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On

ID-BlockElelyen!s (Group 15-18)

SECTION -A 7. Oxidation of l- with MnOa- in acidic medium gives
product
Objectivc Typo Questions
(t) tog-
:.tvch of thfbfollowingcompoundis a bibasic (4) 10-
B. Select the correct statement
(1) H JPOC is tnbasic and reducing
(2 H3P03 is dibasic and reducing
- correct increasing order of enthalpy of OH
(3) H3P03 is dibasic and non-reducing
.aponsatron is
(4) H3P04 is dibasic and non-reducing
NHY, PH,. ASH3 (2) ASH 3,
9. Thermal hydridesof 15th roupfollows
tho order
Which of the followiö¯i51fi s ro NH3 > PH, > AsH3 > SbH3 •
(2) PH3 AsH3 < SbH3 < NHS
Huo (3) NHJ ASH: < PH3< SbH3 0
(4) NH, < PHO < ASH3 < SbH3

s:jc.lz
(3 NF (4) All of these
the correcrstatement
11. Sulphuric acid is used
ICIi more reactve than I
(I) In lead storage batteries
(2) A" rot of are reactions (2) In making
(3) HCI reacts wi Inely powdered iron an ferric 3 As a dehydratingagent c->_
Chloride is formed . CA
( All of these
12. Which of the followingis responsible for turning
i: Whichis incorrect? moist starch iodide paper blue when it is brought in
(i) Hc:o > Hero > HIC) contactwith03? AV--\
strength 1 Liberationof iodine (2) Liberationof 02
HCi0 > HCIQ > HC10a> Had, - Oxidising 3) Formationof alkali (4) All of these
power • The cusctaci@snaturzorderis •
—Enthalpyof (1) HCi02 < HC103 < HCIB D
2
dissociation
(4) HP > H2Te> H2Se > H2S - Boiling
.e__ OA of these AA_ O
Educatiohal• erviG$;PV!,

- z- Lao-
 Last Una?
' 4 SO. ts as an reacts With o' rutroqcn formed when Zn roacts
hot and conc Ht/O, is

N/ of those
Colo.'f st:/uteon dischargedtryshaking
It an solution of

ho halogen which gives With hot conc NaOH (2) Solid PCI. exist as tetr hedral cation and
oG octahedral-anion
(3 NO, has
HNO, as non-planar ih
gaseous state
25, The incorrect stateme is
st)H, > PH Rodingæint)
1) (CH3bN is pyram ,
(2) BiH, SbH, > ASH, >
(Redoong) character are neo' oxides

3 > ASH > > NH > BIH (Volatility) (3) Whe

tetrahedralmolecule, Pa
> PH, > ASH, (Hä (4) Fluorin6 not show dispropuonation
•H O A [Comp?etehydrolysis) •A reacton
the following is nuxed anhydride?
(2) N:oz
(1) T-shaped
(3)sop (4)so,
C sp»d. see-saw
7. Which of the following has maximum
(3) spy, squarepyramidal e, electronegative nature?

( 19 Tcta! number P —O- P bonds and bonds in

Pao,o is F, is Lewis acid while NH, is Lewis base. they
combune. the hybrid ate Of B and N atom in
6. 14 8. 14 duct is
1 N is tetrahedral.U ts sp%etra
20 Select the corro statement (2) N is sm. planar.B is sp' tetrahedra'
( ) H SP02 IS tnbasiC and non-reducinø (3) N is spy. tetrahedral. B is sp2 planar
can form two type of salts (4) N is spa. pyramidal.E is sp3 tetrahedralq•,
(3) In solid state.PCI, exists as an ionicsolid 29. The ayrect order of boitng points of noble gases is
He Ne Ar < Kr Xe
(4) Both (2) & (3)
(2) He > Ne >
21. Which of the following oxide o nitrogen is
(3) He Ne Kr < Ar Xe
coloured? _vg_m
(2) N20, He Ne Ar Xe Kr —
(4) All of these
. ' Which of the following compound does not have Number o! lone pairs on the central element of Z
bond.rva? is
C (1) HsPOa (2) HC104 sq
(3) H2S04
3) (4) zero
 E_ss
Olock Clemonts Gr
etching of glass by hydronuonc acid. which •40 VVhichof the is correct structure ot S2CtJ?
compound formed?

