Any malpractice or any attempt to commit any kind of malpractice

WARNI\G in the Examination will DISQUALIFY THE CANDIDATE.

PAPER_ I PHYSICS & CHEMISTRY-20l9
Question Booklet
Serial Number:

Tinre: 150 Minutes Number of Questions : 120 N{aximum Marks : 480

\ame of the Candidate 4 ruur L T{ATg e V
Roll Number (rlf3?
Signature of the Candidate
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H
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 )
PLEASE ENSURE THAT THIS QUESTION BOOKLET CONTAINS 120
euEsrIoNS SERTALLv NUMBERED Fnovl I To 120. rRTNTED rAGES 32.

1. ln the amplitude modulation mode of transmission, the norma'l speech signal is

with^a maximum frequency of 5 kHz. If the carrier frequency is 200 kHz, the
modriffied t$nal will.have the frequenci ing between
(A) 190 kll; to 2lolHz @-ffi to 205 kHz (C) 195 kHz to 200 kHz
(D) z}pk}lzto 205 kHz (E) 199.5 kFIz to 200.5 kHz

6r signal transmission, modulation is necessary

(A) to reduce distortion ofthe signal
(B) to modifu the frequency content of the signal
(C)
to mask the signal information from enemy
radiate the signal to a large distance using antennas
"*1D4"
(E) to make it easy to ampli$r the signal
3. A light emitting diode is
(A) a n-p-n type semi"Eonductor with a forward bias
Jel
(C)
a p-n-p semiconduCtor with a reverse bias
a p-n-p semiconductor with a forward bias
"-Hn--:*
r ---j
rL-- *ir
:F -}|r

tor with a reverse bias

-n semiconductor with a forward bias

I\tlxontext of p-n junction, select the eorrect statement from the following
W\ W*ier potential remains constant unddr forward bias
') The width of the depletion region depends on the doping level in the p-type
and n-type regions
(C) Under forward bias condition, the p-n junction behaves like a pure resistor .i.."
.).
irrespective of bias voltage ', ' , ;
(D) UndEr reverse bias condition, the p-n junction behaves like a pure resistor '

irrespective of bias voltage I

P/ The barrior" poJential decreases under reverse bias
Space for rough work

:,
i:

a
Phy-Chy-I-A2n019 J [P.T.O.
j -i
lr!
:i .-
 center of a hollow sPhere rvith
5. The radius of gyration about an axis through the

(A)M
external radius a and internal radius\b is

,r,.,m
'b4)
(c) F1; -n
_ b2)
,t--\
{z
.2-
*i:e
-u4)
/I W^)
n>+ <
2- fifc.r
',\
(E) \''/r
\\ __-/
(

A ball of mass 1 kg and radius 0'5 m, starting from rest rolls down on a 30o
istance of the 7 m from the
inclined plane. The torque acting on the ball at t
starting point is close to
(Take acceleration due to graviya<fi m/sr)
(A) 0.25 N-mN-m <$ 0.7 N-m (C) 0.5 N-m
rD) 0.4-N-m
(D) 0.4 Nm (E) 1'4 N-m
(fQe radius of the earth suddenly decreases
by half of its present t'aiue. Then the
<,/a
ime duration of one daY will be 1= *'BM (C) 1? hours
\\ \!-/
6 hours (B) 8 hours
ff., (D) 24 hours (E) 48 hours
radii roli 'lou'n
hollow sphere and a solid sphere, of equal mass and equai
experiencgd H *-
plane' If the torque expertenceo,,A
qlinnins on an inclined plane.
rhnrrt slipping
the hollow
lvithout
. , *J'lnu
- TH)TS (c) TH = l-i
{^ d-
(A) TH (Ts
"'r@9, xH -0 (E) rs=0
m and angle iU'. If the
A brick of mass 2 kg slides down an incline of height 5
T";, y\' L.-
3n'Jffi .i.nt of friction of the incline i, lr,
the veloci
'"r-\* 2,J3

5 ilA o\$ bottom of the incline is

(Assume the acceleration due to gravity is 10 m/s2)
vw (A).'3/mls
(D) 0
(B) 50 m/s
, (E) 10 m/s
,p- Space forroughwork <
bt(
Nd
A
+
(
+ D
{'0o6 ' ?-.'- 'n..il 6* J@ + f
'-r ^ /A a
'/
n' ,L

Phy-Chy-I-A212019
z o\\uo-
-r\ lt
i ^ 4 ,a $------ o\
.n{
\.d %*v:E W-E)
 Suppose two planets A and B revolve. around a Sun in the galaxy. The semi-
major axis of A and B are I and 5 AU (astronomical unit) respectively. If the
period of revolution of A is,rl yrp:Y-period pevolution of B is T6; \ v,3: (
5 years 5T
---,"
(A) I year -U h6f r^
>- Q) r).ffears.-^=\
(D) 25 yearsffii u- (p) I.?", F i ,/ @ t
:2:
tz. The half-rife of o,r.n' is 6 hours . rr r2rrE 5r. orr." t\ tff..LE 3t;[tmt, after
24 hours how much- Tc will be left il!h. patient's body? n-(fl\iY-
(A) 0 ms &Yffi5 ms (C) 3mg ^""X) ffi
(D) 6 rng (E1 t2 mg .?J\
-
a'i- r

13. For atoms--:xrhich of the following statement is correct? *'\)

eavier nuclei have more neutrons than protons
'a?\
(B) Heavier nuclei have equal nurnber of protons and neutrons
(o) T.,ighter nuclei have more neutrons than protons
{-; 'f
,(D) Lighter nuclei have less number of neutronS"than protons T; ,,W*
(E) For heavier nuclei, atomic mass varies as squard of atomic number

L4. Whieh of the following statements is not a property of nuclear fqrce? : l

\ >(--
(A) it is an attractive force ".\ ?*
iei
(B) inJependent ot
it is independent
it.is gS
of mteractmg
interacting nlcleon
il.rcleons
glf.fl
deg
Jertis force
&r'utongranserorce
lohg range
a
-q
-''@. 5#5 rf
,I1
',,)
,q,(#.i;1-&X(-
,fr 6q
'
u ,. tv
(D) '''..
it is non-cenffal forcc .t',' '
l. '[ -1 \fY ]
irl force
\_ \
it is a shbrt range
L\ ,f' l
15. Which of the following elements you neffi6ffie,to form an isotorre family?
(A) *o'u ( (B) ,N't s (c) uc'o

