a.

ISOBUTILENO

T 280 C P
T 553.15 K p 20

ij Tcij (K) Pcij (bar) Vcij (cm3/mol) Zcij

11 417.9 40 238.9 0.275

Coeficiente de Fugacidad 𝜙 0.9320 *

𝑓_𝐼 = 18.64 bar

b. ISOBUTILENO

T 280 C P
T 553.15 K p 100

ij Tcij (K) Pcij (bar) Vcij (cm3/mol) Zcij

11 417.9 40 238.9 0.275

Coeficiente de Fugacidad 𝜙 0.7032 *

𝑓_𝐼 = 70.32 bar

 R 83.14 cm3bar/molK

kPa Pr 0.50
bar Tr 1.32

𝜔ij Trij Bij0 Bij1 Bij (cm3/mol)

0.194 1.32364202 -0.18645086 0.0860224152 -147.45659386

P 20

R 83.14 cm3bar/molK

kPa Pr 2.50
bar Tr 1.32

𝜔ij Trij Bij0 Bij1 Bij (cm3/mol)

0.194 1.32364202 -0.18645086 0.0860224152 -147.45659386

P 100
 a. CICLOPENTANO

T 110 C P
T 383.15 K p 5.267

ij Tcij (K) Pcij (bar) Vcij (cm3/mol) Zcij

11 511.8 45.02 258 0.273

Coeficiente de Fugacidad 𝜙 0.9123 *

𝑓_𝐼 = 4.80 bar

b. 1-BUTENO

T 120 C P
T 393.15 K p 25.83

ij Tcij (K) Pcij (bar) Vcij (cm3/mol) Zcij

11 420 40.43 239.3 0.277

Coeficiente de Fugacidad 𝜙 0.7581 *

𝑓_𝐼 = 19.58 bar

 R 83.14 cm3bar/molK

kPa Pr 0.12
bar Tr 0.75

𝜔ij Trij Bij0 Bij1 Bij (cm3/mol)

0.196 0.74863228 -0.58762969 -0.441230487 -637.14185462

P 5.267

R 83.14 cm3bar/molK

kPa Pr 0.64
bar Tr 0.94

𝜔ij Trij Bij0 Bij1 Bij (cm3/mol)

0.191 0.9122619 -0.40578873 -0.113945164 -369.27063776

P 25.83
 a. N-PENTANO

T 36.2 C P
T 309.35 K p 1.01325

ij Tcij (K) Pcij (bar) Vcij (cm3/mol) Zcij

11 469.7 33.7 313 0.27

Coeficiente de Fugacidad 𝜙 0.9668 *

𝑓_𝐼 = 0.98 bar

b. ISOBUTILENO

T -6.85 C P
T 266.3 K p 1.01325

ij Tcij (K) Pcij (bar) Vcij (cm3/mol) Zcij

11 417.9 40 238.9 0.275

Coeficiente de Fugacidad 𝜙 0.9764 *

𝑓_𝐼 = 0.99 bar

c. 1-BUTENO
 T -6.25 C P
T 266.9 K p 1.01325

ij Tcij (K) Pcij (bar) Vcij (cm3/mol) Zcij

11 420 40.43 239.3 0.277

Coeficiente de Fugacidad 𝜙 0.9764 *

𝑓_𝐼 = 0.99 bar

 R 83.14 cm3bar/molK

kPa Pr 0.030
bar Tr 0.659

𝜔ij Trij Bij0 Bij1 Bij (cm3/mol)

0.252 0.65861188 -0.74019961 -0.854766366 -1107.3302221

P 1.01325

R 83.14 cm3bar/molK

kPa Pr 0.025
bar Tr 0.637

𝜔ij Trij Bij0 Bij1 Bij (cm3/mol)

0.194 0.74024886 -0.59982286 -0.469333734 -600.09637071

P 1.01325

R 83.14 cm3bar/molK
kPa Pr 0.025
bar Tr 0.635

𝜔ij Trij Bij0 Bij1 Bij (cm3/mol)

0.191 0.73654762 -0.60532116 -0.482276549 -602.36526502

P 1.01325
 Sistema Etileno(1)/Propileno(2)

