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Construction and Building Materials 72 (2014) 340–357

Contents lists available at ScienceDirect

Construction and Building Materials


journal homepage: www.elsevier.com/locate/conbuildmat

Review

Recycled waste glass as fine aggregate replacement in cementitious


materials based on Portland cement
Alaa M. Rashad ⇑
Building Materials Research and Quality Control Institute, Housing & Building National Research Center, HBRC, Cairo, Egypt

h i g h l i g h t s

 Glass sand increased mixture workability, bleeding and segregation, whilst it decreased density.
 Glass sand decreased mechanical strength and drying shrinkage, whilst it increased ASR.
 As the particle size and glass content increased as the ASR expansion increased.
 Green sand colour effected ASR expansion. MK, FA, slag, SF, Ni2CO3, LiNO3 can it.
 Glass increased chemical and fire resistance. At long terms, it increased carbonation resistance.

a r t i c l e i n f o a b s t r a c t

Article history: Disposal of waste glass derived from container or packaging glass, flat glass, domestic or tableware glass
Received 12 August 2014 and continuous filament glass fibres is one of the major environmental challenges. This challenge contin-
Received in revised form 23 August 2014 ues to increase with increasing the amount of waste glass and decreasing the capacity of landfill space.
Accepted 28 August 2014
Therefore, studies have been carried out to find practical ways to recycle waste glass in building materials
such as cement, mortars, concretes and blocks. This paper presents an overview of the previous studies
carried out on the use of waste glass as partial or full natural fine aggregate replacement in traditional
Keywords:
mortar/concrete mixtures based on Portland cement (PC). Fresh properties, mechanical properties, abra-
Waste glass
Recycling
sion resistance, water absorption, chloride ion penetration, permeability, chemical resistance, carbon-
Fine aggregate ation resistance, drying shrinkage and alkali-silica reaction (ASR) expansion of mortar/concrete
Mechanical strength mixtures containing waste glass as fine aggregate replacement have been reviewed.
Durability Ó 2014 Elsevier Ltd. All rights reserved.

Contents

1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 341
2. Heat of hydration and heat transfer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 342
3. Workability and setting time. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 343
4. Bleeding and segregation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 344
5. Density . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 344
6. Mechanical strength. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 345
6.1. Mortars . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 345
6.2. Concretes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 346
7. Fire resistance. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 349
8. Abrasion and skid resistance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 349
9. Water absorption . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 349
10. Chloride ion penetration and permeability. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 350
11. Chemical resistance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 351
12. Carbonation resistance and capillary sorptivity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 351
13. Drying shrinkage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 351

⇑ Tel.: +20 (2)33351564; fax: +20 (2)33367179.


E-mail addresses: alaarashad@yahoo.com, a.rashad@hbrc.edu.eg

http://dx.doi.org/10.1016/j.conbuildmat.2014.08.092
0950-0618/Ó 2014 Elsevier Ltd. All rights reserved.
A.M. Rashad / Construction and Building Materials 72 (2014) 340–357 341

14. ASR expansion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 352


14.1. Effect of glass content . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 352
14.2. Effect of glass colour . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 353
14.3. Effect of glass particle size . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 353
14.4. Suppressing ASR expansion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 354
15. Waste glass combined with other recycled materials . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 355
16. Remarks . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 355
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 356

1. Introduction materials in Taiwan was approximately 600,000 tonnes [8], whilst


the amount waste of glass dumped into landfills was approxi-
Glass is produced in many forms, including packing or container mately 0.52 million tonnes in 2009 [9]. In 2010, approximately
glass, flat glass and bulb glass [1]. The uses of glass products have 425,000 tonnes of waste glass were produced in Portugal and only
increased tremendously resulting in large amounts of waste glass. 192,000 tonnes of them were recycled [10]. In 2006, the waste
In 2005, the estimated production of the global glass was 130 Mt. glass consumption was 2.3% and 2% in eastern Africa and Middle
Container glass accounts was approximately fifths and flat glass Africa, respectively [11]. In 2005, the recycling rate of waste glass
was approximately one third of the production. Production was approximately 67% and 91% in Republic of Korea and Japan,
volumes for fibre and special glass are small. The European Union respectively [12]. Overall, there is unclear information about the
produced approximately 33 Mt of glass, whilst China and USA pro- whole quantity of waste glass in the world, because of the lack of
duced approximately 32 and 20 Mt, respectively [2]. In 2004, the information from different countries like the Middle East as an
United Nations estimated the volume of yearly disposed solid example. However, it was estimated that the total amount of waste
waste to be 200 million tonnes, 7% of which is made up of glass glass generated in the EU-27 in 2007 was 25.8 Mt. This result from
the world over. In 2010, the percentage of waste glass was approx- a total production of glass in the EU-27 of 37.4 Mt in 2007. The
imately 4.6% of total MSW generation in the United States (Fig. 1) extra-EU trade of manufactured glass represented only 5–10% of
[3]. In 1999/2000, the percentage of waste glass was approxi- the production (Fig. 2) [13,14]. The amount of waste glass is grad-
mately 2.1% of total MSW generation in India [4]. In Turkey, this ually increased over the recent years due to an ever-growing used
amounts to 120,000 tonnes, 80,000 tonnes of which are recycled, of glass products. Most of waste glass that is produced is dumped
with Germany reporting 3 million tonnes of waste glass being into landfill sites or roadways sites (Fig. 3). With increasing scar-
recycled [5]. In 2006, Americans generated approximately 12 mil- city of landfill sites and the fact that glass is not biodegradable,
lion tonnes of glass, of which only 22% was recovered for recycling landfills did not provide an environmental friendly solution.
[6]. Of this small percentage of recycled glass, most (90%) is used to Waste reduction and recycling are very important elements in a
make new containers, whereas the remaining 10% is used for sec- waste management framework because they help to conserve nat-
ondary applications, such as roadbed aggregates and fibreglass ural resources, reduce demand for valuable landfill space [7],
insulation [6]. In Hong Kong it was estimated that approximately diminish the need of raw materials to make new product, reduce
373 tonnes of waste glass is generated daily in 2010. Approxi- air and water pollution, reduce energy and create new jobs. It
mately 4500 tonnes of the glass were recycled annually, the recy- worth mentioning that in European zero waste program it is esti-
cled percentage was 3.3% and the remaining 96.7% was sent to mated that resource efficiency improvements all along the chains
landfill for direct dumping [7]. In 2002, the annual waste of glass could reduce material inputs needs by 17–24% by 2030 and a bet-
ter use of resources could represent an overall saving potential of
€630 billion/year for European industry. Furthermore, more than
180,000 direct jobs in the EU by 2020, in addition to the estimated
400,000 jobs that will be created by the implementation of the
waste legislation in force. They will lead to satisfying between
10% and 40% of the raw material demand in the EU, while contrib-
uting to achieving the EU target to reduce greenhouse gas emis-
sions by 40% – 62 Mt of CO2/year would be avoided in 2030 [15].
Anyway, the use of recycled glass in the manufacturing of new
glass reduces energy consumption, raw materials use, and wear
and tear on machinery. However, not all used glass can be recycled
into new glass because of impurities, cost, or mixed colours [16].
Indeed, there is a need to establish new options for recycling waste
glass. One important option is to employ waste glass in building
materials. Since 1963, the first study had been carried out on the
use of glass chips to produce architectural exposed aggregate for
concrete [7]. Later, owing to the excellent hardness of glass, exten-
sive researches have been carried out to utilize recycled glass as
coarse or fine aggregate in concrete and mortar [5,17–20]. Crushed
glass particles that were used as aggregate are generally angular in
shape and may contain some elongated and flat particles. The
degree of angularity and the quantity of flat and elongated parti-
cles depends on the degree of crushing. Smaller particles, resulted
from extra crushing, exhibited somewhat less angularity and
Fig. 1. Percentage of waste glass related to total MSW generation in the United reduced quantities of flat and elongated particles [1]. Other
States [3]. investigations studied the feasibility of milling the glass cullet into
342 A.M. Rashad / Construction and Building Materials 72 (2014) 340–357

Fig. 2. Mass balance of glass production, consumption, waste glass collection, recycling, traded and disposed [13].

Fig. 3. Waste glass landfill.

powder form and used it to replace cement in concrete and mortar that the previous studied that recycled special glass (i.e. cathode
[21–26]. ray tube (CRT) glass and liquid crystal display (LCD) glass) as fine
Already the literature has abundant of review papers related to aggregate in mortar/concrete will be reviewed elsewhere.
employing waste glass as a component of building materials. The
previous studies summarized the progresses and pointed out the 2. Heat of hydration and heat transfer
directions for the proper uses of waste glass in PC and concrete
[27]; corrosion of glass and expansion mechanism of concrete con- Poutos et al. [29] studied the temperature within glass concrete
taining waste glass as aggregate [16]; incorporation waste glass during hydration when concrete exposed to 60 °C and 20 °C. The
into concrete as a supplementary cementing material [28]; man- grading of the natural aggregate and glass cullet complied with BS
agement and recycling situation of waste glass and the experience 882: 1992 requirements for 10 mm all-in aggregates. Natural sand
of using recycled waste glass in concrete products in Hong Kong [7]. was replaced with waste glass at levels of 0% and 100%, by weight.
Indeed, there is no article that summarizes the previous studies car- There were three colours of glass named emerald, amber and clear.
ried out on the fresh properties, hardened properties and durability The results showed higher temperatures generated during hydra-
of mortar/concrete containing waste glass (derived from container tion of concrete made of glass aggregate compared to the control.
or packaging glass, flat glass, domestic or tableware glass and con- Concrete made of green cullet showed the highest temperature fol-
tinuous filament glass fibres) as partial/full natural fine aggregate lowed by concrete made of clear cullet and brown cullet, respec-
replacement which can serve market. Therefore, this paper was tively (Fig. 4). Exposed concrete to 60 °C, glass concrete showed
written to present the previous findings related to this topic, to the lowest rise in temperature. Exposed concrete to 20 °C, glass
act as a reference base for future researches. It worth mentioning concrete showed the lowest reduction in temperature.
A.M. Rashad / Construction and Building Materials 72 (2014) 340–357 343

