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Zvonimir Jankovi C, Jaime Sieres, Fernando Cerdeira, Branimir Pavkovi C
Zvonimir Jankovi C, Jaime Sieres, Fernando Cerdeira, Branimir Pavkovi C
a r t i c l e i n f o a b s t r a c t
Article history: This paper presents the mathematical modeling of a liquid-to-water heat pump with scroll compressor,
Received 23 June 2017 brazed plate heat exchangers, additionally built-in liquid-vapor heat exchanger (LVHX) and a desuper-
Revised 12 October 2017
heater for domestic hot water (DHW) production. The refrigerant is the zeotropic mixture R407C and
Accepted 3 November 2017
the liquid used in the outdoor loop is a propylene-glycol water mixture. Developed mathematical model
Available online 9 November 2017
is validated on experimental data and used as a tool for the heat pump analysis. Simulation results are
Keywords: obtained for the effect of the degree of superheat at the evaporator outlet, the subcooling degree at the
Heat pump condenser outlet, the effect of using or not the LVHX and the effect of using or not the desuperheater
Mathematical model for DHW for typical operating conditions of liquid-to-water heat pumps (EN-14,511-2, 2011) in the cool-
Desuperheater ing and heating modes (low and medium temperature applications). Results show that the effect of the
Liquid-vapor heat exchanger degree of superheat or the decision on the suitability of using or not a LVHX may be different for heat
Experimental results
pumps that include or not a desuperheater for DHW. In particular, if DHW is a priority, the use of a
LVHX is recommended because it leads to higher COP (or EER) values as well as to higher DHW heating
powers.
© 2017 Elsevier Ltd and IIR. All rights reserved.
Mots-clés: Pompe à chaleur; Modèle mathématique; Désurchauffeur; Èchangeur de chaleur liquide-vapeur; Données expérimentales
https://doi.org/10.1016/j.ijrefrig.2017.11.005
0140-7007/© 2017 Elsevier Ltd and IIR. All rights reserved.
Z. Janković et al. / International Journal of Refrigeration 86 (2018) 282–291 283
Fig. 1. Schematic representation of the heat pump with LVHX (cooling and heating mode). (Numbers in square brackets are related to refrigerant states in the model
description).
pump is reversible and includes a scroll compressor, brazed plate The heat losses in refrigerant pipes are negligible (pipes are
heat exchangers (indoor and outdoor heat exchangers in the func- well insulated);
tion of condenser/evaporator and desuperheater), a coaxial LVHX, a Heat transfer between the heat exchangers and surroundings is
4-way valve and a thermostatic expansion valve. The refrigerant is negligible;
the zeotropic mixture R407C. The liquid used in the outdoor loop Pressure drops in the refrigerant pipes between main compo-
is a 15% of propylene-glycol and water mixture (mass basis). nents are negligible.
The compressor is a hermetic scroll compressor with a dis- Total heat transfer coefficients for all heat exchangers are calcu-
placement of 9.44 m3 ·h−1 for a rotational speed of 2900 rpm. The lated according to the following equation:
desuperheater has 30 effective plates. Indoor and outdoor heat ex-
1
changers are identical brazed plate heat exchangers with 20 effec- Uheatexchanger = . (1)
tive plates.
1
αrefrigerant + λewall + α 1
wall secondflowmedium
In the heating (cooling) mode of operation of the heat pump, In the following sections the model equations are given for the
the outdoor heat exchanger behaves as an evaporator (condenser), heating mode of operation; i.e. the outdoor and indoor heat ex-
whereas the indoor heat exchanger behaves as a condenser changers behave as the evaporator and condenser, respectively. For
(evaporator). the sake of brevity, the equations for the cooling mode of op-
The LVHX is used with the goal of analyzing the effect on the eration are not given, but they can be easily obtained by intro-
system performance of using or not this heat exchanger. According ducing minor changes in the model equations. Essentially, these
to Fig. 1, when the LVHX is used (not used) the valves A1, A2, B1 modifications involve interchanging the condenser and evaporator
and B2 are opened (closed), and the valves A3 and B3 are closed refrigerant-side equations (for heat transfer and pressure drop) for
(opened). the indoor and outdoor heat exchangers, respectively. The mathe-
The 4-way valve is used for the reversion between the winter matical model has been programmed using Engineering Equation
and the summer cycles. Solver (EES) (Klein, 1992–2016). Heat transfer correlations for cal-
