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Construction and Building Materials 257 (2020) 119522

Contents lists available at ScienceDirect

Construction and Building Materials


journal homepage: www.elsevier.com/locate/conbuildmat

Review

Recycled aggregate concretes – A state-of-the-art from the


microstructure to the structural performance
Hoai-Bao Le a,b, Quoc-Bao Bui a,⇑
a
Sustainable Developments in Civil Engineering Research Group, Faculty of Civil Engineering, Ton Duc Thang University, Ho Chi Minh City, Viet Nam
b
Mien Tay Construction University, Vinh Long, Viet Nam

h i g h l i g h t s

 Review of investigations on recycled aggregate concretes (RAC).


 Techniques of demolition, recycling and pre-treatment of aggregates.
 Review on mechanical properties and durability of RAC.
 Structural and fire resistances of reinforced RAC structures.

a r t i c l e i n f o a b s t r a c t

Article history: In the context of a circular economy, the recycling becomes more than more important. In the construc-
Received 24 February 2020 tion industry, the wastes from the destructions of old structures are significant. The recycling of the old
Received in revised form 8 May 2020 concretes can contribute to reduce the extraction of the new natural resources (gravel, sand) and to
Accepted 11 May 2020
reduce the waste deposit areas. Numerous studies have already been performed to investigate different
aspects of recycled aggregate concretes (RAC). Several publications have also done the detailed reviews
on certain topics of RAC (such as mechanical properties, mix proportioning); however, still few articles
Keywords:
have done the global synthesis on different aspects of RAC. This paper presents a rapid state-of-the-art
Recycled aggregate concrete (RAC)
Mechanical properties
of numerous topics related to RAC: from the recycling techniques of old-concrete-aggregates, the mix
Reinforced RAC columns proportioning, the mechanical properties, the durability, the structural behavior and the fire resistance.
Reinforced RAC beams The number of existing studies synthesized is relatively important (about 170 publications). The aim
Durability of the present paper is to provide a rapid overview about existing scientific investigations on RAC, which
Fire resistance can offer a good guidance to researchers and engineers who are entering to this area.
Ó 2020 Elsevier Ltd. All rights reserved.

Contents

1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
2. Aggregates obtained from the recycling . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
2.1. Main techniques of demolition. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
2.2. Main techniques of recycling . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
3. Applications of recycled fine aggregates. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
4. Recycled aggregate concretes (RAC) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
4.1. Pre-treatment of recycled aggregates and mixing processing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
4.2. Effects of recycled aggregates on early-age RAC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
4.3. Microstructure of hardened RAC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
4.4. Mechanical properties of RAC. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
4.4.1. Compressive strength . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
4.4.2. Tensile strength . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
4.4.3. Elastic modulus. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6

⇑ Corresponding author.
E-mail address: buiquocbao@tdtu.edu.vn (Q.-B. Bui).

https://doi.org/10.1016/j.conbuildmat.2020.119522
0950-0618/Ó 2020 Elsevier Ltd. All rights reserved.
2 H.-B. Le, Q.-B. Bui / Construction and Building Materials 257 (2020) 119522

4.4.4. Evolution of compressive strength following the time . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7


4.4.5. Peak strain and ultimate strain . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
4.4.6. Stress-strain relationship under uniaxial compression . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
4.5. Shrinkage, creep, fatigue . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
4.5.1. Shrinkage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
4.5.2. Creep . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
4.5.3. Fatigue. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
5. Durability of RAC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
5.1. Risks of steel reinforcement corrosion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
5.1.1. Carbonation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
5.1.2. Chloride penetration. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
5.1.3. Permeability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
5.1.4. Conclusions on risks of steel corrosion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
5.2. Resistance to thawing-freezing cycles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
5.3. Alkali-silica reaction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
5.4. Risk of ettringite and thaumasite formations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
6. Reinforced RAC structures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
6.1. Bonding between steel reinforcement rebars and RAC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
7. Fire behavior of RAC. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
8. Conclusion and prospect . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
Declaration of Competing Interest . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
Acknowledgement . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12

1. Introduction on different aspects relative to RAC: from the recycling techniques


of old-concrete-aggregates, the mix proportioning, the mechanical
Until now, the demolished concrete is usually destinated for the properties, the durability, the structural behavior and the fire resis-
construction of the roads. However, the necessity to incorporate tance. For each aspect, only the fused results obtained from differ-
the recycled aggregates in other applications is rising because in ent studies is presented, which enables to the readers to rapidly
numerous countries, the number of buildings which have been have a global overview about RAC. It is worth noting that this syn-
constructed in the 1950s and 1960s is high (especially in Europe, thesis work is not easy because the results obtained in each study
after the 2nd Word War) which will touch the end of their life; depend to numerous parameters such as: type and quality of
the destruction of these buildings are likely probable because the parent-old-concrete, recycling method, replacement ratios of recy-
demand about the energy performance in the actual norms cle aggregates, strategy for the mix proportioning (considering the
increased, but the energetic renovation on these old buildings are water absorption by the recycled aggregates or not), type and
complicated. Furthermore, in developed countries and in many amount of binder used, using admixture or not,. . . So, for further
developing countries, there are less than less new roads to be con- detailed information, the readers can refer to the cited references.
structed, so the use of recycled aggregates in the roads will be
reduced. Another reason is that other materials or wastes (such 2. Aggregates obtained from the recycling
as natural aggregates of low quality, mix of construction wastes,
non-toxic wastes, . . .) which have less quality than recycled aggre- The wastes of constructions and demolitions are divided into
gates from old concretes can also be used for the road sub-layers; two categories: dangerous and non-dangerous wastes. The danger-
so the recycled aggregates from the old concretes which have bet- ous wastes are such as asbestos or old concretes from the nuclear
ter quality than such wasted materials, should be used for struc- plants. The current investigations concentrate on non-dangerous
tural applications [1]. The recycling of destructed concretes can wastes [8].
on one hand, reduce the exploitation of new natural resources,
and on the other hand, reduce the waste deposit areas, which 2.1. Main techniques of demolition
become an environmental, economic and societal problem [2,3].
The recycling old-concrete to produce recycled aggregates and Different techniques of demolition exist, but there are three
use them to manufacture new concretes (called ‘‘recycled aggre- most current ones. The first technique is the demolition with hand
gate concrete” – RAC) is an approach which has already been inves- tools such as hammer, mallet, pickaxe which can be electric, pneu-
tigated since numerous years. However, one of the most important matic or hydraulic [9,10]; this technique is used for small volumes,
points which slows down the development of this approach in or in the preparation phases of demolition (for example remove the
practice is the cost. Until now, when the natural resources for con- dangerous elements such as asbestos, plomb, . . .); this technique is
crete manufacturing (gravel, sand) is still available for the most of slow and expensive, but enables a better sorting than other
countries on the world, the use of RAC has not yet presented con- techniques.
siderable economic advantages. Nevertheless, in the new context The second current technique is the demolition with mechani-
of a circular economy, where the environmental aspect is high- cal engines, such as balls, pliers, cutters. For high-rise buildings,
lighted, the exploitation of natural resources and generate wastes mini-engines can also be used to destruct the highest stories first,
must be reduced, RAC takes more than more place in the construc- and then other larger engines demolish the structure from the
tion industry [1]. The number of studies existing in literature on ground.
the topic of RAC is high. There have been already several interest- The third technique is the use of blasting, which is a robust
ing review papers or books on this topic [1,4–7]; these publications technique. This technique is applied when the above classical tech-
presented carefully in details for one or several aspects relative to niques are not applicable in reason of the building size or the risk,
RAC. The aim of the present paper is to propose a global synthesis or the low-efficacity of other techniques. This technique is rapid
H.-B. Le, Q.-B. Bui / Construction and Building Materials 257 (2020) 119522 3