Mixed colour beverage glass containers were crushed to produce


graded aggregate (size <5 mm). Natural sand was partially
replaced with waste glass at levels of 0%, 5%, 10%, 15%, 20%, 30%
and 50%, by weight. The results showed a reduction in the slump
value with increasing waste glass proportions beyond 30%. Chen
et al. [37] observed a reduction in the workability of concrete mix-
tures containing waste E-glass (size 38–300 lm and 40% <150 lm)
as natural sand replacement at levels of 10%, 20%, 30%, 40% and
50%, by weight. The workability decreased with increasing glass
sand content.
Ismail and Al-Hashmi [38] partially replaced natural sand in
concrete mixtures with crushed waste glass (size 4.75–0.15 mm)
at levels of 0%, 10%, 15% and 20%, by weight. They measured the
workability in term of slump. The results showed a reduction in
the slump value by 23.33%, 30% and 33.33% with the inclusion of
10%, 15% and 20% glass sand, respectively. de Castro and de Brito
[39] partially replaced natural sand in concrete mixtures with
Fig. 4. Relationship between temperature and time during hydration with the waste glass (size <4 mm) at levels of 5%, 10% and 20%, by overall
inclusion of glass sand [29]. aggregate volume. Various w/c ratios were used. The workability,
by slump, was measured. The results showed a reduction in the
workability with the inclusion of glass sand. The reduction in the
Borhan [30] partially replaced natural sand in concretes with
slump value was 1.97%, 1.57% and 4.33% with the inclusion of 5%,
recycled waste mixed colour glass (size 3–0.5 mm) at levels of
10% and 20% glass sand, respectively. Batayneh et al. [40] partially
0%, 20%, 40% and 60%, by weight. Heat transfer was studied. The
replaced sand in concrete mixtures with crushed glass at levels of
results showed a slight reduction in the amount of heat conducted
0%, 5%, 10%, 15% and 20%. The gradation curve of crushed glass was
through the thickness of concrete specimens at a temperature
close to lower limit of the specified fine aggregate limits according
below 100 °C. The reduction became clearer at temperature above
to BS 882:1992. Fixed w/c ratio was used. The results showed that
100 °C. With high percentage of glass there was a significant reduc-
the workability of the mixtures did not affect by the inclusion of
tion in the heat transfer for all temperature levels.
glass sand.
From the above review of the literature in this section, it is
Malik et al. [41] reported an increase in the workability of con-
clearly noted that the heat of hydration with the inclusion of waste
crete mixtures by replacing natural sand with waste glass (size
glass sand is still needs more investigations. However, it can be
1.18–0 mm) at levels of 10%, 20%, 30% and 40%, by weight. The
concluded that the inclusion of glass sand in the matrix increased
workability increased as the content of glass sand increased. Ali
temperature during hydration.
and Al-Tersawy [42] partially replace natural sand with recycled
glass (size 5–0.075 mm) at levels of 0%, 10%, 20%, 30%, 40% and
3. Workability and setting time 50%, by weight in SCC mixtures. They reported that the inclusion
of waste glass increased the slump flow. The increase in the slump
Metwally [31] reported that the use of finely milled waste glass flow, at cement content level of 400 kg/m3, was 1.52%, 4.54%,
in concrete mixtures had bad effect on the workability. Taha and 7.58%, 10.61% and 12.12% with the inclusion of 10%, 20%, 30%,
Nounu [32] studied the workability of concrete mixtures contain- 40% and 50% glass sand, respectively. Sharifi et al. [43] partially
ing recycled glass (size <5 mm) as natural sand replacement at lev- replaced natural sand in SCC mixtures with recycled glass (size
els of 50% and 100%, by volume. The results showed a reduction in 2.36–0.3 mm) at levels of 0%, 10%, 20%, 30%, 40% and 50%, by vol-
the workability with increasing glass sand content. The reduction ume. Fixed content of w/c ratio and various dosages of superplast-
in the slump value was 28.83% and 33.33% with the inclusion of icizer were used. The results showed an increase in the workability
50% and 100% glass sand, respectively. Taha and Nounu [33] with the inclusion of glass sand. Borhan [30] partially replaced nat-
replaced natural sand in concrete mixtures with mixed colour ural sand in concrete mixtures with recycled waste mixed colour
waste recycled glass (size <5 mm) at levels of 0%, 50% and 100%. glass (size 3–0.5 mm) at levels of 0%, 20%, 40% and 60%, by weight.
They measured the workability of all mixtures by slump. The The results showed an increase in the workability with increasing
results showed a reduction in the workability with the inclusion glass sand content. Terro [44] replaced natural sand in concrete
of glass sand. The workability decreased with increasing glass sand mixtures with crushed bottle glass (size 4.75–0.075 mm) at levels
content. The reduction in the slump value was 20.83% and 33.33% of 0%, 10%, 25%, 50% and 100%, by weight. The mixtures containing
with the inclusion of 50% and 100% glass sand, respectively. Tan waste glass showed higher workability than the control. On the
and Du [34] replaced natural sand in mortar mixtures with four same line, the initial and final setting time increased with increas-
different glass colours named brown, green, clear and mixed colour ing glass sand content. Penacho et al. [45] reported an increase in
at levels of 0%, 25%, 50%, 75% and 100%, by weight. The grain sizes the workability of mortar mixtures by replacing natural sand with
of the natural sand and waste glass sand were between the upper waste glass (size 2.38–0.149 mm) at levels of 20%, 50% and 100%,
and lower limits of ASTM C33. The flow, which defined as the per- by weight. The workability of the mixtures slightly increased with
centage increase in mortar mixture base diameter after 15 times of increasing glass sand content.
drop on a flow table, decreased as the glass sand content increased. Ling et al. [46] reported higher workability of mortar mixtures
Park et al. [35] partially replaced natural sand with recycled containing waste glass (with approximately 23% coarser particles
glass (size 5 mm) at replacement levels of 0%, 30%, 50% and 70%, 10–5 mm) as natural sand replacement at levels of 25%, 50%, 75%
by weight, in concrete mixtures. They used three different colours and 100%, by weight. The results showed that the workability
named amber, emerald green and flint. They reported that the increased as the content of glass sand increased. Ling and Poon
slump and compaction efficiency decreased as the content of glass [47] replaced natural sand in mortar mixtures with crushed
sand increased. Limbachiya [36] studied the workability of beverage glass (size 5–0.15 mm) at levels of 0%, 50% and 100%,
concrete mixtures containing mixed colour beverage waste glass. by volume. The results showed that the flow table values increased
344 A.M. Rashad / Construction and Building Materials 72 (2014) 340–357

Table 1
Effect of glass sand on the workability of mortar and concrete mixtures.

Author Glass content (%) Glass size (mm) Positive effect


Taha and Nounu [32] 50 and 100 <5 
Taha and Nounu [33] 50 and 100 <5 
Tan and Du [34] 25, 50, 75 and 100 ASTM C33 
Park et al. [35] 30, 50 and 70 5 
Limbachiya [36] 5, 10, 15, 20, 30 and 50 <5 
Chen et al. [37] 10, 20, 30, 40 and 50 0.038–0.3 and 40% <0.150 
Ismail and Al-Hashmi [38] 10, 15 and 20 4.75–0.15 
de Castro and de Brito [39] 5, 10 and 20 <4 
Batayneh et al. [40] 5, 10, 15 and 20 BS 882:1992 No effect
p
Malik et al. [41] 10–40 1.18–0
p
Ali and Al-Tersawy [42] 10, 20, 30, 40 and 50 5–0.075
p
Sharifi et al. [43] 10, 20, 30, 40 and 50 2.36–0.3
p
Borhan [30] 20, 40 and 60 3–0.5
p
Terro [44] 10, 25, 50 and 100 4.75–0.075
p
Penacho et al. [45] 20, 50 and 100 2.38–0.149
p
Ling et al. [46] 25, 50, 75 and 100 23% (5–10)
p
Ling and Poon [47] 50 and 100 5–0.15
p
Ling and Poon [48] 100 60% <2.36, 40% 5–2.36
p
Ling and Poon [49] 100 <5

reduce w/c ratio for glass sand mixture to reach the same work-
ability of the control. This has a major effect on the strength. How-
ever, on the contrary, other studies reported that the inclusion of
waste glass sand in the mixture reduced the workability. This
reduction was related to the sharp edges, harsh texture, more
angular shape and higher aspect ratio of glass particles that hinder-
ing the movement of cement paste and the particles [33,34].

4. Bleeding and segregation

Ling and Poon [48] reported a slight increase in the bleeding


and segregation of mortar mixtures with the inclusion of glass
sand. They also reported that the more glass sand content with
large particle sizes (10–5 mm), the higher bleeding and segrega-
tion. Taha and Nounu [32] reported severe bleeding and segrega-
Fig. 5. Research numbers versus the effect of glass sand on the workability of tion were clearly noted in concrete mixtures containing 100%
mixtures. waste glass sand (size <5 mm). Taha and Nounu [33] reported
severe bleeding and segregation of concrete mixtures containing
mixed colour waste glass as natural sand replacement at levels of
with increasing glass sand content. Ling and Poon [48] replaced 50% and 100%. The bleeding and segregation were resulted from
natural sand (passing through 2.36 mm) in mortar mixtures with the inherent smooth surface and very low water absorption of
recycled blue bottles waste glass at levels of 0% and 100%, by waste glass, both led to lack in adhesive bond between the compo-
weight. 60% of the glass had particle size <2.36 mm, whilst the nents of the concrete mixture. On the other hand, Tan and Du [34]
remaining 40% had particle size of 5–2.36 mm. The results showed and Du and Tan [50] reported no segregation or bleeding was
higher workability with the inclusion of glass sand. The increase in observed in mortar mixtures containing waste glass sand at levels
the slump value was 5.76%. Ling and Poon [49] reported that mor- of 25%, 50%, 75% and 100%, by weight.
tar containing 100% beverage glass aggregate (size <5 mm) showed From the above review of the literature in this section, it can be
higher flow table than the control. The increase in the flow table concluded that the inclusion of waste glass sand in the mixture
was approximately 47%. Table 1 summarizes the mentioned increased its bleeding and segregation. The bleeding and segrega-
studies about the effect of waste glass sand on the workability of tion increased with increasing glass sand content.
mortar and concrete mixtures.
From the above review in this section, it can be noted that sev- 5. Density
eral studies reported that the inclusion of waste glass sand in the
mixture increased the workability (Fig. 5). They related this posi- Ismail and Al-Hashmi [38] reported that the fresh density of
tive effect of glass sand on the workability to the poorer cohesion concrete mixtures decreased by 1.26%, 1.96% and 2.26% with the
between the glass sand (impermeable) and smooth surface [47] inclusion of 10%, 15% and 20% waste glass (size 4.75–0.15 mm)
and the cement paste [44]. Also, lower absorption capacity [46] as natural sand replacement, by weight. Batayneh et al. [40]
and smoother surface of glass sand [49] are the main reasons for reported a reduction in the fresh unit weight of concrete mixtures
higher workability. The improvement of the workability with the containing crushed waste glass (close to lower limit of the speci-
inclusion of glass sand is one advantage of using this recycled fied fine aggregate limits according to BS 882:1992) as partially
material. It is possible to use glass sand to produce HPC in which replacement of natural sand, by weight. The reduction in the fresh
high workability is required. On the same line, it is possible to unit weight was 0.24%, 0.15%, 0.71% and 0.84% with the inclusion
use glass sand to increase the workability instead of using chemical of 5%, 10%, 15% and 20% glass sand, respectively. de Castro and
admixtures as superplasticizer or HRWR. Moreover, it is possible to de Brito [39] reported a reduction in the fresh density of concrete
A.M. Rashad / Construction and Building Materials 72 (2014) 340–357 345

Table 2
Effect of glass sand on the fresh and dry density of mortars and concretes.