-1p11ffit G) ,F" tr s
Space for rorlgh work
fi*^\ @ r^})F )
I -*g-
la z-S{
iy ix Yte;,n
Phy-Chy-I -A2l2Or9
t fr.T.o.
il
,-L ,,6-D
1o z*
 16. A magnetic field of 1 T applied at an angle nl3 to the vertical direction is
decreased to zero at a steady rate in one second. The magnitude of induced emf
in a horizontally placed circular loop of radius 5 cm is given by
(A) t "Zs rf3n mV (B) 12.s JlnY (c)
(D) 12.5rcY (E) 25n Y

17. The dimension of mutual inductan enote dimension of current as A)

(A) MI.2T2A-2 ML2T-2A-2 (c) M L-2T2 A-2
(D) M L2 T -3 A*1 (E) M L2 T -3 A-3

18. A pure inductor of,. inductance 0.1 H is connected to an AC source (of rms
voltage) 220 V and angular frequenc Hz. The rms current is
.' 11
(A)
)t );o (c) fre
(D)
fi9a (E) 3o
J7l

19. In an LCR series circuit (of inductance L, capacitance C and resistance R), the
impedance is minimum when the angular frequency of the source is by
-eir.en

(A) JLC (C)

E
tr
t_
(D)
!r (E) JLcR
Space for rough work

f"^^.* =JTf,\-
7r.--- urflo'\./ V
.z z-'>
/1 A =
="{--B
-b+ W = BPU.>-
rz-f
=l s ryr
A
1..D,'S
T{
lLt
J-, { fV-
*7*l* ^^ "@3
{''L T
- z;--
*L
I
LW Ar' t-<l

nr L ,9'r,,4
a{: l'r" ^ tt-)-L-
L<'"
Phy-Chy-I-A212019 M.ry,Na 'A^ LI fi
K
 r
I

:
L ',
Dl

r 'rl
24. A Carnot engine is operating between" a hot body and cold body maintained at 1-Ftr-
vl<
temperatures T1 and T2 respectively. Consider the following three cases
Case-I : The temperature of the hot body is changed to T1 * AT and cold body
is at T2
Case-II: The temperature of the hot body is atTi dnd cold body is changed to
T2+ AT
Case-III: The temperature of the hot body is at T1 and cold body is changed to'
T., -
AT
Jef# efficiercy of the Camot cyc19 is highest for case-I
(B) The efficiency of the Carnot eycle is highest for case-Il
(C) The efficiency of the Carnot cycle is highest for case-III
(D) The efficiency of case-Il is higher than case-III
(E) The efficiency of the Camot cycle is same for all three cases

ZL. Some smoke is trapped in a small glass container and is viewed through a
microscope. A number of very small smoke particles are seen in continuous
random motion as a result of their bombardment by air molecules. If the mass of
the,smoke particle is about 1012 times higher than that of an air molecule the
average speed of a smoke particle is
,t e*i \
(A) 1!6 times the average speed of an air molecule
trn
lrtO-r2 times the average speed of an air molecule
/ (C) 1012 times the average speed of anhir.mglecule
1O
I'L--
(D) 10{ times the average speed of an air molecule 1o
f-

(E) 10-10 times the average speed of an air motecule

22. The standard of length is maintained by a 1 meter long bar made up of a material
:
having coeff'rcient of linear expansion c, 0.00001
oc-l. If the length of the bar
were to be preserved to an accuracy of I part per million, what would be
maximum allowed temperature variation2
(A) + 0. 01 "c 0. 1'c (c) * 0. 001 'c
(D) + 0.0001 'c. (E) 1.0 oc *
Space for rough work rt I tF> tf I
t^' = to

Ff= o
- tra,,bL
\ _ . o. f

*{
'9o P'l
-)_ lf -t c
f:;
ho M LT A
-")--' - d:V-J- lxf r

Phy{hy-l -Aztzltg o-,e}l OT t 2' I

[P.T.O.

tO ---
 23. Inside the engine of an automobile, the cylinder compresses the air from
approximately standard temperature and pressure to one-twentieth of the original
volume and a pressure oI
of )U
50 atm. WhgrXis
WBrI-{s the temperature of the comp
compressed air?
(A) s00 K tD{aszK (c) ssO K
;v\r
) l A
1000 K
r.
"(E)
/,-,
200 K
A spring of natural length I and spring constant 50 N/m is kept on a horizontal
frictionless table with one end attached to a rigid support. First the spring was
compressed by 10 cm and then released to hit a ball of mass 20 g kept at a
distance / from the rigid support. If after hitting the ball, the natural length of the
spring is restored, what is the speed rvith which the ball moved?
air resistance)
m/s (B) 7 mls (C) 25 mls
)
50 m/s (E) 2500 m/s

In a water container, an aluminum piece of volume 0.5 m3 is lowered through an

external force, until it is completely submerged. In another identical rvater
c ontaineJ, lead p ie ce o f 5ama_taalurrte fy_aqslrndAl\r g_u,bm9rge_{_11 i n g the same
_a .

aurounl-o-Lextemal -fioree *he mass density of lead is 4 times largeffian the

mass density of the aluminum. If Fa and Fs are the buoyancy forces acting on
o aluminum and lead respectively, then which of the following statements is
Y93 correct?
(A) FA>4FL FL>4FA (c) FA>2FL
*&''t\
"
(D) FL>2FA (E) Fl: Fa

26. A boy formed a bubble and a liquid drop from the same soapy water. The
c- t 9nr pressure difference between inside and outside of the soap bubble is measured to
be 100 N/m2. If the radius of the droplet is half of the radius of the bubble, then
\"'qhr the pressure difference between the inside and outside of the droplet is
(A) 0 (B) 50 N/m2
(D) 200 N/m2 (E) 400N/m2
Space for rough work ruu- --l
It- - \oo fu :===-7-
/
I

-u- P.{-
rL - t
L4/t
/'?- +k"& u-*L
T, 'e r-
. 1--
Sz
). tt -R I,v {o v
z.o fo x lo-a : Wv
x-wfr
{o
TZ 79o
Phy-Chy-I -Or,rOrfr) 868
( .._ -t z t?: W
-?
-)
,Z
 11 27. A mass ,??, suspended vertically by a massless ideal spring with spring constant ft,
a1 is at rest. The mass is displaced upward by a height ft. When released, the kinetic
t|
) energy of the mass will be proportional to ^-. ,) "
(Neglecting air resistance) L >V,t I
{--?
!.J-{

'1,/
(A) ontyh LV\"'
(-.._J.ffiivti , )" L".
al
(c)m \vG-*
n
1S
(D) a linear combination of terms involvin g n ina tt2
a
(E)

Instantaneous power delivered to a darnped harmonic oscillator (natural

frequency is ro6) by an external periodic force (driving frequency co) under
steady state conditions is
\=
Q- VI
always
-Wfititive
(B) negative always
LN
(C) positive and negative with poweJ integrated over a period being zero
3r
(D) positive and negative with power integrated over a period being positive
1e