but the sorting of wastes after the demolition is more complex concrete is limited, due to its low quality. That is why other alter-
than other techniques. native ways should be found to use the recycled fine aggregate.
Three main solutions are found in the practice:
2.2. Main techniques of recycling
- Recycled fine aggregate is used as alternative raw material in
fabrication of Porland clinker. It was shown that the recycled
There are different techniques for the recycling of wastes from
sand principally constitutes of quartz and calcite, with a minor
construction and demolition, but the current processes generally
presence of feldspars and mica [30]. The experimental tests
compose of the following operations [11]:
from this study also showed that the recycled sand could be
an alternative raw material to produce clinker, with a maxi-
- Elimination of light elements (plaster, wood, plastic etc.) by the
mum substitution ratio of 25% (in mass) and an optimum sub-
sorting systems (manual/pneumatic/hydraulic separators)
stitution ratio of 15%. The obtained clinker had very similar
- Extraction of metal elements by using the magnetic separators
mineral and chemical characteristics to that of the reference
- Crushing, screening to produce compatible desirable materials
clinker.
- Flocculation of clays, for example by floatation technique.
- Recycled fine aggregate is used as a complementary material in
the fabrication of Porland cement (other than clinker). Recycled
A typical recycling platform of recycled aggregates for RAC is
fine aggregate can be used to successfully replace the limestone
following [12]: at the entrance, the wastes are visually inspected,
fillers in the fabrication of cement [31].
sorted by hydraulic excavators and then stocked. The large con-
- Recycled fine aggregate is grinded and used as a filler in con-
crete blocks are reduced by appropriate equipment such as
crete. The results in Cyr et al. (2018) [31] showed that the recy-
hydraulic clamps; the material is then crushed. The metal elements
cled fine aggregate behaved as inert charge or with very low
are retired by a magnetic separator. Finally, the material is
pozzolanic effects (due to the presence of elements from the
screened in several times to obtain the desirable sizes of aggre-
hardened cement paste). When compared to two above options
gates. Some practice platforms may apply simpler processing,
for the use of recycled fine aggregate, this third option is gener-
however several publications proposed different more complex
ally less interesting. However, for each context, an economical
techniques to improve the recycling process, which can be cited:
study should be done to choose the best solution among these
aeraulic sorting for contaminants such as paper, plastic, wood
three options.
[13,14]; rotative sieving for large blocks and large size contami-
nants [15,16]; until three steps of crushing [17]; compressed air
4. Recycled aggregate concretes (RAC)
for the dust liberation [18]; washing for dust liberation [19]; water
jig [20,21]; air jig [22]; sorting by sensors [14,23]; systems for sep-
4.1. Pre-treatment of recycled aggregates and mixing processing
aration of mortar from recycled aggregates [24]; magnetic separa-
tion of mortar and clay bricks [25,26]; manual separation on the
One of the difficulties in the application of recycled aggregate
treatment carpet to eliminate the grand size impurities after the
concrete in practice is the control of recycled aggregate’s water
first crushing [27]. The thermal treatment was also investigated,
content. A high water absorption and heterogeneity of recycled
however this technique is only efficient for temperature from
aggregate causes difficulties to determine the accurate water from
600 °C, which can cause damages for aggregates treated [21].
the formulas [32,33]. Moreover, the water absorption, between the
The recycled aggregate is usually a mix of natural aggregate,
end of mixing and the casting on site, can modify the concrete
hardened cement paste which is generally bonded to natural
workability during the transport. Indeed, it was shown that recy-
aggregate. Therefore, the properties of the recycled aggregate
cled aggregates could absorb between 100 s and 1 h until 5% of
depend on the properties of these two components and their pro-
water of the mixture [34]. To avoid variation of concrete consis-
portion in the original concrete. The recycled aggregate’s porosity
tency, several studies proposed to immerse recycled aggregates
is generally higher than that of natural aggregate, which changes
in water during 10 min to obtain a complete saturation state
significantly the characteristics of recycled aggregates when com-
[35,36], which enables to avoid the water transfer into the recycled
pared to natural aggregate. Indeed, the recycled aggregates have a
aggregates. Effects of the pre-saturation on the recycled coarse
higher water absorption and a lower specific density than natural
aggregate were diverse in different studies; it was noted in several
aggregates. The chemical composition of the combination of natu-
studies that the pre-saturation had few importance on the slump
ral aggregate and hardened cement paste bonded may cause later
values [37]. Kadri et al. (2018) [38] observed that the concrete hav-
some pathologies for the RAC, such as the alkali-silice reaction
ing admixture (superplasticizer or retarder) had better fluidity
[28].
when the recycled aggregates were pre-saturated. The pre-
After the crushing, numerous hardened cement paste fall into
saturation is primordial for the case of recycled fine aggregate
the fine aggregate fraction which causes the important hetero-
which enables to reduce several risks of cracking [39].
geneities in the fine recycled aggregate and increases the water
It is worth noting that the pre-humidification of recycled aggre-
adsorption of the fine fraction (recycled sand). The water absorp-
gates, by fixing a constant water amount added, increases the con-
tion of fine recycle aggregate is about 6–9% while for natural sand,
crete workability but decreases the concrete compressive strength
this value is only about 0.5–2% [28]. Due to the low quality of the
[40,41]. However, Kurowa et al. (1999) [42] showed that the water
recycled fine aggregate, it is not recommended to replace totally
absorbed by the recycled aggregates, before or during the mixing,
natural sand by recycled fine aggregate; several authors proposed
could improve the concrete strength. From these results, the
to mix the natural sand with the recycled fine aggregate which has
Two-Stage Mixing Approach (TSMA) was proposed: 50% of total
a proportion less than 30% [28,29].
water was introduced first to the aggregates, then the cement
was introduced. This two-stage mixing approach enables to
3. Applications of recycled fine aggregates increase about 15% of the compressive strength, about 20–25% of
the tensile strength, and also the durability of concrete (penetra-
The recycled fine aggregate obtained is about 50% after the tion of chloride ions and carbonation) when compared to one-
crushing of concrete recycled, however as mentioned in the previ- stage mixing. The positive effect is explained by an improvement
ous section, the use of recycled fine aggregate directly in a new of the new interfacial transition zone around the recycled
4 H.-B. Le, Q.-B. Bui / Construction and Building Materials 257 (2020) 119522

