Sri Chaitanya IIT Academy, India: A Right Choice For The Real Aspirant Icon Central Office, Madhapur-Hyd

Sri Chaitanya IIT Academy 21-04-16_ Sr.
IPLCO/IC/ISB/LIIT _Jee-Adv_New Model-VII_P2_Key &Sol’s
Sri Chaitanya IIT Academy, India

A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON CENTRAL OFFICE, MADHAPUR-HYD
Sec: Sr.IPLCO JEE–ADVANCE _GTA-5 Date: 21-04-16
Time: 3 Hours New Model-VII_P2-Model Max Marks: 336
MATHS
1 2 3 4 5 6 7 8 9 10
ABCD AC ABD ABD BC ABCD ACD ABCD 5 1
11 12 13 14 15 16 17
2 2 1 1 7 2 A-Q; B-R; C-P; D-S
18 19 20
A-P; B-S; C-P; D-Q a-r, b-r ,c-s ,d-r a-r ,b-q, c-p, d-s
PHYSICS
21 22 23 24 25 26 27 28 29 30
ACD ABC D AD ACD BCD AB ACD 4 2
31 32 33 34 35 36 37 38 39 40
A-qr; B-q; A-q; B-q A-r; B-s A-r; B-s
4 4 5 2 1 6
C-pr; D-pr C-q; D-s C-p; D-q C-p; D-q
CHEMISTRY
41 42 43 44 45 46 47 48 49 50
B AC B BC ABCD AD AC ABCD 2 2
51 52 53 54 55 56
4 2 5 0 8 7
57 A -P Q S, B -R S, C -Q, D – RS 58 A - P; B - P; C - QS ; D – PRS
59 A-S; B-R; C-Q; D-P 60 A-RS; B-S; C-S; D-PQ
Sec: Sr.IPLCO/IC/ISB/LIIT Page 1

Sri Chaitanya IIT Academy 21-04-16_ Sr.IPLCO/IC/ISB/LIIT _JEE-ADV_(New Model-VII_P2)_GTA-5_Q.P
SOLUTIONS:-
MATHS
1. Assume (i), That is ABC  AC  CA . Now
ABC  A  B  C  AC  CA   AB  BC  CA   AC  AB  BC
Thus ( A  I )(B  I )(C  I )  ABC  AB  BC  AC  A  B  C  I   I
 Inverse of C  I  ( A  I )( B  I )  (C  I )( A  I )( B  I )   I
CAB  CA  AB  CB  C  A  B  I   I
CAB  CB  BC
Then i and iii are equivalent. Similarly we get i and ii equivalent
2.
2 x 3  px 2  qx  r  0
  x  a1   x  a3  x  a5    x  a2  x  a4   x  a6   0  f  x 
f  a1    a1  a2  a1  a4   a1  a6   0
f  a2    a2  a1   a2  a3  a2  a5   0
 f  x   0 has a root as  a1 , a2 
& f  a3   0 & f  a4   0
 f  x   0 has a root is  a3 , a4 
3. a) Let h  x   f  x   g  x 
h  x   f   x    g   x   0
 h x  e
b) Consider a continuous function defined on [0, 2], g(x)=f(x+1)-f(x)
g(0)=f(1)-f(0)= f(1)-f(2)
g(1)=f(2)-f(1)
g  0  g 1  0
g  c   0; c   0,1
f  c  1  f  c  ; c   0,1
f  x1   f  x2  ; x1  x2  1

ln  2  x  , in  0,1

  
c) f  x    sin x, in 1, 
  2
 ln 3  sin1
 , x 1
 2
Sec: Sr.IPLCO/IC/ISB/LIIT _P2_Solutions Page 2

