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www.plasticsengineering.org JUNE 2019 | PLASTICS ENGINEERING | 1
CONTENTS
SPME
6
Focus on: Kristina Queen
Meet SPE’s Sales Support Associate, Kristina Queen.
SPE Podcast
8
New Plastics Podcast
PlastChicks: The Voices of Resin 8 Hosted by Lynzie Nebel and Mercedes
Landazuri, the podcast will feature guest
interviews, popular plastics topics, trends
and the people that inspire our industry!
Adulting 101
12
Adulting 101: Social Do’s and Don’ts at
Professional Events
By Lynzie Nebel
Medical 3D Printing
14
3D Printing the Future of Healthcare
By Geoff Giordano
14 A “smart” medication monitoring pill
Additive manufacturing, or 3D printing, is fast-tracking bottle made with Carbon’s MPU 100 medical
developments in the medical device industry. polyurethane.
Design Notes
18
Adapting to Fast-Changing Product Sectors
By Robert Grace
Covestro is designing its materials portfolio to address
needs in mobility, healthcare, energy storage, appliances,
lighting, and other emerging markets.
24
Stabilizing Recyclables Building Greener
Plastics
By Geoff Giordano Additives Produce More
over time. Some additives, however, can enhance the durability and
strength of these sustainable goods time and time again.
About the cover:
Stabilizers help make recycled plastics more durable—process after
process.
Sustainability
28
Almost Like New
By Pat Toensmeier
Recyclers rely on stabilizers to rebuild properties of
reclaimed resins. If PCR demand accelerates, a new
generation of additives could remake the market.
Sustainability
28 Baeropol stabilizers improve melt
32
stability, color, and solubility of polyolefins Prepare for Round Three of the Plastic Waste Trade War
in deck boards and other applications By Doug Woodring & Trish Hyde
After China closed its doors to scrap plastic imports and
Westerners scrambled to find other export targets, diplomats
chew on a proposal to add mixed plastic waste to a list of
materials that require the receipt of a country’s informed
acceptance of this type of trade under the Basel Convention.
As I See It
36
Destination Düsseldorf
By Pat Toensmeier
32 The heady mix of plastic waste, global The K Show in Germany will attract more than 3,000 exhibitors
damage, and national interest has already from 60 countries. Petra Cullmann, Messe Düsseldorf, talks
sparked two sparring matches, and another
about why K 2019 is so important to the industry.
is set to begin.
Departments
38 46 52
Industry News Patents Market Place
In this issue’s roundup Our regular roundup
of industry news, we of notable patents.
explore developments By Dr. Roger Corneliussen
54
from ExxonMobil, and
Editorial Index
50
more. Events
SPE and Partnered
43 Energy-Saving Tip
Extrusion Blow Molding
Conferences, SPE Meetings,
Non-SPE Events and
56
– Insulation Webinars Advertiser Index
By Dr. Robin Kent
BYK, www.byk.com.................................................................................13
Global Sciences Sales Director
Ewikon, www.ewikon.com......................................................................45 Dan Nicholas
ID Additives, www.iDadditives.com........................................................27 Tel: +1 716-587-2181
IMS Company, www.imscompany.com/G27................................... Cover 3 E: dnicholas@wiley.com
J.P. Curilla Associates, email: jpcecl@aol.com........................................52
Shepherd, www.shepherdcolor.com.........................................................5
SPE, www.4spe.org............................................................................. 4, 44
Struktol, www.4struktol.com..................................................................33
shepherdcolor.com
“WE HAVE MADE SOME GREAT CHANGES FOR
ANTEC® 2020 THAT WILL OFFER EXHIBITORS MORE
DEDICATED HOURS AND NEW FOOD & BEVERAGE
EVENTS IN THE HALL. OUR GOAL IS TO INCREASE
THE NETWORKING OPPORTUNITIES AT ANTEC®
AND OFFER MORE TARGETED EXHIBIT HOURS.”
SO, YOU JUST ATTENDED YOUR FIRST ANTEC®. WHAT DID YOU THINK? FAVORITE MEMORY?
I thought it was fantastic! I cannot even remotely begin to count how many trade shows I have worked in the last
10 years in association management, and this one was great! My favorite memory was a dinner I had at a local
brew pub with the SPE staff. This was the first time I had met the SPE team. Everyone was fun and open, and I
felt very comfortable.
sp e
SALES SUPPORT ASSOCIATE...
KRISTINA QUEEN
Sales Support Associate
SPE PODCAST
M: We had already said we were going to do one and M: Right. And I was talking to Steve Russell from ACC
then you pitched it to Pat at the EB meeting. I know for (American Chemistry Council) about these images like
me it was that you had already been on a podcast, so I the turtle with the plastic straw in its nose. A picture tells
had in the back of my head for a long time that I needed a thousand words; they tell a story. And stories are what
to get on a podcast. stay with people—stories are what changes peoples’
minds. So why not replace those images and those
L: Fair enough. stories with new stories that people will remember and
M: And then you got me hooked on the My Favorite which will change the narrative so that it encompasses
Murder podcast, and it was like, “Oh, two girls who talk the whole truth, and nothing but the truth.
about murder. We could be two girls who talk about L: Yeah. That is a very nice way to look at it instead of it
plastics.” just being fueled by my anger.
M: Yeah like, “I spiraled one day and I just wanted peo- M: I think that any publicity is good publicity. Give me
ple to listen to me.” some haters. Give me some mean ones.
L: Like, “I was just really mad and I needed people to L: Alright, then let’s get ready, ‘cause I’m gonna start
understand that they are wrong.” something.
How do you decide the subject matter How do you prepare for a podcast?
of your podcast episodes? Any special prep?
L: It was very much trial and error, because our original M: Well, I for one like to get a full night’s sleep. Like a
two episodes were not the same. It was trying to figure full 14 hours.
out what our audience would want to hear from us with- L: Which starts with you not sleeping.
out making it just straight facts in your face. I think a
lot of that had to do with the people we wanted to have M: Yeah. I dunno. Do you prepare for a podcast?
speak. L: I usually look at their LinkedIn to make sure I have the
highlights, but I kind of prefer a little bit of surprise.
M: I think we’re still deciding what we want the subject
matter to be. M: Yeah. I mean I think our whole friendship has been
preparation for this podcast. I feel good and confident
L: I’m sure we’ll evolve.
about that. Like I don’t really need to do anything else
M: Yes, on a case-by-case basis. On a “we need to do as long as I know how to pronounce our guests’ names.
something now” basis. Any preparation that we do, other than scheduling the
L: Exactly. My favorite way to operate. guests, would be done day-of. If not a couple hours be-
fore, then a few minutes before.
Will the themes (other than plastics) be L: Certainly not our IT. We don’t prep our IT at all. Be-
cause that goes bananas every time.
intertwined?
L: Yeah. What type of guests do you usually
M: We’ll have callbacks to past episodes for sure. look for?
L: And if we’re at SPE events or conferences, that kind M: Most of the people we’ve solicited to be guests we
of drives the subject, and it could vary from what the know through SPE.
speaker has to say.
L: Well, we have a pretty big pot to choose from right
M: Maybe if we get more feedback from our listeners, we now. I could probably name you 10 more people from
could incorporate that. SPE that I want to talk to off the top of my head.
L: Maybe if we get some reviews. But just the nice ones. M: I think we’re looking for guests that have something
I don’t want the mean ones. new and interesting that they are allowed to talk about.
You know, a lot of people in our industry aren’t allowed Best advice you’ve gotten from
to talk about what they’re working on.
someone on doing the podcast?
L: So key. There’s a certain boy that works at a certain
company that would be a very boring interview just M: Did we get any advice?
based on how much we’d have to censor. L: I think most of the advice was, “You’re doing a pod-
M: Yeah. Aww, I hope we get to have him on someday. cast?”
M: Well, Pat Farrey was the only one who told us that
Favorite guest so far? rather than diving into history we should take more of
a forward look on things. Let’s talk about the new hot
L: That could get really mean, couldn’t it? topics, which I think was great advice.
M: Depends who’s reading this. Gosh, I think Eric Larson L: Although our history stories were quite fun. I mean,
because you were just so tired. we were talking about whale bone corsets.
L: I was SO out of my element. M: Well, hopefully we’ll be releasing the original two we
M: Not your area of expertise. did as specials.
L: NO.
M: I was nerding out HARD.
L: You guys were talking about language and origins of
words, and I was just ready to take a nap.
M: I think it’s hard to pick who our favorite guest is.