aggregate grains [43,44]. This two-stage mixing approach could (such as covalent force in the cement matrix) have not yet been
limit several negative aspects for concretes using recycled fine developed. As this capillarity force is weak, it is unstable and the
aggregates [45]. Brand et al. (2015) [46] tested the performance air can start to penetrate in the pores, creating some ‘‘local drilling”
of TSMA on three types of recycled aggregates: oven-dried, par- of the capillarity pressure. When the air starts to fill the big pores,
tially saturated and completely-saturated; the results showed that there is a rearrangement of the particles due to the capillarity pres-
partially-saturated was the most adapted for TSMA. sure – equivalent to a decrease of the volume [53]. When the vol-
Other mixing procedures were also tested. Liu et al (2016) [47] ume diminution is not equal to the volume of water evaporated,
mixed firstly the cement paste, then incorporate the sand and the the cracking appears. Therefore, the air penetration is correlated
gravels, to envelop the aggregates by cement paste; this technique to the cracking [54]. The second phenomenon play the role on
had an intermediary effect on the mechanical properties, between the early-age-cracking is the plastic shrinkage. The elastic modulus
the normal mixing and two-stage mixing approach. Liang et al. of concrete increases rapidly during the early-age while the tensile
(2015) [48] investigated the Sand Enveloped Mixing Approach strength increases slowly, which reduces the capacity of deforma-
(SEMA), by mixing first the natural sand, cement and ¾ total water, tion [55]. The cracking starts when the tensile stresses exceed the
then the aggregate coarse aggregates were added; this technique tensile strength [56]. The recycled aggregates are well known as
enabled to mix easily the sand with cement and water, before that promote the shrinkage and creep of concrete, reduce the compres-
recycled coarse aggregates absorbed water. The results with sand sive strength and the elastic modulus (with a given binder). That is
enveloped mixing technique were better than that with two- why it is not easy to predict the cracking for recycled aggregate
stage mixing. concrete.
The process to envelop the recycled aggregates with cement Roziere et al. (2018) [57] tested two sequences of curing: the
grout in TSMA improved the compressive strength of concrete, that first one is a ‘‘moderate curing” with 50% RH and the wind velocity
was why some other treatment techniques were tested. It was less than 0.3 m/s; the second one is a ‘‘severe curing” with 45% RH
observed that immersing recycled aggregates in a pozzolanic liquid and 8 m/s of wind velocity. The results showed that due to a rela-
could increase the concrete compressive strength, but this tech- tively high porosity, recycled aggregates absorbed the water which
nique had also a negative effect on the workability of fresh con- could be released to the cement paste during the curing. With the
crete [42]. Other studies combined the use of mineral additives moderate curing, the plastic shrinkage could be reduced, thanks to
with the mixing processing, for example the addition of fly ash the ‘‘internal curing” with water released from recycled aggregates
or slag have the positive effects on the compressive strength and [58]. However, under the severe curing, the high evaporation
the penetration of chloride ions when the three-stage mixing tech- increased the shrinkage. It was also observed that the initial satu-
nique is used [49]. Tam & Tam (2008) [50] showed that the combi- ration ratio had a low influence when the total water (water exist-
nation of adding silica fume and the two-stage mixing approach ing in the recycled aggregates + water added) was constant. That is
developed a thick interfacial zone around the recycled aggregate, why a suitable curing is recommended.
therefore increased the compressive strength. Liang et al. (2015)
[48] proposed a pre-treatment to create new cement layers 4.3. Microstructure of hardened RAC
enveloping the recycled aggregates, at 7-days before the concrete
casting, but this technique seems difficult to apply in practice. The recycled aggregates are composed of natural aggregates
Zhan et al. (2015) [51] proposed to pre-treat the recycled aggre- covered by cement paste (or hardened mortar). The presence of
gates with accelerated CO2 curing and limewater soaking process these old carbonated and porous pastes can modify the formation
to strengthen the attached old cement mortar on recycled aggre- of the interfacial transition zones between the aggregates and the
gates. The results showed that after the treatment, the density of cement matrix. To understand these mechanisms, several studies
the cement mortar slightly increased by 5.7%, while the water have been performed to investigate the microstructure of hard-
absorption decreased by over a half, which enabled to increase sig- ened RAC [59,60]. The interfacial transition zone is located at the
nificantly the mechanical properties of RAC (compressive strength interface between the aggregate and the cement paste [61,62]. In
and flexural strength). this zone, a gradient of porosity is observed: the porosity increases
from the cement paste to the aggregate surface. The reason of this
4.2. Effects of recycled aggregates on early-age RAC

The recycled aggregates have specific properties due to the


presence of the old cement paste, porous mortar, impurities such
as plaster, gypsum. When compared to natural aggregates, the
recycled aggregates are lighter, more angular, lower compacity;
more porous, more brittle, a higher water absorption; potentially
reducing efficacity of superplasticizer due to the interaction with
sulfates and impurities. That is why influences of the recycled
aggregates on the behaviour of concrete at early age are important
to be investigated. However, there are less studies on the behavior
of RAC at early-age (especially at plastic state) than at hardened
state.
One of the important phenomena of the early-age concrete is
the cracking. There are different reasons which can generate the
early-age cracking, but the main following reasons can be listed.
The first reason is related to the water evaporation, at very early
time after the casting [52]. The water layers around the particles
disappears progressively with the evaporation; the water menis-
cuses are formed between the particles which create the bonding
between the particles which is a weak force from the capillarity Fig. 1. Classification of aggregates based on the water absorption and the oven-
pressure, because at the very early state, other bonding forces dried density [67].
H.-B. Le, Q.-B. Bui / Construction and Building Materials 257 (2020) 119522 5

impacts if the natural aggregate substituted possesses excellent


or poor mechanical properties. Second, different strategies were
adopted to compare the RAC with different substitution ratios:
the same total water/cement ratio, or the same effective water/ce-
ment ratio, or the same workability which cause the different
effective water/cement ratio. Finally, the conclusions depend also
on the characteristics of recycled aggregates used: form, size,
mechanical properties etc.
From 119 articles published in the literature, Silva et al. (2014)
[67] performed a statistic study and proposed a classification of
recycled aggregates in function of the water absorption and the
dry density (Fig. 1). The recycled coarse aggregates are usually
located in the zones A and B, while the recycled fine aggregates
are usually located in the zones C and D, due to their higher con-
Fig. 2. Statistic result on the influence of replacement level of recycled aggregates tent of cement paste. Then, the authors proposed also a very inter-
on the relative compressive strength, for a same effective water/cement ratio; fcm-
esting figure which was a synthesis about relationship between the
control is the mean compressive strength of referent concrete which uses natural
aggregates; fcm-RAC is the mean compressive strength of RAC [67]. relative compressive strength and the replacement level of recy-
cled aggregates (Fig. 2). This figure shows a general trend when
the replacement level of recycled aggregate increases, the com-
microstructure is that: at the boundary of the aggregates, in the pressive strength decreases, for a same water/cement ratio. This
cement paste, the water content increases and so the cement con- diminution can be amplified if the same cement amount or the
tent decreases. The initial thickness of this zone is several dozens same workability is demanded, because the use of recycled aggre-
of microns. During the curing, the porosity decreases because the gates generally increases the necessary water. The decrease of
hydration products are created, so the thickness of the interfacial compressive strength is explained also because the general
transition zone decreases also. During this period, there is the mechanical properties of recycled aggregates are lower than that
transfers of hydrated product (mainly Porlandites) between the of natural aggregates. Indeed, the natural aggregates are generally
rich cement zones and poor cement zones. obtained from the rocks having compressive strength higher than
With porous aggregates (such as recycled aggregates) which 50 MPa, while the recycled aggregates are obtained by the crushing
have a high water absorption, the mechanisms for the formation of concretes which have compressive strength lower than 50 MPa.
of interfacial transition zones are strongly influenced by the water Therefore, for a same replacement level, if the recycled aggregates
exchanges between the aggregates and the fresh cement paste. For are obtained from a high performance concrete, no significant dif-
light aggregates having macropore networks (from several hun- ference is observed when compared to the natural aggregates [68].
dreds of micron to several millimeters), an initial dry state of The figure confirms that the recycled fine aggregates have lower
aggregates causes an absorption of water during the mixing and mechanical qualities than the recycled coarse aggregates, so the
casting, this water absorption leads to a more compact and more recycled fine aggregates reduced the compressive strength of RAC.
‘‘bonding” interfacial transition zone [59,60,63,64]. For non- Although the figures above are very interesting, they are only
porous aggregates, the similar porosities were observed for over- the results of a statistic study, the models with more scientific con-
saturated aggregates and dry aggregates; however, for the interfa- siderations about different parameters are still necessary for the
cial transition zones between the old cement and the new one, an mix proportioning. Several studies proposed different approaches
improvement was observed when the humid aggregates were used for the mix design and the prediction of compressive strength for
[65]. RAC [69–75]. Among these studies, the model proposed by De Lar-
Garcia-Diaz et al. (2018) [66] investigated also the interfacial rard (1999) [75] which is a modified version of the classical Feret’s
transition zones for RAC, but for normal concretes (grades from model for ordinary concrete had been adopted for RAC and showed
C25 to C35) and higher strength concrete (C45). The results con- its robustness, for the accuracy, the simplicity and the scientific
firmed that the interfacial transition zones obtained for humid significance [74,76,77]. In this model, the mean compressive
aggregates were more porous that that of dry aggregates, due to strength of concrete fcm is determined by:
the release of water from the humid aggregates. However, for
higher strength concrete, where the water/cement ratio was f cm ¼ K g : Rc28 : ½V C = ðV C þ V W þ 0:5V A Þ2 : EMP 0:13
decreased, the water released from the humid aggregates partici- where
pated to the hydration of cement (like a ‘‘internal curing”) which
could reduce also the porosity of the interfacial transition zone. - Rc28 is the characteristic compressive strength of cement paste
at 28 days old.
- VC, VW and VA are the volume of cement, water and air, respec-
4.4. Mechanical properties of RAC tively. The volume of air in the current concretes is about 1–3%
of the total volume.
4.4.1. Compressive strength - EMP is the maximum thickness of the paste (distance between
The most important parameter characterising a concrete is its two big gravels), which is calculated by:
compressive strength. Numerous studies in the literature investi-
gated about influences of the recycled aggregates on the compres-
EMP ¼ Dmax ðg  =gÞ1=3  1
sive strength of RAC. Silva et al. (2014) [67] mentioned 236 articles
on the topic of RAC, among which there were 119 articles investi-
gating on the compressive strength. It was difficult to have the uni- - Dmax is the maximum diameter of aggregates, defined as diam-
vocal conclusions, due to different reasons: First, RAC is usually eter of 90% passing.
compared to reference concretes using natural aggregates, but - g* is the compacity of the aggregate skeleton, which can be
the quality of natural aggregates strongly influenced the conclu- determined by the ratio of the dry density of aggregate skeleton
sions because the same recycled aggregate can have different on the solid density.
6 H.-B. Le, Q.-B. Bui / Construction and Building Materials 257 (2020) 119522