5 5 5
4. a) 3  3C .2  3C .1  150
1 2
b) 7 C 5!  2520
2
 5! 5! 
d) 3    150
 2!2!1! 3!1!1! 
5. Conceptual
7. a) ax 2  2hxy  by 2  2 gx  2 fy  1  0
& h 2  ab  4  order
d)  ax  by  1 bx  ay  c   0
2 2
 ax  by  1   bx  ay  c 
   
 a 2  b 2   a 2  b2 
c)   1 & relation between p & q is given.
p2 q2
2 2
b)
 x  a 
 y  b  1 (a, b are given)
2
p q2
8. an21  10an an 1  an2  1  0
an2  10an 1an  an21  1  0
 an1 , an 1 are the roots of t 2  10tan  an2  1  0
 an 1  an1  10an , n  2, an 1.an1  an2  1 n  2
1 
 
dx 2 x 2 dx
9. a =    4 
 1
2
2  0 x  x 2  a 2  2   1
0
a2   x    
 x
1
  4

 x2  1    x2 1 dx 
2  0 x  x 2  a 2  2   1 0 x 4  x 2  a 2  2   1 
 
 2
x 1 1
I1   4 divide by x2 and put x   t
0 x  x  a  2  1
2 2
x

x2  1 1
I2  0 x4  x2  a 2  2   1 dx divide by x2 and put x   y
x
and evaluate
x
10. (1) Let   x    f  t  dt ,  '  x   f  x   x   0,  
0
x x 2
1 2 1 
On differentiating  f  t  dt    f  t  dt 
20 x 0 
2
 x  ' x   x  ' x 
We get    4    2  0
  x    x 
 ' x 2  2
i.e.,  and on integrating we have
 x x
  x   c.x 2  2
 
  '  x   2  2 c.x 1 2 , f  x   2  2 c.x 1   2

Since f  x  is continuous on 0,  and  
f  x   2  2 c.x 1 2
Since f 1   2  
2  c 1
1 1
0 f  x  dx  0  2  2  x
1 2
dx  1
11. n  S   53  125
Number of favorable ways.
  2,   1,   1
  3,   1,   2 (or)   3,   2,   1
  4,   2,   2 (or)   4,   1,   3
(or)   4,   3,   1
  5,   2,   3 (or)   5,   3,   2 or   5,   4,   1
Or   5,   1,   4
 n  E   10
 P  E   10 2
125 25
12.
T
1
P

A 1 1 B C
O
1 BP
sin     1  BP
OC BC
BP  1  sin 

ABP   
2
2
AP  4  1  sin    4 1  sin   sin 
2
 5  3sin 2   2sin 
2
 1  1 16
5  3  sin      .
 3 3 3
4
AP 
3
13. r 1
p q
So, the equation z 3  p z 2  q z  r  0
 
  z  1 z 2   p  1 z  1  0

a b
14. K1  K 4  K 7  .....  K 3n2 
2
K 2  K 5  K8  .....  K3n 1  c
ba
K3  K 6  K9  .....  K 3n 
2
a  b b  a   a  b   a  b 
 c    .  1
 2 2   2  2 
15. normal at P meets major axis
  a 2  b2  cos    a 2  b2  cos 
G ; 0  and Q  ; 2b sin  
 a   a 
   
2 2
a x y2
Locus of Q is 2
 2 1
a 2
 b2  4b
e  1 
12  4  1  2 
e  1   b
49 7
  3 
 a 2 
   
16. Then is possible only when  
cos 2    sin x  2 cos 2 x   1
4 
1
  
& tan 2  x  tan 2 x   0  2
 4 
Equation (1)   sin x  2 cos 2 x  k
 
4
 sin x  2 cos x  4k it is possible only when k  0
2
 2 sin 2 x  sin x  2  0
1
 sin x  , 2
2
 5
 x  2n   or  2n 
4 4

