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Construction and Building Materials 156 (2017) 443–467

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Construction and Building Materials


journal homepage: www.elsevier.com/locate/conbuildmat

Review

Practical recycling applications of crushed waste glass in construction


materials: A review
Abbas Mohajerani a,⇑, John Vajna a, Tsz Ho Homan Cheung a, Halenur Kurmus a, Arul Arulrajah b,
Suksun Horpibulsuk c
a
School of Engineering, RMIT University, Melbourne, Australia
b
Swinburne University of Technology, Australia
c
Suranaree University of Technology, Thailand

h i g h l i g h t s

 Detailed review of Crushed Waste Glass (CWG) as a Construction Material (CM).


 Physical, mechanical and chemical characteristics of CWG are discussed.
 Use of foamed waste glass in concrete as a lightweight aggregate is reviewed.
 Introducing expanded waste glass in ultra-lightweight fibre reinforced concrete.
 Assessing the environmental impacts of CWG and foamed recycled glass in CM.

a r t i c l e i n f o a b s t r a c t

Article history: The disposal of waste glass in landfills is an important environmental challenge that many countries face
Received 22 February 2017 around the world. The repurposing of waste glass into a construction material reduces the consumption
Received in revised form 26 August 2017 of natural resources, minimizes greenhouse emissions and alleviates landfill scarcity. Over the last sixty-
Accepted 1 September 2017
five years, numerous investigators have studied reusing crushed waste glass (CWG) as a construction
material. However, CWG has not been widely used in concrete or asphalt construction applications across
the globe. Additionally, barriers still exist that prevent CWG from being used as a fine aggregate in con-
Keywords:
crete, such as the severity of Alkali-silica reaction (ASR) expansions within concrete consisting of CWG,
Waste glass
Foamed recycled glass
and the lack of understanding of these reactions. This paper presents an overview of previous studies car-
Normal concrete ried out by researchers to reuse CWG as an aggregate in concrete and asphalt mixtures, an aggregate in
Asphalt concrete unbound base and subbase applications, lightweight engineering material and a cementitious material.
Fine aggregates From the literature review conducted, it can be concluded that CWG has potential use as an aggregate
Construction materials in construction materials. More research is required to clarify contradictions regarding the properties
Recycling of concrete containing CWG as fine aggregate, as well as further investigation of the properties of foamed
waste glass concrete and ultra-lightweight fibre reinforced concrete containing expanded waste glass,
and the use of glass powder as a filler in asphalt.
Ó 2017 Elsevier Ltd. All rights reserved.

Contents

1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 444
2. Properties of glass . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 447
2.1. Chemical properties . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 447
2.2. Physical properties . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 447
2.3. Mechanical properties. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 447
3. Crushed glass as a fine aggregate in concrete . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 447
3.1. Workability of concrete with fine aggregates replaced with crushed waste glass . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 447

⇑ Corresponding author.
E-mail address: abbas.mohajerani@rmit.edu.au (A. Mohajerani).

http://dx.doi.org/10.1016/j.conbuildmat.2017.09.005
0950-0618/Ó 2017 Elsevier Ltd. All rights reserved.
444 A. Mohajerani et al. / Construction and Building Materials 156 (2017) 443–467

3.2.Mechanical strength of concrete containing glass as a replacement for fine aggregates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 449
3.2.1. Compressive strength . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 449
3.2.2. Flexural strength. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 449
3.2.3. Splitting tensile strength . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 450
3.2.4. Modulus of elasticity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 450
3.3. Density . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 451
3.4. Alkali-silica reaction expansions in concrete consisting of crushed waste glass fine aggregate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 452
3.4.1. Effect of glass colour on ASR . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 452
3.4.2. Effect of glass particle size . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 452
3.4.3. Effect of glass content . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 452
3.4.4. Effectiveness of additives and other methods at mitigating ASR . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 453
3.5. Chloride penetration resistance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 453
3.6. Water absorption. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 453
4. Recycling crushed waste glass in asphalt concrete . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 453
4.1. Crushed waste glass as an aggregate in asphalt concrete. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 453
4.2. Glass powder as a filler in asphalt concrete . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 456
4.3. Performance of asphalt concrete containing crushed waste glass at high and low temperatures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 456
4.4. Stripping . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 457
5. Use of crushed waste glass in the base and subbase of roads. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 457
6. Environmental impact of crushed waste glass in road applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 458
7. Crushed waste glass as a cementitious material . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 459
7.1. Workability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 459
7.2. Mechanical strength of concrete containing glass as a cementitious material . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 459
7.2.1. Compressive strength . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 459
7.2.2. Strength activity index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 460
7.3. Alkali-silica reaction expansions in concrete consisting of crushed waste glass as a replacement for Portland cement . . . . . . . . . . . . . . 460
8. Foamed waste glass . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 461
8.1. Foamed waste glass as an aggregate in concrete . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 461
8.1.1. Workability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 461
8.1.2. Compressive strength . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 462
8.1.3. Flexural strength. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 462
8.1.4. ASR expansion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 462
8.2. Foamed waste glass as a lightweight engineering material . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 462
8.2.1. Engineering properties . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 462
8.2.2. Environmental properties . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 462
9. Expanded waste glass in ultra-lightweight fibre reinforced concrete. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 463
9.1. Density . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 463
9.2. Mechanical properties of ultra-lightweight fibre reinforced concrete containing expanded waste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 463
9.2.1. Compressive behaviour . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 463
9.2.2. Flexural behaviour . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 463
9.3. Thermal conductivity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 463
10. Summary and conclusion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 463
10.1. Recommendations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 464
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 465

1. Introduction The first steps in the glass manufacturing process are the min-
ing, transporting and processing of materials that become glass
The disposal of waste glass has become a major environmental inputs [130,131]. After the inputs are transported to a glass manu-
concern due to the increasing demand for landfill space and natu- facturing facility, the main processes in glass manufacturing are
ral resources, and a greater emphasis on reducing the carbon foot- batch preparation, melting and refining, forming and post forming
print of the construction industry. The production of glass dates [128]. For every tonne of glass recycled, approximately 560 kg of
back to 3500 BCE in Mesopotamia, northern Syria and Ancient sand, 190 kg of soda ash, 176 kg of limestone and 64 kg of feldspar
Egypt. By the late 1400s, early 1500s glass had already become are conserved Glass Packaging [47]. The most common types of
an important commodity in European countries [52]. Ever since glass include soda-lime glass (Fig. 2), lead crystal and crystal glass,
then, the rate of generation of waste glass (WG) has increased sig- borosilicate glass, and electric glass, which is also called E-glass.
nificantly. Even though glass is an inert material, all glass products The varying chemical composition of glass is the main reason
have a limited lifespan [144,145], which leads many researchers to why most WG cannot be remanufactured into glass products.
look for ways to redirect the amount of WG (Fig. 1) disposed of in Due to the inert nature of glass it is a non-biodegradable material.
landfills. WG that is not reused stays in landfills for an extremely long time
Initially, the uses of glass were limited to jars, beads and with glass bottles taking around 1 million years to decompose (U.S.
bowls [53], but, due to advances in technology, the number of National Parks Service), which takes up valuable space that can be
applications of glass has skyrocketed to include windows, used for biodegradable materials.
shelves, lighting, appliances, fibre optic cables and solar panels, According to the U.S. Environmental Protection Agency [130], in
etc. The surge in the number of applications of glass is largely 2013, Americans generated 10.37 million tonnes of glass in the
due to the discovery of different types of glass with varying municipal solid waste stream, the majority of which were food
properties. and drink containers. Out of the glass disposed of, 2.78 million
A. Mohajerani et al. / Construction and Building Materials 156 (2017) 443–467 445

Fig. 1. Crushed recycled glass and discarded glass bottles.

Fig. 2. Fine window and Soda-Lime glass aggregate, and LCD glass aggregate.

tonnes of glass (27%) were recovered for recycling, which resulted Furthermore, in 2007 it was estimated that 130 million tonnes of
in 7.59 million tonnes of WG being discarded in landfills. glass were produced globally [59], and with the ever-increasing
In addition, in 2013, the European Union produced 1.5 million demand for glass products the amount of WG produced will conse-
tonnes of glass waste from demolition and renovation [50], and quently increase [98,123,144].
approximately 15.9 million tonnes of glass packaging waste [44]. Although the total amount of WG recovered may be high, only
a fraction of this amount may be remanufactured due to the strict
limitations of glass remanufacturing. Traditionally, glass needs to
Table 1
Glass recycling rate of various countries. be collected and sorted into different colours. Glass that cannot
be sorted is broken or mixed during the collection phase along
Country Glass Recycling Rate 2010 (%)
with glass that contains composite materials or contaminants
Belgium 96Container Recycling [28] that are not economical or technically impossible to remanufac-
Switzerland 94Container Recycling [28]
ture [30,62]. Mixed glass cannot be reused due to chemical
Luxembourg 93Container Recycling [28]
Netherlands 91Container Recycling [28] incompatibility and problems that arise from the differences in
Sweden 91Container Recycling [28] the melting temperatures of each type of glass, as only 5 g of
Norway 89Container Recycling [28] non-recyclable glass is enough to contaminate a tonne of recy-
Germany 82Container Recycling [28] clable glass [4]. The remanufacturing of WG is environmentally
Italy 74Container Recycling [28]
France 67Container Recycling [28]
friendly as it reduces the amount of raw materials required and
United Kingdom 61Container Recycling [28] decreases the total amount of energy consumed during the man-
Spain 57Container Recycling [28] ufacturing process, since the melting points for recycled glass are
Australia 34 [58] typically lower than the melting points of the raw materials that
USA 33Container Recycling [28]
constitute glass [26].
446 A. Mohajerani et al. / Construction and Building Materials 156 (2017) 443–467

Table 2
Chemical composition of common commercial glass types [77].

Glasses and uses SiO2 Al2O3 B2O3 Na2O K2O MgO CaO BaO PbO Others
Soda-Lime Glasses
Containers 66–75 0.7–7 12–16 0.1–3 0.1–5 6–12
Float 73–74 13.5–15 0.2 3.6–3.8 8.7–8.9
Sheet 71–73 0.5–1.5 12–15 1.5–3.5 8–10
Light Bulbs 73 1 17 4 5
Tempered Ovenware 75 1.5 14 9.5
Borosilicate
Chemical apparatus 81 2 13 4
Pharmaceutical 72 6 11 7 1
Tungsten sealing 74 1 15 4
Lead glasses
Colour TV funnel 54 2 4 9 23
Neon Tubing 63 1 8 6 22
Electronic parts 56 2 4 9 29
Optical dense flint 32 1 2 65
Barium glasses
Colour TV panel 65 2 7 9 2 2 2 2 10% SrO
Optical dense barium crown 36 4 10 41 9% ZnO
Aluminosilicate glasses
Combustion tubes 62 17 5 1 7 8
Fiberglass 64.5 24.5 0.5 10.5
Resistor substrates 57 16 4 7 10 6

Table 3
Chemical composition of different coloured glass [32,93,96,101].