0 :608
- g is the ratio of volume of aggregate skeleton on volume of f ctm ¼ 0:364 ð1  afctm Cm Þðf cm Þ
concrete,
- Kg is the aggregate coefficient which depend on the mechanical where afctm = 0.142; Cm is the replacement level (in mass), which is
properties of aggregates, following their proper strength and the ratio (in mass) between the recycled aggregates on the total
the quality of the bonding between aggregates and cement aggregates (natural aggregates + recycled aggregates).
paste. Kg can be separately calculated for different aggregates
in the mix (natural aggregates, recycled aggregates, fine aggre- 4.4.3. Elastic modulus
gates, coarse aggregates): As mentioned earlier, the recycled aggregates contain the
  cement paste and therefore their elastic modulus is generally less
Kg ¼ R VFj :Kg;j than that of natural aggregates. That is why the elastic modulus
Where VFj is the volumic fraction of the aggregate j considered; of RAC is generally less than that of ordinary concrete.
Kg,j is the aggregate coefficient of the aggregate j considered De Larrard (1999) [75] proposed a tri-spheres based model for
Following Dao et al. (2014) [78], the aggregate coefficient of the determination of elastic modulus of ordinary concrete which
recycled sand can be approximately estimated by a constant value could be adapted for RAC [76]. The mean elastic modulus of con-
Kg,s = 4.42; the aggregate coefficient of recycled gravel can be esti- cret Ecm is determined by:
mated by the formula:
Ecm ¼ f1 þ 2gðEg 2  Em 2 Þ =½ðg  gÞEg 2 þ 2ð2  gÞEg :Em þ ðg þ gÞEm 2 g Em
Kg;g ¼ 0:0952 MDE þ 8:3927
where
Where MDE is the micro-Deval coefficient which specifies the
attrition properties of aggregate, can be determined following - g* is the compacity of the aggregate skeleton, which can be
micro-Deval test (NF EN 1097-1 [79]). determined by the ratio of the dry density of aggregate skeleton
For example, Kg presented in Ghorbel et al. (2018) [76] for nat- on the solid density.
ural sand, natural gravels (4/10 and 6/20) is 5.767; for recycled - g is the ratio of volume of aggregate skeleton on volume of
gravels (4/10 and 10/20) is 5.173. concrete,
This approach is very interesting, not only because it separates - Em is the elastic modulus of cement paste, which can be esti-
the influence of the aggregates, the cement strength, the water/ce- mated from the compressive strength of cement: Em = 226 Rc
ment ratio, but also because one can easily estimate the compres- - Eg is the elastic modulus of the aggregate skeleton; Eg can be
sive strength of RAC when know the compressive strength of the separately calculated for different aggregates in the mix:
reference concrete (using natural aggregates). Indeed, by assuming
that EMP is the same for RAC and reference concrete [76], from the  
Eg ¼ R VFj :Eg;j
de Larrard’s formula, the ratio of Kg-recycled aggregate/Kg-natural aggregate
is also the ratio of fcm-RAC/fcm-control, which is in the intervals of where VFj is the volumic fraction of the aggregate j considered; Eg,j
[0.46–0.62], [0.62–0.79] and [0.79–1] for the aggregates of classes is the elastic modulus of the aggregate j considered
C, B and A, respectively, so one re-obtains the values in Fig. 2. For recycled aggregates, Dao et al. (2014) [78] noted that the
elastic modulus of recycled fine aggregates and recycled coarse
4.4.2. Tensile strength aggregates was close (the difference less than 7%) and proposed a
Several studies showed that the tensile strength of RAC formula to calculate the elastic modulus of recycle aggregates
decreased when the substitution level (of natural aggregates by (Eg,RA) from that of the source concrete (Es) and that of the source
recycled aggregate) increased. This diminution could reach 13% gravels (Egs):
in function of the substitution level [80,81].
A formula to obtain the tensile strength fctm from the compres- Eg;RA ¼ 0:65 Es þ 0:35 Egs
sive strength fcm was proposed by de Larrard (1999) [75] and have
The usual values obtained for Eg,RA were of 35–60 GPa, which is
been validated by numerous studies which showed the good accu-
less than the most of natural aggregates. This observation explains
racy of this formula [76,80]:
why when the replacement level increases, the elastic modulus of
0:57 concrete decreases.
f ctm ¼ kt :f cm
The above model is interesting and provide high accuracies,
where kt is the coefficient which is determined by: kt = Ʃ(VFj.kt,j) however, for the structure design, simpler formulas should be pro-
Several studies [67,82] showed that the above relationship posed for a rapid calculation (with an acceptable higher error).
between the tensile strength and the compressive strength is inde- Numerous empirical formulas were proposed by simplifying the
pendent to the replacement level of recycled aggregates. relationship between the elastic modulus and the compressive
The values of kt,j presented in Ghorbel et al. (2018) [76], Ajdu- strength, but most of them are for ordinary concrete. Ghorbel
kiewicz & Kliszczewicz (2007) [80], were of 0.373–0.471 for natu- et al. (2018) [76] verified the validity of these existing formulas
ral aggregates (in function of the type of aggregate where higher by using the data with 441 values obtained by the authors and
quality provides higher value of kt) and 0.312–0.446 for recycled from the literature. The authors showed that the existing formulas
aggregate, respectively. So the values of kt can vary case by case, proposed for ordinary concretes were not suitable for RAC; they
however, for the studies cited, the value of kt for recycled aggregate proposed a modification to take into account the recycled aggre-
was generally 7–13% less than that of the corresponding natural gates and showed that the modified version of the Wardeh et al.
aggregate. (2015) [84] formula was the most suitable:
To avoid characterizing the values of kt, other empirical formu-
0 :42
las were also proposed for the simplified relationship between the Ec ¼ 17 553 ð1  aEc Cm Þðf cm =10Þ
tensile strength of RAC and its compressive strength. Ghorbel et al.
(2018) [76] did a comparative study to verify the performance of where aEc = 0.131
these formula, then these authors have proposed a modified ver- Cm is the mass replacement level, which is the mass ratio
sion of Omary et al. (2016) [83] formula to obtain the most suitable between the recycled aggregates on the total aggregates (natural
formula: aggregates + recycled aggregates).
H.-B. Le, Q.-B. Bui / Construction and Building Materials 257 (2020) 119522 7