From equation (2) then only possible solution is x  2n 
4
 Number of solutions is 2
9 92 9999
1   2  .........  999
17. a) p  10 10 999
10
 9
10  9. 
 10 
p=1
 
b) cos cos x  sin x  cos    sin x  cos x
 2 

 
cos x  sin x  2n    sin x  cos x
 2 
 
cos x  n   cos x 
4 4
16   2
 sin x 
4

(or) sin x 
4
c) discontinuity points are 4 , 3, 2 , 1, 3, 4
2
d)  a 2  2 y   4 y 2  4 x 2
dy
4a 2  8x
dx
d2y 2

dx 2 a 2
18.a) x 2 1  c   x  a  c    b  c   0
Is an identity  c 1
a 1
b 1
a  b  c  3
b) according to the conditions all the roots of f  x  0 are to be +ve
c)
d)
19. a) If line cuts the graph at 6 points then using LMVT there exists atleast 5 points
where f '  x   p (slope of the line )
 using Rolle’s theorem there exists atleast 4 points where f ''  x   0
b)

(0, 1)
f '  x   0 x & Lt  f  x    , Lt f  x    also as x  , f  x    and x  , f  x   

x 1 x 1
 f  x  0 has one  ve root & one ve root

c)
y = -c
b2 b3 .............b6
b1
6
ai2  6 ai2 
f  x    c  0 , f '  x     2
i 1 x  bi  i 1  x  bi  
2
d) B  A
1
20. a) ee  , eh  2
2
x2  2 y 2  p 2
2 p22
x y 
2
2
9x
 36
y2
b) x1  2 R cos A
a  2 R sin A
dx1
  tan A
da
  tan A   tan B   tan C   3 3
 dx dy dz 
 3  1  1  1   15  6
 da db dc 
c)

(0, 1)
(1, 1)
D C
F
(0, x)
A B (1, 0)
E
(0, 0) (x, 0)
x 2 1 x 
Area CDFE  1   A
2  2 
1 x  x 2

2
1 5
“A” is maximum when x and Amax 
2 8
d) i)
A /6
Slope of OP > slope OQ


A sec A 
3 3
ii) slope OP > slope OQ
Q
P
A  
4 2

 A cos ecA 
2 2
iii) slope OQ > slope OP

 A cot A 
3 3
Q
P

PHYSICS
21. When particle passes through point 2 shown speed is zero and
speed is maximum when particle passes through point 4. Frame of
trolly in identical and continuously in trolly frame particle is
mv 2
performing uniform circular motion. T ; at all the position
l
22. Slope dy/dx is zero instantaneously that’s why instantaneous power
transfer in both case is zero. At point ‘B’ slope remains zero all the
time.
23. PV
0 1  2 R  200  - (I)
1
0 1  2 R  300 
PV - (II)
0 2  1R  500 
PV - (III)
1
0 2  1R  300 
PV - (IV)
During process pressure of two gas compartment remains same
equals to atmospheric
V1  V2  V11  V21 ; work done by two gas system on surrounding is zero.
Net heat trasnfered to gas in compartment 1  W  V  500 RJ
24. liq and glass contact angle is accute, so combination is wetting. In
gravity free space system will attain least P.E. surface energy of
glass, liq and vapour system will be become least.
25.  AR  A  2 A sin 450

 A 1 2 
 Phase of resulting motion differs with both by 1st and last by  4
Energy of resultant S.H.M= 1 mw2 A2 1 
2

2
2 
1 10
26. Density of block = 4
kg / m   103 kg / m 3
3
3  10 3
Buoyant force B = 3 × 10–4 × 103 × g = 3 N
 TB = 10 – 3 = 7 N
Reading of B = 14 + 3 = 17 N
Reading of C = {14 + (10 – 3) + 3}N = 24 N
27. capacitance of system is increased. Charge supplied by battery
increases. Potential difference across A is increased.
28. CONCEPTUAL
29. Geometrical path ‘d’ is equivalent to d / 2 is medium. At high temp
TH  4TLow  .
d  V
So   .
2 2 f
f min  4 Hz