Chemical Composition Amber Glass (%) [101] Green Glass (%) [96] Brown Glass %) [93] White Glass %) [32]
SiO2 70.66 72.25 72.1 69.82
CaO 9.12 12.35 – 8.76
Na2O 8.32 10.54 – 8.42
Al2O3 6.53 2.54 1.74 1.02
Fe2O3 2.52 – 0.31 0.55
MgO 1.45 1.18 – 3.43
K2O 1.03 1.15 – 0.13
TiO2 0.27 – – –
P2O5 0.07 – – –
MnO2 0.04 – – –
Cr2O3 – – 0.01 –
SO3 – – 0.13 0.20
Na2O + K2O – – 14.11 –
CaO + MgO – – 11.52 –

Table 4
Physical properties of crushed waste glass.
estimated that yearly 181.4 million tonnes of solid waste was dis-
Bulk Density 1360 kg/m3 [31,104] posed, of which 12.7 million tonnes was glass [123]. With the con-
Specific gravity 2.4–2.8 [93] struction industry producing approximately 92.53 million tonnes
2.5 (Green), 2.52 (Brown)
of asphalt concrete in 2013 [127], 4.6 billion tonnes of cement in
Shape Index (%) 30.5 [31,104]
Fineness modulus 4.25 [64,68] 2015 [119,120] and 3.82 billion cubic metres of concrete annually
0.43–3.29 [23], the endeavors to find alternative materials to minimize the
Flakiness Index 84.4–94.7 [33] consumption of virgin materials have gained greater precedence.
In order to redirect WG from being sent to landfills and to mini-
mize the construction industry’s impact on the environment, over
Table 5 the last 70 years, researchers have studied the use of crushed
Mechanical Properties of CG. waste glass (CWG) in construction applications. Research has cov-
Los Angeles Value (%) 38.4 [31,33] ered various applications, such as using CWG as an aggregate in
24.8–27.7 [104] asphalt, aggregate in subbase and unbound base, lightweight engi-
27.7 [7] neering material, cementitious material and aggregate in concrete.
CBR (%) Approx. 50–75. [90]
The aim of this literature review is to focus on the various con-
Friction Angle crit = 38 (Loose RG) [90]
Friction Angle = 50–61 (Dense RG) [90] struction applications of CWG within the construction industry.
Over the last 20 years, numerous studies have been conducted to
determine the effects of incorporating different types of waste
materials in construction materials such as bricks, normal con-
In 2015, the European Union recycled up to 73% of glass crete, asphalt concrete and other pavement materials (e.g., Moha-
packaging with Sweden, Belgium, Luxembourg and Germany being jerani et al. [84]; Mohajerani et al. [85]; Mohajerani et al. [86];
the best performers [28,121], Table 1. In 2004, the United Nations Ukwatta et al. [126]).
A. Mohajerani et al. / Construction and Building Materials 156 (2017) 443–467 447

Fig. 3. Slump of concrete containing various amounts of CWG as a replacement for fine aggregate, which was acquired from numerous studies.

2. Properties of glass particles with a ratio of length/thickness of more than 3, and is


expressed as a percentage of the total dry mass of the particles
2.1. Chemical properties tested. The fineness modulus is the sum of the total percentages
of a sample of aggregates retained on each of a specified series of
Glass comes in a diverse range of types and colours, with differ- sieves, and the sum divided by 100 [88]. The flakiness index is
ent chemical compositions. The differing chemical properties of the percentage, by mass, of the particles whose least dimension
mixed coloured glasses are one of the primary reasons why glass is less than three-fifths of the mean dimension [121].
is not remanufactured. Table 2 [77] shows the chemical composi-
tions of common commercial glass types. Table 3 shows the chem- 2.3. Mechanical properties
ical compositions of various colours of glass.
The mechanical properties of crushed waste glass are listed in
2.2. Physical properties Table 5.

The physical properties of crushed waste glass are listed in 3. Crushed glass as a fine aggregate in concrete
Table 4. Bulk density is the loose bulk density, which is calculated
by the division of weight by volume. Shape index is the mass of In 2010, it was estimated that around 12 billion tonnes of con-
crete were produced worldwide [79], an amount that is steadily
increasing. Concrete is comprised of cement, aggregates (Fine
and Coarse) and water along with additives to enhance specific
properties. Over the last 20 years, numerous studies have been
conducted to determine the effects of crushed waste glass as a fine
aggregate substitute on the properties of concrete.

3.1. Workability of concrete with fine aggregates replaced with


crushed waste glass

In general, the inclusion of fine waste glass aggregates in con-


crete mixtures results in a reduction in concrete workability. How-
ever, the results from the reviewed literature were quite
contradictory. Abdallah and Fan [1], Park et al. [94], Taha and
Nounu [115], Chen et al. [25], Ismail and Al-Hashmi [60], and
Bateyneh et al. [15] reported that concrete mixes consisting of
crushed waste glass (CWG) were less workable than the control
for all replacement levels, while all the concrete mixes containing
Fig. 4. Compressive strength of concrete with different glass content. CWG tested by Malik et al. [73,74] exhibited slump values greater
448 A. Mohajerani et al. / Construction and Building Materials 156 (2017) 443–467

Fig. 5. Compressive strength of concrete containing various amounts of CWG as a replacement for fine aggregate, which was acquired from numerous studies.

than the control. Despite the decline in workability, Ismail and Al- basalt fibres, by total mix volume. The results showed that an
Hashmi [60] found that concrete mixes containing CWG were still increase in the CWG replacement level resulted in an increase in
workable. workability, with concrete consisting of 60% CWG achieving the
Adaway and Wang [3] reported that concrete containing 15% highest workability value for concrete consisting of CWG.
and 25% CWG exhibited an increase in slump, while concrete con- The smooth surfaces, sharp edges and harsh textures of fine
taining 20%, 30% and 40% CWG underwent a decrease in slump. Ali CWG aggregate harmed the fluidity of concrete, and, in turn,
and Al- Tersawy [5] tested the workability of self-compacting con- reduced the workability of concrete mixtures
crete using the slump flow test. They observed that concrete con- [1,3,15,60,70,94,97,115]. Additionally, Taha and Nounu [116]
taining CWG obtained slump flow values similar to the control observed that the smooth surface and minute water absorption
despite having lower dosages of superplasticizer. Additionally, of CWG particles resulted in a weaker cohesive force in the con-
concrete consisting of 50% CWG as a replacement for fine aggregate crete mixtures, which led to segregation and bleeding of the
acquired the highest slump flow value of 740 mm, which was 12% concrete.
higher than the control. Additionally, Borhan [18] tested concrete On the other hand, the weaker cohesion between the waste
containing fine aggregates replaced with CWG, and 0.3% or 0.5% glass sand (WGS) and cement due to their smooth surfaces

Fig. 6. Flexural strength of concrete containing various amounts of CWG acquired from numerous researchers.
A. Mohajerani et al. / Construction and Building Materials 156 (2017) 443–467 449

[5,118], and the impermeable nature of glass [118] resulted in an compressive strength of concrete blocks with CWG aggregate of
increase in workability. In addition, the inclusion of fine liquid various sizes (unsieved, <2.36 mm, <1.18 mm and <0.60 mm). They
crystal display (LCD) glass aggregates enhanced the workability reported that at 28 days of curing only concrete blocks containing
of concrete due to LCD glass’s hydrophobic nature, which causes <0.60 mm CWG achieved compressive strength values superior to
excessive amounts of water to be present in concrete mixtures the control.
[136]. From the studies reviewed, the optimum waste glass sand The strength and surface texture of glass aggregate compared to
(WGS) content for achieving the best workability was found to natural sand can result in an increase in the compressive strength
be 20%. Fig. 3 depicts the slump results acquired from numerous of concrete [15]. Additionally, the larger surface area of glass par-
studies. ticles enables greater bonding with the cement paste, thus creating
a stronger concrete matrix and subsequently improving the com-
pressive strength of concrete [3]. In addition, the compressive
3.2. Mechanical strength of concrete containing glass as a replacement strength of concrete can be improved by the pozzolanic reactions
for fine aggregates caused by the chemical composition of glass [1,46,124].
Conversely, the reduction in the compressive strength of con-
3.2.1. Compressive strength crete has been attributed to the weakening of the bond between
Generally, the inclusion of fine waste glass aggregates in con- glass aggregates and the cement paste [5,31,60,68,117,123,137]
crete mixtures leads to an increase in compressive strength; how- and the higher water content ratio of the glass aggregate mixes
ever, many studies reported a decrease in compressive strength. All [31,97]. Moreover, they reported that the addition of basalt fibres
the concrete mixes Turgut and Yahlizade [124], Chen et al. [25], increased the compressive strength of the concrete since the fibres
Pereira de Oliveira et al. [95], and Batayneh et al. [15] tested suppress the growth of cracks within the concrete structure. Fig. 5
achieved compressive strengths higher than the control. On the depicts the compressive strength results acquired from numerous
other hand, all the concrete specimens Ali and Al-Tersawy [5], studies.
and Park et al. [94] tested obtained compressive strengths lower
than the control.
Malik et al. [74], and Adaway and Wang [3] observed that con- 3.2.2. Flexural strength
crete containing up to 30% crushed waste glass CWG) exhibited As with the case for compressive strength, the majority of stud-
compressive strength values higher than the control at 7 and ies reported that the inclusion of fine crushed waste glass aggre-
28 days, while concrete with replacement levels higher than 30% gates resulted in an increase in flexural strength; however,
underwent a reduction in compressive strength. Additionally, at numerous studies observed a decrease in compressive strength
28 days, concrete with replacement ratios up to 30% exhibited with the inclusion of CWG. The concrete specimens Abdallah and
compressive strengths higher than the control. Moreover, Lim- Fan [1], Turgut and Yahlizade [124], Ismail and Al-Hashmi [60]
bachiya [70] reported that the compressive strength of specimens and Batayneh et al. [15] tested achieved flexural strengths higher
containing CWG decreased with increasing CWG replacement than the control. On the other hand, the concrete specimens Park
levels when they were higher than 20%. et al. [94], Taha and Nounu [115], and Ali and Al-Tersawy [5] tested
Moreover, Taha and Nounu [115] found that the control obtained flexural strengths lower than the control. Taha and
obtained higher compressive strengths compared to the specimens Nounu [115], Ali and Al-Tersawy [5], Ismail and Al-Hashmi [60],
containing 50% and 100% CWG between approximately 0–200 days and Park et al. [94] observed that increasing percentages of glass
of curing. However, at 366 days concrete containing 50% CWG aggregate led to a decrease in flexural strength. In contrast, Batay-
obtained a compressive strength slightly lower than the control, neh et al. [15], and Abdallah and Fan [1] reported that increasing
while concrete consisting of 100% CWG obtained a compressive proportions of waste glass resulted in an increase in flexural
strength marginally higher than the control. Fig. 4 depicts the com- strength.
pressive strength of concrete with varying levels of glass content. Limbachiya [70] reported that concrete containing fine glass
Chen et al. [25] tested the compressive strength of concrete aggregate with proportions up to 20% observed no change in flex-
with natural sand replaced with E-glass aggregate and found that ural strength. However, concrete containing fine glass aggregate
the inclusion of E-glass significantly improved the compressive replacement levels higher than 20% exhibited reductions in flexu-
strength of concrete. Additionally, Lee et al. [68] tested the ral strength. In addition, Park et al. [94] observed that the flexural

Fig. 7. Splitting tensile strength of concrete containing various amounts of CWG acquired from numerous studies.
450 A. Mohajerani et al. / Construction and Building Materials 156 (2017) 443–467

Fig. 8. Modulus of elasticity of concrete containing various amounts of CWG acquired from numerous studies.