Author Glass content (%) Glass size (mm) Decreased fresh density Decreased dry density
p
Ismail and Al-Hashmi [38] 15 and 20 4.75–0.15
p
Batayneh et al. [40] 5, 10, 15 and 20 BS 882:1992
p
de Castro and de Brito [39] 5, 10 and 20 <4
p
Borhan [30] 20, 40 and 60 3–0.5
p
Penacho et al. [45] 20, 50 and 100 2.38–0.149
p
Taha and Nounu [32,33] 50 and 100 <5 mm
p
Tan and Du [34] 100 ASTM C33
p
Ismail and Al-Hashmi [38] 15 and 20 4.75–0.15
p
Sharifi et al. [43] 10, 20, 30, 40 and 50 2.36–0.3
p
Penacho et al. [45] 20, 50 and 100 2.38–0.149
p
Lee et al. [9] 25, 50, 75 and 100 Un-sieved, <2.36, <1.18 and <0.6
p
Ling et al. [51] 25, 50, 75 and 100 2.36–0.15
p
Ling and Poon [49] 100 <5
p
Ling and Poon [47] 50 and 100 5–0.15

mixtures containing waste glass (size <4 mm) as natural fine particle size. The reduction in the hardened density was approxi-
aggregate (fine limestone river sand) replacement at levels of 5%, mately 1.744% and 7.28% with the inclusion of 25% and 100% glass
10% and 20%, by overall aggregate volume. The results showed that sand (size <600 lm), whilst it was approximately 0.46% and 1.97%
the reduction in the fresh density was 0.72%, 0.72% and 1.1% with with the inclusion of 25% and 100% glass sand (size <2.36 mm),
the inclusion of 5%, 10% and 20% glass sand, respectively. respectively. Ling et al. [51] replaced natural sand in mortar spec-
Borhan [30] reported a reduction in the fresh unit weight of imens with recycled glass derived from crushed beverage glass
concrete mixtures containing recycled waste mixed colour glass (size 2.36–0.15 mm) at levels of 0%, 25%, 50%, 75% and 100%, by
(size 3–0.5 mm) as partially replacement of natural sand at levels volume. The hardened density of the mortar specimens slightly
of 20%, 40% and 60%, by weight. The reduction in the fresh unit decreased with increasing glass sand content. Ling and Poon [49]
weight was 0.12%, 0.54% and 1.86% with the inclusion of 20%, reported a reduction in the hardened density of mortar by replac-
40% and 60% glass sand, respectively. Penacho et al. [45] replaced ing natural sand with 100% beverage glass (size <5 mm). This
natural sand in mortar mixtures with waste glass (size 2.38– reduction was approximately 1.71%. Ling and Poon [44] reported
0.149 mm) at levels of 20%, 50% and 100%, by volume. The results a slight reduction in the hardened density of mortar specimens
showed a reduction in the fresh bulk density of the mixtures with containing beverage glass (size 5–0.15 mm) as natural sand
the inclusion of glass sand. The fresh density decreased with replacement at levels of 50% and 100%, by volume. The hardened
increasing glass sand content. Taha and Nounu [32,33] reported a density decreased as the content of the glass sand increased.
reduction in the fresh density of concrete mixtures containing Table 2 summarizes the mentioned studies about the effect of
mixed colour waste glass (size <5 mm) as natural sand replace- waste glass sand on the fresh and dry density of mortar and con-
ment at levels of 50% and 100%. The reduction in the fresh density crete mixtures.
was 0.41% and 2.05% with the inclusion of 50% and 100% glass sand, From the above review in this section, it can be noted that the
respectively. Tan and Du [34] reported a reduction in the fresh den- inclusion of waste glass sand decreased the fresh and dry density.
sity of mortar mixtures containing higher content of different col- This reduction in the density can be attributed to the lower specific
ours waste glass as natural sand replacement. The fresh density gravity [34,38] and the lower density of waste glass sand compared
decreased as the glass sand content increased. The fresh density to natural sand [32,33]. The reduction in the concrete density with
of mortar with 100% brown, green, clear and mixed colours glass the inclusion of glass sand would lead to a reduction in the dead
sand was 97%, 96%, 95% and 97% of the normal mortar, respec- weight of the building constructed. This can be considered as one
tively. Du and Tan [50] replaced natural sand in concrete mixtures advantage of using this material. This also may a courage factor
with recycled brown-coloured soda-lime glass at levels of 0%, 25%, of the used glass sand in concrete in engineering applications.
50%, 75% and 100%, by weight. The results showed a reduction in
the fresh density of the mixtures with the inclusion of glass sand.
The fresh density decreased with increasing glass sand content. 6. Mechanical strength
Ismail and Al-Hashmi [38] reported that the dry density of
concrete specimens decreased by 0.17%, 0.58% and 0.71% with 6.1. Mortars
the inclusion of 10%, 15% and 20% crushed waste glass (size
4.75–0.15 mm) as natural sand replacement, by weight. Sharifi Shayan and Xu [52] studied the compressive strength, at age of
et al. [43] reported a reduction in the density of SCCs by partially 28 days, of mortars containing waste glass (size 4.75–0.15 mm) as
replacing natural sand with recycled glass (size 2.36–0.3) at levels natural sand replacement at levels of 10%, 20%, 30% and 40%, by
of 10%, 20%, 30%, 40% and 50%, by volume. The reduction in the weight. The results showed an increase in the compressive
density was 4.71%, 0.95%, 1.32%, 1.51% and 1.28% with the inclu- strength with increasing glass sand content. Corinaldesi et al.
sion of 10%, 20%, 30%, 40% and 50% glass sand, respectively. Pena- [53] studied the compressive strength and flexural strength, at
cho et al. [45] reported a reduction in the dry density of mortar age of 180 days, of mortars containing waste glass as fine aggre-
specimens by replacing natural sand with waste glass (size 2.38– gate. Natural sand was partially replaced with waste glass at levels
0.149 mm) at levels of 20%, 50% and 100%, by weight. This reduc- of 0%, 30% and 70%, by weight. There were three different particle
tion increased with increasing glass sand content. Lee et al. [9] sizes of waste glass: up to 36 lm, from 36 to 50 lm and from 50 to
replaced natural sand in concrete blocks with waste glass at levels 100 lm. Various w/c ratios were used. The results showed that the
of 0%, 25%, 50%, 75% and 100%. Various waste glass particle sizes of inclusion of 30% glass sand (size 36 lm) exhibited the highest flex-
un-sieved, <2.36 mm, <1.18 mm and <600 lm were used. The ural strength followed by 70% (size from 50 to 36 lm), 70% (size
results showed a reduction in the hardened density of concrete 36 lm), 30% (size from 50 to 36 lm), 30% (size 100–50 lm), 70%
blocks with increasing glass sand content and decreasing glass (size 100–50 lm), whilst the control mixture came in the last
346 A.M. Rashad / Construction and Building Materials 72 (2014) 340–357

place. The mixture of 70% glass (size 100–50 lm) showed the high- 75% and 100% glass sand, respectively. Ling et al. [51] replaced nat-
est compressive strength followed by 70% (size 50–36 lm) or 30% ural sand in mortars with conventional crushed beverage glass
(size 100–50 lm) and 70% (size 36 lm), respectively. Mixtures of (size 2.36–0.15 mm) at levels of 0%, 25%, 50%, 75% and 100%, by
30% (size 36 lm) and 30% (size 50–36 lm) showed comparable volume. The compressive strength and flexural strength at age of
compressive strength to the control. Penacho et al. [45] reported 28 days decreased with increasing glass sand content due to the
higher compressive strength at age of 90 days of mortars by replac- weaker adhesion between the smooth surface of the glass particles
ing natural sand with waste glass (size 2.38–0.149 mm) at levels of and cement. Ling and Poon [47] reported a reduction in the 90 days
20%, 50% and 100%, by volume. flexural strength of mortars containing beverage waste glass (size
Bhandari and Tajine [54] partially replaced natural sand in mor- 5–0.15 mm) as natural sand replacement at levels of 50% and
tar blocks with white and colour glass (size 4.74–1.18 mm) at lev- 100%, by volume. The reduction was 13.33% with the inclusion of
els of 0%, 10%, 20% and 30%, by weight. They reported a reduction 50% glass sand. The reduction in the flexural strength increased
in the compressive strength with the inclusion of glass sand. The as the glass sand content increased. They also studied the compres-
reduction in the white glass sand specimens was higher than that sive strength of all mixtures. Similar trend of the results was
of colour ones. Tan and Du [34] reported a reduction in the com- obtained. Ling and Poon [48] reported a reduction in the compres-
pressive strength and flexural strength of mortars containing sive strength and flexural strength at ages of 7, 28 and 90 days of
waste glass with different colours as natural sand replacement at mortars containing 100% recycled blue bottles waste glass (60%
levels of 25%, 50%, 75% and 100%, by weight. At almost cases, these <2.36 mm and 40% 5–2.36 mm) as natural sand (passing through
strengths decreased with increasing glass sand content. The reduc- 2.36 mm) replacement, by weight. The reduction in the flexural
tion in the 28 days flexural strength was smaller than 10% if the strength due to the inclusion of waste glass was 36.7% and 33.6%
content of glass sand was less than 75%. At 100% glass sand, the at ages of 28 and 90 days, respectively. Ling and Poon [49] reported
reduction in the flexural strength was dropped from 70% to 90% a reduction in the compressive strength and flexural strength of
according to glass type. The splitting tensile strength slightly mortar containing 100% beverage glass (size <5 mm) as natural
increased with the inclusion of 25% glass sand, then decreased with sand replacement compared to the control. Table 3 summarizes
increasing glass sand content. The static and dynamic modules of the mentioned studies about the effect of waste glass sand on
elasticity decreased with increasing glass sand content. This reduc- the mechanical strength of mortars.
tion was high in the case of clear glass. Park and Lee [35] partially
replaced natural sand in mortars with brown waste glass (size 6.2. Concretes
4.75–0.3 mm) at levels of 10%, 20%, 30%, 50% and 100%, by weight.
They found a reduction in the compressive strength and flexural Metwally [31] reported that the use of finely milled waste glass
strength with increasing glass sand content. The strength was in concrete mixtures improved the mechanical properties of con-
noticeably decreased when the glass sand content was more than crete at later ages. Batayneh et al. [40] reported a gradually
20%. Degirmenci et al. [55] studied strength characteristics, at ages increase in the compressive strength, splitting tensile strength
of 7, 28 and 90 days, of mortars containing waste glass (size and flexural strength of concretes containing crushed waste glass
4–0.25 mm) in term of waste glass contents and glass colours. (close to lower limit of the specified fine aggregate limits according
Natural fine aggregate (limestone) was replaced with different col- to BS 882:1992) as natural sand replacement at levels of 5%, 10%,
ours of waste glass (white, green and brown) at levels of 10%, 30% 15% and 20%, by weight. Borhan [30] reported 15% enhancement
and 100%, by weight. Fixed w/c ratio of 0.47 was used. The lime- in the 28 days splitting tensile strength of concrete containing
stone aggregate and glass aggregate had the same sieve size. They 20%, by weight, recycled waste mixed colour glass (size
reported that the compressive strength and flexural strength 3–0.5 mm) as natural sand replacement. On the other hand, the
decreased with increasing glass content. Mortars containing 30% inclusion of 60% of waste glass as natural sand replacement caused
glass sand achieved comparable compressive strength and flexural 22% reduction. The compressive strength results at age of 28 days
strength with that of limestone sand. The difference in strength showed an enhancement by 4.23% at replacement level of 20%,
due to glass colour could be ignored. whilst it showed a reduction of 6.6% with the inclusion of 60% glass
Ling et al. [46] reported a reduction in the compressive strength sand. At age of 90 days, the compressive strength decreased with
and flexural strength of mortars containing waste glass (with increasing glass sand content (Fig. 6).
approximately 23% coarser particles 10–5 mm) as natural sand Turgut and Yahlizade [56] reported an enhancement in the
replacement at levels of 25%, 50%, 75% and 100%, by weight. The mechanical strength of paving concrete blocks by partially
reduction in the 28 days compressive strength was 5.1%, 10.9%, replacement natural sand (size 4.75–0 mm) with white waste glass
13.5% and 16.7% with the inclusion of 25%, 50%, 75% and 100% glass (size 1.18–0 mm) at levels of 10%, 20% and 30%, by weight. The
sand, respectively. The reduction in the 90 days flexural strength enhancement in the compressive strength with the inclusion of
was 8.2%, 19.1%, 22.5% and 34.5% with the inclusion of 25%, 50%, 10%, 20% and 30% glass sand was 47.66%, 68.94% and 31.49%,

