9/6/2021 CN101186622A - Method for preparing solid glyphosate potassium salt - Google Patents

 Patents

Method for preparing solid glyphosate potassium salt

Abstract
CN101186622A
The invention provides a preparation method of glyphosate potassium salt solid wet product or
China
relative raw pesticide, which comprises mixing solid glyphosate with some water, to be added and
reacted with alkali containing potassium cation, controlling the reaction temperature, cooling,
crystallizing and drying to obtain glyphosate potassium salt drug. The invention further provides a Download PDF Find Prior Art Similar
preparation method of glyphosate potassium salt raw pesticide, which comprises that solid
glyphosate is mixed some water, to be added and reacted with alkali containing potassium cation, Other languages: Chinese
the reaction mixture is directly dried to obtain glyphosate potassium salt raw pesticide. The
Inventor: 王伟, 周曙光, 秦龙, 陈丰收, 刘侠
invention further provides a high-content soluble solid glyphosate potassium salt. The inventive
glyphosate potassium salt raw pesticide, compared with other glyphosate potassium salts, has
better weeding speed and rain resistance in same conditions, while the potassium ions on leaf and Worldwide applications
in soil can be effectively absorbed by plant to feed potassium fertilizer. And the invention has simple
2006 CN
package, storage and transmission of prepared glyphosate potassium salt raw pesticide, to reduce
cost.
Application CN 200610154745 events

2006-11-17 Application led by 浙江新安化工集团股份有限公

司

2006-11-17 Priority to CN 200610154745

2008-05-28 Publication of CN101186622A

2013-03-20 Application granted

2013-03-20 Publication of CN101186622B

Info: Patent citations (3), Cited by (8), Legal events, Similar

documents, Priority and Related Applications

External links: Espacenet, Global Dossier, Discuss

Claims (19) Hide Dependent

1. method for preparing glyphosate potassium solid wet product or its former medicine, comprise solid glyphosate acid, suitable quantity of water and the alkali hybrid reaction
that contains potassium cationic, and control reaction temperature, after question response was complete, the control cooling rate was cooled to certain temperature, to be
crystallized separate out a large amount of white crystals after, lter, obtain glyphosphonic acid potassium solid wet product, be dried again and obtain the former medicine of
glyphosate potassium.

2. the method for claim 1 is characterized in that: the weight percent of the add-on of control glyphosphonic acid and water is 1: 0.1-4.

3. method as claimed in claim 2 is characterized in that: the weight percent of the add-on of control glyphosphonic acid and water is 1: 2～4.

4. as each described method among the claim 1-3, it is characterized in that: temperature of reaction is controlled at more than 50 ℃.

5. method as claimed in claim 4 is characterized in that: temperature of reaction is controlled at more than 65 ℃.

6. the method for claim 1 is characterized in that: after reacting completely, be cooled to below 30 ℃.

7. method as claimed in claim 6 is characterized in that: after reacting completely, be cooled to below 0 ℃.

8. the method for claim 1 is characterized in that: the described alkali that comprises potassium cationic be selected from potassium hydroxide, salt of wormwood and
the saleratus any one or multiple.

9. method as claimed in claim 8 is characterized in that: the described alkali that comprises potassium cationic is potassium hydroxide.

10. method for preparing the former medicine of glyphosate potassium, it is characterized in that: the water of solid glyphosate acid with suitable amount is fully mixed, add the
alkali that contains potassium cationic again and react, after question response is complete, the reaction mixture convection drying is obtained the former medicine of
glyphosate potassium.

11. method as claimed in claim 10 is characterized in that: described drying means comprises spraying drying, vacuum-drying.

12. method as claimed in claim 10 is characterized in that: the described alkali that comprises potassium cationic be selected from potassium hydroxide, salt of
wormwood and the saleratus any one or multiple.

13. glyphosate potassium solid wet product or its former medicine are made by each described method among the claim 1-12.

14. high-content solubility glyphosate potassium solid dosage, it comprises glyphosate potassium solid wet product or its former medicine 20-95 weight part, tensio-
active agent 5-25 weight part and other llers 0-75 weight part that is made by each described method among the claim 1-12.

