Narayana IIT Academy 22-03-20_Sr.

IIT_N-SC/N-C_JEE-Adv_GTA-7_2018(P2)_Key & Sol's

17.

1 1 1 
18.  R 2  2 
  n1 n2 
1 15 
For transition 4  1,  1.1107  
1 16 
16
1   970 A0
15 1.1107

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9
For transition 3  1 ; 2   1023 A0
8 1.110 7

4
For transition 2  1; 3   1212 A0
3 1.110 7

For Li atom  2  3 , for Transition 2  1,

2

1  1
 Rz 2 1  2 
 1
 2 
1
1   134 A0
1.110  9  0.75
7

For He  atom ( Z = 2) for transition 2  1,

1  1
 Rz 2 1  2 
 1
 2 
1
1   303 A0
1.110  4  0.75
7

CHEMISTRY
19.
NH 2
NaNO2 / HCl Re arrangement CH 2
OH Cl
OH
OH
CH 2 OH CH 2 Cl

20. Benzaldehyde reduces Tollen’s reagent while acetophenone is not while acetophenone
reacts hypoiodite and give iodoform reaction while benzaldehyde is not.
21. Phenol gives violet colour with FeCl3 and also reacts with aqueous NaOH but Anisole
OCH 3

doesn’t react with FeCl3 as well as NaOH. So FeCl3 and aqueous NaOH
can be used to distinguish phenol from anisole.
22. Both are non super impossible mirror image of each other and OH are in different
side.
23. S N 2 and E2 are the concerted mechanism, in which no intermediate is formed.
Br
Br
24. Styrene is is can be prepared from and by
OH

dehydrohalogenation and from by acid catalyzed dehydration

25.
26.
27.
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Narayana IIT Academy 22-03-20_Sr.IIT_N-SC/N-C_JEE-Adv_GTA-7_2018(P2)_Key & Sol's

28. PCl exists as anion.
6

2 PbS  3O2  2 PbO  2SO2

29.
M  238 g M  32 g
23.8 1 3
 Volume of oxygen at S.T.P  10000     22.4  336 litres
100 238 2
30.
 Volume of gas adsorbed/g of adsorbent  
  700  400 1  22400
 60mL / g

 760  0.0821 300  6
31.
2 A  4B  C
P0 0 0
P0  2 P 4 P P
 P1  P0  2P  P  4P  P0  3P
P0  0.1 atm; P1  0.145 atm
0.145  0.1  3P  3P  0.145  0.1  0.045
 P  0.015atm
1 0.1
t ln  t  47.8 s
7.48 10 3
0.1   2  0.015
32.  H    K a  C  1.77 104  0.5  0.9407 102 M
HCOOH

 H    1.8 105 1  4.2426 103 M

CH3COOH

 H   4.2426 103
Ecell  0.0591log10 RHS
 0.0591log
 H   0.9407 102
10
LHS

 Ecell  0.0204V

33. (1) 1.2% UREA is at temp. T

M UREA  60
1.2 1
Curea   10 
60 5
1 ST
  1  S  T 
5 5
(2)   2  2  ST  4ST
(3) Tb 
 0.52   5.85 1000  2  1.100 C
58.5  94.155
(4) Tb 
  1.8 1000  0.0520 C
0.52
180  98.2
Column-II
(p)   4 1 ST   4ST 

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Narayana IIT Academy 22-03-20_Sr.IIT_N-SC/N-C_JEE-Adv_GTA-7_2018(P2)_Key & Sol's
1 6.84 10
(q)    S  T   0.2 ST 
342
Therefore it can be seen
(1) and (q) have same osmotic pressure i.e.  
ST
 5 
(2) and (p) are isotonic solution and have same osmotic pressure
(3)   S  as Tb  1.100 C
(4)   r  as Tb  0.0520 C
34. Conceptual
35.
Or r 
p
M  2 d 
d
r1 p1 M 2 X1. pT M2
  
r2 p2 M1 X 2 . pT M1
(2) Partial pressure=mole fraction  total pressure
PA  xA  p
And pA  CA RT
(3) KE  T (Kinetic theory of gases)
8RT
(4) u Ar 
M

36. (A) d  d   bonding 

(B) p  d   bonding 

(C) p  d  antibonding 

(D) d  d   antibonding 
MATHS
2ln  x  3  ln  ax    x  3  ax
2
37.