T 150 C P
T 423.15 K p 30

ij Tcij (K) Pcij (bar) Vcij (cm3/mol) Zcij

11 282.3 50.4 131 0.281
22 365.6 46.65 188.4 0.289
12 488.28 73.241946 157.966116469656 0.285

Tc12=(Tc11*Tc22)^1/2 Vc12=[((Vc11)^1/3+(Vc22)^1/3)/2]^3

Zc12=(Zc11+Zc22)/2 𝜔12=(𝜔11+𝜔22)/2

Pc12=Zc12*R*Tc12/Vc12 Trij=T/Tcij

𝛿12=2B12 - B11 -B22

𝛿12 20.96 cm3/mol

lnO1=P/RT(B11+Y22𝛿12)

ln𝜙1 -0.0435 𝜙1 0.957 𝑓 ̂_1

ln𝜙2 -0.1283 𝜙2 0.872 𝑓 ̂_2

RESPUESTA Los coeficientes de fugacidad para el etileno y propileno en disolución son de 0.957 y 0.8
 kPa y1 0.35 R 83.14
bar y2 0.65

𝜔ij Trij Bij0 Bij1 Bij (cm3/mol)

0.087 1.4989373 -0.13783042 0.10757771 -59.826833175
0.14 1.15741247 -0.25098841 0.04591533 -159.34940882
0.1135 0.86661342 -0.44763 -0.17480635 -259.10351577

Bij0=0.083-0.0422/Trij^1.6

Bij1=0.139-0.172/Trij^4.2

Bij=R*Tcij*(Bij0+𝜔ij*Bij1)/Pcij

10.04
17.00

o en disolución son de 0.957 y 0.872 respectivamente.

cm3bar/molK
 Sistema Metano(1)/Etano(2)/Propano(3)

T 150 C P kPa
T 423.15 K p 30 bar

ij Tcij (K) Pcij (bar) Vcij (cm3/mol) Zcij 𝜔ij

11 190.6 45.99 98.6 0.286 0.012
22 305.3 48.72 145.5 0.279 0.1
33 369.8 42.48 200 0.276 0.152
12 241.2 47.0051633 120.5334969683 0.2825 0.056
23 336.0 45.2525128 171.3078099766 0.2775 0.126
13 265.5 43.2590823 143.3784693222 0.281 0.082

Tc12=(Tc11*Tc22)^1/2 Vc12=[((Vc11)^1/3+(Vc22)^1/3)/2Bij0=0.083-0.0422/Trij^1.6

Zc12=(Zc11+Zc22)/2 𝜔12=(𝜔11+𝜔22)/2 Bij1=0.139-0.172/Trij^4.2

Pc12=Zc12*R*Tc12/Vc12 Trij=T/Tcij Bij=R*Tcij*(Bij0+𝜔ij*Bij1)/Pc

𝛿12=2B12 - B11 -B22

𝛿12 23.81 cm3/mol 𝛿13 83.04 cm3/mol

lnO1=P/RT(B11+Y22𝛿12)

ln𝜙1 -0.0089 𝜙1 0.991 𝑓 ̂_1 6.24

ln𝜙2 -0.0663 𝜙2 0.934 𝑓 ̂_2 12.04
ln𝜙3 𝜙2

RESPUESTA Los coeficientes de fugacidad para el etileno y propileno en disolución son de 0.957 y 0.8
 y1 0.21 R 83.14 cm3bar/molK
y2 0.43
y3 0.36

Trij Bij0 Bij1 Bij (cm3/mol)

2.22009444 -0.03479263 0.13296373 -11.438504528
1.38601376 -0.16731356 0.09533788 -82.201715571
1.14426717 -0.25714849 0.04134079 -181.56492683
1.75416118 -0.08871224 0.12276559 -34.917324943
1.25935302 -0.20879407 0.07370063 -123.16123731
1.59385733 -0.1171674 0.11472044 -54.984020702

0=0.083-0.0422/Trij^1.6

1=0.139-0.172/Trij^4.2

=R*Tcij*(Bij0+𝜔ij*Bij1)/Pcij

𝛿23 17.44 cm3/mol

olución son de 0.957 y 0.872 respectivamente.