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Thermal Storage Comparison and Design for Rock,

Saturated Soil and Sodium Sulfate Decahydrate for


Agricultural Applications
Steven R. Eckhoff, M a r t i n R. O k o s
ASSOC. MEMBER ASSOC. MEMBER
ASAE ASAE

ABSTRACT is also defined as an aid in comparing and designing


HREE thermal storage media; water, saturated soil, thermal storage devices.
T rock and phase change materials, were tested to
determine their feasibility as a media for a thermal L I T E R A T U R E SURVEY
storage to be used for grain drying. The thermal ef- The application of rock storage to different
fectiveness of phase change material, rock and saturated agricultural energy storage needs has been tried by
soil was found to be 0.79, 0.38 and 0.31, respectively. A various researchers. King-Ling (1975) used a rock
dimensionless thermal storage parameter is derived to storage device in order to store heat for a solar machine
aid in comparing and designing thermal storage devices. shed. Davis (1958, 1959), Mowry and Davis (1960,
1901), and Mowry (1963) used rock storage as part of a
INTRODUCTION solar supplemented heat p u m p . Greenhouse heating us-
Solar grain drying is attracting the interest of many ing rock storage has been documated by Huang et al.
farmers as a means of hedging against increasing cost (1975), Bowers et al. (1975; 1976), Willits et al. (1976),
and decreasing availability of petroleum products. Wilson et al. (1977), Baird et al. (1977) and Price et al.
One way to increase the amount of useable energy (1977).
from a solar collector would be to use large thermal Some of the early work on heat transfer between a pipe
storage facilities which would store heat from the late and soil was done by researchers investigating soil as a
summer and early fall to be used in the late fall for grain heat sink or source for the heat p u m p . Ingersoll et al.
drying. Other agricultural applications for heat storage (1948a, 1948b), Guernsey et al. (1949), King and Martus
include livestock ventilation, air heating, farm shop (1947), Pappas and Freberg (1949), Pease et al. (1947),
heating and possibly even home heating. Several and Kemler (1947) all concluded the same basic problem
materials are available for long term heat storage. These with using soil. They found that heat transfer to the soil
include rock, phase change materials and soil. Design in- became difficult as the soil dried out. Other work related
formation on heat storage is available for the rock and to the heat transfer is soils has been in the area of waste
phase change storage devices but very little is available heat utilization (Kendrick and Haven, 1973; Shapiro and
on soil storage. Roller, 1975; Sepaskhah et al., 1973; Slegel and Davis,
On a crop production farm, one of the most plentiful 1975). The major problem again seems to be the migra-
materials available is the soil. Soil has many tion of the ground water from the heat transfer pipes.
characteristics that make it a desirable storage material. One of the main problems with rock and soil as heat
It has a high heat capacity when wet, is readily available, storage devices is the large volume required. Phase
and can be considered as a free material if a proper loca- change materials can store up to 100 times the energy per
tion on the farm is selected. It can be used to store heat unit weight per change in degree temperature. There are
by blowing air through an array of parrallel pipes buried many different materials that change phase at a
in an encased soil mass. The soil mass would be encased temperature that is suitable for solar heating applica-
in a moisture impermeable liner to prevent moisture dif- tions (Eckhoff, 1977). Sodium sulfate decahydrate
fusion away from the heat transfer pipes and therefore, (Glauber's Salt), which changes phase at 32 °C, has been
retain the system's heat capacity. one phase change material (PCM) that has been propos-
This paper presents the results of a research effort to ed for home heating for many years. This salt has the ad-
determine how three different storage materials; rock, vantages of a high heat of fusion, low cost compared to
saturated soil and Glauber's salt, compare in thermal other PCM's and it is easily available in large quantities
performance and economics as they relate to thermal (Telkes, 1974).
storage. Factors such as storage capacity, heat stratifica- Schumann (1929) developed an analytical solution for
tion, heat loss and heat transfer characteristics which transient heat flow in a rock bed. In recent years, com-
will affect the potential utilization and design of storage puter models have been developed to simulate the tran-
devices will be investigated. A dimensionless parameter sient thermal response of the rock storage device. Some
such models are presented by M u m m a and Marvin
Article was submitted for publication in February 1979; reviewed (1976), Duncan et al. (1976) and Duffie and Beckman
and approved for publication by the Electric Power and Processing
Division of ASAE in August 1979.
(1974). While the models appear reliable, their major
The authors are: STEVEN R. ECKHOFF, Agricultural Engineer, problem is the large amount of computations, hence
Agricultural Engineering Dept., Purdue University; and MARTIN R. computer time, that is required (Klein, 1975). Analytical
OKOS, Associate Professor, Agricultural Engineering Dept., Purdue solutions for various conditions of heat transfer in soil
University, W. Lafayette, IN.
were developed by Guernsey et al. (1949).
Acknowledgment: The authors wish to express their sincere ap-
preciation for the help of Dr. V. M. Puri and Mr. M. Broder for their Ingersoll et al. (1948), discussed the theroy of earth
technical assistance in the preparation of this work. heat exchangers for heat p u m p applications. The