culating the heat transfer coefficients in the evaporator, condenser,
3. Thermodynamic and heat transfer model of the heat pump desuperheater and LVHX are summarized in Table 1.
The mathematical model takes into account specific data and 3.1. Hermetic scroll compressor
dimensions of components with goal to predict the actual operat-
ing conditions of the heat pump, which follows the model descrip- From the manufacturer’s data two efficiencies were defined as
tion published by researches Janković et al. (Janković et al., 2016). a function of the pressure ratio (PR) to predict the refrigerant mass
The following general assumptions are made: flow rate and electric power for the compression process.
Z. Janković et al. / International Journal of Refrigeration 86 (2018) 282–291 285
Table 1
Heat transfer coefficient correlations.
Authors Correlation
.12−0.2log10 R p
Cooper (Cooper, 1984) α = 55 p0red (−log10 pred )−0.55 q˙ 0.67 Mref
Thonon (Thonon, 1995) Nu = 0.2946 Re0.7 P r 1/3
Mancin et al. (Mancin et al., 2011) α= αA2 + αNu
2
wall )
)
( ρρVL )
0.3685 μL 0.2363
(1 − μμVL )
2.144
αA = αLO (1 + 1.128 X 0.817
( μV ) P r −0.1 )
α LO from Thonon (Thonon, 1995) using liquid properties with the total flow rate
1
Petukhov (Petukhov, 1970) f =
(0.79 ln(Re )−1.64)2
f /8 Re Pr
Gnielinski (Gnielinski, 1976) Nu = √
1.07+12.7 f /8(P r 2/3 −1 )
Petukhov and Roizen (Petukhov and Roizen, 1964) Nu = N ucil 0.86 ( ddouter )−0.16
inner
The volumetric efficiency was obtained by a simple regression 3.3. Evaporator (outdoor heat exchanger)
analysis, with a coefficient of determination R2 of 96.5%:
The total heat transfer rate for the evaporation process is eval-
ηvol = 1.04783 − 0.028886 · PR. (2)
uated by applying energy balances for the refrigerant flow and for
For the overall efficiency, a higher order polynomial fit as a the propylene-glycol water mixture
function of pressure ratio was obtained, with a coefficient of de-
Q˙ E = m˙ ref · (h[8] − h[7] ), (9)
termination R2 of 91.6%:
Q˙ E = m˙ E,PGW · cp,E,PGW · (TPGW,E,in − TPGW,E,out ), (10)
ηov = 0.257 + 0.366 · PR − 0.09517 · PR2 + 0.00679 · PR3 . (3)
Q˙ E = Q˙ E,boil + Q˙ E,sup . (11)
Pressures at the compressor’s outlet and at inlet define the
pressure ratio: The evaporation heat transfer process is observed in two parts:
heat transfer in the boiling region and heat transfer in the super-
PR = p[2] /p[1] . (4)
heated region. Researches Dutto et al. (Dutto et al., 1991) and Pri-
The refrigerant state at the compressor outlet was obtained us- mal et al. (Primal et al., 2004) suggested a model with the log-
ing the next two equations arithmic mean temperature difference for both parts. The same
method is applied in Longo and Gasparella (A.G. Longo and Gaspar-
h[2]is − h[1]
ηis = , (5) ella, 2007) for the vaporization process by applying the following
h [2 ] − h [1 ] equations:
Q˙ E
ηis = 0.8302 − 0.0332 · PR − 6.551 · 10−5 · Tdew@ p[1] , (6) TE,ln = , (12)
Q˙ E,boil Q˙ E,sup
TE,ln,boil + TE,ln,sup
where the presented coefficients given in Eq. (6) were obtained
AE = AE,boil + AE,sup , (13)
from linear regression of experimental results as a function of the
pressure ratio and the dew-point temperature at the compressor where the boiling heat transfer rate is obtained as
suction pressure. The refrigerant mass flow rate (m˙ ref ) is calcu-
Q˙ E,boil = AE,boil · UE,boil · TE,ln,boil , (14)
lated from the compressor displacement (V˙ comp ), the volumetric
efficiency (ηvol ) and the refrigerant density at the compressor inlet TPGW,E,m − TE(x=1,p≈p[8] − TPGW,E,out − T[7]
TE,ln,boil = , (15)
(ρ [1] ): TPGW,E,m −TE(x=1,p≈p[8])
ln TPGW,E,out −T[7]