They’ve all been so wonderful. Did we have a least fa-
vorite guest?
L: Comin’ after you, Jeremy Dworshak! Ha. No, Jeremy’s
was really good. I think we let the ratings decide.
Y
ou can’t swing a business card these days without Another way to move the conversation into a topic you’re
hearing how important networking is to your more comfortable with is to come prepared with a few
career. Sure, that’s great in theory, but how does generic questions. They can be industry specific or just
one actually “network?” There’s the awkward small talk, general small talk questions.
the uncomfortable questions, and the all too important
question of what’s the drinking etiquette. We’ve gathered Relax. At the end of the day, unless you personally
a few pieces of advice to walk you through your next insult someone, the worst-case scenario is that your
networking event so that you can actually enjoy it for the conversation is forgettable. That happens sometimes.
fun opportunity that it is. Find another person and start up a new conversation.
Rinse and repeat throughout the evening until you find a
great conversation.
Wind Power is one of the key technologies of our time. Our high-quality processing additives and
coupling agents make resin infusion more efficient and enable the production of lighter and stronger
composite structures. This leads to more energy-efficient, durable components and also interesting
cost-saving possibilities.
www.byk.com
MEDICAL 3D PRINTING
By Geoff Giordano
T
he escalating adoption of 3D printing (3DP) is conference in Anaheim, Calif., on Feb. 5.
spurring increasing development of new plastics,
some of them specifically for medical and dental “Manufacturers who use plastic for production—molding,
applications. extrusion machining—are finding opportunities and de-
mand to explore using 3D printing, and there is appeal to
In its earlier days, 3D printing, also known as additive having the materials used for 3D printing match up with
manufacturing, relied largely on generic resins developed materials being used for conventional processes,” Kawola
for pre-3DP applications. But as 3DP gains a firmer adds.
foothold in manufacturing beyond the rapid generation of
part prototypes, industry-leading companies are crafting Generally, he says, plastics for 3DP are quite similar at the
plastics for specific medical uses. chemical level to resins for traditional processes. In the
case of filament used in the fused deposition modeling
Plastics companies have begun pursuing collaborations process Ultimaker employs, additives akin to lubricants, as
with these 3DP leaders to invent materials that can be well as others materials, are incorporated to improve
used throughout the entire product development flow during extrusion.
cycle, according to John Kawola, president of
Ultimaker North America. New Material for
a New Part
“Numerous plastics/resin companies have
entered the 3D printing space in the fast few When healthcare giant
years … due to demand from their customers Becton, Dickinson and
and the fact that a portion of the equipment Co. of Franklin Lakes, N.J.,
market is now open to third-party materials,” needed an alternative to
says Kawola, interviewed a few weeks before injection molding to make a
his scheduled discussion of these trends at critical component of a gene-
the Medical Device and Manufacturing West analysis system, Carbon of
Redwood City, Calif., had the
answer.
and create an overlapping continuum of material. working on the BD Rhapsody single-cell genomic analysis
system, one of the toughest parts to produce was the
In September, the company introduced a new material hemocytometer adapter. The microfluidic holder is made
for life sciences applications called MPU 100, a medical up of numerous square recesses set at 90º angles and
polyurethane. requires trapped negative space for the slide holder,
undercut structures, and a window for optics.
One struggle in growing adoption of its resins for medical
manufacturing was that they were black to facilitate With this system, genomic sequencing can be done cell
Carbon’s photochemical process, explains Steven Pollack, by cell. “You’re not just taking a tumor or other biopsy
Carbon’s senior staff research scientist. “When you use sample and averaging the genomics over all the cells of
light as your chisel, you’d like to be able to control how the sample,” Pollack explains. The BD system isolates cells
deep the light gets into the part—and black is a great in the hemocytometer adapter’s microwells, each of which
light-stopping pigment.” is bar coded. The adapter then slides into the reader.
MPU 100 took about a year to develop and addressed Given the limited number of adapters that made to be
concerns such as use in a surgical environment, where made, 3D printing was the ideal process. And MPU 100
healthcare personnel would not know if a black-pigment was the perfect material. “It’s got the right mechanical
device had been cleaned or not. Once this new white resin properties, surface feel and texture,” Pollack notes.
was developed, Carbon sent it to BD to see what they
could achieve with it. BD and Carbon experts worked together to refine the part’s
design to minimize resin use and maximize print speed.
More importantly, MPU 100 possesses the temperature Rotating the honeycomb structure by 45º, for instance,
made the walls self-supporting and reduced resin usage
and solvent resistance, smooth surface and non-porous
by 7 percent per build. A custom print script reduced print
properties ideal for a hospital setting, unlike other resins
time by 55 percent.
3D printed with photochemistry.
Ultimately, the project was successfully completed from
“In our dual cure concept, we use photochemistry to create development to part production using the same Carbon
the shape, then use a thermosetting chemistry to create printers. Injection molding the part would have entailed
the mechanical properties,” Pollack says. “After the part prohibitive costs for complex molds to produce about
is built, you bake it—and that baking essentially turns on 1,000 parts a year.
a thermosetting reaction. You can make a polyurethane,
a polyepoxy, a silicon chemistry. MPU has a latent MPU 100 has also been used by Biolase of Irvine, Calif., as a
polyurethane chemistry; baking turns it on, and it goes replacement material for cast urethane parts and reduced
from a material that is mechanically weak to a material by 70 percent the time between design and final part.
with the mechanical properties of ABS or unfilled nylon.”
suited for 3D printing to perfectly customize implants and working toward creation of the final product,” he notes.
surgical guides for patients. “With 3D printing—specifically the NextDent solution—
the entire process can be accomplished up to four times
3D Systems of Rock Hill, S.C., has bet big on demand for faster than other available solutions while reducing
digital dentistry, launching the NextDent 5100 printer material waste and capital equipment expenditure as well
in 2018 to accompany its portfolio of 30 dental resins. as reliance upon milling centers.”
Offered in a range of colors, the resins can be used by
dental labs and clinics to closely match patients’ teeth and At press time, 3D Systems was planning to add NextDent
gums. Denture 3D+ to its dental repertoire by the first quarter
of this year. The material, aimed at producing removable
“All of our NextDent materials are biocompatible as well dental bases, could secure Class IIa certification by March.
as FDA listed and CE-certified, making them suitable for a “This material has significantly lower shrinkage compared
wide range of prosthodontic and orthodontic applications,” to standard denture base materials resulting in production
says Rik Jacobs, vice president and general manager for of excellent-fitting denture bases,” Jacobs says.
3D Systems dental operations.
Continued development of dental-specific 3DP resins is
Several of the company’s dental resins have earned Class not only a function of manufacturing efficiency but patient
IIa certification, which Jacobs says means that “for the first safety, Jacobs adds. Allergic reactions are a danger.
time in dental history” multiple long-term applications such
as splints, denture bases, crowns and bridges can now be “The biggest challenge experienced with traditional
manufactured for long-term use in the oral photopolymer resins are allergic
cavity using 3D printing technology. reactions resulting from cytotoxicity,”
he explains. “When a traditional
“NextDent Ortho Rigid material enables dental photopolymer reacts with a
production of splints for long-term use patient’s saliva, the resin can begin
in the patient’s mouth,” Jacobs explains. to break down and release monomers
“NextDent Base material was specifically (the individual molecules that create
developed for the printing of denture the photopolymer). These monomers
bases.” Mostly recently, NextDent C&B MFH can cause soreness and a burning
(Micro Filled Hybrid), developed to produce sensation in the mouth.”
crowns and bridges with high strength and
wear resistance, received the certification. 3D Systems’ new dental biocompatible
photopolymers are monomer-free
Increased manufacturing speed and and being validated with testing
minimizing human error are key drivers institutions. “From early results, we
in developing these new resins, Jacobs anticipate almost no allergic reactions
explains. For example, it can take 14 hours to the materials.”
of lab work to go from an initial impression
Carbon, too, has seen a surge in
of a patient’s mouth to a final set of
dental demands for new additive
dentures. After that, models are shipped
materials, Pollack notes. Dental
back and forth between the lab and
applications have grown to such an
dentist’s office. Patients make an average
extent that Carbon has broken out
of five visits to be fitted for the device,
a growing team specifically to meet
Jacobs adds.
those needs.
