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Section A : Gas Laws

A-1. At constant temperature, in a given mass of an ideal gas -
(A) The ratio of pressure and volume always remains constant
(B) Volume always remains constant
(C) Pressure always remains constant
(D) The product of pressure and volume always remains constant

A-2. Three flasks of equal volumes contain CH4, CO2 and Cl2 gases respectively. They will contain equal
number of molecules if -
(A) the mass of all the gases is same
(B) the moles of all the gas is same but temperature is different
(C) temperature and pressure of all the flasks are same

A-3.
(D) temperature, pressure and masses same in the flasks

i r
A certain mass of a gas occupies a volume of 2 litres at STP. Keeping the pressure constant at what
temperature would the gas occupy a volume of 4 litres -

A-4.
(A) 546ºC (B) 273ºC (C) 100ºC (D) 50ºC

At 100 ºC a gas has 1 atm. pressure and 10 L volume. Its volume at NTP would be -
S
(A) 10 litres
(C) More than 10 litres
(B) Less than 10 litres
(D) None

t a
A-5.

(A) 100 torr (B) 650 torr

u p
If 500 ml of a gas 'A' at 1000 torr and 1000 ml of gas B at 800 torr are placed in a 2L container,
the final pressure will be-
(C) 1800 torr (D) 2400 torr

A-6.
G
Two flasks A and B of 500 ml each are respectively filled with O2 and SO2 at 300 K and 1 atm.
pressure. The flasks will contain-
(A) The same number of atoms
(B) The same number of molecules

a m
(C) More number of moles in flask A as compared to flask B
(D) The same amount of gases

A-7.

u p
In the gas equation PV = nRT, the value of universal gas constant would depend only on -
(A) The nature of the gas (B) The pressure of the gas

A-8.
A n
(C) The temperature of the gas (D) The units of measurement

8.2 L of an ideal gas weight 9.0 gm at 300 K and 1 atm pressure. The molecular mass of gas is-
(A) 9 (B) 27 (C) 54 (D) 81

A-9. Energy in an ideal gas is -

(A) Completely kinetic (B) Completely potential
(C) KE + PE (D) All the above.

A-10. A 0.5 dm 3 flask contains gas 'A' and 1 dm 3 flask contains gas 'B' at the same temperature. If density
of A = 3.0 gm dm –3 and that of B = 1.5 gm dm –3 and the molar mass of A = 1/2 of B, then the
ratio of pressure exerted by gases is-
(A) PA/PB = 2 (B) PA/PB = 1 (C) PA/PB = 4 (D) PA/PB = 3.

A-11. One litre of an unknown gas weighs 1.25 gm at N.T.P. which of the following gas pertains to the above
data -
(A) CO2 (B) NO2 (C) N2 (D) O2
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A-12. If the density of a gas A is 1.5 times that of B then the molecular mass of A is M. The molecular
mass of B will be-
(A) 1.5 M (B) M/1.5 (C) 3M (D) M/3

A-13. When the pressure of 5L of N2 is doubled and its temperature is raised from 300K to 600K, the final
volume of the gas would be-
(A) 10 L (B) 5 L (C) 15 L (D) 20 L

A-14. The value of gas constant per mole is approximately-

(A) 1 cal (B) 2 cal (C) 3 cal (D) 4 cal

A-15. A gas is found to have a formula [CO]x. If its vapour density is 70 the value of x is-
(A) 2.5 (B) 3.0 (C* ) 5.0 (D) 6.0

A-16.
temperature must be :
(A) 250 K (B) 250ºC (C) 25ºC (D) 25 K
r
If the pressure of a gas contained in a closed vessel is increased by 0.4 % when heated by 1ºC its initial

i
A-17.
S
A thin balloon filled with air at 47ºC has a volume of 3 litre. If on placing it in a cooled room its volume
becomes 2.7 litre , the temperature of room is :

A-18.
(A) 42ºC (B) 100ºC (C) 15ºC

t a (D) 200ºC

If a mixture containing 3 moles of hydrogen and 1 mole of nitrogen is converted completely into ammonia, the

(A) 3 : 1 (B) 1 : 3 (C) 2 : 1p

ratio of initial and final volume under the same temperature and pressure would be :

u (D) 1 : 2

A-19.
G
Two flasks of equal volume are connected by a narrow tube (of negligible volume) all at 27ºC and contain
0.35 mole of H2 each at 0.5 atm. One of the flask is then immersed into a bath kept at 127º C, while the other
remains at 27º C. The final pressure in each flask is :
(A) Final pressure = 0.5714 atm
(C) Final pressure = 0.5824 atm

a m (B) Final pressure = 1.5714 atm

(D) None of these

A-20.
p
Two flasks of equal volume are connected by a narrow tube (of negligible volume) all at 27º C and contain

u
0.70 moles of H2 at 0.5 atm. One of the flask is then immersed into a bath kept at 127º C , while the other

n
remains at 27º C. The number of moles of H2 in flask 1 and flask 2 are :
(A) Moles in flask 1 = 0.4, Moles in flask 2 = 0.3 (B) Moles in flask 1 = 0.2, Moles in flask 2 = 0.3

A
(C) Moles in flask 1 = 0.3, Moles in flask 2 = 0.2 (D) Moles in flask 1 = 0.4, Moles in flask 2 = 0.2

