SRE) ao: 134

V . S A K T H E E N A R A N

X-A1

CHEMISIBy

Hgme chleMd@gp
uchlcgromePDle
D e c c i e h
petangses Sn B
-chlas
chlano.pem uncoase
gteacih thoct -chlozo pentoua
c
AAH
CH-CH-CHhk
CHC CH-CHg
Ctts CH3
mchylbut-2-gs03
C C-CH2C3
cH3
a-Methy#pea1)
2Tn chosoken zerp He cl-atem s_limad o
a hybrsidi zed C-aen olmeaa in_aplotg
ooica, tha C aom ia linkad to a ybrki zd
CoDbs. P hybaicld Casben h mop s-
dkocs n ap hyoriclizeel Caks agm..
horo the
Iieto, thodonafy of e ot C-d
reo daHom ess ta) in apotot
ChoicAlso,tR eftd C benzis igot
chloobenz age tta ednziy ot Cay bed
t h o C-adon., polaoity V Pchbrcberaa
Honce, dip meNONIEo chkombenzaie e su
Mlan thal cpobxyl dhlo
 Date

iGoingod eacien Neay c t a , in

ase

stoya. h the pcsemeKa ot moistug

thoy zeotbiua alMaD

R-H H,o Rt +6 HDx.

houdbs prepaod un anhydaub

CondHich
2-boempa-mathy pemam K2 bremepentoua
) (
AI-omemerot ana.
- b o n 2-netasKa-oueme mdhy) , brong3-heh
butuo outaro

5CH-CH=CH+H-H)
preo. Oiboona
CHOH C cH-CH C, BH
H BHa
Cis-CHcrecHa-cHCH3B 3tt,OH
CHCHCH OH +60tD
SUenan-1-o

OH OH

o
&melhy pod 2-elyl plarsk
C
CHa
 Date

Th-CH gty afackd o tlu benaens vim

actiuts it, touands elaclapilks subsitufiey
nashg qoeun to ov/o
esien in 1pas tlwe ostfisl8
n e 2ich die b 1 dSCan cHet
Cased ky -CqY)
s chamge at o P lie
aciuat berai sin toob dto.
T c subgtrtutish Deachisn.
ot-H H
2

CHocs aON CHO

+NaCH O)s0)
Bcnuchiosictt Benzy
atchel
C O tcHfaBz
cth

Ctl3

HaoH)60+ ct3-c -ctl3

 Date

HtinCy
CHTH--HIC CH CH2 - -O
orth aot,
phona
p/gynexicle, poclucd; Wlon
d cort
FOdiuun phaTxdt Deacls uot79ce8
lleed y acidriiccuie, iio
etphlic Fupat1tquie) o g i

COR|O,
otho lpdoxbnaic
phortd Socith
phnoxic
aCo

khon a ptnd tosted wrth

dilarotoon in ieRoesere ot 3o/hoH,a CHO0
gun s iodueat tho oho posish at
Laizeno ding -Ihis c a l k Hei emm

PhuekOeHClzo9lloot

QHL inimdiuo
CHO CHO

alieyhdehy
atem r ) .
E CH-0-CHH
 Date

CH
CH-C-cil3

+H
O - C-C-Ç-C-Ç-C -H
H4OH HOH H

ILhe de oinreacisnci scion doord

en gobiy OT hocatisen io.Tho Jenzl
CObbocaon
hiahlayia oy esptne eia
hia eocio o d tHsgN,
Bcactig

-etbudasn qpicglluaciua bu
DOnosLtao_3 eticou InaciNG becae
brmObtkh hdUO
to henobrtahg. ha achigal CaksN
 Eleclrophilkc qubolituh ), sqcion in
haponeNS cceOSbuly duo
tho sing gts faotial,
cucti ycild

lleus 1odon Kindeza ordKinc

*sle poces 1leN pocce
Cdn-of seoctity Odm ot scactii
X
3p
Casbcccrtien fcoMay no-qoboet ioN
ieNmmcligc
k cemisatien tateb
Pke
fao h
Gesd ieniza allot Wolan odic olois
*Unimolccuh Bimdoc1ko)
easanMOT ny tafa X NG
place ScdUn9MOM
An_ciect os moeculk hich is ngt,
uDEm.bsabk on, jts image Uscalle
cha and thu plonghanoN ja
callad
ilOptioa gems which a Aat nen
UPIMOOoe MDDN_inDgo a aled
 Oate

cationcs Gth phoenonen w coalltd as

encienMLYM
tSubsshnaewhich oldl3 1ha PP to
ho Jig sidg o cloc4-wise dIoEcticn u
doxtoonotaty whon athe
phch poaly tho TPA ,E sd Gni-clra

iaoadinglkncs b,algt haids by ta

addrtion drogon talice
m oe of gclitiH to usyMIICrical alltro
Haicuinisv5 pule u3 tolucd.£g-pogere
io poopluk1 but ony H Pcaninates
accooli
CH3CttCth fHI CHCtCH
Tnine)
C-CHctl3

n danpbaholnenatioh
pcljict tttalhole whch has qnere
unlen_at alhik qruh outkdhed to to doualy
ercbd -afmg
ClgCH-ch-CH
Ot
Ot
HC-CtCH=CH-CH 3 HCHctbi,CHG
pe-to.(812
 seacin,
eechcphilkc subsirkri which tto
An
chamcg eactGn in. cempeud
atkctd o a
t u c i e reyn
xed an,sltcpiile.

aubstits
ot electsophilic
h types
talapnafon phace by veacig
Ihx vecchen takpB in t a pieaice
hqlo azaNch th hakadhs
ofc teoaic sdt

1-gichbpbermk
C Cmine)
-dichbebeizoo
Cmais)
i Ubartisn retig hgcatD
llo serctieh hhs Dore by
pocbence t con-HT
oth ceie.HNO in tioC
c

enHS1-chso-2-pTebee No
-chlzo-L-Drtobora
Cmcsj
Suphonatien ha Dacien toatos phre bu
hechig acaoonos th coc.HS
c

chlookerso -chicdcehze so,H Ldhke kenat

Gulenic ac0 au plenic cd
miney Ureij)
 Date

wFsCafis Rendren
Hiylatien:
c
CH3
+

I-ch amotuyl bezeeti3

(mine
I-chkeo-L,-metra
ehze
ieyisn. cysn).

OHCHC0
a-chitaetgite
Cmno

CH 4chleaeaccpppee
cH3 Coajn
O
BAlza0 diazonin
halide
4No1

CHBt AF CHf +AgBu

Hethy FlUO
oosmidb tUODICO uloio
 pate

To eaien alhy hsljiold wih

a in coy e f o "gi,hydo cosh
cofainig osudo tho Catom
delet in the uloQ is Wtz vsCICi

Rx1NaSR-R+QNox
vkhon a mixtuo, at an al hakicb
dohaio gila alybrano wjon beta
Lofh Ma iH doyethons this u
Wurt2. iHi yeacting

4a tRx
halicbs GjgSanalageus,csnpeur)
mteasd Wth Nain, coy e

+Na 6U

aax
Dmon
7 CCH C H/H CH2-CH,-CH-6
Proyo

Ctlg CtCH OH
PE-1-d
 Date

CH3Chi-CH-Br hOH/ACHCHCi
ehghohalgsdien HB r6devinkoy
adbliien
CH-¢l3
B
Ctl3 CH HO

Teuoy Balal_acha

I23-ZI

Anlina

Chiob-bezeno
2CHcHOH H CH:l HB
thandk
e Hgct B
CHEcH 4cHCH B TNal v2 cHECH -CH-CH
butl-uMO