“The process also results in significant “We are seeing a huge uptick in
material waste in the form of plaster and wax adoption of our machines in dental
that is used in all iterations of the models laboratories by the people who
fabricate things like dental models,
surgical guides for patients
The NextDent 5100 high-speed 3D who need implants, and more
printer from 3D Systems is pow- recently a huge growth in
ered by Figure 4 technology com- digitally fabricated dentures
bined with the broadest portfo- at lower cost than typical
lio of dental materials. Courtesy devices,” Pollack explains.
of 3D Systems
Plastics in the dental space are “a very odd thing,” he says, qualified and tested for these materials.”
because the FDA regulates the liquids or solids that become
devices. Generally, the FDA regulates the final product. That collaboration is helping bring new investment and
(Pollack came to Carbon after 10 years running the FDA’s brain power from more established plastics and chemicals
Office of Science and Engineering Laboratories.) giants like BASF, Dupont, Clariant, and SABIC into the
heretofore more insular world of 3DP startups.
Carbon has partnered with a number of companies that
have developed 3D-printable resins and has validated “3D printing has matured over the years without the
those resins to work on Carbon machines to produce participation of the large plastics companies,” Kawola
dental models. Those companies includes Dentca of explains. “The nature of closed hardware platforms meant
Torrance, Calif., and its denture resins; Germany’s Dreve that these companies were rarely part of the ecosystem.
and its gingiva guide; and Whip Mix of Louisville, Ky., and
Now that the market is more open, we are starting to see
its surgical guide-compatible resin.
much faster innovation and application development.
In the past, the 3DP hardware companies had materials
“We’ve opened the resin store for third-party resins in the
dental space,” Pollack concludes. science capability and developed their own materials.
These products were good, but the scope of investments
and the collective people working on it in the industry was
Future Applications limited.”
While 3DP is gaining ground in numerous industries,
traditional manufacturing processes dwarf its impact. But With 3DP, “simulation is evolving and processes are
Ultimaker’s John Kawola foresees huge opportunity in the improving,” he says. “The goal is that engineers in the
next five or more years. future will be able to accurately predict and design the
(material) properties required.”
“If you take just take one segment—medical devices—
including all the plastic components being used in probes
or medical equipment or other such equipment, the
percentage being produced using 3DP in the world today ABOUT THE AUTHOR
is much less than 1 percent in terms of end-use parts,”
he explains. Injection molding output, by comparison, is Geoff Giordano has been a contributor to
Plastics Engineering since 2009, covering
worth “hundreds of billions of dollars of plastic parts… a range of topics, including additives,
That’s why most of us are optimistic that there’s real infrastructure, flexible electronics,
opportunity (to grow 3DP) from 1 percent to 5 percent.” design software, 3D printing and
nanotechnology. He has served as editor-
in-chief of numerous industry magazines
To that end, Ultimaker has started a Materials Alliance and is founder and chief creative officer
Program with a number of plastics companies. “We have a of content marketing firm Driven
platform that allows quick development of the parameters Inbound. He can be reached at geoff@
and profiles that are needed for specific materials,” Kawola driveninbound.com.
By Robert Grace
A
s a supplier of advanced polymer materials, That said, he notes, the
Covestro finds itself on the front lines of numerous growth ventures portfo-
emerging and evolving industries. Work must lio functions like an incu-
be done to stay one step ahead of both customer and bator and helps the busi-
consumer needs. ness in question grow till
it reaches a critical mass.
Recent interviews with three of the group’s business
leaders shed light on key industry trends and on where Serving the
they see some of the best growth opportunities in the
Connected-
foreseeable future. Two of those executives—Shanghai-
based David Hartmann and Leverkusen, Germany- Healthcare Space
based Phillip Polenz—were elevated into new roles just “The largest [sector] for
last September. The third—Shanghai-based Andreas me is our global health-
Brandt—has held his position as vice president of care business and that’s
marketing for electrical and electronics, and appliances really an exciting space,” Hartmann: steering Growth
for polycarbonates, for the past two-plus years. he says. There is an ex- Ventures. All photos courtesy of
plosion of wearable Covestro
Hartmann, a New Zealand native, has assumed the devices that feature in-
recently created role of senior vice president for growth tegration between elec-
ventures, which represents a much broader portfolio tronics and digitalization
than his previous focus on the firm’s Maezio™ brand and healthcare—for example, the Apple Watch with an
for continuous fiber-reinforced, thermoplastic (CFRTP) ECG (electrocardiogram) function. “You see unbelievable
composites. As such, he now oversees efforts across opportunities for improving people’s lives, on a day-to-
a diverse set of ventures and entrepreneurial activities day basis.”
where Covestro projects significant growth. These
include CFRTP plus aspects of mobility, electric vehicles Technology has always played a central role in healthcare,
(EVs) and energy storage, global healthcare, non- but today the soaring popularity of connected medical
automotive LED lighting, business model innovation, devices is transforming how healthcare is delivered. And
and work on a brand-new polymer that Hartmann says these changes have huge implications for both product
is being developed as we speak. design and the materials used to make those devices.
“I now oversee seven different businesses around the Connected health is a healthcare management and delivery
world—each needs different types of tools, so it’s an system that relies on information and communications
interesting challenge. I also get a chance to work with core technology. Essentially, this technology is transforming
businesses at PCS (Covestro’s name for its polycarbonates care delivery by making it simpler, more collaborative,
business), for example, in mobility,” he says. and more data-driven. Digital technologies included in
»» Sensors
»» Voice recognition technology
»» Wireless connectivity (to be advanced by the adoption
of 5G wireless networking)
»» Mobile devices and applications
»» Videoconferencing platforms
»» Big Data analytics, and
»» Cloud computing
This opens up yet more opportunities related to Mobility Beyond the Vehicle
exterior styling and illuminated branding features. Such
Hartmann points out that other aspects of the future
aesthetics are increasingly important in mobility, as
of mobility also hold promise. He says firms like his
users strive to personalize their rides. need to be asking, “What’s next? How will smart cities
really integrate solutions? Where are some of the best
“It’s all about integrating those obtrusive Lidar radar
practices in the world?”
[cameras and lenses] that are sometimes sitting on top
of the car, into the body panels,” Polenz says. “Then
Interestingly enough, he says, an automotive designer
you also need materials that the Lidar radar can pass
in China recently told him that his benchmark in this
through and still fully function while also being scratch- regard was Tokyo. The designer said, “China may have
and impact-resistant. And you don’t need the front grille better rail systems, and Hong Kong may have fantastic
anymore, so again you can use different materials.” small connectivities, but when you look at the timing of
the public mobility in Tokyo, it’s impeccable. You arrive
And still, Polenz stresses, the growth of autonomous
from a small bus and it gives you just enough time to
vehicles (AV) and advanced driver assistance systems go up to your rail platform to catch your train, then you
(ADAS) means not only a need for more sensors but also go from a long-range train to a local subway, and it’s all
for artificial intelligence (AI) to analyze the reams of timed perfectly. It’s this kind of integration that’s the
data being captured. next wave, and we’ve got a team studying that.”
“AI means dramatically higher computational power will As for other parts of Hartmann’s portfolio, he notes the
be required. More computations mean more heat—heat global LED lighting business is growing quickly.
Digital displays and touchscreens in vehicles are getting larger and more functional while driving advances in the integration of
polymers and electronics.
“There are really interesting luminaires being developed, expect bigger visions and bigger thought leadership.
as architects and designers start to realize that, wow, we They can’t just follow the wisdom of the herd, that’s not
don’t need to just retrofit fluorescent or incandescent. a winning strategy.
We can design completely new stuff. They’re starting to
get that, so we’re beginning to see new solutions being “That’s also why,” he adds, “when you look at our
rolled out. We want to participate in that wave and get new setup, at Covestro we’re trying to build a really
the right materials for that.” agile business, because we understand that things
are changing super-fast, and we can make a positive
Hartmann also is charged with exploring new contribution—but only if we have the capability to
organizational strategies, which he says includes change quickly and help our customers drive new things
seeking ways to pivot existing operations to new
forward, even before they know that they want it.”
business models, or to brand entirely new businesses.