15. glyphosate potassium solid dosage as claimed in claim 14 is characterized in that: described tensio-active agent is anion surfactant, cats product, nonionogenic
tenside or amphoterics.

16. as claim 14 or 15 described glyphosate potassium solid dosages, it is characterized in that: described tensio-active agent is selected from one or more in alkyl
glycoside class tensio-active agent, cattle and sheep lipid tensio-active agent, ethylene oxide tensio-active agent, the polyethenoxy ether class tensio-active agent.

https://patents.google.com/patent/CN101186622A/en 1/8
9/6/2021 CN101186622A - Method for preparing solid glyphosate potassium salt - Google Patents
17. glyphosate potassium solid dosage as claimed in claim 16 is characterized in that: described tensio-active agent is selected from alkyl glycoside class tensio-active
agent and/or cattle and sheep lipid tensio-active agent.

18. glyphosate potassium solid dosage as claimed in claim 17 is characterized in that: described ller is selected from one or more in the solubility salt.

19. glyphosate potassium solid dosage as claimed in claim 18 is characterized in that: described ller is selected from one or more in yellow soda ash, ammonium
sulfate, the ammonium chloride.

Description

A kind of method for preparing solid glyphosate potassium salt

Technical eld

The present invention relates to a kind of agricultural that is applied to, and other needs the weedicide solid preparation in the place of management of weeds or other
plant.Sylvite solid preparation method in particular to herbicidal active component N-phosphonomethyl glycine (glyphosate).

Background technology

Glyphosate is a kind of wide spectrum steriland herbicide, but because the solubleness of glyphosphonic acid in water is very low, in actual applications, normally
glyphosphonic acid is mixed with water miscible salt.At present most popular is glyphosate isopropyl amine salt, ammonium glyphosate, glyphosate potassium, sodium
glyphosate etc.

At present, the glyphosate formulation is still based on aqua, thereby because aqua comprises a large amount of aqueous solvent and brings many-sided inconveniences
such as packing, transportation and storage, increased cost simultaneously.Along with the development and the demand in market, the technical need for preparing high-
load solid dosage glyphosate is more and more urgent.What the former medicine of common at present employing glyphosate salt was prepared into the solid
preparation product is ammonium glyphosate.

Chinese patent application 96196134.1 discloses a kind of method with Dilute Ammonia Solution and glyphosphonic acid prepared in reaction ammonium glyphosate,
and wherein a large amount of moisture content needs to remove by warming wind exsiccant form, and it is not high that energy consumption height and moisture
content are removed e cient.Because hot air dries causes the oxidation of glyphosphonic acid for a long time, can generate the nitrosamine that needs controlled
contents, reaction process also need be added the antioxidant S-WAT.

Chinese patent application 02141788.1 by the applicant's application discloses a kind of glyphosate and water of adding earlier, and then feeding ammonia gas react,
generate the glyphosphonic acid aqueous ammonium after reacting completely, utilizing organic solvent that ammonium glyphosate is extracted acquisition ammonium
glyphosate solid then.This method speed of response is fast, simple to operate, has increased cost but introduced organic solvent.

Glyphosate potassium is compared with other soluble salts such as ammonium glyphosates has following advantage: under the same conditions, the weeding speed of
glyphosate potassium is more excellent, and resistance of rainwater washing against more.Simultaneously the blade face and enter the potassium ion of soil can be
effectively by plant absorbing, thereby reach a great deal of ground potash fertilizer ground effect that replenishes.

At present, glyphosate potassium still former capital is an aqua product, still nd no glyphosate potassium solid preparation method's bibliographical information so far,
and because the different in kind of raw materials for production and product, according to the above-mentioned method for preparing ammonium salt raw powder, can
not obtain the former medicine of sylvite or can not obtain the former medicine of high quality sylvite with and solid preparation.

