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Abstract
Three composites were fabricated based on Polyetherimide (PEI) matrix and carbon fabric (CF) (55 vol.%) of different weaves, viz. plain, twill
and satin (4H) by impregnation technique. These composites were evaluated for various mechanical properties and tribological performance in
low amplitude oscillating wear (LAOW)/fretting wear mode. It was observed that CF reinforcement led to a significant enhancement in all strength
and modulus properties of PEI except elongation to break (e). Twill weave proved to be the most effective followed by satin and plain weave in
almost all the properties. The LAOW mode evaluation under various loads revealed that the wear performance order was exactly opposite to the
above trend. Overall, plain weave composite was the best performer followed by twill and satin. Various wear mechanisms, such as fiber-matrix
debonding due to repetitive reciprocating shearing stresses, micro-cracking, micro-cutting and pulverization of fibers followed by removal of debris
from the contact zone were operative during such wear situation. Amongst these processes, generation of fiber debris, their temporary retention in
fabric weaves and subsequent removal from the crater played a key role in overall wear performance. The ability of plain weave to hold back the
debris was maximum that resulted in lowest wear while satin weave had the minimum retention ability that led to the highest wear. The proposed
wear mechanisms were supported by SEM studies.
© 2006 Published by Elsevier B.V.
Keywords: Low amplitude oscillating wear; Fretting wear; Carbon fabric reinforced composites; Fabric-weave tribology
Table 1b
Properties of three weaves of carbon fabric measured in the laboratory
Carbon fabric Plain Twill Satin (4H)
Table 2 The specific wear rate was calculated using the equation:
Details of the composition and properties of fabricated composites
V
Composites PEI* IP55 IT55 IS55 K0 =
2AνtFN
Density (g/cm3 ) ASTM D 1.27 1.55 1.53 1.54
792 where Ko is the specific wear rate in m3 /N m, V the wear
Contents of fabric (%, v/w) – 55/65 55/65 55/65 volume (m3 ) and FN the applied normal load (N). 2Aνt (where
Tensile strength (MPa) 105 535 888 575 A is the full oscillation width (m), ν the frequency (Hz) and t is
ASTM 638
Tensile modulus (GPa) 03 73 106 76
the experimental duration in (s)) indicates total sliding distance.
ASTM 638
Elongation at break (%) 60 0.54 0.08 0.32 3. Results and discussion
ASTM 638
Toughness (MPa) ASTM 638 – 3.8 2.2 2.8
Flexural strength (MPa) 150 589 951 832
As seen from Table 2, the strength performance of the com-
ASTM 790 posites was in the order; IT55 > IS55 > IP55 ≫ PEI for all prop-
Flexural modulus (MPa) 3.3 40 54 46 erties except toughness and elongation, where the order was
ASTM 790 reverse.
Inter laminar shear strength – 49 66 63 The friction and wear performance of the selected composites
(ILSS) (MPa) ASTM 2344
under various loads is shown in Fig. 3. Possible wear mecha-
* Properties of PEI as per supplier’s data. nisms are shown in Fig. 4 and SEM micrographs of worn pin
surfaces are shown in Figs. 5–7.
Fig. 3a shows the variation of friction coefficient (µ) with
increasing loads for all the three composites. The µ decreased
with increasing loads and was in the range of 0.3–0.4. For
Test duration—2 h;
Oscillating frequency—50 Hz,
Temperature—25 ◦ C.
1 In the case of LAOW all selected parameters including amplitude are set
before the experiment starts. Once the oscillation starts, generally amplitude
falls below the set value and it is reset with the control panel. However, when
load is very large and shearing forces are high, amplitude cannot be maintained
even after applying maximum range provided in the control unit. This shows that
the limiting load has reached. Sometimes amplitude reduces because of trapping
of large particles of metal or polymer and falls to a low value for a short time. It
regains once the particle either is thrown off or gets “wear thinned”. However, if
the value falls below 80% of original value for a long time even after applying full
possible force through control unit, it is realized that the material has reached
the “failure limit” and cannot withstand the selected load. The experiment is Fig. 3. (a) Coefficient of friction and (b) specific wear rate (Ko ) as a function of
abandoned and lower load is selected for next experiment. load.
