BSCH611: INORGANIC CHEMISTRY-IV

Coordination Chemistry 6 Hours

Werner’s coordination theory and its experimental verification, different types of ligands
Unit
including chelates and pi accepter ligands, nomenclature and formulation of coordination
1
compounds, effective atomic number, stereoisomerism in complexes of coordination number
4 and 6.
Metal Ligand Bonding in Complexes 6 Hours
Valence bond theory of complexes and its limitation, Crystal field theory, Crystal field
Unit
splitting of energy levels in octahedral, tetrahedral and square planer complexes, crystal-
2
field stabilization energy of octahedral complexes (Calculation Only). Application of crystal
field theory and Jahn Teller effect.
Stability of Transition Metal Complexes 6 Hours
Unit A brief outline of thermodynamic stability of metal complexes and factors affecting the
3 stability. Kinetic stability, labile and inert complexes, experimental determination of stability
constant and composition of complex (Job’s Method and Bjerrum’s Method).
Electronic Spectra of Transition Metal Complexes: 6 Hours
LS coupling and determination of spectroscopic ground states, selection rules for d-
Unit d transitions, Orgel-energy level diagrams for weak ligand field and explanation of
4 number of peaks in spectrum (qualitative aspect only).
Hard and Soft Acid & Bases Concept (HSAB)
Classification of acid and base as hard and soft, Pearson’s HSAB concept and its
applications. Symbiosis and limitation of HSAB principle.
Complexometric Titrations: Titration curve, types of EDTA titrations, titration of 6 Hours
mixtures: masking and demasking agents, metal ion indicators: general properties and its
theory.
Unit
Organometallic Chemistry
5
Definition, nomenclature and classification of organometallic compounds, bonding,
preparation, properties and application of organometallic compounds of Li, Al and Sn
(alkyls and aryl).18 electron rule and its limitations.
Suggested Readings:
1. Principles of Inorganic Chemistry by B.R.Puri, L.R.Sharma and Kalia.
2. Advanced Inorganic Chemistry, vol II, by Satyaprakash, G.D.Tuli, S.K.Basu and R.D.Madan.
3. Selected Topics in Inorganic Chemistry by Wahid.U.Malik, G.D.Tuli, R.D.Madan.
4. Fundamental concepts of Inorganic Chemistry, vol.I, by Asim.K.Das.
5. Inorganic Chemistry, vol III by Ameta, Daga, Sharma and Mehta. , Himanshu publication (Hindi)
6. Inorganic Chemistry, vol III by Ojha ,Chaturvedi, Ramesh book depot (Hindi & English)
 BSCH612: PHYSICAL CHEMISTRY-IV
Quantum Mechanics 6 Hours
Black-body radiation, Planck's radiation law, photoelectric effect, Bohr’s model of hydrogen
Unit atom and its defects. Compton Effect. De Brogile hypothesis, Heisenberg's uncertainty
1 principle. Operators, Schrodinger wave equation and its physical interpretation of the wave
function, postulates of quantum mechanics. Particle in a one dimensional box & its
importance.
Spectroscopy-I 6 Hours
Introduction: Electromagnetic radiation, regions of the spectrum, principle and basic features
of different spectrometers, Born-Oppenheimer approximation and degrees of freedom.
Rotational Spectrum:Diatomic molecules. Energy levels of a rigid rotor (semi-classical
Unit principles), selection rules, spectral intensity, distribution using population distribution
2 (Maxwell-Boltzmann distribution) determination of bond length, qualitative description of
non-rigid rotor, isotope effect
Infrared spectrum:Energy levels of simple harmonic oscillator, selection rules, pure
vibrational spectrum, intensity, determination of force constant and qualitative relation of
force constant and bond energies, effect of anharmonic motion and isotope on the spectrum.
Spectroscopy-III 6 Hours
Raman spectrum: Concept of polarizability, pure rotational and pure vibrational Raman
spectra of Diatomic molecules and selection rules,raman rotational vibrational spectra.
Unit
Electronic Spectrum: Concept of potential energy curves for bonding and antibonding
3
molecular orbitals. Qualitative description of selection rules and Frank-Condon principle.
Qualitative description of an σ, π and n MO, their energy levels and the respective
transitions.
Photochemistry 6 Hours
Interaction of radiation with matter, difference between thermal and photochemical
processes. Laws of photochemistry : Grothus-Draper law, Stark-Einstein law, Jablonski
Unit
diagram depicting various processes occurring in the excited state, qualitative description of
4
fluorescence, radiative processes (internal conversion, intersystem crossing), quantum yield
and there methods of determination by using chemical actinometer, photosensitized
reactions-energy transfer processes (simple examples).
Physical Properties and Molecular Structure 6 Hours
Optical activity, polarization - (Clausius-Mossotti equation), orientation of dipoles in an
Unit
electric field, dipole moment, induced dipole moment. Measurement of dipole moment-
5
temperature and refractivity method, dipole moment and structure of molecules, magnetic
properties-paramagnetism, diamagnetism and ferromagnetics.

