CHEMISTRY

( I NORGANIC )

SHEET
Sheet Topic: d & f Block Elements

10. The equivalent mass of K2Cr2O7, when it acts as

Choose the correct answer :
oxidising agent in acidic medium is equal to
1. Ore of copper is
(1) Calamine (2) Dolomite M M M M
(1) (2) (3) (4)
(3) Malachite (4) Horn silver 3 2 6 5
2. Lunar caustic is the name of 11. Heating the mixture of Cu2O and Cu2S will give
(1) Silver chloride (2) Silver nitrate (1) Cu2SO3 (2) CuO + CuS
(3) Sodium nitrate (4) Potassium nitrate (3) Cu + SO3 (4) Cu + SO2
3. Which of the following species have highest magnetic 12. Calomel (Hg2Cl 2) on reaction with ammonium
moment? hydroxide gives
(1) Cu+2 (2) Fe+3 (1) HgO (2) Hg2O
+3
(3) Mn (4) Cr+3 (3) Hg(NH2)Cl · Hg (4) HgNH2Cl
4. Monds process belong with extraction of 13. In dichromate di-anion
(1) Ti (2) Ni (1) 4 Cr – O bonds are equivalent
(3) Mo (4) Fe (2) 6 Cr – O bonds are equivalent
5. Actinide series contains (3) All Cr – O bonds are equivalent
(1) 6 elements (2) 8 elements (4) All Cr – O bonds are non equivalent
(3) 10 elements (4) 14 elements 14. Which of the following does not form coloured
6. The number of unpaired electron in Mn2+ is complexes?
(1) 2 (2) 3 (1) Ni(II) (2) Cu(I)
(3) 4 (4) 5 (3) Fe(II) (4) Cr(IV)
7. Transition metal does not exhibit the property of 15. The stability of ferric ion is due to
(1) Formation of coloured salt (1) Completely filled d-orbitals
(2) Variable oxidation states (2) Half filled d-orbitals
(3) Inert pair effect (3) Half filled f-orbitals
(4) Catalytic activity (4) Completely filled f and d orbitals
8. Which of the following exhibits largest number of
16. Number of shells which are partially filled in inner
oxidation states?
transition elements?
(1) Zr (2) V
(1) 3 (2) 4
(3) Mn (4) Ni
(3) 2 (4) 1
9. KMnO4 act as oxidising agent in
(1) Acidic medium only 17. The reaction MnO 4  e   MnO 24 takes
(2) Neutral and acidic medium only place in
(3) Neutral and alkaline medium only (1) Basic medium
(4) Neutral, acidic and alkaline medium (2) Acidic medium
(3) Neutral medium
(4) Both acidic and basic medium

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18. Equivalent mass of KMnO4 in acidic, neutral and 27. The outer electronic configuration of gadolinium (At.
alkaline medium will be respectively No. 64) is :
(M = Molar Mass of KMnO4). [1] 4f 75d16s2 [2] 4f 85d06s2
8 1
[3] 4f 5d 6s 1 [4] 4f 75d06s2
M M M M M M
(1) , , (2) , , 28. The outer electronic configuration of the element No
5 3 1 5 1 3
(Nobelium. At. No. 102) is
M M M M M M [1] 5f 146d07s2 [2] 5f 136d17s2
(3) , , (4) , ,
3 1 5 1 3 3 [3] 5f 146d17s1 [4] none of the above
19. Dichromate and chromate ions exist in equilibrium. 29. The element with the electronic configura ion [Xe]54
Which are interconvertible by changing the pH of 4f 14 5d16s2 is a
the solution [1] representative element [2] transition element
2– 2–
2CrO4 Cr2O7 [3] lanthanide [4] actinide
The colour of solution pH < 5 and pH > 10 medium 30. The most characteristic oxidation state of
will be respectively lanthanides is :
(1) Orange, yellow (2) Yellow, orange [1] +2 [2] +3
(3) Orange, orange (4) Yellow, yellow [3] +4 [4] None of these
3
20. Fe 2  Fe (CN)6   A
4
Fe3   Fe (CN)6   B
A and B are respectively
Answer
(1) Prussian blue, Turnbull’s blue
(2) Turnbull’s blue, Prussian blue 1. (3) 2. (2) 3. (2)
(3) Ferric thiocyanate, Ferric ferrocyanide 4. (2) 5. (4) 6. (4)
(4) Ferrocyanide, Ferric ferrocyanide 7. (3) 8. (3) 9. (4)
10. (3) 11. (4) 12. (3)
21. The elements from cerium (At No. 58) to lutetium
13. (2) 14. (2) 15. (2)
(At No. 71) in which 4f energy levels are filled up
16. (1) 17. (1) 18. (1)
are called:
19. (1) 20. (2) 21. (4)
[1] lanthanides [2] rare earths 22. (3) 23. (2) 24. (4)
[3] lanthanones [4] all the above 25. (2) 26. (4) 27 (1)
22. The actinides showing + 7 oxidation state are: 28. (1) 29. (3) 30. (2)
[1] U, Np [2] Pu, Am
[3] Np, Pu [4] None of these
23. +2
In aqueus solution Eu acts as :
[1] an oxidising agent [2] reducing agent
[3] can act either ot these
[4] can act as redox agent
24. Give the ions having 4f 145do6so outer electronic
configuration:
[1] Yb2+ [2] Lu3+
[3] Yb3+ [4] Both [1] and [2]
25. The maximum oxidation state shown by actinides
is :
[1] +6 [2] +7
[3] +5 [4] +4
26. Which of the following is a lanthanide:
[1] Ta [2] Rh
[3] Th [4] Gd

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