Professional Documents
Culture Documents
Edition 2
Unleaded petrol
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SANS 1598:2006
Edition 2
Table of changes
Change No. Date Scope
Foreword
This South African standard was approved by National Committee StanSA SC 5140.07A, Steering
committee for petroleum products, biofuels and lubricants – Petrol and diesel fuel, in accordance
with procedures of Standards South Africa, in compliance with annex 3 of the WTO/TBT agreement.
This standard was published in December 2006. This edition cancels and replaces edition 1.5
(SABS 1598:2004).
Annexes A and B form an integral part of this standard. Annexes C, D, E and F are for information
only.
A reference is made in the note to clause 1, in table 1 and in table 2 to "regulations". In South Africa
this means the regulations regarding Petroleum Products Specifications and Standards
promulgated in terms of the Petroleum Product Act, 1977 (Act No. 120 of 1977).
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Edition 2
Contents
Page
Foreword
1 Scope ......................................................................................................................................... 3
2 Normative references ................................................................................................................. 3
3 Definitions .................................................................................................................................. 6
4 Requirements ............................................................................................................................. 6
5 Packing and marking .................................................................................................................. 9
6 Methods of test ......................................................................................................................... 10
6.1 General .................................................................................................................................. 10
6.2 Reid vapour pressure ............................................................................................................ 10
6.3 Flexible volatility index (FVI) .................................................................................................. 10
Annex A (normative) Notes to purchasers .................................................................................. 11
Annex B (normative) Sampling and compliance with this standard............................................ 11
Annex C (informative) Information pertinent to this standard....................................................... 12
Annex D (informative) Water tolerance test................................................................................. 13
Annex E (informative) Alcohol content test.................................................................................. 14
Annex F (informative) Quality verification of unleaded petrol ...................................................... 14
Bibliography ............................................................................................................................... 15
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SANS 1598:2006
Edition 2
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.
SANS 1598:2006
Edition 2
Unleaded petrol
1 Scope
This standard specifies requirements and test methods for marketed and delivered metal-containing
unleaded petrol and metal-free unleaded petrol grades suitable for use in spark-ignition
internalcombustion engines excluding aviation piston engines.
NOTE Some of the requirements contained in this standard are identical to those prescribed by regulations
(see foreword) for fuel quality.
2 Normative references
The following referenced documents are indispensable for the application of this document. All
normative documents are subject to revision and, since any reference to a normative document is
deemed to be a reference to the latest edition of that document, parties to agreements based on
this document are encouraged to take steps to ensure the use of the most recent editions of the
normative documents indicated below. Information on currently valid national and international
standards can be obtained from Standards South Africa.
ASTM D86, Standard test method for distillation of petroleum products at atmospheric pressure.
ASTM D130, Standard test method for detection of copper corrosion from petroleum products by
the copper strip tarnish test.
ASTM D323, Standard test method for vapor pressure of petroleum products (Reid method).
ASTM D381, Standard test method for gum content in fuels by jet evaporation.
ASTM D525, Standard test method for oxidation stability of gasoline (induction period method).
ASTM D873, Standard test method for oxidation stability of aviation fuels (potential residue
method).
ASTM D1298, Standard test method for density, relative density (specific gravity), or API gravity of
crude petroleum and liquid petroleum products by hydrometer method.
ASTM D1319, Standard test method for hydrocarbon types in liquid petroleum products by
fluorescent indicator adsorption.
ASTM D2699, Standard test method for research octane number of spark-ignition engine fuel.
ASTM D2700, Standard test method for motor octane number of spark-ignition engine fuel.
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SANS 1598:2006
Edition 2
ASTM D3120, Standard test method for trace quantities of sulfur in light liquid petroleum
hydrocarbons by oxidative microcoulometry.
ASTM D3231, Standard test method for phosphorus in gasoline.
ASTM D3237, Standard test method for lead in gasoline by atomic absorption spectroscopy.
ASTM D3242, Standard test method for acidity in aviation turbine fuel.
ASTM D 3341, Standard test method for lead in gasoline – Iodine monochloride method.
