emergency Overview: COMBUSTIBLE liquid and vapor. Reacts violently with common materials including
water, alcohols, bases and amines. Harmful if inhaled. Eye, skin and respiratory tract irritant. Possible
sensitizer.

Effects Of Overexposure - Eye Contact: May cause eye irritation.

Effects Of Overexposure - Skin Contact: Irritant. May produce symptoms similar to those from inhalation.
Can cause dryness, loss of natural oils, allergic reaction.

Effects Of Overexposure - Inhalation: Harmful if inhaled. May cause hoarseness, upper respiratory tract
irritation, intoxication, headache, confusion, coma, liver damage, kidney damage.

Effects Of Overexposure - Ingestion: Harmful if ingested. May produce symptoms similar to those from
inhalation. Can cause nausea, abdominal cramps.
Effects Of Overexposure - Chronic Hazards: Prolonged contact may cause liver damage, kidney damage,
chronic damage to intestines, central nervous system damage, dizziness, weakness, headache, nausea.
Repeated, prolonged contact may cause intestinal disturbances. Reports have associated repeated and
prolonged occupational overexposure to solvents with permanent brain and nervous system damage.

Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Ingestion, Eye Contact

Medical Conditions Prone to Aggravation by Exposure: If sensitized to isocyanates or other chemicals, do


not use. See a physician if a medical condition exists. If you have a condition that could be aggravated by
exposure to dust or organic vapors, see a physician prior to use.

Section 4 - First Aid Measures

First Aid - Eye Contact: If material gets into eyes, flush with water immediately for 15 minutes. Consult a
physician.

First Aid - Skin Contact: In case of contact, immediately wash with plenty of soap and water for at least 15
minutes. Seek medical attention. Remove contaminated clothing and shoes. Clean contaminated clothing and
shoes before re-use.

First Aid - Inhalation: If inhaled, remove to fresh air. Administer oxygen if necessary. Consult a physician if
symptoms persist or exposure was severe.

First Aid - Ingestion: If swallowed do not induce vomiting. Seek immediate medical attention.

Section 5 - Fire Fighting Measures


Flash Point, F: 127F (53C) Lower Explosive Limit, %: 0.9
(Setaflash) Upper Explosive Limit, %: 10.4

Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam

Unusual Fire And Explosion Hazards: Combustible Liquid. Vapors are heavier than air and will accumulate.
Vapors will form explosive concentrations with air. Vapors travel long distances and will flashback. Use
mechanical ventilation when necessary to keep percent vapor below the "Lower Explosion Level" (LEL).
Eliminate all ignition sources. Keep away from sparks, open flames and heat sources. All electric equipment
and installations should be made and grounded in accordance with the National Electrical Code. In areas
where explosion hazards exist, workers should be required to use non-ferrous tools and to wear conductive
and non-sparking shoes.

Special Firefighting Procedures: Combustible. Cool fire-exposed containers using water spray. Firefighters
should wear NIOSH/MSHA approved self-contained breathing apperatus and full protective clothing. Cool
tightly closed containers exposed to fire with water.

Section 6 - Accidental Release Measures

Steps To Be Taken If Material Is Released Or Spilled: Eliminate all ignition sources. Handling equipment
must be grounded to prevent sparking. Evacuate the area of unprotected personnel. Wear appropriate
personal protection clothing and equipment. Follow exposure controls/personal protection guidelines in Section
8. Contain and soak up residual with an aborbent (clay or sand). Take up absorbant material and seal tightly for
proper disposal. Dispose of in accordance with local, state and federal regulations. Refer to Section 15 for
SARA Title III and CERCLA information.
Section 7 - Handling And Storage

Handling: Do not get in eyes, on skin, or on clothing. Keep container tightly closed when not in use. Wear
personal protection equipment. Do not breathe vapors. Wash thoroughly after handling. If pouring or
transferring materials, ground all containers and tools. Do not weld, heat, cut or drill on full or empty containers.
Use only in accordance with Carboline application instructions, container label and Product Data Sheet.

Storage: Keep away from heat, sparks, open flames and oxidizing agents. Keep containers closed. Store in a
cool, dry place with adequate ventilation.

Section 8 - Exposure Controls / Personal Protection

Engineering Controls: Use explosion-proof ventilation when required to keep below health exposure
guidelines and Lower Explosion Limit (LEL).

Respiratory Protection: Use only with ventilation to keep levels below exposure guidelines listed in Section 2.
User should test and monitor exposure levels to ensure all personnel are below guidelines. If not in a confined
space, and not able to monitor, use MSHA/NIOSH approved organic vapor respirator. Follow all current OSHA
requirements for respirator use.

Skin Protection: Recommend impervious gloves and clothing to avoid skin contact. If material penetrates to
skin, change gloves and clothing. The use of protective creams may be beneficial to certain individuals.
Protective creams should be applied before exposure.

Eye Protection: Recommend safety glasses with side shields or chemical goggles to avoid eye contact.

Other protective equipment: Eye wash and safety showers should be readily available.

Hygienic Practices: Wash with soap and water before eating, drinking, smoking, applying cosmetics, or using
toilet facilities. Use of a hand cleaner is recommended. Launder contaminated clothing before reuse. Leather
shoes can absorb and allow hazardous materials to pass through. Check shoes carefully after soaking before
reuse.

Section 9 - Physical And Chemical Properties


Boiling Range: 262 F (128 C) - 262F (128C) Vapor Density: Heavier than Air
Odor: Slight Odor Odor Threshold: N/D
Appearance: Colorless, Mobil Liquid Evaporation Rate: Slower Than Ether
Solubility in H2O: Reacts
Freeze Point: N/D Specific Gravity: 1.12
Vapor Pressure: N/D PH: N/D
Physical State: Liquid

(See section 16 for abbreviation legend)

Section 10 - Stability And Reactivity

Conditions To Avoid: Heat, sparks and open flames.