A-21. A gas is heated from 0°C to 100°C at 1.0 atm pressure. If the initial volume of the gas is 10.0  , its final
volume would be :
(A) 7.32  (B) 10.00  (C) 13.66  (D) 20.00 

A-22. Under what conditions will a pure sample of an ideal gas not only exhibit a pressure of 1 atm but also a
concentration of 1 mol litre 1. [ R = 0.082 litre atm mol 1 K 1 ]
(A) at S.T.P. (B) when V = 22.42 L
(C) when T = 12 K (D) impossible under any condition

A-23. A and B are two identical vessels. A contains 15 g ethane at 1atm and 298 K. The vessel B contains 75 g of
a gas X2 at same temperature and pressure. The vapour density of X2 is :
(A) 75 (B) 150 (C) 37.5 (D) 45

A-24. The density of neon will be highest at :

(A) STP (B) 0°C, 2 atm (C) 273°C. 1 atm (D) 273°C. 2 atm
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A-25. A 0.5 dm3 flask contains gas A and 1 dm3 flask contains gas B at the same temperature. If density of A = 3
g/dm3 and that of B = 1.5 g/dm3 and the molar mass of A = 1/2 of B, the ratio of pressure exerted by gases
is :
PA PA PA PA
(A) P = 2 (B) P = 1 (C) P = 4 (D) P = 3
B B B B

A-26. Which expression among the following represents Boyle's law ?

(A) (dP/dV)T = K/V (B) (dP/dV)T = –K/V2 (C) (dP/dV)T = –K/V (D) (dP/dV)T = K

A-27. For a fixed mass of a gas at constant pressure, which of the following is correct -
(A) Plot of volume versus Celsius temperature is linear with intercept zero
(B) Plot of volume versus kelvin temperature is linear with a nonzero intercept
(C) Plot of V/T versus T is linear with a positive slope

A-28.
(D) Plot of V/T versus T is linear with a zero slope

The density of carbon monoxide at STP is -

(A) 0.625 g L–1 (B) 1.25 g L–1 (C) 2.5 g L–1 (D) 1.875 g L–1
i r
A-29. S
At a given temperature (X) = 2(Y) and M(Y) = 3 M(X), where  and M stand respectively for
density and molar mass of the gases X and Y, then the ratio of their pressures will be -
(A) p(X) / p(Y) = 1/4 (B) p(X) / p(Y) = 4 (C) p(X) / p(Y) = 6

t a
(D) p(X) / p(Y) = 1/6

A-30.
d2 P2 T1
(A) d  P T
d1T1
(B) d2  T
d2 T2
(C) d  T
u p
Which of the following expression gives the variation of density of ideal gas with changes in temperature?
d2P2 T2
(D) d2  P T

G
1 1 2 2 1 1 1 1

A-31. The volume of ammonia obtained by the combination of 10ml of N2 and 30ml H2 is -

A-32.
(A) 20ml (B) 40 ml

a m (C) 30ml (D) 10ml

Hydrogen and Argon are kept in two separate but identical vessels at constant temperature and
pressure -

p
(A) Both contain same number of atoms.

u
(B) The number of atoms of argon is half that of hydrogen.

A-33.
n
(C) The number of atoms of argon is double that of hydrogen

A
(D) None of these

Which of the following represents the avogadro number -

(A) Number of molecules present in 1 L of gas at N.T.P.
(B) Number of molecules present in 22.4 ml of gas at N.T.P.
(C) Number of molecules present in 22.4 L of gas at 298K and 1 atm. pressure
(D) Number of molecules present in one mole of gas at any temp. and pressure.

A-34. 26 c.c. of CO2 are passed over red hot coke. The volume of CO evolved is -
(A) 15 c.c (B) 10 c.c. (C) 32 c.c. (D) 52 c.c.

A-35. 10 gm of a gas at NTP occupies 5 litres. The temp. at which the volume becomes double for the same
mass of gas at the same pressure is -
(A) 273 K (B) -273ºC (C) 273ºC (D) 546ºC

A-36. An ideal gas is at a pressure (P) and temperature (T) in a box, which is kept in vacuum within a
large container. The wall of the box is punctured. What happens as the gas escape through the hole ?
(A) the temperature falls (B) its temperature rises
(C) its temperature remains the same (D) unpredictable
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A-37. V versus T curves at constant pressure P1 and P2 for an ideal gas are shown in fig. Which is
correct -

(A) P1 > P2 (B) P1 < P2 (C) P1 = P2 (D) All

A-38. If pressure of a gas contained in a closed vessel is increased by 0.4% when heated by 1ºC its initial
temperature must be -
(A) 250K (B) 250ºC (C) 2500K (D) 25ºC

A-39.

i r
At a constant pressure, what should be the percentage increase in the temperature in kelvin for a
10% increase in volume -
(A) 10% (B) 20% (C) 5% (D) 50%
S
A-40.

