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Composites: Part B 44 (2013) 565–574

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Composites: Part B
journal homepage: www.elsevier.com/locate/compositesb

Effect of polyurea coatings on the response of curved E-Glass/Vinyl ester


composite panels to underwater explosive loading
James LeBlanc a,⇑, Nate Gardner b, Arun Shukla b
a
Naval Undersea Warfare Center (Division Newport), 1176 Howell Street, Newport, RI 02841, United States
b
University of Rhode Island, 92 Upper College Road, Kingston, RI 02881, United States

a r t i c l e i n f o a b s t r a c t

Article history: The effects of polyurea coatings on the response of E-Glass/Vinyl ester curved composite panels subjected
Received 23 November 2011 to underwater explosive loading has been studied. The thickness and location of the polyurea coating has
Received in revised form 5 January 2012 been varied to determine how these parameters affect the transient response. The composite material is a
Accepted 28 February 2012
0°/90° biaxial layup and the coatings are applied to either the loaded or non-loaded faces. The current
Available online 8 March 2012
work utilizes a conical shock tube facility which produces shock loading conditions equivalent to the
underwater detonation of an explosive charge. The transient response of the plates is recorded using a
Keywords:
three-dimensional (3D) Digital Image Correlation system, consisting of high-speed photography and spe-
A. Glass fibers
B. Damage tolerance
cialized post processing software. The results show that for a given polyurea thickness, better perfor-
B. Impact behavior mance is obtained when the back face of the panel is coated. Similarly the performance is improved as
C. Damage mechanics the coating thickness is increased; however this comes at a cost in terms of increased areal weight.
Polyurea The results show that there is likely an optimal coating thickness, that when located on the back face,
provides a balanced tradeoff between panel performance and weight increase.
Published by Elsevier Ltd.

1. Introduction Historically, there have been two experimental methodologies


used to impart shock loading conditions to structures: (1) explo-
Composite materials have been widely used in a variety of sives and (2) shock tubes. Although the use of explosives offers
applications in the marine, automotive, and transportation indus- an ease of use, there are associated deficiencies such as spherical
tries. These materials offer the advantages of high strength to wave fronts and pressure signatures which are often spatially com-
weight ratios, reduced maintenance costs, and improved corrosion plex and difficult to capture. Shock tubes offer the advantage of
resistance. Recently, there has been an increased interest in com- plane wave fronts and wave parameters that are easily controlled
posite materials for use in military applications including land and repeated. The current study utilizes a water filled, conical
vehicles (structural components and armor solutions), advanced shock tube that replicates the free field pressure wave expansion
ship hull designs, and submarine components. The use of these of an underwater explosion.
materials in wartime environments requires that they not only The response of materials subjected to shock loading has been
be able to withstand the loads produced by everyday use, but also studied over a wide range of conditions including underwater
those imparted from explosions and high-speed projectile impact. and air blasts as well as impacts. The effect of shock loading on
The response of these materials under quasi-static conditions is stainless steel plates subjected to underwater impulsive loads
well established. However, the response at the high strain rates has been presented by Espinosa et al. [1]. Nurick et al. [2,3] have
that shock loading can induce is not well understood. This leads studied the effects of boundary conditions on plates subjected to
to an inherent conservative approach to be taken when these blast loading and identified distinct failure modes depending on
structures are designed and constructed. Typically this results in the magnitude of the impulse and standoff. The response of E-Glass
structures which do not fully utilize the weight savings afforded and Carbon based composite laminates under shock and explosive
by these materials. The focus of the current research is on the re- loading (including the effects of heat generation during combus-
sponse of composite materials subjected to underwater explosions, tion) has been presented by Tekalur et al. [4]. Mouritz [5] studied
UNDEX. the effectiveness of adding a light weight, through thickness
stitching material to increase the damage resistance of composites.
LeBlanc et al. [6] have studied the effects of shock loading on three-
⇑ Corresponding author. Tel.: +1 401 832 7920; fax: +1 401 832 7207. dimensional woven composite materials. Recently, there has been
E-mail address: JAMES.M.LEBLANC@Navy.mil (J. LeBlanc). an increased interest in the study of the effect of shock loading on