IC t-/
,ffl positive and negative with power integratdd over a period being negative
,
factor for a damped oscillator is given bV
)n
' ,Zr' lT 9 lhe V r-- QVL
is
(B) Ratio of energy dissipated per cycle to the initial energy A
*-g-{^rio of energy stored per cycle to the energy dissipated per cycle ND
(D) Ratio of energy dissipated per cycle to the energy stored per cycle '\-,
(E) Ratio of the damping coefficient to the natural frequency
ne

30. A ball of mass lz is projected upward with a speed vs . The speed at a height h is
I

to
!'n (N.g]gpt*
(Ne glegtingg air resr stance)
arr resistance)
independent of angle and direction of projection
-k{
,M independent of mass, angle and the direction of projection
(c) dependent on the direction of projection
and angle of projection
PI dependent on the shape, size and mass of the ballof the angle and direction of
(E) dependent on mass of the ball but independent
projection
to:"Yi'*P-
{,*
{r fiut
'At
= @V""]
dJ* \
*A
^.t V' t
P
ffh' 'r'- \'
-t! f, tft, q - u '-": *i"uo --
c-l{3nVt=v*""{ 1 q_
vo \*\
Phr -chr,-l-A212019 1 9 [P.r.o.

9rU a 1f*t
\-pu
 31' An object having a velocity 5 m/s is
accelerated at the rate 2 m/s2for 6 s. Find
the distance travelled during
the period of acceleration
(A) 60 m
. / _-_- - (B) 25m (C) 36m
l.DT'66 m (E) 45 m
32, A vehicle moving at 36 kmlhr is
to be stopped by applying brakes in
5 m. If the vehicle weighs 2000 the next
kg, determine the average force that
applied on it must be
(A) 104 N 2x104 N
(D) (C) 3x104 N
5x 103 N (E) l03N
33. A block of mass 20 kg is suspended
through two spring
balances with negligible ,u.,
will be the readings in the upper and lower
as shown lJfigur.. **r"
balance
respectively?

(C) 20 kg, 10 kg
(D) 10 kg, l0 kg
g, 20 kg
20kg

34. Two masses connected

vvrvu ,r
in strrrss
series *itnlrt*o
wrrn two massless
,nur{ strings are hanging from
support as shown in the figure.
Find the tension in the upper
unner srrirrn
stflng
(,\) neg
(B) (ry - m)s
(c) mE
pl-ry-+-m11g
(E) (m1x nt2)g
Q,**L) 1
Space for rough work

f'a +
t\ ")_
v r.t .\le- tr I

ry F+4- 4
V *2-t
t7
.,- a-g\ -,?_{
e=5YL ?6
D e :-{.eq
+

(3A
Phy-Chy-I -ff!20|s l0
rL
).og = u -.t,\ .,C:\ -'4
(4-
ne \ c>*C \t: lO"^ale
z-9 s z-x to9%
35. An electron, placed in an electric field, experiences a force F of 1 N. What are
the magnitude and direction of the electric field E at the point where the electron
is located (e :llYS4)* 977 t
t\- r \
1 N/C, F and E are along the same direction 1/-
e r- F -e_
k.--:
I

(B) 1N/c,FandEare against each other

Z-

(c) lN/c,FandEare perpendicular

( ) eNlC,f a\d E
(

36. Tlre distance betweeR two charges (lt : *2 pC +8 pC is 15 cm.

and q2 :
Calculate the distance from the charge q1 to the points on the line segment
o++f-
joining the two charges where the electric field is zero
%, tt('^4 t.
(A) 1 cm (B) 2 cm ^
(c) 3cm (

6r*c
(D) 4 cm 8vc
3i. Four point charges (with equal magnitude of charge of 5 C; but with different
signs) are placed at four coffrers of a square of side 10 m. Assuming that the
square is centered at the origin and the configuration of the charges are as given
in the figure, the potential and the magnitude of eiectric field at the origin,
\-
respectively are I D Jr
I rl y'- rJ-'
4n%) =t
fNotetk=
t- Li
(A) 0Vand0V/m \)r14 f ; "-7 L(

{ou,* r kg-
(c) Ji-o v and Qo u,* +5C -5C Y
5"v4uu5'"
Io'7.t
(D) 0Vand 5V/m
Ji-- Vf
(E) :atVandov/m g'z< t-
5
Space for rough work obL
*q__
fu,

C t---,
r-
=
2-
rrsmY \
Ph-v-Chy-I-A212019 11 \_c-l rft: ) [P.r.o,
 l-'
Gw€
point dipole dipolemoment,
F=pst, is kept at the origin. An extemal
electric field given by, E =Eo(2f _3 j * +k1, is
applied on it. Which one of the
fy-tlg-11dl1e statements is true?
The force on the dipole is zero wirile torque rotates
the dipole on the
xy-plane
W_-rnt f,orce on the dipole moves it along the direction of electric field
d9{ rnt interaction energy befween the dipole and electric field is zero
The potential due to the dipole alone on the
*)-rrr{9)l
d xy-planewith z: 0 depends on
I vallre of,p6
"-J*he
61 o -"fi The application of the electric field orients the dipole along the
\ -k direction
39. Fjnd the total capacitance and total charge
on the capacitors
sffi.'g nC
(B) 3.0 nF,18 nC l'(-x 6
(c) 1.5 nF, 4.5 nC
(D) 3.0 nF,9 nC
(E) 3.0 nF, 4.5 nC

40. A circuit is made using Rr, Rz, R3, Ra and a battery as shown in the follorving
figure. Find the equivalent resistance of the giveh
circuit and the current passing
through R3

I R1:0.5 Q
(A) 3 c), ;A Q,27 A -J
g
-1 t]r)
i
21 II

(c) 1a,
J 2A (D) n,To 4
N

2t
(E)
la, -;A
J

\. rr
A.',
r
(^(
V

Phy-Chy-I-A2120t9
tu
7
 rl 41. Find the voltage and current passing through the resistor R2 shown in the
following circuit
GJY<-
@-ffi
(B) 1V, lrlA //.f -/-
J
(C) 3V, 1mA 0,

(D)-L\l,2rlaA .{ >V
a-)--'
\t= I*nA
Hzv, lmA
42. The resistor R1 3 O and R2 : 1 f) are connected in parallel
: toa20Vbatteu.#L,

le
Find the heat developed in the rersistor R1 in one minute
(A) J _---.-
@*BAsrf
600 (B) 800 J
(E) 7000 J 4u0--,6
:--'-7-Y
a_a (c) 6ooor lw
{
i 43. The velocity and acceleiation of a particle p#fo.*ing simple harmonic motion
have a steady phase relationship. The accelerati'on shows a phase lead over the
velocity in radians of V: t" A c*f c"r't '
(A) + rE (B) 0 a=-*"As;t^:t
(D) - nl2 (E) - 7t