722 © 1980 American Society of Agricultural Engineers 0001-2351/80/2303-0722S02.00 TRANSACTIONS of the ASAE—1980
TABLE 1. STORAGE DEVICE VARIABLES DURING THE TESTS

Soil Soil
Variable 1.4 m 3 /min 2.8 m 3 /min Rock Salt

Length 3.05 m 3.05 m 1.83 m 0.61m


Width 0.30 m 0.30 m 0.91 m 0.30 m
Height 0.30 m 0.30 m 0.61 m 0.61 m
Volume 0.27 m 3 0.27 m 3 1.02 m3 0.11 m 3
Mass 4 9 7 . 8 Kg 4 9 7 . 8 Kg 1634 Kg 7 5 Kg
Density 1757 Kg/m3 1757 Kg/m3 1634 Kg/m3 1460 Kg/m3 *
(Bulk)
External
surface area 3.75 m 2 3.75m2 8.53 m 2 2.59 m 2
(incl. p l e n u m ) (incl. p l e n u m )
Thermal
conductivity 5 0 4 5 J/h-m-°C 5 0 4 5 J/h-m-°C 1603 J/h-m-°C* 2055 J/h-m-°C*
Specific h e a t 4 x 106 J/m3-°C* 4 x 106 J / m 3 - ° C * 1.3 x 1 0 6 J / m 3 - ° C * 3 3 4 2 J/Kg-°C*
(Liquid)
2 0 8 9 J /Kg-° C*
(Solid)
Latent heat NA NA NA 253,000 J/Kg*
Flow rate 84m3/h 168m3/h 84 m 3 /h 84 m 3 / h
Mass flow rate 9 5 . 7 Kg/h 1 9 1 . 3 Kg/h 9 5.7 Kg/h 9 5 . 7 Kg/h
Air velocity 10,698 m/h 21,395 m/h 436 m/h 914 m / h
Superficial flow area 0.0079 m 3 0.0079 m2 0.55 m2 0.019 m 2
Superficial air velocity 10,698 m/h 21,395m/h 152m/h 457 m/h
Heat transfer area 1.98 m 2 1.98 m 2 78 m 2 8.92 m 2
Heat transfer
coefficient 46,000 J/m2-°C-h 65,000 J/m2-°C-h 11,600 J/m2-°C-h* 30,200 J/m2-h-°C*
Equivalent d i a m e t e r 0.1 ra 0.1 m 0.87 m 0.46 m
Length of h e a t
transfer p a t h 3.05 m 3.05 m 1.83 m 0.61 m
Thermal diffusivity 0.00126 m 2 / h 0.00126 m 2 / h 0.007 m 2 / h * 0 . 0 0 0 6 9 m 2 /h*
(Solid)
0 . 0 0 0 4 2 m 2 /h*
(Liquid)
Reynolds no. 1.8 x 1 0 4 3.7 x 1 0 4 71 212
Pectelt No. 8.6 x 1 0 5 1.7 x 1 0 6 5.4 x 1 0 4 6.1 x 1 0 6
(Solid)
1.0 x 1 0 6
(Liquid)
Nusselt N o . 0.92 1.30 1.08 6.78
Ave. rate of h e a t
6
accumulation 1.04 x 1 0 J / h 6
1.55 x 1 0 J / h 1.30 x 1 0 6 J / h 2.70 x 1 0 6 J / h
Ave. rate of h e a t losses 0.067 x 106 J/h 0.332 x 106 J/h 1.70 x 1 0 6 J / h 0.253 x 106 J/h
Ave. rate of h e a t
transfer p e r u n i t vol 3.85 x 1 0 6 J / h - m 3 5.74 x 1 0 6 J / h - m 3 1.27 x 1 0 6 J / h - m 3 2.4 x 1 0 6 J / h - m 3
Biot n u m b e r h V / k A 1.2 1.75 0.0212 0.18

*(Telkes, 1 9 7 4 )

analytical procedures available at that time are presented materials is a very difficult task. Procedures have been
and discussed. Parkerson (1951), concerned about the developed for the evaluation of commercial thermal
relationship between soil physical properties and soil storage devices (Lorsch et al., 1976; Hill et al., 1976;
thermal properties, investigated the existing theory of Kelly and Hill, 1975) but these procedures rate the
soil thermal characteristics and developed design equa- design of the storage container as much as the storage
tions that could be used by engineers sizing soil heat material. This inseparability of the storage material and
pump installations. Cropsey (1966), attempting to cor- the design of the storage container during testing ap-
relate some experimental results with the various theories pears unavoidable.
on heat transfer to a saturated soil showed good agree- For the purposes of these laboratory tests, small
ment with the heat transfer equations given by Ingersoll storage devices (1 mJ/C) were designed and constructed
and Plass (1948). in accordance with presently available design informa-
Analytical methods for determining the heat flux in tion from the literature. Some of the design variables are
phase change materials have focus on two areas, the listed in Table 1. Because of the storage media and
mechanism of phase change (Luikov, 1968) and the storage configuration interaction, the testing procedure
design of phase change heat storage systems (Morrison that appears most feasible involves testing the heat
and Abdel-Khalik, 1978). Recently, Morrison and storage system under similar conditions of storage
Abdel-Khalik (1978) considered various models for com- volume and air volumetric flow rates. Any differences in
parison of rock and phase change heat storage systems. performance between the systems can then be attributed
They concluded that the approach of Hughes et al. to the storage material.
(1976) adequately describes the storage performance The rock used in the rock storage was unwashed septic
characteristics. For most solar collection systems, about gravel between 19 mm and 63.5 mm in diameter pur-
4 times more volume is needed for rock storage as for chased from a local quarry. The storage container has a
phase change material heat storage. 0.29 m plenum on each end for air distribution and
utilized 3.2 mm expanded metal to constrain the rock.
The cross-section to air glow for the rock bed was 0.55
PROCEDURE m2. Styrofoam insulation (25.4 mm) was used to insulate
Comparing the performance of thermal storage the perimeter of the storage device.

