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722 © 1980 American Society of Agricultural Engineers 0001-2351/80/2303-0722S02.00 TRANSACTIONS of the ASAE—1980
TABLE 1. STORAGE DEVICE VARIABLES DURING THE TESTS
Soil Soil
Variable 1.4 m 3 /min 2.8 m 3 /min Rock Salt
*(Telkes, 1 9 7 4 )
analytical procedures available at that time are presented materials is a very difficult task. Procedures have been
and discussed. Parkerson (1951), concerned about the developed for the evaluation of commercial thermal
relationship between soil physical properties and soil storage devices (Lorsch et al., 1976; Hill et al., 1976;
thermal properties, investigated the existing theory of Kelly and Hill, 1975) but these procedures rate the
soil thermal characteristics and developed design equa- design of the storage container as much as the storage
tions that could be used by engineers sizing soil heat material. This inseparability of the storage material and
pump installations. Cropsey (1966), attempting to cor- the design of the storage container during testing ap-
relate some experimental results with the various theories pears unavoidable.
on heat transfer to a saturated soil showed good agree- For the purposes of these laboratory tests, small
ment with the heat transfer equations given by Ingersoll storage devices (1 mJ/C) were designed and constructed
and Plass (1948). in accordance with presently available design informa-
Analytical methods for determining the heat flux in tion from the literature. Some of the design variables are
phase change materials have focus on two areas, the listed in Table 1. Because of the storage media and
mechanism of phase change (Luikov, 1968) and the storage configuration interaction, the testing procedure
design of phase change heat storage systems (Morrison that appears most feasible involves testing the heat
and Abdel-Khalik, 1978). Recently, Morrison and storage system under similar conditions of storage
Abdel-Khalik (1978) considered various models for com- volume and air volumetric flow rates. Any differences in
parison of rock and phase change heat storage systems. performance between the systems can then be attributed
They concluded that the approach of Hughes et al. to the storage material.
(1976) adequately describes the storage performance The rock used in the rock storage was unwashed septic
characteristics. For most solar collection systems, about gravel between 19 mm and 63.5 mm in diameter pur-
4 times more volume is needed for rock storage as for chased from a local quarry. The storage container has a
phase change material heat storage. 0.29 m plenum on each end for air distribution and
utilized 3.2 mm expanded metal to constrain the rock.
The cross-section to air glow for the rock bed was 0.55
PROCEDURE m2. Styrofoam insulation (25.4 mm) was used to insulate
Comparing the performance of thermal storage the perimeter of the storage device.
JLi
STORAGE DEVICE
.3 .6 .9 1.2
cc
2
UJ
a.
UJ 30
15 mm
FIG. 5 Longitudinal salt temperature profiles at various times. tion in air space was 4.42 mm while the space near the
top was 10.82 mm. The variation in air space caused
from the laboratory test results. Due to this temperature more air to flow through the top. This result indicates
variation, it would appeat most advisable to design rock that additional structural support may be necessary to
heat storage devices so that air flow is vertical instead of insure proper spacing between the trays and that not
horizontal. more than 10 trays high should be stacked. Upon
heating, some leakage of salt out of the trays occurred.
Soil Heat Storage
The results indicate that the major limiting factor Heat Storage Comparison
found with the soil heat storage is the low heat transfer A heat comparison of the outlet temperature for rock,
rate from the air to the soil due to low surface area per soil and salt heat storage tests as a function of time is
unit volume. Fig. 4 shows the air temperature profiles shown in Fig. 6. The soil storage has an average
during energy charging for 24 h and discharging for 48 h temperature drop of 6 °C during charging and an
at an airflow of 1.4 mVmin. The temperature drop of the average temperature gain of 4 °C during discharging.
air over the length of the storage varies from 14 °C at the The rock bed showed the most significant average
beginning of the charging cycle to 4 °C after 24 h. There temperature drop of 27 °C during charging and 10 °C
is at the most a 4 °C temperature gradient through the during discharging. If the air flow were reversed during
soil as shown in Fig. 4, therefore the rate limiting factor discharging, the outlet air temperature would be higher.
is the convective heat transfer from the air. Air flow tests As indicated in Table 1 the amount of heat transferred
of 2.8 mVmin showed similar trends. The Reynold's over the entire test period was approximately the same
number for the tests were in the turbulant range, 1.8 X for the soil storage as compared to rock. However, the
104 for the 1.4 mVmin test and 3.7 X 104 for the 2.8 low temperature drop for the soil system results in lower
mVmin test. efficiency.