44. Consider a driven damped mechanical oscillator is in resonance. Which of the

followins statements is true?
)6ilring frequency is twice the natural frequency of the oscillator
.\€t Power transfer from the driving source to system is minimum
frequency is the same as the natural frequency of the oscillator
--(ffiriving
- (O) The force damping the oscillations are at a minimum value
(E) The driving force is in phase with the displacement
45. A body undergoing simple harmonic motion has a maximum acceleration of
8n m/s2 and maximum speed of 1.6 m/s. What is the time period T?
(A) 0.1 seconds - (B) 0.2 seconds (C) 0.3 seconds
(D) 0.4 se?orrf (E) 0.5 seconds
Space for rough work '

@ [,]
)
A: Bn-
t-,\-/ As l. G
tal .: 3r 5.- -r 2t
p"r-"-"- a \

l1
Phr -Chy-I -AZl20l9 IJ [P.r.o.
 46. A bat emits an ultrasonic sound wave at 33.0 kHz and receives an echo 0.1 s
later. What is the distance of the bat from the object-producing echo? (Speed of
sound in air is 330 m/s)
(A) 10.0 m (B) 20.0 m (C) 33.0 rn
(D) 66.0 m (E) ffi
47. A wave along a string has the following equationy:0.05 sin (2gr _ 2.0x) m
(where I is in seconds and x is in meters). What are the amplitude, frequency and
wavelength of the wave?
amplitude : 0.05 m, frequen cy : 4.456 Hz and waverengtli :3 .5 1 g m
(B) amplitude : 0.05 m, frequen cy : 28 Hz and, wavelength :2.0 n-r
amplitude : 5.0 m, frequency : 4.456 Hz and.wavelength =3.51 g m
amplitude : 0.05 m, frequency :2.0 Hz and wavelength : 2g m
amplitude : 0.05 m, frequency : 3.456 Hz and,wavelength :4.5 1
gm

A train sounds its whistle as it

approaches an observer standing at a point near
the track. The observer measures a frequency of 216 Hz as the train approaches
and a frequency of 184 Hz as the train leaves. What is the frequency of its
whistle?---
-.,.
2t0Hz (B) 190 Hz (C) 205 Hz
-W
(D) 202 Hz (E) 200 Hz
Space for rough work
n,r(l
2d )L
= w@ 4 /' ...l_.),5,
gLx
\>,-
{ \4
-YqO =O.:+
'/n
7
1kb-'"/1 \\
?
c^J :
4t
A, w = ;-{

Yl- )
r,,\
.-.IJ
vvln
Lco'\
) \P%: - --
)
,,

Ltc 4$
f) \ k *+- It \,
L/ ^Ly- .'1
q :_
*v,
qh 5
,%
o 2tL U.t$
\1
?
24'6 €
rvI.., I (<4 ur- t
,

t\ /.
' L F @:i4J ,I L)
=-r?
ov
+a-o- * .-.-----
L/
( 6-gr
--/'
(?*: ., r -y---l
L "'*U ?*z s
7{-:)
Phy-Chy-I-A212019 (z{t t4 5----V,
\<-/
zA'\ lb. ft3
,)b. , o=t-
'v .\ e'
S
following'figure is the combination of logic gates. The inputs are A and B'
The output is C. Which one of the following choices gives the correct matchins?
,,€""B
of
A
B
4* ftB
P' At+n
A
tr 9.1Fr" A
(a B.
B

Bfr B
,AR

A A B C A B C
0'
B
0
C
1
4A-B 0 0 1 0 0 .U
0 I 0 0 (c -v '7 1
(A)
1 0 1 h-)er 1 0 I 1 0 0
I 1 I I I 0 I I I

A B C A B C
0 0 1 0 0 0
(D) 0 1 1
(E) 0 I 0
I 0 0 I 0 0
I 1 0 1 0

50. A particle of mass m and charge q with an initial velocity il is subjected to a

uniform magnetic field B along the vertical direction. The particle will
(A) follow a circular path if f is along the vertical direction
(B) rnake helical motion if i is along the horizontal direction
-_ (C) make helical motion if f is neither parallel nor orthogonal to B
(D) always make circular motion rtz^\
\/
(E) always make helical motion
Space for rough work

t<-

21 1): #,o
t
'€ .\ F*
2-1
h A--.La^I:
--/ ^
-?E2-
\ @'c/ (oe
Phy-Chy-I -A2l2llg 15 r.84 ( bg'r [P.T.O.
>
6t-
 51. Consider a circular loop of radius R on the xy_plane carrying
a steady current

(A)
#r, \n o\
r4ra--/
(B) #"
(D) (E)
fli *',
52' Consider two parallel current carrying conductori separated
by a distance. Which
one of the following statements is true?
(A) currents flowing in same direction wil read to repulsion | r .,
I i
(B) Currents flowing in opposite directions rvill lead to attraction 1 "f-
(C) The conductors will always attracr each orher
(D) The conductors will always repel each other
I

Currrents flowlng in same direction will lead to attraction

and opposite
-JW directions will lead to repulsion

53. The energy gap is much more in silicon than in germanium

because
(A) It has less number of electrons
(B) It has high atomic mass number
(c) Its crystal has much stronger bonds cailed ionic bonds
ffi'alencee1ectronsaremoretightlyboundtotheirparentnuc1ii
(E) Its valence electrons are more loosely'bound to their parent
nuclii
Space for rough work

Phy-Chy-I-A2/2019 I6
 (c) M-'L-'r'

speed of 10 mls
Themagnitudeofdecelerationrequiredforabody,movingata
to come to a complete halt at a distance
of 100 m is e-6= vro
(A) 20 mlsz ,-,- -- (B) 10 m/s2 (C) ' 4j"
2 mls e<-6
(D) 0.5 kr{ (E) i m/s2
56. An accurate measurement implies tlat
around the mean value
(A) the spread of the readingS6re broad
(B)thespread.ofthereadingsarenaffowaroundthemeanvalue
(C)themeanvalueofthereadingsisalwayslowerthanthetruevalue
(D)themeanvalueofthereadingsisalwayshigherthanthetruevalue
(E)ztheclosenessofthemeanofthereadingstothetruevalue
the variation of acceleration (mis2) with time (s) for an
sin"fo[owing plot gives
s' The velocity at time r: 15 s
(v15)
object that started from rest at time /:0
are 'J > a'
and at 25 s (V25), respectively
t tt
15
w 7^E-
a
tsl0
d<
o
6
to t0
Time (s)