Stabilizing Recyclables
Recycled plastics are subjected to chemical processes that weaken them
over time. Some additives, however, can enhance the durability and
strength of these sustainable goods time and time again
By Geoff Giordano
I
n the emerging world of closed-loop plastics recycling, other AOs in the system. (It) also acts as a lubricant as
resins are going to have to perform double or triple well as an antacid.”
duty—or more. Girding them to tackle such Herculean
feats is a new generation of performance enhancers that Baeropol DRS 6812 is the most recent RST additive. Like
provide strength and stability every step of the way. the full range of Baeropol products, it is meant as a drop-
in replacement for resin makers and compounders. While
Not long after announcing the newest grades of its stabilizers are no mystery to those users, recyclers might
Baeropol Resin Stabilization Technology (RST) at NPE need more guidance. For recyclers having problems
2018, Technical Director Robert Sherman of Baerlocher’s incorporating high levels of reprocessed material into
Special Additives North America group addressed their conversion stream, increased stabilization can
emerging trends in bolstering recycled polymers in a neutralize the acid found in postconsumer recycled
presentation at ANTEC® 2019 in Detroit in March. (PCR) material and bolster resins that weren’t necessarily
designed for multiple extrusions.
Reducing the number of additives required to achieve
various mechanical and aesthetic properties is the goal Unique Solutions
of RST technology, Sherman explained at ANTEC®.
“We work downstream with recycling companies,
RST additives are derived from palm oil-based stearate converters, and brand owners designing, specifying, and
chemistry and emerged from Baerlocher’s investigation delivering stabilization that allows people to recycle,”
into blends of common additives that improve the says Roberto Nunez, business director for specialty
function of antioxidants. Not only do certain blends additives. Consumers, particularly in the U.S., are
improve the performance of commodity phenols and requesting that brand owners avoid single-use plastics
phosphites, but the process by which they are combined “at all costs.”
also boosts their effectiveness.
Providing guidance to stakeholders across the processing
Baeropol stabilizers inhibit the oxidative process to spectrum is a key role Baerlocher plays in ensuring robust
preserve a polymer’s structure. Furthermore, RST “is polymer performance over repeat uses, whether those
specifically composed of additives with the broadest repurposed plastics are industrial or postconsumer. A
global food contact approvals,” Sherman explained in his current priority is replacing phosphites.
presentation. He detailed the history of the creation of
RST, which has produced a range of stabilizing additives “Every solution is a little bit unique,” Nunez says, with
that maintain resin color, improve melt stability and Baerlocher offering “an infinite number” of custom
long-term heat stability, as well as reduce blooming. stabilizers in up to three forms: compacted rod pellet,
prill, or pastille.
RST is being used to stabilize polypropylene (PP),
polyethylene (PE), styrenics, and polyamides, Sherman With the T-Blends stabilizers, “the choice of phenolic AO
noted. RST “helps to boost commodity antioxidants and used in the blend is dependent upon the resin,” like low-
owners avoid single-use When working with customers, “we will typically receive
samples of resins, and in our lab, we will go through
plastics “at all costs. multi-pass extrusion and other processes to try to
determine how we can meet the customer’s requirements
for stability,” Sherman explains. “We will take that data
back to the customer, and from there we work with LLDPE film is “very commonly put back into recycling,”
them to sampling additives they can incorporate into Sherman explains, although post-industrial film is
their resin either in their labor, occasionally, straight still far easier to reuse given how clean it remains in
into production trials.” controlled conditions, as opposed to postconsumer film
that is subject to multiple unknown contaminants.
Stabilizers in Recycling
If postconsumer film “is not properly cleaned, or if there
A significant part of Baerlocher’s role in the recycling
is contamination from cleaning surfactants, that can be
revolution is educating recyclers about how to extend
the longevity of various polymers with stabilizers. very detrimental for the antioxidants when you extrude
it. That’s part of where RST works very well, because
When Baerlocher gets involved in upstream processing many of those contaminants are acidic, and RST is a very
with masterbatchers and converters, that education good antacid.”
might take the form of presentations similar to the
one Sherman gave at ANTEC® 2019, detailing the When RST T-blends are added to post-consumer
performance enhancements RST provides as a drop- polyolefins, the initial properties of the resin are
in replacement for other commercially available retained to such a degree they are similar to prime
additives. resin—allowing for stable rheology and improved long-
term stability.
The various antioxidants in the many grades of Baeropol
prevent changes in rheology and color, as well the That can be particularly important in cases where
formation of gels, Sherman explains. Gels—crosslinked manufacturers are trying to “upcycle” a resin for a
polymers—will give a product like top bags “a texture demanding use than its initial function—for instance,
somewhat like sandpaper instead of being perfectly using a recycled milk jug resin for plastic pipe. “In that
smooth and transparent.” case, you would want a much more robust additive
package. If you’re down cycling by taking some recycled
While of course many products are “a one-and-done
part and turning it into lawn edging, you’re typically less
molding process”—like many pipe resins and injection
interested in long-term stability.”
molded plastics—thermoforming and blow molding
produces a lot of waste. “On a normal basis, about 30 RST greatly improves two key performance parameters
percent of that molded part is sent for regrinding. If you
when stabilizing PCR: melt index and OIT. RST added
are a resin manufacturer, you typically will have a more
to PCR HDPE flake produces nearly the same rheology
robust stabilization package.”
through three extrusions while resulting in better initial
In a case where RST is used as a partial phosphite OIT and retention of OIT through three extrusions. OIT
replacement in high-density polyethylene (HDPE), is extended from about seven to 11 minutes in flaked
Baerlocher can provide data on stabilizer-improved repro to between about 34 to 36 minutes to oxidation
performance through five passes through an extruder— with 2,500 ppm of RST T-blend T-1214.
the equivalent of being recycled four times.
By Pat Toensmeier
E
fforts to improve the level and quality of plastics
recycling are growing in many parts of the world as
consumers, business, and regulators seek common
ground in addressing litter, waste disposal practices,
marine pollution, and the need to promote sustainable
lifestyles as effective ways of reducing society’s carbon
footprint and environmental impact.
Baerlocher is among the companies that actively promote formulations that could become more common as
stabilizer use as a way to improve recycling. Products regulatory pressures grow on resin producers and product
include Baeropol T-Blends, which boost the stabilization brandholders to improve the efficiency and effectiveness
of recyclate by combining multiple stabilizers to capture of recycling.
free radicals, eliminate hydroperoxides, and neutralize
acidic species, all of which, if untreated, would reduce the “As customers require more and more recycled content,
properties of PCR. additives will be needed to allow resins to retain their
properties,” Sherman says.
The T-Blends retain PCR’s initial aggregated properties,
said Sherman in an ANTEC presentation earlier this year, Recycling could evolve into big business, though not in all
and maintain stability similar to that of prime resin, as regions. Europe appears to have the broadest programs in
well as long-term control over properties. During the the world, experts say, primarily because of regulations
presentation, he noted that while HDPE flake has poor and laws that increasingly focus on product redesign to
optimize PCR content.
OIT (oxidation induction time), the addition of a T-Blend
stabilizer improved initial OIT in tests and retained it Recycling in the U.S. lags the European model. As a result,
during three extruder passes. “It is generally rare in the U.S. to find someone that uses
stabilizers when recycling resins,” Sherman remarks.
The company also supplies Baeropol RST (resin stabilization
technology) grades, which blend additives in a balanced
formulation that contains multiple antioxidant as well Finding Markets
as antacid chemistries for polyethylene, polypropylene, One analyst explains that the U.S. recycling rate is declining
polystyrene, and low-temperature polyamides. RST after the overseas market for post-consumer plastics
chemistry is generally recognized as safe for indirect food collapsed following the 2018 ban by China on imports of
contact. plastics waste. In 2016, China took 51 percent of global
plastics waste shipments, most of which were from the
Recent additions to the RST line include Baeropol DRS U.S. China’s ban on imports led to many collection and
6812, an antioxidant that is formulated to improve melt recycling programs being abandoned in the U.S. and
stability, color, and solubility in polyolefin PCR. The offsetting demand for PCR has yet to develop.
stabilizer replaces phosphite on a 1:1 drop-in basis, acts
as a synergist to reduce phosphite loading, and allows the Recycling is a more profitable business in Europe due
use of lower-cost phosphite without affecting properties. to regulations that cover European Union members.
