CONFIDENTIAL, AS/JUN 2018/CHM131/160 a) es UNIVERSITI TEKNOLOGI MARA FINAL EXAMINATION COURSE GENERAL CHEMISTRY/PRINCIPLES OF GENERAL CHEMISTRY COURSE CODE (CHM131/160 JUNE 2018 2 HOURS INSTRUCTIONS TO CANDIDATES 1 This question paper consists of two (2) parts: PART A (10 Questions) PART B (10 Questions) 2, ‘Answer ALL questions from all two (2) parts i) Answer PART A in the Objective Answer Sheet. ji) Answer PART B in the Answer Booklet. Start each answer on a new page. Do not bring any material into the examination room unless permission is given by the invigilator. 4, Please check to make sure that this examination pack consists of i) the Question Paper ii) aone- page Appendix ili) an Answer Booklet ~ provided by the Faculty iv) an Objective Answer Sheet ~ provided by the Faculty 5 ‘Answer ALL questions in English. DO NOT TURN THIS PAGE UNTIL YOU ARE TOLD TO D0 SO This examination paper consists of 7 printed pages (© Hak Cipta Universiti Teknologi MARA CONFIDENTIALCONFIDENTIAL, 2 ASIJUN 2018/CHM131/160 PARTA 1 Identify the similarity between the atoms of Co and ®Co. A. Same number of neutrons and electrons. B. Same mass number. C. Same number of protons and electrons. D. Same number of neutrons and ions. 2, Find the quantity that does not represent 1.00 mol of the indicated substance. 6.02 x 10” C atoms 26.0gFe 12.01gC 65.49 Zn pop> 3. __ Indicate the number of orbitals in the n = 2 shell pom> RON 4. Analkaline earth metal, X, reacts with a halogen, Q. State the formula of the resulting ‘compound. A XQ2 B. XQ C. XQ D. XQ Magnesium forms a monatomic ion which has the electronic configuration of a noble gas. Identify the electron configuration of that noble gas. A. 18%2p% B. 18°2s?2p® C. 1828?2p°3s" D. 18?2s?2p%3s (© Hak Cipta Universiti Teknologi MARA CONFIDENTIALCONFIDENTIAL, 3 ASIJUN 2018/CHM131/160 10, Select the type of intramolecular forces that exist between the nitrogen (N) atom in the nitrogen molecule, Ne. A. Asingle covalent bond B. Adouble covalent bond C. A triple covalent bond D. Aan der Waals forces Name the geometry of CIF: molecule using VSEPR model A. Bent B. Trigonal planar C. T-shaped D. _Trigonal pyramidal Select the reaction that involves the reduction process. 2H'"(aq) + COs*(aq) + H20(I) + CO2g) CrO.*(aq) > Cr*(aq) Ba*(aq) + CrO,*(aq) > BaCrO«(s) Mn02(s) > MnO,(aq) gom> Consider this reaction: 2CO2g) = 2CO(g) + 02(g). The equilibrium constant, Ke value for this reaction is 26.2 at 827°C. Find the value of Kp at that temperature. A 290x107 B. 3.86 x 10" C. 1.78x 10° D. 237% 10° Identify the FALSE statement about chemical equilibrium. ‘A. At equilibrium, the reactant and the product concentrations show no further change with time. B. Chemical equilibrium can only be attained by starting with reagents from the reactant side of the equation C. At equilibrium, the forward reaction rate equals the reverse reaction rate. D. At equilibrium, the reactant and product concentrations are constant. @ Hak Cipta Universiti Teknologi MARA CONFIDENTIALCONFIDENTIAL 4 ASIJUN 2018/CHM131/160 PARTB QUESTION 1 a) State the name or chemical formula for each of the following compounds. HlO2 Tin (ll) fluoride (2 marks) b) Elemental analysis of butanedione gave the following mass percent composition, 55.80% C, 7.03% H and the remainder is oxygen. Determine the empirical formula of butanedione. (3 marks) QUESTION 2 The following information is given AloSs + 6H2O — 2AI(OH)s + 3H:S IF 15.0 g of AlSs reacts with 10.0 g of H.0. a) Determine the limiting reactant. (3 marks) b) Find the mass of H2S produced (2 marks) QUESTION 3 a) Predict the arrangement of Si, K, Cl, and S according to these three (3) trends: Decreasing atomic radius Increasing electronegativity Decreasing electron affinity (3 marks) b) Given the symbol of an atom is 22X. Illustrate the orbital diagram of atom