Revision date: 05/05/2015

SAFETY DATA SHEET

BPO Powder Catalyst
According to EC Regulation No 1272/2008 (CLP)

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name BPO Powder Catalyst

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Catalyst.

1.3. Details of the supplier of the safety data sheet

Supplier STIRLING LLOYD POLYCHEM LTD.
UNION BANK, KING STREET,
KNUTSFORD,
CHESHIRE, WA16 6EF.
UNITED KINGDOM
T : +44(0)1565 633111
(Technical/Commercial enquiries)
F : +44(0)1565 633555
sdsadministrator@stirlinglloyd.com

1.4. Emergency telephone number

Emergency telephone For Chemical Emergency (Spill, Leak, Fire, Exposure or Accident) - Call CHEMTREC
(Day/Night) on:- Within USA & Canada : 1-800-424-9300 Outside USA & Canada : +1 703-
527-3887

National emergency telephone CHEMTREC UK +(44)-870-8200418

number

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification
Physical hazards Org. Perox. D - H242

Health hazards Eye Irrit. 2 - H319 Skin Sens. 1 - H317 Repr. 2 - H361fd

Environmental hazards Aquatic Acute 1 - H400 Aquatic Chronic 3 - H412

Classification (67/548/EEC or Xi;R36. R43. O;R7. N;R50/53.

1999/45/EC)

2.2. Label elements

Pictogram

Signal word Danger

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Hazard statements H242 Heating may cause a fire.

H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.
H400 Very toxic to aquatic life.
H412 Harmful to aquatic life with long lasting effects.

Precautionary statements P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P313 Get medical advice/attention.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P410 Protect from sunlight.
P411+P235 Store at temperatures not exceeding °C/°F. Keep cool.
P420 Store away from other materials.
P501a Dispose of contents/container in accordance with local regulations.

Contains DIBENZOYL PEROXIDE, DICYCLOHEXYL PHTHALATE

WHMIS Label Oxidizing Material. Materials Causing Other Toxic Effects. Dangerously Reactive Material.

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

DIBENZOYL PEROXIDE 30-60%

CAS number: 94-36-0 EC number: 202-327-6 REACH registration number: 01-
2119511472-50-XXXX
M factor (Acute) = 10

Classification Classification (67/548/EEC or 1999/45/EC)

Org. Perox. B - H241 E;R3 O;R7 Xi;R36 R43
Eye Irrit. 2 - H319
Skin Sens. 1 - H317
Aquatic Acute 1 - H400

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DICYCLOHEXYL PHTHALATE 30-60%

CAS number: 84-61-7 EC number: 201-545-9 REACH registration number: 01-
2119978223-34-XXXX

Classification Classification (67/548/EEC or 1999/45/EC)

Skin Sens. 1 - H317 -
Repr. 2 - H361fd
Aquatic Chronic 3 - H412

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation Remove affected person from source of contamination. Get medical attention if any discomfort
continues.

Ingestion Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not
enter the lungs. Get medical attention immediately.

Skin contact Remove contaminated clothing. Wash skin thoroughly with soap and water. Get medical
attention promptly if symptoms occur after washing.

Eye contact Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15
minutes and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Extinguish with the following media: Water spray. Foam. Dry chemicals, sand, dolomite etc.

Unsuitable extinguishing Halon.

media

5.2. Special hazards arising from the substance or mixture

Specific hazards Fire or high temperatures create: Toxic gases/vapours/fumes of: Carbon monoxide (CO).
Carbon dioxide (CO2). Benzoic acid. May re-ignite after fire is extinguished. Risk of explosion
if heated. Dust may form explosive mixture with air.

Hazardous combustion Carbon dioxide (CO2). Carbon monoxide (CO). Benzoic Acid & Benzene
products

5.3. Advice for firefighters

Protective actions during Risk of re-ignition after fire has been extinguished. Risk of explosion.
firefighting

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

SECTION 6: Accidental release measures

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6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet.