m˙ ref = V˙ comp · ηvol · ρ[1] . (7)
and for the superheating zone
The electric power of compressor (W˙ comp,elec ) is obtained from
Q˙ E,sup = AE,sup · UE,sup · TE,ln,sup , (16)
the overall efficiency and the isentropic power
TPGW,E,in − T[8] − TPGW,E,m − TE(x=1,p≈p[8])
W˙ is m˙ ref · h[2]is − h[1] TE,ln,sup = . (17)
ηov = = . (8) ln
TPGW,E,in −T[8]
˙
Wcomp,elec W˙ comp,elec TPGW,E,m −TE(x=1,p≈p[8])
The idea is to use only compressor manufacturer data about The total heat transfer coefficients for the boiling region
overall efficiency in order to calculate the input electric to drive (UE, boil ) and for the superheating region (UE, sup ) are calculated ac-
the compressor. The manufacturer overall efficiency data is based cording to Eq. (1). The temperature of the propylene-glycol water
on the compressor isentropic power, so the total engaged electric mixture (TPGW, E, m ) at the end of the boiling region (start of the
power is obtained by dividing isentropic power of the compressor superheated region) is calculated from an energy balance:
with overall efficiency from Eq. (8).
T[8] − TE(x=1,p≈p[8])
TPGW,E,m = TPGW,E,in − m˙ ref · cp,ref · . (18)
m˙ E,PGW · cp,E,PGW
3.2. Thermostatic expansion valve
The heat transfer coefficient on the refrigerant side for the
A thermostatic expansion valve with external equalizer is used. boiling process (α E, ref, boil ) is calculated according to the Copper
The valve is well insulated; therefore, an isenthalpic process (h[6] = correlations (Cooper, 1984). The heat transfer coefficient for the
h[7] ) is considered. It is assumed that the thermostatic expansion propylene-glycol water mixture (α E, PGW ) and for the superheating
valve is adjusted in order to control the degree of superheat at the phase (refrigerant single phase – vapor) in the evaporator are cal-
evaporator’s outlet. culated using correlations from Thonon (Thonon, 1995).
286 Z. Janković et al. / International Journal of Refrigeration 86 (2018) 282–291
3.4. Condenser (indoor heat exchanger) For the liquid phase, the heat transfer coefficient is calculated
from the widely known correlations for friction factor and Nus-
In general, the condensation process in this type of equipment selt number according to Petukhov (Petukhov, 1970) and Gnielinski
can be divided into three zones: vapor desuperheating, conden- (Gnielinski, 1976), respectively. The heat transfer coefficient for the
sation and liquid subcooling. However, in our case, the refrigerant vapor flow in the concentric annular duct was calculated accord-
side surface temperature of the condenser was always lower ing to the Petukhov and Roizen (Petukhov and Roizen, 1964) and
than the refrigerant dew point temperature. As a result, only two Petukhov (Petukhov, 1970), using a modified form of the correla-
zones (condensation and liquid subcooling) are considered in the tion for turbulent flow from Gnielinski (Gnielinski, 1976).
analysis.
The total heat transfer in the condenser is given by the three 3.6. Desuperheater
following equations:
In this paper, the mathematical model of the desuperheater was
Q˙ C = m˙ ref · (h[4] − h[5] ), (19) simplified based on the domestic hot water temperature values
used for the heat pump analysis covered in Section 4. As a result, it
Q˙ C = m˙ C,W · cp,C,W · (TC,W,out − TC,W,in ), (20)
is considered that during hot water production the refrigerant will
Q˙ C = Q˙ C,cond + Q˙ C,sub . (21) not condense. The heat exchanger is modeled as a single-phase
flow heat exchanger in both sides using the widely used correla-
The surface of the condenser is also divided into two zones: tions of Thonon (Thonon, 1995).