Fig. 9. Effects of Alkali-Silica Reaction [37].

Park et al. [94], Taha and Nounu [115], and Wang (Design strengths
of 28 and 35 MPa) [135] found that increasing proportions of CWG
in concrete resulted in a decrease in the splitting tensile strength.
Wang [135] reported that concrete with design strengths of
35 MPa and 21 Mpa, and 20% and 40% CWG obtained splitting ten-
sile strengths higher than the control, while concrete with design
strength of 28 MPa and 20–80% CWG also exhibited splitting ten-
sile strengths higher than the control. Furthermore, Borhan [18]
noted that at 28 days concrete consisting of 20% CWG achieved
splitting tensile strengths higher than the control, while concrete
containing 40% and 60% CWG obtained splitting tensile strengths
lower than the control. Batayneh et al. [15] observed that all the
concrete specimens they tested obtained splitting tensile strengths
similar to the control, except for concrete containing 20% CWG,
which exhibited strengths marginally lower than the control. Taha
Fig. 10. SEM image of a mortar bar that has cracked due to ASR expansion [97].
and Nounu [115] observed that concrete consisting of 50% CWG
obtained splitting tensile strengths similar to the control, while
concrete containing 100% CWG exhibited splitting tensile strengths
strength of concrete was not notably affected by the colour of glass lower than the control. Moreover, Park et al. [94] tested the split-
sand. ting tensile strength of concrete containing emerald, flint and
Fig. 6 depicts the flexural strength results acquired from numer- amber CWG and found that the colour of glass did not have a sig-
ous studies. nificant impact on the tensile strength of concrete.
Fig. 7 depicts the splitting tensile strength results acquired from
numerous studies.
3.2.3. Splitting tensile strength
The results from literature regarding the effect of replacing fine
aggregate with crushed waste glass (CWG) on the splitting tensile 3.2.4. Modulus of elasticity
strength of concrete are inconclusive. All the concrete specimens The modulus of elasticity of concrete is a function of the mod-
Ali and Al-Tersawy [5], Malik et al. [73] and Park et al. [94] tested ulus of elasticity of the lightweight and normal-density aggregates,
attained splitting tensile strengths lower than the control. How- cementitious matrix and their relative proportions in the mixture
ever, all the concrete specimens Turgut and Yahlizade [124] tested [43]. The inclusion of fine waste glass aggregates in concrete
attained splitting tensile strengths higher than the control. In addi- resulted in higher values for the modulus of elasticity [1,135].
tion, Ali and Al-Tersawy [5], Batayneh et al. [15], Malik et al. [73], However, Ali and Al-Tersawy reported that the replacement of fine
A. Mohajerani et al. / Construction and Building Materials 156 (2017) 443–467 451

Fig. 11. ASR expansions of 30, 45, and 60 MPa mortar consisting of green and brown glass [37].

aggregates with crushed waste glass (CWG) led to lower modulus 3.3. Density
of elasticity values. Additionally, increases in CWG replacement
levels resulted in a decrease in the modulus of elasticity of concrete The inclusion of fine waste glass aggregates in concrete mixes
[5,135]. However, Abdallah and Fan [1] found that at 14 days of reduced the unit weight, fresh density and wet density of concrete
curing, concrete consisting of 5% CWG obtained the highest modu- [1,15,18,31,60,68,73,116]. However, Adaway and Wang [3]
lus of elasticity followed by concrete containing 15% and 20% CWG, reported that concrete consisting of 15% crushed waste glass
while at 28 days, concrete containing 20% CWG achieved the high- (CWG) obtained a fresh density higher than the control, while all
est modulus of elasticity followed by concrete containing 15% and other CWG specimens with replacement levels higher than 15%
5% CWG. Furthermore, Limbachiya [70] reported that CWG content obtained fresh densities lower than the control, with an increase
up to 20% had no influence on the modulus of elasticity of concrete. in glass content resulting in a reduction in fresh density.
However, replacement levels higher than 20% resulted in a reduc- The reduction in density can be attributed to the lower specific
tion in the modulus of elasticity. Fig. 8 depicts the modulus of elas- gravity of natural aggregates compared to glass aggregates
ticity results acquired from numerous studies. [18,31,116] and lower specific gravity of sand [68].
452 A. Mohajerani et al. / Construction and Building Materials 156 (2017) 443–467

3.4. Alkali-silica reaction expansions in concrete consisting of crushed chromium oxide in green glass can ensure better performance
waste glass fine aggregate against alkali attack [36,81]. In contrast, the mortar bars Tan and
Du [117], and Du and Tan [36] tested consisting of brown glass
Alkali-silica reaction (ASR) is a chemical reaction between the expanded less than mortar bars containing green glass. Degirmenci
silica in aggregate and the hydroxyl ions in the concrete pore water et al. [32] observed that mortar containing white crushed waste
[139]. The products from this reaction cause swelling and the pres- glass expanded significantly more than mortar consisting of green
sures produced create micro-cracks in the glass particles that dam- or brown crushed waste glass. All the mortar specimens containing
age the concrete [81,82]. This reaction can also expedite other coloured glass aggregates exhibited expansions less than the 14-
reactions that, in turn, cause damage, such as freeze–thaw or cor- day proposed limit of 0.10% used by many standardization agen-
rosion related damage to concrete pavements and structures [118]. cies. Mortar consisting of 10% and 100% green glass expanded more
ASR occurs in the presence of alkali, silica and water [116,133]. A than brown glass of the same replacement levels; however, mortar
few measures that can be taken to avoid or mitigate ASR include containing 30% green glass expanded less than mortar containing
using special ASR resistant cements, making glass particles ASR 30% brown glass. In addition, Yuksel et al. [143] attributed the
resistant, modifying the chemistry of glass, grinding the glass par- presence of Cr2O3 in mortar bars consisting of green glass as the
ticles to less than 0.3 mm, sealing the concrete to isolate it from cause for their significantly lower ASR expansions compared to
moisture and adding mineral admixtures to concrete mixtures mortar bars containing flint or amber glass.
[80]. Fig. 9 shows the effect of ASR in mortar and concrete with Fig. 11 depicts the ASR expansion of 30, 45, and 60 MPa grade
the secondary calcium-silicate-hydrate (C-S-H). mortar containing green and brown glass [37].
The expansion caused by Alkali-Silica Reaction (ASR) has been
known for over 70 years but there has been little research in the 3.4.2. Effect of glass particle size
area due to the length of time required for the reaction to take An increase in the particle size of CWG aggregate in concrete or
place. mortar results in an increase in ASR expansion. The optimal
The traditional alkali-silica reactions of concrete differ signifi- crushed waste glass (CWG) particle size, which shows the lowest
cantly from the alkali-silica reactions of concrete consisting of ASR expansion in concrete or mortar varies amongst the literature.
crushed waste glass [112]. An accelerated test of two weeks, ASTM Rajabipour et al. [101] reported that CWG with a particle size less
C 1260 introduced in 1994 attracted more research to this partic- than 0.6 mm was innocuous during the period of testing, while Idir
ular area [16]. However, the ASR reactions in concrete and mortar et al. [55] found that CWG with particle sizes less than 0.9–1 mm
containing CWG are yet to be fully understood. In 1998, when Pol- did not expand deleteriously. In addition, Corinaldesi et al. [29]
ley et al. [97] investigated the reactivity of crushed waste glass reported that no deleterious ASR expansion occurred between
with moderate-alkali cement and with no measures taken to mit- CWG and the cement paste when glass aggregates had particle
igate ASR, the specimens had expanded more than 10 times greater sizes up to 100 mm.
than the acceptable criterion after 730 days. Fig. 10 depicts the
cracks in concrete due to ASR expansion. 3.4.3. Effect of glass content
The percentage of natural sand replaced with fine glass aggre-
3.4.1. Effect of glass colour on ASR gate has a substantial effect on the ASR reactions in concrete or
The research conducted over the years regarding the effects of mortar. Generally, an increase in glass content resulted in an
glass colour on ASR expansions has been quite inconclusive. The increase in ASR expansion [32,60,63,70,71,94,103,110,122,143].
studies that used flint, clear and white glass as a replacement for Conversely, Abdallah and Fan [1], reported that an increase in glass
fine aggregates observed that they were the most susceptible to proportions resulted in a decrease in ASR expansion. Saccani and
ASR expansions out of the colours tested; however, the results Bignozzi [103] tested the ASR expansions of soda-lime, borosili-
regarding green and brown glass were contradictory. The cate, amber borosilicate and lead-silicate glass. They reported that

Fig. 12. ASR expansion of mortar containing brown glass fine aggregates and various additives [37].
A. Mohajerani et al. / Construction and Building Materials 156 (2017) 443–467 453