Incompatibility: Keep away from strong oxidizing agents, heat and open flames.

Hazardous Decomposition Products: Carbon monoxide, nitrogen oxides, and unidentified organic
compounds. Consider all smoke and fumes from burning material as very hazardous. Welding, cutting or
abrasive grinding can create smoke and fumes. Do not breathe any fumes or smoke from these operations.

Hazardous Polymerization: Will not occur under normal conditions.

Stability: This product is stable under normal storage conditions.

Section 11 - Toxicological Information

Product LD50: N/D Product LC50: N/D

Chemical Name CAS Number LD50 LC50


HOMOPOLYMER OF HDI 28182-81-2 >5000 MG/KG, ORAL, RAT 3124 MG/KG
N-BUTYL ACETATE 123-86-4 7.4 G/KG RABBIT ORAL >1800 PPM/6H INHALATION
AROMATIC HYDROCARBON 64742-95-6 4700 MG/KG, ORAL, RAT 3670 PPM/8 HOURS, RAT, INHALATION
1,2,4 TRIMETHYLBENZENE 95-63-6 5 GM/KG, ORAL, RAT 18 GM/M3/4HOURS
HEXAMETHYLENE DIISOCYANATE 822-06-0 710 MG/KG, ORAL RAT 23 PPM / 4 HRS

Section 12 - Ecological Information

Ecological Information: No data

Section 13 - Disposal Information

Disposal Information: Dispose of in accordance with State, Local, and Federal Environmental regulations.
Responsibility for proper waste disposal is with the owner of the waste.

Section 14 - Transportation Information

DOT Proper Shipping Paint Packing Group: III


Name:
DOT Technical Name: N/A Hazard Subclass:N/A
DOT Hazard Class: 3 Resp. Guide 128
Page:
DOT UN/NA Number: UN 1263

Additional Notes: None.

Section 15 - Regulatory Information

CERCLA - SARA HAZARD CATEGORY

This product has been reviewed according to the EPA Hazard Categories promulgated under Sections 311and
312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:

IMMEDIATE HEALTH HAZARD, FIRE HAZARD

SARA SECTION 313

This product contains the following substances subject to the reporting requirements of Section 313 of Title III
of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS Number
1,2,4 TRIMETHYLBENZENE 95-63-6
HEXAMETHYLENE DIISOCYANATE 822-06-0

TOXIC SUBSTANCES CONTROL ACT

All components of this product are listed on the TSCA inventory.

This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if
exported from the United States:

No TSCA 12(B) Substances exist in this product

U.S. STATE REGULATIONS AS FOLLOWS:

NEW JERSEY RIGHT-TO-KNOW

The following materials are non-hazardous, but are among the top five components in this product.

PENNSYLVANIA RIGHT-TO-KNOW

The following non-hazardous ingredients are present in the product at greater than 3%.

CALIFORNIA PROPOSITION 65

Warning: The following ingredients present in the product are known to the state of California to cause
Cancer:

Chemical Name CAS Number


CUMENE 98-82-8
ETHYL BENZENE 100-41-4

Warning: The following ingredients present in the product are known to the state of California to cause
birth defects, or other reproductive hazards:

Chemical Name CAS Number


TOLUENE 108-88-3

INTERNATIONAL REGULATIONS AS FOLLOWS:

CANADIAN WHMIS

This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16
headings.

CANADIAN WHMIS CLASS: B3 D2A D2B

Section 16 - Other Information

HMIS Ratings
Health: 2 Flammability: 3 Reactivity: 1 Personal Protection: X

VOLATILE ORGANIC COMPOUNDS, GR/LTR MIXED (UNTHINNED): Refer to Part A MSDS

REASON FOR REVISION: New Product


Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined

The information contained herein is, to the best of our knowledge and belief accurate. However, since the
conditions of handling and use are beyond our control, we make no guarantee of results, and assume no
liability for damages incurred by use of this material. It is the responsibility of the user to comply with all
applicable federal, state, and local laws and regulations
CHEMTREC Transportation
Emergency Phone: 800-

Material 424-9300
Pittsburgh Poison Control

Safety Data Center


Health Emergency No.: 412-
681-6669
Sheet NOTE: The CHEMTREC Transportation
Emergency Phone is to be used only in the
event of chemical emergencies involving a
spill, leak, fire, exposure or accident
involving chemicals

Section 1 - Chemical Product / Company Information

Revision
Product Name: CARBOTHANE 134 HG PART A 04/22/2010
Date:
Identification
PLMSDS 0859A1NL Supercedes : 04/19/2007
Number:
Product Aliphatic Acrylic Polyurethane -
Use/Class: FOR INDUSTRIAL USE ONLY
Preparer: Regulatory, Department
Manufacturer: Carboline Company
2150 Schuetz Road
St. Louis, MO 63146
(800) 848-4645

Section 2 - Composition / Information On Ingredients

Chemical Name CAS Number Weight % Less Than ACGIH TLV-TWA ACGIH TLV-STEL OSHA PEL-TWA OSHA-CEIL
TITANIUM DIOXIDE 13463-67-7 40.0 10 MGM3 N/E 10 MGM3 N/E
MICROCRYSTALLINE 14808-60-7 35.0 0.025 MG/M3 N/E 0.1 MG/M3 N/E
SILICA (respirable) (respirable)
N-BUTYL ACETATE 123-86-4 10.0 150 PPM 200 PPM 710 MG/M3 N/E
TOLUENE 108-88-3 10.0 20 PPM N/E 375 MGM3 NE
CARBON BLACK 1333-86-4 10.0 3.5 MG/M3 N/E 3.5 MG/M3 N/E
META-XYLENE 108-38-3 5.0 434 Mg/M3 651 Mg/M3 434 Mg/M3 N/E
ALIPHATIC DIOL TRADE SECRET 5.0 25 PPM N/E 25 PPM N/E
LIMESTONE 1317-65-3 5.0 N/E N/E 5 MGM3 N/E
ETHOXYPROPIONATE 763-69-9 5.0 N/E N/E N/E N/E
ETHYL BENZENE 100-41-4 5.0 100 PPM 125 PPM 435 MGM3 N/E
PARA-XYLENE 106-42-3 5.0 100 PPM 150 PPM 435 MGM3 N/E
1-METHOXY-2- 108-65-6 5.0 N/E N/E N/E N/E
PROPANOL ACETATE
ORTHO-XYLENE 95-47-6 5.0 434 Mg/M3 651 Mg/M3 434 Mg/M3 N/E
STODDARD SOLVENT 8052-41-3 5.0 100 PPM N/E 500 PPM N/E

