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Procedia CIRP 29 (2015) 432 – 437

The 22nd CIRP conference on Life Cycle Engineering

Life Cycle Assessment of CRT, LCD and LED Monitors


Vikrant Bhakar, Aashray Agur, A. K. Digalwar, Kuldip Singh Sangwan*
a
Birla Institute of Technology and Science, Pilani, INDIA - 333031

* Corresponding author. Tel.: +91-1596-515730; fax: +91-1596-244183. E-mail address: kss@pilani.bits-pilani.ac.in

Abstract

The increasing consumption patterns in emerging economies like India and China with half the world population has increased the
environmental concerns. E-waste in these countries is rapidly increasing and monitor is one of the major contributors to it. The paper aims at
assessing the life cycle environmental impact of Cathode Ray Tube (CRT), Liquid Crystal Display (LCD) and Light Emitting Diode (LED)
monitors. Life Cycle Assessment (LCA) of three widely used monitors has been performed based on the international standards of ISO 14040
series. The LCA was constructed using Umberto software version 5.6 and expressed with both CML (Centrum voor Milieuwetenschappen)
2001, mid-point assessment method and Impact 2002+, end point assessment method. This study is expected to guide policy makers in
government to improve e-waste management strategies and also it will create awareness among the user. The monitor manufacturers may
leverage the study to improve the environmental impact of these products. Sensitivity analysis for the use phase has been performed to confirm
the robustness of results.
©
© 2015
2015 The
The Authors.
Authors. Published
Published by
by Elsevier B.V. This is an open access article under the CC BY-NC-ND license
Elsevier B.V.
Peer-review under responsibility of the International Scientific Committee of the Conference “22nd CIRP conference on Life Cycle
(http://creativecommons.org/licenses/by-nc-nd/4.0/).
Engineering.
Peer-review under responsibility of the scientific committee of The 22nd CIRP conference on Life Cycle Engineering

Keywords: life cycle; environmental impact assessment; end-of-life; e-waste management

1. Introduction less than 20%. It is estimated that out of 260 million display
units expected in market by 2014, major contribution will be
In recent times, the access to personal computers (PCs) has of LED only. Major benefit associated with LED display is its
increased many folds. One of the major components of these lower power consumption during use phase.
PCs is monitor. The monitor technology has rapidly changed Electronic Industries Association of India (ELCINA) has
in last two decades, from cathode ray tube to liquid crystal estimated that commercial sector accounts for 80% of total
display, plasma display, light emitting diode, organic light market penetration of computer and IT hardware in India. The
emitting diode, etc. Moreover, the increasing penetration of association report on consumer behavior highlights that at
PCs in emerging economies like India and China with half the corporate/business level only 6% of the organizations were
population of the world will increase the number of monitors found to be disposing off their computers in environment
required worldwide. For example, in terms of sheer numbers, friendly manner [5]. A monitor generates many environmental
the Indian PC market is higher than that of many of the impacts throughout its life cycle. The manufacturing of a
developed countries [1]). Dwivedy and Mittal [2]) has monitor is a complex process, involving many hazardous
predicted that the PC penetration in India could overtake that materials as well as precious metals. The use phase of a
of US (highest PC penetration) by 2046, while the number of monitor consumes considerable amount of electricity, and
obsolete computer inventory in India will be two times that of End-of-Life (EoL) phase can seriously affect human health, if
US by 2022. not properly disposed off. For example, liquid crystal mixture
Monitors consume a significant amount (15 to 35%) of of LCD and LED monitors contains benzene, cyano-group, F,
energy in PC system [3]. According to EE Times [4], it is Cl, etc., which are potentially harmful to human health and
estimated that by 2014-15 market share of LED monitors will environment [6]. Similarly, plastic housing and frames contain
increase to 80% and LCD market share will come down to brominated flame retardants such as Poly Brominated Di-

2212-8271 © 2015 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license
(http://creativecommons.org/licenses/by-nc-nd/4.0/).
Peer-review under responsibility of the scientific committee of The 22nd CIRP conference on Life Cycle Engineering
doi:10.1016/j.procir.2015.02.003
Vikrant Bhakar et al. / Procedia CIRP 29 (2015) 432 – 437 433