1980—TRANSACTIONS of the ASAE 723


, SMALL
ROTAMETER CHARGING
DISCHARGING

JLi

STORAGE DEVICE

.3 .6 .9 1.2

FIG. 1 Schematic of laboratory test equipment. DISTANCE FROM INLET (meters)


FIG. 2 Longitudinal bed temperature profiles—24 to 48 h.
The phase change storage consisted of 48 trays of
Glauber's salt mixture. Each tray was 0.3 m X 0.3 m X storage device and monitored during the test. Inlet and
2.5 cm and contained 1.8 kg of salt. The trays which are outlet air temperatures were measured with thermopiles
fabricated to form an air heat exchanger when stacked, to determine the heat transfer to the storage. Data ac-
were stacked in two columns of 24 trays each in accor- quisition was done with a programmable multiplexer
dance with manufacturer recommendations (Solar, Inc., capable of automatically sampling thirty channels of in-
1975). formation at designated intervals. The multiplexer was
The soil used in the water saturated-soil device was connected to a cassette tape drive where the information
blended top soil consisting of 49.6 percent sand, 41.5 was stored on cassette tape until it could be processed on
percent silt and 8.9 percent clay. The soil had an initial the computer system.
moisture content of 12.0 percent but water was added The air tlow was measured by the use of two
until the moisture content reached 24.5 percent. Above rotameters in parallel. Air temperature was maintained
this level the soil was over saturated and lost structural by thermostatically controlled heaters. The inlet air was
capabilities. Thermal conductivity of the soil was preconditioned with an Aminco unit. The air mass tlow
measure experimentally by a thermal conductivity probe rate was controllable within 3 percent and the
(Sweat and Haugh, 1974) and determined to be 1.40 temperature could be controlled within 1.0 °C. Fig. 1
W / n r K (Kelvin). The soil was contained with a 20 mm shows a schematic of the laboratory test equipment.
plactic liner and was insulated with 50.8 mm of
styrofoam insulation. Heat transfer from the air was RESULTS AND DISCUSSION
achieved by using a 10.2 cm unperforated ribbed plastic Rock Heat Storage
drainage tile through the center of the soil mass. Longitudinal temperature profiles of the rock heat
The method used to compare the thermal properties of storage for various times are shown in Fig. 2. During the
the materials was to subject the storage, initially at a twenty-four hour charging cycle, heat quickly transferred
uniform temperature, to a step change in inlet air to the rocks closest to the inlet air plenum, giving an in-
temperature and then monitor the thermal response of dication of the high rate of heat transfer. However, the
the storage. In all four tests, the initial bed temperature air How through the rock is in the laminar range (Re =
was 27 °C and the step change was to 62 °C (AT = 35 71) and the convection heat transfer coefficient was
°C) for 24 h. The inlet air temperature was then dropped found to be only 0.307 W / m 2 K (Lof and Hawley, 1948).
27 °C again for discharging during the next 24 h. The The large surface area, (78 m 2 ) to volume (lm 3 ) of
charging and discharging period was 48 h each for an air storage media, gives the indication of good convective
How rate of 1.4 mVmin in the second soil storage test. heat transfer and allows for the rapid heat build up near
Twenty-nine thermocouples were located within each the inlet. In the laboratory test, 70 percent of the heat ac-
cumulated for the first six hours of the run was in the
CHARGING
DISCHARGING first 0.3 m of the storage bed. As much as a 12 °C ver-
tical temperature stratification in the rock was observed

cc

2
UJ
a.
UJ 30

15 mm

0 254 50.8 76.2


6 12 18 2 5 3 1
DISTANCE FROM PIPE (mm)
DISTANCE FROM INLET (meters)
FIG. 4 Radial temperature profiles vs. time at 2.4 m from the inlet for
FIG. 3 Air temperature in soil storage tile at various times. the 1.4 mVmin test.

724 TRANSACTIONS of the ASAE—1980


CHARGING
DISCHARGING

0 10 ~20 30 "~ 40~


TIME (hours)
FIG. 6 Outlet air temp for all three storages.