X and determine the set of quantum numbers (n, |, ms, ms) for the unpaired electron in this atom, (2 marks) (© Hak Cipta Universiti Teknologi MARA CONFIDENTIALCONFIDENTIAL 5 ASIJUN 2018/CHM131/160 QUESTION 4 a) Suggest the electron configuration for: Chromium atom Nitride ion (2 marks) b) Predict the molecular geometry of the following molecules, based on VSEPR theory. Given xenon (Xe) belongs to group 18 in the periodic table. SFe XeFs BeCh (3 marks) QUESTION 5 a) Identify the type of intermolecular forces that exists between the following molecules: CoH2 NH3 (2 marks) b) Using Lewis dot symbol, illustrate the formation of ionic bond between magnesium atom and bromine atom. (3 marks) QUESTION 6 Consider the chemical equation of the following redox reaction: Cr(OH)s + Bra > CrO.? + Br a) Identify the oxidizing and reducing agent for the above reaction. (2 marks) b) Express a balanced redox equation using the ion-electron method in acidic solution. (3 marks) (© Hak Cipta Universiti Teknologi MARA, CONFIDENTIALCONFIDENTIAL 6 ASIJUN 2018/CHM131/160 QUESTION 7 a) Indicate the oxidation number of the underlined elements. Naoc! cro? (2 marks) b) Carbon dioxide, (CO.) is a colourless gas with a faint, sharp odour and a sour taste. In an experiment, 4.56 g of solid CO; was put in an empty and sealed 4.00 L container at a temperature of 27°C. Find the pressure in the container, when all the solid CO2 becomes gas. (3 marks) QUESTION 8 a) An unknown gas Y effuses 1.79 times faster than CaHs. Identify the molecular mass of gas (2 marks) b)_A mixture of oxygen (02) and nitrogen (N2) is prepared in which there are 0.20 mol O2 and 0.50 mol No. If the total pressure of the mixture is 745 torr, find the partial pressure of the 2.gases in the mixture. (3 marks) QUESTION 9 a) Express the equilibrium constant expression, K. for each of the following reactions: Ni(s) + 4CO(Q) = Ni(CO).(g) 2802(g) + O2(g) = 2SO3(g) (2 marks) b) The reaction of solid calcium carbonate will produce calcium oxide in a solid form and carbon dioxide gas. At equilibrium, the pressure of the reacting mixture is 0.105 atm at 350°C. Express the balanced equation and find the value of Kp and Ke for this reaction, (3 marks) (© Hak Cipta Universiti Teknologi MARA CONFIDENTIAL,CONFIDENTIAL 7 ASIJUN 2018/CHM131/160 QUESTION 10 . a) The following information is given: 2NO(g) + Ch(g) = 2NOCI(g) Ke 5 x 104 at 35°C In a certain experiment, 2.0 x 10 mol of NO, 8.3 x 10 mol of Clz and 6.8 mol of NOCI are mixed in a 2.0 L flask. Suggest the direction in which reaction will occur to reach equilibrium, (3 marks) b) Predict the direction of equilibrium if i, NO() is removed from the system ji, The volume of the system is increasing at constant temperature (2 marks) END OF QUESTION PAPER (© Hak Cipta Universiti Teknologi MARA CONFIDENTIALCONFIDENTIAL, APPENDIX ASIJUN 2018/CHM131/160 TABLE OF ATOMIC NUMBER AND RELATIVE ATOMIC MASS oe Element ‘Symbol Relative Atomic Mass 1 Hydrogen: —_H 1.0 2 _ Helium. He 4.0 3 Lithium Li 69 4 ~ Beryllium Be 3.0 5 Boron B 1.0 | _6 Carbon Cc 42.0 7 Nitrogen N 14.0 _8 ‘Oxygen 0 76.0 9 Fluorine F 79.0 10" Neon _ 20.0 4 Sodium | 23.0 12 Magnesium oo Pal 13 ____ Aluminum Al 27.0 14 Silicon Si 28.0 15 Phosphorus P 310 aC Sulphur Ss 32.0 7 Chiorine cl 35.5 18 Argon Ar 40.0 19 _____ Potassium K 39.0 20 Calcium Ca ao 21 Scandium Sc 45.0 22 Titanium: Ti 48.0 23 ‘Vanadium V. 510 24 Chromium - Cr 52.0 25 Manganese Mn 55.0 Iron ___Fe 558 Nickel Ni 58.7 Copper Cu 63.5 Zinc Zn 65.4 Bromine Br 79.9 Todine 1 127.0 Xenon Xe 131.3 Gold Au 197.0 Lead Pb 207.0 Constants Rydberg Constant, Ru = 1.097 x 10” m* or 2.18 x 10" J ‘Speed of Light, ¢ = 3.00 x 10°ms"* Planck Constant, h = 6.63 x 10% Js Avogadro's Number, Na = 6.02 x 10 mol" Gas Constant, R = 0.0821 L atm mol" K7 (© Hak Cipta Universiti Teknologi MARA CONFIDENTIAL,