(C) 546ºC and 0.5 atm

(B) 273ºC and 2 atm
(D) 0ºC and 0 atm
t a
There is 10 litre of a gas at STP. Which of the following changes keeps the volume constant -
(A) 273 K and 2 atm

A-41.

u p
The density of oxygen gas at 25ºC is 1.458 mg/litre at one atmosphere. At what pressure will oxygen
have the density twice the value-
(A) 0.5 atm/25ºC (B) 2 atm/25ºC
G
(C) 4 atm/25ºC (D) None

A-42.

m
A flask of methane (CH4) was weighed. Methane was then pushed out and the flask again weighed
when filled with oxygen at the same temperature and pressure. The mass of oxygen would be -
(A) The same as the methane
a (B) Half of the methane

A-43.
u p
(C) Double of that of methane (D) Negligible in comparison to that of methane

A balloon filled with methane (CH4) is pricked with a sharp point and quickly plunged into a tank of
hydrogen at the same pressure. After sometime, the balloon will have -

A-43.
(A) Enlarged

A n
(C) Remain unchanged in size
(B) Shrinked
(D) Ethylene (C2H4) inside it

Containers X, Y and Z of equal volume contain oxygen, neon and methane respectively at the same
temperature and pressure. The correct incereasing order of their masses is -
(A) X < Y < Z (B) Y < Z < X (C) Z < X < Y (D) Z < Y < X

A-44. Two flasks X and Y have capacity 1L and 2L respectively and each of them contains 1 mole of a gas.
The temperature of the flask are so adjusted that average speed of molecules in X is twice as those
in Y. The pressure in flask X would be -
(A) Same as that in Y (B) Half of that in Y
(C) Twice of that in Y (D) 8 times of that in Y

A-45. A gas can be liquefied by -

(A) Cooling (B) Compressing (C) Both (D) None of these.
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Section B: Daltons Law of Partial Pressures

B-1. A cylinder is filled with a gaseous mixture containing equal masses of CO and N2. The ratio of their
partial pressure is-
1
(A) PN = PCO (B) PCO = 0.875 PN2 (C) PCO = 2 PN (D) PCO = P
2 2 2 N2

B-2. The total pressure of a mixture of two gases is -

(A) The sum of partial pressures of each gas
(B) The difference in partial pressures
(C) The product of partial pressures
(D) The ratio of partial pressures.

B-3. Equal masses of SO2, CH4 and O2 are mixed in empty container at 298 K, when total pressure is
2.1 atm. The partial pressures of CH4 in the mixture is -

B-4.
(A) 0.5 atm (B) 0.75 atm (C) 1.2 atm (D) 0.6 atm

Air contains 79% N2 and 21% O2 by volume. If the pressure is 750 mm of Hg, the partial pressure
i r
of O2 is -
(A) 157.5 mm of Hg (B) 175.5 mm of Hg (C) 315.0 mm of Hg (D) 257.5 mm of Hg S
B-5.
pressure exerted by hydrogen is:
(A) 1: 2 (B) 1: 1 (C) 1: 16 (D) 15: 16
a
Equal weights of ethane & hydrogen are mixed in an empty container at 25º C, the fraction of the total

t
B-6.

u p
A mixture of hydrogen and oxygen at one bar pressure contains 20% by weight of hydrogen. Partial pressure
of hydrogen will be
(A) 0.2 bar (B) 0.4 bar
G
(C) 0.6 bar (D) 0.8 bar

B-7.

m
A compound exists in the gaseous phase both as monomer (A) and dimer (A2). The atomic mass of A is 48
and molecular mass of A2 is 96. In an experiment 96 g of the compound was confined in a vessel of volume

a
33.6 litre and heated to 273ºC. The pressure developed if the compound exists as dimer to the extent of 50

u p
% by weight under these conditions will be :
(A) 1 atm (B) 2 atm (C) 1.5 atm (D) 4 atm

B-8.

1mol gas A
250 mm
n
In the below experiment, the value of P is -

A 2 mol gas B
250 mm
Partition
 
removed at
same tem 
perature( T )
Pr essure
P

(A) 250 mm (B) 500 mm (C) 300 mm (D) 400 mm

B-9. A closed vessel contains equal number of oxygen and hydrogen molecules at a total pressure of 740
mm. If oxygen is removed from the system, the pressure -
(A) Becomes half of 740 mm. (B) Remains unchanged
(C) Becomes 1/9th of 740 mm. (D) Becomes double of 740 mm.

B-10. At constant temperature 200 cm 3 of N2 at 720 mm and 400 cm 3 of O2 at 750 mm pressure are put
together in a one litre flask. The final pressure of mixture is -
(A) 111 mm (B) 222 mm (C) 333 mm (D) 444 mm

B-11. A box of 1L capacity is divided into two equal compartments by a thin partition which are filled with
2g H2 and 16gm CH4 respectively. The pressure in each compartment is recorded as P atm. The total
pressure when partition is removed will be -
(A) P (B) 2P (C) P/2 (D) P/4
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B-12. The partial pressure of hydrogen in a flask containing 2gm of H2 & 32gm of SO2 is -
1 1
(A) of total pressure (B) of total pressure
16 2
2 1
(C) of total pressure (D) of total pressure.
3 8

B-13. The mass of CO2 that must be mixed with 20 g of oxygen such that 27 ml of a sample of the
resulting mixture contains equal number of molecules of each gas –
(A) 13.75 g (B) 27.5 g (C) 41.25 g (D) 55 g

B-14. A mixture of hydrogen and oxygen (45 ml) is sparked to form liquid water. The component not in excess
reacts completely and 15 ml is left over. (All measurements are made at the same temperature and
pressure). The composition by volume in the original mixture of H2 : O2 is
(A) 4 : 5
(C) either 4 : 5 nor 7 : 2
(B) 7 : 2
(D) 2 : 1
i r
B-15. In a gaseous mixture at 20°C the partial pressure of the components are, :
H2 : 150 Torr, CO2 : 200 Torr, CH4 : 300 Torr,
(A) 26.67 (B) 73.33
S
C2H4 : 100 Torr, Volume percent of H2 is :
(C) 80.00 (D) 20