1359-8368/$ - see front matter Published by Elsevier Ltd.


http://dx.doi.org/10.1016/j.compositesb.2012.02.038
566 J. LeBlanc et al. / Composites: Part B 44 (2013) 565–574

sandwich structures. These studies include the effects of shock and the dry fabric is 0.406 kg/m2 (12 oz/yd2). The panels in the study
impact loading conditions (Jackson and Shukla [7], Schubel et al. consist of 6 plies of the fabric, with each ply oriented in the same
[8], Arora et al. [9]). direction, i.e. the 0° fibers in each ply are parallel. The finished part
In recent years, the use of polyurea materials to enhance the has a thickness of 2.54 mm (0.10 in.), areal weight of 4.25 kg/m2
failure resistance of materials subjected to explosive loading has (126 oz/yd2), and a fiber content of 60% by weight. All panels are
become a topic of interest. Polyurea is a synthetic, high strength/ manufactured through vacuum assisted resin transfer molding.
high elongation coating that is typically spray cast onto existing The composite laminate serves as the baseline substrate to
structures to increase their resistance to shock and ballistic/shrap- which polyurea coatings are applied. In this study both the thick-
nel loading events such as those of an improvised explosive device ness and location of the coating is varied to determine relative ef-
(IED). The armed forces have begun to investigate the suitability of fects. Two coating thicknesses are utilized: 2 mm (0.08 in.) and
these materials for use on military and naval vehicles such as 4 mm (0.16 in.). Additionally each coating thickness is applied to
Humvees, troop carriers and ship hulls, Hodge [10]. Research ef- either the front (loaded) or back (non-loaded) side of the panels.
forts have focused on the use of polyurea coatings on composite These constructions are chosen to represent what would typically
plates, steel plates and as inner layers of sandwich composite be found in a real world application where structures are retrofit-
structures. Tekalur et al. [11] studied polyurea based layered com- ted (spray coated) with this material as opposed to being incorpo-
posite materials subjected to blast loading and showed that sand- rated into the original design (Hodge [10]). The polyurea material
wich materials prepared by sandwiching the polyurea between is applied to the composite panel after manufacturing and is not
two composite skins had the best blast resistance compared to part of the infusion process. The polyurea is sprayed on the panels
the E-Glass/Vinyl ester composite and polyurea layered plates. and then post cured for 48 h at a temperature of 160 F.
Amini et al. [12,13] have studied the effects of monolithic and poly- The polyurea material used for coating the panels is Dragon-
urea coated steel plates subjected to impulsive loads and showed shield-BC available from Specialty Products, Inc. of Lakewood,
that polyurea has a positive damage mitigation effect when applied WA. This is a 2 part material that can be spray applied to a wide
to the back face of the material. Similar results were observed by range of surfaces and materials. The product is typically used for
Gardner et al. [14] when investigating the effect of polyurea in blast mitigation and fragment containment in applications includ-
sandwich composites. Results indicated that when a layer of poly- ing walls, structures, and vehicle protection. Mechanical properties
urea is placed between the foam core and the back face of the of the polyurea published by the manufacturer include a tensile
sandwich the blast resistance is improved, while conversely if strength of over 37.9 MPa (5500 lb/in.2) and an elongation of 344%.
the polyurea is placed between the front face and the foam core A summary of the panel thicknesses and areal weights is pro-
the performance is degraded. vided in Table 1, and a schematic of the laminate designs are
shown in Fig. 1. The mechanical properties for the 0°/90° baseline
composite are provided in Table 2.
2. Composite material The geometry of the plates consists of a curved midsection with
a flat boundary as shown in Fig. 2. The convex face of the plate rep-
The composite material used in this study is an E-Glass/Vinyl resents the mold line in the manufacturing process and has a ra-
ester composite with a 0°/90° biaxial layup. The glass fabric is a dius of curvature of 18.28 cm (7.2 in.), an outer diameter of
balanced construction of 0° and 90° fibers with the two layers 26.54 cm (10.5 in.), and the curved portion of the plate is
being stitched together rather than woven. The areal weight of 22.86 cm (9.0 in.) in diameter.