30. Very close to conductor at out side point electric field will be
perpendicular and always equal to  ; where  is charge density at
0
that point.
31. When the frame has turned through at angle ,
  BA cos
y y
where A   2 xdy  2  y dy 
4
y 3/2
0 k 0 3 k
1
Since y  at 2
2
B 2 3/2 3
  a t cos 
3 K
d
By Faraday’s law, Eind 
dt
Ba 3/ 2 2 3  d  
or Eind   t sin   2
  3t cos  
3 K   dt  
When the frame turns through /4,
 
t 
 4
y 2 a 2a 
R   2 x  .2  t
k k 2 k 4
Eind     12  Ba k 4 Ba   12 
2 3/ 2
I  2

R 192 k 2a  48 2 
1
32. let time taken to hit OB are t1 & t2 respectively a g cos  t12
2
1 t
b g tan  t12 1  4 .
2 t2
33. Relative to ‘A’ , ‘C’ goes down with speed 4 m/s. ground frame speed of
c  4 2  32  5 m / s .
34.  = r2 [where  is a constant]
Charge in the shell (element)
dq = (4r2dr) = (4)r4dr
r 5
 Charge enclosed in sphere of radius r, q = 4  r 4 dr  4 r
0
5
By Gauss's theorem,
at r = R/2

5
Total charge enclosed, Q = 4 R
5
35. Velocity of ball just before striking the bat v0 = 2gh
v0  vb
e=  vb = v0 (1  e) = 2 gh
(1  e)
=1
v0  vb 1 e 1 e
36.  = I
 m 2
mg sin 45° × = 
2 3
N
N
45°
mg
3g
=
2 2
tangential acceleration of centre of mass (at) =  ×  = 3g

2 4 2
radial acceleration of centre of mass (ar) = m  = 0 (initially  is 0 )

2
17
net hing force N 2  N||2  mg  34 = 5.83 = 6 (rounded of to nearest integer)
4 2
38. (A) and (B) B is displacement node

 a = 0, v = 0 and E = 0 and deformation maximum  PE max.
(D) B is displacement antinods  a = max, KE = 0, PE = 0, V = 0
40. a) in case of  -decay continuous energy distribution is obtained (with out any
peak)
b) in  -decay energy distribution will be discreate
c) continuous distribution with dark line in between
d) continuous distribution with peak

CHEMISTRY
41. B
Sol: CH3Cl is formed by SN2 while CH3CHClC2H5 is formed by SNi.
42. AC
Sol: gold sol is obtained from AuCl3 by reduction while FeCl3 is hydrolysed to obtain
ferric hydroxide sol
Spondumene is simple chain silicate

Na2 S 2 O3 .5 H 2 O   Na2 S 5  Na2 SO4  H 2O
43. B
44. BC
Br
Br Br Br
alc KOH
+
Br Br
45. ABCD
It is an example of Sulphonation of aromatic ring; B is perchlorate and C is
hydronium ion
46. AD
Diazotization of aniline happens at a pH of around 6
B and C have pH above 7
47. AC
Eq of ferrous oxalate used for excess acid=2X1.5X3=9meq
Eq of excess H2SO4 (nf =6)=9
Eq of H2SO4 added for ammonia released from salt=3X2X2=12 (nf=2)
Eq of excess H2SO4 with nf 2 = 9X2/6=3meq
Eq of H2SO4 used up for NH3 = 12-3 = 9
Meq of ammonia in 1L=9X4=36
So W of ammonium chloride = 0.036X53.5=1.926g
%purity=19.26
48. ABCD
Integer:
49. 2
Sol:  = CRT × i
hence i = 1.1; so  = 0.1
and [H+] = c  = 0.1 x 0.1 = 10-2 M
pH = 2
50. 2
Sol: BaCrO4 – Yellow, soluble in dil HNO3
Hg2CrO4 – Red, soluble in conc. HNO3
ZnS – White, soluble in Conc. HNO3
BaSO4 – White, insoluble in all mineral acids
CH3COOAg and AgNO2 all are white solid and are soluble in dilute HNO3
solution
51. 4
sol: Let x% be the decrease in density of Ge crystals. Let ‘a’ be the total no. of Ge
atoms missing and ‘b’ be the no. of boron atoms replacing Ge atoms.
b
100  2.376 ..........(i )
a
72.6a  11b 
1    1  0.01x
N AV  N AV 
72.6a 11b
  0.01x ……….(ii)
N AV N AV
150 N
Also, b  6 AV  1  0.01x  ……………(iii)
10 11
 Solving (i), (ii) and (iii)
X = 4%
52. 2
53: 5
Sol:
PCl3  3H 2O  H 3 PO3  3HCl
Number of moles required to neutralise H3 PO3  2

