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Composites: Part B
journal homepage: www.elsevier.com/locate/compositesb
a r t i c l e i n f o a b s t r a c t
Article history: The effects of polyurea coatings on the response of E-Glass/Vinyl ester curved composite panels subjected
Received 23 November 2011 to underwater explosive loading has been studied. The thickness and location of the polyurea coating has
Received in revised form 5 January 2012 been varied to determine how these parameters affect the transient response. The composite material is a
Accepted 28 February 2012
0°/90° biaxial layup and the coatings are applied to either the loaded or non-loaded faces. The current
Available online 8 March 2012
work utilizes a conical shock tube facility which produces shock loading conditions equivalent to the
underwater detonation of an explosive charge. The transient response of the plates is recorded using a
Keywords:
three-dimensional (3D) Digital Image Correlation system, consisting of high-speed photography and spe-
A. Glass fibers
B. Damage tolerance
cialized post processing software. The results show that for a given polyurea thickness, better perfor-
B. Impact behavior mance is obtained when the back face of the panel is coated. Similarly the performance is improved as
C. Damage mechanics the coating thickness is increased; however this comes at a cost in terms of increased areal weight.
Polyurea The results show that there is likely an optimal coating thickness, that when located on the back face,
provides a balanced tradeoff between panel performance and weight increase.
Published by Elsevier Ltd.
sandwich structures. These studies include the effects of shock and the dry fabric is 0.406 kg/m2 (12 oz/yd2). The panels in the study
impact loading conditions (Jackson and Shukla [7], Schubel et al. consist of 6 plies of the fabric, with each ply oriented in the same
[8], Arora et al. [9]). direction, i.e. the 0° fibers in each ply are parallel. The finished part
In recent years, the use of polyurea materials to enhance the has a thickness of 2.54 mm (0.10 in.), areal weight of 4.25 kg/m2
failure resistance of materials subjected to explosive loading has (126 oz/yd2), and a fiber content of 60% by weight. All panels are
become a topic of interest. Polyurea is a synthetic, high strength/ manufactured through vacuum assisted resin transfer molding.
high elongation coating that is typically spray cast onto existing The composite laminate serves as the baseline substrate to
structures to increase their resistance to shock and ballistic/shrap- which polyurea coatings are applied. In this study both the thick-
nel loading events such as those of an improvised explosive device ness and location of the coating is varied to determine relative ef-
(IED). The armed forces have begun to investigate the suitability of fects. Two coating thicknesses are utilized: 2 mm (0.08 in.) and
these materials for use on military and naval vehicles such as 4 mm (0.16 in.). Additionally each coating thickness is applied to
Humvees, troop carriers and ship hulls, Hodge [10]. Research ef- either the front (loaded) or back (non-loaded) side of the panels.
forts have focused on the use of polyurea coatings on composite These constructions are chosen to represent what would typically
plates, steel plates and as inner layers of sandwich composite be found in a real world application where structures are retrofit-
structures. Tekalur et al. [11] studied polyurea based layered com- ted (spray coated) with this material as opposed to being incorpo-
posite materials subjected to blast loading and showed that sand- rated into the original design (Hodge [10]). The polyurea material
wich materials prepared by sandwiching the polyurea between is applied to the composite panel after manufacturing and is not
two composite skins had the best blast resistance compared to part of the infusion process. The polyurea is sprayed on the panels
the E-Glass/Vinyl ester composite and polyurea layered plates. and then post cured for 48 h at a temperature of 160 F.
Amini et al. [12,13] have studied the effects of monolithic and poly- The polyurea material used for coating the panels is Dragon-
urea coated steel plates subjected to impulsive loads and showed shield-BC available from Specialty Products, Inc. of Lakewood,
that polyurea has a positive damage mitigation effect when applied WA. This is a 2 part material that can be spray applied to a wide
to the back face of the material. Similar results were observed by range of surfaces and materials. The product is typically used for
Gardner et al. [14] when investigating the effect of polyurea in blast mitigation and fragment containment in applications includ-
sandwich composites. Results indicated that when a layer of poly- ing walls, structures, and vehicle protection. Mechanical properties
urea is placed between the foam core and the back face of the of the polyurea published by the manufacturer include a tensile
sandwich the blast resistance is improved, while conversely if strength of over 37.9 MPa (5500 lb/in.2) and an elongation of 344%.
the polyurea is placed between the front face and the foam core A summary of the panel thicknesses and areal weights is pro-
the performance is degraded. vided in Table 1, and a schematic of the laminate designs are
shown in Fig. 1. The mechanical properties for the 0°/90° baseline
composite are provided in Table 2.