B-16.

t a
At STP, a container has 1 mole of Ar, 2 moles of CO2, 3 moles of O2 and 4 moles of N2. Without
changing the total pressure if one mole of O2 is removed, the partial pressure of O2 :
(A) is changed by about 26 %
(C) is unchanged

u p
(B) is halved
(D) changed by 33 %

B-17.
(i) CO,
(A) CO,CO2,C2H4
(ii) CO2, (iii) N2O,
(B) CO2,C2H4,N2O
G
Which of the following gases will have the same rate of diffusion under identical conditions?
(iv) N2,
(C) C3H8,N2O,CO2
(v) C2H4 (vi) C3H8
(D) CO, N2,C2H4,C3H8

Section C : Grahams Law of Diffusion.

C-1.
a m
The rates of diffusion of SO3, CO2, PCl3 and SO2 are in the following order -

u p
(A) PCl3 > SO3 > SO2 > CO2
(C) SO2 > SO3 > PCl3 > CO2
(B) CO2 > SO2 > PCl3 > SO3
(D) CO2 > SO2 > SO3 > PCl3

C-2.
n
20  of SO2 diffuses through a porous partition in 60 seconds. Volume of O2 diffuse under similar conditions

A
in 30 seconds will be :
(A) 12.14  (B) 14.14  (C) 18.14  (D) 28.14 

C-3. See the figure-1 :

The valves of X and Y are opened simultaneously. The white fumes of NH4Cl will first form at:
(A) A (B) B (C) C (D) A,B and C simultaneously

C-4. X ml of H2 gas effuses through a hole in a container in 5 sec. The time taken for the effusion of the same
volume of the gas specified below under identical conditions is :
(A) 10 sec. He (B) 20 sec. O2 (C) 25 sec. CO2 (D) 55 sec. CO2
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C-5.* The rate of diffusion of 2 gases ‘A’ and ‘B’ are in the ratio 16: 3. If the ratio of their masses present in the
mixture is 2 : 3. Then
(A) The ratio of their molar masses is 16 : 1
(B) The ratio of their molar masses is 1 : 4
(C) The ratio of their moles present inside the container is 1 : 24
(D) The ratio of their moles present inside the container is 8 : 3

C-6. A gas 'A' having molecular weight 4 diffuses thrice as fast as the gas B. The molecular weight of gas
B is-
(A) 36 (B) 12 (C) 18 (D) 24

C-7. The increasing order of effusion among the gases, H2, O2, NH3 and CO2 is-
(A) H2, CO2, NH3, O2 (B) H2, NH3, O2, CO2
(C) H2, O2, NH3, CO2 (D) CO2, O2, NH3, H2

C-8.

(A) 64 (B) 32 (C) 4 (D) 8

i r
The rate of diffusion of methane at a given temperature is twice that of a gas X. The molecular weight
of X is -

C-9.
1 1 1 1
S
A gas X diffuses three times faster than another gas Y the ratio of their densities i.e., Dx : Dy is-

(A)
3
(B)
9
(C)
6

t a (D)
12

C-10.

(A) NO, CO (B) NO, CO2 (C) NH3, PH3

u p
In which of the following pairs the gaseous species diffuse through a porous plug with the same rate
of diffusion -
(D) NO, C2H6

C-11.
G
A balloon filled with ethylene is pricked with a sharp pointed needle and quickly placed in a tank full of
hydrogen at the same pressure. After a while the balloon would have :
(A) shrunk
(C) completely collapsed

a m (B) enlarged
(D) remain unchanged in size.

C-12.

p
A certain gas is diffused from two different vessels A and B. The vessel A has a circular orifice while
vessel B has square orifice of length equal to the radius of the orifice of vessel A. The ratio of the

u
rates of diffusion of the gas form vessel A to that of in vessel B assuming same T & P is :

C-13.
(A) 

A n (B) 1/ (C) 1 : 1 (D) 2 : 1

The vapour densities of CH4 and O2 are in the ratio 1 : 2 . The ratio of rates of diffusions of O2 and
CH4 at same P and T is -
(A) 1 : 2 (B) 2 : 1 (C) 1 : 1.41 (D) 1 : 4.14

C-14. A balloon is filled with I gm of He and had a radius of 10 cm. after some time 0.27 gm of He the effused
out from the balloon. If pressure & temp. remains constant what would be the radious of balloon now–
(A) 9.5 (B) 9.0 (C) 8.0 (D) 6.5

Section D: Kinetic Theory of Gases.

D-1. Which is not correct in terms of kinetic theory of gases-
(A) Gases are made up of small particles called molecules
(B) The molecules are in random motion
(C) When molecules collide, they lose energy
(D) When the gas is heated , the molecules moves faster

D-2. The kinetic energy of 1 mole of gas is equal to -

3 3 RT 2R
(A) RT (B) KT (C) (D)
2 2 2 3
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D-3. Which of the following expression does not give root mean square velocity-
1 1 1 1
 3RT  2  3P  2  3P  2  3PV  2
(A)   (B)   (C)   (D)  
 M   DM   D   M 

D-4. Which one of the following gases would have the highest R.M.S. velocity at 25ºC -
(A) Oxygen (B) Carbon dioxide (C) Sulphur dioxide (D) Carbon monoxide.