Its reason is that the crystallization di culty increases because glyphosate potassium is bigger than ammonium glyphosate solubleness in water on the one hand; On
the other hand, because the glyphosate potassium soltion viscosity is very big, and glyphosate potassium comparatively rmly is di cult to remove by ordinary methods
such as heating with combining of water.In addition, be di cult to nd a kind of organic solvent of routine can from its system, extract the good solid of form at
present.Therefore, be badly in need of addressing the above problem, with development and the demand that satis es market.

Glyphosate potassium generally is meant the monopotassium salt of glyphosate, unless context has explanation in addition, " glyphosate potassium " all refers to the
monopotassium salt of glyphosate at this.Its chemical formula is as follows:

Summary of the invention

At above de ciency, the invention provides a kind of prepare the former medicine of glyphosate potassium with and the method for solid preparation.

For reaching the goal of the invention the technical solution adopted in the present invention be: the water that in the popular response device, adds former medicine of
glyphosphonic acid and suitable amount, fully mix, add any alkali reaction that contains potassium cationic again, the water that perhaps adds suitable amount in the
popular response device earlier forms alkali lye with any alkali reaction stirring and dissolving that contains potassium cationic, add glyphosate technicals again and fully
mix reaction, control reaction temperature is more than 50 ℃, after question response fully also becomes clari cation, the control cooling rate, be cooled to certain
temperature, a large amount of white crystal crystallizations are separated out, and lter and obtain glyphosphonic acid potassium solid wet product, obtain the former
medicine of glyphosate potassium after the oven dry.

Because the consumption of solvent is most important to the crystalline in uence.So, must strictly control the mass area ratio of rst glyphosphonic acid of reaction and
adding in order effectively to obtain glyphosphonic acid potassium solid.

Too many as the moisture content that adds, the glyphosate potassium that obtains after the reaction be dissolved in the reaction solution fully and concentration too
low, reduce the saturation concentration that the afterreaction system can not reach glyphosate potassium in temperature, will cause not having crystal to separate out;
And the moisture content that adds very little, then there is a large amount of glyphosphonic acids to suspend in the reaction, and the glyphosate potassium that reaction
obtains can dissolve fully and be suspended in the system in a large number, cause glyphosate potassium crystal parcel that glyphosphonic acids a large amount of in
the suspended solid is generated as crystal seed and can not complete reaction, will contain more glyphosphonic acid in the glyphosate potassium solid wet product that
nally obtain.In addition, amount of water is crossed the major general and is caused the nal reaction product that forms will be pulpous state, and serious a kind of
similar vitreous state that also can form gets the viscosity block, can not directly obtain the glyphosate potassium solid.

The weight percent of the add-on of control glyphosphonic acid and water is 1 among the present invention: 0.1-4, preferred 1: 2～4.

And the conditions such as adding of temperature controlling and stirring, crystal seed all have very important in uence equally to crystallisation process.

Temperature of reaction should be controlled at 50 ℃ among the present invention, and is preferred more than 65 ℃.Because heat release in the reaction process can
make full use of reaction liberated heat reacting by heating liquid.Keep reaction system under comparatively high temps, one can increase the solubleness of glyphosate
potassium in system, and the minimizing suspended solid is bene cial to reaction further to carry out; It two reacts under comparatively high temps, reduces the mother
liquor amount thereby can reduce the water yield in right amount under the condition of identical glyphosphonic acid add-on, thereby obtains more glyphosate potassium
solid.Temperature of reaction such as too high simultaneously, then reaction solution arrives boiling and will cause that moisture scatters and disappears in a large
number and in uence crystallizing system and be unfavorable for safety control.

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9/6/2021 CN101186622A - Method for preparing solid glyphosate potassium salt - Google Patents
It is necessary carrying out continuously stirring among the present invention, but should control stirring velocity faster in initial reaction stage, glyphosphonic acid is
evenly suspended in water so that the acid-base neutralisation reaction is carried out smoothly; Reaction then should be controlled in the decrease temperature
crystalline process and to be stirred in lower speed in the later stage, is bene cial to crystalline and forms and grow up.