Table 6 14 days. Fig. 12 depicts the ASR expansion of mortar containing


Top producers of asphalt concrete as listed by [127]. brown glass fine aggregates and various additives.
Country Total production asphalt
concrete in 2013
3.5. Chloride penetration resistance
(million tonnes)
United States of America 17.57 The chloride-induced corrosion of steel reinforcement is one of
China 16.27
Russian Federation 5.61
the most common problems affecting the long-term performance
India 4.34 of concrete structures [22]. The inclusion of fine waste glass aggre-
Canada 3.93 gate in concrete mixtures resulted in a decrease in chloride-ion
Iran 3.53 penetration [25,137]. However, de Castro and de Brito [31]
Japan 3.32
observed a slight increase in chloride-ion penetration with the
Republic of Korea 3.28
Germany 3.09 replacement of fine aggregate in concrete with crushed waste glass
Italy and San Marino 2.82 (CWG). They concluded that the inclusion of CWG does not signif-
Turkey 2.65 icantly alter the chloride-ion penetration of concrete since the
Brazil 2.41 chloride-ion penetration is governed by the quality of the cement
Saudi Arabia 2.22
Singapore 2.02
paste. In contrast, Wang et al. [137] and Chen et al. [25] observed
Spain 1.90 that increasing amounts of glass content resulted in a decrease in
France (including Monaco) 1.75 chloride-ion penetration. Wang et al. [137] reported that concrete
consisting of 20–60% glass aggregate underwent moderate
penetration while concrete consisting of 80% CWG exhibited low
penetration. In addition, the investigation conducted by Chen
an increase in lead-silicate glass content led to an increase in ASR et al. [25] found that the concrete specimens containing CWG
expansion, while amber borosilicate glass and soda-lime glass had very low chloride ion penetrability.
exhibited a decrease in ASR expansion with an increase in glass
content. ASTM C 1260-01 states that mortar bars with ASR expan- 3.6. Water absorption
sion less than 0.1% at 14 days show innocuous behaviour [25]. All
the mortar bars Abdallah and Fan [1], Limbachiya [70], Kou and The inclusion of waste glass in concrete mixtures resulted in a
Poon [63], Ismail and Al-Hashmi [60], Pereira de Oliveira et al. reduction in the water absorption of concrete specimens
[95], and Chen et al. [25] tested obtained expansion values of less [1,73,74,116]. Additionally, an increase in the replacement levels
than 0.1%. Saccani and Bignozzi [103] observed that mortar bars of fine aggregate with crushed waste glass (CWG) led to a decrease
containing 10%, 25% and 35% soda-lime glass, and 35% amber in water absorption [1,73,74,115,116]. Taha and Nounu [115]
borosilicate glass expanded less than 0.1%. reported that concrete mixtures consisting of 50% CWG exhibited
water absorption values marginally higher than the control, while
mixtures containing 100% CWG obtained water absorption values
3.4.4. Effectiveness of additives and other methods at mitigating ASR
significantly lower than the control. Conversely, Lee et al. [68]
The inclusion of additives, such as metakaolin, fly ash, steel
noted that all the concrete blocks tested exhibited water absorp-
fibre, polypropylene fibre, granulated blast furnace slag, lithium
tion values higher than the control. When particle sizes of CWG
compounds and silica fume, can mitigate the ASR expansion in
were reduced to less than 600 mm the water absorption values of
concrete and mortar. Topcu et al. [122] observed that 20% fly ash
the concrete specimens increased significantly.
and 2% lithium carbonate were able to provide sufficient ASR resis-
tance for mortar bars consisting of 25% crushed waste glass CWG)
of all colours. Lee et al. [67] reported that Metakaolin was more 4. Recycling crushed waste glass in asphalt concrete
effective than fly ash at lower concentrations. Furthermore, Du
and Tan [36] reported that out of fly ash, granulated blast- In 2013, it was estimated that more than 92.53 million tonnes
furnace slag, silica fume, lithium chloride, lithium carbonate and of asphalt concrete were produced around the globe [127]. The lar-
steel fibre, fly ash was the most effective additive at mitigating gest two producers of bituminous concrete are the U.S.A. and
ASR expansion followed by granulated blast-furnace slag. More- China, with 17.57 and 16.27 million tonnes produced, respectively.
over, out of the additives Taha and Nounu [116] tested, metakaolin Table 6 [127] tabulates the asphalt concrete production of the top
was the most effective at suppressing ASR followed by granulated producers globally.
blast-furnace slag then Lithium Nitrate. The effectiveness of fly ash The incorporation of glass in asphalt concrete, otherwise com-
at mitigating ASR was attributed to pozzolanic reactions consum- monly known as glasphalt was first introduced into several inter-
ing the OH ions and Ca ions [97], and electrostatic trapping of national markets in the late 1960s [51,106]. In recent years, more
alkali ions, which is caused by the pozzolanic reaction lowering studies have been conducted to successfully incorporate glass into
the Ca:Si ratio of the pore solution and the CSH gel [39]. asphalt concrete mixtures without detrimental effects on its per-
In addition, the application of the dry-mixed method on mortar formance. Generally, before all tests are conducted, the Marshall
considerably reduced ASR expansions, and was even able to miti- test is used to identify the optimum content of bituminous mate-
gate the ASR expansions created by larger sized and highly reactive rial, glass and other materials used as additives [9,11,54,114,141].
aggregate [67]. Additionally, the optimum contents for fly ash,
granulated blast furnace slag, silica fume, lithium chloride or 4.1. Crushed waste glass as an aggregate in asphalt concrete
lithium carbonate and steel fibre were 10–50%, 45–60%, 12.5%,
0.5–2.0% and 1.5–2.0%, respectively [37]. The effectiveness of fly Different types of waste materials have been studied for the
ash and GGBS was due to their ability to reduce the alkalinity in incorporation in asphalt concrete (e.g., Mohajerani et al. [84]; Para-
the pore solution, and to decrease the permeability and porosity navithana and Mohajerani [91,92]). Hughes [54] used Marshall
of the cement paste [36]. Maraghechi et al. [75] reported that Properties to determine the feasibility of using waste glass (WG)
annealing mortar at temperatures of 650 °C and 680 °C for in asphalt concrete. He compared the control specimen with
40 min reduced ASR expansions below the ASTM threshold at asphalt concrete containing up to 15% WG and concluded that it
454 A. Mohajerani et al. / Construction and Building Materials 156 (2017) 443–467

Fig. 13. Density of asphalt concrete with various percentages of glass [9].

Fig. 14. Stability of asphalt concrete with various percentages of glass [9].

Fig. 15. Voids in mineral aggregates with various percentages of glass [9].
A. Mohajerani et al. / Construction and Building Materials 156 (2017) 443–467 455

Fig. 16. Flow of asphalt concrete with various percentages of glass [9].

Table 7
Tabulated Results [61]

Type of Filler % of filler by weight of total mix Stability (kN) Flow (mm) Bulk Density (gm/cm3)
Ordinary Portland Cement 4% 6.2 2.0 2.48
7% 8.5 3.0 2.5
10% 9.1 3.0 2.54
Limestone Powder 4% 5.6 2.4 2.43
7% 8.9 3.3 2.39
10% 8.6 3.6 2.4
Glass Powder 4% 7.6 3.0 2.4
7% 9.6 2.0 2.28
10% 9.1 2.0 2.2

was indeed possible to incorporate waste glass in asphalt concrete aggregate sizes. The study investigated the stiffness modulus of
mixtures. This was followed by West et al. [140] who tested the asphalt concrete containing glass at replacement levels of 5%, 10%,
effects of substituting 15% of aggregates with either fine or coarse 15% and 20% by weight of mix, at various temperatures 5 °C, 25 °C
crushed glass. The mixtures prepared with crushed glass (CG) had and 40 °C) with different aggregate gradations (Topeka and Binder).
lower Marshall Stability values and dry tensile strengths compared The results indicated that mixes containing 15% glass consistently
to the control mixture. In spite of this, mixtures with coarse glass achieved higher stiffness modulus values compared to other mixes
performed favorably with respect to retained tensile strengths. and obtained a stiffness modulus value almost 200% higher than the
They also observed improved bonding between asphalt binder control mix. A similar investigation was conducted by Arabani et al.
and glass particles with the addition of 0.5% anti- stripping addi- [11] in 2012 where they modeled the long term fatigue behaviours
tive. However, it was determined to be ineffective in reducing of asphalt concrete mixtures with glass replacement levels of 5%,
moisture damage (the asphalt-aggregate bond behaviour exhibited 10%, 15%, and 20% under various temperatures 5 °C, 25 °C and
under wet conditions). West et al. [140] concluded that the substi- 40 °C) with the addition of lime. Cycles of stresses of 250 kPa and
tution of glass for natural aggregates would not be economically 400 kPa were continuously applied to the specimen to determine
feasible unless the asphalt plant and source of CG were within a the relationship between the number of cycles and tensile strain
reasonable distance and recommended that caution should be related to failure. Controlled strain tests were also conducted and
exercised with further applications. the results were compared with the control specimen. Like his pre-
Su and Chen [114] tested the Marshall Stability value for asphalt vious experiments [10], specimens containing glass endured more
concrete with 0%, 5%, 10% and 15% of glass substituting aggregates. cycles compared to the control with the 10% glass specimen exhibit-
They used the Marshall apparatus to test the optimum asphalt con- ing a fatigue life 100% longer than the control specimen. The con-
tent and found it to decrease with increasing glass content. This trolled strain tests showed similar results with the control
observation was explained by the low water/asphalt absorption specimen performing the poorest [11]. In 2014, Androjić and Dimter
rate of glass. The stability tests revealed slightly lower stability val- [9] studied the properties of HMA with substituted WG in the cre-
ues compared to the control mix but they were still within the ation of the surface layers of asphalt concrete. The researchers
limit of the relevant standards. Nicholls and Lay [89] conducted experimented on the addition of glass in asphalt concrete and found
laboratory tests on aggregates with and without 30% CG and com- that an increase in the glass fraction led to a decrease in the density,
pared its properties with the Highways Agency Procedure for Eval- stability, and void content of the mixture. Using these results, they
uating New Materials. Road trials were also carried out at three derived the equations shown in Figs. 13–16.
locations, each having sections of both materials. The trials proved Fig. 13 shows the density of asphalt against the WG content,
the feasibility of replacing 30% of aggregate with CG whilst only Fig. 14 shows the stability of asphalt against the % of WG, Fig. 15
resulting in a marginal reduction in the indirect tensile stiffness. depicts the voids in mineral aggregate against the % of WG and
Arabani [10] evaluated the behaviour of hot mix asphalt (HMA) Fig. 16 shows the flow of asphalt concrete against the % of WG.
at different temperatures with various admixture contents and From the figures above, density showed a tendency to decrease
456 A. Mohajerani et al. / Construction and Building Materials 156 (2017) 443–467

Table 8
Repeated load triaxial test results for recycled glass – crushed rock blends [6]

Blend %MDD %Wopt Permanent strain (103 mƐ) Resilient modulus (MPa)
Stage 1 Stage 2 Stage 3 Stage 1 Stage 2 Stage 3
RG10/CR90 98.1 86.5 22.0 F F 144 NR NR
97.7 81.6 7.5 17.2 F 179 191 NR
97.5 67.0 4.9 6.2 9.9 196 277 263
RG15/CR85 99.2 72.5 18.1 F F 216 NR NR
98.3 70.5 8.6 18.0 F 199 210 NR
97.9 60.9 4.5 8.3 17.6 226 243 243
RG20/CR80 98.9 72.4 14.1 F F 185 NR NR
98.4 67.0 10.6 16.5 F 198 242 NR
98.2 57.3 7.2 12.6 F 209 241 NR
RG30/CR70 98.6 76.3 9.5 F F 224 243 NR
98.5 67.0 8.8 17.4 F 217 250 NR
98 58.6 7.4 12.6 F 227 272 NR
Natural Granular Subbase 98.0 70.0 3–10 4–15 5–20 175–350 200–400 225–400
98.0 80.0 5–10 7–15 10-F 150–300 175–300 200–300
98.0 90.0 7–15 10-F F (>2) 125–300 150–300 175–300

MDD – Maximum Dry Density.