D-6. If the r.m.s. velocity of nitrogen molecules is 5.15 ms–1 at 298 K, then a velocity of 10.30 ms–1 will
be possessed at a temp-
(A) 149 K (B) 172.6 K (C) 596 K (D) 1192 K

D-7. The RMS velocity at NTP of the species can be calculated from the expression -

i r
(A)
 3P 

 d
 (B)
 3PV 

 M 
 (C)
 3RT 

 M 

S
(D) All are correct.

D-8.
(A) SO2 (B) N2 (C) O2 (D) Cl2 a
Among the following gases which one has the lowest root mean square velocity at 25ºC-

t
D-9.
p
By how many folds the temp of a gas would increase when the r.m.s. velocity of gas molecules in

u
a closed container of fixed volume is increased from 5 x 104 cm s–1 to 10 x 104 cm s–1-

D-10.
(A) 0.5 times (B) 2 times

G
(C) 4 times (D) 16 times.

At S.T.P. the order of mean square velocity of molecules H2, N2, O2 and HBr is -
(A) H2 > N2 > O2 > HBr
(C) HBr > H2 > O2 > N2

a m (B) HBr > O2 > N2 > H2

(D) N2 > O2 > H2 > HBr

D-11.
p
Most probable speed, average speed and RMS speed are related as -

u
(A) 1 : 1.128 : 1.224 (B) 1 : 1.128 : 1.424 (C) 1 : 2.128 : 1.224 (D) 1 : 1.428 : 1.442

D-12.

A n
The root mean square velocity of an ideal gas in a closed container of fixed volume is increased from
5 x 104 cm. s–1 to 10 x 104 cm. s–1. Which of the following statements might correctly explain how
the change accomplished -
(A) By heating the gas, the temperature is doubled
(B) By heating the gas, the pressure is made four times
(C) By heating the gas, the volume is tripled
(D) By heating the gas, the pressure is doubled.

D-13. Temperature at which r.m.s. speed of O2 is equal to that of neon at 300 K is :

(A) 280 K (B) 480 K (C) 680 K (D) 180 K

D-14. The R.M.S. speed of the molecules of a gas of density 4 kg m 3 and pressure 1.2  105 N m 2 is :
(A) 120 m s 1 (B) 300 m s 1 (C) 600 m s 1 (D) 900 m s 1

D-15. The mass of molecule A is twice that of molecule B. The root mean square velocity of molecule A is twice that
of molecule B. If two containers of equal volume have same number of molecules, the ratio of pressure PA/PB
will be :
(A) 8 : 1 (B) 1 : 8 (C) 4 : 1 (D) 1 : 4
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D-16. The average kinetic energy (in joules of) molecules in 8.0 g of methane at 27º C is :
(A) 6.21 × 10-20 J/molecule (B) 6.21 × 10-21 J/molecule
-22
(C) 6.21 × 10 J/molecule (D) 3.1 × 10-22 J/molecule

D-17. According to kinetic theory of gases, for a diatomic molecule :

(A) The pressure exerted by the gas is proportional to the mean velocity of the molecule.
(B) The pressure exerted by the gas is proportional to the r.m.s. velocity of the molecule.
(C) The r.m.s. velocity of the molecule is inversely proportional to the temperature.
(D) The mean translational K.E. of the molecule is proportional to the absolute temperature.

D-18. The temperature of an ideal gas is increased from 120 K to 480 K. If at 120 K the root-mean-square velocity
of the gas molecules is v, at 480 K it becomes :
(A) 4v (B) 2v (C) v/2 (D) v/4

D-19. The ratio between the r.m.s. velocity of H2 at 50 K and that of O2 at 800 K is:
(A) 4 (B) 2 (C) 1 (D) 1/4

i r
D-20.* If a gas is allowed to expand at constant tempeature then which of the following does not hold true :
(A) the kinetic energy of the gas molecules decreases
(B) the kinetic energy of the gas molecules increases
(C) the kinetic energy of the gas molecules remains the same
S
(D) Can not be predicted

t a
D-21.
(B) 1681 J (C) 2245 J

u p
The total kinetic energy of 0.6 mol of an ideal gas at 27° C is -
(A) 1122 J (D) 2806 J

D-22.
(A) CO (B) CH4 (C) CO2
G
Which of the following molecule has the lowest average speed at 273 K ?
(D) C2H6

D-23. Which of the following is true -

(A) urms >  > .

a m
(B) urms <  < . (C) urms >  < . (D) urms <  > .

D-24.
p
At what temperature will be total kinetic energy (KE) of 0.30 mole of He be the same as the total

u
KE of 0.40 mole of Ar at 400K-

D-25.
(A) 400K

A n (B) 373 K (C) 533K (D) 300 K

Four particles have speed 2,3,4 and 5 cm/s respectively. Their rms speed is -
(A) 3.5cm/s (B) (27/2) cm/s (C) 54 cm/s (D) ( 54 /2) cm/s]

D-26. The RMS velocity of an ideal gas at 27 ºC is 0.3 m sec–1. Its RMS velocity at 927 ºC is -
(A) 0.6 m sec–1 (B) 0.9 m sec–1 (C) 2.4 m sec–1 (D) 3.0 m sec–1

D-27. Average velocity is equal to -

(A) 0.9213 RMS velocity (B) 0.9 RMS velocity
(C) 0.9602 RMS velocity (D) 0.9813 RMS velocity

D-28. The velocity possessed by most of the gaseous molecules is -

(A) Average velocity (B) Most probable velocity
(C) R.M.S. velocity (D) None of these.