Number of moles required to neutralise HCl = 3
Total number of moles of NaOH required to neutralise the solution = 5
54. 0
55. 8
Sol: 1st titration
1 1
Meq. Of NaOH  Meq. of Na2CO3  Meq. of HCl  50   5
2 10
2nd titration

1 1
Meq. of Na2CO3  Meq. of HCl  10   1
2 10
Meq. Of NaOH = 5-1 = 4
Meq. of NaOH  Equivalent weight
Wt. of NaOH 
1000
4  40

1000
= 0.16 g
56. 7
Matrix matching:
57. (A p, q, s), (B  r, s), (C  q), (D  r, s)
58. A  p; B  p; C  q,s ; D  pr
Mn has 6 oxides; MnO, Mn2O3, MnO2, MnO3, Mn2O7, Mn3O4
59. A-S; B-R; C-Q; D-P

60. A-RS; B-S; C-S; D-PQ
B shows cation frenkel defect
C shows anion frenkel defect

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Sri Chaitanya IIT Academy 21-04-16_ Sr.

IPLCO/IC/ISB/LIIT _Jee-Adv_New Model-VII_P2_Key &Sol’s

Sri Chaitanya IIT Academy, India

Sec: Sr.IPLCO/IC/ISB/LIIT Page 1

Sec: Sr.IPLCO/IC/ISB/LIIT _P2_Solutions Page 2

Sec: Sr.IPLCO/IC/ISB/LIIT _P2_Solutions Page 3

Sec: Sr.IPLCO/IC/ISB/LIIT _P2_Solutions Page 4

Sec: Sr.IPLCO/IC/ISB/LIIT _P2_Solutions Page 5

Sec: Sr.IPLCO/IC/ISB/LIIT _P2_Solutions Page 6

f '  x   0 x & Lt  f  x    , Lt f  x    also as x  , f  x    and x  , f  x   

 f  x  0 has one  ve root & one ve root

Sec: Sr.IPLCO/IC/ISB/LIIT _P2_Solutions Page 7

Slope of OP > slope OQ

Sec: Sr.IPLCO/IC/ISB/LIIT _P2_Solutions Page 8

Sec: Sr.IPLCO/IC/ISB/LIIT _P2_Solutions Page 9

Sec: Sr.IPLCO/IC/ISB/LIIT _P2_Solutions Page 10

tangential acceleration of centre of mass (at) =  ×  = 3g

radial acceleration of centre of mass (ar) = m  = 0 (initially  is 0 )

38. (A) and (B) B is displacement node

Sec: Sr.IPLCO/IC/ISB/LIIT _P2_Solutions Page 11

Number of moles required to neutralise H3 PO3  2

Sec: Sr.IPLCO/IC/ISB/LIIT _P2_Solutions Page 13

Mn has 6 oxides; MnO, Mn2O3, MnO2, MnO3, Mn2O7, Mn3O4

59. A-S; B-R; C-Q; D-P

Sec: Sr.IPLCO/IC/ISB/LIIT _P2_Solutions Page 14

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