phenyl Ethers (PBDE) and Poly Brominated Bi-phenyls 2. Materials and methods
(PBB), which are harmful to brain, kidneys, nervous system,
liver, endocrine and reproductive systems [6]. A typical desktop PC is an assembly of three main
Complex components used in monitors such as PWB components, i.e. monitor, CPU and key board. With
(Printed Wiring Board) have a large variety of precious metals technological innovation in the recent past, there is a drastic
such as gold, silver and hazardous materials like lead (Pb) [7]. improvement in each of these components especially in the
A recent review has revealed that there is high concentration monitors. CRT monitor is the oldest and heaviest and requires
of Pb, PBDEs, PCDD (Polychlorinated di-benzo dioxins) and maximum power amongst the three monitors. LCD monitor
PBDD (poly brominated di-benzo-p-dioxins) in air, bottom uses different technology and is sleeker compared to CRT. It
ash, dust, soil, water and sediments in WEEE recycling areas uses Cold Cathode Fluorescent Lamp (CCFL) as its light
of the developing countries as compared to developed nations source in the backlight unit and has liquid crystals sandwiched
[8]. The ancillary materials like nitrogen tri-fluoride (NF3), between the glasses of its screen. LED monitor in principle is
which is used during the manufacturing process of LCDs to an LCD monitor as it has the same display screen, but uses
clean the vacuum chambers, can cause a lot of environmental light emitting diode instead of CCFL as light source in the
impact, as it is a greenhouse gas with a global warming backlight unit [17]. The environmental performance of the
potential (GWP) 17,000 times more potent than carbon three monitors has been done by conducting an LCA study
dioxide (CO2) [9]. based on the international standards of the ISO 14040 series
The increasing awareness of environmental protection and [13][18] [19].
the possible negative effects due to the activities at every stage
of a product’s life cycle, i.e. production, distribution, usage, 2.1. Goals and Scope
and disposal, have led to the creation of plethora of concepts,
strategies, approaches, tools, etc. to assess and understand the 2.1.1. Objectives of the Study
environmental impacts of products throughout their lifecycle The objective of the study is to assess and compare
[10]. Life Cycle Assessment (LCA) of products throughout quantitatively the environmental impacts of CRT, LCD and
various phases is one such approach used to find the LED monitors on different parameters covering various
environmental impact of products during pre-manufacturing, aspects of nature, i.e. human health, ecosystem quality,
manufacturing, use, and disposal. This paper aims at assessing climate change, resource depletion, etc., and thereby to find
the environmental impact of high growth market segment of the monitor which causes the least environmental burden.
PC monitors. The paper also compares the most prevalent
CRT (Cathode Ray Tube) monitors in developing countries, 2.1.2. System Boundaries
widely used LCD (Liquid Crystal Display) monitors in The scope of the present study is a traditional LCA from
developed countries and fast emerging LED (Light Emitting cradle to grave, i.e. from the extraction of the various
Diode) monitors. resources used in the production of these monitors to the final
LCA is an investigative instrument that incorporates all the disposal at the end of life. The production data of various
environmental impacts of a product, process and human parts of the monitor was obtained from the Eco-invent
activities from raw material extraction, production, use phase database 2.2. However, due to lack of availability of data with
and waste management [11]. LCA is the internationally respect to transportation between various distribution
standardized environmental assessment method [12] with a channels in India because of diversified and complex
methodological framework for estimating and assessing the transportation system, transportation has not been included in
environmental impacts attributable to the life cycle of a the system boundary. Indian electricity mix has been created
product, such as climate change, stratospheric ozone based on the data provided in Table 1.
depletion, tropospheric ozone (smog) creation, eutrophication,
acidification, toxicological stress on human health and 2.1.3. Functional Unit
ecosystems, resource depletion, water use, land use, noise, etc. The functional unit of the study is taken to be a standard
[13]. Few LCA studies have been conducted to assess the monitor with a diagonal viewing area of 15 inches, working
environmental impacts of CRT and LCD monitors at different 240 days a year for 6 year in which five hour normal
geographical locations [9] [14] [15] [16]. Such studies are not operation, two hour sleep mode and one hour standby mode.
available for emerging economies which have poor e-waste The CRT monitor closest to that diagonal viewing area is a 17
management and poor quality of energy mix. This paper inches CRT monitor which has diagonal viewing area of 15.9
provides LCA of CRT, LCD and LED monitors as well inches [20]. The other possible design parameters for
provides a comparative assessment of these monitors in an monitors are brightness, resolution, weight and power
Indian context on different parameters. Further, the results are consumption [16]. Kim and Kara [16] have pointed out the
expressed using CML 2001 and Impact 2002+ methodologies. limitations of functional unit as the products are sold and
Sensitivity analysis has also been performed to check the bought as a whole unit and not based on the functional unit.
robustness of the results. This paper is expected to help the
industry in general and Indian industry in particular to take
better decisions during purchase and replacement of monitors.
It will also guide the government policy makers to develop
better policies for e-waste management.
434 Vikrant Bhakar et al. / Procedia CIRP 29 (2015) 432 – 437