D-29. A 2.24L cyclinder of oxygen at N.T.P. is found to develop a leakage. When the leakage was plugged
the pressure dropped to 570 mm of Hg. The number of moles of gas that escaped will be -
(A) 0.025 (B) 0.050 (C) 0.075 (D) 0.09
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D-30. Helium atom is twice times heavier than a hydrogen molecule. At 25ºC the average K.E. of helium
atom is -
(A) Twice that of hydrogen (B) Same as that of hydrogen
(C) Four times that of hydrogen (D) Half that of hydrogen

D-31. If a gas is expanded at constant temperature-

(A) Number of molecules of the gas decreases
(B) The kinetic energy of the molecule decreases
(C) The kinetic energy of the molecules remains the same
(D) The kinetic energy of the molecules increases

D-32. Three gases of densities A(0.82), B(0.25), C(0.51) are enclosed in a vessel of 4L capacity. Pick up the
correct statement :
I. Gas A will tend to lie at the bottom
II. The number of atoms of various gases A, B, C are same
III. The gases will diffuse to form homogeneous mixture.
IV. The average kinetic energy of each gas is same.
(A) I , IV (B) only III (C) III , IV (D) II, III
i r
D-33. Which of the following statements is not true ?
(A) The ratio of the mean speed to the rms speed is independent of the temperature. S
t a
(B) The square of the mean speed of the molecules is equal to the mean squared speed at a certain
temperature.
(C) Mean kinetic energy of the gas molecules at any given temperature is independent of the mean
speed.

D-34.
(D) None of these

u p
The temperature of an ideal gas is increased from 140 K to 560 K. If at 140 K the root-mean square

(B) 2 V
G
velocity of the gas molecules is V, at 560 K it becomes :
(A) 5 V (C) V/2 (D) V/4

D-35.

(A) density
a
(B) pressure m
If for two gases of molecular weights MA and MB at temperature T A and T B, T AMB = T BMA, then which
property has the same magnitude for both the gases :
(C) K. E. per mole (D) r.m.s. speed

D-36.
p
At what temperature will the total K. E. of 0.30 mol of He be the same as the total K.E. of 0.40 mol of Ar
at 400 K ?
u
D-37.
(A) 533 K

A n (B) 400 K (C) 346 K (D) 300 K

A mixture of methane and ethene in the mole ratio X : Y has a mean molecular weight = 20. What would
be the mean molecular weight if the same gases are mixed in the ratio Y : X
(A) 22 (B) 24 (C) 20.8 (D) 19

D-38. For two gases, A and B with molecular weights MA and MB, it is observed that at a certain temperature,
T, the mean velocity of A is equal to the root mean squared velocity of B. Thus the mean velocity of A
can be made equal to the mean velocity of B, if –
(A) A is at temperature, T, and B at T 1, T > T 1
(B) A is lowered to a temperature T 2 < T while B is at T
(C) Both A and B are raised to a higher temperature
(D) Both A and B are lowered in temperature

Section E: Real Gases

E-1. The Vander Waals' equation explains the behaviour of -
(A) Ideal gases (B) Real gases (C) Vapours (D) Non-real gases.

E-2. The correct expression for the vander waal's equation of states is-
(A) (p + a/n2 V2) (V - nb) = nRT (B) (p + an2/V2) (V - nb) = nRT
(C) (p + an2/V2) (V - b) = nRT (D) (p + an2/V2) (V - nb) = nRT
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E-3. The term that accounts for intermolecular force in vander Waal's equation for non ideal gas is -
(A) RT (B) V - b (C) (P + a / V2) (D) [RT]-1

E-4. The critical temperature of a substance is -

(A)The temperature above which the substance undergoes decomposition
(B)The temperature above which a substance can exist only as a gas
(C) Boiling point of the substance
(D) All are wrong

E-5. Critical temperature of the gas is the temperature-

(A) Below which it cannot be liquified (B) Above which it cannot be liquified
(C) At which it occupies 22.4 L of volume
r
(D) At which one mole of it occupies volume of 22.4 L

i
E-6. The units of the Van der Waal’s constant ‘a’ are -
(A) atm L2 mol–2 (B) atm L–2 mol–2 (C) atm L mol–1 (D) atm mol L–2
S
E-7. The units of the van der Waal’s constant ‘b’ are -
(A) atmosphere (B) joules (C) L mol–1

t a (D) mol L–1

E-8. The Van der Waal’s parameters for gases W, X, Y and Z are -
Gas a(atm L2 mol 2 ) b(Lmol 1 )
u p
W
X
Y
4.0
8.0
6.0
0.027
0.030
0.032
G
Z 12.0 0.027

a m
Which one of these gases has the highest critical temperature ?