Section 3 - Hazards Identification

Emergency Overview: Warning! Flammable. Harmful if inhaled. Causes eye and skin irritation.
Aspiration may cause lung damage. May cause dizziness and drowsiness. Keep away from heat, sparks,
flame. Avoid breathing vapor. Avoid contact with eyes, skin and clothing. Do not swallow. Keep container
closed. Use with adequate ventilation. Wash thoroughly after handling. Contains SILICA which can cause
cancer. Risk of Cancer depends on duration and level of exposure.

Effects Of Overexposure - Eye Contact: May cause eye irritation.

Effects Of Overexposure - Skin Contact: Direct skin contact may cause irritation.

Effects Of Overexposure - Inhalation: Harmful if inhaled, may affect the brain or nervous system,
causing dizziness, headache, or nausea. May cause nose and throat irritation.

Effects Of Overexposure - Ingestion: Harmful if swallowed.

Effects Of Overexposure - Chronic Hazards: Crystalline silica is known to cause silicosis. Crystalline
silica (Quartz) is classified as a known human carcinogen (Group 1) by IARC. Exposure is by route of

Page 1 of 6
inhalation. If material is in a liquid matrix it is unlikely to be inhaled. However, when sanding or grinding
the finished product, there may be potential for crystalline silica to become airborne. Reports have
associated repeated and prolonged occupational overexposure to solvents with permanent brain and
nervous system damage.

Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation, Ingestion, Eye Contact

Medical Conditions Prone to Aggravation by Exposure: If you have a condition that could be
aggravated by exposure to dust or organic vapors, see a physician prior to use.

Section 4 - First Aid Measures

First Aid - Eye Contact: If material gets into eyes, flush with water immediately for 15 minutes. Consult
a physician.

First Aid - Skin Contact: In case of contact, immediately flush skin with plenty of water while removing
contaminated clothing and shoes. Launder clothing before reuse. If rash or irritation develops, consult a
physician.

First Aid - Inhalation: If inhaled, remove to fresh air. Administer oxygen if necessary. Consult a
physician if symptoms persist or exposure was severe.

First Aid - Ingestion: If swallowed do not induce vomiting. Seek immediate medical attention.

Section 5 - Fire Fighting Measures


Flash Point, F: 50F (10C) Lower Explosive Limit, %: 0.6
(Setaflash) Upper Explosive Limit, %: 10.4

Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog

Unusual Fire And Explosion Hazards: Flammable Liquid. Vapors are heavier than air and will
accumulate. Vapors will form explosive concentrations with air. Vapors travel long distances and will
flashback. Use mechanical ventilation when necessary to keep percent vapor below the "Lower Explosion
Level" (LEL). Eliminate all ignition sources. Keep away from sparks, open flames and heat sources. All
electric equipment and installations should be made and grounded in accordance with the National
Electrical Code. In areas where explosion hazards exist, workers should be required to use non-ferrous
tools and to wear conductive and non-sparking shoes.

Special Firefighting Procedures: Flammable. Cool fire-exposed containers using water spray.

Section 6 - Accidental Release Measures

Steps To Be Taken If Material Is Released Or Spilled: Eliminate all ignition sources. Handling
equipment must be grounded to prevent sparking. Evacuate the area of unprotected personnel. Wear
appropriate personal protection clothing and equipment. Follow exposure controls/personal protection
guidelines in Section 8. Contain and soak up residual with an aborbent (clay or sand). Take up absorbant
material and seal tightly for proper disposal. Dispose of in accordance with local, state and federal
regulations. Refer to Section 15 for SARA Title III and CERCLA information.

Section 7 - Handling And Storage

Handling: Do not get in eyes, on skin, or on clothing. Keep container tightly closed when not in use. Wear
personal protection equipment. Do not breathe vapors. Wash thoroughly after handling. If pouring or
transferring materials, ground all containers and tools. Do not weld, heat, cut or drill on full or empty
containers. Use only in accordance with Carboline application instructions, container label and Product
Data Sheet. Avoid breathing vapors or spray mist.

Storage: Keep away from heat, sparks, open flames and oxidizing agents. Keep containers closed. Store
in a cool, dry place with adequate ventilation.

Page 2 of 6
Section 8 - Exposure Controls / Personal Protection

Engineering Controls: Use explosion-proof ventilation when required to keep below health exposure
guidelines and Lower Explosion Limit (LEL).

Respiratory Protection: Use only with ventilation to keep levels below exposure guidelines listed in
Section 2. User should test and monitor exposure levels to ensure all personnel are below guidelines. If
not sure, or not able to monitor, use MSHA/NIOSH approved supplied air respirator. Follow all current
OSHA requirements for respirator use. For silica containing coatings in a liquid state, and/or if no
exposure limits are established in Section 2 above, supplied air respirators are generally not required.

Skin Protection: Recommend impervious gloves and clothing to avoid skin contact. If material penetrates
to skin, change gloves and clothing. The use of protective creams may be beneficial to certain individuals.
Protective creams should be applied before exposure.

