Solution of DPP # 5

TARGET : JEE (ADVANCED) 2015

Course : VIJETA & VIJAY (ADP & ADR)
CHEMISTRY

2. F2 + HCl  HF + Cl2 ; Cl2 is greenish yellow gas.

( X) (Y)

2Cl2 + 3(a(OH)2  Ca(OCl)2. Ca(OH)2 .CaCl2.2H2O

(Y) ( Z)

Z is bleaching powder it turns red litmus paper to white.

1
3. (B) H2SO4 + PbO2  PbSO4  + O + H2O (PbO2 is not peroxy compound) (PbO2 ijkWDlh ;kSfxd ugha gS)
2 2

H2SO4 + BaO2  BaSO4  + H2O2

+ H2 O 2

Electrolysis
(NH4)2SO4 2NH 4 + SO 24 – ; At anode : 2SO24 –  S2O82 – + 2e–
Peroxo sulphate on hydrolysis, produces H2O2.

F5  + HIO3

4._ (A )
+ H2O  HF
(P ) (Q)

HF is used in etching of glass

HIO3 I2 O 5
(Q) (R )

I2 O 5
(R )
+ CO  I2 + CO2

5. (D) Aqueous solution of SO2 acts as a reducing agent

SO2 + 2H2O  H2SO4 + 2H
nascent hydrogen
Thus, SO2 in presence of moisture is used as bleaching agent. This is due to the reducing nature of SO2.
For delicate articles
Coloured matter + H  Colourless matter
Similarly, CI2 acts as bleaching agent in presence of moisture
CI2 + H2O  2HCI + [O]
Coloured matter + [O]  Colourless matter

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6. (b) XeF4 + SbF5  [XeF3]+ [SbF6]–  [XeF3]+ + [SbF6]–
sp3 d sp3 d2
bent T -shape octahedral

9. (B) 6CI2 + 2Ba(OH)2  Ba(CIO3)2 + 5BaCI2 + 6H2O

(X)
Ba(CIO3)2 + H2SO4  2HCIO3 + BaSO4 
(Y)

 2CIO + H O + 1 O

2HCIO3 
  365 K 2 2 2 2

11. (I) Ni + 4CO 50 º C [Ni(CO)4] 230 º C Ni + 4CO 

   
(impure) (volatile) (pure)
3
(II) Cu2S + O 
 Cu2O + SO2
2 2
high
Cu2S + 2Cu2O   6Cu + SO2
temp .

electrolys is
(III) MgCl2 (s)    Mg2+ () + 2Cl– ()

At Cathode : Mg2+ + 2e–  Mg ; At anode : 2Cl– ()  Cl2 (g) + 2e–


12. (i) Cr2O3 + 2Al (R.A.)  Al2O3 + 2Cr ; H = –ve
(ii) Mg is extracted by electrolysis of fused MgCl2 and NaCl.
3
(iii) PbS + O  PbO + SO2 ; PbO + C  Pb + CO
2 2
(iv) Red Bauxite is purified by Baeyer’s process.

13._ MgCl2 + Na2CO3  MgCO3 + NaCl

Ca(HCO3)2 + Na2CO3  CaCO3 + 2NaHCO3
H2SO4 + Na2CO3  Na2SO4 + H2O + CO2
Na2CO3 + H2O + CO2  2NaHCO3

14. For 2C(s) + O (g)  2CO(g)

2
S = +ve, slope is –ve

15. Na2B4O7.10H2O + aq 4H3BO3 + 2NaOH; H3BO3 + OH– B(OH)4–

+ B(OH)4– +  + 2H2O

 Optically resolvable due to asymmetric structure

 Two six membered rings.

16. NH3(excess) + Cl2  NH4Cl + N2

NH3 + Cl2(excess)  NCl3 + HCl

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17. SO2 + PCl5  SOCl2 + POCl3
No change in oxidation number of any element. So, not a redox reaction.
SOCl2 is thionylchloride; SO2Cl2 is sulphuryl chloride.

POCl3 + H2O  H3PO4 + HCl  strongly acidic solutions




SOCl2 + H2O  H2SO3 + HCl


SO2
Both the products have sp3 hybridisation of central atom.