FIG. 5 Longitudinal salt temperature profiles at various times. tion in air space was 4.42 mm while the space near the
top was 10.82 mm. The variation in air space caused
from the laboratory test results. Due to this temperature more air to flow through the top. This result indicates
variation, it would appeat most advisable to design rock that additional structural support may be necessary to
heat storage devices so that air flow is vertical instead of insure proper spacing between the trays and that not
horizontal. more than 10 trays high should be stacked. Upon
heating, some leakage of salt out of the trays occurred.
Soil Heat Storage
The results indicate that the major limiting factor Heat Storage Comparison
found with the soil heat storage is the low heat transfer A heat comparison of the outlet temperature for rock,
rate from the air to the soil due to low surface area per soil and salt heat storage tests as a function of time is
unit volume. Fig. 4 shows the air temperature profiles shown in Fig. 6. The soil storage has an average
during energy charging for 24 h and discharging for 48 h temperature drop of 6 °C during charging and an
at an airflow of 1.4 mVmin. The temperature drop of the average temperature gain of 4 °C during discharging.
air over the length of the storage varies from 14 °C at the The rock bed showed the most significant average
beginning of the charging cycle to 4 °C after 24 h. There temperature drop of 27 °C during charging and 10 °C
is at the most a 4 °C temperature gradient through the during discharging. If the air flow were reversed during
soil as shown in Fig. 4, therefore the rate limiting factor discharging, the outlet air temperature would be higher.
is the convective heat transfer from the air. Air flow tests As indicated in Table 1 the amount of heat transferred
of 2.8 mVmin showed similar trends. The Reynold's over the entire test period was approximately the same
number for the tests were in the turbulant range, 1.8 X for the soil storage as compared to rock. However, the
104 for the 1.4 mVmin test and 3.7 X 104 for the 2.8 low temperature drop for the soil system results in lower
mVmin test. efficiency.
Calculations of the convective heat transfer coefficient The salt heat storage average temperature drop during
from the laboratory tests showed good agreement with charging was 20 °C however, during discharging the
the empirical equations for smooth pipes found in average temperature rise was 7 °C with a final steady
McAdams (1954) and McCabe and Smith (1976) if the state discharge temperature rise of 3 °C. This large dif-
total surface area of the ribs in the tile was used. The ference between the rate of heat tranferred during charg-
heat transfer coefficient for the soil storage was found to ing and the rate released during discharging was due to
be 12.50 and 18.05 W/m 2 'K for 1.4 mVmin and 7.8 the temperatures used in the tests. The melting point of
mVmin respectively, however since the amount of heat Glauber's salt (32 °C) was near the initial bed
transfer area was only 2 m2 the average temperature drop temperature. This means that there was a large
of the air was only 6 °C. temperature differential (AT = 30 °C) for heat transfer
to occur during charging but a small differential (AT = 5
Phase Change Salt Heat Storage °C) during discharging. The discharge temperature
Thermocouples located in the Glauber's salt trays were dropped quickly from 50 °C to near 3 °C where it reach-
able to monitor the salt temperature during charging and ed a steady value. The initial high temperature was due
discharging as shown in Fig. 5. The amount fo heat to the specific heat of the material however, since the
transfer area was 9 m2 and the Reynold's number for the bulk of the heat stored is as latent heat, most of the
run was in the laminar range (212). The calculated heat energy would be released near 30 °C. When designing a
transfer coefficient was 8.38 W/m 2 , K based on flat plate PCM storage system, it is important to realize that the
empirical equations (McCabe and Smith, 1976) which temperature differential between the charging and
correlated well with the experimentally determined discharging temperatures, and the phase change
value. temperature will dictate the rate of heat transfer in a
As the temperature of the storage increased it was PCM system.
found that the plastic containers lose their rigidity. The Hill et al. (1976), Kelly and Hill (1975) and Lorsch et
salt temperature varied perpendicular to air glow by as al. (1976) present a method of rating thermal storage
much as 18 °C from the top to the bottom. Measurement devices based on the accumulation for a time period (T)
of the air space between trays with a micrometer revealed determined by;
that the spaces near the middle of the stack was 4.42 mm TSC
while the space near the top was 10.82 mm. The varia- r = [i]
C A *G*AT

1980—TRANSACTIONS of the ASAE 725


TABLE 2. COMPARISON OF SOIL STORAGE DESIGN TO SALT STORAGE DESIGN

Material TSC r Accumulation TE Accumulation* TE*


Rock 47,721,870 J 14 h 18,152,058 J 0.38 41,995,245 J 0.88
Soil
(1.4m 3 /min) 43,866,900 J 13 h 13,532,428 J 0.31 14,410,850 J 0.33
Soil
(2.8 m 3 /min) 43,866,900 J 6.5 h 10,079,636 J 0.25 12,235,832 J 0.28
Salt 27,273,325 J 8h 21,550,679 J 0.79 23,569,078 J 0.86
* Based on amount of energy removed from air.