730 R. Rattan et al. / Wear 262 (2007) 727–735
Fig. 4. (a) Cross-section view of unit cell of (a) plain, (b) twill and (c) satin weave fabric; L1, L2 and L3 denote distance between mid-point of contact and the point
where the crimp starts. (b) Schematic of the events of most probable sequence during fretting wear of plain weave fabric reinforced composite. A—Situation prior
to fretting: (a) top view of weave and direction of fretting, (b) cross-section of unit cell and (c) contact configuration. B—Just initiation of fretting: (a) wear debris
generation due to fiber damage, (b) larger sized fiber/matrix debris in contact zone and (c) sub-surface damage. C—Fretting continued: (a) initiation of travel of
debris towards pockets, (b) retention of debris in pockets and (c) thick layer of entrapped fibrous and polymeric debris leading to third body interphase. D—Fretting
continued: (a) wear thinned fibrous debris accumulation in pockets, (b and c) shearing of debris. E—Fretting in advanced stage: (a) pocket saturated with fibrous
debris offering more wear resistance by further wear thinning, (b and c) accumulation beneath the crimp leading to saturation; excess debris escape the contact zone
leading to measurable wear.
R. Rattan et al. / Wear 262 (2007) 727–735 731
Fig. 5. Scanning electron micrographs (×15) of IP55 worn under (a) 100 N and (b) 250 N; and IT55 worn under (c) 100 N and (d) 250 N loads, respectively.
almost all loads plain weave composite showed the lowest µ resistance which is calculated as per following equation
followed by twill and satin composites. µ of PEI, however, was
Wear resistance of composite
always high 0.41 and was independent of load as reported in RWR =
our earlier paper [10]. Thus, inclusion of CF reduced µ by Wear resistance of PEI
approximately 25%, which was due to the lubricating action Since limiting load for PEI was 200 N, the data for comparison
of CF. A lower µ at higher loads was attributed to the lubric- was selected accordingly. As seen from Table 3, a significant
ity provided by the fine CF powder formed due to crushing increase in wear performance due to CF inclusion can be seen.
and grinding of fiber pieces that accumulated at the contact Approximately 8.4 times increase in performance was showed
zone. by IP55 . Overall, the improvement was in the range 4–8.4 for
The specific wear rate (Ko ) plotted as a function of load in various composites evaluated under different loads.
Fig. 3b indicates that Ko increased with increase in load for It is a well known fact that wear behavior in fretting wear
all the composites, which is a general trend observed in the mode is very different than that in sliding wear mode. It is the
case of fiber-reinforced composites [3,10,11]. The limiting load reciprocating motion in the former, which makes the major dif-
(and hence range of utility of the composite in harsh operating ference in wear mechanisms in two modes. Wear processes in
conditions) of plain and satin weave composites was 300 N while such dry frictional contacts are considered as a succession of
that of twill weave was slightly lower (250 N). IP55 was the individual events involving particle detachment from the con-
best performer from tribological point of view, but poorest from tacting bodies i.e., debris formation, its trapping and shearing in
strength point of view. Composite IS55 showed second best wear the contact zone and subsequent escape from the same. Among
performance under only moderate loads (100–150 N). At higher
loads, however it showed highest wear rate. Its friction behavior
was also poorest in all conditions. Table 3
Twill weave composite IT55 on the other hand was second Relative wear resistance of composites at various loads (RWR = Ko of
best in both wear as well as friction performance under higher composite/Ko of PEI)
loads. Ko was least dependent on load as compared to other Material Relative wear resistance (RWR)
composites.
50 N 150 N 200 N
Overall order of friction and wear performance of compos-
ites was: IP55 > IT55 > IS55 . The strength and modulus of the PEI 1 1 1
composites, however, did not follow the same order. The wear IP55 6.55 8.38 7.28
IT55 4.08 6.00 6.08
performance of the composites was compared with that of Neat
IS55 7.03 6.55 5.17
PEI (data taken from Ref. [10]) in the form of relative wear
732 R. Rattan et al. / Wear 262 (2007) 727–735
Fig. 6. SEM (×500) of composites worn under 100 N (WR -IS55 ∼ = IP55 ≫ IT55 ); (a) long fibers, longitudinally wear thinned and embedded in the matrix, (b) back-
transfer of matrix, (c) magnified view (×1500) of fiber damage with micro-cracking, (d) shows worn surface of IP55 and back-transfer of matrix in the form of
patches and (e) shows the worn surface of the composite IT55 and debris embedded in the matrix.
