JEE(ADVANCED)-2020-Paper-1-PCM-11

Section 3 (Maximum Marks: 24)

 This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
 For each question, enter the correct numerical value of the answer using the mouse and on-screen virtual
numerical keypad in the place designated to enter the answer. If the numerical value has more than tow
decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct numerical value is entered;
Zero Marks : 0 If all the cases.

*13. Put a uniform meter scale horizontally on your extended index fingers with the left one at 0.00 cm and the
right one at 90.00 cm. When you attempt to move both the fingers slowly towards the center, initially only
the left finger slips with respect to the scale and the right finger does not. After some distance, the left
finger stops and the right one starts slipping. Then the right finger stops at a distance xR from the center
(50.00 cm) of the scale and the left one starts slipping again. This happens because of the difference in the
frictional forces on the two fingers. If the coefficients of static and dynamic friction between the fingers
and the scale are 0.40 and 0.32, respectively, the value of xR (in cm) is ______.

Sol. 25.6 (25.60 to 25.60)

Initially CM
40N1  50N2

50 cm 40 cmN
N2 1
For first move CM
kN3   sN4 …(i)
xN3  40 N4 …(ii)
x = 32 cm x cm 40 cmN
N3 4

For second move CM

 sN5  kN6 …(i)
32(N5 )  XR N6 …(ii)
XR = 25.6 cm 32 cm xR N6
N5

*14. When water is filled carefully in a glass, one can fill it to a height h above the rim of the glass due to the
surface tension of water. To calculate h just before water starts flowing, model the shape of the water above
the rim as a disc of thickness h having semicircular edges, as shown schematically in the figure. When the
pressure of water at the bottom of this disc exceeds what can be withstood due to the surface tension, the
water surface breaks near the rim and water starts flowing from there. If the density of water, its surface
tension and the acceleration due to gravity are 103kg m−3, 0.07 Nm−1 and 10 ms−2, respectively, the value of
h (in mm) is _________.

Sol. 3.75 (3.65 to 3.85)

 gh 
S(2R)    h(2R)
 2 
h = 3.75  103 mm

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15. One end of a spring of negligible unstretched length and spring constant k is fixed at the origin (0,0).
A point particle of mass m carrying a positive charge q is attached at its other end. The entire system is kept

on a smooth horizontal surface. When a point dipole p pointing towards the charge q is fixed at the origin,
the spring gets stretched to a length l and attains a new equilibrium position (see figure below). If the point
mass is now displaced slightly by  l << l from its equilibrium position and released, it is found to oscillate

1 k
at frequency . The value of is ______.
 m

Sol. 3.14 (0.50 to 0.50) or (3.13 to 3.15)

Potential energy of a system after a small displacement.
1 k pq
U  kx 2 
2 (  x)2
dU 2k pq
 kx 
dx (  x)3
d2U 6k pq
k  k  3k  4k
dx 2
(  x)4
1 4k
f
2 m
1 k
f
 m
So,  = 3.14
and for angular frequency
1 k

 m
 = 0.5

*16. Consider one mole of helium gas enclosed in a container at initial pressure P1 and volume V1. It expands
isothermally to volume 4V1. After this, the gas expands adiabatically and its volume becomes 32 V1. The
work done by the gas during isothermal and adiabatic expansion processes are Wiso and Wadia, respectively.

Wiso
If the ratio = ln2, then is ________.
Wadia

Sol. 1.77 (1.77 to 1.79)

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AB
A
P1V1 = PB  4V1 P1
P
 PB  1
4
4V1
Wiso  1 R  Tn B
V1 P1/4
P1V1n4  2P1V1n2
BC C
PB VB  PC VC V1 4V1 32V1
P1
(4V1 )  PC (32V1 )
4
 5 /3
1 1 1 1  P1
 PC    P1   3  P1 =
48 42  128
P1 P
 32V1  1  4V1
Wadic  128 4
5
1
3
P1V1 3
 P1V1  P1V1
9
= 4  4  P1V1
2 2 8
 
3 3
Wiso 2P1V1n2 16
  n2
Wadio 9 9
PV
8 1 1
Comparing with given expression of = 16/9 = 1.78

*17. A stationary tuning fork is in resonance with an air column in a pipe. If the tuning fork is moved with a
speed of 2 ms−1 in front of the open end of the pipe and parallel to it, the length of the pipe should be
changed for the resonance to occur with the moving tuning fork. If the speed of sound in air is 320 ms−1,
the smallest value of the percentage change required in the length of the pipe is ____________.