E-9.
(A) W

u p
(B) X (C) Y

If the Vander Waal’s constants of gas A are given as -

(D) Z

A n
a (atm L2 mol2) = 6.5
b (L mol–1) 0.056
than ciritical pressure of A is
(A) 56.24 atm (B) 76.77 atm (C) 42.44 atm (D) 36.42 atm

E-10. A real gas obeying Vander Waal's equation will resemble ideal gas , if the :
(A) constants a & b are small (B) a is large & b is small
(C) a is small & b is large (D) constant a & b are large

E-11. For the non-zero values of force of attraction between gas molecules, gas equation will be :
n2a nRT
(A) PV = nRT – (B) PV = nRT + nbP (C) PV = nRT (D) P =
V V b

E-12. Compressibility factor for H2 behaving as real gas is :

Pb  RTV
(B)  1 a 

(A) 1 (C)  1   (D)
 RTV   RT  (1  a)
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E-13. At low pressures (For 1 mole), the Vander Waal’s equation is written as
 a 
p  2  V = RT
 V 
The compressibility factor is then equal to :

 a   RTV   a   RTV 
(A)  1   (B)  1   (C)  1   (D)  1  
 RTV   a   RTV   a 

E-14. Calculate the radius of He atoms if its Vander Waal's constant ‘b’ is 24 ml mol 1.
(Note ml = cubic centimeter)
(A) 1.355 Å (B) 1.314 Å (C) 1.255 Å (D) 0.355 Å

E-15. In vander Waal's equation of state for a non ideal gas the term that accounts for intermolecular forces is :

E-16.
(A) nb (B) nRT (C) n2a/V2 (D) (nRT)-1

i r
The values of Vander Waal's constant "a" for the gases O2, N2, NH3 & CH4 are 1.36, 1.39, 4.17, 2.253 L2 atm
mole-2 respectively. The gas which can most easily be liquified is:
(A) O2 (B) N2 (C) NH3 (D) CH4 S
E-17.

(A) O2< N2 < NH3 < CH4

t a
The correct order of normal boiling points of O2, N2, NH3 and CH4, for whom the values of vander Waal's
constant ‘a’ are 1.360, 1.390, 4.170 and 2.253 L2. atm. mol2 respectively, is :
(B) O2< N2 < CH4 < NH3

E-18.
(C) NH3 < CH4 < N2 < O2

NH3 gas is liquefied more easily than N2. Hence:

u p
(D) NH3 < CH4 < O2 < N2

G
(A) Vander Waal’s constants 'a' and 'b' of NH3 > that of N2
(B) Vander Waal’s constants 'a' and 'b' of NH3 < that of N2
(C) a (NH3) > a (N2) but b (NH3) < b (N2)

a m
(D) a (NH3) < a (N2) but b (NH3) > b (N2)

E-19.* The vander waal gas constant ‘a’ is given by

(A)
1
V
3 C
u p(B) 3 PC VC2
1 RTC
(C) 8 P
C
(D)
64
2 2
27 R TC
PC

E-20.

(A) Z  1– A n
At low pressure the Vander Waals equation is reduced to
a
(B) Z 
pVm
 1
b
b
Vm RT RT RT
pVm a
(C) pVm = RT (D) Z   1
RT RT

PV
E-21. Consider the equation Z  Which of the following statements is correct ?
RT
(A) When Z . 1, real gases are easier to compress than the ideal gas.
(B) when Z = 1, real gases get compressed easily.
(C) When Z > 1 , real gases are difficult to compress .
(D) When Z = 1 , real gases are difficult to copress.

E-22. A mixture of C3H8 and CH4 exerts a pressure of 320 mm Hg at temperature TK in aV litre flask. On
complete combustion, gasesous contains CO2, only and exerts a pressure of 448 mm Hg under idetical
conditions. Hence, mole fraction of C3H8 in the mixture is :
(A) 0.2 (B) 0.8 (C) 0.25 (D) 0.75
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E-23. Let the most probable velocity of hydrogen molecules at a temperature 1oC is Vo. Suppose all the molecules
dissociate into atoms when temperature is raised to (2t + 273)oC then the new rms velocity is :

2
(A) V0 (B) 3( 2  273) 1 / Vo (C) 2 / 3Vo (D) 6Vo
3

E-24. The P of real gases is less than the P of an ideal gas because of -
(A) Increase in number of collisions (B) Finite size of molecule
(C) Increase in KE of molecules (D) Intermolecular forces

E-25. Average K.E. of CO2 at 27ºC is E. The average kinetic energy of N2 at the same temperature will
be-
(A) E (B) 22E (C) E/22 (D) E/ 2

E-26. The rate of diffusion of hydrogen is about -

(A) One half that of He (B) 1.4 times that of He
i r
E-27.
(C) Twice that of He (D) Four times that of He

S
A gas is said to behave like an ideal gas when the reaction PV/T = constant, holds. When do you
expect a real gas to behave like an ideal gas -
(A) When temperature and pressure are low
(B) When temperature and pressure are high
(C) When temperature is low and pressure is high
t a
E-28.
(D) When temperature is high and pressure is very low.

u p
If temperature and volume are same, the pressure of a gas obeying Vander Waals equation is -
(A) Smaller than that of an ideal gas
(C) Same as that of an ideal gas
G
(B) Larger than that of an ideal gas
(D) None of these

E-29.
(A) Strong
m
In case of hydrogen and helium the Vander Waals forces are -

a
(B) Very strong (C) Weak (D) Very weak

E-30.

(A) NH3
u p
Which of the following can be most readily liquefied ? Given value of 'a' for NH3 = 4.17, CO2 = 3.59,
SO2 = 6.71 , Cl2 = 6.49)
(B) Cl2 (C) SO2 (D) CO2

E-31.

