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(BATCHES: 022 A/B/C/D/R/T1 Lot Regular, 022

A/B/C/D/W/X/T1 Lot Weekend)

IIT – JEE 2022


Time: 2 Hours Maximum Marks: 156

A. Question Paper Format


1. The question paper consists of 3 sections (Physics-Section-I, Chemistry-Section-II, Mathematics-Section-III) and
each part consists of four parts.
2. Part A – (I) contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which only one is correct.
3. Part A – (II) contains 3 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which one or more is/are correct.
4. Part – C contains 4 questions. The answer to each of the questions is a single – digit integer, ranging from 0 to 9.
The answer will have to be appropriately bubbled in the ORS as per the instructions given at the beginning of the
section.

B. Marking scheme:
5. For each question in Part A (I), you will be awarded 3 marks if you darken only the bubble corresponding to the
correct answer and zero mark if no bubbles are darkened. In all other cases, minus one (1) mark will be awarded.
6. For each question in Part A (II), you will be awarded 4 marks if you darken only the bubble corresponding to the
correct answer and zero mark if no bubbles are darkened. In all other cases, minus one (1) mark will be awarded.
7. For each question in Part C, you will be awarded 4 marks if you darken the bubble corresponding to the correct
answer and zero mark if no bubble is darkened. No negative marks will be awarded for in this Section

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S
SEEC
CTTIIO
ONN -- II:: P
PHHY
YSSIIC
CSS
PART – A(I) (Single Correct Choice Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.

1. A parallel plate capacitor having a separation between the plates d, plate area A and material with
dielectric constant K has capacitance C0. Now one-third of the material is replaced by another
1
material with dielectric constant 2K, so that effectively there are two capacitors one with area A ,
3
2
dielectric constant 2K and another with area A and dielectric constant K. If the capacitance of this
3
C
new capacitor is C then is:
C0
(A) 1 (B) 4/3
(C) 2/3 (D) 1/3

2. Three concentric metal shells A, B and C of respective radii a, b and c (a < b < c) have surface charge
densities + , – and + respectively. The potential of shell B is :
  b2  c 2    a2  b2 
(A)   a (B)  a  c
0  c   0  
  a2  b2    b2  c 2 
(C)   c (D)   a
0  b  0  b 

3. The diagram shows a small bead of mass m carrying charge q. The


bead can freely move on the smooth fixed ring placed on a smooth
horizontal plane. In the same plane a charge +Q has also been fixed as +Q
a 4a P
shown. The potential at the point P due to +Q is V. The velocity with
which the bead should be projected from the point P so that it can
complete a circle should be greater than: (Assume gravity free space)
6qV qV
(A) (B)
m m
3qV
(C) (D) none of these
m

Space for rough work

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4. A Gaussian surface in the figure is shown by dotted line. The electric


field on the surface will be
(A) due to q1 and q2 only
q1 q2
(B) due to q2 only -q1
(C) zero
(D) due to all

5. What is the potential difference between P and Q in the circuit P Q


shown in the figure + R 2A
(A) 15 V 15V 5
(B) 10 V
(C) 5 V E
(D) 2.5 V

6. In the circuit shown, the current in the 1 resistor 6V P 2


is :
(A) 0 A
(B) 0.13 A, from Q to P 1 9V
(C) 0.13 A, from P to Q
(D) 1.3 A, from P to Q
3 Q 3

7. Consider a thin square sheet of side L and thickness t, made of a material of


resistivity . The resistance between two opposite faces, shown by the shaded
areas in the figure is t
L
(A) directly proportional to L (B) directly proportional to t
(C) independent of L (D) independent of t

8. Power generated across a uniform wire connected across a supply is H. If the wire is cut into n equal
parts and all the parts are connected in parallel across the same supply, the total power generated in
the wire is
H 2
(A) 2 (B) n H
n
H
(C) nH (D)
n
Space for rough work

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PART – A(II) (Multiple Correct Choice Type)

This section contains 3 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.

9. For the resistance network shown in the figure, choose the P I2 2 S


correct option(s) 2 2
(A) The current through PQ is zero.
(B) I1 = 3A 1 1
(C) The potential at S is less than that at Q. 4 4
(D) I2 = 2A Q T
4
I1
12V

10. Two free point charges +4Q and +Q are placed at a distance r. A third charge q is so placed that all
the three are in equilibrium.
1
(A) q is placed at a distance r from 4Q
3
1
(B) q is placed at a distance r from Q
3
4Q
(C) q 
9
4Q
(D) q  
9

11. In the circuit shown, when the switch is closed, the C R


capacitor charges with a time constant t1 and
when the switch is opened (after the capacitor,
R
has been charged) then the capacitor discharges
with a time constant t2. Then

t2
(A) 2 (B) t1  t 2  3RC
t1
t1
(C) 1 (D) t1  t 2  2RC
t2

Space for rough work

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TYCP-022 A/B/C/D/R/T1 Lot Regular, 022 A/B/C/D/W/X/T1 Lot Weekend LOT-PCM-5

Part C (Integer Answer Type)

This section contains 4 questions. The answer to each question is a single-digit integer, ranging from 0 to
9. The correct digit below the question number in the ORS is to be bubbled.