:0 m/s .*BT\{15:
--/ t
100 m/s and V25 : 150 m/s
(A) V15:50 m/s and V25
:25 mls (P) V15 : 100 m/s and V25 :25 mls
(c) V15: 50 m/s andY11
(E) V15: 75 m/s and V25
: 50 m/s
Space for rough work

t7 [P.T.O.
Phy-ChY-I-A212019
 58. An object, moving with velocity 5 m/s, undergoes an acceleration of 1 m/s2 at
. time t : 0.If the object has a mass of I kg, the kinetic energy (KE) of the object
at time /: 5 s is
(A) KE: 12.5 Joules (B) KE:20 Joules (C) KE:30 Joules
JD-6:50 Joules (E) KE:0 Joules
59. The variation of speed (in m/s) of an object with time (in seconds) is given by the
: 5t2 * { :-
L''- b I
expression V(4 Yo- 5t +
(A) /: 0 s, the instantaneous acceleration is zero
At time

EffiimeAt time /: 0 s, there is a deceleration of the object

l: 1 s, the object is at rest
.l\,o
5oE t'(C)
Vr- \ (D) At time r: I s, the instantaneous acceleration is zero
(E) The distance travelled by the object at time /: 1 s is Vs m

60. A boat is moving from the east bank to the west bank on a south flowing river. If
the speed of the boat is 4 km/h and that of the river is 3 km/h. If the rvidth of the
river is 2krn, the distance travelled by the boat is
(A) s km (B) 4 km (C) 3 km
(E) 2km
.*) 61. A bead is tied on one end of a stiff rope of length 1 m. With the other end of the
rope as the center, the rope is rotated in such a way that the bead completes 10
revolfiom per second. The centripetal accoleration of the bead is

k.
1-
1af mls2
+oo n2 (B) 200 nz mlsz (c) 400 nls2
(D) 200 mlsz (E) 100 m/s2

w\ Space for rough work

l.&"*{) <[r
.^'-- \ '
v:5rf ffi
_ ________O
=
qw d[z v- { ftr
r
/>
'^ -'-x
- , t{ ='-'- r
R ! +lD

:
\/ fr: L
r
+ary o"{1 '
ltu
*t
@}D
*.' 1
lrb Y_i
i,.r\ "M -(
u^a/ \
Phy-Chy-I-A2/2019 l8

\I,, h k- | t"
 \4 \ z-- ,.,i- * ? u

of an electromagnetic wave
PVV
in free space ib given by
1'
62. The electric field
1, {
is correct? .6\-7

.?fr 7{
V'- A
3 a1
9
A
fl
/'t\o
,1)
@ \C
{rr K - A'
R
-:/
'(Q'r7
bl '/
/q'
\7" 1D
which rrries

energy but not momentum

electromagnetic wave which
carrles
(B) The radiation is in the form of an
momentum but not energy
an electromagnetic wave
which carries both
he radiation is in the form of \o
energl'and momentum
(D) The radiation neither carries.tlttgy i*,TTt^":::
distance fi soufcev K/r/ ({,
l;; ;;.;;;.;;t;v orradiation is independent orthe
of radius ro
A para11el plate capacitor
(of capacitance C) with circular p
64.
resistor and is charged
located at positions t o, is connected in series with a
paraltel to
a circular loop L of radius f
by a batter)' of voltage V' Consider
statements IS
plates is located at the center' Which of the following
capacitor
t(c.)) 1' 7' (/,- tr9
at time t is q(t)= cn(r - e-t
,;ttil charge on rhe capacitor

q(t) =cv - u-rrtcvi )

(B) The charge on the capacitor at time t is (r

L is indep*ott:".11:^1t:i enclosed bv it
(C) The flux through the loop

Ei ;; ;;;tic ield is directed orthoelna,l to the loop L

the loop L
il'. *^gr.,ic field is direited along
Space for rough work

19 [P.T.O.
Phy-ClrY-I -A2120r9
 65. A monochromatic light of frequency ,=*,1016 Hz is produced by a laser'
The power emitted is P=10-2W. The average number of photons per second
emined bv the source is

'b i - ^,^
1016
(A) -f-=*" x 1016
,, ,-\z ,n2o
(6.63)2 ,1020
(B) (6'63)2 1020 ,r\\ lt(6'$)2
(c) (6.
. Jg ', "
101(

- -
6y46 .
,{$))e'o
t' Sdrne work function of three photosengid've
--ro;U ,-yt -*
materialt #d ro build photoele;lric
U arvices are given as: Sodium (2.75{eY), copper g.6s ev1 and gbtd
:\'t' t:''
Which of the fotlowing statements is correct. (The frequencl of visible light
li:s
"-
in the range 4xrrlaHzto 8x 1014H2;? ,fl"-*:;ll-#' ) '
o;1 (A) Devices built by copper and gold can op{rffe rilttr vlsiUle light
A 9-^ (B) Devices built using sodium can operate with ultraviolet light r,,- -
6 \# (C) A1_.9he devices can operate with infrared light W'
iy- Qrtthe devices can operate with visible light 't ,,r ' 'L-^'
.fr-76].,Iodevicecanoperatervithvisibletight,,?,?>
-fficti,ff"edat9cmint,on,{u"on,u{,=kofra,liu-sofcunai-*re
2
cm.The following statement is true U -* - 1c-"
1

mirror +-
(A) The image is formed 36 cm behind the e- f "*
mirror 1 I - -
(B) The image is 36 crn in front of the
'-
'

(Ci The image is magnified, virtual and erect -u 9

image is magnified, real and erect
J- -- ,G _7--
--
3 Z
."rgt )gnfre mage is magnified, real and inverted t - l ,f .-- 1
(ov

\<1 6g. An optician prescribes a lens of power +2.5 D. The lbcai length of the lens in
v' water are respectir e11' I .5 and 1 .33)
Ct 1\ water is (Refractive indices of the lens and
"!, Q-t)
pI U)te) 40 cm tl17 srn (C) 17 1660 cm
*.ar-^1
i= \"-" -{ ,+r_ffi _4 { tt":9k \' / g
i_.+*io'-
vl
gW"* r "
j:'1
\ u '
-? "1hy,Ur.{"k
-\9
.ol
,{ : 'L
\ )<-
nyl*
\t

ke_ -_ z
Phy-chy-t-!?t2o1e 'fr,no,o xts
A \ f
&*,'\a;{ a A"'T
x
 ,DJ
\/ /
r. i,4
)", -- cA
,