Automotive is an important outlet for PCR, which is used
These stabilizers demonstrate some of what’s available in blends or as core layers in parts. Even so, the European
for recycling. They also represent the types of additive Commission reports that only 6 percent of new plastics in
Another factor affecting recycling in the U.S. is the lack One technique involves BASF’s Joncryl ADR functional
of a broad and effective system of collection, sortation, additives which, when used in reactive extrusion, restore
and processing. America needs to increase investments mechanical properties by rebuilding molecular weight and
in infrastructure to support recycling, analysts say, so chain branching in thermoplastic polyesters (PET and PBT),
that PCR is not only collected and processed, but the polycarbonate, polyamide, thermoplastic polyurethane,
system generates viable products for many markets. One and polylactid acid (PLA) resins.
approach that may become common is to reduce the types
and amounts of plastics collected. By focusing on products Schaffrannek also cited Recycloblend 660 and Recyclostab
with high-demand resins such as HDPE, PET, and 451 additives, both from Byk, which repair and upgrade
polyamides, and establishing mono-material the properties of recycled plastics. Loadings of 0.7 to
processing streams, quality recyclate 1.2 percent of Recycloblend 660 neutralizes solid
could be produced that would, with impurities and retains mechanical properties
stabilization, attract users. in polyolefins and TPOs. Typical appli-
This will likely happen as cations include vehicle bumpers,
more brandholders demand filled PP systems, and roto-
PCR content in their products. molded parts. Recyclostab
451, in 0.2 to 0.5 percent
A third factor, at least for now, loadings, improves the
is the low price of virgin resins, long-term stability of re-
notably polyolefins. Analysts cycled PP from automotive
attribute part of this to frack- battery cases and minimiz-
ing, which is increasing U.S. oil es the effects of acidic resi-
and natural gas production and due.
consequently depressing these
prices. A related price influence is Stabilizing PCR from PP battery
an effort by some large resin suppliers cases is especially important
because the application comprises
a model for future recycling: a
relatively pristine, mono-material
PP battery cases are recycled in mono-material streams
stream. In the U.S., estimates are that
and used in high-value recycling applications. Courtesy of
Scrap Mart Metals
90 percent of all automotive battery
cases are recycled, with the PP reused in new cases and well, in Europe and lately the U.S. While it’s unlikely that the
other high-end applications, Schaffrannek says. bags will be effectively collected and recycled, alternative
approaches are appearing. BASF, for example, offers a
BASF supplies additional stabilizers for recycling. compostable, bio-based polymer called ecovio FS, which
These include Irganox, an antioxidant; Irgafos, a high- can be used as a retail bag and then for organic waste. The
performance organo-phosphite that acts as an antioxidant product runs on LDPE blown film lines, is moisture and
in some versions; and Chimasorb and Tinuvin, hindered tear-resistant, and designed for effective composting.
amine light stabilizers that prevent UV degradation
and maintain the chemistry, physical properties, and For the foreseeable future, stabilizers will be an important,
appearance of polymers. if underused, means of increasing PCR performance. If the
market for PCR is to develop in the U.S., or expand in Europe,
Image and Reality resin producers, recyclers, and product brandholders will
need an infrastructure that guarantees the collection of
The success rate of recycling will be decided as much specific materials for cleaning, compounding, and reuse in
by consumer opinion and regulation as by product high-volume, high-value applications. Commingled waste
development. One issue that provokes controversy is streams and low-performance PCR will not build a viable
marine litter, notably the amount of plastics waste in recycling business. Current stabilizers are necessary
global waterways and oceans and washed up on beaches. for immediate recycling needs. In the future, growing
Estimates put the amount of plastics dumped in oceans performance demands and application options will likely
yearly at 8.8 million metric tons. China alone accounts for generate entirely new classes of stabilizers.
2.4 million metric tons of plastics ocean waste every year.
As a result, marine litter is a powerful image and incentive
for recycling. ABOUT THE AUTHOR
European countries, the U.S., and other nations are Pat Toensmeier is a Hamden, Conn.-based
working to reduce this pollution, most of which originates freelance writer and reporter with more
than 35 years of business journalism
in Asia. The European Parliament (EP) seeks aggressive experience, much of it with Modern
rules that limit the amount of single-use plastics for sale Plastics and Aviation Week. Over the
and increase the collection rate of PET bottles as one way years he has specialized in writing about
manufacturing, plastics and chemicals,
of keeping these products from becoming marine litter. By technology development and applications,
2029, the EP wants a 90 percent collection rate for plastic defense, and other technical topics.
bottles in Europe. By 2030 it seeks a 30 percent recycle-
content rate for PET and other bottles.
T
he heady mix of plastic waste, global damage, and In 2018, China formalized its plan, and ceased importing
national interest has already sparked two sparring a number of materials, for recycling, including all
matches, and another is set to begin. At the heart unprocessed plastic––leaving plastic exporting nations
of the issue is that much of the planet relies heavily on with enormous volumes of waste on their own front doors
global trade––exporting and importing what we value. The and declaring a plastic waste crisis. China’s border closure
trading of plastic waste can fit these criteria. However, was the modern day “shot heard around the world” in terms
the exported value often comes with a toxic cost. Finding of Western countries and their abilities to easily offshore
the value in circular economy trading can help negate the their domestic plastic waste liabilities. Lack of homegrown
need for some of these plastic waste trade wars. capacities and high labor costs helped to shut the door on
value-adding opportunities for many developed markets,
The increased inability to easily move commodities, which while “commodity traders” often grabbed the resources
properly processed plastic resources are, is part of the from domestic processors as the buyers in China paid
reason for the world’s plastic pollution problem. The other more, for lower quality material.
significant issue is the lack of local capacity for proper
With China’s borders closed, Round 2 of the plastics
collection, sorting, and basic processing for material
challenge resulted in Western countries turning quickly
recovery, across communities of all levels of economic
to find new export markets. Malaysia, Thailand, Vietnam,
advancement, including both Hong Kong and Singapore,
and Indonesia became the targets. Joining legitimate
which are two of the wealthiest cities in the world. and responsible processors of these resources was a
groundswell of illegal and irresponsible businesses.
In Round 1 of the plastic pollution fight, China announced
Like China, these countries felt, and feared, the harsh
its intention to cease the acceptance of scrap plastic
impacts of poor quality, contaminated imported plastics
imports in early 2017. Western industry insiders said which had nowhere to go except into the environment.
it would never happen. They trusted market forces, Their relatively quick actions to slow plastic imports for
expecting that such a ban would be viewed as an economic recycling, following China’s lead, means most exporters
trade barrier. did not find quick solutions for re-routing their previously
China-bound exports.
This was a grave miscalculation. We now know China’s
application to the World Trade Organization also opened the Round 3 is on the way, as diplomats have been considering
door to human and environmental damage. This created the a proposal to add mixed plastic waste to a list of materials
need to manage and limit the importation of plastic waste, where that require the receipt of a country’s informed acceptance
up to 40 percent of a bale shipped to China was unrecoverable, of this type of trade under the Basel Convention. If
due to contamination and poor material quality. successful, trading mixed plastic waste resources will
INVENTIVE COMPOUNDING
V is c os it y R
Im pr ov e d M
a re b or
e d uc t io n
ol d or
n he re
!
e
D ie R e le a s
compound processing.
F il le r
Enhanced
D is pe r io n
s
ou g h pu t
Faster Thr
Rates
economies of scale from smaller markets to larger ones and resources through collection, sorting, and processing
transferring only value, instead of burden (waste). should take priority over downcycling the materials.
1. Continue the pressure: With the disruptive forces Yet, the greater challenge is what to do with the rest––
already in play, countries that have been a dumping the dirty mixed plastics where it is hard to derive
ground should continue putting pressure on waste- value. These materials can be converted from waste
exporting nations so that only recovered plastic to energy, but increasingly entrepreneurs, scientists,
feedstock is exported. In other words, only high- and researchers are looking beyond the calorific value
quality, fit-for-purpose material that has a second life and using dirty plastic’s embedded characteristics; for
in the recipient country. example, extracting the aluminium from chip packets
and using a processed form to create a higher-
2. Business focus on sustainable market opportunities: performing building aggregate. Chemical recycling
One Plasticity alumnus recently said that, despite the is also a new opportunity which can yield a pure,
fact that his business collects and processes used high-quality polymer as a byproduct, without the
materials and then manufactures new goods for sale, contamination burdens with which some mechanical
his business is not that of a recycler. Rather, he says recycling processes contend.
his business is a plastics engineering, design, and
product manufacturer that happens to specialize in 6. Innovative substitutes for non-recoverable
using recovered plastic. hazardous plastics: There are more than 43,000 types
and combinations of plastics. While all are technically
Like many entrepreneurs in this space, he starts recoverable and reusable, it is simply not viable to do
with his customers, combining their needs with his so for many of them with today’s technologies and
strategic strengths to determine which profitable economies of scale in sorting and collection. Where
products to make and sell within the specialty market there is no value, and not even energy, the innovation
he serves (in this case, agricultural and aquaculture challenge should be set globally to identify substitutes
products where there is good market turnover and or recovery solutions. Over time, the “too-hard basket”
margin for profit). of plastics will diminish.