Table 3
Effect of glass sand on the mechanical strength of mortars.

Author Glass content (%) Glass size (mm) Positive effect


p
Shayan and Xu, [52] 10, 20, 30 and 40 4.75–0.15
p
Corinaldesi et al. [53] 30 and 70 0.1–0.036
p
Penacho et al. [45] 20, 50 and 100 2.38–0.149
Bhandari and Tajine [54] 10, 20 and 30 4.75–1.18 
Tan and Du [34] 25, 50, 75 and 100 ASTM C33 
Park and Lee [35] 10, 20, 50 and 100 4–0.3 
Degirmenci et al. [55] 10, 30 and 100 4–0.25 
Ling et al. [46] 25, 50, 75 and 100 23% 10–5 
Ling et al. [51] 25, 50, 75 and 100 2.36–0.15 
Ling and Poon [47] 50 and 100 5–0.15 
Ling and Poon [48] 100 60% <2.36 and 40% 5–2.36 
Ling and Poon [49] 100 <5 
A.M. Rashad / Construction and Building Materials 72 (2014) 340–357 347

strength requirement of pozzolanic materials as proposed by Shao


et al. [21] and E-glass had higher aluminosilicate content, which
behaved very beneficial performance in concrete mixtures. Oliveira
et al. [58] replaced natural sand in concretes containing 101.5 kg/
m3 fly ash (FA) with amber waste glass (size 10–0.07 mm) at levels
of 0%, 25%, 50% and 100%, by weight. The maximum particle size of
glass sand was 4.76 mm. Fixed w/b ratio and 0.2% of HRWR, by
cement weight, for 25% glass sand and 0.3% for 50% and 100% glass
sand were used. The results showed an increase in the compressive
strength at ages of 7 and 28 days with increasing glass sand con-
tent. The enhancement in the compressive strength was 24%, 25%
and 29% with the inclusion of 25%, 50% and 100% glass sand,
respectively.
Du and Tan [50] reported that no effect of glass sand, up to
100%, on concrete compressive strength before 28 days. At age of
90 days, the compressive strength increased with the inclusion of
Fig. 6. Effect of glass sand content on concrete compressive strength [30]. 25%, 50%, 75% and 100% glass sand as natural sand replacement,
by weight. The compressive strength increased with increasing
glass sand content. Lee et al. [9] reported a reduction in the com-
pressive strength at ages of 7 and 28 days by replacing natural sand
in concrete blocks with waste glass (particle sizes of un-sieved,
<2.36 mm and < 1.18 mm) at levels of 25%, 50%, 75% and 100%.
On the contrary, glass sand with particle size <600 lm increased
the compressive strength. The reduction in the 28 days compres-
sive strength was 10.55% and 16.75% with the inclusion of 25%
and 100% glass sand (size <2.36 mm), whilst the enhancement in
the 28 days compressive strength was 5.1% and 34.31% with the
inclusion of 25% and 100% glass sand (size <600 lm). Ismail and
Al-Hashmi [38] studied the compressive strength and flexural
strength of concretes containing crushed waste glass (size 4.75–
0.15 mm) as natural sand replacement at levels of 10%, 15% and
20%, by weight. The compressive strength at age of 3 and 7 days
increased with the inclusion of glass sand, whilst it decreased at
age of 14 days. At age of 28 days, 20% glass sand showed the high-
est compressive strength. The enhancement in the compressive
strength with the inclusion of 20% glass sand was 4.32%, whilst
the reduction in the compressive strength with the inclusion of
10% and 15% glass sand was 8.41% and 4.54%, respectively. The
flexural strength increased with the inclusion of glass sand, at all
ages. The enhancement in the 28 days flexural strength was
Fig. 7. Effect of glass sand content on concrete compressive strength [37]. 3.56%, 6.96% and 11.2% with the inclusion of 10%, 15% and 20%
glass sand, respectively.de Castro and de Brito [39] reported a
respectively. The enhancement in the flexural strength was 22.29%, reduction in the compressive strength of concretes containing
90% and 49.27% with the inclusion of 10%, 20% and 30% glass sand, waste glass (size <4 mm) as natural fine aggregate replacement
respectively, whilst the enhancement in the splitting tensile at levels of 5%, 10% and 20%, by overall aggregate volume. The
strength was 27.86%, 46.56% and 3.82%, respectively. The enhance- reduction in the compressive strength was approximately 10.94%,
ment in the ultrasonic pulse velocity was 27.86%, 46.56% and 3.82% 17.19% and 14.06% with the inclusion of 5%, 10% and 20% glass
with the inclusion of 10%, 20% and 30% glass sand, respectively. sand, respectively. Ali and Al-Tersawy [42] reported a reduction
Gautam et al. [57] reported that partially replacement natural sand in the compressive strength, splitting strength, flexural strength
in concretes with waste glass (size 4.75–0.15 mm) at levels of 10% and Young’s modulus of SCCs containing waste glass (size 5–
and 20% increased the compressive strength, whilst replacement 0.075 mm) as natural sand replacement at levels of 10%, 20%,
levels of 30% and 40% decreased it. Malik et al. [41] partially 30%, 40% and 50%, by weight. When cement content was 400 kg/
replaced natural sand with recycled waste glass (size 1.18– m3, the reduction in the 28 days compressive strength was 4.5%,
0 mm) at levels of 0%, 10%, 20%, 30% and 40%, by weight. The 14.47%, 17.04%, 22.19% and 23.63% with the inclusion of 10%,
results showed an increase in the compressive strength with the 20%, 30%, 40% and 50% glass sand, respectively, whilst the reduc-
inclusion of 10%, 20% and 30% glass sand, whilst the inclusion of tion in the Young’s modulus was 2.28%, 7.52%, 8.92%, 11.79% and
40% glass sand reduced it. The enhancement in the 28 days com- 12.61%, respectively. Sharifi et al. [43] reported a reduction in the
pressive strength was 20%, 25% and 9.8% with the inclusion of SCCs compressive strength at ages of 3, 7, 14 and 28 days by par-
10%, 20% and 30% glass sand, respectively, whilst the reduction in tially replacing natural sand with recycled glass (size 3.36–0.3)
the 28 days compressive strength was 8.5% with the inclusion of up to 50%, by volume. The reduction in the 28 days compressive
40% glass sand. Chen et al. [37] observed a significant improvement strength was 2.93%, 3.28%, 5.92%, 7.15% and 8.22% with the inclu-
in the compressive strength of waste E-glass (size <75 lm) con- sion of 10%, 20%, 30%, 40% and 50% glass sand, respectively. Lim-
crete mixtures at late ages (Fig. 7). The compressive strength of bachiya [36] studied the compressive strength, flexural strength
specimens with 40 wt.% E-glass content was 17%, 27% and 43% and elastic modulus of concretes containing mixed colour beverage
higher than that of control specimen at ages of 28, 91 and 365 days, waste glass (size <5 mm) as natural sand replacement. Natural
respectively. The particle size of 75 lm approximately passed the sand was partially replaced with waste glass at levels of 0%, 5%,
348 A.M. Rashad / Construction and Building Materials 72 (2014) 340–357

Table 4
Effect of glass sand on the mechanical strength of concretes.

Author Glass content (%) Glass size (mm) Positive effect


p
Batayneh et al. [40] 5, 10, 15 and 20 BS 882:1992
p
Borhan [30] 20 3–0.5 (age 28-d)
60 3–0.5  (age 28-d)
20, 40 and 60 3–0.5  (age 90-d)
p
Turgut and Yahlizade [56] 10, 20 and 30 1.18–0
p
Gautam et al. [57] 10 and 20 4.75–0.15
Gautam et al. [57] 30 and 40 4.75–0.15 
p
Malik et al. [41] 10, 20 and 30 1.18–0
Malik et al. [41] 40 1.18–0 
p
Chen et al. [37] 40 <0.75
p
Oliveira et al. [58] 25, 50 and 100 10–0.07
p
Du and Tan [50] 25, 50, 75 and 100 – (age 90-d)
p
Lee et al. [9] 25, 50, 75 and 100 <0.6
Lee et al. [9] 25, 50, 75 and 100 Un-sieved, <2.36, <1.18 
p
Ismail and Al-Hashmi [38] 10, 15 and 20 4.75–0.15 (Flexural)
p
10, 15 and 20 4.75–0.15 (Compressive at ages of 3 and 7 days)
10, 15 and 20 4.75–0.15  (Compressive at age of 14 days)
de Castro and de Brito [39] 5, 10 and 20 <4 
Ali and Al-Tersawy [42] 10, 20, 30 40 and 50 5–0.075 
Sharifi et al. [43] 10, 20, 30, 40 and 50 2.36–0.3 
Limbachiya [36] 5, 10, 15, 20, 30 and 50 <5  (For 30% and 50%)
Park et al. [35] 30, 50 and 70 <5 
Taha and Nounu [32] 50 and 100 <5 
Terro [44] 25, 50 and 100 4.75–0.075 
Taha and Nounu [33] 50 and 100 <5 