Wopt – Optimum Water Content.
F – The sample failed during the test before reaching next stage.
NR – Not recorded as the sample failed before this stage.

Table 10
Table 9
Shear strength and physical properties of fine recycled glass, medium recycled glass
Gradation of Recycled Glass [33]
and typical quarry materials [13].
Sample Fine content Gravel content Sand content
Engineering Properties Fine Medium Typical
(<0.075 mm) (%) (>2.36 mm) (%) (0.075 < 2.36 mm) (%)
recycled recycled quarry
FRG 5.4 9.2 85.4 glass glass materials
MRG 5.2 53 41.8
Gravel Content (%) 9.2 53 30–60
CRG 0.9 96.4 2.7
Sand Content (%) 85.4 41.8 30–60
Fines Content (%) 5.4 5.2 <10
with increasing percentages of WG. This was attributed to the Coefficient of uniformity, Cu 6.9 7.2 >30
lower density of WG compared to natural aggregates. Stability Coefficient of curvature, Cc 1.2 1.3 >1
USCS classification SW SW GW or SW
increased with increasing percentages of glass, with stability peak-
Specific gravity of coarse 2.44 2.50 >2
ing at 29% before it decreased, which was derived from the equa- fraction
tion: y ¼ 0:0012x2 þ 0:0686x þ 11:604 and R2 ¼ 0:9151. The Specific gravity of fine fraction 2.43 2.46 >2
percentage of voids in mineral aggregate decreased with increasing Water absorption coarse 1.0 0.5 <10
fraction (%)
percentages of glass. This was caused by an increase in the air Water absorption fine fraction 1.8 1.8 <10
voids, which ultimately increased the number of voids filled by (%)
bitumen. The number of air voids depends on the origin of the Los Angeles abrasion (max) 25 25 <35–40
raw material and how it was crushed. The flow of asphalt concrete Modified compaction: max dry 1.78 1.99 >1.78
density (Mg/m3)
showed a tendency to decrease until the percentage of glass
Modified compaction: 10 8.8 8–15
reached 63%, before it started to increase again, which was derived optimum moisture content
from the equation: y ¼ 0:0003x2  0:0379x þ 3:9149 and (%)
California bearing ratio (%) 42–46 73–76 >80
R2 ¼ 0:9653:
Unconfined compression test: 0 0 >0
UCS (kPa)
4.2. Glass powder as a filler in asphalt concrete Direct Shear Test
Peak apparent cohesion (kPa) 0 0 0
In 2011, Jony et al. [61] explored the use of glass powder (93% Peak friction angle (degrees) 41 50 >35
passed through a 0.075 mm sieve) as filler in asphalt concrete as Critical state apparent 0 0 0
cohesion (kPa)
opposed to using the traditional limestone powder and ordinary
Critical state friction angle 41 50 0
Portland cement (OPC) in hot mix asphalt concrete. The investiga- (degrees)
tion involved nine mixtures, three types of filler (lime stone pow-
Triaxial test (CD)
der, OPC and glass powder) and three filler contents (4%, 7%, and Peak apparent cohesion (kPa) 0 0 0
10%, by weight of total aggregate). The test results are shown in Peak friction angle (degrees) 39 42 > 35
Table 7. From Table 7, it is shown that glass powder achieved the Critical state apparent 0 0 0
cohesion (kPa)
highest stability of the three fillers with an optimum of 7% for all
Critical friction angle (degrees) 39 42 > 35
types of filler.

4.3. Performance of asphalt concrete containing crushed waste glass at deformation while low temperatures result in cracking of the pave-
high and low temperatures ment surface. Both these attributes lead to serious deformation of
travelling performance [48]. Diatomite, which is lightweight, has a
A major problem with HMA is its performance at high temper- high porosity and is an effective insulator, has been used to modify
atures and low temperatures. High temperatures result in rutting glasphalt mixtures to prevent rutting and cracking. However, it has
A. Mohajerani et al. / Construction and Building Materials 156 (2017) 443–467 457

been determined that the penetration and ductility of asphalt con- 5. Use of crushed waste glass in the base and subbase of roads
crete decreases [48], and the viscosity of asphalt concrete increases
[27] with an increase in diatomite content. Other issues that Many studies have been undertaken by researchers to deter-
emerge with the inclusion of diatomite in asphalt concrete are a mine the feasibility of incorporating crushed waste glass in the
decrease in the bending stiffness modulus, bending strength and unbound base and subbase of roads. The main tests associated with
bending tensile strain at low temperatures. Therefore, although determining whether a certain material or mixture is considered to
diatomite improves the characteristics of asphalt concrete at high be suitable for base and subbase applications in roads are the Los
temperatures, the characteristics at low temperatures declines Angeles (LA) abrasion test, California bearing ratio (CBR) and mod-
[48]. Guo et al. [48] investigated the use of glass fibres to counter- ified proctor compaction test. Research results in terms of the LA
act these properties and found promising results. The tendency to abrasion value, Modified Proctor test and CBR have generally pro-
rut at both high and low temperatures decreased, while the fatigue ven to be promising for the use of crushed glass (CG) in subbase
property of the asphalt mixture improved. This ultimately resulted applications with up to 30% of crushed rock by mass being replaced
in a longer service life, increased stiffness modulus at temperatures by glass [6].
above 10 °C and caused little influence on the tensile strength. Ali et al. [6] investigated blending <4.75 mm recycled glass (RG)
with 20 mm crushed rock (CR) produced from recycled excavation
stone. RG was mixed with CR to enhance the shear strength prop-
4.4. Stripping erties of the blend. They conducted basic classification, Los Angeles
abrasion, California bearing ratio and modified compaction tests on
Stripping is the weakening or destruction of the bond between blends consisting of 50%RG/50%CR, 40%RG/60%CR, 30%RG/70%CR,
the aggregate and the asphalt [30]. Stripping occurs when water 20%RG/80%CR, 15%RG/85%CR and 10%RG/90%CR. All the mixes
displaces the asphalt on the aggregate particle surface in asphalt obtained LA abrasion values within the range of 23 to 25 and
concrete [102]. Day et al. [30] used ASTM-D-1075 to evaluate the acquired CBR values between 121% and 199%, which satisfied the
effectiveness of anti-stripping agents and Ca(OH)2. They found that local road authority requirements. Additionally, they reported that
commercial anti-stripping agents could not completely eliminate a maximum of 30% RG can replace CR in RG/CR blends to achieve a
stripping. However, the addition of Ca(OH)2 was found to be the satisfactory after compaction gradation curve. Further testing was
most effective method to mitigate the stripping of asphalt con- conducted using the Austroads Repeated Load Triaxial (RLT) test
crete. West et al. [140] tested asphalt concrete containing coarse method to compare permanent strain and the resilient moduli of
glass aggregates and fine glass aggregates using the boil test. The the mixes with natural aggregates. Table 8 lists the results of the
fine glass aggregates were stripped significantly less than the various blends of RG/CR from the RLT tests, and their permanent
asphalt concrete containing the coarse aggregates. Furthermore, strain and resilient values.
the addition of an anti-stripping agent in the asphalt mixes signif- Ali et al. [6] concluded that up to 30% RG could be substituted in
icantly minimized the stripping of samples. Wu et al. [141] found CR for subbase applications, which has minimal effects on the
that by adding hydrated lime and an anti-stripping agent the physical and mechanical properties while satisfactorily meeting
asphalt concrete’s resistance to water damage would increase. local road authority requirements. Furthermore, 15% of RG with a
The anti-stripping agent was found to be more effective than maximum particle size of 4.75 mm can safely substitute Class 3
hydrated lime in mitigating the stripping of asphalt concrete. Fur- classified crushed rock.
thermore, they found that increasing the glass replacement level Disfani et al. [33] investigated the use of three different sizes of
resulted in an increase in stripping weight loss. recycled glass in roadwork applications, Fine Recycled Glass (FRG),

Fig. 17. Water flow balance chart for a layer of RG in road pavement [34].
458 A. Mohajerani et al. / Construction and Building Materials 156 (2017) 443–467

The field trials included two control sections consisting of RCA and
WR, and 7 sections consisting of FRG blends with recycled glass
content varying between 10 and 30%. Arulrajah et al. [12] con-
cluded that FRG blends are not fully compliant with local road
authority requirements but are suitable for pavement subbase
applications. Additionally, an optimum limit for recycled glass
additives replacing RCA or WR was found to be 20% based on the
results from field trials.

6. Environmental impact of crushed waste glass in road


applications

The main environmental concern with the application of glass


in road works is the leaching of contaminants, such as heavy met-
als, into the ground water table. The possible flow path of precip-
itation on a paved surface has been illustrated below by Disfani
et al. [34] in Fig. 17. Disfani et al. studied the environmental risk
of using waste glass in road applications during its service life.
They tested fine recycled glass (FRG) and medium recycled glass
(MRG) for leachable and total concentration for a variety of con-
taminant constituents. The total contaminant values for FRG and
MRG fulfilled the EPA Victoria requirements for fill material and
were significantly below the acceptable thresholds except for chro-
Fig. 18. LCD glass powder [137]. mium. In spite of this, the chromium found in MRG and FRG is not
all chromium VI. This makes FRG and MRG a suitable fill material
according to EPA Victoria requirements and allows it to be used
for filling and leveling applications [42]. The ASLP acidic and alka-
Medium Recycled Glass (MRG) and Coarse Recycled Glass (CRG).
line values of FRG and MRG fall within the threshold for all con-
Table 9 shows the gradations of the different sizes of RG that Dis-
taminant constituents. In addition, the leaching contaminant
fani used.
concentrations for both FRG and MRG samples were well within
The LA abrasion test, CBR and, modified Proctor tests, along
the acceptable limits for solid inert waste. Moreover, the ASLP val-
with various other tests concluded that CRG was not suitable for
ues of FRG and MRG are well below the threshold of hazardous
road applications. MRG and FRG were only deemed suitable if
waste according to the U.S. EPA guidelines. Disfani et al. concluded
blended with other materials which would require further
that the environmental risks of using recycled glass in road appli-
investigation.
cations in terms of contaminants leaching into water streams, sur-
In 2014, Arulrajah et al. [13] tested the physical properties and
face or ground water is negligible.
shear strength responses of recycled construction and demolition
The application of appropriate design and methodology can
materials in unbound pavement base and subbase applications.
mitigate the leaching of contaminants. Recycled glass (RG) should
They conducted the California bearing ratio, direct shear, drained
be used in places with a sealed surface, for example, an asphalt
triaxial, gradation, Los Angeles abrasion and unconfined compres-
paved surface, or in elevated ground. Also, appropriate processing
sion tests on FRG (<4.75 mm) and MRG (<9.5 mm). FRG and MRG
of RG before application can be used to remove contaminants
met the requirements for the LA abrasion, gradation, water absorp-
before they can harm the water table [13,57].
tion, compaction, direct shear test and consolidated drained tri-
Imteaz et al. [57] did a series of tests to determine the environ-
axle tests. However, MRG and FRG failed the CBR requirements
mental impacts of using glass as a pavement material by soaking
with CBR values of 42–46% and 73–76% for MRG and FRG, respec-
three samples of glass in three different solutions, water, 1 mol L1
tively. Additionally, FRG and MRG were unable to satisfy the
HNO3 and 1 mol L1 solution, each with a w/w ratio of 10: 1 solu-
unconfined compression strength requirements due to their inabil-
tion to glass. Using these samples, Imteaz et al. tested the values of
ity to hold together after being removed from their moulds.
Table 10 depicts the shear strength and physical properties of
FRG, MRG and typical quarry materials.
Arulrajah concluded that FRG and MRG have the potential for
being used in unbound base and subbase applications. However,
FRG and MRG would be required to be blended with other higher
quality aggregates to enhance their physical properties, in particu-
lar, LA abrasion and CBR.
This was followed up by Arulrajah et al. [12] in the same year
who conducted field trials and laboratory tests on blends with
waste rock (WR) (<20 mm) and recycled concrete aggregate
(RCA) (<20 mm) replaced with FRG (<4.75 mm). The blends used
in the laboratory testing had WR and RCA replaced with FRG at
percentages of 10%, 15%, 20%, 30%, 40% and 50%. The blends
obtained LA abrasion with values of 23–25 and 25–32 for WR
and RCA blends, respectively, which fulfilled the local road author-
ity requirements. In addition, the blends consisting of FRG met the
local road authority requirements regarding CBR with WR and RCA Fig. 19. Compressive strength of concrete containing 30% ground glass compared to
blends obtaining CBR values of 121–199 and 98–203, respectively. the control [109].
A. Mohajerani et al. / Construction and Building Materials 156 (2017) 443–467 459

