Cambridge International AS Level Chemistry Answers to end-of-chapter questions

Answers to EOCQs
Chapter 1 f 0.2 × 24 = 4.8 dm3 [1]
Total = 10
1 a i The weighted average mass of the atom of
4 a C = 80 20
12 ; H = 1.0[1]
an element on a scale where one atom of
carbon-12 has a mass of exactly 12 units. C = 6.67; H = 20
[1] divide by lowest
ii (18.7 × 10) + (81.3 × 11) = 10.8 [2] C = 6.67 20
6.67 = 1; H = 6.67 = 3 [1]
100
[1 mark for showing masses × % abundance empirical formula is CH3[1]
or 1 error carried forwards from this] b empirical formula mass = 15
b 2[1] 15 × n = 30; n = 2, so molecular formula is C2H6
 [1]
c i 184.2[1]
c Any three explanatory statements from:
ii Fe has several isotopes. [1]
Total = 6 volume of gas proportional to number of
moles;[1]
2 a 262.5[1] mole ratio is 50 : 300 : 200
72 Hf[1] so 1 mol hydrocarbon : 6 mol oxygen : 4 mol
b 180
carbon dioxide. [1]
c i (51.5 × 90) + (11.2 × 91) + (17.1 × 92) + (17.4 × 94) + (2.8 × 96) As 4 moles of carbon dioxide from 1 mole
100
[2] of hydrocarbon, hydrocarbon has 4 carbon
[1 mark for showing masses × % abundance atoms.[1]
or 1 error carried forwards from this] 4 carbon atoms will react with 4 moles of
ii The average mass of an atom of a oxygen molecules, leaving 2 moles of oxygen
particular isotope on a scale in which an molecules (4 moles of oxygen atoms) to react
atom of carbon-12 has a mass of exactly with the hydrogen; [1]
12 units.[1] so 4 moles of water formed, meaning 8
Total = 5 hydrogen atoms in hydrocarbon. [1]
And final deduced equation:
3 a Na2CO3(aq) + 2HCl(aq) C4H8 + 6O2 → 4CO2 + 4H2O[1]
 → 2NaCl(aq) + CO2(g) + H2O(l) 600 = 0.025 mol
[1] d moles propane = 24 000 [1]
b molar mass of sodium carbonate calculated mass = 0.025 × 44.0 = 1.1 g [1]
Total = 10
correctly = 106 [1]
41.5
moles sodium carbonate = 106 = 0.039 mol[1] 5 a 4Na + TiCl4 → 4NaCl + Ti [2]
moles HCl = 2 × 0.039 = 0.078 mol [1] [1 mark for correct formulae; 1 mark for
c The amount of substance that has the same balancing]
number of specified particles / atoms / b 1 mole of TiCl4 gives 1 mole of Ti
molecules, etc. as there are atoms in exactly
189.9 g TiCl4 → 47.9 g Ti [1]
12 g of the carbon-12 isotope (or similar
47.9  g Ti
1.0 g TiCl4 → 189.9
wording).[1]
d i moles sodium carbonate = 1000 25.0  × 0.0200 47.9  g Ti = 95.9 g Ti
380 g TiCl4 → 380 × 189.9 [1]
= 5.0 × 10–4 mol [1] c 4 moles of Na gives 1 mole of Ti
–4 –3
ii moles HCl = 2 × 5.0 × 10 = 1.0 × 10  mol [1] 4 × 23.0 g Na → 47.9 g Ti [1]
1000
concentration of HCl = 1.0 × 10–3 × 12.50 47.9  g Ti
–3
1.0 g Na → 4 × 23.0
= 0.080 mol dm [1] 47.9  g Ti = 24.0 g Ti
46.0 g Na → 46 × 4 × 23.0 [1]
e 0.2 mol [1] Total = 6

Cambridge International AS and A Level Chemistry © Cambridge University Press 2014

 Cambridge International AS Level Chemistry Answers to end-of-chapter questions

6 a i 0.0150 dm3[1] c mass of water is 28.05

56.1  × 18.0 = 9.0 g [1]
ii 0.0200 dm3[1] Total = 5
b 0.0200 × 0.0500 = 0.00100 mol [1] 11

a NH3(g) + HCl(g) → NH4Cl(s)[2]
c 0.00100 mol [1] [1 mark for reactants and products; 1 mark
0.00100 = 0.0667 mol dm–1[1] for state symbols]
0.0150
Total = 5 b NH3 = 17.0 g mol–1[1]
7 a 80.0 (g mol–1)[1] HCl = 36.5 g mol–1[1]
b 0.800 NH4Cl = 53.5 g mol–1 [1]
80.0 [1]
= 0.0100 mol [1] c 10.7
53.5  g NH4Cl = 10.7 = 0.2 mol [1]
c moles nitrogen(IV) oxide = 0.0100 [1] moles of NH3 and of HCl = 0.2 mol [1]
volume = 0.0100 × 24.0 = 0.024 dm = 240 cm3
3
0.2 × 24.0 = 4.8 dm3 of NH3 and HCl [1]
[1] Total = 8
Total = 5

8 a i moles of HCl = 1.20

24.0 = 0.0500 mol [1]
ii
concentration = moles 0.0500 [1]
3 =
volume in dm 0.100
= 0.500 mol dm–3 [1]
25.0
b i 0.500 ×  1000 [1]
= 0.0125 mol [1]
ii moles NaOH = moles of HCl
= 0.0125 mol [1]
volume = moles
concentration
= 0.0125 3
0.200 = 0.0625 dm [1]
Total = 7

9 a moles of Cl2 = 4.80

24.0 = 0.200 mol [1]
b moles of NaOCl = moles of Cl2 = 0.200 mol [1]
mass of NaOCl = 74.5 × 0.200 = 14.9 g [1]
c moles of NaOH = 2 × moles of chlorine
= 0.400 mol [1]
0.400
volume of NaOH = 2.00 = 0.200 dm [1] 3

d Cl2(g) + 2OH–(aq)
 → Cl–(aq) + OCl–(aq) + H2O(l)
[1]
Total = 6

10

a 1 mole of CaO gives 1 mole of CaCl2
56.1 g CaO → 111.1 g CaCl2[1]
28.05 g CaO → 111.1 × 28.05
56.1  g CaCl2
= 55.5 g CaCl2[1]
b 1 mole of CaO reacts with 2 moles of HCl
56.1 g CaO reacts with 73.0 g HCl [1]
28.05 g CaO reacts with 73.0 × 28.05
56.1 = 36.5 g HCl
[1]

Cambridge International AS and A Level Chemistry © Cambridge University Press 2014