after there was gradual reduction in these values with increasing


glass sand content. Park et al. [35] partially replaced fine aggregate
with recycled glass (size <5 mm) at replacement levels of 0%, 30%,
50% and 70%, by weight, in concretes. They used three different col-
ours named amber, emerald green and flint. The compressive
strength, tensile strength and flexural strength of concretes demon-
strated a decreasing tendency with increasing glass sand content.
The mechanical properties of concretes did not display any notable
difference depending on the colour of glass sand.
Taha and Nounu [32] reported that no major difference was
found in compressive strength of concretes with the presence of
recycled glass (size <5 mm) as natural sand replacement at levels
of 50% and 100%, by volume. The reduction in the 28 days compres-
sive strength was approximately 5% and 3.33% with the inclusion of
50% and 100% glass sand, respectively. At age of 364 days, the inclu-
Fig. 8. Research numbers versus the effect of glass sand on the mechanical strength sion of 50% glass sand reduced the compressive strength by approx-
of mortars. imately 3.7%, whilst the inclusion of 100% glass sand increased it by
7.4%. Terro [44] reported that 10% waste glass (size 4.75–0.075 mm)
as natural sand replacement showed comparable compressive
strength to the control concrete. On the other hand, the replace-
ment levels of 25%, 50% and 100%, by weight, decreased it. The
reduction in the compressive strength was 6.33%, 8.86% and
40.51% with the inclusion of 25%, 50% and 100% glass sand, respec-
tively. Taha and Nounu [33] reported a reduction in the splitting
tensile strength and flexural strength of concretes containing mixed
colour waste glass (size <5 mm) as natural sand replacement at lev-
els of 50% and 100%. On the other hand, no significant differences in
the compressive strength were obtained with the inclusion of glass
sand. Table 4 summarizes the mentioned studies about the effect of
waste glass sand on the mechanical strength of concretes.
From the above review in Sections 6.1 and 6.2, it can be noted
that the inclusion of waste glass sand in mortars/concretes
decreased the strength as reported by several studies (Figs. 8 and
9). The reduction in the strength was mainly due to the smooth
Fig. 9. Research numbers versus the effect of glass sand on the mechanical strength surface and sharper edges of glass particles, resulted in weaker
of concretes. bond strength at the interfacial transition zone (ITZ) between glass
particles and cement paste matrix [34]. Ling and Poon [48] related
10%, 15%, 20%, 30% and 50%, by weight. The results showed that up the reduction in the strength due to the weaker bonding strength
to 20% glass sand, no influence on the compressive strength, flex- of cement paste with smooth surface glass aggregate compared
ural strength and elastic modulus values of the concretes, but there- to that of rough natural sand aggregate. Park and Lee [35] related
A.M. Rashad / Construction and Building Materials 72 (2014) 340–357 349

the reduction in the strength to the cracks created by expansion 9. Water absorption
pressure caused by the ASR generated from the silica in waste
glass, and the reduction in adhesive strength between the surface Taha and Nounu [32] reported a reduction in the percentage of
of the waste glass and the cement paste. The reduction in the water absorption with the inclusion of recycled glass (size <5 mm)
strength by using glass sand is the one of the shortcoming of using as natural sand replacement at levels of 50% and 100%, by volume.
this material which limits its wide use by engineers However, on Taha and Nounu [33] reported a reduction in the water absorption
the contrary, few number of studies reported higher mechanical of concretes containing mixed colour recycled waste glass (size
strength with the inclusion of waste glass sand. The increase in <5 mm) as natural sand replacement at levels of 50% and 100%.
the strength mainly was due to the surface texture and strength The water absorption reduced with increasing glass sand content.
of the glass particles compared to natural sand [40]. Another study Ling and Poon [49] reported a reduction in the percentage of water
[21] related this enhancement in strength to the pozzolanic absorption of mortar containing 100% beverage glass (size <5 mm)
reaction of fine glass particles (particle size of 75 lm). instead of natural sand. The reduction was approximately 14.49%.
According to the colour of glass sand, some studies [55,59] Malik et al. [41] reported a reduction in the percentage of water
reported that the colour of the glass did not display any notable absorption of concretes by replacing natural sand with waste glass
difference on the strength. On the other hand, Tan and Du [34] (size 1.18–0 mm) at levels of 10%, 20%, 30% and 40%, by weight. The
reported that clear glass exhibited lower strength. reduction in the percentage of water absorption was 26.2%, 37.64%,
46.36% and 55.86% with the inclusion of 10%, 20%, 30% and 40%
glass sand, respectively. Bhandari and Tajine [54] reported a reduc-
7. Fire resistance tion in the water absorption of mortar blocks by replacing natural
sand with waste glass (size 4.75–1.18 mm) at levels of 10%, 20%
Terro [44] replaced natural sand in concretes with crushed bot- and 30%, by weight. de Castro and de Brito [39] partially replaced
tle glass (size 4.75–0.075 mm) at levels of 0%, 10%, 25%, 50% and natural fine aggregate in concretes with waste glass (size <4 mm)
100%, by weight. The residual compressive strength after exposure at levels of 0%, 5%, 10% and 20%, by volume. The water absorption
to 60, 150, 300, 500 and 700 °C were studied. The mixture contain- by capillary results showed a reduction in the 5% and 10% glass
ing 10% glass sand showed higher residual compressive strength concretes compared to the control. On the contrary, 20% glass con-
above 150 °C. crete showed higher water absorption (by capillary) than the con-
It can be clearly noted that there is a distinct lack in the study trol. The results of water absorption by immersion showed an
the effect of waste glass sand on the fire resistance of mortar/con- increase with the inclusion of glass sand. Ling and Poon [48]
crete. Indeed the fire resistance of mortar/concrete containing replaced natural sand (passing through 2.36 mm) in mortars with
waste glass sand is still needs more investigations. This can be a recycled blue bottles waste glass (60% <2.36 mm and 40% 5–
major topic for future investigations. 2.36 mm) at levels of 0% and 100%, by weight. The results showed
a slight increase in the initial surface absorption and a slight reduc-
tion in the final water absorption of mortar specimens with the
8. Abrasion and skid resistance inclusion of glass sand.
Turgut and Yahlizade [56] reported an increase in the percent-
Turgut and Yahlizade [56] partially replaced natural sand in age of water absorption of paving concrete blocks at age of 28 days
concrete paving blocks with white waste glass at levels of 0%, by replacing natural sand (size 4.75–0 mm) with white waste glass
10%, 20% and 30%, by weight. The particle sizes of natural sand (size 1.18–0 mm) at levels of 10%, 20% and 30%, by weight. The per-
ranging from 4.75 to 0 mm, whilst they ranging from 1.18 to centage of water absorption for all glass sand specimens was
0 mm for glass sand. Fixed w/c ratio was used. They studied the approximately similar, which exhibited 16.67% higher water
abrasion resistance at age of 28 days according to TS 2824 EN absorption in comparison with the control. Limbachiya [36]
1338 [60]. They reported that the enhancement in the abrasion reported an increase in the initial surface absorption of concretes
resistance was 9.45%, 14.81% and 8.53% with the inclusion of containing mixed colour beverage glass (size <5 mm) as natural
10%, 20% and 30% glass sand, respectively. Su and Chen [61] par- sand replacement at levels of 5%, 10%, 15%, 20%, 30% and 50%, by
tially replaced sand in asphalt concretes with waste glass (size weight. The results showed an increase in the initial surface
64.75 mm) at levels of 0%, 5%, 10% and 15%, by total aggregate absorption with increasing glass sand content beyond 15%. Ling
weight. They reported that the skid resistance in both longitudinal et al. [46] replaced natural sand in mortars with waste glass (con-
and transverse directions increased as the glass sand content taining approximately 23% coarser particles 10–5 mm) at levels of
increased. 25%, 50%, 75% and 100%, by weight. The results showed a slight
On the contrary, Ling et al. [46] reported a reduction in the abra- increase in the initial surface absorption and final water absorption
sion resistance, at age of 28 days, of mortars containing waste glass with the inclusion of glass sand. The increase in the initial surface
(with approximately 23% coarser particles 5–10 mm) as natural absorption was 43.68% with the inclusion of 100% waste glass. This
sand replacement at levels of 25%, 50%, 75% and 100%, by weight. could be attributed to the larger particle size and angular shape of
The reduction in the abrasion resistance increased with increasing glass, resulted in larger pore volumes in mortars. Lee et al. [9]
glass sand content. On the same line, Ling and Poon [48] reported a replaced natural sand in concrete blocks with waste glass at levels
reduction in the abrasion resistance, at age of 28 days, of mortar of 0%, 25%, 50%, 75% and 100%. Various w/c ratios and various
containing 100% recycled blue bottles waste glass (60% <2.36 mm waste glass particle sizes of un-sieved, <2.36 mm, <1.18 mm and
and 40% 2.36–5 mm) as natural sand (passing through 2.36 mm) <600 lm were used. The results showed an increase in the percent-
replacement, by weight. age of water absorption with increasing glass sand content. Speci-
It is safe to conclude that the abrasion resistance of mortar/con- mens containing glass sand with particle size <600 lm showed the
crete with the inclusion of waste glass sand is still needs more highest percentage of water absorption. Penacho et al. [45]
investigations. It is clearly noted that there are contradictory reported an increase in the water absorption of mortars by replac-
reports about the effect of glass sand on abrasion resistance. Some ing natural sand with waste glass (size 2.38–0.149 mm) at levels of
studies reported positive effect, whilst the others reported negative 20%, 50% and 100%, by volume. The water absorption increased
effect. with increasing glass sand content. Table 5 summarizes the
350 A.M. Rashad / Construction and Building Materials 72 (2014) 340–357

Table 5
Effect of glass sand on the water absorption/ of mortars and concretes.

Author Glass content (%) Glass size (mm) Positive effect


p
Taha and Nounu [32] 50 and 100 <5
p
Taha and Nounu [33] 50 and 100 <5
p
Ling and Poon [49] 100 <5
p
Malik et al. [41] 10–40 1.18–0
p
Bhandari and Tajine [54] 10, 20 and 30 4.75–1.18
p
de Castro and de Brito [39] 5, 10 and 20 <4 (For 5% and 10% (by capillary)
5, 10 and 20 <4  (By immersion)
Ling and Poon [48] 100 60% <2.36 and 40% 5–2.36  (Initial)
p
Ling and Poon [48] 100 60% <2.36 and 40% 5–2.36 (Final)
Turgut and Yahlizade, [56] 10, 20 and 30 4.75–0 
Limbachiya [36] 5, 10, 15, 20, 30 and 50 <5 
Ling et al. [46] 25, 50, 75 and 100 23% 10–5 
Lee et al. [9] 25, 50, 75 and 100 Un-sieved, <2.36, <1.18 and <0.6 
Penacho et al. [45] 20, 50 and 100 2.38–0.149 

increased proportion of porous matrix, with inherent segregation/


bleeding characteristics of glass sand mixtures.