Table 1 Composition of Indian electricity mix (Source: CEA, Govt. of India, effect is least in the human health category. The next
2009-2010) prominent contributors are metals. Metals have high effect on
Energy source Electricity produced in 2009-2010 ecosystem quality and human health. Various plastics in CRT
GWh Percentage
monitor have negligible effect on the ecosystem quality. The
Coal + lignite 539.501 67.9
Oil 7.878 1.0 effect of metals on ecosystem quality and human health is
Natural Gas 93.159 11.6 about 30-35%.
Hydroelectricity (large) 109.255 13.6
Nuclear power 18.636 2.3
Wind power 18.187 2.3
Biomass power 7.001 0.9
Hydroelectricity (small) 8.211 1.0
Total 801.828 100.0

2.2. Life Cycle Inventory

Major source of the inventory data for the study was


Environmental Protection Agency (EPA) of USA and
published literature. The EPA has published bill of primary
materials for 17 inches CRT monitor and 15 inches LCD
monitor. For the purpose of uniformity in the data for the use
phase, the power consumption of each of the monitors at 230 Fig. 1 Environmental impacts of an CRT monitor production
VAC and 50 Hz has been taken from the Hewlett Packard
(HP). 3.1.2. Environmental impact of LCD monitors using end
point assessment method
2.3. Life Cycle Impact Assessment (LCIA) The LCD end point assessment results shown in Fig.
reflect that PWB is the major impact contributor. The
For the impact assessment, two well known LCIA methods contribution of backlight is also noteworthy in LCD monitors.
were used: the Impact 2002+ (End point) and the CML 2001 Backlight consists of CCFL and light guide. Plastics, metal
(Mid point). The categories under the Impact 2002+ are and glass contribute very low in all categories. The rest of the
climate change, ecosystem quality, human health and parts such as color filter pigments, polarizers, alignment layer,
resources, while those under the CML 2001 methodology are spacers, adhesives, etc. are placed under the misc. group. The
Acidification Potential (AP), Climate Change (CC), metals used in LCD monitor consist of steel, copper,
Eutrophication Potential (EP), Freshwater Aquatic Eco- aluminum, tin, and lead. Similarly, plastics consist of
Toxicity Potential (FAETP), Freshwater Sediment Eco- polycarbonate, ABS, Polyethylene ether (PEE), Tri-phenyl
Toxicity Potential (FSETP), Human Toxicity Potential (HTP), phosphate (TPP) and Polyethylene tere-phthalate (PET). The
Ionizing Radiation (IR), Malodours air, Marine Aquatic Eco- contributing trends of plastics and metals in LCD monitor are
Toxicity Potential (MAETP), Marine Sediment Eco-Toxicity very similar to that of CRT monitor. In the CRT monitor, the
Potential (MSETP), Photochemical ox (summer smog), plastic set of LCD has a small effect of less 1% on the
Abiotic Depletion Potential (ADP), Ozone Depletion Potential ecosystem quality. Similarly, the contribution of metal parts is
(ODP), and Terrestrial Eco-toxicity potential (TETP). higher on the ecosystem quality and human health as
compared to the other two categories. The effect of the
3. Results and Discussion backlight is around 20% for ecosystem quality and human
health measures.
3.1. End Point Assessment
3.1.3. Environmental impact of LED monitors using end
3.1.1. Environmental impact of CRT monitors using end point assessment method
point assessment method
The results of the environmental impact assessment of the The results of the impact assessment of the LED monitor
CRT monitor using Impact 2002+, an end point assessment are shown in the Fig. 3. The major part having significant
method, are shown in Fig. 1. As observed from the Fig., the contribution to each of the impact categories is again PWB.
major parts which have a significant contribution to various The metals consisting of steel, copper, aluminum, tin, and
categories are Printed Wiring Board (PWB), plastics, metals, lead contribute around 15% to the ecosystem quality and
and glass. The rest of the parts such as phosphors, aquadag, human health categories and around 10% to the climate
ferrite, magnetite, shield assembly, etc. are placed under the change and resources categories. Plastics consisting
misc. category.
It is evident that PWB has the major impact in all the four
impact categories. It affects climate change the most and its
Vikrant Bhakar et al. / Procedia CIRP 29 (2015) 432 – 437 435

the climate change, acidification and abiotic depletion. Use


phase is responsible for more than 70% contribution to
climate change and abiotic depletion. The EOL phase
contributes around 10% to the FAETP, FSETP, MAETP, and
MSETP categories.