Eye Protection: Recommend safety glasses with side shields or chemical goggles to avoid eye contact.

Other protective equipment: Eye wash and safety showers should be readily available.

Hygienic Practices: Wash with soap and water before eating, drinking, smoking, applying cosmetics, or
using toilet facilities. Use of a hand cleaner is recommended. Launder contaminated clothing before
reuse. Leather shoes can absorb and allow hazardous materials to pass through. Check shoes carefully
after soaking before reuse.

Section 9 - Physical And Chemical Properties


Boiling Range: 232F (111C) - 284 F (140 C) Vapor Density: Heavier than Air
Odor: Solvent Odor Threshold: N/D
Appearance: Viscous Liquid, Various Evaporation Rate: Slower Than Ether
Colors
Solubility in H2O: N/D
Freeze Point: N/D Specific Gravity: app. 1.28
Vapor Pressure: N/D PH: N/D
Physical State: Liquid

(See section 16 for abbreviation legend)

Section 10 - Stability And Reactivity

Conditions To Avoid: Heat, sparks and open flames.

Incompatibility: Keep away from strong oxidizing agents, heat and open flames.

Hazardous Decomposition Products: Carbon monoxide, nitrogen oxides, and unidentified organic
compounds. Consider all smoke and fumes from burning material as very hazardous. Welding, cutting or
abrasive grinding can create smoke and fumes. Do not breathe any fumes or smoke from these
operations.

Hazardous Polymerization: Will not occur under normal conditions.

Stability: This product is stable under normal storage conditions.

Section 11 - Toxicological Information

Product LD50: N/D Product LC50: N/D

Chemical Name CAS Number LD50 LC50


TITANIUM DIOXIDE 13463-67-7 >25 G/KG, ORAL, RAT >6.82 MG/L 4 HR, RAT
MICROCRYSTALLINE SILICA 14808-60-7 NOT AVAILABLE NOT AVAILABLE
N-BUTYL ACETATE 123-86-4 7.4 G/KG RABBIT ORAL >1800 PPM/6H INHALATION
TOLUENE 108-88-3 5.0 G/KG RAT ORAL, 14G/KG RABBIT DERMAL 8000 PPM/4HRS, RAT, INHALATION
CARBON BLACK 1333-86-4 NOT AVAILABLE >8000 MG/KG, ORAL, RAT

Page 3 of 6
META-XYLENE 108-38-3 NOT AVAILABLE NOT AVAILABLE
ALIPHATIC DIOL TRADE SECRET NOT AVAILABLE NOT AVAILABLE
LIMESTONE 1317-65-3 NOT AVAILABLE NOT AVAILABLE
ETHOXYPROPIONATE 763-69-9 NOT AVAILABLE NOT AVAILABLE
ETHYL BENZENE 100-41-4 3500 MG/KG RAT,ORAL NOT AVAILABLE
PARA-XYLENE 106-42-3 NOT AVAILABLE NOT AVAILABLE
1-METHOXY-2-PROPANOL 108-65-6 NOT AVAILABLE NOT AVAILABLE
ACETATE
ORTHO-XYLENE 95-47-6 NOT AVAILABLE NOT AVAILABLE
STODDARD SOLVENT 8052-41-3 NOT AVAILABLE NOT AVAILABLE

Section 12 - Ecological Information

Ecological Information: No data

Section 13 - Disposal Information

Disposal Information: Dispose of in accordance with State, Local, and Federal Environmental
regulations. Responsibility for proper waste disposal is with the owner of the waste.

Section 14 - Transportation Information

DOT Proper Shipping Paint Packing Group: II


Name:
DOT Technical Name: N/A Hazard N/A
Subclass:
DOT Hazard Class: 3 Resp. Guide 128
Page:
DOT UN/NA Number: UN 1263

Additional Notes: None.

Section 15 - Regulatory Information

CERCLA - SARA HAZARD CATEGORY

This product has been reviewed according to the EPA Hazard Categories promulgated under Sections
311and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is
considered, under applicable definitions, to meet the following categories:

IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD, FIRE HAZARD

SARA SECTION 313

This product contains the following substances subject to the reporting requirements of Section 313 of
Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:

Chemical Name CAS Number


TOLUENE 108-88-3
META-XYLENE 108-38-3
ETHYL BENZENE 100-41-4
PARA-XYLENE 106-42-3
ORTHO-XYLENE 95-47-6

TOXIC SUBSTANCES CONTROL ACT

All components of this product are listed on the TSCA inventory.

This product contains the following chemical substances subject to the reporting requirements of TSCA
12(B) if exported from the United States:

Chemical Name CAS Number


PARA-XYLENE 106-42-3

Page 4 of 6
U.S. STATE REGULATIONS AS FOLLOWS:

NEW JERSEY RIGHT-TO-KNOW

The following materials are non-hazardous, but are among the top five components in this product.

Chemical Name CAS Number


ACRYLIC COPOLYMER TRADE SECRET
ORGANIC PIGMENT 5567-15-7
ORGANIC PIGMENT 31837-42-0

PENNSYLVANIA RIGHT-TO-KNOW

The following non-hazardous ingredients are present in the product at greater than 3%.

Chemical Name CAS Number


ACRYLIC COPOLYMER TRADE SECRET
ORGANIC PIGMENT 5567-15-7
ORGANIC PIGMENT 31837-42-0
AZO PIGMENT 82199-12-0
YELLOW IRON OXIDE 51274-00-1
IRON OXIDE 1317-60-8
POLYMER NON HAZARDOUS TRADE SECRET
AZO PIGMENT 2786-76-7
RED PIGMENT 84632-65-5
ORANGE PIGMENT 15793-73-4
QUINACRIDONE PIGMENT 1047-16-1
COLOR PIGMENT 1328-53-6
IRON OXIDE 1332-37-2

CALIFORNIA PROPOSITION 65

Warning: The following ingredients present in the product are known to the state of California to
cause Cancer:

Chemical Name CAS Number


MICROCRYSTALLINE SILICA 14808-60-7
CARBON BLACK 1333-86-4
ETHYL BENZENE 100-41-4

Warning: The following ingredients present in the product are known to the state of California to
cause birth defects, or other reproductive hazards:

Chemical Name CAS Number


TOLUENE 108-88-3

INTERNATIONAL REGULATIONS AS FOLLOWS:

CANADIAN WHMIS

This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of
the 16 headings.