Fig. 20. Compressive strength of concrete and mortar containing various amounts of glass powder as a cement replacement, which was acquired from numerous studies after
28 days of curing.

pH, conductivity, inorganic material content including chloride and


sulphate, organics and surfactant. The values obtained were put
against EPA Victoria Guidelines or National Australian Standards
and it was found that all values except for iron content extracted
from the acid sample were below the accepted limits.

7. Crushed waste glass as a cementitious material

The possibility of using finely ground-powdered glass (Fig. 18),


as a pozzolanic material to replace cement was first examined by
Pattengill and Shutt in 1973 [2]. A pozzolanic material should have
a high silica content and a large enough surface area [78]. Carpen-
ter and Cramer [20] reported that powdered glass was effective in
reducing alkali-silica reaction expansions in accelerated mortar bar
tests, and was comparable to the effects of fly ash, silica fume, and
slag on ASR.
Fig. 21. Strength Activity Index for concrete containing 30% mineral additives as a
Multiple researchers noted that waste glass fulfills the basic replacement for ordinary Portland cement [109].
chemical requirements for a pozzolan, but did not comply with
the additional requirement for alkali content since waste glass
has a high percentage of Na₂ O [96,111]. In spite of this, finely that an increase in the replacement level of glass powder in con-
ground glass powder had a very high pozzolanic activity due to crete or mortar mixtures resulted in a decrease in workability.
its Blaine specific surface of 250 m2/kg [96]. Moreover, according The high specific surface areas [78] and the angular shapes of the
to the ASTM C 618 glass has the potential to acceptably function glass particles [109] harmed the workability of concrete and mor-
as a supplementary cementitious material SCM) [45]. tar mixtures.
Producing one tonne of cement consumes approximately 110–
220 kWh of electricity [8] and releases 0.64 tonnes of CO2 [24]. 7.2. Mechanical strength of concrete containing glass as a cementitious
With the global demand for Portland cement expected to increase material
for at least the next 35 years [41], the research focusing on alterna-
tive cementitious materials, such as glass powder, can minimize 7.2.1. Compressive strength
the consumption of natural resources by the construction industry Generally, the inclusion of glass powder as a replacement for
and reduce carbon emissions. cement in concrete and mortar resulted in an increase in compres-
sive strength. However, some studies observed that the inclusion
7.1. Workability of glass powder as a cement replacement resulted in a decrease
in compressive strength [21,117,137]. Additionally, a reduction in
The inclusion of glass powder as a cement replacement in con- the particle size of glass powder coincided with improvements in
crete or mortar resulted in no change in workability [96,115], compressive strength [21,56,96,107,109], Fig. 20.
while Wang et al. [137] observed that mortar obtained similar Bignozzi et al. [17] tested crystal, funnel, fluorescent lamp and
slump values compared to the control with cement replacement soda-lime glass powder as a replacement for cement in mortar.
ratios up to 40%. However, some studies concluded that the All mortar specimens obtained compressive strengths lower than
replacement of cement with glass powder led to a reduction in the control at 90 days except for mortar containing 25% funnel
workability [78,109]. Metwally [78] and Wang et al. [137] reported glass, which achieved a higher compressive strength than the con-
460 A. Mohajerani et al. / Construction and Building Materials 156 (2017) 443–467

trol. Dyer and Dhir [40] partially replaced the cement in concrete In addition, Pereira-de-Oliveira et al. [96] observed that mortar
with white, green and amber glass. They reported that mortars containing amber and green powdered glass with particles sizes
containing 10% white, and 10%, 20% and 30% green glass obtained of 0–45 mm and 45–75 mm fulfilled the requirements set by NP
compressive strengths higher than the control, while mortar con- EN 450 and can be classified as a potential pozzolanic material.
sisting of 10% and 20% amber glass exhibited compressive strength Ismail and Al-Hashmi [60] found that concrete consisting of 20%
values similar to the control. Fig. 19 depicts the development of glass powder as a cement replacement obtained strength activity
compressive strength of concrete specimens containing crushed values higher than the minimum requirements set by ASTM
glass compared to the control. C618-03. The results showed that glass powder is effective at
Shao et al. [109], and Shao and Leboux [107] tested concrete improving the strength of concrete and can be considered as a poz-
with fly ash, silica fume and glass powder as partial replacements zolanic material.
for cement in concrete. They reported that at 90 days concrete con- The effect of curing temperature on the strength activity index
taining 30% 38 mm glass powder obtained compressive strength of mortar and concrete consisting of glass powder was quite signif-
values higher than the control and concrete consisting of 30% fly icant. Shi et al. [111] tested mortars containing GP-4000 and fly ash
ash, but significantly lower than concrete consisting of 30% silica were tested at elevated temperatures of 35 and 65 °C. Mortar con-
fume. Carsana et al. [21] tested the compressive strength of mortar sisting of GP-4000 obtained significantly higher strength activity
with cement replaced with natural pozzolana, ground quartz sand, indexes then mortar at a curing temperature of 23 °C but was
silica fume and coal fly ash. They reported that mortar consisting of lower than fly ash at an elevated temperature. Mirzahosseini and
glass powder exhibited a compressive strength greater than mortar Riding [83] observed that a curing temperature of 50 °C resulted
containing natural pozzolana, quartz sand and coal fly ash at in higher strength activity indexes after 7 days of curing compared
90 days. However, mortar containing glass powder obtained lower to a curing temperature of 23 °C.
compressive strength values than ordinary Portland cement and Moreover, a reduction in the particle size of glass powder
silica at 90 days. Furthermore, Du and Tan [38] found that the addi- resulted in a superior strength activity indexes [21,108,110]. Shao
tion of 15% glass powder in concrete mixtures increased the com- et al. [109] observed that smaller glass particle sizes led to higher
pressive strength values by 32%, 25% and 24% compared to the strengths, especially at later ages. Additionally, they attributed the
control at 7, 28 and 91 days, respectively. early strength development of concrete containing fine glass pow-
The pozzolanic reaction in concrete consisting of glass powder der to the alkalis in concrete acting as a catalyst in the formation of
as a cement replacement improved the pore structure in the bulk calcium silicate hydrate [109]. Fig. 21 depicts the strength activity
cement paste, and interfacial transition zone between aggregate index results for concrete containing 30% mineral additives as a
particles and paste, which increased the compressive strength of replacement for ordinary Portland cement.
concrete [35,38]. In addition, Du and Tan [38] found that there
was an upper limit where at higher concentrations of cement
replacement no further pozzolanic reaction would occur and glass 7.3. Alkali-silica reaction expansions in concrete consisting of crushed
powder would become inactivated inert filler. They reported that waste glass as a replacement for Portland cement
pozzolanic reactions occurred in cement with replacement levels
up to 30%. It can be concluded from the literature reviewed that glass pow-
In contrast, the reduction in compressive strength was attribu- der can be used as cementitious material without causing deleteri-
ted to an increase in porosity due to an increase in effective water ous expansions in mortar or concrete. The inclusion of glass
content and reduction in cement content [87,137]. powder as a cement replacement in mortars and concrete resulted
in ASR expansions lower than the control [96,107,109,116]. An
increase in glass content resulted in a reduction in ASR expansion
7.2.2. Strength activity index in concrete and mortar specimens [78,105,116]. Multiple research-
In general, the inclusion of glass powder as a cement replace- ers found that the expansion of mortars containing glass powder
ment in concrete or mortar can fulfill the requirements set by as a cement replacement was lower than the 0.1% acceptable limit
ASTM C618 or equivalent standards. Shao and Leboux [107], and stated by ASTM C1260 [78,96,107,109].
Shao et al. [109] reported that concrete containing 75 mm and Pereira-de-Oliveira et al. [96] tested mortar consisting of green,
38 mm ground glass fulfilled the minimum requirements set by flint and amber glass powder. They observed that mortar contain-
ASTM C618, which requires a pozzolan to have a minimum ing amber glass expanded the least, while mortar consisting of
strength activity of 75% for it to benefit concrete. Additionally, green glass expanded the most. Shao et al. [109], and Shao and
Metwally [78] found that all the specimens consisting of finely
milled waste glass fulfilled the ASTM C 618-2001 requirements.

Fig. 22. Expansion curves for concrete prisms containing a very reactive coarse
aggregate in combination with the materials indicated (SF10 denotes concrete
containing 10% silica fume as a replacement for Portland cement, GLP40 denotes to Fig. 23. Relationship between 28-day compressive strength and w/c) of concrete
concrete consisting of 40% Portland cement replaced with fine glass powder and containing granulated foam glass. w/c refers to the water to cement ratio of the
with low-alkali cement, HA denotes 1.4% cement alkali) [110]. concrete [69].
A. Mohajerani et al. / Construction and Building Materials 156 (2017) 443–467 461

The partial replacement of ordinary Portland cement with GLP


was effective at mitigating ASR expansion, but studies found that
the inclusion of additives, such as fly ash, metakaolin and lithium
nitrate, was more effective at mitigating ASR. However, studies
reported contradictory results regarding the effectiveness of silica
fume compared to GLP at mitigating ASR reactions.