these, the escape of wear debris is minimal if the slip amplitude mechanisms. The wear process involves various mechanisms
is very small. In the case of engineering polymers, the effect of such as fiber-matrix debonding followed by fiber breakage as a
contact zone kinematics on the wear is significant when the third result of micro-cracking, micro-cutting and micro-pulverization
body formation leads to abrasion or the transfer of polymer films due to reciprocating shearing stresses. The wear also depends
to the counterface as well. The wear process is also affected by on the amount of fiber debris produced and its escape from
the formation of ‘loose’ or ‘tight’ compacts from the debris and the contact zone. Amongst all weaves, plain weave is the most
its subsequent rheological behavior [3]. Thus, the wear behav- tight (least flexible) followed by twill and satin. This would
ior of materials is quite different from that in other wear modes result maximum fiber damage to the plain weave composite.
and cannot be predicted a priori. There are a number of cases However, the same weave is also responsible for the retention
reported where inclusion of solid lubricants or fibers or both did of fiber debris in the contact zone. Thus, fretting wear of fabric-
not render the expected benefits. The performance on the other reinforced composites is a complex phenomenon that comprises
hand deteriorated [14,15]. multiple mechanisms which are operative successively and then
The wear resistance (WR ) (inverse of wear rate, Ko ), was simultaneously. Fig. 4a shows the unit cells of three weaves.
highest for plain weave composite followed by twill and satin. It highlights the variation in distance between mid-point of
This was not related to any strength properties of these com- contact and the point of starting of crimp. This distance has
posites, rather it was mainly because of the difference in wear critical impact on wear mechanisms. Higher the distance,
R. Rattan et al. / Wear 262 (2007) 727–735 733
Fig. 7. SEM of IP55 worn under 250 N showing (a) weave of fabric (marked as 1), (b) magnified view (×1000) fiber debris embedded in the matrix, (c) retention of
fiber debris in the weave pockets marked as 1 and fiber-matrix debonding marked as 2, (d) magnified view (×1000) for IT55 showing cavities (marked as 1), fiber
piece escaped from cavity (marked as 2), fiber-matrix debonding (marked as 3) and (e) worn surface of (×500) IS55 showing long fibers and cavities.
lower is the probability of fiber debris reaching to crimp and extent. The satin weave is the least compact (Table 1a) amongst
getting entrapped. If entrapped, they will cause negative wear. three followed by twill and plain. Hence, the tendency of reten-
The distance being largest in satin weave, the probability of tion of debris beneath the crimp and pockets is minimum for satin
entrapment was lowest. This was one of the reasons for highest and maximum for plain weave composite, a fact that supports the
wear of satin weave composite. The same distance was lowest highest and lowest wear rates for the former and latter. Thus, the
for plain weave composite and hence offered highest possibility initial fiber breakage process though is maximum in plain weave
of retention of debris beneath the crimp leading to lowest composite, the further damage processes are minimal and reten-
wear. tion processes are maximum. Satin weave being loose, on other
Fig. 4b is self-explanatory and depicts fretting mechanisms hand, fiber breakage is minimal because of highest length of
of plain weave composite. Various events that take place sequen- fiber, and hence maximum flexibility, between crossover points.
tially are collected in Table 4. The impact (positive or negative) Thus, plain weave composite showed highest WR , despite maxi-
on weight loss of a composite is also indicated in the same table. mum fiber pulverization, mainly because of its highest tendency
The mechanisms suggested in Table 4 and Fig. 4b are supported of retention of wear debris in the pockets and beneath the crimp
by SEM studies as discussed in the subsequent section. point. The maximum tightness of the plain weave and maximum
In the case of satin weave composite, similar mechanisms crimp points (Table 1a) were responsible for retention of debris
(Fig. 4a) take place except for the difference in the degree of leading to lowest wear of this composite.