Suggested Readings:
1. Physical Chemistry, G.M. barrow, International Student Edition, McGrawHill.
2. Physical Chemistry, R.A.Alberty, WileyEasternLtd.
3. The Elements of Physical Chemistry, P.W.Atkins, Oxford.
4. Physical Chemistry Through problems, S.K.Dogra and S.Dogra, WileyEasternLtd.
5. Principles of Physical chemistry, B.R.Puri, L.R.Sharma and M.S. Pathania, Shobhan Lal Nagin chand
& Co.
6. Physical Chemistry, Bahland Tuli, S.Chand & Co. (P) Ltd.
7. Physical Chemistry, Vol. I &II, S.Pahari, New Central Book Agency (P) Ltd.
8. Physical Chemistry, Vol. I, II & III, KL Kapoor, MacMillan
9. Physical Chemistry, S Ameta, Himanshu Publication (Hindi)
10. Physical Chemistry, PD Sharma, Ramesh Book Depot
 BSCH621: LABORATORY COURSE-VI
A. Inorganic
i. Inorganic preparations
i. Ammonium Ferrous Sulphate.
ii. Potash alum (Aluminiumpotassium sulphate).
iii. Microcosmic salt.
iv. Tetraamminecopper(II) sulphate.
v. Hexathiourealead(II) nitrate.
vi. Sodium trioxalatoferrate(III).
B. Soil & Chalk Analysis
i. Determine the available carbon in the given soil sample.
ii. Estimation of calcium in chalk by permanganametric titration.
C. Complexometric titrations:
i. Determine the permanent, temporary and total hardness of the given water sample.
ii. Estimation of nickel using EDTA by back titration method.
D. Physical
i. To verify the Lambert-Beer’s law and determine the concentration of given solution
(CuSO4, KMnO4 & NiSO4).
ii. Jobs method for composition of Fe(III) and SCN - complex.
 BSMT611 - DISCRETE MATHEMATICS

Unit-I Counting and Recursion: Principle of Inclusion & Exclusion, Pigeonhole 9

Principle, Mathematical induction, Recurrence relation, Generating
Functions.

Relation & Diagraphs: Product sets & Partitions, Relations & diagraphs,
Unit-II paths in relation & Diagraphs, properties of relations, Equivalence relations, 9
computer representation of relations& diagraphs, manipulation of relations.
Logic and propositions: Tautology and contradiction and related problems.

Unit-III Ordered Relations & Structures: Partially ordered sets, external elements of 9
partially ordered sets, Bounding Elements, Well Ordered Set, Lattices,
Principle of Duality, Bounded, Distributed, and Complemented Lattices,
Boolean algebra, functions on Boolean algebra.