Adding to crystal seed in the crystallisation process among the present invention realizes by the control amount of water, initial reaction stage control amount of water,
be that the glyphosate potassium salt loading that forms after the glyphosphonic acid complete reaction still has after reaction system and can not dissolve on a small
quantity and be suspended in the reaction system with ne particle, then this parts of ne small-particle is the crystal seed in the crystallisation process, and
crystallisation process is carried out smoothly.

It is lower to control the cooling gradient in the crystallisation process of the present invention.As the gradient of lowering the temperature is excessive, and then reaction
system moment forms a large amount of tiny glyphosate potassium crystal, and crystal grain can't be grown up; Glyphosate potassium crystal grain tiny in the ltration
procedure in later stage will be easy to the moisture absorption, and form a kind of very heavy-gravity liquid after the moisture absorption, thereby can't lter smoothly or
dewater.Be the low cooling gradient of control, so preferably naturally cooling or recirculated water cooling of the type of cooling.

The minimum temperature of being controlled in the crystallisation process of the present invention should remain on lesser temps, and is preferred below 30 ℃, to
reduce the solubleness of glyphosate potassium in water, bears more crystal.Actual crystallization reaction process is preferably and is controlled at below the room
temperature, more preferably below 0 ℃.

The present invention is by the glyphosphonic acid of control adding and the proportioning of water, and decrease temperature crystalline obtains glyphosphonic acid
potassium crystal after reaction is nished, and this method is simple, and is very easy to realize suitability for industrialized production.

Glyphosphonic acid solid described in the present invention can be that the glyphosate acid wet product also can be dry products, preferably adopts the glyphosate acid
wet product.Adopt glyphosate acid wet product preparation sylvite, not only dispersion is more even but also can save the drying process of the former medicine of
glyphosphonic acid and reduce water consumption in dispersion process.

The alkali that comprises potassium cationic described in the present invention can be potassium hydroxide, salt of wormwood and saleratus etc., preferred potassium
hydroxide.Add alkali, can be dissolved into solution in advance, add again to react in the reactor and make reaction more even, as 50wt% potassium hydroxide solution
(its water yield counts and adds water inventory).

With the mixed solution that contains glyphosate potassium that obtains after ltration or spin-dry, obtain glyphosate potassium solid wet product and mother liquor
(saturated glyphosphonic acid potassium solution), technical scheme of the present invention also comprises above-mentioned saturated glyphosphonic acid potassium
solution recycled: mother liquor is originated as moisture, add a certain amount of glyphosphonic acid solid inward, be stirred to and be uniformly dispersed, use mother
liquor dissolved potassium hydroxide solution in advance adding gradually, control reaction temperature is under comparatively high temps, slowly be cooled to certain
temperature after question response is complete, a large amount of white crystals are separated out, ltration obtains glyphosphonic acid potassium solid wet product,
obtains the former medicine of glyphosate potassium after the oven dry.Adopt the mother liquor place of water to divide the source to react and since mother liquor be
glyphosate potassium salts solution saturated under the low temperature therefore its dissolved glyphosate potassium amount is less, it is more to obtain the former
dose of glyphosphonic acid potassium, and is convenient to big realization of producing.

The present invention comprises that also the water with solid glyphosate acid and suitable amount fully mixes, adding the alkali that contains potassium ion again
reacts, after question response is complete, the mixture convection drying that comprises glyphosphonic acid potassium that obtains after having reacted is obtained the
former medicine solid of glyphosate potassium.The convection drying method comprises other drying meanss such as spraying drying, vacuum-drying.

The present invention also provides a kind of glyphosate potassium solid that utilizes this method to obtain to prepare the method for high-content solubility glyphosate
potassium solid dosage.

By the former medicine 20-95 of the glyphosate potassium weight part that aforesaid method obtains, after tensio-active agent 5-25 weight part and other llers 0-75
weight part mix, through pulverize drying (as, the oven dry) after can obtain the glyphosate potassium salt powder; After granulation, can obtain glyphosate potassium
salt tablets or granula.

Described glyphosate potassium can be the wet product of the former medicine of glyphosate potassium, also can be the glyphosate potassium dried salted products
after drying, and preferably uses the former medicine of the glyphosate potassium product that wet.