20. 2AI + 2NaOH + 2H2O  2NaAIO2 + 3H2 

Zn + 2NaOH  Na2ZnO2 + H2 
sod. zincate
4S + 6NaOH  2Na2S + Na2S2O3 + 3H2O
P4 + 3NaOH + 3H2O  3NaH2PO2 + PH3 
sod. hypophosphite
CI2 + 2NaOH  NaCIO + H2O

H O on
P2O3 2 H3PO3 
 PH3   H3PO4
24. cold heating
(A ) (C) (D)
220 C 320 C further
H3PO4    H4P2O7    HPO3   P2O5
strong heating

25. BeCl2 + 2H2O  Be (OH)2 + 2HCl

Be(OH)2 + 2H2O Be(OH)4 2– + 2H+

BeCl2 + 4H2O Be(OH)4 2– + 2HCl + 2H+

26. SF4 + H2O  H2SO3 + HF ; TeF6 + H2O  Te(OH)6 + HF

28. P + conc. H2SO4  HCl(g) (X)

(some chloride)
HCl (g) + NH3 (g)  NH4Cl (s) (white fumes) ; P + AgNO3  AgCl  (white)
AgCl¯ + NH3(aq)  [Ag(NH3)2]Cl(aq)
CuCl2
HCl + O2   Cl2 + H2O()
 ; H2O + Cl2 + Na2S2O3  NaHSO4 + NaCl

31. Ca2B6O11 + 2Na2CO3  2CaCO3 + Na2B4O7 + 2NaBO2

(Calemanite) (Z)
Na2B4O7 + H2SO4  H3BO3 + Na2SO4
H3BO3 
 B2O3 + H2O
(C)
B2O3 + Mg  MgO + B
Cl2 + B2O3 + C  BCl3 + CO
(E) (F)
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32. Conc.H2SO4, anhyd. CaCl2, CaO and P2O5

33. By product is CaCl2 , x = CaCO3 , y = CO2.

CaCl2 + Na2CO3  CaCO3 + 2NaCl

34. XeF2 is a strong oxidising agent with SRP = +2.64.

XeF2 + Cl–  Cl2 + Xe
Br–  Br2
–  I2
XeF2 + NH3  N2 + NH4F + Xe
XeF2 + CrF2  CrF3 + Xe
Pt + XeF2  PtF6 + Xe
S8 + XeF2  SF6 + Xe

35. KO3, RbO2, Cs2O2, BaO2

 
38. H2C2O4  H2O + CO + CO2 H3PO2  H3PO4 + PH3
 
H3PO3  H3PO4 + PH3 HClO  HClO3 + HCl
 
HNO2  HNO3 + NO + H2O H2SO3  H2O + SO2
 
H2SO4  No reaction HClO3  HClO4 + Cl2

39. Except HCl, HBr, HI, HCN, HF it will react with all other compounds, replacing OH–group by Cl–group.

41. x = Na2PbO2 y = Na2SnO3 z = NaAlO2

 1
43. (A) NaNO3  NaNO2 + O
2 2

(B) K + O2 (excess)  KO2

(C) 2Na + O2 (excess)  Na2O2

(D) K (dissolved in liquid NH3)  paramagnetic solution

 
44. NH4ClO4  N2 + Cl2 + O2 + H2O (NH4)2CO3  NH3 + CO2 + H2O
 
(NH4)2Cr2O7  N2 + Cr2O7(s) + H2O Mg (NH4)PO4  Mg2P2O7 + NH3 + H2O

45. (A) BF3 can not get oxidised, but being acidic dissolves in KOH, changes color of litmus and is colourless
gas.
(B) HCl gets oxidised to Cl2 by KMnO4 and being acidic, dissolves in aqueous KOH and change color of
litmus from blue to red. It is colorless gas.
(C) SO2 gets oxidised to SO 24– by KMnO4, and being acidic dissolves significantly in aqueous KOH. It
changes color of litmus from blue to red and it is colorless gas.
(D) F2 does not get oxidised by KMnO4 and dissolves in KOH, to form O2 and KF. It bleaches litmus solution.
It is yellow colour gas.

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