Unit-IV Graphs Theory: Basic Terminology, types of graph, paths & cycles, Euler 9
graph & cycles, Hamiltonian graph & cycles, shortest path algorithm
( Djikstras algorithm), Graph Isomorphism, Planar Graph,

Unit-V Trees: Introduction, labeled trees, m-ary trees, undirected trees, properties 9
of tree, Spanning tree, Minimal spanning tree, Binary search trees.

Suggested Readings:

1.Bernard Kolmann, Robert C. Busby and Sharon Ross,”Discrete MathematicalStructures”,

PHI.
2.C.L.Liu, Elements of Discrete Mathematics, McGraw-Hill BookCompany.
3.V. K. Balakrishnan, Introductory discrete mathematics, Prentice Hall, .
4.Richard Johnsonbaugh, Discrete Mathematics, Pearson Education.
5 Norman Biggs, Discrete mathematics, Oxford University Press.
6.Kenneth H.Rosen, “Discrete Mathematics and its Applications, TataMcGraw Hill Pub. Co.
Ltd., New Delhi.
7.Pandey and Garg: Discrete Mathematics, JPH, Jaipur
8. U.S. Gupta “Discrete Mathematical Structures” , Pearson Education, Delhi
 BSMT612 Real Analysis

Unit-I Introduction of Real number system, Peano’s Axioms, Field, Field 9

properties, Order, order field, order properties, upper bound, least upper
bound, Lower bound, greatest lower bound, completeness, complete
ordered field, Archimedean properties of real number, Archimedean
properties of order field,

Unit-II Intervals, Nested Interval Theorem, Neighborhood (nbd) of a point, some 9

theorems on neighborhood, Limit point of a set, Isolated Point, Bolzano
Weierstrass (B-W) Theorem, Open and Closed sets, Theorem on open and
closed sets, Compactness, Heine Borel (H-B) Theorem, Count ability of
sets, Theorem on countable set.

Unit-III Definition of Function, Monotonic function, Limit of a function of one 9

variable at a point, Epsilon-delta (€-δ) theorem, Limit of functions of two
variables, algebra of limits.Cauchy’s definition of continuity, classification
of discontinuity, Heine’s definition of continuity, Types of discontinuity

Unit-IV Borel’s covering theorems, Moistest theorem, Bolzano’s theorem, 9

Intermediate value theorem.Definition of differentiability, Algebra of
derivatives, Properties of derivative, Darboux intermediate value theorem,
Differentiability of functions of two variables.

Unit-V Riemann Integration:Theorems of Darboux sums, Upper and lower 9

Riemann integral, Riemann integral, Function of R-Intgrable
Functions,Fundamental theorem of Integral calculus, Mean value theorems.

Suggested Readings:

1. Shanti Narayan: Real Analysis, S.Chand And Company , Merrut.

2. G.N.Purohit: Real Analysis, JPH, Jaipur.
3. Bhargava, Goyal: Real Analysis, JPH, Jaipur.
4. Gokhroo, Saini, Ozgha: Real Analysis, Navkar Publications, Ajmer.
Teaching : 3 Periods (40 minutes each) per week for Theory Paper
4 Periods (60 minutes each) per week for Practical.

Theory Paper 3 hours duration Max Marks : 50

Practical Examination 3 hours duration Max. Marks : 30

BSMT613 Computer Oriented Numerical Analysis

Significant digits, floating point representation of numerals, arithmetic
Unit-I operations with normalized floating point number–addition, subtraction, 9
multiplication and division, errors in numerical computation. Pitfalls in
computing.