734 R. Rattan et al. / Wear 262 (2007) 727–735
Table 4
Possible wear mechanisms and extent of their contribution towards weight loss/wear rate
Parameters and events during fretting of a ball on a composite plate Effect on wear rate Extent of Effect
(WR , wear resistance)
Plain Twill Satin
1 Wear thinning of fibers parallel to the direction of slip; higher the − Minimum Moderate Maximum
better for WR . Longer the fibers more the wear thinning
2 Breakage of fibers due to micro-cracking and micro-cutting. Lesser, + Maximum Moderate Minimum
the better for WR
Generation of wear debris. Lesser, the better for WR +
3 Length of the fibers between crimp points and associated flexibility. + Maximum Moderate Minimum
Higher, the better for WR ; LS > LT > LP
4 Wear debris escape from the contact zone. Lesser the probability, + Minimum Moderate Maximum
the better for WR
5 Retention of debris trapped in the pockets of the weave. Higher, the − Maximum Moderate Minimum
better for WR
6 Formation of intermediate layer due to shearing of debris. Thicker − Maximum Moderate Minimum
the better for WR
7 Embedment of debris retained in the zone followed by wear − Maximum Moderate Minimum
thinning; Higher, the better for WR
8 Tightness of weave responsible for efficient entrapment of debris; − Maximum Moderate Minimum
tighter, the better for WR
9 Quick entrapment of debris beneath the length of crimp (crossover − Maximum Moderate Minimum
points); Higher, the better for WR
(+) Sign indicates contribution to weight loss; (−) sign indicates protection from wearing. For plain weave composites events 1–3 are unfavorable for increasing
WR while factors 4–9 are favorable. Resultant of these led to highest WR . Exactly reverse is true for satin weave composite. However, extent of contribution of these
mechanisms depends on operating parameters, especially applied load.
3.1. SEM studies matrix in the form of patches (marked as 1). The pulverized
debris of fibers is efficiently embedded in these patches (this
Scanning electron micrographs of worn composite surfaces was one of the very critical factors i.e., retention of debris-
in the order of increasing wear rate are shown in Figs. 5–7. Fig. 5 responsible for highest WR ). The dark boundaries of patches
shows the general appearance of craters and influence of load give the false notion of being cracks. Carbon fibers longitu-
on their size at lower magnification (×15). Micrographs 5a and dinally wear thinned can also be seen. The length of such
b show the craters for composite IP55 worn under 100 and 250 N fibers, however, is shorter than that observed in IS55 . These
loads, respectively, while 5c and d are for composite IT55 worn broken fibers and pulverized debris are very well embedded
under 100 and 250 N loads, respectively. The size of the craters in the matrix and no evidence of fiber-matrix debonding could
has increased with load because of higher wear. Micrographs be seen.
6 and 7 show surfaces worn under lower (100 N) and higher Micrograph 6e shows the worn surface of the composite IT55 ,
(250 N) loads, respectively. At 100 N, wear performance of that exhibited the highest wear rate at 100 N. The wear damage
composites was in the order IP55 ≈ IS55 ≫ IT55 . Micrographs to the fibers is severe as compared to mild wear observed in
6a–c show worn surface of IS55 . As seen in micrograph earlier micrograph (6d). Another difference was in the nature
6a, the weave being satin, long fibers, longitudinally wear of back-transferred layer of matrix (marked as 1). The extent
thinned and well embedded in the matrix appear on the surface of debris embedded in the matrix and hence retention of wear
(event 1 described in Table 4). A little back-transfer of resin debris was less, which could be the cause of highest wear rate
(marked 1) is also appearing on the surface. Micrograph 6b of the composite.
shows another location where various stages of fiber damage Micrographs of composites worn under higher load
(marked 1) and back-transfer of the matrix (marked as 2) can be (250 N) are shown in Fig. 7. At this load order of WR was
clearly seen. Few fibers are completely broken leaving behind IP55 > IT55 > IS55 . The features in micrographs 7a–c support
cavities (marked as 3). Enhanced fiber-matrix debonding the highest WR of IP55 . Though the fiber damage is severe
responsible for higher wear can also be seen (marked as 4). (events 2, 3 in Table 4) hardly any cavities are seen (events 6, 7
Micrograph 6c shows finer features of fiber damage which in Table 4). This indicated the high capability of this composite
initiates with micro-cracking, followed by micro-cutting, for wear debris retention, which was suggested as main reason
pulverization in the form of powder and subsequent removal of highest WR of the composite. The micrograph also shows the
from the surface leaving behind cavities as seen in the weave of fabric (marked as 1) (event 5 in Table 4). Micrograph
micrograph. 7b shows magnified view (×1000) of the surface confirming
Micrograph 6d shows worn surface of IP55 . Surface, overall is well-embedded fiber debris in the matrix in various orientations
very smooth supporting lowest wear rate (similar to IS55 ) of this that provided temporary wear protection. Micrograph 7c shows
composite. Most of the area was covered with back-transferred another location of the same composite surface (×1000) with
R. Rattan et al. / Wear 262 (2007) 727–735 735