AC = AC,cond + AC,sub . (22) 3.7. Pressure drops in the refrigerant circuit
For the condensation process it is considered that the subcool-
ing region starts somewhere inside (denoted as ‘∗ ’) of the con- The pressure drops on the refrigerant side in the evaporator,
denser (presumably close to the outlet port), then condenser and desuperheater are calculated based on accordance
to Collier and Thome (Collier and Thome, 1996).
Q˙ C,cond = m˙ ref · (h[4] − h∗(x=0;p≈p[5]) ), (23) The total pressure drop in the evaporator (pE, t ) is calculated
from the frictional(pE, f ), momentum(pE, a ), gravity(pE, g ) and
Q˙ C,cond = m˙ C,W · cp,C,W · (TC,W,out − TC∗,W ), (24)
the manifolds and ports (pE, c ) pressure drops:
Q˙ C,cond = AC,cond · UC,cond · TC,cond,ln · Ft . (25) pE ,t = pE ,f + pE ,a + pE ,g + pE ,c . (33)
The logarithmic mean temperature difference for the condensa- The momentum and gravity pressure drops are estimated by
tion process is calculated by the following equation: the homogeneous model for the two-phase flow as follows:
pE,a = m˙ 2flux,E · (vV,E − vL,E ) · XE , (34)
TC(x=1,p≈p[4]) − TC,W,out − TC(x=0,p≈p[5]) − TC∗,W
TC,cond,ln = . pE,g = g · ρm,E · HE , (35)
TC(x=1,p≈p[4]) −TC,W,out
ln TC(x=0,p≈p[5]) −TC∗,W where (XE )is the vapor quality change between inlet and out-
let of the evaporator. The average two-phase density between inlet
(26)
and outlet is calculated by the following equation:
Similarly, for the subcooling part of the condenser, the next −1
Xm,E (1 − Xm,E )
equations are obtained: ρm , E = + , (36)
ρV , E ρL , E
Q˙ C,sub = m˙ ref · (h∗(x=0;p≈p[5]) − h5 ), (27)
where (Xm, E )is the average vapor quality between inlet and outlet
Q˙ C,sub = m˙ C,W · cp,C,W · (TC∗,W − TC,W,in ), (28) of the evaporator.
The pressure drops in the inlet and outlet manifolds and ports
Q˙ C,sub = AC,sub · UC,sub · TC,sub,ln · Ft , (29) are empirically estimated, in accordance with Collier and Thome
(Collier and Thome, 1996), as follows:
TC∗(x=0,p≈p[5]) − TC∗,W − T[5] − TC,W,in 1.5 · m˙ 2flux,E
TC,sub,ln = T∗ . (30) pE ,c = , (37)
C(x=0,p≈p[5] )
−TC∗,W 2 · ρm , E
ln T[5] −TC,W,in The frictional pressure drop calculation was based on the exper-
imental data from Longo and Gasparella (A.G. Longo and Gaspar-
In this paper correction factor (Ft ) for the condensation of
ella, 2007) and Longo and Gasparella (A.G. Longo and Gasparella,
R407C has been included as suggested by researchers Shah and
2007):
Focke (Shah and Focke, 1988). The correction factor is calculated
as a function of the number of transfer units, according to Mancin m˙ 2flux,E
pE,f = 1553 · , (38)
et al. (Mancin et al., 2011) and (Mancin et al., 2012). The heat 2 · ρm , E
transfer coefficient for the water side (α C, W ) is calculated from In the condenser, a similar procedure was followed. For cal-
Thonon (Thonon, 1995) and the computation approach suggested culating the frictional pressure drops the correlation from Longo
by Mancin et al. (Mancin et al., 2011) is used for the refrigerant (Longo, 2009) was used. The same model is set for the desuper-
side. heater where, in this case, the momentum pressure rise is ne-
glected because it is considered that refrigerant will not condense
3.5. Liquid−vapor heat exchanger (no phase change).
Pressure drops in the LVHX are also included in the mathe-
Energy balances for the liquid and vapor sides of this heat ex- matical model, the friction factor for the liquid and vapor sides
changer are described by the following equations: (concentric annular duct) are calculated (for turbulent flow) from
Q˙ LVHX = m˙ ref · (h[5] − h[6] ), (31) Petukhov (Petukhov, 1970) and Gnielinski (Gnielinski, 1976).