Method of successive approximations: Concepts of roots by synthetic

Unit-II division, value and values of derivative of a polynomial by synthetic 9
division, Bairstow's method..
Solution of ordinary differential equations - Taylor’s method, Euler’s
Unit-III method, Runge Kutta second and fourth order method, Picard’s method, 9
modified Euler’s method.
Solution of simultaneous linear equation: Gauss elimination method,
Unit-IV Pivoting, ill conditioned equations, Refinement of solution, Gauss Seidal 9
iterative method. Curve fitting - Method of least squares, fitting of straight
lines, polynomials, exponential curves.
Definitions of Algorithm and flowchart, Introduction to c-Language,
Unit-V Constant and variables, structure of C-program, operators, looping 9
statements, Array and Strings
Suggested Readings:

1. Computer Oriented Numerical & Statistical Techniques ,R. Singh,I. Singh, Khanna
Publication Co., New delhi.
2. Computer Oriented Numerical Methods, V Rajaraman, Prentice Hall India
3. Calculus of Finite Differential & Numerical Analysis, Gupta & Malik, Krishna Prakashan
Media (P) Ltd, Meerut
4. Computer Oriented Numerical Methods, R S Salaria, Khanna Publication
5. Computer Oriented Numerical Methods, P Thangaraj, PHI Publication
6. The Complete Reference C, Herbert Schildt, TMH
7. Let Us C, Yashavant P. Kanetkar , BPB Publications
8. Programming in ANSI C, Balaguruswamy, Mc Graw Hill
PRACTICAL

Distribution of Marks:

Two practical (10 marks each) : 20 Marks

Practical Record: 05 Marks
Viva-voce: 05 Marks

Total : 30 Marks

Programming in C of the following problems:

(1)Solution of linear algebraic equations

A)Gauss elimination
B) Jacobi-Iteration method.

(2) Solution of algebraic and transcendental equations by

A) Bisection methods
B)Regula False position method
C) Newton-Raphson
D) Iteration methods.

(3) Numerical solution of ordinary Differential Equation by

A) Euler’s methods
B) Runge-Kutta Methods.

(4) Numerical Integration by

A) Trapezoidal Rule
B) Simpson’s Rule
C) Simpson’s three eight rule.

1. Each candidate is required to appear in the Practical examination to be conducted by internal

and external examiners. External examiner will be appointed as per University rules and internal
examiner will be appointed by the Head of the Department.
2. Each candidate has to prepare his/her practical record.
3. Each candidate has to pass in Theory and Practical examinations separately.
 Lachoo Memorial College of Science & Technology (Autonomous), Jodhpur
Faculty of Science

BSc. III Year (VI Semester)

Physics Paper I

BSPH611: NUCLEAR PHYSICS

Unit I

General Properties: Rutherford scattering and Rutherford’s scattering formula, Constituents of

nucleus, Measurement of radius by (i) Hofstadter experiment, (ii) Mesonic X-ray method. (iii)
Lifetime of alpha emitters, Nuclear spin and parity, Magnetic dipole moment of nuclei, Basic idea
about quadruple moment of nucleus, Measurement of magnetic moment by Rabi’s method.

Unit II

Binding Energy and Semi-Empirical Mass Formula: Mass defect, Mass difference, Packing fraction
and binding energy of nucleus, Variation of binding energy with mass number, Liquid drop model of
nucleus, Semi-empirical mass formula (Volume, Surface, Coulomb, Asymmetry and Pairing energy
terms), Prediction of stability against beta-decay for members of an isobaric family, Stability limits
against spontaneous fission.

Unit III

Radioactivity: The law of radioactive decay, Statistical nature of radioactivity, Radioactive growth
and decay, Successive disintegrations, Radioactive equilibrium; Transient and secular equilibrium.

Nuclear Reactions: Types of nuclear reactions (only qualitative statement), Conservation laws in
nuclear reactions, The balance of mass and energy in nuclear reaction, Q value equation, Solution of
the Q value equation.

Unit IV

Alpha Decay: Range of particles, Geiger Nuttal’s law, Fine structure of the alpha-ray spectra;
Gammow theory of alpha disintegration.

Beta Decay: Beta ray spectrometer (principle and working), Beta ray spectrum and its qualitative
explanation (Neutrino hypothesis).