ASTM D3348, Standard test method for rapid field test for trace lead in unleaded gasoline
(colorimetric method).
ASTM D3606, Standard test method for determination of benzene and toluene in finished motor and
aviation gasoline by gas chromatography.
ASTM D3831, Standard test method for manganese in gasoline by atomic absorption spectroscopy
ASTM D4052, Standard test method for density and relative density of liquids by digital density
meter.
ASTM D4057, Standard practice for manual sampling of petroleum and petroleum products.
ASTM D4177, Standard practice for automatic sampling of petroleum and petroleum products.
ASTM D4294,Standard test method for sulfur in petroleum and petroleum products by
energydispersive x-ray fluorescence spectrometry.
ASTM D4815, Standard test method for determination of MTBE, ETBE, TAME, DIPE, tertiary-amyl
alcohol and C1 to C4 alcohols in gasoline by gas chromatography.
ASTM D4953, Standard test method for vapor pressure of gasoline and gasoline-oxygenate blends
(dry method).
ASTM D5059, Standard test methods for lead in gasoline by X-ray spectroscopy
ASTM D5191, Standard test method for vapour pressure of petroleum products (mini method).
ASTM D5443, Standard test method for paraffin, naphthene and aromatic hydrocarbon type
analysis in petroleum distillates through 200 degrees C by multidimensional gas chromatography.
ASTM D5453, Standard test method for determination of total sulphur in light hydrocarbons, spark
ignition engine fuel, diesel engine fuel, and engine oil by ultraviolet fluorescence.
ASTM D5580, Standard test method for determination of benzene, toluene, ethyl benzene,
p/mxylene, o-xylene, C9 and heavier aromatics, and total aromatics in finished gasoline by gas
chromatography.
ASTM D6730, Standard test method for determination of individual components in spark ignition
engine fuels by 100-metre capillary (with precolumn) high-resolution gas chromatography.
EN 238, Liquid petroleum products – Petrol – Determination pf benzene content by infrared
spectrometry.
EN 12177, Liquid petroleum products – Unleaded petrol – Determination of benzene content by gas
chromatography.
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SANS1598:2006
Edition 2
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3 Definitions
For the purposes of this standard, the following definitions apply.
3.1
acceptable
acceptable to the authority administering this standard, or to the parties concluding the purchase
contract, as relevant
3.2
additive
compound added to petrol to improve either the performance of the petrol or its storage stability or
both
NOTE Such compounds include alcohols and certain other oxygenated compounds.
3.3
ASTM method
test method published by the ASTM (American Society for Testing and Materials) International, 100
Barr Harbor Drive, PO Box C700, West Conshohocken, PA, 19428-2959 USA.
<http://www.astm.org>
3.4
IP method
test method published by the Energy Institute, 61 New Cavendish Street, London W1G 7AR, UK.
http://www.energyinst.org.uk
4 Requirements
4.1 General
4.1.1 The petrol shall be a hydrocarbon fuel to which additives might have been added to improve
its performance or its storage stability (or both) and shall be suitable for use in spark-ignition
internal-combustion engines other than aviation piston engines. The petrol can also contain small
quantities of harmless colouring materials to give it a distinctive appearance.
4.1.2 At 20 ºC or at the ambient temperature (whichever is higher), the petrol shall be clear and
free from visible water, sediment, suspended matter and any other contaminant that can cause
malfunctioning of equipment designed to use this type of fuel.
4.2.1 The unleaded petrol shall be either a metal-containing grade or a metal-free grade.
4.2.2 The metal-free grade unleaded petrol shall comply with the requirements given in table 1
And table 3 (see also annex A).
4.2.2 The metal-containing grade unleaded petrol shall comply with the requirements given in
table 2 and table 3 (see also annex A).