Fig. 2 Environmental impacts of an LCD monitor production

Fig. 4 LCA results of CRT monitor across all the phases

3.2.2. LCA results of LCD monitor using midpoint assessment


method

Fig. 3 Environmental impacts of an LED monitor production

polycarbonate, ABS, Polyethylene ether (PEE), Tri-phenyl


phosphate (TPP), poly-methyl meth-acrylate (PMMA) and
Polyethylene tere-phthalate (PET) contribute around 12% to
climate change and resources categories. Contribution of
plastics to ecosystem quality is almost negligible. The effect
of diodes in LED has significant impact on all categories, Fig. 5 LCA results of LCD monitor across all the phases
even though its weight is only 35 grams. The contribution of a
strip of 100 diodes is higher than that of entire group of Similar to CRT results, manufacturing is the dominating
metals to the climate change and the resources categories. phase across all impact categories except climate change and
abiotic depletion as shown in Fig. 5. The use phase dominates
3.2. Mid Point Life Cycle Assessment in climate change and abiotic depletion categories and also
has a significant contribution of more than 40% to
Midpoint assessment for the three types of monitors has acidification potential. EoL phase contributes more than 30%
been done using CML method to assess manufacturing to FSETP, FAETP and MSPTP categories and more than 20%
(including pre-manufacturing), use and end-of-life phases. to MAETP category. In all these four categories, the effect of
Detailed results of the assessment of CRT, LCD and LED EoL phase is more pronounced than the use phase.
monitors for all the fourteen categories across the three phases
is given in Appendix. 3.2.3. LCA results of LED monitor using midpoint assessment
It is observed that in term of absolute values, the method
malodours air contributes very high. Therefore, this category The manufacturing phase dominates in all the categories
has been excluded from the graphical representation. Its for LED monitors as shown in Fig 6. The LED monitors
highest contribution is for CRT in all phases. Within CRT, its consume less power, so the effect of use phase is very low in
contribution is highest in manufacturing phase followed by most of the categories except acidification potential, climate
use and EOL phases. change and abiotic depletion categories. It contributes
negligibly to all eco-toxicity categories. The EoL phase effect
3.2.1. LCA results of CRT monitor using midpoint significantly in term of FAETP, FSETP, MAETP, and
assessment method MSETP and also to some extent in term of acidification
Manufacturing of the CRT dominates the impact in 10 potential and climate change, unlike CRT and LCD monitors.
categories as shown in Fig. 4. CRT use has higher potential to
436 Vikrant Bhakar et al. / Procedia CIRP 29 (2015) 432 – 437

3.4. Sensitivity analysis

To check the robustness of the results, a sensitivity analysis


has been performed on the impact assessment data. A typical
sensitivity analysis is performed by changing one of the input
independent variable and at the same time measuring its
influence on the dependent variable(s). It measures how
different values of an independent variable will impact a
particular dependent variable under different conditions.
Sensitivity analysis is very useful for measuring the impact of
two or more than two assumed independent variables. In this
case Indian electricity mix was replaced with the German
electricity mix [21] to measure robustness of the model as
Fig. 6 LCA results of LED monitor across all the phases shown in Table 2.

3.3. Comparison of CRT, LCD and LED Monitors Table 2 German [21] and Indian Electricity mix [22]
Energy source German Indian
The analyses in the preceding sections dealt with each of Electricity Electricity
the monitors independently using different parameters. This Mix mix
section compares the three monitors on the impact categories Coal + lignite 43.24% 67.9 %
using CML 2001 methodology. The climate change potential Oil 1.42% 1.0 %
Natural Gas/gases 14.94% 11.6%
during all the three phases of life cycle is more for CRT
Hydroelectricity 2.96% 13.6%
monitors (Fig. 7). It also shows that climate change potential (large)
of LED monitors during manufacturing phase is more when Nuclear power 23.76% 2.3%
compared to LCD monitors and the impact is comparable Wind 10.37% 2.3%
during EOL phase. Only during the use phase the impact of power/Renewable
LED monitors is less. The effect of various types of eco- Biomass power 1.74% 0.9%
toxicities during all the three phases of lifecycle shows that Hydroelectricity 1.57% 1.0%
the FSETP is the major contributor, followed by FAETP and (small)
MSETP. The LCD monitors have more eco-toxicity potential Total 100% 100.0
as compared to LED monitors but the values are close to each
other. The effect of CRT monitors is more pronounced. It is Fig. 8 shows that the effect of change of electricity mixes
interesting to observe that the trend for all six types of during the three lifecycle phases. It clearly indicates that with
toxicities is similar for three types of monitors, i.e. CRT the change of electricity mix, the trends are similar across the
followed by LCD and LED. The effect of CRT monitors on life cycles of monitors. The German and Indian electricity
environment is much more than LCD and LED monitors. The mixes are giving similar values for manufacturing and EoL
percentage effect ranges from 57 to 68 percent across phases where the electricity consumption is low. However,
categories. The percentage effect for LCD monitors ranges there is a change in the use phase as seen from Fig. 8, but the
from 18 to 22 percent and for LED monitors the range is 13 to trend is similar. The change is high for CRT and negligible
21 percent. The significant differences between LCD and for LED monitors.
LED monitors are in term of acidification potential, climate
change, abiotic depletion, and maladours air. A CRT monitor
as compared to LED monitor affects the environment
approximately three times throughout its life cycle.