69. In a single slit diffraction (of width o) by a monochromatic sourQe of wavelength

Xthe firsUffiium of the intensity distribution occurs at an angle v - ^a)--
(L)'-.K (B) t (c) ; dv\'4
/-' ct 2c, o
(D) , CL
(E) ; U1,,r
?)
-7'
tu
70. A monochromatic source of wavelengtb 600 nm was used in Young's double slit
experiment to produce interference pattern. Ir is the intensity of tight at a point e1:
'3
on the screen where the path difference is 150 nm. The intensity of light at a
lPqlrrJ9<l n
r.vherglhe path difference is 200 nm is given
polnt w by \ b
"r''-

(D) ] r, (E) * ,, 2 -. /LJ-"-" ? A

I
71. The Brew ster!-aee+e for air to water interface is = T'.. , J, = tily
J. t
-

72. A TV transmitting antenna is 81 m tall. It has a half-power beam width of 10

degrees. If the receiving antenna is at the ground level, the service area covered
by the transmitter is determined by
(A) the half-pos.er beam width, the height of the transmitter and the radius of
the earth
J&{t, height of the transmitter and the radius of the earth
/*q,, the half-pox'er beam width and the radius of the earth
the height of the.transmitter and the haif-power beam width
the height of the transmitter (
Space fqr rougt(uork )-r t,E

ry C
g. \ *XAto -3.1

/o
I *--

k e-l Ee {>6i,,< 4-ctr

W
Phy-Chy -r-A2120t9
11-

(o
s"
-%-.-
2l
r_l
I 6
[P.r.o.

# -v
/D
 l. 1,4
Orl
t, ' (---",
)
cA

69. In a single slit diffraction (of width o) by a monochromatic source of wavelength

I the firsgnidfrum of the intensity distribution occurs at an angle u -"QL
(c) dv\- /\
.W{ r,) * * o
(D) + (E) ; uu^
Ov
a
70. A monochromatic source of wavelengt[ 600 nm was used in Young's double slit
experiment to produce interference pattern. Ir is the intensity of light at a
point |y
e screen where the path difference is 150 nm. The intensity of ttght at a
j
ontheScreenwherethepathdifferenceis150nm.Theintensityoflishtata.< :4 n
,r.here the path difference
point wheryJhe by
difference is 200 nm is given by -4n
{t, (B)
} r, (c) ! r, n, .-
f
i ,, ?
7a
(D) i t, (E) 2 -- /+Jo"" A
I
71. The Brewst(+angie for air to water interface isJ. r= Too
i e' ry
'/ ' " -
,*Ku.rt, (B) sin-l1t.::; ' ?.j'*rt(t.::) 5

72. A TV transmitting antenna is 81 m tall. It has a half-power beam width of 10

degrees. If the receiving antenna is at the ground level, the service area covered
by the transmitter is determined by
(A) the half-pou'er beam width, the height of the transmitter and the radius of
the earth
$theheight of the transmitter and the radius of the earth
/*CrX the half-porver beam width and the radius of the earth
the height of the.transmitter and the half-power beam width
the height of the transmitter(
Space rouqt(vork 1."3
t *X Qr/i- l o' -2. .,
2-1 Cd@
C-
Gv v *.<.-*; 7(--

Ltr
X-
kr-/
Phy-Chy-I-A2120r9

#.V
 4 oLv3s-
"^[L "& ;$y1
. (-\ 2-ecs
passinglilent electric discharge through bxygenffi asn ozonizer, 5,5 mol Yo of
FF -to, -

oxygen is converted to ozone. How many moles of 02 and Ol.result whea 35

r4oles of Oz is originally present?
\4.4 lt (c)3s.0
]l'o # *Jav,_
Carnatlitfis a n\ifidral Fnre+
conthinitry{ ' z3
(A) K yo o)* f6 N4 --'
(c) Mg
(D) Fe )9{">
/ t\
(E) tnlatatcl .-q
t\ _F-'.S
,ts&-
i 75. .Maximum number' of photons emitted by a hi{b capalte.
riibnochromatic light of wavelength 550 nm is , if
iuppliedplone hour.
{
rcz! (B) 5 * l02a .,

s*td1 ' 5 x 1022

'(E)
16i'.t Wtligh of the foll0wing is the correct unit of angular drlhnil h
mrym-.=->-,
an-orbital of ari-aam?
(B) J/s
Ml/A"* (q;F
.(A)
'(D) (E) Js2 f.g
Consider a fcc lrtfice made of a metal cation O,f)'@d lke cru drc per
unit cell. The resukrrt structure would have pA;) lv
(A) 3D network ofe@e shared octahedra
(B) 3D network of corner shared octahedra
or-3lu
(C) 2D network of edge shared octahedra MB
lpetwork of corner shared octahedra
network of face shared octahefua
Space for rough work

bot -?or Fl .{ tt L't

L&g,u, ,.1 o gx 3oao

,:ffi,%
5;G xtfl-, ..
'1

'i
 A-
I\,*''4. L='-<--
6ur\n,
L )-=
->Jt- ]rr -
)--'q ' d.y, t
7t. The edge length of a solid possessing cubic unit cell is zJir (structure I), based v'
on hard sphere model, which upon subjecting to a phase transition, a new cubic C/z
where r is the q
tu
strucrure (structure II) having an edge length of + is obtained,
J: "e6r,
\Y !
=

radius of the hard sphere. Which of the following statements is true'

' tl, = \6,I> r 3
(A) Density of the structure II is lower than structure I _ tihyV 3 \.\ -
(.B )-lensity of structure II is higher than structure I - -&'
The oore volume in structure I is 1.2 times higher than that of structure I Il
- -d \,
fne pore volume of both the structures are equal a. \ n\ l
@f
(E) The octahedral voids in structure T.is transformed into tetrahedral voids in
')ururtureu \ h'
4-,r31rr ., J,\
An ideal gas "A" having vokime-o-il L at 27 nC is kept in a container having {6.
movable piston and adiabatic walls-in ambient condition. If 1.33 L atm of
energy is supplied inside the system, find out the final temperature of the

(A) 3ee K 5 4ss K (c) see K C-, ,

@) 299 K
\:")
L\ (E) 4s0 K
\-/
b,/^u
r-., ,,'
-i/ '/^

closed container contains some water and N2(g) at 29 "C. The total X
L
\
hli 5.2
q'v
(/
)/l
\/ "
pressure of the system and water tension are 1 atm and 0.04 atm, respectively. - {-*
' Upon electroiysing the liquid water inside completely, the final pressure of 01-
system \vas at 2 atm. What is number of tnoles of water that was p?:T, inside t

H '^,ok'ffiS
{6 :;
Z:
(A)
(D) 0.208
RT
0208
'f,(L' (B)
(E) 8.0
fr
',.;
t-
g\-
?^, " * o
P,,.,
i- \-
>cc^-- Z
\"#
\a"/ lu >./r-1

Space for rough lvork I ,.t=^

hq-o ' r Li- +
\o .