Sol. 0.62 (0.62 to 0.64)

320 320
f  f0  f0
320  2 318
2
 f  f0 …(1)
318
(2n  1)v
 f0 
4L
2 L

318 L
L 200
100    0.62983  0.63
L 318

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JEE(ADVANCED)-2020-Paper-1-PCM-14

 r
18. A circular disc of radius R carries surface charge density  0  r    0 1   , where 0 is a constant and r
 R
is the distance from the center of the disc. Electric flux through a large spherical surface that encloses the
R
charged disc completely is 0. Electric flux through another spherical surface of radius and concentric
4

with the disc is  . Then the ratio 0 is_________


Sol. 6.40 (6.40 to 6.40)

Total charge on disc
R
 r R 1
R

q0   0  1   2rdr    2   rdr   r 2 dr 
0  R 0 R0 
R2 R2 
= 2   
 2 3 
 R2 
q0  2   …(1)
 6 
Change enclosed by second sphere
R/ 4 1
R/ 4

q0    2   rdr   r 2 dr 
0 R 0 
2 2
R R 
= 2   
 32 192 
 5R2 
q0  2  
 192 
 q R2 / 6 192 32
 0  0     6.40
 q 5R2 / 192 5  6 5

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 JEE(ADVANCED)-2020-Paper-1-PCM-15

PART II: CHEMISTRY

SECTION-1 (Maximum Marks: 18)
 This section contains SIX (06) questions
 Each question has FOUR options. ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following making scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : 1 In all other cases

*1. If the distribution of molecular speeds of a gas is as per the figure shown below, then the ratio of the most
probable, the average, and the root mean square speeds, respectively, is

(A) 1:1:1 (B) 1 : 1 : 1.224

(C) 1 : 1.128 : 1.224 (D) 1 : 1.128 : 1

Sol. B
Since the graph is symmetrical about the peak. So, the average speed and most probable speed will coincide
3RT
but rms speed will remain
M
2RT
So, ump   uav
M
3RT
urms 
M
3
ump : uav : urms  2 : 2 : 3  1: 1:
2
 1: 1: 1.224

*2. Which of the following liberates O 2 upon hydrolysis?

(A) Pb3 O4 (B) KO 2
(C) Na2 O2 (D) Li2O2

Sol. B
Pb3 O4  H2 O  No reaction
KO2  H2O 
 KOH  H2 O2  O2
Na2 O2  H2O  NaOH  H2 O2
Li2O2  H2O LiOH  H2 O2

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3. A colorless aqueous solution contains nitrates of two metals, X and Y. When it was added to an aqueous
solution of NaCl, a white precipitate was formed. This precipitate was found to be partly soluble in hot
water to give a residue P and a solution Q. The residue P was soluble in aqueous NH3 and also in excess
sodium thiosulfate. The hot solution Q gave a yellow precipitate with KI. The metals X and Y, respectively
are
(A) Ag and Pb (B) Ag and Cd
(C) Cd and Pb (D) Cd and Zn
Sol. A

X  AgNO3 , Y  Pb NO3 2

NaCl

AgCl PbCl2  Q 
P  Partly soluble in hot water 
AgCl  2NH3   Ag NH3  2  Cl KI
 Na3  Ag  S2 O3 2   2NaCl
AgCl  2Na2 S2 O3 
PbI2
 Yellow 

*4. Newman projections P, Q, R and S are shown below:

Which one of the following options represents identical molecules?

(A) P and Q (B) Q and S
(C) Q and R (D) R and S
Sol. C
(I) HO
Me HO
Me
Me
Me Me HO Me
Et Me 2,3,3  trimehyl pen tan 2 ol
Me Et Me
Me Et
Me Me
P 

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(II) H
Me H Et
HO H Me
H
Me H H Et H
Me Et Me
H Et H or Me Me
H Et
Me Me C Me OH

Me OH  Q
OH 3  ethyl,2  methyl pen tan 2ol
 Q
(III) Et
Et
H Et
H
Me
Et Et H
Me Et
OH Me OH
HO Me
Me R  Me

3  ethyl, 2  methylpen tan 2ol

(IV) Et
Et
CHMe2 OH
CHMe2
Me Me
OH Et HC
H OH
Me
H H H
H H
Me Me
S
3  ethyl, 2  methyl pentan  3ol
Only (Q & R) are same.

*5. Which one of the following structures has the IUPAC name 3-ethynyl-2-hydroxy-4-methylhex-3-en-5-
ynoic acid?
(A) (B)

(C) (D)

Sol. D
OH
H C C
2 COOH
3
1 3  ethynyl, 2  hydroxy, 4  methyl hex  3  en  5  ynoic acid
4
C CH3
C 5
H 6

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*6. The Fischer projection of D-erythrose is shown below:

D—Erythrose and its isomers are listed as P, Q, R and S in Column-I. Choose the correct relationship of P,
Q, R and S with D-erythrose from Column-II.

(A) P  2, Q  3, R  2, S  2 (B) P  3, Q  1, R  1, S  2
(C) P  2, Q  1, R  1, S  3 (D) P  2, Q  3, R  3, S  1

Sol. C
Given structure : (2R, 3R)
P   2R,3R  , so, identical. Hence P  2
Q   2S,3R  , so, Diastereomers. Hence Q  1
R   2R,3S  , so, Diastereomers. Hence R  1
S   2S,3S  , so, Enantiomers. Hence S  3

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