A thermal efficiency (TE) can be defined as the tained from the Laplace transform of equation [2] where
measured accumulation of the storage over the time Ts remains essentially constant:
period (T) divided by the theoretical storage capacity
(T g - T s )/(T g o - T s ) = exp [-h/P A C A ) (A/V A ) (x/u)]
(TSC). Thermal efficiency (TE) is simply a measure of
the fraction of the energy absorbed in the storage device. for t > x/u [4]
From Table 2 it can be seen that for the system tested,
the salt has a much higher thermal efficiency of 0.78 This solution is based on the idealized case for
compared to the other two heat storage efficiencies of temperature of the solid remaining constant. This is an
0.38 and 0.31 for rock and soil respectively. acceptable assumption since the bulk of the stored
As shown in Table 2, the efficiency of all systems, par- energy is usually latent heat.
ticularly for the rock, increases when no heat loss exists. When comparing the solutions for the sensible heat
This points out the importance of the need for adequate storage of Schumann (1929) and phase change storage,
insulation in a heat storage device. The optimum in- the solution of the sensible heat storage collapses to the
sulation thickness is a matter of economic evaluation and solution of the phase change heat storage when t = x/u,
is especially important for long-term applications. For the residence time. Therefore, the dimensionless
the case of no heat loss, the salt and rock storage are parameter (h/pACA) (A/WA) (x/u) can be used as a
more efficient than the soil storage by approximately 2.6 means of comparing the performances of both PCM and
times. Several variables seem to be related to thermal sensible heat storage on a common basis. This parameter
storage efficiency. Airflow has a significant effect on effi- is important when compating different types of heat
ciency. As shown in Table 2, increasing the airflow from storages or when comparing different configurations of
84 m 3 /h to 168 m 3 /h for the soil storage decreased the ef- the same type of heat storage in order to keep the
ficiency from 0.31 to 0.25. Even though h increases with temperature response the same.
increase in airflow, increasing the air flow rate decreases The storage parameter can assist in determining the
residence time, thereby decreasing TE. Therefore, for relative effect of fluid velocity, length of airflow path,
every system there will exist a mass flow to give the max- volume of storage system, area of heat transfer and void
imum TE. The optimum flow rate will depend on the fraction. The equivalent length of storage can be deter-
rate of heat transfer as compared to the rate of heat mined for various systems. The temperature response
losses. When heat losses are neglected, the thermal effi- characteristics of the 3.0 m long soil system at 1.4
ciency for all storage media is directly related to mVmin is equivalent to 0.10 m of the rock heat storage
residence time. The amount of heat transfer surface area and 0.17 m of the salt heat storage used in this study.
also seems to have an effect on efficiency. Based on the storage parameter defined above, the soil
The above method is useful for evaluating existing storage would have to be 150 m long, to have exactly the
storage systems, however, it provides little guidance to same air temperature response as the rock storage used
the engineer as to the design variables important for effi- in this work.
cient heat storage. It is necessary to develop a simple Lower airflows will increase the efficiency of the system
evaluation criteria for effective heat storage comparison as indicated by the results of the soil storage in Table 2.
and design. Since the storage number is proportional to h/u the total
dependency of velocity on heat transfer efficiency will be
Thermal Storage Parameter proportional to u° Vu. Decreasing the velocity by 1/2 in-
The equation relating the fluid temperature profile creases the storage parameter by 14 percent which is
along the length of any heat storage system can be ex- comparable to the increase in efficiency given in Table 2.
pressed in rectangular coordinates as However, lower airflows mean that more storage is need-
9 T 9 T
ed at a given total airflow. On an equivalent basis the 53
A A
^ACAVA[-^+u-^=hAfTs-TA} ™
m soil storage could be replaced by four parallel pipes
one foot apart each having 1/4 the airflow and 40 m
long. The relative efficiency of the heat storage system
Solution of equation [2] for both the sensible and latent
can be determined from the product of the ratios of heat
heat storage systems would provide such a means of heat
transfer coefficient to fluid heat capacity, heat transfer
storage evaluation. Such a solution will provide the
surface area to void volumes and residence time for a
temperature profile at any place in the storage at any
system with (h)(x1)/(k) < 0.1.
time. The solution for the sensible heat storage where
An unsteady-state finite difference model for each of
Bi = (h) (x, )/(k) < 0.1 [3] the storage systems was developed based on equation [2]
(Holman, 1972; Geankoplis, 1978). The physical proper-
is available from Schumann (1929). ties used for each system are listed in Table 1. Based on
The solution for the phase change material can be ob- observations, the temperature range for salt phase

726 TRANSACTIONS of the ASAE—1980


/-PCM STORAGE SIMULATION TABLE 3. ECONOMIC COMPARISON OF STORAGE MATERIALS
_JL—- _ — ^ - ^
"Z—_2fiQ^^CL~ROCK STORAGE SIMULATION

SOIL STORAGE SIMULATION


Mass 2,636,364 Kg 6,422,018 Kg 671,685 Kg
Volume 1637 m 3 4112m3 715m3
Storage
dimensions 30.5 x 6.1 m x 8.8 m 30.5 m x 6.1 m x 22.1 m 9mx9mx9m
Amount of
liner 1019 m 2 1989 m 2
Liner cost $2302 $4494 —
Amount of

tile 2134 m
Tile cost $9450 — —
Excavation — —
cost $2900 $7000
Material cost $35,000