6.2. Environmental precautions

Environmental precautions Do not discharge into drains or watercourses or onto the ground.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up
Dampen spillage with water. Eliminate all sources of ignition. No smoking, sparks, flames or
other sources of ignition near spillage. Provide adequate ventilation. Use non sparking
handtools and explosion-proof electric equipment. Collect and place in suitable waste disposal
containers and seal securely. Label the containers containing waste and contaminated
materials and remove from the area as soon as possible. Flush contaminated area with plenty
of water. Avoid generation and spreading of dust. Containers with collected spillage must be
properly labelled with correct contents and hazard symbol.

6.4. Reference to other sections

Reference to other sections Collect and dispose of spillage as indicated in Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Keep away from heat, sparks and open flame. Avoid spilling. Avoid contact with skin and
eyes. Avoid handling which leads to dust formation. Use explosion proof electric equipment.
Do not handle broken packages without protective equipment. Persons susceptible to allergic
reactions should not handle this product.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in closed original container at temperatures between 5°C and 25°C.

Storage class Oxidiser storage.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure Controls/personal protection

8.1. Control parameters

Occupational exposure limits
DIBENZOYL PEROXIDE
Long-term exposure limit (8-hour TWA): WEL 5 mg/m³
Short-term exposure limit (15-minute): WEL
DICYCLOHEXYL PHTHALATE
Long-term exposure limit (8-hour TWA): WEL 5 mg/m³
WEL = Workplace Exposure Limit

DNEL Professional - Inhalation; Long term systemic effects: 11.75 mg/m³

Professional - Dermal; Long term systemic effects: 6.6 mg/kg/day

PNEC - Fresh water; 0.000602 mg/l

- Marine water; 0.0000602 mg/l
- STP; 0.35 mg/l
- Sediment (Freshwater); 0.338 mg/kg
- Soil; 0.0758 mg/kg

8.2. Exposure controls

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Protective equipment

Appropriate engineering Use explosion-proof general and local exhaust ventilation.

controls

Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates
eye contact is possible. The following protection should be worn: Chemical splash goggles.

Hand protection Wear protective gloves made of the following material: Neoprene. Nitrile rubber. Polyethylene.
Polyvinyl chloride (PVC). The most suitable glove should be chosen in consultation with the
glove supplier/manufacturer, who can provide information about the breakthrough time of the
glove material.

Other skin and body Wear appropriate clothing to prevent repeated or prolonged skin contact.
protection

Hygiene measures Do not smoke in work area. Promptly remove any clothing that becomes contaminated. Wash
promptly with soap and water if skin becomes contaminated. When using do not eat, drink or
smoke. Wash hands at the end of each work shift and before eating, smoking and using the
toilet.

Respiratory protection Respiratory protection must be used if the airborne contamination exceeds the recommended
occupational exposure limit. Particulate filter, type P2.

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Appearance Dusty powder.

Colour White.

Odour Slight.

Melting point >40°C

Flash point N/A°C

Bulk density 620-650 kg/m³

Solubility(ies) Insoluble in water.

9.2. Other information

Other information Not applicable.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity The following materials may react with the product: Strong reducing agents. Strong alkalis.
Acids. The following materials may react strongly with the product: Strong acids. Strong
alkalis. Organic compounds. Some metals.

10.2. Chemical stability

Stability SADT-(self accelerating decomposition temperature)is the lowest temperature at which self
accelerating decomposition may occur with a substance in the packaging as used in transport.
A dangerous self-accelerating decomposition reaction and, under certain circumstances,
explosion or fire can be caused by decomposition at and above the following temperature.:
55°C. Will decompose at temperatures exceeding 55 °C

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10.3. Possibility of hazardous reactions

Possibility of hazardous Will not polymerise.
reactions

10.4. Conditions to avoid

Conditions to avoid Avoid heat, flames and other sources of ignition.

10.5. Incompatible materials

Materials to avoid Chemically-active metals. Metal oxides. Copper. Acids. Alkalis. Reducing agents.

10.6. Hazardous decomposition products

Hazardous decomposition Benzoic Acid & Benzene
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Toxicological effects No data recorded.

Other health effects

Skin corrosion/irritation
Animal data Slightly irritating.