Calculations of the convective heat transfer coefficient The salt heat storage average temperature drop during
from the laboratory tests showed good agreement with charging was 20 °C however, during discharging the
the empirical equations for smooth pipes found in average temperature rise was 7 °C with a final steady
McAdams (1954) and McCabe and Smith (1976) if the state discharge temperature rise of 3 °C. This large dif-
total surface area of the ribs in the tile was used. The ference between the rate of heat tranferred during charg-
heat transfer coefficient for the soil storage was found to ing and the rate released during discharging was due to
be 12.50 and 18.05 W/m 2 'K for 1.4 mVmin and 7.8 the temperatures used in the tests. The melting point of
mVmin respectively, however since the amount of heat Glauber's salt (32 °C) was near the initial bed
transfer area was only 2 m2 the average temperature drop temperature. This means that there was a large
of the air was only 6 °C. temperature differential (AT = 30 °C) for heat transfer
to occur during charging but a small differential (AT = 5
Phase Change Salt Heat Storage °C) during discharging. The discharge temperature
Thermocouples located in the Glauber's salt trays were dropped quickly from 50 °C to near 3 °C where it reach-
able to monitor the salt temperature during charging and ed a steady value. The initial high temperature was due
discharging as shown in Fig. 5. The amount fo heat to the specific heat of the material however, since the
transfer area was 9 m2 and the Reynold's number for the bulk of the heat stored is as latent heat, most of the
run was in the laminar range (212). The calculated heat energy would be released near 30 °C. When designing a
transfer coefficient was 8.38 W/m 2 , K based on flat plate PCM storage system, it is important to realize that the
empirical equations (McCabe and Smith, 1976) which temperature differential between the charging and
correlated well with the experimentally determined discharging temperatures, and the phase change
value. temperature will dictate the rate of heat transfer in a
As the temperature of the storage increased it was PCM system.
found that the plastic containers lose their rigidity. The Hill et al. (1976), Kelly and Hill (1975) and Lorsch et
salt temperature varied perpendicular to air glow by as al. (1976) present a method of rating thermal storage
much as 18 °C from the top to the bottom. Measurement devices based on the accumulation for a time period (T)
of the air space between trays with a micrometer revealed determined by;
that the spaces near the middle of the stack was 4.42 mm TSC
while the space near the top was 10.82 mm. The varia- r = [i]
C A *G*AT
A thermal efficiency (TE) can be defined as the tained from the Laplace transform of equation [2] where
measured accumulation of the storage over the time Ts remains essentially constant:
period (T) divided by the theoretical storage capacity
(T g - T s )/(T g o - T s ) = exp [-h/P A C A ) (A/V A ) (x/u)]
(TSC). Thermal efficiency (TE) is simply a measure of
the fraction of the energy absorbed in the storage device. for t > x/u [4]
From Table 2 it can be seen that for the system tested,
the salt has a much higher thermal efficiency of 0.78 This solution is based on the idealized case for
compared to the other two heat storage efficiencies of temperature of the solid remaining constant. This is an
0.38 and 0.31 for rock and soil respectively. acceptable assumption since the bulk of the stored
As shown in Table 2, the efficiency of all systems, par- energy is usually latent heat.
ticularly for the rock, increases when no heat loss exists. When comparing the solutions for the sensible heat
This points out the importance of the need for adequate storage of Schumann (1929) and phase change storage,
insulation in a heat storage device. The optimum in- the solution of the sensible heat storage collapses to the
sulation thickness is a matter of economic evaluation and solution of the phase change heat storage when t = x/u,
is especially important for long-term applications. For the residence time. Therefore, the dimensionless
the case of no heat loss, the salt and rock storage are parameter (h/pACA) (A/WA) (x/u) can be used as a
more efficient than the soil storage by approximately 2.6 means of comparing the performances of both PCM and
times. Several variables seem to be related to thermal sensible heat storage on a common basis. This parameter
storage efficiency. Airflow has a significant effect on effi- is important when compating different types of heat
ciency. As shown in Table 2, increasing the airflow from storages or when comparing different configurations of
84 m 3 /h to 168 m 3 /h for the soil storage decreased the ef- the same type of heat storage in order to keep the
ficiency from 0.31 to 0.25. Even though h increases with temperature response the same.