$369,429
3 4 5 6 7 Insulation cost —
$1202 $2348 $571
STORAGE PARAMETER Total cost $13,552 $48,842 $369,998
Relative cost 1 3.6 27.3
TE 0.31 0.38 0.79
FIG. 7 Thermal efficiency of each thermal storage system at various TE' 0.33 0.88 0.86
storage parameters. $/TE $43,716 $128,532 $468,352
S/TE' $41,066 $55,502 $430,227

change was taken to be between 24 °C and 40 °C. Inter-


nal temperature gradients were assumed to be negligible a moisture impermeable pond liner with a cost of
for a heat storage system. The standard deviation bet- $2.30/m 2 . The pond liner acts to keep the water in the
ween the model predictions and the experimental data saturated-soil storage and out of the rock storage. The
(Figs. 2-5) is 6 °C. Once validated, the simulations were cost of soil excavation was calculated at $1.10/1000 Kg.
run over a range of air flow rates and bed lengths. The Rock cost was $5.45/1000 Kg and the Glauber's salt tray
thermal efficiency as defined by Hill (1976) was deter- cost was $0.56/kg. 2.54 cm of styrofoam insulation was
mined for each simulation. The thermal efficiency for applied to all storages at a cost of $1.18/m 2 . The pipe
each simulated thermal storage system at various storage cost was $0.48/m. The temperature range over which the
parameters is plotted in Fig. 7. Comparison of the ther- heat was stored was 45 °C over ambient.
mal efficiencies predicted by the proposed model against Table 3 shows that under the above conditions, the soil
the experimental data indicate a good correlation with storage is the most economical. The rock storage was 3.6
the storage parameter. Theoretically, all storage systems times more expensive and the salt storage was 27 times
should generate the same curve. The fit is remarkably more expensive. If the thermal efficiency (TE) coefficient
good considering the types of storage systems. The rock is divided into the cost ($/TE), all three storages will
size and tile ribbing for the soil could easily affect the ac- have an equal performance basis. The size of the storage
tual heat transfer coefficient. (therefore cost) is being increased to compensate for the
The correlation of storage parameter with thermal effi- difference between the 100 percent efficiency assumed in
ciency for the three heat storage media is a significant the initial cost calculation and the performance ex-
finding. This means that for a well insulated rock, soil or perimentally determined. When considering the
salt heat storage system, the thermal efficiency can be measured efficiency, the soil storage is 2.9 times more
predicted based on the storage parameter. Two storage economical than the rock storage and 10.7 times more
systems, regardless of their dissimilarity, will respond economical than the salt storage. More work is needed to
identically if the two storage parameter values are equal. develop economically optimum storage systems.
The width of temperature prodile to accomplish a
given change in temperature (i.e., (Tg-Tso)/(Tgo-Tso) — CONCLUSIONS
0.05) given in equation [4] is also an indication of how ef- The thermal performance of the storage materials
ficiently the storage system is utilized. Wide profiles in- varied considerably due to significant differences in the
dicate that significant portions of the storage will not be design variables. The rock storage and the Glauber's salt
heated before large portions of heated air will be storage showed rapid response to the change in inlet air
discharged at the exit. Therefore, the heat storage system temperature while the soil storage showed slow response
should be designed to contain a profile small compared due to low heat transfer area per storage volume and low
to the total length of the storage. However, the final residence time.
design will depend on many considerations the most im- Heat transfer by conduction in the soil was rapid,
portant of which may be economic. More work is under- however, the low area limited heat transfer rates. The
way to further develop the storage parameter concept. temperature drop was low over the 3.1 meters of tile us-
ed, indicating a need for longer residence time, to
Economic Comparison transfer heat more effectively. The heat transfer coeffi-
If the thermal characteristics of several storage cient for ribbed pipe can be estimated from smooth pipe
materials are equal for a given application the deciding correlation when the entire ribbed area is used. The main
factor becomes the cost. The economic comparison disadvantage of the salt system was found to be the loss
presented in Table 3 for rock, Glauber's salt, and of structural rigidity upon heating.
saturated-soil is based upon the cost (excluding labor) to Based on the method of Hill et al. (1976) the thermal
build a thermal storage large enough to dry 10,000 efficiency of equal energy sized storage devices was 0.38
bushels of corn from 30 percent moisture to 15.5 percent for the rock storage, 0.31 for the saturated-soil storage
moisture (2.45 X 1011J) with no additional heat source. and 0.79 for the Glauber's salt. The high thermal effi-
The literature values for specific heat, density, and la- ciency value for the Glauber's salt storage is partially due
tent heat were used in the economic comparison. All to sensible heat storage. A lower rate of heat transfer
prices are based on 1977 values. The rock and soil could be expected for the Glauber's salt storage during
storages were considered to be contained underground in discharging. A modified thermal efficiency value (TE's),