Described tensio-active agent is anion surfactant, cats product, nonionogenic tenside or amphoterics.

In the described tensio-active agent, the mixture of two or more of a kind of or any proportioning in preferred alkyl glucosides class tensio-active agent, cattle and sheep
lipid tensio-active agent, ethylene oxide tensio-active agent, the polyethenoxy ether class tensio-active agent, more preferably, alkyl glycoside class tensio-active agent,
cattle and sheep lipid tensio-active agent.

Wherein said ller is selected from one or more in the solubility salt, one or more in preferred yellow soda ash, ammonium sulfate, the ammonium chloride.

Solid dosage of the present invention can be pulvis, tablet or granule.

Glyphosate potassium solid dosage of the present invention is with respect to other salts of glyphosate, under the same conditions, the weeding speed of glyphosate
potassium is better than other glyphosate salt, and resistance of rainwater washing against more, simultaneously the blade face and enter the potassium ion of soil can
be effectively by plant absorbing, thereby reach a great deal of ground potash fertilizer ground effect that replenishes.

The invention provides a kind of succinct method for preparing the former medicine of glyphosate potassium, reduced the oven dry thermal load, reduced the generation
of nitrosamine, entire reaction course does not need to add antioxidant, also avoid the intervention of organic solvent in addition, avoid the introducing of the third
material, reduced and pollute, reduced cost.

Embodiment

Embodiment

Following examples do not limit the scope of the invention only in order to illustrative purposes, and these embodiment help better to understand the present invention,
understand the variation of its advantage and some skills.

Embodiment 1:

Wherein add entry 100g and glyphosate acid wet product 100g (dry product purity 95%, water ratio 8%) in the reaction that has stirring and refrigerating unit, stirring
forms the suspension that contains glyphosate; 35g potassium hydroxide is dissolved in the 100g water forms alkali lye; Under stirring state, gradually alkali lye is added
drop-wise to and makes its reaction in the glyphosate suspension, produce a large amount of heat in the reaction process, the reaction mixture temperature rises to 75 ℃
gradually by 20 ℃, and reaction system changes water white solution into by the suspension system of white gradually simultaneously.Dropwise postcooling, separate
out by crystal gradually.To be cooled when the room temperature ltering separation, obtain the wet product 44.8g of glyphosate potassium, mother liquor 290.2g.Get the
former medicine 41.2g of glyphosate potassium behind the wet product of oven dry glyphosate potassium, content is 96.3wt% (in glyphosate potassium) by analysis.

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9/6/2021 CN101186622A - Method for preparing solid glyphosate potassium salt - Google Patents
Embodiment 2:

The former dried bean noodles product of disposable adding 100g water and 120g glyphosphonic acid (purity 95%) in having the 1L reactor of agitator, thermometer, it is
that 50% potassium hydroxide solution of being converted into 1.1 times of the glyphosphonic acids of 100% purity reacts that whipped state adds down mole number,
temperature of reaction is controlled at 30～90 ℃, react after 1.5 hours, feed clari cation, top temperature is 68 ℃, and the solid-liquid mixed solution that cooling
concentration obtains lters and obtains glyphosate potassium crystal 86.5g.Analyzing the glyphosate potassium salts contg is 98.2wt% (in glyphosate
potassium).Filtering mother liquor can be used for preparing 41% sylvine aqua with glyphosate.

Embodiment 3:

Disposable adding embodiment 2 mother liquid obtained 330g and the former dried bean noodles product of 120g glyphosphonic acid (purity 95%) in having the 1L
reactor of agitator, thermometer, it is that the 50wt% potassium hydroxide solution of being converted into 1.1 times of the glyphosphonic acids of 100% purity reacts that
whipped state adds down mole number, temperature of reaction is controlled at 30～90 ℃, react after 1.5 hours, feed clari cation, top temperature is 71 ℃, and the solid-
liquid mixed solution that cooling concentration obtains lters and obtains glyphosate potassium crystal 130.8g.Analyzing the glyphosate potassium salts contg is
97.5wt% (in glyphosate potassium).Filtering mother liquor can be used for preparing 41% sylvine aqua with glyphosate.