10. Chloride ion penetration and permeability

Chen et al. [37] exposed concretes containing waste E-glass


(size <75 lm) as natural sand replacement at levels of 10%, 20%,
30% and 40%, by weight, to rapid chloride penetration depth (RCPT)
according to ASTM C1202-97. They reported that by incorporation
of E-glass in the mixtures, the total charge passed was less than
2000 Coulimbs which indicated very low chloride ion penetration.
Concretes with E-glass particles have a denser internal structure
providing the specimens with effective barrier against chloride-
Fig. 10. Research numbers versus the effect of glass sand on the water absorption of ion penetration. Chen et al. [37] reported that the inclusion of
mortars and concretes. waste glass in mortars as natural sand replacement at levels of
25%, 50%, 75% and 100%, by weight, led to higher resistance to chlo-
ride ion penetration (Fig. 11). Du and Tan [50] reported that the
inclusion of glass sand in concretes as natural sand replacement
at levels of 25%, 50%, 75% and 100%, by weight, led to higher resis-
tance to chloride ion penetration. This resistance increased with
increasing glass sand content.
On the contrary, de Castro and de Brito [39] studied the chloride
penetration depth of concretes containing waste glass (size
<4 mm) as natural fine aggregate replacement at levels of 5%,
10% and 20%, by overall aggregate volume. The results showed
an increase in the chloride penetration depth by approximately
28.88%, 34.4% and 7.77% with the inclusion of 5%, 10% and 20%
glass sand, respectively. Su and Chen [61] reported an increase in
the asphalt concretes permeability by replacing part of natural
sand with waste glass (size 64.75 mm) at levels of 5%, 10% and
15%, by total aggregate weight. The increase in the permeability
increased as the glass sand content increased. Oliveira et al. [58]
Fig. 11. Total charge passed versus E-glass sand content [37].
replaced natural sand in concretes with amber waste glass (maxi-
mum particle size 4.76 mm) at levels of 0%, 25%, 50% and 100%, by
weight. They reported that concretes containing 25% and 50% glass
mentioned studies about the effect of waste glass sand on the sand showed higher water and oxygen permeability at ages of 28
water absorption of mortars and concretes. and 63 days, whilst concrete containing 100% glass sand showed
From the above review in this section, it can be noted that there lower water and oxygen permeability at age of 28 days compared
are contradictory conclusions about the effect of glass sand on the to the control. At age of 63 days, 100% glass sand showed compa-
water absorption (Fig. 10). Some researchers believed that the rable water and oxygen permeability to the control. Penacho
inclusion of glass sand in the matrix reduced the water absorption et al. [45] studied water permeability of different types of mortars
value. This reduction may be related to the nature of glass which under pressure based on EN 1015-21. Natural sand was replaced
impermeable material [32] and its negligible water absorption with waste glass (size 2.38–0.149 mm) at levels of 0%, 20%, 50%
value [33,49]. On the contrary, others believed that the inclusion and 100%, by volume. The results showed an increase in the perme-
of glass sand in the matrix increased the water absorption value. ability with the inclusion of glass sand.
Limbachiya [36] reported that the increase in the water absorption From the above review of the literature in this section, it can be
value due to the inclusion of glass sand is thought to be due to the noted that there are contradictory results about the effect of waste
A.M. Rashad / Construction and Building Materials 72 (2014) 340–357 351

glass sand on the chloride penetration depth and permeability.


However, most of studies reported that the inclusion of glass sand
in the matrix increased the chloride penetration depth and perme-
ability of matrix.

11. Chemical resistance

Chen et al. [37] exposed concretes containing waste E-glass (size


<75 lm) as natural sand replacement at levels of 10%, 20%, 30%, 40%
and 50%, by weight, to sulphate attack according to ASTM C267-01.
They concluded that the addition of E-glass significantly improved
sulphate resistance of concrete according to the results of weight
loss and strength reduction. Ling et al. [48] studied the chemical
resistance of mortars containing waste glass (with approximately
23% coarser particles 10–5 mm) as natural sand replacement at lev-
els of 25%, 50%, 75% and 100%, by weight, by immersing the speci-
mens in 3% sulphuric acid solution (H2SO4), up to 12 weeks, in
accordance to ASTM C267. The results showed better resistance to
acid attack with the inclusion of 75% and 100% glass sand. This is Fig. 12. Drying shrinkage of mixed colour glass sand mortars [34].
because the glass had higher resistance to acid attack than natural
sand [62]. Ling and Poon [48] exposed mortars containing recycled
glass (size 5–0.15 mm) as natural sand replacement at levels of
blue bottles waste glass (60% <2.36 mm and 40% 5–2.36 mm) as
50% and 100%, by volume. The reduction in the drying shrinkage
natural sand (passing through 2.36 mm) replacement at levels of
increased as the glass sand content increased. Limbachiya [36]
0% and 100%, by weight, to 3% H2SO4 up to 12 weeks. The results
studied the drying shrinkage of concretes containing mixed colour
showed that the control specimen exhibited the most significant
beverage glass (size <5 mm) as natural sand replacement at levels
deterioration with respect to the loss of mass. The inclusion of glass
of 5%, 10%, 15%, 20%, 30% and 50%, by weight. The results showed
sand in mortar significantly reduced the mass loss. The increase in
that up to 20% glass sand there was no influence on the drying
the sulphate resistance with the inclusion of glass sand is one
shrinkage, but thereafter there was a gradual reduction in the
advantage of using this recycled material. Thus, glass concrete
shrinkage with increasing glass sand content. Ling and Poon [49]
may be suitable for applications in the cases of aggressive sulphate
reported a reduction in the drying shrinkage of mortar containing
soil, groundwater, industrial effluents, and wastes from chemical
100% beverage waste glass (size <5 mm) as natural fine aggregate
and mining industries, as well as in seawater.
replacement compared to the control. Tan and Du [34] studied
From the above review of the literature in this section, it can be
the drying shrinkage of mortar specimens containing mixed colour
noted that the effect of waste glass sand on the chemical resistance
waste glass (size between the upper and lower limits of ASTM C33)
of the matrix is still needs more investigations. However, the inclu-
as natural sand replacement at levels of 25%, 50%, 75% and 100%, by
sion of glass sand in the matrix increased its sulphate and its sul-
weight. They reported that the drying shrinkage values were less
phuric acid resistance.
than 750  106 mm/mm at 56 days, specified as acceptable for
concrete by Australian Standard AS3600. The natural sand mortar
12. Carbonation resistance and capillary sorptivity had the highest drying shrinkage. The drying shrinkage reduced
with the inclusion of glass sand. The reduction in the drying
de Castro and de Brito [39] reported a general improvement in shrinkage increased with increasing glass sand content up to 45%
terms of carbonation resistance of concretes containing waste glass (Fig. 12). Du and Tan [50] reported that the inclusion of glass sand
(size <4 mm) as natural fine aggregate replacement at levels of 5%, in concrete specimens, as natural sand replacement at levels of
10% and 20%, by overall aggregate volume, at long terms (56 and 25%, 50%, 75% and 100%, by weight, showed innocuous drying
91 days). On the other hand, at ages of 7 and 28 days the carbon- shrinkage. Ling et al. [46] reported a reduction in the drying shrink-
ation depths were greater in glass concretes and grew with the age, up to 112 days, of mortars containing waste glass (with
replacement level. Oliveira et al. [58] reported that concrete sorp- approximately 23% coarser particles 10–5 mm) as natural sand
tivity coefficient at ages of 28 and 63 days reduced with the inclu- replacement at levels of 25%, 50%, 75% and 100%, by weight. This
sion of amber waste glass sand (size 4.75 mm). The sorptivity reduction increased as the glass sand content increased. Mortar
coefficient, at ages of 28 and 63 days, decreased as the content of containing 100% waste glass showed 17% reduction in the drying
glass sand increased. The reduction attained its maximum value shrinkage.
of 39%, at age of 28 days, with the inclusion of 100% glass sand, de Castro and de Brito [39] studied the shrinkage of concrete
whilst it attained 29% at age of 63 days. specimens containing waste glass (size <4 mm) as natural sand
From the above review of the literature in this section, it can be replacement at levels of 5%, 10% and 20%, by overall aggregate vol-
noted that there is a distinct lack in the study the effect of waste ume. The results showed approximately 12.77% and 18% increase
glass sand on the carbonation resistance of mortar/concrete. in the shrinkage with the inclusion of 5% and 20% glass sand,
However, according to the available literature, it can be concluded respectively. On the other hand, the inclusion of 10% glass sand
that the inclusion of glass sand (5–20%) improved carbonation reduced the shrinkage by approximately 7.28%. Ling and Poon
resistance at long terms (56 and 91 days), whilst it decreased [48] reported a reduction in the drying shrinkage of mortar con-
carbonation resistance at ages of 7 and 28 days. taining 100% recycled blue bottles waste glass (60% <2.36 mm
and 40% 5–2.36 mm) as natural sand replacement, by weight. This
13. Drying shrinkage reduction was valid from 1 day up to approximately 85 days.
Beyond 85 days up to 112 days, the control mortar showed lower
Ling and Poon [47] reported a reduction in the drying shrinkage, drying shrinkage. Penacho et al. [45] reported that mortars con-
up to 90 days, of mortar specimens containing crushed beverage taining 20% and 50% waste glass (size 2.38–0.149 mm) as partially
352 A.M. Rashad / Construction and Building Materials 72 (2014) 340–357

Table 6
Effect of glass sand on the drying shrinkage of mortar and concrete specimens.

Author Glass content (%) Glass size (mm) Positive effect


p
Ling and Poon [47] 50 and 100 5–0.15
p
Limbachiya [36] 5, 10, 15, 20, 30 and 50 <5
p
Ling and Poon [49] 100 <5
p
Tan and Du [34] 25, 50, 75 and 100 ASTM C33
p
Ling et al. [46] 25, 50, 75 and 100 23% 10–5
p
de Castro and de Brito [39] 10 <4
5 and 20 <4 
p
Ling and Poon [48] 100 60% <2.36 and 40% 2.36–5 1 day to 85 days
Ling and Poon [48] 100 60% < 2.36 and 40% 2.36–5  Beyond 85 days up to 112 days
Penacho et al. [45] 20 and 50 2.38–0.149 No effect
Penacho et al. [45] 100 2.38–0.149 

