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Thermodynamics
Scope
1st Law
Fundamental Fundamental
Property Relation 1 Property Relation 2
Fundamental Property Relations
H = f (S,P)
Fundamental
Property Relation 3 Fundamental
Property Relation 3
Fundamental Property Relations
Fundamental Property Relations
P, T, phase, concentration
First Law:
For H:
Subst. for dU:
Def. of G:
Subst. for dH:
Chemical Potential, µ x 1500
Melting point
Temperature, T
Chemical Potential, µ x 1500
Boiling point
liquid
Temperature, T
Same phase: higher concentration higher µ
High µ Low µ
Gas Vacuum
Chemical Potential: 2 Phases
Liquid N1
1. Fixed T, P: dT = 0; dP = 0
2. Assume equilibrium: dG = 0
Note:
Mixing of nA moles of A and nB moles of B at constant T and P.
, ,
nA Vm,A nB Vm,B
mixing
Partial Molar Properties
𝒊
𝒊 𝑻,𝑷,𝒏𝒋 𝒊
The concept of partial molar quantity can be applied to any extensive state function
Partial Molar Volume