e2 t 21 e4 t 24

e4 t 25 e4 t 23
UO 22 N pO 22
P u O 22 Am O 22
LiAlH
4
H CHO, a q.Me 2 N H
AcOH , h ea t
 Na NH 2 (2eq.)
Toluen e, r eflu x
H 2 (1 a tm)
PtO 2
MeOH
Na NO 2 i. MeOH ,H 2SO 4
a q.H Br ii. Na N 3

Na NO 2
HCl
 Br 2 /F e

(+)DE T, Ti(OP r )4
t Bu OOH , CH 2 Cl 2
4Å, m ol. sieves
 (i) h
(ii)O 2
 (i) H 2O 2 ,
(ii) Zn , AcOH
DDQ
 A ensem ble
A tim e

J L 21 I L 21
= =
I T =0 L 11 J T =0 L11

I L 21 J L 21
= =
J P =0 L 11 I P =0 L11

Ad Ad
d iS 0 d iS 0
T T

Ad Ad
diS – 0 diS – 0
T T
C 4H 6
 K1
O 3 +M O 2 +O+M
K –1

K2
O 3 +O 2O 2

d [O 3 ]
– k1[O 3 ][M] k1[O 2 ] [O][M] – k 2[O 3 ][O]
dt

d [O 3 ]
k1 [O 3 ][M ] – k – 1[O 2 ] [O][M] k 2 [O 3 ][O]
dt

d [O 3 ]
– k1[O 3 ][M] k1[O 2 ][M] k 2[O 3 ][O]
dt

d [O 3 ]
k1 [O 3 ][M] – k1[O 2 ][M] k 2[O 3 ][O]
dt

k p b vr
 1
[A]0 /M [B]0 /M Ra t e/M.s
3
0.1 0.1 1.2 × 10
3
0.1 0.2 1.2 × 10
3
0.2 0.1 2.4 × 10
( )
0.005 0.0707

C
Ag Ag + N O 3– ,N O ,P t
G 0Vap 0 H 0Va p 0

S 0Va p 0

1 / (4 – X);0 X 10

1 / (4 – X);0 X 3