The pressure drop in the 4-way valve is considered to be equal
h [1 ] − h [9 ] = h [5 ] − h [6 ] . (32) to 14,0 0 0 Pa, based on manufacturer data.
Z. Janković et al. / International Journal of Refrigeration 86 (2018) 282–291 287
Table 2
Types of sensors used and accuracies.
Q˙ C + Q˙ DHW
COP = , (39)
W˙ TOTAL,elec
Q˙ E + Q˙ DHW
EER = , (40)
W˙ TOTAL,elec
The total power consumption includes the compressor and
three pumps power: for the propylene-glycol water mixture in the
outdoor heat exchanger, for the water pump in the indoor heat ex-
changer, and also for the DHW in the desuperheater. For all three
pumps, the electrical power is obtained from the manufacturer
data as a function of the volumetric flow rate using the following
general equations with coefficients a, b and c:
W˙ elec,pump = −a · V˙ 2 + b · V˙ + c, (41)
4. Validation of the model During each experiment, steady state conditions were reached
within a period of 2–3 h while data recording during the next
The model was validated against steady state tests performed 60 min was done for measured temperatures and pressures.
on an experimental station with the heat pump described in The inputs used in order to validate the model were: inlet tem-
Section 2. The experimental station was equipped with proper in- perature and volumetric flow rate of PGW at the outdoor heat ex-
strumentation. Fig. 1 shows the location of the different sensors changer (evaporator), inlet temperature and volumetric flow rate
used in the experimental setup and Table 2 summarize their main of water at the indoor heat exchanger (condenser), degree of su-
characteristics. perheat controlled by thermostatic expansion valve and subcooling
For the validation of the mathematical model a set of 19 steady degree measured at condenser outlet.
state tests were considered. For these tests the LVHX and desuper- Figs. 2 and 3 present the deviations between experimental and
heater were not used and the heat pump was run for the heating simulation results (pressures and temperatures). Deviation of the
mode of operation (winter cycle) as described in Section 2. temperatures between experimental and numerical results are in-
The propylene-glycol water mixture (PGW) is pumped to the side 2.5 K bands. Pressure deviations shown in Fig. 3 are mostly
outdoor heat exchanger from a 750 L PGW tank. Similarly, water within 0.3 bar bands. Fig. 3 also shows that experimental and sim-
is pumped from a 280 L tank to the indoor heat exchanger. The ulation results predict non-negligible pressure drops in the high
PGW and water flow rates through the outdoor and indoor heat and low pressure refrigerant circuit of the heat pump (for exam-
exchangers were controlled manually. The supply temperature to ple, average pressure differences of 0.4 bar were measured between
each heat exchanger was controlled by adjusting the temperature compressor outlet and condenser outlet). Since pressure drops af-
levels of the corresponding tanks using an additional water circuit fect adversely the system performance, it was necessary to include
and an air-to-water heat pump (not shown in Fig. 1). them in the mathematical model (as described in Section 3.7).
Experiments were carried out with PGW supply temperatures Fig. 4 shows that the deviation for total electric power is in
(outdoor heat exchanger) from 8 to 12 °C and water supply tem- the range from 5 to 10 %. It should be clarified that the electric
peratures (indoor heat exchanger) from 18 °C to 36.5 °C. The power measured by the power transducer includes the compres-
PGW and water flow rates were nearly constant during all ex- sor, pumps, electronic control board and additional electric com-
periments, with values equal to (6.85 ± 0.05) x 10−4 m3 /s and ponents; the later values are not included in the simulation calcu-
(5.9 ± 0.1) x 10−4 m3 /s, respectively. The degree of superheat at the lations, so the simulated results are expected to be slightly lower
evaporator outlet was adjusted initially by manual rotation of the than the experimental ones.
side stem of the thermostatic expansion valve. During all the ex- It can be seen, that the accordance between experimental and
periments, the degree of superheat at the evaporator outlet was simulation results are reasonable. As a result the model can be
nearly constant and equal to 3.0 ± 0.5 K. used as an effective tool for further heat pump analyses.