Table 1 Table 2
Thickness and areal weight of laminates. 0°/90° Baseline laminate – mechanical properties (ASTM 638).

Thickness, Areal weight MPa (lb/in.2)


mm (in.) kg/m2 (oz/yd2)
Tensile modulus (0°) 15.8e3 (2.3e6)
0°/90° Baseline laminate 2.54 (0.10) 4.25 (126) Tensile modulus (90°) 15.8e3 (2.3e6)
0°/90° Baseline with 2 mm polyurea coating 4.57 (0.18) 6.54 (193) Tensile strength (0°) 324.0 (47.0e3)
0°/90° Baseline with 4 mm polyurea coating 6.60 (0.26) 8.40 (248) Tensile strength (90°) 324.0 (47.0e3)

Fig. 1. Composite plate construction – schematic (not to scale).


J. LeBlanc et al. / Composites: Part B 44 (2013) 565–574 567

Fig. 2. Composite plate geometry (section view).

Fig. 3. Conical shock tube schematic (not to scale).

3. Shock loading apparatus

A conical shock tube (CST) facility located at the Naval Undersea


Warfare Center, Division Newport, was utilized in the shock load-
ing of the composite materials. The shock tube is a horizontally
mounted, water filled tube with a conical internal shape, as shown
in Fig. 3. The tube geometry represents a solid angle segment of the
pressure field which results from the detonation of a spherical,
explosive charge (Fig. 4). In an open water environment, the pres-
sure wave expands from the charge location as a spherical wave. In
the shock tube, the rigid wall acts to confine the expansion of the
pressure wave in a manner that simulates a conical sector of the
pressure field. In order to compare free field and shock tube pres-
sure values, it is useful to define an amplification factor, which is
the ratio between the volume of a spherical charge to the volume
of the conical sector charge and is defined by Poche and Zalesak
[15] as
Fig. 4. Explosive charge in shock tube [15].
1
AF ¼ 2 
sin a4
tance as that produced in the shock tube by a segment of charge
where a is the cone angle. weight, w. The reduction in the amplification factor is typically
This equation assumes perfectly rigid wall conditions which are attributed to the elastic deformation of the shock tube walls. Fur-
not fully realized. Therefore, the actual amplification factor is less ther discussion on the development and history of the water filled
than the calculated value and is typically reported as an effective conical shock tube is provided by Refs. [16,17].
weight amplification factor. This is defined by Poche and Zalesak The internal cone angle of the shock tube is 2.6°. The tube is
[15] as the ratio between the weight of a spherical charge, W, re- 5.25 m (207 in.) long from the charge location to the location of
quired to produce the same peak pressure at a given standoff dis- the test specimen and internally contains 98.4 L (26 gal) of water
568 J. LeBlanc et al. / Composites: Part B 44 (2013) 565–574

Fig. 5. Typical pressure profile generated in the conical shock tube.

incoming shock fronts. This is chosen so that the experiment will


represent geometries commonly used in underwater applications
with curved surfaces typically facing into the fluid (i.e. submersible
vehicle hull forms).

