pure zinc i1I,ould not be uued ~t;, tJu,; oonti,v....u ra n 1 m $frruvu u, u,v.-,.c. ...,,, ,,,.,,,_ """,,....,,~ .

. 1n the lahorato r
Y Prep11ratl tn-.t. zll'IC I~ porwc. in na!ure """' ,i.-.
Pure ,_J.,,.,,, •,tr.?- u ,
•l n ;c .n~ . ,i,. ·-'I '
1
oltlydrogen exh ibi ts nuclea r .
spin l5omP.rlsm ,
on ot H;e.
l he two P.lec.1r<>M. p,~ nt ,n a Hi ,,.,~;;N; i,r,,~ f1,, ~Cl
. . \
tr,~ l
Of)IX>!,lte: d1r'!>(.\ i<,rt, j,\"1
Saline hydrides are Ionic In nature .
Si,lino tlyd r'tdP.\ 3r!! fo<IT\bd t~/ l:h, '!f-(::rrH " . ,,
el~.trr,r;,, Jl1i'lt!y val!.~ . · , ...,; t ~ v.,
~ ~ .-~ \ • \

Hard w ater produces lather w 1th soa P so lution read ily.

11
Hard watr.,
<solut inn , pr()(I~
· ,
. J•Jt~
" at ~ u,y q,.,-,v_.. ..-_,j,,, -.1:t","l v~ \\

Answers
2. (a) 3.
'l 1. (b) (c) 4. Ch) 5. (c l 6. (,j) .

~NCERT TEXT.a •
·9 ,1.
Hint: See § .1.
c:
Justify the pos ,t1 o n of h d
b asis o f its electronic
.

n igu rat1un .
O O K EXERC
/ 0P,enIn ll1P, [)eriodk \:Jbl
. • e r,n !he
ISES
'
(W .,th H ., ntJa and Sol ution <'; )
,,
·...;.,.... ,:-; - ~ ,

9
tfheh na m es· of iso t opes of hydr
O fo
~,:' · 9 .2 . Write
t ·
ra 10 o t ese isotopes' ogen . Whal i~ the 1.. ,

Hint: See§ 9. . . · rr .. .,s

2 2 (i·.n Zri' ·,J -
9.3. Why does hydroge . a rJ .1atom · t
, n occur in
a monoatom ic fo rm under norm I I~ _0rm rather than in
Ans. The electronic co f' . a cond1t1ons ?
of I n tguratIon of hyd 1
. ~ne e ectron to achieve the rogen ls . It is short
s1m1lar to that of helium. Th st:ble ~lectronic configuration (ii) CO(g) + 2Hz<g)
stable electronic confi . ere ?r~, tn order to achieve the
shares Its only electro~ura!~~n s1m1lar to that of helium it
1 th at of some other hydro~en
atom and forms a diato ~
9. 4. How can t he productiom,c t~lecule H2 (H-H).
gasi'.ication ', ?~
in creas~;? di hyd rogen, obtained from 'crJal
Disc..uss tt-.e -c.'jrV:.:.-"=i'•·:~:- :..~=i (.,;', -- ~ ~ ... ~~ ~ -:: ~ - - - :.,:, ... :. -
Ans. Coal gasification' in 1
with steam at 1270 K (Bovo vhes th e reaction of red hot coke 9.7 . tf:f~f'I S Gf c.r,e:; r0 :". . .~ ~ rr:.~,.."'::: , '~J ~"' ::·.,. J-:, r:,.~~- .
sc process) .
Ans. Due to high enthal py of H-H t,;x-od (425,eZ ~J
C (s) + H2 o 1270 K CO( ) mol- 1), dihydrogen is not mut:h raa::;<.£-; e et 0'6";.- zr-J
Coal Steam g + H2(g)
Syn gas temperature. Howe-Jer, at high temp:::ra'"illf(5 or in p:-~
(Water gas) of catalyst it is quite reactr-1e and foons a la? r,:;r.-.:a ~
The production. of dihydrogen can b e .increased by reacting compounds with a large numi:r.:r ot e;~ .
'I/hat c·'.:l /CJ !.. --:::::<:;;..a- '.! -:.. f , - u::,-,,,_.[._-:;.- ..
.
carbon monoxide of syngas mi·xture w1·th stearn .m the 9.8 .
(H ) e ·,E:ctfG!"'t · Cr~,:·. s;:; , a .. ~ ' · , £: c ::: .. ::, - . ..· s.-._ :,.:;-~ :.(.; J .. -:.z . . .
presence of iron chromate as catalyst.
h1or0g<::ri ? Pr::.,/:: ':: ;:.s:·· :.":_ :. - ,. ·_- s ;--.a:. '='~,.a:-:.'!:'>.
CO (g) + H20 (g) ~ COz(g) + H2 (g) Hint: See § 9 .3.3.
FeCr0 4
9 .9.
This is called water gas shift reaction . Carbon dioxide is
removed by scrubbing with sodium arsenite solution . Ans. (i) E.1ectron-def1dent h'f drides oo rd l-~ suffioed
b
Describe th e bu lk p reparati o n of d ihyd rogen by electrolytic number of e\ectrons to form oonna\ co,,alent ~
9.5.
met hod. What is the role of an electrolyte in t his p rocess? Therefore . i n OC'der to ma\l..e u? the e«tron ~ \te'f
exist in polymeric forms such as f½"6, B4\\ 1o, tJ,n-\~11• elt.-
Hint: See§ 9.2.3[CJ (3).
Compl ete the following react ions : ot ele c t r o n s . ~ ~
(ii) Due to deficiency
9.6. I\ act as Lewis acids and fonn c.om\)lelleS ~ lew6 biSS·
(i) H (g)
2
+ MmO,)s)