12. A battery of internal resistance 4  is connected to the


R R
network of resistances as shown. In order that the E
R 6R R
maximum power can be delivered to the network, the
4 R 4R
value of R in  should be

13. When two identical batteries of internal resistance 1 each are connected in series across a resistor
R, the rate of heat produced in R is J1. When the same batteries are connected in parallel across R,
the rate is J2. If J1 = 2.25 J2 then the value of R in  is

14. A charged particle q is shot towards another charged particle Q which is fixed, with a speed v from a
very large distance. It approaches Q upto a closest distance r and then returns. If q were given a
speed 2v, the closest distance of approach would be r/k. Find the value of k.

15. In the figure, find the potential difference between P and Q in 2F Q 4F
volt.

P
4F 2F

12V

Space for rough work

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TYCP-022 A/B/C/D/R/T1 Lot Regular, 022 A/B/C/D/W/X/T1 Lot Weekend LOT-PCM-6

S
SEEC
CTTIIO
ONN -- IIII:: C
CHHE
EMMIIS
STTR
RYY
PART – A(I) (Single Correct Choice Type)

This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.

1. Br  CH  CuLi
3 2
 ?
Br
The product formed in the given reaction is:
(A) CH (B)
3

CH3

(C) (D)

2. Select the incorrect statement about Grignard reagent


(A) It may be made from primary, secondary and tertiary alkyl halides
(B) It cannot be made from vinyl halide
(C) Reactivity follows the order R – I > R – Br > R – Cl > R – F
(D) These are strong nucleophiles and strong bases

3. In the reaction,
NaNH2 CH3I 2
Hg
H  C  C  H  A   B 
H O
C
3

the final product ‘C’ is:


(A) CH3CHO (B) CH3CH2CHO
O
||
(C) CH3  C CH3 (D) CH3CH2COOH

4. Fehling’s solution can make distinction between


(A) CH3CHO and C6H5CHO (B) CH3CHO and CH3 – C –CH2OH
||
O
(C) Lactose and glucose (D) CH3CHO and HCHO

Space for rough work

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5. The dehydration of 1-butanol gives


(A) 1-butene as the main product (B) 2-butene as the main product
(C) equal amounts of 1-butene and 2-butene (D) 2-methyl propene

6. Which of the following compounds give most stable carbonium ion on dehydration?
CH3
CH3——CH——CH2OH
(A) CH3 — C – OH (B)
CH3
CH3
CH3——CH——CH2—CH3 CH3CH2CH2CH2OH
(C) (D)
OH

7. The hydrolysis of which of the following takes the longest time?


(A) CH3COCl (B) (CH3CO)2O
(C) CH3COOC2H5 (D) CH3CONH2

8. CH3COCl is used to detect the number of amino groups in the organic compounds. When a
compound of molecular mass 180 is acetylated, gives a compound of molecular mass 390. The
number of amino groups in the compound is:
(A) 1 (B) 2
(C) 5 (D) 4

Space for rough work

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PART – A(II) (Multiple Correct Choice Type)


This section contains 3 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.

9. The lithium enolate base from cyclohexanone reacts with alkyl halides, often in different ways. As
shown here, methyl iodide and tert-butyl bromide react to give different organic products, I and II,
together with lithium halides. What are the products from these reactions?
+
CH3 O Li
H3C C Br
CH3
H3 CI
II
THF
 
THF
I

(A) I is 1-methoxycyclohexene
(B) II is 1-t-butoxycyclohexene
(C) I is 2-methylcyclohexanone
(D) II is a mixture of cyclohexanone and 2-methylpropene

10. Which of the following does/do not react with Fehling’s solution?
(A) Benzaldehyde (B) Acetaldehyde
(C) Glucose (D) Acetophenone

11. Grignard reagents give alkanes with


(A) phenol (B) ether
(C) alkyne (D) water

Space for rough work

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Part C (Integer Answer Type)


This section contains 4 questions. The answer to each question is a single-digit integer, ranging from 0 to
9. The correct digit below the question number in the ORS is to be bubbled.

12. Me
|
Me
|
H2 O
Et  C  Br  Et  C  OH  HBr
| |
H H
80% racemisation 
The percentage of backside attach in Solvolysis reaction is given as 10x%. What is value of x.

