Narayana IIT Academy 22-03-20_Sr.

IIT_N-SC/N-C_JEE-Adv_GTA-7_2018(P2)_Key & Sol's

11.

12

13.

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14.

15.

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Narayana IIT Academy 22-03-20_Sr.IIT_N-SC/N-C_JEE-Adv_GTA-7_2018(P2)_Key & Sol's

16.

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17.

1 1 1 
18.  R 2  2 
  n1 n2 
1 15 
For transition 4  1,  1.1107  
1 16 
16
1   970 A0
15 1.1107

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Narayana IIT Academy 22-03-20_Sr.IIT_N-SC/N-C_JEE-Adv_GTA-7_2018(P2)_Key & Sol's
9
For transition 3  1 ; 2   1023 A0
8 1.110 7

4
For transition 2  1; 3   1212 A0
3 1.110 7

For Li atom  2  3 , for Transition 2  1,

2

1  1
 Rz 2 1  2 
 1
 2 
1
1   134 A0
1.110  9  0.75
7

For He  atom ( Z = 2) for transition 2  1,

1  1
 Rz 2 1  2 
 1
 2 
1
1   303 A0
1.110  4  0.75
7

CHEMISTRY
19.
NH 2
NaNO2 / HCl Re arrangement CH 2
OH Cl
OH
OH
CH 2 OH CH 2 Cl

20. Benzaldehyde reduces Tollen’s reagent while acetophenone is not while acetophenone
reacts hypoiodite and give iodoform reaction while benzaldehyde is not.
21. Phenol gives violet colour with FeCl3 and also reacts with aqueous NaOH but Anisole
OCH 3

doesn’t react with FeCl3 as well as NaOH. So FeCl3 and aqueous NaOH
can be used to distinguish phenol from anisole.
22. Both are non super impossible mirror image of each other and OH are in different
side.
23. S N 2 and E2 are the concerted mechanism, in which no intermediate is formed.
Br
Br
24. Styrene is is can be prepared from and by
OH

dehydrohalogenation and from by acid catalyzed dehydration

25.
26.
27.
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