Embodiment 4:

Wherein add the former medicine dry product of glyphosphonic acid 200g (purity 95%), potassium carbonate powder 90g in the uncovered reaction that has agitator, mix
back adding 50g water and do not stop to stir.Exothermic heat of reaction is not parked out carbon dioxide, and material water ratio increases simultaneously.Be stirred
to when not having bubble formation substantially, the soup compound of semi-solid is directly dried, obtain blocky white solid, obtain the former medicine 245.3g of
glyphosate potassium after crushed.Content is 95.2wt% (in glyphosate potassium) by analysis.

Embodiment 5:

Wherein add the former medicine dry product of glyphosphonic acid 200g (purity 95wt%), powdery saleratus 130g in the uncovered reaction that has agitator, mix back
adding 50g water and do not stop to stir.Exothermic heat of reaction is not parked out carbon dioxide, and material water ratio increases simultaneously.Be stirred to
when not having bubble formation substantially, the soup compound of semi-solid is directly dried, obtain blocky white solid, obtain the former medicine 243.7g of
glyphosate potassium after crushed.Content is 97.2wt% (in glyphosate potassium) by analysis.

Embodiment 6:

The former dried bean noodles product of disposable adding 400g water and 500g glyphosphonic acid (purity 95wt%) in having the 2L reactor of agitator, thermometer, it
is that the 50wt% potassium hydroxide solution of being converted into 1.1 times of the glyphosphonic acids of 100% purity reacts that whipped state adds down mole
number, after reacting completely reaction solution is carried out spraying drying, get glyphosate potassium crystal 5 68.7g.Analyzing the glyphosate potassium salts
contg is 98.6wt% (in glyphosate potassium).

Embodiment 7:

Take by weighing the former medicine of glyphosate potassium (content 96wt.%) dry product 67.7g, ammonium sulfate 20.3g mixes, pulverizes, and adds 12g tensio-
active agent NP-10 again, after stirring, and the granulation oven dry.Obtain the glyphosate potassium soluble granula of 100g content 65wt%.

Patent Citations (3)

Publication number Priority date Publication date Assignee Title

Family To Family Citations

US4405531A * 1975-11-10 1983-09-20 Monsanto Company Salts of N-phosphonomethylglycine

MY158895A * 2000-05-19 2016-11-30 Monsanto Technology Llc Potassium glyphosate formulations

CN1203766C * 2002-05-27 2005-06-01 浙江新安化工集团股份有限公司 Soluble solid dosage typed salt of glyphosate

* Cited by examiner, † Cited by third party

Cited By (8)

Publication number Priority date Publication date Assignee Title

CN102532193A * 2011-12-26 2012-07-04 浙江金帆达生化股份 Synthesis method of glyphosate potassium salt technical product
有限公司

CN102578138A * 2010-12-22 2012-07-18 陶氏环球技术有限公 Synergistic combination of a glyphosate compound and IPBC
司

CN101695298B * 2009-09-30 2012-10-03 四川省乐山市福华通 Method for preparing glyphosate potassium salt granules
达农药科技有限公司

CN104478925A * 2014-12-18 2015-04-01 山东潍坊润丰化工股 Preparation method of glyphosate potassium salt, glyphosate potassium salt water-
份有限公司 soluble granule and preparation method of glyphosate potassium salt water-soluble
granule

CN104604932A * 2015-02-11 2015-05-13 南通江山农药化工股 Glyphosate potassium salt preparation and forming equipment thereof
份有限公司

US9221853B2 2009-12-09 2015-12-29 Zhejiang Wynca Glyphosate dimethylamine salt crystal, preparation method and use thereof
Chemical Industry
Group Co., Ltd.

https://patents.google.com/patent/CN101186622A/en 4/8
9/6/2021 CN101186622A - Method for preparing solid glyphosate potassium salt - Google Patents
CN106279269A * 2016-07-28 2017-01-04 浙江新安化工集团股 A kind of method preparing glufosinate-ammonium potassium salt
份有限公司