13. Which hydrogen of the given compound is least acidic in nature?


O
(1) H H (2)

(1) H
CH3 (3)
H H
(4) (4)

14. The n-factor for phenol in following reaction is


OH

(NH4 )2 Cr2O7
 

15. Nitration of given compound will takes place at which one of the carbons indicated by number.
NO2

4 1

3 COOH
2

Space for rough work

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TYCP-022 A/B/C/D/R/T1 Lot Regular, 022 A/B/C/D/W/X/T1 Lot Weekend LOT-PCM-10

S
SEEC
CTTIIO
ONN -- IIIIII:: M
MAAT
THHE
EMMA
ATTIIC
CSS
Sec – I (Single Correct Choice Type)

This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.

ln x  1
1. lim is equal to
x e xe
1
(A) e (B)
e
2 1
(C) e (D)
e2

1
2.
n 

lim 4n  5n  n is equal to
(A) 4 (B) e
(C) 5 (D) none of these

 x 3  x 2  16x  20
 2
 x2
3. Let f  x     x  2 , then the value of k so that f is a continuous function, is

k  x2
(A) 5 (B) 7
(C) 6 (D) 4

 
ax  1  x
2 is continuous then
4. If f  x   
sin x  b  x  
 2
b
(A) a = 1, b = 0 (B) a  1
2
a 
(C) b  (D) a  b 
2 2

Space for rough work

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5.  
Let f  x   loge x  x 2  1 , then f(x) equals

x
(A) x2  1 (B)
x2  1
x 1
(C) 1  (D)
2
x 1 x2  1

sin x  h  sin x
6. lim is equal to
h0 h
1
(A) cos x (B)
2sin x
cos x
(C) (D) sin x
2 x

7. If f(x) = ax2 + b, b  0,  x  1
= bx2 + ax + c,  x > 1, then f(x) is continuous and differentiable at x = 1 if
(A) c = 0, a = 2b (B) a = b, c arbitrary
(C) a = b, c = 0 (D) a = b, c  0

x
8. Let f: R  R f  x   , then f(x) is
1 x
(A) injective but not surjective (B) surjective but not injective
(C) injective as well as surjective (D) neither injective nor surjective

Space for rough work

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Sec – II (Multiple Correct Choice Type)

This section contains 3 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.

3x 2  12x  1  x   1, 2


9. If f  x    then
37  x  x  (2, 3]
(A) f(x) is increasing in [–1, 2] (B) f(x) is continuous [–1, 3]
(C) f(2) does not exist (D) f(x) is decreasing in [–1, 2]

10. If x + |y| = 2y, then y as a function of x is


(A) defined for all real x (B) continuous at x = 0
(C) differentiable for all x (D) not differentiable at x = 0

0  x  0
11. Let f  x    2 , then for all x
 x  x  0
(A) f is differentiable (B) f is differentiable
(C) f is continuous (D) f is continuous

Sec – III (Integer Answer Type)

This section contains 4 questions. The answer to each question is a single-digit integer, ranging from 0 to
9. The correct digit below the question number in the ORS is to be bubbled.

2
12. Let f(x) = ax + 1  x > 1
= x + a  x  1 if “f” is derivable at x = 1, then the value of “4a” is

13. If f(x) = 2x3 + 7x – 5, then f–1(4) is equal to

e 5x  e x
14. The value of lim is equal to
x 0 x
2 4
15. Let f(x) = sin x + cos x + 2 and g(x) = cos(cos x) + cos(sin x). If period of f(x) and g(x) be T1 and T2
T
respectively then 1 is equal to
T2

Space for rough work

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TYCP-022 A/B/C/D/R/T1 Lot Regular, 022 A/B/C/D/W/X/T1 Lot Weekend LOT-PCM-13

(BATCHES: 022 A/B/C/D/R/T1 Lot Regular, 022


A/B/C/D/W/X/T1 Lot Weekend)

IIT – JEE 2022


ANSWERS
PHYSICS [SECTION-I]

1. B 2. C 3. A 4. D
5. C 6. B 7. C 8. B
9. A, B, C, D 10. B, D 11. A, B 12. 2
13. 4 14. 4 15. 4

CHEMISTRY [SECTION-II]
1. A 2. B 3. C 4. A
5. B 6. A 7. D 8. C
9. C, D 10. A, D 11. A, C, D 12. 6
13. 2 14. 4 15. 3

MATHEMATICS [SECTION-III]

1. B 2. C 3. B 4. C
5. D 6. C 7. A 8. A
9. A, B, C 10. A, B, D 11. B, C, D
12. 2 13. 1 14. 4 15. 2

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