1980—TRANSACTIONS of the ASAE 727


taking into account the thermal losses, showed that the 16 Ingersoll, L. R., O. J. Zobel and A. C. Ingersoll. 1948b. Heat
conduction. Ed. 1st. McGraw Book Company, NY. 278 pgs.
large external surface area of the rock storage and high
17 Kelly, G. E. and J. E. Hill. 1975. Method of testing for rating
temperature concentration makes good insulation of the thermal storage devices based upon thermal performance. National
rock storage device extremely necessary. Bureau of Standards, NBSIR 74-634.
The thermal storage comparison method of Hill et al. 18 Kemler, E. N. 1947. Methods of earth heat recovery for the heat
(1976) was found to be of value for existing storage pump. Heating and Ventilating, Vo. 44, Sept. 1947. p. 69-72.
19 Kendrick, J. H. and J. A. Havens. 1973. Heat transfer models
devices and of little value for designing or scaling up a for a subsurface water pipe, soil warming system. Journal of En-
storage device. Based on fundamental principles, a vironmental Quality, 2:188-196.
dimensionless parameter was defined and shown to agree 20 King, W. F. and M. S. Martus. 1947. Heat transfer from
with measured results. This parameter can be used to ground to water in buried coils. Heating and Ventilating, Vol. 44, July,
p. 71-74.
design various storage devices on an equivalent basis.
21 King-Ling, Du. 1975. Application of an inexpensive solar
The length of the temperature profile can also be used as heating system to pre-engineered metal buildings. Ph.D. Thesis,
a design parameter. Mississippi State University.
The economic comparison showed that the soil storage 22 Klein, S. A. 1975. Mathematical models of thermal storage.
device has a greater economic potential than does either Proceedings of the Workshop on Solar Energy Storage Subsystems for
the Heating and Cooling of Bldgs., p. 119-121.
the rock storage or the salt storage. The soil storage was
23 Lof, G. O. G. and R. W. Hawley. 1948. Unsteady-state heat
shown to be approximately one-half the cost of the rock transfer between air and loose solids. Industrial and Engineering
storage and one-nineteenth the cost of the salt storage for Chemistry, 40:1061-1070.
equivalent measured thermal performance. It is obvious 24 Lorsch, H. G. et al. 1976. Method of testing thermal storage
that at the very least more research attention should be devices based on thermal performance. ASHRAE Standard 94-p.
American Soc. of Heating, Refrigerating and Air Conditioning
given to the development of saturated-soil storage devices Engineers, Inc.
for agricultural applications. There are still many ques- 25 Luikov, A. V. 1968. Analytical heat diffustion theory. Academic
tions to be answered such as the optimum tile spacing Press, NY.
and configuration, the optimum tile length, the effect of 26 McAdams, W. H. 1 954. Heat transmission, 3rd Ed., McGraw
heat on the soil and reliability of the system against Hill Book Company, NY. 31 pgs.
27 McCabe, W. L. and J. C. Smith. 1976. Unit operations of
damage, but there is sufficient economic desirability for chemical engineers. 3rd Ed., McGraw Hill Book Co., NY. 1028 pgs.
the development of such a system. 28 Morrison, D. J. and S. I. Abdel-Khalik. 1978. Effects of phase-
change energy storage on the performance of air-based and liquid-
References based solar heating systems. Solar Energy, Vol. 20, pg. 57.
1 Baird, C. D., W. E. Waters and D. R. Mears. 1977. 29 Mowry, G. R. and C. P. Davis. 1960. Operational
Greenhouse solar heating system utilizing underbench rock storage. characteristics of a solar-supplemented air-type heat pump. Annual
ASAE Paper No. 77-4012. ASAE, St. Joseph, Ml 49085. Report to the Kansas Committee on the Relation of Electricity to
2 Bowers, C. G., Jr., B. K. Huang and C. F. Abrams, Jr. 1975. Agriculture.
Solar energy utilization in a bulk curing/greenhouse system. ASAE 30 Mowry, G. R. and C. P. Davis. 1961. A solar-supplementally
Paper No. 75-3504. ASAE, St. Joseph, MI 49085. heated home. Annual Report to the Kansas Committee on the Relation
3 Cropsey, M. G. 1966. Analysis of soil as heat source for heat of Electricity to Agriculture.
pump system. TRANSACTIONS of the ASAE 9(5):846-848. 31 Mowry, G. R. 1963. Solar energy to assist a rural home heat
4 Davis, C. P. 1958. A field installation of a solar-supplemented pump. Annual Report to the Kansas Committee on the Relation of
air-type heat pump. Annual Report to the Kansas Committee on the Electricity to Agriculture.
Relation of Electricity to Agriculture. 32 Mumma, S. A. and W. C. Marvin. 1976. A method of
5 Davis, C. P. 1959. Solar energy supplementation of the air-type simulating the performance of a pebble bed thermal energy storage and
heat pump. Annual Report to the Kansas Committee on the Relation of recovery system. Proceedings of the Conference on Improving Efficien-
Electricity to Agriculture. cy and Performance of HVAC Equipment and Systems for Commercial
6 Duffie, J. A. and W. A. Beckman. 1974. Solar energy thermal and Industrial Buildings. Vol. 1, p. 126-136.
processes, Ed. 1. John Wiley and Sons, NY. 386 pp. 33 Pappas, S. L. and C. R. Freberg. 1949. Heat transfer of buried
7 Duncan, G. A., O. J.tLoewer, Jr. and D. G. Colliver. 1976. pipe in clay or sand. Heating and Ventilating, Vol. 46, p. 85-86.
Simulation of solar energy availability, utilization and storage in 34 Parkerson, W. 1951. Thermal characteristics of soils for ground
greenhouses. ASAE Paper No. 76-4010. ASAE, St. Joseph, MI 49085. coil design. Heating and Ventilating. Vol. 48, p. 83-86.
8 Eckhoff, S. R. 1977. Evaluation of selected thermal storage 35 Pease, W. C , C. R. Freberg and Sabert Oglesby. 1947.
devices for agricultural applications. Masters of Science in Engineering Preliminary tests on heat transfer to the ground from buries horizontal
Thesis. Purdue University. 202 pages. pipes. Research Report for Southeastern Electric Exchange.
9 Geankoplis, Christie J. 1978. Transport processes and unit 36 Price, D. R., G. E. Wilson, D. P. Froehlich and P. W. Crump.
operations. Allyn and Bacon, Inc. Boston, MA. 1976. Solar heating of greenhouses in the Northeast. 33rd Annual Pro-
10 Guernsey, E. W., P. L. Betz and N. H. Skau. 1949. Earth as a gress Report to the New York Farm Electrification Council.
heat source or storage medium for the heat pump. Trans, of the Am. 37 Schumann, T. 1929. Heat transfer: A liquid flowing through a
Soc. Heating and Ventilating Engineers 55:321-344. porous prism. Journal of the Franklin Institute, Vo. 208, No. 3.
11 Hill, J. E., E. R. Streed, G. E. Kelly, J. C. Geist and T. 38 Sepaskhah, A. R., L. Boersma, L. R. Davis and D. L. Slegel.
Kusuda. 1976. Development of proposed standards for testing solar 1973. Experimental analysis of a subsurface soil warming and irriga-
collectors and thermal storage devices. U.S. Dept. of Commerce—Na- tion system utilizing waste heat. The American Society of Mechanical
tional Bureau of Standards. NBS Technical Note 899. Engineers Publication.
12 Huang, B. K, C. F. Abrams, L. L. Coats and C. G. Bowers. 39 Shapiro. H. N. and W. L. Roller. 1975. Feasibility of soil warm-
1975. Development of greenhouse bulk drying systems for solar energy ing with power plant waste heat. ASAE Paper No. 75-3542. ASAE, St.
utilization and plantbed mechanization. ASAE Paper No. 75-1018. Joseph, Ml 49085.
ASAE, St. Joseph, Ml 49085. 40 Slegel, D. L. and L. R. Davis. 1975. Transient heat and mass
13 Hughes, P. J., S. A. Klein and D. J. Clise. 1976. Packed bed transfer in soils in the vicinity of heated porous pipes. Oregon State
thermal storage models for solar air heating and cooling systems. University.
Trans. ASME. J. Heat Transfer. Volume 98. page 336. 41 Sweat, V. E. and C. G. Haugh. 1974. A thermal conductivity
14 Hughes, P. J., T. L. Freeman and H. Grunes. 1976. Design of probe for small food samples. TRANSACTIONS of the ASAE
an experimental solar house heating system. ASAE Paper No. 76-4554. 17(l):56-58.
ASAE, St. Joseph, Ml 49085. 42 Telkes, M. 1974. Solar energy storage. ASHRAE Journal,
15 Ingersoll, L. R. and H. J. Plass. 1948a. Theory of the ground 9:38-44.
pipe heat source for the heat pump. Trans, of the American Society 43 Willits, D. H., C. G. Bowers, Jr., P. V. Nelson and B. K.
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(Continued on page 734)
728 TRANSACTIONS of the ASAE—1980
systems. Canadian Journal of Chem. Engg. 51:22-30.
References 15 Stephens, L. E., and G. H. Foster. 1976. Grain bulk properties
1 Brooker, D. B. 1961. Pressure patterns in grain drying systems as affected by mechanical grain spreaders. TRANSACTIONS of the
established by numerical methods. TRANSACTIONS of the ASAE ASAE 19(2):354-358, 363.