CANADIAN WHMIS CLASS: B2 D2A D2B

Section 16 - Other Information

HMIS Ratings
Health: 2 Flammability: 3 Reactivity: 1 Personal Protection: X

VOLATILE ORGANIC COMPOUNDS, GR/LTR MIXED (UNTHINNED): 264

REASON FOR REVISION: Changes made in Section(s): 1, 2, 3, 5, 8, 11, and 15

Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined

The information contained herein is, to the best of our knowledge and belief accurate. However, since the
conditions of handling and use are beyond our control, we make no guarantee of results, and assume no
liability for damages incurred by use of this material. It is the responsibility of the user to comply with all

Page 5 of 6
applicable federal, state, and local laws and regulations

Page 6 of 6
Page 1/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.01.2017 Version number 5 Revision: 10.01.2017

SECTION 1: Identification of the substance/mixture and of the company/


undertaking
· 1.1 Product identifier
· Trade name: Nullifire FS702
· MSDS code: TK-N-FS702
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
· Application of the substance / the mixture Sealant
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
tremco illbruck Dış Ticaret A.Ş.
Ömerli Mah. Yamaç Sok. No: 7 A-Blok Arnavutköy, Istanbul
T: +90 (0) 2126232191, F: +90 (0) 2126232190
info.tr@tremco-illbruck.com
· Further information obtainable from:
tremco illbruck Ltd
Torrington Avenue, Coventry, CV4 9TJ
T: +44 (0) 2476855000, F: +44 (0) 2476469547
www.nullifire.com, protect@nullifire.com
· 1.4 Emergency telephone number:
During office hours tel.: +44 (0) 2476855000. At all other times please contact your national poisoning
centre.

SECTION 2: Hazards identification


· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
The product is not classified according to the CLP regulation.
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008 Void
· Hazard pictograms Void
· Signal word Void
· Hazard statements Void
· Supplemental information:
EUH208 Contains CIT [EC 247-500-7] : MIT [EC 220-239-6] (3:1). May produce an allergic reaction.
EUH210 Safety data sheet available on request.
· Regulation (EC) No 528/2012 on biocidal products Contains a biocidal product: C(M)IT/MIT (3:1)
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

SECTION 3: Composition/information on ingredients


· 3.2 Mixtures
· Description: Mixture of substances listed below with non-hazardous additions.
· Dangerous components: Void
· Additional information: For the wording of the listed hazard phrases refer to section 16.
(Contd. on page 2)
GB

44.0
Page 2/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.01.2017 Version number 5 Revision: 10.01.2017

Trade name: Nullifire FS702

(Contd. of page 1)
· Regulation (EU) No 528/2012 Biocidal Products Regulation
55965-84-9 CIT [EC 247-500-7] : MIT [EC 220-239-6] (3:1) PT6

SECTION 4: First aid measures


· 4.1 Description of first aid measures
· General information: Immediately remove any clothing soiled by the product.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing:
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; call for medical help immediately.
· 4.2 Most important symptoms and effects, both acute and delayed
Sensitising effect by skin contact is possible by prolonged exposure.
· Information for doctor: No further relevant information available.
· Hazards No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures


· 5.1 Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Use fire extinguishing methods suitable to surrounding conditions.
· 5.2 Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
Carbon dioxide
Carbon monoxide (CO)
· 5.3 Advice for firefighters
· Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
· Additional information Cool endangered receptacles with water spray.

SECTION 6: Accidental release measures


· 6.1 Personal precautions, protective equipment and emergency procedures
Wear protective clothing.
· 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
(Contd. on page 3)
GB

44.0
Page 3/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.01.2017 Version number 5 Revision: 10.01.2017

Trade name: Nullifire FS702

(Contd. of page 2)
See Section 13 for disposal information.

SECTION 7: Handling and storage


· 7.1 Precautions for safe handling Avoid contact with the eyes and skin.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Store only in unopened original receptacles.
· Information about storage in one common storage facility: Protect from heat and direct sunlight.
· Further information about storage conditions:
Store in cool, dry conditions in well sealed receptacles.
Storage temperature: +5 °C to +35 °C
· 7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection


· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
· Respiratory protection: Use only in well-ventilated areas.
· Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
· Material of gloves
Rubber gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to
be checked prior to the application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and
has to be observed.
· Eye protection: Safety glasses
(Contd. on page 4)
GB

44.0
Page 4/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.01.2017 Version number 5 Revision: 10.01.2017

Trade name: Nullifire FS702

(Contd. of page 3)
· Body protection: Protective work clothing

* SECTION 9: Physical and chemical properties


· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Pasty
Colour: According to product specification
· Odour: Mild
· pH-value at 20 °C: 8.2 - 9.5
· Initial boiling point and boiling range: >100 °C
· Flash point: >100 °C
· Explosive properties: Product does not present an explosion hazard.
· Density at 20 °C: 1.52 g/cm³
· Solubility in / Miscibility with
water: Fully miscible.
· Solvent content:
VOC (EU) 6.3 g/l
VOC (EC) < 0.5 %
· 9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity


· 10.1 Reactivity Stable
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products: No dangerous decomposition products known.