288 Z. Janković et al. / International Journal of Refrigeration 86 (2018) 282–291
Fig. 4. Deviation between simulated and experimental values of total input power
for the heat pump (electric power of compressor and three pumps) (R407C).
Fig. 7. Influence on the heating and DHW heating powers of the subcooling and
superheating degrees (R407C). The low temperature heating mode of operation is
considered. (Arrows beside curves indicate that the right side ordinate should be
used).
Fig. 8. p-h diagrams for the refrigerant cycles (R407C) with and without LVHX for
the cases with and without DHW production.
would lead to higher heating effects per unit mass and COP values.
For the results shown in Fig. 6, the COP reaches a maximum for a to low variations for the heat transfer values in the condenser
subcooling degree of 3 K, as a result of the trade-off between in- but higher heat transfer values for hot water production in the
creasing the heating effect and compression work. desuperheater. With regards to the effect of the degree of super-
Fig. 7 shows the corresponding heat transfer rates in the con- heat, Fig. 7 shows that increasing the degree of superheat leads to
denser and desuperheater (when DHW-ON) for the same cases an- higher powers for hot water production which may be interesting
alyzed in Fig. 5. Focusing on the DHW-OFF case, it can be seen in those situations where hot water production is a priority.
that increasing the degree of superheat has a negative effect on
the heating power of the heat pump, whereas increasing the sub- 5.2. Heating mode of operation (medium temperature)
cooling degree has a positive effect. Moreover, using the LVHX has
a negligible effect on the heating power, as both curves (LVHX-ON A similar analysis is performed for the medium tempera-
and LVHX-OFF) collapse into a single one. This can be clearly seen ture heating mode of operation, considering inlet/outlet tempera-
in the p-h diagrams shown in Fig. 8a), where it can be seen that tures of 0/−3 °C for the outdoor heat exchanger (evaporator) and
using the LVHX has two opposite effects on the heating power. On 40/45 °C for the indoor heat exchanger (condenser). The results are
the one hand, using the LVHX leads to higher discharge tempera- collected in Figs. 9 and 10.
tures which will lead to higher heating powers; but on the other Fig. 9 shows similar trends of COP’s to the ones obtained for
hand, if the LVHX is used, the compressor suction temperature and the low temperature applications; however, the COP values for the
specific volume increase, which leads to lower mass flow rates and, medium temperature applications are around 23% and 25% (0.67
consequently, lower heating powers. Results in Fig. 7 show that and 0.70) lower for the DHW-ON and DHW-OFF cases, respectively.
both effects nearly cancel each other, and the heating power is al- For the DHW-OFF case, the effect on the COP of the LVHX is in-
most unaffected by the LVHX. significant, but for the DHW-ON case, using the LVHX has a slight
A similar analysis has been performed when the desuperheater positive effect on the COP of the heat pump.
is used for hot water production (DHW-ON case) and the results Fig. 10 also shows that the trends for the heat transfer values
of this analysis are also included in Fig. 7. As shown in the p-h di- are similar to the ones obtained for the low temperature heating
agram of Fig. 8b) using the LVHX leads to higher compressor suc- mode of operation; though the heating power values in the con-
tion and discharge temperatures which finally leads to a greater denser are lower (16% and 5.1% in average for the DHW-ON and
amount of heat that can be used for hot water production, as con- DHW-OFF cases, respectively), while the heating power that can be
firmed in Fig. 7. As a consequence, the heating power in the con- used for DHW is higher (around 0.8 kW or 90%) due to the higher
denser decreases in a similar value, being the total power (con- vapor temperatures at the compressor outlet. Once again, using the
denser and desuperheater) nearly the same. The results also show LVHX has a positive effect on the heating power that can be used
that, for the DHW-ON case, increasing the subcooling degree leads for DHW, whereas it has a slight negative effect on the heating
290 Z. Janković et al. / International Journal of Refrigeration 86 (2018) 282–291
Fig. 10. Influence on the heating and DHW heating powers of the subcooling and
Fig. 9. Influence on the system performance (COP) of the subcooling and super-
superheating degrees (R407C). The medium temperature heating mode of operation
heating degrees (R407C). The medium temperature heating mode of operation is
is considered. (Arrows beside curves indicate that the right side ordinate should be
considered.
used).
References