as Resonence Educating for better tomorrow TARGET : JEE (Main + Advanced) 2017 Course : VIKAAS (JA) This DPP is to be discussed in the week (30.11.2015 to 05.12.2015) DPP No. # 44 (JEE-ADVANCED) Total Marks : 71 Max. Time : 43 min. Single choice Objective ('-1' negative marking) Q.1 to Q.6 (3 marks, 2 min.) (18, 12) Multiple choice objective ('-1" negative marking) Q.7 to Q.9 (4 marks, 2 min.) [12, 06) ‘Comprehension ('-1" negative marking) Q.10 to Q.12 (3 marks, 2 min.) 09, 06) Integer type Questions (‘-1" negative marking) Q.13, (4 marks 3 min.) [04, 03] Match the Following (no negative marking) Q.14 (8 marks, 6 min.) 08, 06) ‘ChemINFO : 5 Questions (-1' negative marking) 2.15 to.Q.19 (4 marks, 2 min.) {[20, 10] ANSWER KEY DPP No. # 44 (JEE-ADVANCED) i Goth =) = Go) = Ge he (ee tee Cian) 8. (ABD) 9. @D 1. @ 1. @ 12 @& 43, (i) Na,S+ 4Na,0, ——+ Na,SO, + 4Na,0, MnSO,+ 2Na,O, ——>Na,MnO,+Na,SO, (iii) 2NaOH + 2NO, ——> NaNO,+NaNO,+H,O —_(iv)6NaOH+3Br, ——> 5NaBr+ NaBrO,, + 3H,O (v) NaOH +48 ——> 2Na,S + Na,S,0, + 3H,0. (vi) 4NaOH + 2F, ——> 4NaF + 0, +'2H,0. (vii) PbO + 2NaOH — Na,PbO,+H,0 (viii) Form insoluble hydroxides CrCl, + NaOH ——> Cr(OH), { (Green) + 3NaCl. (ix) HgCl, + 2NaOH ——> Hg(OH), | +2NaCl ; Hg(OH), ——> HgO | (yellow or brown) + H,0. 180-200" (x) NaH + CO S55, > HCOONa. 14. (A-p); 6-45.) (C-);O-an 15. © 16. © 17. ® 18. © 2 © 4. Which ofthe following statements are true about the alkali metals ? (1) All alkali-metal salts impart a characteristic colour to the Bunsen flame. (2) The correct order of increasing thermal stability of the carbonates of alkali metalsis Li,CO, NaH > KH > RbH > CsH. (9 (1), @)and @) ©) (1),@and(4) (©) @),@)and@) (0) (1), @), @)and 4) arta angst & fry Presta a atera wert aa 8 ? () A arta argst } sau, FI SET a Uw aT FAT BATE Qpantra angst & waite & endha wafea or aE wea BSH HH Li,CO, NaH > KH > RbH > CsH®| (A*) (1), (2) ae (3) (8) (1), (3) ae @) (C) (2), (3) sem (4) (O) (1), (2), (3) sem 4) Hint: (4) Reducing nature increases down the group as their stability decreases down the group CsH > RbH > KH > NaH > LiH (4) ef 8 48 or oe svar wepft zach 8 aif af A Aa GP oe gear eenfaea wea 8 CsH > RbH > KH > NaH > LiH D Resonance nalawar Road, Kola (Raj) 324005 Educating for better tomorrowSol. Sol. Sol. HCI is added to following oxides. Which one would give H.0.? (ayMno, (@)Pb0, (C*)Ba0,8H,0 Hola} fr 9 a ats stages A Pert WH,O, re ele 8 2 (@aMno, (®)PbO, (C*)Ba0, 8,0 BaO,.8H.O + 2HCl —> BaCl, + H,0, + 8H,0 : Plaster of paris is a hemihydrate of calcium sulphate obtained by heating the gypsum above 393 K. Sodium carbonate is used in water softening, : The order of mobilities of the alkali’ metal ions in aqueous solutions is Lit > Na‘ > K* > Rb'> Cs" + force 1 393K & coe anf are wy Sere eee ar Seheress ret ear 8, Ge caNey aw Aer we Ss, Ss, Ss, 8, a 8,288 areiie a ordi, oat ah ge ae A Pa one S,: ciefta foray 4 atta eng sas wl afeteftera @T WA Lit > Na* > Kt > Rb*> Cs* 2) (A)TTF (TTT (C) FTF (O)FFF 8, 1(2CaSO,2H,0) 5 2 (CaSO). H,0 + 3H, above 393 K dead bumt plasteris obtained $,:Ca*+Na,CO, —+ Caco, | +2Na* S.:Li cad + ‘CO, (Basic) (Acidic) (erty @rttey Resonance