Fig. 3. Influence of the replacement level on the peak strain ec1 (a) and ultimate strain ecu (b) [76].

n o
4.4.4. Evolution of compressive strength following the time ecu ¼ 0:00298  0:0625½ð50  f cm Þ=100
4
ð1 þ 0:2 Cm Þ
The results from Omary et al. (2016) [83] shows that evolution
of the compressive strength is independent on the replacement However, the validity of this formula should be checked with
level and the formula proposed in Eurocode 2 for ordinary con- more experimental data.
cretes can also be applied for RAC:
f cm ðtÞ = f cm ð28 daysÞ ¼ bcc ðtÞ 4.4.6. Stress-strain relationship under uniaxial compression
Ghorbel et al. (2018) [76] adopted the analytical expressions of
n =2
o stress-strain relationship for ordinary concretes under uniaxial
bcc ðtÞ ¼ exp s½1  ð28=tÞ1 compression and tested their relevancy for RAC (data from Omary
et al. 2016 [83]). For example, following Eurocode 2 (2005) [89]:
where s is a coefficient depending to cement type, for example for  
CEM II, s = 0.2. r=f cm ¼ kg  g2 =½1 þ ðk  2Þg
where k = Ec.ec1/fcm; g = e/ec1
4.4.5. Peak strain and ultimate strain
The authors showed that the Eurocode 2 formula could repro-
The peak strain ec1 is the strain corresponding to the maximum
duce the pre-peak behaviour of RAC under uniaxial compression,
stress in uniaxial compression. Numerous studies showed that
while there was more difference for the post-peak behaviour.
when the replacement level increases, the peak strain increases
[83–88].
The ultimate strain ecu is the strain determined at the post-peak 4.5. Shrinkage, creep, fatigue
side, corresponding to the stress equal to 0.6 of the maximum
stress. When the replacement level increases, the ultimate strain 4.5.1. Shrinkage
increases also [83] (Fig. 3). Influences of recycled aggregates on the long term shrinkage of
After a comparative study on different existing formula, Ghor- RAC have been investigated in numerous studies [90–96]. The
bel et al. (2018) observed that the formula proposed by Wardeh results showed that the replacement by recycled aggregates
et al. (2015) [84] was the most suitable to predict the peak strain: increased the shrinkage, from 15 to 60%, in function of the replace-
ment level: until 30% of replacement level, the shrinkage increase
:175
ec1 ¼ 1:1ðf cm Þ0 was limited, and less then 10% in the most of cases; however, when
the replacement level is more than 50%, the shrinkage increase
For the ultimate strain, a formula was also proposed for con- becomes high, which can be 60% in some cases, but in general,
crete having characteristic compressive strength fck  50 MPa, the shrinkage increase is not more than 25% [97]. The increase of
which is a normal grade: shrinkage for RAC is explained by the high water absorption of
the recycled aggregates which are porous and contains the old
cement paste. Brand et al. (2015) [46] investigated the shrinkage
with three pre-saturation levels of recycled aggregate: saturated,
partially saturated (80%) and oven dried. The authors have
observed that during the first 24 h, the pre-saturation did not have
any effect on the shrinkage; however at the long term, the RAC
with pre-saturated aggregates had less shrinkage than that of
RAC with oven dried aggregates.

4.5.2. Creep
The recycled aggregates have also significant effects on the
creep of RAC. Several studies showed that the creep increased
when the replacement level of recycled aggregate increased
[91,93,94,98,99]. Fig. 4 presents the result of Gomez-Soberon
Fig. 4. Specific creep for different recycled concretes at different substitution ratio
(2002) [98] study for the creep under a permanent stress at 40%
r; own creep (continuous lines) and desiccation creep (discontinuous lines). Source: of the compressive strength. The creep of RAC having replacement
Gomez-Soberon (2002) [98]. ratios of recycled aggregate from 20% to 100% is higher from 35 to
8 H.-B. Le, Q.-B. Bui / Construction and Building Materials 257 (2020) 119522

51% respectively, comparing to that of natural aggregate concrete. - The aggregates recycled from the crushed masonries can con-
The basic creep is not significantly affected by the recycled aggre- tain different materials (light concrete, bricks, ceramics, etc)
gate replacement but the drying creep is clearly affected, especially which increases the carbonation thickness.
when the replacement ratio is more than 30%. The results from Fan - When the replacement ratio (of recycled aggregate) increases,
et al. (2014) [100] study showed that the characteristics of the old the carbonation increases. The use of recycled fine aggregates
mortar bonded to recycled aggregates are the source of this creep increases more significantly the carbonation than the recycled
increase. coarse aggregates. Comparing to the control ordinary concrete,
the ratio of carbonation thicknesses varies from 1 to 2.5 for a
4.5.3. Fatigue substitution of coarse aggregate and varies from 1 to 8.7 for a
For the RAC applied for the roads, the fatigue performance is a substitution of fine aggregate.
topic to be investigated. However, this topic is less presented in - It is possible to produce RAC having the same carbonation resis-
the literature than other topics. The fatigue behaviour of concrete tance as ordinary concrete by optimizing the Water/Binder ratio
in compression, tension and bending is usually described by Arora and the nature of binder.
& Singh (2015) [101]:
5.1.2. Chloride penetration
rlogN =r0 ¼ A þ B logN The penetration of chloride ions, with the carbonation, is a prin-
where r0 represents the static strength, rlogN is the stress causing cipal cause of steel reinforcement corrosion. Numerous studies
the failure after N cycles; rlogN/r0 is the endurance of concrete after have been carried out in the literature on this topic [29,44,107–
N cycles; A and B are two empirical parameters, in function of load- 111,116]. These studies showed that:
ing type and concrete type, B is negative.
Different results from Xiao et al. (2013) [102], Sobhan et al. - The diffusion coefficient linearly increases with the replace-
(2016) [103], Arora & Singh (2015, 2016) [101,104] showed that ment ratio of recycled aggregate.
the endurance had the trend to decrease slightly (about 5%) and - The substitution by recycled fine aggregates leads to the chlo-
increase the standard deviation (about 5%) when the replacement ride diffusion coefficients higher than that of substitution by
ratio increased. More data are necessary for the design of the roads, recycled coarse aggregates.
but it seems that the fatigue is not a blocking factor for the appli- - Similar to ordinary concrete, the migration of chloride ions can
cation of recycled aggregates for the road construction. be extenuated by reducing the water/binder ratio, or by using
the blast furnace slag, the fly ash or the silica fume.
- An improvement of the resistance to chloride ion migration was
5. Durability of RAC observed when the fine aggregates recycled from the bricks
replaced the natural sand; the reason could probably be due
The properties related to the durability are usually the risks of to the pozzolanic nature of this material.
steel reinforcement corrosion (carbonation, chloride penetration,
air/water permeability, porosity), the resistance to thawing- Certain studies proposed to use polyvinyl alcohol to improve
freezing cycles (with and without de-icing salt), to alkali-silica the resistance to chloride penetration of RAC [29]. Some studies
reaction and the presence of sulphates (ettringite formation). have found that the chloride diffusion coefficient of their RAC
was similar to that of the ordinary concretes [116,117]. So, a large
5.1. Risks of steel reinforcement corrosion dispersion of results between different studies is observed.