4. Experimental procedure

Shock testing of the composite material has been performed


with the CST utilizing a fixed end cap. The use of the fixed end
cap configuration allows the plate to absorb the full energy level
of the shock and sustain a level of visible damage (matrix cracking,
fiber breakage, and delamination). The tube can also be configured
with a sliding piston end cap (LeBlanc and Sfukla [18]) to lower the
level of energy the plate absorbs, but is not utilized in this study.
All experiments were performed two times to ensure repeatability.
High-speed photography coupled with a 3D Digital Image Correla-
tion system, is utilized to capture the back face transient response
during the shock event. This system offers the advantage that it is a
non-contact measurement technique which gives full-field infor-
mation and eliminates the difficulties associated with measure-
Fig. 6. Shock tube mounting configuration. ment techniques which require direct bonding of gages and
transducers. These methods often suffer from transducer/gage sep-
aration and de-bonding at high shock levels with large flexural
at atmospheric pressure. The pressure shock wave is initiated by deformations. The explosive charge used in the study is an M6
the detonation of an explosive charge at the breech end of the tube blasting cap with a net TNT equivalence of 1.32 g. This yields peak
(left side of figure) which then proceeds down the length of the pressures at the sensor location (.508 m in front of the test speci-
tube. Peak shock pressures from 10.3 MPa (1500 lb/in.2) to men) of approximately 11 MPa (1600 lb/in.2).
20.6 MPa (3000 lb/in.2) can be obtained depending on the amount The Digital Image Correlation (DIC) technique is used to capture
of explosive charge used. A typical pressure profile, as obtained the transient response of the back face (dry) of the plates. DIC is a
from the pressure transducers is shown in Fig. 5. This figure illus- non-intrusive, optical technique for capturing the full-field, tran-
trates the rapid pressure increase associated with the shock front sient response of the panels through the use of high-speed photog-
followed by a general exponential decay of the wave. This profile raphy and specialized software. Capturing the three-dimensional
was obtained using a M6 Blasting Cap – 1.32 g (.00292 lb) TNT response of the plates requires that two cameras be used in a ste-
Equivalency and is measured 0.508 m (20 in.) from the impact face reo configuration. To record the transient response with this sys-
of the plate. The length of the tube is sufficient so that the curva- tem, the cameras must be calibrated and have synchronized
ture of the wave front is minimal and plane wave conditions are image recording throughout the event. The calibration of the cam-
nearly established at the specimen. eras is performed by placing a grid containing a known pattern of
A mounting fixture has been designed so the test specimens are points (dots) in the test space where the composite sample is lo-
air backed with fully clamped edges. The specimens have an over- cated during the experiment. This grid is then translated and ro-
all diameter of 26.54 cm (10.5 in.) with a 22.86 cm (9.0 in.) unsup- tated in and out of plane while manually recording a series of
ported middle section. The mounting arrangement is shown in images. As this grid pattern is predetermined, the coordinates of
Fig. 6. In all experiments the panels are mounted such that the the center of each point (dot) is extracted from each image. The
material directions are consistent, i.e. the 0° fibers run vertically. coordinate locations of each dot extracted uniquely for each cam-
The specimens are mounted with the convex surface towards the era, allows for a correspondence of the coordinate system of each
J. LeBlanc et al. / Composites: Part B 44 (2013) 565–574 569

Fig. 7. Schematic of the Digital Image Correlation setup.

camera (Tiwari et al. [19]). The DIC analysis is then performed on


the image pairs that are recorded during the shock event. Prior
to the experiment, the back face of the sample is painted white
and then coated with a randomized speckle pattern, as shown in
Fig. 7. The post processing is performed with the VIC-3D software
package (Correlated Solutions) which matches common pixel sub-
sets of the random speckle pattern between the deformed and un-
deformed images. The matching of pixel subsets is used to calcu-
late the three-dimensional location of distinct points on the face
of the panel throughout time. This technique has been applied as
a full-field measurement technique in many applications including
shock loading (Tiwari et al. [20]).
Two high-speed digital cameras, Photron SA1, are positioned
behind the shock tube (Fig. 7). The use of two cameras allows for
the out-of-plane behavior and results to be captured. The distance
from the lens of the camera to the specimen is 1.44 m (57 in.) and
Fig. 8. Digital Image Correlation setup (not to scale). each camera is angled at approximately 7° with respect to the sym-

Fig. 9. Pressure–deformation history correlations.