It is only after this analysis that he turns his mind 7. Engage in the conversation: It is easy to want to
to where he can source suitable waste plastic, its blame others for the global plastic waste problem––
costs, and the processes needed to transform it. should governments have done more, are community
Interestingly, he found that his customers are a great attitudes the cause, or are corporates ones at fault?
source of the very waste plastic he needs. The problem with the blame game is that, once
started, the finger pointing rarely ends.
3. Collaborating for competitive advantage markets:
The market disruption currently being experienced Above all else, new collaborations and shared
globally is an opportunity for industries, countries, and responsibility created across business sectors can help
regions to apply this thinking from above. Each group shift thought to action, embed principle to practice,
knows its manufacturing strengths and weaknesses and help change the focus from me to we.
and where it has strategic opportunity.
CALL FOR
PAPERS
ATTEND THE WORLD’S LEADING AUTOMOTIVE COMPOSITES FORUM You’re invited to attend the 19th
Annual SPE Automotive Composites Conference and Exhibition (ACCE), September 4-6, 2019 at the Suburban Collection Showplace in
Novi, MI. The show features technical sessions, panel discussions, keynotes, receptions, and exhibits highlighting advances in materials,
processes, and equipment for both thermoset and thermoplastic composites in a wide variety of transportation applications.
PRESENT BEFORE A GLOBAL AUDIENCE The SPE ACCE draws over 900 attendees from 15 countries on 5 continents
who are interested in learning about the latest composites technologies. Few conferences of any size offer such an engaged, global
audience vitally interested in hearing the latest composites advances. Interested in presenting your latest research? Abstracts are due
ASAP and papers on June15, 2019 to allow time for peer review. Submit abstracts viawww.SubmitACCEPapers.com.
EXHIBIT / SPONSORSHIP OPPORTUNITIES A variety of sponsorship packages are available. Companies interested in
showcasing their products and / or services should contact Teri Chouinard of Intuit Group at teri@intuitgroup.com.
49TH ANNUAL
Destination Düsseldorf
The K Show in Germany will attract more than 3,000 exhibitors from 60
countries. Petra Cullmann, global portfolio director for plastics and rubber at
Messe Düsseldorf, talks about why K 2019 is so important to the industry
By Pat Toensmeier
T
he triennial K Show will be the center of the global plastics industry for eight days this
fall. More than 3,000 exhibitors from over 60 countries will fill the massive fairgrounds
(175,000 square meters) of organizer Messe Düsseldorf in Germany between Oct. 16 and
23, presenting the latest technology, machinery, materials, and applications to attendees from
161 countries. Petra Cullmann is the global portfolio director for plastics and rubber at Messe
Düsseldorf. She discusses why K 2019 is so meaningful for business and what attendees will
see there.
E
xxonMobil, the largest publicly traded international “Our substantial investments in the United States support
oil and gas company, has completed an expansion ExxonMobil’s long-term growth plans and will result
of its specialty elastomers manufacturing plant in in thousands more high-paying jobs,” says Darren W.
Newport, Wales, doubling the plant’s manufacturing Woods, ExxonMobil chairman and chief executive officer.
capacity and increasing global manufacturing capacity “Through the billions of dollars that we’re investing in
of Santoprene™ thermoplastic elastomers by 25 percent. the Permian Basin to increase oil production and the
The company also announced a $2 billion investment to expansion at our operations along the Gulf Coast, our
expand its Baytown, Texas, chemical plant, which will company is making significant, lasting contributions to
create approximately 2,000 jobs during construction the U.S. economy and the many communities where we
and contribute to the approximate 15 percent return the operate.”
company expects from its chemical investments.
ExxonMobil’s Baytown facility is the largest integrated
Regarding the Welsh plant expansion, Karen McKee, petrochemical complex in the U.S. Founded in 1919, the
president of ExxonMobil Chemical Co. says, “ExxonMobil’s complex is located on approximately 3,400 acres along
high-performance plastics help make automotive and the Houston Ship Channel, about 25 miles east of the city.
consumer products lighter, resulting in improved fuel The facility includes a refinery, chemical plant, olefins
efficiency and higher performance, compared with plant, plastics plant, and global technology center. Its
products made with traditional materials. This Newport expansion, expected to begin in 2022, includes a new
investment doubles the site’s manufacturing capacity of Vistamaxx™ performance polymer unit, which produces
higher-value products.” products that offer higher levels of elasticity, softness,
and flexibility. These attributes contribute to a reduction
Santoprene thermoplastic elastomers are engineered in materials used and increased performance, and the
to perform like vulcanized rubber and can be re- new unit will produce about 400,000 tons of Vistamaxx
used and re-engineered, leading to reduced shipping polymers a year. The Baytown project will also enable
weights, improved recycling capabilities, and more- ExxonMobil to enter the linear alpha olefins market.
sustainable manufacturing. The Newport project Linear alpha olefins are used in numerous applications,
created approximately 35 full-time production jobs including high-performing engine and industrial oils,
and supported 130 jobs during construction. The waxes and building blocks for surfactants, polyethylene
announcement of its completion followed ExxonMobil’s plastic for packaging, and other specialty chemicals. The
recently announced plans to expand its Fawley refinery new unit will produce about 350,000 tons of linear alpha
in the United Kingdom to increase production of ultra- olefins a year.
low sulfur diesel by almost 45 percent, or 38,000 barrels
per day. “Our Baytown chemical expansion will put us in a solid
position to maximize the value of increased Permian
The Baytown expansion is in addition to the company’s Basin production and will deliver higher-demand, higher-
2017 Growing the Gulf initiative, which outlined plans value products produced at our Gulf Coast refining and
to build and expand manufacturing facilities along the chemical facilities,” says Woods. “Global demand for
U.S. Gulf Coast, creating more than 45,000 jobs across chemicals is expected to be greater than energy demand
the region. growth and GDP growth over the next 20 years.”
T
upperware Brands Corp., a global marketer of reusable, safe, and environmentally responsible products
food preparation, storage, and serving solutions, that help consumers store, prepare, and cook food.
announced its collaboration with SABIC, a Introducing polymers from recycled material reflects
petrochemical company and one of its long-term Tupperware’s commitment to sustainability. Starting in
suppliers, for the introduction of certified circular the summer of 2019, Tupperware will begin introducing
polymers into its products. This collaboration highlights the certified circular polymers in new products that aid in
both companies’ commitment to advance a circular the reduction of single-use plastics, including a portable
economy where plastic waste and materials are used, reusable straw and an on-the-go coffee cup.
reused, and repurposed.
“We are pleased to extend our collaboration with
“Tupperware Brands is committed to meeting the
Tupperware Brands, as we are unified in our goal to
needs of today’s consumers, who are increasingly
deliver high-quality solutions made from advanced,
asking for solutions that mitigate waste and advance
recycled materials that address consumer needs and
a more circular economy. The introduction of this new
material, and the products in which they will be used, safety standards,” says Sergi Monros, vice president,
reflect our continued dedication to further reduce our performance polymers and industry solutions at
environmental footprint at all levels of the product SABIC. “We continue to innovate with materials and
lifecycle—from design, production, and distribution look to create more sustainable and environmentally
to products’ use and reusability—and also reflects our responsible solutions to support a circular economy.
heritage of innovation and sustainable design,” says Bill Our material is made through a process that takes mixed
Wright, Tupperware’s executive vice president, product plastic waste destined for disposal, breaks it down to its
innovation, and supply chain. original raw state, and recreates high-quality plastic that
maintains the purity and quality that are the hallmark of
For more than 70 years, Tupperware has provided Tupperware products.”
T
rinseo, a global manufacturer of plastics, latex compliance programs, and operational discipline during
binders, and synthetic rubber, named David Stasse his tenure as Trinseo’s CFO. We will miss his counsel
its executive vice president and chief financial and we wish him all the best in his well-deserved
officer effective July 1. He will replace Barry Niziolek, retirement.”
who earlier this year announced his plans
to retire. Stasse, the company’s current Stasse joined Trinseo in 2013 from
vice president, treasury and investor Freescale Semiconductor Inc., where he
relations, will also join its executive served as vice president and treasurer
leadership team. from 2008 to 2013 and as assistant
treasurer from 2006. He previously
“We are extremely pleased to name an served as first vice president, debt
executive the caliber of Dave Stasse as capital markets, at MBNA Corp., as
CFO,” says Frank A. Bozich, president and treasury manager of SPX Corp., and held
chief executive officer of Trinseo. “His numerous financial leadership positions
track record at Trinseo, his strategic and at Honeywell International from 1998 to
financial acumen, and his credibility with 2004, last serving as director of corporate
investors make him ideally suited to take finance. Stasse, who holds a master’s
on this role. Dave has worked closely with degree in business administration in finance from the
Barry Niziolek throughout his tenure, which will enable University of Maryland and a bachelor of science degree
a smooth and seamless transition. On behalf of the in business logistics from Penn State University, will
board, I want to thank Barry Niziolek for his leadership continue to be located at Trinseo’s global operating
in strengthening the company’s financial performance, center in Berwyn, Pa.