increase in airflow, increasing the air flow rate decreases The storage parameter can assist in determining the
residence time, thereby decreasing TE. Therefore, for relative effect of fluid velocity, length of airflow path,
every system there will exist a mass flow to give the max- volume of storage system, area of heat transfer and void
imum TE. The optimum flow rate will depend on the fraction. The equivalent length of storage can be deter-
rate of heat transfer as compared to the rate of heat mined for various systems. The temperature response
losses. When heat losses are neglected, the thermal effi- characteristics of the 3.0 m long soil system at 1.4
ciency for all storage media is directly related to mVmin is equivalent to 0.10 m of the rock heat storage
residence time. The amount of heat transfer surface area and 0.17 m of the salt heat storage used in this study.
also seems to have an effect on efficiency. Based on the storage parameter defined above, the soil
The above method is useful for evaluating existing storage would have to be 150 m long, to have exactly the
storage systems, however, it provides little guidance to same air temperature response as the rock storage used
the engineer as to the design variables important for effi- in this work.
cient heat storage. It is necessary to develop a simple Lower airflows will increase the efficiency of the system
evaluation criteria for effective heat storage comparison as indicated by the results of the soil storage in Table 2.
and design. Since the storage number is proportional to h/u the total
dependency of velocity on heat transfer efficiency will be
Thermal Storage Parameter proportional to u° Vu. Decreasing the velocity by 1/2 in-
The equation relating the fluid temperature profile creases the storage parameter by 14 percent which is
along the length of any heat storage system can be ex- comparable to the increase in efficiency given in Table 2.
pressed in rectangular coordinates as However, lower airflows mean that more storage is need-
9 T 9 T
ed at a given total airflow. On an equivalent basis the 53
A A
^ACAVA[-^+u-^=hAfTs-TA} ™
m soil storage could be replaced by four parallel pipes
one foot apart each having 1/4 the airflow and 40 m
long. The relative efficiency of the heat storage system
Solution of equation [2] for both the sensible and latent
can be determined from the product of the ratios of heat
heat storage systems would provide such a means of heat
transfer coefficient to fluid heat capacity, heat transfer
storage evaluation. Such a solution will provide the
surface area to void volumes and residence time for a
temperature profile at any place in the storage at any
system with (h)(x1)/(k) < 0.1.
time. The solution for the sensible heat storage where
An unsteady-state finite difference model for each of
Bi = (h) (x, )/(k) < 0.1 [3] the storage systems was developed based on equation [2]
(Holman, 1972; Geankoplis, 1978). The physical proper-
is available from Schumann (1929). ties used for each system are listed in Table 1. Based on
The solution for the phase change material can be ob- observations, the temperature range for salt phase
Paper No. 76-3507. ASAE, St. Joseph, MI 49085. G Air mass flow rate k g / h
44 Wilson, G. E., D. R. Price, L. D. Albright, N. R. Scott, R. W. h Heat transfer coefficient J/m 2 -C-h
Langhans and P. Chandra. 1977. Experimental results of a greenhouse k Thermal conductivity W / m ' K
solar collection and modular gravel storage systems. 34th Annual Pro- LH Latent Heat of phase change material J / k g
gress Resport to the New York Farm Electrification Council. M Mass of storage material kg
pA Density of air k g / m 3
t Time h
NOMENCLATURE T* Temperature of air C
Tgo Initial gas temperature C
A Heat transfer surface area m2. T, Temperature of solid C
Bi Biot number (hx^/k TSC (Theoretical Storage Capacity) (C*AT + LH)*M J
C^ Heat capacity of air J/m 3 -C u Velocity of air m / h
Cv Heat capacity of solid J / m 3 - C V.4 Volume of air m 3
AT T h e temperature difference between the initial storage bed V, Volume of solid storage material m
temperature a n d the inlet air temperature x Distance along storage bed m
f Void fraction (Vol. of air/Vol. total) x. Half thickness for heat transfer m