replacement of natural sand, by volume, exhibited similar shrink- glass (30% colourless, 40% green and 30% brown). They used the
age to the control, whilst 100% glass sand increased it by approxi- accelerated test accordance with ASTM C1260 (80 °C, 1 N NaOH
mately 19%. Table 6 summarizes the mentioned studies about the solution). The expansion of mortar bars were measured up to
effect of waste glass sand on the drying shrinkage of mortar and 28 days. The results showed an increase in the ASR expansion with
concrete specimens. increasing glass sand content. Yuksel et al. [65] partially replaced
From the above review in this section, it can be noted that the natural sand in mortars with waste glass at levels of 0%, 10%,
inclusion of waste glass sand in mortar and concrete specimens 20%, 40% and 50%, by weight. The results showed an increase in
reduced the drying shrinkage as reported by several studies. The the ASR expansion with increasing glass sand content. On the other
reduction in the drying shrinkage with the inclusion of waste glass hand, the inclusion of 30% glass sand may not cause deleterious
sand may be related to the low water absorption capacity of the effect.
glass cullet [46–48,62] and impermeable properties of the glass Ling and Poon [47] reported an increase in the ASR expansion of
[49]. The reduction in the drying shrinkage with the inclusion of mortars containing crushed beverage glass (size 5–0.15 mm) as
glass sand is one advantage of using this recycled material. As natural sand replacement at levels of 50% and 100%, by volume.
known, drying shrinkage is one of the main causes of cracks in The ASR expansion increased with increasing glass sand content.
large concrete structures. So that using glass sand in large concrete Oliveira et al. [58] reported that ASR expansion of concretes con-
structures, such as floors and dams, can alleviate this problem. taining amber glass (maximum particle size 4.76 mm) as natural
sand replacement increased with increasing glass sand content.
14. ASR expansion Ling and Poon [49] reported an increase in the ASR expansion of
mortar containing 100% beverage waste glass (size <5 mm) as fine
14.1. Effect of glass content aggregate. Park et al. [59] reported that the expansion rate by ASR
expansion in accordance with ASTM C 1260 showed an increase
Serpa et al. [10] partially replaced natural fine aggregate in mor- tendency with increasing emerald green waste glass (size
tars with Portuguese recycled glass at levels of 0%, 5% and 20%, by <5 mm). The increase in the expansion in mortar specimens by
weight. The results showed that replacing natural fine aggregate ASR was approximately 85.7%%, 116.67%, 159.76%, 228.5% and
with waste glass did not lead to increase in the ASR expansion at 285.71% with the inclusion of 10%, 20%, 30%, 50% and 100% glass
age of 14 days, but led to a slight increase in the ASR expansion sand, respectively, as shown in Fig. 14. Ling et al. [46] reported
at age of 28 days. The expansion increased with increasing glass an increase in the ASR expansion of mortars containing waste glass
content. Limbachiya [36] studied the ASR expansion at ages of 3, (with approximately 23% coarser particles 10–5 mm) as natural
7 and 14 days of concretes containing mixed colour beverage glass sand replacement at levels of 25%, 50%, 75% and 100%, by weight.
(size <5 mm) as natural sand replacement at levels of 0%, 5%, 10%, The ASR expansion increased with increasing glass sand content.
15% and 20%, by weight. The results showed an increase in the ASR Shayan and Xu [52] replaced natural fine aggregate in mortars
expansion with increasing glass sand content (Fig. 13). Idir et al. with recycled waste glass (size 4.75–0.15 mm) at levels ranging
[63] studied the ASR expansion of mortars containing waste glass from 0% to 100% with an increment of 10%, by weight. The ASR
as natural fine aggregate replacement at levels of 20% and 40%, expansion results showed the larger the content of glass in mortar
by weight. The results showed an increase in the ASR expansion bars, the higher the expansion. Jin et al. [66] studied the ASR
with increasing glass sand content. Kou and Poon [64] partially
replaced natural sand in mortars with cullet waste beverage glass
bottles (size <5 mm) at levels of 0%, 15%, 30% and 45%, by weight.
The waste glass was a blend of three different colours of bottles

Fig. 13. Effect of glass sand on expansion of mortar bars [36]. Fig. 14. Relative expansion for mortar bars containing glass sand [59].
A.M. Rashad / Construction and Building Materials 72 (2014) 340–357 353

results showed that clear glass exhibited the highest expansion fol-
lowed by amber glass, whilst green glass showed the lowest
expansion.
Topçu et al. [67] studied the ASR expansion of mortars contain-
ing waste glass with different colours (green, brawn and white) as
natural fine aggregate replacement. The results showed that mor-
tars containing white glass sand showed the highest expansion fol-
lowed by mortars containing brawn glass sand, whilst mortars
containing green glass sand showed the lowest expansion. Degirm-
enci et al. [55] studied the ASR expansion, at ages of 14 and
21 days, of mortars containing waste glass in term of glass colours.
Natural fine aggregate (limestone) was replaced with different col-
ours of waste glass (white, green and brown) at levels of 10%, 30%
and 100%. Fixed w/c ratio of 0.47 was used. The natural limestone
aggregate and glass aggregate had the same sieve size. They
reported that the specimens containing white glass sand exhibited
Fig. 15. SEM image of a glass particle showing an ASR formation in the particle the highest expansion followed by brown glass sand and green
boundary [10]. glass sand, respectively. The different mortar bars did not show
considerable ASR expansion after 14 days in which all bars were
able to mitigate ASR expansion below 0.1%.
expansion, up to 14 days, of mortars containing clear soda-lime Saccani and Bignozzi [70] partially replaced natural sand in
glass as natural sand replacement at levels ranging from 0% to mortars with different types of crushed waste glass derived from
100% with an increment of 10%, by weight. The results showed cullet at levels of 10%, 25% and 35%, by weight. The glass types
an increase in the ASR expansion with increasing glass sand were soda-lime glass, uncoloured boro-silicate glass, amber boro-
content. Topçu et al. [67] studied the ASR expansion of mortars silicate glass and lead-silicate glass. The expansion results showed
containing waste glass as natural fine aggregate replacement. that specimens containing lead-silicate glass exhibited the highest
Natural sand was replaced with waste glass (size 4.75–0.3 mm) expansion followed by boro-silicate glass, amber boro-silicate glass
at levels of 25%, 50%, 75% and 100%, by weight. The results showed and lime glass, respectively. Yuksel et al. [65] partially replaced
an increase in the ASR expansion with increasing glass sand con- natural sand in mortars with flint glass (from post-consumer win-
tent. Degirmenci et al. [55] studied the ASR expansion, at ages of dows glass) and green glass (from soda bottles waste) at levels of
14 and 21 days, of mortars containing 10%, 30% and 100% glass 0%, 10%, 20%, 40% and 50%, by weight. The specimens containing
sand. They reported that the expansion of ASR increased with flint glass showed higher ASR expansion than that containing green
increasing glass sand content. On the contrary, Ismail and Al-Hash- glass. Zhu et al. [71] reported that mortars containing waste glass
mi [38] partially replaced natural sand in concretes with crushed sand (size 4.75–0.3 mm) exhibited higher ASR compared to the
waste glass (size 4.75–0.15 mm) at levels of 0%, 10%, 15% and control. They also reported that the ASR expansion of mortars con-
20%, by weight. They reported that the inclusion of waste glass taining blue glass sand > flint > amber > green. On the other hand,
reduced the ASR expansion. This reduction increased as the con- Dhir et al. [68] replaced natural sand in concretes with different
tent of waste glass increased. Du and Tan [50] replaced natural colours waste glass (green, flint and amber) (size 2–0.063 mm) at
sand in concretes with waste glass at levels of 0%, 25%, 50%, 75% levels of 50% and 100%, by weight. They reported that the use of
and 100%, by weight. They reported that the inclusion of glass sand glass as fine aggregate could produce significant expansion due
reduced the ASR expansion. This reduction increased with increas- to the harmful ASR. The colour of glass played a major role in defin-
ing glass sand content. ing the amount of expansion. Green glass produced the largest
From the above review in this part, it can be noted that glass quantity of expansion, whilst flint glass produced the least. Du
sand content showed a significant impact on ASR expansion. The and Tan [72] reported that brown glass sand showed better ASR
ASR expansion increased with increasing glass sand content. This resistance than green glass sand in the long term.
is because the 100% glass sand had a high quantity of amorphous From the above review in this part, it can be noted that glass
ASR products but the gels were essentially located in the glass par- colour showed a significant impact on ASR expansion. The ASR
ticles interfaces [10]. This indicated, as pointed out by Dhir et al. expansion may be followed the order of blue glass sand > flin-
[68], that the dissolution and superficial leaching of the glass silica t > amber > brawn > green glass. Some studies [35,66] pointed out
and formation of a silica gel surface surrounding the aggregate that green colour glass would be the least reactive in the ASR
(Fig. 15) and explained the expansion evolution over time. expansion due to its high content of Cr2O3, which is added for
greenish colour. Brown glass sand mortar also exhibited similarly
14.2. Effect of glass colour small ASR expansion as mortar containing green glass sand.

Tan and Du [34] studied the ASR expansion of mortar specimens 14.3. Effect of glass particle size
containing waste glass with different colours as natural sand
replacement at levels of 25%, 50%, 75% and 100%, by weight. They Jin et al. [66] studied the ASR expansion up to 14 days of mor-
reported that green and brown glass was non-reactive, whilst clear tars containing 10% clear soda-lime glass as natural sand replace-
glass was potentially deleterious. Du and Tan [69] reported that ment. Different particle sizes of glass sand related to U.S.
mortars with clear glass sand (size 4.75–0.3 mm) exhibited higher standard were used. The results showed that maximum expansion
ASR expansion. The effect was found to be potentially deleterious if occurred for sieve size No. 16 (2.36–1.18 mm), whilst mortar bars
clear glass particles were used to replace more than 50% of natural containing 10% of sieve size No. 50 (0.3 mm) glass sand exhibited
sand. On the other hand, green and brown glass sand mortars approximately the same expansion as the reference. Mortar bars
proved to be innocuous regardless of the replacement level. Jin with 10% of sieve No. 100 (0.15 mm) or pan (pass sieve No. 100)
et al. [66] studied the ASR expansion of mortars containing 10% showed less expansion than the reference bars. Xie et al. [73]
waste glass with different colours instead of natural sand. The partially replaced natural sand in mortars with crushed beverage
354 A.M. Rashad / Construction and Building Materials 72 (2014) 340–357

