ARMY PUBLIC SCHOOL & COLLEGE (GIRLS) SADDAR, KARACHI

H.S.C. PRE BOARD EXAMINATION 2021

CHM-01
CHEMISTRY PAPER-II
Total Duration: 2 Hours Total Marks: 85

SECTION “A” (Marks: 43)

MULTIPLE CHOICE QUESTIONS - (M.C.Qs.)
NOTE: i) This section consists of 43-part question all are to be answered.
Each question carries one mark.
ii) Do not copy down the part questions in your answer book. Write only the answer in
full against the proper number of the question and its part.
iii) The code number of your question paper is to be written in bold letter in the
beginning of the answer script.
1. Choose the correct answer for each from the given options:

1. Which of the following element is not including in transition metals?

* Iron * Copper * Barium * Nickel
2. The element which is present in group V A and period 3rd, its atomic number is:
* 15 *7 *8 * 18
3. “A” is the element of II A group which “B” belongs to VI A group. When “A” reacts with “B”
forms:
* A2B3 * AB * AB3 * A3B2
4. Elements in I-B are called:
* Coinage metals * Transition metal *Alkali metals * Halogens
5. Which one possesses both S and P block elements?
* Ionic hydride * Covalent hydride * Complex hydride * All of these
6. Members of group VA form hydrides of ___________ Nature:
* Acidic * Basic * Amphoteric * None
7. The self -linkage of carbon atoms is called:
* Homologue * Catenation * Isomerism * Polymerization
8. In ethyne (C2H2) each carbon is --------- is hybridized:
* dsp3 * sp * sp2 * sp3
9. When NaCl is dissolved in water, the sodium ions become __________.
* Oxidized * Reduced * Hydrolyzed * Hydrated
10. Except lithium, all alkali metal hydroxides are strongly __________.
* Acidic in nature * Basic in nature * Neutral in nature * None of these
11. Which one of the following metals is extracted by electrolysis reduction method?
* Al * Cu * Fe * None of these
12. Β,β` dichloro diethyl sulphide is commonly known as:
* Biogas * Marsh Gas * Mustard gas * phosgene gas
13. ethanol can be converted into ethanoic acid by:
* Hydration * Hydrogenation * Oxidation * Fermentation
14. It is not a nucleophile:
* OH-1 * CN-1 * SH-1 * BF
15. The hydrofluoric acid (HF) is used to make design on glass surface this process is called:
* Knocking * Etching * Hydrogenation * Sublimation
16. The genera formula of alkyne is:
* CnH2n+2 * CnH2n * CnHn * CnH2n-2
17. An isomers of ethanol is:
* Di methyl ether * Di ethyl ether * Methanol * Propanol
18. Removal of one hydrogen from alkane produces a group called:
* Alkene * Alkyne * Alkyl * Alkanol
19. The first organic compound was synthesized in laboratory by:
* Wohler * Kolbe * Kekule * Berzelius
 20. Compounds having same molecular formula but different functional group are called:
* Metamorphism * Position isomerism
* Chain isomerism * Functional group isomerism
21. Nitric acid is a strong __________.
* Reducing agent * Bleaching agent * Oxidizing agent * None of these
22. The metallic character of p-block elements depends electron population of outermost shell and
* Hydration energy * Electron affinity
* Ionization potential * Oxidation number
23. Tollen’s reagent is:
* Ammonical cuperous oxide * Ammonical silver nitrate
* Ammonical silver oxide * Ammonical silver bromide
24. Acetone is formed by oxidation of:
* Primary Alcohol *Secondary Alcohol * Tertiary Alcohol * Ether
25. Acidic hydrogen is present in:
*Acetylene * Benzene *Ethane *Ethene
26. Action of alkyl halides with Na metal yield:
* Alcohols * Alkenes * Alkenes * Phenols
27. Catalyst used for Friedal Craft’s reaction is:
* HNO3 * AlCl3 * FeCl3 * BeCl3
28. Markownikoff`s rule will be applicable in the addition of HBr on:
* CH2 = CH2 * CH2=CH – Br * HC≡CH * None of these
29. Which group is a meta director of benzene?
* –R * -OR * –COOR * –X
30. In the following hydrogenation reaction
H -C ≡ C -H + H2 → H2C = CH2 + H2 → C2H6
Is change in hybridization state of carbon is:
* Sp3 -> sp2 -> sp * sp -> sp2 -> sp3
2 3
* Sp -> sp -> sp * Sp3 -> sp -> sp2
31. Acrylonitrile is used in the manufacture of :
* Acid * Polymer * Acetylene * Aldehyde
32. Benzene was first isolated by:
* Kekule * Faraday * Hoffman * Armstrong
33. Which gas is used in welding:
* Methane * Ethene * Ethyne * Ethane
34. Which of the following is the strongest oxidising agent?
* F2 * Cl2 * l2 * Br2
35. The element of the group II A are called
* Metals * Non metals * Alkaline earth metals * Transition elements
36. Melting and boiling points gradually in a periodic table from left to right up to the middle.
* Increases * Decreases * Remains constant * None of these
37. SN1 is:
* One step process * Two-step process * Three step process * Multi step process
38. Which one of the following gives Tollen`s test positive?
* Alcohols * Ethers * Aldehydes * Carboxylic acid
39. This is an animal starch:
* Glycogen * Amylose * Cellulose * Amino acid
40. Chemical name of fruit sugar is:
* Sucrose * Glucose * Lactose * Fructose
41. A glass which is a mixture of sodium silicate and calcium silicate is called:
* soda glass * pyrex glass * lime glass * None of these
42. Which is a naturally occurring polymer
* Polythene * PVC * Protein * Backlite
43. Most commonly and widely used Nitrogenous fertilizers in Pakistan is:
* Nitrogen * Urea
*Ammonium Sulphate * Ammonium Nitrate
 ARMY PUBLIC SCHOOL & COLLEGE (GIRLS) SADDAR, KARACHI
H.S.C. PRE BOARD EXAMINATION 2021
CHEMISTRY PAPER-II