5.1.1. Carbonation 5.1.3. Permeability


The carbonation is a well known phenomenon which induces The permeability is related to the microstructure. The perme-
with the time the risk of corrosion for steel reinforcement. Indeed, ability depends on the porosity, the connectivity of the pores, the
in atmospheric conditions, the CO2 percentage is about 0.4%, when presence of the cracks and the water content of the concrete. As
the CO2 penetrates in the cement paste, the Porlandite is con- the recycled aggregates are porous, and sometime cracked during
sumed and the calcite is created. This phenomenon induces a the crushing, the incorporation of recycled aggregates increases
decrease of pH in the concrete, which changes from 13 to 8–9, so the permeability [118–121]. However, no effect was observed for
the steel reinforcement is no longer protected, then the corrosion the replacement ratio of natural aggregates by recycled aggregates
starts when the quantity of oxygen and water is enough. less than 30% [118].
The carbonation of RAC has been well investigated in the liter- The permeability can be reduced with the following
ature [105–111]. The effects of the recycled aggregate incorpora- parameters:
tion on the carbonation thickness is related to different factors:
- The hardening time: the diminution of the permeability is
- The replacement ratio of recycled aggregates [29,112] related to the prolongation of the hydration processing. With
- The cement amount [78] a low water/cement ratio, a reduction of capillary voids was
- The characteristics of the old concrete from which the recycled observed [108,121]. Similarly, increasing the cement content
aggregates are obtained [110] reduces also the permeability [120].
- The quality of the recycled aggregates (presence of asphalt - The curing condition: the curing in water reduce significantly
materials, bricks, glass, concrete etc.) [111] the permeability, compared to the curing in air [114]
- The type of crushing [96] - The mixing processing: the two-stage mixing approach (the fine
- The curing [113] and coarse aggregates are firstly mixed with a half of water,
- The use of superplasticizer to reduce the Water/Cement ratio then the cement and the rest of water are added) reduces the
[114] permeability, compared to the normal mixing [50].

There are a heterogeneitiy in the results obtained from different 5.1.4. Conclusions on risks of steel corrosion
studies in literature, however the following conclusions were The increase of the substitution ratio increases the porosity of
observed [105,109]: RAC. The porosity accessible to water is an important indicator of
H.-B. Le, Q.-B. Bui / Construction and Building Materials 257 (2020) 119522 9

the durability of RAC. However, this parameter is not enough for an adding expansion due to the formation of an important quantity of
assessment of the risks of steel corrosion. When a thorough inves- secondary ettringite [131]. This ettringite formation needs other
tigation on the corrosion risk is required, it is more relevant to con- specific simultaneous conditions: humid environment; presence
sider at least the chloride diffusion coefficient and the resistance to of aluminates and alkaline possibly in the cement paste; high tem-
carbonation of RAC. The use of these two parameters takes already perature of concrete at early age; etc. It is worth noting that on
into account the porosity. beside of ettringite, the thaumasite can be also created at the
It is observed that the recycled aggregates decrease the perfor- low temperature.
mance of RAC (compared to natural aggregates), due to the poros- To reduce the risks related to the formations of ettringite or
ity and the compacity of the cement paste in the new concrete. thaumasite due by the sulphate reactions, some authors proposed
However, by optimizing the formulation (especially by reducing to limit the maximum content of acid-soluble sulphates for the
the water/binder ratio), although with high substitution ratio, recycled aggregates at 0.3%, [105], while other references propose
one can obtain RAC with the resistances to carbonation and to to limit at 0.8% [132].
chloride diffusion equivalent to that of ordinary concretes [105].
Corinaldesi & Moriconithe (2009) [115] also showed that the addi-
tion of fly ash could be effective in reducing carbonation and chlo- 6. Reinforced RAC structures
ride ion penetration depths in RAC.
6.1. Bonding between steel reinforcement rebars and RAC
5.2. Resistance to thawing-freezing cycles
Among the first studies on the bonding of steel-concrete, Xiao &
Several studies noted that the thawing-freezing resistance of Falkner (2007) [133] performed pull-out tests on RAC with two
RAC is less than that of ordinary concrete [122,123]. However, this types of steel (smooth and ribbed). Different substitution levels
resistance can be improved by using the pre-saturation of recycled of natural gravels by recycled coarse aggregates were chosen (0%,
aggregates (at 100% or 50% of saturation [124]); this result is 50% and 100%). The quantities of sand, cement and cement/water
explained by a possible internal curing of RAC. Kaihua et al. ratio were constant; so the compressive strength of RAC decreased
(2016) [125] showed that the thawing-freezing resistance of RAC when the substitution level increased, like other results presented
closely depended on the properties of the parent concrete recycled. in the previous sections. The results from the pull-out tests showed
The use of air-entrained can also increase the thawing-freezing that when the coarse aggregate substitution increased, the bonding
resistance of RAC, equivalent to that of ordinary concretes [126]. of smooth steel and RAC decreased, however, the bonding was con-
stant for the case of ribbed steels. This result was confirmed later
5.3. Alkali-silica reaction by numerous other studies which used the similar approach (fixing
the binder amount constant) and showed that there was not signif-
The alkali-silica reaction deteriorates the durability of concrete icant difference of bonding for the cases of ordinary concretes and
because it can provoke the cracking and the damages in the struc- RAC [134–140].
ture. The origin of the alkali-silica reaction is a chemical reaction Ghorbel et al. (2018) [141] used another approach by working
between four components which must be simultaneously present on different ordinary concretes and RAC (with different substitu-
in concrete: the reactive silica in the aggregates, a high concentra- tion levels) which had the same compressive strength. The authors
tion of alkaline, the presence of Portlandite, and a relative humidity carried out the pull-out tests and the four-points-bending tests.
(RH) more than 70–80%. The results showed that although the tensile strength of RAC
The recycled aggregate contains two very different phases: the decreased slightly (less than 10%, comparing to the reference ordi-
cement paste bonded and the natural aggregates (sand and grav- nary concrete), there was no significant difference in the bonding
els). The cement paste contains the alkaline elements (generally strength between RAC and ordinary concretes. The authors also
in small amount). The aggregates have different natures, depend- showed that the formula proposed in Eurocode 2 for the bonding
ing on their source; they can potentially contain the reactive strength of ordinary concretes could predict the bonding strength
phases. Therefore, the recycled aggregates can contain important of RAC with satisfying accuracy (differences with the experimental
quantities of soluble alkaline and potentially reactive silica. As results less than 10%).
the aggregates generally represents about 70% volume of concrete,
the use of recycled aggregates presents a potential risk of alkali- a. Reinforced RAC columns
silica reaction, especially the recycled fine aggregates which con-
tains an important part of cement paste [105,127,128]. Although the studies on RAC at the material scale is numerous,
The alkali-silica reaction causes the expansion in concrete. Rou- as cited in the previous sections, the researches at the structural
geau et al. (2018) [105] adopted the criterion of an acceptable scale of RAC structures (such as column, beam) are relatively
expansion which was 0.02% after 5 months for RAC. The authors recent and the number is limited. The investigations on the beha-
worked on aggregates at potentially reactive classes. The results viour of reinforced RAC columns by Liu et al. (2010) [142], Zhou
show that the RAC with 100% of recycled coarse aggregate can sat- et al. (2010) [143], Choi & Yun (2012) [144] can be cited. These
isfy the criterion of expansion. However, the limit of the recycle studies concentrated on non-slender columns (slenderness from
fine aggregate substituted is not more than 30% and an alkaline 4 to 9), with different substitution levels of natural gravels by recy-
content less than 3 kg/m3. cled coarse recycled aggregates; the natural sand was not substi-
tuted. The columns were tested in compression with different
5.4. Risk of ettringite and thaumasite formations eccentricities. The results showed that for ordinary concretes and
RAC having the same compressive strengths, the behaviour of the
One of problems relative to the use of recycled aggregates is the columns was similar for the both cases.
presence of pollutants which can be mortar, plaster, organic ele- Boissière et al. (2018) [145] tested also the non-slender column
ments, chlorides, sulphates, glass, which can decrease the durabil- with RAC (slenderness of 8); however, for their RAC, the natural
ity of RAC [7]. Several studies showed high contents of soluble sand the natural gravels were both substituted by the recycled
sulphates in RAC [129,130]. In the case of a very high soluble sul- aggregates. The compressive strength was the same for all col-
phate content, an internal sulphate attack can occur, leading to an umns. The results showed that for the low substitution ratio
10 H.-B. Le, Q.-B. Bui / Construction and Building Materials 257 (2020) 119522