SECTION 11: Toxicological information


· 11.1 Information on toxicological effects
· Acute toxicity Based on available data, the classification criteria are not met.
· Primary irritant effect:
· Skin corrosion/irritation Slight irritation possible.
· Serious eye damage/irritation Slight irritation possible.
· Respiratory or skin sensitisation May cause allergic skin disorders in sensitive individuals.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
(Contd. on page 5)
GB

44.0
Page 5/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.01.2017 Version number 5 Revision: 10.01.2017

Trade name: Nullifire FS702

(Contd. of page 4)
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information


· 12.1 Toxicity
· Aquatic toxicity: No further relevant information available.
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Ecotoxical effects:
· Other information:
This product contains no substances in Annex I to Directive EC 1005/2009 concerning ozone
depleting substances
· Additional ecological information:
· General notes:
Not known to be hazardous to water.
Recommendation:
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage
system.
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations


· 13.1 Waste treatment methods
· Recommendation Disposal must be made according to official regulations.
· Waste disposal key: UK (WM3) : n/a
· European waste catalogue
08 04 10 waste adhesives and sealants other than those mentioned in 08 04 09
· Uncleaned packaging:
· Recommendation:
Dispose of packaging according to regulations on the disposal of packagings.
Empty contaminated packagings thoroughly. They may be recycled after thorough and proper
cleaning.
Packagings that may not be cleansed are to be disposed of in the same manner as the product.

SECTION 14: Transport information


· 14.1 UN-Number
· ADR, ADN, IMDG, IATA Void
· 14.2 UN proper shipping name
· ADR, ADN, IMDG, IATA Void
(Contd. on page 6)
GB

44.0
Page 6/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.01.2017 Version number 5 Revision: 10.01.2017

Trade name: Nullifire FS702

(Contd. of page 5)
· 14.3 Transport hazard class(es)
· ADR, ADN, IMDG, IATA
· Class Void
· 14.4 Packing group
· ADR, IMDG, IATA Void
· 14.5 Environmental hazards:
· Marine pollutant: No
· 14.6 Special precautions for user Not applicable.
· 14.7 Transport in bulk according to Annex II of
Marpol and the IBC Code Not applicable.
· UN "Model Regulation": Void

* SECTION 15: Regulatory information


· 15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
"CLP" Regulation (EC) No 1272/2008 (OJ L 353, 31.12.2008, p.1).
"REACH" Regulation (EC) No 1907/2006 (OJ L 396, 30.12.2006, p.1, with subsequent amendments).
"BPR" Regulation (EU) No 528/2012 of the European Parliament and of the Council of 22 May 2012
concerning the making available on the market and use of biocidal products.
Regulation (EU) 2016/131 of 1 February 2016 approving C(M)IT/MIT (3:1) as an existing active
substance for use in biocidal products for product-types 2, 4, 6, 11, 12 and 13.
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.
· National regulations:
· Additional classification according to Decree on Hazardous Materials, Annex II:
No further relevant information available.
· Information about limitation of use: No further relevant information available.
· Other regulations, limitations and prohibitive regulations
· Substances of very high concern (SVHC) according to REACH, Article 57 Not applicable.
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information


This information is based on our present knowledge. However, this shall not constitute a guarantee for
any specific product features and shall not establish a legally valid contractual relationship.
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
PBT: Persistent, Bioaccumulative and Toxic
(Contd. on page 7)
GB

44.0
Page 7/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.01.2017 Version number 5 Revision: 10.01.2017

Trade name: Nullifire FS702

(Contd. of page 6)
SVHC: Substances of Very High Concern
vPvB: very Persistent and very Bioaccumulative
· * Data compared to the previous version altered.
GB

44.0
Date Printed: 12/12/2016 Product: 0298S7NL

Safety Data Sheet


prepared to UN GHS Revision 3

1. Identification of the Substance/Mixture and the Company/Undertaking

1.1 Product Identifier 0298S7NL

Product Name: PYROCRETE 241 HY Revision Date: 12/12/2016


Supercedes Date: 06/02/2015
1.2 Relevant identified uses of the Fireproofing Material
substance or mixture and uses
advised against

1.3 Details of the supplier of the safety data sheet

Manufacturer: Carboline Company


2150 Schuetz Road
St. Louis, MO USA 63146

Regulatory / Technical Information:


Contact Carboline Technical Services at
1-800-848-4645

Alotta, Vicki - ehs@stoncor.com


Datasheet Produced by:

1.4 CHEMTREC 1-800-424-9300 (Inside US)


Emergency telephone number: CHEMTREC +1 703 5273887 (Outside US)
HEALTH - Pittsburgh Poison Control 1-412-681-6669

2. Hazard Identification

2.1 Classification of the substance or mixture

Carcinogenicity, category 1A
STOT, single exposure, category 3, RTI
Skin Corrosion, category 1
Skin Sensitizer, category 1

Page 1 / 9
Date Printed: 12/12/2016 Product: 0298S7NL

2.2 Label elements

Symbol(s) of Product

Signal Word
danger

Named Chemicals on Label


CALCIUM OXIDE, SODIUM SILICATE, MICA, MICROCRYSTALLINE SILICA, PORTLAND CEMENT

GHS HAZARD STATEMENTS

Skin Corrosion, category 1 H314-1 Causes severe skin burns and eye damage.
Skin Sensitizer, category 1 H317 May cause an allergic skin reaction.
STOT, single exposure, category 3, RTI H335 May cause respiratory irritation.
Carcinogenicity, category 1A H350-1A May cause cancer.
GHS PRECAUTION PHRASES
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/
face protection.
P284 Wear respiratory protection.
P302+352 IF ON SKIN: Wash with plenty of soap and water.
P303+361+353 IF ON SKIN (or hair): Remove/Take off immediately all
contaminated clothing. Rinse skin with water/shower.
P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a
position comfortable for breathing.
P308+313 IF exposed or concerned: Get medical advice/attention
P333+313 If skin irritation or rash occurs: Get medical advice/attention.
2.3 Other hazards
No Information

Results of PBT and vPvB assessment:


The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.