4.2.3 Metal based additives shall not be included in metal-free unleaded petrol.
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1 2 3 4 5 6 7
Property Requirement Test method
CF1 a CF2 b
Research octane number (RON), min. 95 93 91 95 93 ASTM D2699 or IP 4237
Lead content, mg Pb/L, max. ASTM D5059 or ASTM
D3237 or ASTM D3348 or
13 5 ASTM D3341 or IP 270 or IP
228 or IP 362 or IP 352
Aromatic contents, % volume fraction, max. ASTM D1319 or ASTM
50 35 D5580 or ASTM D5443
Benzene content, % volume fraction, max. EN 12177 or EN 238 or
5 1 ASTM D5580 or ASTM
D5443, or ASTM D3606 or
ASTM D6730
Sulphur content: ASTM D2622 or
a) Metal-Containing ULP d, mg/kg, max. Refer Table 3 n/a ASTM D5453, IP336, or
b) B0 Metal-free ULP d, mg/kg, max. Refer Table 3 10 ASTM D4294
Olefins (max.), % v/v Refer table 3 18 ASTM D1319
EN 14517
1 2 3 4 5
Property Requirement Test method
Research octane number (RON), min. 95 93 91 ASTM D2699 or IP 4237
Lead content, mg Pb/L, max. ASTM D5059 or ASTM
D3237 or ASTM D3348 or
13 ASTM D3341 or IP 270 or IP
228 or IP 362 or IP 352
Manganese content, mg/L, max. ASTM D3831
36
Potassium, content, mg/L, max. 10 IP 456
Phosphorus, content, mg/L, max. 14 ASTM D3231
Aromatic contents, % volume fraction, max. ASTM D1319, ASTM D5580
50 or ASTM D5443
Benzene content, % volume fraction, max. EN 12177 or EN 238 or
ASTM D5580, ASTM D5443,
5 ASTM D4815 or ASTM
D3606 or ASTM D6730
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Table 3 — Other requirements for metal-free and metal-containing unleaded petrol grades
1 2 3 4 5 6 7
Property Requirement Test method
CF1 a CF2 b
Table 3 (concluded)
a CF1 = Clean Fuels 1 (no longer permitted after 28 February 2017)
b
CF2 = Clean Fuels 2
c
Density can be measured at 20ºC (714.8 – 771.2 kg/m³), but controlled and reported at 15ºC
d
ULP = Unleaded Petrol
e Summer = 1 October to 31 March (inclusive).
NOTE 2 Ethers containing five or more carbon atoms per molecule can be included up to a maximum concentration
as indicated in table 3. The oxygen content of the blend will be determined by method ASTM D4815 (MTBE) and
such other methods that can be developed for other C5 ethers.
5.1 Packing
The condition of drums, intermediate bulk containers and road tank vehicles into which the petrol is
filled shall be such as not to be detrimental to the quality of the petrol during normal transportation
and storage and shall comply with the requirements of the relevant of the following standards:
5.2 Marking
The information on each drum shall be in accordance with SANS 10229-1; information on each
intermediate bulk container shall be in accordance with SANS 10233; and information on each road
tank vehicle shall be in accordance with SANS 10232-1.
In the case of labelling, placarding and preparation of shipping documents for petrol that comply
with this standard, the following shall apply:
d) other information including the supplier's brand name or trade mark, the fuel grade and the
quantity.
9
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6 Methods of test
6.1 General
6.1.1 Use the applicable method (or, when relevant, one of the applicable methods) listed in
column 5 of table 1 and in column 4 of table 2.
6.1.2 In the case of dispute regarding the determination of diesel properties listed in table 4, use
the given methods of test and use as a referee, the relevant given method.
1 2
Property Method of test
Lead content ASTM D3341
Aromatic contents ASTM D5443
Benzene content ASTM D5443
Sulphur content ASTM D5453
6.2.1 When testing petrol containing no alcohol, use test method ASTM D323 or IP 69 or
ASTM D5191.
6.2.2 When testing petrol blends containing oxygenates in the form of alcohols or alcohol/ether
mixtures, use test method ASTM D4953.
NOTE When alcohol is present in the petrol, the water introduced when test method ASTM D323 or IP 69 is
used will extract some of the alcohol, causing low Reid vapour pressure values to be obtained.
where
10
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Annex A
(normative)
Notes to purchasers
A.1 The following requirement shall be specified in tender invitations and in each order or
contract:
The grade and octane number of petrol required (see table 1 and table 2).