(4) Fao
NO; released cn heating
Pb(N031
3) cirys-ct
(2) KNO
NaNCh (4) NaN03

33 The correct Gtatemunt about the Oxoacids Of is

halogens G
of them are good reducing agents Hoe
(2) An of them are monobasic 42 Which of tho foliowing hydride is best reducing
(3) They may be monobasic and polybasic hydr& ?
) They have genera' rorrnulaHXO
In which of the following proper 'cs. whilo
phosphcrus resembles red phosptkus? A white preaptta:e is obtained on hydrokis
Reaction With caustic alkali PCI
12) Burning in air 13 Asa,
(3) Diss ution in CS2 C-S 447 the solid State. SO, ex t as
(1) Cyclic tetramer 2 Cyclictrimer
Whi 0 the f owing is formed when phosphoric O) Discreterndectde (4) Dirner O
a ' is heated to 600 'C? On partial hydrolysis goes
HPC), (2) H,P20, x.0F, xc0F.
(
(3) PH, and (4) and H O (4) XeF,
'Among chalcogen_ the highest tenden Cyclo S, exist in tho
is exhibited by
(1) Boat form
(1) Oxygen Sulphur
Chair
(3) Tellurium S enium
37
S
s o concentrat 4 fall on cntton
(3) Puckered ring structure s
rabnc. the spots blacken with the appearance o/ Octahedra/ arrangement
ole. This is because -e 47. The starting materaal for the preparation of
burns the cotton cross-linked %ihcones is

(2) Causes cotton to form respectve sulphates

.( Removes water fromthe fabric RSCI, SIR,
(4) Heats up the cotton Which amo the following oxides is basic in
38. The halogen having five vacant orbitals in the
natre? 406'... SO 06 Z- g;aC
Outermostshell belongs to (l) P,
(1 3rd penod (2) period (3)SbP, BIA

(3) 2"' period (4) period 49. Which or the following halogen does not
disproportionate with hot and concentrated NaOH
39. Which halogen acid has highest percentage ionic
sduton?
character? uC

(3) HCI
EdUca o
 ror

Of
Wtvch 0' 90 Whic of thu (0110%'tngcompound
Witli ICI • and drO-- respectfvely•»
xeo, (2) xoFa
oxen.
00 the aro not correctly arranged
GO i','hi
as per proportygiven in frontOf it?
H, TO H,Se L . acidic character
litoducenIINO,

(d TICI, > Incl. stability

acidic oxide among tho followingIS
y o and
o' •P•.atorn is
(4) Asp,

C.orroeto:dor o' acidityor somo hydrides is (1) IPOr.J'lPBrJ-

. 63. Thon bonds in SO, is

02
Very pure nitrogengas is prepared by heating
Nar- • sr. • Nacr A)
Tho product •X' be
0 Ing is a mixed anhydride? 3
(2)
CO (4) s,Cl,
reaction which producos a qtcen coloured
Incorrect statement about molecule
product ccxo 1) has Six P-O-P bonds
h CLIO/ (2) NILNOa is hydcotysedto H3P04 and HAP,O,
(3) It does not contain P—P bond

G7, have non-linear ape

(2) KrF;.
(3) BiOCl
known as Which one ot the following is not a psekio halide?
(1) O RCOCY
(2 Phosphinic acid
(3) Diphosphoncacid (4) Diphosphonicacid
58. Ch'ocino on reaction with cold water gives The number of o and 't bonds in P. 0€, is
7
1) 120. 37t (2 120. ox O
(2) Chloric acid (3) 120.5% (4) 150, p
(3) i lypochlorousacid 70. Mostpdaarnong the followingis
(4) Perchloncacid CR (2) HCA
O

Servyccs
ji0@05
 on With hypochlonte ion on heating. orthophosphorous acid

HYPO. and PH,

(3) PH,
the reaction wou.'dresu't jn the XeF, react With F
c' CL gas7 . ISbF.r
(1) . (SbF.tO (2)

OtxeF,y•. (4) O
62. Correct acidic na:ure order

(3) H,po. > Hypo

(4) H,PO, > H,PO:
83 Which of the meta: forms NH. NO, when
react Withvery dib HNO.?
7.3 Which One of the following SPOCieS is likely to
V•ave a Irnear
The numberOf S = O bonds in H7S:O, is
o
following On heating wou d mve
b-zotung gas?
The correct order Of Lewis basc is
o
Cu • HNO,(conc.)
75 Yeatment with forms a
NCI, NF, > >
Napa •s O NA2SP, 0G
'3) nazsos (4) Nag;
75 the is used for prep
86 for-inedwhen CI is treated with excess

KEF: (1) and (2) HCIO

reactsWitheIcess CI togive NCI, ariHCl
87 PCL in solid state exists as

7E The der Waa.ts are greatest In G

3 (4) or these Q
The basicityof pyrophosphorusacid ,P20s)
(2) Krypton
(1) a SQ3
+ COZ
(1) Amrnoniurn carbonate
89
02 oxidizing agent among the following