Section ‘B’ (Short Answer Questions) (Marks: 25)

NOTE: Attempt five questions from this section in all, selecting at least two questions from
Inorganic chemistry and two from organic chemistry. All questions carry equal marks.
INORGANIC CHEMISTRY
Q.2 i. Refer to the list of given compounds.

Compound A B C D

Specific Name Dolomite Whiterite Blue vitriol Potash Alum

* Write the formula of A & B.

* Write the equation when C is heated up to 230 °C
* Write the chemical formula of D and also write two uses.
ii. Write the IUPAC names of the following.
* NH4 [Cr (NCS) 4(NH3)2] * [Cr (NH3)6]+3 * [Fe(CN)6]-3

* [Cr (NH3)3 Cl3] * [Ni (en)2 Cl2]

iii. Identify the groups of the periodic table that have following ground state electronic configuration in
their outer most shell
* 3s2, 3p2 * 3s2, 3p6 4s1 * 4s1, 3d10
2 1
* 4s , 3d * 4s2, 3d10 4p5
iv. Why Hydrogen is misfit in Group I A and VII A of the periodic table?
v. What happens when,
* Nitric acid reacts with sulphur
* Sodium reacts with oxygen
* Sulphur dioxide is treated with chlorine
* Aluminum is treated with H2SO4 (conc.)
* Chlorine reacts with water
vi. Describe the manufacture of chlorine by Nelson cell`s method with the help of diagram.

ORGANIC CHEMISTRY
vii. Define the following:
* Aromatic hydrocarbon * Glycosidic linkage * Functional group
* Esterification * Homologous series
viii. Define the Polymerization and Isomerism. Identify the following pair of compounds as Isomers and
which pair contains polymer
* (CH2=CH2) n, (CH2=CH-Br)n * Glucose and Starch
* CH3-O-CH3 and CH3-CH2-OH * CH3-CH2-CHO and CH3-CO-CH3
* Vinyl Chloride and PVC
ix. How can we prepare following compounds.
* ethylene glycol from ethene
* phenyl hydrazone from formaldehyde
* White solid from Acetylene
* ethane from chloro methane
* ethene from ethane
x. Write the IUPAC names of the following.
 * CH3-CH (CH3)-CH (CH3)-CH3 * CH2=C(CH3)-CH(CH3)-C≡CH
*CH3-CH(CH3)-CH(Cl)-CHO * (CH3)3C.CO-CH2CH3 * CHI3

xi. Why benzene gives electrophilic substitution reaction. Discuss acylation of Benzene with
mechanism.
xii.
xiii. What happens when,
a. Acetylene reacts with water in presence of H2SO4 and HgSO4 at 75°C.
b. Formaldehyde is polymerized in presence of H2SO4
c. Acetic acid is treated with ethyl alcohol in presence of H2SO4
d. Ethanol in excess is heated in presence of H2SO4.
e. Addition of alcohol to formaldehyde

SECTION ‘C’ (Detailed-Answer Questions) (Marks: 17)

NOTE: Attempt any two questions from this section, one from organic and one from inorganic
chemistry.
INORGANIC CHEMISTRY

Q3. Describe the extraction of 99.99% pure Aluminum from bauxite ore containing SiO2 and Fe2O3 as
Impurities. (8)
Q4. The following chart represents stages in manufacture of HNO3 (8)

* Describe the chemical process in stage A along with the conditions for maximum conversion.
* Describe the process in C and D.
* How 98% concentrated HNO3 is obtained.
* How gold is dissolved in aqua regia.

ORGANIC CHEMISTRY

Q5. Explain the reaction mechanism of SN1 and SN2 reactions. Write equations to prepare the following
compounds from ethyl bromide? (9)
* C2H5SH * C2H5O C2H5 * C2H5CN

Q6. Define denatured and absolute alcohol. What is fermentation and how ethyl alcohol manufactured by
fermentation of the following? (9)
* Starch * Molasses