2. Composite material The geometry of the plates consists of a curved midsection with
a flat boundary as shown in Fig. 2. The convex face of the plate rep-
The composite material used in this study is an E-Glass/Vinyl resents the mold line in the manufacturing process and has a ra-
ester composite with a 0°/90° biaxial layup. The glass fabric is a dius of curvature of 18.28 cm (7.2 in.), an outer diameter of
balanced construction of 0° and 90° fibers with the two layers 26.54 cm (10.5 in.), and the curved portion of the plate is
being stitched together rather than woven. The areal weight of 22.86 cm (9.0 in.) in diameter.
Table 1 Table 2
Thickness and areal weight of laminates. 0°/90° Baseline laminate – mechanical properties (ASTM 638).
4. Experimental procedure
transducer in front of the panel. Using the baseline panel as a ref- (Front/Back) the performance is better when the back face is
erence for comparison, it is seen that the panel with 4 mm coated. This is true for both the 2 mm (0.08 in.) and 4 mm
(0.160 in.) of polyurea on the back face has the best overall perfor- (0.16 in.) coating thicknesses. The second is that when comparing
mance, while the panel with 2 mm (0.08 in.) on the front face has the effect of thickness for a given location, the performance is en-
the worst performance in terms of peak deflections. The panels hanced as the coating thickness is increased.
coated with 4 mm on the front and 2 mm on the back have approx- In addition to the point-wise histories presented in Fig. 10, the
imately the same peak deflection. It is noted that although these full-field displacement evolution for each panel configuration is
two panels have approximately the same peak deflections, the pa- shown in Fig. 11. In this figure it is observed that for all of the pan-
nel with the coating on the front has a higher overall thickness and els the deflection profiles are not radially symmetric as would be
areal weight. After the first pressure peak the baseline laminate expected for this type of panel geometry. Rather, the deflections
sustains a center point displacement of 33.5 mm (1.31 in.) while tend to evolve from a point located along one of the 45° plate axes
the deflection for the 4 mm back face polyurea sample is 11 mm and then grow towards the center. For the current 0°/90° panel
(0.43 in.), a decrease of 67%. In the case of the 2 mm front face pa- construction the ±45° axes are the weakest material direction
nel the center point displacement is 40 mm (1.57 in.), an increase and this is the likely cause of this type of deformation behavior.
of 20% over the baseline. It can be seen that when the front face Additionally because each panel is made individually there are
of the panel is coated with 4 mm the peak displacement is less than small thickness variations as well as the possible presence of voids
the baseline panel which is in contrast to the 2 mm on the front and resin rich or dry locations within a given panel. The presence of
face panel. This is likely due to a tradeoff between the performance these manufacturing variables along with the weaker material
degrading effects seen in the 2 mm front face panel, and an in- directions likely causes the deformation to initiate from one of
crease in thickness and mass. Thin polyurea coatings on the front the 45° directions and then propagate from there. On the full-field
face appear to initially degrade the structural performance, and level it is seen that the panel with 4 mm (0.16 in.) of polyurea on
then as the coatings reach a critical point the effects of additional the back shows the least overall displacements, similar to the cen-
mass and thickness become the dominant contributors to the re- ter point displacements discussed previously. The displacement
sponse and decrease the deflections. time histories for the point from which the deformation evolves
From Fig. 10, a couple of trends can be highlighted. The first is for each panel are shown in Fig. 12. Since the weak point varies
that when comparing the effect of polyurea location on the panel from plate to plate, the point of maximum deflection also varies.