3. Composition/Information On Ingredients
3.2 Mixtures
Hazardous Ingredients
CAS-No. Chemical Name %
65997-15-1 PORTLAND CEMENT 25-50
12001-26-2 MICA 10-25
93763-70-3 AMORPHOUS SILICATE 2.5-10
1317-65-3 LIMESTONE 2.5-10
7778-18-9 GYPSUM / CALCIUM SULFATE DIHYDRATE 1.0-2.5
1305-78-8 CALCIUM OXIDE 1.0-2.5
1309-48-4 MAGNESIUM OXIDE 1.0-2.5
1344-09-8 SODIUM SILICATE 1.0-2.5
14808-60-7 MICROCRYSTALLINE SILICA 0.1-1.0

Page 2 / 9
Date Printed: 12/12/2016 Product: 0298S7NL

CAS-No. GHS Symbols GHS Hazard Statements M-Factors


65997-15-1 GHS05-GHS07 H315-317-318 0
12001-26-2 GHS07 H319-335 0
93763-70-3 0
1317-65-3 GHS07 H315-319 0
7778-18-9 0
1309-48-4 0
1305-78-8 GHS05-GHS07 H315-318-335 0
1344-09-8 GHS05-GHS07 H290-314-335 0
14808-60-7 GHS08 H350-372 0

Additional Information: The text for GHS Hazard Statements shown above (if any) is given in Section 16.

4. First-aid Measures
4.1 Description of First Aid Measures
AFTER INHALATION: Remove person to fresh air. If signs/symptoms continue, get medical attention.
AFTER SKIN CONTACT: Wash off with soap and plenty of water.
AFTER EYE CONTACT: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
AFTER INGESTION: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. If swallowed, call
a poison control centre or doctor immediately.

4.2 Most important symptoms and effects, both acute and delayed
Irritating to respiratory system. This product contains silica which is classified by IARC as a known human carcinogen (Group
1). Crystalline silica is known to cause silicosis.
4.3 Indication of any immediate medical attention and special treatment needed

No Information

5. Fire-fighting Measures
5.1 Extinguishing Media:
Carbon Dioxide, Dry Chemical, Foam, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: No Information

5.2 Special hazards arising from the substance or mixture


No Information

5.3 Advice for firefighters


The product is not flammable.

6. Accidental Release Measures


6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Sweep up to prevent slipping hazard. Forms slippery/greasy layers with water.
6.2 Environmental precautions

No Information
6.3 Methods and material for containment and cleaning up
No Information
6.4 Reference to other sections

No Information

7. Handling and Storage


7.1 Precautions for safe handling

INSTRUCTIONS FOR SAFE HANDLING : Avoid breathing dust. Do not breathe vapours or spray mist. Wash thoroughly

Page 3 / 9
Date Printed: 12/12/2016 Product: 0298S7NL

after handling. Do not get in eyes, on skin, or on clothing.


PROTECTION AND HYGIENE MEASURES : Handle in accordance with good industrial hygiene and safety practice. Do not
breathe dust. Wash hands before eating, drinking, or smoking.

7.2 Conditions for safe storage, including any incompatibilities

CONDITIONS TO AVOID: Exposure to moisture.


STORAGE CONDITIONS: Keep containers tightly closed in a dry, cool and well-ventilated place.
7.3 Specific end use(s)

No Information

8. Exposure Controls/Personal Protection


8.1 Control parameters
Ingredients with Occupational Exposure Limits
(US)

Name % ACGIH TLV- ACGIH TLV- OSHA PEL- OSHA PEL- OEL Note
TWA STEL TWA CEILING
PORTLAND CEMENT 25-50 10 MG/M3 N/E 5 MG/M3 N/E
MICA 10-25 3 MGM3 N/E 3 MGM3 N/E
AMORPHOUS SILICATE 2.5-10 10 MGM3 NE 5 MGM3 NE
LIMESTONE 2.5-10 N/E N/E 5 MGM3 N/E
GYPSUM / CALCIUM SULFATE DIHYDRATE 1.0-2.5 N/E N/E N/E N/E
CALCIUM OXIDE 1.0-2.5 2 MGM3 N/E 5 MGM3 N/E
MAGNESIUM OXIDE 1.0-2.5 N/E N/E N/E N/E
SODIUM SILICATE 1.0-2.5 N/E N/E N/E N/E
MICROCRYSTALLINE SILICA 0.1-1.0 0.025 MG/M3 N/E 0.1 MG/M3 N/E
(respirable) (respirable)
FURTHER INFORMATION: No Information

8.2 Exposure controls


Personal Protection
RESPIRATORY PROTECTION: Effective dust mask. Use NIOSH approved respiratory protection.
EYE PROTECTION: Safety glasses with side-shields.
HAND PROTECTION: For prolonged or repeated contact use protective gloves.
OTHER PROTECTIVE EQUIPMENT: Ensure that eyewash stations and safety showers are close to the workstation location.
ENGINEERING CONTROLS: Avoid dust accumulation in enclosed space.

9. Physical and Chemical Properties


9.1 Information on basic physical and chemical properties
Appearance: Grey, Speckled Powder

Physical State Solid


Odor Dusty

Odor threshold N/D


pH N/D
Melting point / freezing point (°C) N/D
Boiling point/range (°C) N/A - N/A
Flash Point, (°C) 999
Evaporation rate N/A

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Date Printed: 12/12/2016 Product: 0298S7NL

Flammability (solid, gas) Not determined

Upper/lower flammability or explosive N/A - N/A


limits
Vapour Pressure, mmHg N/D
Vapour density N/A
Relative density Not determined
Solubility in / Miscibility with water N/D
Partition coefficient: n-octanol/water Not determined
Auto-ignition temperature (°C) Not determined
Decomposition temperature (°C) Not determined
Viscosity Unknown
Explosive properties Not determined
Oxidising properties Not determined

9.2 Other information


VOC Content g/l: 0

Specific Gravity (g/cm3) 0.12

10. Stability and Reactivity


10.1 Reactivity
No Information

10.2 Chemical stability


Stable under normal conditions.