A n
The density of a gas at 27°C and 1 atm pressure is . Pressure remaining constant, the temperature
at which its density is 0.5  is-
(A) 200 K (B) 400 K (C) 600 K (D) 800 K

E-32. A real gas is expected to exhibit maximum deviations from ideal gas laws at -
(A) Low T and High P (B) Low T and Low P
(C) High T and High P (D) High T and Low P

E-33. Which of the following expressions of compression factor Z (= pVm / RT) of a real gas is applicable
at high pressure -
(A) Z = 1 – a / Vm RT (B) Z = 1 + a / Vm RT
(C) Z = 1 + pb / RT (D) Z = 1 – pb / RT

E-34. Which of the following expressions of compression factor Z (= pVm / RT) of a real gas is applicable
at low pressure -
(A) Z = 1 – a / Vm RT (B) Z = 1 + a / Vm RT
(C) Z = 1 + pb / RT (D) Z = 1 – pb / RT
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E-35. Which of the following expressions between the van der Waals constant b and the radius r of spherical
molecules is correct -

4  4  4  4 
(A) b    r 3  N A (B) b    r 3  (C) b  2   r 3  N A (D) b  4   r 3  N A
3  3  3  3 

E-36. The value of compression factor at the critical state of a van der Waals gas is -
(A) 3/8 (B) 8/3 (C) 1 (D) 5/8

E-37. A gas with formula CnH2n+2 diffuses through the porous plug at a rate one sixth of the rate of diffusion
of hydrogen gas under similar conditions. The formula of gas is –
(A) C2H6 (B) C10H22 (C) C5H12 (D) C6H14

E-38. The values of critical temperature (TC) and critical pressure (PC) for some gases are given below. Which
of the gases can not be liquefied at 100 K and 50 atm?
Gases
PC (atm)
(i)
2.2
(ii)
14
(iii)
35
(iv)
45
i r
TC (K)
(A) (iv) only
5.1 33 127
(B) (i) only
140
(C) (i) and (ii)
S
(D) (iii) and (iv)

E-39.
respectively which of the following expressions is correct -
(A) f1 > f2 (B) f1 < f2
t a
Let f1 and f2 be the fractions of molecules in the range c and c + dc for SO2 at 2T and O2 and T,

(C) f1 = f2

p
(D) f1 and f2 cannot be correlated

u
G
a m
u p
A n
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A-1. (D) A-2. (C) A-3. (B) A-4. (B) A-5. (B) A-6. (B) A-7. (D)
A-8. (B) A-9. (A) A-10. (C) A-11. (C) A-12. (B) A-13. (B) A-14. (B)
A-15. (C) A-16. (A) A-17. (C) A-18. (C) A-19. (A) A-20. (A) A-21. (C)
A-22. (C) A-23. (A) A-24. (B) A-25. (C) A-26. (B) A-27. (D) A-28. (B)
A-29. (C) A-30. (A) A-31. (A) A-32. (B) A-33. (D) A-34. (D) A-35. (C)
A-36. (C) A-37. (B) A-38. (A) A-39. (A) A-40. (B) A-41. (B) A-42. (C)
A-43. (A) A-43. (D) A-44. (D) A-45. (C) B-1. (A) B-2. (A) B-3. (C)
B-4. (A) B-5. (D) B-6. (D) B-7. (B) B-8. (A) B-9. (A) B-10. (D)
B-11. (A) B-12. (C) B-13. (B) B-14. (C) B-15. (D) B-16. (A) B-17. (C)
C-1. (D) C-2. (B) C-3. (C) C-4. (B) C-5.* (BD) C-6. (A) C-7. (D)
C-8. (A) C-9. (B) C-10. (D) C-11. (B) C-12. (A) C-13. (C) C-14. (B)
D-1. (C) D-2. (A) D-3. (B) D-4. (D) D-6. (D) D-7. (D) D-8. (D)
D-9. (C) D-10. (A) D-11. (A) D-12. (B) D-13. (B) D-14. (B) D-15. (A)
D-16.
D-23.
D-30.
(B)
(A)
(B)
D-17.
D-24.
D-31.
(D)
(C)
(C)
D-18.
D-25.
D-32.
(B)
(D)
(C)
D-19.
D-26.
D-33.
(C)
(A)
(B)
D-20.*
D-27.
D-34.
(ABD)
(A)
(B)
D-21.
D-28.
D-35.
(C)
(B)
(D)
r
D-22.

i
D-29.
D-36.
(C)
(A)
(A)
D-37.
E-6.
E-13.
(B)
(A)
(A)
D-38.
E-7.
E-14.
(B)
(C)
(A)
E-1.
E-8.
E-15.
(B)
(D)
(C)
E-2.
E-9.
E-16.
(D)
(B)
(C)
E-3.
E-10.
E-17.
(C)
(A)
(B)
E-4.
E-11.
E-18.
(B)
(A)
(C)
S
E-5.
E-12.
E-19.*
(B)
(C)
(BD)
E-20.
E-27.
E-34.
(A)
(D)
(A)
E-21.
E-28.
E-35.
(C)
(A)
(D)
E-22.
E-29.
E-36.
(A)
(D)
(A)
E-23.
E-30.
E-37.
(D)
(C)
(C)
E-24.
E-31.
E-38.
(D)

t
(C)
(C)
a E-25.
E-32.
E-39.
(A)
(A)
(C)
E-26.
E-33.
(B)
(C)

u p
G
a m
u p
A n