570 J. LeBlanc et al. / Composites: Part B 44 (2013) 565–574

Fig. 10. Time history deformation comparison.

metry plane, as observed in Fig. 8. A frame rate of 20,000 was used A2 ¼ A1  A4


which corresponds to an inter-frame time of 50 ls. C 1A qA
A4 ¼ ðA1 þ A2 Þ
C 1B qB
5. Results
where C1 and q are the longitudinal wave speed and the density of
The effectiveness of each of the polyurea coatings, as compared the water (A) and the composite (B).
to the baseline (uncoated) panels, is evaluated through comparison For the water the wave speed and density are 1500 m/s and
of displacement and velocity time histories, as well as full-field DIC 1000 kg/m3 and for the composite material the values are
observations. The deformation and velocity histories are presented 3060 m/s and 1680 kg/m3. These parameters yield a reflected wave
for distinct points on the back face of the panels, and are extracted amplitude that is 55% of the incident wave. The development of
from the DIC post processed data. these equations assume that the surfaces are perfectly bonded
The pressure profile obtained from the experiment with the with matching displacements and stresses at the interface [21]. It
baseline laminate is shown in Fig. 9. The pressure history can be is likely that these conditions are not fully realized with one of
separated into three distinct time regimes. The first is the initial the mediums being water which carries no shear stress, and has
shock wave, which has time duration of less than 1 ms from pres- the possibility of separating from the composite forming a cavitia-
sure arrival to decay to ambient. The second set of pressure waves tion region during the initial deformation of the plate. The develop-
arrive at the pressure transducer approximately 10.5 ms after the ment of cavitiation at the water/plate interface has been observed
initial shock front. This secondary wave is formed when the veloc- by Espinosa et al. [1] for experiments with steel plates. If perfect
ity of the plate is brought to rest. During the initial deformation of matching conditions are not fully realized then the reflected wave
the plate, the water moves with the plate surface. When the move- has the possibility of further magnitude reduction from the analyt-
ment of the plate is arrested, the momentum associated with the ical value of 55%. Furthermore, these equations assume a flat inter-
water causes it to compress against the plate and a high pressure face normal to the incident wave. In the current configuration the
wave is developed. This wave then propagates down the length wave is interacting with a convexly curved surface which will act
of the tube, reaches the breech end, and is reflected back towards to disperse the wave front, further reducing the magnitude of the
the plate. The time delay from this secondary wave reaching the reflected wave that the pressure transducer would measure. Previ-
transducer, traveling down the tube, and arriving back at the trans- ous work has observed similar reduced reflection waves. Experi-
ducer is expected to be on the order of 5.5 ms based on the dis- ments performed by Espinosa et al. [1] with steel plates
tance of travel from the transducer to the charge location and is measured reflected waves on the order of 60% of the incident,
clearly seen in Fig. 9. The bubble pulse for the charge weight and whereas the theory predicts a value of 95%.
conditions that are used in this study is calculated to be on the or- The center point deformation time history along with the corre-
der of 30 ms, and is confirmed by the high pressures seen in the sponding pressure profile for the case of the baseline laminate is
pressure profiles at this time. The pressure profiles recorded for shown in Fig. 9. It can be seen in this figure that the initial shock
each test are comparable to that presented in Fig. 10 in terms of causes a deformation of the center point (0–5 ms), a small recovery
peak pressure and time decay. It is important to note the absence (5–10 ms), and finally a temporary arresting of the motion (10–
of a reflection of the incident shock wave in the pressure signal. 15 ms). After this arresting of the motion, the secondary pressure
This is attributed to the similar acoustic impedance values of the wave reflection arrives (15 ms) and restarts the deformation pro-
water and the composite plate, as well as the fluid–structure inter- cess of the plate. The effect of the secondary pressure wave is suf-
action of a plane wave with a curved surface. Consider the case of a ficient to restart the deformation process which continues to full
dilatation wave arriving at the interface between two dissimilar inversion of the plate. A similar trend is seen for the other panel
materials (water–composite interface). The wave will be partially configurations in this study.
transmitted into the plate and partially reflected back into the The center point displacement–time history as obtained from
water. The magnitudes of the reflected (A2) and transmitted (A4) the DIC data for the five panel configurations tested is shown in
waves as a function of the incident wave (A1) are given by Sadd Fig. 10. In all of the following time history plots, time zero is taken
[21] as to be the time of arrival of the initial shock front at the pressure
J. LeBlanc et al. / Composites: Part B 44 (2013) 565–574 571

Fig. 11. Full-field deformation evolution.