A.2 The following requirement shall be agreed upon between the supplier and the purchaser:
When the petrol is to be stored for a period exceeding 6 months, any additional requirements for
storage stability (see 4.3.2).
Annex B
(normative)
B.1 Sampling
B.1.1 General
The sampling procedure given in B.1.3 shall be applied in determining whether a lot complies with
the relevant requirements of this standard. The samples so drawn shall be deemed to represent the
lot.
B.1.2 Definitions
B.1.2.1
defective
a test sample of petrol that fails in one or more respects to comply with the relevant requirements of
this standard
B.1.2.2
lot
that quantity of petrol in containers bearing the same brand name or trade mark, grade designation
and batch identification, from one manufacturer, and submitted at any one time for inspection and
testing
11
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Annex C
(informative)
12
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Annex D
(informative)
D.1 Scope
Blends of petrol and alcohol and oxygenates can, from time to time, cause problems with wet or dry
corrosion or both. The water tolerance test determines the ability of such blends to retain water in
solution or in a stable suspension at the specified temperature to which they are likely to be
exposed in use.
D.2.1 Glass measuring cylinder, of capacity 100 mL and fitted with a ground-glass stopper.
D.2.2 Micropipette (complete with disposable tip), capable of accurately dispensing a volume
of 200 µL.
D.3 Procedure
NOTE Conduct the test at a temperature of 20 °C ± 2 °C.
D.3.1 Rinse the measuring cylinder (including its stopper) with the test sample and allow to drain.
D.3.2 Fill the measuring cylinder up to the 100 mL graduation mark with the test sample and,
using the micropipette, add 200 µL of the water.
D.3.3 Stopper the measuring cylinder, shake vigorously for 1 min, and then inspect the test
specimen for signs of phase separation or persistent haze.
D.3.4 Report the sample as having passed the test if no sign of phase separation or persistent
haze is visible.
13
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Annex E
(informative)
E.1 Scope
There may be a need from time to time in the field to establish whether or not a sample of petrol
contains alcohol. The alcohol content test is simple and quick and does not require sophisticated
equipment or specialist operator skills.
E.2.1 Glass mixing cylinder, graduated in millilitres and fitted with a ground-glass stopper. The
cylinder is capable of accepting a total volume of at least 125 mL with the stopper in place.
E.2.3 Ethylene glycol, analytical reagent grade, and that can contain, if so desired, a suitable
concentration of a water-soluble dye (for example 0,02 g of methyl violet per litre).
E.3 Procedure
E.3.1 Fill the mixing cylinder to exactly the 25 mL graduation mark with the ethylene glycol (taking
care not to wet the wall of the cylinder with the ethylene glycol) and, using the measuring cylinder,
add 100 mL of the petrol under test.
E.3.2 Stopper the mixing cylinder, invert it and shake it back and forth 25 times in 15 s, using
strokes each of length approximately 25 cm.
E.3.3 Immediately thereafter, place the mixing cylinder on a vibration-free surface, allow the
contents to settle undisturbed for 5 min, and then record, to the nearest 0,2 mL, the volume of the
layer of ethylene glycol and alcohol in the bottom of the cylinder.
E.3.4 Calculate the difference between the volume of the layer of ethylene glycol and alcohol and
the volume of the ethylene glycol used for the extraction (i.e. 25 mL), and report it as the
percentage, by volume, of alcohol in the petrol.
Annex F
(informative)
14
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Bibliography
ASTM D1250, Standard guide for use of the petroleum measurement tables. (Description only;
tables published separately in 12 volumes.)
SANS 10089-1, The petroleum industry – Part 1: Storage and distribution of petroleum products in
above-ground bulk installations.
SANS 10089-2 (SABS 089-2), The petroleum industry – Part 2: Electrical installations in the
distribution and marketing sector.
SANS 10089-3 (SABS 089-3), The petroleum industry – Part 3: The installation of underground
storage tanks, pumps/dispensers and pipework at service stations and consumer installations.
15
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