fara ames 26 toner a6 ‘Hoar City Mal, Jhalawar Roed, Kola (Raj) 224005 gusting fr bets to morro | WH vw eeonan oT | Ema = SorieT@rosoaTo Th a Fre £0 POD ZS [ DD DE SESE] CO USSSA OOTP TOOEOES6. An inorganic compound (X) which produces brick red coloration as flame when (X) dissolves in water. produces alkaline solution and a combustible gas (Y). (X) and (Y) are respectively. ee wd Tew OK) caren A e Seay aot Sr Tears Hee & | aX) BY ore} Pa Moar sae a 2) aa ferorert ce qa cert frat He (¥) ae B | OK) Te (Y) wT B | (A) CaO, Op (8) CagNz, NHg (©)CaCOg, Cop (0) Cay, Hy Sol. Calg +H20 —_, Ca(OH), +H, 7. Select correct matching. (a) Hydrolith = CaH, (@*) Bleaching powder= CaCl, Ca(OC)), et ee ret Pray are — (as) etegifere = CaH, (B*) favoie aI = Cacl,.ca(Och, (C) wae Zar = MgSO, 7H,O (0) TREX site HiT = Caso, ; Ho 8. Which of the following is/are correct? (4°) lonization energy =Ca>K (8*) Melting point = Ca > K (©) Stability = MgCO, K* fre 8 8 ere /ars wel 8/8 2 (a) srr wat = Ca> Kk (ey wate = Ca>k (C*) waft = MgcO, Ans. Na,S+ 4Na,0, > Na,SO, + 4Na,0. (i) Mn80,+Na,0, —> Ans. MnSO,+2Na,0, ——» Na,MnO,+ Na,SO, (i) NaOH +NO, —> Ans. 2Na0H+2NO, —> NaNO,+ NaNO, *H,O (iv) NaOH (hot & cone.) (74 «et ire) + Br, ——> Ans. 6NaQH+3Br, ——> 5NaBr + NaBrO, + 3H,O. () NaQH+S —> Ans. 6Na0H+4S ——> 2Na,S +Na,S,0, + 3H,0. (vi) NaOH (hot & cone.) (ri ae ArH) +F, —> ‘Ans. 4NaOH + 2F, ——> 4NaF +O, + 2H,O. (ii) PbO+NaoH —> Ans. PbO+2NaOH ——>Na,PbO,+H,0 (viii) crcl, + Nao —> Ans. Form insoluble hydroxides. swyerftt CrOl, + NaOH —> Cr(OH), | (Green) + 3NaCl (e)—HgCl, #NaoH —> ‘Ans. HgCl, + 2NaOH —> Hg(OH), | + 2NaCl Hg(OH), —> Hg0 | (yellow or brown) + H,0. 150-200%¢ () NaOH + co “SS 150-2004 Ans. NaQH+CO —=a2 > HCOONa. 14. Match the compounds listed in column-I with the characteristic(s) listed in column Column Column (A) BeO(s) (p)Amphoteric in nature (®) NaHCO, (crystalline) (q) Imparts characteristic colour to Bunsen flame. (©) BeCl,6) (0 Produce H.O, and O, on reaction with water. 0)Cs0,8) (6) Show hydrogen bonding (®) Has a chain structure era 1 FRA ART a TAT AA eT} er GARR PPA | wal wa ll (A) BeO(s) (p) Senn ght (©) NaHco, (rea (q) FFs care A rover eo zara | (©) Bec) (0 574 & eet sfhiPeaT wH,O, a0, 28 8 | (0)Cs0,6) (© eggior du cua 8 () sere weer wee Ans. (A-p);(8-4.5,0 ;(C-9 0-4.) Sol. (A) BeO is amphoteric in nature becuase it reacts with acid as well as base. Resonance fara ames 26 toner a6 ‘Hoar City Mal, Jhalawar Roed, Kola (Raj) 224005 gusting fr bets to morro | WH vw eeonan oT | Ema = SorieT@rosoaTo Th a Fre £0 POD ZS [ DD DE SESE] CO USSSA OOTP TOOEOES(B) Hydrogen bonding ; HCO. ions are linked into an infinite chain through H-bonding, © Ne Ne Ne ON “Na Sa Sai (0) 2CsO, + 2H,O ___, 20s" # 20H +H,0, + 0, (A) BeO sre maf a Se & a ae om ere AY aM BET RPT eT 8 | (©) wegtor da | HCO, ore Heda ara oe: yeiot H ge ae cl cl cl Ne NB N07 SN © Ng NG NG (D) 2Cs0, + 2H,O __, 2Cs*+ 20H" +H,0, +0, & emINFO-7.1 HYDROGEN Daily Self-Study Dosage for mastering Chemistry Preparation of H, "There are three main sources from which hydrogen may be prepared. These are () Water (i Acids (©)Alkaiines (i) Hydrogen from water : (@) Cold water react with alkali and alkaline earth matals to evolve hydrogen 2Na~ (Hg) + 2H,0 —> 2NaOH +H, 7 Sodium amalgam Note : The reaction are vigorous to minimum the rate of reaction, alkali metals are used in the form of amalgam (b) Hot water or steam, when passed over metals like Zn, Fe, Mn, Co, Cr, Sn etc is decompose to librate hydrogen. Zn+H.0 ——> ZnO+H,? Note: When steam, when passed over hot coke, hydrogen is produced in the form of water gas, C+HO —> H,+C0 Steam water gas () Hydrogen from Acid : [Many reactive metals such as alkali metals, alkaline earth metals, Zn, Mg, Fe etc. react with dil HCI or dl H,SO, to evohe: hydrogen, Mg +2HCI ——» Mgcl, + Ht Note : Mn and Mg react with cl HINO, to evolve hydrogen. t) Hydrogen from alkali: Zn, Al, Sn, Pb, Si (Amphoteric metals) reacts with boling NaOH or KOH to evolve hydrogen Zn+2NaOH ——» Na,zn0, +H, ‘Sodium Zincate Sn + 2NaOH + H0 ——> Na,Sn0, + 2H, t Sodium stannate [Memorize this theory as Soon as you get the DPP, Revise lt regularly and master this concept by practice D Resonance fara ames 26 toner a6 ‘Hoar City Mal, Jhalawar Roed, Kola (Raj) 224005 DISGLTS far Detar omar MEPRTS Fv resonance aon | Ema coracgvesmrance aT [DD PSE SESE] CH SORTA OOTP TOURS48. Which of the following metal give H. afterreac- 4g peat Which of the following metal gives H, gas after reaction with acid as well as alkali oni ee (acu (8)Na ge ort (zn (Fe 46. Metals on reaction with water or dilute mineral acids can give 49. Which of the following metal does not give H, ()Monotydrogen —@)O, after reaction with dil H,SO, (C’) Dihydrogen (0) Tritium: (A) Mg (B)Fe (zn (@ycu 47. Water gas is (A)CO+N, (8) CO+H, (©)CO, +H, (CO, +N, & hemINFO-7.1 HYDROGEN Daily Sel-Study Dosage for mastering Chemistry Preparation of H, raat cia got Gata & fara wegiors arta on word = ag & (i) oe Gi) Fa (Cyan (i) Set erggrora wet wT + (2) S01 ay ane cen ania Be TGA ener ar aT er Prev wee B 2Na~ (Hg) +2H,O —> 2NaOH +H, t ates afitiran dha ae & ste atten ah ae wT am coy a ry arta age ome wr A maT ere e (0) 24 ici 1 ara 3} Gia arg BR Zn, Fe, Mn, Co, Cr, Sr Zena ae vant we & ch ae fue eae eestor Freee oer @ Zn+H,0 —> Zn0+H,t fate sora ara wh al ar oR saree et &, ch REI Te eS wT A eT ate 8 C+HO—> H,+c0 a a te (ar @ erggtora sted eT : entra erg, entta yar arg , Zn, Mg Fe scat & cart oft farts ange ay HOLM ay H,S0,3 Te frat oe ergs Preartarr wet @] Mg + 2HCl_—> Mooi, +H, te = Mn den Moar HNO, @ ser rar aed anggtory Fret ae | (nant 8 estos ar wet: 2n,Al, Sn, Pb, Si (rR are Seer BE NOH a KOH sre HT 3 Zn + 2NeOH ——» Nazno, + H,7 fea fide Sn + 2NaOH + HO ——> Na,Sn0, + 2H, 7 afin he [Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice. 15.0 PHAM aM ago oa + ae afte S17, Ue Hee. Wea H, eft & ? (A)CO#N, (8) CO+H, (ACu ~ (B)Ag (C)CO,+H, (0)CO, +N, ek ort 18,0 RA a ahaha ora} wer eres aA 46. ange, a am ag ah ores aA oer Ow a Pafen & cywere| H, all 8 ? (A) Firtergstort @)0, (acu (8)Na (C)Zn —(O)Fe (C1) SeeTERT Oy zaten 49, fer HS aha arg aq H,SO, 3 oe fT & yea Hel Bah 8? (A)Mg (B)Fe (C)Zn (0) Cu y Resonence| ear City Mall, Jhalawar Road, Kota (Raj }-324005, Educating fr better tomorrow