C
ovestro LLC announced that Jerry MacCleary will from Bayer AG and establishment as an independent
retire from his current position as chief executive company in 2015, and was named to his current position as
officer and chairman of the board, effective Dec. 31, chief executive officer and chairman in 2018. MacCleary’s
2019. leadership extends into the chemical industry as well,
where he serves as chairman of the American Chemistry
“I’ve had a long, fulfilling career with this company, and Council’s board of directors and chairs its sustainability
I’m incredibly proud of what we’ve accomplished over committee. He also serves on the board of directors
the years,” says MacCleary. “Covestro has a vibrant new for the National Association of Manufacturers and the
culture, a strong, diverse leadership team, and a promising executive committee for the Society of Chemical Industry.
Both inside and outside Covestro, MacCleary is known for
future here in the region—I can’t think of a better time
championing initiatives that help to advance sustainability,
to retire. Saying goodbye to my Covestro family won’t be
innovation, and diversity and inclusion.
easy, but I’m looking forward to starting this next chapter
of my life.”
“Our team, our business, and our reputation in North
America have thrived under Jerry’s leadership, and we’re
MacCleary’s retirement caps a 40-year career at Covestro. grateful for his many contributions over the years,” says
He first joined the company in November 1979 as an Dr. Markus Steilemann, chief executive officer of Covestro
accountant, and he has held roles in sales, marketing, AG. “While Jerry will retire at the end of 2019, the impact
general management, and strategic leadership. In 2004, he’s had on our culture, community and industry will be
MacCleary was named head of the North American felt for years to come.”
Polyurethanes business, a responsibility he maintained
even after taking the helm at Covestro LLC in 2012. He Covestro’s North American polyurethanes division
led the North American organization through a number of produces high-performance polymers as part of the global
transformative changes, including Covestro’s separation Covestro business.
T
he Camille and Henry Dreyfus
Foundation announced that Robert
Langer, institute professor at
Massachusetts Institute of Technology,
won the 2019 Dreyfus Prize in the
Chemical Sciences. The biennial prize,
which includes a $250,000 award, is
being conferred this year in Chemistry
in Support of Human Health. The award
ceremony will be held at MIT on Sept. 26
and will include a lecture by Langer.
Langer is being honored for discoveries provide to society than the many profound contributions
and inventions of materials for drug delivery systems to the science and technology of human health,” says
and tissue engineering that have had a transformative Matthew Tirrell, chair of the Dreyfus Foundation
impact on human health through chemistry. His work Scientific Affairs Committee and director of the Institute
on drug delivery is at the interface of biotechnology and for Molecular Engineering at the University of Chicago.
materials chemistry, with a strong focus on the study and “Bob Langer created two rich fields at the intersection
development of polymers to deliver drugs continuously of chemistry and medicine: controlled release materials
and at controlled rates for prolonged periods. His for delivery of therapeutic macromolecules and tissue
innovations have been lauded as the cornerstone of engineering. His discoveries have been translated, often
that industry and translated into commercial products by Langer himself, to many products that profoundly
used in the treatment of brain and prostate cancer, impact human health. In a diverse field of chemists and
macular degeneration, and a variety of mental health chemical engineers with many powerful contributors,
disorders, including schizophrenia and opioid addiction. the enormous body and influence of Bob Langer’s work
His pioneering work with Joseph Vacanti in tissue stands out in a singular way.”
engineering has led to the creation of new skin, cartilage,
bone, corneas, and blood vessels in humans. Langer is Initiated in 2009, the Dreyfus Prize in the Chemical
further renowned as a mentor, with nearly 1,000 former Sciences is conferred in a specific area of chemistry
students and postdocs becoming established leaders in each cycle and is the highest honor of the Camille
in academia, industry, and government. His papers and Henry Dreyfus Foundation. Based in New York
have been cited in scientific publications more than any and established in 1946 by chemist, inventor, and
other engineer in history, and his leadership in both businessman Camille Dreyfus, the foundation is a leading
the underlying science and its applications have given non-profit organization devoted to the advancement
rise to entirely new fields of the chemical sciences and of the chemical sciences. Its mission is to advance the
engineering. science of chemistry, chemical engineering, and related
sciences as a means of improving human relations and
“There is no greater benefit that the chemical sciences circumstances throughout the world.
W
estfall Technik, Inc., a global holding company company plans to expand Delta’s current footprint to
that provides plastics manufacturing solutions allow the business to scale alongside its customers.
to the medical, packaging, and consumer goods
industries, acquired Delta Pacific Products and its wholly “We chose to join Westfall Technik because we knew
owned subsidiaries, Prism Plastics Products and NxTBio Westfall would expand the services and production
Technologies, each of which operate on a standalone capacity we offer to the medical device community in the
basis. This acquisition marks a significant investment in Bay area and greater Minneapolis. We can now offer our
the medical/healthcare space for Westfall. customers high-volume production, device assembly, and
rapid precision toolmaking throughout the United States
As an injection molding company with over thirty years and, through Westfall’s extensive sales team, can offer our
of operating experience in the San Francisco Bay Area, services to customers we could never previously reach,”
Delta serves the large and growing medical device startup says Yuan Tian, Delta’s president and chief executive
community in that region, working with med-tech research officer.
and development professionals from the prototyping
phase through FDA approval and full production. Prism, Westfall also acquired NxTBio Technologies, a developer,
located outside Minneapolis, also marks a strategic marketer, and distributor of branded bioscience laboratory
investment for Westfall as the company looks to expand its consumables including pipette tips, filter tips, tubes and
presence and provide additional capacity and capabilities strip tubes, vials, multi-well plates, and related racking
to its customers in the Midwest. On a combined basis, systems. Westfall’s ability to engineer and build high-
the additions of Prism and Delta add over 50,000 square volume production systems will accelerate the growth of
feet of production space to Westfall’s capacity, and the NxTBio’s product portfolio.
S
C Johnson is continuing to address the plastic refills, including Scrubbing Bubbles, Windex, and Mr
waste crisis by expanding and widening access to Muscle®, will be available for purchase online in Mexico
its concentrate offerings. this July, in the United Kingdom starting in August, and
in China and Japan beginning this September.
“Plastic waste is becoming a bigger and bigger
environmental problem,” says Fisk Johnson, chairman
The benefits of concentrate refills are primarily
and chief executive officer of SC Johnson. “We hope
environmental and in line with the steps SC Johnson
more people can give concentrates a try, as every single
has taken regarding waste reduction and the circularity
time you use a concentrate bottle you [create] nearly 80
of its products. For example, the company’s trigger
percent less plastic waste.”
bottles deliver more than 10,000 sprays and can be
Since the unveiling of Windex® concentrates in 2011, refilled dozens of times; by purchasing bottles with a
SC Johnson has expanded its refill options to other long lifespan, millions of pounds of plastic waste can be
popular cleaning brands, including Pledge®, Scrubbing stopped from ending up in landfills.
Bubbles®, Shout® and fantastik®. The new line of SC
Johnson concentrates will begin rolling out in the “Refilling with a concentrate is a small change that could
U.S. and Canada, when Scrubbing Bubbles, Windex, make a real difference in minimizing plastic waste,”
and fantastik bottles, and two-count refill sets hit Johnson says. “Together, we can reduce plastic waste
e-commerce retailers. The next wave of concentrate and work towards a cleaner planet.”