Fig. 8 Effect on life cycle stages (eco indicator 99 total impact points)
with German and Indian electricity mix

Fig. 7 Climate change potential of three monitors (Kg Co2 Eq.)


Vikrant Bhakar et al. / Procedia CIRP 29 (2015) 432 – 437 437

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Appendix: Detailed results of impact categories with CML 2001


Impact Categories Unit Manufacture Use End Of Life
CRT LCD LED CRT LCD LED CRT LCD LED
Acidification Potential kg SO2-Eq 1.65E+00 5.58E-01 5.55E-01 2.08E+00 4.42E-01 1.59E-01 1.04E-02 2.99E-03 3.96E-02
Climate Change kg CO2-Eq 2.00E+02 9.06E+01 9.77E+01 5.37E+02 1.14E+02 4.10E+01 1.43E+01 6.94E+00 6.98E+00
Eutrophication Potential kg PO4-Eq 1.87E+00 7.59E-01 7.42E-01 8.90E-01 1.89E-01 6.79E-02 3.88E-03 2.14E-03 2.16E-03
Freshwater Aquatic Eco-toxicity kg 1,4-DCB 4.43E+02 1.77E+02 1.70E+02 1.32E+02 2.81E+01 1.01E+01 7.81E+01 8.98E+01 9.03E+01
Freshwater Sediment Eco-Toxicity kg 1,4-DCB 8.45E+02 3.36E+02 3.25E+02 2.73E+02 5.81E+01 2.09E+01 1.94E+02 2.24E+02 2.25E+02
Human Toxicity kg 1,4-DCB 3.15E+02 1.40E+02 1.19E+02 3.47E+01 7.38E+00 2.65E+00 7.47E+00 3.79E+00 3.81E+00
Marine Aquatic Eco-toxicity kg 1,4-DCB 2.55E+02 1.01E+02 9.71E+01 7.91E+01 1.68E+01 6.04E+00 3.00E+01 3.54E+01 3.57E+01
Marine Sediment Eco-toxicity kg 1,4-DCB 3.83E+02 1.52E+02 1.46E+02 1.26E+02 2.69E+01 9.64E+00 6.70E+01 7.86E+01 7.91E+01
Terrestrial Eco-toxicity kg 1,4-DCB 3.71E-02 1.58E-02 1.42E-02 1.35E-02 2.87E-03 1.03E-03 8.88E-05 2.74E-05 2.76E-05
Ionizing Radiation DALYs 1.45E-06 6.34E-07 7.24E-07 6.27E-07 1.33E-07 4.79E-08 9.24E-09 2.22E-09 2.24E-09
Malodours Air m3 air 2.14E+06 6.75E+05 7.25E+05 2.02E+06 4.31E+05 1.54E+05 1.12E+04 5.33E+03 5.37E+03
Photochemical Ox (Smog) kg ethylene 2.84E-02 1.29E-02 1.33E-02 1.08E-02 2.29E-03 8.22E-04 1.13E-04 4.20E-05 4.23E-05
Depletion of Abiotic Resources kg antimony 1.39E+00 6.10E-01 6.60E-01 3.69E+00 7.85E-01 2.82E-01 9.93E-03 2.00E-03 2.02E-03
Stratosphic O3 Depletion(40) kg CFC-11 2.46E-05 1.02E-05 1.07E-05 1.20E-05 2.54E-06 9.13E-07 1.58E-07 3.38E-08 3.40E-08

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