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 x2   6  a  x  9  0
D  0  a  0,12
a  0  a  12
And a  0 also gives one negative root in  3, 0

   
cos  
y  b sin  b  2 
38. 
x  a cos  a    
sin  
 2 
 a e, 0 lies on it
     
b sin  .a sin   a e  a cos    b cos 
2  2 
       
cos  cos    sin  sin  
e  2   2 
   
cos  
 2 

1900 f 1990  2000

39.  
90 90 90
 f 1990   f 1990 
21     22    21, 23
 90  90
1990   f 1990  
1990  f 1990   19    90  
 19   90 
 f 1990  
Let    21  1990  f 1990   86  f 1990   1904
 90 
 f 1990  
Let    22  1990  f 1990    4  f 1990   1994
 90 

40. A) lim  esin x.ln  tan x   e tan x.ln sin x  

x  0

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Narayana IIT Academy 22-03-20_Sr.IIT_N-SC/N-C_JEE-Adv_GTA-7_2018(P2)_Key & Sol's
sin x ln  tan x  tan x ln  sin x 
 
lim  e 1/ x
e x 1/ x

x 0 
 
1+1=2
1  e x  1  cos x
B) lim
x 0 
sin x  1  e x  1  cos x 
x2  x x2 
1   .... 1   ..... 
lim
2!  1! 2!  1
 
x 0 sin x x
x 1  e  1  cos x
x
C)Base is exact 1
 n  1 n  2  n  3  1
D) lim
x  n  n  1 2n  1
6.
6
x y z c
41. Equation of L1   
0 b c
x y zc
Equation of L2   
a 0 c

iˆ ˆj kˆ
Direction of  is 0 b c  bciˆ  acjˆ  abkˆ
a 0 c

Equation of  is
bc  x  0  ac  y  0  ab  z  c   0

x y z
   1  0
a b c

Distance between L1 & L2 is


 0,0, 2c  ,  bc, ac, ab 
b 2 c 2  a 2 c 2  a 2b 2

1 2abc

4 b c  c 2 a 2  a 2b
2 2

1 1 1
   64
a 2 b2 c2

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 a r   ABC    a r   OAB   a r   OBC   a r   OCA 
2 2 2 2
42.

If A & C are on positive axes &B is on negative axis then equation of plane is
x y z
  1
2 3 4
If A & B are on positive axes & C is on negative axis then equation plane is
x y z
  1
2 3 4
1 3
1/2

43. I2  0 1  x 2 1  x 
dx

Let x  sin 
 /6
1 3
 /6 1  3  sec 2
2

I2    
2
d     
2
d
 sin  cos   tan  1
0 0

 2 2  2 

Let tan  y
2
2 3

2 1  3 dy  1
2 3

I  
0  y  1
2 
 2 1 3
y 1 0
 
 2 1 3  1 1 3 1  2 1  3  3 1
2
2

44. Let Q   0, 0, z1  , then P is image of Q in x  y  3

xp 0 yp 0 2  3
   3
1 1 2
 P   3, 3, z1 
  3  z12  25  z1  4
2

Length of PR  2 z1  8

45. Let the sides of parallelogram are a and b and smallest diagonal is d 1 and the larger
diagonal is d 2 . Then 2a 2  2b 2  d12  d 2 2 and d 2 2  3 d12 (given)

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Also by cosine rule in  ADB

a 2  b2  d12
cos 600   ab  d12 ------ (1)
2ab
  a  b   4 d12  a  b  2 d1
2
------ (2)
a
From (1) and (2) a  b  d1   1
b
46. Let x  7 x  6 x  5 x   x  1 q  x   f  x  , where f  x   ax  b
2015 3 2 2

Then
a  b  1  7  6  5 ............. (i)
a  b  1  7  6  5 ............. (ii)
 2a  2 14 10
a  1 7  5
 2015 x 2014  21x 2  12 x  5   x 2  1 q '  x   q  x  2 x  f '  x 
x  0, 5  q '  0  0  1  7  5
q '  0  8

The coefficient of r th ,  r  1 and  r  2  terms are in A.P.

th th
47.

Tr Tr  2
or coefficients of , 1, are in A.P. ------ (1)
Tr 1 Tr 1

Tr 1 n  r  1
 x
Tr r

Tr 1 14  r  1 15  r
 coefficient of   ------ (2)
Tr r r

Now put r  1 for r .

Tr  2 15   r  1 14  r
 coefficient of   ------ (3)
Tr 1 r 1 r 1

Also taking reciprocal of (2) coefficient of

Tr r
 ------ (4)
Tr 1 15  r

Hence from (1)

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