bottles glass having different particle sizes (sieved with #8, #16,
#30, #50 and #100) at levels of 0% and 10%, by weight. The results
showed a slight increase in the ASR expansion of mortars contain-
ing 10% glass sand finer than sieve #50 (0.3 mm). The coarser
aggregate (larger than #50) resulted higher ASR expansion. Rajabi-
pour et al. [74] partially replaced natural sand in mortars with
mixed colour soda-lime glass, containing different particle sizes,
at levels of 0%, 10%, 25%, 50% and 100%, by weight. They reported
that glass sand containing particles smaller than sieve #30
(0.6 mm), the ASR expansion was minimal. On the other hand, lar-
ger size glass particles showed larger and more active microcracks
that render their high ASR reactivity.
Corinaldesi et al. [53] reported that no ASR expansion has been
detected with particle size up to 100 lm of glass particles that par-
Fig. 16. Effect of different particle sizes of glass sand on ASR expansion at 14 and
tially replaced natural sand at levels of 30% and 70%, by weight,
28 days [75].
thus reflecting the feasibility of waste glass reuse as fine aggregate
in mortar and concrete. Idir et al. [63] studied the ASR expansion of
mortars containing different fineness of mixed colour waste glass.
Marble sand was partially replaced with waste glass at levels of
20% and 40%, by weight. The mean diameters of the used waste
glass ranging from 3750 to 7.8 lm. The results showed that the
ASR expansion decreased with increasing waste glass fineness.
Lee et al. [75] crushed post-consumer glass bottles with a green
colour for four different particle sizes of un-sieve glass having max-
imum size of 5 mm, <2.36 mm, <1.18 mm and <0.60 lm. In mor-
tars, natural sand was replaced with waste glass at levels of 0%
and 100%, by weight. The glass mortars showed higher ASR expan-
sion than the control. The expansion increased with increasing
glass sand particle size (Fig. 16).
Idir et al. [76] reported that ASR expansion of mortars contain-
ing mixed colour glass (40% colourless, 33% brawn, 20% green, 15
blue and 6% impurities) at levels of 20% and 40% decreased with Fig. 17. Mitigated ASR expansion of glass sand mortar by MK [78].
increasing glass sand specific surface area. No swelling due to
ASR was observed when glass grains were less than 1 mm. They
also reported that fine glass powders with specific surface areas met the ASTM C 1260 requirements at age of 14 days. On the other
ranging from 180 m2/kg to 540 m2/kg reduced the expansions of hand, at age of 28 days serious expansion and cracks were
mortars subjected to ASR. Du and Tan [69] partially replaced natu- observed. For higher content of glass sand, the incorporation of
ral sand in mortars with different colours of waste glass at levels of mineral admixtures such as FA and metakaolin (MK) (at least
0% and 25%. For each colour there were different particle sizes of 10%) were able to suppress the ASR expansion (Fig. 17). Topçu
2.36, 1.18, 0.6, 0.3 and 0.15 mm. The results showed an increase et al. [67] reported that the inclusion of 10–20% FA or 1–2% Li2CO3
in the ASR expansion with increasing glass size regardless glass (lithium carbonate) in mortars containing glass sand was able to
colour. The maximum and minimum ASR expansion occurred at reduce the ASR expansion. Kou and Poon [64] reported that replac-
2.36 mm and 0.15 mm sized glass sand, respectively. They also ing cement with 33% FA can reduce the ASR expansion, in mortar
reported that if glass sand was smaller than 2.36 mm, pozzolanic bars, resulted from replacing natural sand with waste glass (size
reaction would occur since the ASR expansion started to decrease <5 mm) at levels of 15%, 30% and 45%, by weight. Ling et al. [46]
from 2.36 mm till 0.15 mm. reported that 10–30% MK was able to suppress mortars ASR expan-
From the above review in this part, it can be noted that all stud- sion caused by glass sand. Ling and Poon [48] reported higher ASR
ies agreed that the ASR expansion of glass mortars decreased with expansion of mortars containing 100% recycled blue bottles waste
increasing glass sand fineness. On the other hand, the optimal glass glass (60% <2.36 mm and 40% 5–2.36 mm) as natural sand (passing
sand particle size that showed the lowest ASR expansion is still dif- through 2.36 mm) replacement, by weight. The harmful in the ASR
ferent from one research to another. Jin et al. [66] and Xie et al. [73] expansion caused by glass sand could be mitigated by replacing
believed that glass sand with 0.3 mm particle size is enough to sup- part of cement (20%) with MK.
press ASR expansion of glass sand mortars, whilst Rajabipour et al. Du and Tan [69] reported that 30% FA or 60% slag were the most
[74] reported <0.6 mm and Idir et al. [76] reported <1 mm. What- effective ASR expansion suppressing methods since they could
ever, the critical particle size for pozzolanic reaction to occur was reduce the alkalinity in the pore solution and decrease the porosity
differently observed as 1.18–0.6 mm [76] or 0.3–0.15 mm [77]. In and permeability of the cement paste, thus controlling the ASR
fact, increasing ASR expansion by using glass sand is the major expansion mechanism. The inclusion of 10% silica fume (SF) could
shortcoming of this recycled material. However, the ASR expansion also reduce the ASR expansion. Addition of steel fibres or lithium
can be mitigated as will be explained in the following section. compounds was less effective. By using supplementary cementi-
tious materials, ASR expansion in clear glass sand mortar could
14.4. Suppressing ASR expansion be reduced to below acceptable limits. Taha and Nounu [32]
reported that the use of recycled glass (size <5 mm) as natural sand
Lam et al. [78] reported that mortar bars containing 100% mixed replacement at levels of 50% and 100%, by volume, in concretes
colour (30% colourless, 40% green and 30% brown) recycled glass possessed high risk of ASR expansion and cracks were observed,
(size <5 mm) had ASR expansion coupled with serious cracks., whilst 60% slag, 10% MK and 1% lithium nitrate (LiNO3) limited
whilst mortar bar containing 50% glass sand plus 50% natural sand the potential ASR expansion risk.
A.M. Rashad / Construction and Building Materials 72 (2014) 340–357 355

Table 7 reduction in the density of the blocks with the inclusion of 5T5G
Different methods to suppress ASR expansion in glass sand mortar and concrete and 4B4G2T, respectively. The compressive strength and splitting
specimens.
tensile strength decreased with the inclusion of these waste mate-
Author Protection method rials. The reduction in the 28 days compressive strength was
Lam et al. [78] – At least 10% FA or MK 22.48% and 17.76% with the inclusion of 5T5G and 4B4G2T, respec-
Topçu et al. [67] – 10–20% FA tively. The results also showed that the percentage of water
– 1–2% Li2CO3 absorption increased by 47.17% and 35.85% with the inclusion of
Kou and Poon, [64] – 33% FA
Ling et al. [46] – 10–30% MK
5T5G and 4B4G2T, respectively. The results showed higher skid
Ling and Poon [48] – 20% MK resistance for 5T5G and 4B4G2T compared to the control. It was
Du and Tan [69] – 30% FA or 60% slag mainly due to the rough surface texture of the contaminating par-
– 10% SF ticles. On the other hand, the abrasion resistance was lower.
– Fibres or lithium compounds
Lam et al. [78] replaced recycled aggregate which used as fine
Taha and Nounu, [32] – Slag, 10% MK and 1% LiNO3
Oliveira et al. [58] – FA aggregate in concrete blocks with mixed colour (30% colourless,
Dhir et al. [68] – MK or slag 40% green and 30% brown) recycled crushed glass (size <5 mm)
Lee et al. [75] – 10% MK or 50% FA at levels of 0%, 25%, 50%, 75% and 100%, by weight. They studied
Maraghechi et al. [79] – Glass sand annealed at 650 °C for 40 min the compressive strength, tensile splitting strength, the percentage
Du and Tan [72] – 10–50% FA, 45–60% slag, 12.5% SF, 1.5–2%
of water absorption and ASR expansion. The results showed a
steel fibres and 0.5–2% lithium compounds
reduction in the 90 days compressive strength with increasing
glass sand content. On the same line, the tensile splitting strength
Oliveira et al. [58] reported that ASR expansion of concretes decreased with increasing glass sand content. ASR expansion
containing amber waste glass (maximum particle size 4.76 mm) increased with increasing glass sand content. On the other hand,
as natural sand replacement at levels of 25%, 50% and 100%, by the percentage of water absorption decreased with increasing glass
weight, largely mitigated with the inclusion of FA. Dhir et al. [68] sand content.
reported that ASR expansion caused by the inclusion of glass sand
in concretes could be controlled by the use of slag and MK. Lee 16. Remarks
et al. [75] reported that ASR expansion caused by glass sand could
be reduced by using 50% FA or 10% MK. Maraghechi et al. [79] The current review paper carried out on reviewing the previous
incorporating 100% mixed colour glass sand with gradation in works that investigated the effect of waste glass (derived from con-
the range of #4 to #100 sieves (4.75–0.15 mm) annealed at differ- tainer or packaging glass, flat glass, domestic or tableware glass
ent temperatures for different periods in mortars. They reported and continuous filament glass fibres) which used as fine aggregate
that exposed glass to elevated temperatures could effectively mit- replacement in mortars and concretes. Fresh properties, hardened
igate ASR expansion. It was found that the reactive size fraction of properties and durability of mortars and concretes containing glass
glass cullet (between #4 and #30 sieves) (4.75 and 0.6 mm), when sand were reviewed. The remarks of this literature review can be
annealed at 650 °C for 40 min showed the lowest ASR expansion. summarized as following:
Du and Tan [72] reported that ASR expansion of concretes contain-
ing glass sand can be mitigated by incorporation 10–50% FA, 45– 1. The inclusion of glass sand in the matrix increased temper-
60% slag, 12.5% SF, 1.5–2% steel fibres and 0.5–2% lithium com- ature during hydration.
pounds. Table 7 summarizes the mentioned studies about different 2. Some studies reported that the inclusion of glass sand
methods to suppress ASR expansion in mortar and concrete speci- increased the workability of the mixtures. Others reported
mens containing glass sand. contradictory effect. The initial and final setting time
From the above review in this part, it can be noted that the ASR increased with increasing glass sand content.
expansion of mortar and concrete specimens containing glass sand 3. Bleeding and segregation increased with increasing glass
can be mitigated by adding 10–30% MK, 20–50% FA, 50–60% slag, sand content, whilst density (fresh and dry) decreased with
10% SF, 1–2% Ni2CO3, 1% LiNO3 and suitable amount of fibres. increasing glass sand content.
In general view, using glass as fine aggregate in mortars and 4. Most of studies reported lower mechanical strength with
concretes showed some advantages, in which some properties increasing glass sand content. This reduction was mainly
are improved, and some disadvantages, in which some properties due to the smooth surface and sharper edges of glass parti-
are defected. The advantages of using glass sand are increasing cles that resulted in weaker bond at the ITZ between glass
workability, reducing density, increasing carbonation resistance particles and cement paste matrix. Others reported higher
at later ages, increasing chemical resistance, increasing fire resis- strength by the inclusion of glass sand with particle size of
tance and decreasing shrinkage. On the other hand, the disadvan- 75 lm. The enhancement in strength was related to the poz-
tages of using glass sand are decreasing compressive strength, zolanic reaction of glass at this particle size. There is no sig-
decreasing carbonation resistance at early ages and increasing nificant impact of the colour of the glass on the strength.
ASR expansion. Some properties are still need more investigations 5. The inclusion of 10% glass sand increased the residual com-
as abrasion resistance, fire resistance, water absorption, chloride pressive strength of concrete after exposure to fire up to
ion penetration and permeability. 700 °C.
6. There are contradictory reports about the effect of glass sand
15. Waste glass combined with other recycled materials on abrasion resistance. Some studies reported positive
effect, whilst the others reported negative effect.
Poon and Chan [80] partially replaced recycled concrete aggre- 7. Some studies reported that the inclusion of glass sand
gate which used as aggregate in concrete blocks with 10% of differ- reduced the water absorption. This reduction may be related
ent waste materials. These materials were 5% crushed tile to the negligible water absorption of the glass. Others
combined with 5% waste glass (5T5G) and 4% crushed brick with reported adverse impact.
4% waste glass combined with 2% crushed tile (4B4G2T). Only 8. Most of studies reported that the inclusion of glass sand in
the recycled fine aggregate was used (size <5 mm). The aggre- the matrix increased the chloride penetration depth and per-
gate/cement ratio was 3:1. The results showed 5.42% and 4.52% meability of concretes.
356 A.M. Rashad / Construction and Building Materials 72 (2014) 340–357

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