Thermal Storage Comparison


(Continued from page 728)

Paper No. 76-3507. ASAE, St. Joseph, MI 49085. G Air mass flow rate k g / h
44 Wilson, G. E., D. R. Price, L. D. Albright, N. R. Scott, R. W. h Heat transfer coefficient J/m 2 -C-h
Langhans and P. Chandra. 1977. Experimental results of a greenhouse k Thermal conductivity W / m ' K
solar collection and modular gravel storage systems. 34th Annual Pro- LH Latent Heat of phase change material J / k g
gress Resport to the New York Farm Electrification Council. M Mass of storage material kg
pA Density of air k g / m 3
t Time h
NOMENCLATURE T* Temperature of air C
Tgo Initial gas temperature C
A Heat transfer surface area m2. T, Temperature of solid C
Bi Biot number (hx^/k TSC (Theoretical Storage Capacity) (C*AT + LH)*M J
C^ Heat capacity of air J/m 3 -C u Velocity of air m / h
Cv Heat capacity of solid J / m 3 - C V.4 Volume of air m 3
AT T h e temperature difference between the initial storage bed V, Volume of solid storage material m
temperature a n d the inlet air temperature x Distance along storage bed m
f Void fraction (Vol. of air/Vol. total) x. Half thickness for heat transfer m

734 T R A N S A C T I O N S of the ASAE—1980

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