8. Foamed waste glass

Foamed waste glass is a relatively new material that has been


scantily researched over the last two decades. The lightweight,
low embodied energy and acute friction angle of foamed waste
Fig. 24. Foamed recycled glass as an engineering material.
glass make it a promising material to use in construction applica-
tions [69]. In 2004, Lu and Onitsuka [72] reported that, in Japan,
foamed waste glass was used in construction applications, such
Leboux [107] reported that mortar consisting of 38 mm glass pow- as an improvement material for surplus soft clay, lightweight fill
der expanded less than mortar containing 75 mm and 150 mm glass material, water holding material for greening, subgrade or subbase
powder. Furthermore, they found that silica fume as a cement improvement material and lightweight concrete aggregate.
replacement mitigated ASR expansions more effectively than fly
ash or glass powder. Taha and Nounu [116] tested concrete mixes 8.1. Foamed waste glass as an aggregate in concrete
containing cement partially replaced with 60% ground granulated
blast furnace slag (GGBS), 10% metakaolin (MK), 20% pozzolanic Limbachiya et al. [69] investigated the feasibility of using gran-
glass powder (PGP) (particle size <45 mm) and 1% lithium nitrate ulated foam glass (GFG) in concrete production as a substitute for
(LiNO3). They found that concrete containing additives expanded natural aggregate, by volume. The GFG aggregates used were pro-
less than concrete consisting of glass powder. In addition, MK duced from mixed colour glass bottle waste. Natural gravel was
achieved the lowest expansions followed by GGBS and then replaced by coarse foamed glass (CFG) at replacement levels of
Lithium Nitrate. Shaynan and Xu [110] reported that mortar con- 30%, 40%, 50%, 60% and 100% by volume, while natural sand was
taining 10% silica fume and >20% fine glass powder (GLP) was replaced by fine foamed glass (FFG) at replacement levels of 10%
effective in suppressing ASR expansion. Likewise, mortar contain- and 15%, by volume.
ing 20% GLP was more effective at mitigating ASR expansion than
mortar containing 10% silica fume. In addition, mortar containing 8.1.1. Workability
30% GLP suppressed the ASR expansions of mortar consisting of The workability of fresh concrete was tested in concordance
very susceptible aggregate. Fig. 22 depicts the ASR expansion with BS EN 12350: 2000 Parts 1, 2 and 4, and BS EN 12390: 2000
curves for concrete prisms containing a very reactive aggregate. Parts 1 and 2 requirements. The incorporation of granulated foam
However, Shi et al. [111] found that a minimum of 30% Class F glass (GFG) had no imperceptible effects on the initial slump of
fly ash is required to mitigate deleterious expansion in mortars concrete mixes. However, an increase in GFG content resulted in
consisting of reactive aggregates, while a minimum of 50% a decrease in the compacting factor over time, which was due to
GP4000 is required to achieve the same effect. the high water absorption of concrete containing GFG [69].

Table 11
Engineering properties of foamed waste glass as a lightweight aggregate [49,83,99,100].

Engineering parameters Foamed recycled glass Typical lightweight material [49,83] Typical heavyweight material [99,101]
D10 (mm) 0.13 – 0.09
D30 (mm) 1.2 – 1.30
D50 (mm) 18.7 – 4.40
D60 (mm) 20.6 – 6.70
Cu 158 – 78.83
Cc 0.53 – 2.97
Gravel sized particles: 66 <70 47.9
4.75–40 mm (%)
Sand sized particles: 32 <40 42.2
0.075–4.75 mm (%)
Clay and Silt sized particles: 2 <3 9.90
<0.075 mm (%)
Particle density – coarse fraction (kg/m3) 462.8 408–1529 2600–2700
Particle density – fine fraction (kg/m3) 1508 408–1529 2400–2600
Minimum dry density (kg/m3) 170 112–204
Maximum dry density (kg/m3) 290 204–306 2080
Water absorption – coarse fraction (%) 60 50–60 6.50 – 6.70
Water absorption – fine fraction 0.3 < 1.0 6.50 – 7.50
pH 10.48 9–12 10.20 – 11.40
Organic content (%) 0 0 1.7 – 2.1
CBR (%) 9–12 2–10 172
LA abrasion loss (%) 94 80 – 100 29.9 – 31.7
DST: Peak apparent cohesion, c; (kPa) 23.4 20 – 100 95
DST: Peak friction angle, /’ (degrees) 55.7 35 – 60 65
DST: Critical state apparent cohesion, c’ (kPa) 22.1 20 – 100 95
DST: Critical state friction angle, /’ (degrees) 54.7 35 – 60 39
462 A. Mohajerani et al. / Construction and Building Materials 156 (2017) 443–467

Table 12
Leachate analysis data of foamed recycled glass EPA Victoria [42,129,138].

Contaminant ASLP: acet. ASLP: Borate Threshold for solid inert waste (mg/ Drinking water standards [129] Hazardous waste designation (mg/L)
(mg/L) (mg/L) L) [42] (mg/L) [138]
Arsenic 0.22 0.1 0.35 0.05 5.0
Barium 0.09 <0.1 35.0 2.0 100.0
Cadmium 0.05 <0.02 0.1 0.005 1.0
Chromium 0.09 <0.1 2.5 0.1 5.0
Lead 0.42 <0.1 0.5 0.015 5.0
Mercury <0.001 <0.01 0.05 0.002 0.2
Selenium <0.01 <0.1 0.5 0.05 1.0
Silver <0.01 <0.1 5.0 0.05 5.0

8.1.2. Compressive strength Table 13


Limbachiya et al. [69] tested the compressive strength of con- Fibre content of concrete mixes [142].

crete cubes containing granulated foam glass GFG) according to Concrete Stiff and long polypropylene Short polypropylene fibres
BS EN 12390-3 at 3, 7, 14, 28, 60, 180 and 365 days. Concrete mixes Mixture fibres (LPF) (%) (SPF) (%)
containing 5% and 15% of natural sand substituted for fine foamed No. 1 0.1 0
glass (FFG) and designed with a w/c of 0.40 developed early No. 2 0.2 0
strength more rapidly compared to the control and obtained higher No. 3 0.3 0
No. 4 0.15 0.05
compressive strengths than the control in the long term. Concrete
No. 5 0.1 0.1
consisting of larger proportions of FFG obtained higher compres- No. 6 0.05 0.15
sive strengths, with concrete consisting of 15% FFG achieving an No. 7 0.6 0
approximately 4.72% increase in compressive strength at 365 days. No. 8 0.9 0
No. 9 1.2 0
Limbachiya et al. [69] hypothesized that the pozzolanic reaction of
FFG particles, improved particle packing and porous texture attrib-
uted to the moderate strength improvement of concrete consisting
of FFG. The compressive strength of concrete containing coarse 8.2. Foamed waste glass as a lightweight engineering material
foamed glass (CFG) was strongly related to the CFG replacement
levels and w/c. The compressive strengths of concrete mixes con- Arulrajah et al. [14] investigated the engineering and environ-
taining 30%, 40% and 50% CFG content and designed with a w/c mental properties of foamed recycled glass (FRG) to ascertain its
of 0.62 were all lower than the control. However, concrete mixes suitability as a lightweight fill material in civil engineering applica-
containing 30% CFG content and designed with a w/c of 0.76 tions. The FRG used in the laboratory experiments consisted of 98%
obtained compressive strengths higher than the control at all ground glass and 2% mineral additives.
stages, while concrete consisting of 40% CFG content and designed
with a w/c of 0.76 exhibited higher compressive values than the 8.2.1. Engineering properties
control in the long term. Fig. 23 depicts the relationship between The California bearing ratio of foamed recycled glass (FRG) was
compressive strength and w/c of concrete containing GFG. See within the range of 2–5%, which is typical for structural fill mate-
Fig. 24. rial in road embankments according to the local road authority
(VicRoads) specification requirements [132–134]. The LA abrasion
tests determined that FRG has a low particle strength and conse-
8.1.3. Flexural strength
quently high LA abrasion value of 94%. The LA abrasion results
The flexural strength of concrete containing granulated foam
exceeded the maximum LA abrasion value for pavement base
glass (GFG) was tested in accordance with BS EN: 12390-5:2000.
and subbase applications by 54%, this indicates that FRG is suscep-
Overall, all of the concrete consisting of GFG generally achieved
tible to crushing under repeated loading and inadequate for appli-
higher flexural strengths than the control with 28 day strengths
cations that involve dynamic loads [14].
ranging from 4.6 MPa to 6.2 MPa [69].
FRG’s high friction angle and cohesion values are consistent
with dense gravel materials and meet the shear strength property
8.1.4. ASR expansion requirements for lightweight fill materials [19,113]. The CBR and
Limbachiya et al. [69] tested the ASR expansions of mortar bars LA abrasion tests prove that FRG is unsuitable for heavier loading
containing 30%, 50% and 100% granulated foam glass (GFG) as a applications, such as subbase or pavement base. However, FRG
replacement for natural aggregates in mortar bars according to can be blended with higher quality aggregates to facilitate its usage
ASTM C1260. They reported that increasing the GFG content led in pavement subbase as a supplementary additive. Table 11 sum-
to an increase in ASR expansions. All mortar bars consisting of marizes the engineering properties of foamed recycled glass.
GFG exhibited ASR expansions greater than the control, but less
than the 0.10% expansion limit required by ASTM C1260, except 8.2.2. Environmental properties
for mortar containing 100% GFG at 14 days, which obtained ASR Arulrajah et al. [14] tested the total concentration of trace ele-
expansions marginally higher than the 0.10% limit. The results ments in foamed recycled glass (FRG) and performed leachate
acquired from the ASR accelerated mortar bar tests indicate that analysis for different types of heavy metal according to the Aus-
GFG replacement levels up to 50% in concrete mixes do not cause tralian Standards protocol. The results from the total concentration
potentially deleterious expansion or innocuous behaviour. tests indicated that the contaminant constitutions for FRG were
The results from testing demonstrate that that granulated foam significantly below the threshold limits specified for soil, waste
glass (GFG) has the potential to be a substitute for natural aggre- materials and backfill [65,66,125]. In addition, the arsenic and lead
gate in concrete. GFG can replace up to 40% of coarse aggregate leaching concentrations of FRG came close to the EPA [42] defined
and 15% of fine aggregate in concrete without considerable detri- threshold concentrations. Before the application of FRG samples
mental effects. should be tested for the potential leeching of arsenic and lead.
A. Mohajerani et al. / Construction and Building Materials 156 (2017) 443–467 463

Fig. 25. Compressive strength of ultra-lightweight fibre reinforced concrete mixtures at 28 days [142].