10.3 Possibility of hazardous reactions


Hazardous polymerisation does not occur.

10.4 Conditions to avoid


Exposure to moisture.

10.5 Incompatible materials


Strong oxidizing agents.

10.6 Hazardous decomposition products


None known.

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Date Printed: 12/12/2016 Product: 0298S7NL

11. Toxicological Information


11.1 Information on toxicological effects
Acute Toxicity:
Oral LD50: N/D
Inhalation LC50: N/D

Irritation: Unknown

Corrosivity: Unknown

Sensitization: Unknown

Repeated dose toxicity: Unknown

Carcinogenicity: Unknown

Mutagenicity: Unknown

Toxicity for reproduction: Unknown

If no information is available above under Acute Toxicity then the acute effects of this product have not been tested.
Data on individual components are tabulated below:

CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50


65997-15-1 PORTLAND CEMENT Not Available Not Available

12001-26-2 MICA Not Available Not Available

93763-70-3 AMORPHOUS SILICATE Not Available Not Available

1317-65-3 LIMESTONE 6450 mg/kg, oral, rat Not Available Not Available

7778-18-9 GYPSUM / CALCIUM SULFATE DIHYDRATE Not Available Not Available

1309-48-4 MAGNESIUM OXIDE Not Available Not Available

1305-78-8 CALCIUM OXIDE Not Available Not Available

1344-09-8 SODIUM SILICATE Not Available Not Available

14808-60-7 MICROCRYSTALLINE SILICA 22500 mg/kg Not Available Not Available

Additional Information:
Irritating to respiratory system. This product contains silica which is classified by IARC as a known human carcinogen (Group 1).
Crystalline silica is known to cause silicosis.

12. Ecological Information


12.1 Toxicity:

EC50 48hr (Daphnia): Unknown


IC50 72hr (Algae): Unknown

LC50 96hr (fish): Unknown

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Date Printed: 12/12/2016 Product: 0298S7NL

12.2 Persistence and degradability: Unknown

12.3 Bioaccumulative potential: Unknown

12.4 Mobility in soil: Unknown

12.5 Results of PBT and vPvB The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.
assessment:

12.6 Other adverse effects: Unknown

CAS-No. Chemical Name EC50 48hr IC50 72hr LC50 96hr

65997-15-1 PORTLAND CEMENT No information No information No information


12001-26-2 MICA No information No information No information
93763-70-3 AMORPHOUS SILICATE No information No information No information
1317-65-3 LIMESTONE No information No information No information
7778-18-9 GYPSUM / CALCIUM SULFATE DIHYDRATE No information No information No information
1305-78-8 CALCIUM OXIDE No information No information No information
1309-48-4 MAGNESIUM OXIDE No information No information No information
1344-09-8 SODIUM SILICATE No information No information No information
14808-60-7 MICROCRYSTALLINE SILICA No information No information No information

13. Disposal Considerations


13.1 WASTE TREATMENT METHODS: Dispose of in accordance with local regulations.

14. Transport Information


14.1 UN number None
14.2 UN proper shipping name Not Regulated
Technical name N/A
14.3 Transport hazard class(es) None
Subsidiary shipping hazard N/A
14.4 Packing group N/A
14.5 Environmental hazards Unknown
14.6 Special precautions for user Unknown
EmS-No.: N/A

14.7 Transport in bulk according to Annex II Unknown


of MARPOL 73/78 and the IBC code

15. Regulatory Information


15.1 Safety, health and environmental regulations/legislation for the substance or mixture:

U.S. Federal Regulations: As follows -


CERCLA - Sara Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:

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Date Printed: 12/12/2016 Product: 0298S7NL

Chronic Health Hazard


Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS-No.
No Sara 313 components exist in this product.
Toxic Substances Control Act:
All components of this product are either listed on the TSCA Inventory or are exempt.

This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
Chemical Name CAS-No.
No TSCA 12(b) components exist in this product.
U.S. State Regulations: As follows -
New Jersey Right-to-Know:

The following materials are non-hazardous, but are among the top five components in this product.

Chemical Name CAS-No.


ALUMINUM HYDROXIDE 21645-51-2
VERMICULITE 1318-00-9
Pennsylvania Right-To-Know

The following non-hazardous ingredients are present in the product at greater than 3%.

Chemical Name CAS-No.


ALUMINUM HYDROXIDE 21645-51-2
VERMICULITE 1318-00-9
California Proposition 65:
Warning: The following ingredients present in the product are known to the state of California to cause Cancer:

Chemical Name CAS-No.


MICROCRYSTALLINE SILICA 14808-60-7
Warning: The following ingredients present in the product are known to the state of California to cause birth defects, or other
reproductive hazards.

No Proposition 65 Reproductive Toxins exist in this product.

International Regulations: As follows -


* Canadian DSL:

No Information

15.2 Chemical Safety Assessment:


No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

16. Other Information


Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.

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Date Printed: 12/12/2016 Product: 0298S7NL

H318 Causes serious eye damage.


H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H350 May cause cancer.
H372 Causes damage to organs through prolonged or repeated exposure.

Reasons for revision


No Information

The information contained herein is, to the best of our knowledge and belief accurate. However,
since the conditions of handling and use are beyond our control, we make no guarantee of results,
and assume no liability for damages incurred by use of this material. It is the responsibility of
the user to comply with all applicable federal, state, and local laws and regulations.

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