2 * C. 'L z{zc, -;::,

/ tro,rc ! 6a o t:+*-- tat , \ 0,z c'"
t {<s-t,/
3bY (a /-K
JDA {d Lo '{rt 2A==
tra
/ '94-e r*-le
-?
"
Phy-Chy-I-A212019 /,J [P.r.o.
,YT ?/
rOrPoY t t)
 "5L
/ D'ht 'ztr^l"r ' 'h'JZo\ '

(
c
q-r -{:;,".',,",] "m;l :il : l!;?r, % by,m.E,?..-;,],L-*o,*.
jr methanol have densities of 0.964 kg L-' 0.793 kg L-', respectively, find the
attd
per cent of methanol by weight? I C,iG ".,S rf,
(A) 1s.8 {G." (c) 2a I ,-f isr
9-b
e

(D) 14.8 (E) t7.6 fz-C

Yd 82' The Henry's law constant for 02 dissolved in water is 4.34x 104 atm at certain
+s
.sL
a'r.- r
temperature. If the partial pressure of 02 in a gas mixture that is in equilibrium
with water is |!/,34 atm, what is the mole fraction of 02 in the solution?
k^ =tr'34^,J
1
J\-r\

Lt .1#
cq (B) 1x10+ F-\
{o (c) 2 x 10-5
(D) 1 x 10-6
Y-?"
(E) 2x104 0.A34 =rffi,J--
The standard heat of formation of CHa, CO2 and HzO (1) are -76:. -19-1.5 and
-285.82 kJ mol-1, respectively. Heat of vaporization of water is -1-: kJ mol-l.
lculate the amount of heat evolved when 22.4 L of CHa, kept uniier normal
conditions, is oxidized into its gaseous products
(A) 802 kJ @-sr.{fr' (C) 701 kr
(D) 788.4 kJ (E) soo kJ

Acetic acid dimerizes when dissolved in benzene. As a result boiling :'rn: trt the
solution rises by 0.36oC, when 100 g of benzene is mixed rvith "X* g l: acetic
acid. In this solution, if experimentally measured molecular ri'eiehi ci acetic
acid is 117.8 and motrar elevation constant of benzene is 2.57 K kS rr] . n'hat
is the weight Yo and degree of dissoc:[4tion (in %o) of acetic acid in 'rerzEne?
(A) 1.62 and 98.3 '{0.s1 and 98.3 (C) 0-5 anc s5
(D) 1 and 98.3 (E) 1.4 and99
/./'
.S{ At a certain temperature,2 moles of CO and 4 moles of Cil gases u'-r. rs3cted tO
form COCI2 tn a 10 L vessel. At equilibrium if one mole of CO is rr;sent then
equilibrium constant for the reyyF
(A) 4 (3) 3.3 (ci 1

(p) ?.s ,
\,,o[ --
cHr::sr Lhzt3) J'i'"E;"'b,',.'.
r -(E) 1's

I'- t
W,r-chy-r-A2 t2ors ,04,*
' ' t 0 \o 2
'U +
{yt
 ,
.t,'=ffi'r*t
u":_#*4
r hturlt
86. The equilibrium constant for the reaction, Nz (g) + 3H, 2NH3 (!y ' uni 1

=:
2Nz (g) + 6H,
==
aNH, (g) are Kr and Kz, respectively. The relationship
between (pnd K2 is
t*TKr: Kr' (B) Kz: Kr-2 (C) Kr : &2 *4-
o{^
(D) t<r: fr 1p) K1=.,82
C't
€,
-€
87. For a first order reaction, A(g) * B(g) at 35, "C, the volume. of 0.A,, left in the _i --o

/4;:6.Or6r-t*]nt' - {
, / minutes 0 10 20
t)
30 40 L: t-fi *11
V/mL 25 20 t5.7 12.s 9.6 -
"*V\'@ ?^
' '/
What is the vdlre of rate
@ffizz3 r min-r
const4nt?
rril a.04231mfn-l (c) 0.0623r min-r t
"7'"
(D) 0.08231 min-l (E) a.tz3tr min-,
'
rrrrrr
-l'\'.' t l-
88. E""11
,
of t#totlflowing cell is e ^-, p 'B ,3 j, L. U o
"cePx ----'--'=
-' \ '- " -
Pt(s) | Hz(s), l Agljc.(l M) u.1o.r "n t>
ii ar I P(s)
gff - igffi (c)
+4;@4 zu€r{
-2.3-oJRr r<r-v,,1u"yr-
2F
(D) 2iq:RT zF (E)
\L,, S &tr .. L=
W.o-,*-
*lt^<+zt*t \z-,
zr ,A- i
@r
89' In a lead-acid battery, if'l A current is passed to charge
the battery for t h,.w.hat E;t
(o.r7l=
is the amount of pbso+ converted topwz? (Given
daia: lf :96500 c mol-r) , -a-
(A) 0.0373 moles 86 moles (C) 0.0093 moles
to
(D) 0.0268 Roles 0.0400 moles
, ,Space for rough work
;':"-- _)

260
a-d
o <+
lsTt lBoo -2_
(rc

4e'*
/ r>=D- tl_Eer
--.-----_-.---:
76{* r
/

'2s
eorlff
' i
le,+€-
[P'r'o'

/4
-r'-
sd
 l

'O fuel cell operates at constant current, with H2 fuel (1 bar) and 02 oxidant
,0.
(1 bar). The electrolyte used is 0.001 M HCI and the produet(s) of the reaction
are confined inside the fuel celt. Wn-ich of the following is true about the
electrolyte?
(A) Boiling point of the electrolyte decreases with increase in the duration of
fuel'cell operation
(B) Boiling point of the electrolyte increases with increase in the duration of
'fuel cell operation
Circuit voltage of the fuel cell remains constant with increase in
duration of operation - '

(D) Open circuit voltage of the fuel cpll increases with increasei4-duration'of
operation
(E) Both (A) and (C)

91.; The porrept IUPAC narne for methylisopropylacetylene is

' q<ery
(A) 2-methYl-4-PentYne*
ethyl-2-pentyne ,.*. r N,,\
@
(C) isopropylmethylacetylene rt ^a L crhS
,7\
c= c-Ei%
(E) 2-methyl-3-PentYng.
*,
L- / "5 l
v- 3 5r-
92. Cycph*ylamine and aniline can be distinguished by
\J.Kf Hinsberg'stest @ (c)
@ (@ --:-
':;.1 --
93. The compounds pyridine and planar cydlboq$traene are

aroinaiid and non-aromatic

(B) aromatic and anti-arornatic
(c) aroriratic and aromatic
'"'(D} an{i-aromatic and non-aromatic
(E) anti-aromatic and aqti-4romatic. * r