T
he Society of Chemical Manufacturers and Affiliates executive officer of SOCMA. “Whether it is pigments,
(SOCMA) says the Trump administration’s decision agrochemicals, or pharmaceuticals, specialty chemicals
to raise tariff rates from 10 to 25 percent on $200 are vital inputs to critical sectors of American industry.
billion in Chinese imports will disproportionately burden These sectors are thriving, but cannot continue to
specialty chemical manufacturers. The U.S. Trade sustain the volatility introduced by these actions. We
Representative (USTR) notice of the tariff increase was have illustrated the interdependency of these supply
published in the Federal Register on May 9 and went into chains to USTR at every opportunity and have stressed
effect at 12:01 a.m. May 10. the need for a product exclusion request process for List
3. The promised exclusion process in today’s Federal
Specialty chemical supply chains are particularly Register notice acknowledges this, and SOCMA looks
dependent on China because, in many cases, China is forward to working with the administration towards an
the sole supplier of raw materials and building block expeditious and transparent process for evaluating List
chemicals. The fact that chemical tariff lines made up 3 exclusion requests.”
nearly half of the delistings for List 3 (the products
effected by the tariff increase) speaks volumes regarding To date, the U.S. has levied tariffs on 1,517 Chinese-
the degree to which certain inputs are simply unavailable origin chemical products valued at roughly $15.4 billion.
outside of China at reasonable costs and in sufficient China has levied retaliatory tariffs on more than 1,000
quantities, if at all. chemical and plastics products valued at roughly $10.8
billion. As the U.S. and China negotiate the sequencing
“While SOCMA supports the administration’s end goal of tariff removal, SOCMA is proactively monitoring and
of zero tariffs and improved IP protection in China, a advocating on behalf of the specialty chemical industry,
25 percent tariff on $250 billion in Chinese imports particularly advocating for the USTR to roll back tariffs
will place a significant burden on our members and on chemical products in Harmonized Tariff Schedule
the industry,” says Jennifer Abril, president and chief chapters 28, 29, 32, and 38, as soon as possible.
#92
T
he Society of Chemical Manufacturers and Affiliates executive officer of SOCMA. “Whether it is pigments,
(SOCMA) says the Trump administration’s decision agrochemicals, or pharmaceuticals, specialty chemicals
to raise tariff rates from 10 to 25 percent on $200 are vital inputs to critical sectors of American industry.
billion in Chinese imports will disproportionately burden These sectors are thriving, but cannot continue to
specialty chemical manufacturers. The U.S. Trade sustain the volatility introduced by these actions. We
Representative (USTR) notice of the tariff increase was have illustrated the interdependency of these supply
published in the Federal Register on May 9 and went into chains to USTR at every opportunity and have stressed
effect at 12:01 a.m. May 10. the need for a product exclusion request process for List
3. The promised exclusion process in today’s Federal
Specialty chemical supply chains are particularly Register notice acknowledges this, and SOCMA looks
dependent on China because, in many cases, China is forward to working with the administration towards an
the sole supplier of raw materials and building block expeditious and transparent process for evaluating List
chemicals. The fact that chemical tariff lines made up 3 exclusion requests.”
nearly half of the delistings for List 3 (the products
effected by the tariff increase) speaks volumes regarding To date, the U.S. has levied tariffs on 1,517 Chinese-
the degree to which certain inputs are simply unavailable origin chemical products valued at roughly $15.4 billion.
outside of China at reasonable costs and in sufficient China has levied retaliatory tariffs on more than 1,000
quantities, if at all. chemical and plastics products valued at roughly $10.8
billion. As the U.S. and China negotiate the sequencing
“While SOCMA supports the administration’s end goal of tariff removal, SOCMA is proactively monitoring and
of zero tariffs and improved IP protection in China, a advocating on behalf of the specialty chemical industry,
25 percent tariff on $250 billion in Chinese imports particularly advocating for the USTR to roll back tariffs
will place a significant burden on our members and on chemical products in Harmonized Tariff Schedule
the industry,” says Jennifer Abril, president and chief chapters 28, 29, 32, and 38, as soon as possible.
#92
sp e
PROCESS ENGINEER
EDWIN TAM
DIRECTOR, MARKETING AND
sp e
NEW BUSINESS DEVELOPMENT
By Roger Corneliussen
micropores having an average micropore size 3.0 to 5.0 Injection Molding Thermosets
Angstroms. These materials can separate gas mixtures
including propane/propylene; nitrogen/methane and U.S. Patent 10,239,246 (March 26, 2019), “Injection
ethane/ethylene. Such membranes are prepared from Molding Machine,” John E. Burton and Christopher J.
vinylidene chloride copolymer beads. A melt extruded Burton (Limworks, LLC, Ludington, Mich.)
film or fiber are pretreated to form a precursor that is
finally carbonized at high temperature. Preselection Most injection molding machines are based on molding
based on precursor crystallinity and maximum pyrolysis thermoplastics. Even thermoset injection units are
temperature enables prediction of the average micropore typically built based on a screw-based injection system
size if the crystallinity percentage ranges from 25 to 75 designed for thermoplastic polymers. Burton and Burton
percent and temperature ranges from 800º to 1,700º
developed an injection molding machine with a special
C. The beads, fibers, or film may be ground, post-
injecting and clamping system for thermosets. This
pyrolysis, and combined with a non-coating binder to
form extruded pellets. Alternatively, the fibers may be includes a removable injection module consisting of a
woven, either before or after pre-treatment, to form a moveable valve between fill and injecting positions to
fiber sheet which is thereafter pyrolyzed to form a woven eject material from the injection module into the mold.
fiber adsorbent. The actuators for the injection module are supported
on the machine rather than the injection module. The
clamping system includes a platen linear actuator to
Stretch Molded Containers open and close the mold. The system also uses hydraulic
forces to clamp the mold closed.
U.S. Patent 10,239,267 (March 26, 2019). “Process
for Producing Injection Stretch Blow Molded Polyolefin
Containers,” Mike Rogers and Anja Gottschalk (Basell
Poliolefine Italia S.r.l., Milan)
ABOUT THE AUTHOR
Stretch blow molding is an effective method to produce
polyolefin containers. This is a two-step process of Dr. Corneliussen is professor emeritus of
molding a preform and then stretching the preform. materials engineering of Drexel University
in Philadelphia. He has been an SPE member
Uniform heating of the preform is critical and difficult since 1962 and an active member of the
to achieve. Rogers and Gottschalk developed injection Philadelphia Section serving as president
stretch blow molding process for polyolefin containers and national councilman for several years.
The above patents are selected from the
by preparing a preform by injection molding. This 100 to 400 plastics-related patents found
preform is heated and stretched. They solved the by reviewing 3,000 to 7,000 U.S. patents
uniform heating problem by incorporating a parts-per- published each Tuesday. Readers can
million metal compound such as Cu hydroxy phosphate review the complete list of plastics-related
patents by week at www.plasticspatents.
in the resin. com.
WWW.SPECAD.ORG
REGISTER BY: AUGUST 23, 2019 & SAVE $100
Come join us for The 57th Annual Society of Plastics Engineers
Color and Appearance Division RETEC® to meet and discuss topics
related to plastics coloration. This year’s theme is Rocking Color in
Cleveland. CAD RETEC® is the longest running and largest technical
conference in North America devoted to the coloring of plastics. It
started as a technical conference focused on development, manu-
facturing and research in the field of color science, color mea-
surement, and coloring plastics but has grown to be THE place to
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EVENTS
Sept. 23-25 / SPE CAD RETEC® Color and Sept. 15-17 / SPE 2020 TPE TopCon
Appearance Conference Hilton Fairlawn Hotel
Renaissance Cleveland Hotel Akron, OH
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Contact: Steve Esker Email: rweiler@amfine.com
Tel: 614-679-4677
Email: steve@paramountcolor.com Sept. 23-25 / SPE CAD RETEC® Color and
Web: www.specad.org
Appearance Conference
Renaissance Orlando at SeaWorld
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Foam Materials & Technology Contact: Cheryl Treat
University of Valladolid Email: cheryl.treat@basf.com
Valladolid, Spain Web: www.specad.org
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Plastics Engineering (ISSN 0091-9578) is published monthly, except bimonthly in July/August and November/December, by Wiley Subscription Services, Inc., a Wiley Company,
111 River Street, Hoboken, NJ 07030 USA. The magazine is compiled and edited by the Society of Plastics Engineers, Editorial and Business Office, 6 Berkshire Blvd., Suite 306,
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ADVERTISERS INDEX
BYK, www.byk.com.................................................................................13
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ID Additives, www.iDadditives.com........................................................27 Tel: +1 716-587-2181
IMS Company, www.imscompany.com/G27................................... Cover 3 E: dnicholas@wiley.com
J.P. Curilla Associates, email: jpcecl@aol.com........................................52
Shepherd, www.shepherdcolor.com.........................................................5
SPE, www.4spe.org............................................................................. 4, 44
Struktol, www.4struktol.com..................................................................33