CN107746415A * 2017-10-31 2018-03-02 浙江金帆达生化股份 The preparation method of glyphosate potassium salt technical product
有限公司

Family To Family Citations

* Cited by examiner, † Cited by third party, ‡ Family to family citation

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Priority And Related Applications

Priority Applications (1)

Application Priority date Filing date Title

CN 200610154745 2006-11-17 2006-11-17 Method for preparing solid glyphosate potassium salt

Applications Claiming Priority (1)

Application Filing date Title

CN 200610154745 2006-11-17 Method for preparing solid glyphosate potassium salt

Legal Events

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Date Code Title Description

2008-05-28 C06 Publication

2008-05-28 PB01 Publication

2008-07-23 C10 Entry into substantive examination

2008-07-23 SE01 Entry into force of request for substantive examination

2013-03-20 C14 Grant of patent or utility model

2013-03-20 GR01 Patent grant

Concepts

machine-extracted Download Filter table

Name Image Sections Count Query match

potassium;2-(phosphonomethylamino)acetate title,claims,abstract,description 83 0.000

K+
OH O
O H
P N
OH
O-

solids title,claims,abstract,description 48 0.000

chemical reactions claims,abstract,description 48 0.000

water claims,abstract,description 36 0.000

products claims,abstract,description 31 0.000

Glyphosate claims,abstract,description 28 0.000

glyphosate claims,abstract,description 28 0.000

drugs claims,abstract,description 26 0.000

potassium claims,abstract,description 18 0.000

potassium claims,abstract,description 18 0.000

alkali claims,abstract,description 15 0.000

drying claims,abstract,description 12 0.000

potassium claims,abstract,description 12 0.000

cooling claims,abstract,description 10 0.000

reaction mixtures claims,abstract,description 3 0.000

Glyphosate claims,abstract 4 0.000

OH O
O H2+
P N
OH
HO

acids claims,description 44 0.000

chemical substances by application claims,description 20 0.000

potassium hydroxide claims,description 13 0.000

HO- K+

potassium hydroxide claims,description 11 0.000

potassium hydroxide claims,description 11 0.000

potassium carbonate claims,description 6 0.000

potassium carbonate claims,description 6 0.000

alkyl glycoside claims,description 5 0.000

llers claims,description 5 0.000

https://patents.google.com/patent/CN101186622A/en 6/8
9/6/2021 CN101186622A - Method for preparing solid glyphosate potassium salt - Google Patents

salts claims,description 5 0.000

Bos taurus claims,description 4 0.000

NaHCO3 Na+ claims,description 4 0.000

HO O-

Pecora claims,description 4 0.000

lipids claims,description 4 0.000

Ammonium chloride claims,description 3 0.000

Ammonium sulfate O claims,description 3 0.000

OH
S
HO
O
NH3NH3

ammonium sulfate claims,description 3 0.000

ammonium sulphate claims,description 3 0.000

sodium chloride claims,description 3 0.000

spraying claims,description 3 0.000

Felis catus claims,description 2 0.000

ammonium chloride claims,description 2 0.000

anions claims,description 2 0.000

ethers claims,description 2 0.000

monochloramine claims,description 2 0.000

H2N Cl

oxane claims,description 2 0.000

O
sodium carbonate Na+
claims,description 2 0.000
O- O-
Na+

sodium carbonate claims,description 2 0.000

sodium carbonate claims,description 2 0.000

sodium carbonate claims,description 2 0.000

surface-active agents claims,description 2 0.000

vacuum drying claims,description 2 0.000

preparation methods abstract,description 9 0.000

potassium ion abstract,description 5 0.000

K+

potassium ion abstract,description 4 0.000

fertilizer abstract,description 3 0.000

soil abstract,description 3 0.000

weeding abstract,description 3 0.000

storage abstract,description 2 0.000

pesticides abstract 5 0.000

https://patents.google.com/patent/CN101186622A/en 7/8
9/6/2021 CN101186622A - Method for preparing solid glyphosate potassium salt - Google Patents
biological transmission abstract 1 0.000

drugs abstract 1 0.000

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https://patents.google.com/patent/CN101186622A/en 8/8