(30% gravel and 30% sand; or 100% gravels and 0% sand), the beha- forced RAC beams would be more important. Therefore, the
viour was quasi-identical for the columns in ordinary concretes specifications in Eurocode 2 for the exemption of deflection calcu-
and in RAC. However, for the total substitution of natural aggre- lations, which had been proposed for ordinary reinforced con-
gates (100% gravel and 100% sand, especially for the case of 100% cretes, should be revised for reinforced RAC beams.
sand), the structure stiffness decreased significantly. This result is For the cracking of reinforced RAC beams, although Bai & Sun
due to the decrease of the elastic modulus (already discussed in (2010) [147] noted that the incorporation of recycled aggregates
the Sections 4.4.3) which increased the lateral deformations and did not significantly modify the spacing between the cracks, other
the second-order moments. Therefore, the ultimate resistance of studies [148,150–152] have shown that the crack spacing
RAC columns in that case decreased slightly (about 10%). The decreased when the substitution ratio of recycled aggregates
authors also showed that the calculation of the ultimate axial force increased. This result is due to the bonding-strength/tensile-stren
following Eurocode 2 (EN 1992-1-1), with the adapted security gth which is slightly higher for RAC than that of ordinary concrete.
coefficients, could be applied for non-slender reinforced RAC col- Indeed, as presented in the Sections 4.4.2 and 6.1, RAC has similar
umns both for Ultimate Limit State (ULS) and Serviceability Limit bonding strength but lower tensile strength than ordinary concrete
State (SLS). [151]. The crack openings of RAC beams was also observed
The most of studies in the literature indicate that the behaviour decreased when the substitution ratio increased. Mercado-
of non-slender columns in reinforced RAC can be considered the Mendoza et al. (2018) [151] showed that when compared to the
same as reinforced ordinary concrete, when the substitution ratio experimental results, the formulations in Eurocode 2 over-
is not higher than 50% [143,145]. However, for slender columns, estimated the crack openings and crack spacings. The reason was
the differences are more significant because as mentioned earlier, probably due to irrelevant parameters taken for RAC, such as the
RAC has lower elastic modulus and higher creep than ordinary con- tensile strength.
crete, which can increase the second-order moment (causing the The shear behaviour is a complex phenomenon, even for ordi-
buckling) and therefore reduce the ultimate capacity of slender nary concretes. The shear performance of a reinforced concrete
reinforced RAC columns. However, the number of experiments on beam depends not only on the concrete properties, but also on
the slender columns in reinforced RAC is not available in the liter- the steel reinforcements (stirrups and longitudinal steels) and
ature. Fouré (2018) [146] carried out an analytical investigations the beam geometry (especially the effective height). Therefore, to
on the slender columns in which the characteristics were adapted investigate the shear performance of reinforced RAC beams, certain
following the properties of RAC: the stress-strain relationship, the authors choose to investigate the beams with or without stirrups
elastic modulus and the creep. The results showed that for short- [153–158]. The results showed that for a same compressive
term loadings (where the creep phenomenon has not yet strength, the shear strength of RAC beams was slightly lower than
occurred), when compared to the ordinary concrete columns, that of ordinary concrete, but the mechanisms of failure (cracks)
although the second-order moment increased significantly for were the same. The decrease of shear strength in RAC beams is
RAC columns (about 30%, due to a lower elastic modulus), the directly related to the lower tensile strength of this concrete when
resistant ultimate axial force decreased slightly (about 10%) which compared to ordinary concretes. The results also showed that the
could be neglected in the structural design. However, for the long- formula proposed in Eurocode 2 for ordinary concretes could pre-
term loadings (where the creep phenomenon is included), the dict the shear strength of RAC beams. The analyses at the macro-
decrease of the resistant force became non-neglected (about scopic scale showed that while the shear failures in ordinary
25%). Therefore, the author proposed that for the structural design concrete beams occurred at the interfaces between the natural
of reinforced RAC structures, the creep phenomenon should be aggregates and the mortar, the shear failures in RAC beams
carefully taken into account, such as the coefficient A in the calcu- occurred through the recycled aggregates [158].
lation of the limit slenderness (where A = 1/(1 + 0.2uef); with uef is
the creep coefficient).
7. Fire behavior of RAC
b. Reinforced RAC beams
The number of studies investigating the performance of RAC at
The beams are generally verified for the performances against high temperature is still limited [159,160]. When the concrete is
bending moments, shear forces, deflections and cracking (opening heated up, numerous phenomena appear, such as the dilatation
and spacing). The number of studies on the behaviour of beams in of aggregates, the shrinkage of cement paste, the increase of vapor
reinforced RAC is still limited, however, several important results pressure, the cracking or the spalling. The RAC uses not only natu-
were reported in the existing studies. For the bending perfor- ral aggregates but also recycled aggregates which are more porous,
mance, Bai & Sun (2010) [147] Ajdukiewicz & Kliszczewicz have higher water absorption than natural aggregates, and contain
(2007) [149], Arezoumandi et al. (2015) [148], Knaack & Kurama also the hydrates (cement paste). Moreover, recycled aggregates
(2015) [149], Wardeh & Ghorbel (2015) [150], Mercado-Mendoza possess two interfacial transition zones: the first one is between
et al. (2018) [151] showed that the ultimate bending resistance the mortar and the natural aggregates, the second one is between
of the beams did not be affected by the substitution of natural the new cement paste and recycled aggregates [161]. These transi-
aggregates by recycled aggregates; however, the deflections of tion zones are considered as the weak zones of mechanical proper-
beams in RAC increased when the substitution ratio increased, ties [162,163].
due to a lower elastic modulus of RAC than that of ordinary Like ordinary concretes, there are deteriorations in the mechan-
concrete. ical properties when RAC is exposed to high temperature [164–
For the deflection topic, Mercado-Mendoza et al. (2018) [151] 168]. When there is no contaminants in recycled aggregates (wood,
showed that the calculations following Eurocode 2 could repro- asphalt, etc.), the evolution of compressive strength of RAC in func-
duce with satisfying accuracy the experimental deflections mea- tion of temperature is similar to ordinary concretes, however, the
sured, which were at the short-term. To our knowledge, no study tensile strength of RAC decreases more rapidly. The non-
was experimentally investigated on the long-term deflections of cementitious contaminants had negative impacts on the residual
reinforced RAC beams, but with a higher creep of RAC than ordi- mechanical properties of RAC, because when they are pyrolyzed,
nary concrete, it is expected that the long-term deflections of rein- the cracking and porosity are created [169].
H.-B. Le, Q.-B. Bui / Construction and Building Materials 257 (2020) 119522 11

