PHYSICAL CHEMISTRY

(ENTHUSE)

DPP # 1

1.

Mark as true or false with appropriate reason- T/F Reason

Assertion
1. ΔH is a state function

2. CV is independent of T for aerfect (ideal)

gas.
3. ΔU = q + w for every thermodynamic
system at rest in the absence of external
field.
4. A process in which final temperature equals
initial temperature must be an isothermal
process
5. U remain constant in every isothermal
process in a closed system

6. q = 0 for every cyclic process.

7. ΔU = 0 for every cyclic process.

8. A thermodynamic process is specified by

specifying only initial and final state of
system.
9. P-V work is usually negligible for solid and
liquid.

10. If neither heat nor matter can enter or leave a

System ,that system must be isolated

H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 www.nucleuseducation.in 1

 PHYSICAL CHEMISTRY
(ENTHUSE)

ONLY ONE OPTION IS CORRECT

2. Which of the following statements is correct?

(A) The presence of reacting species in a covered beaker is an example of open system.
(B) There is an exchange of energy as well as matter between the system and the surroundings
in a closed system.
(C) The presence of reactants in a closed vessel made up of copper is an example of a closed
system.
(D) The presence of reactants in a thermos flask or any other closed insulated vessel is an
example of a closed system.

3. Which one of the following statement is false :

(A) work is a state function
(B) temperature is a state function
(C) change in the state is completely defined when the initial and final states are specified
(D) None.

4. In thermodynamics, a process is called reversible when -

(A) surroundings and system change into each other
(B) there is no boundary between system and surroundings
(C) the surroundings are always in equilibrium with the system
(D) the system changes into the surroundings spontaneously

H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 www.nucleuseducation.in 2