Nuclear Energy: Nuclear induced fission, Energy released in fission of U235, Fission chain reaction,
Bohr-Wheeler theory of fission (qualitative idea), Neutron cycle in thermal reactor, Four factor
formula.

Unit V

Radiation Detectors: Introduction of various methods used in detection of nuclear radiation, Principle
and working of (i) Ionization chamber (ii) Proportional counter (iii) Geiger- Muller counter; Dead
time, Recovery time and paralysis time.

Elementary Particles: Properties of particles, Classification of elementary particles: Leptons, Mesons

and Baryons, Conservation laws (only qualitative discussion): Energy, Momentum, Angular
momentum, Charge, Lepton numbers, Iso-spin, Strangeness and Baryon number, Resonance states
and Quark model (only qualitative idea).

Suggested Reading:

Faculty of Science : Syllabus from Session 2017 -Page 96

 Lachoo Memorial College of Science & Technology (Autonomous), Jodhpur
Faculty of Science

1. S.N. Ghoshal: Nuclear Physics, 1st edition, S. Chand Publication, Delhi, 2012.
2. D.C. Tayal: Nuclear Physics, 4th edition, Himalaya Publishing House, 1982
3. R.D. Evans: The Atomic Nucleus, Mc-Graw Hill, 1955.
4. N.S. Saxena, S. Singh and S.S. Rawat: Nuclear Physics (Hindi), College Book House, Jaipur,
2006.

Faculty of Science : Syllabus from Session 2017 -Page 97

 Lachoo Memorial College of Science & Technology (Autonomous), Jodhpur
Faculty of Science

BSc. III Year (VI Semester)

Physics Paper II
BSPH612 (A): Analog and Digital Electronics
(For Students not having Electronics as an Optional Subject)
Unit I

Feedback Amplifiers : Feedback concept, Positive and negative feedbacks and their properties,
Sampling and mixing, Feedback topology: Voltage series, Voltage shunt, Current series, Current
shunt, Effect of positive and negative feedback on gain of amplifier, Frequency response, Gain-
stability, Noise, Distortions, Effect of negative feedback on input and output impedances of an
amplifier, CE amplifier with current series feedback,

Unit II

Sinusoidal Oscillators: Classification of oscillators, Barkhausen criterion for sustained oscillations, R-

C Phase shift oscillator, Hartley oscillator, Colpitts oscillators.

Non Sinusoidal Oscillators: Transistor as a switch, Introduction to multivibrators, Astable (free

running multivibrator).

Unit III

OPAMP and its Basic Applications: Differential Amplifier: Common mode and difference mode
signals and their gains, CMRR, Emitter- Coupled differential amplifier.

Basic Operational Amplifier (Op-Amp): Ideal operational amplifier, Concept of virtual ground,
Inverting and non-inverting OPAMP.

Applications of Op-Amp: Inverting Op-Amp as constant multiplier, Sign-Changer, Adder or summing

amplifier, Integrator, Differentiator.

Unit IV

Number System : Decimal, Binary, Octal and Hexadecimal, Interconversion, Character codes, ASCII,
BCD, Gray code, Logical operations, Boolean algebra, Simplification of boolean expression,

Gates: NOT, AND, OR, NAND, NOR and XOR gates, De-Morgans theorems, Universal gates, Logic
circuits for boolean expressions

Unit V

Combinational Circuits: Half adder, Full adder, Parallel adder, Half subtractor, Full subtractor,
Parallel subtractor,

Sequential Circuits: Flipflops; RS, D, JK, Clocked and edge triggered, PRESET and CLEAR,
Counters: Synchronous and Asynchronous counter,

Books Suggested:

1. Allen Mottershed: Electronic Devices and circuits, PHI, 2005

2. Jacob Millman and Christos C. Halkias: Electronic Devices and circuits, TMH, 2000
3. A.P. Malvino and D.P. Leach: Digital principle and applications IV Ed. TMH, 1990.

Faculty of Science : Syllabus from Session 2017 -Page 98