Space for rough work ,

ai
fl 1 i

r:
i. Phv-Chv-I.A2/2419
-JJr'k

'' s g-:'

_ :i
 ({-b<wqw
94.Propylen9o{treatmentwithHBr/H2O2provides
*5.--
-bromopropane (B) 2-bromopropane (C) l,2-dibromopropane
(D) 1-bromopropan-2-o1 (E) 2-bromopropan-1-ol
is a potent vasodilator.
($)zI{istamine (B) Serotonin (C) Codeine
Cimetidine (E) Aspirin
Iq)
An invert sugar is
(A) Isorotatory (B) Levorotatory (C) Dextrorotatory
(D) Optically inactive (E) MutaroyW
Th6 sffpngest base among the following is
(B) oH- (C) CH:C-
(D) CH3CH2- (E) OEt-
98. The neopentyl halide in ethanol yields alkenes by E1 mechanism due to
1o{ concentration of solvent G
c+\
absenee ofbase
it is a primary halide
(- '_L-
r
ad&
I
factor which prevents E2 mechanism
{@J-$ffi" C-
. (E) solvation effect r->

99. Arylbromides are not good candidates for I

5T
,2"-\r
(A) Wurtz-Fittig reaction
(B) Fittig reaction
\,DI
\,/
(C) Friedel-Crafts reaction
dDf Grignard reaction
*-@f G abri el -phthalimide synthesi s
'5oB
100. Sulfonation of benzene with excess sulfuric acid provides
,\
(

t(C)
(BWenzened ulfonic ac i d
is

o-benzenedisulfonic acid
ry
(D) m-benzenedisulfonic acid
@ofbenzene , ,

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Phy-Chy-I -A212019 27 [P.r.o.

 ':

101. The fol,towing reaction is named as

ry.:" -#- ry;;

(A) Reimer-Tiemann
,4
(B) Kplbe-Schmitt
\t
'- ffiizz*o t-\ C
(D) Gattermann
^--\
(E) Aldol L?l
102. When C6H5COCOCoHs is iEdusea with LiAlHa, the product formed has
stereoisomers.
(A) 2 (B) 3
! (D)6 (E) 8
103. The compoundwhich does not lead to benzoie acid by oxidation withKMno+ is
(A)'tolupne _.^ (B) benzyl alcohol (C) n-butflbwpene
(D) t-butyl$ffi G) styrene ',
,@+ the rmf,ann reaffangement of primary amides having optically active-iroup
\t itt'r S-canfiguration, the product amine has a_
.
(A) R-conhguration t-
(B) S-configuration qi ---F .*^(
(D) Meso form G
(E) Achiral nature

4n'L-
!
't'

b,
Phy-Chy-I-A212019
 fq}* nc..,.- Ior^
/+\ 1-

Qs
105. Benzonitrile can be prepared from benzaldehyde on treatment with Q"b @
(A) NH3
(B) NH3 followed by hydrogenation with Ni
I
..(.\ Urtfi <* J
(d I
Nc
(c) NH2OH \l
-q
+/'-{D}trJ2OH
followed by dehydration with acetic anhydride
(E) Hydrogen cyanide
106. The product formed in the below reaction is
YU
W- 2-
@L-- g*i'J'fi-eh
CHO O
lo" cl
H3C-N-CH3
,t{ f5
{_,/
o
H2SO4/HNO3

--.-------------
,/1\
cnud cH" o CH" O
)6 ct
ft}fN-cH3
lo" cl
H3C-N-CH3
lo_ cr
H3C-N-CH3

{Q Noz
(D) q-"'
Noz
(E)
P*",
Noz

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Phy-Chy-I -A2/2019 29 [P.T,O.

 I

i-i
107;*N0t has bond order

least boiling point?

- (A). Nr*s (C) AsH3
, (D) SbH: (E) Bir{3
I09, 'dhich of the followi@ets has Lewis acid behaviour for all the components?,
,O$
BF: . (B) BF3, SiF4, PFs (c) siFa, PF5
(D)]BFr, PF,
110. The rcarbon atoms in calcium carbide are held by
(A) Ionic bonds
(B) Two sigma bonds i S CrZ_
(C) Two sigma and one coordinate bond _€.

(E) One sigma and one zr bond ".,

\ 'H-
111- According to the vsEpR theory, the.shapeof clo3-
would be
(A)Linear (Bi
T,*;i,;il;'"-'"[ffi;r
(D) Square planar (E) Aqgular
112. Acetic acid in tiquid ammonia behaves as
(A) Weaker acid than that in water i[..- iJ 9,
(Bt'Stronger acid than that in water
(C) Base acid
(D) Neutral acid
\J
(E) (C) and (D) .:.];

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Y, e1
9r
Phy-Chy-I -A2/2019 Llt 30
114. Rare ga-ses are sparingly soluble in water because of
(A) Hydrogen bonding-.-
#)dpote-dipol e interaction
tCl hduced'dipole-induced dipole interaction
(D) Dipole-induced dipole interaction
CE) (A) and (D) t
'., O L{
-when heated is
115. An example of a non-stoichiometric q
(A) Beo (C) MgO t<^-(-s"-
(D) Cao cq, r,{--t.,^ ^
CtT" N^
116. The donor atom in EDTA are
(A) Two N and two O Two N and four O (C) Four N and.two O
N and three O Two N and three O .,
./
ids prefer to combine with
'Soft bases
s
(B) Soft acids (C) Hardlcids
.
.8qc;
(D) Hard bases . (E) {W+s--- 'f'
5'\'
I
\-N*
118. Among the foll olving, *hi.h "rp.cies represents a pseudohalideJ?
(B) Cao (C) t\S f-t.
(ArcN-
(D) K2HgIa (E) BiOef :' "':., --
12
dr-\I'rtf";' .
119. PC13 is stored in a well stoppered bottle since \A.>
(A) " It decomposes in the pres€nce Qf moisture q">
(B) It is decomposed by light
(C) It ishighly volatile
(D) It reacts with air to form POCI;'"' '

fZ6. en orange solid (A) on heating gives a green residue (B), a colourTes's gas (C)
and water vapours. The dry gas (C) upon pdssing over heated Mg gave a white
solid (D) which upon subsequent reiction with whts gave a gas (E) that gave

ffi (B) CuN2

Gtrseei"-- .\"'i 't
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13 _i
A 31 *-*-+
Phy-Chy-I -A2120t9 T*"^^