transducer in front of the panel. Using the baseline panel as a ref- (Front/Back) the performance is better when the back face is
erence for comparison, it is seen that the panel with 4 mm coated. This is true for both the 2 mm (0.08 in.) and 4 mm
(0.160 in.) of polyurea on the back face has the best overall perfor- (0.16 in.) coating thicknesses. The second is that when comparing
mance, while the panel with 2 mm (0.08 in.) on the front face has the effect of thickness for a given location, the performance is en-
the worst performance in terms of peak deflections. The panels hanced as the coating thickness is increased.
coated with 4 mm on the front and 2 mm on the back have approx- In addition to the point-wise histories presented in Fig. 10, the
imately the same peak deflection. It is noted that although these full-field displacement evolution for each panel configuration is
two panels have approximately the same peak deflections, the pa- shown in Fig. 11. In this figure it is observed that for all of the pan-
nel with the coating on the front has a higher overall thickness and els the deflection profiles are not radially symmetric as would be
areal weight. After the first pressure peak the baseline laminate expected for this type of panel geometry. Rather, the deflections
sustains a center point displacement of 33.5 mm (1.31 in.) while tend to evolve from a point located along one of the 45° plate axes
the deflection for the 4 mm back face polyurea sample is 11 mm and then grow towards the center. For the current 0°/90° panel
(0.43 in.), a decrease of 67%. In the case of the 2 mm front face pa- construction the ±45° axes are the weakest material direction
nel the center point displacement is 40 mm (1.57 in.), an increase and this is the likely cause of this type of deformation behavior.
of 20% over the baseline. It can be seen that when the front face Additionally because each panel is made individually there are
of the panel is coated with 4 mm the peak displacement is less than small thickness variations as well as the possible presence of voids
the baseline panel which is in contrast to the 2 mm on the front and resin rich or dry locations within a given panel. The presence of
face panel. This is likely due to a tradeoff between the performance these manufacturing variables along with the weaker material
degrading effects seen in the 2 mm front face panel, and an in- directions likely causes the deformation to initiate from one of
crease in thickness and mass. Thin polyurea coatings on the front the 45° directions and then propagate from there. On the full-field
face appear to initially degrade the structural performance, and level it is seen that the panel with 4 mm (0.16 in.) of polyurea on
then as the coatings reach a critical point the effects of additional the back shows the least overall displacements, similar to the cen-
mass and thickness become the dominant contributors to the re- ter point displacements discussed previously. The displacement
sponse and decrease the deflections. time histories for the point from which the deformation evolves
From Fig. 10, a couple of trends can be highlighted. The first is for each panel are shown in Fig. 12. Since the weak point varies
that when comparing the effect of polyurea location on the panel from plate to plate, the point of maximum deflection also varies.
572 J. LeBlanc et al. / Composites: Part B 44 (2013) 565–574

Fig. 12. Maximum deflection point time history.

Fig. 13. Time history deformation comparison (thickness effect).

The point for which each time history in Fig. 12 was extracted is tios for the 2 mm (0.08 in.) and 4 mm (0.16 in.) panels are 1.8 and
annotated below the figure for clarity. From this plot it evident that 2.6 respectively. Similarly the areal weight ratios for the 2 mm and
the trends that were observed when comparing the center point 4 mm panels are 1.5 and 2 respectively. The values are not the
displacements remain unchanged. The 4 mm back face configura- same for thickness and areal weight due to the panels being a com-
tion provides the largest performance increase while the 2 mm bination of composite and polyurea rather than a homogeneous
(0.08 in.) on the front degrades the performance as compared to material.
the baseline. The displacement data that has been adjusted to account for
When evaluating the effects of these types of coatings the pen- thickness and areal mass increases is shown in Figs. 13 and 14
alty in terms of thickness and areal weight increases should also be respectively. In these plots it is seen that when the displacements
considered. Observations based on the transient displacement data are adjusted to account for the cost due to increased thickness and
do not highlight the fact that both the panel thickness and areal areal weight, the baseline panel outperforms both panels with
weights have been increased. In order to investigate this, the dis- polyurea coatings on the front face and also the panel with 2 mm
placement data is adjusted based on the thickness and areal weight (0.08 in.) on the back. The 4 mm (0.16 in.) coating on the back
ratios between the coated panels and the baseline by multiplying has approximately the same thickness adjusted performance and
the displacement data by the corresponding panel ratio. The thick- a better areal weight adjusted performance than the baseline.
ness ratio (TR) and areal weight ratio (AWR) are defined as the Although the 4 mm front face coated panel had a better perfor-
coated panel value divided by the baseline value. The thickness ra- mance than the baseline when using the raw displacement data,
J. LeBlanc et al. / Composites: Part B 44 (2013) 565–574 573

