NAME ASSIGNMENT 3 FINALS

CHM 414: Analytical Chemistry

Skoog
Chapter 19
9. Calculate the potential of the following two half-cells that are connected by a salt bridge:
b.) a galvanic cell with two platinum electrodes, the one on the left immersed in a solution
that is 0.0445 M in Fe3+ and 0.0890 M in Fe2+, the one on the right in a solution that is 0.00300
M in Fe(CN)64- and 0.1564 M in Fe(CN)63-.

11. Generate equilibrium constant expressions for the following reactions. Calculate numerical
values for Keq.
b.) Fe(CN)63- + Cr2+ ⇌ Fe(CN)64- + Cr3+

d.) Tl3+ + 2Fe2+ ⇌ Ti+ +2Fe3+

Chapter 20
13. A solution prepared by dissolving a 0.2541 g sample of electrolytic iron wire in acid was
passed through a Jones reductor. The iron (II) in the resulting solution required a 36.76 mL
titration. Calculate the molar oxidant concentration if the titrant used was
b.) Cr2O7 2- (product: Cr3+)

c.) MnO4- (product: Mn2+)

17. A 0.1298 g sample of KBrO3 was dissolved in dilute HCl and treated with an unmeasured
excess of KI. The liberated iodine required 41.32 mL of a sodium thiosulfate solution. Calculate
the molar concentration of the Na2S2O3.

19. A 0.7120 g specimen of iron ore was dissolved and passed through a Jones reductor.
Titration of the Fe(II) produced required 41.63 mL of 0.01926 M KMnO4. Express the results of
this analysis in terms of
(a) percent Fe

(b) percent Fe2O3

Chang and Overby

Chapter 4
NAME ASSIGNMENT 3 FINALS

95. Iron (II) can be oxidized by an acidic K2Cr2O7 solution according to the net ionic equation
Cr2O72- + 6Fe2+ + 14H+ → 2Cr3+ + 6Fe3+ + 7H2O
If it takes 26.0 mL of 0.0250 M K2Cr2O7 to titrate 25.0 mL of a solution containing Fe2+, what is
the molar concentration of Fe2+?

97. A sample of iron ore (containing only Fe2+ ions) weighing 0.2792 g was dissolved in dilute
acid solution, and all the Fe(II) was converted to Fe(II) ions. The solution required 23.30 mL of
0.0194 M K2Cr2O7 for titration. Calculate the percent by mass or iron in the ore.

99. Oxalic acid (H2C2O4) is present in many plants and vegetables. If 24.0 mL of 0.0100 M
KMnO4 solution is needed to titrate 1.00 g of a sample of H2C2O4 to the equivalence point, what
is the percent by mass of H2C2O4 in the sample? The net ionic equation is
2MnO4- + 16H+ + 5C2O42- → 2Mn2+ + 10CO2 + 8H2O