(3) Eiurate (1) cto,- (2) 10,-

(3) Has (4 Bro. -
• Sf rviCes pyt%Ltd.Regg. '0005 50
 Las: Leap
72 ( G' •
bond angle?
of the has bond? 100 Which rno'ecule has m:nirnum
(1) H.spe NH, \ on. t 12)HP
OH.sq (C) At theso
I •s 101 Tho r.hapo 01 XeFe •s //
correct bond eno.• h."Co
) Octahedral /
(2 Pentagonal b•pyramvdal
D'%totteaoctahedral
cotrect statement SO
(4) Square pyramdal
reduction
From wt"ch compound iod'no displaces chlorine?
CU bleaches by oxidation
by ondatton
(3) Naa O KCIO,
103 Identify the incorrect statements among the
93
— fokh%ng
PE'. contains Caton (1) PH, is a colourlessgas Withrottenrtshsmolt
Ovo!e momentof SO, gas O (2) CT, reacts WithoxcesS of NHS to give and
0 0,. NO. aro earQrnoqnct'Cmolecule
i.: H, PO, is stronger ac%l than HPC) Br;, reacts with hot and conc NaOH to give
having same hybridization and same NaBr. NaBr02 and
geometry (4) Ozone oxldtses SO;, to SO,
t 04 In ring test or nitra•.cion. charge Of Fe and NO in
(3) CIF,. NHr sq brown ong complex respectively G
95 Heating ammomurn dichroma e and ammonium (1) •2 and O ( +1 and
, carbonate produces respectively co (3) •1 and O •2 and —1
105 F ina the Corr ma
gond - 109'28"
A the given oxo acids, tho acid CI Disproportionates with hot
h'ghest K, conc NaOH
(21 HBroH1 0f VVeakeracid than HOBr
(4) A" have equal Ka (4) CIF, hybndtzabon
97 Setect the Incorrect statement about ICE Ono mote of calcium phosphide on treatment with
(I) It is anhydnde Of HNO, excess of water gives

12' It IS a powerful oxjdizing agent (1) One

It contains one [N OJ bond 2) Two moles of phosphonc acid
(4) A" of these 3 Two "des of phosphine
0B Colour Of iodine solution is disappeared by shaking (4) One mole of phosphorus pentoxide
't With aqueous of 107. Which Of the following pairs Of species react with
water to produce colourless gas that gives white
(4) Nap, fumes With HCI?
(3 Na,SaOs
(1) Calcium chloride and calcium Cyanamide
91 The numberof P-O-P bonds in cyclic
metaphosphoric acid is (2) Calcium carbide and alumimurncarbide
( Magnesium nitride and calcium nitride
o
Four (4) Calcium c.arbide and calcium mtride
Aaki
Ltg.@gg, liC00S
 Eiorner•.ts Errzup 15-1

o' the follooing correct about Contact 116 Most votatdo halogen aed vs
voc-ess for the manufacture •sulphuncaod? HCi (2) HBr
a Is used tor catalytic oxidat'on o! SC)Z to
11T Least bond anglo is possesod by
b SO. ptoduced which absorbed in ter
01120
d SO, is in 'troted Sul add \ oav
on:y c (4) coz
as d 118, Correct order of botbng point is
How many P —H and O —H bonds rcspoctivel (1) Hzs Hzso H2TO
aro present in H, rndecule?•

H,se
Ht cannot be proparod by the action of K' and 119. Which of the following cannot be for drying
. H,SO, because
(1) much weaker acid tnan .(2PH2SO,
( of these
(3) H2SO. is a dehydratingreagent C,Qoob •t
HI is less volatde than Moleculo Shapo
Which of the reaction is not feasible? XeF SPY Octahedral
2NaBr sps Pyramidal
sep'd? Square planat—
2KlO, 2KClO, xeOF, sp'cf Square wrarnidal
are feasible I?IÄ Which of the followingmatch is incorrect? 11
Wnicb the following is the anhydride of HCIO,? Moleculcnon Shape Bond anglo
(1) Ciao 109%
) NIL Tetrahedral
(3CIO, g) CIA
Cornp'etehydrolysisof forms a compound Tetrahedra' 103%
whtch explodes violently in dry state. 'A'
(2) xe0fz (3 CIO; Pyramidal 1032B'
3) XeOF, (4)
Trigonal planar 120'
. XeF2 reacts With to form
[XOF)• (2) txcFJI• 122. Correct order among the given belov.' is
(4) XoF4 (AtornL%onic radii)
The strongest oxidizing agent among the fotky.v•ng First ionizationenergy)
Ill. Oxidizing )

(Bond energy)

(2) 111
(3) ctoa
(4) Ati have same oxidizing power (4) '.11. Ill.

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