Fig. 14. Time history deformation comparison (areal weight effect).

Fig. 15. Velocity history deformation comparison.

the performance is worse when the cost of additional thickness/ cuses on the velocity profile resulting from the initial shock pres-
areal weight is factored in. A similar effect is seen for the case of sure. From the figure it is seen that the magnitude of the kick off
the 2 mm back face panel, which although it outperformed the velocity for each of the laminates is nearly the same, approxi-
baseline panel from a pure displacement perspective, it is worse mately 16–17 m/s (52.5–55.7 ft/s). There is a difference, however,
than the baseline when thickness and weight considerations are in the time that it takes for the velocity to decay back to zero for
made. From these figures it can also be seen that the 2 mm and each of the panels. The velocity of the baseline laminate fully de-
4 mm coatings on the front face have approximately the same rel- cays over 4.5 ms. The panel with 2 mm (0.08 in.) on the front face
ative performance when thickness and areal weight penalties are takes a slightly longer time to fully decay, 4.7 ms to return to rest
taken into account. Finally when comparing the 4 mm back face resulting in the larger displacement previously discussed. Con-
panel from an areal weight penalty perspective it still outperforms versely, the back face coated panels and the 4 mm (0.16 in.) on
the baseline panel. This indicates that there is likely an optimal the front panel all come to rest quicker than the baseline, 4 ms
polyurea thickness, when located on the back face, that outper- for the 4 mm front face and the 2 mm back face configurations,
forms a baseline structure on both a pure displacement level as and 2.25 ms for the 4 mm on the back face.
well as when increased thickness and areal weight penalties are
factored in. These observations indicate that the shock perfor-
mance of a baseline structure can be improved if an optimal thick- 6. Summary and conclusions
ness of polyurea is applied to the back face of a curved structure.
The velocity time history comparison for the center point of The effects of polyurea coatings on the dynamic response of E-
each of the panel configurations is shown in Fig. 15. The plot fo- Glass/Vinyl ester composite plates have been studied, specifically
574 J. LeBlanc et al. / Composites: Part B 44 (2013) 565–574

the effects of thickness and location. A water filled, conical shock edged. Arun Shukla would like to acknowledge the support of Of-
tube facility has been used to impart shock loading to the compos- fice of Naval Research under ONR Grant No. N00014-10-1-0662
ite plates. The loading conditions are similar to those resulting (Dr. Y.D.S. Rajapakse) to the University of Rhode Island. Bruce
from a free-field underwater detonation of an explosive charge. Booker, Steve Morin, and Jim Sinclair are thanked for their opera-
The composite plates have a curved midsection and are oriented tion of the shock tube facility. Lastly the authors acknowledge Spe-
with the convex surface facing towards the incident shock wave. cialty Products, Inc., specifically Shere Bush, for providing the
The panels are held with clamped boundary conditions at the outer polyurea material used in this study.
edge. A 3D Digital Image Correlation system is used to capture the
full-field, transient response of the back (dry) surface of the plates. References
This allowed for real time recording of the displacement and veloc-
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and velocity of the back face of the panels. The results are com- stiffened square plates. Int J Impact Eng 1995;16:273–91.
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which is adjusted to account for relative thickness and areal weight [4] Tekalur AS, Shivakumar K, Shukla A. Mechanical behavior and damage
increases. The displacement data shows that depending on the evolution in E-glass vinyl ester and carbon composites subjected to static
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