572 J. LeBlanc et al. / Composites: Part B 44 (2013) 565–574
The point for which each time history in Fig. 12 was extracted is tios for the 2 mm (0.08 in.) and 4 mm (0.16 in.) panels are 1.8 and
annotated below the figure for clarity. From this plot it evident that 2.6 respectively. Similarly the areal weight ratios for the 2 mm and
the trends that were observed when comparing the center point 4 mm panels are 1.5 and 2 respectively. The values are not the
displacements remain unchanged. The 4 mm back face configura- same for thickness and areal weight due to the panels being a com-
tion provides the largest performance increase while the 2 mm bination of composite and polyurea rather than a homogeneous
(0.08 in.) on the front degrades the performance as compared to material.
the baseline. The displacement data that has been adjusted to account for
When evaluating the effects of these types of coatings the pen- thickness and areal mass increases is shown in Figs. 13 and 14
alty in terms of thickness and areal weight increases should also be respectively. In these plots it is seen that when the displacements
considered. Observations based on the transient displacement data are adjusted to account for the cost due to increased thickness and
do not highlight the fact that both the panel thickness and areal areal weight, the baseline panel outperforms both panels with
weights have been increased. In order to investigate this, the dis- polyurea coatings on the front face and also the panel with 2 mm
placement data is adjusted based on the thickness and areal weight (0.08 in.) on the back. The 4 mm (0.16 in.) coating on the back
ratios between the coated panels and the baseline by multiplying has approximately the same thickness adjusted performance and
the displacement data by the corresponding panel ratio. The thick- a better areal weight adjusted performance than the baseline.
ness ratio (TR) and areal weight ratio (AWR) are defined as the Although the 4 mm front face coated panel had a better perfor-
coated panel value divided by the baseline value. The thickness ra- mance than the baseline when using the raw displacement data,
J. LeBlanc et al. / Composites: Part B 44 (2013) 565–574 573
the performance is worse when the cost of additional thickness/ cuses on the velocity profile resulting from the initial shock pres-
areal weight is factored in. A similar effect is seen for the case of sure. From the figure it is seen that the magnitude of the kick off
the 2 mm back face panel, which although it outperformed the velocity for each of the laminates is nearly the same, approxi-
baseline panel from a pure displacement perspective, it is worse mately 16–17 m/s (52.5–55.7 ft/s). There is a difference, however,
than the baseline when thickness and weight considerations are in the time that it takes for the velocity to decay back to zero for
made. From these figures it can also be seen that the 2 mm and each of the panels. The velocity of the baseline laminate fully de-
4 mm coatings on the front face have approximately the same rel- cays over 4.5 ms. The panel with 2 mm (0.08 in.) on the front face
ative performance when thickness and areal weight penalties are takes a slightly longer time to fully decay, 4.7 ms to return to rest
taken into account. Finally when comparing the 4 mm back face resulting in the larger displacement previously discussed. Con-
panel from an areal weight penalty perspective it still outperforms versely, the back face coated panels and the 4 mm (0.16 in.) on
the baseline panel. This indicates that there is likely an optimal the front panel all come to rest quicker than the baseline, 4 ms
polyurea thickness, when located on the back face, that outper- for the 4 mm front face and the 2 mm back face configurations,
forms a baseline structure on both a pure displacement level as and 2.25 ms for the 4 mm on the back face.
well as when increased thickness and areal weight penalties are
factored in. These observations indicate that the shock perfor-
mance of a baseline structure can be improved if an optimal thick- 6. Summary and conclusions
ness of polyurea is applied to the back face of a curved structure.
The velocity time history comparison for the center point of The effects of polyurea coatings on the dynamic response of E-
each of the panel configurations is shown in Fig. 15. The plot fo- Glass/Vinyl ester composite plates have been studied, specifically
574 J. LeBlanc et al. / Composites: Part B 44 (2013) 565–574
the effects of thickness and location. A water filled, conical shock edged. Arun Shukla would like to acknowledge the support of Of-
tube facility has been used to impart shock loading to the compos- fice of Naval Research under ONR Grant No. N00014-10-1-0662
ite plates. The loading conditions are similar to those resulting (Dr. Y.D.S. Rajapakse) to the University of Rhode Island. Bruce
from a free-field underwater detonation of an explosive charge. Booker, Steve Morin, and Jim Sinclair are thanked for their opera-
The composite plates have a curved midsection and are oriented tion of the shock tube facility. Lastly the authors acknowledge Spe-
with the convex surface facing towards the incident shock wave. cialty Products, Inc., specifically Shere Bush, for providing the
The panels are held with clamped boundary conditions at the outer polyurea material used in this study.
edge. A 3D Digital Image Correlation system is used to capture the
full-field, transient response of the back (dry) surface of the plates. References
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