Skin sensitisation
Skin sensitisation Sensitising.

Inhalation Prolonged inhalation of high concentrations may damage respiratory system.

Ingestion May cause chemical burns in mouth, oesophagus and stomach.

Skin contact May cause sensitisation by skin contact.

Eye contact Irritating to eyes.

Toxicological information on ingredients.

DIBENZOYL PEROXIDE

Other health effects IARC Class 3. NTP Not Listed.

Acute toxicity - oral

Acute toxicity oral (LD₅₀ 5,000.0

mg/kg)

Species Rat

Acute toxicity - inhalation

Acute toxicity inhalation 24.3

(LC₅₀ dust/mist mg/l)

Species Rat

ATE inhalation 24.3

(dusts/mists mg/l)

Skin corrosion/irritation

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Animal data on the skin: rabbit - weak irritant

Serious eye damage/irritation

Serious eye Irritating to eyes.

damage/irritation

Skin sensitisation

Skin sensitisation Epidemiological studies have shown evidence of skin sensitisation.

SECTION 12: Ecological Information

12.1. Toxicity
Toxicity Toxic to aquatic organisms.

Acute toxicity - fish LC₅₀, 96 hours: 0.06 mg/l, Fish

Acute toxicity - aquatic EC₅₀, 48 hours: 0.11 mg/l, Daphnia magna

invertebrates

12.2. Persistence and degradability

Persistence and degradability The product is biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential BCF: 66.6,

12.4. Mobility in soil

Mobility The product is partly miscible with water and may spread in the aquatic environment.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This substance is not classified as PBT or vPvB according to current EU criteria.
assessment

12.6. Other adverse effects

Other adverse effects Not determined.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information Waste is classified as hazardous waste. Dispose of waste to licensed waste disposal site in
accordance with the requirements of the local Waste Disposal Authority.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 3106

UN No. (IMDG) 3106

UN No. (ICAO) 3106

14.2. UN proper shipping name

Proper shipping name ORGANIC PEROXIDE TYPE D, SOLID (CONTAINS DIBENZOYL PEROXIDE)
(ADR/RID)

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Proper shipping name ORGANIC PEROXIDE TYPE D, SOLID (CONTAINS DIBENZOYL PEROXIDE)
(IMDG)

Proper shipping name (ICAO) ORGANIC PEROXIDE TYPE D, SOLID (CONTAINS DIBENZOYL PEROXIDE)

Proper shipping name (ADN) ORGANIC PEROXIDE TYPE D, SOLID (CONTAINS DIBENZOYL PEROXIDE)

14.3. Transport hazard class(es)

ADR/RID class 5.2

ADR/RID subsidiary risk

ADR/RID label 5.2

IMDG class 5.2

IMDG subsidiary risk

ICAO class/division 5.2

ICAO subsidiary risk

Transport labels

14.4. Packing group

Not applicable.

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

14.6. Special precautions for user

EmS F-J, S-R

Emergency Action Code 1WE

Tunnel restriction code (D)

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations Control of Substances Hazardous to Health Regulations 2002 (as amended).
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (SI 2009
No. 716).

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EU legislation Dangerous Substances Directive 67/548/EEC.

Dangerous Preparations Directive 1999/45/EC.
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).

Guidance CHIP for everyone HSG228.

Workplace Exposure Limits EH40.
Approved Classification and Labelling Guide (Sixth edition) L131.
Safety Data Sheets for Substances and Preparations.

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

General information
This product is intended for use for the application set out in the technical data sheet only.
The Risk Phrases shown below relate to the individual components in Section 3 and NOT to
the Product.
The Risk Phrases for the Product are shown in Section 2.
.

Revision comments Change from previous version concerns: Revised to Comply with Regulation (EC)
No.1907/2006 Annex II

Revision date 05/05/2015

SDS number 10091

Risk phrases in full R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.

Hazard statements in full H241 Heating may cause a fire or explosion.

H242 Heating may cause a fire.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.
H400 Very toxic to aquatic life.
H412 Harmful to aquatic life with long lasting effects.

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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