a. Thermal conductivity and specific heat

The conductivity and the specific heat are the thermo-physic


parameters which have important influences on the fire behavior
of RAC. To interpret different phenomena observed during the fire
tests, these parameters must be investigated. Robert et al. (2018)
[160] used the Transient Plane Source technique to measure these
two parameters of different concretes: ordinary concrete with
natural aggregates (0S0G), RAC in which 100% natural gravels
were substituted by recycled coarse aggregates (0S100G), RAC
in which 30% of natural sands and 30% of natural gravels were
substituted by recycled fine and coarse aggregates, respectively
(30S30G). These concretes have the same compressive strength
grade (C25/30). The measurements were performed on the cycles
of heating-cooling. The results are illustrated on Figs. 5 and 6.
Fig. 6. Evolution of specific heat following the temperature, for the heating and
From Fig. 5, it is observed that at the ambient temperature, RAC cooling, obtained by Robert et al. (2018) [160].
have a lower thermal conductivity than the reference concrete.
This difference comes from the higher porosity and the higher
paste content in the RAC, as mentioned in the previous sections.
The second observation is the thermal conductivity decreases b. Thermo-mechanical properties
when the temperature increases. This diminution of conductivity
can be explained by the damage development in the concrete, Robert et al. (2018) performed tests on specimens of 10-cm-
because the residual strength of concretes having suffered ther- diameter and 30-cm-height following recommendations TC 129-
mal cycles is lower than that of unheated concretes. The potential MHT of RILEM [172]. The concrete was of C35/45 grade. For each
mechanisms of damages are: the evaporation of water, because test, the specimen was preloaded at 20% of the compressive
the thermal conductivity of water (0.6 W/(m.K)) is higher than strength at the ambient temperature (20 °C), this preloading was
that of air (0.02 W/(m.K)); the diminution of links due to the kept constant during the heating test. Then, the temperature was
decomposition of hydrates; the microcracking from 300 °C. The increased 1 °C/min until:
conductivity of the reference concrete (0S0G) decreases more
rapidly than that of RAC. This result is similar to other studies - 300 °C then stabilized during 2 h (for the tests at 300 °C),
which showed that concretes having higher conductivity loss - Or 600 °C then stabilized during 1 h (for the tests at 600 °C).
more quickly their conductivity with the increase of temperature Two types of compression tests were performed: tested at high
[170]. Then, the differences of results between heating and cool- temperature and tested in residual state; for the second type, the
ing phases in the Fig. 5 shows a hysteresis which confirms the specimens were let cooled down during 12 h after the stabilisation.
irreversibility, especially that the concretes were really damaged The loading rate for the compression tests was 0.5 MPa/second.
[171]. The results obtained are presented in Fig. 7, which shows the vari-
The results from Fig. 6 show that the specific increases with the ation of the ratio between of the compressive strength at a temper-
temperature increase; the recycled aggregates do not have signifi- ature (fc(T)) on the compressive strength at the ambient
cant influences on the specific heat, although some differences can temperature (fc(20 °C)). Fig. 7 illustrates the decrease of the com-
be note between 500 °C and 600 °C. In the case of specific heat, the pressive strength when the RAC was exposed to the high temper-
hysteresis is significantly less remarked than that of the thermal ature. This result confirms the damages appeared when the
conductivity. So, the increase of specific heat with the temperature concrete suffers to the high temperature, especially from 300 °C.
is related to reversible phenomena. Indeed, the specific heat The figure also shows that the analytical calculations following
depends directly to the atomic vibrations, which is the principal Eurocode 2–1-2 (discontinuous lines) provides the acceptable
mode of thermal energy absorption in the solids. When the tem- results comparing to the experimental ones, in particular for the
perature increases, the energy of atomic vibrations increases, case of silicate aggregates.
which leads to a higher specific heat [160].

Fig. 5. Evolution of thermal conductivity following the temperature, for the heating Fig. 7. The ratio fc(T)/fc(20 °C) in function of the temperature, obtained by
and cooling, obtained by Robert et al. (2018) [160]. experiments and following Eurocode 2. Source: Robert et al. (2018) [160].
12 H.-B. Le, Q.-B. Bui / Construction and Building Materials 257 (2020) 119522

tution ratio for coarse aggregates can reach 100% in many cases,
while for fine aggregates, it is more reasonable to limit the substi-
tution ratio at 30% to satisfy the demand of numerous different cri-
teria, although in many cases, higher substitution ratio (such as
50%) can be successfully applied.
Today, most of recycling processes provides the recycled aggre-
gates which are still covered by old cement pastes and contami-
nants. To obtain a same grade of compressive strength, the
incorporation of these recycled aggregates demands more cement
and admixtures, this problem can strongly influence on the eco-
nomic and environmental competitions of RAC when compared
to ordinary concretes. Therefore, with the current recycling tech-
niques, the reasonable substitution ratios are about 30–40%, even
for recycled coarse aggregates. It is worth noting that the recycled
fine aggregates are less suitable for a high substitution ratio in con-
crete, but they can be used in the processing of cement production.
Fig. 8. Specified furnace temperature in function of time, following EN 1363-1. For the future of RAC industry, different tracks still need to be
investigated and improved:

c. Spalling tests and thermal profile - More efficient methods of aggregate recycling to provide recy-
cled aggregates of better quality, the old-cement-paste should
Interesting spalling tests were presented by Robert et al. (2018):
be separated from the recycled aggregates, the contaminants
four slabs of 4.6-m-length  1.5-m-width  0.2-m-thickness were
should be better eliminated.
tested during 60 min following the standard EN 1363-1 (Fig. 8).
- The new methods should be developed to incorporate the recy-
Two slabs were in ordinary concrete and two others are in RAC.
cled fine aggregates with higher substitution rates.
The spalling was manually investigated (with a rule) after the tests,
- The use of cements of new generation which are ‘‘greener” than
on the surface exposed to the fire. The results showed that the
the current cement. The use of other alternative binders (such
spalling on RAC slabs were slightly more remarked than that of
as geopolymer [173,174]) for RAC to replace cement will be
ordinary concrete slab: about 1–3 cm of spalling-thickness for
interesting to reduce the environmental impacts.
RAC slabs, compared to 0–2 cm for ordinary concrete slabs. How-
- The creep and the fatigue of RAC need more investigations (ex-
ever, the spalling on RAC slabs are local (about 10% of the total sur-
perimental and numerical). The experiments on the structural
face), superficial and does not affect on the mechanical stability of
elements of reinforced RAC are interesting to be continued,
the slabs. The higher water content of recycled aggregates may
especially on the complex domains such as the shear design,
explain the reason of the higher spalling [160]. The results also
the punching behavior.
showed that the application of a numerical code for the fire resis-
tant design following Eurocode 2–1-2 could reproduce with satis-
fying accuracy the experimental behaviour obtained.
Declaration of Competing Interest
d. Fire resistant tests
The authors declare that they have no known competing finan-
The beams (0.3-m  0.4-m of cross-section and 4.2-m-length) cial interests or personal relationships that could have appeared
in reinforced RAC were tested in Robert et al. (2018) [160]. Two to influence the work reported in this paper.
beams (0S100G and 30S30G) were tested in 3-point-bending test
at ambient conditions; two others were tested also in 3-point- Acknowledgement
bending test but after a thermal treatment of 60 min, following
EN 1363-1 (Fig. 8). The results showed that for the beams tested The author would like to thank the European Union’s Horizon
at ambient conditions, the experimental results were slightly 2020 Research and Innovation Programme for the funding under
higher than the analytical calculations following Eurocode 2 (about grant agreement no. 777823.
10%). For the beams tested after the heating, the experimental
results were significantly higher than that following Eurocode 2- References
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