Table 12 contains the data from the leachate data of foamed recy- sion between the concrete matrix and fibres, and can improve
cled glass. the compressive strength of the ULFRC [142]. Yu et al. [142] also
reported that the compressive strength of concrete containing
9. Expanded waste glass in ultra-lightweight fibre reinforced hybrid fibres was highly influenced by the proportions of LPF and
concrete SPF. The ULFRC consisting of 75% LPF and 25% SPF, by volume,
obtained the highest compressive strength out of the mixes con-
Yu et al. [142] investigated the engineering properties of taining hybrid fibres, which was approximately 10.16% higher than
expanded glass in ultra- lightweight fibre reinforced concrete ULFRC containing 25% LPF and 75% SPF, by volume. These results
(ULFRC). They replaced the natural aggregates in the ULFRC with can be explained by Markovic [76] who found that the LPF is more
expanded waste glass, and added polypropylene fibre to enhance effective at mitigating the development of macro cracks, while SPF
the density and mechanical properties of the ULFRC. Stiff and long is efficient at bridging micro-cracks. In addition, the ULFRC speci-
polypropylene fibres (LPF) (length 45 mm, diameter 0.5 mm), and mens containing 0.9% and 1.2% LPF, by volume, obtained compres-
soft and short polypropylene fibres (SPF) (length 18 mm, diameter sive strengths approximately 9.43% and 11.56% lower than ULFRC
22 mm) were added to ULFRC. LPF were added to concrete mixtures consisting of 0.6% LPF, by volume. This reduction in compressive
at 0%, 0.1%, 0.2%, 0.3%, 0.15%, 0.1%, 0.05%, 0.6%, 0.9% and 1.2%, by vol- strength was associated with the LPF pushing apart big particles
ume, while SPF was also added to concrete mixes at 0%, 0.05%, 0.1% and creating air voids within the ULFRC. The compressive strengths
and 0.15%, by volume. Additionally, the Andreasen & Andersen par- obtained from ULFRC specimens tested were higher than light-
ticle packing model was utilized to design the densely compacted weight concrete with the same density from the literature [142].
concrete matrix. In addition, the size fractions of the lightweight Table 13 shows the fibre content in the concrete mixes tested.
aggregates used in this study were 0.1–0.3 mm, 0.25–0.5 mm, Fig. 25 depicts the compressive strength of ultra- lightweight fibre
0.5–1.0 mm, 1.0–2.0 mm, 2.0–4.0 mm and 4.0–8.0 mm. reinforced concrete mixtures at 28 days.

9.1. Density 9.2.2. Flexural behaviour


Yu et al. [142] reported that in order for ULFRC mixtures to
Yu et al. [142] reported that the dry densities of the ultra- obtain good post crack responses in the 4-point bending test, LPF
lightweight fibre reinforced concrete (ULFRC) were less than should be added at percentages higher than 0.6%, by volume.
800 kg/m3, which is the lower limit of the definition of lightweight
concrete set by EN 206-1 (2001). Mix No. 9, which had the highest 9.3. Thermal conductivity
percentage of LPF and attained the lowest densities out of all the
ULFRC tested, with a dry and wet density of 720 kg/m3 and The reports found that the thermal conductivity of ULFRC
790 kg/m3, respectively. They attributed the low densities of ULFRC remains stable with hybridization and variations in fibre amounts.
mixes to the large amounts of fibres within the internal structure. All the ULFRC mixes tested obtained thermal conductivities that
The relatively stiff LPF alters the granular skeleton of the concrete fluctuated around 0.165 W/(m K).
by pushing the surrounding particles (mainly low density LWA). Yu et al. [142] concluded that the low thermal conductivity, low
This forms air voids that are entrapped in the ULFRC, which make density and acceptable mechanical properties make ULFRC an
the concrete porous and reduce its density. The very low density of interesting new material for the production of insulating elements,
ULFRC containing expanded glass enables it to float on water. even load bearing elements and floating structures. When com-
pared to other lightweight concretes with the same thermal con-
9.2. Mechanical properties of ultra-lightweight fibre reinforced ductivity or density the ULFRC developed higher compressive
concrete containing expanded waste strengths of around 16 MPa.

9.2.1. Compressive behaviour 10. Summary and conclusion


The results showed that the addition of polypropylene fibres
improve the compressive strength of ULFRC. The increase in com- Reusing waste glass as a construction material is a promising
pressive strength can be associated with the polypropylene fibres way to lessen the amount of glass disposed of in landfills across
restricting the crack formation and development of the ULFRC. Fur- the globe, reduce the consumption of natural minerals, and mini-
thermore, the rough surfaces of the LPF can strengthen the adhe- mize the carbon footprint and impact of the construction industry
464 A. Mohajerani et al. / Construction and Building Materials 156 (2017) 443–467

on the environment. Crushed waste glass (CWG) has the potential Despite the inconclusive nature of the results, the inclusion of
to be a suitable replacement for aggregate in asphalt mixtures. The CWG in concrete has a huge amount of potential for non-
presence of glass in asphalt mixtures can have negative effects on structural and structural applications. The addition of CWG in con-
the Marshall properties, dry tensile strength, indirect tensile stiff- crete mixes can enhance the mechanical and durability properties
ness and stability of asphalt. In spite of this, a maximum of 15% of concrete, reduce the dead load of concrete structures and offer
of aggregate can be replaced with crushed waste glass in asphalt an environmentally friendly alternative to natural aggregates.
mixes in order to obtain suitable performance and durability of Numerous studies reported that fine glass powder (GLP) is clas-
the pavement. In addition, glass powder, when used as filler in sified as a pozzolanic material. The optimum amount of cement
asphalt, achieved superior stability values compared to ordinary replacement was generally found to be 10%. Generally, the replace-
Portland cement and limestone powder. The stripping of asphalt ment of ordinary Portland cement with GLP resulted in an increase
mixtures containing CWG can be mitigated with the addition of in compressive strength. In general, the strength activity index of
anti-stripping agent or hydrated lime. However, the literature mortar specimens fulfilled the requirements set by ASTM C618,
reviewed observed contradictory results regarding which additive and, in some cases, was higher than the control or specimens con-
was the most effective at mitigating stripping. taining fly ash and silica fume as a cement replacement. Further-
Furthermore, the stability of the asphalt containing CWG can be more, the workability of cement containing GLP was found to be
significantly improved by the addition of lime. In addition, investi- lower than concrete specimens solely consisting of Portland
gations found that CWG can also be mixed with aggregates in sub- cement.
base and unbound base applications. Some researchers found that Additionally, GLP was reported to be effective at mitigating ASR
up to 30% of rock in subbase applications can be replaced with expansions when used as a replacement for ordinary Portland
crushed waste glass (<4.75 mm) aggregates. However, others cement. However, additives, such as fly ash, metakaolin and
noted that fine recycled glass (<4.75 mm) and medium recycled lithium nitrate, were found to be more effective. Moreover, in some
glass (<9.5 mm) aggregates have to be blended with high quality cases GLP was found to be more effective than silica fume as an
aggregates in order to enhance their LA abrasion and CBR values ASR suppressor. The inclusion of GLP as a supplementary cementi-
to sufficient levels before being used in unbound base and subbase tious material in concrete and mortar can reduce construction
applications. Moreover, the leaching of contaminants from CWG in costs since it can replace more expensive materials, such as silica
road applications is negligible. The environmental impacts of all fume, fly ash and Portland cement. Furthermore, the use of GLP
contaminants in asphalt containing CWG were negligible accord- in construction applications can help facilitate the increasing
ing to the EPA Victoria and USA guidelines. However, one study demand for Portland cement.
observed that iron leeching was above the limits set by the EPA In general, the literature focused on testing concrete consisting
Victoria. of soda-lime glass so the results might vary for concrete containing
Crushed waste glass has the potential to be a suitable replace- other types of glass. Additionally, not many studies covered the use
ment for fine aggregate in concrete. The optimum level of fine of other glass types as an aggregate or cement replacement for
aggregate replacement was reported to be around 20%. The results concrete.
from the literature were quite inconclusive regarding concrete Multiple studies reported that foamed waste glass has great
properties, such as workability, compressive strength, flexural potential for use in construction applications. Foamed waste glass
strength, splitting tensile strength, modulus of elasticity, water can be used as an aggregate in concrete, and can replace up to 15%
absorption and chloride-ion penetration. Generally, the results of fine aggregates and 40% of coarse aggregates. In addition,
demonstrated that the compressive strength, flexural strength foamed waste glass can be used as a lightweight engineering mate-
and modulus of elasticity of concrete improved with the inclusion rial in construction applications, such as a fill in embankments,
of CWG. However, the results regarding the splitting tensile retaining wall backfills, pipe bedding and as a supplementary addi-
strength of concrete were contradictory. tive in pavement base/subbase applications. Additionally, the
In general, the workability of concrete mixes containing CWG as inclusion of expanded waste glass in ultra-lightweight fibre rein-
a partial replacement for fine aggregates was lower than for spec- forced concrete (ULFRC) created a material with a low thermal con-
imens containing natural aggregates; however, some researchers ductivity, acceptable mechanical properties, low density and the
found that despite the lower workability the mixes were still rea- ability to float on water. Moreover, ULFRC can be used in construc-
sonably workable. Generally, the inclusion of CWG increased the tion applications, such as insulating elements, load bearing ele-
chloride penetration resistance of concrete, which gives additional ments and floating structures.
protection for steel reinforcement in concrete structures that are
exposed to seawater and de-icing salts. Moreover, the majority of 10.1. Recommendations
literature reported that the water absorption of concrete mixtures
was reduced with the inclusion of CWG. Additionally, the replace- Further research is recommended on the mechanical strength
ment of natural aggregates with CWG in concrete mixtures and durability of glass powders when used as filler in asphalt
resulted in a reduction in concrete density. before its application in the industry. The effect of various glass
The literature reviewed reported that concrete containing CWG types and colours on asphalt mixtures should be investigated thor-
was more prone to ASR expansion compared to regular concrete. oughly in the future.
The particle size, glass colour, glass content and the presence of The testing of the ASR expansions in concrete containing
micro- cracks had considerable effects on the ASR expansions in crushed waste glass (CWG) should be undertaken before its appli-
concrete. The inclusion of additives, such as fly ash, silica fume, cation in the field to ensure that deleterious expansions does not
metakaolin or ground granulated blast furnace slag (GGBS), finely occur. Additionally, the workability of concrete consisting of
ground powdered glass, steel fibre, polypropylene fibre or lithium CWG should be tested prior to its use to ensure sufficient workabil-
compounds, can mitigate ASR expansions in concrete containing ity. Moreover, additional research should be undertaken to clarify
CWG. Out of the additives tested, ground granulated blast furnace the contradictions regarding the properties of concrete containing
slag and fly ash were found to be the most effective at mitigating crushed waste glass as a replacement for fine aggregate, especially
ASR. In addition, by annealing concrete, and by applying the dry- the effects of fine glass aggregates on the water absorption and
mix method ASR expansion in concrete and mortar containing chloride penetration resistance of concrete. Despite numerous
CWG can also be effectively mitigated. studies regarding the use of fine waste glass aggregates in concrete
A. Mohajerani et al. / Construction and Building Materials 156 (2017) 443–467 465

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